Gas Chromatography

Capillary Column
Application DataULBON Series
The capillary column performs very higher separation than the packed column because of the small
diffusion and good permeability of the sample. The fused silica capillary column coated polyimide resin on
the outside of tubing was developed in around 1980. The inert surface and flexibility of fused silica tubing
lead to high performance separation and easy handling. To satisfy your analytical requirement, we arepreparing various columns including the chemical bonding (HR) and wall coated types (WCOT).

Products List of Capillary column
HR (Chemical Bond)

WCOT (Wall Coated Open Tubular)

Inactive Processed
Stainless Steel Tube

Fused Silica

Fused Silica

Stainless SteelULBON HR-1
GeneralPurposeTypeULBON HR-52
ULBON HR-17
ULBON HR-1701
ULBON HR-20M
ULBON HR-SS-10

SpecialTypeULBON HR-TGC1ULBON SPX-1

ULBON ALPhen

ULBON HR-Thermon-3000B

ULBON DMN 267

ULBON HR-Thermon-600T

ULBON PLCULBON HR-Thermon-HG

ULBON Xylene Master
ULBON Advance-DS
ULBON FFAP“ULBON” is a generic name of the Shinwa capillary columns.
“ULBON HR” is a generic name of the Shinwa capillary columns with chemical bonding layer.
ColumnType

ULBONThe chemical bond layer
HR Series
ULBON
Wall Coated (Open Tubular)

FeatureULBON HR series are capillary columns
chemically bonded between silica
surface and stationary phase.

Capillary column coated with stationary
phase on the inner wall.

WCOT Series

Material
Fused silica covered withpolyimide resin
Inactive processed stainlesssteel
Fused silica covered withpolyimide resin
Stainless steel

ULBON HR Series
We have ten types of stationary phases for general analysis and each analytical purpose, as an ULBON HR
series. We also stock the columns with various lengths, inner diameter and the film thickness of stationary
phase for your requirement.

■ Characteristics
1. The inert inner surface of the column results in high quantitative analysis.
The adsorption point of the inner surface of the column has been completely removed by a rigid
treatment. Therefore, free acid and free amine which are easily adsorbed are eluted without interaction
with the active surface.
2. No exfoliation and bleeding of stationary phase lead to high sensitive analysis .
In HR series column, the rigid chemical bonding is treated on the surface, therefore there is almost no
exfoliation and bleeding of stationary phase. No bleeding from the column results in the high sensitive
analysis.
3. The maximum temperature is higher than that of ordinary WCOT column.
The maximum temperature of HR-20M (correspondence to PEG-20M) is 240 ℃ and HR-silicone
series are 330 ℃ (except HR-1701 and HR-17). The maximum temperature of chemical bond typecolumn rises about 70 ℃ compared with the WCOT type.
2

ULBON HR Series
Capillary Column for General Purpose
For general analysis, we have five types of capillary columns chemically bonded with stationary phases
having non-polar to polar.

■ ULBON HR-1 (Corresponding OV-1, OV-101)■ ULBON HR-52 (Corresponding SE-52)■ ULBON HR-17 (Corresponding OV-17)■ ULBON HR-1701 (Corresponding OV-1701)■ ULBON HR-20M (CorrespondingPEG-20M)
Capillary Column for Special Purpose
These capillary columns are coated with our original stationary phase developed for the special analytical
purpose. A series of column is higher sensitivity and separation compared with the general analytical
purpose type column.

1. For Fatty Acid Methyl Ester Analysis■ ULBON HR-SS-10■ ULBON HR-Thermon-3000B
The analysis of fatty acid methyl ester by the capillary column in GC is an important method in the field ofbiochemistry. Especially, the separation of cis, trans isomer and a regioisomer is indispensable for the
analysis of the fatty acid ester.
Our company put ULBON HR-SS-10 and ULBON HR-Thermon-3000B * on the market as a capillarycolumn only for the analysis of fatty acid ester.

2. Excellent resolution for Perfumes and Refined Oils
■ ULBON HR-Thermon-600T
It is indispensable to use the capillary gas chromatography, when essential oil and the perfumes areanalyzed. The major component of essential oil and perfumes are terpenes, hydrocarbon having chain or
cyclic structure of chemical formula of (C5H8)n, and its derivatives which are chemically unstable alcohols,
aldehydes and ketones.
It is necessary for the analysis of essential oil and perfumes that the chemical bond and technical innert
treatment is perfectly performed. The stable and good technical treated column reslts in a high sensitive
and a quantitative analysis. As an original capillary column for the essential oil and perfume, we ecommendULBON HR-Thermon-600T for your work.

3. For the Analysis of Organic Mercury (Methyl and Ethyl Mercury) and Tributyl Tin■ ULBON HR-Thermon-HG
ULBON HR-Thermon-HG is the best column for the analysis of the organic mercury that has already been
regulated and the harmful substances such as tributyltin used for the stain-proofing agent of fishing net andthe ship bottom paint.
In the analyses of TBTC (Tributyltin chloride) and alkylmercury, the use of packed column results in thepoor reproducibility of the separation because of the adsorption to the material.
The adsorption phenomenon is extremely few on the ULBON HR-Thermon-HG, the high sensitive andreproducible quantity analysis are possible. ULBON HR-Thermon-HG is excellent separation abilities in theanalysis of Tributyltin chloride compared with packed column because of the no adsorption phenomenon.

4. For the Analysis of Triglyceride (Stainless inside is processed inert treatment)■ ULBON HR-TGC１
The separation of triglyceride in the high boiling point range is difficult on the ordinary polyimide coatedcapillary column. However, triglyceride can be analyzed with stainless steel capillary column that has
processed innert treatment inside and the newly developed heat-resistance stationary phase.

3

ULBON Series
ULBON WCOT Series
5. For Alkyl Phenol Analysis■ ULBON ALPhen
Isomers of the alkyl phenol compounds such as cresol, xylenes and ethyl phenols which are known todifficult substances to analyze can be completely separated with ULBON ALPhen.
1. All isomers of xylenol (six isomers) can be separated on the ULBON ALPhen, especially 2,4-Xylenol
and 2,5-Xylenol are resoluted completely.

2. The separation of the isomers of the cresol and the ethyl phenol is excellent.
ALPhen can offer you the best analysis of the alkyl phenol mentioned above.

6. For 2,6-, and 2,7-Dimethylnaphthalene Analysis■ ULBON DMN267
Dimethylnaphthalene have ten isomers. Of ten isomers, the chemical and physical characteristics of 2,6DMN and 2,7-DMN is very similar. The two isomers can be separated on the ULBON DMN267 (WCOTtype) .
ULBON DMN267 has the following characteristics.
1. Maximum operation temperature is 160 ℃. ULBON DMN267 is stable column.
2. The column life is long.

7. For Dimethylnaphthalene Isomers Analysis■ ULBON PLC
Recently, high purity 2,6-Dimethylnaphthalene (DMN) has attracted attention as a high functional raw
material of heat-resistance and the high strength resin. There are ten isomers of DMN. Because of thesimilar physical and chemical characteristics of DMN, the separation of 2,6-DMN and 2,7-DMM isespecially difficult in gas chromatography. ULBON PLC is a capillary column to separate all isomers of
DMN completely.
The stationary phase of ULBON PLC is a liquid crystal phase developed by our technical group. The
operation temperature range (the appearance of liquid crystal state) as the stationary phase is 150-160 ℃,
and a fine separation of 2,7-DMN, 1,3-DMN and 2,6-DMN can be obtained by the proper control of the oventemperature.
To maintain good column performance, please take care of the following points.
1. Please analyze efficiently to prevent the deteriorate of stationary phase.
2. When the analysis is temporarily interrupted, please adjust the temperature of the column oven to 50 ℃
or less or stop the apparatus without stopping the career gas.

3. As for the career gas, nitrogen is more excellent than helium in the point of the separation and thedetection sensitivity.

8. For Xylene Isomers Analysis■ ULBON Xylene Master1. Xylene Master shows excellent separation because of the about 1.1 relative retention value
for the isomer of xylene.
2. The large separation capacity of Xylene Master capillary column and the inactive surface offused silica used as a base material lead to perform the trace analysis of several ppm.
3. The maximum operation temperature is 160 ℃. The heat-resistance of Xylene Master ishigher than that of the stationary phase of phthalic acid ester for general analysis.
Therefore, the analysis of the alkyl benzene isomer with a high boiling point is also
applicable.

■ ULBON SPX-1 (SUS)
1. For the separation of impurities (for instance, m-xylene, Cumene and etc.) of p-xylene.
2. SPX-1 is a stainless steel (SUS) capillary column coated with stationary phase of the
halogenation phthalic acid ester structure (WCOT) .
3. As for the analysis of m-xylene in p-xylene, the capillary column analysis is said to be a very
difficult analysis so that p-xylene is eluted and then m-xyrene in a usual GC analysis.
Especially, small amount analysis of m-xylene is said to be an extremely difficult. m-Xyleneof a small amount in front of p-xylene is eluted on the SPX-1. Therefore, the quantitative
analysis is possible.
4

ULBON Series■ Specification
ULBON HR Series (General purpose type)
ColumnStationary Phase

Polarity

Maximum
Temperature

Dimethyl silicone resin

Non

330℃

General analysis

5％Phenylmethyl
silicone

Low

330℃

General analysis

Usage

HR-1
(Corresponding OV-1, OV-101)
HR-52(Corresponding SE-52)
HR-17

50％Phenylmethyl
silicone(Corresponding OV-17)

300℃
Medicine, saccharide, TMS derivatives,
phenols, steroids, and solvents

Mid
HR-1701

14 ％ Cyanopropyl
phenylmethyl silicone(Corresponding OV-1701)

280℃

HR-20M
Polyethyleneglycol

High

240℃

(Corresponding PEG-20M)

General analysis, polar compounds,
esters, ketones and alcohols

ULBON HR Series (Special purpose type)
ColumnStationary Phase

Polarity

Maximum
Temperature

Usage

HR-SS-10

Nitrile silicone

High

220℃/230℃

Fatty acid ester(especially, geometric isomer of C1=18 andC2=18)

HR-Thermon-3000B

Phthalic acid ester

High

220℃/230℃

Fatty acid esters(analysis of unsaturated C20)

HR-Thermon-600T

Phthalic ester

High

240℃

Essential oil, Perfume

Methylmercury, Ethyl mercury,
Toribtyl tin

Alkyleneglycol
HR-Thermon-HG

Phthalic acid ester
polymer

High

160℃

HR-TGC1

Phenylmethyl silicone

Low

360℃/390℃

ULBON WCOT Series (Original)
ColumnMaximum
Temperature

Triglyceride

ULBON WCOT Series (SUS)
Usage

ColumnMaximum
Temperature

Usage

ALPhen160 ℃

Alkyl phenols

SPX-1

110 ℃

m-Xylene in p-Xylene
The exclusive column for
xylene isomer analysis

DMN 267

160 ℃

Dimethylnaphthalenes(separation of 2, 6- DMN,
2, and 7- DMN)

Squalane

70 ℃

Hydrocarbon (Rigroin)
The exclusive column for
low hydrocarbon analysis

PLC

160 ℃

Separation of all isomers
of dimethylnaphthalene

Xylene Master

160 ℃

Separation of isomer ofxylen

Advance-DS

220 ℃

Fatty acid methylic esters

FFAP

180 ℃

Lower free fatty acids

5

ULBON Series
Fixed Price ListULBON HR Series (General purpose type)

