田丸良直	
 研究室	
  業績	
 (1990.4.~	
 2008.3)	
 
	
 
Ⅰ．学	
  術	
  論	
  文	
 

63.

“Chameleon Reactivity of the Allene Bond of 4-Vinylidene-2-oxazolidinone: Novel Through-space
Conjugative Nucleophilic Addition of Electron-rich Alkenes and Hetero-nucleophiles”
Chemistry - A European Journal, Vol. 13, No. 34, pp. 9686-9702 (2007-12).
著者	
  M. Kimura, Y. Horino, M. Mori, Y. Tamaru

62.

“Palladium-Catalyzed 1,3-Diol Fragmentation: Synthesis of ω-Dienyl Aldehydes”
Chem. Commun., No. 43, pp. 4504-4506 (2007-11).
著者	  M. Kimura, M. Mori, Y. Tamaru

61.

“Alkyne as a Spectator Ligand for the Nickel-Catalyzed Multi-Component Connection Reaction ofDiphenylzinc, 1,3-Butadiene, Aldehydes, and Amines”
Org. Lett., Vol. 9, No. 10, pp. 1871-1873 (2007-5).
著者	  M. Kimura, Y. Tatsuyama, K. Kojima, Y. Tamaru

60.

“Pd(0)-Catalyzed Amphiphilic Allylation of Aldehydes with Vinyl Epoxide”
J. Am. Chem. Soc., Vol. 129, No. 14, pp. 4122-4123 (2007-4).
著者	  M. Kimura, R. Mukai, T. Tamaki, Y. Horino, Y. Tamaru

59.

“Pd-Catalyzed Allylic Alkylation of Polyhydroxybenzenes with Allyl Alcohol Promoted by
Triethylborane”
Synthesis, No. 21, pp. 3611-3616 (2006-11).
著者	  M. Kimura, M. Fukasaka, Y. Tamaru

58.

“Nickel Catalyzed Grob Fragmentation via β-Carbon Elimination: Efficient Entry to ω-Dienyl
Aldehydes”
Chem. Commun., No. 41, pp. 4303-4305 (2006-10).
著者	  M. Mori, M. Kimura, Y. Takahashi, Y. Tamaru

57.

“Nickel-Catalyzed Multi-Component Connection Reaction of Isoprene, Aldimines (Lactamines),and Diphenylzinc”
Tetrahedron, Vol. 62, No. 32, pp. 7512-7520 (2006-8).
著者	  K. Kojima, M. Kimura, S. Ueda, Y. Tamaru
156.

“Regio- and Stereoselective Nickel-Catalyzed Homoallylation of Aldehydes with 1,3-Dienes”
J. Am. Chem. Soc., Vol. 128, No. 26, pp. 8559-8568 (2006-7).
著者	  M. Kimura, A. Ezoe, M. Mori, K. Iwata, Y. Tamaru

55.

“Nickel Catalyzed Stereoselective Conjugate Addition of Dimethylzinc upon Aldimines Across
1,ω-Dienynes”
Chem. Commun., No. 26, pp. 2813-2815 (2006-6).
著者	  M. Kimura, M. Mori, N. Mukai, K. Kojima, Y. Tamaru

54.

“Nickel-Catalyzed Multi-Component Connection of Dimethylzinc, Alkynes, 1,3-Butadiene,
Aldehydes, and Amines”
J. Am. Chem. Soc., Vol. 128, No. 19, pp. 6332-6333 (2006-5).
著者	  M. Kimura, K. Kojima, Y. Tatsuyama, Y. Tamaru

53.

“Pd-Catalyzed Allylic Alkylation of Pyrroles with Allyl Alcohols Promoted by Triethylborane”
Heterocycles, Vol. 67, No. 2, pp. 535-542 (2006-2).
著者	  M. Kimura, M. Fukasaka, Y. Tamaru

52.

“Use of Allyl, 2-Tetrahydrofuryl, and 2-Tetrahydropyranyl Ethers as Useful C3-, C4-, andC5-Carbon Sources: Palladium-Catalyzed Allylation of Aldehydes.”Chem. Eur. J., Vol. 11, No. 22, pp. 6629-6642 (2005-11).
著者	  M. Shimizu, M. Kimura, Y. Tamaru

51.

