5G-001 FULLONMASK MA-1

Safety Data Sheet(SDS)
Enacted data :Revised date :1. Product and Corporate Information
Reference number：5G-001
Product name
：FULLON MASK MA-1
Company name
：FURUTO INDUSTRIAL CO., LTDAddress：12-1 YOSHIMA INDUSTRIAL PARK, IWAKI City, FUKUSHIMA Prefecture970-1144 JAPAN
Charge section：Sales Planning Department or Sales Department
Telephone number：+81-246-36-4001
FAX number：+81-246-36-7157
Urgent information contact ：Iwaki Yoshima Plant Technology Department
Telephone number：+81-246-36-7154
Expected application andprecautions：Recommended for masking applications
Please refer to 7. HANDLING AND STORAGE and 8. EXPOSURE CONTROLS/PERSONAL PROTECTION.

2. Hazards Identification【GHS classification】
Physical and Chemical Hazards
Explosives
Flammable gases
AerosolOxidizing gases
High pressure gases
Flammable liquids
Flammable solids
Self-reactive chemicals
Spontaneous combustion liquids
Spontaneous combustion solids
Self-heating chemicals
Chemicals which in contact withwater emits flammable gases
Oxidizing liquids
Oxidizing solids
Organic peroxide
Metal corrosive substances
Desensitized explosives：Cannot be classified：Not applicable：Not applicable：Not applicable：Not applicable：Category2：Not applicable：Cannot be classified：Cannot be classified：Not applicable：Cannot be classified：Cannot be classified：Cannot be classified：Not applicable：Cannot be classified：Cannot be classified：Cannot be classifiedHealth Hazards
Acute toxicity (Oral)：Not applicable
Acute toxicity (Skin)：Not applicable
Acute toxicity (Inhalation: Gas)
：Not applicable
Acute toxicity (Inhalation: Vapor)：Category4
Acute toxicity (Inhalation: Dust, mist)：Cannot be classified
Skin corrosive / Irritation：Category2
Serious eyes damage /Eyes irritation：Category2
Respiratory organs sensitization：Cannot be classified
Skin sensitization：Cannot be classified
Germ cell mutagenicity：Cannot be classified
Carcinogenicity：Category1B
Reproduction toxicity：Category1A
Reproduction toxicity/Breastfeeding effect ：Additional category
Specific target organ toxicity-single exposure：Category1(Central nerve system)

Category2(Kidney)
Category3(Respiratory tract irritation, anesthetic action )Specific target organ toxicity-repeated exposure：Category1(Nervous system, kidney)
Aspiration hazard：Cannot be classified

Environmental hazards
Aquatic environmental toxicity-acute：Category2
Aquatic environmental toxicity-chronic ：Category2
Hazardous to the ozone layer：Cannot be classified

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5G-001 FULLONMASK MA-1
【GHS label element】
Pictorial indication:

Signal word
Hazards statement：DANGER：Highly flammable liquids and vapors：Skin irritation：Serious eye irritation：Harmful if inhaled：May cause respiratory irritation：May cause drowsiness or dizziness：Risk of cancer：May cause harm to reproductive or fetus：May cause harm to breast-fed children：Cause damage to central nervous system：May cause damage to the kidneys：Damage to the nervous system and kidneys throughprolonged or repeated exposure：Toxic to aquatic life
：Toxic to aquatic life with long-lasting effects

Cautions
Precautionary statement：Obtain the instruction manual before use：Keep away from heat, hot surfaces, sparks, open flames
and other sources of ignition/No smoking：Keep the container closed well
：Do not breathe dust /fume /gas /mist /vapors /spray：Avoid contact during pregnancy / nursing：Wear protective gloves/ protective clothing/ protective glasses/protective surface.
：If exposed or suspected to be exposed, contact a doctor：If exposed or suspected to be exposed, seek medical attention/treatment.
：If skin irritation occurs, seek medical attention /treatment.
：In case of fire, use dry chemicals, water-soluble liquid foam,carbon dioxide, etc. to extinguish the fire.

First aid measures

Storage
Disposal：Store in a well-ventilated place/Keep in a cool place：The contents/containers must be outsourced to a professional waste
disposal company licensed by the prefectural governor

3. Composition / information on ingredients
Mixture /Substance selection：Mixture

Chemical name /general name (Another name)：None

Ingredient and concentration
Ingredient nameCAS No.

