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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 30.03.2023*Version number 1

Revision: 30.03.2023

SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Trade name: PFC-14
Article number: DF14
EC number:
200-896-5
1.2 Relevant identified uses of the substance or mixture and uses advised against:
Sector of Use SU8 Manufacture of bulk, large scale chemicals (including petroleum products)
1.3 Details of the supplier of the safety data sheet
Manufacturer/Supplier:
DAIKIN INDUSTRIES, LTD. CHEMICALS DIVISION:OSAKA UMEDA TWIN TOWERS SOUTH, 1-13-1 Umeda, Kita-ku, Osaka-shi, Osaka, 530-0001, Japan
Phone:+81-6-6147-9702 Fax:+81-6-6147-9807
Further information obtainable from: http://www.daikin.com/
1.4 Emergency telephone number:
Japan: +81-6-6349-7521
China: +86-532-8388-9090, +86-21-34151689
South Korea: +82-2-568-1722
Americas: CHEMTREC +1-800-424-9300 (Outside US/Canada: +1-703-527-3887)
Europe: +49-211-179 225-0

SECTION 2: Hazard identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008

Press. Gas (Comp.) H280 Contains gas under pressure; may explode if heated.
2.2 Label elements
Labelling according to Regulation (EC) No 1272/2008:
The substance is classified and labelled according to the CLP regulation.
Signal word: Warning
Precautionary statements:
P410+P403 Protect from sunlight. Store in a well-ventilated place.

SECTION 3: Composition/information on ingredients
Information on ingredients:
CAS: 75-73-0 Carbon tetrafluoride
Press. Gas (Comp.), H280
Identification number(s)EC number: 200-896-5>99.9%SECTION 4: First aid measures
4.1 Description of first aid measures
General information: Seek medical treatment.
After inhalation:
If the patient does not breathe or hardly breathes, unbutton clothes, secure the airway for breathing and perform
artificial respiration.
After skin contact:
Rinse with warm water.
Consult a doctor in case of complaints.
After eye contact: Consult an ophthalmologist in case of complaints.
Information for doctor:
Catecholamines such as adrenaline, and other compounds having similar effects, should be reserved for emergencies
and then used only with special caution.
(Contd. on page 2)

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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 30.03.2023

Version number 1

Revision: 30.03.2023

Trade name: PFC-14(Contd. of page 1)

4.2 Most important symptoms and effects, both acute and chronic: No further relevant information available.
4.3 Indication of any immediate medical attention and special treatment needed:
No further relevant information available.

SECTION 5: Firefighting measures
5.1 Extinguishing media
Suitable extinguishing agents: Use fire extinguishing methods suitable for surrounding conditions.
5.2 Special hazards arising from the substance or mixture:
In case of fire, the following can be released:
Hydrogen fluoride (HF)
Formation of toxic gases is possible during heating or in case of fire.
5.3 Advice for firefighters:
Protective equipment:
Wear fully protective suit.
Wear self-contained breathing apparatus and protective suit.
Do not inhale explosion gases or combustion gases.

SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures:
Ensure adequate ventilation before entering the area.
Keep out unauthorized persons.
6.2 Environmental precautions: Suppress gases/fumes/haze with water spray.
6.3 Methods and material for containment and cleaning up:
Turn the container to discharge gas (not liquid) if possible.
Cool the container to prevent evaporation. Spray water to diffuse the generated vapor cloud.
6.4 Reference to other sections:
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.

SECTION 7: Handling and storage
7.1 Precautions for safe handling:
Danger of ignition/explosion if mixed with flammable gas.
Do not inhale the gas.
Ensure good ventilation/exhaustion at the workplace.
Do not handle until all safety precautions have been read and understood.
Information about fire - and explosion protection: Keep ignition sources away - Do not smoke.
7.2 Conditions for safe storage, including any incompatibilities:
Storage
Requirements to be met by storerooms and receptacles:
Store material at 5
to 25 .
Store in a cool and dry location.
Information about storage in one common storage facility:
No further information available.
See section 10 for information on incompatible materials.
Further information about storage conditions:Store in cool, dry conditions in well sealed receptacle.
Protect from heat and direct sunlight.
Store containers in a well ventilated area.
7.3 Specific end use(s): No further relevant information available.