“Nickel-Catalyzed Four-Component Connection of Organoaluminum (Organozinc), Isoprene,
Aldehydes,

andAmines:Stereo-andRegioselective

SynthesisofTrisubstituted(E)-Homoallylamines”
Chem. Commun., No. 37, pp. 4717-4719 (2005-10).
著者	  K. Kojima, M. Kimura, Y. Tamaru

50.

“Pd-Catalyzed C3-Selective Alkylation of Indoles and C3-endo-Selective Alkylation of
Tryptophans with Allyl Alcohols Promoted by Triethylborane”
J. Am. Chem. Soc., Vol. 127, No. 13, pp. 4592-4593 (2005-4).
著者	  M. Kimura, M. Futamata, R. Mukai, Y. Tamaru

49.

“Pd-Catalyzed Nucleophilic Allylic Alkylation of Aliphatic Aldehydes by The Use of Allyl
Alcohols”
2Tetrahedron, Vol. 61, No. 15, pp. 3709-3718 (2005-4).
著者	  M. Kimura, M. Shimizu, S. Tanaka, Y. Tamaru

48.

“Palladium-Catalyzed Allylation of Imines with Allyl Alcohols”
Org. Lett., Vol. 7, No. 4, pp. 637-640 (2005-2).
著者	  M. Shimizu, M. Kimura, T. Watanabe, Y. Tamaru

47.

“Nickel-Catalyzed Addition of Dimethylzinc to Aldehydes Across Alkynes and 1,3-Butadiene: An
Efficient Four-Component Connection Reaction”
J. Am. Chem. Soc., Vol. 127, No. 1, pp. 201-209 (2005-1).
著者	  M. Kimura, A. Ezoe, M. Mori, Y. Tamaru

46.

“Nickel-Catalyzed Three-Component Connection Reaction of Dimethylzinc, 1,ω-Ene-Diene, andAcetone: Synthesis of 1,2-Disubstituted Cycloalkanes”
Synthesis, No. 18, pp. 3089-3091 (2004-12).
著者	
  M. Kimura, K. Kojima, Y. Tamaru

45.

“Highly Stereo- and Regioselective Ni-Catalyzed Homoallylation of Aldimines with Conjugated
Dienes Promoted by Diethylzinc”
J. Am. Chem. Soc., Vol. 126, No. 44, pp. 14360-14361 (2004-11).
著者	  M. Kimura, A. Miyachi, K. Kojima, S. Tanaka, Y. Tamaru

44.

“Pd(0)-Catalyzed Amphiphilic Activation of Bis-Allyl Alcohol and Ether”
J. Am. Chem. Soc., Vol. 126, No. 36, pp. 11138 - 11139 (2004-9).
著者	  R. Mukai, Y. Horino, S. Tanaka, Y. Tamaru, M. Kimura

43.

“Triethylborane as an Efficient Promoter for Palladium-catalyzed Allylation of Active Methylene
Compounds with Allyl Alcohols”
Tetrahedron, Vol. 59, No. 39, pp. 7767-7777 (2003-9).
著者	  M. Kimura, R. Mukai, N. Tanigawa, S. Tanaka, Y. Tamaru

42.

“Catalytic Enantioselective Conjugate Reduction of Lactones and Lactams”
J. Am. Chem. Soc., Vol. 125, No. 37, pp. 11253-11258 (2003-9).
著者	
  G. Hughes, M. Kimura, S. L. Buchwald

41.

“Pd-Catalyzed Nucleophilic Alkylation of Aliphatic Aldehydes with Allyl Alcohols: Allyl,
32-Tetrahydrofuryl, and 2-Tetrahydropyranyl Ethers as Useful C3, C4, and C5 Sources”
Angew. Chem. Int. Ed. Engl., Vol. 42, No. 29, pp. 3392–3395 (2003-7).
著者	  M. Kimura, M. Shimizu, K. Shibata, M. Tazoe, Y. Tamaru

40.

“Preparation, Structure, and Unique Thermal [2+2], [4+2], and [3+2] Cycloaddition Reactions of
4-Vinylideneoxazolidin-2-one”
Chem. Eur. J., Vol. 9, No. 11, pp. 2419-2438 (2003-6).
著者	  Y. Horino, M. Kimura, S. Tanaka, T. Okajima, Y. Tamaru

39.