ColumnHR-1

Inner
DiameterFilmThickness

Length

(mm)

(μm)

(m)

(Yen)

0.2

0.25

25

69,000HR-52

50127,000(Corresponding
SE-52）

25

69,000330℃

30(Corresponding
OV-1, OV-101)
330℃

0.25

0.15

0.25

0.5

0.32

0.15

0.25

0.5

1

0.53

1

2

3

5

Inner
DiameterFilmThickness

Length

Price

(mm)

(μm)

(m)

(Yen)

0.2

0.25

25

69,00050

127,000

25

69,00077,00030

77,00050

127,000

50

127,000

25

69,00025

69,00030

77,00030

77,00050

127,000

50

127,000

25

69,00025

69,00030

77,00030

77,00050

127,000

50

127,000

25

75,00025

75,00030

88,00030

88,00050

130,00050

130,000

25

75,00025

75,00030

88,00030

88,00050

130,00050

130,000

25

75,00025

75,00030

88,00030

88,00050

130,00050

130,000

25

75,00025

75,00030

88,00030

88,00050

130,00050

130,000

15

61,00015

61,00030

99,00030

99,00015

61,00015

61,00030

99,00030

99,00015

61,00015

61,00030

99,00030

99,00015

61,00015

61,00030

99,00030

99,000Price
Column

0.25

0.15

0.25

0.5

0.32

0.15

0.25

0.5

1

0.53

1

2

3

5

6

ULBON Series
Fixed Price ListULBON HR Series (General purpose type )Column

HR-17

Inner
DiameterFilmThickness

Length

(mm)

(μm)

(m)

(Yen)

0.25

0.25

25

69,000HR-20M50

127,000(Corresponding
PEG-20M ）25

69,000240℃

50(Corresponding
OV-17 ）300℃
HR-1701

0.2

0.25(Corresponding
OV-1701）
280℃

0.25

0.15

0.25

0.5

0.32

0.15

0.25

0.5

1

0.53

1

2

3

5

Inner
DiameterFilmThickness

Length

Price

(mm)

(μm)

(m)

(Yen)

0.2

0.25

25

69,00050

127,000

25

69,000127,000

30

77,00025

69,00050

127,000

30

77,00025

69,00050

127,000

30

77,00025

69,00050

127,000

30

77,00025

69,00050

127,000

30

77,00025

69,00050

127,000

30

77,00025

75,00050

127,000

30

88,00025

75,00050

130,000

30

88,00025

75,00050

130,000

30

88,00025

69,00050

130,000

30

88,00025

75,00050

130,000

30

88,00025

75,00050

130,000

30

88,00025

75,00050

130,000

30

88,00025

75,00050

130,000

30

88,00015

61,00050

130,000

30

99,00015

61,00015

61,00030

99,00030

99,00015

61,00015

61,00030

99,00030

99,00015

61,00015

61,00030

99,00030

99,00015

61,00030

99,000Price
Column

0.25

0.15

0.25

0.5

0.32

0.15

0.25

0.5

1

0.53

1

2

3

5

7

ULBON Series
Fixed Price ListULBON HR Series (Special purpose type)
ColumnHR-SS-10

Inner
diameter

Length

(mm)

(m)

(Yen)

0.25

25

69,000HR-Thermon-600T

30

83,000240 ℃/240 ℃

50

127,000

25

79,000HR-Thermon-HG

30

91,000160 ℃

50149,000*HR-TGC1

25

69,000360 ℃/390 ℃

30

83,00050

127,000

25

77,00030

88,00050

143,000

220 ℃/230 ℃

0.53

HR-Thermon-3000B

0.25

220 ℃/230 ℃

0.32

0.53

Price
Column15

66,00030

108,000

Inner
diameter

Length

Price

(mm)

(m)

(Yen)

0.25

25

69,00030

82,00050

126,000

0.53

15

75,0000.25

30

59,000

Inner
Diameter(mm)

Length
(m)

Price
(Yen)

0.32

50

69,000ULBON WCOT Series (Original)
Inner
Diameter(mm)

Length
(m)

Price
(Yen)

ALPhen0.2

50108,000

Xylene Master

160 ℃

0.32

50

132,000

160 ℃

0.2

50

198,000

ColumnDMN 267
160 ℃
PLC
160 ℃

0.25

50

Column0.25

25

69,000

Advance-DS

0.25

30

77,000

220 ℃

0.25

50

126,000

180,000ULBON WCOT Series (SUS)
ColumnInner
Diameter
(mm)

SPX-1
10〜110 ℃

0.25

Length
(m)

Price
(Yen)

60

107,80090

140,800

8

Applications directory

Applications

Page

Hydrocarbons…

10

Organic Solvents…

18

Alcohols…

22

Triglyceride…

23

Fatty Acids and Esters…

24

Perfume…

31

Flower fragrance using NeedlEx for organic solvent…

32

Food flavor using NeedlEx for organic solvent…

34

Steroids…

35

Environmental Pollutants…

37

Others…

41

Application Index…

42

Product Index

…

51

9

Hydrocarbons
Paraffin wax (m.p. 68 〜 70 ℃)

1. n-Hexacosane (C26)
2. n-Hexatriacontane (C36)2

1Column : ULBON HR-1 25 m x 0.25 mm I.D. df = 0.15μm
Column temp : 200 ℃ 〜 320 ℃ Program rate 6 ℃/min
Injection : 330 ℃ (Sprit ratio: 53 :1)
Detector : FID (330 ℃)
Carrier gas : He, 0.74 mL/min
Sample Volume: 1.0μL

Paraffin wax (m.p. 48 〜 50 ℃)

1. n-Eicosane (C20)
2. n-Pentacosane (C25)21Column : ULBON HR-1 25 m x 0.25 mm I.D. df = 0.15μm
Column temp : 200 ℃ 〜 320 ℃ Program rate 6 ℃/min
Injection : 330 ℃ (Sprit ratio: 53 :1)
Detector : FID (330 ℃)
Carrier gas : He, 0.74 mL/min
Sample Volume: 0.5 μL

10Hydrocarbons
Paraffin wax (m.p. 68 〜 70 ℃)

1. n-Hexacosane (C26)
2. n-Hexatriacontane (C36)2

1Column : ULBON HR-52 25 m x 0.25 mm I.D. df = 0.15μm
Column temp : 200 ℃ 〜 320 ℃ Program rate 6 ℃/min
Injection : 330 ℃ (Sprit ratio: 56 :1)
Detector : FID (330 ℃)
Carrier gas : He, 0.7 mL/min
Sample Volume: 1.0μL

Paraffin wax (m.p. 48 〜 50 ℃)

1. n-Eicosane (C20)
2. n-Pentacosane (C25)21Column : ULBON HR-52 25 m x 0.25 mm I.D. df = 0.15μm
Column temp : 200 ℃ 〜 320 ℃ Program rate 6 ℃/min
Injection : 330 ℃ (Sprit ratio: 56 :1)
Detector : FID (330 ℃)
Carrier gas : He, 0.7 mL/min
Sample Volume: 0.5 μL

11Hydrocarbons
Regular gasoline

1

2

3

5

7
10
4

1. n-Pentane (n-C5)
2. n-Hexane (n-C6)
3. Benzene
4. iso-Octane (iso-C8)
5. Toluene
6. Ethylbenzene
7. m, p-Xylene
8. o-Xylene
9. m-Ethyltoluene
10. 1,2,4-Trimethylbenzene

986Column : ULBON HR-1 50 m x 0.25 mm I.D. df = 0.5μm
Column temp : 60 ℃ 〜 220 ℃ Program rate 4 ℃/min
Injection : 250 ℃ (Sprit ratio: 200 :1)
Detector : FID (250 ℃)
Carrier gas : He, 0.75 mL/min
Sample Volume: 0.5 μL

Aromatic hydrocarbons in Regular gasoline

25

1. Benzene
2. Toluene
3. Ethylbenzene
4. p-Xylene
5. m-Xylene
6. iso-Propylbenzene
7. o-Xylene
8. n-Propylbenzene
9. p-Ethyltoluene
10. m-Ethyltoluene
11. o-Ethyltoluene
12. 1,2,5-Trimethylbenzene
13. 1,2,4-Trimethylbenzene
14. 1,2,3-Trimethylbenzene
15. Naphthalene

13

10

7
9
1

4

11

3

12
8

14

6

15

Column : ULBON HR-20M 50 m x 0.25 mm I.D. df = 0.5μm
Column temp : 50 ℃ 〜 180 ℃ Program rate 2 ℃/min
Injection : 250 ℃ (Sprit ratio: 200 :1)
Detector : FID (250 ℃)
Carrier gas : He, 1.04 mL/min
Sample Volume: 0.2 μL

12Hydrocarbons
Premium gasoline

1

4

5

9

10

3

1. n-Pentane (n-C5)
2. n-Hexane (n-C6)
3. Benzene
4. iso-Octane (iso-C8)
5. Toluene
6. Ethylbenzene
7. m, p-Xylene
8. o-Xylene
9. m-Ethyltoluene
10. 1,2,4-Trimethylbenzene

7
2
8
6

Column : ULBON HR-1 50 m x 0.25 mm I.D. df = 0.5μm
Column temp : 60 ℃ 〜 220 ℃ Program rate 4 ℃/min
Injection : 250 ℃ (Sprit ratio: 200 :1)
Detector : FID (250 ℃)
Carrier gas : He, 0.75 mL/min
Sample Volume: 0.5μL

Aromatic hydrocarbons in Premium gasoline

2

1. Benzene
2. Toluene
3. Ethylbenzene
4. p-Xylene
5. m-Xylene
6. iso-Propylbenzene
7. o-Xylene
8. n-Propylbenzene
9. p-Ethyltoluene
10. m-Ethyltoluene
11. o-Ethyltoluene
12. 1,2,5-Trimethylbenzene
13. 1,2,4-Trimethylbenzene
14. 1,2,3-Trimethylbenzene
15. Naphthalene

13

10

5

7

9

11

4
3

12
8

1

14

6

15

Column : ULBON HR-20M 50 m x 0.25 mm I.D. df = 0.5μm
Column temp : 50 ℃ 〜 180 ℃ Program rate 2 ℃/min
Injection : 250 ℃ (Sprit ratio: 200 :1)
Detector : FID (250 ℃)
Carrier gas : He, 1.04 mL/min
Sample Volume: 0.2 μL

13Hydrocarbons
Polycyclic aromatic hydrocarbons

2
1

3

9
4

8

6
5

10

14
11

7

13
12

1. Naphthalene
2. Biphenyl
3. Fluorene
4. Phenanthrene
5. Anthracene
6. o-Terphenyl
7. Fluoranthene
8. Pyrene
9. m-Terphenyl
10. p-Terphenyl
11. Chrysene
12. 4,5-Benzpyrene
13. 1,2-Benzpyrene
14. Perylene

Column : ULBON HR-1 50 m x 0.25 mm I.D. df = 0.25μm
Column temp : 200 ℃ 〜 320 ℃ Program rate 4 ℃/min
Injection : 330 ℃ (Sprit ratio: 60 :1)
Detector : FID (330 ℃)
Carrier gas : He, 0.68 mL/min
Sample Volume: 1.0μL

