2012/2013

CZ 1203-02/12-20.000

Intermediates

We Create Chemistry
Building Blocks andReagents for ourCustomers’ Needs

www.intermediates.basf.com
info.intermediates@basf.com

bi11_1_8_Umschlag_RZ_09022012.indd 1

10.02.2012 17:29:32 Uhr

We Create Chemistry
Building Blocks andReagents for ourCustomers’ Needs

BASF – The Chemical Company
BASF is the world’s leading chemical company:
The Chemical Company. Its portfolio ranges
from chemicals, plastics, performance products
and crop protection products to oil and gas.
We combine economic success, social
responsibility and environmental protection.
Through science and innovation we enable ourcustomers in almost all industries to meet thecurrent and future needs of society. Our
products and system solutions contribute toconserving resources, ensuring healthy foodand nutrition and helping to improve the qualityof life. We have summed up this contribution
in our corporate purpose: We create chemistry
for a sustainable future.

Top Intermediates Supplier
The BASF Group’s Intermediates division develops,
produces and markets a comprehensive portfolioof more than 600 intermediates around the world.
The most important of the division’s productgroups include amines, diols, polyalcohols, acids
and specialties. Among other applications,intermediates are used as starting materials forcoatings, plastics, pharmaceuticals, textile fibers,
detergents and crop protectants. Innovativeintermediates from BASF help to improve theproperties of final products and the efficiency
of production processes. The ISO 9001:2000certified Intermediates division operates plants at
production sites in Europe, Asia, and the Americas.

Content

Foreword and Guidelines

4

Product Catalog

6

1. Acid Chlorides, Alkyl Chlorides
and Chloroformates

6

1.1
1.2
1.3
1.4

Acid Chlorides
Aliphatic Chlorides
Carbamoyl Chlorides
Chloroformates

6
10
12
14

5. Amino Alcohols
5.1
5.2
5.3
5.4

Ethanolamines
Isopropanolamines
Alkylamino Alcohols
Other Amino Alcohols

74
78
80
84

6. Carboxylic Acids and Derivatives

88

6.1
6.2

Carboxylic Acids
Derivatives

7. Heterocyclic Compounds
2. Alcohols, Diols and Polyols
2.1
2.2

Mono Alcohols
Diols and Polyols

3. Aldehydes, Acetals and Ketones
3.1
3.2
3.3

Acetals
Aldehydes
Ketones

4. Amines
4.1
4.2
4.3
4.4
4.5
4.6
4.7

2

18
18
22
32
32
34
36
38

Aliphatic Monoamines
38
Aliphatic Diamines
48
Aliphatic Oligoamines
54
Etheramines
58
Polyurethane Catalysts (Lupragens) 62
Aromatic Amines and Nitro
66
Compounds
AMIX
72

74

7.1
7.2
7.3
7.4
7.5
7.6
7.7
7.8

Carbonates
Imidazoles and Pyrazoles
Lactones and Lactams
Morpholines
Other Heterocycles
Oxiranes
Piperazines
Piperidines

88
92
94
94
98
104
110
112
114
116
118

7.9
7.10

Pyrrolidines
Tetrahydropyrans

120
122

8. Optically Active Compounds

124

8.1
8.2
8.3

Chiral Alcohols and Epoxides
Chiral Amines
Chiral Carboxylic Acids andDerivatives

124
126
140

9. Others

142

9.1
9.2
9.3
9.4
9.5
9.6
9.7
9.8
9.9

142
144
146
148
156
158
160
162
168

AmidesHydrocarbons
IminesIonic Liquids
NitrilesPhosphorus Compounds
Urea Derivatives
Vinyl Compounds and Ethers
OthersAlphabetical Index

170

CAS Registry No. Index

180

GHS Assignment Scheme
190– How to Get Easily from H to P
Overview GHS Pictogram

198

Contact, Imprint

199

Foreword

Dear customers
and future customers:
Information about our new, enhanced andproven chemical intermediates is what awaits
you in this revised version of our BASF’s
Intermediates product catalog. This comprehensive reference work is meant to provide
an overview of our globally unique portfolio
of intermediates. A review of the book has
become necessary because we are constantly
developing new products and improving
existing intermediates. This is our contribution
to enhancing our customers’ products andmaking them more successful.

www.basf.com/productfinder. Here you cantake a closer look at BASF, the world’s leadingchemical company.

In the Intermediates Division, we keep an evertighter focus on the market, and we target ouractivities clearly at change and innovation. We
believe that developing innovations close to ourcustomers is a vital key to shaping the future.
Our approach is based on the unparalleledexpertise available in our BASF ‘Verbund’. As
our customers’ long-term, reliable partner,
we seek to use this expertise to contributepurposefully and sustainably to their success.

Our new product catalog contains new, provenand enhanced products. Mainly, pure compounds are listed. If you need specific mixtures,
just ask, we’ll be glad to help you.

Our updated, extended range of products
offers you many options for selecting the
optimal solution to your production requirements. If you cannot find a product in thiscatalog that is just right for your needs, thenplease contact us. We will be happy to develop
customized solutions that meet your specificrequirements. You may telephone us or contact
us via e-mail (info.intermediates@basf.com).
More details on our portfolio offers the website

We do not think we have succeeded unless
our intermediates help you to succeed in yourmarket: so don’t wait too long before you talkto us. We look forward to hearing from you.

Your BASF Intermediates teamHandling notes

There are several different ways for you to findthe right product for your processes:■

Search for the English name (indexed inalphabetical order), or■

search for the CAS number (indexed byascending numbers).

The table section also includes somecommon trivial names and IUPAC-compliant
product names.
Additionally, you will find some information onregistration in the following chemical inventories:
REACH (EU), TSCA (USA), IECSC (China) andENCS/IS (Japan).

Please note
The data contained in this publication are based on
our current knowledge and provide no legally binding
warranties or guarantees. In view of the many factorsthat may affect the application of our products, thesedata do not relieve processors from carrying out theirown investigations and tests. Any proprietary thirdparty rights and all existing laws and regulations
must be respected. The safety data are provided for

4

information only and are no substitute for the legallybinding material safety data sheet. The current material
safety data sheet for each product is available on
request from your supplier, or directly from BASF
(info.intermediates@basf.com).
We offer no guarantees for the information and datacontained herein.

Guidelines

Customer orientation

Superior quality

Intensive research and a close focus on ourcustomers’ needs are the foundations of ourbusiness. In order to constantly expand ourportfolio we fulfill our customers’ specific needs.
We place great emphasis on flexibility andbelieve that anything is possible – fromthe smallest amounts on a laboratory scale,
all the way up to use in bulk production lines.
Thanks to our broad and innovative range ofintermediates, we have competencies in all
markets. This fact allows us to make our
products globally available. For us, fast andreliable delivery is of paramount importance.

The BASF Intermediates Division is ISO 9001
certified. We offer a particularly broad rangeof chem-ical products. In addition, we develop
innovative technologies and proceduresthat will allow you to integrate our products
seamlessly and cost effectively into yourexisting processes. Throughout, we support
our customers with an extensive range ofservices. Our combination of three building
blocks for your success – excellent products,
technologies, and services – demonstrates
our commitment to a unique level of qualitythat has made BASF the world’s leadingchemical company.

Reliable partnership
Our broad range of products, multitude ofcomprehensive solutions, and high innovation
potential all translate into the added valuethat BASF brings to you. As our customer, youwill benefit from the greatest assurance of
success for your processes. And, looking
forward, you can also rely on us to stand by
your side with a comprehensive offering in
the future.

5

1

Acid Chlorides, Alkyl Chlorides and Chloroformates

1.1

Acid Chlorides

No.

Product[CAS Registry No.]

1.1.1

2-Ethylhexanoyl chloride[760-67-8]

1.1.2

3-Chlorpropionyl chloride[625-36-5]

1.1.3

4-Chlorobutyryl chloride[4635-59-0]

1.1.4

5-Chlorovaleryl chloride[1575-61-7]

1.1.5

Heptane acid chloride[2528-61-2]

1.1.6

Isobutyryl chloride[79-30-1]

1.1.7

Isononanoyl chloride[36727-29-4]

6

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

162.66 g/mol
0.953 g/cm³ (20 °C)
min. 99.0
73 – 75 °C (23 hPa)
< –75 °C

H290; H302; H314; H317;
H330; EUH071
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

126.97 g/mol
1.33 g/cm³ (13 °C)
min. 98.0
144 °C–32 °C

H226; H302; H314; H330
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

141.00 g/mol
1.26 g/cm³ (20 °C)
min. 99.0
120 – 160 °C–49 °C

H302; H314; H330
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

155.02 g/mol
1.2056 g/cm³ (20 °C)
min. 97.5
80 °C (15 hPa)
–58 °CH290; H302; H314
Danger

REACH;IECSC

M
d% (w/w)b.p.
m.p.

148.63 g/mol
0.9615 g/cm³ (20 °C)
min. 98.5
173 °C< –50 °C

H314; H330; H412
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

106.55 g/mol
1.02 g/cm³ (20 °C)
min. 99.0
92 – 94 °C< –70 °C

H225; H290; H302; H314;
H330
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

176.69 g/mol
0.94 g/cm³ (20 °C)
min. 98.0
192 °C< –50 °C

H290; H302; H314; H317;
H330; H412; EUH071
Danger

REACH;TSCA;
IECSC;
ENCS/IS

Explanation of symbols
M = Mol. Weightd = Density% (w/w) = Purity/Content

Pictogramb.p. = Boiling Point

ChemicalInventory

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

7

1.1

Acid Chlorides

No.

Product[CAS Registry No.]

1.1.8

Isovaleroyl chloride[108-12-3]

1.1.9

Neodecanoyl chloride[40292-82-8]

1.1.10Octanoyl chloride[111-64-8]

1.1.11

Pivaloyl chloride[3282-30-2]

1.1.12

Propionyl chloride[79-03-8]

1.1.13

Valeroyl chloride[638-29-9]

8

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

120.58 g/mol
0.98 g/cm³ (20 °C)
min. 98.5
114 – 116 °C< –70 °C

H225; H290; H314; H332;
H412
DangerTSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

190.71 g/mol
0.95 g/cm³ (20 °C)
min. 99.0
100 °C (28 hPa)
< –50 °C

H290; H302; H314; H317;
H330; H412; EUH071
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

162.66 g/mol
0.949 g/cm³ (20 °C)
min. 98.0
196 °C–63 °CH290; H315; H317; H318;
H330; EUH071
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

120.58 g/mol
0.98 g/cm³ (20 °C)
min. 99.0
103 – 108 °C–57 °CH225; H290; H302; H314;
H330; H412; EUH071
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

92.52 g/mol
1.06 g/cm³ (20 °C)
min. 99.5
77 – 79 °C–94 °CH225; H314; H332;
EUH014Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

120.58 g/mol
0.99 g/cm³ (20 °C)
min. 99.0
125 – 127 °C< –50 °C

H226; H290; H314; H332;
H412
Danger

REACH;TSCA;
IECSC;
ENCS/IS

Explanation of symbols
M = Mol. Weightd = Density% (w/w) = Purity/Content

Pictogramb.p. = Boiling Point

ChemicalInventory

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

9

1.2

Aliphatic Chlorides

No.

Product[CAS Registry No.]

1.2.1

1,6-Dichlorohexane[2163-00-0]

1.2.2

1-Chloro-3-methoxypropane (standard)[36215-07-3]

1.2.3

1-Chloro-3-methoxypropane > 99%[36215-07-3]

1.2.4

1-Chloro-3-methoxypropane Pharma
Premium[36215-07-3]

1.2.5

2-Ethylhexylchloride[123-04-6]

1.2.6

Ethylene chlorohydrine[107-07-3]

10

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

155.07 g/mol
1.07 g/cm³ (20 °C)
min. 99.0
208 °C–13 °C

H412

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

108.57 g/mol
0.9979 g/cm³ (20 °C)
min. 97.0
111 °C< –70 °C

H225; H332
DangerREACH

Md% (w/w)b.p.
m.p.

108.57 g/mol
0.9979 g/cm³ (20 °C)
min. 99.0
111 °C< –70 °C

H225; H332
DangerREACH

Md% (w/w)b.p.
m.p.

108.57 g/mol
0.9979 g/cm³ (20 °C)
min. 99.8
111 °C< –70 °C

H225; H332
DangerREACH

Md% (w/w)b.p.
m.p.

148.68 g/mol
0.882 g/cm³ (20 °C)
min. 98.0
172 °C< –20 °C

H226; H315; H411
Warning

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

80.51 g/mol
1.2 g/cm³ (20 °C)
min. 99.0
128.7 °C
–63 °C

H226; H300; H310; H330;
H411
Danger

REACH;TSCA;
IECSC;
ENCS/IS

Explanation of symbols
M = Mol. Weightd = Density% (w/w) = Purity/Content

Pictogramb.p. = Boiling Point

ChemicalInventory

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

11

1.3

Carbamoyl Chlorides

No.

Product[CAS Registry No.]

1.3.1

Diethylcarbamoyl chloride[88-10-8]

12FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

H302; H315; H319; H332;
H335; H351
Warning

135.59 g/mol
1.07 g/cm³ (20 °C)
min. 98.0
121 – 123 °C (133 hPa)
–32 °C

Explanation of symbols
M = Mol. Weightd = Density% (w/w) = Purity/Content

Pictogramb.p. = Boiling Point

ChemicalInventory
REACH;TSCA;
IECSC;
ENCS/IS

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

13

1.4

Chloroformates

No.

Product[CAS Registry No.]

1.4.1

2-Ethylhexyl chloroformate[24468-13-1]

1.4.2

4-tert.-Butylcyclohexyl chloroformate[42125-46-2]

1.4.3

Benzyl chloroformate[501-53-1]

1.4.4

Cetyl chloroformate RD[26272-90-2]

1.4.5

Ethyl chloroformate[541-41-3]

1.4.6

Methyl chloroformate[79-22-1]

1.4.7

Myristyl chloroformate[56677-60-2]

14

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

192.69 g/mol
0.988 g/cm³ (20 °C)
min. 99.0> 120 °C
< –75 °C

H290; H315; H317; H330
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

218.72 g/mol
1.05 g/cm³ (20 °C)
min. 97.0
90 – 100 °C (5 hPa)
–20 – –10 °C

H314; H331; H412;
EUH071Danger

REACH;
TSCA;
IECSC

M
d
% (w/w)b.p.
m.p.

170.60 g/mol
1.21 g/cm³ (20 °C)
min. 97.0
30 °C< –18 °C

H314; H330; H350; H373;
H400; H410; EUH071
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

304.90 g/mol
0.93 g/cm³ (20 °C)
min. 99.0
120 °C
15 °C

H290; H315; H317
Warning

REACH;
TSCA;
ENCS/ISMd% (w/w)b.p.
m.p.

108.52 g/mol
1.14 g/cm³ (20 °C)
min. 99.0
93 – 95 °C–80 °CH225; H290; H301; H314;
H330; EUH071
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

94.50 g/mol
1.237 g/cm³ (15 °C)
min. 99.0
71 – 72 °C–61 °CH225; H290; H300; H312;
H314; H330; EUH071
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

276.85 g/mol
0.94 g/cm³ (20 °C)
min. 98.0
not available
4 °C

H315
Warning

REACH

Explanation of symbols
M = Mol. Weightd = Density% (w/w) = Purity/Content

Pictogramb.p. = Boiling Point

ChemicalInventory

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

15

1.4

Chloroformates

No.

Product[CAS Registry No.]

1.4.8

n-Hexyl chloroformate[6092-54-2]

1.4.9

Propyl chloroformate[109-61-5]

16

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

164.63 g/mol
1.007 g/cm³ (20 °C)
min. 99.0
60 °C (9 hPa)
< –70 °C

H315; H330; H411
Danger

REACH;
TSCA;
IECSC

M
d
% (w/w)b.p.
m.p.

122.55 g/mol
1.09 g/cm³ (20 °C)
min. 99.0
106 °C< –70 °C

H225; H290; H302; H314;
H330; EUH071
Danger

REACH;TSCA;
IECSC;
ENCS/IS

Explanation of symbols
M = Mol. Weightd = Density% (w/w) = Purity/Content

Pictogramb.p. = Boiling Point

ChemicalInventory

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

17

2

Alcohols, Diols and Polyols

2.1

Mono Alcohols

No.

Product[CAS Registry No.]

2.1.1

1-Ethynyl-1-cyclohexanol[78-27-3]

2.1.2

2-Mercaptoethanol[60-24-2]

2.1.3

2-Methyl-3-butyn-2-ol[115-19-5]

2.1.4

3,7,11-Trimethyldodecyn-3-ol[1604-35-9]

2.1.5

3-Butyne-2-ol 55% sol.
[2028-63-9]

2.1.6

4-Ethyl-1-octyn-3-ol[5877-42-9]

2.1.7

Propargyl alcohol 50%[107-19-7]

18

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

124.18 g/mol
0.9760 g/cm³ (20 °C)
min. 99.0
179.75 °C
28 °C

H302; H311; H315; H319
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

78.14 g/mol
1.12 g/cm³ (20 °C)
min. 99.0
154 – 161 °C< –50 °C

H301; H310; H315; H317;
H318; H331; H373; H400;
H410
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

84.12 g/mol
0.86 g/cm³ (20 °C)
min. 98.5
102 – 105 °C
3 °C

H225; H302; H318
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

224.39 g/mol
0.849 g/cm³ (20 °C)
not available
145 °C (13 hPa)
–65 °C

H302; H315; H400; H410
Warning

REACH;IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

70.09 g/mol
0.95 g/cm³ (20 °C)
min. 55.0
95 – 96 °C–12 °C

H226; H301; H310; H315;
H319; H330; H412
Danger

REACH;
TSCA;
IECSC

M
d
% (w/w)b.p.
m.p.

154.25 g/mol
0.87 g/cm³ (20 °C)
min. 98.0
205 °C–45 °CH315; H318; H412
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

not available
0.9852 g/cm³ (20 °C)
48.0 – 52.0
97 °C
–18 °C

H226; H301; H310; H314;
H330; H411
DangerTSCA;
IECSC;
ENCS/IS

Explanation of symbols
M = Mol. Weightd = Density% (w/w) = Purity/Content

Pictogramb.p. = Boiling Point

ChemicalInventory

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

19

2.1

Mono Alcohols

No.

Product[CAS Registry No.]

2.1.8

Propargyl alcohol highly conc.
[107-19-7]

2.1.9

tert.-Amyl alcohol[75-85-4]

20

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

56.06 g/mol
0.949 g/cm³ (23 °C)
min. 99.3
114 – 115 °C–52 – –48 °C

H226; H301; H310; H314;
H330; H411
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

88.15 g/mol
0.806 g/cm³ (20 °C)
min. 99.0
102.4 °C
–8.4 °C

H225; H312; H315; H318;
H332; H335
Danger

REACH;TSCA;
IECSC;
ENCS/IS

Explanation of symbols
M = Mol. Weightd = Density% (w/w) = Purity/Content

Pictogramb.p. = Boiling Point

ChemicalInventory

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

21

2.2

Diols and Polyols

No.

Product[CAS Registry No.]

2.2.1

1,2-Pentanediol[5343-92-0]

2.2.2

1,4-Butanediol[110-63-4]

2.2.3

1,5-Pentanediol[111-29-5]

2.2.4

2,5-Dimethyl-2,5-hexanediol[110-03-2]

2.2.5

2-Butyne-1,4-diol pure cryst. unstab.
[110-65-6]

2.2.6

3-Hexyne-2,5-diol[3031-66-1]

2.2.7

Butane-2,3-diol[513-85-9]

22

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

104.15 g/mol
0.97 g/cm³ (20 °C)
min. 98.0
208 – 210 °C< –40 °C

H318
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

90.12 g/mol
1.02 g/cm³ (20 °C)
min. 99.5
230 °C
20.4 °C

H302; H336
Warning

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

104.15 g/mol
0.99 g/cm³ (20 °C)
min. 97.0
240 – 244 °C–16 °CMd% (w/w)b.p.
m.p.

146.23 g/mol
0.898 g/cm³ (20 °C)
min. 99.5
214 – 215 °C
87 – 89 °C

H319
Warning

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

86.09 g/mol
1.11 g/cm³ (20 °C)
min. 99.0
125 – 127 °C (3 hPa)
56 °C

H301; H311; H314; H317;
H331; H373
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

114.14 g/mol
0.996 g/cm³ (50 °C)
min. 95.0
230 °C
20 – 70 °C

H301; H315; H318; H412
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

90.12 g/mol
1.003 g/cm³ (20 °C)
min. 97.0
183 – 184 °C
20 °C

Explanation of symbols
M = Mol. Weightd = Density

PictogramChemicalInventory

TSCA;
IECSC;
ENCS/ISREACH;TSCA;
IECSC;
ENCS/IS% (w/w) = Purity/Content

b.p. = Boiling Point

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

23

2.2

Diols and Polyols

No.

Product[CAS Registry No.]

2.2.8

HDO® 1,6-Hexanediol flakes[629-11-8]

2.2.9

HDO® 1,6-Hexanediol molten[629-11-8]
Remark 1

2.2.10Hydroxypivalic acid neopentylglycolester
flakes[1115-20-4]

2.2.11

Hydroxypivalic acid neopentylglycolester
molten[1115-20-4]
Remark 1

2.2.12

Neol® Neopentylglycol flakes[126-30-7]

2.2.13Neol® Neopentylglycol pure liquid[126-30-7]
Remark 2

2.2.14

Neol® Neopentylglycol sol. 90% fix
calc. 100%
[126-30-7]

Remarks
1 Also available as flakes
2 Also available as flakes and 90% solution

24

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHS

PictogramChemicalInventoryMd% (w/w)b.p.
m.p.

118.18 g/mol
0.96 g/cm³ (20 °C)
min. 96.0
253 – 260 °C
40 – 42 °C

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

118.18 g/mol
0.96 g/cm³ (20 °C)
min. 96.0
253 – 260 °C
40 – 42 °C

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

204.27 g/mol
1.02 g/cm³ (67 °C)
min. 97.5
283.2 °C
46 – 50 °C

H318
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

204.27 g/mol
1.02 g/cm³ (67 °C)
min. 97.5
283.2 °C
46 – 50 °C

H318
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

104.15 g/mol
1.06 g/cm³ (20 °C)
min. 99.0
210 °C
127.5 – 129.6 °C

H318
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

104.15 g/mol
0.886 g/cm³ (150 °C)
min. 99.0
210 °C
125 – 130 °C

H318Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

104.15 g/mol
0.98 g/cm³ (40 °C)
89.5 – 90.5
118 – 210 °C< 35 °C

H318
Danger

REACH;TSCA;
IECSC;
ENCS/IS

Explanation of symbols
M = Mol. Weightd = Density% (w/w) = Purity/Content

b.p. = Boiling Point

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

25

2.2

Diols and Polyols

No.

Product[CAS Registry No.]

2.2.15

PolyTHF® 1000
[25190-06-1]

2.2.16

PolyTHF® 1000 S[25190-06-1]

2.2.17

PolyTHF® 1400
[25190-06-1]

2.2.18

PolyTHF® 1800
[25190-06-1]

2.2.19

PolyTHF® 2000
[25190-06-1]

2.2.20

PolyTHF® 250 techn.
[25190-06-1]

2.2.21

PolyTHF® 650 S[25190-06-1]

26

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHS

PictogramChemicalInventoryMd% (w/w)b.p.
m.p.

1000 g/mol
0.982 g/cm³ (30 °C)
min. 99.9> 250 °C
26 °C

TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

1000 g/mol
0.982 g/cm³ (30 °C)
min. 99.9> 250 °C
26 °C

TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

1400 g/mol
0.9872 g/cm³ (20 °C)
min. 99.9> 250 °C
26 – 36 °C

TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

1800 g/mol
0.975 g/cm³ (40 °C)
min. 99.9> 250 °C
27 °C

TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

2000 g/mol
0.973 g/cm³ (40 °C)
min. 99.9> 250 °C
36 °C

TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

250 g/mol
1.00 g/cm³ (20 °C)
min. 99.9> 250 °C
–14 °C

H412

TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

650 g/mol
0.987 g/cm³ (25 °C)
min. 99.9> 250 °C
25 °C

H412

TSCA;
IECSC;
ENCS/IS

Explanation of symbols
M = Mol. Weightd = Density% (w/w) = Purity/Content

b.p. = Boiling Point

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

27

2.2

Diols and Polyols

No.

Product[CAS Registry No.]2.2.22

Thiodiglycol[111-48-8]

2.2.23

Thiodiglycol HP[111-48-8]

2.2.24

Thiodiglycol ultra[111-48-8]

2.2.25TMDD 100%[126-86-3]

2.2.26

TMDD 440[9014-85-1]

2.2.27TMDD 50% BG[126-86-3]

28

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

122.19 g/mol
1.18 g/cm³ (20 °C)
min. 95.0
284 °C–18 °C

H319
Warning

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

122.19 g/mol
1.18 g/cm³ (20 °C)
min. 98.5
284 °C–18 °C

H319
Warning

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

122.19 g/mol
1.18 g/cm³ (20 °C)
min. 99.0
284 °C–18 °C

H319
Warning

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

226.36 g/mol
0.89 g/cm³ (25 °C)
min. 98.0
262 °C< 55 °C

H318; H412
DangerTSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

not available
0.98 g/cm³ (21 °C)
not available
291 °C
not available

H319; H411
Warning

TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

not available
0.9076 g/cm³ (15 °C)
50.0 – 54.0
not available
not available

H302; H312; H315; H318;
H332; H412
DangerTSCA;
IECSC;
ENCS/IS

Explanation of symbols
M = Mol. Weightd = Density% (w/w) = Purity/Content

Pictogramb.p. = Boiling Point

ChemicalInventory

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

29

2.2

Diols and Polyols

No.

