ISSN

Faculty of Engineering are compiled herein. Abstracts of paper presented elsewhere
during the current year are also compiled in the latter part of the volume.
All communications with respect to Memoirs should be addressed to:
Dean of the Graduate School of Engineering
Osaka City University
3-3-138, Sugimoto, Sumiyoshi-ku
Osaka 558-8585, Japan
Editors

MEMOIRS OF THE FACULTY OF ENGINEERING OSAKA CITY UNIVERSITYThis Memoirs is annually issued. Selected original works of the members of the0078－6659

MEMOIRSOF THEFACULTY OF ENGINEERINGOSAKA CITY UNIVERSITY

VOL. 58
DECEMBER 2017

Yoshinori KANJO
Makoto UCHIDA
Masafumi MURAJI
Hisayoshi SUGIYAMA
Takeshi NAKANISHIEri GAVANSKI

VOL. 58.
2017

1711-0100 大阪市立大学 工学部
1-4
工学部英文紀要VOL.57（2016）

PUBLISHED BY THE
GRADUATE SCHOOL OF ENGINEERINGOSAKA CITY UNIVERSITY

見本

スミ

This Memoirs is annually issued. Selected original works of the members of theFaculty of Engineering are compiled herein. Abstracts of paper presented elsewhere
during the current year are also compiled in the latter part of the volume.
All communications with respect to Memoirs should be addressed to:
Dean of the Graduate School of Engineering
Osaka City University
3-3-138, Sugimoto, Sumiyoshi-ku
Osaka 558-8585, Japan
Editors
Yoshinori KANJO
Makoto UCHIDA
Masafumi MURAJI
Hisayoshi SUGIYAMA
Takeshi NAKANISHIEri GAVANSKI

1711-0100 大阪市立大学 工学部2-3
工学部英文紀要VOL.57（2016）

スミMEMOIRS OF THE FACULTY OF ENGINEERINGOSAKA CITY UNIVERSITY
VOL. 58

DECEMBER 2017

CONTENTS
Regular Articles ·························································································· 1
Electronics and Informatics
Electric and Information Engineering
Power Distribution Protocol Among Power Plants and Consumers in Energy Packet Networks
Hisayoshi SUGIYAMA···········································································

1

Urban Engineering
Urban Design and Engineering
Method of Evaluating Dialogue Robots for Visually Impaired and Elderly People
Hiroko MATSUMOTO, Takashi UCHIDA and Kanami BESSYO ························

13

Understanding the Nature of Walking and Cycling for Transport in Japan
Pola BERENT and Nagahiro YOSHIDA ·····················································

25

Abstracts of Papers Published in Other Journals ···········································

45

Mechanical and Physical Engineering
Mechanical Engineering ······································································

47

Electronics and Informatics
Applied Physics and Electronics ······························································ 62
Electric and Information Engineering ······················································· 69
Applied Chemistry and Bioengineering
Applied Chemistry and Bioengineering······················································ 73

Urban Engineering
Architecture and Building Engineering ······················································ 90
Urban Design and Engineering ·································································· 93

ISSN

MEMOIRSOF THEFACULTY OF ENGINEERINGOSAKA CITY UNIVERSITY――――――――
VOL. 58――――――――DECEMBER 2017

PUBLISHED BY THE
GRADUATE SCHOOL OF ENGINEERINGOSAKA CITY UNIVERSITY

0078－6659

Power Distribution Protocol Among Power Plants and Consumers
in Energy Packet Networks
Hisayoshi SUGIYAMA*(Received September 30, 2017)
Synopsis
Power distribution protocol among power plants and consumers in electric energy packet networks is
proposed. Energy packet networks have advantages of affinity with decentralized power plants such like aphotovoltaic power generation and of manageability of energy coloring in the process of power distribution.
Differing from conventional data packet networks, this protocol provides the energy packet networks withsimultaneous multipoint-to-multipoint power transmissions among power plants and consumers and with thepower transmission procedure triggered by an occurring of a consumer demand. The aspect of dece ntralized
control of data packet networks is succeeded for reliability of power distribution against partial failure of the
network. The operations of the energy packet network based on the proposed protocol are confirmed bycomputer simulations.
KEYWORDS: smart grid, power packet, energy packet, power packet, energy packet, Transmission protocol.
1. Introduction
Smart grid technologies have been investigated for the purpose to enhance efficiency and reliability ofcurrent power systems with smooth integration of renewable and alternative energy sources[1]. As one of thebasics of this upcoming power grid, electric energy packet transmission is proposed to distribute electric powerover the network[2,3,4].
The power networking with electric energy packets has advantages as follows:First, it has affinity with decentralized generating plants such like a photovoltaic power generator or windturbine generator. In current power systems, where power lines are always filled with electric signal of
specified voltage, reverse power flow from decentralized plants causes voltage fluctuations that degrade powersource quality to neighboring customers[5]. On the other hand, reverse power flow with electric energy packets
never cause such voltage fluctuations because of their independency of other energy packets.
Second, it has manageability of energy coloring in the process of power distribution. For consumers, energy
coloring is necessary to identify which power source the incoming energy is generated by and how far thesource is located[6,7]. This information assists the consumers to select the power source or electric power itselfof the lowest environmental load concerning greenhouse gas emissions or such global scale problems.
However, in energy packet networks, differences from data packet networks cause subjects to be solved. In
my previous work[8,12], a scheme for power networking with electric energy packets is proposed to solve theproblem of packet discarding caused by packet collisions or routing buffer overflow. In addition, the scheme
eliminates the power loss accumulation caused by store and forward of energy packets at successive routers.
In this paper, as one of the residual subjects of energy packet networking, a protocol is proposed forreasonable process of power distribution among power plants and consumers. This protocol must be
investigated because of the differences from that for the conventional data packet transmission as follows:First, in contrast to the data packet transmission that is basically point-to-point, the power transmission
possibly be multipoint-to-multipoint. This difference is caused by the aspects of the packet payloads in bothcases. The payload of a data packet is a message distinctive for individual recipient. Whereas, that of a n energy
packet is only an electrical power that cannot be distinguished from other ones. Therefore, in energy packet
networks, every consumer is possible to satisfy its power demand with energy packets transmitted from various
power plants simultaneously, or equivalently, every power plant may transmit its surplus power by series ofenergy packets addressed to various consumers that express power demand coincidentally.
Second, though the procedure of data packet transmission always begin with a call of a t ransmitter, that ofenergy packet transmission must be triggered by a consumer demand. This means that there must be somepreceding process before the transmission of each energy packet with a specified destination as its packet*

Associate Professor, Department of Physical Electronics and Informatics－1－

header. This preceding process must begin with an expression of a power demand by a consumer and thedetermination of power plants follows. This determination specifies the destination of energy packets
transmission and payload volume of the electric power. If various demands are expressed by different
consumers coincidentally, the determination of each power plant for these consumers may depend on theirlocation, each demand volume, power transmission path congestion, or so.
To realize theses aspects of the power transmission protocol, the proposed protocol specifies two kinds ofprocess of power network operation: First, the process of information accumulation of all the nodes to eachpower plant. Second, the process of energy packet transmission among power plants and consumers. Ba sed on
the first process, every node constructs and updates its own extended forwarding table (or EFT). This tablebasically indicate routing information for energy packet transmissions in the network. In addition, the tableindicates the current power demand and distance of every consumer. Based on this EFT, in the second process,each power plant determines the target consumers and performs multipoint-to-multipoint transmissions ofenergy packets to the consumers. This second process is triggered by a consumer demand appears at the EFT.
Because these processes are executed individually by each node in the network, the aspect of decentralized
control of conventional data packet network is succeeded for reliable power distribution against partial failureof the network.
In section 2, the first process of the proposed protocol: EFT operation is explained. In section 3, the second
process: energy packet transmission is explained. In section 4, simulation results are described that confirm theenergy packet network operation with the proposed power distribution protocol.
2. POWER DISTRIBUTION PROTOCOL: EFT OPERATIONAs described in the previous section, the proposed power distribution protocol consists of following two
processes:
1. The process of information accumulation and EFT construction and update at each node.
2. The process of energy packet transmissions among power plants and consumers.
In this section, the former process of the power distribution protocol is explained. First, an example ofpower network configuration is indicated with overview of energy packet transmissions and informationexchanges among the nodes. Second, based on this example of power network, details of EFT operation is
explained including the configuration of the table and its construction and update.
2.1 Power network configuration
An example of the configuration of the energy packet network is shown in Fig. 1. This network consists ofend users, power routers, and a power gateway. These nodes are connected by power communication links. In
this figure, five end users A E are indicated. They usually consume power, or some of them possibly be
decentralized power plants provided they have surplus power over their own consumption. The figure denotes
the consumers (B, C, and E) and power plants (A and D) by white and gray circles, respectively. On the other
hand, four power routers F, H, I, and J are indicated. Each of them receives an energy packet and forward it toan adjacent node connected with the router directly (this adjacent node is called next hop). The next hop
possibly be another power router or a consumer as the energy packet destination. The double circle in the figure
denotes the power gateway G. In this example of the power network, the power gateway is assumed to execute
following operations:Fig. 1.

An example of power packet network.

1. To connect this power network with an adjacent outer network. If the outer network is conventional one
with continuous power signal, the gateway decomposes the continuous signal into energy packets withspecified configuration of the inner network.

－2－2. To stock its own rechargeable battery with excess power supplied by outer power network. This power
storage at the gateway node assists the arbitrary power consumption of the inner network to some extent
especially when power supply from outer network halts because of some troubles.
In addition to these inherent roles of the power gateway, it also executes the routing process by relaying
incoming energy packets to the next hop.
The power communication link consists of an electric wire for power transmission and a data cable for
information exchange between its terminal nodes. In this network configuration, because the data cable isassumed to be divided from the electric wire, the media for data transmission may be another candidate forsmart grid communications[1]. In addition, the information exchanges may follow the protocol standards forthe smart grid communications recommended by ETSI[13].
2.2 Extended forwarding table
The proposed power distribution protocol is based on the EFT (extended forwarding table) that every nodein the network individually construct and update repeatedly. This table consists of current information ofrouting for the energy packet transmissions and that of all consumers including their power demands anddistances.
The examples of the EFT are shown in Fig. 2 according to the network configuration in Fig. 1. The upperand lower part of this figure show the EFT owned by the power plant A and power router F in F ig. 1,
respectively. In both tables, the first line denotes tags of table contents as follows:
dst: The destination node for the power transmission. (In the following items, dst denotes this destination
node.)
nxt: The next hop node to the dst that specifies one of adjacent nodes on the most preferable powertransmission path to the destination.
hop: Hop count to the dst.
mtr: The metric to the dst that indicates a value considered when a power plant determines a target
consumer for its power transmission. For example, if only the distance to the dst is considered, this metricequals to the distance. Or, if the power transmission path congestion is also considered, the metric alternatesaccordingly.

Fig. 2.

Examples of EFT of power plant A and power router F in Fig. 1.

Above four contents are the basics of the forwarding table of routing method of DSDV(Destination-Sequenced Distance-Vector Routing) that is a typical scheme for mobile network routing[10].
Therefore, these four contents are mentioned as the basic contents. Whereas, additional three contents arecounted in the EFT (these are mentioned as the additional contents):
dist: The distance to the dst along with the transmission path.
c/p/r/g: The information about the dst that indicates which class the node belongs to. These four character
represent consumer, power plant, power router, and power gateway, respectively.

－3－

pow: If the class of the dst is power plant, this value indicates the surplusage for the power transmission of
the dst, or if the class is consumer, this indicates its power demand.
The second and the succeeding lines indicate the entries toward every node in the network . (From now on,
an entry toward an node means that an entry with the node as its destination.)
When a power plant determines a target consumer as the power transmission destination, the power planttransmits the energy packets and power routers relay them according to their EFT until the packets arrive at theconsumer.
For example in Fig. 1, if power plant A determines consumer E as the target, A searches the target E in its
own EFT (upper part of Fig. 2) and finds the next hop F. Then A assembles the energy packets addressed to E
and transmits them to the next hop F. Because the entry toward E indicates that the next hop is node I in the
EFT of power router F (lower part of Fig. 2), the router F relays the received energy packets to the next hop I.
The same relay process is repeated according to the EFT of routers until the energy packets arrive at thedestination consumer E.
2.3 EFT construction and update
EFT is constructed and updated at each node individually based on information exchanges between adjacentnodes. Along with the repetition of this EFT operation over the network, each EFT entry conve rges the correct
information even though the entry toward a distant node in the network.
The EFT operation corresponds with that of conventional forwarding table in DSDV routing method where
only the basic contents contribute the operation[14]. Additional contents are gradually spread over the network
along with the repetitive information exchanges between adjacent nodes in the network.
The overview of the EFT operation is explained as follows:
1. At the beginning of the EFT operation, each node records the initial entry in its own EFT. This initialentry indicates the owner node itself. An example of this initial entry is shown at the right side of Fig. 3. Thispart of figure shows the initial entry in EFT of node Z. The content ‘seq’ represents the sequenc e number thatindicates the newness of the information attached with.
2. Each node receives the EFT data from one of adjacent node, and updates its own EFT based on thecomparison of each entry with the received one. The process of this each entry update is as follows:a. If the node has not the entry with the same ‘dst’ as the received one, adds the entry to its own EFT.
b. If the received entry of the same ‘dst’ has larger (or newer) sequence number than its own one, overwrite
it with the received one.
c. If the received entry of the same ‘dst’ has smaller (or more preferable) metric than its own one, overwrite
it with the received one.
d. If the received entry has passed the above screenings, discard the received one.
3. The node receives the EFT data from another adjacent node and returns to the stage 2.
An example of this EFT update is shown in Fig. 3. In this figure, node A intends to update its entry toward
Z based on information exchanges with B and D. This entry is initially made by the node Z as sho wn at theright side of the figure. According to the second stage in the EFT operation above indicated, node A firstcompares its own entry with that fromB. As the result, the entry from B is discarded because of its smaller
sequence number. Then, according to the third stage, node A compares its entry with that from D. Because theentry from D has larger sequence number, A overwrite its entry with that from D even though it has larger
metric.

Fig. 3.

An examples of EFT entry update by node A.

－4－

3. POWER DISTRIBUTION PROTOCOL: ENERGY PACKET TRANSMISSION
In this section, the proposed protocol for energy packet transmissions among power plants and consumers is
explained. First, overview of the protocol is described. Second, the detailed procedure f or each consumer tosatisfy its power demand is described. Third, the procedure for each power plant to transmit energy packets to
consumers is described. Finally, an example of power distribution procedure among power plants andconsumers is described.
3.1 Overview of energy packet transmission protocol
As mentioned in section 1, the energy packet transmissions must be multipoint-to-multipoint in the power
network and the process of the power transmissions must be triggered by an occurring of a consumer d emand.
Based on these essential requirements, the proposed power distribution protocol is designed to satisfy thefollowing conditions.
1. According to the protocol, energy packets are transmitted from power plants to consumers in
multipoint-to-multipoint configuration.
2. The power transmission procedure is triggered by an occurring of a consumer demand.
3. Each power transmission and routing is planned by individual node in the network and no center stationis necessary.
4. Each power supplying gradually increase or decrease to avoid misadjustment to unexpected fluctuationsof consumer demands.
The third condition is inherent of conventional data packet networks and must be taken over by the energy
packet networks because of its reliability of network operations against a partial failure of the network causedby disasters or terrorisms.
In the fourth condition, the unexpected fluctuations of consumer demands may be caused by the alternationof their power consumptions or by power transmissions from other power plants in the network. Though theformer problem cannot be resolved, the latter one can be handled by negotiations among power plants to maketheir accumulated power equalized just to the consumer demands. However, because the negotiations amongnodes possibly induce traffic congestions of data cables and take unreasonable time until the convergence, theprocess of the negotiations among power plants is not adopted in the proposed power transmission protocol.

Fig. 4.

Procedure of each consumer to satisfy its power demand.

－5－

3.2 Energy packet transmission: consumer procedure
The procedure for energy packet transmissions is explained for consumers and power plants, individually.
First, the procedure for each consumer is expressed by the flow chart shown in Fig. 4. This processproceeds as follows (descriptions are tagged by corresponding numbers in the flow chart):(1) Each consumer examines itself whether or not the power demand exist.
(2) If exists, the consumer records the demand volume on the initial entry of its EFT and transmits the data
to neighbor nodes for their EFT update.
(3) (Because this stage is not the process of individual consumer, enclosed by a dashed rectangle in the flow
chart.) The demand is propagated to every power plant in the network along with the EFT updates amongnodes.
(4) The consumer examines the arrival of a notice from a power plant that indicates the energy packet
transmission to the consumer.
(5) If the notice arrives, the consumer increases or decreases its power demand volume recorded in its EFT
according to the notice description.
(6) The process returns to the first stage.
In the fifth stage above described, the cases of increase or decrease the power demand may occur because of
the following reasons:• Power demand increase: Because a power plant stops its continuous transmission of energy packets tothe consumer, the node increases its power demand. The power plant possibly lost its surplus power orchanged the power transmission destination for some reasons.
• Power demand decrease: Because a power plant increases its energy packet transmission to theconsumer, or because some another plant begins to transmit energy packets to the same node, theconsumer decreases its power demand.
3.3 Energy packet transmission: power plant procedure
The procedure for each power plant is expressed by the flow chart shown in Fig. 5. This process proceeds asfollows:(1) Each power plant waits the decision timing when the plant makes decisions about the energy pac kettransmissions.
(2) The power plant examines itself whether or not it has a surplus power to satisfy consumer demands.
(3) If the plant has a surplus power, it scans the entries in its EFT and make up a list of all consumers. The list
consists of the power demand of each consumer and its distance from the power plant.
(4) The plant determines the way of energy packet transmission to each consumer (the details are describedlater).
(5) According to the determination, the plant send the notice to each consumer that the way of powertransmission is changed.
(6) The power plant transmits energy packets to each consumer according to the determination executed in the
fourth stage. This transmission continues until the next decision timing. For example, if 1[W] is transmitted to a
consumer and each payload of energy packet equals 1[J], the packet transmission repeats every 1[sec].
(7) The process returns to the first stage.
The decision timing in the first stage above, and the transmission power increasing or de creasing at the timing
in the succeeding stages concern the fourth condition mentioned before on the power distribution protocol. The
condition requires gradual alternation of the power volume. For example, the interval of the decision timing is
set to 0.1[sec], and the step of power alternation is set to 1[W], the alternation cannot exceed 10[W/sec].
In the fourth stage above, the power plant determines the way of energy packet transmission. This way isclassified according to the previous way of power transmission and current state of each consumer as follows.
• If a power transmission has been continued to the consumer and the consumer has no power demand,
this means the power transmission and consumption keep equivalent. Therefore, the plant does notchange the way of the power transmission.
• In this case, if the consumer has a power demand, the plant increases the power volume of thetransmission. For example, raise the frequency of the energy packet transmission.
• On the other hand, if the power transmission was not executed to the consumer and it has a power
demand, the plant begins to transmit energy packets to the consumer.

－6－

3.4 Example of power distribution procedure
Based on the protocol described in previous subsections, an example of power distrib ution procedure is
described in Fig. 6 among power plants and consumers in Fig. 1.
The followings are assumed in Fig. 6:(1) Each of power plants A and D has an initial surplus power.
(2) Each of consumers B and E has an initial power demand.
(3) At the beginning of the procedure, no energy packet transmission exists.
(4) The determination of target consumer by each power plant concerns the power demand and distance ofthe consumer.

Fig. 5.

Procedure of each power plant to transmit energy packets to consumers.

Based on these assumptions, the power distribution procedure shown in Fig. 6 proceed as follows(descriptions are tagged by corresponding numbers in the figure):(1) First, the power demands of consumer B and E spread over the network along with repetition of EFT
update among adjacent nodes. Power plants A and D receive these informations.
(2) At the predetermined decision timing, power plants A and D determine their power transmission
destination as the same consumer E. This decision depends on the power demands of consumers and distances
to them .
(3) Power plants A and D transmit their decisions to the consumer E as a notice. This notice is transmitted
directly through the intermediate communication links. According to this notice, consumer E decreases its
power demand.
(4) Power plants A and D begin to transmit their energy packets to the consumer E . To satisfy the gradualincrease of transmitted power volume, the transmitted power is a least unit (several watts or  so) and the seriesof packets conveying this least power continues until the next decision change.
(5) At this decision timing, because of the power demand decrease at consumer E, power plant A determines
the new target as neighboring consumer B. Beyond this timing, A transmits energy packets to consumer B and E－7－simultaneously. Another power plant D keeps the target as E and increases its power transmission to twice ofthe least unit.
(6) Both consumers are noticed these decisions of power plants and decrease their power demands
accordingly.
(7) Both power plants continue power transmissions according to their latest decision of the destinations
and power volume of their energy packets.

Fig. 6.

An example of power transmission procedure among power plants and consumers in Fig. 1.
4. COMPUTER SIMULATION

For the purpose to confirm the operations of energy packet network with the proposed power distribution
protocol, computer simulations are executed. The overview of the simulations, and the simulation results aredescribed in this section.
4.1 Overview of computer simulations
The aspects of the power network operation to be confirmed with the proposed protocol are as follows:
1. Are the power demands of consumers finally satisfied with the energy packet transmission procedure thatis triggered by themselves?
2. At the decision timing, each power plant determines a target consumer concerning the power demand ofeach consumer and its distance. There must be an appreciation ratio between these two essentials. Does thisappreciation ratio affect the power network operation? And is there the optimal value of the ratio?
3. Do the multipoint-to-multipoint transmissions of energy packets appear during the power network
operation?
For the purpose to confirm these aspects, an elemental system model for the simulations is adopted asshown in Fig. 7.

