SAFETY DATA SHEETDoc.No. SDE02009R1

SUMIKAFLEX® 950HQ Series
Revision Date:
10.11.2021

Spec ID:
900000052196

Date of last issue: 12.11.2019
Date of first issue: 19.08.2016

1. PRODUCT AND COMPANY IDENTIFICATION
Product name: SUMIKAFLEX® 950HQ Series(ADHESIVES F-3 )Manufacturer or supplier's details
Details of the supplier of the safety data sheet
Manufacturer or supplier’s details Company name of supplier：
HISAKA WORKS, LTD.QA Sect. HEAT EXCHANGER DIV.
Address：2-1-48, HIGASHI-KONOIKECHO HIGASHI-OSAKA CITY OSAKA 578-0972, JAPANTelephone：+81-72-966-9606
Emergency telephone number：+81-72-966-9606

Recommended use of the chemical and restrictions on use
Recommended use: For general industrial use

2. HAZARDS IDENTIFICATIONGHS Classification
Explosives:

Classification not possible

Flammable gases:

Not applicable

Aerosols:

Not applicable

Oxidizing gases:

Not applicable

Gases under pressure:

Not applicable

Flammable liquids:

Not classified

Flammable solids:

Not applicableSelf-reactive substances and mixtures:

Classification not possible

Pyrophoric liquids:

Not applicable

Pyrophoric solids:Not applicableSelf-heating substances and mixtures:

Classification not possible

Substances and mixtures, which in contact :with water, emit flammable gases

Not applicable

Oxidizing liquids:

Classification not possible

Oxidizing solids:

Not applicableSDS No. FFARD1638ENG4SG 1 / 11

SAFETY DATA SHEETDoc.No. SDE02009R1

SUMIKAFLEX® 950HQ Series
Revision Date:
10.11.2021

Spec ID:
900000052196

Date of last issue: 12.11.2019
Date of first issue: 19.08.2016

Organic peroxides:

Not applicable

Corrosive to metals:

Classification not possible

Acute toxicity (Oral):Classification not possible

Acute toxicity (Dermal):

Classification not possible

Acute toxicity (Inhalation - gas):

Not applicable

Acute toxicity (Inhalation - vapor):

Classification not possible

Acute toxicity (Inhalation - dust and mist):

Classification not possible

Skin corrosion/irritation:

Classification not possible

Serious eye damage/eye irritation:

Classification not possible

Respiratory sensitisation:

Classification not possible

Skin sensitisation:

Classification not possible

Germ cell mutagenicity:

Classification not possible

Carcinogenicity:

Classification not possible

Reproductive toxicity:

Classification not possibleSpecific target organ toxicity - single
exposure:Classification not possible

Specific target organ toxicity - repeatedexposure:Classification not possible

Aspiration hazard:

Classification not possible

Acute aquatic toxicity:

Classification not possible

Chronic aquatic toxicity:

Classification not possible

Hazardous to the ozone layer:

Classification not possible

GHS label elements
Hazard pictograms:

Not Applicable

Signal word:

Not Applicable

Hazard statements:

Not Applicable

Precautionary statements:

Prevention:
Not Applicable
Response:
Not ApplicableSDS No. FFARD1638ENG4SG 2 / 11

SAFETY DATA SHEETSUMIKAFLEX® 950HQ Series
Revision Date:
10.11.2021

Spec ID:
900000052196

Doc.No. SDE02009R1
Date of last issue: 12.11.2019
Date of first issue: 19.08.2016

Storage:
Not Applicable
Disposal:
Not Applicable
Other hazards which do not result in classification
When heated, the vapors/fumes given off may cause respiratory tract irritation.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance / Mixture:

MixtureChemical Name

CAS-No.

Concentration(%)

Neodecanoic acid, ethenyl ester, polymer with etheneand ethenyl acetate

Trade secret

52-56

Wateremulsifier7732-18-5
Trade secret44-48
Trade secret

4. FIRST AID MEASURES
If inhaled:

Remove victim to fresh air and keep at rest in a position
comfortable for breathing.
Administer oxygen if breathing is difficult.
Apply artificial respiration if victim is not breathing.
Rinse nose, mouth and throat with water.
Keep victim warm with a blanket etc.
Get immediate medical advice/attention.
If vomiting occurs, keep head low so that stomach content
doesn't get into the lungs.

In case of skin contact:

Gently wash with plenty of soap and water.
Remove/Take off immediately contaminated clothing andshoes.
If skin irritation or rash occurs: Get medical advice/attention.