Content(%)

Toluene108-88-3

21-22

Methyl-ethyl-ketone

78-93-3

48-49

Another name: MEK

Methyl isobutyl ketone108-10-1

6.0-7.0

Another name: MIBK

Remarks

Listed only if applicable to the Industrial Safety and Health Act, Chemical Substances Control Law,
(PRTR Act) or the Poisonous and Deleterious Substances Control Act

4. First aid measures
If in eyes
If on skin

If inhaled

If swallowed：Rinse cautiously with water for several minutes.
Remove contact lenses, remove it out if easy. Continue rinsing：If eye irritation persists, get medical advice/attention：If it gets on skin or hair, remove all contaminated clothing immediately
and wash with plenty of running water/shower：If contact skin, wash with plenty of water and soap
：If contact skin and feel unwell, contact a doctor：If skin irritation or rash occurs, seek medical advice and treatment：Remove person to fresh air and keep comfortable for breathing：Call a doctor if inhaled：If feel unwell, contact the doctor and get medical advice/attention：If breathing stops or becomes difficult, loosen clothing, secure airway,
administer artificial respiration, and seek medical attention：Do not force to vomit.
：If feel unwell, contact the doctor：If swallowed, rinse mouth

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5. Fire-fighting measures
Specific hazards：Extremely flammable/Can be easily ignited by heat, sparks or flame：Container may explode if heated：Fire may produce irritating, toxic, or corrosive gases：Highly flammable liquid and vapour
Extinguishing media：Powder, carbon dioxide, dry sand, fire foam
Fire extinguishers should ：Water
not be used
：Do not use water jets to extinguish fires
Specific fire fighting method：When extinguishing a fire, wear appropriate protective equipment andwork from upwind to avoid contact with harmful gases, etc：In the event of a large fire in the vicinity, spray water or foam extinguishing agentsfrom a distance to the surrounding area
：Avoid spraying water in a straight line
Protective equipment：Wear appropriate protective equipment (gloves, glasses, mask, etc.)
for fire fighters

6. Accidental release measures
Personal precautions,protective equipment
and emergency procedures：

Environmental Precautions：
Methods and materials forcontainment and cleaning up：

7. Handling and storage
Handling(Technical measures,
safety precautions,hygiene measures)

If indoors, provide sufficient ventilation until treatment is complete
Prevent non-involved personnel from entering the area around the leakage siteby erecting ropes, etc.
If there is a large amount, evacuate people safely
Work from upwind and evacuate people downwind
When working, wear appropriate protective equipment to avoid getting dropletson skin or inhaling gas
Prepare fire extinguishing equipment in case a fire ignites. Be careful as the spilledarea can be slippery
Be careful not to discharge spilled products into rivers or other bodies of water,
thereby causing an impact on the environment
Do not allow spills to enter rivers or sewer systems directly
When evaporating or dispersing, be careful of fire and ventilation
If the amount is small, absorb it with dry sand, soil, etc. and collect it ina sealable container
If there is a large amount, surround it with embankments to prevent it fromflowing out, guide it to a safe place, and then dispose of it
If the oil spills onto water, use absorbent materials (oil absorption mats, etc.)
to recover the oil：Obtain the instruction manual before use and do not handle until all safety
precautions have been read and understood：Wear appropriate protective equipment (safety glasses, mask, gloves)and handle in a well-ventilated area

：Do not handle the container by tipping it over, dropping it, or subjecting it to impact：Do not eat, drink or smoke when using this product：Wash hands thoroughly after handling：Avoid release to the environment
Storage
Safe condition：Seal the container and store indoors away from direct sunlight and moisture：Store in a cool, well-ventilated place：Make sure there are no leaks in the container and ensure that it does not tip over,fall, or collapse：Store away from oxidizing agents and do not store near open flamesor high heat sources：Lock and keep it safe

8. Exposure control/ personal protection
Control parameters(The data of this product is not set. Component data are shown for reference.)

Ingredient name

Adopted value(ppm)

Toluene20

Methyl-ethyl-ketone

200

Methyl-isobutyl-ketone20

Occupational Exposure Limits(The data of this product is not set. Component data are shown for reference.)

