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㹙⤖ᯝ࣭⪃ᐹ㹛Fig.1(a)࡟ Tc = 200ºC ࡜ Tc = 220ºC ࡛⤖
Dᬗ໬ࡉࡏࡓࢼ࢖ࣟࣥ 9,2 ࡢ᪼ ㏿ᗘ 3000 K/s ࡛ ᐃࡋ
ࡓ⼥Ⅼࡢ⤖ᬗ໬ ᗘಖᣢ᫬㛫౫Ꮡᛶࢆ♧ࡍࠋ⤖ᬗ໬ᗘಖᣢ᫬㛫'tiso ࡀ㛗ࡃ࡞ࡿ࡜⼥Ⅼࡀୖ᪼ࡍࡿࠋFig. 1(b)
ࡣ Tc = 200ºC, 220ºC ࡛⤖ᬗ໬ࡉࡏࡓࢼ࢖ࣟࣥ 9,2 ࡢ⤖ᬗ࣓ࣛࣛཌࡢ'tiso ౫Ꮡᛶ࡛࠶ࡿࠋ➼ ⤖ᬗ໬ ᗘ࡛ಖᣢࡋ࡚࠸ࡿ㛫ࠊ⤖ᬗ࣓ࣛࣛཌࡣ࡯࡜ࢇ࡝ኚ໬ࡋ࡞࠸ࡇ࡜ࡀࢃ࠿ࡗࡓࠋ㧗ศᏊ⤖ᬗ࡟࠾࠸࡚⼥Ⅼ࡜⤖ᬗ࣓ࣛࣛཌ࡟ࡣ௨ୗࡢࡼ࠺࡞㛵ಀࡀᚓࡽࢀࡿ(Gibbs-Thomson ຠE ᯝ)ࠋC2V e 0Tm Tm0  , CTm    (1)'hfl0

ࡇࡇ࡛ Tm0 ࡣᖹ⾮⼥ⅬࠊVe ࡣ࣓ࣛࣛ⤖ᬗ➃㠃ࡢ⾲㠃⮬⏤࢚ࢿࣝࢠ࣮ࠊ'hf ࡣ⼥ゎ࢚ࣥࢱࣝࣆ࣮࡛࠶ࡿࠋC ࡀ୍ᐃ࡛࠶ࡿ࡜⪃࠼ࡿ࡜⼥Ⅼࡣ lc ࡟ࡼࡗ࡚ኚ໬ࡍࡿࠋᮏ◊✲ࡢ⤖ᯝࡢሙྜࠊ⤖ᬗ࣓ࣛࣛཌࡀ୍ᐃ࡛࠶ࡿࡢ࡟⼥Ⅼ
ࡣ'tiso ࡜࡜ࡶ࡟ቑຍࡋ࡚࠾ࡾࠊࡇࢀࢆㄝ᫂ࡍࡿ࡟ࡣ CFig. 1 Semilogarithmic plots of (a):࡟'tiso ౫Ꮡᛶࢆᑟධࡍࡿᚲせࡀ࠶ࡿࠋලయⓗ࡟ࡣ⤖ᬗ
melting point Tm and heat of fusion 'Hm,໬ᚋ࡟㉳ࡇࡿఱࡽ࠿ࡢ෌⤌⧊໬࡟ࡼࡾࠊ⼥ゎ࢚ࣥࢱࣝand (b): crystalline lamellar thickness lc,
amorphous layer thickness la, and longࣆ࣮ࡸ⾲㠃⮬⏤࢚ࢿࣝࢠ࣮ࡀኚ໬ࡋࠊ⼥Ⅼኚ໬ࢆࡶࡓ
period LS of nylon-9,2 against 'tiso .
ࡽࡋ࡚࠸ࡿ࡜᥎ ࡉࢀࡿࠋ1) G. R. Strobl, M. Schneider, J. Polym. Sci. Polym. Phys. Ed. 18, (1980) 1343.

