Product Name: IJ Primer PR-100
SDS No. 037-O050453
First issue: 2016/07/27
Revised: 2022/02/25

Safety Data Sheets
1.

Identification

Product Name

: IJ Primer PR-100

Order No.

: SPC-0732/SPC-0731/PR100-Z-BA/PR100-Z-CA/PR100-Z-C6

General Use: For ink jet printer

Product Description: The undercoating liquid

SDS Number: 037-O050453

Manufacture
Company Name

: Mimaki Engineering Co., Ltd.

Address: 2182-3 Shigeno-otsu, Tomi-shi, Nagano 389-0512 JAPAN

Telephone No.

: +81-268-64-2413

Importer / Distributor Established in USA
Company Name

: MIMAKI USA, INC.

Address: 150 Satellite Boulevard NE , suite A, Suwanee, Georgia 30024,
U.S.A.

Telephone No.

: +1-678-730-0170

Emergency Telephone No.

: +1 866 928 0789 (within United States only, Toll free)+1 215 207 0061

2.

Hazards Identification[GHS Classification]
Physical Hazards
Flammable Liquids: Not classifiedHealth Hazards
Skin Corrosion / Irritation: Category 2

Eye Damage / Irritation: Category 2ASensitization – Skin

: Category 1A

Toxic to Reproduction: Category 2

Specific Target Organ Toxicity: Category 3(Single Exposure)Specific Target Organ Toxicity(Repeated Exposure): Category 1 (central nervous system, blood,
respiratory system, and thyroid gland)

Environmental Hazards

Page 1 of 13

Product Name: IJ Primer PR-100
SDS No. 037-O050453
First issue: 2016/07/27
Revised: 2022/02/25

Safety Data Sheets
Hazardous to the Aquatic: Category 1

Environment - Acute Hazard
Hazardous to the Aquatic: Category 1

Environment - Long Term Hazard
The above list does not include category being non-classifiable or not-applicable.
[GHS Label Elements]
SymbolSignal Word
DangerHazard Statements
H315 Causes skin irritation.
H317 May cause an allergic skin reaction
H319 Cause serious eye irritation
H335 May cause respiratory irritation.
H361 Suspected of damaging fertility or the unborn child
H372 Causes damage to organs through prolonged or repeated exposure (central
nervous system, blood, respiratory system, and thyroid gland)
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
Precautionary Statements[Prevention]
P201 Obtain SDS (Safety Data Sheet) and printer's operation manual before use.
P202 Do not handle until all safety precautions have been read and understood.
P260 Do not breathe gas/mist.
P264 Wash thoroughly after handling.
P270 Do not eat, drink, or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
[Response]
P302+P352 IF ON SKIN: Wash with plenty of soap and water.
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position
comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P312 Call a POISON CENTER or doctor/physician if you feel unwell.
P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
P337+P313 If eye irritation persists: Get medical advice/attention.
P362+P364 Take off contaminated clothing and wash before re-use.
Page 2 of 13

Product Name: IJ Primer PR-100
SDS No. 037-O050453
First issue: 2016/07/27
Revised: 2022/02/25

Safety Data Sheets

P391 Collect spillage.
[Storage]
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
[Disposal]
P501 Dispose of contents/container in accordance withlocal/regional/national/international regulation (to be specified).
NFPA Rating (scale 0 – 4)
Health = 2
1

Flammability = 1
Instability = 020Special = None
3.

Composition / Information on IngredientsNo

Chemical Name

Wt%

CAS No.

1

Acryl acid ester A

40-50

Trade Secret2

Acryl acid ester B

30-40

Trade Secret

3

Initiator

5-15

Trade Secret

42-Ethylhexyl acrylate

5-10103-11-75Additive

0.1-1

Trade Secret

4.

First Aid Measures

Inhalation: Remove person to fresh air and keep comfortable for breathing. Giveartificial respiration if not breathing. Call a POISON CENTER or
doctor/physician.

Eye Contact: Flush eyes with plenty of water for at least 15 minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. If
irritation or pain persists after fifteen minutes of eye irrigation, seek
medical attention.

Skin Contact: Wash with plenty of soap and water. If skin irritation or rash occurs:
Get medical advice/attention. Take off contaminated clothing andwash before re-use.

Ingestion: If swallowed, get medical attention. If vomiting occurs, keep headlower than hips to help prevent aspiration.

