1 / 10 Page
CANON OPTRON INC.
SDS Number：
Product Name：

EA03
Ａｌ

SAFETY DATA SHEET
rev. 8.0

SECTION 1

2013/10/16
2024/3/15

Chemicals and company identification

Product nameＡｌ

Product code

EA03

Company nameCANON OPTRON INC.

Address

1744-1, Kanakubo, Yuki-shi, Ibaraki-ken, 307-0015 Japan

Section nameSales Department

Telephone number+81-296-21-3700

Fax number+81-296-21-3770

Emergency telephone tumber+81-296-21-3700

Use

Vacuum deposition material

SECTION 2

Date of Issue
Revised Date

Hazards identification

GHS Classification （A classification by JIS Z 7252 "classification methods such as chemical substances based on GHS"）
Physical hazards

Health hazards

Explosives

Classification not possible

Flammable gases

Not applicable

Aerosols

Not applicable

Oxidizing gases

Not applicableGas under pressure

Not applicable

Flammable liquids

Not applicable

Flammable solids

Classification not possible

Self-reactive substances and mixtures

Classification not possible

Pyrophoric liquids

Not applicable

Pyrophoric solids

Classification not possible

Self-heating substances and mixtures

Classification not possible

Substances and mixtures which,incontact with water,emit flammablegases

Classification not possible

Oxidizing liquids

Not applicable

Oxidizing solids

Classification not possible

Organic peroxides

Classification not possible

Corrosive to metals

Classification not possible

Desensitize explosives

Classification not possible

Acute toxicity(oral)

Classification not possible

Acute toxicity(dermal)

Classification not possible

Acute toxicity (Inhalation: Gases)

Not applicable

Acute toxicity (Inhalation: Vapors)

Classification not possible

2 / 10 Page
CANON OPTRON INC.
SDS Number：
Product Name：

EA03
Ａｌ

SAFETY DATA SHEET
rev. 8.0

Date of Issue
Revised Date

Acute toxicity (Inhalation: Dusts andmists)

Classification not possible

Skin corrosion/irritation

Classification not possible

Serious eye damage/eye irritation

Classification not possible

Respiratory sensitization

Classification not possible

Skin sensitization

Classification not possible

Germ cell mutagenicity

Classification not possible

Carcinogenicity

Classification not possible

Reproductive toxicity

Classification not possible

2013/10/16
2024/3/15

Reproductive toxicity, effects on or via Classification not possible
lactation

Environmental hazards

Specific target organ toxicity(singleexposure)

Category 1

Specific target organ toxicity(repeatedexposure)

Category 1

Aspiration hazardClassification not possible

Hazardous to the aquatic environment
Short-term(acute)Classification not possible

Hazardous to the aquatic environmentLong-term(chronic)

Classification not possible

Hazardous to the ozone layer

Classification not possible

Label elements
hazard Pictograms

Health Hazard
Health Hazard

Signal word

DangerDangerous goods hazard
information

Causes damage to organs Respiratory organs.
Causes damage to organs through prolonged or repeated exposure Respiratoryorgans.

Precautionary statements【Safety measures】

Do not breathe dust/fume/gas/mist/vapours/spray.
Wash hands thoroughly after handling.
Do not eat, drink or smoke when using this product.

3 / 10 Page
CANON OPTRON INC.
SDS Number：
Product Name：EA03ＡｌSAFETY DATA SHEETrev. 8.0

SECTION 3

Date of Issue
Revised Date【First-aid measures】

IF exposed or concerned: Call poison center or doctor/physician.
Get medical advice/attention if you feel unwell.
Specific treatment.

【Storage】

Store locked up.

【Disposal】

Dispose of contents/container in accordance with national regulations.

【Other hazards】-Composition/information on ingredients

Substance/Mixture

Substance

Chemical name

Aluminum

Chemical formulaAlConcentration or concentration
range

99.9%<CAS No.

7429-90-5

TSCA Inventry

Aluminum

EINECS number

231-072-3

Radioactive information

Radioactive substances are not used as the material. Therefore, there is no
reason that ionizing radiation would be generated.

SECTION 4

First aid measures

Inhalation

Remove person to fresh air and keep comfortable for breathing.
Get medical advice/attention if you feel unwell.

Skin contact

Take off immediately all contaminated clothing. Rinse affected areas withwater/shower.
IF ON SKIN：Wash with plenty of soap and water.
If skin irritation or rash occurs: ：Get medical advice/attention.

Eye contact

Rinse cautiously with water for several minutes.Remove contact lenses, if
present and easy to do. Continue rising.
If eye irritation persists：Get medical advice/attention.

Ingestion

Rinse mouth.
Get medical advice/attention.

