Materials science

6th Edition

Ionic Liquids General Catalog-[(CF3SO 2) 2N]

+

N

[I]

[(FSO2)2N]

-

N+

[BF4]

-

-

N

-

-

[(CF3SO 2) 2N]

+

N

N

CF3SO2)2N]

N

-

[I]
N+

[(FSO2)2N]

-

-

-

N

N+

[CF3SO 3][(CF3SO 2) 2N]

+

-

-

N+

N

[I]

N+

+

-

N

[(FSO2) 2N]

-

N

+

N

N+

[CF3SO3]N+[(FSO2)2N]

N[CF3SO3]N+[BF4][(FSO2)2N]

-

+

N

[(FSO2)2N]

N
-

N+

[CF3SO3]
N+[BF4][(CF3SO2)2N]

+

N

N

[(CF3SO2)2N]

N

-

[I]
N+

[(FSO2)2N]

+

-

N+

N+

+

[CF3SO 3]

N

-

N+

N

[(CF3SO2)2N][(CF3SO 2) 2N]

+

N

+

N

-

[I]
N+

-

[BF4]

-

N+

+

N

N

-

-

-

N+

N

[(FSO2)2N][(CF3SO2)2N][(FSO2) 2N]

-

-

-

-

N+

-

-

-

[(CF3SO2)2N]

N+

[BF4]

+

+

[(FSO2)2N]

-

N+
-

-

N

+

N

[(CF3SO 2) 2N]+

N

For your safe
The use of reagents involves potential danger; fires, explosions, accidental ingestion, poisoning, irritation of
mucous membranes due to inhalation of vapor, chemical or physical damage to the skin, etc. Furthermore, it isrequired to use reagents while considering the impact on the environment.
Although various regulations and hazard information are described as much as possible on catalogs or labels,
there are many chemicals with little knowledge or information on hazard. We would like you to pay attention to
the following, when handling reagents.
 When ordering, please use the product code and product name listed in the catalog for accuracy.
 Please refer to the description of label, SDS, related regulations and etc when use.
 Please manage properly in accordance with the laws and regulations, and take all possible measures toprevent reagents from tipping over and falling. Please take appropriate safety measures such as wearing
protective equipment.
 Please store the remaining reagents properly and manage them thoroughly. Build a database to manage
usage.
 Dispose of waste or remaining reagents appropriately accordance with corresponding regulations, referring to
SDS.

Contents of the catalog
The prices, packaging or other properties of products listed in the catalog are subject to change due tofluctuations of circumstances, also specification, grades, etc. are subject to change. Please check the productsearch site "Cica-Web" for the information. The product may be deleted due to various reasons, but if possible,
a replacement may be available. Please contact distributor.
Please be aware that some products require registration, permission for use, information necessary for stablesupply and legally required procedures when ordered or received.

Ionic liquid is
Compounds consisting solely of ions (anions and cations) with a melting point below 100 °C. are called ionicliquids (Ionic Liquids). Ionic liquids are substances that combine features such as non-volatility, flame
resistance, high ionic conductivity and excellent electrochemical properties. As a result, they are highly
promising as materials in various fields, including energy, bio- and environment-related fields. Although not allionic liquids have all the aforementioned characteristics, research and development by industry, academia andgovernment is expanding from the acquisition of basic data to the study of practical applications, anddevelopments that "can only be realised with ionic liquids" are being proposed.
We have about 50 ionic liquids in various combinations of anions and cations.
*Application example

CONTENTS
Page#
1-allyl-3-alkylimidazolium ionic liquids

4

Cellulose soluble ionic liquid

7

Iodine-based ionic solution

8

Pick up 1

9

Pick up 2 ～ Nisshinbo Holdings Inc. Ionic Liquid

10

Pick up 3 ～ Nippon Chemical Industrial Quaternary Phosphonium Ionic Liquids 12
FSI ( Bis fluorosulfonyl imide ) Ionic Liquids

13

Item List
Imidazolium based ionic liquids

14

Pyrrolidinium based ionic liquids

21

Piperidinium based ionic liquids

23

Ammonium based ionic liquids

24

Phosphonium based ionic liquids

26

Related products

27

Guide⑪⑩⑫① 1-Ethyl-3-methylimidazolium tetrafluoroborate③ 143314-16-3②

14644-53

5 mL

14644-33

25 mL④ C6H11N2BF4⑤ 198.0⑦ 34 cP (25 ℃ )⑥15 ℃⑧d 1.28 (24 ℃ ) ⑨ 14.1 mS/cm (25 ℃ )① Name② Structure③ CAS RN®

④ Formula⑤ Formula weight⑥ Melting point⑦ Viscosity⑧ Density(Specific gravity)⑨ Conductivity⑩ Product No.

⑪ Grade⑫ Package

Grade
The purity item is left blank, but each product has its own guaranteed items such as moisture value.
Please refer to the “Cica-Web” on our website. Regulations are also listed.
※Colour of products
We are trying to make our products as colourless and transparent as possible, but due to the current manufacturing process,there are products with a strong colour tone even in high-purity products. We ask for your understanding.

