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Prepared on April 20, 2001
Revised on March 24, 2016

Safety Data Sheet
1. Chemical product and company identification
Chemical product name (product ：DOP
name)
Company name

：Japan Plasticizer Industry Association

Address：Tobu Building, 5-26, Motoakasaka 1-chome, Minato Ward, Tokyo,
Japan 107-0051

Department in charge：Japan Plasticizer Industry Association

Person in charge (prepared by)：Technical Department

Phone：03-3404-4603

Emergency phone：Same as aboveFax：03-3404-4604

Recommended use and limitations：Plasticizer and solvent for various resins

Reference number：0001

2. Hazards identification
GHS category
Physical hazard statements

Health hazards：Explosive

Not applicable：Flammable gases (including chemicallyunstable gas)

Not applicable：Aerosol

Not applicable：Oxidizing gases

Not applicable：Gases under pressure

Not applicable：Flammable liquids

Not classified：Flammable solids

Not applicable：Self-reactive substances

Not applicable：Pyrophoric liquids

Not classified：Pyrophoric solids

Not applicable：Self-heating substancesClassification notpossible：Substances and mixtures which, in contact
with water, emit flammable gases

Not applicable：Oxidizing liquids

Not applicable：Oxidizing solids

Not applicable：Organic peroxides

Not applicable：Corrosive to metals

Classification notpossible：Acute toxicity (oral)

Not classified：Acute toxicity (subcutaneous)

Not classified：Acute toxicity (inhalation: gas)

Not applicable：Acute toxicity (inhalation: vapor)

Classification not

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possible

Environmental hazards：Acute toxicity (inhalation: dust)

Not applicable：Acute toxicity (inhalation: mist)

Not classified：Skin corrosion/irritation

Not classified：Serious eye danger/eye irritation

Category 2B：Respiratory sensitization

Classification notpossible：Skin sensitization

Not classified：Germ cell mutagenicity

Not classified：Carcinogenicity

Not classified：Reproductive toxicity

Not classified：Specific target organ toxicity(single exposure)Classification notpossible：Specific target organ toxicity (repeatedexposure)

Not classified：Aspiration hazard

Classification notpossible：Hazardous to the aquatic environment(acute)Not classified：Hazardous to the aquatic environment(chronic)

Not classified：Hazardous to the ozone layer

Classification notpossible

GHS label
Hazard pictogram：None

Signal word

：Warning

Hazard statements：Eye irritation

Precautionary statements：[Safety measures]
Obtain the SDS before use.
Do not handle until all safety precautions have been read andunderstood.
Wear personal protective equipment as needed.
Do not breathe the mist.
Use only outdoors or in a well-ventilated area.
Avoid releasing into the environment.
[First aid measures]
If in eyes, rinse cautiously with water for several minutes. Next, remove
contact lenses, if present and easy to do. Continue rinsing.
If exposed or concerned, get medical advice/attention. Call a doctor if you
feel unwell.
If inhaled, remove person to fresh air and keep comfortable for breathing.
Collect spillage.
[Storage]
Keep container tightly closed and store in a well-ventilated place.
[Disposal]

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Commission disposition of the content/container to the dedicated waste
disposer authorized by the prefectural governor.
3. Composition/information on ingredients
Discrimination of single substanceor mixture：Single substanceChemical name：Bis(2-ethylhexyl) phthalate

Generic name：Di(2-ethylhexyl) phthalate (Abbr. DEHP)

Other name

：Dioctyl phthalate (Abbr. DOP)
1,2-Benzenedicarboxylic acid bis(2-ethylhexyl) ester

Chemical property (chemical
formula)：C6H4(COOCH2CH(C2H5)C4H9)2CAS No.

：117-81-7

Concentration or concentration
range：Not less than 99%

Reference number in gazette list in
Japan：(Chemical Substances Law, Industrial Safety and Health Law) (3)-1307

4. First-aid measures
If inhaled：Remove person to fresh air and keep at rest immediately and get
medical advice as needed.

If on skin

：Flush with running water and soap. If symptoms such as blisters andpain occur, get medical advice as needed.

If in eyes

：Rinse cautiously with water for several minutes. Next, remove contactlenses, if present and easy to do. Continue rinsing. Get medical
attention/advice.

If swallowed：Get water to rinse out mouth. Get medical attention/advice if the person
feels unwell.

