Annex to the Citizen Group Green
Procurement Guidelines
List of Controlled Substances
Ver. 14.3

Rank 1:

Standards for substances whose use in materials is prohibited

Rank 2: Standards for substances whose use is restricted by conditions
such as thresholds and content parts

Rank 3:Standards for substances for which accurate information must

be provided, as well as the identification and management ofcontent and content parts

Rank 4:Standards for substances that are prohibited from use in the
manufacturing process of procured items

Issued on July 1, 2024

Citizen Watch Co., Ltd.

Rank 1：

Ver. 14.3

Rank １:

Standards for substances whose use in materials is prohibited

１．Relevant legislation:

Class 1 Specific Chemical Substances prescribed in the Act on the

Evaluation of Chemical Substances and Regulation of Their Manufacture, etc.
(hereafter, the “Chemical Substances Control Law”), Article 2, Paragraph 2,

Substances Prohibited for Manufacture by the Industrial Safety and Health Act,

Article 55, Specified Substances prescribed in the Law Concerning theProtection of the Ozone Layer Through the Control of Specified Substances andother Measures (hereinafter referred to as the Ozone Layer Protection Law),
Article 2, Paragraph 1, 5 types of PBT substances according to the U.S. Toxic

Substances Control Act (TSCA), Article 6(h), Substances prohibited underparagraph 2 of Supplementary Provision 16 (PFAS) of the Swiss Chemicals Risk

Reduction Decree, and substances covered by Annex A (Elimination) of the POPs
Convention.

Meanwhile, Class 1 Specific Chemical Substances, which are byproducts of the
manufacture of other chemical substances, should be managed in accordancewith the principles of best available technology (BAT) and in compliance withNo.

the standards set by government agencies.

Chemical substances

CAS No.

Primary

legislation
Chemicalenvironmental effects
Persistency, high1-1-1 Aldrin

309-00-2

1-1-2 Endrin

72-20-8

1-1-4 Dieldrin

60-57-1

As above

As above

1-1-5 Hexachlorobenzene

118-74-1

As above

As above

1-1-6 DDT

50-29-3

As above

As above

As above

As above

1-1-3 Chlordanes

1-1-7

N,N'-Ditolyl-p-

phenylenediamine

1-1-8 2,4,6-Tri-tert-butylphenol732-26-3

Substances

Primary

Control Law
As above

As above

As above
TSCA

accumulability
As above

As above

As above

1-1-9 Toxaphene

8001-35-2

As above

As above

1-1-10 Mirex

2385-85-5

As above

As above

Primary applications
Insecticides
Insecticides

Termite disinfestants etc.
Insecticides

Raw material for insecticides
etc

Insecticides

Antioxidants for rubber,styrene-butadiene rubber
Antioxidants and otheradditives (limited to lubricatingoils and fuel oils) , lubricatingoil

Insecticides, mite control

agents (in agricultural andlivestock farming applications)
Flame retardants for resins,

paints, paper, electricalRank 1：
No.

Chemical substances

CAS No.

Primary

legislation

Primary

environmental effects

Ver. 14.3
Primary applications
products etc., insecticide, ant
repellant

1-1-11 Bis(tributyltin) oxide

Antifouling agent for fishing

As above

As above

As above

As above

Insulating oils etc.

1-1-13 (with 2 or more chlorine

As above

As above

Machine oils etc.

1-1-14 Dicohol

As above

As above

Mite preventative agents

As above

Solvents

As above

As above

UV light absorbents

As above

As above

1-1-1256-35-9

Polychlorinated biphenyls(PCB)

Polychloronaphthalenes
atoms)

1-1-15 Hexachlorobuta-1,3-diene
2-(2H-1,2,3-Benzotriazole-

1-1-16 2-yl)-4,6-di-tert-butylphenol87-68-33846-71-7

Perfluoro

1-1-17 (octane-1-sulfonicacid)(PFOS) or its salts
Perfluoro

As above
TSCA

nets, and boat hulls etc.

Water and oil repellents,
surfactants

1-1-18 (octane-1-sulfonyl) =307-35-7

As above

As above

1-1-19 Pentachlorobenzene

608-93-5

As above

As above319-84-6

As above

As above

Lindane by-product319-85-7

As above

As above

Lindane by-product1-1-22 exane (also known as

58-89-9

As above

As above

1-1-23 Chlordecone143-50-0

As above

As above

As above

Flame retardants

As above

As above

As above

As above

As above

As above

As above

As above

As above

As above

As above

As above
Agricultural chemicals

fluoride (PFOSF)

1-1-201-1-21alpha-Hexachlorocyclohe
xane

beta-Hexachlorocyclohex
ane

gamma-Hexachlorocycloh
Lindane)1-1-24 Hexabromobiphenyl
1-1-251-1-26
1-1-27
1-1-28

Tetrabromodiphenyl

36355-01-8

ether

Pentabromodiphenyl
ether

Hexabromodiphenyl
ether

Heptabromodiphenylether

As above

1-1-29 Endosulfan

115-29-7

As above

As above

1-1-303194-55-6

As above

As aboveHexabromocyclododecane (HBCD)

3

PFOS raw material
Agricultural chemicals,
by-products

Agricultural chemicals,
insecticides
As above

Flame retardant treatment for

textiles, flame retardant beads

Rank 1：No.

1-1-31

Chemical substances

CAS No.

Primary

legislation

Primary

environmental effects

Pentachlorophenol andits salts and esters

paraffin(having 10 to 13
carbon atoms andcontaining more than

48% of chlorine by total
weight)1-1-33 Decabromodifenyl ether
Perfluorooctanoic acid
PFOA-related substances

1-1-35 Asbestos
1-1-37 4-Aminodiphenyl
1-1-384-Nitrodiphenyl and its
salts

for EPS, flame-proofed textiles

542-88-1
92-67-1

Wood antiseptics,

As above

As above

As above

As above

As above

As above

As above

As above（*2)

Carcinogenic

As above

As aboveDyes, Pigments

As above

As above

Dye intermediateTSCA

1-1-34 （PFOA）and its salts,

1-1-36 Bis(chloromethyl) ether

Primary applications
and curtains

Polychlorinated linear
1-1-32

Ver. 14.3

As above

As above

Insecticides and fungicides

Flame retardants

As above
For semiconductor,

extinguishing agents,
water repellents

Insulator, filler, thermal
insulation
Pigments

1-1-39 Benzidine and its salts

92-87-5

As above

As aboveDyes, Hardener

1-1-4091-59-8

As above

As aboveDyes, Antioxidant intermediatebeta-Naphthylamine andits salts

1-1-41 Yellow phosphorous

As above

Benzene adhesive

1-1-42 (greater than 5%
benzene)Ozone depleting

1-1-43 substances

1-1-441-1-45

Pentachlorobenzenethiol(PCTP)

Tris(isopropylphenyl)
phosphate

PIP (3:1)

133-49-3

68937-41-7

1-1-47

Rubber adhesive

Ozone Layer

Ozone layer

Refrigerants, foaming agents,

TSCA

TSCA
Chemicals Risk

and related substances

DecreeMethoxychlor

Reduction

72-43-5

Matches

Carcinogenic

Perfluorohexanesulfonic

1-1-46 acid (PFHxS), its chlorides

toxicity

As above

Protection Law(*3)

Flammability, acute

ChemicalSubstances

4

destruction

Non-decomposable
and highly

accumulative

Non-decomposable
and highly

accumulative

extinguishing agents

Additive for improving rigidityof rubber products

Flame retardant plasticizers forvinyl chloride products

Persistent and highly

Extinguishing foam, abrasives

Non-decomposable,

Insecticides, etc.

accumulative

bio-accumulativeand cleaners, coatings, etc.

Rank 1：No.

1-1-48Chemical substances

Decloramprass and its
isomers

1-1-49 UV-328

CAS No.
13560-89-9

Primary

legislation

Control Law

135821-03-3

As above25973-55-1

As above

135821-74-8

Primary

environmental effects
Non-decomposable,
bio-accumulative

Non-decomposable,
bio-accumulative

Ver. 14.3
Primary applications

Flame retardants, etc.

Ultraviolet absorbents, etc.

(*1) The term "ozone-depleting substances" refers to the Specified Substances listed in the middle
column of Annex 1 of The Law Concerning the Protection of the Ozone Layer Through the Control ofSpecified Substances and other Measures.

5

Rank 2：

Rank 2:

Ver. 14.3
Standards for substances whose use is restricted by conditions such as

thresholds and content parts
１．Relevant legislation: 2011/65/EU (RoHS), Annex II、Annex III、Annex IV, provided that Annex
II shall be according to Amendment Directive 2015/863/EU.
No.

Chemical substances

2-1-1
2-1-2

Cadmium and its compounds
Hexavalent chromium
compounds

Threshold
value

0.1%

Carcinogenic

Pigments, paints, inks, catalysts

Central nervous system dysfunction

Rubber curing agents, pigments,

Brain defects

Luminescence materials, electrical

0.1%

2-1-4

Mercury and its compounds

0.1%

2-1-5

PBBs

0.1%

2-1-7
2-1-8
2-1-9
2-1-10-Di (2-ethylhexyl)

phthalate DEHP

Butyl bezy phthalate
BBP

Dibutyl phthalate
DBP

Diisobutyl phthalate
DIBP

Pigments, anti-rust treatments,

Reproductive defects

Lead and its compounds

PBDEs

Kidney dysfunction

Primary applications

0.01%

2-1-3

2-1-6

Primary environmental effects

0.1%

0.1%

Carcinogenic

Carcinogenic

Mental disorders

Bioaccumulative Production of Dioxins
during combustion
Bioaccumulative

Production of Dioxins during
combustion

Serious influential anxiety toenvironment

Reproductive toxicity

batteries

solder, plating
contacts

Flame retardant
Flame retardant
Plasticizers for resin, Paints,

pigments, adhesives, lubricating
oil additives

0.1%

Reproductive toxicity

As above

0.1%

As above

As above

0.1%

As above

As above

It is also acceptable to keep the content rate below the threshold. (Regardless of whether it isintentional or not)Refer to 2011/65/EU (RoHS) Annex III and Annex IV for exemptions.

