Symposium on Creation of Functional Materials
2009

Program & Abstracts

Strategic Initiative A for Interdisciplinary Materials Science andpre-Strategic Initiative for Creation of Functional Molecules,
University of Tsukuba

2009/12/3-4
Tsukuba International Congress CenterProgram
December 3 (Thu)
9:10-9:15

Opening Remarks: Youiti Ootuka and Hideo Kigoshi
Chair; Tatsuya Nabeshima

9:15-10:00

L-01 Takeshi Akasaka (University of Tsukuba)
In-depth Understanding of pi-Electron Systems: New Vistas in Fullerene
Endohedrals

10:00-10:45

L-02 Teruo Shinmyozu (Kyushu University)
A Study on Charge Transfer Interaction Using Cyclophanes as Model
Compounds

10:45-10:55

BreakChair; Hiroki Oshio

10:55-11:15

L-03 Vladimir Lee (University of Tsukuba)
Cyclopentadienyl Anions of the Heavy Group 14 Elements: New Generation
Ligands for Coordination Chemistry

11:15-12:15

L-04 Xiao-Ming Chen (Sun Yat-Sen University, China)
Porous Coordination Polymers: Flexibility and Sorption

12:15-13:15

Lunch
Chair; Takahiko Kojima

13:15-14:15

L-05 James M. Mayer (University of Washington, USA)
Moving Protons and Electrons Together: From Organic Hydrogen Atom
Transfer Reactions to Marcus Theory of Proton-Coupled Electron Transfer

14:15-15:00L-06 Takayuki Kawashima (University of Tokyo)
Creation of Functional Molecules Utilizing Characteristics of Boron

15:00-15:10

BreakChair; Takeshi Akasaka

15:10-15:55

L-07 Atsuhiro Osuka (Kyoto University)
Möbius Aromatic Expanded Porphyrins

15:55-16:40

L-08 Yousuke Yamamoto (Hiroshima University)
Synthesis and Structure of Hypervalent Carbon and Boron Compounds

16:50-18:20

Poster Session

18:30-

Reception at “Espoir,” Epochal

December 4 (Fri)
Chair; Akira Sekiguchi
9:00-9:45

L-09 Norio Teramae (Tohoku University)
Molecule Recognition by Fluorophores in Combination with Abasic
Site-containing Oligonucleotides

9:45-10:30

L-10 Hideo Nagashima (Kyushu University)
Living Polymerization by Reusable Iron-amine Catalysts: From Fundamental
Chemistry to Industrial Potentials

10:30-10:40

BreakChair; Takaki Kanbara

10:40-11:00

L-11 Tsuyoshi Michinobu (Tokyo Institute of Technology)
Click Synthesis of Donor-Acceptor Type Conjugated Polymers

11:00-12:00

L-12 Yong-Joo Kim (Kangnung-Wonju National University, Korea)
Chemistry of Group 10 Metal Azides: Reactivity toward Organic Unsaturated
Compounds

12:00-13:00

Lunch
Chair; Toshiharu Teranishi

13:00-13:45

L-13 Kazuo Takimiya (Hiroshima University)
Design and Synthesis of New Heteroarene-Based Organic Semiconductors
for Thin-Film Transistors

13:45-14:30

L-14 Hiroshi Nishihara (University of Tokyo)
Coordination Programming of Electron-Conducting Molecular Wires on theSurface

14:30-15:15

L-15 Koji Kimoto (National Institute for Materials Science)
Material Characterization with High Spatial Resolution Using Transmission
Electron Microscopy and Electron Energy-loss Spectroscopy

15:15-15:25

BreakChair; Junji Ichikawa

15:25-15:45

L-16 Junpei Kuwabara (University of Tsukuba)
Synthesis of Functional Polymer by Pd-Catalyzed C-N Coupling Reaction15:45-16:45

L-17 Zhenfeng Xi (Peking University, China)
Synthesis of Pyridines, Pyrroles, and 5-Azaindoles