Physical property
The physical properties values vary from literature to literature due to the influence of small amounts ofimpurities resulting from differences in synthesis methods.
Some compounds in this catalogue have actual measured values specified, but these are basically
based on literature values. We ask for your understanding that these are reference data.
● EMIm X (25 ℃ )Anion
BF4PF6CH3SO3CF3SO3[(CF3SO2)2N][(C2F5SO2)2N]-

Melting point (℃ )111),152)621)
393)-103),-94)-151),-162)-11),-195)

Density (g/cm3)
1.241),1.282)
1.561)
1.253)
1.3833)
1.521), ※ ,1.5182)-

Viscosity (mPa·s)431),31.82)
1603)
42.73)
281),40.72)
611)※ 22 ℃
1) A. A.B.McEwen, H.LNgo, K. LeCompte, and J.L.Goldman, J.Electrochem. Soc., 146,1687 (1999)
2) A.Noda, K.Hayamizu, and M.Watanabe, J.Phys, Chem. , B, 105,4603 (2001)
3) E.I. Cooper and E.J.M. O' Sullivan, Proc. Of 8th Int. Symp ., 382(1992)
4) P.BonHote, A.-P.Dias, M.Armand, N.Papageorgiou, K.kalyanasundaram, and M.Gratzle, Inorg. Chem., 35,
1168 (1996)
5) M.Yosizawa, W.Ogihara, and H.Ohno, Electrochem.Solid-State Lett., 4, E25 (2001)

2

Conductivity (mS/cm)
13.01),13.62)
5.21)
2.73)
9.293)
8.41),5.72)
3.41)

Viscosity by temperature change
The relationship between temperature and viscosity is shown as follows for the typical ionic liquids, 1-Butyl-3methylimidazolium triflate, 1-Butyl-3-methylimidazolium tetrafluoroborate, 1-Butyl-3-methylimidazolium
hexafluorophosphate and 1-Butyl-3-methylimidazolium chloride.
From the following figure, it can be seen that the viscosity changes significantly with slight changes in

Viscosity / cP

temperature and that differences in the constituent ions have a significant effect on the viscosity.

a : BMIm CF3SO3
b : BMIm BF4
c : BMIm PF6
d : BMIm Cl

Temperature / ℃
Viscosity by temperature change

Ultraviolet-visible absorption spectrum
Ultraviolet-visible absorption spectrum is shown as follows for the typical ionic liquids, 1-Ethyl-3methylimidazolium tetrafluoroborate, N-Methyl-N-propylpyrrolidinium bis(trifluoromethanesulfonyl)imide,
N ,N ,N-Trimethyl-N-propylammonium bis(trifluoromethanesulfonyl)imide, N-Methyl-N-propylpiperidiniumbis(trifluoromethanesulfonyl)imide. EMIm BF4 has a slight absorption, but little absorption is observed in thevisible range (350-700 nm), making it colorless in appearance.

EMIm
EMIm
BFBF
4 4
P13TFSI
TFSI
P13
TMPA TFSI
TMPA
TFSI
PP13 TFSI

Ultraviolet-visible absorption
spectrum3

1-allyl-3-alkylimidazolium ionic liquids
Among the 1-allyl-3-alkylimidazolium ionic liquids developed by Prof. Ohno and his colleagues6) at the Tokyo
University of Agriculture and Technology, typical compounds have been commercialised. They are morepolar than conventional ionic liquids and are expected to dissolve a wide range of compounds.
6) T. Mizuno, E. Marwanta, N. Matsumi, and H. Ohno, Chem. Lett .,. 33, 204, 1360.

Item List【AMIm Br】

1-Allyl-3-methylimidazolium bromide
31410-07-801986-55

for advanced material research

5g

C7H11BrN2

01986-35

for advanced material research

25g

203.1

01986-15

for advanced material research

250g

65039-07-8

01120-35

for advanced material research

25g

C7H11IN201120-25

for advanced material research

100g655249-87-901988-55

for advanced material research

5mL

C9H11F6N3O4S201988-35

for advanced material research

25mL

403.3

01988-15

for advanced material research

250mL

851606-63-801987-55

for advanced material research

C7H11BF4N2

01987-35

for advanced material research

25mL

210

01987-15

for advanced material research

250mL

652134-09-3

01930-55

for advanced material research

5g

C8H13BrN2

01930-35

for advanced material research

25g

217.1

01930-15

for advanced material research

250g

920981-07-3

01119-35

for advanced material research

25mL

C8H13IN201119-25

for advanced material research

100mL

652134-11-7

01932-55

for advanced material research

5mL

C10H13F6N3O4S201932-35

for advanced material research

25mL

417.4

01932-15

for advanced material research

250mL

58℃

1.60 mS/cm【AMIm I】

1-Allyl-3-methylimidazolium iodide

250.1
57℃

【AMIm TFSA】

1-Allyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide

35 cP

1.49

8.87 mS/cm【AMIm BF4】

1-Allyl-3-methylimidazolium tetrafluoroborate

5mL【AEIm Br】

1-Allyl-3-ethylimidazolium bromide【AEIm I】

1-Allyl-3-ethylimidazolium iodide

264.1【AEIm TFSA】

1-Allyl-3-ethylimidazolium bis(trifluoromethanesulfonyl)imide41-allyl-3-alkylimidazolium ionic liquids【AEIm BF4】