Fig. 7.

A system model of power distribution network with energy packet transmissions for computer
simulations.

－8－This system model consists of six end users numbered 1 to 6, and eight power routers. Among the end users,
two power plants 1 and 5 are indicated by gray circles. The othersindicated by white circles are consumers.
Initial surplus power or initial power demand is indicated in watts with each power plant or consumer,
respectively. As shown in the figure, the longest distance between adjacent power routers is set to 100[m].
Other dimensions are proportional to what the figure actually indicates.
As the simulation goes on, each power plant increases its power transmission to the consumers that havepower demands. Equivalently, each consumer decreases its power demand provided some surplus power exists
among the power plants. Because the summation of initial surplus powers and power demands is set to zero,these powers gradually approach zero and absolutely become zero at the end of the simulation. Concerning thissimulation scenario, these assumptions are set:
1. Only the power transmission of each power plant decreases its surplus power, and only the power
reception of each consumer decreases its power demand. No other causes exist that fluctuate their surplus
powers or power demands.
2. The least unit of power transmission increase is set to 1[W], and the interval of decision timing of eachpower plant is set to one simulation step. Therefore, if the step equals 0.1[sec] in actual power network
operation, and if each energy packet conveys 1[J] of power, the increase of least unit causes an addition of one
energy packet at every ten decision timing interval.
In addition, each power plant determines a target consumer concerning the power demand of the consumer
and its distance. For this determination, the evaluation function Eij for each power plant i and consumer j isadopted. Eij is defined as follows:(1)

Eij  rdist  Dijn  (1  rdist )  Pjn

In this equation, Dnij denotes the normalized distance of consumer j from power plant i. From the actual
distance Dij, the normalization converts its average and standard deviation into 0 and 1, respectively. Similarly,
Pnj denotes the normalized power demand of consumer j. rdist denotes the appreciation ratio of Dnij that takes
0 to 1.
At every decision timing, each power plant i calculates Eij of all consumers according to (1) and select thetarget consumer j that yields the smallest Eij.
4.2 Simulation results
Fig. 8 shows the simulation result of the power network performance versus the appreciation ratio rdist .
Left and right vertical axis represent the total transmission length and the satisfiability time, respecti vely.
Horizontal axis represents the appreciation ratio rdist. Because the total transmission length is sensitive to smallvalue of rdist , the horizontal axis is scaled logarithmic.
The total transmission length is derived by integrating every energy packet transmission path length in the
network. This value is proportional to the power dissipation by Joule loss along with the energy packet
transmissions. Whereas, the satisfiability time means the elapsed time in simulation steps from the beginning of
the simulation when the power demand of a consumer becomes zero.

Fig. 8. power network performance versus the appreciation ratio rdist .

－9－

As the figure shows, the total transmission length roughly decrease as rdist increases. This is because atlarge rdist , power plants tend to determine their target consumer with smaller distance. On the other hand, atlarge rdist , satisfiability times of four consumers become sparse. Especially when rdist equals the maximum
value 1, consumer 6 firstly satisfies its power demand at 60 simulation steps. This is mainly because theconsumer 6 is located closest to the power plant 5. As shown by the figure, the maximum satisfiability timealways equal 350 regardless of rdist . This is because at this time, the surplus powers of power plants are
exhausted and coincidently the power demands of consumers become zero according to the assumption
mentioned before.

Fig. 9.

Surplus power and power demand alternations versus elapsed time when rdist equals 0.1.

The satisfiability times mean that the power demands of consumers are finally satisfied with the proposed
protocol. This simulation result confirms the first aspect of the power network operation described in theprevious subsection. However, the optimal value of rdist , that is mentioned in the second aspect, is not foundapparently. Therefore, in the following simulation results, 0.1 is adopted as a moderate value of rdist instead.
This value is indicated by a dashed line in Fig. 8.

Fig. 10.

Breakdown of power supply from each power plant to consumers versus elapsed time ofsimulation.

Fig. 9 shows the simulation results of the surplus power and power demand alternations versus elapsed time
when rdist equals 0.1. Left and right vertical axis represent the power demand of consumers and the surplus
power of power plants, respectively. Horizontal axis represents the elapsed time from the beginning of thesimulation. The alternation of power demands and surplus powers are indicated by solid lines and dashed lines,
respectively.
As the dashed lines show, each surplus power of power plant decreases monotonically. Because a power
demand always exist in the network until the simulation finishes, each surplus power decreases 1[W] a step. On
the other hand, each power demand sometimes stay constant for a while. During this while, none of the power
plants transmit their power to the consumer. Otherwhiles, the consumer receives a power and its power demand
gradually approaches zero.

－10－

The breakdown of power supply from each power plant to consumers is shown in Fig. 10. Vertical axis
represents the power supply and horizontal axis represents the elapsed time of the simulation. Each numberedarea indicates the breakdown of power supply to the consumer with the corresponding number. Whereas, thepower source is indicated by display colors. A white area and a gray area indicate power plant 5 and 1,
respectively. Depending on their initial surplus power, power supply from plant 1 and 5 finish at 200[step] and350[step], respectively.

Fig. 11.

Breakdown of power supply from each power plant at elapsed time 130[step].

As the figure shows, the power network operation of multipoint-to-multipoint transmission is confirmed
from this simulation result. For example, when the elapsed time is 130[step] as indicated by the vertical dashedline, power plant 5 transmits energy packets to consumers 3 and 4,simultaneously. Especially, 96[W] of poweris transmitted to consumer 4 as shown in the figure. At the same time, consumer 3 also receives energy packets
from power plant 1. The breakdown of the whole transmitted power at 130[step] is shown in Fig. 11.
5. CONCLUSION
Power distribution protocol among power plants and consumers in electric energy packet networks is
proposed. The proposed power distribution protocol consists of two processes: The process of information
accumulation and EFT (extended forwarding table) construction and update at each node, and the process ofenergy packet transmissions among power plants and consumers.
These processes are simulated on an elemental system model with assumptions for the network operation.
From the simulation results, these points are confirmed. First, the power demands of consumers are finallysatisfied with the energy packet transmission procedure that is triggered by themselves. Second, the power
network performance is affected by appreciation ratio rdist that is an essential factor in the determination ofeach power plant on its target consumer. Third, the multipoint-to-multipoint transmissions of energy packets
surely appear during the power network operation.
In further studies, these points should be investigated. First, though omitted in this paper, the powertransmission path congestion should be counted in the metric in each entry of EFT. This subject is essential
especially in the pulsed power network [9] for there is a hard limit of packet number in each power link. Second,though only power demand and distance of consumers are counted in this paper at the determinat ion of power
plants on their target consumers, other various factors should be considered including the preferable type of thepower plant, upper limit of electricity charge, or so. For the purpose to consider these personal demands ofconsumers, more actual and complicated power system design is necessary. Third, though the optimal value ofappreciation ratio rdist is not found apparently, the optimization of power distribution network should be
investigated depending on the coordination of the ratio rdist and the metric evaluation mentioned above.
References
1) V. C. Gungor, et al., ``Smart Grid Technologies: Communication Technologies and Standards'', IEEE Trans.
Industrical Informatics, Vol.7, No.4, pp. 529-539, 2011.
2) J. Toyoda, H. Saitoh, ``Proposal of an Open-Electric-Energy-Network (OEEN) to Realize Cooperative
Operations of IOU and IPP,'' EMPD'98, Mar. 1998.
3) T. Takuno, M. Koyama, and T. Hikihara, "In-Home Power Distribution Systems by Circuit Switching andPower Packet Dispatching," SmartGridComm, pp. 427-430, Oct. 2010.
4) V. Krylov, D. Ponomarev, and A. Loskutov, ``Toward the Power InterGrid,'' IEEE Energy Conference, pp.
351-356, Dec. 2010.
5) H. Hatta, M. Asari, and H. Kobayashi, ``Study of Energy Management for Decreasing Reverse Power Flowfrom Photovoltaic Power Systems,'' SAE2009, pp. 1-5, Sept. 2009.
6) T. Kato, et al., "Appliance Recognition from Electric Current Signals for Information -Energy Integrated
Network in Home Environmens," Int. J. Assistive Robotics and Systems, Vol.10, No.4, pp. 51-61, 2009.
7) K. Saito and Y. Okabe, "Quality-Aware Energy Routing Toward On-Demand Home Energy Networking,"
CCNC2011, Jan. 2011.

－11－8) H. Sugiyama, ``Direct Relayed Power Packet Network with Decentralized Control for Reliable and Low
Loss Electrical Power Distribution,'' GCCE2013, pp. 32-36, Oct. 2013.
9) R.F.M. Brandao, J.A.B. Carvalho, and F.M. Barbosa, ``GPS Synchronized Measurements in Power Systems
State Estimation: An Overview,'' UPEC '06, Sept. 2006.
10) C. E. Perkins and P. Bhagwat, ``Highly Dynam-ic Destination-Sequenced Distance-Vector Routing(DSDV) for Mobile Computers,'' ACM SIGCOMM'94, pp.234-244, 1994.
11) H. Sugiyama, ``Packet Switched Power Network with Decentralized Control Based on Synchronized QoS
Routing,'' ICTA2012, pp. 147-152, Nov. 2012.
12) H. Sugiyama, ``Pulsed Power Network Based on Decentralized Intelligence for Reliable and Low Loss
Electrical Power Distribution,'' CIASG'14, Orlando, FL, USA, Dec. 2014.
13) ``ETSI GS OSG001 V1.1.1: Open Smart Grid Protocol,'' European Telecommunications Standards
Institute (ETSI), 2012.
14) S. A. Hamid, H. S. Hassanein, and G. Takahara, “Routing for Wireless Multi-Hop Networks,” Springer,
2013.

－12－

Method of Evaluating Dialogue Robots for Visually Impaired and Elderly People
Hiroko MATSUMOTO*, Takashi UCHIDA** and Kanami BESSYO***(Received September 30, 2017)
Synopsis
To support the daily living of visually impaired people, we have been conducting research on pedestriannavigation, mainly audio guidance by a “Verbal map.” In collaboration with “Verbal map,” we plan a dialogue
robot that can guide a person in a plaza space. As the first step, this study establishes an evaluation experimentto quantify the degree of pleasant feeling a person has when talking with a robot.
This paper first presents the research background and objectives. Chapter 2 describes the evaluation
experiment method. In chapter 3, using results of the experiment conducted, we specifically examine a function
evaluation questionnaire and measurements of the psychological load. Finally, this report provides a summaryof the research.
KEYWORDS: Dialogue experiment, AI, Function evaluation, Psychological load, Movement support,
Barrier free

1. Research Background and Objectives
There is a continuing movement in support of daily life for visually impaired people (e.g., traveling towork, going to hospital, shopping, eating out) under poor circumstances. With the spread of smartphones,sighted people can better enjoy a town walk in unknown places because of pedestrian navigation. However,visually impaired people remain reliant on Braille blocks and their own memory. When going to unknown
places, visually impaired people must be guided by a sighted person. This current state presents importantobstacles to visually impaired people’s active movement. Therefore, we have conducted research on pedestriannavigation, mainly an audio guidance “Verbal map” as movement support for the daily living of visually
impaired people. Takahashi et al.1) describe effects of the verbal map audio AR application. Although it
functions well in a linear space such as a road, the route guidance directions are difficulty in a plaza space.
Therefore, using verbal map, we plan a dialogue robot that provides guidance in a plaza space within a public
facility.
The population of visually impaired people is small. It is not practical to cover the costs of setting up the
dialogue robot for visually impaired people alone. Therefore, it is also necessary to target sighted persons using
it. Currently, elderly people do not go out frequently. As a result, their body condition is adversely affected.
Furthermore, venturing out of home imposes a mental load. Elderly who are shut-ins are becoming animportant social problem. Other benefits of going out might include maintenance of independent living andreduction in hospital visits and nursing burdens. For this reason, elderly people are added as targeted users of
dialogue robots.
We expect that visually impaired people and elderly people can feel pleasant when meeting and talking to*
URP Research Fellow, Osaka City University Urban Research Plaza** Professor, Department of Civil Engineering*** Engineer, Komaihaltec Inc.

－13－

dialogue robots and that they will increasingly engage in dialogues with robots themselves. We also expect toenhance the motivation of visually impaired people and elderly people using the dialogue robot.
This study was conducted to develop the dialogue robot dialogue functions. The artificial intelligence (AI)function can enhance motivation to go out when added to a commercially available dialogue robot as anapplication. This study was conducted to establish an evaluation experiment method to clarify whether thefunction engenders enhanced motivation to go out. We use a dialogue robot “RoBoHoN” (Sharp Corp.), which
can express feelings by changing the tone. The study contents are the following three.
1) Referring to a dialogue system that incorporates user preferences2), we create a dialogue scenario
with tone set in predetermined conversation contents. Then we perform an evaluation experiment.
2) In the experiment, we attempted to evaluate whether the tone of RoBoHoN is perceived by the
subject correctly and to evaluate how the subject’s feeling of use and satisfaction change throughdialogue task. The instrument consists of both a function evaluation questionnaire and psychologicaltests.
3) We examine the validity of the experimental protocol and psychological tests, as a whole.

2. Evaluation experiment method(1) Outline flow of an evaluation experiment
An outline flow of an evaluation experiment is presented in Figure 1. The evaluation instrument consistsof a function evaluation questionnaire (Table 1) and a psychological test.
First, a psychological test (1) is conducted immediately after the start of the experiment. Then we start a
dialogue task with RoBoHoN. Every time a dialogue task is completed, a function evaluation questionnaire isadministered. This process is repeated J times. Psychological test T was administered at the midpoint of repeat(J/2). After all dialogue tasks are completed, the principal researcher conducts hearing research. Subsequently,
a psychological test (2) is applied. Finally, after administrative procedures are completed, a psychological test(3) is administered. The experiment is finished.
In the dialogue task, RoBoHoN talks based on predefined dialogue scenario with the subject. Details of the
dialogue scenario are presented in 2. (2).
The function evaluation questionnaire assesses whether the tone of RoBoHoN is perceived by the subject
with the correct feeling. Details are presented in 2. (3).
The psychological test measures the psychological load of the subject. The instrument is STAI3). We would
also like to measure the psychological load for every dialogue task iteration like the function evaluationquestionnaire. However, many more questions exist than those of the function evaluation questionnaire. Whenquestions continue, it is possible that stress is imposed on the subject by fatigue. Therefore, the psychologicalload during the dialogue task is measured only at the midpoint of the task (psychological test T). In
psychological test (1), we measure STAI-Y1 and Y2. In psychological test T, we measure STAI-Y1. In
psychological test (2), we measure STAI-Y1 and Y2. In psychological test (3), we measure STAI-Y1. Details
are presented in 2. (4).
In the function evaluation questionnaire and psychological test, it is natural that the subject should silently
read and answer the questions. However, in this experiment, the subjects are visually impaired people.
Therefore, the experimenter reads the question and asks the subject to answer.

－14－

START
Psychological test (1)j=1
Dialogue task
Function evaluation questionnaire

NO
NO

j=J

Psychological test Tj←j+1

j = J/2

YES

YES

Hearing research
Psychological test (2)Administrative procedures
Psychological test (3)END

Figure 1

Flow of the evaluation experiment(2) Dialogue Scenario
Kobayashi et al. report that user satisfaction of the dialogue system improves by considering the user’s
preferences and human relations.
Jimenez et al.4), points out a problem by which a person’s interest in the robot decreases over time. For
example, this study has reported that one factor of a person’s interest in the robot decreases when the robot
performs the same action. To stop that, a method exists to express feelings as if robot has feelings. Furthermore,some reports describe that a robot with an emotional expression model can perform interaction with people
effectively and reports describe that it tends to give much familiarity. Therefore, a dialogue scenario is createdby combining a predefined dialogue theme considering a user’s preferences and human relations and tone
expressing feeling. Dialogue lengths of two types are created: short dialogue (about five utterances) and long
dialogue (about eight utterances). The utterance interval is set to 5 s, which the subject is regarded as able torespond to asking from RoBoHoN. We set a tone that does not match the content of the conversation. We createa scenario that gives a sense of incompatibility because we confirm whether the tone of RoBoHoN is perceived
by the subject correctly, or not, and evaluate whether the tone influences the subject’s satisfaction.
RoBoHoN is set as a boy of about five years old. Therefore, the set is based on words and casual phrases
such as those used by children.
2)1) Dialogue theme
When the subject talks with RoBoHoN, prepare the following dialogue themes.
• Weather• Birthplace• Favorite food
• Breakfast• Hobby• Family• Trip• News• Year-end and New Year holidays－15－2) Tone
RoBoHoN used for this study is a dialogue robot equipped with a function to express feelings by “tone”
and “motion.” Subjects in this experiment are visually impaired people. Therefore, feelings are expressed onlyby the tone function. Tone is created by combining a type of feeling and level of feeling. Types of feelings offour kinds are used: Standard, Happiness, Sadness, and Anger. The level of feeling can be set in four stages. A
large number represents a high feeling level. To clarify the difference in tone, the level of feeling is set at thehighest feeling level (level 4).

(3) Function evaluation questionnaire
The function evaluation questionnaire is shown in Table 1. It consists of 10 items. Questionnaire item 1 isintended to check whether the tone of RoBoHoN is perceived as the correct feeling (Q 1). And, 9 items exist
to investigate feeling of use and satisfaction of the subject (Q 2–10). In addition, answers to questions 2–10
are evaluated on four levels: 1, Dissatisfied; 2, Slightly dissatisfied; 3, Slightly satisfied; 4, Satisfied.
Questionnaire items used to investigate the feeling of use and satisfaction of the subject from evaluating
the user satisfaction of the dialogue system by Kobayashi et al.2) and Sugo et al.5) were used on the questionnaire.
Specifically, the items include “Do you want to use it again?,” “Could you hear the talk ?,” “It was easy totalk?”
Furthermore, in the dialogue scenario used in this experiment, tones are combined with a predetermined
dialogue theme that incorporates the user preferences and human relations. Therefore, we added an item toevaluate how a subject feels if a change exists in tone. Specifically, “Were you able to talk without getting
tired?”
Table 1
No.

Question of function evaluation questionnaire
Evaluation questionnaire item

1

Which did you feel about the RoBoHoN’s feeling?
Happiness, Sadness, Anger, Standard, Do not know

2

Do you want to use it again?

3

Could you hear the talk?

4

Is it easy to talk?

5

Is the flow of talk natural?

6

Did you feel that you were interested?

7

Was the feeling suggested?

8

Did you feel friendly?

9

Were you able to talk without getting tired?

10

Are you satisfied as a companion?

(4) Measurement of psychological load – Use of STAI
We measured using psychological test STAI3) to ascertain how the psychological load of the subject changes
by talking with RoBoHoN. STAI comprises scales of two types: STAI-Y1 for measuring State-anxiety and
STAI-Y2 for measuring Trait-anxiety. Each question has 20 items, giving an indication in four stages. Each－16－

question is rated on a four point scale, with higher scores indicating greater anxiety.
STAI-Y1 that measures State-anxiety evaluates “how do you feel right now?” State-anxiety is a transient
situation reaction to an event that arouses anxiety. State-anxiety changes at that time. In situations of perceived
threat, State-anxiety is high. In situations where there is no danger at all or little danger, State-anxiety is low.
In addition, some reports of the relevant literature describe that it is useful to investigate how a person was
feeling at a very recent time, and evaluates how a person expects to feel in certain scenes that might beconfronted in the future or in various virtual scenes.
STAI-Y2 that measures Trait-anxiety evaluates “how do you feel in general?” Trait-anxiety perceives
various threatening situations in the same way. It shows a tendency to respond in the same way to such asituation. It has stable characteristics. It shows stable individual differences in anxiety tendencies.
Actually, STAI-Y1 was created to respond sensitively to implementation conditions. Therefore, we started
with STAI-Y1 when STAI-Y1 and STAI-Y2 are executed simultaneously.
In this study, STAI-Y2 score is made using a psychological test (2) that can be expected to be close to thenormal value is set as the reference value. We decided to measure the movement of psychology from thetransition of the score deviation of STAI conducted at
the beginning of the experiment (psychological test
STAI-Y1(1),Y2(1)(1)), at the midpoint of the experiment (psychological(Approximately 8 min.)test T, psychological test (2)), and at the end of thePracticeexperiment (psychological test (3)).
(Approximately 10 min.)
STAI is commercially available for psychological
Task 1, Questionnaire
tests and applications in psychosomatic medicine.
(Approximately 3 min.)Previous reports show that it is applicable to evaluate
Task 2, Questionnaire
psychological stress as in this experiment. However,(Approximately 3 min.)because the adequacy of repeated measurements is
Task 3, Questionnaire
unknown, it is the subject of this study.
(Approximately 3 min.)

STAI-Y1-T

3. Evaluation experiment result(1) Experiment outline
The experiment protocol is depicted in Figure 2.
First, we conducted psychological test STAI-Y1(1)and Y2(1). Furthermore, the subject took a practicedialogue to become accustomed to RoBoHoN for
approximately 10 min. Subsequently we set dialogue
task and function evaluation questionnaire as 1 cycle.
Then tasks 1–3 were conducted. After task 3 at the
midpoint of the task, STAI-Y1-T was conducted.
Tasks 4–6 were conducted again. After the tasks had
been completed, the principal researcher conducted
the hearing research for approximately 20 min. Then
STAI-Y1(2) and Y2(2) were conducted. Finally, afteradministrative procedures were completed, STAIY1(3) was conducted and the experiment was
finished. The total time necessary for the experiment
was about 80 min.