16:45-16:50

Closing Remarks: Hideo Kigoshi

Poster Program
P-01

Synthesis and Cation Recognition of Macrocyclic Salen-type Complex
Shunjin Piao, Fumihiko Utsuno, Shigehisa Akine, and Tatsuya Nabeshima
Univ. of Tsukuba

P-02

Functions of Molecular Clefts Bearing Inert Terpyridine Platinum Complexes
Yuki Hasegawa, Masaki Yamamura, Robert Trokowski, and Tatsuya Nabeshima
Univ. of Tsukuba

P-03

Synthesis and Cation Recognition of Chiral Pseudomacrocyclic Terpyridine
Metallohost
Futoshi Sato, Masaki Yamamura, and Tatsuya Nabeshima
Univ. of Tsukuba

P-04

Synthesis and Cation Recognition Ability of Oligodipyrrin BF2 Complexes by theB–F•••Cation Interaction
Naoya Sakamoto, Chusaku Ikeda, and Tatsuya Nabeshima
Univ. of Tsukuba

P-05

Spontaneous Enrichment of One-handed Helix by Dissolution of Pseudoracemic
Crystal of a Helical Metal Complex
Sayaka Hotate, Shigehisa Akine, and Tatsuya Nabeshima
Univ. of Tsukuba

P-06

Synthesis and Properties of Heteronuclear Trisaloph Complexes
Masao Sasaki, Masaki Yamamura, and Tatsuya Nabeshima
Univ. of Tsukuba

P-07

Synthesis of Helical Metal Complex Using Oligo(bipyridine-phenol) Ligands
Hiroki Nagumo, Shigehisa Akine, and Tatsuya Nabeshima
Univ. of Tsukuba

P-08

Synthesis and Cation Recogniton of Aluminum Complex of N2O4-type Dipyrrin
Manami Daicho, Naoya Sakamoto, Chusaku Ikeda, and Tatsuya Nabeshima
Univ. of Tsukuba

P-09

Synthesis and Ion Recognition of Dipyridylbipyrimidine Ligand Bearing Anion
Recognition Moieties
Yui Togawa, Masaki Yamamura, and Tatsuya Nabeshima
Univ. of Tsukuba

P-10Structure–Activity Relationships of Glaziovianin A
Akiyuki Ikedo, Ichiro Hayakawa, Sayaka Kazami, Takeo Usui, and Hideo Kigoshi
Univ. of Tsukuba, RIKEN Advanced Science Institute, Saitama Univ.

P-11

Study on the Target Proteins of an Antitumor Macrolide Aplyronine A
Yuichiro Hirayama, Miyuki Sugiyama, Yuki Saito, Masaki Kita, and Hideo Kigoshi
Univ. of Tsukuba

P-12

Total Synthesis of Auripyrones A and B by Using a Novel Diastereoselective
Aldol-type Reaction of a γ-Pyrone
Takuma Takemura, Emi Fukasawa, Yuta Ebihara, Natsuki Sato, Takayasu Nakamura,
Tetsuya Sengoku, Kiyotake Suenaga, Ichiro Hayakawa, and Hideo Kigoshi
Univ. of Tsukuba

P-13

Synthetic Studies on Mycalolide B, an Actin-depolymerizing Marine Macrolide
Tomoya Ishitsuka, Yuzo Mogi, Hidekazu Watanabe, Masaki Kita, and Hideo Kigoshi
Univ. of Tsukuba

P-14

Synthetic Studies on a Hybrid Compound of Aplyronine A and Mycalolide B
Kenichi Kobayashi, Yusuke Fujii, Shinichi Kobayashi, Ichiro Hayakawa, and Hideo
Kigoshi
Univ. of Tsukuba

P-15

Reactivity of Disilyne toward Hydroborane: Synthesis, Structure, and Properties
of Boryl-substituted Disilene
Katsuhiko Takeuchi, Masaaki Ichinohe, and Akira Sekiguchi
Univ. of Tsukuba

P-16

A Novel Digermene, R2Ge=GeR2 (R=SiMetBu2): Synthesis, Structure and Unusual
Reactivity
Kiera McNeice, Vladimir Ya. Lee, and Akira Sekiguchi
Univ. of Tsukuba