Product[CAS Registry No.]2.2.28TMDD 50% EG[126-86-3]

2.2.29TMDD 50% PG[126-86-3]

30

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

not available
1 g/cm³ (20 °C)
47.0 – 51.0
196 – 200 °C< –20 °C

H302; H318; H373; H412
DangerTSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

not available
0.963 g/cm³ (20 °C)
47.0 – 51.0
186 – 190 °C< –20 °C

H318; H412
DangerTSCA;
IECSC;
ENCS/IS

Explanation of symbols
M = Mol. Weightd = Density% (w/w) = Purity/Content

Pictogramb.p. = Boiling Point

ChemicalInventory

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

31

3

Aldehydes, Acetals and Ketones

3.1

AcetalsNo.

Product[CAS Registry No.]

3.1.1

1,1-Dimethoxy-N,N-dimethyl
methanamine[4637-24-5]

32

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

H225; H317; H318; H332;
H360D
Danger

119.16 g/mol
0.90 g/cm³ (20 °C)
min. 96.0
104 – 108 °C–85 °C

Explanation of symbols
M = Mol. Weightd = Density% (w/w) = Purity/Content

Pictogramb.p. = Boiling Point

ChemicalInventory
REACH;TSCA;
IECSC;
ENCS/IS

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

33

3.2

Aldehydes

No.

Product[CAS Registry No.]

3.2.1

2-Ethylhexanal[123-05-7]

3.2.2

2-Methylpentanal[123-15-9]

3.2.3

3-Formylpinan raw[60113-43-1]

3.2.4

Glutaraldehyde 24% sol.
[111-30-8]

3.2.5

Glutaraldehyde 50% solution low
methanol[111-30-8]

3.2.6

Glyoxal 40%[107-22-2]

34

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

128.21 g/mol
0.822 g/cm³ (20 °C)
min. 97.0
162 °C–85 °C

H226; H315; H317; H319;
H361d
Warning

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

100.16 g/mol
0.81 g/cm³ (20 °C)
min. 98.0
118 °C–100 °C

H225; H315; H319; H412
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

not available
0.9292 g/cm³ (20 °C)
min. 50.0
155 – 235 °C< –50 °C

H226; H302; H315; H317;
H319; H411
Warning

TSCA;
IECSC

M
d
% (w/w)b.p.
m.p.

100.12 g/mol
not available
23.5 – 24.5
101.5 °C
–5 °C

H290; H302; H314; H317;
H332; H334
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

100.12 g/mol
1.13 g/cm³ (20 °C)
50.0 – 51.0
101.5 °C
–33 °CH290; H301; H314; H317;
H331; H334; H400
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

58.04 g/mol
1.27 g/cm³ (20 °C)
39.5 – 40.5
103.6 °C
–50 – –15 °C

H315; H317; H319; H332;
H335; H341
Warning

REACH;TSCA;
IECSC;
ENCS/IS

Explanation of symbols
M = Mol. Weightd = Density% (w/w) = Purity/Content

Pictogramb.p. = Boiling Point

ChemicalInventory

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

35

3.3

KetonesNo.

Product[CAS Registry No.]

3.3.1

Cyclododecanone[830-13-7]

3.3.2

Cyclododecanone F[830-13-7]

3.3.3

Cyclopentanone[120-92-3]

3.3.4

Cyclopentanone P[120-92-3]
Remark 1

3.3.5

Diethylketone[96-22-0]

Remarks
1 Also available in drums (180 kg)

36

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

182.31 g/mol
0.9700 g/cm³ (20 °C)
min. 99.0
277 °C
61 °C

H411

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

182.31 g/mol
0.9700 g/cm³ (20 °C)
min. 99.0
277 °C
61 °C

H411

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

84.12 g/mol
0.945 g/cm³ (20 °C)
min. 99.0
131 °C–51 °C

H226; H315; H319
Warning

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

84.12 g/mol
0.945 g/cm³ (20 °C)
min. 99.0
131 °C–51 °C

H226; H315; H319
Warning

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

86.13 g/mol
0.815 g/cm³ (20 °C)
min. 99.0
101 – 102 °C–39 °CH225; H319; H335; H336;
EUH066Danger

REACH;TSCA;
IECSC;
ENCS/IS

Explanation of symbols
M = Mol. Weightd = Density% (w/w) = Purity/Content

Pictogramb.p. = Boiling Point

ChemicalInventory

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

37

4Amines4.1

Aliphatic Monoamines

No.

Product[CAS Registry No.]

4.1.1

2-Ethylhexylamine[104-75-6]

4.1.2

Butylamine[109-73-9]4.1.3

Di-(2-ethylhexyl)amine[106-20-7]

4.1.4

Dibutylamine[111-92-2]

4.1.5

Dicyclohexylamine[101-83-7]

4.1.6

Diethylamine[109-89-7]

4.1.7

Dimethylamine anhydrous[124-40-3]
Remark 1

Remarks
1 Also available as aqueous solution in different concentrations

38

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

129.25 g/mol
0.78 g/cm³ (20 °C)
min. 99.0
169.8 °C
< –70 °C

H226; H302; H311; H314;
H330
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

73.14 g/mol
0.736 g/cm³ (20 °C)
min. 99.5
77 °C–47 °CH225; H290; H302; H311;
H314; H331; H335
DangerTSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

241.46 g/mol
0.803 g/cm³ (20 °C)
min. 99.0
281.1 °C
< –70 °C

H302; H311; H314; H331;
H411
DangerTSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

129.25 g/mol
0.7577 g/cm³ (22.9 °C)
min. 99.5
160 °C–62 °C

H226; H302; H311; H314;
H330
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

181.32 g/mol
0.912 g/cm³ (20 °C)
min. 99.0
256 °C–0.1 °C

H301; H314; H411
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

73.14 g/mol
0.71 g/cm³ (20 °C)
min. 99.5
53.5 – 56.1 °C–50 °CH225; H302; H311; H314;
H332; H335
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

45.08 g/mol
0.67 g/cm³ (7 °C)
min. 99.5
7 °C–92.2 °C

H220; H280; H315; H318;
H332; H335; H412
Danger

REACH;TSCA;
IECSC;
ENCS/IS

Explanation of symbols
M = Mol. Weightd = Density% (w/w) = Purity/Content

Pictogramb.p. = Boiling Point

ChemicalInventory

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

39

4.1

Aliphatic Monoamines

No.

Product[CAS Registry No.]

4.1.8

Dimethylethylamine[598-56-1]

4.1.9

Dimethylpropylamine[926-63-6]

4.1.10

Dipropylamine[142-84-7]

4.1.11

Ditridecylamine mixture of isomers[101012-97-9]

4.1.12Ethylamine solution 70%[75-04-7]

4.1.13Isopropylamine anhydrous[75-31-0]

4.1.14

Lupragen® N 100 –N,N-Dimethylcyclohexylamine[98-94-2]

40

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

73.14 g/mol
0.68 g/cm³ (20 °C)
min. 99.5
36.5 °C–140 °C

H225; H302; H314; H331
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

87.16 g/mol
0.7081 g/cm³ (20 °C)
min. 98.0
65.75 °C
< –20 °C

H225; H302; H315; H318;
H331; H412
Danger

REACH;
TSCA;
IECSC

M
d
% (w/w)b.p.
m.p.

101.19 g/mol
0.738 g/cm³ (20 °C)
min. 99.0
109.3 °C
–40 °CH225; H302; H311; H314;
H331; H335
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

not available
0.836 g/cm³ (20 °C)
min. 90.0
220 – 240 °C (10 hPa)
< –45 °C

H314; H412
Danger

REACH;
ENCS/ISMd% (w/w)b.p.
m.p.

45.08 g/mol
0.8 g/cm³ (20 °C)
min. 99.8
39 °C< –70 °C

H225; H302; H311; H314;
H335
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

59.11 g/mol
0.6871 g/cm³ (20 °C)
min. 99.5
32 °C< –90 °C

H224; H315; H319; H335
DangerTSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

127.23 g/mol
0.85 g/cm³ (20 °C)
min. 99.0
162.3 °C
< –77 °C

H226; H301; H311; H314;
H331
Danger

REACH;TSCA;
IECSC;
ENCS/IS

Explanation of symbols
M = Mol. Weightd = Density% (w/w) = Purity/Content

Pictogramb.p. = Boiling Point

ChemicalInventory

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

41

4.1

Aliphatic Monoamines

No.

Product[CAS Registry No.]

4.1.15

Monomethylamine anhydrous[74-89-5]
Remark 1

4.1.16

N,N-Dimethylisopropylamine[996-35-0]

4.1.17

N-Ethyldiisopropylamine[7087-68-5]

4.1.18N-Ethyl-N-propylamine azeotrope[20193-20-8]

4.1.19

N-Methyl-N-isopropylamine[4747-21-1]

4.1.20N-Octylamine[111-86-4]

4.1.21

Propylamine[107-10-8]

Remarks
1 Also available as aqueous solution

42

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

31.06 g/mol
1.384 kg/m³ (0 °C)
min. 99.5–6.5 °C–92.5 °C

H220; H280; H315; H318;
H331; H335
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

87.16 g/mol
0.72 g/cm³ (20 °C)
min. 99.0
66.25 °C
< –70 °C

H225; H302; H314; H331;
H411
Danger

REACH;
TSCA;
IECSC

M
d
% (w/w)b.p.
m.p.

129.25 g/mol
0.7561 g/cm³ (20 °C)
min. 99.5
127 °C–127 °C

H225; H302; H314; H402;
H412
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

87.16 g/mol
0.776 g/cm³ (22.7 °C)
min. 99.0
83 °C–75 °CH225; H302; H314
Danger

REACH;
TSCA;
IECSC

M
d
% (w/w)b.p.
m.p.

73.14 g/mol
0.704 g/cm³ (20 °C)
min. 99.0
50 – 53 °C< –40 °C

H225; H301; H314; H331
DangerREACH

Md% (w/w)b.p.
m.p.

129.25 g/mol
0.779 g/cm³ (25 °C)
min. 99.0
178.49 °C–1 °C

H226; H302; H312; H314;
H332; H400
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

59.11 g/mol
0.72 g/cm³ (20 °C)
min. 99.5
47.2 °C–83 °CH225; H290; H302; H311;
H314; H331
Danger

REACH;TSCA;
IECSC;
ENCS/IS

Explanation of symbols
M = Mol. Weightd = Density% (w/w) = Purity/Content

Pictogramb.p. = Boiling Point

ChemicalInventory

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

43

4.1

Aliphatic Monoamines

No.

Product[CAS Registry No.]

4.1.22

tert.-Butylamine[75-64-9]

4.1.23

Tributylamine[102-82-9]
Remark 1

4.1.24

Tridecylamine mixture of isomers[86089-17-0]

4.1.25Triethylamine anhydrous[121-44-8]

4.1.26

Trimethylamine anhydrous[75-50-3]

4.1.27

Trimethylaminehydrochloride sol. 70%[593-81-7]

4.1.28Tripropylamine[102-69-2]
Remark 1

Remarks
1 Also available as high purity special grade

44

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

73.14 g/mol
0.7008 g/cm³ (15 °C)
min. 99.5
45.2 °C–68 – –67.5 °C

H225; H302; H314; H331;
H412
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

185.35 g/mol
0.78 g/cm³ (20 °C)
min. 99.0
215 °C< –70 °C

H302; H310; H315; H330
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

not available
0.818 g/cm³ (20 °C)
min. 97.0
248 – 255 °C< –70 °C

H302; H314; H400; H410
Danger

REACH;IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

101.19 g/mol
0.7275 g/cm³ (20 °C)
min. 99.0
89.3 °C–114.7 °C

H225; H302; H311; H314;
H332; H335
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

59.11 g/mol
0.258 g/l (not available)
min. 99.5
2.87 °C–117.1 °C

H220; H280; H315; H318;
H332; H335
DangerTSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

95.57 g/mol
1.03 g/cm³ (20 °C)
min. 70.0
130 °C
1 – 8 °C

H319
Warning

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

143.27 g/mol
0.76 g/cm³ (20 °C)
min. 98.0
156.5 °C
–93.5 °C

H226; H302; H311; H314;
H330; H412
Danger

REACH;TSCA;
IECSC;
ENCS/IS

Explanation of symbols
M = Mol. Weightd = Density% (w/w) = Purity/Content

Pictogramb.p. = Boiling Point

ChemicalInventory

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

45

4.1

Aliphatic Monoamines

No.

Product[CAS Registry No.]

4.1.29Tris-(2-ethylhexyl)amine[1860-26-0]

46

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)
b.p.
m.p.

H413

353.68 g/mol
0.8174 g/cm³ (20 °C)
min. 99.0
204 – 211 °C (30 hPa)
–48.6 °C

Explanation of symbols
M = Mol. Weightd = Density% (w/w) = Purity/Content

PictogramChemicalInventory
REACH;TSCA;
IECSC;
ENCS/ISb.p. = Boiling Point

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

47

4.2

Aliphatic Diamines

No.

Product[CAS Registry No.]

4.2.1

1,2-Propylenediamine techn.
[78-90-0]
Remark 1

4.2.2

1,3-Diaminopropane[109-76-2]

4.2.3

2-(Diethylamino)ethylamine[100-36-7]

4.2.4

2-(Diisopropylamino)ethylamine[121-05-1]

4.2.5

3-(Cyclohexylamino)propylamine[3312-60-5]
Remark 2

4.2.6

3-(Diethylamino)propylamine[104-78-9]4.2.7

3-(Dimethylamino)propylamine[109-55-7]

Remarks
1 Also available as solution on request
2 Marketed as Baxxodur® EC 252 for epoxy applications

48

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

74.13 g/mol
0.86 g/cm³ (20 °C)
min. 99.0
119 – 121 °C–37 °C

H226; H302; H311; H314;
H412
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

74.1 g/mol
0.89 g/cm³ (20 °C)
min. 99.0
140 °C–12 °C

H226; H290; H302; H310;
H314; H317
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

116.21 g/mol
0.819 g/cm³ (20 °C)
min. 99.0
144 °C< –70 °C

H226; H290; H302; H311;
H314
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

144.26 g/mol
0.825 g/cm³ (20 °C)
min. 99.0
179 – 180 °C–30 °C

H226; H302; H314
Danger

REACH;
TSCA;
IECSC

M
d
% (w/w)b.p.
m.p.

156.27 g/mol
not available
min. 99.0
236 °C–16 °C

H302; H314; H317; H412
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

130.23 g/mol
0.826 g/cm³ (20 °C)
min. 99.0
170 °C< –60 °C

H226; H302; H311; H314;
H317
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

102.18 g/mol
0.818 g/cm³ (20 °C)
min. 99.8
134 °C< –50 °C

H226; H302; H311; H314;
H317; H331
Danger

REACH;TSCA;
IECSC;
ENCS/IS

Explanation of symbols
M = Mol. Weightd = Density% (w/w) = Purity/Content

Pictogramb.p. = Boiling Point

ChemicalInventory

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

49

4.2

Aliphatic Diamines

No.

Product[CAS Registry No.]

4.2.8

3,3'-Dimethyl-4,4'-diaminodicyclohexylmethane[6864-37-5]

4.2.9

4,4'-Diaminodicyclohexylmethane[1761-71-3]

4.2.10Baxxodur® ECX 210

4.2.11

Baxxodur® PC 136[93940-97-7]

4.2.12Ethylenediamine[107-15-3]

4.2.13Isophorone diamine[2855-13-2]
Remark 1

Remarks
1 Marketed as Baxxodur® EC 201 for epoxy applications

50

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

238.42 g/mol
0.9456 g/cm³ (20 °C)
min. 99.6
347 °C–7.1 °C

H302; H311; H314; H330;
H411
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

210.36 g/mol
0.93 g/cm³ (60 °C)
min. 99.0
329.76 °C
33.5 – 44 °C

H302; H314; H411
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

128.22 g/mol
0.9395 g/cm³ (20 °C)
min. 99.0
210 °C–92 °C

H302; H314; H317; H412
Danger

REACH;
TSCA;
IECSC

M
d
% (w/w)b.p.
m.p.

276.4 g/mol
0.9878 g/cm³ (20 °C)
min. 95.0> 200 °C
< –20 °C

H302; H317; H412
Warning

REACH;
TSCA;
IECSC

M
d
% (w/w)b.p.
m.p.

60.10 g/mol
897 g/cm³ (20 °C)
min. 99.5
117.1 °C
11.1 °C

H226; H302; H311; H314;
H317; H334
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

170.30 g/mol
0.92 g/cm³ (20 °C)
min. 99.7
247 °C
10 °C

H302; H312; H314; H317;
H412
DangerTSCA;
IECSC;
ENCS/IS

Explanation of symbols
M = Mol. Weightd = Density% (w/w) = Purity/Content

Pictogramb.p. = Boiling Point

ChemicalInventory

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

51

4.2

Aliphatic Diamines

No.

Product[CAS Registry No.]

4.2.14

Lupragen® N 500 – Tetramethyl1,6-hexanediamine[111-18-2]

4.2.15

N,N,N',N'-Tetramethyl-1,3-propane
diamine[110-95-2]

4.2.16

Neopentanediamine (2,2-Dimethyl
propane-1,3-diamine)[7328-91-8]

4.2.17

Octamethylenediamine[373-44-4]

52

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

172.31 g/mol
0.803 g/cm³ (20 °C)
min. 99.0
212 – 216 °C–46 °C

H302; H314; H330; H411
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

130.23 g/mol
0.78 g/cm³ (20 °C)
min. 99.0
144 – 148 °C< –70 °C

H226; H302; H312; H314;
H331; H412
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

102.18 g/mol
0.85 g/cm³ (40 °C)
min. 97.5
153 °C
28 – 30 °C

H226; H302; H312; H314;
H317
Danger

REACH;
TSCA;
IECSC

M
d
% (w/w)b.p.
m.p.

144.26 g/mol
0.827 g/cm³ (60 °C)
min. 99.0
237 – 238 °C
51 °C

H302; H314; H317
Danger

REACH;IECSC;
ENCS/IS

Explanation of symbols
M = Mol. Weightd = Density% (w/w) = Purity/Content

Pictogramb.p. = Boiling Point

ChemicalInventory

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

53

4.3

Aliphatic Oligoamines

No.

Product[CAS Registry No.]

4.3.1

AMIX 1000[68910-05-4]
Remark 1

4.3.2

AMIX A
[92731-41-4]
Remark 1

4.3.3

Diethylenetriamine[111-40-0]

4.3.4

Dipropylene triamine[56-18-8]
Remark 2

4.3.5

Lupragen® N 301 – Pentamethyldietylenetriamine[3030-47-5]

4.3.6

N,N-Bis-(3-aminopropyl)methylamine[105-83-9]

4.3.7

N3-Amine 3-(2-Aminoethylamino)
propylamine[13531-52-7]

Remarks
1 Ethyleneamines mixture
2 Marketed as Baxxodur® EC 110 for epoxy applications

54

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

not available
1.034 g/cm³ (20 °C)
not available
236 – 310 °C–30 °C

H314; H317; H331; H335;
H360FD; H410
Danger

REACH;
TSCA;
IECSC

M
d
% (w/w)b.p.
m.p.

not available
0.980 g/cm³ (20 °C)
not available> 200 °C
< –20 °C

H302; H311; H314; H317;
H360FD; H412
Danger

REACH;
TSCA;
IECSC

M
d
% (w/w)b.p.
m.p.

103.17 g/mol
0.9586 g/cm³ (20 °C)
min. 98.5
206 °C–39 °C

H302; H311; H314; H317;
H330; H335
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

131.22 g/mol
0.928 g/cm³ (20 °C)
min. 99.0
239 °C–16 °CH290; H302; H311; H314;
H317; H330; H412
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

173.30 g/mol
0.830 g/cm³ (20 °C)
min. 98.0
199 °C< –20 °C

H302; H311; H314
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

145.25 g/mol
0.904 g/cm³ (20 °C)
min. 99.0
235 °C< –35 °C

H302; H310; H314; H330
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

117.19 g/mol
0.93 g/cm³ (20 °C)
min. 99.0
221 °C
10 °C

H302; H310; H314; H412
Danger

REACH;TSCA;
IECSC;
ENCS/IS

Explanation of symbols
M = Mol. Weightd = Density% (w/w) = Purity/Content

Pictogramb.p. = Boiling Point

ChemicalInventory

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

55

4.3

Aliphatic Oligoamines

No.

Product[CAS Registry No.]

4.3.8

N4-Amine N,N'-Bis-(3-Aminopropyl)
ethylenediamine[10563-26-5]

56

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

H302; H310; H314; H317;
H412
Danger174.29 g/mol
0.95 g/cm³ (20 °C)
min. 93.0> 169 °C
–1.5 °C

Explanation of symbols
M = Mol. Weightd = Density% (w/w) = Purity/Content

Pictogramb.p. = Boiling Point

ChemicalInventory
REACH;TSCA;
IECSC

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

57

4.4

Etheramines

No.

Product[CAS Registry No.]

4.4.1

2-Methoxyethylamine[109-85-3]

4.4.2

3-Methoxypropylamine[5332-73-0]

4.4.3

4,7,10-Trioxatridecane-1,13-diamine[4246-51-9]
Remark 1

4.4.4

4,9-Dioxadodecane-1,12-diamine[7300-34-7]
Remark 2

4.4.5

Di-(2-methoxyethyl)amine[111-95-5]

4.4.6

Lupragen® N 205 – Bis(2-dimethylaminoethyl)ether[3033-62-3]

4.4.7

Polyetheramine D 2000
[9046-10-0]
Remark 3

Remarks
1 Marketed as Baxxodur® EC 130 for epoxy applications
2 Marketed as Baxxodur® EC 280 for epoxy applications
3 Marketed as Baxxodur® EC 303 for epoxy applications

58

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

75.11 g/mol
0.871 g/cm³ (20 °C)
min. 98.5
90.4 °C< –70 °C

H225; H302; H312; H314
Danger

REACH;
TSCA;
IECSC

M
d
% (w/w)b.p.
m.p.

89.14 g/mol
0.8761 g/cm³ (15 °C)
min. 99.0
116 °C< –70 °C

H226; H302; H314; H317;
H412
DangerTSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

220.31 g/mol
1.01 g/cm³ (20 °C)
min. 98.0
146 – 148 °C (1 hPa)
–32 °C

H314
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

204.31 g/mol
0.956 g/cm³ (20 °C)
min. 98.5
298 °C
4.5 °C

H314; H332
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

133.19 g/mol
0.911 g/cm³ (20 °C)
min. 98.5
169 – 173 °C< –60 °C

H226; H312; H314
Danger

REACH;
TSCA;
IECSC

M
d
% (w/w)b.p.
m.p.

160.26 g/mol
0.853 g/cm³ (20 °C)
min. 97.0
188 °C< –80 °C

H302; H311; H314; H332;
H412
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

2.000 g/mol
0.9943 g/cm³ (20 °C)
min. 97.0> 250 °C
–29 °C

H302; H314; H412
DangerTSCA;
IECSC;
ENCS/IS

Explanation of symbols
M = Mol. Weightd = Density% (w/w) = Purity/Content

Pictogramb.p. = Boiling Point

ChemicalInventory

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

59

4.4

Etheramines

No.

Product[CAS Registry No.]

4.4.8

Polyetheramine D 230[9046-10-0]

FormulaRemark 1

4.4.9

Polyetheramine D 400[9046-10-0]
Remark 2

4.4.10Polyetheramine T 403[39423-51-3]
Remark 3

4.4.11Polyetheramine T 5000
[64852-22-8]
Remark 4

Remarks
1 Marketed as Baxxodur® EC 301 for epoxy applications
2 Marketed as Baxxodur® EC 302 for epoxy applications
3 Marketed as Baxxodur® EC 310 for epoxy applications (available in all regions except Europe)
4 Marketed as Baxxodur® EC 311 for epoxy applications

60

Physical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

not available
0.9476 g/cm³ (20 °C)
min. 97.0> 200 °C
–88 °C

H302; H312; H314; H412
DangerTSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

not available
0.97 g/cm³ (20 °C)
min. 97.0> 200 °C
< –40 °C

H302; H312; H314; H412
DangerTSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

not available
0.987 g/cm³ (20 °C)
not available> 250 °C
< –20 °C

H301; H315; H318; H412
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

not available
0.998 g/cm³ (20 °C)
min. 97.0> 200 °C
–50 °CH315; H318
DangerTSCA;
IECSC;
ENCS/IS

Explanation of symbols
M = Mol. Weightd = Density% (w/w) = Purity/Content

Pictogramb.p. = Boiling Point

ChemicalInventory

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

61

4.5

Polyurethane Catalysts (Lupragens)No.