1-Allyl-3-ethylimidazolium tetrafluoroborate
945732-42-3

01931-55

for advanced material research

5mL

C8H13BF4N2

01931-35

for advanced material research

25mL

224

01931-15

for advanced material research

250mL

863498-30-001933-55

for advanced material research

5mL

C10H17BrN201933-35

for advanced material research

25mL

245.2

01933-15

for advanced material research

250mL【ABIm Br】

1-Allyl-3-butylimidazolium bromide

0.50 mS/cm【ABIm TFSA】

1-Allyl-3-butylimidazolium bis(trifluoromethanesulfonyl)imide
863498-34-4

01935-55

for advanced material research

5mL

C12H17F6N3O4S201935-35

for advanced material research

25mL

445.4

01935-15

for advanced material research

250mL

863498-32-2

01934-55

for advanced material research

5mL

C10H17BF4N201934-35

for advanced material research

25mL

252.1

01934-15

for advanced material research

250mL

1.53 mS/cm【ABIm BF4】

1-Allyl-3-butylimidazolium tetrafluoroborate

1.22 mS/cm【AAIm Br】

1,3-Diallylimidazolium bromide
31483-71-3

11475-55

for advanced material research

5mL

C9H13BrN2

11475-35

for advanced material research

25mL

229.1

11475-15

for advanced material research

250mL

803732-17-4

11477-55

for advanced material research

5mL

C11H13F6N3O4S2

11477-35

for advanced material research

25mL

429.4

11477-15

for advanced material research

250mL

0.74 mS/cm【AAIm TFSA】

1,3-Diallylimidazolium bis(trifluoromethanesulfonyl)imide【AAIm BF4】

1,3-Diallylimidazolium tetrafluoroborate
852699-06-0

11476-55

for advanced material research

5mL

C9H13BF4N2

11476-35

for advanced material research

25mL

236

11476-15

for advanced material research

250mL

5

1-allyl-3-alkylimidazolium ionic liquids
Solubility●Compatibility when mixed with various solvents ( Volume ratio 1:1)
Solvent

AMIm Br

AMIm TFSI

AMIm BF4

AEIm Br

AEIm TFSI

Water

〇

×

○

○

×

○

Methanol

○

○

○

○

○

○

Ethanol

○

○

×

○

○

△ ※2

2- propanol

○

○

×

○

○

×

Acetone

×

○

○

△

○

○

Ethyl acetate

×

○

△

×

○

△ ※3

Acetonitrile

○

○

○

○

○

○

Tetrahydrofuran

×

○

×

×

○

Diethyl ether

×

△

×

×

△

Hexane

×

×

×

×

×

×

Toluene

×

△

×

×

△ ※1

×

Dichloromethane

○

○

○

○

○

○

Chloroform

○

○

○

○

○

○

Solvent

ABIm Br

ABIm BF4

ABIm TFSI

AAIm Br

AAIm BF4

AAIm TFSI

Water

〇

×

×

〇

Methanol

○

○

○

○

○

○

Ethanol

○

○

○

○

△ ※5

○
○

AEIm BF4

△ ※2
※1

△ ※2

×

×

2- propanol

○

○

○

○

△ ※3

Acetone

○

○

○

○

○

○

Ethyl acetate

×

○

○

×

△ ※6

○

Acetonitrile

○

○

○

○

○

○

Tetrahydrofuran

×

○

○

×

○

○

Diethyl ether

×

×

○

×

×

△ ※6

Hexane

×

×

×

×

×

×

Toluene

×

△ ※4

×

×

×

△ ※6

Dichloromethane

○

○

○

○

○

○

Chloroform

○

○

○

○

○

○

○ ： Dissolve △ ： Partly dissolved × ： Insoluble※ 1 : 80% dissolved ※ 4 : 40% dissolved※ 2 : 50% dissolved※ 5 : 70% dissolved※ 3 : 30% dissolved※ 6 : 90% dissolved

Ultraviolet-visible absorption spectrum
1-Allyl-3-butylimidazolium bis(trifluoromethanesulfonyl)imide (ABIm TFSI), a typical ionic liquid with allyl groups, iscolourless in appearance and has little absorption observed in the visible range (350 ～ 700 nm).
1.0

ABImTFSI
ABIm TFSI

Absorbance

0.8

0.6

0.4

0.2

0.0
200

300

400

500

Wavelength (nm)

6

600

700

Cellulose soluble ionic liquid
We commercialize a phosphonate-based ionic liquid, which has been actively researched by Prof. Ohno of theTokyo University of Agriculture and Technology.
This compound has a highly polar phosphoric acid derivative as an anion and can dissolve cellulose under mild
conditions 7).

7) JY. Fukaya, K. Hayashi, M. Wada, and H. Ohno, Green Chem ., 2008, 10, 44-46.

