Product Name: POLIXRESIN SXSDS No. 037-O030394
First issue: 2015/03/05
Revised: 2019/12/12

Safety Data Sheets
1.

Identification

Product Name

: POLIXRESIN SX

Order No.

: SPC-0397

General Use: Adhesive anti-wrinkling agents for textile printing

Product Description: Adhesive clear liquid

SDS Number: 037-O030394

Manufacture
Company Name

: Mimaki Engineering Co., Ltd.

Address: 2182-3 Shigeno-otsu, Tomi-shi, Nagano 389-0512 JAPAN

Telephone No.

: +81-268-64-2413

Importer / Distributor Established in USA
Company Name

: MIMAKI USA, INC.

Address: 150 Satellite Boulevard NE , suite A, Suwanee, Georgia 30024,U.S.A.

Telephone No.

: +1-678-730-0170

Emergency Telephone No.

: +1 866 928 0789 (within United States only, Toll free)+1 215 207 0061

2.

Hazards Identification[GHS Classification]
Physical Hazards
Flammable Liquids: Category 2

Health Hazards
Acute Toxicity – Oral

: Not classified

Acute Toxicity – Dermal: Not classified

Acute Toxicity – Inhalation: Category 4 (~30% unknown)

Skin Corrosion / Irritation: Category 2

Eye Damage / Irritation: Category 2Carcinogenicity: Category 2

Toxic to Reproduction: Category 1

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Product Name: POLIXRESIN SXSDS No. 037-O030394
First issue: 2015/03/05
Revised: 2019/12/12

Safety Data Sheets
Specific Target Organ Toxicity: Category 1 (respirator, liver, kidneys,(Single Exposure)

central nerve system)
Category 2 (blood vascular system)
Category 3 ( Narcotic effects)

Specific Target Organ Toxicity: Category 1 (respirator, nerve system)(Repeated Exposure)

Category 2 (hearing organ)

Aspiration Hazard: Category 1

Environmental HazardsHazardous to the Aquatic: Category 1

Environment - Acute Hazard
Hazardous to the Aquatic: Category 3

Environment - Long Term Hazard
The above list does not include category being non-classifiable or not-applicable.
[GHS Label Elements]
SymbolSignal Word
DangerHazard Statements
H225 Highly flammable liquid and vapour
H304 May be fatal if swallowed and enters airways
H315 Cause skin irritation
H319 Cause serious eye irritation
H332 Harmful if inhaled
H336 May cause drowsiness or dizziness
H351 Suspected of causing cancer
H360 May damage fertility or the unborn child
H370 Causes damage to organs (respirator, liver, central nerve system)
H371 May causes damage to organs(blood vascular system)
H372 Causes damage to organs through prolonged or repeated exposure(respirator, nerve system)
H373 May cause damage to organs through prolonged or repeated exposure(hearing organ)
H400 Very toxic to aquatic life
H412 Harmful to aquatic life with long lasting effects
Precautionary Statements[Prevention]
P201 Obtain SDS (Safety Data Sheet) and printer's Operation Manual before use.
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Product Name: POLIXRESIN SXSDS No. 037-O030394
First issue: 2015/03/05
Revised: 2019/12/12

Safety Data Sheets

P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from heat/sparks/open flames/hot surfaces.-No smoking.
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ventilating/lighting/equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P260 Do not breathe mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
[Response]
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P302+P352 IF ON SKIN: Wash with plenty of soap and water.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminatedclothing. Rinse skin with water/shower.
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position
comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P308+P311 IF exposed or concerned: Call a POISON CENTER or doctor/physician.
P312 Call a POISON CENTER or doctor/physician if you feel unwell.
P331 Do NOT induce vomiting.
P332+P313 If skin irritation occurs: Get medical advice/attention.
P337+P313 If eye irritation persists: Get medical advice/attention.
P362+P364 Take off contaminated clothing and wash before reuse.
P370+P378 In case of fire: Use dry chemical, carbon dioxide, foam, sand for extinction.
P391 Collect spillage.
[Storage]
P405 Store locked up.
P403+P233+P235 Store in a well-ventilated place. Keep container tightly closed.
Keep cool.
[Disposal]
P501 Dispose of contents/container in accordance with local/regional/national/international regulation (to be specified).
3.

Composition / Information on IngredientsNo

4.

Chemical Name

Wt%

CAS No.