Most Important Symptoms/Effects
Acute: skin irritation, eye irritation, allergic skin reaction, respiratory tract
Page 3 of 13

Safety Data Sheets

Product Name: IJ Primer PR-100
SDS No. 037-O050453
First issue: 2016/07/27
Revised: 2022/02/25

irritation.
Delayed: allergic skin reaction, reproductive effects, central nervous systemdamage, blood disorders, respiratory system damage, thyroid
effects.

Indication of Immediate: Treat symptomatically and supportively.

Medical Attention andSpecial Treatment
Needed, If Needed
5.

Fire Fighting Measures

Flammable Properties: Flash point >93℃

Extinguishing Media: carbon dioxide, regular dry powder, regular dry chemical, water
spray, alcohol resistant foam.

Unsuitable Extinguishing: Do not scatter spilled material with high-pressure water streams.

Media
Special Hazards Arising: Irritating fumes and gases may be released upon thermal processing

from the Chemicalor during combustion.

Hazardous Combustion: oxides of carbon.

Products
Fire Fighting: Move container from fire area if it can be done without risk. Do not

Measuresscatter spilled material with high-pressure water streams. Coolcontainers with water spray until well after the fire is out. Stay
away from the ends of tanks. Avoid inhalation of material or
combustion by-products.

Special Protective: Wear full protective fire fighting gear including self contained

Equipment andbreathing apparatus (SCBA) for protection against possible

Precautions for

exposure.

Firefighters
6.

Accidental Release Measures

Personal Precautions,: Wear personal protective clothing and equipment, see Section 8.

Protective Equipment
and Emergency
Procedures
Page 4 of 13

Safety Data Sheets

Product Name: IJ Primer PR-100
SDS No. 037-O050453
First issue: 2016/07/27
Revised: 2022/02/25

Methods and Materials: Eliminate all ignition sources if safe to do so. Stop leak if possible

for Containment andwithout personal risk. Reduce vapors with water spray.

Cleaning Up

Small spills: Absorb with sand or other non-combustible material.
Collect spilled material in appropriate container for disposal.
Large spills: Dike for later disposal. Keep unnecessary people away,
isolate hazard area and deny entry. Stay upwind and keep out of low
areas.

Environmental: Avoid release to the environment.

Precautions
7.

Handling and Storage

Precautions for Safe

: Obtain special instructions before use. Do not handle until all safety

Handling

precautions have been read and understood. Do not breathe vapor or
mist. Use only outdoors or in a well-ventilated area. Avoid contact
with eyes, skin and clothing. Do not eat, drink, or smoke when using
this product. Wear protective gloves/clothing and eye/face protection.
Wash thoroughly after handling. Contaminated work clothing should
not be allowed out of the workplace.

Conditions for Safe

: Store in a well-ventilated place. Keep container tightly closed.

Storage, including any

Store locked up.

Incompatibilities

Store and handle in accordance with all current regulations andstandards. Keep separated from incompatible substances.

Incompatible Materials
8.

: oxidizing materials, acids, bases, peroxides.

Exposure Controls / Personal Protection

Component Exposure: The following constituents are the only constituents of the product

Limitswhich have a PEL, TLV or other recommended exposure limit. At thistime, the other constituents have no known exposure limits.

ACGIH - Threshold: There are no biological limit values for any of this product's

Limit Values - Biologicalcomponents.

Exposure Indices (BEI)
Exposure Controls
Occupational Exposure Controls
Page 5 of 13

Product Name: IJ Primer PR-100
SDS No. 037-O050453
First issue: 2016/07/27
Revised: 2022/02/25

Safety Data Sheets
Appropriate: Provide local exhaust or process enclosure ventilation system. Ensure

Engineering Controls

compliance with applicable exposure limits.

Personal Protection
Respiratory: Consult with a health and safety professional for specific respirators

Protection

appropriate for your use.

Hand Protection: Wear appropriate chemical resistant gloves.

Eye Protection: Wear splash resistant safety goggles with a faceshield.

Skin Protection: Wear appropriate chemical resistant clothing.

Protective: Provide an emergency eye wash fountain and quick drench shower inMaterials
9.

the immediate work area.