Styrene monomer (10ppm) in DMF

8

1
3
2

4
5 6

7

Column : ULBON HR-20M 30 m x 0.53 mm I.D. df = 5.0μm
Column temp : 120 ℃
Injection : 200 ℃ (Direct)
Detector : FID (200 ℃)
Carrier gas : He, 10 mL/min
Sample Volume: 0.5μL

14

1. Benzene
2. Acrylonitrile
3. Toluene
4. Ethylbenzene
5. iso-Propylbenzene
6. n-Propylbenzene
7. Styrene
8. N,N-DimethylformamideHydrocarbons
Dimethylnaphtalene (DMN) mixture

1. 2-Methylnaphthalene
2. 1-Methylnaphthalene
3. 1-Ethylnaphthalene
4. 2-Ethylnaphthalene
5. Diphenyl
6. 1,7-DMN
7. 2,7-DMN
8. 1,3-DMN
9. 2,6-DMN
10. 1,6-DMN
11. 1,4-DMN
12. 1,5-DMN
13. 2,3-DMN
14. 1,2-DMN
15. 1.8-DMN

5
8
10

4
6

7

14
9 11
12
13

2
1

15

3

Column : ULBON PLC 50 m x 0.25 mm I.D.
Column temp : 155 ℃
Injection : 200 ℃ (Sprit ratio: 70 :1)
Detector : FID (200 ℃)
Carrier gas : N2, 0.46 mL/min
Sample Volume: 1.0μL

2,6-, 2,7-Dimethylnaphtalene
3

1

5
4
2

7
6
8

Column : ULBON DMN267 50 m x 0.20 mm I.D.
Column temp : 160 ℃
Injection : 250 ℃ (Sprit ratio: 70 :1)
Detector : FID (250 ℃)
Carrier gas : N2, 0.42 mL/min
Sample Volume: 1.0 μL

15

1. 2,6-DMN
2. 2,7-DMN
3. 1,3-DMN
4. 1,4-DMN
5. 1,5-DMN
6. 1,2-DMN
7. 2.3-DMN
8. 1,8-DMN

Hydrocarbons
Alkyl benzene isomers
1. n-Hexane
2. Benzene
3. n-Octane
4. Toluene
5. n-Nonane
6. Ethylbenzene
7. p-Xylene
8. m-Xylene
9. o-Xylene
10. Isopropylbenzene
1

2

3 4
7
6
5

8 9
10

11
12 13

11. Styrene
12. n-Propylbenzene
13. p-Ethyltoluene
14. m-Ethyltoluene
15. o-Ethyltoluene
16. 1,3,5-Trimethylbenzene
17. 1,2,4-Trimethylbenzene
18. 1,2,3-Trimethylbenzene
19. 4-n-Propyltoluene
20. 3-n-Propyltoluene
21. 2-n-Propyltoluene
22. 1,2,3,5-Tetramethylbenzene
23. 1,2,4,5-Tetramethylbenzene
24. 1,2,3,4-Tetramethylbenzene

14 15
17
19
16
20
18
21

23
22

24

Column : ULBON Xylene Master 50 m x 0.32 mm I.D.
Column temp : 70 ℃ 〜 120 ℃ Program rate 2 ℃/min
Injection : 200 ℃ (Sprit ratio: 29 :1)
Detector : FID (200 ℃)
Carrier gas : He, 1.4 mL/min
Sample Volume: 1.0 μL

Ethylbenzene

1. Ethylbenzene (99.66 %)2. p-Xylene (2790 ppm)
3. o-Xylene (210 ppm)
1

2

16

12

8

4

3

Column : ULBON Xylene Master 50 m x 0.32 mm I.D.
Column temp : 70 ℃
Injection : 200 ℃ (Sprit ratio: 55 :1)
Detector : FID (200 ℃)
Carrier gas : He, 1.2 mL/min
Sample Volume: 1.0 μL

16Hydrocarbons
m-Xylenep-Xylene

1. Toluene (90 ppm)
2. Ethylbenzene (1040 ppm)
3. p-Xylene (99.71 %)4. m-Xylene (1210 ppm)
5. o-Xylene (580 ppm)

3

1. Toluene (550 ppm)
2. p-Xylene (1850 ppm)
3. m-Xylene (99.49 %)4. o-Xylene (2630 ppm)
3

4

5

1

2

12

2

8

4

16

4

16

12

8

4

1

Column : ULBON Xylene Master 50 m x 0.32 mm I.D.
Column temp : 70 ℃
Injection : 200 ℃ (Sprit ratio: 55 :1)
Detector : FID (200 ℃)
Carrier gas : He, 1.2 mL/min
Sample Volume: 1.0 μL

Column : ULBON Xylene Master 50 m x 0.32 mm I.D.
Column temp : 70 ℃
Injection : 200 ℃ (Sprit ratio: 55 :1)
Detector : FID (200 ℃)
Carrier gas : He, 1.2 mL/min
Sample Volume: 1.0 μL

m-Xylene in p-Xylene

o-Xylene

1. p-Xylene (6780 ppm)
2. m-Xylene (740 ppm)
3. o-Xylene (98.95 %)4. Isopropylbenzene(1320 ppm)
5. n-Propylbenzene (760 ppm)
6. p-Ethyltoluene (190 ppm)
7. m-Ethyltoluene (90 ppm)

3

1

1. Toluene
2. Ethylbenzene
3. m-Xylene
4. p-Xylene
5. iso-Propylbenzene (Cumene)
6. o-Xylene

4
5
7
20

6
16

12

8

4

2

Column : ULBON SPX-1 60 m x 0.25 mm I.D.
Column temp : 80 ℃
Injection : 200 ℃ (Sprit ratio: 55 :1)
Detector : FID (200 ℃)
Carrier gas : He, 1.1 mL/min
Sample Volume: 1.0 μL

Column : ULBON Xylene Master 50 m x 0.32 mm I.D.
Column temp : 70 ℃
Injection : 200 ℃ (Sprit ratio: 55 :1)
Detector : FID (200 ℃)
Carrier gas : He, 1.2 mL/min
Sample Volume: 1.0 μL

17Organic Solvents
Solvents

12

1. Methanol
2. Acetone
3. Ethyl Ether
4. Dichloromethane
5. trans-1,2-Dichloroethylene
6. Methyl Ethyl Ketone
7. 2-Butanol
8. Ethyl Acetate
9. Chloroform
10. Tetrahydrofuran

20

3
6

25

7 12
4 10 1121
16
13 17 19824

22262829

27
30

15

5

31
32

33

36
35

37

34
9
23
14

18

11. 1,2-Dichloroethane
12. 1,1,1-Trichloroethane
13. n-Butanol
14. Carbon Tetrachloride
15. 1,4-Dioxane
16. n-Propyl Acetate
17. Isoamyl Alcohol
18. Active Amyl Alcohol
19. Isoamyl Acetate
20. Toluene
21. Methyl n-Butyl Ketone
22. n-Butyl Acetate
23. Tetrachloroethylene
24. Chlorobenzene
25. Ethylbenzene
26. m-Xylene
27. Cyclohexanone
28. Styrene
29. o-Xylene
30. n-Amyl Acetate
31. 2-Methylcyclohexanol
32. 4-Methylcyclohexanone
33. m-Dichlorobenzene
34. p-Dichlorobenzene
35. o-Dichlorobenzene
36. o-Cresol
37. p-Cresol

Column : ULBON HR-1 50 m x 0.25 mm I.D. df = 0.5μm
Column temp : 60 ℃ 〜 120 ℃ Program rate 2 ℃/min
Injection : 250 ℃ (Sprit ratio: 59 :1)
Detector : FID (250 ℃)
Carrier gas : He, 0.93 mL/min
Sample Volume: 1.0 μL

Solvents

85

3

1. Methanol
2. Ethanol
3. Acetone
4. 1-Propanol
5. n-Hexane
6. Ethyl Acetate
7. Chloroform
8. Benzene
9. Methyl Isobutyl Kentone
10. Toluene
11. Isobutyl Acetate
12. n-Butyl Acetate
13. Ethylbenzene
14. m-Xylene
15. o-Xylene
16. Cellosolve Acetate

14
2

4
10

1

13

6

9

11

15

12
16

7

Column : ULBON HR-52 25 m x 0.32 mm I.D. df = 0.5μm
Column temp : 40 ℃ 〜 90 ℃ Program rate 2 ℃/min
Injection : 250 ℃ (Sprit ratio: 71 :1)
Detector : FID (250 ℃)
Carrier gas : He, 0.83 mL/min
Sample Volume: 1.0 μL

18Organic Solvents
Solvents

12

1. Methanol
2. Acetone
3. Dichloromethane
4. trans-1,2-Dichloroethylene
5. n-Hexane
6. Ethyl Acetate
7. Tetrahydrofuran
8. 1,1,1-Trichloroethane
9. Carbon Tetrachloride
10. Trichloroethylene18
19 21 11. 1,4-Dioxane
12. Methyl Isobutyl Ketone
1720
13. Toluene
14. Methyl n-Butyl Ketone
15. n-Butyl Acetate

13
5

7

3
4 6
12
11
8 10

14

27

25 26

15

29

16. Tetrachloroethylene
17. Chlorobenzene
18. Ethylbenzene
19. p-Xylene
20. Styrene
21. o-Xylene
22. Butyl Cellosolve
23. 1,1,2,2-Tetrachloroethane
24. 3-Methylcyclohexanol(cis, trans)
25. 2-Methylcyclohexanone
26. 4-Methylcyclohexanone
27. m-Dichlorobenzene
28. p-Dichlorobenzene
29. o-Dichlorobenzene
30. o-Cresol
31. p-Cresol
30
31

24
9

16

28

22
23

Column : ULBON HR-52 50 m x 0.25 mm I.D. df = 0.5μm
Column temp : 60 ℃ 〜 130 ℃ Program rate 3 ℃/min
Injection : 250 ℃ (Sprit ratio: 60 :1)
Detector : FID (250 ℃)
Carrier gas : He, 1.2 mL/min
Sample Volume: 1.0 μL

Solvents

1. Methanol
2. Ethanol
3. Acetone
4. 2-Propanol
5. 1-Propanol
6. Ethyl Acetate
7. Methyl Ethyl Ketone
8. Chloroform
9. Benzene
10. n-Butanol
11. Toluene
12. Methyl Isobutyl Ketone
13. Isobutyl Acetate
14. n-Butyl Acetate
15. Ethylbenzene
16. m-Xylene
17. o-Xylene
18. Cellosolve Acetate

16

4
9
2
3
1

11

5 7
10

6

15

12

13

17

14
18

8

Column : ULBON HR-1701 25 m x 0.32 mm I.D. df = 0.5μm
Column temp : 40 ℃ 〜 90 ℃ Program rate 2 ℃/min
Injection : 250 ℃ (Sprit ratio: 78 :1)
Detector : FID (250 ℃)
Carrier gas : He, 0.83 mL/min
Sample Volume: 1.0 μL

