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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 04.04.2023*

Version number 1

Revision: 04.04.2023

SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Trade name: OPTOOL DAC-100
Article number: DAC100 STD
1.2 Relevant identified uses of the substance or mixture and uses advised against:
Sector of Use SU8 Manufacture of bulk, large scale chemicals (including petroleum products)
1.3 Details of the supplier of the safety data sheet
Manufacturer/Supplier:
DAIKIN INDUSTRIES, LTD. CHEMICALS DIVISION:OSAKA UMEDA TWIN TOWERS SOUTH, 1-13-1 Umeda, Kita-ku, Osaka-shi, Osaka, 530-0001, Japan
Phone:+81-6-6147-9702 Fax:+81-6-6147-9807
Further information obtainable from:http://www.daikin.com/
sales@daikinchem.de
1.4 Emergency telephone number:
Japan: +81-6-6349-7521
China: +86-532-8388-9090, +86-21-34151689
South Korea: +82-2-568-1722
Americas: CHEMTREC +1-800-424-9300 (Outside US/Canada: +1-703-527-3887)
Europe: +49-211-179 225-0*

SECTION 2: Hazard identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008

Flam. Liq. 2

H225 Highly flammable liquid and vapour.

Eye Irrit. 2
Skin Sens. 1
STOT SE 3

H319 Causes serious eye irritation.
H317 May cause an allergic skin reaction.
H336 May cause drowsiness or dizziness.

Aquatic Chronic 3 H412 Harmful to aquatic life with long lasting effects.
2.2 Label elements
Labelling according to Regulation (EC) No 1272/2008:
The product is classified and labelled according to the CLP regulation.
Signal word: Danger
Hazard-determining components of labelling:
Butanone
Acrylic compound
Precautionary statements:
P210
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P241
Use explosion-proof [electrical/ventilating/lighting] equipment.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [orshower].
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.
P405
Store locked up.
P501
Dispose of contents/container in accordance with local/regional/national/international
regulations.
(Contd. on page 2)

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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 04.04.2023

Version number 1

Revision: 04.04.2023

Trade name: OPTOOL DAC-100(Contd. of page 1)*

SECTION 3: Composition/information on ingredients
Information on ingredients:
Fluorocompound15-25%

CAS: 15290-77-4 1,1,2,2,3,3,4-Heptafluorocyclopentane
Aquatic Chronic 3, H412

35-45%

CAS: 78-93-3

28-38%

Butanone
Flam. Liq. 2, H225
Eye Irrit. 2, H319; STOT SE 3, H336
EUH066

OthersAdditional information: For the wording of the listed hazard phrases refer to section 16.
*

SECTION 4: First aid measures
4.1 Description of first aid measures
General information: Seek medical treatment.
After inhalation:
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.
Supply fresh air; consult doctor in case of complaints.
After skin contact:
Remove contaminated clothes immediately.
Immediately wash with water and soap and rinse thoroughly.
Consult a doctor in case of complaints.
After eye contact:
Immediately rinse with a lot of water for several minutes. Remove contact lenses if possible. Continue rinsing.
Consult an ophthalmologist in case of complaints.
After swallowing:
Rinse mouth with water. Do not induce vomiting.
Consult a doctor in case of complaints.
4.2 Most important symptoms and effects, both acute and chronic: Allergic reactions
4.3 Indication of any immediate medical attention and special treatment needed:
No further relevant information available.

SECTION 5: Firefighting measures
5.1 Extinguishing media
Suitable extinguishing agents:
Foam
Fire-extinguishing powder
COFor safety reasons unsuitable extinguishing agents: Water with full jet
5.2 Special hazards arising from the substance or mixture:
Formation of toxic gases is possible during heating or in case of fire.
Receptacle may explode when heated.
Extremely flammable; can ignite easily with heat, sparks, fire.
5.3 Advice for firefighters: Remove receptacles from area of fire if possible.
Protective equipment:
Wear self-contained breathing apparatus and protective suit.
Do not inhale explosion gases or combustion gases.

SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures:
Ensure adequate ventilation before entering the area.
(Contd. on page 3)

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Safety data sheet
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Printing date 04.04.2023

Version number 1

Revision: 04.04.2023

Trade name: OPTOOL DAC-100(Contd. of page 2)

Stay on the windward side.
Keep out unauthorized persons.
Wear appropriate protective devices (See Section 8 Exposure Controls/Personal Protection).
Avoid contact with eyes and skin.
Do not swallow the product.
6.2 Environmental precautions:
Do not allow to enter sewers/surface or ground water.
Prevent seepage into sewage system, workpits and cellars.
6.3 Methods and material for containment and cleaning up:
Do not flush with water or aqueous cleansing agents
For a small amount of leakage: Absorb with liquid-binding material (sand, diatomite, acid binders, universal
binders) or collect in an empty container that can be sealed tightly.
For a small amount of leakage: Use clean anti-static tools when absorbing the product.
For a large amount of leakage: Enclose with banks to avoid outflow. Lead the leakage to a safe place and collect.
Remove ignition sources immediately.
Ground all equipment when the product leaks.
There is a danger of explosion. Prepare fire extinguisher in case of emergency.
6.4 Reference to other sections:
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
*

SECTION 7: Handling and storage
7.1 Precautions for safe handling:
Ensure good ventilation/exhaustion at the workplace.
Handle with care. Avoid jolting, friction and impact.
Do not handle until all safety precautions have been read and understood.
Information about fire - and explosion protection:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
Use flame proof electric/lighting devices and ventilation equipment.
Ground/bond container and receiving equipment.
7.2 Conditions for safe storage, including any incompatibilities:
Storage
Requirements to be met by storerooms and receptacles:
Store in a cool and dry location.
Provide solvent resistant, sealed floor.
Prevent any seepage into the ground.
Keep containers tightly sealed.
Information about storage in one common storage facility:
Store away from oxidising agents.
See section 10 for information on incompatible materials.
Further information about storage conditions:Protect from heat and direct sunlight.
Store containers in a well ventilated area.
Store locked up.
7.3 Specific end use(s): No further relevant information available.

*

SECTION 8: Exposure controls/personal protection
8.1 Control parameters No further information available.
Ingredients with limit values that require monitoring at the workplace:
CAS: 78-93-3 Butanone
IOELV (EU) Short-term value: 900 mg/m³, 300 ppm
Long-term value: 600 mg/m³, 200 ppm
8.2 Exposure controls
Appropriate engineering controls No further data; see item 7.
(Contd. on page 4)56.0

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Printing date 04.04.2023

Version number 1

Revision: 04.04.2023

Trade name: OPTOOL DAC-100(Contd. of page 3)

Individual protection measures, such as personal protective equipment
General protective and hygienic measures:
Wash hands before breaks and at the end of work.
Do not eat or drink while working.
Keep away from tobacco products.
Respiratory protection:
Use respiratory protective device with filters for organic and acid gas (or airline respirators in some cases) if
formation of toxic gases is possible while the product is heated.
Use respiratory protective device with organic gas cartridge.
Hand protection
Protective gloves
Material of gloves: Rubber
Eye/face protection
Safety glasses
Body protection: Protective work clothing*

SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
General Information
Fluid
Physical state
Light yellow
Colour:Ether-like
Odour:
Not determined.
Odour threshold:
Undetermined.
Melting point/freezing point:
Boiling point or initial boiling point and boiling range 80 °C
Not applicable.
Flammability
Lower and upper explosion limit
2.3 Vol %Lower explosive limit:
20 Vol %Upper explosive limit:
2 °C (TCC)
Flash point:
270 °C
Ignition temperature:
No further information available.
Decomposition temperature:
Not determined.
Not determined.
pH
Not determined.
Viscosity:
Not determined.
Kinematic viscosity
Not determined.
Dynamic:
Solubility
No further information available.
water:
Not determined.
No further information available.
Partition coefficient n-octanol/water (log value)
Not determined.
No further information available.
Vapour pressure:
Density and/or relative density
Not determined.
Density:
Not determined.
Relative density
Not determined.
Vapour density
No further information available.
Particle characteristics(Contd. on page 5)56.0

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Printing date 04.04.2023

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Trade name: OPTOOL DAC-100(Contd. of page 4)