Rank 2：

Ver. 14.3

2．Relevant legislation:94/62/EC (EU Packaging Waste Disposal Directive)
No.

Chemical substance

2-2-1

Cadmium

2-2-2

Threshold

2-2-3

Lead

2-2-4

Mercury

Renal dysfunction, reproductive defects,
carcinogenic

Hexavalent chromium
compounds

Major toxicities

Carcinogenic

0.01%

by gross weight

Central nervous system dysfunction,
carcinogenic

Brain damage, mental disorders

3．Relevant legislation: 2023/1542 (EU Battery Regulation)
No.

2-3-1
2-3-2
2-3-3

Chemical substanceCadmium

Threshold

Major toxicities

0.002%

Renal dysfunction, reproductive defects, carcinogenesis

Lead
Mercury

Central nervous system dysfunction,

0.01%

carcinogenic

0.0005%Brain damage, mental disorder

4．Relevant legislation: France Ministerial Order dated April 13, 2022 specifying substances
contained in mineral oils prohibited for use in packaging materials and printed matter
intended for the public.
No.

Chemical substances
MOAH：Mineral oil aromatic

2-4-1 hydrocarbons with 1 to 7 aromaticrings

MOSH：Mineral oil saturated

2-4-2 hydrocarbons with 16 to 35 carbon
atoms

Thresholdvalue

Primary environmental
effects

1%(*1)

0.1%(*2)

1ppm(*3)

Reproductive toxicity
Carcinogen0.1%(*2)

Primary applications‧Packaging materials, one-way
advertisements, leaflets, etc.

‧General printed materials (excluding
books) (*2)

Restrictions do not apply to procured items incorporated into products that are clearly destined forcountries other than France at this time.
*1) Until December 31, 2024
*2) After January 1, 2025

*3) After January 1, 2025 Regulation value for aromatic rings from 3 to 7

7

Rank 2：

Ver. 14.3

5．Relevant legislation: 1907/2006/EC (REACH) Annex XVIIThe following table shows the items in Annex XVII that may be contained in the
Citizen Group's products. For details of the regulations, please refer to the originalNo.

document.
Chemical

2-5-1
2-5-2

2-5-3

2-5-4
2-5-5
2-5-6
2-5-7

2-5-8

Threshold

Main hazards

0.88μ g/cm2/week

Skin allergy

substances
Nickel

0.003％

Specific azo dye

0.0003％Hexavalentchromiumhydrocarbons

Phthalate esters

0.1％

Dimethyl fumarate

0.00001%
0.05％

Lead

acids

Total of PFCAs andtheir salts <25 ppb(C9-C14PFCAs), their Total of PFCAs andsalts and related(*1)

substances

Carcinogenic

0.0001%

Polycyclic aromatic

Perfluorocarboxylic

Carcinogenic

related substances

Carcinogenic

Restricted use
Molded articles that come into contact with theskin directly and for a long time.

Textile and leather which are expected to comeinto direct contact with the skin or oral cavity for along time

A leather part of a molded article including leather

which is supposed to come into contact with theskin

Molded articles containing rubber and plastic parts

that directly contact the skin and oral cavity for along period of time and repeatedly

Reproductive toxicity Articles containing plasticizers
Skin irritation

Central nervous

articlessystem dysfunction Exterior parts of the watch touching the skin
Carcinogenic

Persistent, Highly<260 ppb

accumulative

Manufacture and sale of individual substances

Use and sale of mixtures and molded products

For details of the regulations, please refer to the list of specific aromatic amines in Table 1.

Table 1 List of specific aromatic amines
Chemical substances

CAS No.

2-naphthylamici

91-59-8

4-Aminobiphenyl

92-67-1o-Toluidine

95-53-4o-anisidine

90-04-03,3'-Dichlorobenzidine

91-94-1

Benzidine

92-87-58

Rank 2：4-Chloro-2-methylaniline

95-69-2

2,4-Diaminotoluene

95-80-7o-aminoazotoluene

97-56-3

5-Nitro-o-toluidine

99-55-83,3'-Dichloro-4,4101-14-4'-Diaminodiphenylmethane
4,4 '-methylenedianiline

101-77-9

4,4 '-Diaminodiphenyl ether

101-80-4

P-chloroaniline

106-47-8

3,3'-Dimethylbenzidine

119-93-7

3,3'-Dimethoxybenzidine

119-90-4

2-methoxy-5-methylaniline

120-71-8

2,4,5-Trimethylaniline

137-17-7

2,4-Diaminoanisole

615-05-44,4'-Diaminodiphenyl sulfide

139-65-1

4,4'-Diamino-3,3838-88-0'-dimethyldiphenylmethane
4-aminoazobenzene

60-09-3

2,4-Xylidine

95-68-1

2-Amino-5-chlorotoluene hydrochloride

3165-93-3

4-Methoxy-1,3-benzenediamine sulfate

39156-41-7

2,6-Xylidine

87-62-7

2-Naphthaleneamine acetic acid553-00-4

2,4,5-Trimethylaniline hydrochloride

21436-97-5

9Ver. 14.3

Rank 3：

Ver. 14.3

Rank 3:Standards for substances for which accurate information must be

provided, as well as the identification and management of content and content parts
1. Relevant legislation: EU REACH Regulations (EC) No 1907/2006 Candidate List of SVHC
If the content rate of the following substances exceeds 0.1%, it is subject to reporting.
No
3-1-1
3-1-2
3-1-3
3-1-4

3-1-5

3-1-6
3-1-7
3-1-8
3-1-9
3-1-103-1-113-1-123-1-13Chemical substances

CAS No.

121-14-2

Substances classified as

4,4'-Diaminodiphenylmethane(MDA)

101-77-9

Substances classified as

2,4,6-Trinitro-5-t-butyl-1,3-xylene (musk81-15-2

Acrylamide
Short-chain chlorinated paraffins (carbon

xylene)chain length 10-13)

3-1-163-1-173-1-183-1-193-1-20carcinogenic - Article 57(a)explosive intermediates, dyes)

Curing agents for epoxy resins andpolyurethane resins

79-06-1

Carcinogenicity - Article 57(a)Synthesis of polyacrylamide, preparation of

85535-84-8"Persistent, bioaccumulative

Rubber, paints, gaskets, adhesives,(vPvB) - Article 57(e)Mutagenicity - Article 57(b)and toxic (PBT) - Article 57(d)Persistent, bioaccumulative

7789-09-5

Anthracene120-12-7
90640-80-5(vPvB) - Article 57(e)"CMR - Article 57(a), (b), (c)Persistent, bioaccumulative,
toxic (PBT) - Article 57(d)90640-81-6

Article 57(a)(b)(d)(,e)

Atlases、Petrol、Reserve points

91995-15-2

Article 57(a)(b)(d)(,e)

Anthracene oil, paste, light distillate

91995-17-4

Article 57(a)(b)(d)(,e)

90640-82-7

Benzyl butyl phthalate (BBP)

85-68-7

Bis(2-ethylhexyl) phthalate (DEHP)

117-81-7

polyacrylamide gel

lubricants, flame retardants, plasticizers

Manufacturing of photoconductor screen(CRT)

Dyes, catalysts, plastic products

Article 57(a)(b)(d)(,e)

Anthracene oil, Paste

Atlases (Atlases with low content)

organic synthesis (toluene diamine,

Fragrance ingredients

Ammonium heptaoxide dichromate

Anthracene oil

carcinogenic - Article 57(a)Usage Example

Chemical intermediates, raw materials for

Persistent, bioaccumulative

Article 57(a)(b)(d)(,e)

Reproductive toxicity - Article
57(c)Endocrine disruptive"Reproductive toxicity - Article

57(c).

Tar oil constituents, chemical products,

impregnants, tar special paint constituents

Plasticizers

Vinyl chloride plasticizer

Serious effects on the

3-1-143-1-15

Reason2,4-Jinitrotoluen

environment

Endocrine disrupting, PBT or
Tributyl tin oxide (TBTO)

56-35-9

Boric acid

10043-35-3

Boric acid11113-50-1

Cobalt chloride (CoCl)

7646-79-9

Pentadecanoic acid dihydrogen1303-28-2

Dibutyl phthalate (DBP)

84-74-2

Arsenic trioxide

1327-53-3

vPvB - Article 57(f)"Persistent, bioaccumulative,

Construction Industry

Reproductive toxicity - Article

Flame retardants, paints, brake fluid,

Reproductive toxicity - Article

Flame retardants, paints, brake fluid,

toxicity (PBT) - Article 57(d)
57(c)

57(c)

Carcinogenicity - Article 57(a)Carcinogenicity - Article 57(a)Carcinogenicity - Article 57(a)Reproductive toxicity - Article

57(c)Endocrine disrupting, PBT or

soldering products, film developers
soldering products, film developers

Ink for invisible writing revealed byapplying heat, lubricant, desiccant (used forsilica gel, etc.)

Dyeing, metallurgy, wood preservatives
Raw material for metallic arsenic

Plasticizers for vinyl chloride resin, etc.