Product[CAS Registry No.]

4.5.1

Lupragen® N 100 –N,N-Dimethylcyclohexylamine[98-94-2]

4.5.2

Lupragen® N 101 – Dimethylethanolamine[108-01-0]

4.5.3

Lupragen® N 105 – N-Methylmorpholine[109-02-4]
Remark 1

4.5.4

Lupragen® N 106 –
2,2'-Dimorpholinodiethylether[6425-39-4]

4.5.5

Lupragen® N 107 –Dimethylaminoethoxyethanol[1704-62-7]

4.5.6

Lupragen® N 201 – Triethylenediamine indipropyleneglycol[280-57-9]
Remark 2

4.5.7

Lupragen® N 203 – Triethylendiamine inmonoethyleneglycol[280-57-9]
Remark 2

Remarks
1 Methylmorpholine P is available for pharma applications
2 Exclusively marketed by Evonik Industries AG

62

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

127.23 g/mol
0.85 g/cm³ (20 °C)
min. 99.0
162.3 °C
< –77 °C

H226; H301; H311; H314;
H331
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

89.14 g/mol
0.887 g/cm³ (20 °C)
min. 99.8
134.1 °C
–59 °C

H226; H302; H312; H314;
H331; H335
DangerTSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

101.15 g/mol
0.82 g/cm³ (20 °C)
min. 99.0
115 °C–65 °CH225; H312; H314
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

244.33 g/mol
1.0603 g/cm³ (20 °C)
min. 99.0309 °C–28 °CH315; H319
Warning

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

133.19 g/mol
0.9549 g/cm³ (20 °C)
min. 98.0
203.5 °C
< –70 °C

H314
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

not available
1.025 g/cm³ (20 °C)
33.1 – 33.5
not available–39 °C

H302; H315; H318
DangerTSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

not available
1.09 g/cm³ (25 °C)
33.1 – 33.5
196 °C–67 °C

H302; H315; H318; H335
DangerTSCA;
IECSC;
ENCS/IS

Explanation of symbols
M = Mol. Weightd = Density% (w/w) = Purity/Content

Pictogramb.p. = Boiling Point

ChemicalInventory

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

63

4.5

Polyurethane Catalysts (Lupragens)No.

Product[CAS Registry No.]

4.5.8

Lupragen® N 205 –Bis(2-dimethylaminoethyl)ether[3033-62-3]

4.5.9

Lupragen® N 301 –Pentamethyldietylenetriamine[3030-47-5]

4.5.10

Lupragen® N 400 –Trimethylaminoethylethanolamine[2212-32-0]

4.5.11

Lupragen® N 500 –Tetramethyl-1,6-hexanediamine[111-18-2]

4.5.12

Lupragen® N 600 – S-Triazine[15875-13-5]

4.5.13

Lupragen® N 700 –
1,8-Diazabicyclo-5,4,0-undecene-7[6674-22-2]
Remark 1

Remarks
1 Diazabicycloundecene P is available for pharma applications

64

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

160.26 g/mol
0.853 g/cm³ (20 °C)
min. 97.0
188 °C< –80 °C

H302; H311; H314; H332;
H412
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

173.30 g/mol
0.830 g/cm³ (20 °C)
min. 98.0
199 °C< –20 °C

H302; H311; H314
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

146.23 g/mol
0.914 g/cm³ (15 °C)
min. 98.5
210 °C< –70 °C

H315; H318
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

172.31 g/mol
0.803 g/cm³ (20 °C)
min. 99.0
212 – 216 °C–46 °C

H302; H314; H330; H411
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

342.57 g/mol
0.91 g/cm³ (25 °C)
not available
225 °C–59 °CH312; H315; H318
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

152.24 g/mol
1.019 g/cm³ (20 °C)
min. 98.0
261.86 °C–70 °C

H302; H314; H412
Danger

REACH;TSCA;
IECSC;
ENCS/IS

Explanation of symbols
M = Mol. Weightd = Density% (w/w) = Purity/Content

Pictogramb.p. = Boiling Point

ChemicalInventory

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

65

4.6

Aromatic Amines and Nitro Compounds

No.

Product[CAS Registry No.]

4.6.1

2,6-Xylidine[87-62-7]

4.6.2

2-Phenylethylamine[64-04-0]

4.6.3

4,4'-Diaminodiphenylmethane moltenplus[101-77-9]

4.6.4

Aniline[62-53-3]

4.6.5

Anthranilic acid amide dry[88-68-6]

4.6.6

Benzylamine[100-46-9]

4.6.7

Diethanol-para-toluidine[3077-12-1]

66

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

121.18 g/mol
0.96 g/cm³ (20 °C)
min. 99.5
216 °C11.2 °C

H302; H312; H315; H319;
H332; H335; H351; H411
Warning

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

121.18 g/mol
0.985 g/cm³ (25 °C)
min. 99.0
200 – 202 °C< –60 °C

H301; H314
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

198.27 g/mol
1.08 g/cm³ (96 °C)
min. 96.5
398 °C
90 °C

H317; H341; H350; H370;
H373; H410
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

93.13 g/mol
1.02 g/cm³ (20 °C)
min. 99.9
184.1 °C
–6 °C

H301; H311; H317; H318;
H331; H341; H351; H372;
H400
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

136.15 g/mol
not available
min. 99.0
not available
107 – 111 °C

H318
Danger

REACH;
TSCA;
IECSC

M
d
% (w/w)b.p.
m.p.

107.16 g/mol
0.983 g/cm³ (19 °C)
min. 99.0
182 – 185 °C–42.8 °C

H302; H312; H314; H411
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

195.26 g/mol
1.107 g/cm³ (20 °C)
not available> 200 °C
< –10 °C

H302; H312; H318; H412
Danger

REACH;TSCA;
IECSC;
ENCS/IS

Explanation of symbols
M = Mol. Weightd = Density% (w/w) = Purity/Content

Pictogramb.p. = Boiling Point

ChemicalInventory

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

67

4.6

Aromatic Amines and Nitro Compounds

No.

Product[CAS Registry No.]

4.6.8

Diethanol-para-toluidine in MMA, 50 : 50

4.6.9

Diisopropanol-p-toluidine[38668-48-3]

4.6.10N-(2-Hydroxyethyl)aniline[122-98-5]

4.6.11

N,N-Di-(2-hydroxyethyl)aniline[120-07-0]

4.6.12N-Ethyl-N-(2-hydroxyethyl)aniline[92-50-2]

4.6.13o-Toluidine pure[95-53-4]

68

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

not available
1.026 g/cm³ (20 °C)
50.0
not available
not available

H225; H315; H317; H318;
H335
DangerTSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

223.32 g/mol
0.99 g/cm³ (80 °C)
min. 96.0> 300 °C
65 – 72 °C

H300; H318; H412
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

137.18 g/mol
1.0954 g/cm³ (20 °C)
min. 99.0
278 °C–32 °C

H301; H311; H318; H373
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

181.23 g/mol
1.1 g/cm³ (60 °C)
min. 95.0
380 °C57.8 °C

H317; H318; H412
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

not available
1.03 g/cm³ (40 °C)
min. 98.0
270 °C
15 °C

H302; H317; H318
DangerTSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

107.16 g/mol
1.00 g/cm³ (20 °C)
min. 99.5
200 – 201 °C–23 °C

H301; H315; H317; H319;
H331; H350; H400
Danger

REACH;TSCA;
IECSC;
ENCS/IS

Explanation of symbols
M = Mol. Weightd = Density% (w/w) = Purity/Content

Pictogramb.p. = Boiling Point

ChemicalInventory

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

69

4.6

Aromatic Amines and Nitro Compounds

No.

Product[CAS Registry No.]

4.6.14p-Nitrotoluene pure[99-99-0]70

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

H301; H311; H331; H373;
H411
Danger137.14 g/mol
1.29 g/cm³ (20 °C)
min. 99.5
238 °C51.3 °C

Explanation of symbols
M = Mol. Weightd = Density% (w/w) = Purity/Content

Pictogramb.p. = Boiling Point

ChemicalInventory
REACH;TSCA;
IECSC;
ENCS/IS

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

71

4.7

AMIX

No.

Product[CAS Registry No.]

4.7.1

AMIX 1000[68910-05-4]

FormulaRemark 1

4.7.2

AMIX A
[92731-41-4]
Remark 1

4.7.3

AMIX M[68909-77-3]
Remark 2

4.7.4

AMIX TE[68953-70-8]
Remark 3

4.7.5

AMIX TI solution[122-20-3]
Remark 4

Remarks
1 Ethyleneamines mixture
2 High boiling morpholine derivatives
3 Min. 75% Triethanolamine (GC)
4 Solution of Triisopropanolamine technical grade, Diisopropanolamine and water72

Physical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

not available
1.034 g/cm³ (20 °C)
not available
236 – 310 °C–30 °C

H314; H317; H331; H335;
H360FD; H410
Danger

REACH;
TSCA;
IECSC

M
d
% (w/w)b.p.
m.p.

not available
0.980 g/cm³ (20 °C)
not available> 200 °C
< –20 °C

H302; H311; H314; H317;
H360FD; H412
Danger

REACH;
TSCA;
IECSC

M
d
% (w/w)b.p.
m.p.

not available
1.0993 g/cm³ (20 °C)
not available
266 – 330 °C–65 °CH315; H317; H318
Danger

REACH;
TSCA;
IECSC

M
d
% (w/w)b.p.
m.p.

not available
1.161 g/cm³ (20 °C)
min. 75.0> 360 °C
< 0 °CMd% (w/w)b.p.
m.p.

191.27 g/mol
1.0318 g/cm³ (20 °C)
not available
100 – 370 °C
0 °C

Explanation of symbols
M = Mol. Weightd = Density

PictogramChemicalInventory

REACH;TSCA;
IECSC

REACH;TSCA;
IECSC;
ENCS/IS

H319; H412
Warning% (w/w) = Purity/Content

b.p. = Boiling Point

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

73

5

Amino Alcohols

5.1

Ethanolamines

No.

Product[CAS Registry No.]

5.1.1

AMIX TE[68953-70-8]

FormulaRemark 1

5.1.2

Diethanolamine pure
[111-42-2]
Remark 2

5.1.3

Ethanolamine mixtures (anhydrous)
Remark 3

5.1.4

Monoethanolamine pure[141-43-5]
Remark 4

5.1.5

Triethanolamine pure[102-71-6]
Remark 5

5.1.6

Triethanolamine S[102-71-6]

Remarks
1 Min. 75% Triethanolamine (GC)
2 Also available as aqueous solution in different concentrations (lower freezing points for easier handling)
3 Composition on request
4 Also available as electronic grade, as personal care grade and as aqueous solution in different concentrations(lower freezing points for easier handling)
5 Also available as personal care grade and as aqueous solution in different concentrations (lower freezing points
for easier handling)74

Physical Data

H-Phrases EU-GHS
Signal Word GHS

PictogramChemicalInventoryMd% (w/w)b.p.
m.p.

not available
1.161 g/cm³ (20 °C)
min. 75.0> 360 °C
< 0 °CMd% (w/w)b.p.
m.p.

105.14 g/mol
1.0953 g/cm³ (20 °C)
min. 99.3
269.9 °C
27.4 °C

H302; H315; H318; H373
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

not available
1.1 g/cm³ (20 °C)
not available> 268 °C
< 20 °C

H302; H315; H318; H373
DangerTSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

61.08 g/mol
1.0157 g/cm³ (20 °C)
min. 99.7
170.3 °C
10.5 °C

H302; H312; H314; H332;
H335
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

149.19 g/mol
1.125 g/cm³ (20 °C)
min. 99.3
336.1 °C
18 – 23 °CMd% (w/w)b.p.
m.p.

149.00 g/mol
1.13 g/cm³ (20 °C)
82.0 – 88.0
175 – 185 °C (2 hPa)
8 °C

Explanation of symbols
M = Mol. Weightd = Density

REACH;TSCA;
IECSC

REACH;TSCA;
IECSC;
ENCS/ISTSCA;
IECSC;
ENCS/IS

H318; H373
Danger% (w/w) = Purity/Content

b.p. = Boiling Point

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

75

5.1

Ethanolamines

No.

Product[CAS Registry No.]

5.1.7

Triethanolamine T 85
[102-71-6]

FormulaRemark 1

Remarks
1 Triethanolamine mixture with diethanolamine; also available as aqueous solution in different concentrations(lower freezing points for easier handling)76

Physical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

H318; H373
Danger

149.19 g/mol
1.13 g/cm³ (20 °C)
min. 85.0> 270 °C
13 °C

Explanation of symbols
M = Mol. Weightd = Density% (w/w) = Purity/Content

PictogramChemicalInventory
TSCA;
IECSC;
ENCS/ISb.p. = Boiling Point

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

77

5.2

Isopropanolamines

No.

Product[CAS Registry No.]

5.2.1

AMIX TI solution[122-20-3]

FormulaRemark 1

5.2.2

Diisopropanolamine[110-97-4]
Remark 2

5.2.3

Isopropanolamine[78-96-6]

5.2.4

Triisopropanolamine[122-20-3]
Remark 3

Remarks
1 Solution of Triisopropanolamine technical grade, Diisopropanolamine and water
2 Also available in different purity grades and as aqueous solution in different concentrations on request
3 Also available as technical grade and 85% aqueous solution

78

Physical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

191.27 g/mol
1.0318 g/cm³ (20 °C)
not available
100 – 370 °C
0 °C

H319; H412
Warning

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

133.19 g/mol
0.9849 g/cm³ (50 °C)
min. 99.0
248.8 – 254.5 °C
44.5 – 45.5 °C

H319
Warning

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

75.11 g/mol
0.962 g/cm³ (20 °C)
min. 99.0
158 – 159 °C
2 °C

H312; H314
DangerTSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

191.27 g/mol
1.0 g/cm³ (20 °C)
min. 99.0
301.1 °C
45 °C

H319; H412
Warning

TSCA;
IECSC;
ENCS/IS

Explanation of symbols
M = Mol. Weightd = Density% (w/w) = Purity/Content

Pictogramb.p. = Boiling Point

ChemicalInventory

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

79

5.3

Alkylamino Alcohols

No.

Product[CAS Registry No.]

5.3.1

3-Dimethylaminopropane-1-ol[3179-63-3]

5.3.2

Butyldiethanolamine[102-79-4]

5.3.3

Butylethanolamine[111-75-1]

5.3.4

Dibutylethanolamine[102-81-8]

5.3.5

Diethylethanolamine[100-37-8]

5.3.6

Ethylethanolamine[110-73-6]

5.3.7

Lupragen® N 101 – Dimethylethanolamine[108-01-0]

80

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

103.16 g/mol
0.886 g/cm³ (20 °C)
min. 99.0
159 °C–35 °C

H226; H302; H314
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

161.24 g/mol
0.9689 g/cm³ (20 °C)
min. 99.0
264 °C–45 °C

H314
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

117.19 g/mol
0.89 g/cm³ (20 °C)
min. 98.0
199 °C–2.1 °C

H302; H315; H318
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

173.30 g/mol
0.86 g/cm³ (20 °C)
min. 98.0
227 °C< –70 °C

H302; H314; H412
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

117.19 g/mol
0.88 g/cm³ (20 °C)
min. 99.5
162.36 °C< –70 °C

H226; H302; H311; H314;
H331; H335
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

89.14 g/mol
0.914 g/cm³ (20 °C)
min. 99.0
168 °C–5.8 °C

H302; H314
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

89.14 g/mol
0.887 g/cm³ (20 °C)
min. 99.8
134.1 °C
–59 °C

H226; H302; H312; H314;
H331; H335
DangerTSCA;
IECSC;
ENCS/IS

Explanation of symbols
M = Mol. Weightd = Density% (w/w) = Purity/Content

Pictogramb.p. = Boiling Point

ChemicalInventory

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

81

5.3

Alkylamino Alcohols

No.

Product[CAS Registry No.]

5.3.8

Methyldiethanolamine[105-59-9]

5.3.9

Methyldiisopropanolamine[4402-30-6]

5.3.10N,N-Dimethylethanolamine S[108-01-0]

5.3.11

N,N-Dimethylisopropanolamine[108-16-7]
Remark 1

5.3.12

N-Methylethanolamine[109-83-1]

Remarks
1 Also available as 77% aqueous solution on request

82

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

119.16 g/mol
1.04 g/cm³ (20 °C)
min. 99.0
243 °C–21 °C

H319
Warning

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

147.22 g/mol
0.954 g/cm³ (20 °C)
min. 98.0
226 – 233 °C< –32 °C

H318
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

89.14 g/mol
0.887 g/cm³ (20 °C)
min. 99.8
134.1 °C
–59 °C

H226; H302; H312; H314;
H331; H335
DangerTSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

103.16 g/mol
0.85 g/cm³ (20 °C)
min. 99.0
126 °C–85 °C

H226; H302; H312; H314
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

75.11 g/mol
0.94 g/cm³ (20 °C)
min. 99.0
158 – 160 °C–3 °C

H302; H312; H314; H335
Danger

REACH;TSCA;
IECSC;
ENCS/IS

Explanation of symbols
M = Mol. Weightd = Density% (w/w) = Purity/Content

Pictogramb.p. = Boiling Point

ChemicalInventory

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

83

5.4

Other Amino Alcohols

No.

Product[CAS Registry No.]

5.4.1

2-(2-Aminoethoxy)ethanol[929-06-6]

5.4.2

3-Amino-1-propanol[156-87-6]

5.4.3

4-(2-Hydroxyethyl)morpholine[622-40-2]

5.4.4

5-Amino-1-pentanol sol. 50%[2508-29-4]

5.4.5

Hydoxyethylpiperazine[103-76-4]

5.4.6

Lupragen® N 107 –Dimethylaminoethoxyethanol[1704-62-7]

5.4.7

Lupragen® N 400 –Trimethylaminoethylethanolamine[2212-32-0]

84

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

105.14 g/mol
1.06 g/cm³ (20 °C)
min. 98.0
222.6 °C
–11 °C

H314
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

75.11 g/mol
0.99 g/cm³ (20 °C)
min. 99.0
187.71 °C
11.5 – 12.4 °C

H302; H314
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

131.17 g/mol
1.06 g/cm³ (20 °C)
min. 99.0
223 – 225 °C
1 – 2 °C

H319
Warning

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

not available
0.9869 g/cm³ (20 °C)
min. 97.0
100 – 222 °C–25.6 °C

H302; H314
DangerREACH

Md% (w/w)b.p.
m.p.

130.19 g/mol
1.059.8 g/cm³ (20 °C)
min. 98.5
245.8 °C
–38.5 °C

H315; H318
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

133.19 g/mol
0.9549 g/cm³ (20 °C)
min. 98.0
203.5 °C
< –70 °C

H314
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

146.23 g/mol
0.914 g/cm³ (15 °C)
min. 98.5
210 °C< –70 °C

H315; H318
Danger

REACH;TSCA;
IECSC;
ENCS/IS

Explanation of symbols
M = Mol. Weightd = Density% (w/w) = Purity/Content

Pictogramb.p. = Boiling Point

ChemicalInventory

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

85

5.4

Other Amino Alcohols

No.

Product[CAS Registry No.]

5.4.8

N-(2-Aminoethyl)ethanolamine[111-41-1]

5.4.9

N-(2-Hydroxyethyl)aniline[122-98-5]

5.4.10N,N-Di-(2-hydroxyethyl)aniline[120-07-0]

86

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

104.15 g/mol
1.024 g/cm³ (25 °C)
min. 99.5
243.1 °C
< –18 °C

H314; H317; H360FD
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

137.18 g/mol
1.0954 g/cm³ (20 °C)
min. 99.0
278 °C–32 °C

H301; H311; H318; H373
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

181.23 g/mol
1.1 g/cm³ (60 °C)
min. 95.0
380 °C57.8 °C

H317; H318; H412
Danger

REACH;TSCA;
IECSC;
ENCS/IS

Explanation of symbols
M = Mol. Weightd = Density% (w/w) = Purity/Content

Pictogramb.p. = Boiling Point

ChemicalInventory

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

87

6

Carboxylic Acids and Derivatives

6.1

Carboxylic Acids

No.

Product[CAS Registry No.]

6.1.1

2-Ethylhexanoic acid[149-57-5]

6.1.2

Formic acid 85%[64-18-6]

FormulaRemark 1

6.1.3

Formic acid 94%[64-18-6]
Remark 2

6.1.4

Formic acid 99 – 100%[64-18-6]
Remark 3

6.1.5

i-Nonanoic acid[3302-10-1]

6.1.6

Isononanoic acid C[3302-10-1]

6.1.7

Propionic acid pure[79-09-4]

Remarks
1 Also available as 99 – 100% and 94% aqueous solutions, also available in feed grade, see also www.formicacid.de
2 Also available as 99 – 100% and 85% aqueous solutions, also available in feed grade, see also www.formicacid.de
3 Also available as 85% and 94% aqueous solutions, also available in feed grade, see also www.formicacid.de

88Physical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

144.21 g/mol
0.91 g/cm³ (20 °C)
min. 99.5
226 – 229 °C–59 °C

H361d
Warning

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

46.03 g/mol
1.195 g/cm³ (20 °C)
min. 85.0
107.3 °C
–13 °C

H314
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

46.03 g/mol
1.21 g/cm³ (20 °C)
min. 94.0
103 °C–2 °C

H226; H314
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

46.03 g/mol
1.2195 g/cm³ (20 °C)
min. 99.0
100.23 °C
4 °C

H226; H314
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

158.24 g/mol
0.9 g/cm³ (20 °C)
min. 96.0
230 – 240 °C< –60 °C

H302; H315; H318
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

158.24 g/mol
0.8996 g/cm³ (20 °C)
min. 96.0
230 – 240 °C–77 °C

H302; H315; H318
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

74.08 g/mol
0.992 g/cm³ (20 °C)
min. 99.5
140.7 – 141.6 °C–20 °C

H226; H314
Danger

REACH;TSCA;
IECSC;
ENCS/IS

Explanation of symbols
M = Mol. Weightd = Density% (w/w) = Purity/Content

Pictogramb.p. = Boiling Point

ChemicalInventory

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

89

6.1

Carboxylic Acids

No.

Product[CAS Registry No.]

6.1.8

Sarcosine sodium 40% sol.
[4316-73-8]

90

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)
b.p.
m.p.

H314
Dangernot available
1.21 g/cm³ (20 °C)
39.5 – 40.5
not available
1 – 10 °C

Explanation of symbols
M = Mol. Weightd = Density% (w/w) = Purity/Content

PictogramChemicalInventory
REACH;TSCA;
IECSC;
ENCS/ISb.p. = Boiling Point

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

91

6.2

Derivatives

No.

Product[CAS Registry No.]

6.2.1

2-Hydroxyethyl carbamate[5395-01-7]

6.2.2

Formamide[75-12-7]

6.2.3

Isatoic anhydride dry[118-48-9]

6.2.4

Methyl formate pure
[107-31-3]

92

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

105.09 g/mol
1.26 g/cm³ (20 °C)
min. 97.0
130 – 135 °C (1.33 hPa)
10 – 30 °C

H319; H412
Warning

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

45.04 g/mol
1.133 g/cm³ (20 °C)
min. 99.5
210 °C
2.2 °CH351; H360D; H373
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

163.13 g/mol
1.52 g/cm³ (not available)
min. 99.5
not available
210 – 225 °C

H317; H319
Warning

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

60.05 g/mol
0.968 g/cm³ (20 °C)
min. 97.0
32.3 °C–100.4 °C

H224; H302; H319; H332;
H335
Danger

REACH;TSCA;
IECSC;
ENCS/IS

Explanation of symbols
M = Mol. Weightd = Density% (w/w) = Purity/Content

Pictogramb.p. = Boiling Point

ChemicalInventory

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

93

7

Heterocyclic Compounds

7.1

Carbonates

No.

Product[CAS Registry No.]

7.1.1

3,4-Dihydro-2H-pyrane[110-87-2]

7.1.2

Carbonate Mix 50

7.1.3

Carbonate Mix 60

7.1.4

Ethylene carbonate S®
[96-49-1]

7.1.5

Propylene carbonate S®
[108-32-7]

7.1.6

THF Pharma non-stab.
[109-99-9]

7.1.7

THF Pharma stab.
[109-99-9]

94

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

84.12 g/mol
0.927 g/cm³ (20 °C)
min. 99.0
87 °C–70 °CH225; H315; H319;
EUH019DangerMd% (w/w)b.p.
m.p.

not available
1.27 g/cm³ (20 °C)
not available
240 – 246 °C
0.4 °CMd% (w/w)b.p.
m.p.

not available
1.3 g/cm³ (20 °C)
not available
240 – 246 °C–10 °C

H319
Warning

TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

88.06 g/mol
1.32 g/cm³ (39 °C)
min. 99.5
246 °C
36 °C

H319
Warning

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

102.09 g/mol
1.2047 g/cm³ (20 °C)
min. 99.7
240 – 243 °C–48.8 °C

H319
Warning

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

72.11 g/mol
0.887 g/cm³ (20 °C)
min. 99.95
65.5 – 66.5 °C–108.5 °C

H225; H302; H319; H335;
H336; EUH019
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

72.11 g/mol
0.887 g/cm³ (20 °C)
min. 99.95
65.5 – 66.5 °C–108.5 °C

H225; H302; H319; H335;
H336; EUH019
Danger

REACH;TSCA;
IECSC;
ENCS/IS

Explanation of symbols
M = Mol. Weightd = Density

PictogramChemicalInventory
REACH;TSCA;
IECSC;
ENCS/ISTSCA;
IECSC;
ENCS/IS% (w/w) = Purity/Content

b.p. = Boiling Point

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

95

7.1

Carbonates

No.