9.2 Other information:
Form:
Auto-ignition temperature:
Explosive properties:
Evaporation rate
Information with regard to physical hazard classes
Explosives
Flammable gases
Aerosols
Oxidising gases
Gases under pressure
Flammable liquids
Flammable solids
Self-reactive substances and mixtures
Pyrophoric liquids
Pyrophoric solids
Self-heating substances and mixtures

LiquidProduct is not self-igniting.
Product is not explosive. However, formation of explosive
air/vapour mixtures are possible.
Not determined.
Not applicableNot applicableNot applicableNot applicableNot applicableNot applicableNot applicableNot applicableNot applicableNot applicable
Highly flammable liquid and vapour.
Not applicableNot applicableNot applicableNot applicableNot applicableNot applicableNot applicableNot applicableNot applicableNot applicableNot applicable

Substances and mixtures, which emit flammable gases
Not applicablein contact with water
Not applicableNot applicable
Oxidising liquids
Not applicableNot applicable
Oxidising solids
Not applicableNot applicable
Organic peroxides
Not applicableNot applicable
Corrosive to metals
Not applicableNot applicable
Desensitised explosives
Not applicable

SECTION 10: Stability and reactivity
10.1 Reactivity No further relevant information available.
10.2 Chemical stability
Thermal decomposition / conditions to be avoided: To avoid thermal decomposition do not overheat.
10.3 Possibility of hazardous reactions:
Danger of polymerisation.
No dangerous reactions known under normal conditions of use.
10.4 Conditions to avoid: Keep away from heat, sparks, flame, high temperature.
10.5 Incompatible materials:
Strong acids, strong alkali, amines and alkali metals
Oxidizing agents
10.6 Hazardous decomposition products:
As for decomposition products, particulate matters and extremely toxic/corrosive fumes may be generated(HF, carbonyl fluoride, monomers, perfluoroisobutylene).
Decomposition products differ depending on the temperature and conditions.
(Contd. on page 6)56.0

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Printing date 04.04.2023

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Trade name: OPTOOL DAC-100(Contd. of page 5)*

SECTION 11: Toxicological information
11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008
Acute toxicity Based on available data, the classification criteria are not met.
LD/LC50 values relevant for classification: No further information available.
Skin corrosion/irritation: No further information available.
Serious eye damage/irritation: Causes serious eye irritation.
Respiratory or skin sensitisation: May cause an allergic skin reaction.
STOT-single exposure: May cause drowsiness or dizziness.
STOT-repeated exposure: No further information available.
Other information (about experimental toxicology): No further information available.
Subacute to chronic toxicity: No further information available.
Additional toxicological information:
General effects:
Fumes generated during burning may cause "polymer fume fever" (flu-like symptoms such as fever, chill, cough).
This may last for a whole day and night.
Fumes are not absorbed in skin. No sensitizing effect known.
Effects of hydrogen fluoride:
Low concentration of hydrogen fluoride may cause feeling of dyspnea, cough, irritation in eyes, nose, throat, fever,chill for 1-2 days.
After that, dyspnea, cyanosis and pulmonary edema may be seen.
High concentration of hydrogen fluoride damages liver and kidney.
Effects of carbonyl fluoride:
Skin: Irritation or eruption
Eye: Ulcer in cornea, conjunctiva
Respiratory system: Irritation
Lung: Temporary symptoms such as cough, pain, dyspnea
Persons who have experienced lung diseases are vulnerable to toxicity caused by excessive exposure to pyrolysis
products
11.2 Information on other hazards:
Endocrine disrupting properties:
None of the ingredients is listed.

*

SECTION 12: Ecological information
12.1 Toxicity
Aquatic toxicity: No further relevant information available.
12.2 Persistence and degradability: No further relevant information available.
12.3 Bioaccumulative potential: No further relevant information available.
12.4 Mobility in soil: No further relevant information available.
12.5 Results of PBT and vPvB assessment
PBT: No further relevant information available.
vPvB: No further information available.
12.6 Endocrine disrupting properties For information on endocrine disrupting properties see section 11.
12.7 Other adverse effects:
Ecotoxical effects: no data
Remark: Harmful to fish
Additional ecological information:
General notes: Harmful to aquatic organisms

SECTION 13: Disposal considerations
13.1 Waste treatment methods
Recommendation: Disposal must be made according to official regulations.
(Contd. on page 7)56.0