Physical and Chemical Properties

Appearance- Physical State: Liquid- Color: pale yellow clear

Odor: unique odorpH

: Not available

Boiling Point / Boiling Range: Not available

Melting Point / Melting Range: Not available

Decomposition Temperature: Not available

Flash Point: >93℃

Auto ignition temperature: Not available

Flammability (Solid, Gas)

: Not available

Explosive Properties: Not available
Page 6 of 13

Product Name: IJ Primer PR-100
SDS No. 037-O050453
First issue: 2016/07/27
Revised: 2022/02/25

Safety Data Sheets
Oxidizing Properties: Not available

Upper / Lower Flammability or: Not available

Explosive Limits
Vapor Pressure
Specific Gravity: 1.03 (25℃)

Solubility: Not available

Water Solubility: Not available

Partition Coefficient (n-octanol / Water): Not available

Viscosity: 19±3 mPa・s (25℃)

Vapor Density: Not available

Evaporation Rate

: Not available

VOC: Not available

10. Stability and Reactivity
Reactivity: No reactivity hazard is expected.

Chemical Stability: Stable under normal conditions of use.

Possibility of Hazardous: Will not polymerize.

Reactions
Conditions to Avoid: Avoid flames, sparks, and other sources of ignition. Avoid contact
with incompatible materials.

Incompatible Materials: oxidizing materials, acids, bases, peroxides.

Hazardous: Combustion: oxides of carbon.

Decomposition
11. Toxicological Information
Acute Toxicity: The components of this material have been reviewed in various

Component Analysis -sources and the following selected endpoints are published:

LD50/LC50

Acryl acid ester A (Trade Secret)
Oral LD50 Rat 4890 mg/kg
2-Ethylhexyl acrylate (103-11-7)
Oral LD50 Rat 4435 mg/kg
Dermal LD50 Rabbit 7522 mg/kg
Product Toxicity Data
Acute Toxicity Estimate
Page 7 of 13

Safety Data Sheets

Product Name: IJ Primer PR-100
SDS No. 037-O050453
First issue: 2016/07/27
Revised: 2022/02/25

Dermal > 2000 mg/kg
Oral > 2000 mg/kg
Information on Likely Routes of Exposure
Inhalation: irritation, headache, respiratory system damage.

Ingestion: vomiting, nausea.

Skin Contact: irritation, allergic skin reaction.

Eye Contact: irritation

Immediate Effects: skin irritation, eye irritation, allergic skin reaction, respiratory tract
irritation.

Delayed Effects: allergic skin reaction, reproductive effects, central nervous systemdamage, blood disorders, respiratory system damage, thyroid effects.

Irritation/Corrosivity: skin irritation, eye irritation.

Data
Respiratory: No information available for the product.

Sensitization
Dermal Sensitization: May cause an allergic skin reaction.

Component: 2-Ethylhexyl acrylate (103-11-7)

Carcinogenicity

IARC: Monograph 60 [1994] (Group 3 (not classifiable))Germ Cell Mutagenicity: No information available for the product.

Tumorigenic Data

: No information available for product.

Reproductive Toxicity: Available data characterizes components of this product asreproductive hazards.

Specific Target Organ: respiratory tract.

Toxicity - Single
Exposure
Specific Target Organ: central nervous system, blood, respiratory system, thyroid gland.

Toxicity - Repeated
Exposure
Aspiration Hazard: Not expected to be an aspiration hazard.

Medical Conditions: No information available for the product.

Aggravated by Exposure
12. Ecological Information
Handling is noted because it might influence the environment whenleaking and abandoning it.
Page 8 of 13

Safety Data Sheets

Product Name: IJ Primer PR-100
SDS No. 037-O050453
First issue: 2016/07/27
Revised: 2022/02/25

Especially, note that the product doesn't flow directly to ground, theriver, and the drain ditch.
Ecotoxicity: Very toxic to aquatic life with long lasting effects.

Component Analysis -: 2-Ethylhexyl acrylate (103-11-7)

Aquatic Toxicity

Algae: EC50 72 h Desmodesmus subspicatus 44 mg/L IUCLID ; EC50
96 h Desmodesmus subspicatus 47 mg/L IUCLID
Invertebrate: EC50 48 h Daphnia magna 17.45 mg/L IUCLID

Persistence and: No information available for the product.

Degradability
Bioaccumulation: No information available for the product.

Mobility: No information available for the product.

Other Toxicity: No information available for the product.

13. Disposal Considerations: Comply with all USA, national and local regulations.
Do not dump this product into sewers, on the ground or into any bodyof water.
Disposal Methods: Dispose in accordance with all applicable regulations.