Rank 3：No

3-1-213-1-22

Ver. 14.3
Chemical substances

Diisobutyl phthalate (DIBP)

Sodium tetraborate

Sodium tetraborate pentahydrate

Disodium tetraborate, decahydrate

3-1-233-1-243-1-293-1-303-1-313-1-323-1-333-1-343-1-351303-96-4

Hexabromic chlododecane (HBCDD) and

25637-99-4

Hexabromic chlododecane (HBCDD) andUsage Example

Reproductive toxicity - Article

Plasticizer, combined with other

Endocrine disrupting, PBT or

the manufacture of plastics, explosives, and57(c)vPvB - Article 57(f)Reproductive toxicity - Article
57(c)Reproductive toxicity - Article

57(c)Reproductive toxicity - Article
57(c)plasticizers, as a gelation accelerator, forpaintsGlass and glass fiber, ceramics, detergents,
personal care products, metallurgy,adhesives, flame retardants, industrial
fluidsGlass and glass fiber, ceramics, detergents,
personal care products, metallurgy,adhesives, flame retardants, industrial
fluidsGlass and glass fiber, ceramics, detergents,
personal care products, metallurgy,adhesives, flame retardants, industrial
fluidsFire retardant

Persistent, bioaccumulative,

Fire retardant3194-55-6

Persistent, bioaccumulative,

Fire retardant

Hexabromic chlododecane (HBCDD) and

134237-50-6

Persistent, bioaccumulative,

Fire retardant

Hexabromic chlododecane (HBCDD) and

134237-51-7

Persistent, bioaccumulative,

Fire retardant

Hexabromic chlododecane (HBCDD) and

134237-52-8

Persistent, bioaccumulative,

Fire retardant

Lead chromate(II)7758-97-6

Carcinogenicity - Article 57(a)Dyes and pigments, pigments for paints andall major diastereomers

all major diastereomers

3-1-2812179-04-3

ReasonvPvB - Article 57(f)Reproductive toxicity - Article

all major diastereomers

3-1-271330-43-4

12267-73-1

all major diastereomers

3-1-2684-69-5Tetraboron disodium acid hydrate

all major diastereomers

3-1-25CAS No.

Lead chromate molybdate sulphate (C.I.
Pigment Red 104)

12656-85-8

Lead hydrogen arsenate(II)7784-40-9

Yellow lead (C.I. Pigment Yellow 34)

1344-37-2

Coal tar pitch (high temperature)

Potassium chromate

65996-93-2

7789-00-6

Potassium dichromate

7778-50-9

Sodium chromate

7775-11-3

57(c)toxic (PBT) - Article 57(d)toxic (PBT) - Article 58(d)toxic (PBT) - Article 58(d)toxic (PBT) - Article 58(d)toxic (PBT) - Article 58(d)Reproductive toxicity - Article
57(c)Carcinogenicity - Article 57(a)Reproductive toxicity - Article
57(c)Carcinogenicity - Article 57(a)Reproductive toxicity - Article
57(c)Carcinogenicity - Article 57(a)Reproductive toxicity - Article
57(c)for plastics, printing

Insecticides, wood preservatives, pesticides

Pigments for paints, coatings, plastic
colorants, printing

Electrodes, carbon products molding

Carcinogenicity - Article 57(a)and coatings

toxic (PBT) - Article 57(d)Carcinogenicity - Article 57(a)Reproductive toxicity - Article
57(c)pigments, other graphite products, paints
Treatment and coating of metals, tanningand care of leather, electrodes, ink
production

Carcinogenicity - Article 57(a)Chromium metal manufacturing, metal

Carcinogenicity - Article 57(a)Production of other chromium compounds

7789-12-0

Disodium dichromate

10558-01-9

Carcinogenicity - Article 57(a)Trichloroethylene

79-01-6

Carcinogenicity - Article 57(a)15606-95-8

Pigments for paints and coatings, colorants

Persistent, bioaccumulative,

Disodium dichromate

Triethyl arsenate

varnishes

Carcinogenicity - Article 57(a)Carcinogenicity - Article 57(a)11processing and coating, photolithography
Production of chromic acid compounds(chromium sulfate), production of inorganic
chromic acid pigments

Production of chromic acid compounds(chromium sulfate), production of inorganic
chromic acid pigments

Cleaning or degreasing agent

Pesticide, wood rod, semiconductor.

Rank 3：No
3-1-36

Ver. 14.3
Chemical substances

CAS No.

Tris(2-chloroethyl) phosphate (TCEP)

115-96-8

Cobalt(II) sulfate

10124-43-3

ReasonFire retardant, plasticizer, adhesive

Carcinogenicity - Article 57(a)Manufacturing of chemicals, catalysts and57(c)3-1-393-1-403-1-413-1-423-1-433-1-44

production of pigments, bleaching (glass,ceramics), batteries, animal nutrition
Cobalt(II) nitrate

Cobalt carbonate (II)Cobalt acetate (II)513-79-1

71-48-7

Carcinogenicity - Article 57(a)Reproductive toxicity - Article
57(c)Carcinogenicity - Article 57(a)Manufacture of catalysts, manufacture of57(c)adhesives (ground coat frit)

Reproductive toxicity - Article
Carcinogenicity - Article 57(a)Reproductive toxicity - Article

chemicals, manufacture of pigments,
Catalyst manufacturing, chemical

manufacturing, surface treatment, alloys,
pigments, paints, dyes, rubber adhesives,
feed additives

Solvents, intermediate chemicals, fuel

2-Ethoxyethanol

110-80-5

Reproductive toxicity - Article

Solvents, intermediate chemicals

Chromium trioxide1333-82-0

Acid produced from chromium trioxide

Methyl cellosolve
Cellosolve

Chromic anhydride (Ⅵ)
and its oligomers

57(c)
57(c)

additives

Carcinogenicity - Article 57(a)Metal finishing, waterborne wood

7738-94-5

Carcinogenicity - Article 57(a)Dissolution of chromium trioxide

13530-68-2

Carcinogenicity - Article 57(a)Dissolution of chromium trioxide111-15-9

Carcinogenicity - Article 57(a)Solvents for paints, printing inks andMutagenicity - Article 57(b)preservative fixative(Chromic acid)(Dichromic acid, Dichromic acid)(Oligomers of chromic acid and dichromic

and its oligomers(Chromic acid)(Dichromic acid, Dichromic acid)(Oligomers of chromic acid and dichromic
2-ethoxyethyl acetate (cellosolve acetate)electronic materials (for resist inks), coating
solvents, intermediates for instant3-1-46
3-1-47(DHNUP: including 1,2-benzenecarboxylic

Di-C7-11-branched and linear alkyl esters
acid)

Hydralazine - hydrate

7789-06-2

68515-42-4

7803-57-8

Carcinogenicity - Article 57(a)Carcinogenicity - Article 57(a)Carcinogenicity - Article 57(a)adhesives

Anti-corrosive pigments

Plasticizers (PVC, bubble rubber, adhesives,
coatings)

Raw materials for foaming agents,

detergents, water treatment agents,

synthetic raw materials for industrial

3-1-48chemicals, synthetic raw materials for
agricultural chemicals, synthetic raw
Hydrazine

3-1-51surface treatment, batteries

Reproductive toxicity - Article

Strontium chromate

3-1-50

Manufacture of chemicals and catalysts,

109-86-4

acid)

3-1-49supplements, chemical fertilizers

2-Methoxyethanol

Acid produced from chromium trioxide

3-1-4510141-05-6

57(c)

acid)

3-1-44drying materials, surface treatment (e.g.
electroplating), corrosion protection,

3-1-373-1-38

Usage Example

Reproductive toxicity - Article

302-01-2

Carcinogenicity - Article 57(a)1-Methyl-2-pyrrolidone (NMP)

872-50-4

Carcinogenicity - Article 57(a)1,2,3-Trichloropropane

96-18-4

Carcinogenicity - Article 57(a)1,2-Benzenedicarboxylic acid, 6 to
8-carbon side-chain alkyl esters

71888-89-6

Carcinogenicity - Article 57(a)consisting mainly of 7-carbon side-chainhydrocarbons

12materials for pharmaceuticals, etc.

Resin solvents, acetylene solvents, solventsfor MOS semiconductor manufacturing,base materials for cosmetics

Cleaning agents, plasticizer raw materials

Plasticizers (PVC, sealants, coatings, inks))

Rank 3：
No

Ver. 14.3
Chemical substances

1,2-Benzenedicarboxylic acid with 6 to 8

CAS No.

ReasonUsage Example

Endocrine disrupting, PBT or

Manufacturing of polymer formulations andCarcinogenicity - Article 57(a)Manufacture of dyes for colored papers,
For the removal of air bubbles from ceramic

carbon atoms

3-1-523-1-533-1-543-1-553-1-56
3-1-573-1-583-1-593-1-603-1-613-1-623-1-633-1-643-1-65

3-1-66
3-1-67
3-1-684-(1,1,3,3-tetramethylbutyl)phenol

140-66-9

2-methoxyaniline

90-04-0

Arsenic acid

7778-39-4

Carcinogenicity - Article 57(a)Calcium arsenate

7778-44-1

Carcinogenicity - Article 57(a)Lead arsenate

3687-31-8

Carcinogenicity - Article 57(a)(4-tert-octylphenol)

1,2-Dichloroethane

107-06-2

Bis(2-methoxyethyl) ether

111-96-6

Bis(2-methoxyethyl) phthalate

57(c)polymers and aluminum foils

glass melts and the manufacturing oflaminated printed circuit boards

Metal refining process for the condensationof nickel from molten copper

Manufacturing of copper, lead, and many
precious metals

Raw materials for synthesis, solvents, etc.