ᖺ᭶᪥䠄Ỉ䠅 ஑ᕞ䝅䞁䜽䝻䝖䝻䞁ග◊✲䝉䞁䝍䞊◊✲ᡂᯝሗ࿌఍㧗ศᏊࡢ⤖ᬗ໬࡜㧗ḟᵓ㐀ศᏊ㙐䛿ఙ䜃ษ䛳䛶ᖹ⾜䛻㓄ิ⌮᝿ⓗ䛺⤖ᬗ໬㧗ศᏊ䛾⤖ᬗ໬䞉⼥ゎ䡚ᗘ䝆䝱䞁䝥䛻䜘䜛;⥺ᑠゅᩓ஘䛸;⥺ᗈゅᅇᢡ䛭䛾ሙ ᐃ䡚㧗⼥ᾮ䠄䝷䞁䝎䝮䝁䜲䝹䠅ఙ䜃ษ䜚㙐⤖ᬗ䠄᭱Ᏻᐃ≧ែ䠅ศᏊ㙐ࡣᢡࡾ␚ࡲࢀ࡞ࡀࡽᖹ⾜࡟㓄ิᒣཱྀ኱Ꮫ ኱Ꮫ㝔๰ᡂ⛉Ꮫ◊✲⛉⤖ᬗ䝷䝯䝷㠀ᬗ㡿ᇦ㔝ᓮ ᾈ஧ᐇ㝿䛻ほ 䛥䜜䜛⤖ᬗ໬ᢡ䜚␚䜏㙐⤖ᬗ䠄‽Ᏻᐃ≧ែ䠅࣓ࣛࣛ⤖ᬗࡢศᒱ

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⤖ᬗᛶ㧗ศᏊࡢ㧗ḟᵓ㐀ࡣ୺࡟⤖ᬗ໬㐣⛬࡛Ỵࡲࡿ✚ᒙ䝷䝯䝷ᵓ㐀◊✲ࡢ┠ⓗ⤖ᬗᛶ㧗ศᏊ䝫䝸䜶䝏䝺䞁 3( 䠈䜰䜲䝋䝍䜽䝏䝑䜽䝫䝸䝥䝻䝢䝺䞁 L33 䠈䝘䜲䝻䞁 3$䝫䝸䝣䝑໬䝡䝙䝸䝕䞁 39') 䠈䝫䝸䝤䝏䝺䞁䝔䝺䝣䝍䝺䞊䝻 3%7 䠈䝫䝸䜶䝏䝺䞁䝔䝺䝣䝍䝺䞊䝖 3(7⤖ᬗ໬᮲௳࡟ࡼࡗ࡚≀ᛶࡀ␗࡞ࡿ⤖ᬗ໬ࡢᇶᮏ⌮ゎࡣᮦᩱ㛤Ⓨ࡟ࡣ㔜せ⤖ᬗ໬ࡀ᏶஢ࡋࡓ㧗ศᏊ⤖ᬗᗘ䝆䝱䞁䝥䛻䜘䜚䛥䜎䛦䜎ࡉࡲࡊࡲ࡞෌⤌⧊໬ࡀ㐍⾜ࡍࡿ㸦ᚋ࡟ㄝ᫂㸧ᗘ䠄㐣෭༷ᗘୗ䠅䛷䛾⤖ᬗ໬䜢ᐇ⌧䛧䚸⤖ᬗ໬୰䛚䜘䜃⤖ᬗ໬ᚋ䛻㐍⾜䛩䜛ᵓ㐀ᙧᡂ䜢;⥺ᑠゅᩓ஘䠄ᮦᩱࡢ≀ᛶ౛㸸⪏⇕ᛶ➼࡟኱ࡁࡃ㛵ಀࡍࡿ⤖ᬗࡢ⼥ゎᣲືึᮇࡢ⤖ᬗ໬ࡑࡢᚋࡢ෌⤌⧊໬ࡢ୧᪉ࡀᙳ㡪ࡍࡿ

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ཌ໬

⤖ᬗ໬

⼥Ⅼ䛜ୖ᪼
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෌⛛ᗎ໬

7P

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