Product[CAS Registry No.]

7.1.8

THF Pharma stab. super dry[109-99-9]

7.1.9

Vinylene carbonate E[872-36-6]

96

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

72.11 g/mol
0.887 g/cm³ (20 °C)
min. 99.95
65.5 – 66.5 °C–108.50 °C

H225; H302; H319; H335;
H336; EUH019
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

86.05 g/mol
1.3535 g/cm³ (25 °C)
min. 99.9
162 °C
22 °C

H302; H315; H317; H319
Warning

REACH;TSCA;
IECSC;
ENCS/IS

Explanation of symbols
M = Mol. Weightd = Density% (w/w) = Purity/Content

Pictogramb.p. = Boiling Point

ChemicalInventory

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

97

7.2

Imidazoles and Pyrazoles

No.

Product[CAS Registry No.]

7.2.1

1,4-Dimethylpyrazole[1072-68-0]

7.2.2

1-Ethylimidazole[7098-07-9]

7.2.3

1-Methylimidazole[616-47-7]

7.2.4

2-Ethyl-4-methylimidazole[931-36-2]

7.2.5

2-Ethyl-4-methylimidazole dist.
[931-36-2]

7.2.6

2-Ethyl-4-methylimidazole S[931-36-2]

7.2.7

2-Ethylimidazole ultra pure[1072-62-4]

98

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

96.13 g/mol
0.9626 g/cm³ (20 °C)
min. 99.0
150.37 °C–45.8 °C

H226; H302; H318
Danger

REACH;
ENCS/ISMd% (w/w)b.p.
m.p.

96.13 g/mol
0.995 g/cm³ (20 °C)
min. 98.5
104 °C (35 hPa)
–27 °C

H302; H314; H412
DangerREACH

Md% (w/w)b.p.
m.p.

82.11 g/mol
1.03 g/cm³ (20 °C)
min. 99.0
198 °C–2 °C

H302; H311; H314
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

110.16 g/mol
0.9715 g/cm³ (40 °C)
87.0 – 92.0
272.8 °C
36 – 42 °C

H302; H315; H318
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

110.16 g/mol
0.9715 g/cm³ (40 °C)
min. 98.0
272.8 °C
36 – 42 °C

H302; H318
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

not available
1.0173 g/cm³ (20 °C)
83.0 – 87.0
270 – 276 °C
36 – 42 °C

H302; H311; H314
DangerTSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

96.13 g/mol
not available
min. 99.0
268 – 270 °C
77 – 78 °C

H302; H315; H318
Danger

REACH;TSCA;
IECSC;
ENCS/IS

Explanation of symbols
M = Mol. Weightd = Density% (w/w) = Purity/Content

Pictogramb.p. = Boiling Point

ChemicalInventory

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

99

7.2

Imidazoles and Pyrazoles

No.

Product[CAS Registry No.]

7.2.8

2-Methylimidazole flakes[693-98-1]

7.2.9

2-Methylimidazole pure[693-98-1]

7.2.10Imidazole[288-32-4]

7.2.11Imidazole aqueous solution 50%

7.2.12

Lupragen® API – N-(3-Aminopropyl)
imidazole[5036-48-6]

7.2.13

Lupragen® DMI – 1,2-Dimethylimidazole[1739-84-0]

7.2.14

Lupragen® NMI – N-Methylimidazole[616-47-7]

100

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

82.11 g/mol
not available
min. 98.5
268 °C
136 – 138 °C

H302; H314; H360D
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

82.11 g/mol
not available
min. 99.7
268 °C
144 – 145 °C

H302; H314
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

68.08 g/mol
1.0257 g/cm³ (110 °C)
min. 99.5
256 °C
88 – 90 °C

H302; H314; H360D;
EUH071Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

68.08 g/mol
1 g/cm³ (20 °C)
50.0
104 °C
2 °C

H302; H314; H360;
EUH071Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

125.17 g/mol
1.062 g/cm³ (20 °C)
min. 97.0
296 °C–68 °C

H302; H314
Danger

REACH;
TSCA;
IECSC

M
d
% (w/w)b.p.
m.p.

96.13 g/mol
0.99 g/cm³ (40 °C)
min. 96.0
205 °C
20 – 40 °C

H302; H315; H318; H412
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

82.11 g/mol
1.03 g/cm³ (20 °C)
min. 99.0
198 °C–2 °C

H302; H311; H314
Danger

REACH;TSCA;
IECSC;
ENCS/IS

Explanation of symbols
M = Mol. Weightd = Density% (w/w) = Purity/Content

Pictogramb.p. = Boiling Point

ChemicalInventory

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

101

7.2

Imidazoles and Pyrazoles

No.

Product[CAS Registry No.]

7.2.15N-(3-Aminopropyl)imidazole[5036-48-6]

102

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

H302; H314
Danger125.17 g/mol
1.062 g/cm³ (20 °C)
min. 97.0
296 °C–68 °C

Explanation of symbols
M = Mol. Weightd = Density% (w/w) = Purity/Content

PictogramChemicalInventory
REACH;TSCA;
IECSC

b.p. = Boiling Point

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

103

7.3

Lactones and Lactams

No.

Product[CAS Registry No.]

7.3.1

2-Pyrrolidone crude[616-45-5]

7.3.2

2-Pyrrolidone dist.
[616-45-5]

7.3.3

Cyclohexylpyrrolidone[6837-24-7]

7.3.4

gamma-Butyrolactone dist.
[96-48-0]

7.3.5

epsilon-Caprolactone[502-44-3]

7.3.6

N-(2-Hydroxyethyl)-2-pyrrolidone[3445-11-2]

7.3.7

N-(2-Hydroxyethyl)-2-pyrrolidone 95%[3445-11-2]

104

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

85.11 g/mol
1.1 g/cm³ (30 °C)
min. 89.0
250 °C
23 °C

H319
Warning

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

85.11 g/mol
1.103 g/cm³ (30 °C)
min. 99.5
250 °C
25.5 °C

H319
Warning

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

167.25 g/mol
1.03 g/cm³ (20 °C)
min. 99.0
290 – 292 °C
15 °C

H302; H312; H314
Danger

REACH;
TSCA;
IECSC

M
d
% (w/w)b.p.
m.p.

86.09 g/mol
1.13 g/cm³ (20 °C)
min. 99.7
204.6 °C
–43.2 – –42 °C

H302; H318; H336
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

114.14 g/mol
1.07 g/cm³ (20 °C)
min. 99.8
241 °C–2 °C

H319
Warning

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

129.16 g/mol
1.1448 g/cm³ (20 °C)
min. 99.5
309 °C
26.4 °C

REACH;
TSCA;
IECSC

M
d
% (w/w)b.p.
m.p.

129.16 g/mol
1.1448 g/cm³ (20 °C)
94.0 – 96.0
309 °C
26.4 °C

REACH;TSCA;
IECSC

Explanation of symbols
M = Mol. Weightd = Density% (w/w) = Purity/Content

Pictogramb.p. = Boiling Point

ChemicalInventory

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

105

7.3

Lactones and Lactams

No.

Product[CAS Registry No.]

7.3.8

N-Dodecyl-2-pyrrolidone[2687-96-9]

7.3.9

N-Ethylpyrrolidone-2[2687-91-4]

7.3.10N-Methylpyrrolidone dist.
[872-50-4]

7.3.11

N-Methylpyrrolidone Life Science[872-50-4]

7.3.12

N-Octyl-2-pyrrolidone dist.
[2687-94-7]

7.3.13delta-Valerolactone[542-28-9]

7.3.14

N-Vinyl-2-pyrrolidone stab. 0.1% NaOH
[88-12-0]

106

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

253.43 g/mol
0.903 g/cm³ (20 °C)
min. 98.0
361 °C
10 °C

H314; H317; H400; H410
Danger

TSCA;
IECSC

M
d
% (w/w)b.p.
m.p.

113.16 g/mol
0.9974 g/cm³ (20 °C)
min. 99.4
212.5 °C
< –75 °C

H318; H361d
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

99.13 g/mol
1.028 g/cm³ (25 °C)
min. 99.8
204.3 °C
–23.6 °C

H315; H319; H335;
H360D
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

99.13 g/mol
1.028 g/cm³ (25 °C)
min. 99.8
204.3 °C
–23.6 °C

H315; H319; H335;
H360D
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

197.32 g/mol
0.92 g/cm³ (20 °C)
min. 99.0
306 – 307 °C–26 °C

H314; H412
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

100.12 g/mol
1.107 g/cm³ (20 °C)
min. 97.0
230 °C–12.5 °C

H318
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

111.14 g/mol
1.043 g/cm³ (20 °C)
min. 99.5
92 °C (13 hPa)
13 – 14 °C

H302; H311; H318; H331;
H335; H351; H373
Danger

REACH;TSCA;
IECSC;
ENCS/IS

Explanation of symbols
M = Mol. Weightd = Density% (w/w) = Purity/Content

Pictogramb.p. = Boiling Point

ChemicalInventory

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

107

7.3

Lactones and Lactams

No.

Product[CAS Registry No.]

7.3.15

N-Vinyl-2-pyrrolidone stab. 10 ppm
Kerobit[88-12-0]

7.3.16

N-Vinyl-2-pyrrolidone stab. 100 ppm
Kerobit[88-12-0]

7.3.17

N-Vinyl-2-pyrrolidone stab. 25 ppm
Kerobit[88-12-0]

108

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

111.14 g/mol
1.043 g/cm³ (20 °C)
min. 99.5
90 – 92 °C (13 hPa)
13 – 14 °C

H302; H311; H318; H331;
H335; H351; H373
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

111.14 g/mol
1.043 g/cm³ (20 °C)
min. 99.5
90 – 92 °C (13 hPa)
13 – 14 °C

H302; H311; H318; H331;
H335; H351; H373
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

111.14 g/mol
1.043 g/cm³ (20 °C)
min. 99.5
90 – 92 °C (13 hPa)
13 – 14 °C

H302; H311; H318; H331;
H335; H351; H373
Danger

REACH;TSCA;
IECSC;
ENCS/IS

Explanation of symbols
M = Mol. Weightd = Density% (w/w) = Purity/Content

Pictogramb.p. = Boiling Point

ChemicalInventory

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

109

7.4

Morpholines

No.

Product[CAS Registry No.]

7.4.1

4-(2-Hydroxyethyl)morpholine[622-40-2]

7.4.2

AMIX M[68909-77-3]
Remark 1

7.4.3

Lupragen® N 105 –N-Methylmorpholine[109-02-4]
Remark 2

7.4.4

Lupragen® N 106 –
2,2'-Dimorpholinodiethylether[6425-39-4]

7.4.5

Morpholine[110-91-8]

7.4.6

N-Acetylmorpholine[1696-20-4]

7.4.7

N-Formylmorpholine[4394-85-8]

Remarks
1 High boiling morpholine derivatives
2 Methylmorpholine P is available for pharma applications

110

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

131.17 g/mol
1.06 g/cm³ (20 °C)
min. 99.0
223 – 225 °C
1 – 2 °C

H319
Warning

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

not available
1.0993 g/cm³ (20 °C)
not available
266 – 330 °C–65 °CH315; H317; H318
Danger

REACH;
TSCA;
IECSC

M
d
% (w/w)b.p.
m.p.

101.15 g/mol
0.82 g/cm³ (20 °C)
min. 99.0
115 °C–65 °CH225; H312; H314
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

244.33 g/mol
1.0603 g/cm³ (20 °C)
min. 99.0309 °C–28 °CH315; H319
Warning

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

87.12 g/mol
1.00 g/cm³ (20 °C)
min. 99.0
128 – 130 °C–5 °C

H226; H302; H311; H314;
H332
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

129.16 g/mol
1.115 g/cm³ (20 °C)
min. 99.0
244.7 °C
14 °C

REACH;
TSCA;
IECSC

M
d
% (w/w)b.p.
m.p.

115.13 g/mol
1.1429 g/cm³ (20 °C)
min. 99.5
244 °C
23 °C

REACH;TSCA;
IECSC;
ENCS/IS

Explanation of symbols
M = Mol. Weightd = Density% (w/w) = Purity/Content

Pictogramb.p. = Boiling Point

ChemicalInventory

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

111

7.5

Other Heterocycles

No.

Product[CAS Registry No.]

7.5.1

1,4-Dioxan stab. ultra pure
[123-91-1]
Remark 1

7.5.2

1,4-Dioxane[123-91-1]

7.5.3

1,4-Dioxane stab.
[123-91-1]

7.5.4

Lupragen® N 201 – Triethylenediamine
in dipropyleneglycol[280-57-9]
Remark 2

7.5.5

Lupragen® N 203 – Triethylenediamine
in monoethyleneglycol[280-57-9]
Remark 2

7.5.6

Lupragen® N 700 –
1,8-Diazabicyclo-5,4,0-undecene-7[6674-22-2]
Remark 3

Remarks
1 Only upon request
2 Exclusively marketed by Evonik Industries AG
3 Diazabicycloundecene P is available for pharma applications

112

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

88.1 g/mol
1.034 g/cm³ (20 °C)
min. 99.9
100 – 102.5 °C
11 °C

H225; H319; H335; H351
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

88.1 g/mol
1.0300 g/cm³ (20 °C)
min. 99.8
100 – 102.5 °C
12 °C

H225; H319; H335; H351;
EUH019Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

88.1 g/mol
1.034 g/cm³ (20 °C)
min. 99.8
100 – 102.5 °C
11 °C

H225; H319; H335; H351;
EUH019Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

not available
1.025 g/cm³ (20 °C)
33.1 – 33.5
not available–39 °C

H302; H315; H318
DangerTSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

not available
1.09 g/cm³ (25 °C)
33.1 – 33.5
196 °C–67 °C

H302; H315; H318; H335
DangerTSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

152.24 g/mol
1.019 g/cm³ (20 °C)
min. 98.0
261.86 °C–70 °C

H302; H314; H412
Danger

REACH;TSCA;
IECSC;
ENCS/IS

Explanation of symbols
M = Mol. Weightd = Density% (w/w) = Purity/Content

Pictogramb.p. = Boiling Point

ChemicalInventory

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

113

7.6

Oxiranes

No.

Product[CAS Registry No.]

7.6.1

Isobutyleneoxide[558-30-5]

114

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

H225; H314
Danger

72.11 g/mol
0.81 g/cm³ (20 °C)
min. 99.0
51 °C
not available

Explanation of symbols
M = Mol. Weightd = Density% (w/w) = Purity/Content

PictogramChemicalInventory
REACH;TSCA;
IECSC;
ENCS/ISb.p. = Boiling Point

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

115

7.7

Piperazines

No.

Product[CAS Registry No.]

7.7.1

Hydroxyethylpiperazine[103-76-4]

7.7.2

N-Ethylpiperazine[5308-25-8]

7.7.3

N-Methylpiperazine[109-01-3]

7.7.4

Piperazine[110-85-0]
Remark 1

Remarks
1 Available as chips or 68% aqueous solution

116

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

130.19 g/mol
1.059.8 g/cm³ (20 °C)
min. 98.5
245.8 °C
–38.5 °C

H315; H318
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

114.19 g/mol
0.895 g/cm³ (20 °C)
min. 99.0
155 °C< –60 °C

H226; H302; H314
DangerREACH

Md% (w/w)b.p.
m.p.

100.16 g/mol
0.903 g/cm³ (20 °C)
min. 99.0
136.66 °C–5.57 °C

H226; H312; H314
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

86.14 g/mol
not available
min. 99.9
147.7 °C
107 – 111 °C

H228; H314; H317; H334;
H361fdDanger

REACH;TSCA;
IECSC;
ENCS/IS

Explanation of symbols
M = Mol. Weightd = Density% (w/w) = Purity/Content

Pictogramb.p. = Boiling Point

ChemicalInventory

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

117

7.8

Piperidines

No.

Product[CAS Registry No.]

7.8.1

N-Ethylpiperidine[766-09-6]

7.8.2

N-Methylpiperidine 80% calc. 100%
[626-67-5]

7.8.3

Piperidine[110-89-4]

118

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

113.20 g/mol
0.82 g/cm³ (20 °C)
min. 99.0
131 °C< –50 °C

H225; H301; H314; H331;
H412
Danger

REACH;
TSCA;
IECSC

M
d
% (w/w)b.p.
m.p.

99.18 g/mol
0.87 g/cm³ (20 °C)
77.0 – 83.0
106.56 °C–103.23 °C

H225; H302; H314; H412
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

85.15 g/mol
0.861 g/cm³ (20 °C)
min. 99.0
106 – 107 °C–11.5 °C

H225; H311; H314; H331
Danger

REACH;TSCA;
IECSC;
ENCS/IS

Explanation of symbols
M = Mol. Weightd = Density% (w/w) = Purity/Content

Pictogramb.p. = Boiling Point

ChemicalInventory

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

119

7.9

Pyrrolidines

No.

Product[CAS Registry No.]

7.9.1

N-Methylpyrrolidine[120-94-5]

7.9.2

Pyrrolidine pure
[123-75-1]

120

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

85.15 g/mol
0.80 g/cm³ (20 °C)
min. 98.0
78 – 82 °C< –80 °C

H225; H301; H314; H332;
H411
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

71.12 g/mol
0.866 g/cm³ (20 °C)
min. 99.0
86 – 88 °C< –60 °C

H225; H302; H314; H332
Danger

REACH;TSCA;
IECSC;
ENCS/IS

Explanation of symbols
M = Mol. Weightd = Density% (w/w) = Purity/Content

Pictogramb.p. = Boiling Point

ChemicalInventory

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

121

7.10

TetrahydropyransNo.

Product[CAS Registry No.]7.10.14-Formyltetrahydropyran[50675-18-8]

7.10.2

Tetrahydropyran-4-carboxylic
acid methylester[110238-91-0]

122

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

114.14 g/mol
1.046 g/cm³ (20 °C)
min. 97.0
184.3 °C
–67 °CH317; H319
Warning

REACH;
ENCS/ISMd% (w/w)b.p.
m.p.

144.17 g/mol
1.08 g/cm³ (20 °C)
min. 98.0
196.8 °C
–33.0 °C

H319; H412
Warning

REACH

Explanation of symbols
M = Mol. Weightd = Density% (w/w) = Purity/Content

Pictogramb.p. = Boiling Point

ChemicalInventory

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

123

8

Optically Active Compounds

8.1

Chiral Alcohols and Epoxides

No.

Product[CAS Registry No.]

8.1.1

ChiPros® (R)-1-(3,5-Ditrifluormethyl)
phenylethanol[127852-28-2]

8.1.2

ChiPros® (S)-1-(3,5-Ditrifluoromethyl)
phenylethanol[225920-05-8]
Remark 1

8.1.3

ChiPros® (S)-2-Pentanol[26184-62-3]
Remark 1

8.1.4

ChiPros® (S)-Butan-2-ol[4221-99-2]

Remarks
1 Developmental products, material available on request

124

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

258.16 g/mol
not available
not available
115 °C (2 – 5 hPa)
59 °C

H302; H319; H400; H410
WarningMd% (w/w)b.p.
m.p.

258.16 g/mol
not available
not available
not available
not availableMd% (w/w)b.p.
m.p.

88.15 g/mol
not available
not available
not available
not available

H226; H315; H318; H332;
H335
DangerMd% (w/w)b.p.
m.p.

74.12 g/mol
0.80 g/cm³ (20 °C)
min. 99.0
99 – 100 °C–114.7 °C

H226; H319; H335; H336
Warning

Explanation of symbols
M = Mol. Weightd = Density% (w/w) = Purity/Content

Pictogramb.p. = Boiling Point

ChemicalInventory

REACH;IECSC;
ENCS/IS

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

125

8.2

Chiral Amines

No.

Product[CAS Registry No.]

8.2.1

1-Phenylethylamine[618-36-0]
Remark 1

8.2.2

ChiPros® (1R, 2R)-trans-2-Amino
cyclopentanol hydrochloride[68327-11-7]

8.2.3

ChiPros® (1R-trans)-2-(Phenyl methoxy)
cyclohexanamine[216394-06-8]

8.2.4

ChiPros® (1S, 2S)-trans-2Benzyloxycyclohexylamine[216394-07-9]
Remark 2

8.2.5

ChiPros® (R)-1-(1-Naphthyl)ethylamine[3886-70-2]

8.2.6

ChiPros® (R)-1-(2-Methoxyphenyl)
ethylamine[68285-23-4]
Remark 2

8.2.7

ChiPros® (R)-1-(2-Naphthyl)ethylamine[3906-16-9]
Remark 2

Remarks
1 Also available in enantiomerically pure form
2 Developmental products, material available on request

126

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

121.18 g/mol
0.94 g/cm³ (20 °C)
min. 99.0
187 °C–65 °C

H302; H311; H314
DangerMd% (w/w)b.p.
m.p.

137.62 g/mol
not available
min. 99.0
not available
158 – 160 °CMd% (w/w)b.p.
m.p.

205.30 g/mol
1.001 g/cm³ (20 °C)
min. 99.0
79 – 80 °C (0.1 hPa)
21 °C

M
d
% (w/w)b.p.
m.p.

205.3 g/mol
not available
min. 98.0
79 – 80 °C (0.1 hPa)
not availableMd% (w/w)b.p.
m.p.

171.24 g/mol
1.06 g/cm³ (20 °C)
min. 99.0
93 °C (0.4 hPa)
not availableMd% (w/w)b.p.
m.p.

151.2 g/mol
not available
min. 99.0
118 °C (23 hPa)
not availableMd% (w/w)b.p.
m.p.

171.2 g/mol
not available
min. 99.0
69 – 97 °C (0.2 hPa)
not available

Explanation of symbols
M = Mol. Weightd = Density

PictogramChemicalInventory
REACH;TSCA;
IECSC;
ENCS/ISH302; H314; H411
DangerH301; H312; H314; H411
Danger% (w/w) = Purity/Content

b.p. = Boiling Point

REACH;TSCA;
IECSC;
ENCS/IS

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

127

8.2

Chiral Amines

No.

Product[CAS Registry No.]

8.2.8

ChiPros® (R)-1-(3-Methoxyphenyl)
ethylamine[88196-70-7]

8.2.9

ChiPros® (R)-1-(4-Chlorphenyl)ethylamine[6299-02-1]
Remark 1

8.2.10ChiPros® (R)-1-(4-Fluorphenyl)ethylamine[374898-01-8]

8.2.11

ChiPros® (R)-1-(4-Methoxyphenyl)
ethylamine[22038-86-4]

8.2.12

ChiPros® (R)-1-(4-Methylphenyl)
ethylamine[4187-38-6]

8.2.13

ChiPros® (R)-1-Aminoindane[10277-74-4]
Remark 1

8.2.14

ChiPros® (R)-1-Aminotetraline[23357-46-2]

Remarks
1 Developmental products, material available on request

128

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

151.21 g/mol
1.02 g/cm³ (20 °C)
min. 99.0
240 °C
5.4 °C

H302; H314; H332; H412
DangerMd% (w/w)b.p.
m.p.

155.6 g/mol
not available
min. 96.0
232°C
not availableMd% (w/w)b.p.
m.p.

139.17 g/mol
1.03 g/cm³ (20 °C)
min. 99.0
76 °C (29 hPa)
–30 °C

H302; H315; H318; H411
DangerMd% (w/w)b.p.
m.p.

151.21 g/mol
1.02 g/cm³ (20 °C)
min. 99.0
65 °C (0.5 hPa)
< –20 °C

H302; H312; H314
DangerMd% (w/w)b.p.
m.p.

135.21 g/mol
0.94 g/cm³ (20 °C)
min. 96.0
204 °C< –20 °C

H302; H312; H314; H317
DangerMd% (w/w)b.p.
m.p.

133.2 g/mol
1.098 g/cm³ (20 °C)
min. 99.0
69 – 97 °C (11 hPa)
not availableMd% (w/w)b.p.
m.p.

147.22 g/mol
1.02 g/cm³ (20 °C)
min. 99.0
118 – 120 °C (10 hPa)
< –20 °C

Explanation of symbols
M = Mol. Weightd = Density

PictogramChemicalInventory

REACH

H302; H315; H412
Warning% (w/w) = Purity/Content

b.p. = Boiling Point

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

129

8.2

Chiral Amines

No.

Product[CAS Registry No.]