5. Fire-fighting measures
Appropriate extinguishants：Foam, powder and carbon dioxide gas are effective.

Extinguishants that should not beused：No information.

Specific hazards regarding
fire-fighting：Irritating, toxic or corrosive gas may be generated according to the fire.

Specific fire extinguishing：Perform fire-fighting having the wind at your back.
Sprinkle the surrounded facilities with water for cooling.

Protection of the fire-fighting
person：Wear appropriate protective equipment (gloves and glasses or masks).

6. Accidental release measures
Personal precautions, protective
equipment and emergency
procedures：When indoors, perform ventilation sufficiently by the end of disposition.
In accidental release, prohibit the access of persons other than theinterested party by stretching a rope around the surroundings.
Take care of the place of accidental release because it is slippery.

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Wear protective equipment (see “8. Exposure controls/personal
protection”) when working.
Environmental precautions：Take care so that the spill will not be discharged into rivers and affectthe environment.

Collection/neutralization：Stop accidental release.

(Method and materials forcontainment and clean up)

For a small spill, collect the spill by adsorbing it with absorbent (sawdust,soil, sand, or waste cloth) and wipe the residue well with waste cloth anddust cloths.
For a large spill, prevent it from spreading by enclosing with
noncombustible matter (such as soil) and collect it with a shovel or suction
machine into an empty container.

Prevention of secondary disaster：Remove all the fire sources quickly (prohibit nearby smoking, sparks
and flames).
Prevent inflows into drains, sewers, basements and closed places.

7. Handling and storage
Handling
Technical measure：Take the actions for facilities described in “8. Exposure controls/personal
protection” and wear protective equipment.

Local ventilation/general
ventilation：Perform the local ventilation and general ventilation described in “8.
Exposure controls/personal protection.”

Precautions：Prevent leakage, spills and projection and do not generate vapor for noreason.
Keep away from high-temperature objects, sparks and flame and avoid
contact with strong oxidants. Take countermeasures against static
electricity and wear anti-static work clothes and shoes.

Precautions for safe handling：Do not handle until all safety precautions have been read andunderstood.
Watch out for fire.
Do not contact, inhale or swallow.
Avoid contact with eyes.
Do not inhale mist or vapor.
Wash your hands thoroughly after handling.
Avoid releasing into the environment.

Avoidance of contact
Hygiene measure：See “10. Stability and reactivity.”：Rinse hands well after handling.

StorageTechnical measures：Provide the daylighting equipment , lighting and ventilation required forstorage or handling of hazardous materials in the storage place.

Reactive hazardous substances：See “10. Stability and reactivity.”

Storage condition：Store away from oxidants.
Store in a well-ventilated place.

Packaging material of container：Use the container specified in the Fire Service Act.

8. Exposure controls/personal protection
Control level：Not established.

DOP Japan Plasticizer Industry Association 0001
Permissible level

Actions for facilities

2016-03-24：ACGIH (2012 version)

TLV-TWA

5 mg/m3

Japan Society for
Occupational Health (2012version)

TLV-TWA

5 mg/m3

5/12：For using indoors, it is desirable to close the source or establish local
ventilation equipment.
Provide shower, hand-washing and eye-washing equipment and indicate
the places clearly.

Protective equipment
Respirators：Use gas masks for organic gas, air-supplied respirators, air respirators,
etc. as the situation demands.

Protective gloves：Impermeable protective gloves

Protective glasses：Protective glasses with side panels (goggle type or full-face protective
glasses as needed)

Protective equipment for skin andbody：Antistatic long-sleeve protective clothes and shoes

9. Physical and chemical properties
Appearance：Colorless liquid

Odor：Almost odorless

Threshold of odor

：No data available

pH：No data available

Melding point/freezing point：－50℃

Boiling point：386℃

Flash point：218℃ (open)

Evaporation rate

：No data available

Flammable range：Lower limit of explosion range 0.1 vol% (in the air)1)

Vapor pressure：160 Pa（200℃）6.7×10－3Pa（68℃）

Vapor density (air = 1)

：13.46 (calculated value)

Specific gravity：0.986（20 / 20℃）

Solubility：Solubility in water: insoluble, 0.003 mg/L（25℃）：EU20012)

n-Octanol/water partition
coefficient：log Pow = 7.60 29)

Spontaneous ignition temperature：400℃

Decomposition temperature：No data available

Viscosity：77 mPa･s（20℃）

10. Stability and reactivity
Reactivity：Stable in usual handling and less reactive.

Chemical stability：Not self-degradable and chemically stable.