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5G-001 FULLONMASK MA-1
Japanese Society ofOccupational Health

ACGIH

Ingredient

TWA*(ppm)

STEL**(ppm)(ppm)(mg/m3)

Toluene20-50188

Methyl ethyl ketone200

300200590

Methyl isobutyl ketone

207550200*TWA(Time Weighted Average)
Airborne concentrations of chemicals that most workers can be exposed
to repeatedly every day without causing harmful health effects**STEL(Short Term Exposure Limit)
A 15-minute time-weighted average value above which workers
should not be exposed at any given time during their work
even if the TWA is within the acceptable range.
Equipment Measures：No fires：Properly install general ventilation and local exhaust ventilation systems：Install hand washing and eye washing facilities near the handling area
and indicate their locations：Use explosion-proof electrical equipment, ventilation equipment, and lighting equipment：Ground container. Take precautions against static discharge
Protective equipment ：Wear appropriate personal respiratory protection, protective gloves,eye protection and clothing as required(Reference MIBK Protective Equipment)：
Respiratory protective equipment：Consider wearing respiratory protective equipment(gas mask, etc.) if workers are exposed to gas or vapor
When handling high concentrations of chemical substances consider wearing an air-supplied
respirator (JIS T8153). When selecting a gas mask, keep the following points in mind
・Do not use in locations where the oxygen concentration is less than 18%. If the oxygen
concentration is less than 18%, consider wearing an air-supplied mask, air respirator,or oxygen respirator
・When workers use gas masks in environments where they are exposed to dust,
they should use canisters with dust protection

・Gas masks must conform to the Japanese Industrial Standards(JIS T8152) and have performance and structure appropriate for the work
Refer to the data in the instruction manual, etc.
・Because working while wearing a gas mask puts more strain on therespiratory system than usual, those with respiratory diseases should consult a doctor
to see if it is appropriate for them to work while wearing a gas mask
Hand protection：If protective gloves are considered effective,
consider wearing impermeable gloves. When selecting protective gloves,keep the following points in mind
・Refer to the permeation resistance class listed in the instruction manual,
set a sufficient usage time for the work, and use protective gloves within that time
Eye and face protection：Protective glasses (goggles)
Skin and body protection: Protective boots (antistatic, oil-resistant)protective clothing (antistatic), protective apron
9. Physical and chemical properties
Appearance：LiquidColor：RedOｄor：Solvent odor
Melting point/freezing point：No knowledge(Reference value MEK melting point： -86℃)
Boiling point, initial boiling point ：No knowledge(Reference value MEK boiling point： 80℃)
and boiling range
Flammability：No knowledge
Lower and upper explosion limits ：No knowledge(Reference value MEK：1.8～11.5vol％)/flammability limits
Flash point：No knowledge(Reference value MEK：-9℃ closed)
Spontaneous ignition point：No knowledge(Reference value MEK： 505℃)
Decomposition temperature：No knowledge
pH：No knowledge
Dynamic Viscosity：No knowledgeSolubility：Soluble in toluene, ethyl acetate, acetone, etc.
n-Octanol partition coefficient ：No knowledge
Vapor pressure：No knowledge
Density and/or relative density ：No knowledge(Reference value MEK：0.80)
Relative Gas Density：No knowledge
Particle Characteristics：No knowledge

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10. Stability and Reactivity：Stable under normal storage / handling condition
Stability
Possibility of hazardous reactions：May react with strong oxidants, inorganic acids, basic substances,and reducing agents and cause fire
Condition to avoid：Heating and contact with incompatible materials
Hazardous materials：Strong oxidizing agents, strong acids, bases, reducing agents
Hazardous decomposition products：Carbon monoxide, carbon dioxide, etc. are produced by thermal decomposition