8.2.15ChiPros® (R)-1-Cyclohexylethylamine[5913-13-3]

8.2.16

ChiPros® (R)-1-Cyclopropylethylamine[6240-96-6]
Remark 1

8.2.17

ChiPros® (R)-1-Phenylethylamine[3886-69-9]

8.2.18ChiPros® (R)-1-Phenylpropylamine[3082-64-2]

8.2.19ChiPros® (R)-2-Aminobutane[13250-12-9]

8.2.20ChiPros® (R)-2-Hexylamine[70095-40-8]
Remark 1

8.2.21

ChiPros® (R)-3-Aminobutan-1-ol[61477-40-5]

Remarks
1 Developmental products, material available on request

130

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

127.23 g/mol
0.85 g/cm³ (20 °C)
min. 99.0
175 °C< –20 °C

H226; H302; H311; H314;
H411
DangerREACH

Md% (w/w)b.p.
m.p.

85.15 g/mol
0.7991 g/cm³ (20 °C)
min. 99.0
95 – 98 °C–68 °CMd% (w/w)b.p.
m.p.

121.18 g/mol
0.9491 g/cm³ (25 °C)
min. 99.0
187 °C–10 °C

H302; H311; H314
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

135.21 g/mol
0.93 g/cm³ (20 °C)
min. 99.0
205 °C–69 °C

H301; H314; H373; H411
DangerMd% (w/w)b.p.
m.p.

73.14 g/mol
0.723 g/cm³ (20 °C)
min. 99.0
63 – 65 °C< –100 °C

H225; H302; H314; H332;
H400
DangerMd% (w/w)b.p.
m.p.

101.2 g/mol
not available
min. 99.0
116 °C
not availableMd% (w/w)b.p.
m.p.

89.14 g/mol
0.9459 g/cm³ (20 °C)
min. 99.0
90 °C (20 hPa)
< –30 °C

Explanation of symbols
M = Mol. Weightd = Density

PictogramChemicalInventory

REACH;
ENCS/ISH302; H314
Danger% (w/w) = Purity/Content

b.p. = Boiling Point

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

131

8.2

Chiral Amines

No.

Product[CAS Registry No.]

8.2.22

ChiPros® (R)-3-Methyl-2-butylamine[34701-33-2]
Remark 1

8.2.23

ChiPros® (R)-N-Benzyl-1phenylethylamine[38235-77-7]

8.2.24

ChiPros® (S)-1-(1-Naphthyl)ethylamine[10420-89-0]

8.2.25ChiPros® (S)-1-(2-Naphthyl)ethylamine[3082-62-0]

8.2.26

ChiPros® (S)-1-(3-Methoxyphenyl)
ethylamine[82796-69-8]

8.2.27

ChiPros® (S)-1-(4-Chlorphenyl)ethylamine[6299-02-1]
Remark 1

8.2.28ChiPros® (S)-1-(4-Fluorphenyl)ethylamine[66399-30-2]

Remarks
1 Developmental products, material available on request

132

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

87.2 g/mol
not available
min. 99.0
84 – 87 °C
not available

H225; H301; H315; H318;
H411
DangerMd% (w/w)b.p.
m.p.

211.31 g/mol
1.01 g/cm³ (20 °C)
min. 99.0
155 °C (75 hPa)
not available

H302; H315
WarningREACHMd% (w/w)b.p.
m.p.

171.24 g/mol
1.06 g/cm³ (20 °C)
min. 99.0
93 °C (0.4 hPa)
not available

H301; H314; H411
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

171.24 g/mol
not available
min. 99.0
90 °C (0.2 hPa)
52 °C

H315; H319; H411
Warning

REACH;
ENCS/ISMd% (w/w)b.p.
m.p.

151.21 g/mol
1.02 g/cm³ (20 °C)
min. 99.0
240 °C
5.4 °C

H302; H314; H317; H332;
H412
DangerMd% (w/w)b.p.
m.p.

155.6 g/mol
not available
min. 96.0
232 °C
not availableMd% (w/w)b.p.
m.p.

139.17 g/mol
1.03 g/cm³ (20 °C)
min. 99.0
76 °C (29 hPa)
–30 °C

Explanation of symbols
M = Mol. Weightd = Density

PictogramChemicalInventory

H302; H315; H318; H411
Danger% (w/w) = Purity/Content

b.p. = Boiling Point

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

133

8.2

Chiral Amines

No.

Product[CAS Registry No.]

8.2.29ChiPros® (S)-1-(4-Methoxyphenyl)
ethylamine[41851-59-6]

8.2.30ChiPros® (S)-1-(4-Methylphenyl)
ethylamine[27298-98-2]

8.2.31

ChiPros® (S)-1-Aminoindane[61341-86-4]
Remark 1

8.2.32

ChiPros® (S)-1-Aminotetraline[23357-52-0]

8.2.33

ChiPros® (S)-1-Cyclohexylethylamine[17430-98-7]

8.2.34

ChiPros® (S)-1-Cyclopropylethylamine[195604-39-8]

8.2.35ChiPros® (S)-1-Phenylethylamine[2627-86-3]

Remarks
1 Developmental products, material available on request

134

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

151.21 g/mol
1.02 g/cm³ (20 °C)
min. 99.0
65 °C (0.5 hPa)
< –20 °C

H302; H312; H314
DangerMd% (w/w)b.p.
m.p.

135.21 g/mol
0.94 g/cm³ (20 °C)
min. 96.0
77 °C (15 hPa)
< –20 °C

H302; H312; H314
DangerMd% (w/w)b.p.
m.p.

133.2 g/mol
1.098 g/cm³ (20 °C)
min. 99.0
69 – 97 °C (11 hPa)
not availableMd% (w/w)b.p.
m.p.

147.22 g/mol
1.02 g/cm³ (20 °C)
min. 99.0
250 °C< –20 °C

H302; H314; H332; H411
DangerMd% (w/w)b.p.
m.p.

127.23 g/mol
0.875 g/cm³ (15 °C)
min. 98.0
175 °C
not available

H226; H302; H311; H314
DangerMd% (w/w)b.p.
m.p.

85.15 g/mol
0.7991 g/cm³ (20 °C)
min. 99.0
95 – 98 °C–68 °CMd% (w/w)b.p.
m.p.

121.18 g/mol
0.94 g/cm³ (20 °C)
min. 99.0
187 °C–10 °C

Explanation of symbols
M = Mol. Weightd = Density

Pictogram

REACH;TSCA;
IECSC;
ENCS/ISH302; H311; H314
Danger% (w/w) = Purity/Content

ChemicalInventory

b.p. = Boiling Point

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

135

8.2

Chiral Amines

No.

Product[CAS Registry No.]

8.2.36

ChiPros® (S)-1-Phenylpropylamine[3789-59-1]

8.2.37

ChiPros® (S)-2-Hexylamine[70492-67-0]
Remark 1

8.2.38ChiPros® (S)-3,3-Dimethyl-2aminobutane[22526-47-2]

8.2.39ChiPros® (S)-3-Methyl-2-butylamine[22526-46-1]
Remark 1

8.2.40ChiPros® (S)-Methoxyisopropylamine[99636-32-5]

8.2.41

ChiPros® (S)-N-Benzyl-1phenylethylamine[17480-69-2]

8.2.42

ChiPros® Clophar[27298-99-3]

Remarks
1 Developmental products, material available on request

136

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

135.21 g/mol
0.93 g/cm³ (20 °C)
min. 99.0
205 °C–69 °C

H302; H314; H373; H411
DangerREACH

Md% (w/w)b.p.
m.p.

101.2 g/mol
not available
min. 99.0
116 °C
not availableMd% (w/w)b.p.
m.p.

101.19 g/mol
0.7551 g/cm³ (20 °C)
min. 99.0
103 °C–4 °C

H225; H302; H314; H412
Danger

ENCS/ISMd% (w/w)b.p.
m.p.

87.2 g/mol
not available
min. 99.0
84 – 87 °C
not availableMd% (w/w)b.p.
m.p.

89.14 g/mol
0.8434 g/cm³ (20 °C)
min. 98.0
92 – 94 °C
not available

H225; H302; H314; H412
Danger

REACH;
TSCA;
IECSC

M
d
% (w/w)b.p.
m.p.

not available
0.94 g/cm³ (20 °C)
min. 99.0
82 – 85 °C (0.4 hPa)
not available

H302; H315
WarningMd% (w/w)b.p.
m.p.

155.63 g/mol
1.115 g/cm³ (15 °C)
min. 99.0
232 °C
not available

H302; H315; H317; H318;
H411
DangerExplanation of symbols
M = Mol. Weightd = Density% (w/w) = Purity/Content

Pictogramb.p. = Boiling Point

ChemicalInventory

REACH

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

137

8.2

Chiral Amines

No.

Product[CAS Registry No.]

8.2.43

ChiPros® Clophas[4187-56-8]

138

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

H302; H315; H317; H318;
H330; H411
Danger

155.63 g/mol
1.115 g/cm³ (15 °C)
min. 95.0
232 °C
not available

Explanation of symbols
M = Mol. Weightd = Density% (w/w) = Purity/Content

Pictogramb.p. = Boiling Point

ChemicalInventory
REACH

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

139

8.3

Chiral Carboxylic Acids and Derivatives

No.

Product[CAS Registry No.]

8.3.1

ChiPros® (R)-2-Chloromandelic acid
[52950-18-2]

8.3.2

ChiPros® (R)-Isobutyllactate raw (D-LIB)[61597-96-4]

8.3.3

ChiPros® (R)-Mandelic acid[611-71-2]

140

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

186.59 g/mol
1.48 g/cm³ (20 °C)
min. 99.0
not available
121 – 123 °C

H317; H318
DangerREACH

Md% (w/w)b.p.
m.p.

146.19 g/mol
0.97 g/cm³ (20 °C)
85.0 – 90.0
178 °C–4.5 °C

H319
Warning

REACH;IECSC

M
d% (w/w)b.p.
m.p.

152.15 g/mol
not available
min. 99.0
249.17 °C
131 – 135 °C

H318Danger

REACH;TSCA;
IECSC;
ENCS/IS

Explanation of symbols
M = Mol. Weightd = Density% (w/w) = Purity/Content

Pictogramb.p. = Boiling Point

ChemicalInventory

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

141

9

Others9.1

AmidesNo.

Product[CAS Registry No.]

9.1.1

3-Amino-2,2-dimethylpropionicacidamide[324763-51-1]

9.1.2

Anthranilic acid amide dry[88-68-6]

9.1.3

Dimethylformamide[68-12-2]
Remark 1

9.1.4

N,N-Dimethylacetamide[127-19-5]
Remark 2

9.1.5

N-Acetylmorpholine[1696-20-4]

9.1.6

N-Formylmorpholine[4394-85-8]

9.1.7

N-Methylacetamide[79-16-3]

Remarks
1 Also available as high purity special grade
2 Also available as electronic grade

142

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

116.16 g/mol
not available
min. 99.0
not available
82.6 °C

H318
DangerREACH

Md% (w/w)b.p.
m.p.

136.15 g/mol
not available
min. 99.0
not available
107 – 111 °C

H318
Danger

REACH;
TSCA;
IECSC

M
d
% (w/w)b.p.
m.p.

73.09 g/mol
0.94 g/cm³ (20 °C)
min. 99.9
152 – 153 °C–61 °C

H226; H312; H319; H332;
H360D
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

87.12 g/mol
0.94 g/cm³ (20 °C)
min. 99.8
165 – 166 °C–20 °CH312; H319; H332;
H360D
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

129.16 g/mol
1.115 g/cm³ (20 °C)
min. 99.0
244.7 °C
14 °C

REACH;
TSCA;
IECSC

M
d
% (w/w)b.p.
m.p.

115.13 g/mol
1.1429 g/cm³ (20 °C)
min. 99.5
244 °C
23 °C

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

73.09 g/mol
0.946 g/cm³ (35 °C)
min. 99.0
206 – 208 °C
29 – 30 °C

Explanation of symbols
M = Mol. Weightd = Density

Pictogram

H360
Danger% (w/w) = Purity/Content

ChemicalInventory

REACH;TSCA;
IECSC;
ENCS/ISb.p. = Boiling Point

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

143

9.2

Hydrocarbons

No.

Product[CAS Registry No.]

9.2.1

Cyclododecatriene[4904-61-4]

144

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

H304; H400; H410
Danger

162.27 g/mol
0.892 g/cm³ (20 °C)
min. 99.0
238 – 242 °C–17 °C

Explanation of symbols
M = Mol. Weightd = Density% (w/w) = Purity/Content

PictogramChemicalInventory
REACH;TSCA;
IECSC;
ENCS/ISb.p. = Boiling Point

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

145

9.3

IminesNo.

Product[CAS Registry No.]

9.3.1

Benzophenonimine techn.
[1013-88-3]

146

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

H315; H319; H411
Warning181.24 g/mol
1.08 g/cm³ (20 °C)
min. 93.0
216 °C (100 hPa)
–30 °C

Explanation of symbols
M = Mol. Weightd = Density% (w/w) = Purity/Content

PictogramChemicalInventory
REACH

b.p. = Boiling Point

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

147

9.4

Ionic Liquids

No.

Product[CAS Registry No.]

9.4.1

1-Ethyl-3-methyl imidazolium
methylcarbonate in methanol[251102-25-7]
Remark 1

9.4.2

Basionics™ AL 01 –EMIM Cl : AlCl3 = 1 : 1.5
Remark 1

9.4.3

Basionics™ BC 01[143314-17-4]

9.4.4

Basionics™ EE 03[143314-16-3]

9.4.5

Basionics™ FS 01
Quart. ammonium salt

9.4.6

Basionics™ FS 13[75-05-8]

Remarks
1 Quantities up to 20 kg only available from SIGMA-ALDRICH

148

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

186.21 g/mol
0.9066 g/cm³ (20 °C)
ca. 30% in MeOH
not applicable–20 °CH225; H301; H311; H315;
H331; H370
DangerREACH

Md% (w/w)b.p.
m.p.

not available
1.350 g/cm³ (20 °C)
not available
not applicable–16 °C

H302; H314
Danger

TSCA;
IECSC

M
d
% (w/w)b.p.
m.p.

170.22 g/mol
1.027 g/cm³ (25 °C)
min. 98.0
not applicable< –20 °CMd% (w/w)b.p.
m.p.

197.97 g/mol
1.2695 g/cm³ (20 °C)
min. 98.0
not applicable–65 °CMd% (w/w)b.p.
m.p.

not available
1.32 g/cm³ (20 °C)
min. 98.0
not applicable–20 °CMd% (w/w)b.p.
m.p.

193.21 g/mol
1.1863 g/cm³ (25 °C)
min. 97.0
not applicable–74 °C

Explanation of symbols
M = Mol. Weightd = Density

PictogramChemicalInventory

REACH;TSCA;
IECSC;
ENCS/ISH302; H411
Warning

IECSC;
ENCS/ISREACH;TSCA;
IECSC;
ENCS/IS

H318; H302; H317
Danger% (w/w) = Purity/Content

b.p. = Boiling Point

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

149

9.4

Ionic Liquids

No.

Product[CAS Registry No.]

9.4.7

Basionics™ HP 01[174899-82-2]
Remark 1

9.4.8

Basionics™ LQ 01[342573-75-5]

9.4.9

Basionics™ LQ 11[848641-69-0]
Remark 1

9.4.10Basionics™ OH 01[250358-46-4]
Remark 2

9.4.11

Basionics™ ST 35[145022-45-3]

Remarks
1 Quantities up to 20 kg only available from SIGMA-ALDRICH
2 10% in water

150

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

391.3 g/mol
1.5236 g/cm³ (20 °C)
min. 98.0
not applicable–9 °C

H301; H311; H314; H373;
H411; EUH071
DangerMd% (w/w)b.p.
m.p.

236.3 g/mol
1.2391 g/cm³ (20 °C)
min. 98.0
not applicable< –30 °C

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

264.26 g/mol
1.146 g/cm³ (25 °C)
min. 98.0
not applicable
10 °C

ENCS/ISMd% (w/w)b.p.
m.p.

128.2 g/mol
1.002 g/cm³ (20 °C)~10.0 (in water)
not applicable
–7 °C

M
d
% (w/w)b.p.
m.p.

206.27 g/mol
1.247 g/cm³ (25 °C)
min. 97.0
not applicable
35 °C

Explanation of symbols
M = Mol. Weightd = Density

PictogramChemicalInventory
REACH;
ENCS/IS

ENCS/IS% (w/w) = Purity/Content

b.p. = Boiling Point

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

151

9.4

Ionic Liquids

No.

Product[CAS Registry No.]

9.4.12

Basionics™ ST 70[79917-90-1]
Remark 1

9.4.13

Basionics™ ST 80[65039-09-0]
Remark 1

9.4.14

Basionics™ UV 33[917956-73-1]

9.4.15

Basionics™ UV 43
Quart. ammonium salt

9.4.16

Basionics™ VS 01[331717-63-6]

9.4.17

Basionics™ VS 03[370865-89-7]

Remarks
1 Quantities up to 20 kg only available from SIGMA-ALDRICH

152

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

not available
1.086 g/cm³ (20 °C)
min. 95.0
not applicable
70 °C

H301; H315; H319; H411
DangerREACH

Md% (w/w)b.p.
m.p.

146.64 g/mol
1.112 g/cm³ (25 °C)
min. 95.0
not applicable
87.5 °C

H302; H319
Warning

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

not available
1.1091 g/cm³ (20 °C)
min. 98.0
not applicable–90 °C

H318; H315; H302; H317;
H411; H335
DangerMd% (w/w)b.p.
m.p.

not available
0.9334 g/cm³ (100 °C)
min. 98.0
not applicable
82 °C

H318; H315; H302; H317;
H335
DangerMd% (w/w)b.p.
m.p.

169.25 g/mol
1.1140 g/cm³ (25 °C)
min. 98.0
not applicable< –24 °C

H312; H332; H412
Warning

ENCS/ISMd% (w/w)b.p.
m.p.

177.21 g/mol
1.1 g/cm³ (20 °C)
min. 98.0
not applicable–11 °C

H302; H317; H318
Danger

REACH

Explanation of symbols
M = Mol. Weightd = Density% (w/w) = Purity/Content

Pictogramb.p. = Boiling Point

ChemicalInventory

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

153

9.4

Ionic Liquids

No.

Product[CAS Registry No.]

9.4.18

Basionics™ VS 11[145022-44-2]
Remark 1

Remarks
1 Quantities up to 20 kg only available from SIGMA-ALDRICH

154

FormulaPhysical DataMd% (w/w)b.p.
m.p.

H-Phrases EU-GHS
Signal Word GHS

Pictogram

260.14 g/mol
1.379 g/cm³ (25 °C)
min. 98.0
not applicable–13 °C

Explanation of symbols
M = Mol. Weightd = Density

ChemicalInventory
ENCS/IS% (w/w) = Purity/Content

b.p. = Boiling Point

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

155

9.5

NitrilesNo.

Product[CAS Registry No.]

9.5.1

Baxxodur® PC 136[93940-97-7]

9.5.2

o-Phthalodinitrile[91-15-6]

9.5.3

Suberonitrile[629-40-3]

156

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

276.4 g/mol
0.9878 g/cm³ (20 °C)
min. 95.0> 200 °C
< –20 °C

H302; H317; H412
Warning

REACH;
TSCA;
IECSC

M
d
% (w/w)b.p.
m.p.

128.13 g/mol
1.24 g/cm³ (20 °C)
min. 98.0
304.5 °C
141 – 142 °C

H301; H311; H331; H412
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

136.20 g/mol
0.942 g/cm³ (20 °C)
min. 97.0
325 °C–4 °C

H302
Warning

REACH;TSCA;
IECSC;
ENCS/IS

Explanation of symbols
M = Mol. Weightd = Density% (w/w) = Purity/Content

Pictogramb.p. = Boiling Point

ChemicalInventory

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

157

9.6

Phosphorus Compounds

No.

Product[CAS Registry No.]

9.6.1

Triphenyl phosphine molten[603-35-0]

9.6.2

Triphenyl phosphine pellets[603-35-0]

158

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

262.29 g/mol
1.194 g/cm³ (20 °C)
min. 99.5
195 – 205 °C (7 hPa)
79 – 81 °C

H302; H317; H373
Warning

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

262.29 g/mol
1.194 g/cm³ (20 °C)
min. 99.5
195 – 205 °C (7 hPa)81.3 – 81.6 °C

H302; H317; H373
Warning

REACH;TSCA;
IECSC;
ENCS/IS

Explanation of symbols
M = Mol. Weightd = Density% (w/w) = Purity/Content

Pictogramb.p. = Boiling Point

ChemicalInventory

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

159

9.7

Urea Derivatives

No.

Product[CAS Registry No.]

9.7.1

Ethylene urea
[120-93-4]
Remark 1

9.7.2

N-(2-Hydroxyethyl)ethylene urea
[3699-54-5]
Remark 2

9.7.3

N,N'-Dimethyl propylene urea
[7226-23-5]

9.7.4

N,N'-Dimethyl urea
[96-31-1]

Remarks
1 Available in crystalline form and as 30% aqueous solution
2 Also available as 75% aqueous solution

160

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

86.09 g/mol
not available
87.0 – 90.0
132.6 °C
68.2 °C

H319
WarningMd% (w/w)b.p.
m.p.

130.15 g/mol
1.203 g/cm³ (70 °C)
min. 98.0> 280 °C
54 °C

Md% (w/w)b.p.
m.p.

128.17 g/mol
1.064 g/cm³ (20 °C)
min. 99.0
246.5 °C
–14 °CMd% (w/w)b.p.
m.p.

88.11 g/mol
1.14 g/cm³ (20 °C)
min. 96.5
260 °C
106 °C

Explanation of symbols
M = Mol. Weightd = Density

PictogramChemicalInventory
REACH;TSCA;
IECSC;
ENCS/ISREACH;TSCA;
IECSC;
ENCS/ISH302; H315; H318; H361f
Danger

REACH;
ENCS/ISREACH;TSCA;
IECSC;
ENCS/IS% (w/w) = Purity/Content

b.p. = Boiling Point

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

161

9.8

Vinyl Compounds and Ethers

No.

Product[CAS Registry No.]

9.8.1

1,3-Divinylimidazolidin-2-one[13811-50-2]

9.8.2

1-Vinylimidazole[1072-63-5]

9.8.3

2-Ethylhexyl vinyl ether[103-44-6]

9.8.4

3,4-Dihydro-2H-pyrane[110-87-2]

9.8.5

Butanediol divinyl ether[3891-33-6]

9.8.6

Cyclohexyl vinyl ether[2182-55-0]

9.8.7

Diethyleneglycol divinyl ether[764-99-8]

162

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHS

PictogramChemicalInventoryMd% (w/w)b.p.
m.p.

138.17 g/mol
1.02 g/cm³ (90 °C)
min. 99.0
108 °C (4 hPa)
65 – 67 °CMd% (w/w)b.p.
m.p.

94.12 g/mol
1.039 g/cm³ (20 °C)
min. 99.5
192 °C< –50 °C

H302; H318
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

156.27 g/mol
0.809 g/cm³ (20 °C)
min. 99.0
177 °C–100 °C

H226; H302; H315; H319;
H411
Warning

REACH;
ENCS/ISMd% (w/w)b.p.
m.p.

84.12 g/mol
0.927 g/cm³ (20 °C)
min. 99.0
87 °C–70 °CH225; H315; H319;
EUH019Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

142.20 g/mol
0.898 g/cm³ (20 °C)
min. 95.0
166 °C–8 °C

H226; H412
Warning

REACH;
TSCA;
IECSC

M
d
% (w/w)b.p.
m.p.

126.20 g/mol
0.891 g/cm³ (20 °C)
min. 99.0
150 – 152 °C–109 °C

H226; H315; H412
Warning

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

158.20 g/mol
0.968 g/cm³ (20 °C)
min. 99.5
191 °C–21 °C

Explanation of symbols
M = Mol. Weightd = Density

REACH;IECSC

REACH;TSCA;
IECSC;
ENCS/IS% (w/w) = Purity/Content

b.p. = Boiling Point

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

163

9.8

Vinyl Compounds and Ethers

No.

Product[CAS Registry No.]

9.8.8

Dodecyl vinyl ether[765-14-0]

9.8.9

Ethylvinylether stab. 0.01% KOH[109-92-2]

9.8.10Ethylvinylether stab. 0.1% DEA[109-92-2]

9.8.11Ethylvinylether stab. 0.1% KOH[109-92-2]

9.8.12

Hydroxybutyl vinyl ether[17832-28-9]

9.8.13

Isobutylvinylether stab. 0.1% DEA[109-53-5]

9.8.14

Isobutylvinylether stab. 0.1% KOH[109-53-5]

164

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

212.38 g/mol
0.8165 g/cm³ (20 °C)
min. 99.0
90 °C (1 hPa)
–12 °CH315; H319; H412
Warning

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

72.11 g/mol
0.754 g/cm³ (20 °C)
min. 99.0
36 °C–115 °C

H225; H412
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

72.11 g/mol
0.759 g/cm³ (20 °C)
min. 99.0
36 °C–115 °C

H225; H412
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

72.11 g/mol
0.754 g/cm³ (20 °C)
min. 99.0
36 °C–115 °C

H225; H412
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

116.16 g/mol
0.94 g/cm³ (20 °C)
min. 99.0
189.53 °C–33 °C

H302; H319; H412
Warning

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

100.16 g/mol
0.769 g/cm³ (20 °C)
min. 99.0
83 °C–112 °C

H225; H315; H412
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

100.16 g/mol
0.769 g/cm³ (20 °C)
min. 99.0
83 °C–112 °C

H225; H315; H412
Danger

REACH;TSCA;
IECSC;
ENCS/IS

Explanation of symbols
M = Mol. Weightd = Density% (w/w) = Purity/Content

Pictogramb.p. = Boiling Point

ChemicalInventory

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

165

9.8

Vinyl Compounds and Ethers

No.