Component Waste: The U.S. EPA has not published waste numbers for this product's

Numbers

components.

Disposal of: Empty containers may contain product residue. Dispose inContaminatedaccordance with all applicable regulations.

Packaging
14. Transport Information
US DOT Information
Shipping: Environmentally hazardous substance, liquid, n.o.s.

Name(Contains: Acryl acid ester)

UN Number: UN3082

Hazardous Class or:9

Division
Packing Group (PG)

: III

Label(s) Required:9

TDG Information
Page 9 of 13

Safety Data Sheets

Product Name: IJ Primer PR-100
SDS No. 037-O050453
First issue: 2016/07/27
Revised: 2022/02/25

Shipping: Environmentally hazardous substance, liquid, n.o.s.

Name(Contains: Acryl acid ester)

UN Number: UN3082

Hazardous Class or:9

Division
Packing Group (PG)

: III

Label(s) Required:9

Marine Pollutant: YesInternational Bulk

: This material contains one or more of the following chemicals

Chemical Coderequired by the IBC Code to be identified as dangerous chemicals inbulk.
2-Ethylhexyl acrylate (103-11-7)
IBC Code: Category Y

Remarks: Single or inner packaging less than 5 L (liquid) or 5 kg net (solids) is
excepted from Dangerous Goods regulations.
Refer to ICAO/IATA A197, IMDG 2.10.2.7, ADR SP 375.

15. Regulatory Information
U.S. Federal: None of this products components are listed under SARA Sections

Regulations

302/304 (40 CFR 355 Appendix A), SARA Section 313 (40 CFR
372.65), CERCLA (40 CFR 302.4), TSCA 12(b), or require an OSHA
process safety plan.

SARA Section 311/312: Acute Health: Yes(40 CFR 370 Subparts B

Chronic Health: Yes

and C) 2016 reporting

Fire: No

categories

Pressure: No
Reactive: No

SARA Section 311/312: Reproductive Toxicity; Skin Corrosion/Irritation; Respiratory/Skin(40 CFR 370 Subparts B

Sensitization; Serious Eye Damage/Eye Irritation; Specific Target

and C) 2017 reporting

Organ Toxicity

categories
U.S. State Regulations: The following components appear on one or more of the following
state hazardous substances lists:
Page 10 of 13

Product Name: IJ Primer PR-100
SDS No. 037-O050453
First issue: 2016/07/27
Revised: 2022/02/25

Safety Data Sheets
Component
2-Ethylhexyl acrylate
California Proposition 65

CAS

CA

MA

MN

NJ

PA

(103-11-7)

No

Yes

No

Yes

Yes

: WARNING
This product can expose you to chemicals including Phenyl
glycidyl ether, Toluene, and 2-Ethylhexyl acrylate which are
known to the State of California to cause cancer/ birth defects
or other reproductive harm. For more information go to
www.P65Warnings.ca.gov.

Canada Regulations
Canadian WHMIS: Components of this material have been checked against the

Ingredient Disclosure

Canadian WHMIS Ingredients Disclosure List. The List is composed

List (IDL)of chemicals which must be identified on MSDSs if they are included
in products which meet WHMIS criteria specified in the Controlled
Products Regulations and are present above the threshold limits
listed on the IDL.
2-Ethylhexyl acrylate (103-11-7)
1%Component Analysis – Inventory
Acryl acid ester A (Trade Secret)
US

Yes

CA

DSL

EU

EIN

AU

Yes

PH

Yes

JP

-

JP

-

KR

KECI

-

KR

KECI

-

KR - REACH

CN

NZ

MX

TW

ENCS

ISHL

Annex 1

Annex 2

CCA

Yes

Yes

Yes

No

No

Yes

Yes

No

Yes

KR - REACH

CN

NZ

MX

TW

Acryl acid ester B (Trade Secret)
US

Yes

CA

NSL

EU

EIN

AU

Yes

PH

No

JP

-

JP

-

KR

KECI

-

KR

KECI

-

ENCS

ISHL

Annex 1

Annex 2

CCA

Yes

Yes

Yes

No

No

Yes

Yes

No

Yes

KR - REACH

CN

NZ

MX

TW

Initiator (Trade Secret)
US

Yes

CA

DSL

EU

EIN

AU

Yes

PH

Yes

JP

-

JP

-

KR

KECI

-

KR

KECI

-

ENCS

ISHL

Annex 1

Annex 2

CCA

Yes

Yes

Yes

No

No

Yes

Yes

Yes

Yes

KR - REACH

CN

NZ

MX

TW

2-Ethylhexyl acrylate (103-11-7)
US

CA

EU

AU

PH

JP
ENCS

-

JP
ISHL

-

KR

KECI

Annex 1

-

KR

KECI

Annex 2-

CCA

Page 11 of 13

Product Name: IJ Primer PR-100
SDS No. 037-O050453
First issue: 2016/07/27
Revised: 2022/02/25