P-17

Disilaallyllithium: Interconversion of η 3-Allyllithium and η 1-Coordination to a
Silyllithium Fragment
Hiroaki Tanaka, Shigeyoshi Inoue, Masaaki Ichinohe, and Akira Sekiguchi
Univ. of Tsukuba

P-18

Tetrahedrane and Cyclobutadiene: Valence Bond Isomerization of Tetrahedranewith σ-π Conjugation
Yusuke Inagaki, Masaaki Nakamoto, and Akira Sekiguchi
Univ. of Tsukuba

P-19

Influence of Structural Change around the Heme Active Site of Hydrogenobacter
thermophilus Cytochrome c552 on Its Thermostability and Redox Potential
Kiyofumi Irie, Shin-ichi Mikami, Naoki Watanabe, Naoya Shinohara, Akihiro
Sugimoto, Hulin Tai, Shigenori Nagatomo, and Yasuhiko Yamamoto
Univ. of Tsukuba

P-20

Heme Fe3+–N-terminal Amino Group Coordination Bond in Denatured
Cytochrome c that Strongly Affect the Overall Protein Stability
Hulin Tai, Naoki Watanabe, Akihiro Sugimoto, Shin-ichi Mikami, Kiyofumi Irie,
Naoya Shinohara, Shigenori Nagatomo,, Toratane Munegumi, and Yasuhiko
Yamamoto
Univ. of Tsukuba, Oyama Natl. Coll. of Tech.

P-21

Relationship between Oxygen Affinity of Myoglobin and the Electron Density ofHeme Fe Atom in the Protein
Tomokazu Shibata, Hulin Tai; Shigenori Nagatomo, Kenji Morihashi, Akihiro Suzuki,

and Yasuhiko Yamamoto
Univ. of Tsukuba, Nagaoka Natl. Coll. of Technology
P-22

Control of Redox Potential of Pseudomonas aeruginosa Cytochrome c551 throughAltering pKa of Heme 17-Propionic Acid Side Chain
Shin-ichi Mikami, Hulin Tai, Kiyofumi Irie, Shigenori Nagatomo, and YasuhikoYamamoto
Univ. of Tsukuba

P-23

Application of Transition Metal Complexes to Cathode Active Materials ofRechargeable Lithium ion Batteries
Yuko Iida, Masayuki Nihei, Masaharu Satoh, Jun Wada, and Hiroki Oshio
Univ. of Tsukuba, Murata Manufacturing Co., Nippon Kasei Chemical Co.

P-24

Structures and Physical Properties of Fe(II) Complexes Coordinated by Pyridine
Ligands with a Triphenylamine MoietyEmiko Oshiro, Kiyotaka Mitsumoto, Hiroyuki Nishikawa, and Hiroki Oshio
Univ. of Tsukuba, Univ. of Ibaraki

P-25

Multiple Bistability in a Multi-component Material of[Fe(dpp)2][Ni(mnt)2]2·MeNO2
Hirotaka Tahira, Masayuki Nihei, and Hiroki Oshio,
Univ. of Tsukuba

P-26

Thermal Charge-transfer-induced Spin Transition in Cyanide-bridged Molecular
Squares in Solution
Kento Nakazawa, Nihei Masayuki, Sekine Yoshihiro, and Oshio Hiroki
Univ. of Tsukuba

P-27

Construction of Conglomerates Composed of a Saddle-Distorted
Metalloporphyrin and Heteropolyoxometarates
Atsutoshi Yokoyama, Kei Ohkubo, Takahiko Kojima, and Shunichi Fukuzumi
Osaka Univ., SORST(JST), Univ. of Tsukuba

P-28

Structure and Reactivity of Mononuclear Side-on Copper(II)-superoxo Complex
with a Bulky Hydrotris(pyrazolyl)borate Ligand
Itaru Samusawa, Kiyoshi Fujisawa, and Takahiko Kojima
Univ. of Tsukuba

P-29

Differential Reactivity of Copper(II) Complexes with 1,2-Diphenylhydrazine:
Formation Diazene Complex or Tetrazene Compound
Masaki Sugiyama, Kiyoshi Fujisawa, Tomoya Ishizuka, and Takahiko Kojima
Univ. of Tsukuba

P-30

Influence of Intramolecular Hydrogen Bond on Redox Behavior andSolvato-thermochromism of Ni(II) and Co(II) Thiolato Complexes
Tetsuya Mitsui, Kiyoshi Fujisawa, Taka-aki Okamura, Tomoya Ishizuka, and TakahikoKojimaUniv. of Tsukuba, Osaka Univ.

