HAG - 1 / 4SAFETYDATASHEET
2020-12-17

May be used to comply with
OSHA's Hazard Communication Standard,
29 CFR 1910. 1200.
Standard must be consulted for specific requirements.

U.S. Department of Labor
Occupational Safety and Health Administration(Non-Mandatory Form)
Form Approved OMB No.1218-0072

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§ 1 - IDENTITY INFORMATION
Product Name (as used on label and list) :HOLBEIN ACRYLA GOUACHE
HOLBEIN ACRYLIC GOUACHE

Manufacturer : HOLBEIN Works, Ltd.
Address : 2-2-5, Ueshio, Chuo-ku, OSAKA 542-0064 JAPAN
Telephone Number for information : 81-6-6191-7722
Department for Emergency : Technical division
Telephone Number : 81-72-985-1221
Preparer : ALAKI, Yutaka───────────────────────────────────────────────

§2 - HAZARD IDENTIFICATIONThis product is water-based and not classified as dangerous for supply or conveyance.
The ingredients are water-reducible and falls well within the acceptable safety limits.
Danger : Nonflammable
Eye irritation : Class 2B (Irritant)
Skin irritation : Class 3 (Irritant, inflammation)
Oral Toxicity : Toxicity of this product is not confirmed.
On pigments of three products, to be noted.
Blue Violet : Class 4 (contains formaldehyde, carcinogen)
Jet Black, Super Opaque Black : Class 4 (soluble copper, induce anemia)
Ecological consideration : As fish toxicity, acrylic polymer emulsion may obstruct thebreathing of fishes, in case of pouring the excess colors to riveror pond.
GHS label elements : Void───────────────────────────────────────────────

§3 - COMPOSITION / INGREDIENTS
Substance/Mixture: Mixture(＊: Main Ingredients.)
Components (Specific Chemical Identity, Common Name (s))
Colorant *Binder *Dispersant
Moisturizer
Thickener
pH Agent
Preservative
Preservative(Pigment)**(Acrylic-Metacrylic Copolymer Emulsion) CAS 25852-37-3(Sodium Polycarboxylate)
CAS 25549-84-2(Propylene Glycol)
CAS 57-55-6(Polyacrylate)
CAS 9003-01-4(Dimethylaminoethanol)
CAS 108-01-0(Benzimidazole)
CAS 148-79-8(Benzisothiazoline)
CAS 2634-33-5**: Colorant, pigment, is shown in our catalogue.
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§4 - FIRST AID MEASURESEyes : In case of eye contact, rinse with plenty of water and if necessary consult
an eye specialist.
Ingestion : In case of swallowing, drink plenty of water. Induce vomiting.

HAG - 2 / 4

If you feel unwell, seek medical advice.
Skin Contact : Upon skin contact, wash with plenty of water, soap or other non-irritating
cleansing agents.
Inhalation : Upon inhalation of aerosol/vapor, take the person to fresh air.
If there is difficulty in breathing, medical advice is required.
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§5 - FIRE AND EXPLOSION HAZARD DATA
Flammability : Not combustible
Flash Point, Ignition Point : Not below 100 ﾟ CCombustion Products : Formation of carbon dioxide and oxide of metal according topigment.
Extinguishing Method : Regular
Extinguishing Media : Water (Foam, Dry powder and Carbon dioxide, if necessary)
Precaution for Firefighters : Do not inhale combustion gases.
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§6 - ACCIDENTAL RELEASE MEASURES
Accidental Release Measures : Wipe off.
Environmental Precautions : Prevent spills from entering storm sewers or drains andcontact with soil.
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§7 - HANDLING AND STORAGE
Precautions for Storing : None, especially───────────────────────────────────────────────

§8 - EXPOSURE CONTROLS / PERSONAL PROTECTIONAvoid invasion to the eyes or body. Avoid prolonged or repeated contact with skin.
Wash mouth or hands well after use. Avoid inhaling aerosols.
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§9 - PHYSICAL / CHEMICAL CHARACTERISTICS
Appearance and Odor : Colored Paste with faint acrylic odor
Specific Gravity (H2O = 1) : 1.1～1.5 (Av. 1.37)
Boiling Point : Approx. 100℃
Vapor Density (Air = 1) : －pH : 7.5～8.5
Solubility in Water : Can be diluted. Not so, after dried.
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§10 - HAZARD INFORMATION AND STABILITYPhysical Dangers : Nonflammable
Stability : Stable under normal state
Reactivity : None
Byproducts : Carbon dioxide, oxides of metals and water in case of fire.
No thermal decomposition when stored and handledcorrectly.
Incompatibility (Materials to Avoid) : None───────────────────────────────────────────────

§11 - TOXICOLOGICAL INFORMATION
Primary Routes of Entry : Dermal, eye contact, inhalation, swallowing
Oral Toxicity : Toxicity of acrylic colors is not confirmed. On pigments, to benoted.
Jet Black, Super Opaque Black : Soluble copper, induce anemia
Blue Violet : Formaldehyde, carcinogen
Eye irritation : Irritant, but not damage the organization
Skin irritation : Irritant by repeated or prolonged contact, and may cause
inflammation.

