R J Hill Laboratories Limited
1 Clyde Street
Private Bag 3205
Hamilton 3240, New Zealand

ANALYSIS
Client::Contact::

Tel +64 7 858 2000
Fax +64 7 858 2001
Email mail@hill-labs.co.nz
Web www.hill-labs.co.nz

REPORT

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Page 1 of 5:642034

Saido Co. (R8635)

Lab No:Saido Co. (R8635)

Date Registered::

2008-05-13

Date Reported:

1-10-21, Imaizumi, Chuo-ku, Fukuoka, Japan

Reference::

POPJv1(yyyy-mm-dd): 2008-05-22(yyyy-mm-dd):

JC493-2543

Sample Type: Food and Biologicals
SAIDO-PS501:Sample Name:

CARICACELAPI (papaya fermentation powder):

642034.1

Lab Number:

GC
Multiresidue GC Analysis (dried/oil Cat. C samples):

Analytes Detected:

None

LCMSMS1
Multiresidue LCMSMS1 Analysis (fresh & dried samples):

Analytes Detected:

None

These samples were collected by yourselves (or your agent) and analysed as received at the laboratory. This report must not be reproduced, except in full, without
the written consent of the signatory.
Refer to the following pages for method details, list of analytes screened and detection limits.

Hisashi ItoCountry Manager
Hill Laboratories
TEL 0476-48-8835
email: all@hill-labs.jp(Confirmation of Receipt)

Colin Malcolm BSc
Divisional Manager - Food & Bioanalytical Division(ILAC-MRA)(ILAC)(IANZ)

This Laboratory is accredited by International Accreditation New Zealand (IANZ), which represents New Zealand in the International Laboratory Accreditation
Cooperation (ILAC). Through the ILAC Mutual Recognition Arrangement (ILAC-MRA) this accreditation is internationally recognised.
The tests reported herein have been performed in accordance with the terms of accreditation, with the exception of tests marked *, which are not accredited.

SUMMARY OF METHODS
The following table(s) gives a brief description of the methods used to conduct the analyses for this job. The detection limits given below are those attainable in a relatively clean sample type.
Detection limits may be higher for individual samples should insufficient sample be available, or if the sample type requires that dilutions be performed during analysis.

:Sample Type: Food and Biologicals

Test

Method Description
GCGC-ECD/NPD

Multiresidue GC Analysis (dried/oil Cat. Csamples)

Default Detection Limit

GPCGC-MS
229

Samples-1-1Ethyl acetate extraction, GPC cleanup, GC-ECD/NPD analysis.
Confirmation by GC-MS.
This analytical method covers 229 analytes, as in following lists.
Note: The detection limits have been raised four fold to account fora dilution required during the analysis. Sample types that havebeen refined or concentrated necessitate a smaller sub-sample (5grams compared to 20 grams used for fresh or raw samples) to betaken for the analysis. This ensures the amounts of interferences
or co-extractives that may affect the analysis are kept to aminimum.
Analysis performed at Hill Laboratories - Food & Bioanalytical
Division, Waikato Innovation Park, Ruakura Lane, Hamilton.

LCMSMS1

SPE

Multiresidue LCMSMS1 Analysis (fresh & driedsamples),,52, LC-MS/MS

Solvent extraction, SPE cleanup, dilution, LC-MS/MS analysis.
This analytical method covers 52 analytes, as in following lists.
Analysis performed at Hill Laboratories - Food & Bioanalytical
Division, Waikato Innovation Park, Ruakura Lane, Hamilton.

Samples are held at the laboratory after reporting for a length of time depending on the preservation used and the stability of the analytes being tested. Once thestorage period is completed the samples are discarded unless otherwise advised by the client.

Detection Limits
Analytes

Detection Limit

Analytes

GC

Detection Limit

Multiresidue GC Analysis (dried/oil Cat. C samples)

Multiresidue GC Analysis (dried/oil Cat. C samples)

0.040 mg/kg
Benodanil

0.040 mg/kg
Benoxacor

0.020 mg/kg
0.040 mg/kg

BHC

0.020 mg/kg

0.040 mg/kg

BHC

0.020 mg/kg

0.12 mg/kg-BHC

0.020 mg/kg

BHC

0.020 mg/kg
0.040 mg/kg

Bifenox0.040 mg/kg
Bifenthrin

0.040 mg/kg
Bitertanol

0.080 mg/kg
Carbaryl

0.040 mg/kg

0.040 mg/kg
Bromacil: 642034 v 1

0.040 mg/kg
Captan0.080 mg/kg

Lab No:0.040 mg/kg
Captafol

0.080 mg/kg

Azoxystrobin

0.040 mg/kg
Cadusafos

0.040 mg/kg

Azinphos-methyl0.040 mg/kg
Butamifos

delta-BHC

Azaconazole

0.040 mg/kg
Butachlorgamma-BHC (Lindane)