11. Toxicological information
Acute toxicity (Oral)
Acute toxicity (Skin)
Acute toxicity (Inhalation: Gas)
Acute toxicity (Inhalation: Vapor)
Acute toxicity (Inhalation: Dust)
Acute toxicity (Inhalation: Mist)
Skin corrosive / Irritation
Serious eyes damage /Eyes irritation：Not applicable：Not applicable：Not applicable：Based on the GHS classification criteria for mixtures,it was classified into Category4：Cannot be classified：Cannot be classified：Based on the GHS classification criteria for mixtures,it was classified into Category2：Based on the GHS classification criteria for mixtures,it was classified into Category2：Cannot be classified：Cannot be classified：Cannot be classified：Based on the GHS classification criteria for mixtures,it was classified into Category1B
Reproduction toxicity：Based on the GHS classification criteria for mixtures,it was classified into Category1A
Reproduction toxicity/Breastfeeding effect ：Based on the GHS classification criteria for mixtures,it was classified into additional category
Specific target organ toxicity-single exposure：Based on the GHS classification criteria for mixtures,it was classified into Category1(Central nerve system)：Based on the GHS classification criteria for mixtures,it was classified into Category2(Kidney)：Based on the GHS classification criteria for mixtures,it was classified into Category3(Respiratory tract irritation,anesthetic action)
Specific target organ toxicity-repeated exposure：Based on the GHS classification criteria for mixtures,it was classified into Category1(Nervous system, kidney)
Aspiration hazard：Cannot be classified
Respiratory organs sensitization
Skin sensitization
Germ cell mutagenicity
Carcinogenicity

12. Environmental impact information
Aquatic environmental hazards (acute)
Aquatic environmental hazards (chronic)
Persistence and degradability
Bioaccumulation
Mobility in soil
Harm to the ozone layer：Based on the GHS classification criteria for mixtures,it was classified into Category2：Based on the GHS classification criteria for mixtures,it was classified into Category2：No data：No data：No data：No data

13. Disposal considerations：When disposing of this product, follow the relevant laws and regulations as well as
local government standards：The contents and containers will be outsourced to specialized waste disposal
companies authorized by the prefectural governor：When burned, harmful gases such as Carbon monoxide, carbon dioxide
are generated, so incinerate with an incinerator equipped with an exhaust gas
treatment device.
：When treating wastewater containing this product, perform a toxicity test on
activated sludge before treating the wastewater.
：In addition to the precautions described in section, observe the generalprecautions for highly flammable hazardous liquid.
14 Transport information
International Regulations
UN classUN No.
Product name：Class 3(flammable liquid), Container group II：1993 (Medium flash point flammable liquid with no other hazards)：Not applicable

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Special safety measures

15 Regulatory information
Fire Service Act
Industrial Safety
and Health Act：Make sure that the container is free of leaks during transport, and load it up sothat it does not fall or damage, and ensure prevention of load collapse：In addition to the precautions described in section, observe the generalprecautions for highly flammable hazardous liquid.
：Avoid to carry with peroxides and oxidants.

：Class 4, 1st petroleum (water-insoluble liquid)

Toluen, MEK, MIBK

：Dangerous Substance (Flammable)

Toluen, MEK, MIBK

：Organic Solvent Poisoning Prevention Regulations (Organic Solvent Regulations)
Second class organic solvent
Toluen, MEK：Specific Chemical Substances Hazard Prevention Regulations(Specific Chemical Substances Regulations)
Specified chemical substances Class 2, special organic solvents, etc.
MIBK：Article 57-2: Substances subject to the obligation to label and notify
Substances subject to notification
Toluen, MEK, MIBK
Substances subject to display
Toluen, MEK, MIBK：Article 594-2 Chemical substances that cause skin irritation Toluen, MEK
Chemical Substances
Control Law*
(PRTR Law)

：Class 1 designated chemical substances

Toluen, MIBK

Poisonous and Deleterious ：Not applicable
Substances Control Act
Ship Safety Act：Medium flash point flammable liquidToluen, MEK, MIBK

*Law concerning the identification of emissions of specific chemical substances into the environment
and the promotion of improvements in their management
16. Other information
References
・Raw material SDS
・GHS Classification Results Database by National Institute of Technology and Evaluation
i The "Safety Data Sheet" is a brief summary of the precautions for safe use of our products, andassumes normal handling.
ii The "safety data sheet" is based on the findings up to the present and does not guarantee thecompleteness of the information, and may be revised as needed. Please be aware in advance.
iii The information contained in the "Safety Data Sheet" does not guarantee the product specificationor quality.
Please refer to the "Safety Data Sheet" etc. for the conditions under which this product is used andconsider at the user's responsibility.

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