Product[CAS Registry No.]9.8.15

Koresin® pellets[28514-92-3]
Remark 1

9.8.16

N-Butyl vinyl ether[111-34-2]

9.8.17Octadecyl vinyl ether[930-02-9]

9.8.18

tert.-Butyl vinyl ether[926-02-3]

9.8.19Triethyleneglycol divinyl ether[765-12-8]

9.8.20Vinyl caprolactam HO-Tempo[2235-00-9]
Remark 2

9.8.21

Vinyl phosphonic acid[1746-03-8]

Remarks
1 Also available as powder
2 New non-toxic stabilizer

166

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHS

PictogramChemicalInventoryMd% (w/w)b.p.
m.p.

not available
1.03 g/cm³ (20 °C)
not available
not available
135 – 150 °CMd% (w/w)b.p.
m.p.

100.16 g/mol
0.779 g/cm³ (20 °C)
min. 99.0
94 °C–113 °C

H225; H315; H412
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

296.54 g/mol
0.812 g/cm³ (40 °C)
80.0 – 89.0
179 – 192 °C (6.7 hPa)
24 – 28 °C

H412

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

100.16 g/mol
0.762 g/cm³ (20 °C)
min. 98.0
76 °C
not available

H225; H412
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

202.25 g/mol
1.00 g/cm³ (20 °C)
min. 98.5
252.9 °C
–12.6 °CMd% (w/w)b.p.
m.p.

139.20 g/mol
1.01 g/cm³ (40 °C)
min. 98.5
113 – 116 °C (13 hPa)
34 °C

H302; H319
Warning

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

108.03 g/mol
1.37 g/cm³ (30 °C)
90.0 – 97.0
not applicable
36 °C

H314
Danger

REACH;TSCA;
IECSC

Explanation of symbols
M = Mol. Weightd = Density

TSCA;
IECSC;
ENCS/ISREACH;TSCA;
IECSC;
ENCS/IS% (w/w) = Purity/Content

b.p. = Boiling Point

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

167

9.9

OthersNo.

Product[CAS Registry No.]

9.9.1

Methanesulfonic acid 100[75-75-2]

9.9.2

Methanesulfonic acid 70%

168

FormulaPhysical Data

H-Phrases EU-GHS
Signal Word GHSMd% (w/w)b.p.
m.p.

96.11 g/mol
1.48 g/cm³ (20 °C)
min. 99.5
167 °C (10 hPa)
20 °C

H290; H314
Danger

REACH;TSCA;
IECSC;
ENCS/ISMd% (w/w)b.p.
m.p.

not available
1.35 g/cm³ (25 °C)
69.5 – 70.5
135 °C–54 °CH290; H314
DangerTSCA;
IECSC;
ENCS/IS

Explanation of symbols
M = Mol. Weightd = Density% (w/w) = Purity/Content

Pictogramb.p. = Boiling Point

ChemicalInventory

m.p. = Melting Point

If not specified, b.p. and m.p. measured at 1013 hPa.

169

Alphabetical Index
Product

Page

Index

110
142
54
56
84
84
142
84
86
102
54
72
54
72
72
110
72
74
72
78
20
66
66
142

7.4.6
9.1.5
4.3.7
4.3.8
5.4.4
5.4.2
9.1.1
5.4.1
5.4.8
7.2.15
4.3.1
4.7.1
4.3.2
4.7.2
4.7.3
7.4.2
4.7.4
5.1.1
4.7.5
5.2.1
2.1.9
4.6.4
4.6.5
9.1.2

148
148
148
148
148
150
150
150
150
150
152
152
152
152
152
152
154
50

9.4.2
9.4.3
9.4.4
9.4.5
9.4.6
9.4.7
9.4.8
9.4.9
9.4.109.4.11
9.4.129.4.139.4.149.4.159.4.169.4.179.4.184.2.10A
N-Acetylmorpholine
N-Acetylmorpholine
N3-Amine 3-(2-Aminoethylamino)propylamine
N4-Amine N,N'-Bis-(3-Aminopropyl)ethylenediamine
5-Amino-1-pentanol sol. 50%
3-Amino-1-propanol
3-Amino-2,2-dimethylpropionicacid amide2-(2-Aminoethoxy)ethanol
N-(2-Aminoethyl)ethanolamine
N-(3-Aminopropyl)imidazole
AMIX 1000
AMIX 1000
AMIX A
AMIX A
AMIX M
AMIX M
AMIX TE
AMIX TE
AMIX TI solution
AMIX TI solution
tert.-Amyl alcohol
AnilineAnthranilic acid amide dry
Anthranilic acid amide dry

B
Basionics™ AL 01 – EMIM Cl : AlCl3 = 1 : 1.5
Basionics™ BC 01
Basionics™ EE 03
Basionics™ FS 01
Basionics™ FS 13
Basionics™ HP 01
Basionics™ LQ 01
Basionics™ LQ 11
Basionics™ OH 01
Basionics™ ST 35
Basionics™ ST 70
Basionics™ ST 80
Basionics™ UV 33
Basionics™ UV 43
Basionics™ VS 01
Basionics™ VS 03
Basionics™ VS 11
Baxxodur ® ECX 210
170

Product

Baxxodur ® PC 136
Baxxodur ® PC 136
Benzophenonimine techn.
Benzylamine
Benzyl chloroformate
N,N-Bis-(3-aminopropyl)methylamine
Butane-2,3-diol
1,4-Butanediol
Butanediol divinyl ether
Butylamine
tert.-Butylamine
4-tert.-Butylcyclohexyl chloroformate
Butyldiethanolamine
Butylethanolamine
N-Butyl vinyl ether
tert.-Butyl vinyl ether
2-Butyne-1,4-diol pure cryst. unstab.
3-Butyne-2-ol 55% sol.
gamma-Butyrolactone dist.

Page

Index

50
156
146
66
14
54
22
22
162
38
44
14
80
80
166
166
22
18
104

4.2.11
9.5.1
9.3.1
4.6.6
1.4.3
4.3.6
2.2.7
2.2.2
9.8.5
4.1.2
4.1.22
1.4.2
5.3.2
5.3.3
9.8.169.8.18
2.2.5
2.1.5
7.3.4

104
94
94
14
126
126
126
126
126
126
124
128
128
128
128
128
128
128
130
130
130
130
130
140
130

7.3.5
7.1.2
7.1.3
1.4.4
8.2.2
8.2.3
8.2.4
8.2.5
8.2.6
8.2.7
8.1.1
8.2.8
8.2.9
8.2.108.2.118.2.128.2.138.2.148.2.158.2.168.2.178.2.188.2.198.3.1
8.2.20C
epsilon-Caprolactone
Carbonate Mix 50
Carbonate Mix 60
Cetyl chloroformate RD
ChiPros® (1R, 2R)-trans-2-Amino cyclopentanol hydrochloride
ChiPros® (1R-trans)-2-(Phenyl methoxy)cyclohexanamine
ChiPros® (1S, 2S)-trans-2-Benzyloxycyclohexylamine
ChiPros® (R)-1-(1-Naphthyl)ethylamine
ChiPros® (R)-1-(2-Methoxyphenyl)ethylamine
ChiPros® (R)-1-(2-Naphthyl)ethylamine
ChiPros® (R)-1-(3,5-Ditrifluormethyl)phenylethanol
ChiPros® (R)-1-(3-Methoxyphenyl)ethylamine
ChiPros® (R)-1-(4-Chlorphenyl)ethylamine
ChiPros® (R)-1-(4-Fluorphenyl)ethylamine
ChiPros® (R)-1-(4-Methoxyphenyl)ethylamine
ChiPros® (R)-1-(4-Methylphenyl)ethylamine
ChiPros® (R)-1-Aminoindane
ChiPros® (R)-1-Aminotetraline
ChiPros® (R)-1-Cyclohexylethylamine
ChiPros® (R)-1-Cyclopropylethylamine
ChiPros® (R)-1-Phenylethylamine
ChiPros® (R)-1-Phenylpropylamine
ChiPros® (R)-2-Aminobutane
ChiPros® (R)-2-Chloromandelic acid
ChiPros® (R)-2-Hexylamine

171

Alphabetical Index
Product

ChiPros® (R)-3-Aminobutan-1-ol
ChiPros® (R)-3-Methyl-2-butylamine
ChiPros® (R)-Isobutyllactate raw (D-LIB)
ChiPros® (R)-Mandelic acid
ChiPros® (R)-N-Benzyl-1-phenylethylamine
ChiPros® (S)-1-(1-Naphthyl)ethylamine
ChiPros® (S)-1-(2-Naphthyl)ethylamine
ChiPros® (S)-1-(3,5-Ditrifluoromethyl)phenylethanol
ChiPros® (S)-1-(3-Methoxyphenyl)ethylamine
ChiPros® (S)-1-(4-Chlorphenyl)ethylamine
ChiPros® (S)-1-(4-Fluorphenyl)ethylamine
ChiPros® (S)-1-(4-Methoxyphenyl)ethylamine
ChiPros® (S)-1-(4-Methylphenyl)ethylamine
ChiPros® (S)-1-Aminoindane
ChiPros® (S)-1-Aminotetraline
ChiPros® (S)-1-Cyclohexylethylamine
ChiPros® (S)-1-Cyclopropylethylamine
ChiPros® (S)-1-Phenylethylamine
ChiPros® (S)-1-Phenylpropylamine
ChiPros® (S)-2-Hexylamine
ChiPros® (S)-2-Pentanol
ChiPros® (S)-3,3-Dimethyl-2-aminobutane
ChiPros® (S)-3-Methyl-2-butylamine
ChiPros® (S)-Butan-2-ol
ChiPros® (S)-Methoxyisopropylamine
ChiPros® (S)-N-Benzyl-1-phenylethylamine
ChiPros® Clophar
ChiPros® Clophas
1-Chloro-3-methoxypropane (standard)
1-Chloro-3-methoxypropane > 99%
1-Chloro-3-methoxypropane Pharma Premium
4-Chlorobutyryl chloride
5-Chlorovaleryl chloride
3-Chlorpropionyl chloride
Cyclododecanone
Cyclododecanone F
Cyclododecatriene
3-(Cyclohexylamino)propylamine
Cyclohexylpyrrolidone
Cyclohexyl vinyl ether
Cyclopentanone
Cyclopentanone P

Page

Index

130
132
140
140
132
132
132
124
132
132
132
134
134
134
134
134
134
134
136
136
124
136
136
124
136
136
136
138
10
10
10
6
6
6
36
36
144
48
104
162
36
36

8.2.218.2.228.3.2
8.3.3
8.2.238.2.248.2.258.1.2
8.2.268.2.278.2.288.2.298.2.308.2.318.2.328.2.338.2.348.2.358.2.368.2.378.1.3
8.2.388.2.398.1.4
8.2.408.2.418.2.428.2.43
1.2.2
1.2.3
1.2.4
1.1.3
1.1.4
1.1.2
3.3.1
3.3.2
9.2.1
4.2.5
7.3.3
9.8.6
3.3.3
3.3.4

38
68

4.1.3
4.6.11

D
Di-(2-ethylhexyl)amine
N,N-Di-(2-hydroxyethyl)aniline
172

Product

N,N-Di-(2-hydroxyethyl)aniline
Di-(2-methoxyethyl)amine
4,4'-Diaminodicyclohexylmethane
4,4'-Diaminodiphenylmethane molten plus
1,3-Diaminopropane
Dibutylamine
Dibutylethanolamine
1,6-Dichlorohexane
Dicyclohexylamine
Diethanolamine pure
Diethanol-para-toluidine
Diethanol-para-toluidine in MMA, 50 : 50
Diethylamine
2-(Diethylamino)ethylamine
3-(Diethylamino)propylamine
Diethylcarbamoyl chloride
Diethyleneglycol divinyl ether
Diethylenetriamine
Diethylethanolamine
Diethylketone
3,4-Dihydro-2H-pyrane
3,4-Dihydro-2H-pyrane
Diisopropanolamine
Diisopropanol-p-toluidine
2-(Diisopropylamino)ethylamine
1,1-Dimethoxy-N,N-dimethyl methanamine
2,5-Dimethyl-2,5-hexanediol
3,3'-Dimethyl-4,4'-diamino-dicyclohexylmethane
N,N-Dimethylacetamide
Dimethylamine anhydrous
3-(Dimethylamino)propylamine
3-Dimethylaminopropane-1-ol
N,N-Dimethylethanolamine S
Dimethylethylamine
Dimethylformamide
N,N-Dimethylisopropanolamine
N,N-Dimethylisopropylamine
Dimethylpropylamine
N,N'-Dimethyl propylene urea
1,4-Dimethylpyrazole
N,N'-Dimethyl urea
4,9-Dioxadodecane-1,12-diamine
1,4-Dioxane
1,4-Dioxane stab.
1,4-Dioxan stab. ultra pure
Dipropylamine
Dipropylene triamine

Page

Index

86
58
50
66
48
38
80
10
38
74
66
68
38
48
48
12
162
54
80
36
94
162
78
68
48
32
22
50
142
38
48
80
82
40
142
82
42
40
160
98
160
58
112
112
112
40
54

5.4.10
4.4.5
4.2.9
4.6.3
4.2.2
4.1.4
5.3.4
1.2.1
4.1.5
5.1.2
4.6.7
4.6.8
4.1.6
4.2.3
4.2.6
1.3.1
9.8.7
4.3.3
5.3.5
3.3.5
7.1.1
9.8.4
5.2.2
4.6.9
4.2.4
3.1.1
2.2.4
4.2.8
9.1.4
4.1.7
4.2.7
5.3.1
5.3.10
4.1.8
9.1.3
5.3.114.1.16
4.1.9
9.7.3
7.2.1
9.7.4
4.4.4
7.5.2
7.5.3
7.5.1
4.1.104.3.4
173

Alphabetical Index
Product

Ditridecylamine mixture of isomers
1,3-Divinylimidazolidin-2-one
N-Dodecyl-2-pyrrolidone
Dodecyl vinyl ether

Page

Index

40
162
106
164

4.1.11
9.8.1
7.3.8
9.8.8

74
18
148
98
98
98
40
14
42
94
10
50
160
80
34
88
6
38
10
14
162
98
98
68
42
116
118
106
164
164
164
18

5.1.3
2.1.6
9.4.1
7.2.4
7.2.5
7.2.6
4.1.12
1.4.5
4.1.177.1.4
1.2.6
4.2.12
9.7.1
5.3.6
3.2.1
6.1.1
1.1.1
4.1.1
1.2.5
1.4.1
9.8.3
7.2.2
7.2.7
4.6.124.1.18
7.7.2
7.8.1
7.3.9
9.8.9
9.8.109.8.11
2.1.1

92
88
88
88
110

6.2.2
6.1.2
6.1.3
6.1.4
7.4.7

E
Ethanolamine mixtures (anhydrous)
4-Ethyl-1-octyn-3-ol
1-Ethyl-3-methyl imidazolium methylcarbonate in methanol
2-Ethyl-4-methylimidazole
2-Ethyl-4-methylimidazole dist.
2-Ethyl-4-methylimidazole S
Ethylamine solution 70%
Ethyl chloroformate
N-Ethyldiisopropylamine
Ethylene carbonate S®
Ethylene chlorohydrine
Ethylenediamine
Ethylene urea
Ethylethanolamine
2-Ethylhexanal
2-Ethylhexanoic acid
2-Ethylhexanoyl chloride
2-Ethylhexylamine
2-Ethylhexylchloride
2-Ethylhexyl chloroformate
2-Ethylhexyl vinyl ether
1-Ethylimidazole
2-Ethylimidazole ultra pure
N-Ethyl-N-(2-hydroxyethyl)aniline
N-Ethyl-N-propylamine azeotrope
N-Ethylpiperazine
N-Ethylpiperidine
N-Ethylpyrrolidone-2
Ethylvinylether stab. 0.01% KOH
Ethylvinylether stab. 0.1% DEA
Ethylvinylether stab. 0.1% KOH
1-Ethynyl-1-cyclohexanol

F
Formamide
Formic acid 85%
Formic acid 94%
Formic acid 99 – 100%
N-Formylmorpholine
174

Product

N-Formylmorpholine
3-Formylpinan raw
4-Formyltetrahydropyran

Page

Index

142
34
122

9.1.6
3.2.3
7.10.1

34
34
34

3.2.4
3.2.5
3.2.6

24
24
6
16
22
84
164
104
104
68
86
160
84
110
92
116
24
24

2.2.8
2.2.9
1.1.5
1.4.8
2.2.6
5.4.5
9.8.127.3.6
7.3.7
4.6.10
5.4.9
9.7.2
5.4.3
7.4.1
6.2.1
7.7.1
2.2.102.2.11

100
100
92
114
164
164
6
88
6
50
78
40
8

7.2.107.2.11
6.2.3
7.6.1
9.8.139.8.14
1.1.6
6.1.6
1.1.7
4.2.13
5.2.3
4.1.13
1.1.8

GGlutaraldehyde 24% sol.
Glutaraldehyde 50% solution low methanol
Glyoxal 40%

H
HDO® 1,6-Hexanediol flakes
HDO® 1,6-Hexanediol molten
Heptane acid chloriden-Hexyl chloroformate
3-Hexyne-2,5-diolHydoxyethylpiperazine
Hydroxybutyl vinyl ether
N-(2-Hydroxyethyl)-2-pyrrolidone
N-(2-Hydroxyethyl)-2-pyrrolidone 95%
N-(2-Hydroxyethyl)aniline
N-(2-Hydroxyethyl)aniline
N-(2-Hydroxyethyl)ethylene urea
4-(2-Hydroxyethyl)morpholine
4-(2-Hydroxyethyl)morpholine
2-Hydroxyethyl carbamate
Hydroxyethylpiperazine
Hydroxypivalic acid neopentylglycolester flakes
Hydroxypivalic acid neopentylglycolester molten

I
Imidazole
Imidazole aqueous solution 50%
Isatoic anhydride dry
Isobutyleneoxide
Isobutylvinylether stab. 0.1% DEA
Isobutylvinylether stab. 0.1% KOH
Isobutyryl chloride
Isononanoic acid C
Isononanoyl chloride
Isophorone diamine
Isopropanolamine
Isopropylamine anhydrous
Isovaleroyl chloride

175

Alphabetical Index
Product

Page

Index

166

9.8.15

100
100
40
62
62
80
62
110
62
110
62
84
62
112
62
112
58
64
54
64
64
84
52
64
64
64
112
100

7.2.127.2.134.1.14
4.5.1
4.5.2
5.3.7
4.5.3
7.4.3
4.5.4
7.4.4
4.5.5
5.4.6
4.5.6
7.5.4
4.5.7
7.5.5
4.4.6
4.5.8
4.3.5
4.5.9
4.5.10
5.4.7
4.2.144.5.11
4.5.124.5.13
7.5.6
7.2.14

18
168
168
58
58
18
142
14
82
82

2.1.2
9.9.1
9.9.2
4.4.1
4.4.2
2.1.3
9.1.7
1.4.6
5.3.8
5.3.9

K
Koresin® pellets

L
Lupragen® API – N-(3-Aminopropyl)imidazole
Lupragen® DMI – 1,2-Dimethylimidazole
Lupragen® N 100 – N,N-Dimethylcyclohexylamine
Lupragen® N 100 – N,N-Dimethylcyclohexylamine
Lupragen® N 101 – Dimethylethanolamine
Lupragen® N 101 – Dimethylethanolamine
Lupragen® N 105 – N-Methylmorpholine
Lupragen® N 105 – N-Methylmorpholine
Lupragen® N 106 – 2,2'-Dimorpholinodiethylether
Lupragen® N 106 – 2,2'-Dimorpholinodiethylether
Lupragen® N 107 – Dimethylaminoethoxyethanol
Lupragen® N 107 – Dimethylaminoethoxyethanol
Lupragen® N 201 – Triethylenediamine in dipropyleneglycol
Lupragen® N 201 – Triethylenediamine in dipropyleneglycol
Lupragen® N 203 – Triethylenediamine in monoethyleneglycol
Lupragen® N 203 – Triethylenediamine in monoethyleneglycol
Lupragen® N 205 – Bis(2-dimethylaminoethyl)ether
Lupragen® N 205 – Bis(2-dimethylaminoethyl)ether
Lupragen® N 301 – Pentamethyldietylenetriamine
Lupragen® N 301 – Pentamethyldietylenetriamine
Lupragen® N 400 – Trimethylaminoethylethanolamine
Lupragen® N 400 – Trimethylaminoethylethanolamine
Lupragen® N 500 – Tetramethyl-1,6-hexanediamine
Lupragen® N 500 – Tetramethyl-1,6-hexanediamine
Lupragen® N 600 – S-Triazine
Lupragen® N 700 – 1,8-Diazabicyclo-5,4,0-undecene-7
Lupragen® N 700 – 1,8-Diazabicyclo-5,4,0-undecene-7
Lupragen® NMI – N-MethylimidazoleM
2-Mercaptoethanol
Methanesulfonic acid 100
Methanesulfonic acid 70%
2-Methoxyethylamine
3-Methoxypropylamine
2-Methyl-3-butyn-2-ol
N-Methylacetamide
Methyl chloroformate
Methyldiethanolamine
Methyldiisopropanolamine
176

Product

N-Methylethanolamine
Methyl formate pure
1-Methylimidazole
2-Methylimidazole flakes
2-Methylimidazole pure
N-Methyl-N-isopropylamine
2-Methylpentanal
N-Methylpiperazine
N-Methylpiperidine 80% calc. 100%
N-Methylpyrrolidine
N-Methylpyrrolidone dist.
N-Methylpyrrolidone Life Science
Monoethanolamine pure
Monomethylamine anhydrous
Morpholine
Myristyl chloroformate

Page

Index

82
92
98
100
100
42
34
116
118
120
106
106
74
42
110
14

5.3.12
6.2.4
7.2.3
7.2.8
7.2.9
4.1.19
3.2.2
7.7.3
7.8.2
7.9.1
7.3.107.3.11
5.1.4
4.1.15
7.4.5
1.4.7

8
24
24
24
52
70
88

1.1.9
2.2.122.2.132.2.144.2.164.6.14
6.1.5

166
52
8
106
42

9.8.174.2.171.1.107.3.124.1.20

22
22
66
126
156
116
118
8
58
60

2.2.1
2.2.3
4.6.2
8.2.1
9.5.2
7.7.4
7.8.3
1.1.11
4.4.7
4.4.8

N
Neodecanoyl chloride
Neol ® Neopentylglycol flakes
Neol ® Neopentylglycol pure liquid
Neol ® Neopentylglycol sol. 90% fix calc. 100%
Neopentanediamine (2,2-Dimethyl propane-1,3-diamine)p-Nitrotoluene purei-Nonanoic acidO
Octadecyl vinyl ether
Octamethylenediamine
Octanoyl chloride
N-Octyl-2-pyrrolidone dist.
N-OctylamineP
1,2-Pentanediol
1,5-Pentanediol
2-Phenylethylamine
1-Phenylethylamineo-Phthalodinitrile
Piperazine
Piperidine
Pivaloyl chloride
Polyetheramine D 2000
Polyetheramine D 230

177

Alphabetical Index
Product

Polyetheramine D 400
Polyetheramine T 403
Polyetheramine T 5000
PolyTHF ® 1000
PolyTHF ® 1000 S
PolyTHF ® 1400
PolyTHF ® 1800
PolyTHF ® 2000
PolyTHF ® 250 techn.
PolyTHF ® 650 S
Propargyl alcohol 50%
Propargyl alcohol highly conc.
Propionic acid pure
Propionyl chloride
Propylamine
Propyl chloroformate
Propylene carbonate S®
1,2-Propylenediamine techn.
Pyrrolidine pure
2-Pyrrolidone crude
2-Pyrrolidone dist.