In case of eye contact:

Do not rub eye.
Hold eyelids apart.
Begin to rinse with water as soon as possible and rinse
cautiously for several minutes.
Remove contact lenses, if present and easy to do. Continue
rinsing.
Get immediate medical advice/attention.

If swallowed:

Rinse mouth.
Remove victim to fresh air and keep at rest in a position
comfortable for breathing.
Keep victim warm with a blanket etc.
Get immediate medical advice/attention.
If vomiting occurs, keep head low so that stomach content
doesn't get into the lungs.
Administer oxygen if breathing is difficult.
Apply artificial respiration if victim is not breathing.

SDS No. FFARD1638ENG4SG 3 / 11

SAFETY DATA SHEETSUMIKAFLEX® 950HQ Series
Revision Date:
10.11.2021

Spec ID:
900000052196

Protection of first-aiders

Doc.No. SDE02009R1
Date of last issue: 12.11.2019
Date of first issue: 19.08.2016:

During rescue operations, wear protective equipment (see "8.
Exposure control/personal protection").

Suitable extinguishing media:

Dry chemical powder
Regular foam
Carbon dioxide
Dry sandUnsuitable extinguishing
media

:

Straight streams

Specific hazards during
firefighting:

Cool cylinders/containers with an appropriate cooling means,paying heed to incompatible hazardous substances (see "10.
Stability and reactivity").
The combustion gas may contain an irritating, corrosive and/ortoxic gas.
Harmful gases (see "10. Stability and reactivity") and metaloxide fumes may be released by fire and may cause
dizziness, suffocation, or other health hazards.
Heating may cause cylinders/containers to explode or torocket.

Specific extinguishingmethods:

Evacuate immediately before the cylinder/container
temperature higher than their rupture risk level.
Keep upwind.
Fight fire from a protected location.
Keep unauthorized personnel away.
In case of a large fire and large quantities: Evacuate the areaand extinguish the fire from a distance in accordance with therisk of explosion.
Protecting other nearby combustibles before they catch fire:
Remove cylinders/containers or sprinkle them with water, etc.,
if this can be done safely.
Protecting the product from external fire: Remove productcontaining cylinders/containers to a safe place, or cool thenearby equipment with water, etc., if this can be done safely.
If the fire cannot be stopped, let it burn itself out while coolingwith water spray to prevent the fire from spreading.
Confining and smothering fire is preferable.
Stop leak if possible without any risk.
Dike fire water for later disposal; do not spread the material.
Cool containers with flooding quantities of water until well after
fire is out.

Special protective equipment
for firefighters:

Wear regional, national, and local standards approved firefighting turnout gear and positive pressure self-contained
breathing apparatus (SCBA).
Wear flame-resistant or fireproof clothes, with face shield,
helmet and gloves.

5. FIREFIGHTING MEASURESSDS No. FFARD1638ENG4SG 4 / 11

SAFETY DATA SHEETSUMIKAFLEX® 950HQ Series
Revision Date:
10.11.2021

Spec ID:
900000052196

Doc.No. SDE02009R1
Date of last issue: 12.11.2019
Date of first issue: 19.08.2016

6. ACCIDENTAL RELEASE MEASURES
Personal precautions,protective equipment andemergency procedures:

Personal precautions
Use personal protection recommended in "8. Exposurecontrol/personal protection".
Wear appropriate protective equipment (see "8. Exposure
control/personal protection") to avoid contact of droplets withthe skin, or inhalation of mist or vapors.
Emergency procedures
Evacuate people who are downwind, and keep upwind whileworking.
Keep unauthorized personnel away.
If the surrounding area may be affected (including healthimpairment), warn the nearby residents.
Remove immediately all ignition sources nearby.
Form large safety zone.
Prevention of secondary hazards
ELIMINATE all ignition sources such as heat/sparks/open
flames/hot surfaces/static discharges.
Prepare appropriate extinguishing agent. (See "5. Fire-fightingmeasures")

Environmental precautions:

Avoid release to the environment.

Methods and materials forcontainment and cleaning up:

Collect the leakage promptly.
Stop leak if possible without any risk.
Dike far ahead of liquid spill for later disposal.
Absorb remaining liquid in dry earth, sand or other noncombustible material and remove to safe place.
Use explosion-proof electrical/ventilating/lighting/equipment.
ELIMINATE all ignition sources such as heat/sparks/open
flames/hot surfaces/static discharges.
Consult with an expert when collecting the leakage.
Collect leakage after taking measures for safe handling (see"7. Handling and storage").
See "13. Disposal considerations".