19Organic Solvents
Solvents
16. 1,4-Dioxane
1. Methanol
17. Ethyl Cellosolve
2. Ethyl Ether
18. Toluene
3. 2-Propanol
19. Isoamyl Alcohol
4. n-Hexane
5. trans-1,2-Dichloroethylene 20. Tetrachloroethylene
24
21. n-Butyl Acetate
6. Ethyl Acetate
18
22. Methyl n-Butyl Ketone
7. Methyl Ethyl Ketone
23. Ethylbenzene
8. Chloroform
27
3 7
24. p-Xylene
9. Isopropyl Acetate24
25. Isoamyl Acetate
10. Isobutanol
23
10
26. o-Xylene
11. 1,2-Dichloroethane
26
5
27. Styrene
12. Methyl Cellosolve
14
28. n-Amyl Acetate
13. Trichloroethylene
6 9 15
1
29. Cyclohexanol
14. n-Butanol
13
30. Butyl Cellosolve
15. n-Propyl Acetate
1122
31. Cyclohexanone
41
36 38
39
31
32. 1,1,2,2-Tetrachloroethane
37
25 28
40
33. 2-Methylcyclohexanol(cis, trans)
29
21
12
34 35
16
34. 2-Methylcyclohexanone
19
35. 3-Methylcyclohexanone
2033
36. m-Dichlorobenzene
30
37. p-Dichlorobenzene
1732
38. o-Dichlorobenzene
839. o-Cresol
40. p-Cresol
41. m-Cresol

Column : ULBON HR-1701 50 m x 0.25 mm I.D. df = 0.5μm
Column temp : 60 ℃ 〜 180 ℃ Program rate 4 ℃/min
Injection : 250 ℃ (Sprit ratio: 65 :1)
Detector : FID (250 ℃)
Carrier gas : He, 1.4 mL/min
Sample Volume: 1.0 μL

Solvents
1. n-Hexane
2. Ethyl Ether
3. Acetone
4. Methyl Acetate
5. trans-1,2-Dichloroethylene
6. Methanol
7. Isopropyl Acetate
8. 2-Propanol
9. Dichloromethane
10. n-Propyl Acetate
11. cis-1,2-Dichloroethylene
12. Methyl Isobutyl Ketone
13. Chloroform
14. Toluene
15. 1,4-Dioxane
33
34

1
19

14

18 20

2

7

22

24

12

3

29

4 5 8

16 17

11
6 10

27
26

15
25
21 23

9

28 30

16. Isobutanol
17. Isoamyl Acetate
18. Ethylbenzene
19. p-Xylene
20. m-Xylene
21. Methyl Cellosolve
22. o-Xylene
23. Ethyl Cellosolve
24. Styrene
25. Cellosolve Acetate
26. N,N-Dimethylformamide
27. 4-Methylcyclohexanone
28. Butyl Cellosolve
29. cis-4-Methylcyclohexanol
30. m-Dichlorobenzene
31. p-Dichlorobenzene
35
36 32. trans-4-Methylcyclohexanol
33. o-Dichlorobenzene
34. o-Cresol
35. p-Cresol
36. m-Cresol

31
32

13

Column : ULBON HR-20M 50 m x 0.25 mm I.D. df = 0.5μm
Column temp : 60 ℃ 〜 240 ℃ Program rate 3 ℃/min
Injection : 250 ℃ (Sprit ratio: 60 :1)
Detector : FID (250 ℃)
Carrier gas : He, 1.3 mL/min
Sample Volume: 1.0 μL

20Organic Solvents
The work environment

5
17
16
15

12

18

2
6

11

20

13

21

22

7
24
1

4

10

14

8

3

25

19

23

9

1. Methanol (70 ppm)
2. Acetone (39 ppm)
3. Dichloromethane (27 ppm)
4. trans-1,2-Dichloroethylene(23 ppm)
5. n-Hexane (26 ppm)
6. Ethyl Acetate (25 ppm)
7. Tetrahydrofuran (31 ppm)
8. 1,1,1-Trichloroethane (17 ppm)
9. Carbon Tetrachloride (15 ppm)
10. Trichloroethylene (17 ppm)
11. Methyl Isobutyl Ketone (22 ppm)
12. Toluene (24 ppm)
13. Methyl n-Butyl Ketone (22 ppm)
14. Tetrachloroethylene (14 ppm)
15. Chlorobenzene (30 ppm)
16. Ethylbenzene (21 ppm)
17. p-Xylene (21 ppm)
18. Styrene (22 ppm)
19. 1,1,2,2-Tetrachloroethane (13 ppm)
20. 2-Methylcyclohexanone (20 ppm)
21. 4-Methylcyclohexanone (20 ppm)
22. m-Dichlorobenzene (15 ppm)
23. p-Dichlorobenzene (5 ppm)
24. o-Cresol (10 ppm)
25. p-Cresol (7 ppm)

Column : ULBON HR-52 30 m x 0.53 mm I.D. 5.0μm
Column temp : 60 ℃ 〜 130 ℃ Program rate 3 ℃/min
Injection : 250 ℃ (Direct)
Detector : FID (150 ℃)
Carrier gas : He, 8.0 mL/min
Sample Volume: 1.0 mL

The work environment

15
14

11

1. Methanol (70 ppm)
2. Ethyl Ether (30 ppm)
3. 2-Propanol (37 ppm)
4. trans-1,2-Dichloroethylene(23 ppm)
5. Ethyl Acetate (25 ppm)
6. Chloroform (19 ppm)
7. Isobutanol (30 ppm)
8. Trichloroethylene (17 ppm)
9. n-Butanol (30 ppm)
10. 1,4-Dioxane (25 ppm)
24

17

2
23

9

7

13

3

16

5
1

20

4

8

10

22

11. Toluene (24 ppm)
12. Tetrachloroethylene (14 ppm)
13. n-Butyl Acetate (19 ppm)
14. Ethylbenzene (21 ppm)
15. p-Xylene (21 ppm)
16. Isoamyl Acetate (17 ppm)
17. o-Xylene (21 ppm)
18. n-Amyl Acetate (17 ppm)
19. Cyclohexanol (22 ppm)
20. Cyclohexanone (23 ppm)
21. 2-Methylcyclohexanol (10 ppm)
22. 2-Methylcyclohexanone (20 ppm)
23. p-Dichlorobenzene (15 ppm)
24. o-Dichlorobenzene (20 ppm)
25. o-Cresol (10 ppm)
26. m-Cresol (10 ppm)

18
19
25

12

26
21

6

Column : ULBON HR-1701 30 m x 0.53 mm I.D. df = 5.0μm
Column temp : 60 ℃ 〜 180 ℃ Program rate 4 ℃/min
Injection : 250 ℃ (Direct)
Detector : FID (200 ℃)
Carrier gas : He, 10.0 mL/min
Sample Volume: 1.0 mL

21

Alcohols
Higher alcohols in Calnaubawax

1. n-Octadecanol (C18)
2. n-Docosanol (C22)21Column : ULBON HR-52 25 m x 0.25 mm I.D. df = 0.25μm
Column temp : 200 ℃ 〜 320 ℃ Program rate 5 ℃/min
Injection : 330 ℃ (Sprit ratio: 66 :1)
Detector : FID (330 ℃)
Carrier gas : He, 0.5 mL/min
Sample Volume: 1.2μL

Scotch whisky

6
3

2

5

1. Acetaldehyde
2. Ethyl Acetate
3. Ethanol
4. 1-Propanol
5. 3-Pentanol
6. Active Amyl Alcohol
7. Isoamyl Alcohol

7

4

1

Column : ULBON HR-20M 50 m x 0.32 mm I.D. df = 1.0μm
Column temp : 60 ℃ 〜 240 ℃ Program rate 5 ℃/min
Injection : 250 ℃ (Sprit ratio: 10 :1)
Detector : FID (250 ℃)
Carrier gas : He, 4.0 mL/min
Sample Volume: 0.6 μL

22

Triglyceride
ButterColumn : ULBON HR-TGC-1 30 m x 0.25 mm I.D.
Column temp : 250 ℃ 〜 380 ℃ Program rate 5 ℃/min
Injection : 380 ℃ (Sprit ratio: 45 :1)
Detector : FID (380 ℃)
Carrier gas : He, 1.5 mL/min
Sample Volume: 1.0 μL

Salmon oil

Column : ULBON HR-TGC-1 30 m x 0.25 mm I.D.
Column temp : 25 ℃ 〜 380 ℃ Program rate 5 ℃/min
Injection : 380 ℃ (Sprit ratio: 45 :1)
Detector : FID (380 ℃)
Carrier gas : He, 1.5 mL/min
Sample Volume: 1.0 μL

23

Fatty Acids and Esters
Lower fatty acids in water

1. Acetic Acid
2. Propionic Acid
3. iso-Butyric Acid
4. n-Butyric Acid
5. iso-Valeric Acid
6. iso-Caproic Acid
7. n-Caproic Acid
8. n-Heptanoic Acid

2

3 45

1
6

7
8

Column : ULBON HR-20M 30 m x 0.53 mm I.D. df = 3.0 μm
Column temp : 150 ℃
Injection : 250 ℃ (Direct)
Detector : FID (250 ℃)
Carrier gas : He, 10.5 mL/min
Sample Volume: 0.4 μL

Higher fatty acid esters in Calnaubawax

1. Methyl Arachidate (C20:0)
3

2. Methyl Behenate (C22:0)
5

3. Methyl Lignocerate (C24:0)
4. Methyl Cerotate (C26:0)
5. Methyl Montanate (C28:0)
6. Methyl Melissylate (C30:0)

4
1

6
2

Column : ULBON HR-52 25 m x 0.25 mm I.D. 0.25μm
Column temp : 200 ℃ 〜 320 ℃ Program rate 5 ℃/min
Injection : 330 ℃ (Sprit ratio: 61 :1)
Detector : FID (330 ℃)
Carrier gas : He, 0.5 mL/min
Sample Volume: 1.0 μL

24

Fatty Acids and Esters
Fatty acid methyl esters

1. Methyl Caproate (C6:0)
2. Methyl Laurate (C12:0)
3. Methyl Myristate (C14:0)
4. Methyl Palmitate (C16:0)
5. Methyl Palmitoleate (C16:1)
6. Methyl Stearate (C18:0)
7. Methyl Oleate (C18:1n9c)
8. Methyl Linoleate (C18:2n6c)
9. Methyl Linolenate (C18:3n3)
10. Methyl Arachidate (C20:0)
11. Methyl cis-11-Eicosenoate (C20:1n9)
12. Methyl Behenate (C22:0)
13. Methyl Erucate (C22:1n9)
14. Methyl Lignocerate (C24:0)
15. Methyl Nervonate (C24:1n9)

1

2

3
6

4

10
5
12

7
8
11

13

14

15

9

Column : ULBON HR-20M 25 m x 0.25 mm I.D. df = 0.25μm
Column temp : 130 ℃ 〜 240 ℃ Program rate 4 ℃/min
Injection : 250 ℃ (Sprit ratio: 40 :1)
Detector : FID (250 ℃)
Carrier gas : He, 1.1 mL/min
Sample Volume: 1.0 μL