1

Polyalkylsiloxane (Silicon resin)

25-35

Trade Secret2

Cyclohexane

50-65

110-82-7

3

Xylenes5-101330-20-7

4Ethyl benzene

5-10

100-41-4

First Aid Measures
Page 3 of 12

Safety Data Sheets
Inhalation

Product Name: POLIXRESIN SXSDS No. 037-O030394
First issue: 2015/03/05
Revised: 2019/12/12: If inhaled, immediately remove to fresh air and keep warm andcalm.
If breathing irregularly or not breathing, give artificial respirationand consult a doctor immediately.

Eye Contact: Flush eyes thoroughly with water for at least 15 minutes.
Remove contact lenses, if present and easy to do.
Consult a doctor immediately.

Skin Contact: Wash skin thoroughly with plenty of water.
If on clothing, remove immediately contaminated clothing.
If no washing or no taking off the clothing, it may cause
inflammation on the skin.

Ingestion: Do not induce vomiting.
If swallowed, keep calm and consult a doctor immediately.
Keep from swallowing vomit.

Most Important Symptoms/Effects
Acute: cough, respiratory paralysis, stomachache, drowsiness, dizziness,
unconsciousness, nausea, vomiting, stomach / bowel disorders,collapse, narcosis, headache, excitement, spasms, lethargy, skinirritation, eye irritation, central nervous system damage, respirator
damage, liver damage, kidney damage, blood vascular systemdamageDelayed: cancer, reproductive effects, respirator damage, nervous systemdamage,Protection To First-Aiders: Wear tools for appropriate protection.
Ventilate.
See section 7 and 8.

Note To Physician: Treat symptomatically and supportively.
See section 7 and 8.

5.

Fire Fighting Measures

Flammable Properties: Flash point: ≦-20℃
Boiling point: 72℃

Extinguishing Media: Dry chemical, carbon dioxide, foam, sandUnsuitable Extinguishing: Splash water
Page 4 of 12

Safety Data Sheets

Product Name: POLIXRESIN SXSDS No. 037-O030394
First issue: 2015/03/05
Revised: 2019/12/12

Media
Specific Hazards: This product is easy to extremely burn.
There is a possibility that the container will explode by heating.

Fire Fighting: Wear full fire-fighting turn-out gear (full bunker gear) andInstructions

respiratory protection (self-contained breathing apparatus).
Stay upwind. Keep people away. Keep wetted with water
surrounding equipment.

6.

Accidental Release Measures

Personal Precautions: Wear tools for appropriate protection.
Keep unnecessary and unprotected personnel from entering in
vicinity of spill. Ventilate. See section 8.

Land Spill: Promptly remove ignitable, hot, or flammable items. Stop leak if
possible without personal risk. Contain spilled liquid with sand orearth. DO NOT use combustible materials, such as sawdust. Flushthoroughly with plenty of water after removing the spills.
Large spills: Dike for later disposal. Keep unnecessary people away,
isolate hazard area and deny entry.

Water Spill: The material is a water pollutant and should be prevented fromcontaminating soil or from entering sewage and drainage systems
and bodies of water.

Countermeasure to: Remove promptly all ignition sources.

prevent secondary

Prevent flow into drainage ditch, sewers, and closed location such as

disasters

the basement.

7.

Handling and Storage

Handling: Use proper protection to avoid inhalation, touching eyes, nose, skin,and apparels. Do not breathe (vapor, mist, spray). Do not eat, drink or
smoke when using this product. Wash thoroughly after handling.
Destroy contaminated shoes in proper manner. Keep away fromheat/sparks/open flames/hot surfaces.-No smoking. Keep container
tightly closed. Use explosion-proof electrical/ ventilating/ lighting/equipment. To reduce potential for static discharge, bond and groundcontainers and equipment when transferring material. Use
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Product Name: POLIXRESIN SXSDS No. 037-O030394
First issue: 2015/03/05
Revised: 2019/12/12

Safety Data Sheets

spark-proof tools and explosion-proof equipment. Use only outdoors
or in a well-ventilated area.
Storage: No fire. Keep from sunlight. Shut tight the container to avoid
exposing to the air. Keep from open fire or heat source. Do not store
with the oxidizer. Store in a well-ventilated place. Keep container
tightly closed. Keep cool. Store locked up.

Materials to Avoid
8.

: See section 10.

Exposure Controls / Personal Protection

Exposure Limit Values
Chemical

OSHA

ACGIH

NIOSH

California

Name

PEL

TLV

Pocket Guide

OELs

1

XylenesN.E.

TWA :100ppm

TWA :100ppm

STEL :150ppm

STEL: 150ppm

2Ethylbenzene

3

Cyclohexane

No

TWA :100ppm
STEL :125ppm
TWA :300ppm

TWA:20ppm
TWA :100ppm

N.E.