Technical measures:

ELIMINATE all ignition sources.
Take precautionary measures against static electricity such asgrounding and bonding, wearing anti-static footwear andclothing, using grounded conductive floor.
Use explosion-proof electrical/ventilating/lighting/equipment.
Prevent generation of mist.
Use only outdoors or in a well-ventilated area.
Do not eat, drink or smoke when using this product.
Install appropriate equipment and wear appropriate personal
protective equipment (see "8. Exposure control/personalprotection").

Local/Total ventilation:

Ventilate by a system of local and/or general exhaust.

Advice on safe handling:

Keep away from incompatible materials (see "10. Stability andreactivity").

7. HANDLING AND STORAGESDS No. FFARD1638ENG4SG 5 / 11

SAFETY DATA SHEETSUMIKAFLEX® 950HQ Series
Revision Date:
10.11.2021

Conditions for safe storage

Spec ID:
900000052196:

Doc.No. SDE02009R1
Date of last issue: 12.11.2019
Date of first issue: 19.08.2016

Keep in a fire-proof designed place.
Store under controlled lighting and appropriate ventilation.
Take precautionary measures against static electricity such as
grounding and bonding, wearing anti-static footwear andclothing, using grounded conductive floor.
Ground/bond container and receiving equipment.
Keep away from direct sunlight.
Store in a well-ventilated place.
See "10. Stability and reactivity"
Protect from freezing and direct sunlight.
Keep container tightly closed. Store in a well-ventilated coolplace (5 - 30 °C).

Packaging material:

Suitable material: Polyethylene (PE)Unsuitable material: No information available.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters
Contains no substances with occupational exposure limit values.
Engineering measures:

Use a local and/or general ventilation system.
Provide facilities to wash hands, eyes, and the body at theworking place.

Personal protective equipment
Respiratory protection: Be sure to use breathing protective equipment only chosen
according to specific regulatory requirements after a riskassessment.
When an emergency or leak occurs, wear air respirator orpositive pressure self-contained breathing apparatus (SCBA).
Hand protection::

Be sure to use hand protective equipment only chosen
according to specific regulatory requirements after a risk
assessment.
impervious gloves

Eye protection:

Be sure to use eye protective equipment only chosen
according to specific regulatory requirements after a risk
assessment.
chemical safety goggles or glasses and full face shield.

Skin and body protection:

Be sure to use personal protective equipment (PPE) only
chosen according to specific regulatory requirements after arisk assessment.
Suitable impervious protective clothing, including protective
footwear, gloves, lab coat, apron or coveralls.

Hygiene measures:

Do not inhale this product.
Wash face and hands thoroughly after handling.

SDS No. FFARD1638ENG4SG 6 / 11

SAFETY DATA SHEETSUMIKAFLEX® 950HQ Series
Revision Date:
10.11.2021

Spec ID:
900000052196

Doc.No. SDE02009R1
Date of last issue: 12.11.2019
Date of first issue: 19.08.2016

9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance:Emulsion

Colour:Milky whiteOdour:

Slight odorpH:

4.0 - 7.0 (25 °C)

Melting point/freezing point:

no data available

Initial boiling point and boiling
range

:

no data available

Flash point:

Method: Tag closed cup
No data available (Test flame was extinguished by noncombustible vapor generated from the sample during the test.)

Evaporation rate:

no data available

Upper explosion limit:

no data available

Lower explosion limit:

no data available

Vapour pressure:

no data available

Relative vapour density:

no data available

Relative density:

1.0 (25 °C)

Density:no data available

Water solubility:

no data available

Solubility in other solvents:no data available

Partition coefficient: noctanol/water:

no data available

Auto-ignition temperature:

no data available

Decomposition temperature:

no data available

Chemical stability:

no data available

Possibility of hazardous
reactions:Fire may produce metal oxide(s) dust.
Mist may form an explosive mixture with air regardless oftemperature.
Open flame
Mechanical spark
Electrical spark
Welding spark

10. STABILITY AND REACTIVITYSDS No. FFARD1638ENG4SG 7 / 11SAFETY DATA SHEETSUMIKAFLEX® 950HQ Series
Revision Date:
10.11.2021

Spec ID:
900000052196

Doc.No. SDE02009R1
Date of last issue: 12.11.2019
Date of first issue: 19.08.2016

Hot surface(s)heatingFriction heat
Electrostatic discharge
Strong bases: may cause a fire and/or explosion
Strong oxidizers
Strong acids: may cause a fire, explosion, and generation of a toxic gas
Conditions to avoid:

Open flame
Mechanical spark
Electrical spark
Welding spark
heating
Hot surface(s)Electrostatic discharge

Incompatible materials:

Strong oxidizers
Strong acids
Strong basesHazardous decomposition
products:Carbon monoxide
Carbon dioxide
Hydrocarbons
sootNitrogen Oxides
Sulfur oxides.
May generate fine particles containing metal components.