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according to 1907/2006/EC, Article 31
Printing date 04.04.2023

Version number 1

Revision: 04.04.2023

Trade name: OPTOOL DAC-100(Contd. of page 6)

Uncleaned packaging
Recommendation: Disposal must be made according to official regulations.
*

SECTION 14: Transport information
14.1 UN number or ID number
ADR, IMDG, IATA
14.2 UN proper shipping name:
ADR, IMDG, IATA
14.3 Transport hazard class(es):UN1993
FLAMMABLE LIQUID, N.O.S. (Butanone)

ADR

Class:
Label:
IMDG, IATA

3 (F1) Flammable liquids.
3

3 Flammable liquids.
Class:
3
Label:
14.4 Packing group:II
ADR, IMDG, IATA
14.5 Environmental hazards:
No
Marine pollutant:Warning: Flammable liquids.
14.6 Special precautions for user:
33
Hazard identification number (Kemler code):
F-E,S-EEMS Number:
B
Stowage Category
14.7 Maritime transport in bulk according to IMO
Not applicable.
instruments
Avoid direct sunlight. Make sure of no damage, corrosion, leaks
Transport/Additional information:on the receptacles.
Take necessary measures for preventing cargo shift.
ADR
1L
Limited quantities (LQ):
Code: E2
Excepted quantities (EQ)
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 500 ml
2
Transport category:
D/E
Tunnel restriction code:
IMDG
1L
Limited quantities (LQ)
Code: E2
Excepted quantities (EQ)
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 500 ml
UN 1993 FLAMMABLE LIQUID, N.O.S. (Butanone), 3, II
UN "Model Regulation":*

SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
No further relevant information available.
Labelling according to Regulation (EC) No 1272/2008
The product is classified and labelled according to the CLP regulation.
(Contd. on page 8)56.0Page 8/9

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Printing date 04.04.2023

Version number 1

Revision: 04.04.2023

Trade name: OPTOOL DAC-100(Contd. of page 7)

Hazard pictograms

GHS02

GHS07

Signal word Danger
Hazard-determining components of labelling:
Butanone
Acrylic compound
Hazard statements
H225 Highly flammable liquid and vapour.
H319 Causes serious eye irritation.
H317 May cause an allergic skin reaction.
H336 May cause drowsiness or dizziness.
H412 Harmful to aquatic life with long lasting effects.
Precautionary statements
P210
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P241
Use explosion-proof [electrical/ventilating/lighting] equipment.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [orshower].
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.
P405
Store locked up.
P501
Dispose of contents/container in accordance with local/regional/national/international
regulations.
Seveso category P5c FLAMMABLE LIQUIDSDIRECTIVE 2011/65/EU on the restriction of the use of certain hazardous substances in electrical and electronicequipment – Annex II
None of the ingredients is listed.
National regulations No further information available.
15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
*

SECTION 16: Other information
The product is for the industrial use only. We do not guarantee the safety in case the product is used for the otherpurposes. When using the product for health-care application or food/feed application, consult us in advance.
This information is based on our present knowledge. However, this shall not constitute a guarantee for any specificproduct features and shall not establish a legally valid contractual relationship.
Department issuing SDS: EHS Department
Contact:
http://www.daikin.com/
sales@daikinchem.dewww.daikinchem.deAbbreviations and acronyms:
RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning theInternational Transport of Dangerous Goods by Rail)ICAO: International Civil Aviation Organisation
ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International
Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
Flam. Liq. 2: Flammable liquids – Category 2
Acute Tox. 4: Acute toxicity – Category 4(Contd. on page 9)56.0

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Printing date 04.04.2023

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Trade name: OPTOOL DAC-100(Contd. of page 8)
Skin Irrit. 2: Skin corrosion/irritation – Category 2
Eye Irrit. 2: Serious eye damage/eye irritation – Category 2
Skin Sens. 1: Skin sensitisation – Category 1
STOT SE 3: Specific target organ toxicity (single exposure) – Category 3
Aquatic Chronic 2: Hazardous to the aquatic environment - long-term aquatic hazard – Category 2
Aquatic Chronic 3: Hazardous to the aquatic environment - long-term aquatic hazard – Category 3* Data compared to the previous version altered.