<< GE00018 Denaturated Ethanol >>

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Issue date: 1/12/2010
Revision date: 3/1/2024

Safety Data Sheet
1. Chemical product and company identification
Product name: Denaturated Ethanol

Company information
Name of manufacturer
Address
Name of section
Telephone number
Facsimile number
Mail address
Reference No： KANTO CHEMICAL CO., INC.
： 2-1, Nihonbashi, Muromachi 2-Chome, Chuo-Ku, Tokyo, 103-0022, Japan： Electronic materials division technical department： +81-3-6214-1080： +81-3-3241-1043： el-info@kanto.co.jp: GE00018 1.2

Recommended uses andrestrictions: Electronic chemicals

2. Hazards identification
GHS classification
Physical hazards

Flammable liquids

Category 2

Health hazards

Serious eye damage/eyeirritation

Category 1

Carcinogenicity

Category 1A

Reproductive toxicity

Category 1ASpecific target organ toxicity(single exposure)

Category 2 (central nervous system, systemictoxicity)

Specific target organ toxicity(single exposure)

Category 3 (narcosis)

Specific target organ toxicity(single exposure)

Category 3 (respiratory tract irritation.)

Specific target organ toxicity(repeated exposure)

Category 1 (liver)

Specific target organ toxicity(repeated exposure)

Category 2 (blood, central nervous system)

Hazardpictograms

Signal word:

DangerHazard statements:

Highly flammable liquid and vapor
Causes serious eye damage
May cause respiratory irritation
May cause drowsiness or dizziness
May cause cancer
May damage fertility or the unborn child
May cause damage to organs (central nervous system, systemic
toxicity)
Causes damage to organs (liver) through prolonged or repeatedexposure<< GE00018 Denaturated Ethanol >>

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May cause damage to organs (blood, central nervous system) throughprolonged or repeated exposure
Precautionary statements
Prevention:

Do not handle until all safety precautions have been read andunderstood.
Keep away from heat, hot surfaces, sparks, open flames and otherignition sources. No smoking.
Keep container tightly closed.
Ground and bond container and receiving equipment.
Use explosion-proof electrical/ventilating/lighting equipment.
Use only non-sparking tools.
Take action to prevent static discharges.
Do not breathe mist, vapors.
Wash hands, forearms and face thoroughly after handling.
Do not eat, drink or smoke when using this product.
Use only outdoors or in a well-ventilated area.
Wear protective gloves/protective clothing/eye protection/faceprotection.

Response:

IF ON SKIN (or hair): Take off immediately all contaminatedclothing. Rinse skin with water .
IF INHALED: Remove person to fresh air and keep comfortable forbreathing.
IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continuerinsing.
IF exposed or concerned: Call a POISON CENTER or doctor.
IF exposed or concerned: Get medical advice/attention.
Immediately call a POISON CENTER or doctor.
Call a POISON CENTER or doctor if you feel unwell.
Get medical advice/attention if you feel unwell.

Storage:

Store in a well-ventilated place. Keep container tightly closed.
Store in a well-ventilated place. Keep cool.
Store locked up.

Disposal:

Dispose of contents/container to hazardous or special waste
collection point, in accordance with local, regional, national
and/or international regulation.

3. Composition/information on ingredients
Distinction of substance ormixture
Chemical name:

MixtureConcentration(%)

FormulaTSCA

EC-No.

CAS RN

Ethanol

about 85

C2H5OH

Listed200-578-6

64-17-5

2-Propanolless than 5(CH3)2CHOH

Listed200-661-7

67-63-0

1-Propanol

about 10

CH3CH2CH2OH

Listed200-746-9

71-23-8

4. First aid measures
First aid measures
First-aid measures afterinhalation:

Remove victim to fresh air and keep at rest in a position
comfortable for breathing. Get medical treatment if you feel<< GE00018 Denaturated Ethanol >>Page

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unwell.
First-aid measures after skincontact:

Remove contaminated clothing and the substance. Wash with plentyof water. Get medical attention, if you feel unwell.

First-aid measures after eye
contact:

Rinse cautiously with water for several minutes. Get medicaltreatment.

First-aid measures afteringestion:

Rinse mouth. Do not induce vomiting. Get medical attention
immediately.

Personal Protection in FirstAid and Measures:

Rescuers should wear proper protective equipment like rubber
gloves, goggles.

Suitable extinguishing media:

Dry chemical powder, water-soluble fire-extinguishing foam forliquid, water spray, carbon dioxide

Unsuitable extinguishing media:

Foam extinguisher

Firefighting instructions:

Move containers from fire area if it can be done without risk, if
not possible, apply water from a safe distance to cool andprotect surrounding area.

5. Fire fighting measures

Dry chemical powder, carbon dioxide or dry sand should be used
for small fires. Alcohol-resistant foam extinguisher is effective
for a large scale fire.
Personal protection (Emergencyresponse):

Firefighters should wear protective equipment.

6. Accidental release measures
Personal Precautions, Protective Equipment and Emergency Procedures
General measures:

Wear proper protective equipment and avoid contact with skin andinhalation of vapor. Conduct operations from upwind and evacuate
people downwind. Remove all sources of ignition. Keep away
personnel except for authorized ones from spillage area by
stretching ropes.

:

Attention should be given to avoid damage to the environment byflowing of spillage to rivers.

Environmental precautions
Environmental precautions

Methods and Equipment for Containment and Cleaning up
For containment:

Shut down the leak source to stop leakage. For small spill,absorb spill with dry sand, earth, sawdust, or cloth and place insealed container. For large spill, dike area to prevent spillfrom spreading and then collect it.