Fatty acid methyl esters standard

1. Methyl Caprate (C10:0)
2. Methyl Laurate (C12:0)
3. Methyl Myristate (C14:0)
4. Methyl Palmitate (C16:0)
5. Methyl Palmitoleate (C16:1)
6. Methyl Stearate (C18:0)
7. Methyl Oleate (C18:1n9c)
8. Methyl Linoleate (C18:2n6c)
9. Methyl Linolenate (C18:3n3)
10. Methyl Arachidate (C20:0)
11. Methyl cis-11-Eicosenoate (C20:1n9)
12. Methyl Behenate (C22:0)
13. Methyl Erucate (C22:1n9)
14. Methyl cis-4,7,10,13,16,19-Docosahexaenoate (C22:6n3)
15. Methyl Lignocerate (C24:0)
16. Methyl Nervonate (C24:1n9)

12 3
4

5
6
8
7

9
10
12

11

15

13

16
14

Column : ULBON HR-Thermon-3000B 50 m x 0.25 mm I.D.
Column temp : 180 ℃ 〜 220 ℃ Program rate 1 ℃/min
Injection : 250 ℃ (Sprit ratio: 50 :1)
Detector : FID (250 ℃)
Carrier gas : He, 1.7 mL/min
Sample Volume: 1.0 μL

25

Fatty Acids and Esters
Fatty acid methyl esters standard
19. Methyl Linolelaidate (C18:2n6t)
1. Methyl Butyrate (C4:0)
20. Methyl Linoleate (C18:2n6c)
2. Methyl Caproate (C6:0)
1
21. Methyl γ-Linolenate (C18:3n6)
3. Methyl Caprylate (C8:0)
22. Methyl α-Linolenate (C18:3n3)
4. Methyl Caprate (C10:0)34
23. Methyl Arachidate (C20:0)
5. Methyl Undecanoate (C11:0)
24. Methyl cis-11-Eicosenoate (C20:1n9)
6. Methyl Laurate (C12:0)
25. Methyl Henicosanoate (C21:0)
7. Methyl Tridecanoate (C13:0)
26. Methyl cis-11,14-Eicosadienoate
8. Methyl Myristate (C14:0)(C20:2)
9. Methyl Myristoleate (C14:1)
2
27. Methyl cis-8,11,14-Eicosatrienoate
10. Methyl Pentadecanoate (C15:0)
6(C20:3n6)
11. Methyl cis-10-Pentadecanoate (C15:1)
12
28. Methyl Arachidonate (C20:4n6)
12. Methyl Palmitate (C16:0)
29. Methyl cis-,11,14,17-Eicosatrienoate
13. Methyl Palmitoleate (C16:1)(C20:3n3)8
14. Methyl Heptadecanoate (C17:0)
30.
Methyl Behenate (C22:0)
15. Methyl cis-10-Heptadecenoate (C17:1)
31.
MethylErucate(C22:1n9)
16. Methyl Stearate (C18:0)
32. Methyl cis-5,8,11,14,17
17. Methyl Elaidate (C18:1n9t)-Eicosapentaenoate (C20:5n3)
18. Methyl Oleate (C18:1n9c)
5
33. Methyl Tricosanoate (C23:0)
35
16
34. Methyl cis-13,16-Docosadienoate
18
30
23(C22:2)729
35. Methyl Lignocerate (C24:0)
9 10
28
36. Methyl Nervonate (C24:1n9)36
11 13
37. Methyl cis-4,7,10,13,16,19
31 33 34
15 17
20 22 24 25 26
37
19-Docosahexaenoate (C22:6n3)
32
14
21
27

Column : ULBON HR-SS-10 50 m x 0.25 mm I.D.
Column temp : 160 ℃ 〜 220 ℃ Program rate 1.5 ℃/min
Injection : 250 ℃ (Sprit ratio: 60 :1)
Detector : FID (250 ℃)
Carrier gas : He, 1.0 mL/min
Sample Volume: 1.0 μL

Fatty acid methyl esters standard

1

2

3
6

4

7
8
5

9

12

14
16
15

10 13

17
18
11

Column : ULBON HR-SS-10 50 m x 0.32 mm I.D.
Column temp : 150 ℃ 〜 220 ℃ Program rate 3 ℃/min
Injection : 250 ℃ (Sprit ratio: 25 :1)
Detector : FID (250 ℃)
Carrier gas : He, 3.4 mL/min
Sample Volume: 1.0 μL

26

1. Methyl Caprate (C10:0)
2. Methyl Laurate (C12:0)
3. Methyl Myristate (C14:0)
4. Methyl Palmitate (C16:0)
5. Methyl Palmitoleate (C16:1)
6. Methyl Stearate (C18:0)
7. Methyl Elaidate (C18:1n9t)
8. Methyl Oleate (C18:1n9c)
9. Methyl Linolelaidate (C18:2n6t)
10. Methyl Linoleate (C18:2n6c)
11. Methyl α-Linolenate (C18:3n3)
12. Methyl Arachidate (C20:0)
13. Methyl cis-11-Eicosenoate (C20:1n9)
14. Methyl Behenate (C22:0)
15. Methyl Erucate (C22:1n9)
16. Methyl Lignocerate (C24:0)
17. Methyl Nervonate (C24:1n9)
18. Methyl cis-4,7,10,13,16,19-Docosahexaenoate (C22:6n3)

Fatty Acids and Esters
Young yellowtail oil

1

2 3

5

8

1. Methyl Myristate (C14:0)

10

2. Methyl Palmitate (C16:0)
3. Methyl Palmitoleate (C16:1)
4. Methyl Stearate (C18:0)
5. Methyl Oleate (C18:1n9c)
6. Methyl Linoleate (C18:2n6c)
7. Methyl α-Linolenate (C18:3n3)
8. Methyl cis-5,8,11,14,17-Eicosapentaenoate (C20:5n3)

4

9. Methyl cis-7,10,13,16,19-Docosapentaenoate (C22:5n3)
10. Methyl cis-4,7,10,13,16,19

9-Docosahexaenoate (C22:6n3)
6
7

Column : ULBON HR-SS-10 25 m x 0.25 mm I.D.
Column temp : 150 ℃ 〜 220 ℃ Program rate 2 ℃/min
Injection : 250 ℃ (Sprit ratio: 60 :1)
Detector : FID (250 ℃)
Carrier gas : He, 1.5 mL/min
Sample Volume: 1.0 μL

Tuna oil

1

2 3

5

10

1. Methyl Myristate (C14:0)
2. Methyl Palmitate (C16:0)
3. Methyl Palmitoleate (C16:1)
4. Methyl Stearate (C18:0)
5. Methyl Oleate (C18:1n9c)
6. Methyl Linoleate (C18:2n6c)
7. Methyl α-Linolenate (C18:3n3)
8. Methyl cis-5,8,11,14,17-Eicosapentaenoate (C20:5n3)
9. Methyl cis-7,10,13,16,19

8
4-Docosapentaenoate (C22:5n3)
10. Methyl cis-4,7,10,13,16,19-Docosahexaenoate (C22:6n3)
6
7

9

Column : ULBON HR-SS-10 25 m x 0.25 mm I.D.
Column temp : 150 ℃ 〜 220 ℃ Program rate 2 ℃/min
Injection : 250 ℃ (Sprit ratio: 60 :1)
Detector : FID (250 ℃)
Carrier gas : He, 1.5 mL/min
Sample Volume: 1.0 μL

27

Fatty Acids and Esters
Carp oil

Yellowtail oil

1. Methyl Myristate (C14:0)
2. Methyl Palmitate (C16:0)
3. Methyl Palmitoleate (C16:1)
4. Methyl Stearate (C18:0)
5. Methyl Oleate (C18:1n9c)
6. Methyl Linoleate (C18:2n6c)
7. Methyl α-Linolenate(C18:3n3)
8. Methyl cis-5,8,11,14,17-Eicosapentaenoate(C20:5n3)
9. Methyl cis-7,10,13,16,19-Docosapentaenoate(C22:5n3)
10. Methyl cis-4,7,10,13,16,19-Docosahexaenoate(C22:6n3)

2
5

2

3

8

3

10
1

4

5

6

6

1

1. Methyl Myristate (C14:0)
2. Methyl Palmitate (C16:0)
3. Methyl Palmitoleate (C16:1)
4. Methyl Stearate (C18:0)
5. Methyl Oleate (C18:1n9c)
6. Methyl Linoleate (C18:2n6c)
7. Methyl α-Linolenate (C18:3n3)

7

9

Column : ULBON HR-SS-10 50 m x 0.25 mm I.D.
Column temp : 150 ℃ 〜 220 ℃ Program rate 3 ℃/min
Injection : 250 ℃ (Sprit ratio: 60 :1)
Detector : FID (250 ℃)
Carrier gas : He, 0.8 mL/min
Sample Volume: 1.0μL

4

7Column : ULBON HR-SS-10 25 m x 0.25 mm I.D.
Column temp : 170 ℃ 〜 200 ℃ Program rate 2 ℃/min
Injection : 250 ℃ (Sprit ratio: 60 :1)
Detector : FID (250 ℃)
Carrier gas : He, 1.5 mL/min
Sample Volume: 1.0μL

Lard

Beef tallow

2

1. Methyl Myristate (C14:0)
2. Methyl Palmitate (C16:0)
3. Methyl Palmitoleate (C16:1)
4. Methyl Stearate (C18:0)
5. Methyl Oleate (C18:1n9c)
6. Methyl Linoleate (C18:2n6c)

52

1. Methyl Myristate (C14:0)
2. Methyl Palmitate (C16:0)
3. Methyl Palmitoleate (C16:1)
4. Methyl Stearate (C18:0)
5. Methyl Oleate (C18:1n9c)
6. Methyl Linoleate (C18:2n6c)

5

4

4

6

1

3

6

1

Column : ULBON HR-SS-10 50 m x 0.25 mm I.D.
Column temp : 150 ℃ 〜 220 ℃ Program rate 3 ℃/min
Injection : 250 ℃ (Sprit ratio: 60 :1)
Detector : FID (250 ℃)
Carrier gas : He, 0.8 mL/min
Sample Volume: 1.0μL

3Column : ULBON HR-SS-10 50 m x 0.25 mm I.D.
Column temp : 150 ℃ 〜 220 ℃ Program rate 3 ℃/min
Injection : 250 ℃ (Sprit ratio: 60 :1)
Detector : FID (250 ℃)
Carrier gas : He, 0.8 mL/min
Sample Volume: 1.0μL

28

Fatty Acids and Esters
Chicken oil

Butter2

1. Methyl Myristate (C14:0)
2. Methyl Palmitate (C16:0)
3. Methyl Palmitoleate (C16:1)
4. Methyl Stearate (C18:0)
5. Methyl Oleate (C18:1n9c)
6. Methyl Linoleate (C18:2n6c)
7. Methyl α-Linolenate(C18:3n3)

5

1. Methyl Caprylate (C8:0)
2. Methyl Laurate (C12:0)
3. Methyl Myristate (C14:0)
4. Methyl Palmitate (C16:0)
5. Methyl Palmitoleate (C16:1)
6. Methyl Stearate (C18:0)
7. Methyl Oleate (C18:1n9c)
8. Methyl Linoleate (C18:2n6c)

4

7

3
6

6
3
4

1

2

8

5

7

1

Column : ULBON HR-SS-10 50 m x 0.25 mm I.D.
Column temp : 150 ℃ 〜 220 ℃ Program rate 3 ℃/min
Injection : 250 ℃ (Sprit ratio: 60 :1)
Detector : FID (250 ℃)
Carrier gas : He, 0.8 mL/min
Sample Volume: 1.0μL