Reproductive toxicity - Article

Used as a reaction solvent or for chemical

117-82-8

Reproductive toxicity - Article

Plasticizers for paints, lacquers andN,N-dimethylacetamide

127-19-5

Reproductive toxicity - Article

Used as a solvent and for industrial

Aniline-formaldehyde polycondensation

25214-70-4

Carcinogenicity - Article 57(a)Raw materials for synthesis, e.g. curing

Lead azide

13424-46-9

Reproductive toxicity - Article

Detonators and pyrotechnic devices

Lead trinitro-resorcinol

15245-44-0

Reproductive toxicity - Article

Ammunition, fireworks and detonators

2,2 '-Dichloro-4,4 '-methylenedianiline

101-14-4

Carcinogenicity - Article 57(a)Used as a curing agent for resins (such as

Chromium(III) (chromic acid)

24613-89-6

Carcinogenicity - Article 57(a)Potassium hydroxyoctaoxodizinc acid

11103-86-9

Carcinogenicity - Article 57(a)Pentazinc chromate octahydroxide

49663-84-5

Carcinogenicity - Article 57(a)Phenolphthalein

77-09-8

Carcinogenicity - Article 57(a)Aluminosilicate Refractory Ceramic Fibres(See CLP

Carcinogenicity - Article 57(a)product

dichromate

Regulation

57(c)

57(c)
57(c)

57(c)

57(c)

(EC) No 1272/

processing in a wide range of applications,and as an electrolyte in batteries

varnishes (including printing inks)

coatings, polyimide thin films, paintremovers and ink removers

agents for epoxy resins

urethane) and in the production of polymer
products

Mixtures for metal surface treatment in theaerospace, steel and aluminum coating
sectors

Manufacturing of aerospace, steel andaluminum coils and automotive coatings,
paint films and sealants

Manufacturing of automotive coatings,
paint films, paints and thinners

Used as a laboratory agent (in pH indicatorsolutions) for the production of pH test
papers and as a medical indicator

High temperature insulation materials forindustrial applications and fire protection

2008ANNEX IV
Table 3.1
Zirconia Aluminosilicate Refractory

3-1-71

Reproductive toxicity - Article

ethoxylates

Carcinogenicity - Article 57(a)3-1-693-1-70vPvB - Article 57(f)Ceramic Fibres

650-017-00-8)(See CLP

Regulation

Carcinogenicity - Article 57(a)High temperature insulation materials for

Reproductive toxicity - Article

Detonators(EC) No 1272/

industrial use and fire protection

2008ANNEX IV
Table 3.1
Lead nipicrate

650-017-00-8)
6477-64-1

57(c)

13

Rank 3：No
3-1-723-1-73

Ver. 14.3
Chemical substances

1,2 - Bis(2-methoxyethoxy)ethane(TEGDME; triglyme)

1,2 -dimethoxyethane, ethylene glycol
dimethyl ether (EGDME)Boron oxide

CAS No.

112-49-2

110-71-4

1303-86-2

ReasonReproductive toxicity - Article

57(c)Reproductive toxicity - Article
57(c)Reproductive toxicity - Article

57(c)Usage Example

Processing aids in the manufacture andformulation of solvents and industrial

chemicals. Miner, used in brake fluid andmotor vehicle repair

Solvent, used as a processing aid in the

manufacture and formulation of industrial
chemicals, including use as a solvent
electrolyte in lithium batteries

Fungicides and insecticides used innumerous applications in glass and glass

fiber, frit, ceramics, fire retardant, catalysts,
industrial fluids, metallurgy, nuclear power,

3-1-74

electrical equipment, adhesives,

inks/paints, film developers, detergents,
Formamide75-12-7

Reproductive toxicity - Article
57(c)cleaners, reagent chemicals, etc.

Used as intermediates in the manufactureof pesticides, pharmaceuticals andindustrial chemicals. Used as laboratory

reagents and solvents for quality control

3-1-75

purposes in forensic laboratories, hospitals,
pharmaceutical companies, food andbeverage manufacturers and research

3-1-76

Lead(II) methane sulfonate

1,3,5-Tris(oxiranylmethyl)-1,3,5
3-1-77-triazine-2,4,6(1H,3H,5H)-trione (TGIC)

2451-62-9

Reproductive toxicity - Article

57(c)Mutagenicity - Article 57(b)institutions. Used as plasticizer.

Mainly used in plating processes (bothelectrolytic and electroless) for electronic

components (e.g., printed circuit boards).
Used in batteries for special applications.

Curing agents for resins and paints. Printed
circuit board industry, electrical insulationmaterials, resin molding systems,

laminated sheets, silkscreen printing

paints, tools, adhesives, lining materials
1,3,5-Tris[(2S and 2R)-2,3

3-1-7817570-76-2-epoxypropyl]-1,3,5 -triazine-2,4,659653-74-6

Mutagenicity - Article 57(b)and plastic stabilizers.

Used as solder mask ink in the EU. Used inplastic molding systems, laminated sheets,silk screen printing, paints, tools,-(1H,3H,5H)-trione (β -TGIC)

adhesives, lining materials and stabilizers
for plastics, and electrical insulating

4,4′ -Bis(dimethylamino)benzophenone

90-94-8

Carcinogenicity - Article 57(a)materials.

Used as an intermediate in the manufactureof triphenylmethane dyes and othersubstances. Potential uses include use as a

3-1-79dye and pigment additive (photosensitiser)in dry film products and as a process

chemical in the manufacture of electronic
3-1-80

N,N,N',N'-Tetramethyl-4,4'-methylenedia

101-61-1

Carcinogenicity - Article 57(a)C.I. Basic Blue 26

2580-56-5

Carcinogenicity - Article 57(a)niline (Michler's base)

3-1-81circuit boards.

Used as intermediates in the manufactureof dyes and other substances

Used in the formulation of inks, cleanersand coatings, as well as in dyeing,

diagnostic and analytical applications forpaper, packaging, textiles, plastic products
C.I. Basic Violet 3

548-62-9

Carcinogenicity - Article 57(a)and fabrics

Used for paper coloration and as supply ink
for printer cartridges and ballpoint pens.
Staining of dry plants, staining in

3-1-82

microbiological and clinical laboratories,

used as a marker to enhance the visibility ofliquids

14

Rank 3：No
3-1-833-1-843-1-853-1-86

3-1-873-1-883-1-893-1-90Ver. 14.3
Chemical substances

ReasonUsage Example

4,4'-Bis(dimethylamino)-4''-(methylamin561-41-1

Carcinogenicity - Article 57(a)Used in writing formulations for staining

C.I. Solvent Blue 46786-83-0

Carcinogenicity - Article 57(a)Used in mixtures as a windshield washer,

Decabromodiphenyl ether (decaBDE)

1163-19-5

Persistent, bioaccumulative

Pentacosafluorotridecanoic acid,72629-94-8

Persistent, bioaccumulativeo)trityl alcohol

Perfluorotridecanoic acid,
Perfluorotridecanoic acid

Tricosafluorododecanoic acid,
Perfluorododecanoic acid,
Perfluorododecanoic acid

Henicosafluoroundecanoic acid,
Perfluoroundecanoic acid,
Perfluoroundecanoic acid

Heptacosafluorotetradecanoic acid,
Perfluorotetradecanoic acid,
Perfluorotetradecanoic acidformulations

Fire retardant for polystyrene, ABS resin,polyester, adhesive, sealant, textile coating
Surfactant

Surfactant

2058-94-8

Persistent, bioaccumulative

Surfactant

376-06-7

Persistent, bioaccumulative

Surfactant

Endocrine disrupting, PBT or

Foaming agent for rubber and synthetic

Endocrine disrupting, PBT or

Pharmaceuticals, agrochemicals,[1] Cyclohexane-1,2-dicarboxylic

85-42-7[2] Cis-cyclohexane-1,2-dicarboxylic

14166-21-3

anhydride(vPvB) - Article 57(e)for dyeing paper, printing inks and writing

Persistent, bioaccumulative

123-77-3

Diazene-1,2-biscarboamide(vPvB) - Article 57(e)various materials, as well as other inks

307-55-1

Azodicarbonamide, Azobisformamide,

anhydride

3-1-91CAS No.

13149-00-3(vPvB) - Article 57(e)(vPvB) - Article 57(e)(vPvB) - Article 57(e)vPvB - Article 57(f)vPvB - Article 57(f)resinsanthelmintics, raw materials for alkyd

resins, plasticizers, rust inhibitors, resin
modifiers, alkyd resins[3]Trans-cyclohexane-1,2-dicarboxylic
anhydride[Individual isomers of the cis [2] and trans[3] forms and all possible combinations of
cis and trans isomers [1]. All of theisomers are covered by this entry].

[1] Methylhexahydrophthalic anhydride

25550-51-0

anhydride48122-14-1[2] Hexahydro-4-methylphthalic[3]Hexahydro-1-methylphthalic
3-1-92

19438-60-9

Endocrine disrupting, PBT or

Epoxy resin curing agents, polyester

Endocrine disrupting, PBT or

Surfactant, resin, modifier raw materials,

vPvB - Article 57(f)coating materials

anhydride[4] Hexahydro-3-methylphthalicanhydride[[2], individual isomers of [3] and [4](including their cis and transstereoisomers) and all possiblecombinations of isomers [1]. All of theisomers are covered by this entry].

4-Nonylphenol, branched and linear

7311-27-5[substances with a covalently bonded

26027-38-3

4-Nonylphenol, branched and linear

9-carbon linear and/or branched alkyl

chain at position 4 of phenol, including
both individual isomers or mixtures ofisomers, and well-defined substances
3-1-93(substances of known composition, etc.)

68412-54-4

vPvB - Article 57(f)9016-45-9

9016-45-968412-54-4
14409-72-4
20427-84-3
27942-27-4
104-35-8

156609-10-8
20636-48-0

127087-87-0

1119449-38-5
1119449-37-4
127087-87-0
9016-45-915adhesives, paints, inks, rubber additives

Rank 3：
No

Ver. 14.3
Chemical substances

CAS No.