“Pd•Et3B-Catalyzed Alkylation of Amines with Allylic Alcohols”
Chem. Commun., No. 2, pp. 234-235 (2003-1).
著者	  M. Kimura, M. Futamata, K. Shibata, Y. Tamaru

38.

“Remarkably High 1,5-Diastereoselectivity in a Nickel-Catalyzed Conjugate Addition of Me2Zn
and Carbonyl Compounds to 1,ω-Dienynes with Through-Space Coupling”
Angew. Chem. Int. Ed. Engl., Vol. 41, No. 15, pp. 2784–2786 (2002-8).
著者	
  A. Ezoe, M. Kimura, T. Inoue, M. Mori, Y. Tamaru

37.

“Strikingly Simple Direct α-Allylation of Aldehydes with Allyl Alcohols: Remarkable Advance in
the Tsuji-Trost Reaction”
J. Am. Chem. Soc., Vol. 123, No. 42, pp. 10401-10402 (2001-10).
著者	  M. Kimura, Y. Horino, R. Mukai, S. Tanaka, Y. Tamaru

36.

“Nickel-Catalyzed Homoallylation of Aldehyde in the Presence of Water and Alcohols”
Angew. Chem. Int. Ed. Engl., Vol. 40, No. 19, pp. 3600-3602 (2001-10).
著者	  M. Kimura, A. Ezoe, S. Tanaka, Y. Tamaru

35.

“Nickel-Catalyzed Intramolecular Homoallylation of ω-Dienyl Aldehyde”
Org. Lett., Vol. 3, No. 14, pp. 2181-2183 (2001-7).
著者	  K. Shibata, M. Kimura, M. Shimizu, Y. Tamaru

34.

“Practical Synthesis of Myrcene Derivatives Possessing Oxidized Methyl Groups”
J. Org. Chem., Vol. 66, No. 12, pp. 4447-4449 (2001-6).
著者	  M. Naito, A. Ezoe, M. Kimura, Y. Tamaru

33.

“Et3B-Pd-Promoted, Pd-catalyzed C-Allylation of o-Hydroxyacetophenone and its Derivatives with4

Allyl Alcohols”
Tetrahedron Lett., Vol. 42, No. 17, pp. 3113-3116 (2001-4).
著者	  Y. Horino, M. Naito, M. Kimura, S. Tanaka, Y. Tamaru

32.

“Nickel-catalyzed Three-component Connection Reaction of a Phenyl Group, Conjugated Dienes,
and Aldehydes: Stereoselective Synthesis of (E)-5-Phenyl-3-penten-1-ols and(E)-3-Methyl-5-phenyl-3-penten- 1-ols”
J. Organometal. Chem., Vol. 624, No.1-2, pp. 348-353 (2001-4).
著者	
  K. Shibata, M. Kimura, K. Kojima, S. Tanaka, Y. Tamaru

31.

“Ni(0)-Catalyzed Regio- and Stereoselective Coupling Reaction of Me3B, Isoprene, and Aromatic
Aldehydes”
Tetrahedron Lett., Vol. 41, No. 35, pp. 6789-6793 (2000-8).
著者	  M. Kimura, K. Shibata, Y. Koudahashi, Y. Tamaru

30.

“Et3B-Promoted, Pd(0)-Catalyzed Allylation of Active Methylene Compounds with Allylic
Alcohols”
Tetrahedron Lett., Vol. 41, No. 30, pp. 5705-5709 (2000-8).
著者	  Y. Tamaru, Y. Horino, M. Araki, S. Tanaka, M. Kimura

29.

“Et3B-Pd-promoted Allylation of Benzaldehyde with Allylic Alcohols”
Tetrahedron Lett., Vol. 41, No. 19, pp. 3627-3629 (2000-5).
著者	  M. Kimura, T. Tomizawa, Y. Horino, S. Tanaka, Y. Tamaru

28.