Column : ULBON HR-SS-10 50 m x 0.25 mm I.D.
Column temp : 150 ℃ 〜 220 ℃ Program rate 3 ℃/min
Injection : 250 ℃ (Sprit ratio: 60 :1)
Detector : FID (250 ℃)
Carrier gas : He, 0.8 mL/min
Sample Volume: 1.0μL

SoybeanMargarine

63

1. Methyl Laurate (C12:0)
2. Methyl Myristate (C14:0)
3. Methyl Palmitate (C16:0)
4. Methyl Stearate (C18:0)
5. Methyl Elaidate (C18:1n9t)
6. Methyl Oleate (C18:1n9c)
7. Methyl Linoleate (C18:2n6c)
8. Methyl α-Linolenate(C18:3n3)

7

1. Methyl Palmitate (C16:0)
2. Methyl Stearate (C18:0)
3. Methyl Oleate (C18:1n9c)
4. Methyl Linoleate (C18:2n6c)
5. Methyl α-Linolenate(C18:3n3)

4
3

1

5

4
8
1
2

2

5

Column : ULBON HR-SS-10 50 m x 0.25 mm I.D.
Column temp : 150 ℃ 〜 220 ℃ Program rate 3 ℃/min
Injection : 250 ℃ (Sprit ratio: 60 :1)
Detector : FID (250 ℃)
Carrier gas : He, 0.8 mL/min
Sample Volume: 1.0μL

Column : ULBON HR-SS-10 50 m x 0.25 mm I.D.
Column temp : 150 ℃ 〜 220 ℃ Program rate 3 ℃/min
Injection : 250 ℃ (Sprit ratio: 60 :1)
Detector : FID (250 ℃)
Carrier gas : He, 0.8 mL/min
Sample Volume: 1.0μL

29

Fatty Acids and Esters
Breast milk

1. Methyl Caprylate (C8:0)
2. Methyl Laurate (C12:0)
3. Methyl Myristate (C14:0)
4. Methyl Palmitate (C16:0)
5. Methyl Palmitoleate (C16:1)
6. Methyl Stearate (C18:0)
7. Methyl Oleate (C18:1n9c)
8. Methyl Linoleate (C18:2n6c)
9. Methyl α-Linolenate (C18:3n3)
10. Methyl cis-5,8,11,14,17-Eicosapentaenoate (C20:5n3)
11. Methyl cis-7,10,13,16,19-Docosapentaenoate (C22:5n3)
12. Methyl cis-4,7,10,13,16,19-Docosahexaenoate (C22:6n3)

7

4

1
8
2
3

6
5

12
9

10

11

Column : ULBON HR-SS-10 50 m x 0.25 mm I.D.
Column temp : 150 ℃ 〜 220 ℃ Program rate 3 ℃/min
Injection : 250 ℃ (Sprit ratio: 60 :1)
Detector : FID (250 ℃)
Carrier gas : He, 0.8 mL/min
Sample Volume: 1.0μL

30

Perfume
Perfume （1 ）

3

6

5

1. α-Pinene
2. β-Pinene
3. Limonene
4. Linalool
5. Linalyl Acetate
6. Benzyl Acetate
7. Phenethyl Alcohol

7

2
4

1

Column : ULBON HR-Thermon-600T 50 m x 0.25 mm I.D.
Column temp : 70 ℃ 〜 230 ℃ Program rate 4 ℃/min
Injection : 250 ℃ (Sprit ratio: 80 :1)
Detector : FID (250 ℃)
Carrier gas : He, 1.1 mL/min
Sample Volume: 1.0μL

Perfume （2 ）

10
6 7

12

8
9

2
4
3
5

11
1

Column : ULBON HR-Thermon-600T 50 m x 0.25 mm I.D.
Column temp : 70 ℃ 〜 230 ℃ Program rate 4 ℃/min
Injection : 250 ℃ (Sprit ratio: 80 :1)
Detector : FID (250 ℃)
Carrier gas : He, 1.1 mL/min
Sample Volume: 1.0μL

31

1. β-Pinene
2. Limonene
3. Linalool
4. Linalyl Acetate
5. Benzyl Acetate
6. α-Ionene
7. Phenethyl Alcohol
8. Lauryl Alcohol
9. Eugenol
10. Diethyl Phthalate
11. Vanillin
12. Benzyl Salicylate

Flower fragrance using NeedlEx for organic solvent
Fragrant daphne

Narcissus

1. 1,8-Cineole

1. Linalool

2. β-Phenethyl Alcohol

2. Anisaldehyde

3. Benzyl Acetate

3. Geraniol
4. Perillaldehyde

3

1

2

1

2
34

Column : ULBON HR-1 30 m x 0.32 mm I.D.df = 0.25μm
Column temp : 50 ℃ 〜 200 ℃ Program rate 5 ℃/min
Injection : 250 ℃ (Sprit ratio: 10 :1)
Detector : FID (250 ℃)
Carrier gas : He, 2.4 mL/min

Column : ULBON HR-1 30 m x 0.32 mm I.D.df = 0.25μm
Column temp : 50 ℃ 〜 200 ℃ Program rate 5 ℃/min
Injection : 250 ℃ (Sprit ratio: 10 :1)
Detector : FID (250 ℃)
Carrier gas : He, 2.4 mL/min

Rosemary

Peppermint

1. α-Pinene
2. Limonene
3. Isobornyl Acetate

1. Myrcene
2. 1,8-Cineole
3. L-Menthol
4. Anisaldehyde

4. α-Ionone

2

3
4

2

1

1

4

3
Before the extraction

Column : ULBON HR-1 30 m x 0.32 mm I.D.df = 0.25μm
Column temp : 50 ℃ 〜 200 ℃ Program rate 5 ℃/min
Injection : 250 ℃ (Sprit ratio: 10 :1)
Detector : FID (250 ℃)
Carrier gas : He, 2.4 mL/min

Column : ULBON HR-1 30 m x 0.32 mm I.D.df = 0.25μm
Column temp : 50 ℃ 〜 200 ℃ Program rate 5 ℃/min
Injection : 250 ℃ (Sprit ratio: 10 :1)
Detector : FID (250 ℃)
Carrier gas : He, 2.4 mL/min

32

Flower fragrance using NeedlEx for organic solvent
Lemon balm

Angels trumpet

1. α-Pinene

1. L-Menthon

2. 1,8-Cineole

2. Anisaldehyde

3. β-Phenethyl Alcohol

3. Geraniol
4. L-Perillaldehyde
5. α-Ionone

4

2

1

2
3

3

1

5

Column : ULBON HR-1 30 m x 0.32 mm I.D.df = 0.25μm
Column temp : 50 ℃ 〜 200 ℃ Program rate 5 ℃/min
Injection : 250 ℃ (Sprit ratio: 10 :1)
Detector : FID (250 ℃)
Carrier gas : He, 2.4 mL/min

Column : ULBON HR-1 30 m x 0.32 mm I.D.df = 0.25μm
Column temp : 50 ℃ 〜 200 ℃ Program rate 5 ℃/min
Injection : 250 ℃ (Sprit ratio: 10 :1)
Detector : FID (250 ℃)
Carrier gas : He, 2.4 mL/min

Yuzu citron

Holly tree

1. Myrcene

1. Benzyl Alcohol

2. Limonene

2. β-Phethyl Alcohol
3. Eugenol

2

2

1
1

3

Column : ULBON HR-1 30 m x 0.32 mm I.D.df = 0.25μm
Column temp : 50 ℃ 〜 200 ℃ Program rate 5 ℃/min
Injection : 250 ℃ (Sprit ratio: 10 :1)
Detector : FID (250 ℃)
Carrier gas : He, 2.4 mL/min

Column : ULBON HR-1 30 m x 0.32 mm I.D.df = 0.25μm
Column temp : 50 ℃ 〜 200 ℃ Program rate 5 ℃/min
Injection : 250 ℃ (Sprit ratio: 10 :1)
Detector : FID (250 ℃)
Carrier gas : He, 2.4 mL/min

33

Food flavor using NeedlEx for organic solvent
Worcestershire sauce

Soy sauce

1. Ethanol

1. Ethanol
2. Acetic Acid
3. Isoamyl ALcohol

2. Acetic Acid
3. Isoamyl ALcohol
4. 3-(Methylthio)-1-propanol

12 3

12

3
4

Column : ULBON HR-1 30 m x 0.32 mm I.D.df = 0.25μm
Column temp : 50 ℃ 〜 200 ℃ Program rate 5 ℃/min
Injection : 250 ℃ (Sprit ratio: 10 :1)
Detector : FID (250 ℃)
Carrier gas : He, 2.4 mL/min

Column : ULBON HR-1 30 m x 0.32 mm I.D.df = 0.25μm
Column temp : 50 ℃ 〜 200 ℃ Program rate 5 ℃/min
Injection : 250 ℃ (Sprit ratio: 10 :1)
Detector : FID (250 ℃)
Carrier gas : He, 2.4 mL/min

Brandy1. Ethanol
2. 1-Propanol
3. Ethyl Acetate
4. Isobutanol
5. Isoamyl Alcohol
6. Ethyl n-Caproate

14 5
2

3

6

Column : ULBON HR-1 30 m x 0.32 mm I.D.df = 0.25μm
Column temp : 50 ℃ 〜 200 ℃ Program rate 5 ℃/min
Injection : 250 ℃ (Sprit ratio: 10 :1)
Detector : FID (250 ℃)
Carrier gas : He, 2.4 mL/min

34

Steroids
Plant sterols in rice bran oil

Plant sterols

1. Brassicasterol
2. Campesterol
3. Stigmasterol
4. β-Sitosterol

4

1. Campesterol
2. Stigmasterol
3. β-Sitosterol

2 3

2
3

1

1

Column : ULBON HR-52 25 m x 0.25 mm I.D. df = 0.25μm
Column temp : 250 ℃ 〜 320 ℃ Program rate 5 ℃/min
Injection : 330 ℃ (Sprit ratio: 61 :1)
Detector : FID (330 ℃)
Carrier gas : He, 0.5 mL/min
Sample Volume: 0.5μL

Column : ULBON HR-1 30 m x 0.53 mm I.D. df = 1.0μm
Column temp : 290 ℃
Injection : 320 ℃ (Direct)
Detector : FID (320 ℃)
Carrier gas : He, 7.1 mL/min
Sample Volume: 0.5μL

Cholesterol and Plant sterols

1. Cholesterol
2. Brassicasterol
3. Campesterol
4. Stigmasterol
5
1

4
3
2

Column : ULBON HR-17 25 m x 0.25 mm I.D.df = 0.25μm
Column temp : 290 ℃
Injection : 310 ℃ (Sprit ratio: 20 :1)
Detector : FID (310 ℃)
Carrier gas : He, 1.5 mL/min
Sample Volume: 1.5 μL

35

5. β-Sitosterol

Steroids
Cholesterol esters

Cholesterol & Cholestanol

1. Cholesterol
2. Cholesterol Acetate
3. Cholesterol Propionate
4. Cholesterol Isobutyrate
5. Cholesterol n-Butyrate
6. Cholesterol n-Valerate
7. Cholesterol n-Caproate
8. Cholesterol n-Octanoate
9. Cholesterol n-Decanoate
10. Cholesterol Laurate
11. Cholesterol Myristate12
34 5 67