Page

Index

60
60
60
26
26
26
26
26
26
26
18
20
88
8
42
16
94
48
120
104
104

4.4.9
4.4.104.4.112.2.152.2.162.2.172.2.182.2.192.2.202.2.21
2.1.7
2.1.8
6.1.7
1.1.124.1.21
1.4.9
7.1.5
4.2.1
7.9.2
7.3.1
7.3.2

90
156

6.1.8
9.5.3

122
52
94
94
96
28
28
28
28
28
28
30
30
68
44
44
74
74

7.10.24.2.15
7.1.6
7.1.7
7.1.8
2.2.222.2.232.2.242.2.252.2.262.2.272.2.282.2.294.6.134.1.234.1.24
5.1.5
5.1.6

S
Sarcosine sodium 40% sol.
Suberonitrile

T
Tetrahydropyran-4-carboxylic acid methylester
N,N,N',N'-Tetramethyl-1,3-propane diamine
THF Pharma non-stab.
THF Pharma stab.
THF Pharma stab. super dry
Thiodiglycol
Thiodiglycol HP
Thiodiglycol ultra
TMDD 100%
TMDD 440
TMDD 50% BG
TMDD 50% EG
TMDD 50% PG
o-Toluidine pure
Tributylamine
Tridecylamine mixture of isomers
Triethanolamine pure
Triethanolamine S
178

Product

Triethanolamine T 85
Triethylamine anhydrous
Triethyleneglycol divinyl ether
Triisopropanolamine
Trimethylamine anhydrous
Trimethylaminehydrochloride sol. 70%
3,7,11-Trimethyldodecyn-3-ol
4,7,10-Trioxatridecane-1,13-diamine
Triphenyl phosphine molten
Triphenyl phosphine pellets
Tripropylamine
Tris-(2-ethylhexyl)amine

Page

Index

76
44
166
78
44
44
18
58
158
158
44
46

5.1.7
4.1.259.8.195.2.4
4.1.264.1.27
2.1.4
4.4.3
9.6.1
9.6.2
4.1.284.1.29

106
8
106
108
108
108
166
96
162
166

7.3.13
1.1.137.3.147.3.167.3.157.3.179.8.20
7.1.9
9.8.2
9.8.21

66

4.6.1

V
delta-Valerolactone
Valeroyl chloride
N-Vinyl-2-pyrrolidone stab. 0.1% NaOH
N-Vinyl-2-pyrrolidone stab. 100 ppm Kerobit
N-Vinyl-2-pyrrolidone stab. 10 ppm Kerobit
N-Vinyl-2-pyrrolidone stab. 25 ppm Kerobit
Vinyl caprolactam HO-Tempo
Vinylene carbonate E
1-Vinylimidazole
Vinyl phosphonic acidX
2,6-Xylidine

179

CAS Registry No. Index
CAS Registry No.

Product

56-18-8
60-24-2
62-53-3
64-04-0
64-18-6
64-18-6
64-18-6
68-12-2
74-89-5
75-04-7
75-05-8
75-12-7
75-31-075-50-3
75-64-975-75-2
75-85-4
78-27-3
78-90-0
78-96-6
79-03-8
79-09-4
79-16-3
79-22-1
79-30-1
87-62-7
88-10-8
88-12-0
88-12-0
88-12-0
88-12-0
88-68-6
88-68-6
91-15-6
92-50-2
95-53-4
96-22-0
96-31-1
96-48-0
96-49-1
98-94-2
98-94-2
99-99-0
100-36-7
100-37-8

Dipropylene triamine
2-Mercaptoethanol
Aniline2-Phenylethylamine
Formic acid 85%
Formic acid 94%
Formic acid 99 – 100%
Dimethylformamide
Monomethylamine anhydrous
Ethylamine solution 70%
Basionics™ FS 13
Formamide
Isopropylamine anhydrous
Trimethylamine anhydrous
tert.-Butylamine
Methanesulfonic acid 100
tert.-Amyl alcohol
1-Ethynyl-1-cyclohexanol
1,2-Propylenediamine techn.
Isopropanolamine
Propionyl chloride
Propionic acid pure
N-Methylacetamide
Methyl chloroformate
Isobutyryl chloride
2,6-Xylidine
Diethylcarbamoyl chloride
N-Vinyl-2-pyrrolidone stab. 0.1% NaOH
N-Vinyl-2-pyrrolidone stab. 100 ppm Kerobit
N-Vinyl-2-pyrrolidone stab. 10 ppm Kerobit
N-Vinyl-2-pyrrolidone stab. 25 ppm Kerobit
Anthranilic acid amide dry
Anthranilic acid amide dryo-Phthalodinitrile
N-Ethyl-N-(2-hydroxyethyl)aniline
o-Toluidine pure
Diethylketone
N,N'-Dimethyl urea
gamma-Butyrolactone dist.
Ethylene carbonate S®
Lupragen® N 100 – N,N-Dimethylcyclohexylamine
Lupragen® N 100 – N,N-Dimethylcyclohexylamine
p-Nitrotoluene pure2-(Diethylamino)ethylamine
Diethylethanolamine

180

Page

Index

54
18
66
66
88
88
88
142
42
40
148
92
40
44
44
168
20
18
48
78
8
88
142
14
6
66
12
106
108
108
108
66
142
156
68
68
36
160
104
94
40
62
70
48
80

4.3.4
2.1.2
4.6.4
4.6.2
6.1.2
6.1.3
6.1.4
9.1.3
4.1.154.1.12
9.4.6
6.2.2
4.1.134.1.264.1.22
9.9.1
2.1.9
2.1.1
4.2.1
5.2.3
1.1.12
6.1.7
9.1.7
1.4.6
1.1.6
4.6.1
1.3.1
7.3.147.3.167.3.157.3.17
4.6.5
9.1.2
9.5.2
4.6.124.6.13
3.3.5
9.7.4
7.3.4
7.1.4
4.1.144.5.1
4.6.144.2.3
5.3.5

CAS Registry No.

Product

100-46-9
101-77-9
101-83-7
102-69-2
102-71-6
102-71-6
102-71-6
102-79-4
102-81-8
102-82-9
103-44-6
103-76-4
103-76-4
104-75-6
104-78-9
105-59-9
105-83-9
106-20-7
107-07-3
107-10-8
107-15-3
107-19-7
107-19-7
107-22-2
107-31-3
108-01-0
108-01-0
108-01-0
108-12-3
108-16-7
108-32-7
109-01-3
109-02-4
109-02-4
109-53-5
109-53-5
109-55-7
109-61-5
109-73-9
109-76-2
109-83-1
109-85-3
109-89-7
109-92-2
109-92-2

Benzylamine
4,4'-Diaminodiphenylmethane molten plus
Dicyclohexylamine
Tripropylamine
Triethanolamine pure
Triethanolamine S
Triethanolamine T 85
Butyldiethanolamine
Dibutylethanolamine
Tributylamine
2-Ethylhexyl vinyl ether
Hydoxyethylpiperazine
Hydroxyethylpiperazine
2-Ethylhexylamine
3-(Diethylamino)propylamine
Methyldiethanolamine
N,N-Bis-(3-aminopropyl)methylamine
Di-(2-ethylhexyl)amine
Ethylene chlorohydrine
Propylamine
Ethylenediamine
Propargyl alcohol 50%
Propargyl alcohol highly conc.
Glyoxal 40%
Methyl formate pure
N,N-Dimethylethanolamine S
Lupragen® N 101 – Dimethylethanolamine
Lupragen® N 101 – Dimethylethanolamine
Isovaleroyl chloride
N,N-Dimethylisopropanolamine
Propylene carbonate S®
N-Methylpiperazine
Lupragen® N 105 – N-Methylmorpholine
Lupragen® N 105 – N-Methylmorpholine
Isobutylvinylether stab. 0.1% DEA
Isobutylvinylether stab. 0.1% KOH
3-(Dimethylamino)propylamine
Propyl chloroformate
Butylamine
1,3-Diaminopropane
N-Methylethanolamine
2-Methoxyethylamine
Diethylamine
Ethylvinylether stab. 0.01% KOH
Ethylvinylether stab. 0.1% DEA

Page

Index

66
66
38
44
74
74
76
80
80
44
162
84
116
38
48
82
54
38
10
42
50
18
20
34
92
82
62
80
8
82
94
116
62
110
164
164
48
16
38
48
82
58
38
164
164

4.6.6
4.6.3
4.1.5
4.1.28
5.1.5
5.1.6
5.1.7
5.3.2
5.3.4
4.1.23
9.8.3
5.4.5
7.7.1
4.1.1
4.2.6
5.3.8
4.3.6
4.1.3
1.2.6
4.1.214.2.12
2.1.7
2.1.8
3.2.6
6.2.4
5.3.10
4.5.2
5.3.7
1.1.8
5.3.11
7.1.5
7.7.3
4.5.3
7.4.3
9.8.139.8.14
4.2.7
1.4.9
4.1.2
4.2.2
5.3.12
4.4.1
4.1.6
9.8.9
9.8.10181

CAS Registry No. Index
CAS Registry No.

Product

109-92-2
109-99-9
109-99-9
109-99-9
110-03-2
110-63-4
110-65-6
110-73-6
110-85-0
110-87-2
110-87-2
110-89-4
110-91-8
110-95-2
110-97-4
111-18-2
111-18-2
111-29-5
111-30-8
111-30-8
111-34-2
111-40-0
111-41-1
111-42-2
111-48-8
111-48-8
111-48-8
111-64-8
111-75-1
111-86-4
111-92-2
111-95-5
115-19-5
118-48-9
120-07-0
120-07-0
120-92-3
120-92-3
120-93-4
120-94-5
121-05-1
121-44-8
122-20-3
122-20-3
122-20-3

Ethylvinylether stab. 0.1% KOH
THF Pharma non-stab.
THF Pharma stab.
THF Pharma stab. super dry
2,5-Dimethyl-2,5-hexanediol
1,4-Butanediol
2-Butyne-1,4-diol pure cryst. unstab.
Ethylethanolamine
Piperazine
3,4-Dihydro-2H-pyrane
3,4-Dihydro-2H-pyrane
Piperidine
Morpholine
N,N,N',N'-Tetramethyl-1,3-propane diamine
Diisopropanolamine
Lupragen® N 500 – Tetramethyl-1,6-hexanediamine
Lupragen® N 500 – Tetramethyl-1,6-hexanediamine
1,5-Pentanediol
Glutaraldehyde 24% sol.
Glutaraldehyde 50% solution low methanol
N-Butyl vinyl ether
Diethylenetriamine
N-(2-Aminoethyl)ethanolamine
Diethanolamine pureThiodiglycol
Thiodiglycol HP
Thiodiglycol ultra
Octanoyl chloride
Butylethanolamine
N-Octylamine
Dibutylamine
Di-(2-methoxyethyl)amine
2-Methyl-3-butyn-2-ol
Isatoic anhydride dry
N,N-Di-(2-hydroxyethyl)aniline
N,N-Di-(2-hydroxyethyl)aniline
Cyclopentanone
Cyclopentanone P
Ethylene urea
N-Methylpyrrolidine
2-(Diisopropylamino)ethylamine
Triethylamine anhydrous
AMIX TI solution
AMIX TI solution
Triisopropanolamine

182

Page

Index

164
94
94
96
22
22
22
80
116
94
162
118
110
52
78
52
64
22
34
34
166
54
86
74
28
28
28
8
80
42
38
58
18
92
68
86
36
36
160
120
48
44
72
78
78

9.8.11
7.1.6
7.1.7
7.1.8
2.2.4
2.2.2
2.2.5
5.3.6
7.7.4
7.1.1
9.8.4
7.8.3
7.4.5
4.2.155.2.2
4.2.144.5.11
2.2.3
3.2.4
3.2.5
9.8.16
4.3.3
5.4.8
5.1.2
2.2.222.2.232.2.241.1.10
5.3.3
4.1.20
4.1.4
4.4.5
2.1.3
6.2.3
4.6.11
5.4.10
3.3.3
3.3.4
9.7.1
7.9.1
4.2.4
4.1.25
4.7.5
5.2.1
5.2.4

CAS Registry No.

Product

122-98-5
122-98-5
123-04-6
123-05-7
123-15-9
123-75-1
123-91-1
123-91-1
123-91-1
124-40-3
126-30-7
126-30-7
126-30-7
126-86-3
126-86-3
126-86-3
126-86-3
127-19-5
141-43-5
142-84-7
149-57-5
156-87-6
280-57-9
280-57-9
280-57-9N-(2-Hydroxyethyl)aniline
N-(2-Hydroxyethyl)aniline
2-Ethylhexylchloride
2-Ethylhexanal
2-Methylpentanal
Pyrrolidine pure
1,4-Dioxane
1,4-Dioxane stab.
1,4-Dioxan stab. ultra pure
Dimethylamine anhydrous
Neol ® Neopentylglycol flakes
Neol ® Neopentylglycol pure liquid
Neol ® Neopentylglycol sol. 90% fix calc. 100%
TMDD 100%
TMDD 50% BG
TMDD 50% EG
TMDD 50% PG
N,N-Dimethylacetamide
Monoethanolamine pure
Dipropylamine
2-Ethylhexanoic acid
3-Amino-1-propanol
Lupragen® N 201 – Triethylenediamine in dipropyleneglycol
Lupragen® N 201 – Triethylenediamine in dipropyleneglycol
Lupragen® N 203 – Triethylenediamine
in monoethyleneglycol
Lupragen® N 203 – Triethylenediamine
in monoethyleneglycol
Imidazole
Octamethylenediamine
Benzyl chloroformate
epsilon-Caprolactone
Butane-2,3-diol
Ethyl chloroformatedelta-Valerolactone
Isobutyleneoxide
Trimethylaminehydrochloride sol. 70%
Dimethylethylamine
Triphenyl phosphine molten
Triphenyl phosphine pellets
ChiPros® (R)-Mandelic acid
2-Pyrrolidone crude
2-Pyrrolidone dist.
Lupragen® NMI – N-Methylimidazole
1-Methylimidazole

280-57-9
288-32-4
373-44-4
501-53-1
502-44-3
513-85-9
541-41-3
542-28-9
558-30-5
593-81-7
598-56-1
603-35-0
603-35-0
611-71-2
616-45-5
616-45-5
616-47-7
616-47-7

Page

Index

68
86
10
34
34
120
112
112
112
38
24
24
24
28
28
30
30
142
74
40
88
84
62
112

4.6.10
5.4.9
1.2.5
3.2.1
3.2.2
7.9.2
7.5.2
7.5.3
7.5.1
4.1.7
2.2.122.2.132.2.142.2.252.2.272.2.282.2.299.1.4
5.1.4
4.1.10
6.1.1
5.4.2
4.5.6
7.5.4

62

4.5.7

112
100
52
14
104
22
14
106
114
44
40
158
158
140
104
104
100
98

7.5.5
7.2.104.2.17
1.4.3
7.3.5
2.2.7
1.4.5
7.3.137.6.1
4.1.27
4.1.8
9.6.1
9.6.2
8.3.3
7.3.1
7.3.2
7.2.14
7.2.3

183

CAS Registry No. Index
CAS Registry No.

Product

618-36-0
622-40-2
622-40-2
625-36-5
626-67-5
629-11-8
629-11-8
629-40-3
638-29-9
693-98-1
693-98-1
760-67-8
764-99-8
765-12-8
765-14-0
766-09-6
830-13-7
830-13-7
872-36-6
872-50-4
872-50-4
926-02-3
926-63-6
929-06-6
930-02-9
931-36-2
931-36-2
931-36-2
996-35-0
1013-88-3
1072-62-4
1072-63-5
1072-68-0
1115-20-4
1115-20-4
1575-61-7
1604-35-9
1696-20-4
1696-20-4
1704-62-7
1704-62-7
1739-84-0
1746-03-8
1761-71-3
1860-26-0

1-Phenylethylamine
4-(2-Hydroxyethyl)morpholine
4-(2-Hydroxyethyl)morpholine
3-Chlorpropionyl chloride
N-Methylpiperidine 80% calc. 100%
HDO® 1,6-Hexanediol flakes
HDO® 1,6-Hexanediol molten
Suberonitrile
Valeroyl chloride
2-Methylimidazole flakes
2-Methylimidazole pure
2-Ethylhexanoyl chloride
Diethyleneglycol divinyl ether
Triethyleneglycol divinyl ether
Dodecyl vinyl ether
N-Ethylpiperidine
Cyclododecanone
Cyclododecanone F
Vinylene carbonate E
N-Methylpyrrolidone dist.
N-Methylpyrrolidone Life Sciencetert.-Butyl vinyl ether
Dimethylpropylamine
2-(2-Aminoethoxy)ethanol
Octadecyl vinyl ether
2-Ethyl-4-methylimidazole
2-Ethyl-4-methylimidazole dist.
2-Ethyl-4-methylimidazole S
N,N-Dimethylisopropylamine
Benzophenonimine techn.
2-Ethylimidazole ultra pure
1-Vinylimidazole
1,4-Dimethylpyrazole
Hydroxypivalic acid neopentylglycolester flakes
Hydroxypivalic acid neopentylglycolester molten
5-Chlorovaleryl chloride
3,7,11-Trimethyldodecyn-3-ol
N-Acetylmorpholine
N-Acetylmorpholine
Lupragen® N 107 – Dimethylaminoethoxyethanol
Lupragen® N 107 – Dimethylaminoethoxyethanol
Lupragen® DMI – 1,2-Dimethylimidazole
Vinyl phosphonic acid
4,4'-Diaminodicyclohexylmethane
Tris-(2-ethylhexyl)amine

184

Page

Index

126
84
110
6
118
24
24
156
8
100
100
6
162
166
164
118
36
36
96
106
106
166
40
84
166
98
98
98
42
146
98
162
98
24
24
6
18
110
142
62
84
100
166
50
46

8.2.1
5.4.3
7.4.1
1.1.2
7.8.2
2.2.8
2.2.9
9.5.3
1.1.13
7.2.8
7.2.9
1.1.1
9.8.7
9.8.19
9.8.8
7.8.1
3.3.1
3.3.2
7.1.9
7.3.107.3.11
9.8.184.1.9
5.4.1
9.8.17
7.2.4
7.2.5
7.2.6
4.1.16
9.3.1
7.2.7
9.8.2
7.2.1
2.2.102.2.11
1.1.4
2.1.4
7.4.6
9.1.5
4.5.5
5.4.6
7.2.139.8.214.2.9
4.1.29

CAS Registry No.

Product

2028-63-9
2163-00-0
2182-55-0
2212-32-0
2212-32-0
2235-00-9
2508-29-4
2528-61-2
2627-86-3
2687-91-4
2687-94-7
2687-96-9
2855-13-2
3030-47-5
3030-47-5
3031-66-1
3033-62-3
3033-62-3
3077-12-1
3082-62-0
3082-64-2
3179-63-3
3282-30-2
3302-10-1
3302-10-1
3312-60-5
3445-11-2
3445-11-2
3699-54-5
3789-59-1
3886-69-9
3886-70-2
3891-33-6
3906-16-9
4187-38-6
4187-56-8
4221-99-2
4246-51-9
4316-73-8
4394-85-8
4394-85-8
4402-30-6
4635-59-0
4637-24-5
4747-21-1

3-Butyne-2-ol 55% sol.
1,6-Dichlorohexane
Cyclohexyl vinyl ether
Lupragen® N 400 – Trimethylaminoethylethanolamine
Lupragen® N 400 – Trimethylaminoethylethanolamine
Vinyl caprolactam HO-Tempo
5-Amino-1-pentanol sol. 50%
Heptane acid chloride
ChiPros® (S)-1-Phenylethylamine
N-Ethylpyrrolidone-2
N-Octyl-2-pyrrolidone dist.
N-Dodecyl-2-pyrrolidone
Isophorone diamine
Lupragen® N 301 – Pentamethyldietylenetriamine
Lupragen® N 301 – Pentamethyldietylenetriamine
3-Hexyne-2,5-diol
Lupragen® N 205 – Bis(2-dimethylaminoethyl)ether
Lupragen® N 205 – Bis(2-dimethylaminoethyl)ether
Diethanol-para-toluidine
ChiPros® (S)-1-(2-Naphthyl)ethylamine
ChiPros® (R)-1-Phenylpropylamine
3-Dimethylaminopropane-1-ol
Pivaloyl chloride
Isononanoic acid C
i-Nonanoic acid
3-(Cyclohexylamino)propylamine
N-(2-Hydroxyethyl)-2-pyrrolidone
N-(2-Hydroxyethyl)-2-pyrrolidone 95%
N-(2-Hydroxyethyl)ethylene urea
ChiPros® (S)-1-Phenylpropylamine
ChiPros® (R)-1-Phenylethylamine
ChiPros® (R)-1-(1-Naphthyl)ethylamine
Butanediol divinyl ether
ChiPros® (R)-1-(2-Naphthyl)ethylamine
ChiPros® (R)-1-(4-Methylphenyl)ethylamine
ChiPros® Clophas
ChiPros® (S)-Butan-2-ol
4,7,10-Trioxatridecane-1,13-diamine
Sarcosine sodium 40% sol.
N-Formylmorpholine
N-Formylmorpholine
Methyldiisopropanolamine
4-Chlorobutyryl chloride
1,1-Dimethoxy-N,N-dimethyl methanamine
N-Methyl-N-isopropylamine

Page

Index

18
10
162
64
84
166
84
6
134
106
106
106
50
54
64
22
58
64
66
132
130
80
8
88
88
48
104
104
160
136
130
126
162
126
128
138
124
58
90
110
142
82
6
32
42

2.1.5
1.2.1
9.8.6
4.5.10
5.4.7
9.8.205.4.4
1.1.5
8.2.357.3.9
7.3.127.3.8
4.2.13
4.3.5
4.5.9
2.2.6
4.4.6
4.5.8
4.6.7
8.2.258.2.185.3.1
1.1.11
6.1.6
6.1.5
4.2.5
7.3.6
7.3.7
9.7.2
8.2.368.2.17
8.2.5
9.8.5
8.2.7
8.2.128.2.43
8.1.4
4.4.3
6.1.8
7.4.7
9.1.6
5.3.9
1.1.3
3.1.1
4.1.19185

CAS Registry No. Index
CAS Registry No.

Product

Page

Index

4904-61-4
5036-48-6
5036-48-6
5308-25-8
5332-73-0
5343-92-0
5395-01-7
5877-42-9
5913-13-3
6092-54-2
6240-96-6
6299-02-1
6299-02-1
6425-39-4
6425-39-4
6674-22-2
6674-22-2
6837-24-7
6864-37-5
7087-68-5
7098-07-9
7226-23-5
7300-34-7
7328-91-8
9014-85-1
9046-10-0
9046-10-0
9046-10-010277-74-4
10420-89-0
10563-26-5
13250-12-913531-52-7
13811-50-2
15875-13-5
17430-98-7
17480-69-2
17832-28-9
20193-20-8
22038-86-4
22526-46-1
22526-47-2
23357-46-2
23357-52-0
24468-13-1

Cyclododecatriene
144
N-(3-Aminopropyl)imidazole
102
100
Lupragen® API – N-(3-Aminopropyl)imidazole
N-Ethylpiperazine
116
3-Methoxypropylamine
58
1,2-Pentanediol
22
2-Hydroxyethyl carbamate
92
4-Ethyl-1-octyn-3-ol
18
130
ChiPros® (R)-1-Cyclohexylethylamine
n-Hexyl chloroformate
16130
ChiPros® (R)-1-Cyclopropylethylamine
128
ChiPros® (R)-1-(4-Chlorphenyl)ethylamine
132
ChiPros® (S)-1-(4-Chlorphenyl)ethylamine
62
Lupragen® N 106 – 2,2'-Dimorpholinodiethylether
110
Lupragen® N 106 – 2,2'-Dimorpholinodiethylether
64
Lupragen® N 700 – 1,8-Diazabicyclo-5,4,0-undecene-7
Lupragen® N 700 – 1,8-Diazabicyclo-5,4,0-undecene-7 112
Cyclohexylpyrrolidone
104
3,3'-Dimethyl-4,4'-diamino-dicyclohexylmethane
50
N-Ethyldiisopropylamine
42
1-Ethylimidazole
98
N,N'-Dimethyl propylene urea
160
4,9-Dioxadodecane-1,12-diamine
58
Neopentanediamine (2,2-Dimethyl propane-1,3-diamine) 52
TMDD 440
28
Polyetheramine D 2000
58
Polyetheramine D 230
60
Polyetheramine D 400
60
128
ChiPros® (R)-1-Aminoindane
132
ChiPros® (S)-1-(1-Naphthyl)ethylamine
N4-Amine N,N'-Bis-(3-Aminopropyl)ethylenediamine
56
130
ChiPros® (R)-2-Aminobutane
N3-Amine 3-(2-Aminoethylamino)propylamine
54
1,3-Divinylimidazolidin-2-one
162
64
Lupragen® N 600 – S-Triazine
134
ChiPros® (S)-1-Cyclohexylethylamine
136
ChiPros® (S)-N-Benzyl-1-phenylethylamine
Hydroxybutyl vinyl ether
164
N-Ethyl-N-propylamine azeotrope
42
128
ChiPros® (R)-1-(4-Methoxyphenyl)ethylamine
136
ChiPros® (S)-3-Methyl-2-butylamine
ChiPros® (S)-3,3-Dimethyl-2-aminobutane
136
128
ChiPros® (R)-1-Aminotetraline
134
ChiPros® (S)-1-Aminotetraline
2-Ethylhexyl chloroformate
14

9.2.1
7.2.157.2.12
7.7.2
4.4.2
2.2.1
6.2.1
2.1.6
8.2.151.4.8
8.2.168.2.9
8.2.274.5.4
7.4.4
4.5.13
7.5.6
7.3.3
4.2.8
4.1.17
7.2.2
9.7.3
4.4.4
4.2.162.2.26
4.4.7
4.4.8
4.4.9
8.2.138.2.244.3.8
8.2.194.3.7
9.8.1
4.5.128.2.338.2.41
9.8.124.1.188.2.118.2.398.2.388.2.148.2.32
1.4.1

186

CAS Registry No.