－17－

(Approximately 3 min.)Task 4, Questionnaire(Approximately 3 min.)Task 5, Questionnaire(Approximately 3 min.)Task 6, Questionnaire(Approximately 3 min.)Hearing research(Approximately 20 min.)

STAI-Y1(2),Y2(2)(Approximately 8 min.)Administrative procedures(Approximately 5 min.)

STAI-Y1(3)(Approximately 3 min.)Figure 2

Experimental protocolIn a dialogue scenario, there are six scenarios combining the dialogue theme (four items: Weather,
Birthplace, Food, Year-end, and New Year holidays) and the tone (four items: Standard, Happiness, Sadness,
Anger). Weather and birthplace were setting types of two tones to ascertain whether the tone of RoBoHoN is
perceived as correct feeling. Patterns of dialogue scenario and task order are presented in Table 2. An example
of a dialogue task is presented in Table 3.
The contents of dialogue practice show that the subject becomes accustomed to RoBoHoN as follows.
• Subject name and face photo registration (Let RoBoHoN recognize face of the subject.).
• Instruct to sing a song.
• Instruct to dance.
• Search for weather information (today, tomorrow, by region).
• Search for news.
• Search for event information.
• Search for movie information.
Subjects were 10 people (visually impaired people). Attributes of the subjects are presented in Table 4. The
experiment period is January 12–24, 2017. The experiment conditions are shown in Figure 3.

Table 2

Pattern of dialogue scenario and task order
ToneStandard Happiness Sadness

Weather

1

4

Dialogue
theme

Birthplace

5

Food

2

Year-end and New Year holidays

Anger
3

6

※ Subjects A and B did not experiment on tasks 2 and 6.

Table 3

Example of a dialogue task
Task, 1; Subject, A

Speaker

Utterance content

RoBoHoN

What is today’s weather?

Subject

Sunny.

RoBoHoN

That’s good! Which do you like better, sunny or rainy?

Subject

Snow.

RoBoHoN

Me too! Which do you like better, cold or hot?

Subject

Cold.

RoBoHoN

That’s good! Are you going out recently?

Subject

I am out.

RoBoHoN

It’s cold outside, so please go out with a warm.

Subject

Sure.

－18－

Table 4

Attributes of the subject (Visually impaired people; 10-people)

Subject

Sex

Age

Degree of disability

Date

A

male

40

Blindness

January 12

B

male

39

Blindness

January 12

Cfemale64

Blindness

January 13

D

male

50

Low vision

January 17

Efemale39

Blindness

January 17

F

male

23

Blindness

January 17

G

male

70

Low vision

January 20

Hfemale70

Blindness

January 20

I

male

53

Low vision

January 24

Jfemale52

Low vision

January 24

Subject

Dialogue robot

Figure 3

Experimenter

Situation of experiment(2) Validity of function evaluation method
1) Function evaluation questionnaire result
Average mark of functional evaluation questionnaire (Average of answer values to questions 2–10:
maximum 4 points, minimum 1 point) is presented in Figure 4.
As a result, we grouped 10 people into the following four types.
Satisfied– constant : G
Satisfied– fluctuate: C, D, E, H
Dissatisfied – constant : A, I
Dissatisfied – fluctuate: B, F, J
Judging from the hearing research after the experiment, when the score of function evaluation questionnaire
was bad, the influence of scenario and the influence of feeling were apparent.
Influences of the scenario were the following.
• When response of the subject was not in time for RoBoHoN utterance, and when RoBoHoN utterance
progressed unilaterally.
• When conversation contents between the subject and RoBoHoN do not match.
• After response of the subject, when “the interval” was long until RoBoHoN utterance.

－19－

Influences of feelings were the following.
• When RoBoHoN felt sad.
• When the tone of RoBoHoN and conversation content do not match.

2) STAI result
Change in the score deviation of STAI is shown in Figure 5. Results show that we can divide groups
according to the degree of anxiety decrease types. First, we can divide and group them into two types, “Degreeof anxiety gradually decreases.” and “During the experiment, the degree of anxiety increases.”
The latter is even more, we can divide and group them into two types, “The degree of anxiety increases by
dialogue with RoBoHoN (Y1-T*),” “The degree of anxiety increases by dialogue with the principal researcher(Y1(2)*).” Additionally, we can divide even groups in two types: with the degree of anxiety higher than usual,and the degree of anxiety lower than usual (Figure 6).

4.0

A
B

3.5

C
3.0

D
E

2.5

F
G

2.0

H
1.5

J
Year-end and
New Yearholidays（Happiness）

Food（Sadness）

Birthplace（Sadness）

Birthplace（Anger）

Figure 4

Weather（Happiness）

Weather（Standard）

1.0

I

Average mark of a functional evaluation questionnaire

20

A
B

10

C
D

0

E
F

-10

G
H

-20

I
-30

Y1(1)*

Y1_T*

Y1(2)*

Y1(3)*

Figure 5 Change in the score deviation of STAI

－20－

J

Degree of anxiety is higher than usual

Degree of anxiety is lower than usual

Degree of anxiety gradually decreases

20

20
G

10

0

H
10

0

I

-10

-10

-20

-20

-30

Y1(1)*

Y1_T*

Y1(2)*-30

Y1(3)*

Y1(1)*

Y1_T*

Y1(2)*

Y1(3)*

20

0

F

-10

-20

-30

By a dialogue with the principal researcher

Degree of anxiety increases

By a dialogue with RoBoHoN

A

10

20
C
10
E

0

D

-30

Figure 6

Y1(3)*J0-20

Y1(2)*

Y1(1)*

Y1_T*

Y1(2)*

Group of change in the score deviation of STAI

－21－

Y1(3)*

10

-20

Y1_T*

Y1(2)*

B-10

Y1(1)*

Y1_T*

20

-10

-30

Y1(1)*

Y1(3)*

3) Consistency of function evaluation questionnaire result and STAI result
Results obtained from the function evaluation questionnaire and STAI are compared and presented in Table
5. A and F belonging to “The degree of anxiety increases by dialogue with RoBoHoN” belong to “dissatisfied”
in the function evaluation questionnaire. Therefore, probably the functional evaluation questionnaire and thepsychological test result are mutually consistent.
Additionally, among the members assigned to “The degree of anxiety increases by a dialogue with theprincipal resercher,” C, D, and E were “satisfied,” B and J were “dissatisfied.” In other words, probably C, D,
and E were satisfied both functionally and psychologically. However, B and J were dissatisfied for this dialoguefunction, but dialogue with RoBoHoN was more psychologically satisfactory than dialogues with the principal
researcher. We received one comment from a respondent that “I would like to use it if the dialogue function
develops further.” The subject expected that, in the future, we would think that the degree of anxiety in the
dialogue with RoBoHoN was low.

Table 5Function evaluation questionnaire result and the score deviation of STAI result
Function evaluation questionnaire group
Satisfied

Dissatisfied

Constant Fluctuate Constant Fluctuate
The degree of anxiety
gradually decreases

Anxiety-high

STAI group

Anxiety-low

GIH

The degree of anxiety increases
Anxiety-low
through dialogue with RoBoHoN
The degree of anxiety increases
through dialogue withthe principal researcher

A

Anxiety-highC, E

Anxiety-low

D

F

B, J

※ The sign of the cell is the subject label(3) Effect of tone
When the dialogue robot is doing route guidance or chat, we conducted hearing research to ascertain
whether it was a better to have a feeling function. Results of hearing research are presented in Table 6.
Regarding route guidance, 7 out of 10 people, and as for chat, 9 out of 10 people, it was better for the dialogue
robot to have a feeling function.
Table 7 presents questionnaire responses distribution of whether tone of RoBoHoN is perceived correctlyby the subject (Question of function evaluation questionnaire: no. 1). Excluding the answer of “standard” “?,”Many people answered as correct feeling in all scenarios. As a result, we were able to check that the tone of
the RoBoHoN was perceived as correct feeling. In addition, scenarios in which the subject felt “sadness,” anevaluation tended to decrease.

－22－

Table 6

Possibility of the robot to have feeling function

Subject

Route guidance

Chat

A

×

○

B

○

○

C

○

○

D

○

○

E

○

○

F

×

×

G

×

○

H

○

○

I

○

○

J

○

○

○, It is better to have feeling. ×, It is better not to have feeling.

Table 7 Distribution of the answer of feeling communication(Question of a function evaluation questionnaire: no.1)
AnswerStandard Happiness

Anger

Sadness?

Total

Dialogue theme

WeatherStandard

6

4

0

0

0

10

Weather

Happiness

1

6

0

0

3

10

Year-end andHappiness
New Year holidays

5

2

0

0

1

8

Birthplace

Anger

3

1

3

0

3

10

Birthplace

Sadness

3

1

0

4

2

10

Food

Sadness

2

0

0

4

2

8

4. Conclusion
In this study, we established an evaluation experiment method to clarify psychological effects of visually
impaired people and elderly people talking to the dialogue robot. We were able to obtain the following
knowledge. An evaluation experiment method using a function evaluation questionnaire and a psychologicaltest did not elicit contradictory results. We ascertained the characteristics of each group. Therefore, this method
is probably effective.
Additionally, we confirmed that the protocol used for this experiment is useful because there was no majordifficulty in the timing and repeated measurement of STAI used in psychological test. We were able to measure
the psychological load of the subject.
During dialogue, it will be desired that the robot expresses emotions. We confirmed that the tone wasperceived as correct feeling. From this perspective, we expect that setting up the dialogue robot with a feeling－23－

function in a public facility so that people can enjoy route guidance and chat, it can engender enhanced
motivation for visually impaired people and elderly people to venture from their homes.
Future challenges are explained below. When we administered a function evaluation questionnaire andpsychological test, some subjects showed ambiguous reactions and took time to answer. As reasons for suchreactions and low evaluation results, we inferred the following.
• From the beginning, because the expectation of the dialogue function with the robot was great, thesubject felt disappointed because the response of robot was worse than the subject had assumed.
• “The interval” of dialogue was early or late and did not match the pace of the conversation.
• Conversation contents did not match.
To address these problems, first, it is necessary to consider “the interval” in dialogue. Then, it is necessary
to create and classify dialogue scenarios so that dialogue according to the type of user can be conducted. In
addition, contents of this conversation were only chat. Therefore, it is necessary to clarify how an evaluation
changes depending on the expressions of feeling in route guidance.

References
1) M. Takahashi, T. Uchida and K. Matsuura: An Empirical Study of Verbal Sketch for Visually Impaired
People Navigation, Proceedings of the 35th conference of Japan Society of Traffic Engineers, pp. 465-470,
2015. (in Japanese)
2) S. Kobayashi and M. Hagiwara: Non-task-oriented Dialogue System Considering User’s Preference andHuman Relations, Transactions of the Japanese Society for Artificial Intelligence, Vol. 31, No. 1, pp. DSFA_1-10, 2016. (in Japanese)
3) T. Hidano et al.: Shin-Pan STAI manual, Jitsumukyoiku-Shuppan, 2000. (in Japanese)
4) F. Jimenez et al.: Feasibility of Collaborative Learning with Robots Which Prompts Constructive
Interaction, Transactions of the Japanese Society for Artificial Intelligence, Vol. 31, No. 3, pp. A-F93_110, 2016. (in Japanese)5) K. Sugo and M. Hagiwara: Transactions of Japan Society of Kansei Engineering, Vol. 13, No. 4, pp. 519526, 2014. (in Japanese)－24－Understanding the nature of walking and cycling for transport in Japan
Pola BERENT* and Nagahiro YOSHIDA**(Received September 30, 2017)
Synopsis
The following document is a summary of the existing academic articles available in English.
The literature review was conducted for the purpose of gaining an understanding of cycling
and walking behaviors in Japan. This was background research in order to acquire theoreticalknowledge for the further study, which aimed to establish whether people in Japan (where
cyclists regularly mix with pedestrians on sidewalks) show different attitudes and perceptionsof comfort while travelling on segregated or unsegregated shared-use paths and to identify
whether it is dependable purely on technical aspects of path design (i.e. physicalcharacteristics) or/and whether the travel behavior generated by traffic law has impacts on it.
KEYWORDS: Cycling, Walking, Active Travel, Japan, Traffic Law, Shared-use, Comfort,
Level of Service
1. Introduction
This literature review provides a deeper understanding of cycling and walking behavior inJapan, with the focus on the following themes: statistical data on cycling an walking fortransport, transport policy, traffic law, traffic education, factors that may be affecting levels of
walking, promoting cycling, challenges of cycling and shared-space, safety, design guidelines,
shared-use paths, level of service and perceptions of comfort.
2. Literature Review
2.1 Cycling and Walking in Japan
Cycling and walking are popular modes of transport in Japan. Figure 1 shows the share of
representative transport mode by trip distance according to 2015 Nationwide Person Trip
Survey. Walking and cycling constitute as the majority modes for trips up to 3km, andcycling makes up a significant proportion of trips up to 10km.

Share

BicycleWalk

Motorcycle

Car

Bus

Railway

Other

100%
90%
80%
70%
60%
50%
40%
30%
20%
10%
0%

Trip length(km)Source: 2015 Nationwide Person Trip Survey
Figure 1. Mode Share by Trip Distance (MLIT)* Visiting PhD Student (JSPS Fellow), Centre for Urban Sustainability and Resilience,
Department of Civil, Environmental and Geomatic Engineering, University College London** Associate Professor, Department of Urban Design and Engineering－25－

Figure 2 and 3 show in more detail the breakdown of representative transport modes forcommute trips to work and school. Figure 2 shows that in the most recent years (since 1990s)
levels of cycling remain stable, while walking is gradually declining. Figure 3 shows moredetailed data for Japan’s main cities. Osaka city stands out for particularly high levels of
cycling.
Rail
1970

Bus

Car

29

Motorcycle

17

Bicycle

Walk

15

Other

15

23

1980

24

1990

23

6

2000

25

4

45

4

12

2010

24

3

47

3

12

0%

10%

11

20%

29

16

37

30%

40%

15

5

50%

60%

70%

13

10

80%

8

7
90%

100%

Mode Share for Commuting To Work/School
Source: Census(Ministry of Internal Affairs and Communications Statistics Bureau) *Including motorcycle

Figure 2. Mode Share for Commuting To Work/School: Trends since 1970s.
Bicycle
Osaka
Kyoto
Sakai
SaitamaOkayamaShizuoka
Sagamihara
NagoyaHiroshima
FukuokaTokyo
Kumamoto
Chiba
Sendai
Kawasaki
SapporoHamamatsu
Niigata
Kobe
Kitakyusyu
Yokohama
Japan

23.4

Rail＋Bicycle

27.8

18.3
6.0
15.8
7.4
20.8
2.1
20.7
1.9
15.4
5.6
16.6
4.3
17.0
2.2
17.8
2.8
14.2
4.9
17.1
0.8
11.1
5.3
13.2
2.1
10.7
4.2
9.9
3.0
10.5
1.0
9.9
1.3
6.7
2.5
7.5
1.0
5.8
2.5
11.2
3.0

3.2

5.9

0
5
10
15
20
25
30
35
Modal Share of Bicycle for Commuting to Work/School by city (%)

Source: Census 2010(Ministry of Internal Affairs and Communications Statistics Bureau)

Figure 3. Mode Share of cycling for Commuting to Work/School by City.

－26－

40

Figures 4, 5, 6, 7 and 8 show the mode share by distance for trips for different purpose,including: `commuting`, `personal errands`, `going to school`, `business` and `going home`.
Interestingly, for each of these purposes cycling and walking make up a large proportion of
the trips for short distances. Going to school (Figure 6) shows particular reliance on walking
and cycling for the widest variety of distances.
BicycleWalk

Motorcycle

Car

Bus

Rail

Other

100%
90%

Modal share

80%
70%
60%
50%
40%
30%
20%
10%
0%

Distance traveled in km
Source: 2015 Nationwide Person Trip Survey
Figure 4. Mode Share by Distance for Commute (MLIT)
BicycleWalk

Motorcycle

Car

Bus

Rail

100%
90%

Modal share

80%
70%
60%
50%
40%
30%
20%
10%
0%

Distance traveled in km
Source: 2015 Nationwide Person Trip Survey
Figure 5. Mode Share by Distance for Personal Errands.

－27－

Other

Bicycle

Walk

Motorcycle

Car

Bus

Rail

Other

100%
90%

Modal share

80%
70%
60%
50%
40%
30%
20%
10%
0%

Distance traveled in km

Source: 2015 Nationwide Person Trip Survey

Figure 6. Mode Share by Distance for Going to School.
BicycleWalk

Motorcycle

Car

Bus

Rail

100%
90%

Modal share

80%
70%
60%
50%
40%
30%
20%
10%
0%

Distance traveled in km

Source: 2015 Nationwide Person Trip Survey

Figure 7. Mode Share by Distance for Business.

－28－

Other

Bicycle

Walk

Motorcycle

Car

Bus

Rail

Other

100%
90%

Modal share

80%
70%
60%
50%
40%
30%
20%
10%
0%

Distance traveled in km
Source: 2015 Nationwide Person Trip Survey
Figure 8. Mode Share by Distance for Going Home.
Furthermore, cycling in Japan is more popular among women than men. The only groupwhere opposite is observed is men aged 5-14 (11% male cyclists to 8% female cyclists).
Similar applies to walking, with particularly high proportion for women in all age groups.
MEN
100%
90%
80%

BicycleWalk

Motorcycle

3
20

23

Car

Bus

9

Rail

other
6

Modal share

70%
60%
50%
40%

64
65

57

51

30%
20%
10%
0%

8

14

11

11

8

5-14

15-64

65-74
Age
Source: 2015 Nationwide Person Trip Survey
Figure 9. Modal share among men by age group.

－29－

19
12
75-

WOMEN100%
90%80%
Modal share70%

Bicycle
4
1
21

Bus

Rail

other

6
4

9
7

51

39

3

66

30%
20%
0%

17

Car

50

50%

10%

Motorcycle

0

60%
40%

Walk

8

2

2

1
14

20

31

15

16

12

5-14

15-64
65-74
Age
Source: 2015 Nationwide Person Trip Survey

75-

Figure 10. Modal share among women by age group.
Interestingly, ‘the Japanese transportation system is the high number of multimodal bicyclepublic transit trips, particularly in large urban centers’ (Andrade et al., 2011). A similar
pattern is observed for walking: Mitsui et al. (2009) state the relationship between higher
levels of pedestrian activities in urban areas and the existence of well-organized public
transportation systems. Other factors include the inconvenience of owning a private car inlarge cities due to parking shortages and high cost of car maintenance (Mitsui et al., 2009).
It is important to emphasize, that the high levels of cycling and walking are achieved
simultaneously with provision of ‘highly efficient’ and accessible public transport network(rail and subway in particular) (Andrade et al., 2011). In fact, it can be speculated that active
travel modes and public transport in Japan complement each other. However, there is also a
direct association with longer distances to public transport stations (Andrade and Kagaya,2012).
Andrade and Kagaya (2012) identified the socio-demographic characteristics associatedwith the choice to cycle. It was found out that in Japan people living in single-personhouseholds are more likely to choose non-motorized modes of travel. Moreover, people who
cycle for other purposes and those who exercise on a regular basis are more likely tocommute by bicycle. Simultanously, there is no link with car ownership and the decision tocycle (Andrade and Kagaya, 2012). However, it is important to emphasize that this applies to
Sapporo and differences are prominent between major cities, smaller urban areas and rural
areas.
People choose to rely on bicycles for multiple reasons (Figure 11), including the most often
quoted: efficiency (shorter travel time), exercise, financial savings and practicality (ability tostop by on the way).