1.Cholesterol
2.Cholestanol
1

8
9
10
2

11

Column : ULBON HR-1 50 m x 0.25 mm I.D. df = 0.25 μm
Column temp : 300 ℃
Injection : 330 ℃ (Sprit ratio: 60 :1)
Detector : FID (330 ℃)
Carrier gas : He, 0.65 mL/min
Sample Volume: 0.8 μL

Column : ULBON HR-1 25 m x 0.25 mm I.D. df = 0.15 μm
Column temp : 250 ℃ 〜 330 ℃ Program rate 5 ℃/min
Injection : 340 ℃ (Sprit ratio: 48 :1)
Detector : FID (340 ℃)
Carrier gas : He, 1.3 mL/min
Sample Volume: 0.5 μL

Sterols

1. Dehydroepiandrosterone
2. Estrone
3. Cholestane
4. Progesterone
5. Estriol
6. Cholesterol
7. Lanosterol

1
3
4
2

6

5
7

Column : ULBON HR-52 50 m x 0.25 mm I.D. df = 0.25μm
Column temp : 250 ℃ 〜 320 ℃ Program rate 4 ℃/min
Injection : Injection : 330 ℃ (Sprit ratio: 69 :1)
Detector : FID (330 ℃)
Carrier gas : He, 0.5 mL/min
Sample Volume: 2.0μL

36

Environmental Pollutants
Phthalic acid esters

1
2

3

4
5
7

6

8

1. Dimethyl Phthalate
2. Diethyl Phthalate
3. Diallyl Phthalate
4. Di-iso-Butyl Phthalate
5. Di-n-Buthyl Phthalate
6. Di-n-Amyl Phthalate
7. Di-2-Ethylhexyl Phthalate
8. Di-n-Octyl Phthalate

Column : ULBON HR-1 25 m x 0.25 mm I.D. df = 0.25μm
Column temp : 180 ℃ 〜 300 ℃ Program rate 6 ℃/min
Injection : 320 ℃ (Sprit ratio: 36 :1)
Detector : FID (320 ℃)
Carrier gas : He, 0.98 mL/min
Sample Volume: 0.5 μL

Organic acid butyl esters

1. n-Butyl Formate
2. n-Butyl Acetate
3. n-Butyl Propionate
4. n-Butyl iso-Butyrate
5. n-Butyl n-Butyrate
6. n-Butyl Crotonate
7. n-Butyl n-Caproate
8. n-Butyl Lactate
9. n-Butyl n-Caprate
10. Di-n-Butyl Oxalate

24
1
5

9

7

11. n-Butyl Benzoate
12. Di-n-Butyl Malonate
13. Di-n-Butyl Fumarate
14. Di-n-Butyl Succinate
15. Di-n-Butyl Maleate
16. Di-n-Butyl Adipate
17. Di-n-Butyl Malate
18. Di-n-Butyl Phthalate
19. Di-n-Butyl Sebacate
20. Di-n-Butyl Isophthalate
21. Di-n-Butyl Terephthalate
22. Tri-n-Butyl Citrate11
18 19 20 21

8
3

6

13 15
14

10

16

12
17

Column : ULBON HR-20M 25 m x 0.25 mm I.D. df = 0.25μm
Column temp : 80 ℃ 〜 240 ℃ Program rate 4 ℃/min
Injection : Injection : 250 ℃ (Sprit ratio: 40 :1)
Detector : FID (250 ℃)
Carrier gas : He, 1.1 mL/min
Sample Volume: 1.0 μL

37

22Environmental Pollutants
Alkylphenol isomers

1

10

3
6 7

4
5
2

13

16

1. Phenol
2. 2,6-Xylenol
3. o-Cresol
4. p-Cresol
5. m-Cresol
6. o-Ethylphenol
7. 2,4,6-Trimethylphenol
8. 2,4-Xylenol
9. 2,5-Xylenol
10. 2,3,6-Trimethylphenol
11. 2,3-Xylenol
12. p-Ethylphenol
13. m-Ethylphenol
14. 3,5-Xylenol
15. 3,4-Xylenol
16. 2,3,5-Trimethylphenol

8
9

12 14
11

15

Column : ULBON ALPhen 50 m x 0.20 mm I.D.
Column temp : 130 ℃
Injection : 250 ℃ (Sprit ratio: 70 :1)
Detector : FID (250 ℃)
Carrier gas : N2, 0.39 mL/min
Sample Volume: 0.5 μL

m-Cresol in p-Cresol ( 10% benzene solution )3

1. Phenol
2. o-Cresol
3. p-Cresol
4. m-Cresol

412

Column : ULBON ALPhen 50 m x 0.20 mm I.D.
Column temp : 130 ℃
Injection : 250 ℃ (Sprit ratio: 50 :1)
Detector : FID (250 ℃)
Carrier gas : N2, 0.39 mL/min
Sample Volume: 0.5 μL

38

Environmental Pollutants
Impurities in 3,5-xylenol (10% benzene solution)
1. 2,6-Xylenol
2. p-Cresol
3. m-Cresol
4. 2,4,6-Trimethylphenol
5. 2,4-Xylenol
6. 2,5-Xylenol
7. 2,3,6-Trimethylphenol
8. 2,3-Xylenol
9. p-Ethylphenol
10. m-Ethylphenol
11. 3,5-Xylenol
12. 3,4-Xylenol

11

10

4

1

9

56

12

8
7

23

Column : ULBON ALPhen 50 m x 0.20 mm I.D.
Column temp : 130 ℃
Injection : 250 ℃ (Sprit ratio: 50 :1)
Detector : FID (250 ℃)
Carrier gas : N2, 0.39 mL/min
Sample Volume: 0.5 μL

Alkylphenol mixture (0.1 〜 0.3% Acetone solution)

1
2
4
11
3
9

17

Column : ULBON ALPhen 50 m x 0. 32 mm I.D.
Column temp : 130 ℃
Injection : 250 ℃ (Sprit ratio: 20 :1)
Detector : FID (250 ℃)
Carrier gas : He, 1.3 mL/min
Sample Volume: 0.5 μL

39

44

40

36

32

13 15
12 14

10

28

78

24

20

16

12

8

4

56

16

48

1. Acetone
2. Phenol
3. 2,6-Xylenol
4. o-Cresol
5. p-Cresol
6. m-Cresol
7. o-Ethylphenol
8. 2,4,6-Trimethylphenol
9. 2,4-Xylenol
10. 2.,5-Xylenol
11. 2,3,6-Trimethylphenol
12. 2,3-Xylenol
13. p-Ethylphenol
14. m-Ethylphenol
15. 3,5-Xylenol
16. 3,4-Xylenol
17. 2,3,5-Trimethylphenol

Environmental Pollutants
Alkyl Mercury

Tri-n-Butyltin Chloride

1. Methyl Mercuric Chloride(100 ppb) (40 pg)
2. Ethyl Mercuric Chloride(100 ppb) (40 pg)

1.Tri-n-Butyltin Chloride(100 ppb) (40 pg)

2
1
1

Column : ULBON HR-Thermon-HG 15 m x 0.53 mm I.D.
Column temp : 150 ℃
Injection : 250 ℃ (Direct)
Detector : ECD (250 ℃)
Carrier gas : N2, 4.5 mL/min
Sample Volume: 1.0μL

Column : ULBON HR-Thermon-HG 15 m x 0.53 mm I.D.
Column temp : 150 ℃
Injection : 250 ℃ (Direct)
Detector : ECD (250 ℃)
Carrier gas : N2, 4.5 mL/min
Sample Volume: 1.0μL

Organic phosphorus pesticides

1. DDVP
2. Methyldimethone
3. Methylparathion
4. Ethylparathion
5. EPN

1
3
2

4

5

Column : ULBON HR-1 15 m x 0.53 mm I.D. df = 1.0μm
Column temp : 150 ℃ 〜 220 ℃ Program rate 6 ℃/min
Injection : 250 ℃ (Direct)
Detector : FID (250 ℃)
Carrier gas : He, 10.7 mL/min
Sample Volume: 0.5μL

40

Others
Aliphatic amines

1. n-Octylamine
2. n-Decylamine
3. Laurylamine
4. n-Tetradecylamine
5. Cetylamine
6. Stearylamine

3

1
2

4
5
6

Column : ULBON HR-52 25 m x 0.25 mm I.D. df = 0.25μm
Column temp : 150 ℃ 〜 230 ℃ Program rate 4 ℃/min
Injection : 250 ℃ (Sprit ratio: 56 :1)
Detector : FID (250 ℃)
Carrier gas : He, 0.48 mL/min
Sample Volume: 1.5μL

Medicines

Sugars (Acetate)

1. Sucrose
2. Maltose
3. Lactose
4. Raffinose

1. o-Ethoxybenzamide
2. Phenacetine
3. Caffeine
4. Aminopyrine
5. Chlorpheniramine Maleate

2

1

1

4
2

3
3

4
5

Column : ULBON HR-1701 25 m x 0.25 mm I.D. df=0.25μm
Column temp : 180 ℃ 〜 280 ℃ Program rate 4 ℃/min
Injection : Injection : 300 ℃ (Sprit ratio: 58 :1)
Detector : FID (300 ℃)
Carrier gas : He, 0.49 mL/min
Sample Volume: 1.0μL

Column : ULBON HR-1 15 m x 0.53 mm I.D. df = 1.0μm
Column temp : 180 ℃
Injection : 250 ℃ (Direct)
Detector : FID (250 ℃)
Carrier gas : He, 7.2 mL/min
Sample Volume: 0.5μL