Possibility of hazardous reactions：Shows no self-reactivity and reacts with strong oxidants, strong acids
and strong bases.

Reactive hazardous substances：Substance becoming the ignition source such as high temperature,
flame, sparks, etc.

Material to avoid：Avoid blending with alkali metal hydroxides, acids, strong oxidants andnitrates.

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Hazardous degradation products

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6/12：Generates carbon dioxide and carbon oxide by combustion.

11. Toxicological information
Acute toxicity：LD50 (oral)Rat

30 g/Kg 3)

LD50 (oral)

Rabbit34 g/Kg 4)

LD50 (oral)

Guinea pig

26 g/Kg 5)

Rabbit25 g/Kg 6)(Not classified)
LD50 (percutaneous)(Not classified)
LD50 (inhalation: vapor)

No dataavailable(Classification not possible)
LD50 (inhalation: mist)(Not classified)7)
Skin corrosion/irritation：RabbitRat＞15.68 mg/L

（EU-RAR No.42(2003)）
500
mg/24H

Mild 8)

Considered not classified based on this test result.
Serious eye danger/eye irritation：Rabbit500
mg/24H

Mild 8)

According to ACGIH (7th, 2001),9) ATSDR (2002),10) EHC 131 (1992)11)
and EU-ARA No.42 (2003), it is conceivable that DOP is not eye irritatingor slightly eye irritating, and based on the study result that DOP isslightly eye irritating, it was classified into category 2B.
Respiratory sensitization：No data available. (Classification not possible)

Skin sensitization：According to the description in EU-RAR No. 42 (2003), DOP was notshown as skin sensitizing by test results of the “maximizing method andBuehler method using guinea pigs.” It was conceivable that DOP is notskin sensitizing, and it was classified as “not classified.”Germ cell mutagenicity(mutagenicity)：DOP was negative from results of mutagenicity tests with microbes (notinjurious to DNA).12)
According to CERI & NITE’s Hazards Evaluation No. 7 (2004)13) and
ATSDR (2002),10) DOP is positive in mutagenicity tests (dominant lethal
tests) through generations. However, since administration routes in thetests showing positive were not appropriate and other dominant lethal
tests and micronucleus tests proved negative, it was classified as “notclassified. ”

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Carcinogenicity

Reproductive toxicity

2016-03-24

7/12： In 1980, it was reported that DOP administration at very highconcentration to rats induced tumors in the liver. The subsequent
research revealed that the hepatic tumors occur through a mechanism
unique to rodents. 14)15) Based on this, in 2000, IARC (International
Agency for Research on Cancer) modified the DOP carcinogenic
classification from the conventional “2B” (possibly carcinogenic tohumans) to “3” (not classifiable as to carcinogenicity for humans) becauseof no carcinogenicity in humans.12)16) At the meeting in February 2011,
however, IARC decided to return DOP to “2B.”36) It is not because new
evidence in humans was found, but because further investigations andresearch are considered necessary for the mechanism and epidemiology ofcarcinogenicity in rodents. The Japan Plasticizer Industry Association(JPIA) examined in detail the articles used as the evidence for themodification,37)-39) and considered as in the past that species differences
exist in DOP carcinogenicity, and the GHS classification was establishedas “not classified.”：The substance was administered to a pair of male and female mice by
blending into food, and the pair mated multiple times . As a result
administration of 144 mg/kg/day or more was observed to produce
infertility and decrease the number of surviving babies of the same
pair.17), 18)
No influence is observed on testis in testing the substance by using adultand juvenile marmosets. 14), 19), 20), 21)
From the data of rats/marmosets in the studies performed so far, it was
shown that a large species difference exists in the reproductive toxicity(including testoid toxicity) of DOP between rodents and primates, andapplying the data obtained in rodents to humans is not considered. In thepast literatures of the assessment in CSTEE in EU,22) assessment by
CERHR in the U.S.A.23) and assessment by Advanced Industrial Scienceand Technology of Japan,24) , it is observed that there is any species
difference.
In the estimation of acceptable level based on the data of rodents, thediscussion about the above species difference has not been reflected to thesafety coefficient, and the possibility of reproductive toxicity in humans
has not been concluded yet.
It has been reported in the aspect of metabolism of DEHP that there is a
species difference between rodents and humans. That is, after ingestionof DEHP in rodents, its free metabolite is likely to circulate in the body,
but in humans, most of the metabolites are excreted from the bodyquickly in the nontoxic glucuronide form.25) These phenomena have been
confirmed in the experimental result of pharmacokinetics in theliver-humanized chimera mice, and the amount of exposure estimatedfrom the humanized PBPK model and human biomonitoring data is
incommensurably lower than the present TDI value.
That is, it was concluded that the risk is managed appropriately.26)
In compliance with the present manual for GHS classification, theevaluation of species difference is insufficient, it is inappropriate for DOP
with vast amounts of research data to perform the evaluation in humans
as the evaluation of species differences is insufficient, and at present, it
should not be classified (“not classified”).