Item List
1-Ethyl-3-methylimidazolium methylphosphonate
1137959-66-0

14670-35

for advanced material research

25 mL

C7H15N2O3P

14670-25

for advanced material research

100 mL

206.2

Solubility●Compatibility when mixed with various solvents ( Volume ratio 1:1)
Solvent

1-Ethyl-3-methylimidazolium methylphosphonate

Water

○

Methanol○

Ethanol○

Acetone○Ethyl acetate×

Acetonitrile○

Tetrahydrofuran△

Diethyl ether

×

Hexane×

Toluene×

Dichloromethane○

Chloroform○○ ： Dissolve △ ： Partly dissolved × ： Insoluble

Related item
【BMIm Cl】

1-Butyl-3-methylimidazolium chloride
79917-90-1

05068-53

for advanced material research

5g

C8H15ClN2

05068-33

for advanced material research

25 g

174.7
65℃

7

Iodine-based ionic liquids
Iodine-based ionic liquids have long been considered in fields such as dye-sensitized solar cells, but someproducts have been found to be colored due to iodine. This product is an ionic liquid with extremely low
coloration.

Item List
Item List
1,3-Dimethylimidazolium
iodide4333-62-4

10506-35

for advanced material research

25 g

C5H9IN2

10506-25

for advanced material research

100 g35935-34-3

14669-35

for advanced material research

25 g

C6H11IN2

14669-25

for advanced material research

100 g119171-18-5

32520-35

for advanced material research

25 mL

C7H13IN2

32520-25

for advanced material research

100 mL

65039-05-6

04235-35

for advanced material research

25 mL

C8H15IN2

04235-25

for advanced material research

100 mL

178631-05-5

18010-35

for advanced material research

C10H19IN2

18010-25

224
88℃【EMIm I】

1-Ethyl-3-methylimidazolium iodide

238.1
80-85℃

1-Methyl-3-propylimidazolium iodide

252.1
935 cP

1.54

0.96 mS/cm【BMIm I】

1-Butyl-3-methylimidazolium iodide

266.1
-72℃

1183 cP

1.48

0.52 mS/cm

1-Hexyl-3-methylimidazolium iodide
25 mL
100 mL

294.2
1730 cP

0.25 mS/cm【AMIm I】

1-Allyl-3-methylimidazolium iodide
65039-07-8

01120-35

for advanced material research

25g

C7H11IN201120-25

for advanced material research

100g

250.1
57℃

【AEIm I】

1-Allyl-3-ethylimidazolium iodide
920981-07-3

01119-35

for advanced material research

25mL

C8H13IN201119-25

for advanced material research

100mL

218151-78-1

11507-35

for advanced material research

25 g

C8H15IN2

11507-25

for advanced material research

100 g

264.1

1,2-Dimethyl-3-propylimidazolium iodide

266.1
94℃

8

Pick up 1
Aliphatic ionic liquids developed by Mr. Matsumoto and his team at the National Institute of Advanced Industrial
Science and Technology (AIST) have been commercialized.

Item List【P13 TFSA】

1-Methyl-1-propylpyrrolidinium bis(trifluoromethanesulfonyl)imide
223437-05-6

26050-55

for advanced material research

5 mL

C10H18F6N2O4S226050-35

for advanced material research

25 mL

408.4
59 cP

1.43

4.92 mS/cm【P14 TFSA】

1-Butyl-1-methylpyrrolidinium bis(trifluoromethanesulfonyl)imide
223437-11-4

26125-53

for advanced material research

5 mL

C11H20F6N2O4S226125-33

for advanced material research

25 mL

422.4
-18℃

72 cP

1.4

2.12 mS/cm【PP13 TFSA】

1-Methyl-1-propylpiperidinium bis(trifluoromethanesulfonyl)imide
608140-12-1

26039-53

for advanced material research

5 mL

C11H20F6N2O4S226039-33

for advanced material research

25 mL

422.4
176 cP

1.41

2.12 mS/cm【TMPA TFSA】

N,N,N-Trimethyl-N-propylammonium bis(trifluoromethanesulfonyl)imide
268536-05-6

41110-53

for advanced material research

5 mL

C8H16F6N2O4S241110-33

for advanced material research

25 mL

382.3

Solubility and potential window●Compatibility when mixed with various solvents(Volume ratio 1:1)

●Potential window for each ionic liquid

P13
TFSI

P14
TFSI

PP13
TFSI

TMPA
TFSI

80

Solvent
Water

×

×

×

×

60

Methanol

○

○

○

○

○

○

○

○

2- propanol

○

○

○

○

Acetone

○

○

○

○

Ethyl acetate

○

○

○

○

Acetonitrile

○

○

○

○

Tetrahydrofuran

○

○

○

○

Diethyl Ether

△※1

△※4

×

△※1

Hexane××××

Toluene

△※3

△※3

△※3

△※2

Dichloromethane

○

○

○

○

Chloroform○ ： Dissolve△ ： Partly dissolved
× ： Insoluble

○

○

○

○

※ 1 : 20% dissolved※ 2 : 50% dissolved※ 3 : 90% dissolved※ 4 : 40% dissolved

Counter electrode：Pt
Reference electrode：Ag / Ag+ / MeCN / TBAP
Sweep rate：50 mV/s

40

20

0

I /μA

EthanolWorking electrode：Pt (ID1.6 mm, 0.02 cm 2)

－
20

(1
TMPA
TFSI
)

(2
PP13
TFSI
)

－
40

P13
(3 TFSI)P14(4 TFSI

－
60
－
80

)

