News Letter(August, 2016)

SPACC ニュースレター（２０１６年 8 月号）
内容◎SPACC 23のご案内◎

本会会員が主催するシンポジウム、セッション等◎

研究紹介
福本晃造（琉球大学）
岩崎雄大（関西大学）◎事務局からの連絡The 23st International SPACC Symposium– Functional complexes and their new applications –The 1st International RINS Symposium

November 21 to November 23, 2016Okayama, JapanFirst Circular and Call for Papers

Organized by
The Society of Pure and Applied Coordination Chemistry
andOkayama University of ScienceINVITATION
Dear Colleagues,
The 23st International SPACC (The Society of Pure and Applied Coordination Chemistry) Symposium
will be held at Okayama University of Science, from November 21 to November 23, 2016. TheInternational Advisory and Organizing Committee cordially invite you to attend the Symposium andparticipate in its scientific and social programs. The main theme of the Symposium will be“Functional complexes and their new applications.” The Symposium will focus on the chemistry ofnovel and useful application of coordination chemistry that can open the novel area, afford novel
materials, and find insight of the organic, inorganic, and biological system for the new sustainablefeature.
As with previous SPACC Symposia, it is intended that this Symposium will provide a platform foryoung scientists to exchange scientific information among themselves and with the selected leading
scientists. This challenging symposium began in Tokyo just 20 years ago by the SPACC fellow Prof.
Yano, and has being held annually and consecutively in the world. It is our great pleasure to hold this23st Symposium in Okayama.
Presentations will consist of three categories, several invited lectures, oral presentations, and poster
presentations. Prizes will be awarded for the best presentations, especially for students. TheInternational Advisory and Organizing Committee hope all registrants will present a paper, but
acceptance of papers will be at the discretion of the Committee. The official language of thesymposium will be English.
In the following pages, you will find details concerning the Symposium. We look forward to meeting
you in the best season of Okayama, Japan!

Important Deadlines
Early-bird registration: August 26
Application of all presentations: August 26
Payment for registration fee (domestic participants only*1): September 23
Abstract submission: September 23*1

Only bank transfer will be available for early-bird payment. Participants from overseas must pay thefee at the symposium site by JPY.

ADVISORY AND ORGANIZING COMMITTEE
Honorary Chairperson:
Yasunobu Yanagisawa

President of Okayama University of ScienceChairperson:
Haruo Akashi

Okayama University of ScienceCo-chairperson:
Takanori Nishioka

Osaka City University

Shigenobu Yano

Fellow of SPACC/Nara Institute of Science and Technology

Committee member:
Tetsuo Nagano

Tokyo University

Ichiro Okura

Tokyo Institute of Technology

Toshihiko Ozawa

National Institute of Radiological Sciences

Toshifumi Satoh

Hokkaido University

Yutaka Amao

Osaka City University

Yuji Mikata

Nara Women’s University

Hideki Hashimoto

Kwansei Gakuin University

Yuko Sugai

Kwansei Gakuin UniversityMisaki Nakai

Kansai University

Yuriko Matsumura

Tokyo Healthcare University

Keisuke Kawamoto

Kanazawa University

Yuri Maeda

Nagoya Institute of Technology

Local committee member:
Hironobu Hyodo

Okayama University of Science

Minoru Mitumi

Okayama University of Science

Hideyuki Higashimura

Okayama University of Science

Akihiro Orita

Okayama University of Science

Yasushi Sato

Okayama University of Science

Takayoshi Suzuki

Okayama University

Yukinari Sunatsuki

Okayama University

International Advisory Board
Li Lu

National University of Singapore

Cheng-Hsin ChuangSouthern Taiwan University of Science and Technology

Xiao-Yuan Li

Hong Kong University of Science and Technology

Shenguo Wang

Chinese Academy of ScienceOuyang Jie

Tianjin Institute of Technology

Terrence J. Collins

Carnegie Mellon University

Chris Orvig

University of British Columbia

James Wright

Auckland University

Shie-Ming Peng

National Taiwan University

Xiangshi Tan

Fudan University

Handong Yin

Liaocheng University

Jianmin Dou

Liaocheng University

Tim Storr

Simon Fraser University

CORRESPONDENCE
All correspondence concerning the Symposium should be addressed to:Professor Haruo Akashi,
Research Institute of Natural Sciences,
Okayama University of Science
1-1 Ridai-cho,Okayama 700-0005, Japan
Tel: +81-86-256-9721
E-mail: spacc23@rins.ous.ac.jp

SCIENTIFIC PROGRAM （Tentative)
The Scientific Program will include plenary lectures, invited lectures, oral and poster presentations.
The official language of the Symposium is English. Registration, all lectures and the oral and posterpresentations will be held at Okayama University of Science.