Reason37205-87-1

Usage Example

34166-38-6
27177-05-5
26571-11-94-(1,1,3,3-tetramethylbutyl)phenol,

26264-02-8

3-1-94

Endocrine disrupting, PBT or

Emulsifiers, Intermediates

Reproductive toxicity - Article

Organic synthetic intermediates

Reproductive toxicity - Article

Solvents (for urethane synthetic leather,vPvB - Article 57(f)ethoxylate

4-(1,1,3,3-tetramethylbutyl)phenol,

ethoxylate [well-defined substances(substances of known composition, etc.)

and UVCB substances, polymers and theirhomologues
3-1-95

Methoxyacetic acid625-45-6

N,N-dimethylformamide

68-12-2

3-1-96

3-1-973-1-100
3-1-101
3-1-1023-1-1033-1-104

dye intermediates, agricultural chemicals,
pharmaceutical synthesis, various
catalysts, gas absorbers

Dibutyltin dichloride, dichlorodibutyltin

683-18-1

Reproductive toxicity - Article

Vinyl chloride stabilizer intermediates,

Lead monoxide (Lead(II) oxide)1317-36-8

Reproductive toxicity - Article

Inorganic pigments, paints, raw materials(DBTC)

57(c)

57(c)

catalysts, rubber additives

for PVC stabilizers, solid lubricants,

vulcanization promoters for synthetic

rubber, raw materials for glass, batteries,
raw materials for varnishes for glass andceramics, radiation shielding agents

Orange red (lead tetroxide)1314-41-6

Reproductive toxicity - Article

Electronic materials, paints, glass materials,

Lead bismetrafluoroborate, lead

13814-96-5

Reproductive toxicity - Article

Tin plating chemicals, solder plating

Lead bis(carbonate)trihydroxide, basic

1319-46-6

borofluoride

lead carbonate, lead carbonatehydroxide, lead subcarbonate

Lead titanium trioxide, lead titanate

12060-00-3

Lead zirconium titanate, lead zirconate

12626-81-2

Lead silicate, basic lead silicate

11120-22-2

Barium silicate

68784-75-8

titanate(Limited conditions: 1:1 composition
3-1-10557(c)polymers, special inks, textile printing),

3-1-98

3-1-9957(c)ratio, doped with lead, with lead

57(c)
57(c)

batteries

chemicals

Reproductive toxicity - Article

Pigments for ceramics, paints, etc., raw

Reproductive toxicity - Article

Raw materials for semiconductors

Reproductive toxicity - Article

Raw materials for semiconductors

Reproductive toxicity - Article

Pigment, paint desiccant, crystal work,

Reproductive toxicity - Article

Bulb lamp coating

Reproductive toxicity - Article

Raw materials for pharmaceuticals and

57(c)

57(c)

57(c)

57(c)

57(c)

materials for electronic materials

glass raw materials

concentration above the thresholdconcentration for reproductive

threshold concentration for reproductive
toxicity)
3-1-106

3-1-1073-1-1083-1-109
3-1-110

1-Bromopropane (n-propyl bromide)

106-94-5

Methyloxirane (propylene oxide)

75-56-957(c)Reproductive toxicity - Article
57(c)agrochemicals, intermediates, cleaning anddegreasing

Polyester Resin, Urethane Resin Raw
Materials, Surfactant, Solvent Raw

Materials, Pigment, Pharmaceutical
Intermediates Raw Materials

Dipentyl phthalate, branched and linear

84777-06-0

Reproductive toxicity - Article

Diisopentyl phthalate (DIPP)

605-50-5

Reproductive toxicity - Article

Plasticizer

n-pentyl-isopentyl phthalate776297-69-9

Reproductive toxicity - Article

Plasticizer

57(c)

57(c)

57(c)

16

Plasticizer

Rank 3：No
3-1-1113-1-1123-1-1133-1-1143-1-115
3-1-116
3-1-1173-1-118
3-1-1193-1-1203-1-1213-1-1223-1-123
3-1-124
3-1-125
3-1-126
3-1-127
3-1-128
3-1-129
3-1-130

3-1-1313-1-132
3-1-133
3-1-134
3-1-135
3-1-136
3-1-137

Ver. 14.3
Chemical substances

CAS No.

ReasonUsage Example

1,2-Diethoxyethane, diethyl glycol, diethyl629-14-1

Reproductive toxicity - Article

Solvents for nitrocellulose, rubber, resin,

Basic lead acetate

51404-69-4

Reproductive toxicity - Article

Paints, coatings, fillers, intermediates

Lead oxy sulphate12036-76-9

Lead dioxide trilead phthalate

69011-06-9

Lead dioxobis(stearate)trilead, lead

12578-12-0

Lead fatty acid salts (16-18 carbon atoms)

91031-62-8

Lead cyanamide

20837-86-9

Lead dinitrate, lead(II) nitrate

10099-74-8

Tetrabasic lead sulfate

12065-90-6

Pyrochlore, C.I. Pigment Yellow 418012-00-8

Basic lead sulfite

62229-08-7

Tetraethyl lead, Tetraethyl lead

78-00-2

Tribasic lead sulfate

12202-17-4

Dibasic lead phosphate, dibasic lead

12141-20-7

Furan

110-00-9

Diethyl sulfate

64-67-5

Dimethyl sulfate

77-78-13-ethyl-2-isopentyl-2-methyl-1,3-oxazolid

143860-04-2

Reproductive toxicity - Article

Dinoseb (6-sec-butyl-2,4-dinitrophenol)

88-85-7

Reproductive toxicity - Article

Agrochemical intermediates (expired

4,4'-methylenedi-o-toluidine,

838-88-0

Carcinogenicity - Article 57(a)Curing Agents for Epoxy and Urethanecellosolve

dioxobis(stearate)trilead

phosphateine

4,4'-diamino-3,3'-dimethyldiphenylmethane4,4'-oxydianiline and its salts

101-80-44-aminoazobenzene

60-09-3

4-Methyl-m-phenylenediamine

6-methoxy-m-toluidine (p-cresidine)(toluene-2,4-diamine)

Biphenyl-4-ylamineo-aminoazotoluene (4-o-tolyl
azo-o-toluidine)o-Toluidine

57(c)

57(c)

etc., organic synthetic reaction solvents

Reproductive toxicity - Article

PVC additives

Reproductive toxicity - Article

PVC additives

Reproductive toxicity - Article

PVC additives

Reproductive toxicity - Article

PVC additives

Reproductive toxicity - Article

Anti-corrosive pigments

Reproductive toxicity - Article

Raw materials for lead compounds, raw

Reproductive toxicity - Article

PVC additives, Batteries

Reproductive toxicity - Article

Coatings, paints, ceramics

Reproductive toxicity - Article

PVC additives, resins

Reproductive toxicity - Article

Anti-knock agents (gasoline octane

Reproductive toxicity - Article

PVC additives, batteries

Reproductive toxicity - Article

PVC additives

Carcinogenicity - Article 57(a)Raw materials for synthetic resins, raw

57(c)
57(c)

57(c)

57(c)
57(c)
57(c)

57(c)

57(c)

57(c)

57(c)

57(c)
57(c)

"Carcinogenicity - Article 57(a)Mutagenicity - Article 57(b)"Carcinogenicity - Article 57(a)

57(c)

57(c)

Reproductive toxicity - Article
57(c)Mutagenicity - Article 57(b)materials for matches, explosives, opticalglasses, reagents, pigments

improvers), fuel additives

materials for organic synthesis, solvents,
detergents

Ethylating agents, relaxant dehydrating
agents, intermediates

Methylating agents for organic synthesis,
pharmaceuticals (raw materials),intermediates―

agrochemicals)

Resins, Synthetic Resin Intermediates
Organic synthetic intermediates, rawmaterials for polyimide resin

Reproductive toxicity - Article

Dyes, pigments, intermediates

95-80-7

Carcinogenicity - Article 57(a)Raw materials for polyurethane resins,

120-71-8

Carcinogenicity - Article 57(a)92-67-1

57(c)Carcinogenicity - Article 57(a)97-56-3

Carcinogenicity - Article 57(a)95-53-4

Carcinogenicity - Article 57(a)synthetic intermediates for dyes andpigments

Dye raw materials, intermediates―

Dyestuffs
Raw materials for intermediates of dyes andpigments, raw materials for epoxy resin
curing agents17

Rank 3：No
3-1-138
3-1-139
3-1-1403-1-1413-1-1423-1-143

Ver. 14.3
Chemical substances

CAS No.

N-methylacetamide, methylacetylamine

79-16-3

Cadmium

7440-43-9

Cadmium oxide

ReasonUsage Example

Reproductive toxicity - Article

Azo and sulfide dye intermediates

Carcinogenicity - Article 57(a)Pharmaceutical intermediates57(c)1306-19-0

Carcinogenicity - Article 57(a)Ammonium pentadecafluorooctanoate

3825-26-1

Reproductive toxicity - Article

Perfluorooctanoic acid (PFOA)

335-67-1

Reproductive toxicity - Article

Dipentyl phthalate (DPP)

131-18-0

Reproductive toxicity - Article

Plasticizer

4-Nonylphenol, branched and linear

104-40-5

Endocrine disrupting, PBT or

Raw materials for soaps, detergents and(APFO)

ethoxylates

30784-30-6
26543-97-5

57(c)

57(c)

57(c)

vPvB - Article 57(f)Pigments, batteries, alloys (nuclear reactor
control materials, bearings, etc.), plating,phosphors, electronics industry

Cadmium plating bath additives, pigments,
catalysts, alkaline batteries

For semiconductors, fire extinguishing

agents, water repellents, paper surface
treatment agents, resin modifiers

surfactants, textile processing agents,

agricultural chemical extenders, quasi-drug
additives (emulsifiers for cosmetics)

17404-66-952427-13-1

186825-36-5

3-1-144142731-63-3
84852-15-3
11066-49-2

186825-39-825154-52-3
90481-04-2
3-1-145
3-1-146
3-1-1471306-23-6

Carcinogenicity - Article 57(a)Pigments (high-grade paints, synthetic

Dihexyl phthalate (DnHP)