P-31

Synthesis of Tetranuclear Iridium(III) Complexes with a Flavin Analogue asBridging Ligands Showing Unique Structures and Properties
Yuji Inui, Soushi Miyazaki, Motoo Shiro, Takahiko Kojima, and Shunichi Fukuzumi
Univ. of Tsukuba, Osaka Univ., SORST(JST), Rigaku Corp.
P-32

Transfer Hydrogenation of Ketones by a Trinuclear Ruthenium(II) Complex
Involving Two Converged Reactive Sites
Yuichi Yano, Tomoya Ishizuka, Takahiko Kojima, and Shunichi Fukuzumi
Univ. of Tsukuba, Osaka Univ.

P-33

Synthesis and Properties of Paramagnetic Metallofullerene/Electron Donor Dyad
Tatsuya Tanaka, Takahiro Tsuchiya, Takeshi Akasaka, Naomi Mizorogi, and Shigeru
NagaseTARA Center, Univ. of Tsukuba; Institute of Molecular Science

P-34

Anisotropic Magnetic Behavior of Anionic Ce@C82 Carbene Adducts
Yuta Takano, Michio Yamada, Zdenek Slanina, Naomi Mizorogi, Midori O. Ishitsuka,
Takeshi Akasaka, and Shigeru Nagase
TARA Center, Univ. of Tsukuba; Institute of Molecular Science

P-35

Two Step Regioselective Exohedral Functionalization of Endohedral
Metallofullerene La@C82
Satoru Sato, Yutaka Maeda, Koji Inada, Hidefumi Nikawa, Michio Yamada, Naomi
Mizorogi, Tadashi Hasegawa, Takahiro Tsuchiya, Takeshi Akasaka, Tatsuhisa Kato,
Zdenek Slanina, and Shigeru Nagase
TARA Center, Univ. of Tsukuba; Tokyo Gakugei Univ.; Josai Univ.; Institute ofMolecular Science

P-36

Synthesis and Characterization of Stable [4+2] Derivatives of La@C82
Yuki Nagashima, Yuta Takano, Satoru Sato, Naomi Mizorogi, Zdenek Slanina, Takeshi
Akasaka, Shigeru Nagase, and Nazario Martin
TARA Center, Univ. of Tsukuba; Institute of Molecular Science; Complutense Univ. ofMadrid

P-37

Chemical Modification of La2@C80 with Silacyclopropane
Mari Minowa; Michio Yamada, Takahiro Tsuchiya, Naomi Mizorogi, Zdenek Slanina,
Takeshi Akasaka, Masahiro Kako, and Shigeru Nagase
TARA center, Univ. of Tsukuba; Univ. of Electro-Communications; Institute ofMolecular Science

P-38

Structure of Y@C82 and Anisotropic Reactivity of Cage Carbons Dictated by theInternal Yttrium Atom
Xing Lu, Hidefumi Nikawa, Takahiro Tsuchiya, Takeshi Akasaka, Zdenek Slanina, andShigeru Nagase,
TARA Centre, Univ. of Tsukuba; Institute of Molecular Science

P-39

Structural Determination of Scandium-Carbide Endofullerene Sc2 C2@C80
Hiroki Kurihara, Yuko Yamazaki, Hidefumi Nikawa, Naomi Mizorogi, TakahiroTsuchiya, Shigeru Nagase; and Takeshi Akasaka
TARA Centre, Univ. of Tsukuba; Institute of Molecular Science

P-40

Synthesis and Characterization of Novel Electron Donor-acceptor ConjugatedMolecules Based on C60 and exTTF
Azusa Iwano, Lai Feng, Yuta Takano, Takeshi Akasaka, and Nazario Martin
TARA center, Univ. of Tsukuba; Univ. Complutense of Madrid
P-41