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Specific target organ toxicity, single
exposure：Cannot be classified because of lack of data.

Specific target organ toxicity,repeated exposure：As described in the reproductive toxicity section, it was found from thedata of the study in rats/marmosets performed so far that thepharmacokinetics of DOP is different between rodents and primates, and
it is shown that testoid toxicity does not develop in primates. (Notclassified)

Aspiration hazards：No data available. (Classification not possible)

Others：No activations were observed in estrogen activation tests in vivo (uterine
hypertrophy reaction test with the ovariectomized rats).27), 28)

12. Ecological information
Biodegradability
Hazards to the aquatic
environment (acute)：Acute toxicity has not been reported at concentrations up to watersolubility (0.003 mg/L).
(Not classified)(Reference)
Killifish
LC50 ：75 mg/L29)
Salmon gairdneri LC50 ：540 mg/L30)

Hazardous to the aquatic
environment (chronic)：Classified as “not classified” because of rapid degradation and low
bioaccumulation.
The NOEL observed in the toxicity study of killifish in the initial
growth stage by Shioda and Wakabayashi (2000)31) and the Ministryof the Environment (2004d)32) using the dissolution aid by themethod considered appropriate is far higher than water solubility,
and the concentration is the implausible value at the DOP concentr
ation detected in the general aquatic environment. 33)

Persistence/degradation：Rapid degradation from the results of safety inspection on existingchemical substances (BOD solubility: 69%).34)

Bioaccumulation：No or low concentrative property from the results (BCF=29.7) of safety
inspection on existing chemical substances. 35)

Migratory property in soil

：No data available

Hazardous to the ozone layer：Classification not possible

13. Disposal consideration
Residual waste product：Entrust disposition to the dedicated waste disposers licensed by
prefectural governors.
If incinerating, spray into the fire chamber of incinerator with an exhaustgas washer and incinerate.
Take adequate care so that this substance will not be discharged intorivers, lakes and reservoirs, marine areas, sewage, etc.

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Contaminated container/package

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9/12：When disposing of empty containers, remove the content from thecontainers completely.
Do not drain waste water containing DOP before cleaning by disposition ofactivated sludge, etc.
Entrust disposition to the dedicated waste disposers licensed by
prefectural governors.

14. Transport information
International regulation
UN class
UN No.

：Not applicable to the UN classification standard.
：None

National regulation
Land transportation：Load and transport in compliance with the standards of the Fire Service
Act.

Special safety measures fortransportation or transportation
mode：When transporting by vehicles, it is desirable for freighters to deliver the
precautions for transportation to the transporter.
In transportation, confirm that no leakage exists in the container, andload the containers so as to prevent falling, dropping and damage and toprevent cargo from collapsing.

15. Regulatory information
Labor Safety and Health Act

Act on Confirmation, etc. of
Release Amounts of SpecificChemical Substances in theEnvironment and Promotion of
Improvements to the Management
Thereof：Article 57-1 of Act and Article 8-1 of Enforcement Ordinance, Attached
Table 9: Hazards of which the name, etc. should be notified(Cabinet Order No. 481)
：Article 57-2 of the Act and Article 8-2 of the Enforcement Ordinance,
Attached Table 9: Hazards of which the name, etc. should be notified(Cabinet Order No. 481)
：Paragraph 2, Article 2 of the Act, Article 1 of Enforcement Ordinance ,Attached Table 1, class 1 designated chemical substanceFire Service Act：Article 2 of the Act, Attached Table of hazardous materials, class 4
flammable liquids, class 4 petroleum (6,000 L)