SECTION 8: Exposure controls/personal protection
8.1 Control parameters No further information available.
Ingredients with limit values that require monitoring at the workplace: Not required.
Additional information: The lists valid during the making were used as basis.
(Contd. on page 3)

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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 30.03.2023

Version number 1

Revision: 30.03.2023

Trade name: PFC-14(Contd. of page 2)

8.2 Exposure controls
Appropriate engineering controls No further data; see item 7.
Individual protection measures, such as personal protective equipment
General protective and hygienic measures:
Wash hands before breaks and at the end of work.
Do not eat or drink while working.
Keep away from tobacco products.
Respiratory protection: Not required.
Hand protection
Protective gloves
Material of gloves: Leather
Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed.
Eye/face protection
Safety glasses
Body protection: Protective work clothing*SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
General Information
Liquefied gas
Physical state
Colourless
Colour:OdourlessOdour:
Not determined.
Odour threshold:-184 °C
Melting point/freezing point:
Boiling point or initial boiling point and boiling range -128 °C
No data.
FlammabilityLower and upper explosion limit
No further information available.
Lower explosive limit:
Not determined.
Upper explosive limit:
Not applicable.
Flash point:
No further information available.
Decomposition temperature:
Not determined.
pHViscosity:
Not determined.
Kinematic viscosity
Not determined.
Dynamic:
Solubility
0.0015 g/100g
water at 25 °C:
No further information available.
Partition coefficient n-octanol/water (log value)1.202 Mpa
Vapour pressure at -80 °C:
Density and/or relative density
Not determined.
Density:
Not determined.
Relative density
Not determined.
Vapour density
No further information available.
Particle characteristics
9.2 Other information:
Form:
Auto-ignition temperature:
Explosive properties:

Liquefied gas
Not determined.
Not determined.
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 30.03.2023

Version number 1

Revision: 30.03.2023

Trade name: PFC-14(Contd. of page 3)

Evaporation rate

Not applicable.

Information with regard to physical hazard classes
Not applicable
Explosives
Not applicable
Flammable gases
Not applicable
Aerosols
Not applicable
Oxidising gases
Gases under pressure
Contains gas under pressure; may explode if heated.
Not applicable
Flammable liquids
Not applicable
Flammable solids
Not applicableSelf-reactive substances and mixtures
Not applicable
Pyrophoric liquids
Not applicable
Pyrophoric solids
Not applicableSelf-heating substances and mixtures
Substances and mixtures, which emit flammable gases
Not applicablein contact with water
Not applicable
Oxidising liquids
Not applicable
Oxidising solids
Not applicable
Organic peroxides
Not applicable
Corrosive to metals
Not applicable
Desensitised explosives

SECTION 10: Stability and reactivity
10.1 Reactivity No further relevant information available.
10.2 Chemical stability
Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
10.3 Possibility of hazardous reactions: No dangerous reactions known.
10.4 Conditions to avoid: Keep away from heat, sparks, flame, high temperature.
10.5 Incompatible materials: No further relevant information available.
10.6 Hazardous decomposition products:
Danger of forming toxic pyrolysis products.
Fluorophosgene in contact with naked flame or red hot objects.