Chemical Modification of Missing Endohedral Metallofullerene
Tsuyoshi Ito, Hidefumi Nikawa, Hidenori Kuga, Tsukasa Takahashi, Takeshi Akasaka,
Takahiro Tsuchiya, Zdenek Slanina, Naomi Mizorogi, and Shigeru Nagase
TARA Centre, Univ. of Tsukuba; Institute of Molecular Science

P-42

Synthesis and Properties of An Endohedral Metallofullerene Ligand
Ryo Aoyama, Takahiro Tsuchiya, and Takeshi Akasaka
TARA Centre, Univ. of Tsukuba

P-43

Synthesis of New Pincer Iridium Complexes having Benzothiazole Group
Tomomi Namekawa, Junpei Kuwabara, and Takaki Kanbara,
Tsukuba Research Center for Interdisciplinary Materials Science (TIMS), Univ. ofTsukuba

P-44

Aerobic Oxidation of 2-Substituted Imidazolines Promoted by Cyclometalated
Ruthenium Catalyst
Ayako Taketoshi, Akitsu Tsujimoto, Shusaku Maeda, Take-aki Koizumi, and TakakiKanbara
Tsukuba Research Center for Interdisciplinary Materials Science (TIMS), Univ. ofTsukuba: Tokyo Institute of Technology

P-45

Synthesis and Electrochemical Properties of Pt Complexes with a Benzenediamide
LigandTake-aki Koizumi and Kazunori Fukuju
Tokyo Institute of Technology

P-46

Dimensional Crossover and Anisotropic Josephson-vortex Dynamics in a Layered
Organic Superconductor
Hiroaki Koga, Syuma Yasuzuka, Yasuhisa Yamamura, Kazuya Saito, Shinya Uji,
Hidetaka Satsukawa, Motoi Kimata, Taichi Terashima, Hiroki Akutsu, and Jun-ichi
YamadaUniv. of Tsukuba, NIMS, Univ. of Hyogo

P-47

Backflow-induced Asymmetric Annihilation of a Disclination Pair in a Nematic
Liquid Crystal under Electric Field
Takuya Yanagimachi, Syuma Yasuzuka, Yasuhisa Yamamura, and Kazuya Saito
Univ. of Tsukuba

P-48

Synthesis and Characterization of Phthalocyanine-protected Au Nanoparticles
Hikaru Sekine, Masayuki Kanehara, and Toshiharu Teranishi
Univ. of Tsukuba

P-49

Enhancement of Photocatalytic Activity of (Ga1-xZnx)(N1-xOx) by Loading
Manganese Oxide Nanoparticle as a Cocatalyst
Taizo Yoshinaga, Takahiro Ikeda, Anke Xion, Masayuki Kanehara, Kazuhiko Maeda,
Kazunari Domen, and Toshiharu Teranishi
Univ. of Tsukuba, Univ. of Tokyo

P-50

Designed Synthesis of Monodisperse Pd/Pt Core/Shell Nanoparticles
Ryota Sato, Satoshi Nagao, Toshihiro Ikai, Masayuki Kanehara, and Toshiharu
Teranishi
Univ. of Tsukuba, Toyota Motor Co.

P-51

Direct Observation of Plasmon Hybridization Modes in Individual Gold
Nanoparticle Dimers
Hiromu Kobori, Miharu Eguchi, Masayuki Kanehara, Shanjr Gwo, and Toshiharu
Teranishi
Univ. of Tsukuba, National Tsing-Hua. Univ.