“Novel 1,3-Sulfonyl Shift and [4+2] Cycloaddition Reaction of N-Allenyl Sulfonamide Promoted
by Allylsilane”
Tetrahedron Lett., Vol. 41, No. 18, pp. 3427-3431 (2000-4).
著者	  Y. Horino, M. Kimura, M. Naito, S. Tanaka, Y. Tamaru

27.

“Nickel(0)-Catalyzed Three-Component Connection Reaction of Dimethylzinc, 1,3-Dienes, andCarbonyl Compounds”
Angew. Chem. Int. Ed. Engl., Vol. 38, No. 22, pp. 3386-3388 (1999-11).
著者	  M. Kimura, S. Matsuo, K. Shibata, Y. Tamaru

26.

“Allylation of Aldehydes via Umpolung of π-Allylpalladium(II) with Triethylborane”
Tetrahedron Lett., Vol. 40, No. 37, pp. 6795-6798 (1999-11).

5

著者	
  M. Kimura, I. Kiyama, T. Tomizawa, Y. Horino, S. Tanaka, Y. Tamaru

25.

“Nickel-Catalyzed Homoallylation of Aldehydes and Ketones with 1,3-Dienes and Complementary
Promotion by Diethylzinc and Triethylborane”
Angew. Chem. Int. Ed. Engl., Vol. 38, No. 3, pp. 397-400 (1999-2).
著者	  M. Kimura, H. Fujimatsu, A. Ezoe, K. Shibata, M. Shimizu, S. Matsumoto, Y. Tamaru

24.

“Efficient Entry to Tetrahydropyridines: Addition of Enol Ethers to Allene Sulfonamides Involving
a Novel 1,3-Sulfonyl Shift”
Angew. Chem. Int. Ed. Engl., Vol. 38, No. 1, pp. 121-124 (1999-1).
著者	  Y. Horino, M. Kimura, Y. Wakamiya, Y. Tamaru

23.

“Selective Reactions of π-Allyl(alkoxy)palladium(II) Complexes toward β-Decarbopalladation,β-Dehydropalladation, and Reductive Elimination”
Tetrahedron Lett., Vol. 39, No. 46, pp. 8475-8478 (1998-10).
著者	
  H. Harayama, M. Kimura, S. Tanaka, Y. Tamaru

22.

“Novel Carbonyl-Dependent Regioselective Allylation via Diethylzinc-Mediated Umpolung of
π−Allylpalladium”
Tetrahedron Lett., Vol. 39, No. 38, pp. 6903-6906 (1998-9).
著者	  M. Kimura, Y. Ogawa, M. Shimizu, M. Sueishi, S. Tanaka, Y. Tamaru

21.

“Novel and Highly Regio- and Stereoselective Nickel-Catalyzed Homoallylation of Benzaldehydewith 1,3-Dienes”
J. Am. Chem. Soc., Vol. 120, No. 16, pp. 4033-4034 (1998-4).
著者	  M. Kimura, A. Ezoe, K. Shibata, Y. Tamaru

20.

“Unique Regio- and Stereoselectivity In the Allylation of Benzaldehyde with 2-Substituted
Allylzincs Generated by Umpolung of π−Allylpalladium”
Tetrahedron Lett., Vol. 39, No. 7, pp. 609-612 (1998-2).
著者	  M. Shimizu, M. Kimura, S. Tanaka, Y. Tamaru

19.

“Pronounced Chemo-, Regio-, and Stereoselective [2+2] Cycloaddition Reaction of Allenes toward
Alkenes and Alkynes”
J. Am. Chem. Soc., Vol. 119, No. 44, pp. 10869-10870 (1997-11).
著者	  M. Kimura, Y. Horino, Y. Wakamiya, T. Okajima, Y. Tamaru
618.

“Synthesis of Doubly Unsaturated Aldehydes and Ketones via a Novel β−Decarbopalladation
Reaction”
Angew. Chem. Int. Ed. Engl., Vol. 36, No. 21, pp. 2352-2354 (1997-11).
著者	
  H. Harayama, K. Kuroki, S. Tanaka, M. Kimura, Y. Tamaru

17.

“Efficient

Synthesisof

4-Ethenylidene-2-oxazolidinones

viaPalladium-Catalyzed

Aminocyclization of 2-Butyn-1,4-diol Biscarbamates”
Tetrahedron Lett., Vol. 38, No. 22, pp. 3963-3966 (1997-6).
著者	  M. Kimura, Y. Wakamiya, Y. Horino, Y. Tamaru

16.