84-75-3

Reproductive toxicity - Article

Plasticizer

3.3'-[(1,1'-Biphenyl)-4,4'-diylbis(azo)]bis(4573-58-0

Carcinogenicity - Article 57(a)Direct dyes, biological dyes

1937-37-7

Carcinogenicity - Article 57(a)Dyes

96-45-7

Reproductive toxicity - Article

Imidazoline vulcanization accelerators-aminonaphthalene-1-sulfonate)
disodium (C.I. Direct Red 28)
Disodium

3-1-148521947-27-3

Cadmium sulfide

4-amino-3-[4'-(2,4-diaminophenylazo)-1,1'-biphenyl-4-ylazo]-5-hydroxy-6-phenyl

azo-2,7-naphthalene disulfonate (C.I.
Direct Black 38)

Ethylene thiourea (2-imidazolidinedione)
3-1-149

3-1-150
3-1-151
3-1-152
3-1-153
3-1-154
3-1-155
3-1-156
3-1-157

57(c)resins, glass)57(c)(chloroprene rubber, epichlorohydrin

rubber, chlorinated polyethylene), organic
rubber chemicals (vulcanization

Lead(II) acetate

301-04-2

Reproductive toxicity - Article

Tris(dimethylphenyl) phosphate25155-23-1

Reproductive toxicity - Article

Cadmium chloride

10108-64-2

CMR - Article 57(a), (b), (c)

57(c)

57(c)

1,2-Benzenedicarboxylic acid, dihexyl

68515-50-4

CMR - Article 57(a), (b), (c)Sodium peroxoborate; sodium perborate

7632-04-4

CMR - Article 57(a), (b), (c)Sodium perborate; perboric acid, sodium

15120-21-5

CMR - Article 57(a), (b), (c)Cadmium fluoride

7790-79-6

CMR - Article 57(a), (b), (c)10124-36-4

CMR - Article 57(a), (b), (c)ester, branched and linear

salt

Cadmium(II) sulfate

11138-47-9

18

accelerators)

Raw materials for lead compounds,

waterproofing agents, analytical reagents,
pharmaceuticals (astringents)

Plasticizer, raw material for flame retardant
hydraulic oil

Plating, catalyst

Plasticizer

Oxidizing bleach, cleaning and disinfecting

agents, preservatives, dyeing aids

Oxidizing bleach, cleaning and disinfecting
agents, preservatives, dyeing aids
Glass, solar cells, alloys, etc.

Raw materials for inorganic cadmium
compounds, metal surface treatment

Rank 3：No

3-1-157

3-1-158

3-1-159

3-1-160

Ver. 14.3
Chemical substances

CAS No.

Cadmium(II) sulfate31119-53-6

CMR - Article 57(a), (b), (c)2-Benzotriazol-2-yl-4,6-di-tert-butylpheno

3846-71-7"Persistent, bioaccumulative,l (UV-320)

2-(2H-Benzotriazol-2-yl)-4,6-di-tert-pentyl
phenol (UV-328)

10-ethyl-4,4-dioctyl-7-oxo-8-oxa-3,5-dithia-4-stannatetradecanoic acidtoxic (PBT) - Article 57(d)materials

Usage Example

Raw materials for inorganic cadmium
compounds, metal surface treatment
materials

UV stabilizers, UV protectants

Persistent, bioaccumulative
25973-55-1(vPvB) - Article 57(e)""Persistent, bioaccumulative,
toxic (PBT) - Article 57(d)Persistent, bioaccumulative
15571-58-1

2-ethylhexyl (DOTE)

Reaction product of

10-ethyl-4,4-dioctyl-7-oxo-8-oxa-3,5-dithi
3-1-161

Reason(vPvB) - Article 57(e)"stabilizers in coatings

Reproductive toxicity - Article

Heat Stabilizer for PVC

Reproductive toxicity - Article

Heat stabilizer for PVC, Biocide in

Reproductive toxicity - Article

Lubricants, Adhesives, Coating materials

Persistent, bioaccumulative

Flavoring ingredients

57(c)

57(c)

a-4-stannatetradecanoic acid

UV stabilizers, UV protectants, light

antifouling paints

2-ethylhexyl and10-ethyl-4-[[2-[(ethylhexyl)oxy]-2-oxoethyl]thio]-4-octyl-7-oxo-8-oxa-3,5-dithia-4-st
annatetradecanoic acid 2-ethylhexyl(reaction product of DOTE and MOTE)
1,2-Benzenedicarboxylic acid,
3-1-162

di-C6-10-alkyl ester; mixture of
1,2-benzenedicarboxylic acid,

68515-51-5
68648-93-1

decyl-hexyl-octyl diester and more than

0.3% dihexyl phthalate (EC No. 201-559-5)
5-sec-butyl-2-(2,4-dimethylcyclohexa-3-e
3-1-163n-1-yl)-5-methyl-1,3-dioxane[1],3-1-165
3-1-166
3-1-167

3-1-168

n-1-yl)-5-methyl-1,3-dioxane[2] (including
individual isomers of [1] and [2], orNitrobenzene

98-95-3

Reproductive toxicity - Article

Manufacture of other substances

2,4-Di-tert-butyl-6-(5-chlorobenzotriazol-3864-99-1

Persistent, bioaccumulative

UV protectants (paints, plastics, rubber,2-(2H-Benzotriazol-2-yl)-6-sec-butyl-4-ter

36437-37-3

Persistent, bioaccumulative

UV (ultraviolet) light protectant (paints,

1,3-propanesultone

1120-71-42-yl)phenol (UV-327)

t-butylphenol (UV-350)

Perfluorononanoic acid and its sodium
and ammonium salts

-

57(c)

(vPvB) - Article 57(e)(vPvB) - Article 57(e)cosmetics)

plastics, rubber, cosmetics)

Carcinogenicity - Article 57(a)Electrolyte solution for lithium batteries

57(c)manufacturing, lubricant additives,

Reproductive toxicity - Article
PBT (- Article 57(d))

Processing aids: fluoropolymer

Surfactant for fire extinguishers,

detergents, fabric stain inhibitors, polishing
Surfactant, waterproof materials, liquid

Perfluorononanoic acid and its sodium
3-1-168(vPvB) - Article 57(e)5-sec-butyl-2-(4,6-dimethylcyclohexa-3-e

combinations thereof)
3-1-16457(c)and ammonium salts

375-95-1

Reproductive toxicity - Article

57(c)PBT (- Article 57(d))

crystal display panels

Processing aids: fluoropolymer

manufacturing, lubricant additives,
Surfactant for fire extinguishers,

detergents, fabric stain inhibitors, polishing
Surfactant, waterproof materials, liquid

Perfluorononanoic acid and its sodium
and ammonium salts

21049-39-8

Reproductive toxicity - Article

57(c)PBT (- Article 57(d))

crystal display panels

Processing aids: fluoropolymer

manufacturing, lubricant additives,
Surfactant for fire extinguishers,

detergents, fabric stain inhibitors, polishing
Surfactant, waterproof materials, liquid
crystal display panels

19

Rank 3：
No

Ver. 14.3
Chemical substances

Perfluorononanoic acid and its sodium
and ammonium salts

CAS No.

4149-60-4

ReasonUsage Example

Reproductive toxicity - Article

Processing aids: fluoropolymer

PBT (- Article 57(d))

Surfactant for fire extinguishers,

57(c)manufacturing, lubricant additives,
detergents, fabric stain inhibitors, polishing
Surfactant, waterproof materials, liquid

Benzo(def)chrysene
3-1-169

3-1-1703-1-171

Benzo(a)pyrene

50-32-8

Benzo(pqr)tetraphene

Carcinogenicity - Article 57(a)Mutagenicity - Article 57(b)Reproductive toxicity - Article
57(c)PBT (- Article 57(d))
4,4'-isopropylidene diphenol (Bisphenol
A, BPA)

Nonadecafluorodecanoic acid (PFDA) andits sodium and ammonium salts

Nonadecafluorodecanoic acid80-05-7

vPvB (- Article 57e)

Reproductive toxicity - Article
57(c)Endocrine disrupting, PBT or-vPvB - Article 57(f)Reproductive toxicity - Article
57(c)Persistent, bioaccumulative,
335-76-2

toxic (PBT) - Article 57(d)Reproductive toxicity - Article
57(c)Persistent, bioaccumulative,
Sodium salts of decanoic acid andnonadecafluorodecanoic acid

Ammonium Nonadecafluorodecanoate

3830-45-3

toxic (PBT) - Article 57(d)Reproductive toxicity - Article
57(c)Persistent, bioaccumulative,
3108-42-7

toxic (PBT) - Article 57(d)Reproductive toxicity - Article
57(c)Persistent, bioaccumulative,
3-1-172

3-1-173
3-1-174

3-1-175

toxic (PBT) - Article 57(d)epoxy resin hardener manufacturing

Lubricant, Wetting agent, Plasticizer,
Antiseptic

Lubricant, Wetting agent, Plasticizer,
Antiseptic

Lubricant, Wetting agent, Plasticizer,
Antiseptic

Lubricant, Wetting agent, Plasticizer,
Antiseptic

80-46-6

4-tert-pentylphenol (PTAP)

30784-30-6

4-heptylphenol, branched and linear-

Endocrine disrupting, PBT or

Manufacture of polymers; lubricants

Perfluorobutane sulfonic acid and its salts-

Persistent, bioaccumulative

Plasticizer and lubricant; Surfactant,

1,3,4-Thiadiazolidine-2,5-dithione,-

Endocrine disrupting, PBT or

Used as additives in lubricants and greases

Persistent, bioaccumulative

Unplasticized fire retardants, used as"Carcinogenicity - Article 57(a)Usually not intentionally produced, but

vPvB (- Article 57e)"

substances(4-HPbl)formaldehyde and 4-heptylphenol,

branched and linear (RP-HP) [0.1% w/w
4-heptylphenol, branched and linear]
1,6,7,8,9,14,15,16,17,17,18,18-

13560-89-9

2,13 .0 5,10 ]octadeca7,15diene135821-74-8("Dechlorane Plus" TM) [any of its

135821-03-3

Endocrine disrupting, PBT or

Polycarbonate, epoxy resin manufacturing,

4-tert-pentylphenol (PTAP)

Dodecachloropentacyclo [12.2.1.1 6,9 .0
3-1-176

crystal display panels

Byproducts of carbon black production, etc.

vPvB - Article 57(f)Manufacture of chemicals and plastics

Endocrine disrupting, PBT orvPvB - Article 57(f)vPvB - Article 57(f)(vPvB) - Article 57(e)vPvB - Article 57(f)(vPvB) - Article 57(e)wetting agent, preservative, digestive agent

adhesives and sealants, binding materials

individual anti- and syn-isomers Any of its
individual anti- and syn-isomers, or any
combination thereof].