Safety Data Sheets
Yes

DSL

EIN

Yes

Yes

Yes

Yes

Yes

No

No

Yes

Yes

Yes

Yes

KR - REACH

CN

NZ

MX

TW

No

No

No

No

Additive (Trade Secret)
US

No

CA

No

EU

No

AU

No

PH

No

JP

-

JP

-

KR

KECI

-

KR

KECI

-

ENCS

ISHL

Annex 1

Annex 2

CCA

No

No

No

No

No

16. Other Information
Key/Legend
ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road
Transport; AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada;
CA/MA/MN/NJ/PA - California/Massachusetts/Minnesota/New Jersey/Pennsylvania*; CAS Chemical Abstracts Service; CERCLA - Comprehensive Environmental Response,
Compensation, and Liability Act; CFR - Code of Federal Regulations (US); CLP - Classification,
Labelling, and Packaging; CN - China; CPR - Controlled Products Regulations; DFG - Deutsche
Forschungsgemeinschaft; DOT - Department of Transportation; DSD - Dangerous SubstanceDirective; DSL - Domestic Substances List; EC – European Commission; EEC - European
Economic Community; EIN - European Inventory of (Existing Commercial Chemical
Substances); EINECS - European Inventory of Existing Commercial Chemical Substances;
ENCS - Japan Existing and New Chemical Substance Inventory; EPA - Environmental
Protection Agency; EU - European Union; F - Fahrenheit; IARC - International Agency for
Research on Cancer; IATA - International Air Transport Association; ICAO - International Civil
Aviation Organization; IDL - Ingredient Disclosure List; IDLH - Immediately Dangerous to Lifeand Health; IMDG - International Maritime Dangerous Goods; ISHL - Japan Industrial Safety
and Health Law; IUCLID - International Uniform Chemical Information Database; JP - Japan;
Kow - Octanol/water partition coefficient; KR KECI Annex 1 - Korea Existing Chemicals
Inventory (KECI) / Korea Existing Chemicals List (KECL); KR KECI Annex 2 - Korea Existing
Chemicals Inventory (KECI) / Korea Existing Chemicals List (KECL) , KR - Korea; LD50/LC50 Lethal Dose/ Lethal Concentration; LEL - Lower Explosive Limit; LLV - Level Limit Value; LOLI
- List Of LIsts™ - ChemADVISOR’s Regulatory Database; MAK - Maximum Concentration
Value in the Workplace; MEL - Maximum Exposure Limits; MX – Mexico; NDSL – Non-Domestic
Substance List (Canada); NFPA - National Fire Protection Agency; NIOSH - National Institutefor Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National
Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration;
Page 12 of 13

Safety Data Sheets

Product Name: IJ Primer PR-100
SDS No. 037-O050453
First issue: 2016/07/27
Revised: 2022/02/25

PEL- Permissible Exposure Limit; PH - Philippines; RCRA - Resource Conservation andRecovery Act; REACH- Registration, Evaluation, Authorisation, and restriction of Chemicals;
RID - European Rail Transport; SARA - Superfund Amendments and Reauthorization Act; STEL
- Short-term Exposure Limit; TCCA – Korea Toxic Chemicals Control Act; TDG - Transportationof Dangerous Goods; TLV - Threshold Limit Value; TSCA - Toxic Substances Control Act; TW –Taiwan; TWA - Time Weighted Average; UEL - Upper Explosive Limit; UN/NA - United Nations/North American; US - United States; VLE - Exposure Limit Value (Mexico); WHMIS Workplace Hazardous Materials Information System (Canada).
Other Information
This information is furnished without warranty, express or implied, except that it is accurate to
the best knowledge of Mimaki Engineering Corporation.
It relates only to the specific material designated herein, and does not relate to use incombination with any other material or process.
Mimaki Engineering Corporation assumes no legal responsibility for use or reliance upon thisinformation.

Page 13 of 13