Monday, November 21
8:30----

Registration

9:00----9:30

Opening Remarks

Morning Session
9:30----12:00
12:00----13:00

Lunch

Afternoon Session
13:00----17:20
17:20----17:30

The rites of SPACC-awards

17:30----18:00

SPACC-awards lecture

18:30----20:30

Symposium dinner

Tuesday, November 22
Morning Session
9:30----13:00
13:00----14:00

Lunch

Afternoon Session (Poster Session)
14:00----15:45
15:45----16:00

Closing Ceremony & the rites for poster awards

Wednesday, November 23
9:00----12:00

Laboratory Tour for Future CollaborationREGISTRATION FORM
Registration should be made via email. Please use copy and paste the following form, complete it, andsend the form via e-mail to Professor Haruo Akashi (spacc23@rins.ous.ac.jp)with “Registration
SPACC23 + your name” as the subject.
The deadline for early-bird registration would be August 26, through Bank Transfer only from a bankaccount in Japan, by September 23. For participants from overseas, the registration fee should be paid
at the symposium site by JPY, and no payment by credit card would be useful. However, theearly-bird registration for participants from overseas should be made.

Registration form
Name:
Title:
Affiliation:
SPACC member (yes or no):Student (yes or no):Grade (if you are a student):
Banquet (yes or no):E-mail:Telephone number:Name(s) of accompanying person:

To Pay by Bank Transfer (only from a bank account in Japan), please send your payment to:

Bank Name: Japan Post Bank (ゆうちょ 銀⾏行行)
Branch name: 019
Account name: The Society of Pure and Applied Coordination Chemistry (先端錯体⼯工学研究会）

Account number: 0773549（当座)Please input the registration “SPACC23” before your name.

Registration fee
Early-Bird Fee*

Regular Fee(Deadline: July 31)(at symposium site)

General¥ 15,000¥ 20,000

Student¥ 5,000¥ 7,000

General¥ 20,000¥ 25,000

Student¥ 8,000¥ 10,000

Registration Type

MemberNon-member

Banquet General¥ 5,000

Student¥ 3,000

The refund policy for cancellations is as follows:- For cancellations received on or before September 30, 2016: Full refund- For cancellations received on or after October 1 until October 31, 2016: 50% refund- For cancellations received on or after November 1, 2016: no refunds.

APPLICATION FORM FOR PRESENTATIONS
Please use copy and paste the following form, complete it, and send the form via e-mail to Professor
Haruo Akashi (spacc23@rins.ous.ac.jp) with “Presentation for SPACC23 + your name” as the subject,
by August 26. The deadline for abstract submission would be September 23.

Presentation (oral/poster):
Title of the presentation:
Author’s Name(s):Affiliation(s):Address:
Presenter:
Grade (if the presenter is a student):
Student Award (Lecture, Poster, or not apply):
E-mail:Registrations will only be made via e-mail (spacc23@rins.ous.ac.jp).

ORAL PRESENTATIONS:
Abstracts should be prepared according to the Abstract Preparation Guidelines described below. From
July 25, authors can download the abstract template from the website (http://spacc.gr.jp/). The
abstract should be sent via e-mail (spacc23@rins.ous.ac.jp) to Professor Haruo Akashi with“Presentation for SPACC23 #submission ID” as the subject, and “#submission ID + name” as the filename.

The submission ID is a five-digit number. Only Acrobat PDF files will be accepted. The

deadline for abstract submission would be September 23. Authors will be informed within 3 weeks, if
their contribution has been accepted for a poster presentation rather than an oral presentation. Standard
facilities for PC presentations will be available at the Symposium site.