Most important symptoms andeffects, both acute and delayed

Inhalation: Lung disorder symptoms.
Skin contact: Dermatitis symptoms.

Protection of first aiders

Rescuers, wear suitable protective equipment as the situation demands.

Special precautions for physicians

No data available

2013/10/16
2024/3/15

4 / 10 Page
CANON OPTRON INC.
SDS Number：
Product Name：

EA03
Ａｌ

SAFETY DATA SHEET
rev. 8.0

SECTION 5

Date of Issue
Revised Date

2013/10/16
2024/3/15

Firefighting measures

Suitable extinguishing media

Small fire: dry chemical, soda ash, lime, sandLarge fire: dry sand, dry chemical, soda ash, lime

Unsuitable extinguishing media

Water, foam fire extinguishing agent

Specific hazards

There is a risk of fire heat, flame and sparks.
Is likely to re-ignite after the fire.
Is likely to generate a gas corrosive irritation, toxicity, or by fire.

Specific extinguishing methods

It move a container from the fire area if not dangerous.
Immovable case, it is cooled with water spray in and around the container.
The fire fighting operations performed by a sufficient distance can be effectivelyperformed.
Do not pour water into the container.
Even after the fire, cooling the container thoroughly with a large amount of water.

Special protective equipment for
firefighters

On the occasion of fire extinguishing work, It wear appropriate personal
protective equipment and rescue suit.

SECTION 6

Accidental release measures

Personal precautions, protective
equipment, and emergency
procedures

Do not touch the spilled material, you do not walk therein.
Immediately, It isolate leakage area as the appropriate distance in all directions.
It prohibit the entrance except the person concerned.
Wear, the operator avoid inhalation of gas and contact with eyes, to the skin (seesection "protection measures and 8. Exposure prevention") appropriate
protective equipment.
It stay upwind.
It away from the lowland.
Ventilate Before delving into an enclosed area.

Environmental precautions

It should not be released to the environment.
The Note is discharged into rivers or the like, so as not to cause damage to theenvironment.

Methods and material forcontainment and cleaning up

The leak thing gathers you using a clean antistatic tool and enter the plastics
container and, in the case of a small quantity, do a cover loosely and it is after itand disposes it.
In the case of large quantities, a wall prevents an outflow by laying earth on theground and disposes it later. You must not take water without instructions.
The removal of the leak thing disposing it depends on the instructions of theexpert.
If it is not dangerous to do so, stop the leak.
It suppress the evaporation and water it to prevent diffusion of the steam.
It do not bet sprinkling on a leakage directly.
It cover with dry soil, sand and flaming retardant materials and It prevent
scattering and do not get it wet in plastic sheeting in the rain more.
It prevent that the powder which It shed covers with plastic sheeting and isscattered and dry it.

Secondary disaster prevention
measures

Promptly remove all sources of ignition (no smoking, sparks, or flames in thevicinity).
Do not pour water into the container or spilled material.

5 / 10 Page
CANON OPTRON INC.
SDS Number：
Product Name：

EA03
Ａｌ

SAFETY DATA SHEETrev. 8.0

SECTION 7

Date of Issue
Revised Date

2013/10/16
2024/3/15

Handling and storage

Precautions for safe handlingTechnical measures

Take measures for equipment as described in “8. Exposure controls/personalprotection” and wear protective equipment.

Safety handling precautions

Because of the risk of occurrence of fire and violent reaction, it is not in contact
with water.
Do not swallow contact, or inhalation.
Avoiding contact with the skin.
Do not get in eyes.
Do not inhale dust, fumes.

Avoidance of contact

No contact with acid, alcohol, oxidant, and water.

Hygiene measures

Wash hands thoroughly after handling.
Do not eat, drink or smoke when using this product.

Conditions for safe storage,including any incompatibilities

SECTION 8

Safe storage conditions

Because there is a crisis of the outbreak of the intense reaction and fire, youremove possibility of any contact with the water, and keep it.
Keep it in a dry place or an airtight container.
Store locked up.

Safety packaging material

It use the container which It can seal up without damage and the leak.

Exposure controls/personal protection
AlPermissible concentration
ＡＣＧＩＨ

Appropriate engineering controls

TLV-TWA: 1 mg/㎥ of (R) (metal aluminum and insoluble compound)(2015 version)
In the work shop which dust produces, It use a device, an apparatus sealed up by
all means or a local ventilator.