“Chemo-, Regio-, and Stereoselective Diels-Alder Reaction of Ambident Dienophilic
Monothiomaleimide”
Liebigs Ann., No. 5, pp. 907-923 (1997-5).
著者	  Y. Tamaru, H. Harayama, H. Sakata, H. Konishi, K. Fugami, M. Kimura, S. Tanaka, T.
Okajima, Y. Fukazawa

15.

“Palladium(II)-Catalyzed

IntramolecularAminocarbonylationofendo-Carbamates

under

Wacker-Type Conditions”
J. Org. Chem., Vol. 62, No. 7, pp. 2113-2122 (1997-4).
著者	  H. Harayama, A. Abe, T. Sakado, M. Kimura, K. Fugami, S. Tanaka, Y. Tamaru

14.

“Aromatic Allylsulfenylation with in situ Generated Allylic Thiols under the Heck Conditions”
Bull. Chem. Soc. Jpn., Vol. 70, No. 2, pp. 445-456 (1997-2).
著者	  H. Harayama, T. Nagahama, T. Kozera, M. Kimura, K. Fugami, S. Tanaka, Y. Tamaru

13“Chemoselective Intramolecular Aminocarbonylation of Unsaturated Amides under Wacker-type
Conditions”
Tetrahedron Lett., Vol. 37, No. 40, pp. 7287-7290 (1996-10).
著者	
  H. Harayama, H. Okuno, Y. Takahashi, M. Kimura, K. Fugami, S. Tanaka, Y. Tamaru

12.

“Aromatic Allylsulfenylation with in Situ Generated Allyl Thiols under the Heck Conditions”
Chem. Lett. Vol, 25, No. 7, pp. 543-544 (1996-7).
著者	  H. Harayama, T. Kozera, M. Kimura, S. Tanaka, Y. Tamaru

11.

“Propargylation of Carbonyl Compounds by Umpolung of Propargylpalladium Complexes with
Diethylzinc”
7Angew. Chem., Int. Ed. Engl., Vol. 35, No. 8, pp. 878-880 (1996-4).
著者	  Y. Tamaru, S. Goto, A. Tanaka, M. Shimizu, M. Kimura

10.

“Palladium-Catalyzed

Stereoselective

Allylaminocyclization

and(1,3-Butadien-2-yl)aminocyclization of Allenyl Tosylcarbamates”
J. Org. Chem., Vol. 60, No. 12, pp. 3764-3772 (1995-6).
著者	  M. Kimura, S. Tanaka, Y. Tamaru

9.

“Silver(I)-catalyzed Aminocyclization of 2,3-Butadienyl and 3,4-Pentadienyl Carbamates: An
EfficientandStereoselective

Synthesisof

4-Vinyl-2-oxazolidinones

and4-Vinyltetrahydro-2H-1,3-oxazin-2-ones”
Bull. Chem. Soc. Jpn., Vol. 68, No. 6, pp. 1689-1705 (1995-6).
著者	  M. Kimura, S. Tanaka, Y. Tamaru

8.

“Palladium(II) Catalyzed 5-Endo-trigonal Cyclization of 2-Hydroxybut-3-enylamines: Synthesis ofFive-membered Nitrogen Heterocycles”
J. Chem. Soc., Chem. Commun., No. 21, pp. 2531-2533 (1994-10).
著者	  M. Kimura, H. Harayama, S. Tanaka, Y. Tamaru

7.

“Convenient

Synthesisof

4-Methylene-1,3-oxazolin-2-ones

and

4-Methylenetetrahydro-1,3-oxazin-2-ones via Transition-Metal Catalyzed Intramolecular Additionof Nitrogen Atom to Acetylenic Triple Bond”
Bull. Chem. Soc. Jpn., Vol. 67, No. 10, pp. 2838-2849 (1994-10).
著者	  Y. Tamaru, M. Kimura, S. Tanaka, S. Kure, Z. Yoshida

6.