POSTER PRESENTATION:
Poster presentations will be very welcome as well. Authors should submit the same information(including an abstract) as listed for oral presentations above by the same deadlines. The poster
presentation session will be held on afternoon, November 22, Tuesday. However all posters will beplaced on the viewing boards from the Tuesday morning and will therefore be available for viewing
during coffee breaks and lunch for the duration of the conference. A board (approximately 90 cmwidth, 160 cm height) will be available for posting each presentation.

ABSTRACT PREPARATION GUIDELINES
1. The abstract should be submitted in English, the official language of the symposium.
2. As the submitted abstract will be printed and reproduced directly without any editing, special careshould be taken to ensure high quality of text and diagrams.
3. From July 25, authors can download the abstract template from the website (http://spacc.gr.jp/).

◎ 本会会員が主催するシンポジウム、セッション等

HU-NTU-CERMAV Joint Symposium on Functional Materials 2016
HU: Hokkaido University, Japan(北海道大学)
NTU: National Taiwan University, Taiwan（国立台湾大学）
CERMAV-CNRS: Centre de Recherches sur les Macromolécules Végétales, France(フランス国立科学研究センター 植物高分子研究所)

日時：2016 年8 月5 日（金）9:00‐17:30
場所：北海道大学工学部

フロンティア応用科学研究棟セミナー室1

札幌市北区北１３条西８丁目
札幌地下鉄南北線、北12条駅、徒歩15 分参加費：無料
プログラム：http://poly-bm.eng.hokudai.ac.jp/hncjs2016/index.html

Program Summary
Aug 5th, Friday, 2016
at Seminar Room 1, Frontier Research in Applied Sciences Building,
Faculty of Engineering, Hokkaido University
9:00―9:05

Opening Remarks

Toshifumi SATOH (Hokkaido University, Japan)

9:05―9:35
Invited Lecture
IL01
Functionalized Inorganic Nanoporous Materials for Biofuel Production from
Lignocellulosic Biomass
Kevin C.-W. WU (National Taiwan University, Taiwan)
9:35―9:50
Invited Lecture
IL02
Lignin Depolymerization using Water/organic Biphasic Solvent
Takuya YOSHIKAWA (Hokkaido University, Japan)
9:50―10:20
Invited Lecture
IL03
Recovery of Phenolic Compounds from Biomass-derived Lignin
Takao MASUDA (Hokkaido University, Japan)
10:20―10:35

Coffee Break10:35―11:05
Invited Lecture (Special Guest)
IL04
Synthesis and Electrochemical Properties of Hierarchically Porous
Zn(Co1-xMnx)2O4 Anode for Li-Ion Batteries via Cation Substitution Design
Wei-Ren LIU (Chung Yuan Christian University, Taiwan)
11:05―11:35
Invited Lecture
IL05
Unique Monolithic Porous Carbons with a Tunable Hierarchical Pore Systemof Micro-, Meso- and Macropores
Shin MUKAI (Hokkaido University, Japan)
11:35―13:00

Luncheon meeting

13:00―13:30
Invited Lecture
IL06
Functional Materials by Self-Assembly of Cyclic Polymers
Takuya YAMAMOTO (Hokkaido University, Japan)
13:30―14:00
Invited Lecture
IL07
Carbohydrate-based block copolymer self-assemblies: Highly nanostructured
thin films and DSA patterning
Redouane BORSALI(CERMAV-CNRS and Grenoble Alpes University, France)
14:00―14:30
Invited Lecture
IL08
Sub-10 nm Scale Microphase-Separated Structures in Hybrid Block
Copolymers
Toshifumi SATOH (Hokkaido University, Japan)
14:30―14:45
14:45―16:15
IL09

Coffee BreakSpecial Lecture for Hokkaido Summer Institute

Organic Materials for Electrical memory Device Applications
Wen-Chang CHEN (National Taiwan University, Taiwan)

16:15―16:30

Coffee Break

16:30―17:00
Invited Lecture
Inkjet Printed Conductive Thin Film Patterns
IL10
Ying-Chih LIAO (National Taiwan University, Taiwan)

17:00―17:30
Invited Lecture
Facile Synthesis of Various Shaped SnO Particles in Organic Medium
IL11
Mai Thanh NGUYEN and Tetsu YONEZAWA (Hokkaido University, Japan)
17:30―