3-1-177

3-1-178

3-1-179

Chrysene

218-01-9

Cadmium nitrate

10325-94-7

Cadmium hydroxide

21041-95-2

PBT (- Article 57(d))"Carcinogenicity - Article 57(a)Mutagenicity - Article 57(b)""Carcinogenicity - Article 57(a)Mutagenicity - Article 57(b)"20occur as constituents or impurities in other
Used in the manufacture of glass, porcelain
and ceramic products and in researchchemicals

Used in the manufacture of electrical,

electronic, and optical equipment and inresearch chemicals

Rank 3：No
3-1-180

3-1-1813-1-1823-1-183

3-1-184
3-1-1853-1-186

3-1-187

3-1-188

3-1-189
3-1-1903-1-191

3-1-192
3-1-1933-1-194
3-1-195
3-1-1963-1-1973-1-198

3-1-199

3-1-200

Ver. 14.3
Chemical substances

CAS No.

Cadmium carbonate

513-78-0

Benz[a]anthracene Benz[a]anthracene

56-55-3Octamethylcyclotetrasiloxane (D4)556-67-2

Decamethylcyclopentasiloxane (D5)541-02-6

ReasonUsed in pH adjusters, water treatment"Carcinogenicity - Article 57(a)Usually not intentionally produced, but

vPvB (- Article 57e)"

substances

Mutagenicity - Article 57(b)"PBT (- Article 57(d))"PBT (- Article 57(d))

vPvB (- Article 57e)""PBT (- Article 57(d))
vPvB (- Article 57e)"

Dodecamethylcyclohexasiloxane (D6)

540-97-6

Lead7439-92-1

Reproductive toxicity (- Article

Disodium octaborate

12008-41-2

Reproductive toxicity (- Article

Benzo[ghi]perylene

191-24-2"PBT (- Article 57(d))

Terphenyl hydride

61788-32-7

vPvB (- Article 57e)

Ethylenediamine (EDA)

107-15-3

Endocrine disrupting, PBT or

Benzene-1,2,4-tricarboxylic552-30-7

Endocrine disrupting, PBT or

Dicyclohexyl phthalate

84-61-7acid-1,2-anhydride (trimellitic anhydride)

4,4'-(4-methylpentane-2,2-diyl)diphenol

6807-17-6

Benzo[k]fluoranthene

207-08-9

Fluoranthene

206-44-0

Phenanthrene

85-01-8

Pyrene129-00-0

1,7,7-Trimethyl-3-benzylidenebicyclo[2.2.

15087-24-8

2-Methoxyethyl acetate110-49-6

1]heptan-2-one

Tris(linear, branched-chain

4-nonylphenyl) phosphite (TNPP)

containing more than 0.1% by weight ofbranched and linear 4-nonylphenol

2,3,3,3-Tetrafluoro-2-(heptafluoropropoxy)propionic acid and its salts and acidhalides [including individual isomers andUsage Example"Carcinogenicity - Article 57(a)"PBT (- Article 57(d))

vPvB (- Article 57e)"

57c)

57c)

vPvB (- Article 57e)"

vPvB - Article 57(f)vPvB - Article 57(f)Endocrine disrupting, PBT orvPvB - Article 57(f)Reproductive toxicity (- Article

products, research chemicals, cosmetics,
and personal care products

occur as components or impurities in other
Cleaning and cleaning products, abrasives,
waxes, cosmetics and personal careproducts applications

Cleaning and cleaning products, abrasives,
waxes, cosmetics and personal careproducts, textile treatment products anddyestuff applications

For cleaning and polishing products, waxes,
cosmetics and personal care products.

Metal, welding and soldering products,
metal surface treatment products andpolymer applications

Anti-freeze products, heat transfer fluids,
lubricants and greases, washing andcleaning products

No registration under REACH. Usually notintentionally produced, but occurs as aconstituent or impurity of other substances.
Plastic additives, solvents, applications inpaints/inks, applications in adhesives andsealants, heat transfer fluids

Adhesives and sealants, coating products,

filters, putty, plaster, clay, pH adjusters andwater treatment product applications
Ester and polymer manufacturing
applications

Plastisol, PVC, rubber and plastic molded
product applications. As a reactive

desensitizer and dispersant in organic
peroxide formulations.

57c)"Carcinogenic (- Article

57a)PBT (- Article 57(d))
vPvB (- Article 57e)""PBT (- Article 57(d))

vPvB (- Article 57e)"
vPvB (- Article 57e)

"PBT (- Article 57(d))

vPvB (- Article 57e)"

Endocrine disrupting, PBT or

Transportation intermediates for the

manufacture of refined chemical products(fine chemicals)

vPvB - Article 57(f)Reproductive toxicity (- Article

57c)

Endocrine disrupting, PBT or

Mainly used as an antioxidant to stabilize

Endocrine disrupting, PBT or

Processing aids in the production ofvPvB - Article 57(f)vPvB - Article 57(f)combinations thereof] (HFPO-DA)

21

polymers

fluorinated polymers.

Rank 3：No
3-1-201
3-1-2023-1-203
3-1-204

3-1-205

3-1-206
3-1-2073-1-2083-1-209
3-1-210

Ver. 14.3
Chemical substances

CAS No.

98-54-4

Endocrine disrupting, PBT or

Diisohexyl phthalate

71850-09-4

Reproductive toxicity (- Article

Diisobutyl phthalate

84-69-5

Diisobutyl phthalate605-50-5

2-Benzyl-2-(N,N-dimethylamino)-1-(4-mor

119313-12-1

2-Methyl-1-[4-(methylthio)phenyl]-2-mor

71868-10-5pholinophenyl)butan-1-one
pholino-1-propanone

Perfluorobutane sulfonic acid (PFBS) andits salts

3-1-212vPvB - Article 57(f)Reproductive toxicity (- Article

57c)

Reproductive toxicity (- Article

Used for polymer production

Reproductive toxicity (- Article

Used in polymer production

Endocrine disrupting, PBT or

Fire retardant in polycarbonate (for

57c)
57c)

Reproductive toxicity - Article

2-Methylimidazole693-98-1

Reproductive toxicity - Article

Butyl 4-hydroxybenzoate

94-26-8

Dibutyl bis(2,4-pentanedionato)tin(IV)22673-19-4

Bis(2-(2-methoxyethoxy)ethyl)ether

143-24-8

57(c)
57(c)

Endocrine disrupting, PBT orvPvB - Article 57(f)Reproductive toxicity - Article
57(c)Reproductive toxicity - Article

57(c)Reproductive toxicity - Article
57(c)derivatives (the main carbon number ofthe fatty acid acyloxy moiety therein isC12)

2-(4-tert-butylbenzyl)propionaldehyde

80-54-6

Reproductive toxicity - Article

3-1-213

Orthoboric acid, sodium salt

13840-56-7

Reproductive toxicity - Article

3-1-2142,2-bis(bromomethyl)propane1,3-diol

3296-90-0

Carcinogenicity - Article 57(a)2,2-Dimethylpropan-1-ol

36483-57-5

Carcinogenicity - Article 57(a)2,2-bis(bromomethyl)-1-propanol1522-92-5

Carcinogenicity - Article 57(a)2,3-dibromo-1-propanol (2,3-DBPA)

96-13-9

Carcinogenicity - Article 57(a)3-1-215

Glutaral

111-30-8

Endocrine disrupting, PBT or

3-1-216

Medium-chain chlorinated paraffins-

PBT (- Article 57(d))

and its individual stereoisomers(BMP);(TBNPA)(MCCP) [UVCB substances consisting of
more than or equal to 80% linear

other substances.

57c)

1072-63-5

stannane, dioctyl-, bis(fatty acid acyloxy)

adhesives, sealants, and for the synthesis of57c)

1-Vinylimidazolebis(coco acyloxy) derivatives and other

Usage Example

Applications for coated products, polymers,

Reproductive toxicity (- Article

vPvB - Article 57(f)Dioctyltin dilaurate, stannane, dioctyl-,
3-1-211

Reason4-tert-butylphenol (PTBP)

57(c)

57(c)

vPvB - Article 57(f)vPvB (- Article 57e)

22

electrical and electronic equipment),

catalyst, additive and reactant in polymer
production and chemical synthesis.

Rank 3：
No

Ver. 14.3
Chemical substances

chloroalkanes with carbon chain lengths

CAS No.