Individual protection measures,such as personal protective
equipment

SECTION 9Respiratory protection

Dustproof mask

Hand protection

Protective gloves

Eye/face protection

Dust-proof glasses

Skin protection

Protective clothing

Physical and chemical properties

Appearance

6 / 10 Page
CANON OPTRON INC.
SDS Number：
Product Name：EA03ＡｌSAFETY DATA SHEETrev. 8.0

Physical state

SolidFormPellet, wiry

ColourSilvery whiteOdour

None

Date of Issue
Revised Date

Al
Melting point/freezing point

660℃

Boiling point or initial boiling point
and boiling range

2327℃

Flammability

No data available

Upper/lower flammability orexplosive limits

No data available

Flash point

No data available

Auto-ignition temperature

590℃

Decomposition temperature

No data available

pHNo data available

Kinematic viscosity

No data available

Solubility
Water

Insoluble

Other solvents

Hydrochloric acid, sulfuric acid, alkali: Soluble (HSDB (2015))

Partition coefficient: noctanol/water

No data available

Vapour pressure

1 mmHg (1,284 degrees Celsius) (HSDB (2015))

Density and/or relative density

2.7（Density）
Relative vapor density

No data available

Particle characteristics

No data available

Other information

No data available

SECTION 10Stability and reactivity
AlReactivity

It burn whether powder, foil, the ribbon heat up when It mention a flame.
It is a non-flammable solid.
It hardly comes loose in water.

Chemical stability

No data available

2013/10/16
2024/3/15

7 / 10 Page
CANON OPTRON INC.
SDS Number：
Product Name：EA03ＡｌSAFETY DATA SHEETrev. 8.0

Date of Issue
Revised Date

2013/10/16
2024/3/15

Possibility of hazardous reactions

It fire it by overheat, a shock, friction, and the thing which It mixed with anoxidizer may self-ignite with moisture and water.
It may cause a dust explosion when It mix it with air with a powder and granuleform.
It may self-ignite when It contact halogen.
Hydrogen is generated when It contact water, acid, alkali, and hydrogen mayerupt.
(powder), in response to water, alcohol, react with an oxidizer, strong acid,organochlorine intensely again, and pose the danger of a fire and the explosion.

Conditions to avoid

Fire, friction, the strict prohibition including the shock.

Incompatible materials

Water, alkali, acid, oxidizer, alcohol

Hazardous decomposition products No data available

SECTION 11

Toxicological information
Al

Acute toxicity(oral)

No data available

Acute toxicity(dermal)

No data available

Acute toxicity （Inhalation: Gases）

Solid (GHS definition)

Acute toxicity （Inhalation:Vapours）

Solid (GHS definition)

Acute toxicity （Inhalation: Dustsand mists）

No data available

Skin corrosion/irritation

No data available

Serious eye damage/irritation

The classification is not possible due to lack of data. Besides, it is written that
dust of this substance may cause mild inflammation in eyes (HSDB (Access onJune 2015)).

Respiratory or skin sensitization

No data available

Germ cell mutagenicity

The classification is not possible due to lack of data. There are no in vivo and invitro data for metallic aluminum.

Carcinogenicity

In 1970's, increased incidences of bladder and lung cancers were reported inworkers at electrolysis tank of aluminum reduction plants. In IARC, working in thealuminum refining process is related to increased risk of cancers in workers, but
it is estimated that the causative substance of cancers is not aluminum itself, but
polycyclic aromatic hydrocarbon compounds, known carcinogens, or coal tar pitch
volatiles, which are by-products derived from the decomposition of electrodes inthe electrolysis tank. (IARC Suppl. 7 (1984), ACGIH (7th, 2008), ATSDR (2008))
As results of following epidemiological studies, some reports suggested afunctional disorder of respiratory organs, or non-tumor lesions in respiratoryorgans by exposure to this substance, but there is no report on carcinogenicity(ACGIH (7th, 2008), ATSDR (2008)). Therefore, ACGIH classified in A4 (ACGIH(7th, 2008)). From the above, the substance was classified as "Classification notpossible" in this hazard class.

8 / 10 Page
CANON OPTRON INC.
SDS Number：
Product Name：EA03ＡｌSAFETY DATA SHEETrev. 8.0

Reproductive toxicity

Date of Issue
Revised Date

2013/10/16
2024/3/15

Due to no information on reproductive toxicity by exposure to this substance, theclassification is not possible due to lack of data. Besides, it is reported that in atest in which aluminum chloride or aluminum lactate was dosed in an oral route topregnant rats during a gestation period, or to neonatal rats on day 5-17 after
birth, delayed neurobehavioral development or hypoactivity was observed innewborns (ACGIH (7th, 2008), ATSDR (2008)).