－30－

Figure 11. Reasons for using a bicycle (MLIT).
2.2 Transport Policy in Japan
In the past, transport policy in Japan focused primarily on road development (MLIT, 2015).
In more recent years, the main challenges policy-makers have been facing include ‘theprevention of global warming, preservation of natural resources and energy, social andeconomic impacts of a dwindling birth rate, changes in population demographics (aging andshrinking population), development of a safe and comfortable transportation system,
streamlining and globalization of physical distribution, expanding inter-regional gap between
outlying regions and urban centers and funding issues concerning road maintenance andimprovements’ (Japan Research Center for Transport Policy, 2015). Hence, there has been asignificant shift towards more environmentally-friendly approach (Kanemoto, 2002).
The Ministry of Land, Infrastructure and Transport (MLIT) is the key government
department at the national level in Japan responsible for transport (Enoch and Nakamura,2008). Some of the key policies include (International Transport Forum Summit, 2012) :- Compact city development using public transport- Construction of high-speed railways- Ensuring transportation to/from remote island- Expanding ITS (Intelligent Transport System)- Improvement of cycling environment- Improving railway stations as transport hubs
- Developing railway-station-based community rental cycle system in urban area
- Expanding smart interchange- Developing highway bus and rail ride in Tokyo- Improving bus punctuality- Publication of low carbon city development guidance- Road development and improvement of access roads to airports and harbours－31－

In general, transport problems tend to be approach holistically, making transport policies
the key driver for change. The primary focus is ‘on law enforcement and education options,rather than on auto-based engineered solutions like air bags’ (Hayakawa et al., 1999).
Even though cycling is very popular in Japan, there are only a ‘few Japanese transportation
policies and strategies address cycling’(Andrade and Kagaya,, 2012). There is no transportwalking policy. The policy which significantly affects the pedestrians is the ‘barrier-freepolicy’, which is one of the general principles of universal design policy (MLIT, 2005). It
focuses on achieving barrier free conditions in order to make public transportation systems
more accessible.
2.3 Traffic Law in Japan
Traffic law in Japan is defined by the Road Traffic Act which was enacted in 1960. It is adocument which aims at ‘preventing dangers on the road, promoting the safety of other traffic
and its smooth flow, and contributing to the prevention of obstacles due to road traffic’ (Saito
et al.). In the context, where shared use space (between all road users) is such a common
occurrence, traffic law becomes the key to creating a safe street environment.
The pedestrians (which also includes wheelchair users) are expected to use sidewalks orpedestrian lanes when available. If they are not, they should use the right hand side of theroad. Other rules include: never running out into the road, not skipping/running when walking
on the road, crossing at junctions with traffic lights or pedestrian crossings, using pedestrian
bridges or underpasses where available, following traffic lights and always check for safety,
not cross where it is forbidden and never crossing the road diagonally or without checking. In
bad weather and at night, pedestrians are advised to wear bright clothing to increase visibility.
However, this is not regulated by law.
There are also additional rules for using railway crossings (which are common). Pedestrians
are obliged: to always stop in front of the crossing and ensure it is safe to cross, be aware andcareful at all times, not cross when the warning bell sounds or the barrier begins to descend
and not play on or nearby the tracks. Moreover, children are required to cross under
supervision (Gifu Prefectural Police Headquarters, 2007).
In terms of cycling, Japanese law is more complex. It regards bicycles as light vehicles(Road Traffic Act; Article 17 Clause 1)’ (Suzuki and Nakamura, 2017) ‘and cyclists have to
use roads along with normal motor vehicles according to the Road Traffic Law’ (Yamanaka
and Namerikawa, 2007). However, while ‘cyclists are required to ride on vehicle roads, but
may also ride on sidewalks for safety reasons [JFS, 2008]’ (Andrade et al., 2011).
A bicycle is allowed to run on a sidewalk as an exceptional rule for safety reasons, in orderto protect cyclists from fatal traffic accidents (Andrade et al., 2011), (Suzuki et al., 2012): ‘theRoad Traffic Act allowed people to bicycle on sidewalks legally in December, 1978’. Thislaw was introduced as a response to an increasing number of bicycle fatalities observed in the
1960s and an increasing trend of people cycling on sidewalks illegally for their own safety.
‘At the peak around 1960, there were approximately 1,800 deaths every year for a period of
more than 10 years. This was equivalent to a little less than 20% of all fatalities by traffic
accidents at that time’. Initially, it was tested as an experimental solution in Yokohama andKawasaki cities in June, 1970 and proved successful in reducing fatalities (Suzuki andNakamura, 2017). However, it is essential to emphasize that when this law was firstestablished, the intention was to introduce a network of bikeways, which is yet to happen, due
to challenges such as space restrictions. (Suzuki and Nakamura, 2017).
Currently, the Road Traffic Act identifies three cycling facilities: roadways, bikeways, andsidewalks. First, “people must operate a vehicle on a roadway when it is separated from asidewalk or a side strip (Road Traffic Act; Article 17)”. Because a bicycle is a type of vehicle,
people must bicycle on the roadway. Second, “when a bikeway is developed, people mustride a bicycle or a tricycle on it (Road Traffic Act; Article 63 Clause 3, there is an exception)”.
And third, “A person can bicycle on a sidewalk when it is permitted legally (Road Traffic
Act; Article 63 Clause)” (Suzuki and Nakamura, 2017). The rules regarding that have beenreviewed and updated in 2008: ‘permitted legally’ now stands for ‘within and area with roadsigns or other signposts indicating permission to do so’, ‘if the rider is under 13 years old’ and－32－‘in unavoidable circumstances due to roadway of traffic conditions’ (Japan International
Training Cooperation)
Yet, in practice, most cyclists take on different ways depending on the traffic quantity(Tokuyasu et al., 2015) making cycling on sidewalks is a common practice. According toresearch conducted in Tokyo in 2003 ‘there are more people that believe they must bicycle on
sidewalks as the general rule (45%) than people that know the rule (27%). Moreover, whilepedestrians should be given priority, ‘in reality people often honk to get pedestrians out of theway.’ (Suzuki and Nakamura, 2017). Tokuyasu et al. confirmed the issue with following thelaw stating that in practice ‘most of cyclists take on different ways depending on the traffic
quantity’ (Tokuyasu et al., 2015).
Furthermore, there is also a traffic law, which refers to how a bicycle can cross anintersection. Once again, this was introduced after identifying that ‘the majority of bicycle
traffic accidents occur at intersections between turning automobiles and bicycles fromsidewalks’ (Hirotaka and Koike, 2014). The cyclists are not obliged to follow pedestrian signs,
but are free to cycle along the car traffic. Another innovative policy was designed to reduce
bicycle theft: the ‘bicycles must be registered with local authorities, with the licence fee
included in the sale price’ (Enoch and Nakamura, 2008).
Considering the challenges (see Section 2.7) Japanese government continues to review theexisting law. In the last few years the road traffic law has been tightened up, including
strengthening criminal punishments. These include:
Table 1. Traffic Rules and Penalties.
Traffic Rules
Penalty
Riding a bicycle on a right side of the road
Imprisonment for up to three months or a fineof up to 50,000 yen
Riding on a sidewalk when circumstances are Imprisonment for up to three months or a finenot ‘exceptional’of up to 50,000 yen
Not yielding to pedestrians and/or cycling
A fine of up to 20,000 yen or pecuniary
slowly on a sidewalk
penalty
Cycling under influence of alcohol
Imprisonment of up to five years or a fine of
up to one million yen
Riding double on a bicycle (except with aA fine of up to 20,000 yen or pecuniary
child under 6 years old)penalty
Cycling side by side
A fine of up to 20,000 yen or pecuniary
penalty
Cycling without lights (headlights and rear
A fine of up to 50,000 yen
lights or reflectors) during evening hours
Not obeying traffic lights
Imprisonment for up to three months or a fineof up to 50,000 yen
Not stopping and checking for safety at an
Imprisonment for up to three months or a fineintersectionof up to 50,000 yen－33－Other safety measures include children under 13 to be instructed by their guardians to wear
helmets, cyclists should not use their mobile phones or umbrellas while cycling.
(https://www.jitco.or.jp/download/data/leaflet_English.pdf)
Figure 12 identifies all signs for cyclists and pedestrians:

Figure 12. Signs for Pedestrians and Cyclists (National Police Agency).

－34－

2.4 Traffic Education
In Japan, the primary safety concern is fatalities and injuries suffered by children and young
people (aged 24 or less). Therefore, traffic safety education and awareness activities play a
crucial role in delivering a safer transport network.
The implementation system is based on the concept of 3Es of traffic safety: ‘Engineering (inthe form of traffic management and traffic engineering techniques), Enforcement (of the law)and Education, focusing on people, who constitute one of the causal factors in traffic
accidents’ (Nishiuchi, 2014).
Table 2. E of Safety and Measures (Nishiuchi, 2014).
E of Traffic Safety
Measures
The installation of traffic safety facilities (these consist ofEngineering
facilities put in place by public safety commissions (thepolice), including traffic lights, regulatory signs, roadmarkings, and traffic control centers; and facilities put in placeby road managers, such as footbridges, sidewalks, warning
signs, carriageway markings, guard rails, street lights,
delineators, and traffic safety mirrors)
Enforcement of the law (traffic control and enforcement),
Enforcement
education (through promoting and maintaining appropriate
behaviour and attitudes to traffic)
Traffic safety classes at elementary, junior high, and highEducationschools and traffic safety events (organized by prefectural
governments, municipalities, and prefectural police forces).
Educating professionals involved in promoting traffic safety
education activities; producing teaching materials (manuals
compiled by the national government, prefectural government,or municipality)
2.5 Factors Affecting Levels of Walking
Referring to Muraleetharan and Hagiwara (2002) factors that affect the walking behavioursof pedestrians include the distance to their destination, the personal attributes of thepedestrian, the trip purpose, familiarity with the route, the presence of recreational points ofinterest, and environmental conditions (Muraleetharan and Hagiwara, 2002). Interestingly, inJapan, there is no significant association between perception of crime safety and walking. The
reason for that could be potentially small variations in perceptions of safety among theJapanese: Japan is generally regarded as safe (Inoue et al., 2010).
Further study investigating the associations between perceived neighbourhood environment
and walking among adults was conducted. ‘Among Japanese adults, living in walkablecommunities, as defined by high residential density, good land use mix, and good street
connectivity, is an important factor in walking for transport’. On the other hand, walking
facilities (eg, sidewalks), aesthetics, and traffic safety are important factors in walking for
leisure. For women, there is a significant association between walking to work and theenvironment. The reasons suggested are that potentially ‘women are more likely to workwithin walking distance’. Similar was observed for walking for other purposes (daily errands),
which can be explained by women’s role in managing households (Inoue et al., 2010).
Moreover, in Japan, the levels of walking are significantly affected by the relatively highproportion of elderly adults. This age group tends to have different lifestyle (for example theyno longer commute to work, have reduced childcare obligations) and a lower level of fitness
compared to younger age groups. The research was conducted which looked into the factors
correlated to transportation walking among the elderly. Two environmental attributes wereidentified: social environment and aesthetics. ‘In addition, bicycle lanes, access to exercise
facilities, and household motor vehicles were significantly associated with transportation－35－

walking… Among men, significant correlates of this type of walking were bicycle lanes,
crime safety, traffic safety, aesthetics, and household motor vehicles. Among women, accessto shops, access to exercise facilities, and social environment were related to this type ofwalking.’. Interestingly, the neighbourhood environmental characteristics that were proventhe be associated with levels of transportation walking previously (residential density, accessto public transport) did not show any association for elderly adults. ‘These results indicatethat transportation walking among elderly adults might have similar characteristics torecreational walking.’ (Inoue et al., 2011).
2.6 Promoting Cycling in Japan
In the recent years Japan has been experiencing a rapid increase of bicycle users. This
primarily due to changing lifestyles: people are becoming more environmentally and/or healthconscious. Bicycle is no longer seen just a supporting transportation tool (Suzuki et al., 2012).
It has also been affected by the Great East Japan Earthquake in 2011: in terms of urban
mobility, that was a turning point. The natural disaster and urgent need to rebuilt ‘hasprovided the opportunity for a paradigm shift away from the conventional automobiledependent society toward a new mobility society, a movement to switch from automobiles topublic transportation and bicycles’. (Hirotaka and Koike, 2014).
Even though, levels of cycling in Japan are high, there are still ongoing efforts to promote iteven further. These include:- Establishing 98 ’Bicycle Road Model Districs’ by MLIT and NPA in 2007to‘promote the development of bicycle roads, bicycle lanes, and sidewalks shared bycyclists and pedestrians’ (MLIT)- Introducing cycle hire schemes. They have been increasing in popularity since 1990s,
after the successful implementation in the cities of Toyama (Toyama Prefecture),
Kitakyushu (Aichi Prefecture), Saitama (Saitama Prefecture) and Fujisawa(Kanagawa Prefecture). (Andrade et al., 2011). By October 2016, there have been
100 cities with public bicycle systems (Suzuki and Nakamura, 2017). The purpose of
installing the public bicycles is the improvement of the transport network, connectedwith public transport stations (questionnaire survey by MLIT in 2016, shown in
Figure 8.). However, the number of ports available still remains low compared toother countries (Suzuki and Nakamura, 2017).
- Public and private companies (such as Nagoya city office) ‘have been encouraging its
employees to commute by bicycle, by for example increasing bicycle commuting
allowances [JSF, 2010]’. This practice is not common yet. (Andrade et al., 2011)- Cities are adopting local plans to promote cycling further. For example, Utsunomiya
City introduced the Basic Plan to Utilize Bicycles in 2003. The measures pursued
include: the formation of a citywide bicycle route network, provision of bicycle
parking facilities near railway stations and bus stops and short-term parking spots andintroduction of community rental cycle system. In 2010 it introduced Utsunomiya
Bicycle City Promotion Plan, which vowed to continue these measures and also
support the promotion of environment, health, sports, and tourism through cycling(Hirotaka and Koike, 2014). However, in many cases Japanese ‘urban transportationplans often treat bicycle and walking as a single mode, despite the numerous bicycle
users [Hyodo et al., 2000]’. (Andrade et al., 2011)- Introducing measures to promote safer cycling: for example an active campaign has
been taking place to promote the use of helmets among senior cyclists. Tochigi Truck
Association has donated 1000 bike helmets to be donated to the elderly free ofcharge( Hirotaka and Koike, 2014).
- Collaborations between cities and the Regional Offices of the Ministry of Land,
Infrastructure, Transport and Tourism. This allows to introduce new, experimental
solutions, for example blue arrow-shaped pavement markings to guide bicycles,
introduced on the National Highway No.4 in Utsunomiya (Hirotaka and Koike, 2014).

－36－

Monitoring: the majority of new measures introduced are monitored in order tomeasure their effectiveness. These include some of the measures listed above. The
desired outcomes include increase in cycling and reduction in accidents.
Moreover, surveys have been conducted which suggest that cycling in Japan could bepromoted further through ‘implementing exclusive cycle routes, along with improving
existing cycle lanes and increasing the number of free bicycle parking lots, would contributeto more cycle-friendly journeys’ (Andrade and Kagaya, 2012).
-

2.7 Challenges of Cycling and Shared-Space
The presence of high levels cycling and omni-present shared space result in a variety ofissues. In the recent years the situation has been gradually getting worse to the point that
‘violations of traffic rules and etiquette by users of bicycles and other familiar modes oftransport’ have been identified as a social problem. (Nishiuchi, IATSS). Some of the mostprominent challenges include:• Safety issues (Section 1.8)
• ‘Illegal parking around stations and shopping malls: this contributes to increasing
traffic congestion and the number of accidents in surrounding areas.
• High numbers of abandoned bicycles within urban areas. This is caused by the factthat in Japan, the costs of fixing a bicycle are high compared to purchasing a new one.
(Andrade et al., 2011)
However, Japanese national and local governments appear to efficiently identify theseissues and effectively respond to them through introduction of policies and regulations.
(Andrade et al., 2011) (Hirotaka and Koike, 2014).
2.8 Safety (Statistics and Perceptions)
The accident statistics with cyclists and pedestrians involved remain very high. ‘At present,
the number of cyclists has been increasing all over the world, and the collision accidents
which rested in cyclists has been recognized as one of social issues in Japan’ (Tokuyasu et al.,2015). The causes of collisions include ‘by the faults and/or the bad manner of a cyclist, suchas ignoring a traffic light, operating a smartphone, and over speed etc.’ (Tokuyasu et al.,2015).
While ‘one possible reason for the differences in risk environments is the poor separation
between cars and other traffic users in Japan. Approximately 75% of Japan is mountainous,
making its population density extremely high. Because most roads in Japan go throughheavily populated urban areas, isolating pedestrians and bicyclists from motor vehicles is very
difficult’ (Koshi, 1988).
Referring to Hayakawa et al., ‘despite this increased exposure, Japanese accidents tend to
be less lethal’. The potential reason is that, traffic congestion leads to lower speeds ofvehicles (Hayakawa et al., 1999). In fact, despite high figures, Japan has been observing a
steady decrease in road fatalities since 1990 (International Transport Forum, 2016). Table 3
shows the trend.
Table 3. Road Fatalities By Road User Group.

－37－Despite, relatively high number of accidents, cycling is regarded as safe in Japan, primarily
because cyclists ‘ride on sidewalks rather than share roadways with motorized vehicles’(Andrade and Kagaya, 2012). This perception of safety ‘plays an important role in thedecision to cycle (by travelers in Sapporo)’ (Andrade and Kagaya, 2012).
Yet, Suzuki and Nakamura (2017) argue that cycling on a sidewalk is unsafe, despite thecommon perception otherwise. In fact, the statistics report an increase in accidents between
cyclists and pedestrians. Based on that they draw a conclusion that ‘it seems that the Japanesesituation, cycling on sidewalks is safer than the other countries where people bicycle on
roadway, but as you can see the reverse is true. Because of them, we can say that bicycling on
sidewalks is not always safe’ (Suzuki and Nakamura, 2017). Figure 13 shows that while thetotal number of traffic accidents decreased by 30% between 2002 and 2012, the bicyclepedestrian accidents have increased by 30%.

Figure 13. Total traffic accidents versus bicycle-pedestrians accidents (MLIT).
2.9 Design Guidelines
Japan has published a number of design guidelines for pedestrian and cycling facilities.
For walking, the technical guideline to design a pedestrian space has been enacted in thelaw of Road Construction Ordinance, with the focus on pedestrian safety. It specifies thewidth of lane for pedestrians and/or cyclists with a requirement of over three meters. It isbelieved that this dimension will reduce the rate of collisions in pedestrian space (Tokuyasu etal., 2015).
In November 2012, the Road Bureau of the Ministry of Land, Infrastructure, Transport andTourism and Traffic Bureau of the National Police Agency issued the ‘Bicycle Usage
Environment Creation Guidelines for Comfort and Safety’. The document adapted the core ofRoad Traffic Law that ‘a bicycle is a vehicle, which in principle, travels on vehicle road’: ittherefore, focused on comfortable and safe provision of road space for cyclists, hence
promoting segregation between cyclists and pedestrians. Figure 14 shows the proposed types
of facilities, depending on the road conditions (Kobayashi et al.).
Another official document is “Guideline for developing bicycle parking facilities”
published by MLIT, which puts a lot of emphasis on promotion and development of public
bicycle systems. Cycle hire schemes are seen as a potential solution to illegal bicycle parking
and a way to save parking lots and a measure of improving the transport network throughpromoting multi-modal trips (bicycle parking at the stations) (Suzuki and Nakamura, 2017).

－38－

Figure 14. Types of Facilities: Different Levels of Segregation and How to Choose a form of
improvement according to traffic conditions.
2.10
Shared-use Paths
Referring to the Japanese traffic law (Section 2.3) sharing space is allowed in certain
circumstances. In reality, mixed-use is very common. Figure 15 shows the types of
unsegregated and segregated facilities and a total length of provision in Japan.

Figure 15. Segregated and Unsegregated Paths: Types and Total Lengths (MLIT)－39－

Zhe et al. has pointed out the disadvantages and advantages of shared-use paths in Japanesecontext. He points out how cycle/pedestrian shared use negatively affects safety ofpedestrians and enforces the reduction of cyclists speed. However, on the other hand, hementions the association between shared-use and high levels of cycling in Japan for variety of
purposes and among women and elderly, emphasizing the advantage of safety and freedom
for utility cyclists (Zhe et al., 2008). This fits into what some other researchers claim, statingthat ‘the possibility of sharing side- walk space with pedestrians appears to have a strong
positive impact on cycling’ (Andrade and Kagaya, 2012).
Yet, in the recent years, there has been a tendency to encourage segregation as a more
viable option. Currently, most cities still lack extensive cycling networks (infrastructure).
Cycling facilities are primarily parking and designated zones within road intersections(Andrade et al., 2011). Due to high levels of cycling, and consequently, safety concerns, ‘in2008, the Ministry of Land, Infrastructure, Transport and Tourism of Japan [MLIT] haslaunched a plan to establish an extensive bicycle lane network nationwide’ (Andrade et al.,
2011)
Interestingly, Misui (2012) pointed out that the plan to introduce a cycling network might
become more achievable with time. He suggested that the social demand for improved
cycling traffic space will continue. Meanwhile, the demand for automobile traffic is expected
to decline due to population decline. ‘Future maintenance of excess road capacity may
produce excessive burden on the future generations and reallocation of the road space fromautomobile traffic space to bicycle traffic space is the pressing issue’ (Misui, 2012).
2.11
Level of Service
Highway Capacity Manual defines Level of Service as ‘a quality measure describing
operational conditions within a traffic stream, generally in terms of such service measures as
speed and travel time, freedom to maneuver, traffic interruptions, and comfort andconvenience’ (Highway Capacity Manual, 2010). It identifies six levels, from A to F: A
represents the best operating conditions and F the worst. HCM considers a diversity oftransport modes, including walking and cycling, however it is applicable primarily to
American roads which represent significantly different conditions than Japan or Europe.
Hence, considering the high levels of walking and cycling in Japan, multiple studies wereconducted in attempt to define the level of service. Research has been conducted, which
confirmed that ‘in order to promote cycle use in urban areas, improvement level of service forcycling on streets is considered to be an integral part of (…) policy’ (Yamanaka andNamerikawa, 2007). Tsukaguchi et al. have also emphasized the importance of level ofservice for promoting walking stating that ‘regional environment, amount and level of serviceof urban amenities and attributes of the residents form main elements that contribute toward
the attitudes toward walking and pedestrian behaviour in general’ (Tsukaguchi et al., 2007).
Zhe et al. have completed a study which evaluated the level of service of shared use paths,
focusing on users’ safety and comfort with consideration for traffic volume on the path. By
using a video survey of shared use streets, the authors analysed the relationship between
cycling speed, frequency of hindrance and traffic density or traffic volume of street users. In
conclusion, the author proposed the conditions necessary to apply shared use of bicycles andpedestrians on the sidewalks, considering the traffic flow of pedestrians and bicycles per
width of sidewalks’ (Zhe et al., 2008).
In Japan, level of service can play particularly important role in promoting active travel.
While people would usually choose the shortest route to get to their destination, some cities inJapan (for example Sapporo) are designed on a grid. Considering that the distance no longer
plays a significant role, it was proved that the probability that a route will be selected
increases as the average overall LOS of that route increases. The research was conducted forwalking. It was proven that the likelihood that a route will be selected decreases withincreases in the length of the route. The results suggest that when pedestrians choose routes,
they consider the overall LOS in combination with the lengths of sidewalks and crosswalks(Muraleetharan and Hagiwara, 2002).

