ヨウ素系重合開始剤
Iodine-Containing Initiators for Living Radical Polymerization

R-I

モノマー

非金属触媒

Effective for BA ( Bu4NI at 110 oC )Effective for MMA ( Bu3MePI at 70 oC )Ph CH IC O
O Et

Ph CH I
CNEt OO C C I
C O
O Et

CH2 C
I
C O
On

C I
C O
O Et

( PMMA-I )( EMA-I )( EA-I )( E-I )

IBME

RAME

AAME

235

<1

( PhE-I )( EEMA-I )( CP-I )( CE-I )

BCMH

PAME

MMMF

PNMM

PNMH

2500

100

887469アクリレート選択的O
IC I
C OOH

62

メタクリレート選択的OIOOI
OO

CH I
C OO

CH2 IC O
O Et

CH I
CN( PhCN-I )104 ka (M-1 s-1) =(70 oC )

CH I
C O
O Et

C ICN

I

( EMA-II )BBDG

ABA triblock copolymer

OO( PhE-II )
BPDG

OH

I

Telechelic polymer

O
O

I

O

O

Functionalgroup

第63回高分子学会年次大会
May 28th, 2014
1F13iodineIO
OStar polymer( EMA-III )TBTP【有機触媒を用いたリビングラジカル重合の休眠種開始剤の検討
有機触媒を用いたリビングラジカル重合の休眠種開始剤の検討】
有機触媒を用いたリビングラジカル重合の休眠種開始剤の検討（京大化研）（合同資源）○雷 琳・ 谷嶋 美保・ 後藤 淳 ・ 梶 弘典
宮本 充彦ヨウ素系重合開始剤
Iodine-Containing Initiators for Living Radical Polymerization
α-Iodo Esters
AAME

GSS-0006

RAME

Ethyl 2-Iodoacetate[623-48-3]
C4H7IO2 (214.00)

GSS-0003

BAME

Ethyl 2-Iodopropanoate[31253-08-4]
C5H9IO2 (228.03)

GSS-0019

Ethyl 2-Iodobutyrate[7425-47-0]
C6H11IO2 (242.05)

α-IodoCarboxylic Acid
AAMH

GSS-0007

2-Iodoacetic Acid
[64-69-7]
C2H3IO2 (185.95)

RAMH

GSS-0004

IBMH

2-Iodopropanoic Acid
[598-80-1]
C3H5IO2 (199.98)

VAME

GSS-0014

2-Iodoisobutyric Acid
[7425-20-9]
C4H7IO2 (214.00)

GSS-0023

IBME

Ethyl 2-Iodovalerate[31253-09-5]
C7H13IO2 (256.08)

α-IodoAmides

BLMH

RAMA

GSS-0017

EBMH

Benzyl Iodide[620-05-3]
C7H7I (218.03)

IBMM

Methyl 2-Iodoacetate[5199-50-8]
C3H5IO2 (199.98)

GSS-0021

ANMH

GSS-0013

2-Iodoacetonitrile[624-75-9]
C2H2IN (166.95)

Benzyl Iodides
BNMH

GSS-0015

GSS-0046

IBMB

Methyl 2-Iodoisobutyrate[67194-53-0]
C5H9IO2 (228.03)

PNMH

GSS-0030

Benzyl 2-Iodoisobutyrate[NA]
C11H13IO2 (304.12)

α-IodoNitriles2-Iodopropionamide[19221-80-8]
C3H6INO (198.99)

α-Iodo-γ-butyrolactone[31167-92-7]
C4H5IO2 (211.99)

AAMM

Ethyl 2-Iodoisobutyrate[7425-55-0]
C6H11IO2 (242.05)

α-IodoLactones
GSS-0042

GSS-0008

α-IodoKetones

GSS-0022

2-Iodopropionitrile[104024-32-0]
C3H4IN (180.98)

APMH

PNMM GSS-0044

2-Iodoisobutyronitrile[19481-79-9]
C4H6NI (195.00)

GSS-0031

2-Iodoacetophenone[4636-16-2]
C8H7IO (246.05)

Functionalized Compounds

GSS-0005

NTMH(1-Iodoethyl)benzene[10604-60-1]
C8H9I (232.06)

GSS-0045

IBMO

4-Nitrobenzyl Iodide[3145-86-6]
C7H6INO2 (263.03)

GSS-0036

PAMO

2-Hydroxyethyl 2-Iodoisobutyrate[NA]
C6H11IO3 (258.05)

GSS-0039

2-Hydroxyethyl 2-Iodo-2-phenylacetate[NA]
C10H11IO3 (306.10)

Highly Activated Compounds
PAME

GSS-0009

TAME

Ethyl 2-Iodo-2-phenylacetate[78489-65-3]
C10H11IO2 (290.10)

GSS-0034

NPME

Ethyl 2-Iodo-2-(4'-methylphenyl)acetate[NA]
C11H13IO2 (304.12)

GSS-0026

PAMH

Ethyl 2-Iodo-2-(4'-nitrophenyl)acetate[NA]
C10H10INO4 (335.10)

GSS-0018

α-Iodobenzyl Cyanide[63450-93-1]
C8H6IN (243.04)

MMMF

GSS-0010

MAME

Diethyl 2-Iodo-2-methylmalonate[119368-33-1]
C8H13IO4 (300.09)

PMMH

2-Iodo-2-phenylacetic Acid
[615256-95-6]
C8H7IO2 (262.04)

Highly Activated Compounds
BCMH

GSS-0020

GSS-0011

FLMH

Iododiphenylmethane[29704-39-0]
C13H11I (294.13)

GSS-0012

9-Iodo-9H-fluorene[64421-01-8]
C13H9I (292.12)

Multi-Iodinated Compounds
GSS-0032

PXDHEthyl 2-Iodo-2-methylacetoacetate[1005452-92-5]
C7H11IO3 (270.06)

GSS-0001

ADDF

p-Xylylene Diiodide[30362-89-1]
C8H8I2 (357.96)

GSS-0016

Diethyl 2,5-Diiodoadipate[165334-67-8]
C10H16I2O4 (454.04)

Multi-Iodinated Compounds
PXDL

GSS-0027

BBDG

1,4-Bis(1'-iodoethyl)benzene[NA]
C10H12I2 (386.01)

GSS-0024

BPDG

Ethylene Glycol Bis(2-iodoisobutyrate)[NA]
C10H16I2O4 (454.04)

GSS-0037

TBTP

Ethylen Glycole Bis(2-iodo-2-phenylacetate)[NA]
C18H16I2O4 (550.13)

GSS-0025

MSTK

Glycerol Tris(2-iodoisobutyrate)[NA]
C15H23I3O6 (680.05)

GSS-0028

1,3,5-Tris(1'-iodoethyl)benzene[NA]
C12H15I3 (539.96)

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