EMImB
EMIm
BF4
F

－
4

－
3

－
2

－1

0

1

4

2

3

Potential / V vs. Fc / Fc+

9Pick up 2 ～ Nisshinbo Holdings Inc. ionic liquids
Item List
1-(2-Methoxyethyl)-1-methyl-pyrrolidinium bis(trifluoromethanesulfonyl)imide
757240-24-7
for advanced material research25966-55
C10H18F6N2O5S2
for advanced material research25966-35
424.4
for advanced material research25966-05

25967-4525967-2525967-05

C8H18BF4NO
231

5mL
25mL
500g

【MEMP BF4】

1-(2-Methoxyethyl)-1-methyl-pyrrolidinium tetrafluoroborate464927-76-2【MEMP TFSA】

for advanced material research

10mL

for advanced material research

100mL

for advanced material research

500g

N,N-Diethyl-N-methyl-N-(2-methoxyethyl)ammonium bis(trifluoromethanesulfonyl)imide
464927-84-2
for advanced material research
11468-55
C10H20F6N2O5S2
for advanced material research
11468-35【DEME TFSA】
5 mL
25 mL

426.4

N,N-Diethyl-N-methyl-N-(2-methoxyethyl)ammonium tetrafluoroborate464927-72-8
11469-45
C8H20NOBF411469-25【DEME BF4】
for advanced material research

10 mL

for advanced material research

100 mL

233.1

1.24 mS/cm

Solubility●Compatibility when mixed with various solvents ( Volume ratio 1:1)
Solvent

MEMP TFSI

Water

×

Methanol○○

Ethanol○

2- propanol○

Acetone

○

○

○

○

Ethyl acetate

○

△ ※1

○

×

DEME TFSI

DEME BF4

○

○

△ ※1

○

△ ※3

△ ※2

△ ※2

△※ 4

×

○

Acetonitrile

○

○

○

○

Tetrahydrofuran

○

△ ※3

○

△※ 3

Hexane××××

Toluene

○

×

×

×

Chloroform

○

○

○

○ ： Dissolve△ ： Partly dissolved
× ： Insoluble

10

MEMP BF4○○※ 1 : 30% dissolved※ 2 : 10% dissolved※ 3 : 20% dissolved※ 4 : max. 10%
dissolved

Pick up 2 ～ Nisshinbo Holdings Inc. ionic liquids
Potential window

Anion : BF 4

3

Current density [mA/cm2]

WE : Glassy Carbon
2

CE : Pt
Scan rate : 5 mV/sec

1
0-1

MEMP BF4
DEME BF4-2

EMI BF4
-3
-5

-4

-3

-2

-1

0

1

2

3

4

5

Potential [V vs. Ag/Ag+]

Anion : TFSI3

Current density [mA/cm2]

WE : Glassy Carbon
2
1

CE : Pt
Scan rate : 5 mV/sec

0-1
MEMP TFSI
DEME TFSI-2

EMI TFSI

-3
-5

-4

-3

-2

-1

0

1

2

3

4

5

Potential [V vs. Ag/Ag+]

11

Pick up 3 ～ Nippon Chemical Industrial
Quaternary Phosphonium ionic liquids
Item List【P2225 TFSA】

Triethylpentylphosphonium bis(trifluoromethanesulfonyl)imide
1010707-47-7

40334-35

for advanced material research40335-35

for advanced material research40336-35

for advanced material research

25 mL

C13H26F6NO4PS2
469.4
17℃

88 cP

1.32

1.70 mS/cm【P2228 TFSA】

Triethyloctylphosphonium bis(trifluoromethanesulfonyl)imide
1002754-38-2
C16H32F6NO4PS2
511.5< -50(Tg)

129 cP

1.26

0.98 mS/cm【P4441 TFSA】

Tributylmethylphosphonium bis(trifluoromethanesulfonyl)imide
324575-10-2
C15H30F6NO4PS2
497.5
16℃

207 cP

1.28

0.42 mS/cm

Solubility●Compatibility when mixed with various solvents ( Volume ratio 1:1)
Solvent

P2225 TFSI

P2228 TFSI

P4441 TFSIP222(1O1) TFSI

Water

×

×

○

×

Methanol

○

○

○

○

Ethanol

○

○

○

○

Acetone

○

○

○

○

Acetonitrile

○

○

○

○

Hexane××××

Chloroform

○

○

○

○

○ ： Dissolve , △ ： Partly dissolved , × ： Insoluble

Potential window10
作用電極：Glassy
carbonWorking
electrode： Glassy
carbon対

極：PtCounter electrode：Pt

参照電極：Ag/ Ag 掃Referenceelectrode：Ag/ Ag++

Current density [mA/cm2]

引速度：1
/ sec
Sweep
rate：1 mV
m V/sec

50－
5P2225 TFSI
P2228 TFSI

－10
-4

-3

-2

-1

0

1

Potential [V vs. Fc/Fc+]

12

25 mL

2

3

4

25 mL

FSI ( Bis fluorosulfonyl imide ) ionic liquids
FSI-based ionic liquids are widely considered as electrolytes for rechargeable batteries due to theirsuperiority over TFSI-based ionic liquids in terms of viscosity and ionic conductivity.