－40－

2.12
Perception of Comfort
The concept of comfort appears in multiple guidelines and studies conducted in Japan.
The study on improvement of comfort of road space looked closer at the perceptions ofpedestrians, cyclists, other road users and roadside residents. It identified the importance ofbarrier-free pedestrian space, autonomous mobile support and improvement of comfort forliving roads. It also suggested the diversification of needs among the road users leading toroad space reconstruction. Interestingly, it emphasized that to create road environment that ispeople-centred the comfort is the key. This was followed by looking at specific situation in
Japan: with aging population the perception of comfort and needs are changing.(NILIM,
2006).
For cycling, in 2012, the Ministry of Land, Infrastructure, Transport and Tourism (MLITT)
and the National Police Agency published an official guideline for development of safe andcomfortable cycle facilities. It was revised in 2016. This document covers ‘the planning ofbicycle traffic space, design of bicycle traffic space, enforcement of bicycle traffic rules, andcomprehensive action to promote bicycle usage’ (Hirotaka and Koike, 2014).
The document identifies three types of bicycle facilities: “bicycle path” (two-way bicycle
tracks on the both sides of a road), “bicycle lane” (a one-way bicycle lane on the left side of aroadway), and “local discretionary lanes or pictographs” (a sign for clarifying cycling space
on a roadway). This guideline also further emphasizes the need for segregation, by
mentioning the planning process of a bicycle network (Suzuki and Nakamara, 2017).
The research into pedestrian comfort also evolves around segregation. Referring to
Yamanaka and Namerikawa (2017) the key to increasing the comfort of pedestrians lies in
improving the pedestrian and cycling facilities (for example sidewalks). The measures include‘separation of pedestrians and cyclists, removal of on- street bicycle parking and barriers on
sidewalks’ and ‘making priority system appropriate in traffic rules for bicycles on urban
streets and of junctions.’ (Yamanaka and Namerikawa, 2007).
3. Discussion
Cycling and walking are very popular modes of travel in Japan: they constitute as the
majority modes for trips up to 3km, and cycling makes up a significant proportion of trips up
to 6km. ‘The Japanese transportation system is the high number of multimodal bicycle-public
transit trips, particularly in large urban centers’ (Andrade et al., 2011). A similar pattern isobserved for walking.
Traffic law is defined by the Road Traffic Act. The pedestrians (which also includes
wheelchair users) are expected to use sidewalks or pedestrian lanes when available. If they
are not, they should use the right hand side of the road. A bicycle is allowed to run on asidewalk as an exceptional rule for safety reasons, in order to protect cyclists from fatal traffic
accidents (Andrade et al., 2011), (Suzuki et al., 2012): ‘the Road Traffic Act allowed people
to bicycle on sidewalks legally in December, 1978’. Yet, in practice, most cyclists take on
different ways depending on the traffic quantity (Tokuyasu et al., 2015) making cycling on
sidewalks is a common practice and unsegregated shared-use omni-present.
The negatives of shared-use include the affect on safety of pedestrians and enforcing the
reduction of cyclists speed. In fact, in the recent years the ‘violations of traffic rules andetiquette by users of bicycles’ have been identified as a social problem. (Nishiuchi, IATSS).
The accident statistics with cyclists and pedestrians involved remain very high.
However, there is also an association between shared-use and high levels of cycling inJapan for variety of purposes and among women and elderly, emphasizing the advantage ofsafety and freedom for utility cyclists (Zhe et al., 2008).
Interestingly, Japan has managed to achieve the targets set by the UK for the future: highcycling modal share especially for short distance trips, domination of multi-modal trips withcycling and walking stages, high numbers of women and the elderly walking and cycling on
regular basis. This has been done without many design guidelines, but with the focus on
education and by ensuring people feel safe (through allowing cycling on sidewalks).
Hence, while in Japan, in the recent years, there has been a tendency to encourage
segregation as a more viable option, further research is needed to understand if promoting
shared-use could be the key first-step to promoting cycling and walking in the UK.

－41－

4. Acknowledgement
This literature review was a part of the 3-month academic fellowship awarded by Japan
Society of Promotion of Science to Pola Berent.
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Abstracts of Papers
Published in Other Journals

Mechanical and Physical Engineering
Static Analysis of Single/Double Effect Combined Absorption Solar Cooling System
Hiroyuki NAKAGAWA, Ryota SATO, Nobuya NISHIMURA and Kazutaka TERAO
Proc. of the International Sorption Heat Pump Conference 2017, ID:AB-SY3-1155, Tokyo, JAPAN, (2017.8)(on USB).
Solar-assisted absorption chiller-heater can be driven with renewable solar energy. This system can reduceamount of city gas consumption which needed to operate the absorption machine. But, it has not been clear
quantitatively how much impact on the system performance by using solar energy. In this paper, to identify thissystem’s characteristics and to examine the effectiveness of solar energy, static simulation model of solarassisted absorption chiller-heater was constructed and simulation results were compared with experimental
results.
A Novel Production Method for Foundry Cores by Molding Polysaccharide-Coated Sand Using
Superheated Steam and Air
Hiroyuki IYOYA, Isamu IDE, Shinji NISHIDA, Toshinari Nishimura, Katsuhiro OGURA and Kyosuke
MOTOYAMA
Proceedings of 2nd Nordic Baltic Drying Conference (NBDC 2017), (9 pages on USB Memory) (June 2017,
Hamburg, Germany)
Foundry cores are used to create pores inside a foundry, and are usually produced by shell molding, i.e., molding
in a heated die. However, foundry cores tend to worsen working conditions because decomposed bindermaterials are released during molding and casting of high-temperature melted metal. To solve this problem, anovel environmentally friendly and highly productive method for producing foundry cores is developed. Thismethod uses sand coated with polysaccharides made using starch as a naturally occurring binder and superheatedsteam as both the humidifying and drying media. In this study, we construct a laboratory-scale apparatus with atemperature-controlled cylindrical die for performing basic experimental studies on the molding process. The
experimental molding results show the effects of the initial die and sand temperatures and the mixture ratio ofsuperheated steam and air on process and product quality.
Development of Two New Types of Retroreflective Materials as Countermeasures to Urban Heat Islands
Hideki SAKAI and Hiroyuki IYOTA
Int. J. Thermophys, (2017) 38:131 (10 pages) (Published online 11 July 2017)
In this study, the side effects of high-reflective and ordinary retroreflective materials, used as countermeasures tourban heat islands, are discussed. In addition, two retroreflective materials are proposed in order to avoid theseadverse effects. These materials could be applied to roads and building exteriors to reduce their heat absorption
from solar radiation. The first proposed type is the directional retroreflective material, which reflects light only
during summer; therefore, it reduces the cooling load in summer, reduces the heating load in winter, andprevents light pollution at night. However, its structure is complicated and fragile; thus, it is suited for small
areas, such as roofs and walls. The second type is the rough-surface retroreflective material, which shows weak
retroreflectivity but can withstand distortion; thus, it is suited for roads. These two types require little
maintenance, because they have no moving parts. Hence, these materials would not experience any breakdown,
which is a great advantage for roads and building materials. Combining high-reflective, ordinary retroreflective,
directional retroreflective, and rough-surface retroreflective materials, and assigning each type to the appropriate
application would form an advanced mitigation system against urban heat islands.
Development of Measuring Device for Thermal Environment in an Oven for Food Processing
Kazuma KODAMA, Taro OZAKI, Akihiro MORIKAWA, Hiroyuki IYOTA and Tetsuo TSUJIOKA－47－

Trans. of the Society of Instrument and Control Engineers, 52(12), pp.707-712 (2016)
Several types of ovens have been widely used for food processing and cooking. In this process, foods in an ovenare heated by combination of heat transfers such as convection, conduction and thermal radiation. The quality offood products are affected by these heating conditions. In food factories, temperature inside the oven and baking
time are adjusted by empirical human operations based on measured temperatures only at fixed-point. Therefore,
it can be effective to measure the thermal environment where the food actually placed/moved in the process inreal time. We have developed an electronic circuit board and a measuring device having wireless data
communication function to measure the thermal environment parameters of temperature, humidity, wind speed,radiation contribution rate, vibration of the food inside the oven. We have performed the practical experimentwith a reel oven working at food industry over 175°C for 1800s. The results show that the thermal environment
nearby the food in the oven can be measured and temperature profiles also can be traced.
Effect of the Surface Texture Treatment (Wavy Plate) on the Liquid Film Flow on a Plate of Packings
Yoshiaki ISO (IHI Corp.), Ryosuke IKEDA (IHI Corp.), Mitsutoshi YAMAMOTO (IHI Corp.), Kenji KATOH
and Tatsuro WAKIMOTO
Japanese Journal of Multiphase Flow, Vol. 30, No. 5, pp. 475-482 (2017) (in Japanese)
Gas liquid interfacial flows, such as liquid film flow (also known as wetting flows on plates), are encountered inmany industrial processes including absorption, distillation and so on. The present study focuses on detailed
descriptions of the transition phenomena between the film flow and the rivulet flow, as well as how suchphenomena are affected by surface texture treatments on plates. This study uses a numerical simulation ofComputational Fluid Dynamics (CFD) with the volume of Fluid (VOF) model as well as an experimental
measurement technique. Through the comparison of two geometry cases (smooth surface and wavy surface)which are the models simplified from typical structured packings, the numerical and experimental results showthat surface texture treatments can help to prevent the liquid channeling and can increase the wetted area. The
main reason for increasing the wetted area on the wavy surface is that the liquid film break up is inhibited due tothe increasing of liquid film thickness on the plate as well as the spreading of the liquid flow in spanwise
direction by the wavy surface geometry.
Influence of a Side Walls on Dryout of Falling Liquid Film Flowing Down on a Plate
Kenji KATOH, Changing XU, Yoshiaki ISO (IHI Corp.), Ryosuke IKEDA (IHI Corp.) and Tatsuro
WAKIMOTO
Japanese Journal of Multiphase Flow, Vol. 31, No. 2, pp. 171-178 (2017) (in Japanese)A theoretical and experimental study was conducted to investigate the influence of side wall on the dryout of
liquid film flowing on an inclined plate. The film surface forms a meniscus having a minimum thickness near theside wall. The thin film causes the decline of dynamic pressure of flow and the dryout may happen at higher
flow rate. In this study, the meniscus profile near the side wall was theoretically analyzed from the energy
minimum principle under the condition of force balance between gravitational and viscous force. Here we
considered the system energy contributed from the work related to wetting behavior, the work resulted from theincrease of gas-liquid interfacial area, the kinematic energy of film flow, as well as the liquid potential energy.
The calculated results of meniscus radius and minimum film thickness roughly agree with the results ofexperimental measurement and CFD.
Effect of Wettability on Dynamics of a Rotating Cylinder When Plunging into Water
Tatsuro WAKIMOTO, Yoshiaki UEDA (Setsunan Univ.), Kenji KATOH and Manabu IGUCHI
Advanced Experimental Mechanics, Vol. 2, pp. 59-64 (2017)
To investigate the dynamics of the object plunging into water, the sequential images of water entry of rotatinghydrophilic and hydrophobic cylinders were captured with high speed cameras, and the underwater trajectoriesof the cylinders were measured at various impact angles, velocities, and rotational rates. The captured images－48－

reveal that the hydrophobic cylinder splashes sheet-shaped water and turns to the left opposite to pre-impact
moving direction while the hydrophilic cylinder continues moving in the right direction without the splash. The
hydrophobic cylinder commonly produces a fully developed air cavity behind, although the hydrophilic one
generates it only at the impact velocity higher than a critical value. The hydrophilic cylinder with the highimpact velocity turns more rightward, and the fast rotation of the cylinder changes the trajectory leftward
regardless of wettability. From the captured images and the estimated force by trajectory analysis, it can be
deduced that the changes of the trajectory are due to the reaction force of the splash, additional hydrostatic force
induced by the cavity, and lift force by Magnus effect.
Measurement of Dynamic Surface Tension for Liquid Metal by Capillary Jet Method
Tatsuro WAKIMOTO, Kenji KATOH, Yoshiaki UEDA (Setsunan Univ.) and Manabu IGUCHIInternational Journal of Heat and Fluid Flow, Vol. 66, pp. 243-248 (2017)
Most liquid metals are easily oxidized, causing their surface tensions to vary over time. In this study, a novel
method for measuring dynamic surface tension during the oxidization of liquid metals is proposed. This method
is based on the phenomenon that the descent trajectory of a capillary jet ejected horizontally from a small orifice
at a slow speed depends on the surface tension as well as both the inertial and gravitational forces. We derived atheoretical model to predict the jet trajectory and determined the dynamic surface tension of the liquid metal by
matching the predicted theoretical trajectory with an experimentally measured one. Actual measurements for
Wood’s alloy at various oxygen concentrations demonstrated that the surface tension decreases to an equilibrium
value on a time scale of 10–11 ms at oxygen densities of less than 1.5%, whereas it increases for a time scale of
10–17 ms at greater oxygen densities. This method has ability to measure dynamic surface tension with timescale of 1.5 – 55 ms at accuracy of ±1.5 ms and the ability is suitable for measuring dynamic surface tension ofliquid metal in oxidation process.
Development of a 300 L Calibration Bath for Oceanographic Thermometers
S. BABA(JAMSTEC) ， K. YAMAZAWA(NITE) ， T. NAKANO(AIST) ， I. SAITO(AIST) ， J.
TAMBA(AIST)，T. WAKIMOTO and K. KATOH
International Journal of Thermophysics, Vol. 38, No. 11, Article 164 (2017)
The Japan Agency for Marine-Earth Science and Technology (JAMSTEC) has been developing a 300 L
calibration bath to calibrate 24 oceanographic thermometers (OT) simultaneously and thereby reduce thecalibration work load necessary to service more than 180 OT every year. This study investigated characteristicsof the developed 300 L calibration bath using a SBE 3plus thermometer produced by an OT manufacturer. We
also used 11 thermistor thermometers that were calibrated tobe traceable to the international temperature scale of1990 (ITS-90) within 1 mK of standard uncertainty through collaboration of JAMSTEC and NMIJ/AIST.
Results show that the time stability of temperature of the developed bath was within ±1 mK. Furthermore, thetemperature uniformity was ±1.3 mK. The expanded uncertainty (k = 2) components for the characteristics of thedeveloped 300 L calibration bath were estimated as 2.9 mK, which is much less than the value of 10 mK: therequired specication for uncertainty of calibration for the OT. These results demonstrated the utility of this 300
L calibration bath as a device for use with a new calibration system.
Control Method for Helicopters Cabled to Ground Station with Compensation of Disturbance Caused by
Cable Tension
Atsushi IMADU, Takanori SAKAI, Tadao KAWAI
Journal of Robotics and Mechatronics, 29(4), pp. 737-745(2017).
This paper suggests cable tension compensation control for helicopters cabled to the ground station. This method
can be applied to human operated system and reduces required control skill. In this method, cable tension vector
is measured by a force sensor and an angle sensor mounted on the helicopter. Thrust and helicopter attitude to－49－

balance with resultant force of the tension and the gravity force are calculated and added to control input by PID
control. Simulation and experimental result illustrate validity of the proposed method.
in vivo Tomographically Diagnosing Technique of Early Cancer using 2-Color Optical Coherence
Dosigraphy
Yu NAKAMICHI, Souichi SAEKI, Takafumi HIRO，Masunori MATSUZAKI
Journal of Biomechanical Science and Engineering, Vol. 12, No. 2, 16-00591, (2017)
The endoscopic optical coherence tomography (OCT) has been developed for early detection of digestive systemcancer. However, it is difficult to detect cancerous tissue due to complicated speckle patterns contributed by
optical properties of scattering and absorption in the morphological images of OCT. In our previous papers, 2color optical coherence dosigraphy (2C-OCD) was proposed, which quantified OCT signal as scattering andabsorption coefficients and could provide drug distribution at the micro-scale spatial resolution. In this study, an
in vivo tomo-graphically diagnosing technique of early cancer is presented, in which 2C-OCD is applied tocancerous tissue with selective uptake of photosensitizer. The feasibility study was demonstrated andinvestigated, based on 2C-OCD visualization of the subcutaneous tumor-implanted nude mice withphotosensitizer AlPcS administered. Consequently, it was confirmed that drug absorption coefficient obtained by
2C-OCD was correlated with fluorescence intensity from accumulated AlPcS (r = 0.918), comparing with their
histological images. Additionally, 2C-OCD could diagnose tumor tissue significantly with sensitivity of 82.5%
and specificity of 78.3%, respectively. Therefore, 2C-OCD can detect photosensitizer infiltration into cancerous
tissue, and thus has a promising modality for in vivo tomographically diagnosing technique of early cancer.
Micro-Tomographic Study on Viscoelastic Behavior of articular cartilage using Dynamic Optical
Coherence Straingraphy
Daisuke FURUKAWA, Souichi SAEKI, Ryohei NISHINO, Suguru MISHIMA
Journal of the Japanese Society for Experimental Mechanics, Vol. 17, No. 1, pp.52-56 (2017) (in Japanese)
Rheological behavior of interstitial fluid in epidermal tissue, including blood micro-circulation, can vary skinmechanics in micro scale, i.e. visco-elasticity. Therefore, an in vivo quantitative measurement of fluid velocity isnecessary to clarify their properties. In this paper, we constructed OCDV (Optical Coherence Doppler
Velocigraphy), which is a method of tomographic micro-visualizing interstitial fluid velocity using a highfrequency modulated low coherence interferometer. The tomographic detection of modulated Doppler frequency
can determine fluid velocity profile within tissue. An optimal signal processing of OCDV was evaluatedalternately on short time FFT and Hilbert transform, and validated by measuring the fluid velocity of Intralipid
solution (2%) in micro channel. Consequently, Hilbert transform has further advantages in the accuracy evenwith a rapid scanning system than short time FFT. OCDV was suggested to be effective to diagnose flow
velocity profiles in tissue non-invasively and tomographically.
Study on Micro-tomography of Temperature using FEM-based Inverse Analysis applied to Optical
Coherence Straingraphy
Souichi SAEKI, Daisuke FURUKAWA, Ryuki KUNIMOTO
The 19th International Conference on Electronics, Materials, and Packaging (EMAP), USB-memory, 2-5 (2017)
Electronic devices such as LSI have been being improved in terms of high efficiency and integration of micro
and power semiconductor elements. However, there remains serious problems associated with microscopic
fracture attributed to thermal strain, which arises with the increase of quantity and density of exothermic Joule
heating generated from heat sources and electric wires. Therefore, it is quite necessary to perform the optimum
thermal management and design, microscopically and non-destructively. Recently, Optical Coherence
Tomography (OCT) has been improved as a biomedical diagnostic modality. This can tomographically visualize
a spatial variation field of refractive index inside tissue, as a back-scattering intensity distribution at 1 to 10
micrometer resolution. Electronic devices such as LSI have been being improved in terms of high efficiency and－50－integration of micro and power semiconductor elements. However, there remains serious problems associatedwith microscopic fracture attributed to thermal strain, which arises with the increase of quantity and density of
exothermic Joule heating generated from heat sources and electric wires. Therefore, it is quite necessary to
perform the optimum thermal management and design, microscopically and non-destructively. Recently, Optical
Coherence Tomography (OCT) has been improved as a biomedical diagnostic modality. This cantomographically visualize a spatial variation field of refractive index inside tissue, as a back-scattering intensity
distribution at 1 to 10 micrometer resolution. As shown by Fig. 1, OCTH is based on FEM-based inverse
analysis using tomographic deformation vector field data obtained by OCSA. Inverse analyzing region ofinterest (ROI) is set arbitrarily on OCT images, which is discretized to finite elements in consideration of FEM
model such as material properties, e.g. Young's modulus, Poisson’s ratio and thermal expansion coefficient. A
global element equation subjected to thermal expansion can be built under 2-dimensional plane stress anddeformation boundary problems. By interpolating tomographic deformation vectors to every nodes, temperature
variation can be solved as a FEM-based inverse analysis due to given material properties. Moore-Penrose pseud
inverse matrix, mainly defined by shape functions and element discretization, is used selectively to estimate thetemperature variation field as a direct inverse analysis. The absolute temperature variation can be calculated
from temperature calibration by local measurement. In order to validate OCTH, the numerical experiment was
carried out using simulated OCT images constructed by both Monte Carlo simulation and FEM thermal stressanalysis. FEM analysis was conducted using a chip embedded board model, in which a silicon CPU and a copper
wire were embedded as heat sources in the both side and filled with an epoxy seal. A simulated OCT image wascalculated by Monte Carlo simulation for random scattering intensity profile, then the synthetic OCT images
were prepared by speckle pattern movement according to deformation field obtained by FEM.
Study on Micro-tomographic Visualization of Blood Flow Velocity in Capillary Vessels using Optical
Coherence Interferometer Optical Coherence Doppler Velocigraphy
Daisuke FURUKAWA, Souichi SAEKI, Yusuke HARA, Susumu AOKI, Takafumi ITO and Yoshiaki
NISHINOXXVI Congress of the International Society of Biomechanics 2017, USB-memory, pp. 114 (2017)
The skin aging process, e.g. wrinkles and saggings, caused by not only aging but also ultraviolet irradiation,
could be related to the depression of metabolic function. The microcirculation system should be an important
guideline of skin care for the anti/smart-aging. Rheological behavior of interstitial in epidermal and dermal tissue,
including blood micro-circulation, can vary skin mechanics in micro scale, i.e. visco-elasticity. Therefore, an invivo quantitative measurement of capillary blood flow velocity is crucial to clarify their properties. The purposeof this study is to visualize the tomographic flow velocity of red blood cell in capillaries below human epidermalskin using Optical Coherence Doppler Velocigraphy, i.e. OCDV. This is constructed on a low coherence
interferometer, which is based on Hilbert transform and adjacent auto-correlation. The paper presents the resultof applying OCDV to human forearm skin inside, it was possible to provide blood flow velocity of capillary
vessels non-invasively as an in vivo micro-tomographic imaging.
Construction on Tomographic Micro-visualizing System of Delivered Drug Concentration inside
Biological Tissue using 2-Color Coherence Interferometer
Naoya KUSUMOTO, Daisuke FURUKAWA, Ryohei NISHINO and Souichi SAEKIXXVI Congress of the International Society of Biomechanics 2017, USB-memory, pp. 529 (2017)
Recently, clinical treatments applying Drug Delivery System (DDS) have been being developed. However, it isquite difficult to in vivo diagnose spatiotemporal distribution of drug infiltration. An example of chemical
substance, “water”, has significant influence on human body due to physiological carrier media. Therefore, invivo quantitative measurement of moisture content is necessary to classify skin mechanics. In this study, we
propose 2C-OCM (2-Color Optical Coherence Moisturegraphy), which is composed of two-band light sourceshaving different optical absorption properties of moisture content. RSOD (Rapid Scanning Optical Delay line) is－51－