HAG - 3 / 4Inhalation Toxicity : Although some of raw materials are pointed to may stimulate eyes
and respiratory organs with their vapor or mists under highly
concentrated state, the toxic act of acrylic colors is not confirmed.
Carcinogenicity : Blue Violet may contains formaldehyde, carcinogen
Sensitization, Mutagenicity, Teratogenicity, Reproductive Toxicity : No data available on products.
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§12 - ECOLOGICAL INFORMATIONFish Toxicity : Acrylic polymer emulsion may obstruct the breathing of fishes, incase of pouring the excess colors to river or pond.
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§13 - DISPOSAL CONSIDERATIONS
Disposal Considerations : Dispose in accordance with national and/or local regulations.
Avoid entry into the sewage system (danger of clogging).
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§14 - TRANSPORT INFORMATION
Precautions for Transport : None, especially
UN Proper Shipping Name : Not applicable
UN Number : Not applicable
UN Hazard Class : Not applicable
Packing Group : Not applicable───────────────────────────────────────────────

§15 - REGULATORY INFORMATION
Danger Class : N/A (Not flammable liquid)Fire Service Law, Industrial Safety and Health Law : N/APollutant Release and Transfer Register : N/AConforms to ACMI under ASTM D 4236, and are classified into AP or CL genre of ACMIsystem. See the table of Appendix.
ACMI : The Art & Creative Materials Institute, Inc.
ASTM : ASTM International (Former “American Society for Testing and Materials”)───────────────────────────────────────────────

§16 - OTHER INFORMATION
Notice : All information contained herein is for references and guidance for normal use, and notfor all conceivable conditions of handling and use. The responsibility for irregular use
belongs to user individuals. All information are under our knowledge of today, and notsecure the perfection. All information may change according to circumstances.

HAG - 4 / 4Appendix
Table COLOR INFORMATION
Cu : Copper
FA : Formaldehyde
AP (Approved Product) : Contain no materials in sufficient quantities to be toxic or injurious
to humans.
CL (Cautionary Label) : Any known health risks and with information on the safe andproper use of these materials
Name

Hazardous ingredient Classification

Aqua Blue
Ash Blue
Ash Green
Ash Yellow
Ash RoseBeige
Blue GreenBlue Violet
BronzeBurnt Sienna
Burnt Umber
CarmineCerulean Blue
Chinese WhiteCobalt Blue
Cobalt Green
Coral Red
Cosmos Pink
Cream Yellow
CrimsonDeep Green
Deep Magenta
Deep Violet
Deep Yellow
Emerald Green
Flesh
Gold
Grass GreenGreen
Horizon Blue
Ice Green
Ivory White
Jaune Brillant
Jet Black
Lamp Black
Leaf Green
Lemon Yellow
Light Blue
Light Green
Light Magenta
Light Red BrightLight Yellow
Lilac
Luminous Green
Luminous Lemon
Luminous Orange
Luminous Red
Magenta
Metallic Blue
Metallic Green
Metallic Red
Metallic Violet
Metallic White
Metallic Yellow
Mint Green

FA
Cu-AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
APAPAP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP

CL

CLNameHazardous ingredient Classification

Misty Blue
Misty Green
MustardNaples Yellow
Navy Blue
Neutral Grey No.1
Neutral Grey No.2
Neutral Grey No.3
Neutral Grey No.4
OliveOpera
OrangeOrange Yellow
Pale Aqua
Pale Gold
Pale Lavender
Pale Lilac
Pale Lime
Pale Mint
Pale Peach
Pale Pink
Peacock Blue
Pink
Primary Black
Primary Cyan
Primary Magenta
Primary WhitePrimary Yellow
Prussian Blue
Pure Red
Raw Sienna
Raw Umber
Red Violet
Rose
Rose Violet
Sap Green
ScarletSepia
Shell Pink
SilverSky Blue
Smalt Blue
Super Opaque Black
Super Opaque White
Titanium White
Turquoise Blue
Ultramarine Blue
Ultramarine Blue Deep
Vermilion
VioletViridian
Wine Red
Yellow
Yellow OchreCu-AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP
AP

CL