41

Application Index
A
Acetaldehyde

22

Acetic Acid24, 34

Acetone18, 19, 20, 21, 39

Acrylonitrile

14

Active Amyl Alcohol

18, 22

Aminopyrine

41n-Amyl Acetate

18, 20, 21

Anisaldehyde

32, 33

Anthracene

14
B

Benzene12, 13, 14, 16, 18, 19

1,2-Benzpyrene

14

4,5-Benzpyrene

14

Benzyl Acetate

31, 32

Benzyl Alcohol

33

Benzyl Salicylate

31

Biphenyl

14

Brassicasterol

35

n-Butanol

18, 19, 20, 21

2-Butanol

18n-Butyl Acetate

18, 19, 20, 21, 37

n-Butyl Benzoate

37

n-Butyl n-Butyrate

37

n-Butyl iso-Butyrate

37

n-Butyl n-Caprate

37

n-Butyl n-Caproate

37

Butyl Cellosolve

19, 20n-Butyl Crotonate

37

n-Butyl Formate

37

n-Butyl Lactate

37

n-Butyl Propionate

37

n-Butyric Acid24

iso-Butyric Acid

24
C

Caffeine

41

Campesterol

35

42

Application Index
C
iso-Caproic Acid

24

n-Caproic Acid

24

Carbon Tetrachloride

18, 19, 21

Cellosolve Acetate

18, 19, 20

Cetylamine

41

Chlorobenzene

18, 19, 21

Chloroform

18, 19, 20, 21

Chlorpheniramine Maleate

41

Cholestane

36

Cholestanol

36

Cholesterol

35, 36Cholesterol Acetate

36

Cholesterol n-Butyrate

36

Cholesterol n-Caproate

36

Cholesterol n-Decanoate

36

Cholesterol Isobutyrate

36

Cholesterol Laurate

36

Cholesterol Myristate

36

Cholesterol n-Octanoate

36

Cholesterol Propionate

36

Cholesterol n-Valerate

36

Chrysene

14

1,8-Cineole32, 33m-Cresol

20, 21, 38, 39

o-Cresol

18, 19, 20, 21, 38, 39

p-Cresol

18, 19, 20, 21, 38, 39

Cyclohexanol

20, 21

Cyclohexanone

18, 20, 21
D

DDVP

40

n-Decylamine

41

Dehydroepiandrosterone

36

Diallyl Phthalate

37

Di-n-Amyl Phthalate

37

Di-n-Buthyl Phthalate

37

Di-n-Butyl Adipate

3743Application Index
D
Di-n-Butyl Fumarate

37

Di-n-Butyl Isophthalate

37

Di-n-Butyl Malate

37

Di-n-Butyl Maleate

37

Di-n-Butyl Malonate

37

Di-n-Butyl Oxalate

37

Di-n-Butyl Phthalate

37

Di-iso-Butyl Phthalate

37

Di-n-Butyl Sebacate

37

Di-n-Butyl Succinate

37

Di-n-Butyl Terephthalate

37m-Dichlorobenzene

18, 19, 20, 21

o-Dichlorobenzene

18, 19, 20, 21

p-Dichlorobenzene

18, 19, 20, 21

1,2-Dichloroethane18, 20trans-1,2-Dichloroethylene

21

cis-1,2-Dichloroethylene

20trans-1,2-Dichloroethylene

18, 19, 20

Dichloromethane18, 19, 20, 21

Diethyl Phthalate

31, 37Di-2-Ethylhexyl Phthalate

37

Dimethyl Phthalate

37

N,N-Dimethylformamide

14, 201,2-DMN

15

1,3-DMN

15

1,4-DMN

15

1,5-DMN

15

1,6-DMN

15

1,7-DMN

15

1.8-DMN

15

2,3-DMN

15

2,6-DMN

15

2,7-DMN

15

Di-n-Octyl Phthalate

37

1,4-Dioxane

18, 19, 20, 21

Diphenyl

1544Application IndexDn-Docosanol

22E

n-Eicosane (C20)

10, 11EPN

40

Estriol

36

Estrone36

Ethanol

18, 19, 22, 34

o-Ethoxybenzamide

41

Ethyl Acetate

18, 19, 20, 21, 22, 34

Ethyl n-Caproate

34

Ethyl Cellosolve

20

Ethyl Ether18, 20, 21

Ethyl Mercuric Chloride

40

Ethylbenzene

12, 13, 14, 16, 17, 18, 19, 20, 21

1-Ethylnaphthalene

152-Ethylnaphthalene

15Ethylparathion

40

m-Ethylphenol

38, 39o-Ethylphenol

38, 39p-Ethylphenol

38, 39m-Ethyltoluene

12, 13, 16, 17

p-Ethyltoluene

12, 13, 16, 17

o-Ethyltoluene

12, 13, 16

Eugenol

31, 33
F

Fluoranthene

14

Fluorene

14
G

Geraniol32, 33H

n-Heptanoic Acid

24

n-Hexacosane

10, 11n-Hexane

12, 13, 16, 18, 19, 20, 21

n-Hexatriacontane

10, 11I

α-Ionene

31, 32, 33

45

Application Index
I
Isoamyl Acetate

18, 20, 21

Isoamyl Alcohol

18, 20, 22, 34

Isobornyl Acetate

32

Isobutanol

20, 21, 34

Isobutyl Acetate

18, 19Isopropanol

20, 21Isopropyl Acetate

20

Isopropylbenzene

16, 17
L

Lactose41

Lanosterol

36

Lauryl Alcohol31

Laurylamine

41

Limonene

31, 32, 33

Linalool

31, 32

Linalyl Acetate

31
M

Maltose41

L-Menthon

32, 33

Methanol18, 19, 20, 21

Methyl Acetate

20

Methyl Arachidate (C20:0)

24, 25, 26

Methyl Arachidonate (C20:4n6)

26

Methyl Behenate (C22:0)

24, 25, 26

2-Methyl-1-Butanol

22

3-Methyl-1-Butanol

22

Methyl n-Butyl Ketone

18, 19, 20, 21

Methyl Butyrate (C4:0)

26

Methyl Caprate (C10:0)

25, 26

Methyl Caproate (C6:0)

25, 26

Methyl Caprylate (C8:0)

26, 29, 30

Methyl Cellosolve

20

Methyl Cerotate (C26:0)

24

Methyl cis-13,16-Docosadienoate (C22:2)

26

Methyl cis-4,7,10,13,16,19-Docosahexaenoate (C22:6n3)

25, 26, 27, 28, 30

Methyl cis-7,10,13,16,19-Docosapentaenoate (C22:5n3)

27, 28, 30

46

Application Index
M
Methyl cis-11,14-Eicosadienoate (C20:2)

26

Methyl cis-5,8,11,14,17-Eicosapentaenoate (C20:5n3)

26, 27, 28, 30

Methyl cis-,11,14,17-Eicosatrienoate (C20:3n3)

26

Methyl cis-8,11,14-Eicosatrienoate (C20:3n6)

26

Methyl cis-11-Eicosenoate (C20:1n9)25, 26

Methyl Elaidate (C18:1n9t)

26, 29Methyl Erucate (C22:1n9)25, 26

Methyl Ethyl Ketone (MEK)

18, 19, 20

Methyl Henicosanoate (C21:0)

26

Methyl Heptadecanoate (C17:0)

26

Methyl cis-10-Heptadecenoate (C17:1)

26

Methyl Isobutyl Ketone (MIBK)

18, 19, 20, 21

Methyl Laurate (C12:0)

25, 26, 29, 30

Methyl Lignocerate (C24:0)

24, 25, 26

Methyl Linoleate (C18:2n6c)

25, 26, 27, 28, 29, 30

Methyl Linolelaidate (C18:2n6t)

26

Methyl Linolenate (C18:3n3)

25, 26, 27, 28, 29, 30

Methyl γ-Linolenate (C18:3n6)

26

Methyl Melissylate (C30:0)

24

Methyl Mercuric Chloride

40

Methyl Montanate (C28:0)

24

Methyl Myristate (C14:0)

25, 26, 27, 28, 29, 30

Methyl Myristoleate (C14:1)

26

Methyl Nervonate (C24:1n9)25, 26

Methyl Oleate (C18:1n9c)

25, 26, 27, 28, 29, 30

Methyl Palmitate (C16:0)

25, 26, 27, 28, 29, 30

Methyl Palmitoleate (C16:1)

25, 26, 27, 28, 29, 30

Methyl Pentadecanoate (C15:0)

26

Methyl cis-10-Pentadecanoate (C15:1)

26

Methyl Stearate (C18:0)

25, 26, 27, 28, 29, 30

Methyl Tricosanoate (C23:0)

26

Methyl Tridecanoate (C13:0)

26

Methyl Undecanoate (C11:0)

26

2-Methylcyclohexanol

18, 20, 21

3-Methylcyclohexanol(cis, trans)19

cis-4-Methylcyclohexanol

2047

Application Index
M
trans-4-Methylcyclohexanol

20

2-Methylcyclohexanone

19, 20, 21

3-Methylcyclohexanone

20

4-Methylcyclohexanone

18, 19, 20, 21

Methyldimethone

40

1-Methylnaphthalene

15

2-Methylnaphthalene

15

Methylparathion

40

3-(Methylthio)-1-propanol

34

Myrcene32, 33N

Naphthalene12, 13, 14

n-Nonane

16On-Octadecanol

22n-Octane16

iso-Octane

12, 13n-Octylamine

41Pn-Pentacosane

10, 11n-Pentane12, 133-Pentanol

22

L-Perillaldehyde

33

Perillaldehyde

32Perylene

14

Phenacetine

41

Phenanthrene

14

Phenethyl Alcohol31β-Phenethyl Alcohol

32, 33

Phenol38, 39β-Phethyl Alcohol

33

α-Pinene

31, 32, 33

β-Pinene

31

Progesterone

36

1-Propanol

18, 19, 22, 34

2-Propanol

19, 20, 21

48

Application Index
P
Propionic Acid

24

n-Propyl Acetate

18, 20n-Propylbenzene

12, 13, 14, 16, 17

iso-Propylbenzene

12, 13, 14, 17

2-n-Propyltoluene

163-n-Propyltoluene

164-n-Propyltoluene

16

Pyrene14
R

Raffinose

41
S

β-Sitosterol

35

Stearylamine

41

Stigmasterol

35

Styrene14, 16, 18, 19, 20, 21

Sucrose41
T

m-Terphenyl

14o-Terphenyl

14

p-Terphenyl

14

1,1,2,2-Tetrachloroethane19, 20, 21

Tetrachloroethylene

18, 19, 20, 21

n-Tetradecylamine

41

Tetrahydrofuran

18, 19, 21

1,2,3,4-Tetramethylbenzene

16

1,2,3,5-Tetramethylbenzene

16

Toluene12, 13, 14, 16, 17, 18, 19, 20, 21

Tri-n-Butyl Citrate37

Tri-n-Butyltin Chloride

40

1,1,1-Trichloroethane18, 19, 21

Trichloroethylene

19, 20, 21

Triglyceride23

1,2,3-Trimethylbenzene

12, 13, 16

1,2,4-Trimethylbenzene

12, 13, 16

1,2,5-Trimethylbenzene

12, 13

1,3,5-Trimethylbenzene

1649Application IndexT
2,3,5-Trimethylphenol

38, 39

2,3,6-Trimethylphenol

38, 39

2,4,6-Trimethylphenol

38, 39V

iso-Valeric Acid

24

Vanillin

31
X

m-Xylene

12, 13, 16, 17, 18, 19, 20

o-Xylene

12, 13, 16, 17, 18, 19, 20, 21

p-Xylene

12, 13, 16, 17, 19, 20, 21

2,3-Xylenol

38, 392,4-Xylenol

38, 392,5-Xylenol

38, 392,6-Xylenol

38, 393,4-Xylenol

38, 393,5-Xylenol

38, 3950

Product Index
ULBON HR-1

10, 12, 13, 14, 18, 32, 33, 34, 35, 36, 37, 40, 41

ULBON HR-52

11, 18, 19, 21, 22, 24, 35, 36, 41

ULBON HR-17

35

ULBON HR-1701

19, 20, 21, 41

ULBON HR-20M

12, 13, 14, 20, 22, 24, 25, 37

ULBON HR-SS-10

26, 27, 28, 29, 30

ULBON HR-Thermon-3000B

25

ULBON HR-Thermon-600T

31

ULBON HR-Thermon-HG

40

ULBON HR-TGC1

23

ULBON ALPhen38, 39ULBON DMN 267

15

ULBON PLC

15

ULBON Xylene Master16, 17ULBON SPX-1

1751

Shinwa Chemical Industries Ltd. reserves the right to change product specifications, designs
or prices without notice and without liability for such changes.

50-2 Kagekatsu-Cho, Fushimi-Ku, Kyoto
612-8307 JAPANFAX +81-75-602-2660
URL: http://shinwa-cpc.co.jp/eng/index.html
E-mail: info@shinwa-cpc.co.jp
LN1003B