Atrazine-desisopropyl

0.040 mg/kg
Buprofezinbeta-BHC

Atrazine-desethyl0.040 mg/kg
Bupirimatealpha-BHC

Atrazine

0.040 mg/kg
Bromopropylate0.040 mg/kg

Aldrin0.040 mg/kg
Bromophos-ethyl0.040 mg/kg

Alachlor

Multiresidue GC Analysis (dried/oil Cat. C samples)

0.040 mg/kg
Bendiocarb

Acetochlor

Detection Limit

GC

0.080 mg/kg
Acephate

Benalaxyl

Analytes

GC

0.040 mg/kg
Carbofenothion

Hill Laboratories

2/5

Page 2 of 5

Analytes

Detection Limit

Analytes

GC

Detection Limit

Detection Limit

GC

Multiresidue GC Analysis (dried/oil Cat. C samples)

Multiresidue GC Analysis (dried/oil Cat. C samples)

0.040 mg/kg

0.040 mg/kg

Carbofuran

Multiresidue GC Analysis (dried/oil Cat. C samples)

0.080 mg/kg
Epoxiconazole

0.040 mg/kg

Deltamethrin (Tralomethrin)-S-

Carboxin

CIS

0.020 mg/kg

0.12 mg/kg

TRANS

0.020 mg/kg

0.040 mg/kg

0.040 mg/kg

Esprocarb

0.040 mg/kg

Ethion0.040 mg/kg

Ethoprophos

0.040 mg/kg

Etridiazole

0.12 mg/kg

Etrimfos

0.20 mg/kg

Famphur

0.040 mg/kg

Fenamiphos

0.020 mg/kg

Fenarimol

0.040 mg/kg

Fenchlorphos

0.040 mg/kg

Fenitrothion

0.040 mg/kg

Fenobucarb

0.080 mg/kg

Fenoxaprop-ethyl0.040 mg/kg

Fenpiclonil

0.20 mg/kg

Fenpropathrin0.040 mg/kg

Fenpropimorph

0.080 mg/kg

Fensulfothion

0.20 mg/kg

Fenthion

0.080 mg/kg

Fenvalerate

0.040 mg/kg

Fluazifop-butyl

I0.020 mg/kg

Flucythrinate

II0.020 mg/kg

Fludioxonil

0.020 mg/kg

Fluometuron

0.020 mg/kg

Flusilazole

0.020 mg/kg

Flutriafol

0.020 mg/kg

Folpet0.040 mg/kg

Fonofos

Diazinon

0.020 mg/kg
0.020 mg/kg
0.020 mg/kg
0.020 mg/kg
0.020 mg/kg

2,4'-DDTDDT

0.020 mg/kg

0.080 mg/kg

Endrin0.080 mg/kg

Endrin aldehyde

4,4'-DDEDDT

0.040 mg/kg

Endosulfan sulfate

2,4'-DDE

DDT

0.080 mg/kg

Endosulfan II

4,4'-DDD

DDT

0.040 mg/kg

Endosulfan I

2,4'-DDD

DDT

0.040 mg/kg

Edifenphos

Cyprodinil

DDT

0.040 mg/kg

DiuronCyproconazole

0.080 mg/kg

0.080 mg/kg

Disulfoton

Cypermethrin

0.040 mg/kg

0.040 mg/kg

Diphenylamine

Cyhalothrin

0.040 mg/kg

0.040 mg/kg

Dioxabenzofos

Cyfluthrin

0.040 mg/kg

0.040 mg/kg

Dinocap

Cyanophos

0.040 mg/kg

0.040 mg/kg

Dimethylvinphos

Cyanazine

0.040 mg/kg

0.080 mg/kg

Dimethoate

Coumaphos

0.040 mg/kg

0.080 mg/kg

Dimethenamid

Clomazone

0.080 mg/kg

0.040 mg/kg

Diflufenican

Chlozolinate

0.080 mg/kg

0.040 mg/kg

Difenoconazole

Chlortoluron

0.040 mg/kg

0.040 mg/kg

Dieldrin

Chlorthal-dimethyl0.040 mg/kg

0.040 mg/kg

Dicrotophos

Chlorpyrifos-methyl0.040 mg/kg

0.040 mg/kg

Dicofol

Chlorpyrifos