Prevention Measures for
Secondary Accidents:

Absorb vapor by misting with water.

:

Wear proper protective equipment to avoid contact with skin or
inhalation of vapor. Fire is strictly prohibited.

7. Handling and storage
Handling
Technical measures

Ventilate well at working places.
Wash hands, a face, and gargle after handling.
Prevent build-up of electrostatic charges （e.g. by grounding）.

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Use explosion-proof electric apparatus.
Precautions for safe handling:

Use with an enclosed system or a local exhaust ventilation.
Do not allow contact with oxidizing substances.

Storage
Storage conditions:

Keep the bottle tightly closed and store in a cool place. Keepaway from fire and heat sources.
Do not store with acid substances.

Material used inpackaging/containers:

Glass, SUS.

8. Exposure controls / Personal protection equipment
Ethanol
ACGIH

TWA -,STEL 1000 ppm

2-Propanol
ACGIH

TWA 200 ppm,STEL 400 ppm

1-Propanol
ACGIH

TWA 100 ppm,STEL -Appropriate engineering
controls
Protective equipment: Install a local ventilation system in case of vapor, fume or mist
condition.

Respiratory protection: Chemical cartridge respirator with an organic vapor cartage orairline respirator

Hand protection: Organic solvents resistant gloves

Eye protection: Safety goggles

Skin and body protection: Protective clothing, protective boots

9. Physical and chemical properties
Physical state: LiquidColor: Colorless.

Odor: AromaticpH: No data available

Melting point: No data available

Freezing point: No data available

Boiling point: No data available

Flash point: 14.1 °C

Auto-ignition temperature: No data available

Decomposition temperature: No data available

Flammability: No data available

Vapor pressure: No data available

Relative density: No data available

Density: 0.79 g/cm³ (20℃)

Relative gas density: No data available

Solubility: Water: Miscible.

Partition coefficient noctanol/water (log Pow)

: No data available

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Explosive limits (vol %): No data available

Viscosity, kinematic:: No data available

Particle characteristics: No data available

10. Stability and reactivity
Reactivity: May react with oxidizing substances.

Chemical stability: Stable under normal conditions.

Possibility of hazardous
reactions: No data available

Conditions to avoid: Light, heat.

Incompatible materials: Oxidizing substances.

Hazardous decomposition
products: Carbon monoxide.

11. Toxicological information
Acute toxicity (oral)
Acute toxicity (dermal)
Acute toxicity (inhalation): No classification: No classification: No classification (gas)Classification not possible (vapor)
Classification not possible (dust, mist)

Skin corrosion/irritation: No classification

Serious eye damage/irritation: Causes serious eye damage

Respiratory sensitization
Skin sensitization
Germ cell mutagenicity
Carcinogenicity

:
:
:
:

Reproductive toxicity: May damage fertility or the unborn child

STOT-single exposure: May cause damage to organs (central nervous system, systemictoxicity)
May cause drowsiness or dizziness
May cause respiratory irritation

STOT-repeated exposure: Causes damage to organs (liver) through prolonged or repeatedexposure
May cause damage to organs (blood, central nervous system)
through prolonged or repeated exposure

Aspiration hazard: Classification not possible

Classification not possible
Classification not possible
Classification not possible
May cause cancer

12. Ecological information
Ecotoxicity
Aquatic acute
Aquatic chronic: No classification: No classification

Persistence and degradability
Persistence and degradability

High biodegradability.

Bioaccumulative potential
Bioaccumulative potential

No data available

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Mobility in soil
Mobility in soil

No data available

Hazardous to the ozone layer
Ozone
Other adverse effects: Classification not possible: No additional information available

13. Disposal considerations
Ecological waste information: Burn in a chemical incinerator equipped with an afterburnerand a scrubber. Or entrust approved waste disposal companies
with the disposal.

Contaminated container andpackaging: In case of disposal of empty bottles, dispose bottles after
removing the content thoroughly.

14. Transport information
International Regulations
Transport by sea(IMDG)
UN-No. (IMDG)
Proper Shipping Name (IMDG)
Packing group (IMDG)
Transport hazard class(es)(IMDG)Air transport(IATA)
UN-No. (IATA)
Proper Shipping Name (IATA)
Packing group (IATA)
Transport hazard class(es)(IATA)

:
:
:
:

1993
FLAMMABLE LIQUID, N.O.S.
II
3:
:
:
:

1993
Flammable liquid, n.o.s.
II3:

Not applicable:

128

Marine pollutant
MFAG-No

15. Regulatory information
Regulatory information with regard to this substance in your country or region should be examined byyour own responsibility.

16. Other information
Data sources: Solvents Handbook, T, Asahara el, Kodansha Scientific Ltd.
（1976）
Dangerous Properties of Industrial Materials,6th ed.
N.I.Sax Van Nostrand Reinhold Company（1984）
Handbook of 17322 Chemical Products, The Chemical Daily Co.
（2022）ICSC Card（2009）
NITE Chemical Risk Information Platform (NITE-CHRIP), National
Institute of Technology and Evaluation

The information contained herein is based on several references and the present state of ourknowledge. However the SDS does not always cover all information about the product, handle theproduct carefully.The information is intended to ordinary usage, in case of particular handlings,
conduct appropriate safety measurements.The information herein is only provision of information, andit does not represent a guarantee the properties of the product.The Safety Data Sheet(SDS) isprepared based on JIS Z7253.