P-52

Size Tuning of PVP-protected Rh Nanoparticles by Polyol Synthesis
Takahiro Ikeda, Taizo Yoshinaga, Masayuki Kanehara, and Toshiharu Teranishi
Univ. of Tsukuba

P-53

Synthesis and Characterization of ZnS/Au Heterostructured Nanoparticles
Naoko Onigata, Masayuki Kanehara, and Toshiharu Teranishi
Univ. of Tsukuba

P-54

Synthesis of Small Gold Nanoparticles Protected by Thiolated Porphyrins
Daisuke Tanaka, Masayuki Kanehara, and Toshiharu Teranishi
Univ. of Tsukuba

P-55

Development of micro-SQUID Magnetometer for Investigation of Single-Molecule
Magnets
Masamichi Saitoh, Hiroshi Ebina, Hiroki Oshio, and Youiti Ootuka
Univ. of Tsukuba

P-56

Nucleophilic 5-endo-trig Cyclizations of Fluoro Alkenes via Metalloenamides
Masahiro Hattori, Masahiro Ikeda, and Junji Ichikawa
Univ. of Tsukuba

P-57

Fluorophenanthrene Synthesis via Palladium (II)-Catalyzed Electrophilic
Cyclization of 1,1-Difluoro-1-alkenes
Toshiyuki Morikawa, Hiroyuki Tanabe, Kohei Fuchibe, and Junji Ichikawa
Univ. of Tsukuba

P-58

Synthesis of 1,1-Difluoro-1-alkenes via Three-Component Coupling Reaction of1,1-Difluoroallenes
Mikiko Ueda, Ken Oh, Kohei Fuchibe, and Junji Ichikawa,
Univ. of Tsukuba

P-59

Transition Metal-Catalyzed Fluoroindole Synthesis via Electrophilic Activation of1,1-Difluoro-1-alkenes
Shigeyuki Yamashita, Hiroyuki Tanabe, and Junji Ichikawa,
Univ. of Tsukuba

P-60

Selective Hydrogenation of Aryl Nitro Compounds by Platinum-Silica as a
Catalyst
Yasumasa Takenaka, Takahiro Kiyosu, Jun-Chul Choi, Toshiyasu Sakakura, andHiroyuki Yasuda
National Institute of Advanced Industrial Science and Technology (AIST)P-61

DFT Study on Enzymatic Activity in HIV-1 Reverse Transcriptase
Kazuhiro Kuranoo and Kenji Morihashi,
Univ. of Tsukuba

P-62

Constrained Density Functional Study on Intramolecular Electron Transfer
Tomofumi Ogawa, Yasuyo Shimodo, and Kenji Morihashi,
Univ. of Tsukuba

P-63

Photoinduced Electron Transfer Reaction of Anthracene–Guanine Compounds inthe Excited State
Koki Shimamura, Yoshinobu Nishimura, and Tatsuo Arai
Univ. of Tsukuba

P-64

Photochemical Properties of Olefinic Compounds with a Pyrrole and a
Quinoxaline Ring
Kentaro Kudo and Tatsuo Arai
Univ. of Tsukuba

P-65

Photochemical and Photophysical Properties of Diphenylbutadiene Dendrimers
Yousuke Miura and Tatsuo Arai
Univ. of Tsukuba

P-66

Synthesis and Photochemistry of Ionic Liquid Derivatives Capable ofPhotoisomerization
Hiroyasu Tamura, Yoshihiro Shinohara, and Tatsuo Arai
Univ. of Tsukuba

P-67

A Novel Fluorescent Dye That Emits Green-yellow Fluorescence Useful for
Live-cell Imaging
Naoko Senda, Yoshihiro Miwa, Junko Tanaka, Atsuya Momotake, and Tatsuo Arai
Univ. of Tsukuba

P-68

Macroscopic Mechanical Control of Molecular Function
Soichiro Ogi, Kazunori Sugiyasu, and Masayuki Takeuchi
Univ. of Tsukuba, NIMS

P-69

Metal-Ion Assembly in Novel Organic Modules with a Cyclic or Cage Structure
Ryo Shomura and Masayoshi Higuchi
Univ. of Tsukuba, NIMS

P-70

Photo- and Electro-chromic properties of Organic-Metallic Hybrid Polymers withAzo Groups
Toshihiro Hayashi and Masayoshi Higuchi
Univ. of Tsukuba, NIMS

P-71

Conjugation of Organic-Metallic Hybrid Polymers and DNA for application toDDS
Jinghua Li and Masayoshi Higuchi

Univ. of Tsukuba, NIMS