0.040 mg/kg

0.040 mg/kg

Dichlorvos

Chlorpropham

0.040 mg/kg

0.080 mg/kg

Dichloran

Chlorothalonil

0.040 mg/kg

0.040 mg/kg

Dichlofluanid

Chlorobenzilate

0.040 mg/kg

0.040 mg/kg

Dichlofenthion

Chlorfluazuron

0.040 mg/kg

0.080 mg/kg

Dichlobenil

Chlorfenvinphos

0.040 mg/kg

0.040 mg/kg
Esfenvalerate

Chlorfenapyr

0.040 mg/kg

Endrin Ketone

EPN

0.040 mg/kg

EPTC

0.040 mg/kg

trans-chlordane

0.040 mg/kg

EPTC

Demeton-S-methyl

cis-chlordane

0.040 mg/kg

EPN

0.040 mg/kg

4,4'-DDTLab No:Analytes

GC

Furalaxyl: 642034 v 1Hill Laboratories

3/5

Page 3 of 5

Analytes

Detection Limit

Analytes

GC

Detection Limit

Multiresidue GC Analysis (dried/oil Cat. C samples)

Multiresidue GC Analysis (dried/oil Cat. C samples)

0.040 mg/kg
Mevinphos

0.040 mg/kg
Monocrotophos

0.020 mg/kg

0.040 mg/kg
0.12 mg/kg
Naled0.080 mg/kg
Napropamide

0.040 mg/kg
Nitrofen

0.040 mg/kg
Nitrothal-isopropyl

0.12 mg/kg

0.040 mg/kg
0.12 mg/kg
Omethoate

0.040 mg/kg
Oxadiazon

0.040 mg/kg
Oxadixyl

0.020 mg/kg
Oxychlordane

0.040 mg/kg
Oxyfluorfen

0.040 mg/kg
Paclobutrazol

0.040 mg/kg
Parathion-ethyl

0.080 mg/kg

0.040 mg/kg

0.040 mg/kg

0.040 mg/kg
0.040 mg/kg
Pendimethalin

0.20 mg/kg

0.040 mg/kg

0.080 mg/kg
Pyriproxyfen

0.040 mg/kg

0.040 mg/kg
Phenthoate

0.040 mg/kg
Quinalphos

0.080 mg/kg
Mepronil

0.040 mg/kg
Pyrimethanil

Permethrin

Malathion

0.040 mg/kg
Pyrifenox

0.040 mg/kg

Linuron0.12 mg/kg
Pyrethrin

Penconazole

Leptophos

0.080 mg/kg
Pyrazoxyfen

Parathion-methyl

Kresoxim-methyl0.040 mg/kg
Pyrazophos

0.040 mg/kg

Isoprocarb

0.080 mg/kg
Pyraclofos

0.040 mg/kg

Isofenphos

0.040 mg/kg
Prothiofos

0.040 mg/kg

Isazophos

0.040 mg/kg
Propyzamide

0.040 mg/kg

Iprodione

0.080 mg/kg
Propoxur

0.040 mg/kg

Iprobenfos

0.040 mg/kg
Propiconazole0.040 mg/kg

Iodofenphos

0.040 mg/kg
Propham

0.12 mg/kg

Indoxacarb

0.040 mg/kg
Propetamphos

Norflurazon

Imazalil

0.040 mg/kg
Propazine

0.040 mg/kg

Hexythiazox

0.20 mg/kg
Propargite

0.040 mg/kg

Hexazinone

0.040 mg/kg
Propaphos

0.020 mg/kg

Hexaconazole

0.040 mg/kg
Propanil

0.020 mg/kg

Hexachlorobenzene

0.080 mg/kg
Propachlor

Myclobutanil

Heptachlor epoxide

0.040 mg/kg
Prometryn

0.040 mg/kg

Heptachlor

0.040 mg/kg
Profenofos

0.040 mg/kg

Haloxyfop-methyl

Multiresidue GC Analysis (dried/oil Cat. C samples)

0.040 mg/kg
Metribuzin

Halfenprox

0.080 mg/kg
Phorate0.040 mg/kg
Quintozene

0.080 mg/kg

0.080 mg/kg
Phosalone

0.040 mg/kg
Quizalofop-ethyl

Metalaxyl (Mefenoxam)