Sea Water Protection Law：Enforcement Ordinance, Attached Table 1, Hazardous liquid substances(similar to class Y)

Food Sanitation Act：Specifications and standards of foods, additives, etc. 3-A-7 “In thedevices or containers and packages contacting with foods containing oil orfat, the synthetic resin mainly containing polyvinyl chloride usingbis(2-ethylhexyl) phthalate as a raw material should not be used as a raw
material. However, this shall not apply when processed so thatbis(2-ethylhexyl) phthalate may not dissolve or leach and may not bemixed with foods.
Specifications and standards of foods, additives, etc. 4-A-6 “the synthetic
resin mainly containing polyvinyl chloride using bis(2-ethylhexyl)
phthalate as a raw material should not be used as a raw material in toys.”

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Foreign Exchange and Foreign
Trade Law

：Because of being applicable to Item 16 of the attached table of Export
Trade Control Order, referring to the guidelines of Ministry of Economy,
Trade and Industry and prior consultation are desirable.

Revised Act on the Evaluation ofChemical Substances andRegulation of Their Manufacture,etc.

：Paragraph 5, Article 2 of the Act, priority assessment chemical
substances

16. Other information
Where to inquire about the contents
Japan Plasticizer Industry Association

Phone: 03-3403-4603, Fax: 03-3403-4604

Handling of the contents
The contents are prepared based on the materials, information and data available this time, but they do notguarantee the amount of content, physicochemical properties, risks/hazards, etc.
Since the precautions are for the usual handling, please use special handling after taking the safety measuresappropriate for the method of use.
In actual handling and use, please see the SDS issued by the manufacturer of the product that you will use.
References

1) International Chemical Safety Cards (ICSC) Japanese version, volume 3, 834, 835 (1997) edited by
Division of Safety Information on Drug and Food, National Institute of Health Science, supervised by
Safety Measure Division, Ministry of Health, Labour and Welfare.
2) European Union Risk Assessment Report - ECHA – Europa (2008).
3) NPRIRI Raw Material Data Handbook, 2, 32 (1975).
4) Environmental Health Perspectives, 4, 3 (1973).
5) IARC, IARC Monographs on the Evaluation of Carcinogenic Risks to Humans, 29, 269(1982).
6) Journal of Industrial Hygiene and Toxicology, 27, 130 (1945).
7) European Chemical Bureau, EU Risk Assessment Report, Vol.29 (2003).
8) Prehled Prumslove Toxicologie, 85JCAE-, 389 (1986).
9) ACGIH, Documentation of the TLVs and BEI, 7th, (2001)
10) ATSDR, U.S.DHHS: Toxicological profile for di(2-ethylhexyl)phthalate. September 2002,
11) EHC 131 (1992)
12) IARC: IARC Monographs on the Evaluation of Carcinogenic Risks to Humans. Vol.77, Some industrial
chemicals. 2000, IARC
13) CERI/NITE Hazard Assessment Report No. 7 (2004)
14) Kurata, Y., Kidachi, F., et al. “Subchronic toxicity of di(2-ethylhexyl)phthalate in common marmosets:lack of hepatic peroxisome proliferation, testicular atrophy, or pancreatic acinar cell hyperplasia”,
Toxicological Sciences, 42, 49-56 (1998)
15) ATSDR, U.S.DHHS: Toxicological profile for di(2-ethylhexyl)phthalate. September 2002, p.161
16) Report of International Agency for Research on Cancer (IARC) (February 2000)
17) Koizumi, M. et al., “Recent study of the toxic effects of phthalate esters on reproduction anddevelopment,” Japanese Journal of Food Chemistry and Safety, vol.7 (2), 65-71(2000)
18) Lamb JCIV, Chapin RE., et al. “Reproductive effects of four phthalic acid esters in the mouse.” Toxicol.