SECTION 11: Toxicological information
11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008
Acute toxicity LCLo 15H Rat: 895000 ppm
LD/LC50 values relevant for classification: No further information available.
Skin corrosion/irritation: No further information available.
Serious eye damage/irritation: No further information available.
after inhalation: No further information available.
Respiratory or skin sensitisation: Based on available data, the classification criteria are not met.
Germ cell mutagenicity: Based on available data, the classification criteria are not met.
Carcinogenicity: Based on available data, the classification criteria are not met.
Reproductive toxicity: Based on available data, the classification criteria are not met.
STOT-single exposure: Based on available data, the classification criteria are not met.
STOT-repeated exposure: Based on available data, the classification criteria are not met.
Aspiration hazard: Based on available data, the classification criteria are not met.
Other information (about experimental toxicology): No further information available.
Subacute to chronic toxicity: No further information available.
11.2 Information on other hazards:
Endocrine disrupting properties:
Substance is not listed.
*SECTION 12: Ecological information
12.1 Toxicity
Aquatic toxicity: No further relevant information available.
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 30.03.2023

Version number 1

Revision: 30.03.2023

Trade name: PFC-14(Contd. of page 4)

12.2 Persistence and degradability: No further relevant information available.
12.3 Bioaccumulative potential: No further relevant information available.
12.4 Mobility in soil: No further relevant information available.
12.5 Results of PBT and vPvB assessmentPBT: No further relevant information available.
vPvB: No further information available.
12.6 Endocrine disrupting properties The product does not contain substances with endocrine disrupting properties.
12.7 Other adverse effects:
Ecotoxical effects: no data
Additional ecological information:
General notes:
Ozone depletion potential(ODP) : 0
Global warming potential(GWP) : 6500

SECTION 13: Disposal considerations
13.1 Waste treatment methods
Recommendation: Disposal must be made according to official regulations.
Uncleaned packaging
Recommendation: Disposal must be made according to official regulations.
*SECTION 14: Transport information
14.1 UN number or ID number
ADR, IMDG, IATA
14.2 UN proper shipping name:
ADR:
IMDG, IATA
14.3 Transport hazard class(es):UN1982
1982 TETRAFLUOROMETHANETETRAFLUOROMETHANE (REFRIGERANT GAS R 14)

ADRClass:
Label:
IMDG, IATA

2 1A Gases.
2.22 Gases.
Class:
2.2
Label:
14.4 Packing group:
Not applicable
ADR, IMDG, IATA
14.5 Environmental hazards:
No
Marine pollutant:Warning: Gases.
14.6 Special precautions for user:
20Hazard identification number (Kemler code):
F-C,S-V
EMS Number:A
Stowage Category
14.7 Maritime transport in bulk according to IMO
Not applicable.
instruments
Avoid direct sunlight. Make sure of no damage, corrosion, leaks
Transport/Additional information:on the receptacles.
Take necessary measures for preventing cargo shift.
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 30.03.2023

Version number 1

Revision: 30.03.2023

Trade name: PFC-14(Contd. of page 5)

ADR
Limited quantities (LQ):
Excepted quantities (EQ)
Transport category:
Tunnel restriction code:IMDG
Limited quantities (LQ)
Excepted quantities (EQ)UN "Model Regulation":*120 ml
Code: E1
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 1000 ml
3C/E120 ml
Code: E1
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 1000 ml
UN1982, TETRAFLUOROMETHANE (REFRIGERANT GAS R14), 2.2

SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
No further relevant information available.
Labelling according to Regulation (EC) No 1272/2008
The substance is classified and labelled according to the CLP regulation.
Hazard pictograms

GHS04
Signal word Warning
Hazard statements
H280 Contains gas under pressure; may explode if heated.
Precautionary statements
P410+P403 Protect from sunlight. Store in a well-ventilated place.
National regulations No further information available.
15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

SECTION 16: Other information
The product is for the industrial use only. We do not guarantee the safety in case the product is used for the otherpurposes. When using the product for health-care application or food/feed application, consult us in advance.
This information is based on our present knowledge. However, this shall not constitute a guarantee for any specificproduct features and shall not establish a legally valid contractual relationship.
Department issuing SDS: EHS Department
Contact: http://www.daikin.com/Abbreviations and acronyms:
ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International
Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport AssociationGHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
Press. Gas (Comp.): Gases under pressure – Compressed gas* Data compared to the previous version altered.