Citrus Degreaser

SAFETY DATA SHEETACCORDING TO EC-REGULATIONS 1907/2006 (REACH) & 1272/2008 (CLP)SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
1.1

Product identifier
GHS Product Identifier
Chemical Name
Trade name
CAS No.
EINECS No.

Not applicable.
Not applicable.
Citrus Degreaser
MixtureMixture1.2

Relevant identified uses of the substance or mixture and uses advised against
Identified use(s)Degreaser
Uses advised against
None.

1.3

Details of the supplier of the safety data sheet
Company Identification

1.4

Finish Line Technologies, Inc.
50 Wireless Blvd.
Hauppauge, NY 11788
USATelephone
Fax
E-Mail (competent person)+1 (631) 666-7300+1 (631) 666-7391
SDSinfo@finishlineusa.com

Distributor

Madison Cycles
8 Stanmore Hill
Stanmore, Middlesex, HA7 3BQ
United Kingdom

Telephone+44 870 034 7226

Emergency telephone number
Medical Emergency: PROSAR 24 hr: 1-800-2175157 / 1-651-523-0304

Emergency Phone No.

Transportation Emergency: CHEMTREC 24 hr. 1800-424-9300 / 1 (703) 527-3887 (Collect calls
accepted)

SECTION 2: HAZARDS IDENTIFICATION
2.1

Classification of the substance or mixtureRegulation (EC) No. 1272/2008 (CLP).

2.2

Flam. Liq. 3; Asp. Tox. 1; Eye Irrit. 2; Skin Sens. 1B; STOT
SE 3; Aquatic Chronic 2

Label elements
Hazard Symbol

DangerSignal word(s)Hazard statement(s)H226: Flammable liquid and vapour.
H304: May be fatal if swallowed and enters airways.
H317: May cause an allergic skin reaction.
H319: Causes serious eye irritation.
H336: May cause drowsiness or dizziness.
H411: Toxic to aquatic life with long lasting effects.

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P210: Keep away from heat/sparks/open flames/hot surfaces.
– No smoking.

Precautionary statement(s)P264: Wash (hands and exposed skin) thoroughly afterhandling.
P301+P310: IF SWALLOWED: Immediately call a POISONCENTER or doctor/physician.
P331: Do NOT induce vomiting.
P302+P352: IF ON SKIN: Wash with plenty of soap andwater.
P102: Keep out of reach of children.
2.3

Other hazards

None

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
3.2 Mixtures
Regulation (EC) No. 1272/2008 (CLP).
Hazardous ingredient(s)%W/WEC No. and CAS#Distillates (petroleum), hydrotreated light

50-85

265-149-8
64742-47-8

D-limonene

4-8

227-813-5
5989-27-5

Alcohols, C9-11 ethoxylated, < 2.5 EO

1-2.5----68439-46-3

According to Regulation (EC)No. 1272/2008 (CLP)
Flam. Liq. 3; H226
Asp. Tox. 1;H304
STOT SE 3; H336
Flam. Liq. 3; H226
Asp. Tox. 1;H304
Skin Irrit. 2; H315
Skin Sens. 1B; H317
Aquatic Chronic 1; H410
Eye Dam. 1;H318

For full text of H/P phrases see section 16.

SECTION 4: FIRST AID MEASURES

4.1

Description of first aid measures
Inhalation

Move person to fresh air. If breathing is laboured,administer oxygen. If symptoms develop, obtain medical
attention.

Skin Contact

Wash affected skin with soap and water. If symptoms
develop, obtain medical attention.

Eye Contact

IF IN EYES: Rinse cautiously with water for several
minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.If symptoms occur obtain medical
attention.

Ingestion

Do not induce vomiting wash out mouth with water.Do notgive anything by mouth to an unconscious person. Seek
medical treatment.

4.2

Most important symptoms and effects, bothacute and delayed

Aspiration of liquid may cause pulmonary oedema.
Contains:D-limonene. May cause an allergic skin reaction.

4.3

Indication of the immediate medical attention
and special treatment needed

None

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SECTION 5: FIRE-FIGHTING MEASURES
5.1

Extinguishing media-Suitable Extinguishing Media

Extinguish with carbon dioxide, dry chemical, foam orwaterspray.

-Unsuitable Extinguishing MediaDo not use water jet.

5.2

Special hazards arising from the substance or mixture

None known.

5.3

Advice for fire-fighters

A self contained breathing apparatus and suitable protective
clothing should be worn in fire conditions. Keep containers
cool by spraying with water if exposed to fire.