Closing Remarks

Toshifumi SATOH (Hokkaido University, Japan)

HU-NTU-CERMAV Joint Symposium
on Functional Materials 2016

HU: Hokkaido University, Japan
NTU: National Taiwan University, Taiwan
CERMAV: Centre de Recherches sur les Macromolécules Végétales-CNRS, FranceVenue: Seminar Room 1, Frontier Research in Applied Sciences Building,
Faculty of Engineering, Hokkaido University, Japan
Dates: Aug 5th, 2016
Schedule:Aug 5th (Friday)
9:00- Opening Remark
Toshifumi SATOH (Hokkaido University, Japan)
9:05- Functionalized Inorganic Nanoporous Materials for Biofuel Production from
Lignocellulosic Biomass
Kevin C.-W. WU (National Taiwan University, Taiwan)
9:35- Lignin Depolymerization using Water/organic Biphasic Solvent
Takuya YOSHIKAWA (Hokkaido University, Japan)
9:50- Recovery of Phenolic Compounds from Biomass-derived Lignin
Takao MASUDA (Hokkaido University, Japan)
10:35- Synthesis and Electrochemical Properties of Hierarchically Porous
Zn(Co1-xMnx)2O4 Anode for Li-Ion Batteries via Cation Substitution Design
Wei-Ren LIU (Chung Yuan Christian University, Taiwan)
11:05- Unique Monolithic Porous Carbons with a Tunable Hierarchical Pore System ofMicro-, Meso- and Macropores
Shin MUKAI (Hokkaido University, Japan)
13:00- Functional Materials by Self-Assembly of Cyclic Polymers
Takuya YAMAMOTO (Hokkaido University, Japan)
13:30- Carbohydrate-based block copolymer self-assemblies: Highly nanostructured
thin films and DSA patterning
Redouane BORSALI (CERMAV-CNRS and Grenoble Alpes University, France)
14:00- Sub-10 nm Scale Microphase-Separated Structures in Hybrid Block Copolymers
Toshifumi SATOH (Hokkaido University, Japan)
14:45- Organic Materials for Electrical memory Device
Wen-Chang CHEN (National Taiwan University, Taiwan)
17:00- Inkjet Printed Conductive Thin Film Patterns
Ying-Chih LIAO (National Taiwan University, Taiwan)
17:30- Facile Synthesis of Various Shaped SnO Particles in Organic Medium
Mai Thanh NGUYEN and Tetsu YONEZAWA (Hokkaido University, Japan)

http://poly-bm.eng.hokudai.ac.jp/hncjs2016/index.html
Organizers: Toshifumi Satoh (Tel:011-706-6602), Wen-Chang Chen, and Redouane Borsali
This seminar was supported by Faculty of Engineering, Graduate School of Chemical Sciences andEngineering, Frontier Chemistry Center (FCC), Ambitious Leader’s Program (ALP) of Hokkaido
University, and Hokkaido branch of the Society of Polymer Science, Japan.

◎研究紹介ケイ素転位反応を利用した不活性結合の活性化
琉球大学大学院教育学研究科
福本 晃造
不活性結合の活性化は、化合物の新規合成法開発や化合物そのものの新たな反応性解明という学術価値が高いだけでなく、物質循環社会を実現するための基礎技術という視点からも人間生活や産業に大きく貢献できる可能性を持っている。近年、我々は比較的合成容易なピアノイス型鉄錯体と様々な有機化合物との反応について調べてきた。C=S 二重結合を有する第三級チオアミド（R2NC(S)R）とヒドロシラン（R3SiH）共存下、触媒量の鉄錯体（CpFe(CO)2(CH3)）を含む溶液を 80℃加熱したところ、アミン（R2NMe）の生成を確認した。これは C=S 二重結合が直接切断されたことを示している。同様の検討を窒素原子上に水素を導入した第二級チオアミド（RHNC(S)R）
やβ水素を有するイミン（RN=CR(CH2R)）に対して行ったところ、それぞれ対応するイミン（RN=CHR）および N−シリルエナミン（R(R3Si)N−CR=CHR）を与えることが明らかとなった。このように同一の鉄錯体を用いる反応系であっても、炭素－ヘテロ原子間二重結合を含む分子のわずかな置換基の違いによって、様々な分子変換反応が進行することを見出している。