“Highly Regio-, Stereo-, and Chemoselective Diels-Alder Reaction of Monothiomaleimide, anAmbident C:S and C:C Dienophile”
J. Chem. Soc., Chem. Commun., No. 20, pp. 2365-2366 (1994-10).
著者	  Y. Tamaru, H. Sakata, M. Kimura, H. Harayama, H. Konishi, K. Fugami, S. Tanaka

5.

“Palladium-catalyzed Oxidative Aminocarbonylation of O-2,3-Butadienyl and O-3,4-Pentadienyl
N-Tosylcarbamates”
Tetrahedron Lett., Vol. 34, No. 47, pp. 7611-7614 (1993-11).
著者	  M. Kimura, N. Saeki, S. Uchida, H. Harayama, S. Tanaka, K. Fugami, Y. Tamaru

4.

“Palladium-catalyzed Regio- and Stereoselective Allylamination of Allenic Alcohols”
J. Org. Chem., Vol. 57, No. 24, pp. 6377-6379 (1992-10).
8

著者	
  M. Kimura, K. Fugami, S. Tanaka, Y. Tamaru

3.

“Palladium(II)-catalyzed Oxidative Aminocarbonylation of Unsaturated Carbamates”
Tetrahedron Lett., Vol. 33, No. 5, pp. 631-634 (1992-1).
著者	  Y. Tamaru, H. Tanigawa, S. Itoh, M. Kimura, S. Tanaka, K. Fugami, T. Sekiyama, Z.
Yoshida2.

“Silver(I)-catalyzed Aminocyclization of O-(2,3-Butadienyl)carbamates: An Efficient andStereoselective Synthesis of 4-Vinyl-2-oxazolidinones”
Tetrahedron Lett., Vol. 32, No. 44, pp. 6359-6362 (1991-10).
著者	  M. Kimura, K. Fugami, S. Tanaka, Y. Tamaru

1.

“Convenient Synthesis of Densely Functionalized N-Substituted 4-Methylene-2-oxazolidinone”

Tetrahedron Lett., Vol. 31, No. 34, pp. 4887-4890 (1990-8).
著者	  M. Kimura, S. Kure, Z. Yoshida, S. Tanaka, K. Fugami, Y. Tamaru

9Ⅱ．総説、解説及び著書	
 8.

“Palladium-catalyzed Selective Activation of Allyl Alcohols as Allyl Cations, Allyl Anions, andZwitterionic Trimethylenemethanes”
Pure and Applied Chemistry, Vol. 80, No. 5, pp. 979-991 (2008-3).
著者	  Y. Tamaru, M. Kimura

7.

“Nickel-Catalyzed Reductive Coupling of Dienes and Carbonyl Compounds”
Topics in Current Chemistry, Vol. 279, pp. 173-207 (2007-6).
著者	  M. Kimura, Y. Tamaru	 “Nickel-Catalyzed Homoallylation of Aldehydes with 1,3-Dienes”

6.	
 Organic Syntheses, Vol. 83, pp. 88-96 (2006-11).
著者	  Y. Tamaru, M. Kimura5.

「遷移金属触媒と有機亜鉛または有機ホウ素を活用した高効率有機合成反応の開発」	
 有機合成化学協会誌,	
 Vol.64, No.2, pp. 130-140 (2006-2).	
 著者	
  木村正成	
 4.

“Reaction of Dienes and Allenes”
Modern Organonickel Chemistry, Chap. 5, pp. 137-170 (2005-10).
著者	  M. Kimura, Y. Tamaru

3.

“Reactions of Acylpalladium Derivatives with Organometals and Related Carbon Nucleophiles”
Handbook of ORGANOPALLADIUM CHEMISTRY for Organic Synthesis, Vol. 2, pp. 2425-2454(2002-1).
著者	  Y. Tamaru, M. Kimura

2.	
 ニッケル、パラジウム触媒による有機ホウ素、有機亜鉛を用いた位置および立体選択的炭素-炭素結合形成」	
 有機合成化学協会誌,	
 Vol.59, No.5, pp.460-461 (2001-5).	
 著者	
  木村正成	 	 1.

“C-N Bond Formations via Transition Metal Catalysis”
SYNLETT, No. 7, pp. 749-757 (1997-7).
著者	  Y. Tamaru, M. Kimura	 	 10