11. TOXICOLOGICAL INFORMATION
Acute toxicity
Product:
Acute oral toxicity:

Remarks: no data available

Acute inhalation toxicity:

Remarks: no data available

Acute dermal toxicity:

Remarks: no data available

Skin corrosion/irritation
Product:
Remarks: no data available
Serious eye damage/eye irritation
Product:
Remarks: no data available

SDS No. FFARD1638ENG4SG 8 / 11

SAFETY DATA SHEETSUMIKAFLEX® 950HQ Series
Revision Date:
10.11.2021

Spec ID:
900000052196

Doc.No. SDE02009R1
Date of last issue: 12.11.2019
Date of first issue: 19.08.2016

Respiratory or skin sensitisation
Product:
Test Type: Respiratory sensitisation
Remarks: no data available
Test Type: Skin sensitisation
Remarks: no data available
Germ cell mutagenicity
Product:
Genotoxicity in vitro:

Remarks: no data available

Genotoxicity in vivo:

Remarks: no data available:

Remarks: no data available:

Remarks: no data available

Carcinogenicity
Product:
Remarks: no data available
Reproductive toxicity
Product:Effects on fertility
Effects on foetal
development
STOT - single exposure
See Acute toxicity ("11.Toxicological information").
STOT - repeated dose toxicity
Product:Remarks: no data available
Aspiration toxicity
Product:no data available
Further information
Product:
Remarks: When heated, the vapors/fumes given off may cause respiratory tract irritation.

SDS No. FFARD1638ENG4SG 9 / 11

SAFETY DATA SHEETSUMIKAFLEX® 950HQ Series
Revision Date:
10.11.2021

Spec ID:
900000052196

Doc.No. SDE02009R1
Date of last issue: 12.11.2019
Date of first issue: 19.08.2016

12. ECOLOGICAL INFORMATION
Ecotoxicity
Product:
Toxicity to fish:

Remarks: no data available

Toxicity to daphnia and other :aquatic invertebrates

Remarks: no data available

Toxicity to algae:

Remarks: no data available

Toxicity to fish (Chronictoxicity):

Remarks: no data available

Toxicity to daphnia and other :aquatic invertebrates(Chronic toxicity)

Remarks: no data available

Persistence and degradability
no data available
Bioaccumulative potential
no data available
Mobility in soil
no data available
Other adverse effects
Ozone-Depletion Potential:Regulation: UNEP - Handbook for the Montreal Protocol on
Substances that Deplete the Ozone Layer
Remarks: not listed to the Montreal Protocol

13. DISPOSAL CONSIDERATIONS
Disposal methods:

Dispose of contents/container appropriately in accordancewith local/regional/national/international regulations.

14. TRANSPORT INFORMATIONInternational Regulations
UNRTDG
Not regulated as dangerous goods
IATA-DGR
Not regulated as dangerous goods
IMDG-CodeNot regulated as dangerous goods
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC CodeNot applicable for product as supplied.
SDS No. FFARD1638ENG4SG 10 / 11

SAFETY DATA SHEETSUMIKAFLEX® 950HQ Series
Revision Date:
10.11.2021

Spec ID:
900000052196

Doc.No. SDE02009R1
Date of last issue: 12.11.2019
Date of first issue: 19.08.2016

Special precautions for user
Remarks: Make sure no damage, corrosion, leaks, and so on on thecontainer(s) before transportation.
Load not to fall, drop, damage the product, and make sure to
take measures to secure the loaded products.
Equip in automobile or ship for transportation with protective
equipment (gloves, eyeglasses, mask, etc), and fire
extinguisher, tools necessary for emergency.

15. REGULATORY INFORMATION
Please follow local regulations.
16. OTHER INFORMATION
The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only as aguidance for safe handling, use, processing, storage, transportation, disposal and release and is
not to be considered a warranty or quality specification. The information relates only to thespecific material designated and may not be valid for such material used in combination with anyother materials or in any process, unless specified in the text.
This Safety Data Sheet is applied to the following products.
SUMIKAFLEX® 950HQSUMIKAFLEX® 951HQSUMIKAFLEX® 955HQ

販売者：株式会社明成商会
大阪府大阪市中央区4-4-1日生伏見町ビル本館5階
06-6201-2931※労働安全衛生法第五十七条の二に基づき表示

SDS No. FFARD1638ENG4SG 11 / 11