TWA :100ppm

PEL:5ppm

STEL: 125ppm

STEL:30ppm

TWA :300ppm

PEL: 300ppm

California OELs : California-Occupational Exposure Limits
Exposure Controls
Occupational Exposure Controls
Engineering Controls: Use exhaust ventilation to keep airborne concentration below
exposure limits.
Use explosion-proof handling equipment.
Prepare safety shower, lavatory, and washing stand for workers, anddisplay the location visibly.

Personal Protection
Respiratory: An air purifying respirator with organic vapor cartridge or canister

Protection

may be permissible under certain circumstances where air-borne
concentrations are expected to exceed exposure limits.
Protection provided by air purifying respirators is limited.
Use a positive-pressure, air-supplied respirator if there is any
potential for uncontrolled release, exposure levels are unknown, or in
any other circumstances where air-purifying respirators may not
Page 6 of 12

Product Name: POLIXRESIN SXSDS No. 037-O030394
First issue: 2015/03/05
Revised: 2019/12/12

Safety Data Sheets
provide adequate protection.
Hand Protection: Wear gloves resistant to organic solvents and chemicals.

Eye Protection: Wear coverall, chemical goggles and face shield when handling.

Skin Protection: To prevent any contact, wear impervious clothing such as gloves,apron, boots, or whole body suits made from neoprene, asappropriate.

Environmental Exposure Controls: Not Available
9.

Physical and Chemical Properties

Appearance- Physical State: Viscous liquid- Color: Clear light yellowOdor: Specific odor

Boiling Point / Boiling Range: 72℃

Melting Point / Melting Range: Not Available

Flash Point: ≦-20℃

Ignition point: Not Available

Upper / Lower Flammability or: Not Available

Explosive Limits
Specific Gravity: 0.85±0.05(20℃)

Water Solubility: Insoluble

10. Stability and Reactivity
Conditions to Avoid: Heating, high temperature

Stability: Stable under normal temperature and pressure. No self-reactive.

Materials to Avoid: Strong oxidizing agents, strong acids, and strong alkali

Hazardous Reactions /: Carbon monoxide, carbon dioxide, silicon dioxide produced byPage 7 of 12

Product Name: POLIXRESIN SXSDS No. 037-O030394
First issue: 2015/03/05
Revised: 2019/12/12

Safety Data Sheets
Decomposition Productscombustion.

11. Toxicological Information
Acute Toxicity

Eye Irritation: Category 4 (Inhalation) as a product.
OralDermal
Chemical Name（rat）
（rat or rabbit）
LD50
LD50
Cyclohexane
12705mg/kg >2000mg/kg(rat)
LD50
LD50
Xylenes
1700mg/kg>3500mg/kg(rabbit)
LD50
LD50
Ethyl benzene
15400mg/kg
3500mg/kg(rabbit)

LD50(4h)
6350ppm
LD50(4h)
4000ppm: Category 2 as a product.
Chemical NameGHS Classification

Cyclohexane

Category 2A-2B

XylenesCategory 2A-2B

Ethyl benzene
Skin Irritation

Inhalation（rat）
LD50(4h)>13.9mg/L

Category 2B: Category 2 as a product.
Chemical NameGHS ClassificationCyclohexane

Category 2Xylenes

Category 2Sensitization: Not Available

Mutagenicity: Not Available

Carcinogenicity: Category 2 as a product. The table below indicates whether each agency
has listed any ingredient as a carcinogen.
Chemical Name

ACGIH

IARCNTPOSHA

Ethyl benzene

A3Group 2B-Present

Xylenes

A4---

Reproductive and Developmental Toxicity: Category 1 as a product.
Chemical NameGHS Classification

XylenesCategory 2

Ethyl benzene

Category 1B

Page 8 of 12

Product Name: POLIXRESIN SXSDS No. 037-O030394
First issue: 2015/03/05
Revised: 2019/12/12

Safety Data Sheets
Specific Target: Category 1 ((respirator, liver, kidneys, central nerve system), Category 2

Organ Toxicity(blood vascular system), Category 3 (Narcotic effects) as a product.

(Single Exposure)Chemical NameGHS Classification
Category 2 (Blood vascular system)

Cyclohexane

Category 3 (Respiratory tract irritation,Narcotic effects)
Category 1 (respirator, liver, central nerve

Xylenessystem, kidney)
Category 3 (Narcotic effects)

Ethyl benzene

Category 2 (Central nerve system)
Category3 (Respiratory tract irritation)

Specific Target: Category 1 (respirator, nerve system), Category 2 (hearing organ) as a

Organ Toxicity

product.