Specific target organ toxicity(single This substance (dust, powder) is irritating to the respiratory tract (HSDB (Accessexposure)on June 2015)). As for humans, inhalation of this substance (dust) could causelung disorder such as pneumoconiosis (aluminosis) (HSDB (Access on June2015)). As for experimental animals, it is reported that in single inhalation
exposure to this substance (dust) in rats, no change in pulmonary function but
enzymatic and cytological changes in bronchoalveolar lavage fluid were observed
at 0.05 mg/L, and microgranuloma development occurred in the lung and hilumlymph nodes (microscopic observation) at 0.2 mg/L. These were observed atdoses corresponding to Category 1 (ACGIH (7th, 2008), PATTY (6th, 2012)).
From the above, because this substance has effects on the respiratory organs ininhalation exposure, it was classified in Category 1 (respiratory system). Besides,
respiratory tract irritation was included in effects on the respiratory organs.
By adding new information, the previous classification was revised.

Specific target organtoxicity(repeated exposure)

As for humans, in an epidemiological survey of 1,142 workers related to
manufacturing aluminum and its compounds (1975-1981), effects on lung function
were observed in exposure to dust of high concentration (> 100 mg/㎥-year as
total dust), and in chest X-ray examination, small and irregular nodes werereported in a lower part of the lung in 7-8% (ACGIH (7th, 2008)).
As for experimental animals, there is no test report using this substance.
Therefore, the substance was classified in Category 1 (respiratory system).
Besides, as for humans, it is written that decreased cognitive test results wereobserved, but the clear conclusion was not be drawn (ATSDR (2008)). Moreover,
it is written that aluminum is not a factor causing Alzheimer's disease at thistime, and that in many studies, there is no consistent relationship between
aluminum and nervous disorder (ACGIH (7th, 2008)). Therefore, central nervous
system was not included in a target organ.

Aspiration hazard

No data available

Other information

No data available

SECTION 12

Ecological information
AlToxicity
Hazardous to the aquatic
environment Shortterm(acute)Hazardous to the aquatic
environment Longterm(chronic)

No data available

Persistence and degradablility

No data available

Bioaccumulative potential

No data available

Mobility in soil

No data available

Hazard to the ozone layer

No data available

Other adverse effects

No data available

No data available9 / 10 Page
CANON OPTRON INC.
SDS Number：
Product Name：

EA03
Ａｌ

SAFETY DATA SHEET
rev. 8.0

SECTION 13

Date of Issue
Revised Date

2013/10/16
2024/3/15

Disposal considerations

Waste treatment methods

Process is contracted to industrial waste disposers who received approval of aprefectural governor.

Contaminated container andcontaminated packaging

The container is recycled after being cleaned, or is appropriately processed
according to the standards of related laws and regulations.
When disposing of empty containers, the contents should be completely removed.

SECTION 14

Transport information
AlInternational regulation
UN number

Not applicable

UN proper shipping nameNot applicable

UN classification

Not applicable

Transport hazard class

Not applicable

Packing group

Not applicable

Hazardous to the aquaticenvironment

No data available

Maritime transport in bulk
according to IMO instruments

No data available

Japanese lows and regulations

Refer to “15. Regulatory information.”

Special precautions for users

Requires retention of yellow card when transporting.
When transporting, protect from direct sunlight and take on cargo without
breakage of container, corrosion and leakage.
Do not stack heavy good thereupon.

Special Provisions-SECTION 15

Regulatoly information（Japan）
Al

Occupational Safety and Health
Law

There is it in the case of an application or an application

PRTR Law

Not applicable

Poisonous and Deleterious
Substances control Law

Not applicable

Labor Standards Act

There is it in the case of an application or an application

Chemical substances control Law

Not applicable

Fire fighting Law

There is it in the case of an application or an application

Air Pollution Control Act

Not applicable10 / 10 Page
CANON OPTRON INC.
SDS Number：
Product Name：

EA03
Ａｌ

SAFETY DATA SHEET
rev. 8.0

Date of Issue
Revised Date

Water Pollution Prevention Act

There is it in the case of an application or an application

Water Supply Act

There is it in the case of an application or an application

Sewerage Act

Not applicable

Marine Pollution Prevention Law

Not applicable

Waste Management and Public
Cleansing Act

Not applicable

NoteEnsure this material in compliance with federal requirements and ensure
conformity to local regulations.

SECTION 16

2013/10/16
2024/3/15

Other information

The Safety Data Sheet (SDS) has been prepared based on currently available materials, information and data, and may berevised based on new information. Further, the important points in the SDS are made for the purpose of normal handling.
When handling the user product in a specialized manner, take the appropriate safety measures for the application or method.
Further, Canon Optron Inc. has paid sufficient attention to the described contents of the SDS, but does not guarantee theaccuracy of its contents.
The SDS prepared by our company includes all findings from our investigation for reference. Not applicable to all items listed.

Literature Reference[WEB site]
National Institute of Technology and Evaluation Homepage
Japan Advanced Information Center of Safety and Health Homepage
Ministry of Health, Labour and Welfare Homepage[Regulatory review Tools]
ezCRIC+ (Japan Chemical Database Ltd)