Product

25190-06-1
25190-06-1
25190-06-1
25190-06-1
25190-06-1
25190-06-1
25190-06-1
26184-62-3
26272-90-2
27298-98-2
27298-99-3
28514-92-3
34701-33-2
36215-07-3
36215-07-3
36215-07-3
36727-29-4
38235-77-7
38668-48-3
39423-51-3
40292-82-8
41851-59-6
42125-46-2
50675-18-8
52950-18-2
56677-60-2
60113-43-1
61341-86-4
61477-40-5
61597-96-4
64852-22-8
65039-09-0
66399-30-2
68285-23-4
68327-11-7

PolyTHF ® 1000
PolyTHF ® 1000 S
PolyTHF ® 1400
PolyTHF ® 1800
PolyTHF ® 2000
PolyTHF ® 250 techn.
PolyTHF ® 650 S
ChiPros® (S)-2-Pentanol
Cetyl chloroformate RD
ChiPros® (S)-1-(4-Methylphenyl)ethylamine
ChiPros® Clophar
Koresin® pellets
ChiPros® (R)-3-Methyl-2-butylamine
1-Chloro-3-methoxypropane (standard)
1-Chloro-3-methoxypropane >99%
1-Chloro-3-methoxypropane Pharma Premium
Isononanoyl chloride
ChiPros® (R)-N-Benzyl-1-phenylethylamine
Diisopropanol-p-toluidine
Polyetheramine T 403
Neodecanoyl chloride
ChiPros® (S)-1-(4-Methoxyphenyl)ethylamine
4-tert.-Butylcyclohexyl chloroformate
4-Formyltetrahydropyran
ChiPros® (R)-2-Chloromandelic acid
Myristyl chloroformate
3-Formylpinan raw
ChiPros® (S)-1-Aminoindane
ChiPros® (R)-3-Aminobutan-1-ol
ChiPros® (R)-Isobutyllactate raw (D-LIB)
Polyetheramine T 5000
Basionics™ ST 80
ChiPros® (S)-1-(4-Fluorphenyl)ethylamine
ChiPros® (R)-1-(2-Methoxyphenyl)ethylamine
ChiPros® (1R, 2R)-trans-2-Amino cyclopentanolhydrochloride
AMIX M
AMIX M
AMIX 1000
AMIX 1000
AMIX TE
AMIX TE
ChiPros® (R)-2-Hexylamine
ChiPros® (S)-2-Hexylamine
Basionics™ ST 70

68909-77-3
68909-77-3
68910-05-4
68910-05-4
68953-70-8
68953-70-8
70095-40-8
70492-67-0
79917-90-1

Page

Index

26
26
26
26
26
26
26
124
14
134
136
166
132
10
10
10
6
132
68
60
8
134
14
122
140
14
34
134
130
140
60
152
132
126

2.2.152.2.162.2.172.2.182.2.192.2.202.2.218.1.3
1.4.4
8.2.308.2.429.8.158.2.22
1.2.2
1.2.3
1.2.4
1.1.7
8.2.23
4.6.9
4.4.101.1.9
8.2.291.4.2
7.10.1
8.3.1
1.4.7
3.2.3
8.2.318.2.21
8.3.2
4.4.11
9.4.138.2.28
8.2.6

126
72
110
54
72
72
74
130
136
152

8.2.2
4.7.3
7.4.2
4.3.1
4.7.1
4.7.4
5.1.1
8.2.208.2.379.4.12

187

CAS Registry No. Index
CAS Registry No.

Product

Page

Index

82796-69-8
86089-17-0
88196-70-7
92731-41-4
92731-41-4
93940-97-7
93940-97-7
99636-32-5
101012-97-9110238-91-0
127852-28-2
143314-16-3
143314-17-4
145022-44-2
145022-45-3
174899-82-2
195604-39-8
216394-06-8
216394-07-9225920-05-8250358-46-4
251102-25-7

ChiPros® (S)-1-(3-Methoxyphenyl)ethylamine
132
Tridecylamine mixture of isomers
44
128
ChiPros® (R)-1-(3-Methoxyphenyl)ethylamine
AMIX A
54
AMIX A
72
50
Baxxodur® PC 136
156
Baxxodur® PC 136
ChiPros® (S)-Methoxyisopropylamine
136
Ditridecylamine mixture of isomers
40
Tetrahydropyran-4-carboxylic acid methylester
122
124
ChiPros® (R)-1-(3,5-Ditrifluormethyl)phenylethanol
Basionics™ EE 03
148
Basionics™ BC 01
148
Basionics™ VS 11
154
Basionics™ ST 35
150
Basionics™ HP 01
150
134
ChiPros® (S)-1-Cyclopropylethylamine
ChiPros® (1R-trans)-2-(Phenyl methoxy)cyclohexanamine 126
126
ChiPros® (1S, 2S)-trans-2-Benzyloxycyclohexylamine
124
ChiPros® (S)-1-(3,5-Ditrifluoromethyl)phenylethanol
Basionics™ OH 01
150
1-Ethyl-3-methyl imidazolium methylcarbonate
in methanol
148
3-Amino-2,2-dimethylpropionicacid amide
142
Basionics™ VS 01
152
Basionics™ LQ 01
150
Basionics™ VS 03
152
128
ChiPros® (R)-1-(4-Fluorphenyl)ethylamine
Basionics™ LQ 11
150
Basionics™ UV 33
1528.2.264.1.24
8.2.8
4.3.2
4.7.2
4.2.11
9.5.1
8.2.404.1.11
7.10.2
8.1.1
9.4.4
9.4.3
9.4.189.4.11
9.4.7
8.2.34
8.2.3
8.2.4
8.1.2
9.4.10324763-51-1
331717-63-6
342573-75-5
370865-89-7
374898-01-8
848641-69-0
917956-73-1

188

9.4.1
9.1.1
9.4.16
9.4.8
9.4.178.2.10
9.4.9
9.4.14

CAS Registry No.

Product

Page

Index

148
148
152
50
94
94
68
74
100
168

9.4.2
9.4.5
9.4.154.2.10
7.1.2
7.1.3
4.6.8
5.1.3
7.2.11
9.9.2

No CAS Registry No.
Basionics™ AL 01 – EMIM Cl : AlCl3 = 1 : 1.5
Basionics™ FS 01
Basionics™ UV 43
Baxxodur ® ECX 210
Carbonate Mix 50
Carbonate Mix 60
Diethanol-para-toluidine in MMA, 50 : 50
Ethanolamine mixtures (anhydrous)
Imidazole aqueous solution 50%
Methanesulfonic acid 70%

189

GHS Assignment Scheme – How to Get Easily from H to P

Hazard Statement
Hazard Pictogram
Code

Wording

200

Unstable explosives.

201

Explosive; mass explosion hazard.

202

Explosive, severe projection hazard.

203

Explosive; fire, blast or projection hazard.

204

Fire or projection hazard.

205

May mass explode in fire.

220

Extremely flammable gas.

221

Flammable gas.

222

Extremely flammable aerosol.

223

Flammable aerosol.

224

Extremely flammable liquid and vapor.

225

Highly flammable liquid and vapor.

226

Flammable liquid and vapor.

228

Flammable solid.

2401)

Heating may cause an explosion.

2402)

Heating may cause an explosion.

2411)

Heating may cause a fire or explosion.

2412)

Heating may cause a fire or explosion.

GHS01

–

GHS02

1)

Heating may cause a fire.

2422)

Heating may cause a fire.

2503)

Catches fire spontaneously if exposed to air.

2504)

Catches fire spontaneously if exposed to air.

251

Self-heating: may catch fire.

252

Self-heating in large quantities; may catch fire.

260

In contact with water releases flammable gases which may ignite
spontaneously.

2615)

In contact with water releases flammable gases.

2616)

In contact with water releases flammable gases.

270

May cause or intensify fire; oxidiser.

271

May cause fire or explosion; strong oxidiser.

272

May intensify fire; oxidiser.

280

Contains gas under pressure; may explode if heated.

281

Contains refrigerated gas; may cause cryogenic burns or injury.

290

May be corrosive to metals.

242

–

GHS02

GHS01

GHS01 GHS02

GHS02

GHS03

GHS04

GHS05

1)
If self-reactive. 2) If organic peroxide. 3) If liquid. 4) If solid. 5) If hazard category 2. 6) If hazard category 3. 7) The additional codes D, F, d and f
are not described here.

The general precautionary statements P101 “If medical advice is needed, have product container or label at hand”, P102 “Keep out of reachof children” and P103 “Read label before use” are only assigned to consumer products.

© 2012 ecomed SICHERHEIT, Verlagsgruppe Hüthig Jehle Rehm GmbH190

Code of Precautionary Statement
Prevention

Response

Storage

Disposal

201, ((202)), 281

372, (373), 380

401

501

210, 230, ((240)), 250, 280

370+380, 372, (373)

401

(501)

210, 230, ((240)), 250, 280

370+380, 372, (373)

401

(501)

210, 230, ((240)), 250, 280

370+380, 372, (373)

401

(501)

210, ((240)), 250, 280

370+380, 372, (373)

401

(501)

210, 230, ((240)), 250, 280

370+380, 372, (373)

401

(501)

210

377, (381)

403

–

210

377, (381)403–

210, 211, 251–

410+412–210, 211, 251–

410+412–210, 233, ((240)), ((241)), ((242)), ((243)), ((280))((303+361+353)), 370+378

403+235

501

210, (233), ((240)), ((241)), ((242)), ((243)), ((280))((303+361+353)), 370+378

403+235

501

210, ((233)), ((240)), ((241)), ((242)), ((243)), ((280))((303+361+353)), 370+378

403+235

501

210, ((240)), ((241)), ((280))

370+378––

210, (220), 234, 280(((370+378))), 70+380+(((375)))

403+235, 411, (420)501

210, (220), 234, 280–

411+235, 410, (420)501

210, (220), 234, 280

370+378, 370+380+375

403+235, 411, (420)501

210, (220), 234, 280–

411+235, 410, (420)501

210, (220), 234, 280

370+378403+235, 411, (420)501

210, (220), 234, 280–

411+235, 410, (420)501

210, ((222)), 280

302+334, 370+378

(422)

–

210, ((222)), 280

335+334, 370+378

(422)

–

235+410, ((280))–

407, 413, (420)–

235+410, ((280))–

407, 413, (420)–((223)), 231+232, (280)335+334, 370+378(402+404)

501((223)), 231+232, (280)335+334, 370+378(402+404)

501

231+232, (280)

370+378(402+404)

501

220, 244((370+376))

403–

210, ((220)), 221, 280, ((283))(306+360), 371+380+375,
370+378–

501

210, ((220)), 221, (280)

370+378

–

501

–

–

((410+403))–

282

336, (315)((403))

–

(234)

(390)

((406))–

P-Statement code without brackets = highly recommended
P-Statement code with single brackets (…) = recommended
P-Statement code with double brackets ((…)) = optional
P-Statement code with triple brackets (((…))) = not to be used

The assignment was carried out in accordance with the “Guidance on Labellingand Packaging in accordance with Regulation (EC) 1272/2008”, ECHA, Helsinki
2011, pp. 65-153. In some cases a differentiation is made between label and SDS
as well as between the distribution to industrial/professional users and the generalpublic. In any case, please consult the ECHA Guidance Document.

© 2012 ecomed SICHERHEIT, Verlagsgruppe Hüthig Jehle Rehm GmbH191

Hazard Statement
Hazard Pictogram
Code

Wording

300

Fatal if swallowed.

301

Toxic if swallowed.

302

Harmful if swallowed.

GHS06

GHS07
304

May be fatal if swallowed and enters airways.

310

Fatal in contact with skin.

311

Toxic in contact with skin.

312

Harmful in contact with skin.

GHS08

GHS06

GHS07
314

Causes severe skin burns and eye damage.

315

Causes skin irritation.

317

May cause an allergic skin reaction.

318

Causes serious eye damage.

GHS05

GHS07

GHS05
319

Causes serious eye irritation.
GHS07

330

Fatal if inhaled.

331

Toxic if inhaled.

332

Harmful if inhaled.

GHS06

GHS07
334

May cause allergy or asthma symptoms or breathing difficulties if
inhaled.

335

May cause respiratory irritation.

336

May cause drowsiness or dizziness.

340

May cause genetic defects.

341

Suspected of causing genetic defects.

350

May cause cancer.

351

Suspected of causing cancer.

3607)

May damage fertility or the unborn child.

3617)

Suspected of damaging fertility or the unborn child.

362

May cause harm to breast-fed children.

GHS08

GHS07

GHS08

–

1)
If self-reactive. 2) If organic peroxide. 3) If liquid. 4) If solid. 5) If hazard category 2. 6) If hazard category 3. 7) The additional codes D, F, d and f
are not described here.

The general precautionary statements P101 “If medical advice is needed, have product container or label at hand”, P102 “Keep out of reachof children” and P103 “Read label before use” are only assigned to consumer products.

© 2012 ecomed SICHERHEIT, Verlagsgruppe Hüthig Jehle Rehm GmbH192

Code of Precautionary Statement
Prevention

Response

Storage

Disposal

264, 270

301+310, 321, 330

405

501

264, (270)301+310, 321, (330)

405

501

(264), (270)((301+312)), ((330))

–

501

–

301+310, 331

405

501

262, 264, 270, 280(302+350), 310, 322, 361, (363)

405

501

280

(302+352), (312), 322, (361), ((363))

405

501

(280)

((302+352)), (312), 322, ((363))–

501

260, 264, 280

301+330+331, 303+361+353,(363), ((304+340)), 310, 321,
305+351+338

405

501

((264)), (280)((302+352)), 321, ((332+313)), (362)) ––(261), (272), 280(302+352), (333+313), 321, (363)

–

501

280

305+351+338, 310––((264)), (280)(305+351+338), (337+313)––

260, 271, (284)304+340, 310, 320

403+233, 405

501(261), 271((304+340)), (311), 321

403+233, 405

501(261), 271((304+340)), (312)––261, 285

304+341, 342+311–

501(261), 271((304+340)), (312)(403+233), 405

501(261), 271((304+340)), (312)(403+233), 405

501

201, ((202)), 281

308+313405

501(201), ((202)), 281(308+313)

405

501

201, (202), 281

308+313405

501(201), ((202)), 281(308+313)

405

501

201, ((202), 281

308+313405

501

201, ((202)), 281(308+313)

405

501

201, 260, 263, ((264)), (270)(308+313)––

P-Statement code without brackets = highly recommended
P-Statement code with single brackets (…) = recommended
P-Statement code with double brackets ((…)) = optional
P-Statement code with triple brackets (((…))) = not to be used

The assignment was carried out in accordance with the “Guidance on Labellingand Packaging in accordance with Regulation (EC) 1272/2008”, ECHA, Helsinki
2011, pp. 65-153. In some cases a differentiation is made between label and SDS
as well as between the distribution to industrial/professional users and the generalpublic. In any case, please consult the ECHA Guidance Document.

© 2012 ecomed SICHERHEIT, Verlagsgruppe Hüthig Jehle Rehm GmbH193

Hazard Statement
Hazard Pictogram
Code

Wording

370

Causes damage to organs.

371

May cause damage to organs.

372

Causes damage to organs trough prolonged or repeated exposure.

373

May cause damage to organs trough prolonged or repeated exposure.

400

Very toxic to aquatic life.

410

Very toxic to aquatic life with long lasting effects.

411

Toxic to aquatic life with long lasting effects.

412

Harmful to aquatic life with long lasting effects.

413

May cause long lasting harmful effects to aquatic life.

420

Harms public health and the environment by destroying ozone in theupper atmosphere.

GHS08

GHS09
–

GHS07

1)
If self-reactive. 2) If organic peroxide. 3) If liquid. 4) If solid. 5) If hazard category 2. 6) If hazard category 3. 7) The additional codes D, F, d and f
are not described here.

The general precautionary statements P101 “If medical advice is needed, have product container or label at hand”, P102 “Keep out of reachof children” and P103 “Read label before use” are only assigned to consumer products.

No.

Prevention

P201

Obtain special instructions before use.

P202

Do not handle until all safety precautions have been read and understood.

P210

Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P211

Do not spray on an open flame or other ignition source.

P220

Keep/Store away from clothing/…/combustible materials.

P221

Take any precaution to avoid mixing with combustibles…

P222

Do not allow contact with air.

P223

Keep away from any possible contact with water, because of violent reaction and possible flash fire.

P230

Keep wetted with…

P231

Handle under inert gas.

P232

Protect from moisture.

P233

Keep container tightly closed.

P234

Keep only in original container.

P235

Keep cool.

P240

Ground/bond container and receiving equipment.

P241

Use explosion-proof electrical/ventilating/lighting/…/equipment.

P242

Use only non-sparking tools.

P243

Take precautionary measures against static discharge.

P244

Keep reduction valves free from grease and oil.

P250

Do not subject to grinding/shock/…/friction.

P251

Pressurized container: Do not pierce or burn, even after use.

P260

Do not breathe dust/fume/gas/mist/vapors/spray.

P261

Avoid breathing dust/fume/gas/mist/vapors/spray.

P262

Do not get in eyes, on skin, or on clothing.

P263

Avoid contact during pregnancy/while nursing.

© 2012 ecomed SICHERHEIT, Verlagsgruppe Hüthig Jehle Rehm GmbH194

Code of Precautionary Statement
Prevention

Response

260, ((264)), (270)

307+311, 321

405

501

260, ((264)), (270)(309+311)

405

501

260, ((264)), (270)

(314)

–

501

260

(314)

–

501

(273)

(391)

–

501

(273)

(391)

–

501

(273)

(391)

–

501

(273)

–

–

501

(273)

–

–

501

–

–

–

502

P-Statement code without brackets = highly recommended
P-Statement code with single brackets (…) = recommended
P-Statement code with double brackets ((…)) = optional
P-Statement code with triple brackets (((…))) = not to be used

Storage

Disposal

The assignment was carried out in accordance with the “Guidance on Labellingand Packaging in accordance with Regulation (EC) 1272/2008”, ECHA, Helsinki
2011, pp. 65-153. In some cases a differentiation is made between label and SDS
as well as between the distribution to industrial/professional users and the generalpublic. In any case, please consult the ECHA Guidance Document.

P264

Wash … thoroughly after handling.

P270

Do no eat, drink or smoke when using this product.

P271

Use only outdoors or in a well-ventilated area.

P272

Contaminated work clothing should not be allowed out of the workplace.

P273

Avoid release to the environment.

P280

Wear protective gloves/protective clothing/eye protection/face protection.

P281

Use personal protective equipment as required.

P282

Wear cold insulating gloves/face shield/eye protection.

P283

Wear fire/flame resistant/retardant clothing.

P284

Wear respiratory protection.

P285

In case of inadequate ventilation wear respiratory protection.

P231+232

Handle under inert gas. Protect from moisture.

P235+410

Keep cool. Protect from sunlight.

No.

Response

P301

IF SWALLOWED:P302

IF ON SKIN:P303

IF ON SKIN (or hair):P304

IF INHALED:P305

IF IN EYES:

P306

IF ON CLOTHING:

P307

IF exposed:

P308

IF exposed or concerned:

P309

IF exposed or if you feel unwell:P310

Immediately call a POISON CENTER or doctor/physician.
© 2012 ecomed SICHERHEIT, Verlagsgruppe Hüthig Jehle Rehm GmbH

195

P311

Call a POISON CENTER or doctor/physician.

P312

Call a POISON CENTER or doctor/physician if you feel unwell.

P313

Get medical advice/attention.

P314

Get medical advice/attention if you feel unwell.

P315

Get immediate medical advice/attention.

P320

Specific treatment is urgent (see … on this label).

P321

Specific treatment (see … on this label).

P322

Specific measures (see … on this label).

P330

Rinse mouth.

P331

Do NOT induce vomiting.

P332

If skin irritation occurs:

P333

If skin irritation or rash occurs:

P334

Immerse in cool water/wrap in wet bandages.

P335

Brush off loose particles from skin.

P336

Thaw frosted parts with lukewarm water. Do no rub affected area.

P337

If eye irritation persists:

P338

Remove contact lenses, if present and easy to do. Continue rinsing.

P340

Remove victim to fresh air and keep at rest in a position comfortable for breathing.

P341

If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.

P342

If experiencing respiratory symptoms:

P350

Gently wash with plenty of soap and water.

P351

Rinse cautiously with water for several minutes.

P352

Wash with plenty of soap and water.

P353

Rinse skin with water/shower.

P360

Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.

P361

Remove/Take off immediately all contaminated clothing.

P362

Take off contaminated clothing and wash before reuse.

P363

Wash contaminated clothing before reuse.

P370

In case of fire:

P371

In case of major fire and large quantities:

P372

Explosion risk in case of fire.

P373

DO NOT fight fire when fire reaches explosives.

P374Fight fire with normal precautions from a reasonable distance.

P375

Fight fire remotely due to the risk of explosion.

P376

Stop leak if safe to do so.

P377

Leaking gas fire:
Do not extinguish, unless leak can be stopped safely.

P378

Use … for extinction.

P380

Evacuate area.

P381

Eliminate all ignition sources if safe to do so.

P390

Absorb spillage to prevent material damage.

P391

Collect spillage.

P301+310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P301+312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P301+
330+331

IF SWALLOWED: rinse mouth. Do NOT induce vomiting.

P302+334 IF ON SKIN: Immerse in cool water/wrap in wet bandages.
© 2012 ecomed SICHERHEIT, Verlagsgruppe Hüthig Jehle Rehm GmbH196

P302+350 IF ON SKIN: Gently wash with plenty of soap and water.
P302+352 IF ON SKIN: Wash with plenty of soap and water.
P303+
361+353

IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.

P304+340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P304+341 IF INHALED: If breathing is difficult, remove victim to fresh air and keep at restin a position comfortable for breathing.
P307+311 IF exposed: Call a POISON CENTER or doctor/physician.
P308+313 IF exposed or concerned: Get medical advice/attention.
P309+311 IF exposed or if you feel unwell: Call a POISON CENTER or doctor/physician.
P332+313 If skin irritation occurs: Get medical advice/attention.
P333+313 If skin irritation or rash occurs: Get medical advice/attention.
P335+334 Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages.
P337+313 If eye irritation persists: Get medical advice/attention.
P342+311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician.
P370+376 In case of fire: Stop leak if safe to do so.
P370+378 In case of fire: Use … for extinction.
P370+380 In case of fire: Evacuate area.
P370+
380+375

In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion.

P371+
380+375

In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion.

No.

Storage

P401

Store …

P402

Store in a dry place.

P403

Store in a well-ventilated place.

P404

Store in a closed container.

P405

Store locked up.

P406

Store in corrosive resistant/… container with a resistant inner liner.

P407

Maintain air gap between stacks/pallets.

P410

Protect from sunlight.

P411

Store at temperatures not exceeding … °C/… °F.

P412

Do not expose to temperatures exceeding 50 °C/122 °F.

P413

Store bulk masses greater than … kg/… lbs at temperatures not exceeding … °C/… °F.

P420

Store away from other materials.

P422

Store contents under …

P402+404 Store in a dry place. Store in a closed container.
P403+233 Store in a well-ventilated place. Keep container tightly closed.
P403+235 Store in a well-ventilated place. Keep cool.
P410+403 Protect from sunlight. Store in a well-ventilated place.
P410+412 Protect from sunlight. Do no expose to temperatures exceeding 50 °C/122 °F.
P411+235 Store at temperatures not exceeding … °C/… °F. Keep cool.

No.

Disposal

P501

Dispose of contents/container to …

P502

Refer to manufacturer/supplier for information on recovery/recycling.
© 2012 ecomed SICHERHEIT, Verlagsgruppe Hüthig Jehle Rehm GmbH

197

Overview GHS Pictogram

GHS01: Explosives
GHS02: Flammable gases / aerosols / liquids / solids
GHS03: Oxidizing gases
GHS04: Gases under pressure
GHS05: Corrosion
GHS06: Skull and crossbones – toxic
GHS07: Health hazard – warning
GHS08: Health hazard – danger
GHS09: Environmental risk

198

Contact

EuropePhone: +49 621 60-0
North America
Phone: +1 973 245 6000
Asia
Phone: +852 2731 1222

info.intermediates@basf.com
www.intermediates.basf.com

Imprint
Published by:

BASF SE,Intermediates Division

Editors:

Global Communications Intermediates

Phone:+49 621 60-95138

Postal address:

BASF SE,67056 Ludwigshafen, Germany® = registered trademark of BASF SE™ = trademark of BASF SE

The data contained in this publication is based on our current knowledge
and experience. In view of the many factors that may affect processing
and application of our product, the data does not relieve processors fromcarrying out their own investigations and tests; neither does the data imply
any guarantee of certain properties, nor the suitability of the product for a
specific purpose. Any descriptions, drawings, photographs, data, proportions,weights etc. given herein may change without prior information and do
not constitute the agreed contractual quality of the product. It is the
responsibility of the recipient of our products to ensure that any proprietary
rights and existing laws and legislation are observed. The safety data givenin this publication is for information purposes only and does not constitutea legally binding Material Safety Data Sheet (MSDS). The relevant MSDS
can be obtained upon request from your supplier or you may contact BASF
directly at info.intermediates@basf.com. 2012 edition© 2012 BASF SE

199

2012/2013

CZ 1203-02/12-20.000

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We Create Chemistry
Building Blocks andReagents for ourCustomers’ Needs

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