Item List【EMIm FSA】

1-Ethyl-3-methylimidazolium bis (fluorosulfonyl)imide
14697-35

235789-75-0

for advanced material research

25 mL

C6H11F2N3O4S2
291.3
-14℃

20 cP

1.45

【BMIm FSA】

1-Butyl-3-methylimidazolium bis(fluorosulfonyl)imide
05816-35

1235234-58-8

for advanced material research

25 mL

C8H15F2N3O4S2
319.4
33 cP

1.36

【P13 FSA】

1-Methyl-1-propylpyrrolidinium bis(fluorosulfonyl)imide
25978-35

852620-97-4

for advanced material research

25mL

C8H18F2N2O4S2
308.4

Solubility●Compatibility when mixed with various solvents ( Volume ratio 1:1)
Solvent

EMIm FSIBMIm FSI

Water

×

×

×

Methanol○○○

Ethanol○○

P13 FSI○

2- propanol

×△

Acetone○○○Ethyl acetate

○

○

○

Acetonitrile

○

○

○

Tetrahydrofuran

○

○

○

Diethyl ether

×

×

×

Hexane×××

Toluene×○×

Dichloromethane

○

○

○

Chloroform

○

○

○

※1

○ ： Dissolve , △ ： Partly dissolved , × ： Insoluble×※ 1 : 10% dissolved

13Imidazolium based ionic liquids
1-Alkyl-3-methylimidazolium
1,3-Dimethylimidazolium iodide
4333-62-4
C5H9IN2

10506-35
10506-25

for advanced material research

25 g

for advanced material research

100 g

224
88℃

【EMIm Br】

1-Ethyl-3-methylimidazolium bromide
65039-08-9
C6H11BrN2

14609-53
14609-33

for advanced material research

5g

for advanced material research

25 g

191.1
74℃

【EMIm I】

1-Ethyl-3-methylimidazolium iodide
35935-34-3
Imidazolium based ionic liquids

C6H11IN2

14669-35
14669-25

for advanced material research

25 g

for advanced material research

100 g

238.1
80-85℃【EMIm PF6】

1-Ethyl-3-methylimidazolium hexafluorophosphate
155371-19-0
C6H11F6N2P

14643-53
14643-33

for advanced material research

5g

for advanced material research

25 g14670-35
14670-25

for advanced material research

25 mL

for advanced material research

100 mL

256.1
62℃

1.56

1-Ethyl-3-methylimidazolium methylphosphonate
1137959-66-0
C7H15N2O3P
206.2【EMIm FSA】

1-Ethyl-3-methylimidazolium bis (fluorosulfonyl)imide
235789-75-0

14697-35

for advanced material research

14644-53
14644-33

for advanced material research

5 mL

for advanced material research

25 mL

25 mL

C6H11F2N3O4S2
291.3
-14℃

20 cP

1.45

1-Ethyl-3-methylimidazolium tetrafluoroborate
143314-16-3
CH3C3H3N2C2H5BF4
198
15℃

14

34 cP

1.28

14.1 mS/cm

Imidazolium based ionic liquids

1-Methyl-3-propylimidazolium iodide
119171-18-5
C7H13IN2

32520-35
32520-25

for advanced material research

25 mL

for advanced material research

100 mL

252.1
935 cP

1.54

0.96 mS/cm【BMIm Cl】

1-Butyl-3-methylimidazolium chloride
79917-90-1
C8H15ClN2

05068-53
05068-33

for advanced material research

5g

for advanced material research

25 g

174.7
65℃

【BMIm I】

1-Butyl-3-methylimidazolium iodide

C8H15IN2

04235-35
04235-25

for advanced material research

25 mL

for advanced material research

100 mL

266.1-72℃

1183 cP

1.48

0.52 mS/cm【BMIm PF6】

1-Butyl-3-methylimidazolium hexafluorophosphate
174501-64-5
CH3C3H3N2C4H9PF605064-53
05064-33

for advanced material research

5 mL

for advanced material research

25 mL

284.2
-8℃

267 cP

1.37

1.37 mS/cm【BMIm FSA】

1-Butyl-3-methylimidazolium bis(fluorosulfonyl)imide
1235234-58-805816-35

for advanced material research

25 mL

C8H15F2N3O4S2
319.4
33 cP

1.36

【BMIm TFSA】

1-Butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide
174899-83-3

05063-53

for advanced material research

5 mL

CH3C3H3N2C4H9[(CF3SO2)2N]

05063-33

for advanced material research

25 mL

419.4
-4℃

49 cP

1.44

3.41 mS/cm【BMIm BF4】

1-Butyl-3-methylimidazolium tetrafluoroborate
174501-65-6
C8H15N2BF405065-53
05065-33

for advanced material research

5 mL

for advanced material research

25 mL

226
-97(Tg)104 cP

1.21

3.15 mS/cm

15

Imidazolium based ionic liquids

65039-05-6

Imidazolium based ionic liquids

1-Hexyl-3-methylimidazolium iodide
178631-05-5

18010-35

C10H19IN2

18010-25

294.2

1730 cP

Imidazolium based ionic liquids

16

0.25 mS/cm

for advanced material research

25 mL
100 mLImidazolium based ionic liquids
1-Alkyl-3-allylimidazolium
1-Allyl-3-methylimidazolium
bromide【AMIm Br】
31410-07-801986-55