implemented as a depth scanner of interferometer, which can modulate the two-band lights to different
frequencies. In order to verify 2C-OCM, it was in vivo applied to the dorsum of hand skin with varying moisture
condition of tissue.
Micro-tomographic Diagnosis of Skin, Cartilage, Atherosclerosis, Tumor and Regenerative Tissue using
Multi-functional OCT
Souichi SAEKI
8th OCARINA International Symposium, O-4, p. 14 (2017)
In atherosclerosis, malignant neoplasm and osteoarthritis and so on, since the disease condition should reachprogressive stages with the microscopic tissue degeneration of biomechanical and biochemical tissue
characteristics, the development of the non-invasive micro-diagnostic system has been required to carry out
clinically tomographic visualization at the micro scale. Recently, Optical Coherence Tomography (OCT), basedon the low coherence interferometry, has been being improved as a 3-dimensionally and tomographicallysubsurface imaging of micro structural biological tissue with high resolution of 1 to 10μm. However,biomechanical properties; vulnerability and visco-elasticity, and biochemical characteristics; drug infiltration
and water content, have never estimated exhaustively, because OCT can provide only morphological tissue
distribution as scattering intensity profile generated from spatial variation of refractive index. In this presentation,a tomographically diagnostic method "Multi-Functional OCT" [1], is proposed and in/ex vivo performed as a 3dimensional non-invasive detection with micro scale, which can offer the biomechanical properties of ”strain”
by “OCSA” and ”stress” by “OCSE” [2], ”velocity” by “OCDV” [3], and the biochemical characteristics“delivered drug” and “water content” by “OCD” and “OCM” [4], the biological tissue characterization offibrous/lipid by “ARV” [1], respectively.
Study on 3-Dimensional Micro-tomographic Visualizing of Blood Flow Velocity in Capillary Vessels Using
Optical Coherence Doppler Velocigraphy
Daisuke FURUKAWA, Ryohei NISHINO, Naoya KUSUMOTO, Souichi SAEKI, Yusuke HARA, Masatsugu
SHIBA, Susumu AOKI, Takafumi ITO andYoshiaki NISHINO
8th OCARINA International Symposium, P-36, p. 73 (2017)
The skin aging process, e.g. wrinkles and saggings, caused by not only aging but also ultraviolet irradiation,
could be related to the depression of metabolic function. The microcirculation system should be an important
guideline of skin care for the anti/smart-aging. Rheological behavior of interstitial in epidermal and dermal tissue,
including blood micro-circulation, can vary skin mechanics in micro scale, i.e. visco-elasticity. Therefore, an invivo quantitative measurement of capillary blood flow velocity is crucial to clarify their properties. The purposeof this study is to visualize the tomographic flow velocity of red blood cell in capillaries below human epidermalskin using Optical Coherence Doppler Velocigraphy, i.e. OCDV [1]. This is constructed on a low coherence
interferometer [2], which is based on Hilbert transform and adjacent auto-correlation. In order to validate OCDV
system, this was in vivo applied to human forearm skin under the condition of control and avascularization using
a tourniquet, respectively. As a result of skin tomography obtained by OCDV, a cross-sectional imaging of
doppler velocity was found to display networks of capillary blood vessels inside dermal tissue, where low
intensities were distributed in a morphological OCT image. It was confirmed that blood velocity further
decreased in upper dermis under avascularization than control condition. In summary, OCDV system could bequite useful for a micro-tomographic imaging of blood flow velocity of capillary vessels inside skin.
Construction on Tomographic Micro-visualizing System of Delivered Drug Concentration inside
Biological Tissue using 2-Color Coherence Interferometer
Naoya KUSUMOTO, Daisuke FURUKAWA, Ryohei NISHINO, Souichi SAEKI and Takeshi NAGASAKI
8th OCARINA International Symposium, P-17, p. 49 (2017)－52－

Recently, clinical treatments applying Drug Delivery System (DDS) have been being developed. However, it isquite difficult to in vivo diagnose spatiotemporal distribution of drug infiltration. An example of chemical
substance, “water”, has significant influence on human body due to physiological carrier media. Therefore, invivo quantitative measurement of moisture content is necessary to clarify skin mechanics. In this poster
presentation, we propose 2C-OCD/OCM (2-Color Optical Coherence Dosigraphy & Moisturegraphy), which iscomposed of two-band light sources having different optical absorption properties of delivered drug and water,
respectively. These methods are capable of tomographically in vivo diagnosing delivered drug concentration andthe moisture content, respectively. The present system, i.e. OCM, is constructed around an optical fiberinterferometer based on Time-Domain OCT [1], and can simultaneously acquire two interference signals only bya single channel. RSOD (Rapid Scanning Optical Delay line) is implemented as a depth scanner in reference arm
so that it can provide video-rate tomography by rotating a galvanometer mirror. In addition, light of eachwavelength, which is diffracted by a grating, is focused on different position on the surface of scanning mirror
by an achromatic lens, so can modulate lights of the two-band wavelength to respective different frequencies. In
order to verify 2C-OCM, it was applied to the dorsum of hand skin under the condition of control and moisturesaturated skin for 30 minutes. Consequently, it was concluded that 2C-OCM has a promising potential of
diagnosing tomographic concentration of chemical substance, i.e. drug, inside skin tissue.
Study on Tomographic Micro Mechanical Diagnosis of Osteoarthritic Cartilage using Dynamic Optical
Coherence Straingraphy
Kazuma KOTANI, Kiichi HASEGAWA, Hiroaki KOBAYASHI, Souichi SAEKI, Suguru NAKAMURA,
Mitsuhiko IKEBUCHI, Hiroaki NAKAMURA, Nobuo NIIMI, Yoshito TSUKAHARA
8th OCARINA International Symposium, P-16, p. 48 (2017)
Many of the elderly are predisposed to develop osteoarthritis (OA), although it is quite difficult to diagnose theearly-grade OA even by latest imaging modalities. The purpose of this study is to develop a clinical diagnosing
system, which can tomographically and non-invasively visualize mechanical properties of articular cartilage, i.e.
visco-elasticity, in micrometer resolution. We constructed “Dynamic Optical Coherence Straingraphy (DOCSA)” composed of Optical Coherence Tomography (OCT) and a mechanical loading devise [1]. This candiscriminate mechanical propertied by applying the proposed image processing to continuous OCT images,
which should contain huge hidden information as dynamical behavior of deformed cartilage. In this poster
presentation, the arthroscopy-typed OCT, which can intraarticularly diagnose osteoarthritic cartilage, wasdeveloped as an in vivo cross-sectional imaging modality and was applied to a porcine knee joint. In addition, ex
vivo animal experiments were also carried out to apply D-OCSA to the prepared rabbit’s OA cartilage caused by
amputation of knee ACL. As a result, it was confirmed that the constructed system could intraarticularly provide
morphologic diagnosis of cartilage, e.g. tide mark. D-OCSA showed superior increase in attenuation ofcompressive strain rate only for early OA cartilage during relaxation test, which can be seen that there is a lossof visco-elastic properties as compared to normal cartilage. In conclusions, the proposed arthroscopic-typed DOCSA system could be effective to assessments of the early OA as ”Micro Mechanical Biopsy”.
Fundamental Study on Ultrasonic Detection of Uncured Region in GFRP Plates
Akihiro WADA, Tomohiro YAMASAKI, Eiji KITAGAWA and Hiroshi ITO
Journal of the Japan Society for Composite Materials, 43(3), pp.112-119(2017)
Ultrasonic waves are applied to detection of uncured regions in glass-fiber reinforced plastic (GFRP) plates.
Polymer-based composites play an increasingly important role in the field of civil engineering because of theirhigh specific stiffness, strength, and excellent corrosion resistance. For example, GFRP pipes are used torehabilitate aged sewerage pipes. Uncured GFRP tubes are inserted in the aged pipes, and are then inflated andcured with steam blowing to create close-fit pipes. In this cured-in-place pipe (CIPP) method, an uncured region
may be left in the GFRP pipe, so the constructed pipe must be inspected to ensure the integrity of thereinforcement. In this study, for detection of such an uncured region in GFRP structures, the effect of resin cure－53－

on ultrasonic propagation characteristics is investigated experimentally. Through-thickness and in-plane
ultrasonic measurements are conducted, and their sensitivities to resin cure are compared. In addition to wave
attenuation and velocity, several AU parameters are evaluated from the power spectrum of a broadband signal.
It is found that the A2 parameter, which represents the centroid of the power spectrum, has a good correlation
with the mechanical properties of GFRP plates, and is expected to improve the detectability of uncured regions.
Development of a Bridge Inspection Robot Capable of Traveling on Splicing Parts
Yogo TAKADA, Satoshi ITO, and Naoto IMAJO
Inventions, Vol. 2, No. 3, 22 (2017), DOI:10.3390/inventions2030022.
Several infrastructures, such as bridges and tunnels, require periodic inspection and repair to prevent collapse.
There is a strong demand for practical bridge inspection robots to reduce the cost and time associated with theinspection of bridges by an inspector. Bridge inspection robots are expected to pass through obstacles such as
bolted splice part and right-angled routes. The aim of this study involved developing a bridge inspection robotthat can travel on a right-angle path as well as splicing parts. A two-wheel-drive robot was developed andequipped with two rimless wheels as driving wheels. A neodymium magnet was provided at the tip of each
spoke. Non-driving wheels were attached at the rear as a rotatable caster. The robot can turn on the spot to avoid
the bolt on the splicing part. Experiments were conducted to check the performance of the robot. The results
confirmed that the robot passed through the internal right-angle paths in a laboratory and in an actual
environment that corresponds to a box girder of a bridge. It is extremely difficult to manually control a robot on
the splicing part. Therefore, a camera and an LED (light emitting diode) were attached to autonomously control
the robot. The results indicate that the newly developed robot could run through the splicing part without hitting
the nuts.
X-ray Stress Measurement of the Cylindrical Surface by the cos α Method
Taizo OGURI (Technology Research Institute of Osaka Prefecture), Tsutomu TANAKA (Technology ResearchInstitute of Osaka Prefecture), Toshiyuki OKANO (Okano Blast Co. Ltd.), Kazuo MURATA (Okano Blast Co.
Ltd.), Hiroshi KAWAKAMI, and Yoshihiro SATO
Journal of the Society of Materials Science, Japan, Vol. 66, No. 7, pp. 488-494 (2017) (in Japanese)
The investigation was made on the phenomena observed in the X-ray stress measurement on a curved surface by
the cos α method. Numerical analysis was performed simulating the cos α method for the circumferential stressand the axial stress on a cylindrical surface. The X-ray residual stress measurements by the cos α method and thesin2 ψ method were carried out respectively for the blasted surface of round steel bars with various diameters. It
was found that the debye ring turned oval and the slope of cos α diagram decreased as the ratio of the X-ray
beam size to the bar diameter increased, i.e. the magnitude of the measured stress was smaller than that of actualone. These tendencies were remarkable in the circumferential stress measurement. With respect to the relation
between the X-ray beam size and the measured value of stress, the difference between the cos α method and thesin2 ψ ethod was found to be small. The measurement error due to a cylindrical surface was negligible when the
X-ray beam size was less than 1/3 of the diameter.
Estimation of Residual Stress Distribution under Shot-Peened Surface by Using Theory of Thermal Stress
AnalysisToshiyuki OKANO (Okano Blast Co. Ltd.), Kazuo MURATA (Okano Blast Co. Ltd.), Taizo OGURI(Technology Research Institute of Osaka Prefecture), Tsutomu TANAKA (Technology Research Institute of
Osaka Prefecture), Hiroshi KAWAKAMI, and Yoshihiro SATO
Journal of the Society of Materials Science, Japan, Vol. 66, No. 7, pp. 508-514 (2017) (in Japanese)In the shot peening process, the residual stress on the shot-peened surface and its distribution under the surface
are important evaluation items for the high value-added surface creation. In this paper, it was proposed that theresidual stress distribution under the shot-peened surface for a thin plate was non-destructively estimated from－54－

the measured value of residual stress on the surface and that of the arc height, by applying the theory of linear
thermal stress analysis for a thin plate. The analyzed residual stress profile showed good agreement with that of
the experimental results obtained from the surface removal by electro-polishing. From the results of analysis, it
was found that the depth of compressive residual stress (the depth which changes from the compressive stress tothe tensile stress), the residual stress at the depth of the inherent strain and the residual stress on the opposite
surface to the shot-peened surface characterizing the profile of residual stress distribution had a relationship withthe ratio of a thickness of plate to an inherent strain depth.
Effects of Wipe Cleaning with Detergents on Antibacterial Activities of Copper Surface
Pengyuan WANG, Hiroshi KAWAKAMI, and Yoshihiro SATO
Journal of Japan Institute of Copper, Vol. 56, No. 1, pp. 323-328 (2017) (in Japanese)In this study, effects of surface contamination by an oily substance and wipe cleaning using detergents on
antibacterial activities of copper were investigated. Sample used was oxygen free copper (OFC) (> 99.96 %).
Triolein was employed as a model surface contaminant. Detergents used for wiping were hypochlorite (NaOClaq.) and ethanol (EtOH). Distilled water (D.W.) was also used as a detergent for wiping. The test surfaces of
coupon specimens were firstly contaminated with triolein and then subjected to wiping using a sterile wipe
loaded with one of the detergents. The specimens were also subjected to the wet-dry cycles, i.e. the specimens
subjected to the cycle of being wetted with the detergents for about 15 s and being left in an atmosphere for 24hours. Antibacterial tests were carried out according to the film contact method designated in JIS Z 2801, exceptthat the time length of film contact was set to 30 min. The strain used in the antibacterial tests was E. coli
(NBRC 3972). Antibacterial activities of the specimens were reduced by surface contamination with triolein.
The reduced antibacterial activities were reactivated by the application of wipe cleaning using the detergents.
The wiping with a dry sterile wipe also reactivated the reduced antibacterial activities. The surfaces of thespecimens corroded when the specimens were subjected to the wet-dry cycle for several times. The specimens
treated with NaOCl aq. showed severe decrease in the antibacterial activities followed by the specimens treatedwith D.W., and the amount of decrease in the antibacterial activities of the EtOH treated specimens was small.
For the specimens left in an atmosphere for the same period of time as the wet-dry cycles, the antibacterial
activities did not change significantly from that of specimens with clean surface. Such results indicate that thewiping using the detergents is presumably not adequate for copper and the wiping with a dry sterile wipe is apreferred method for copper to reactivate the antibacterial activities reduced by surface contamination by oily
substances.
Investigation of the Quality of Autoclaved Composite Plates through Working Process
Norimichi NANAMI, Toshikazu UCHIDA, Yosuke WATANABE, Katsuyuki HARA, Koji KURODA,
Hiroyuki HAMADA, Akihiko GOTO and Hayato NAKATANI
Proc. JSME/ASME 2017 6th International Conference on Materials and Processing (ICMP2017), Los Angeles,
CA, USA, June 4-8, Paper ID: ICMP2017-4334 (2017).
Carbon fiber reinforced polymer (CFRP) products are utilized in the aerospace industry to provide high specificstiffness/strength. It is necessary to assure of the quality of CFRP products such as strength and stiffness. Defects
in the products are caused by the skill of the working people, leading to the unexpected damage and failure of
the products. Herein, we investigate the influence of the worked surface quality to the open hole tensile strengthand interlaminar shear strength of CFRP plates. The results revealed that the quality of the machined surface ofthe plate in the hole making process altered its tensile strength. However, a further testing method to estimate theinterlaminar shear strength of the plate is required to understand the influence of its surface quality in working
process to its interlaminar shear strength.
Thermal Treatment and Microstructure Observation for Japanese Sewing Scissors made by the "Sohizukuri" Forging Process－55－

Hayato NAKATANI, Yasuko KITAJIMA, Takuya SUGIMOTO, Akihiko GOTO and Hiroyuki HAMADA
Proc. JSME/ASME 2017 6th International Conference on Materials and Processing (ICMP2017), Los Angeles,
CA, USA, June 4-8, Paper ID: ICMP2017-4357 (2017).
The metallic structure observations and hardness measurement are carried out for the so-hizukuri scissors toshow its uniformly sized martensitic structure and much higher hardness compared to standard quenched steel inthe steel part of the blade. These facts are related to the craftsman's action during quenching process. Coating theblades with a kind of clay and shaking the heated blades in cooling water can result in uniform cooling for whole
blade. Pressing the blades against the inner wall of the water vessel during the cooling and annealing by utilizing
remaining heat can be correspond to press quench and marquench, respectively as often employed in forging
technique of today. The forging by hammering should introduce the residual compressive stress and refinementof crystal grains that lead to the excellent sharpness of the scissors.
Shortening in Resin Impregnation Time of VaRTM Process and Interlaminar Toughening for GFRP byinserting Polyamide Mesh
Hayato NAKATANI, Yosuke HANDA and Katsuhiko OSAKA
Proc. JSME/ASME 2017 6th International Conference on Materials and Processing (ICMP2017), Los Angeles,
CA, USA, June 4-8, Paper ID: ICMP2017-4371 (2017).
During vacuum assisted resin transfer molding (VaRTM) process a distribution medium which is incorporated
on fiber preform as a surface layer is used to shorten impregnation time of resin. In this study the distribution
medium is replaced by thermoplastic polyamide meshes and is inserted between fiber fabrics rather than placedon the surface. The mesh is expected to improve not only the resin flow but also interlaminar toughness in thecomposite laminate by remaining in it after the VaRTM process. Multipoint measurements for resin arrivals in
GFRP (Glass fiber fabrics / epoxy composites) during VaRTM process are carried out by using embedded fiber
optic sensors. It is confirmed that the polyamide mesh inserted in the fiber preform increased the flow rateduring the impregnation of resin, and that thicker polyamide mesh resulted in higher flow rate. This fact isrelated to experimentally obtained permeability of the polyamide mesh with different thicknesses. Numericalsimulation based on CV/FEM approach also represents both the flow front of resin where the resin preferentiallyproceeds in the polyamide mesh and flow rate at each measurement point. End notched flexure (ENF) tests using
specimens which have bonded doubler plates of CFRP to both top and bottom surfaces are carried out. The crack
length can be predicted by a simple beam theory for bonded doubler plates during the ENF testing. It is foundthat interlaminar fracture toughness ‫ܫܫܩ‬C is improved by inserting the thinner and finer polyamide mesh due tothe complexity of the crack path. From these results it is shown that improvements in both resin flow andinterlaminar fracture toughness can be achieved by inserting the polyamide mesh.
Comparison of Worker’s Skill during Vacuum-assisted Resin Transfer Molding using Motion Analysis
Yasunari KURATANI, Kentaro HASE, Tomoe KAWAZU, Aya MIKI, Norimich NANAMI, Hayato
NAKATANI and Hiroyuki HAMADA
Advances in Ergonomics of Manufacturing: Managing the Enterprise of the Future, Proc. AHFE 2017
International Conference on Human Aspects of Advanced Manufacturing, Los Angeles, CA, USA, July 17-21,
pp.398-406 (2017).
In the field of carbon fiber reinforced polymer (CFRP), it is difficult to find the optimal molding conditions,since the Vacuum-assisted Resin Transfer Molding(VaRTM) requires a process which makes fiber-basematerials fit into a three-dimensional shape, by applying pressure and heat simultaneously. In this study, threesubjects with a varying number of years’ of experience produced a VaRTM molding, with the objective ofidentifying the factors that contribute to the accuracy in molding conditions. The study showed that the process
was dependent on the ability of the worker and experience. Herein, the researchers analyzed the behavior ofexperts and develop a standard procedure in order to help beginners training and to contribute to the composites
CFRP industry process learning procedures.