ReasonUsage Example

within the range from C14 to C17]
3-1-217

Phenol, alkylation products (mainly in

Reproductive toxicity - Article

linear alkyl chains from oligomerisation,

vPvB (- Article 57e)para position) with C12-rich branched or57(c)covering any individual isomers and/ or
3-1-218

combinations thereof (PDDP)
1,4-dioxane

123-91-1

Endocrine disrupting, PBT or

3-1-2194,4'-(1-methylpropylidene)bisphenol;

77-40-7

Endocrine disrupting, PBT or

3-1-220

Contains any of the individual isomers of(bisphenol B)

ethylene]bicyclo[2.2.1]heptan-2-one(3E)-1,7,7-trimethyl-3-(4-methylbenzylide

1782069-81-1(1R, 3E,

95342-41-9ne)bicyclo[2.2.1]heptanone-2-one4S)-1,7,7-trimethyl-3-(4-methylbenzylidene)bicyclo[2.2.1]heptanone-2-one(1S, 3Z,4R)-1,7,7-trimethyl-3-(4-methylbenzylidene)bicyclo[2.2.1]heptanone-2-one

vPvB - Article 57(f)Persistent, bioaccumulative

Cosmetics (anti-fading agent)

Endocrine disrupting, PBTor

Cosmetics (anti-fading agent)

Endocrine disrupting, PBTor

Cosmetics (anti-fading agent)

Endocrine disrupting, PBTor

Cosmetics (anti-fading agent)

Endocrine disrupting, PBTor

Cosmetics (anti-fading agent)(vPvB) Article 57(e)."(±)-1,7,7-trimethyl-3-[(4-methylphenyl)m
and/or combinations thereof (4-MBC)

vPvB - Article 57(f)852541-25-4

vPvB Article 57(f)vPvB Article 57(f)vPvB Article 57(f)(±)-1,7,7-trimethyl-3-[(4-methylphenyl)m

36861-47-9(1R,4S)-1,7,7-trimethyl-3-(4-methylbenzyl

741687-98-9

Endocrine disrupting, PBTor

Cosmetics (anti-fading agent)(1S, 3E,

852541-30-1

Endocrine disrupting, PBTor

Cosmetics (anti-fading agent)(1R,3Z,4S)-1,7,7-trimethyl-3-(4-methylben

852541-21-0

Endocrine disrupting, PBTor

Cosmetics (anti-fading agent)

3-1-221

6,6'-di-tert-butyl-2,2'-methylenedi-p-cres

119-47-1

Endocrine disrupting, PBTor

Rubber, lubricants, adhesives, inks, fuels

3-1-222S-(tricyclo[5.2.1.0'2,6]deca-3-en-8(or255881-94-8

Endocrine disrupting, PBTor

Lubricants, greases

Tris(2-methoxyethoxy)vinylsilane

1067-53-4

Endocrine disrupting, PBTor

Rubber, plastics, encapsulants (silane

N-(hydroxymethyl)acrylamide

924-42-5

Reproductive toxicity ,Article

Textile leather modification and resin

ethylene]bicyclo[2.2.1]heptanone-2-one
idene)bicyclo[2.2.1]heptanone-2-one

4R)-1,7,7-trimethyl-3-(4-methylbenzylidene)bicyclo[2.2.1]heptanone-2-one

zylidene)bicyclo[2.2.1]heptanone-2-oneol (DBMC)9)-yl) O-(isopropyl or isobutyl or

2-ethylhexyl) O-(isopropyl or isobutyl or
3-1-223
3-1-2242-ethylhexyl) phosphorodithioate

vPvB Article 57(f)vPvB Article 57(f)vPvB Article 57(f)vPvB Article 57(f)vPvB Article 57(f)vPvB Article 57(f)vPvB Article 57(f)57 (c)(antioxidants, anti-aging agents)

coupling agents)

processing, synthetic resin coatings,

adhesives, paper processing enhancers, soil
conditioners

3-1-225

1,1'-[Ethane-1,2-diylbisoxy]bis[2,4,6-tribr

37853-59-1

vPvB (Article 57e)

Flame Retardants for ABS

3-1-226

2,2',6,6'-tetrabromo-4,4'-isopropylidene

79-94-7

Carcinogenicity (Article 57a)

Flame retardants

4,4'-Sulfonyldiphenol

80-09-1"Reproductive toxicity (Article

Dyeing aid 225-agent, flame retardant, raw

3-1-228

Barium metaborate

13701-59-2

Reproductive toxicity (Article

Anti-mold agent, anti-corrosion paint,

3-1-229

Bis(2-ethylhexyl) tetrabromophthalate

26040-51-7

3-1-227

omobenzene]
diphenol

57c)

57c)

e) vPvB (extremely persistent23

material for photographic couplers
flame retardant

Added as plasticizers to polyvinyl chloride

Rank 3：No

3-1-230

3-1-231

Ver. 14.3
Chemical substances

CAS No.

(covering any of the individual isomers
and/or combinations thereof)
Isobutyl 4-hydroxybenzoate

Melamine (monomer)

4247-02-3

108-78-1

ReasonUsage Example

and highly bioaccumulative

products (sheets, leather, wire coating

Endocrine disrupting

Antifungal agents and preservatives for

substance)

properties (Article 57(f) Human health)Equivalent level of concernthat may seriously affecthuman health (Article 57(f) -materials, films for agricultural vinyl, etc.)
cosmetics, pharmaceuticals, foods, etc.
Melamine resin (POM), adhesives,
pharmaceutical raw materials

Human health)Equivalent level of concernthat may have a serious effecton the environment (Article 57
3-1-232(f) - Environment)

Perfluoroheptanoic acid and its salts-

Potassium perfluoroheptanoate

21049-36-5

Sodium perfluoroheptanoate

20109-59-5

Ammonium perfluoroheptanoate
Perfluoroheptanoic acid

Reproductive toxicity (Article

6130-43-4

57c)

375-85-9

vPvB (Article 57e)

PBT (Article 57d)

Equivalent level of concern

with potentially serious effects
on human health (Article 57(f)3-1-233- Human health)

Reaction products ofReproductive toxicity (Article

2,2,3,3,5,5,6,6-octafluoro-4-(1,1,1,2,3,3,3,357c)-heptafluoropropan-2-yl)morpholine and2,2,3,3,5,5,6,6-octafluoro-4-(heptafluorop
3-1-234

3-1-235

ropyl)morpholine

Bis(4-chlorophenyl)sulfone (BCPS)

80-07-9

Article 57e/vPvB"Polyethersulfone (PESU)", "polysulfone

Diphenyl(2,4,6-trimethylbenzoyl)phosphi

75980-60-8

Reproductive toxicity (Article"The mixture is a photo-initiator forne oxide (TPO)

57c)

graphic arts, wood coatings, plastic
adhesives."

2-(2H-benzotriazol-2-yl)-4-(1,1,3,3-tetram

3147-75-9(Article 57e)

3-1-2372-(Dimethylamino)-2-[(4-methylphenyl)m119344-86-4（Article 57c)

ethyl]-1-[(4-morpholin-4-yl)phenyl]butan-

engineering plastics

coatings, metal coatings and other

3-1-236

ethylbutyl)phenol (UV-329)(PSU)" and "polyphenylsulfone (PPSU)" ofBenzotriazole UV absorber

Photoinitiator

1-one
3-1-238

Bumetrizole (UV-326)

2,4,6-Tri-tert-butylphenol732-26-3(Article 57c,d,e)3-1-240

Oligomerization and alkylation products

68512-30-1（Article 57e）

3-1-239of 2-phenylpropene and phenol

3896-11-5(Article 57e)Benzotriazole UV absorber

Antioxidant (fuel, polymer additive)
intermediate"Hydrocarbon Resins(polymer additives)"

2. Relevant legislation: 2011/65/EU(RoHS)‧1907/2006/EC(REACH) Candidate substance
No

3-2-1

3-2-2

Chemical substances

Tetrabromobisphenol A (TBBP-A)

Medium Chain Chlorinated Paraffins (MCCP)
C14-C17

CAS No.

79-94-7―

ReasonAcute toxicity,

carcinogenicity, reproductive
toxicity

Persistent, bioaccumulation

Usage Example

Epoxy and polycarbonate resins,

impact-resistant polystyrene and phenolic
resins, adhesives

Plasticizers to increase flame retardancy of
polyvinyl chloride (PVC) and rubber forcables, etc.

24

Rank 3：

Ver. 14.3

3. Relevant legislation: PFAS (Organic Fluorine Compounds) Candidate Substances forRegulation
No

Chemical substances

3-3-1

PFHxA (perfluorohexanoic acid) its salts andrelated substances

CAS No.

Reason307-24-4

Persistent, bioaccumulative

2923-26-4

21615-47-4

Usage Example
Foam firefighting chemicals, metal plating,textiles, leather goods and interior

decorations, abrasives and cleaners, coatings,
impregnation/reinforcement materials,
electronics and semiconductor

3-3-2

Perfluoroalkyl and polyfluoroalkyl
compounds (PFAS)―

Persistent, bioaccumulative

25

manufacturing, etc.
-

Rank 4：
Rank 4:

Ver. 14.3

Standards for substances that are prohibited from use in the

manufacturing process of procured items (*1)
No.

Chemical substances

Primary legislation

1

Ozone depleting substances (*2)

Ozone Layer Protection Law

2Organochlorine detergents (*3)

Soil Contamination

Countermeasures Law

Primary environmental
effects

Ozone depletion

Primary

applications

Detergents andrefrigerants

Soil contamination

Detergents(*1) Except being used only in a hermetically sealed state (e.g. cooling medium in chillers).

(*2) The ozone-depleting substances prohibited from use in the manufacturing process are the specified
substances listed in the middle column of the Table attached to Annex 1 of the Enforcement Order ofthe Law Concerning the Protection of the Ozone Layer Through the Control of Specified Substancesand other Measures.

(*3) Organochlorine detergents prohibited for use in manufacturing processes are as follows; carbon

tetrachloride, 1,2-dichloroethane, 1,1-dichloroethylene, 1,2-dichloroethylene, 1,3-dichloropropene,dichloromethane,
trichloroethylene,

tetrachloroethylene,

1,1,1-trichloroethane,

1,1,2-trichloroethane,