for advanced material research

5g

C7H11BrN2

01986-35

for advanced material research

25g

203.1

01986-15

for advanced material research

250g

58℃

1.60 mS/cm【AMIm I】

1-Allyl-3-methylimidazolium iodide
65039-07-8

01120-35

for advanced material research

25g

C7H11IN201120-25

for advanced material research

100g

250.1

57℃

35 cP

655249-87-901988-55

for advanced material research

5mL

C9H11F6N3O4S201988-35

for advanced material research

25mL

403.3

01988-15

for advanced material research

250mL

1.49

8.87 mS/cm【AMIm BF4】

1-Allyl-3-methylimidazolium tetrafluoroborate
851606-63-801987-55

for advanced material research

5mL

C7H11BF4N2

01987-35

for advanced material research

25mL

210

01987-15

for advanced material research

250mL【AEIm Br】

1-Allyl-3-ethylimidazolium bromide
652134-09-3

01930-55

for advanced material research

5g

C8H13BrN2

01930-35

for advanced material research

25g

217.1

01930-15

for advanced material research

250g【AEIm I】

1-Allyl-3-ethylimidazolium iodide
920981-07-3

01119-35

for advanced material research

25mL

C8H13IN201119-25

for advanced material research

100mL

264.1

17

Imidazolium based ionic liquids【AMIm TFSA】

1-Allyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide

Imidazolium based ionic liquids【AEIm TFSA】

1-Allyl-3-ethylimidazolium bis(trifluoromethanesulfonyl)imide
652134-11-7

01932-55

for advanced material research

C10H13F6N3O4S201932-35

for advanced material research

25mL

417.4

01932-15

for advanced material research

250mL

5mL

【AEIm BF4】

1-Allyl-3-ethylimidazolium tetrafluoroborate
945732-42-3

01931-55

for advanced material research

C8H13BF4N2

01931-35

for advanced material research

25mL

224

01931-15

for advanced material research

250mL

5mL

【ABIm Br】

1-Allyl-3-butylimidazolium bromide
Imidazolium based ionic liquids

863498-30-001933-55

for advanced material research

C10H17BrN201933-35

for advanced material research

25mL

245.2

01933-15

for advanced material research

250mL

5mL

0.50 mS/cm【ABIm TFSA】

1-Allyl-3-butylimidazolium bis(trifluoromethanesulfonyl)imide
863498-34-4

01935-55

for advanced material research

C12H17F6N3O4S201935-35

for advanced material research

25mL

445.4

01935-15

for advanced material research

250mL

5mL

1.53 mS/cm【ABIm BF4】

1-Allyl-3-butylimidazolium tetrafluoroborate
863498-32-2

01934-55

for advanced material research

C10H17BF4N201934-35

for advanced material research

25mL

252.1

01934-15

for advanced material research

250mL

5mL

1.22 mS/cm【AAIm Br】

1,3-Diallylimidazolium bromide
31483-71-3

11475-55

for advanced material research

C9H13BrN2

11475-35

for advanced material research

25mL

229.1

11475-15

for advanced material research

250mL

5mL

0.74 mS/cm【AAIm TFSA】

1,3-Diallylimidazolium bis(trifluoromethanesulfonyl)imide

18803732-17-4

11477-55

for advanced material research

C11H13F6N3O4S2

11477-35

for advanced material research

25mL

429.4

11477-15

for advanced material research

250mL

5mL

Imidazolium based ionic liquids【AAIm BF4】

1,3-Diallylimidazolium tetrafluoroborate
852699-06-0

11476-55

for advanced material research

5mL

C9H13BF4N2

11476-35

for advanced material research

25mL

236

11476-15

for advanced material research

250mL

Imidazolium based ionic liquids

19

Imidazolium based ionic liquids
1,2,3-Alkylimidazolium
1,2-Dimethyl-3-propylimidazolium iodide
218151-78-1

11507-35

for advanced material research

25 g

C8H15IN2

11507-25

for advanced material research

100 g

266.1

94℃

Imidazolium based ionic liquids

20

Pyrrolidinium based ionic liquids
1-Alkyl-1-methylpyrrolidinium【P13 FSA】

1-Methyl-1-propylpyrrolidinium bis(fluorosulfonyl)imide
852620-97-4

25978-35

for advanced material research

25mL

C8H18F2N2O4S2
308.4【P13 TFSA】

1-Methyl-1-propylpyrrolidinium bis(trifluoromethanesulfonyl)imide
223437-05-6

26050-55

for advanced material research

5 mL

C10H18F6N2O4S226050-35

for advanced material research

25 mL

408.4

59 cP

1.43

4.92 mS/cm【P14 TFSA】

1-Butyl-1-methylpyrrolidinium bis(trifluoromethanesulfonyl)imide
223437-11-4

26125-53

for advanced material research

5 mL

C11H20F6N2O4S226125-33

for advanced material research

25 mL

422.4

72 cP

1.4

Pyrrolidinium based ionic liquids-18℃

2.12 mS/cm

21

Pyrrolidinium based ionic liquids
1-Methyl-1-(X)pyrrolidiniumN -(2-Methoxyethyl)-N -methyl-pyrrolidinium
1-(2-Methoxyethyl)-1-methyl-pyrrolidiniumbis(trifluoromethanesulfonyl)imidebis(trifluoromethanesulfonyl)imide【MEMP TFSA】