－56－

Characteristics of Cutting Performance for Japanese Sewing Scissors Made by the “So-hizukuri” Forging
Process
Yasuko KITAJIMA, Hayato NAKATANI, Akihiko GOTO and Hiroyuki HAMADA
Advances in Physical Ergonomics and Human Factors, Proc. AHFE 2017 International Conference on PhysicalErgonomics and Human Factors, Los Angeles, CA, USA, July 17-21, pp.466-478 (2017).
Scissors are commonly known as a tool that has been used since long ago. The X-shaped scissors currently
commonly used in Japan date back to 160 years ago when Admiral Perry arrived in Uraga. Since that time
Yakichi Yoshida, known as the originator of Japanese scissors, has made many reforms leading scissors to theirpresent shape. His method is called “So-hizukuri”, and today there is a very small number of artisans left who
have inherited the Sohizukuri method. In previous research our research group investigated why sewing scissors
made with the So-hizukuri method have a sharp cutting edge. The results showed that the surface of So-hizukuri
method scissors blades have a curved surface with a difference of about 0–150 μm applied. It was suggested thatthe curved surface being applied causes the cutting power of the scissors to be focused onto the point where thetwo blades overlap when cutting cloth, leading to a sharp cutting edge. We also confirmed that when the two
blades overlap the parts of the other blades are separated. In this research, we intend to extract characteristics of
the So-hizukuri scissors with sharp cutting edges which were not clarified in the previous research. We had atailor who is a specialist in handling scissors use new So-hizukuri sewing scissors and So-hizukuri sewing
scissors which have been used for more than 20 years and which were both made by the same scissors artisan,and examined what effect this had on the operations of the person handling the scissors when cutting cloth. We
had the person cut the same cloth under the same conditions using the same method, and recorded the processwith a high-speed camera for analysis. The results showed a clear difference in the movements of the tailor whenhandling the So-hizukuri scissors and the cheap scissors, but no significant difference between the new Sohizukuri scissors and the So-hizukuri scissors which had been used for more than 20 years. We considered thereasons for this difference including an interview with the tailor, which we will report here.
Eye Movement Analysis of Japanese Sewing Scissors Craftsman
Yasuko KITAJIMA, Hayato NAKATANI, Yoichiro OGURA, Akihiko GOTO, Hiroyuki HAMADA and
Norimichi NANAMI
Advances in Physical Ergonomics and Human Factors, Proc. AHFE 2017 International Conference on PhysicalErgonomics and Human Factors, Los Angeles, CA, USA, July 17-21, pp.479-490 (2017).
The purpose of this study is to elucidate the skill of a blacksmith who has an ability to produce a pair of scissors
whose two blades accurately comes across in the length, width and angle of each blade, even though they were
produced separately. The processing method this scissor artisan employs is known as “So-hizukuri” (total
forging process). The elucidation was conducted through observing the line of sight of the artisan using an eye
movement analysis camera during his forging process. There are four main stages in the So-hizukuri process,and each stage involves several steps. In this study, we asked the scissor artisan to wear an eye movement
analysis camera while engaging with the “Namatogi” (grinding before quenching) step in the “rough finishing
before quenching” stage, which is the second in the four main stages, and observed his eye movements. We
viewed the video recorded by the eye camera, and studied which parts of the blades he focused on, and theamount of time he focused on each part, when the artisan was comparing the two blades by laying one blade on
top of the other. As a result, it was clarified that the artisan works on each of the left and the right blade
alternately and gradually at every step toward the final stage, as the left and right blades of the scissors comeacross accurately when the scissors are completed. At any point in the process, he did not focus on forging one
blade intensively, use a measuring instrument to measure the length of the blades, or use one of the blades as astandard to match the other blade.
Applying Copper-Ball Dissolution for Prolonging Life of Electroless Copper Plating Solution－57－

H. KANEMOTO, T. KAWAMURA, T. ITABASHI, T.MIYAZAKI and Y. KANEKO
Trans. Japan Inst. Electronics Packing, Vol.9, pp.1-10 (2016).
Under the goal of prolonging lifetime of an electroless-copper-plating solution, a new method for supplying Cu2+ions to the solution, copper-ball dissolution method was developed. The effect of the developed method was
examined by comparing with conventional methods: CuO-particle dissolution method and CuSO4-supply
method. Studies on copper ball dissolution reaction clarified that Cu2+ ion could be supplied to the plating
solution by dissolving copper ball in the oxygen-supplied solution. Compared with CuSO4-supply method,copper-ball dissolution method prevents salts from being accumulated in the solution, which can potentiallydouble the lifetime of the solution, similar to CuO-particle dissolution method. The films obtained by copperball dissolution method contain fewer impurities than those of deposited by CuO-particle dissolution. As a result,the mechanical properties of the deposited film and the reliability of through-hole connection are improved. It is
concluded that copper-ball dissolution method is an effective method for prolonging the lifetime of an electrolesscopper-plating solution, leading to reduction in environmental loads.
EBSD Analysis of Local Lattice Rotation below Fracture Surface
Y. KANEKO, C. YONEDA and M. UCHIDA
Proceeding of 14th International Conference on Fracture, (2017), in USB memory.
Microstructures developing below fatigue fracture surface were investigated by local EBSD analysis of small
planes. A fatigue crack growth test was conducted in a center-cracked tension specimen of polycrystalline
copper. After the crack growth test, various positions in the fracture surface were milled by the FIB technique toobtain small flat planes normal to loading direction. The flat planes were analyzed with the EBSD system. To
estimate the lattice rotation quantitatively, lattice rotation angles were calculated from the numerical datacollected by the EBSD analyses. The lattice rotation angle was defined as misorientation angle between a pointof interest and a reference point, which is a center of an analyzed grain. In the present study, the lattice rotation
was calculated along a certain line lying in the milled plane. It is found that the lattice rotation increased withincreasing �KI value, in the milled planes existing at central sites of specimen thickness.
Implementation of an Extended Flory-Rehner Model with Two Scaling Exponents and Basic Analysis
Shoji SHIMIZU, Dai OKUMURA, Makoto UCHIDA, and Hiro TANAKA
Journal of the Japan Society for Computational Methods in Engineering, Vol. 16, pp.37-42 (2016) (in Japanese).
In this study, we perform finite element implementation of a free energy function extended by introducing two
scaling exponents into the Flory-Rehner model for swollen elastomers. This extended model is implemented into
the finite element package Abaqus using the user-defined material subroutine UHYPER. To verify this
implementation, the stress-stretch responses of elastomers at equilibrium swelling under uniaxial tension are
simulated and compared with analytical predictions. The aid of artificial damping is needed to capture a rapid
decrease in stress caused by swelling-induced strain softening. Effects of artificial damping on automaticincrementation analysis are discussed.
Evaluation of Fields of Stress and Strain of Pure Copper during Uniaxial Tensile Test using Digital Image
Correlation Method and Finite Element Method
Makoto UCHIDA, Towa UENO, Takahiro ABE and Yoshihisa KANEKO
Proc. the 11th International Symposium on Advanced Science and Technology in Experimental Mechanics,
Paper No. 56, 5pages (2016)
In order to predict the non-uniform deformation behavior of engineering materials, evaluation and modeling of
the strain field are very important. Recently, accurate and contactless measurement of strain field can be
performed using the optical measurement method such as digital image correlation (DIC) method. Evaluation of
the stress field is also required to model the non-uniform deformation behavior of the material. In this study,
fields of stress and strain are evaluated by coupling the DIC and FEM. Local strain can be decomposed into－58－

elastic and inelastic parts by introducing the stress equilibrium around the displacement measurement points.
Then, local stress tensor can be obtained by introducing the elastic strain components into generalized Hooke’s
law. Large deformation theory based on the update Lagrange method is also introduced to evaluate local truestress and true strain tensors for large strain range. Fields of stress and strain for pure copper specimens were
evaluated during tensile tests of two different-shape specimens, Specimens NU and U. The cross section ofSpecimen NU continuously changes while it is constant for Specimen U. Local true stress ̶ true strain relation
basically located around the global value, and the relation for Specimens NU and U are almost similar. These
results indicated that the proposed methods could evaluate local stress and strain properly.
Computational Simulation of Scale-Dependent Non-Uniform Deformation Behavior of Polymer Foam
Makoto UCHIDA, Keita SUZUKI and Yoshihisa KANEKOKey Eng. Mater., Vol. 725, pp 456-461 (2016).
Polymer foam is widely used in the engineering field because of various functions such as lightweight, shock
absorbing, insulation and so on. However, the strength of the material dramatically decreases with the increase in
the volume fraction of the pore. In the present study, a micro- to macroscopic deformation behavior of polymer
foam is modeled using the rate-form second-order homogenization method. To model the microscopic structure
consisting of the pore and polymer wall, a hexagonal shape periodic structure was used, and the molecular chain
network theory was used to represent an elastic-viscoplastic deformation behavior of the polymer wall. The
bending resistance, in other words, resistance to the strain gradient clearly depended on comparative size
difference between microscopic and macroscopic structures. For smaller pore model, the strain distribution was
point symmetry, and those for different specimen sizes were almost same. On the other hand, in larger poremodel, strain field was not symmetry, and the magnitude of the asymmetry was emphasized for small specimen.
Large difference in the macroscopic strain through the unit cell induced the asymmetry to larger pore model, andit caused size-dependent bending resistance of the low density polyethylene foam.
Numerical Analysis of Evaluation of Local Wall Thinning on the Inner Surface of Pipe by the DirectCurrent Potential Difference Method
Naoya TADA, Manabu NOHARA and Makoto UCHIDA
J. Soc. Mater. Sci, Jpn, Vol. 66, pp. 158-165 (2017) (in Japanese).
Local wall thinning is one of serious problems in aged power generating and chemical plants. As the thinninggrows inside the pipes, it is difficult to detect and evaluate it from the outer surface of pipe. In this study, anevaluation method of semi-ellipsoidal local wall thinning on the inner surface of pipe by the direct-current
potential difference method (DC-PDM) was proposed, and the related numerical analyses were carried out. At
first, very fast electric field analysis method, i.e., defect-current modification method (DCMM), was extended to
the local wall thinning with semi-ellipsoid shape on the inner surface of pipe, and the solution was validated bycomparing with that obtained by the finite element method (FEM). Then, the geometry of the local wall thinningwas evaluated by the proposed method based on the distribution of potential difference on the outer surface ofpipe obtained by FEM. The evaluated results were successful, and it was found that the DC-PDM is applicable tothe evaluation of local wall thinning.
Evaluation of Nonuniform Deformation during Plastic Deformation of Polypropylene-Cu Mesh
Composite
Makoto UCHIDA, Daichi KAWAMOTO and Yoshihisa KANEKO
J. Jpn Soc. Technol. Plast., Vol. 58, pp.145-150 (2017.2) (in Japanese).
To improve the plastic instability of a thermoplastic polymer composite under cold forming, a copper mesh was
filled into the polypropylene (PP). PP-Cu mesh composite plate specimens with the Cu mesh inclined in various
directions were formed by the compression molding of the PP pellet and Cu mesh. First, the tensile behavior of
Cu meshes with the angles of 0/90°, 15/75°, 30/60° and 45° to the tensile direction was examined. The－59－

maximum stress decreased gradually with increasing Cu mesh angle to the tensile direction because the Cu wires
rotated in the tensile direction. The anisotropic response was also confirmed for the PP-Cu mesh composite, andthe anisotropy was emphasized for composites with the higher volume fractions of the Cu mesh. The decrease in
the nominal stress, which is often seen in the tensile deformation of the thermoplastic polymer, almost
disappeared for the composite specimen with the Cu mesh at the angle of 45° to the tensile direction. Also, thedeformation concentration in the specimen was effectively suppressed by reducing the deformation resistance inthe early stage of deformation and by increasing the strain hardening after yielding.
Quantitative Evaluation of the Development of Stress and Strain Fields using Digital Image Correlation
and Finite Element Methods
Makoto UCHIDA, Towa UENO, Takahiro ABE and Yoshihisa KANEKO
Advanced Experimental Mechanics, Vol. 2, pp.76-81 (2017.8).
In order to predict the nonuniform deformation behavior of engineering materials, both the evaluation andmodeling of the strain field are very important. Recently, accurate and contactless measurement of the strain
field was performed using digital image correlation (DIC). Evaluation of the stress field is also required to model
the nonuniform deformation behavior of the material. In this study, the stress and strain fields are evaluated bycoupling the DIC and the finite element methods (FEM). The local strain can be decomposed into elastic andinelastic parts, based on the stress equilibrium around the displacement-measurement points. The local stresstensor can then be obtained by introducing the elastic strain components into a generalized Hooke’s law. The
large deformation theory, based on the updated Lagrange method, is also introduced to evaluate the local truestress and true strain tensors for large strain range. The stress and strain fields for pure copper specimens that had
two different shapes, namely, specimens NU and U, were evaluated during tensile tests. The cross-section of
specimen NU continually changes whereas it is constant for specimen U. Furthermore, two specimens withdifferent crystal grain size were used to investigate the effect of the microscopic heterogeneity. The local truestress ̶ true strain relationship spanned regions in the proximity of the global response, while the relationship for
specimens NU and U were almost similar. The effect of the microscopic heterogeneity on the macroscopic
nonuniform deformation was investigated using the evaluated stress and strain fields. In larger-grain specimens,
the evaluated stress gradient was lower than that estimated using the strain gradient since the hardening ratespatially distributed owing to the microscopic heterogeneity.
Plastic Flow of Glassy Epoxy Network
Shin’ya YOSHIOKA, Yasuhito ITAMI and Akira KAWAI
J. Soc. Mat Sci, Jpn, Vol.66, pp.1-6 (2017). (in Japanese)
Steady plastic flow in specimens of tightly cross-linked glassy epoxy network was analyzed as a rate process to
discuss the mechanism of nonlinear viscoelastic behavior of glassy network polymers under large deformation.
Specimens were uniaxially stretched at temperatures below the glass transition temperature with various strain
rates. True stress σ and birefringence in the specimen were recorded during the deformation as functions of
nominal strain εn. The glassy stress σG was extracted from the σ-εn relations by means of modified stress-opticalrule (MSOR). The obtained σG-εn relations had a steady flow region, which was observed as an almost constantstress state in the post-yield strain range. The flow stress in this region was analyzed by using the Eyring
equation in a special way proposed by Nanzai. The analysis gave an experimental relation between the activation
enthalpy ΔH and the activation entropy ΔS, which agreed fairly well with that derived from WLF equation forthe linear viscoelastic relaxation of the material in the molten state. This agreement provides an experimental
evidence verifying structural change of the glass into liquid-like, highly non-equilibrium structure in the glassy
network polymer under large deformation. Independently of the presence of crosslinked molecular structures, theessential mechanism of nonlinear viscoelasticity of glassy polymers is found to be strain-induced structuralchange.

－60－

Stress-Strain Behavior of Glassy Epoxy Network Subjected to A Stepwise Change of Tensile Rate
Shin’ya YOSHIOKA and Shun KATO
Nihon Reoroji Gakkaishi (J. Soc. Rheol., Jpn), Vol.45, pp.79-82 (2017). (in Japanese)Stress-strain relations of a cured epoxy network subjected to uniaxial stretching during which the tensile ratechanged stepwise were observed at a temperature below the glass transition. When the tensile rate was increased
or decreased to a prearranged identical value, the stress-strain curves after the tensile rate change finallycoincided with each other in the post-yield strain-hardening region, after showing transient variations. Thisbehavior was observed independently of the amount of strain where the strain rate changed. Thus, the stressstrain relation in the strain-hardening region at a given strain rate did not depend on preceding strain rate history.
Since the strain-hardening behavior in this system is ascribable to an increase of the rubbery stress originatedfrom the chain orientation, the strain-hardening behavior independent of strain rate history means that theintensity of glassy stress, which is another stress component of glassy polymers, is uniquely determined only by
the strain rate at the moment. Thus, the glassy stress in the strain range well beyond the yield point proved to bea steady flow stress in the network polymer.

－61－Electronics and Informatics
Applied Physics and Electronics
Impacts of Annealing on Interfaces of Al foil/Si Junctions by Using Surface Activated Bonding
Katsuya FURUNA, Jianbo LIANG, Moeko MATSUBARA (Toyo Aluminum K. K.), Marwan DHAMRIN (ToyoAluminum K. K.), Yositaka NISHIO (Toyo Aluminum K. K.) and Naoteru SHIGEKAWA
Extended Abstracts of the 2017 International Conference on Solid State Devices and Materials, Sendai, 2017,
H-4-01 pp. 387-388 (2017)
We investigated impacts of annealing on Al foil/Si (100) junctions that were fabricated by using surface activatedbonding. By performing X-ray photoelectron spectroscopy analyses as well as scanning electron
microscope/energy dispersive X-ray spectrometry observations, we found that Al was diffused into the Si
substrate and Si and Al reacted across the bonding interfaces when the junctions were annealed at temperatureshigher than 800 °C.
Al-foil-based Low-loss Coplanar Waveguides Directly Bonded to Sapphire Substrates
Keita MATSUURA, Jianbo LIANG, Koichi MAEZAWA (University of Toyama) and Naoteru SHIGEKAWA
Extended Abstracts of the 2017 International Conference on Solid State Devices and Materials, Sendai, 2017,
J-7-03 pp. 495-496 (2017)
We successfully fabricate coplanar waveguides (CPWs) composed of 17 μm Al foils on sapphire sub-strates by
surface activated bonding (SAB). We demon-strate that transmission and line loss are improved by us-ing Al foils
in comparison with CPWs composed of evap-orated Al films. The obtained results imply that CPWs with better
performances are realized by using SAB.
Aluminum Foil/Si Direct Bonding as Prototypes of Ultra-Thick Metal Contacts in Devices
Jianbo LIANG, Katsuya FURUNA, Moeko MATSUBARA (Toyo Aluminum K. K.), Marwan DHAMRIN (ToyoAluminum K. K.), Yositaka NISHIO (Toyo Aluminum K. K.) and Naoteru SHIGEKAWAECS J. Solid State Sci. Technol. 6(9) P626 [7 pages] (2017)
We bonded aluminum (Al) foils to Si substrates to fabricate Al/p-Si, Al/n-Si, Al/p+-Si, and Al/n+-Si junctions by
surface activated bonding (SAB) method and investigated the effects of the annealing process on the electricalproperties of the junctions by measuring their current - voltage (I-V) characteristics. It was found that the leakage
current of the reverse bias voltage in the bonded Al/n-Si junctions significantly decreased and the interface
resistance of the bonded Al/p-Si junctions dramatically decreased with the annealing temperature. The smallest
interface resistances of the bonded Al/p+-Si and Al/n+-Si junctions were obtained to be 0.021 and 0.032 _· cm2,
after annealing at 300 and 400◦C, respectively. We demonstrated the fabrication of Al foil mesa-structures andmicro wiring with complex structures on Si substrates. The sheet resistance of the bonded micro wiring was foundto be more than two orders of magnitude lower than that of the evaporated micro wiring. In addition, Al foil mesa
structures revealed a good thermal stability at the annealing temperature lower than 600◦C. These results
indicated that the fabrication of the thick metal electrode in devices could be realized by SAB.
Room Temperature Direct Bonding of Single Crystal Diamond and Si Substrates for the Combination of
Diamond Devices with Si LSI
Jianbo LIANG, Satoshi Masuya (Univ. of Saga), Makoto Kasu (Univ. of Saga), Manikant Singh (Univ. of Bristol),Michael J. Uren (Univ. of Bristol), Martin Kuball (Univ. of Bristol) and Naoteru SHIGEKAWA
Extended Abstracts of 12th Topical Workshop on Heterostructure Miccroelectronics (TWHM 2017), pp.71-72(2017)
Formation of Contacts with High Thermal Tolerance by Using Si/GaN Junctions
Jianbo LIANG, Takuya NISHIMURA, Moeko MATSUBARA (Toyo Aluminum K. K.), Marwan DHAMRIN(Toyo Aluminum K. K.), Yositaka NISHIO (Toyo Aluminum K. K.) and Naoteru SHIGEKAWA
Extended Abstracts of 12th International Conference on Nitride Semiconductors (ICNS’12), Strasbourg, C01.44(2017)
Plane-view Transmission Electron Microscopy of Si/GaAs Interfaces Fabricated by Surface-activatedBonding at Room Temperature－62－