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Appl. Pharmacol., 88. 255-269 (1987)
19) Tomonari, Y. et al.: Testicular toxicity study of di(2-ethylhexyl)phthalate in juvenile common marmoset.
The Toxicologist, 72, s-1, March 2003, 385.
20) Tomonari Y, Kurata Y, David R M, Gans G, Kawasuso T, Katoh M., “Effect of Di(2-Ethylhexyl) Phthalate(DEHP) on Genital Organs from Juvenile Common Marmosets: I. Morphological and Biochemical
Investigation in 65-Week Toxicity Study”, Journal of Toxicology and Environmental Health A., 69(17),1651-1672, (2006).
21)Kurata Y, Makinodan F, Shimamura N, and Katoh M., “Metabolism of di (2-ethylhexyl) phthalate(DEHP): comparative study in juvenile and fetal marmosets and rats”,
The Journal of Toxicological Sciences, 37, 33-49, (2012).
22) Assessment by CSTEE of EU
23) Assessment by CERHR in the U.S.A.
24) Assessment by National Institute of Advanced Industrial Science and Technology in Japan25) Kurata Y, Katoh M. et al., “Metabolite profiling and identification in human urine after single oral
administration of DEHP”, The Journal of Toxicological Sciences, 37, 401- 414, 2012.
26)Koichiro Adachi, Hiroshi Suemizu, Norie Murayama. Makiko Shimizu,Hiroshi Yamazakia, “Humanbiofluid concentrations of mono(2-ethylhexyl)phthalate extrapolated from pharmacokinetics in chimericmice with humanized liver administered with di(2-ethylhexyl)phthalate and physiologically based
pharmacokinetic modeling”, Environmental Toxicology and Pharmacology , 39, 1067-1073, (2015).
27) A study for estrogen activity of phthalate esters, Mitsubishi Chemical Safety Institute Ltd. (1997)
28) Zacharewski, T., Meek, M.D., Clemons, J.H., et al. Toxicological Sciences, 46.282-293(1998)
29) Report of the experiment to study ecologic impact, Ministry of the Environment (1997)30) Hrudey, SE, et al. (1976). Proc.11th Canadian symp. 1976: Water pollution research Canada
31) Shioda and Wakabayashi “Effect of certain chemicals on the reproduction of medaka (Oryzias latipes).”,40(3), 239-43, (2000)32) Ministry of the Environment (2004d)
33) Nakanishi J, Yoshida K and Naito W. “Detailed Risk Evaluation Series 1 – Phthalate ester –DEHP”(Maruzen) (2005)34) Handbook of Existing Chemical Substance, version 5, P972, 978, the Chemical Daily (1988)
35) “Act on the Evaluation of Chemical Substances and Regulation of Their Manufacture, etc.: Chemical
Substances” (the Chemical Daily), supervised by Chemical Safety Division, Ministry of International Tradeand Industry (1994)36) Grosse Y et al. Carcinogenicity of chemicals in industrial and consumer products, food contaminants andflavourings, and water chlorination byproducts. Lancet Oncology 112: 328-329(2011)37) Yuki Ito et al. Different mechanisms of DEHP-induced Hepatocellular Adenoma
Tumorigenesis in Wild-type and PPARα-null mice. J. of Occup. Health 2008; 50: 169-180
38) Cristina Voss et al. Lifelong exposure to di-(2-ethylhexyl)-phthalate induces tumors in liver and testes ofSprague-Dawley rats Toxicology 206(2005) 359-371
39) Raymond M David et al. Chronic toxicity of di(2-ethylhexyl)phthalate in rats, Toxicological sciences 55,
433-443 (2000)

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Revision history

Dates
revisedReasons

05/20/2001
04/01/2002.

Overhaul by the Japan Plasticizer Industry Association
Additional description due to the revision of the Export
Trade Control Order
Overhaul by the Japan Plasticizer Industry Association
Revision according to JIS Z 7250:2005 (corresponding
to GHS)
Revision of classification in the Act for the Prevention ofMarine Pollution and Maritime Disasters
Revision of octanol/water partition coefficient
Revision due to the PRTR law revision
Revision due to the revision of the Ordinance on
Industrial Safety and Hygiene
Revision according to the revised Act on the Evaluationof Chemical Substances and Regulation of Their
Manufacture, etc.
Revision according to JIS Z 7252:2009
Revision according to the revised Act on the Evaluationof Chemical Substances and Regulation of Their
Manufacture, etc.
Revision associated with the change of classification ofcarcinogenicity in IARC
Revision according to JIS Z 7253:2012
Revision due to the revision of Ordinance on Industrial
Safety and Hygiene

03/01/2005
01/01/2007
12/01/2008
02/09/2009
10/01/2009
02/01/2010.
04/01/2010

08/06/2010
04/18/2011

06/30/2011.
02/28/2013.
03/24/2016

Remarks

12/12