0.040 mg/kg

0.040 mg/kg

Phosmet0.080 mg/kg

Phosphamidon

0.080 mg/kg

Piperonyl-butoxide

0.080 mg/kg

Pirimicarb

0.020 mg/kg

Pirimiphos-methyl0.040 mg/kg

Prochloraz

0.040 mg/kg
Simazine

Methacrifos

0.040 mg/kg

Methamidophos

0.080 mg/kg
Simetryn

0.080 mg/kg

Methidathion

0.040 mg/kg
Sulfentrazone

0.040 mg/kg

0.040 mg/kg
Sulfotep

Methiocarb0.040 mg/kg

Methoxychlor

0.040 mg/kg
Tebuconazole

0.040 mg/kg

0.040 mg/kg
Tebufenpyrad

Metolachlor

0.040 mg/kg
Procymidone: 642034 v 1

Detection Limit

GC

0.080 mg/kg
Furathiocarb

Lab No:Analytes

GC

0.040 mg/kg
TerbacilHill Laboratories

4/5

Page 4 of 5

Analytes

Detection Limit

Analytes

GC

Detection Limit

Analytes

LCMSMS1

Detection Limit

LCMSMS1

Multiresidue GC Analysis (dried/oil Cat. C samples)

0.040 mg/kg

Multiresidue LCMSMS1 Analysis (fresh & driedsamples)

0.040 mg/kg

Chloridazon

0.040 mg/kg

Clethodim0.040 mg/kg

Clofentezine

0.080 mg/kg

Diethofencarb

0.040 mg/kg

Diflubenzuron

0.040 mg/kg

Dodine0.040 mg/kg

Emamectin

0.040 mg/kg

Empenthrin

0.080 mg/kg

Fenhexamid

0.040 mg/kg

Fenoxycarb

0.040 mg/kg

Fenpyroximate

0.040 mg/kg

Fipronil

0.080 mg/kg

Flufenoxuron

0.040 mg/kg

Flumioxazin

0.080 mg/kg

Flutolanil

0.040 mg/kg

Imidacloprid

0.080 mg/kg

Lufenuron

Terbufos

0.040 mg/kg

0.080 mg/kg
Sethoxydim

Terbumeton

0.040 mg/kg

0.040 mg/kg
Spinosad

Terbuthylazine

0.040 mg/kg

0.040 mg/kg
Tebufenozide (Mimic)

Terbuthylazine-desethyl0.040 mg/kg

0.080 mg/kg
Teflubenzuron

Terbutryn

0.080 mg/kg

0.040 mg/kg
Tetraconazole

Tetrachlorvinphos

0.040 mg/kg

0.040 mg/kg
Thiacloprid

Tetradifon

0.040 mg/kg

0.040 mg/kg
Thiamethoxam

Thenylchlor

0.080 mg/kg

0.040 mg/kg
Thifluzamide

Thiobencarb

0.040 mg/kg

0.040 mg/kg
Thiophanate-methyl

Thiometon

0.040 mg/kg

0.040 mg/kg
Triadimenol

Tolclofos-methyl0.040 mg/kg

Tolylfluanid

0.040 mg/kg
Trichlorfon

0.040 mg/kg

0.040 mg/kg
Triflumuron

Triadimefon

P0.040 mg/kg

0.040 mg/kg

Uniconazole

Tri-allate

0.080 mg/kg

Triazophos

0.040 mg/kg

Trifloxystrobin

0.040 mg/kg

Trifluralin0.040 mg/kg

Vinclozolin

0.040 mg/kg

LCMSMS1

Metconazole

Multiresidue LCMSMS1 Analysis (fresh & driedsamples)

0.040 mg/kg
Methabenzthiazuron

0.080 mg/kg

0.040 mg/kg
Methomyl

Abamectin

0.080 mg/kg

0.040 mg/kg
Methoxyfenozide

Acetamiprid

0.040 mg/kg

0.040 mg/kg
Milbemectin

Aldicarb

0.12 mg/kg

0.040 mg/kg
Oryzalin

Aldicarb sulfone

0.040 mg/kg

0.040 mg/kg
Oxamyl

Aldicarb sulfoxide

0.040 mg/kg

0.040 mg/kg
Pencycuron

Ametryn

0.040 mg/kg

0.12 mg/kg
Propargite

Anilazine

0.080 mg/kg

0.040 mg/kg
Pymetrozine

Boscalid

0.040 mg/kg

0.040 mg/kg
Pyraclostrobin

Carbendazim

0.040 mg/kg

0.040 mg/kg
Carfentrazone-ethyl

Lab No:Multiresidue LCMSMS1 Analysis (fresh & driedsamples): 642034 v 1

Pyridaphenthion

Hill Laboratories

5/5

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