分子内に単結合や三重結合を有する化合物との反応も試みている。C≡N 三重結合を持つニトリル化合物との反応では、三重結合の直接切断は進行せず、隣接した単結合の位置選択的切断反応が進行することを報告した。最近ではケイ素－硫黄単結合を持つ化合物との反応も試みており、Si−S 単結合切断反応が進行することを明らかにした。これらの反応機構の解明では、いずれも鉄中心上のケイ素原子が電子飽和な原子へと転位する反応がカギとなって多彩な分子変換反応を提供していることを明らかにしている。現在もカギ反応を利用した新たな不活性結合活性化に取り組んでいる。

連絡先（e-mail）k-fuku@edu.u-ryukyu.ac.jp

PDT 製剤を目指した拡張型ポルフィリンの合成と光特性評価
関西大学大学院
岩崎雄大・中井美早紀
効果的な光線力学療法 (Photodynamic Therapy, PDT)のために吸収極大が近赤外部に
あ る  拡 張 型 ポ ル フ ィ リ ン に 注 目 し た 。 tetraphenyltetraphenanthroporphyrin(H2TPTPhenP) の 合 成 法 を 参 考 に phenyl 部 分 の p 位 に carboxyl 基 を 導 入 し た
tetra(p-carboxyphenyl)TPhenP(H2TCPTPhenP)と、その銅錯体(CuTCPTPhenP)を合成した。
(Fig. 1.) これらのポルフィリン誘導体の DNA 光切断能はアガロースゲル電気泳動を
用 い て 評 価 し た 結 果 、 近 赤 外 領 域 (750 nm ~ 1050 nm) の 光 照 射 下 に お い て
H2TCPTPhenP が DNA 切断能を示すことが判明した。以上のことから H2TCPTPhenPは今後の PDT 治療において身体深部でも使用できる可能性を示唆するものとなった。
現在、がんの治療法として外科的処置や薬による治療などの治療法がありその中に光線力学療法 (Photodynamic Therapy:PDT)と呼ばれる方法がある。PDT は静脈注射により光増感剤を投与し患部に集積させた後に光照射を行うことで腫瘍細胞を攻撃、壊死させる方法である。PDT に用いられる光増感剤として、広く研究されている物質のひとつがポルフィリン誘導体である。PDT 製剤として Laserphyrin ®や Forscan ®などがあるが、これら製剤には光透過性の問題から身体深部に使用できないといった欠点がある。本研究では、この欠点を解決するために光透過性の良い波長域に吸収を持つ
拡張ポルフィリンの合成を行っている。既報にて報告されている拡張ポルフィリンの H2TPTPhenP の合成法を参考に、p 位に carboxyl 基を導入した H2TCPTPhenP とCuTCPTPhenP を合成した。UV-vis スペクトルより、DMF 中の H2TCPTPhenP とCuTCPTPhenP の吸収極大は tetraphenylporphyrin (H2TPP)に比べて 160 nm 程度レッドシフトしていることが判明した。これらのポルフィリン誘導体の DNA 光切断能評価はアガロースゲル電気泳動を用いて行った。全光(350 ~ 750 nm) 照射下では DNA 切断能は H2TCPTPhenP > H2TPP > CuTCPTPhenP の順に高かったのに対して、近赤外領域(750 nm ~ 1050 nm)の光照射下では H2TCPTPhenP のみが DNA 切断能を示すことが判明した。さらに Hela 細胞を用いた細胞毒性評価では
H2TCPTPhenP は赤外光照射した際に細胞毒性をしめすことが判明した。
連絡先：nakai@kansai-u.ac.jp

◎事務局からの連絡
・ SPACC ミニシンポジウム主催者を募集しております。
会員の活発な情報交換のため、ミニシンポジウムを開催していただける会員を募集しております。研究会からの助成がありますので事務局までご連絡ください。
・ SPACC 会員が主催・協賛する研究会・シンポジウムをお知らせください。
ニュースレター等を通して、会員の皆様に周知させていただきます。ニュースレター担当 中井(nakai@kansai-u.ac.jp)までお知らせください。
事務局連絡先jimukyoku@spacc.gr.jp

担当松村