SECTION 6: ACCIDENTAL RELEASE MEASURES
6.1

Personal precautions, protective equipment andemergency procedures

Wear protective gloves/eye protection.

6.2

Environmental precautions

Prevent substance entering sewers.

6.3Methods and material for containment andcleaning up

Cover spills with inert absorbent material.Transfer to acontainer for disposal or recovery.

6.4

Reference to other sections

None

SECTION 7: HANDLING AND STORAGE
7.1

Precautions for safe handling

7.2

Conditions for safe storage, including any incompatibilities

7.3

Avoid contact with skin and eyes. When using do not eat,drink or smoke.

-Storage Temperature-Incompatible materials

Store at room temperature.
Strong oxidising agents.

Specific end use(s)Degreaser

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION8.1

Control parameters

8.1.1

Occupational Exposure Limits

CAS No.

LTEL (8 hr
TWA ppm)

LTEL (8 hr
TWA mg/m³)

STEL(ppm)

STEL(mg/m³)

Note:

Normal and branched chainalkanes ≥C7Mixture

-----

1200

-----

-----

UK - EH40

Cycloalkanes ≥C7

Mixture

-----

800

-----

-----

UK - EH40

SUBSTANCE.

Biological limit value
Limit value type
(country of origin)
None known

SUBSTANCE.
None

8.1.2

Recommended monitoring method

8.2

Exposure controls

8.2.1

Appropriate engineering controls

8.2.2

Personal protection equipment

Revision: 25 April 2014

CAS No.
----------------

Biological limit value
None

Note:None

NIOSH 1550 (Naphthas)

Ensure adequate ventilation.

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8.2.3

Eye/face protection

Wear protective eyewear (goggles, face shield, or safety
glasses).

Skin protection (Hand protection/ Other)

Wear protective gloves.(Nitrile rubber)

Respiratory protection

Normally no personal respiratory protection is necessary. In
case of insufficient ventilation, wear suitable respiratory
equipment.

Thermal hazards

Not normally required.

Environmental Exposure Controls

None assigned.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1

9.2

Information on basic physical and chemical properties
Appearance
ColourOdour
Odour Threshold (ppm)
pH (Value)
Melting Point (°C) / Freezing Point (°C)
Boiling point/boiling range (°C):
Flash Point (°C)
Evaporation rate
Flammability (solid, gas)
Explosive limit ranges
Vapour Pressure (Pascal)
Vapour Density (Air=1)
Density (g/ml)
Solubility (Water)
Solubility (Other)
Partition Coefficient (n-Octanol/water)
Auto Ignition Temperature (°C)
Decomposition Temperature (°C)
Kinematic Viscosity (cP)
Explosive properties
Oxidising properties

LiquidColourlessCitrus
Not available
Not available
Not available>155(Distillates (petroleum), hydrotreated light)
40 (Distillates (petroleum), hydrotreated light)
Not available
Not available
Not available
Not available
Not available
ca. 0.8
Slightly soluble.
Not available
Not available>200 (Distillates (petroleum), hydrotreated light)
Not available
Not available
Not explosive.
Not oxidising.

Other information

Not available

SECTION 10: STABILITY AND REACTIVITY
10.1
10.2
10.3
10.4
10.5
10.6Reactivity
Chemical stability
Possibility of hazardous reactions
Conditions to avoid
Incompatible materials
Hazardous Decomposition Product(s)Stable under normal conditions.
Stable.
None anticipated.
Avoid contact with heat and ignition sources.
Strong oxidising agents
None known

SECTION 11: TOXICOLOGICAL INFORMATION
11.1

Information on toxicological effects

11.1.1 Substances
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Not applicable
11.1.2 Mixtures - By analogy with similar materials:
Acute toxicity
Skin corrosion/irritation
Serious eye damage/irritation
Respiratory or skin sensitization
Germ cell mutagenicity
Carcinogenicity
Reproductive toxicity
STOT - single exposure
STOT - repeated exposure
Aspiration hazard

Not available
Not available
Not available
Not available
Not available
Not available
Not available
Not available
Not available
Not available

11.1.3 Substances in preparations / mixtures
Distillates (petroleum), hydrotreated light (CAS# 64742-47-8)
Acute toxicity
Oral: LD50 >55 g/kg-bw
Dermal: LD50 >3 g/kg-bw

11.2

Skin corrosion/irritation
Serious eye damage/irritation
Respiratory or skin sensitization
Germ cell mutagenicity
Carcinogenicity
Reproductive toxicity
STOT - single exposure
STOT - repeated exposure
Aspiration hazard

Repeated exposure may cause skin dryness or cracking.
Not to be expected.
Not to be expected.
Not to be expected.
Not to be expected.
Not to be expected.
Not to be expected.
Not to be expected.
Aspiration of droplets may cause pulmonary oedema.