(Repeated Exposure)Chemical Name
Xylenes

Aspiration Hazard

GHS Classification
Category 1 (respirator, nerve system): Category 1 as a product.
Chemical NameGHS Classification

Cyclohexane

Category 2

XylenesCategory 1

Ethyl benzene

Category 1

12. Ecological Information
Handling is noted because it might influence the environment whenleaking and abandoning it.
Especially, note that the product doesn't flow directly to ground, theriver, and the drain ditch.
Ecotoxicity
Hazardous to the
Aquatic Environment Acute Hazard: Category 1 as a product.
Chemical Name
Cyclohexane

GHS Classification
Category 1
Daphnia magna EC50(48h): 0.9mg/L
Category2

Xylenes

Rainbow trout LC50(96h): 3.3mg/L
Daphnia magna EC50(48h): 2-12mg/L
Page 9 of 12

Product Name: POLIXRESIN SXSDS No. 037-O030394
First issue: 2015/03/05
Revised: 2019/12/12

Safety Data Sheets

Selenastrum

EC50(72h): 3.2mg/L

Category 1
Ethyl benzene

Rainbow trout

Daphnia magna EC50(48h): 1.8-2.9mg/L
Green algaeHazardous to theLC50(96h): 4.2mg/L
EC50(72h): 3.6-7.7mg/L: Category 3 as a product.

Aquatic

Chemical Name

Environment - Long

XyleneGHS Classification
Category 2

Term Hazard
Persistence and: Not Available

Degradability
Bioaccumulative: Not Available

Potential
13. Disposal Considerations: Comply with all USA, national and local regulations.
This product contains substances that are listed with the State of California as a hazardous
waste.
Chemical Name

California Hazardous Waste Status

Cyclohexane

Toxic; Ignitable

Ethyl benzene

Toxic; Ignitable

Do not dump this product into sewers, on the ground or into any body of water.
14. Transport Information
Check a thing without a leak in a container.
Perform prevention of collapse of cargo surely.
IATA Information
UN Number: UN1866

Proper Shipping Name

: RESIN SOLUTION flammable

Packing Group: II

Page 10 of 12

Product Name: POLIXRESIN SXSDS No. 037-O030394
First issue: 2015/03/05
Revised: 2019/12/12

Safety Data Sheets
ICAO Information
UN Number: UN1866

Proper Shipping Name

: RESIN SOLUTION flammable

Packing Group: II

IMDG Information
UN Number: UN1866

Proper Shipping Name

: RESIN SOLUTION flammablePacking Group: IIMarine Pollutant:
Chemical Name

IBC Code

Cyclohexane

Category Y

XylenesCategory Y

Ethyl benzene

Category Y

15. Regulatory Information
OSHA Status: Following substances are hazardous under 29 CFR 1910. 1200.
Chemical Name

Hazardous

Carcinogen

Chemicals

Cyclohexane

X-XylenesX-

Ethyl benzene

X

X

TSCA Status
Clean Air Act Section: Xylenes (CAS No. 1330-20-7)

112, Hazardous Air

Ethylbenzene (CAS No.100-41-4)

Pollutants
CERCLA
Reportable Quantity(40 CFR 302)

: This product contains the following CERCLA Hazardous Substances.
Chemical Name

Hazardous

RQ

Substances

Cyclohexane

X454kgXylenes

X454kgEthyl benzene

X454kgPage 11 of 12

Product Name: POLIXRESIN SXSDS No. 037-O030394
First issue: 2015/03/05
Revised: 2019/12/12

Safety Data Sheets
SARA TitleⅢ
Section 313: This product contains the following SARA Title III Section 313(40 CFR 372)

chemicals.
Chemical Name

California Proposition
65
OthersOthersEmission
Reporting

Cyclohexane

1.0%

Xylenes1.0%

Ethyl benzene

0.1%: This product contains the following Proposition 65 chemicals.
Chemical Name

Hazardous

CarcinogenChemicals

Cyclohexane

X-Xylenes

X-Ethyl benzene

XX

Please refer to any other federal, state and local regulations.

16. Other Information
This information is furnished without warranty, express or implied, except that it is accurate to
the best knowledge of Mimaki Engineering Corporation.
It relates only to the specific material designated herein, and does not relate to use incombination with any other material or process.
Mimaki Engineering Corporation assumes no legal responsibility for use or reliance upon thisinformation.

Page 12 of 12