757240-24-7

25966-55

for advanced material research

5mL

C10H18F6N2O5S2

25966-35

for advanced material research

25mL

424.4

25966-05

for advanced material research

500g【MEMP BF4】

1-(2-Methoxyethyl)-1-methyl-pyrrolidinium tetrafluoroborate

Pyrrolidinium based ionic liquids

22464927-76-2

25967-45

for advanced material research

10mL

C8H18BF4NO

25967-25

for advanced material research

100mL

231

25967-05

for advanced material research

500g

Piperidinium based ionic liquids
1-Alkyl-1-methylpiperidinium【PP13 TFSA】

1-Methyl-1-propylpiperidinium bis(trifluoromethanesulfonyl)imide
608140-12-1

26039-53

for advanced material research

5 mL

C11H20F6N2O4S226039-33

for advanced material research

25 mL

422.4

176 cP

1.41

2.12 mS/cm

Piperidinium based ionic liquids

23

Ammonium based ionic liquids
Alkylammonium【TMPA TFSA】

N,N,N-Trimethyl-N-propylammonium bis(trifluoromethanesulfonyl)imide
268536-05-6

41110-53

for advanced material research

5 mL

C8H16F6N2O4S241110-33

for advanced material research

25 mL

382.3

Ammonium based ionic liquids

24

Ammonium based ionic liquids
Ammonium [Others]
N ,N-Diethyl-N -methyl-N -(2-methoxyethyl)ammonium
tetrafluoroborate
N,N-Diethyl-N-methyl-N-(2-methoxyethyl)ammonium bis(trifluoromethanesulfonyl)imide【DEME TFSA】

464927-84-2

11468-55

for advanced material research

5 mL

C10H20F6N2O5S211468-35

for advanced material research

25 mL

426.4

【DEME BF4】

N,N-Diethyl-N-methyl-N-(2-methoxyethyl)ammonium tetrafluoroborate464927-72-8

11469-45

for advanced material research

10 mL

C8H20NOBF411469-25

for advanced material research

100 mL

233.1

1.24 mS/cm

Ammonium based ionic liquids

25

Phosphonium based ionic liquids
Alkylphosphonium【P2225 TFSA】

Triethylpentylphosphonium bis(trifluoromethanesulfonyl)imide
1010707-47-7

40334-35

for advanced material research

25 mL

C13H26F6NO4PS2
469.4

17℃

88 cP

1.32

1.70 mS/cm【P2228 TFSA】

Triethyloctylphosphonium bis(trifluoromethanesulfonyl)imide
1002754-38-2

40335-35

for advanced material research

25 mL

C16H32F6NO4PS2
511.5< -50(Tg)

129 cP

1.26

0.98 mS/cm【P4441 TFSA】

Tributylmethylphosphonium bis(trifluoromethanesulfonyl)imide
324575-10-2
C15H30F6NO4PS2
497.5

16℃

Phosphonium based ionic liquids26

207 cP

1.28

0.42 mS/cm

40336-35

for advanced material research

25 mL

Related products

Name

CAS RN®

FormulaweightLithium bis(fluorosulfonyl)imide

171611-11-3

187.1

Lithium bis(trifluoromethanesulfonyl)imide

Potassium bis(trifluoromethanesulfonyl)imide

1,1,1-Trifluoro-N-[(trifluoromethyl)sulfonyl]methanesulfonamide

Lithium bis(nonafluorobutanesulfonyl)imide

90076-65-6

90076-67-8

82113-65-3

119229-99-1

287.1

319.2

281.2

Product CodePackage

24076-555g

24076-35

25 g24290-35

25 g24290-15

250 g24290-95

2 kg

33005-35

25 g

33005-15250 g

33005-95

2 kg

41075-35

25 g41075-15250 g41075-95

2 kg24039-651g24039-55

5g

587.1

Potassium bis(nonafluorobutanesulfonyl)imide

129135-87-1

619.3

33008-55

5g

1,1,2,2,3,3,4,4,4-Nonafluoro-N-

39847-39-7

581.2

28395-651g28395-55

5g[(nonafluorobutyl)sulfonyl]-1-butanesulfonamide

Related products

27

Custom synthesis service
Ionic liquids are known to change their physico-chemical properties, such as viscosity, polarity, hydrophilicity andhydrophobicity, depending on the combination of their constituent cations and anions. For this reason, ionic liquids
are being investigated for practical applications, such as electrolytes for next-generation secondary batteries,
cellulose dissolvers, gas absorbers and lubricants, as liquids with distinctive functions. Our ionic liquids arecharacterised by their high quality with minimal impurities, and we have experience in the contract synthesis of awide range of ionic liquids. Furthermore, we can supply ionic liquids on a variety of scales, from research to

production applications. If you have a specific ionic liquid, grade or quantity you require, please contact us.

R1

+

R2

N
R3

BF4

R4

-

R1

N

R1

+

N

R2

R1

N+

R2

R1

O
O
F3 C S N S CF3O
O

CF3SO 3-

N+

+

R2

P
R2

R3

R4

O
O
F S N S FO
O

etc...

Synthesis

Delivery

From Inquiry to Delivery

Inquiry

Discussion

Considerationand quotation

Agreement*If necessary, we will conclude a confidentiality agreement.
*In the event that synthesis is difficult, or it is predicted that the customer's request will not be met,
we may decline the request.

28

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