D-limonene (CAS#5989-27-5):
Acute toxicity
Skin corrosion/irritation
Serious eye damage/irritation
Respiratory or skin sensitization
Germ cell mutagenicityCarcinogenicity
Reproductive toxicity
STOT - single exposure
STOT - repeated exposure
Aspiration hazard

Oral: LD50 >4g/kg-bw
Causes skin irritation.
May cause eye irritation.
May cause sensitization by skin contact.
Not to be expected.
No data.
Not to be expected.
Not to be expected.
Not to be expected.
Aspiration of droplets may cause pulmonary oedema.

Other information

None known.

SECTION 12: ECOLOGICAL INFORMATION
12.1
12.1.1

Toxicity
Substances in preparations / mixtures
Distillates (petroleum), hydrotreated light (CAS# 64742-47-8) - By analogy with similar materials:
Short term
Not available
Long Term
Not available

12.2
12.3
12.4
12.5
12.6

12.2
12.3
12.4

Persistence and degradability
Bioaccumulative potential
Mobility in soil
Results of PBT and vPvB assessment
Other adverse effects

Not available
The product has low potential for bioaccumulation.
The product is predicted to have high mobility in soil.
Not classified as PBT or vPvB.
None known.

D-limonene (CAS#5989-27-5):
Short termLong Term

LC50 (96 hour) 720µg/l (Fathead minnow (Pimephales promelas))Not available

Persistence and degradability
Bioaccumulative potential
Mobility in soil

Readily biodegradable.
Not available
Not available

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12.5
12.6

Results of PBT and vPvB assessment
Other adverse effects

Not available
None known.

SECTION 13: DISPOSAL CONSIDERATIONS
13.1

Waste treatment methods

Disposal should be in accordance with local, state or national
legislation.Consult an accredited waste disposal contractor or
the local authority for advice.

SECTION 14: TRANSPORT INFORMATIONLand transport(ADR/RID)

Sea transport(IMDG)Air transport(ICAO/IATA)

14.1

UN number

14.2

Proper Shipping Name

14.3
14.4
14.5
14.6
14.7

Transport hazard class(es)33
Packing Group
III
III
Environmental hazards
No.
No.
Special precautions for user
None assigned
None assigned
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code: Not applicable

1268

1268

1268

Petroleum Distillates
n.o.s.

Petroleum Distillates
n.o.s.

Petroleum Distillates
n.o.s.
3
III
No.
None assigned

SECTION 15: REGULATORY INFORMATION
15.1

Safety, health and environmental regulations/legislation specific for the substance or mixture:

15.1.1

EU regulations

ListedRegulation (EC) 2037/2000 - Dangerous to the ozone layer.
Regulation (EC) 850/2004 - Persistent Organic Pollutants
Regulation (EC) 689/2008 - Export/Import of Dangerous Chemicals
Regulation (EC) 1907/2006 - REACH Authorisations and/or restrictions on use

No.
No.
No.
No.

National regulations
Chemical Safety Assessment

Not established.
Not applicable

15.1.2
15.2

SECTION 16: OTHER INFORMATION
The following sections contain revisions or new statements: 1 - 16.
Hazard statement(s) and Precautionary statement(s):- H226: Flammable liquid and vapour.
- H304: May be fatal if swallowed and enters airways.
- H315: Causes skin irritation.
- H317: May cause an allergic skin reaction.
- H318: Causes serious eye damage.
- H336: May cause drowsiness or dizziness.
- H410: Very toxic to aquatic life with long lasting effects.
GHS Classification- Flam. Liq. 3; Flammable Liquid Category 3- Asp. Tox. 1: Aspiration hazard Category 1- Eye Irrit. 2; Serious eye damage/irritation Category 2- Skin Sens. 1B; Skin sensitisation, Category Category 1B- STOT SE 3; Specific target organ toxicity — single exposure Category 3- Aquatic Chronic 2; Chronic aquatic toxicity, Category 2
Training advice: None.
Additional Information: None.
Disclaimer: We believe the statements, technical information and recommendations contained herein are reliable, but they aregiven without warranty or guarantee of any kind. The information contained in this document applies to this specific material assupplied. It may not be valid for this material if it is used in combination with any other materials. It is the user’s responsibility tosatisfy oneself as to the suitability and completeness of this information for the user’s own particular use.
Revision: 25 April 2014

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Date: 20 March 2018