Yutaka OHNO (Univ. of Tohoku), Hideto YOSHIDA (Univ. of Osaka), Seiji TAKEDA (Univ. of Osaka), LiangJIANBO and Naoteru SHIGEKAWA
Extended Abstracts of 2017 IEEE International Workshop on Low Temperature Bonding for 3D Integration(LTB-3D), pp.4 (2017)
Si/GaAs interfaces fabricated by surface-activated bonding at room temperature were examined by plane-viewtransmission electron microscopy. It was hypothesized that the interface resistance would be originated fromsurface defects on the Si and GaAs substrates introduced during the bonding process.
Transport Characteristics of Optically-Excited and Electrically-Injected Minority Electrons acrossp-Si/n-SiC Hetero-Interfaces
Naoteru SHIGEKAWA, Sae SHIMIZU, Jianbo LIANG, Masato SHINGO (Univ. of Fukui), Kenji SHIOJIMA(Univ. of Fukui) and Manabu ARAI (New Japan Radio Co. Ltd.)
Extended Abstracts of 2017 IEEE International Workshop on Low Temperature Bonding for 3D Integration(LTB-3D), p.26 (2017)
We report on the photoresponse of p-Si/n-SiC heterojunctions and the electrical characteristics of SiC/Si
heterojunction bipolar transistors (HBTs), both of which are fabricated by bonding SiC and Si layers. We find thatin the photoresponse measurements the square root of the quantum yield almost linearly depends on the photon
energy and the absorption edge (1.2 V) is close to the bandgap of Si (1.12 eV), which implies that the achieved
signal is attributed to the minority electrons optically excited in the p-Si layer and collected in the n-SiC layer
across the hetero-interfaces. The characteristics of the SiC/Si HBTs reveal the common-base current gain α of ≈0.9 for the base-collector bias voltage of 0 V at room temperature. These results indicate that SiC/Si
hetero-interfaces are applicable for novel minority-carrier-based semiconductor devices.
Electrical Conduction of Si/ITO/Si Junctions Fabricated by Surface Activated Bonding
Jianbo LIANG, Tomoki OGAWA, Kenji ARAKI (Toyota Technological Institute), Takefumi KAMIOKA (Toyota
Technological Institute) and Naoteru SHIGEKAWA
Extended Abstracts of 2017 IEEE International Workshop on Low Temperature Bonding for 3D Integration(LTB-3D), pp.51 (2017)
The electrical properties of n-Si/ITO/n-Si, n-Si/ITO/p-Si, and p-Si/ITO/n-Si junctions fabricated by surface
activated bonding (SAB) were investigated. The current-voltage (I-V) characteristics of n-Si/ITO/n-Si,
n-Si/ITO/p-Si, and p-Si/ITO/n-Si junctions showed excellent linearity. The interface resistance of n-Si/ITO/p-Si
junctions was found to be 0.0249 Ω·cm2, which is the smallest value observed in all the samples.
Impacts of Bonding-layer Resistance of Si Bottom Cells on Interface Resistance in InGaP/GaAs/Si Hybrid
Triple-junction Cells
Naoteru SHIGEKAWA and Jianbo LIANG
Extended Abstracts of 2017 IEEE International Workshop on Low Temperature Bonding for 3D Integration(LTB-3D), pp.52 (2017)
We fabricate InGaP/GaAs/Si hybrid triple-junction (3J) cells with different sheet resistances of bonding layers in
Si bottom cells. We estimate resistances across the p-GaAs/n-Si bonding interfaces of the respective 3J cells bymeasuring the potentials of the bonding layers. We find that the interface resistances are higher in 3J cells with thebonding layers of Si bottom cells with higher sheet resistances.
Electrical Properties of Al-Foil/4H-SiC Schottky Junctions Fabricated by Surface-Activated Bonding
Sho MORITA, Jianbo LIANG, Moeko MATSUBARA (Toyo Aluminum K. K.), Marwan DHAMRIN (ToyoAluminum K. K.), Yositaka NISHIO (Toyo Aluminum K. K.) and Naoteru SHIGEKAWA
Extended Abstracts of 2017 IEEE International Workshop on Low Temperature Bonding for 3D Integration(LTB-3D), pp.68 (2017)17-μm Al-foil/n-4H-SiC Schottky junctions with the foils as contacts are fabricated in order to investigate theimpacts of annealing on their electrical characteristics. By measuring their current-voltage andcapacitance-voltage characteristics, the ideality factor and Schottky barrier height (SBH) are estimated to be 1.31
and 1.37 eV for junctions after annealing at 673 K, respectively.
Analysis of the Influence of Interface Charges on the Electrical Characteristics of GaAs/GaN Junctions
Syoji YAMAJO, Jianbo LIANG and Naoteru SHIGEKAWA
Extended Abstracts of 2017 IEEE International Workshop on Low Temperature Bonding for 3D Integration(LTB-3D), pp.77 (2017)－63－

Electrical properties of p+-GaAs/n-GaN and n+-GaAs/n-GaN, heterojunctions fabricated by using
surface-activated bonding (SAB) are investigated. The measured C-V characteristics of p+-GaAs/n-GaN and
n+-GaAs/n-GaN junctions are in quantitative agreement with modeled ones obtained for the interface states
density and the conduction-band discontinuity of 1.5×1014 cm-2 eV-1 and 0.63 eV, respectively.
Surface-activated Bonding of III-V Compound Semiconductors and Si for Fabricating Hybrid Tandem
Solar Cells
Naoteru SHIGEKAWA and Jianbo LIANG
Extended Abstracts of 2017 International Conference on Electronics Packaging (ICEP 2017) proc. pp. 229-231(2017)The possibility of the surface-activated bonding (SAB) technologies for fabricating III-V-on-Si hybrid tandem
solar cells is discussed. Although the electrical conduction across the bonding interfaces is influenced by theinterface states introduced during the surface-activation process, their impacts are likely to be lowered by
combining more heavily-doped bonding layers and the annealing process after the bonding. InGaP/GaAs/Si
hybrid triple-junction cells are successfully fabricated by bonding III-V heterostructres for InGaP/GaAs
double-junction cells and Si cell structures. This means that the bonding interfaces have an enough tolerance
against the possible stress during the conventional device process sequence and that the SAB is promising as apractical substitute for the conventional semiconductor growth technologies in fabricating III-V-on-Si tandem
cells.
Realization of Direct Bonding of Single Crystal Diamond and Si Substrates
Jianbo LIANG, Satoshi Masuya (Univ. of Saga), Makoto Kasu (Univ. of Saga) and Naoteru SHIGEKAWA
Appl. Phys. Lett. 110, 111603 [4 pages] (2017)
Diamond/Si junctions have been achieved by surface activated bonding (SAB) method without any chemical andheating treatments. Bonded interfaces were obtained that were free from voids and mechanical cracks.
Observations by using transmission electron microscopy indicated that an amorphous layer with a thickness of ∼20 nm across the bonded interface was formed, no structural defects were observed at the interface. The
amorphous layer of the diamond side was confirmed to be the mixture of sp2 and sp3 carbons by electron energy
loss spectroscopy analyzation. The sp3/(sp2 + sp3) ratio estimated from the X-ray photoemission spectra decreased
from 53.8 % to 27.5 %, while the relative intensity of sp2 increased from 26.8 % 72.5 % after the irradiation of Ar
fast beam which should be predominantly attributable to the diamond-graphite conversion.
Research on Output Signal of Piezoelectric Lead Zirconate Titanate Detector Using Monte Carlo Method
Seiji TAKECHI, Tomoaki MITSUHASHI, Yoshinori MIURA, Takashi MIYACHI (Chiba Institute ofTechnology), Masanori KOBAYASHI (Chiba Institute of Technology), Osamu OKUDAIRA (Chiba Institute ofTechnology), Hiromi SHIBATA (Osaka University), Masayuki FUJII (Famscience), Nagaya OKADA (Honda
Electronics), Takeshi MURAKAMI (NIRS) and Yukio UCHIHORI (NIRS)
Nuclear Instruments and Methods in Physics Research A, Vol. 858, pp. 69-72 (2017)
The response of a radiation detector fabricated from piezoelectric lead zirconate titanate (PZT) was studied. The
response signal due to a single 400 MeV/n xenon (Xe) ion was assumed to have a simple form that was composedof two variables, the amplitude and time constant. These variables were estimated by comparing two output
waveforms obtained from a computer simulation and an experiment on Xe beam irradiation. Their values
appeared to be dependent on the beam intensity.
Reaction Mechanisms of Methylene-blue Degradation in Three-dimensionally Integrated Micro-solution
PlasmaTatsuru SHIRAFUJI, Yodai ISHIDA, Ayano NOMURA, Yui HAYASHI and Motonobu GOTO
Jpn. J. Appl. Phys., Vol. 56, 06HF02 (6 pages) (2017)
We have performed matrix-assisted laser desorption ionization time-of-ight (MALDI-TOF) mass spectrometry(MS) on methylene-blue aqueous solutions treated with three-dimensionally integrated micro-solution plasma, inwhich we have acquired the time evolution of mass spectra as a function of treatment time. The time evolution ofmass spectral peak intensities for major detected species has clearly indicated that the parent methylene-blue
molecules are degraded through consecutive reactions. The primary reaction is the oxidation of the parent
molecules. The oxidized species still have two benzene rings in the parent molecules. The secondary reactions are
the separation of the oxidized species and the formation of compounds with one benzene ring. We have also
performed the numerical tting of the time evolution of the mass spectral peak intensities, the results of whichhave indicated that we must assume additional primary reactions before the primary oxidation for better－64－agreement with experimental results.
DOI: 10.7567/JJAP.56.06HF02
Diagnostics of Air-plasma-treated Water Using Fluorescent Reagents
Kentaro NISHIMOTO, Shin-ichi IMAI and Tatsuru SHIRAFUJI
The 34th Symposium on Plasma Processing / The 29th Symposium on Plasma Science for Materials, Jan. 16-18,
2017, Hokkaido University, Sapporo, Hokkaido, Japan, P2-9 (2 pages) (2016)
We have applied fluorescence spectroscopy for detecting peroxynitrite, which may be generated in the water incontact with air plasma. As the fluorescent reagents, we have used aminopheyl fluorescein (APF) andhydroxyphenyl fluorescein (HPF). We have verified that irradiation of 490 nm-light on the aqueous solution withperoxynitrite causes fluorescence around the wavelength of 515 nm. With increasing the treatment time, however,
fluorescence intensity of APF-mixed and HPF-mixed water have shown opposite tendency. These results indicatethat plasma-treated water contains some interference species which cause the same fluorescence around 515 nm.
We have discussed possibility of contribution of H2O2 and HNO3 as the interference species.
Effects of Ambient Gases on Atomic Oxygen Flux from an Atmospheric Pressure Plasma Jet on a Flowing
MediumTatsuru SHIRAFUJI
The 34th Symposium on Plasma Processing / The 29th Symposium on Plasma Science for Materials, Jan. 16-18,
2017, Hokkaido University, Sapporo, Hokkaido, Japan, P1-1 (2 pages) (2016)
We have performed numerical simulation of an atmospheric pressure plasma jet (APPJ) of O2/N2 gas mixture on a
flowing medium. Atomic oxygen flux from the atomic oxygen flux from the APPJ on flowing medium (1 m/s) in
air ambient becomes 10% of that from the APPJ on a static medium. The first cause of this reduction in atomic
oxygen flux is increase in the effective path length from the APPJ nozzle to the target medium surface, which isinevitable. The second cause is the fact that ambient air slip into the gap between the APPJ and medium due to agas drag effect of the medium surface, which is controllable. By changing ambient gas from air to nitrogen, we
can recover atomic oxygen flux from 10% to 30%.
Recognition of Single Japanese Sounds using sEMG Signals and Membership Functions
Hiroki MURAKAMI, Masafumi MURAJI and Tatsuru SHIRAFUJI
IEEJ Transactions on Electronics, Information and Systems, Vol.136, No.12, pp.1821-1826 (2016)
We report a method for recognizing single Japanese sounds including a consonant using surface electromyography(sEMG) signals and membership functions. We focused on six features of the waveforms of four muscles (a totalof 24 indexes) and examined the consistency between the sEMG signals and the distribution of each index
regarded as membership functions. We also introduced π-type membership functions and confirmed an
improvement in the recognition rate (average recognition rate 62.3%, recognition of a series of Japanese syllables
99.1%) by varying the parameter values. These methods allow greater recognition of single Japanese sounds byusers.
Cavity Effect on a Biexciton in a CuCl Microcavity
Yasuyoshi MITSUMORI, Shimpei MATSUURA, Shoichi UCHIYAMA, Keiichi EDAMATSU, and Masaaki
NAKAYAMA
Physical Review B Vol. 94, 115308 (5 pages) (2016)
We studied the population and coherence dynamics of a biexciton in a planar CuCl microcavity. We developed atime-resolved two-photon polarization spectroscopy technique, by which we extracted the population dynamics ofthe biexciton even when the biexciton was spectrally overlapped with the lower cavity polariton. The observed
lifetime of the cavity biexciton in the weak-coupling regime was much shorter than that of a bare CuCl thin film
without a cavity, which directly demonstrates cavity enhancement of the radiative decay rate of the biexciton. The
cavity enhancement originates from the hybridization of the unbound two-cavity-polariton state to the biexciton
wave function by the biexciton-cavity coupling. By comparing the population and coherence decay curves of thebiexciton, we found that the coherence of the cavity biexciton was limited by the radiative population decay.
DOI: 10.1103/PhysRevB.94.115308
Observation of Diffusive and Dispersive Profiles of the Nonequilibrium Polariton-Condensate Dispersion
Relation in a CuBr Microcavity
Masaaki NAKAYAMA and Masafumi UEDA
Physical Review B Vol. 95, 125315 (7 pages) (2017)－65－

We have investigated the dispersion relation of polariton condensates in a CuBr microcavity with the use ofangle-resolved photoluminescence (PL) spectroscopy at 77 K. The polariton condensation was clearly confirmedby the thresholdlike changes in the PL intensity, energy, and bandwidth of the lower polariton at a zero in-planewave-vector k = 0 as a function of excitation power density. A blueshifted flat dispersion of the PL energy
suddenly appeared at the condensation threshold in a small k region accompanied by the dispersion of thenoncondensate PL as a background. With increasing excitation power density from the threshold, the intensity of
the noncondensate PL became negligible. As a result, we found a dispersive profile of the dispersion relation of
the condensate in a large k region in addition to the flat dispersion corresponding to the diffusive profile. The total
dispersion relation of the condensate was explained quantitatively by a theoretical model for nonequilibrium
condensation.
DOI: 10.1103/PhysRevB.95.125315
Initial Process of Photoluminescence Dynamics of Self-Trapped Excitons in a β-Ga2O3 Single Crystal
Suguru YAMAOKA, Yoshiaki FURUKAWA and Masaaki NAKAYAMA
Physical Review B Vol. 95, 094304 (5 pages) (2017)
We investigate the photoluminescence (PL) dynamics of self-trapped excitons (STEs) in a β-Ga2O3 single crystal
from the viewpoint of the transition process from the free exciton to the STE. We succeed in measuring the PL risetime (∼24 ps) at 8 K corresponding to the tunneling time through the barrier between the free exciton and STE
states in the adiabatic potential. From the analysis of the PL rise time of the STE based on perturbation theory forthe tunneling time considering exciton-phonon interactions, we obtain the following results. Acoustic phonons
near the Brillouin zone center contribute to the tunneling process. This suggests that the wave function of the STE
is still spatially extended at the final state in the tunneling process. Furthermore, we investigate temperaturedependence of the PL rise time of the STE. It is found that the PL rise time decreases with increasing temperature.
The PL rise times in the temperature range from 8 to 100 K can be quantitatively explained by an adiabatic theory
for the tunneling process. Consequently, the self-trapping process is dominated by the tunneling process at low
temperatures.
DOI: 10.1103/PhysRevB.95.094304
Polariton-Condensation Effects on Photoluminescence Dynamics in a CuBr Microcavity
Masaaki NAKAYAMA, Katsuya MURAKAMI and Yoshiaki FURUKAWA
Journal of Luminescence, Vol. 191, pp. 68–72 (2017)
Temporal proles of photoluminescence (PL) from the cavity polariton at the ground state in a CuBr microcavity
at 10 K have been investigated from the viewpoint of the cavity-polariton condensation. We measured
angle-resolved reectance spectra to characterize the cavity-polariton dispersions, cavity- photon dispersion, andquality factor from which the intrinsic cavity-polariton lifetime was estimated. The threshold-like changes of the
PL intensity, band width, and energy of the lower polariton as a function of excitation power are consistent withpreviously reported experimental results for the cavity- polariton condensation. It was found that the PL rise anddecay times are markedly decreased by the cavity-polariton condensation, which can be attributed to theappearance of the bosonic nal state stimulation and intrinsic lifetime of polaritons in the relaxation and decay
processes, respectively.
DOI: 10.1016/j.jlumin.2017.02.045
Longitudinal Optical Phonon-Plasmon Coupled Mode in Undoped GaAs/n-Type GaAs Epitaxial Structures
Observed by Raman Scattering and Terahertz Time-Domain Spectroscopic Measurements: Difference inObserved Modes and Initial Polarization Effects
Hideo TAKEUCHI, Takahiro SUMIOKA and Masaaki NAKAYAMAIEEE Transaction on Terahertz Science and Technology, Vol. 7, pp. 124-130 (2017)
We investigated longitudinal optical (LO) phonon-plasmon coupled (LOPC) mode in undoped GaAs/n-type GaAs
epitaxial structures using Raman scattering and terahertz time-domain spectroscopic measurements. In the Raman
measurement, the LOPC mode, the frequency of which is determined by the doped electron density in the n-typelayer, was observed in addition to the LO phonon in the undoped layer. Contrastingly, in terahertz time-domain
measurements, the frequency of the observed coherent LOPC mode is dominated by a photogenerated electron
density: frequency-tunable LOPC mode. This indicates that the LOPC mode is generated in the undoped layer.
Thus, the probing mechanisms for the LOPC mode are different in the Raman and terahertz time-domain
measurements. The built-in electric field exists in the undoped layer. This field enlarges the initial polarization of
the LO phonon and, as a result, enables to observe the coherent LOPC mode generated in the undoped layer withthe use of the terahertz time-domain spectroscopy.

－66－

DOI: 10.1109/TTHZ.2017.2650220
Effects of Photogenerated Carrier Scattering on the Decay Process of Coherent Longitudinal Optical
Phonons in an Undoped GaAs/n-type GaAs Epitaxial Structure Investigated by Terahertz Time-Domain
Spectroscopy
Hideo TAKEUCHI, Takahiro SUMIOKA and Masaaki NAKAYAMA
Journal of Vacuum Science & Technology A Vol.35, 04D104 (6 pages) (2017)
The authors investigated the scattering effect of photogenerated carriers on the decay of the coherent longitudinal
optical (LO) phonons in an undoped GaAs/n-type GaAs epitaxial structure using a terahertz time-domain
spectroscopic technique. The terahertz wave from the coherent LO phonon was observed together with thoseemitted both by the ultrafast photocurrent and by the coherent LO-phonon-plasmon coupled (LOPC) mode. The
simultaneous observation of the coherent LO phonon and coherent LOPC mode originates from the fact that thephotogenerated carrier density laterally distributes around the surface of the undoped GaAs layer owing theGaussian profile of the pump beam. The authors found that the terahertz wave from the coherent LO phonon lives
up to 5.0 ps, whereas those from the coherent LOPC mode and ultrafast photocurrent disappear within 1.0 ps. The
decay time of the coherent LO phonon monotonically decreases with an increase in the pump power. This finding
indicates that the dephasing of the terahertz wave from the coherent LO phonon is dominated by thephotogenerated carrier scattering in the time range shorter than 1.0 ps in which photogenerated carriers remain.
DOI: 10.1116/1.4983637
Controls of Electronic Structures and Phonon Dynamics in Quantum Dot Superlattice by Manipulating
Interior Nano Space
I-Ya CHANG, DaeGwi KIM and Hyeon-Deuk KIM
ACS Appl. Mater. Interfaces Vol. 8, pp. 18321-18327 (2016)
Quantum dot (QD) superlattice, a periodically ordered array structure of QDs, is expected to provide novel
photo-optical functions owing to resonant couplings between adjacent QDs. Here, we computationallydemonstrated that electronic structures and phonon dynamics of QD superlattice can be effectively and selectively
controlled by manipulating its interior nano space where quantum resonance between neighboring QDs appears
rather than by changing component QD size, shape, compositions, etc. A simple H-passivated Si QD was
examined to constitute one-, two- and three-dimensional QD superlattice, and thermally fluctuating band energies
and phonon modes were simulated by finite-temperature ab initio molecular dynamics (MD) simulations. The QD
superlattice exhibited decrease of the band-gap energy enhanced by thermal modulations and also selective
extraction of charge carriers out of the component QD, indicating its advantage as a promising platform to be
implemented in solar cells. Our dynamical phonon analyses based on the ab initio MD simulations revealed thatTHz-frequency phonon modes were created by inter-QD crystalline lattice formed in the QD superlattice, which
can contribute to thermoelectric conversion of low energy and will be useful for direct observation of thedimension-dependent superlattice. Further, we found that crystalline and ligand-originated phonon modes insideeach component QD can be independently controlled by asymmetry of the superlattice and by restriction of theinterior nano space, respectively. Taking into account the thermal effects at the finite temperature, we proposed
guiding principles for designing efficient and space-saving QD superlattice to develop functional photovoltaic andthermoelectric devices.
DOI: 10.1021/acsami.6b03219
Synthesis of Type-I CdTe Core and Type-II CdTe/CdS Core/Shell Quantum Dots by a Hydrothermal
Method and Their Optical Properties
Taichi WATANABE, Kohji TAKAHASHI, Kunio SHIMURA, Hang-Beom BU, Hyeon-Deuk KIM and DaeGwi
KIM
Bull. Chem. Soc. Jpn. Vol.90, pp. 52-58 (2017)
CdTe and CdTe/CdS quantum dots (QDs) weresynthesized via hydrothermal method in one-step processes just bycontrolling a reaction time. A gradual thermal decomposition of thiol ligand N-acetyl-L-cysteine results information of a CdS shell on a CdTe core. The experimental results of X-ray diffraction and energy dispersive
X-ray spectroscopy indicated that growth of the CdS shell started in a longer reaction time than 30 minutes andthat the thickness of the CdS shell increased with increasing the reaction time. The CdTe/CdS QD exhibited alonger photoluminescence-decay time than the CdTe core QD due to the type-II band alignment, and the decay
time in the CdTe/CdS QDs increased with an increase in the reaction time. The increase in the decay time in the
CdTe/CdS QDs was qualitatively reproduced by a decrease in an overlap integral of electron and hole wave
functions caused by an increase of the CdS shell thickness.

－67－

DOI:10.1246/bcsj.20160299
Microwave-Assisted Hydrothermal Synthesis of Highly Luminescent ZnSe-Based Quantum Dots with a
Quantum Yield Higher than 90%
Yong-Shin LEE, Kaoru, NAKANO, Hang-Beom BU and DaeGwi KIM
Appl. Phys. Express Vol. 10, 065001 (4 pages) (2017)
Highly luminescent ZnSe-based quantum dots (QDs) were synthesized by a microwave-assisted hydrothermal
method. The characteristics of the ZnSe precursor solution strongly influenced the photoluminescence (PL)quantum yields (QYs) of the QDs. The PL QY of ZnSe-core QDs synthesized under the optimum conditions
reached 60%. Furthermore, the PL QY further increased to higher than 90% when a ZnS shell was applied toprepare ZnSe/ZnS-core/shell QDs.
DOI:10.7567/APEX.10.065001
Influence of Carrier Localization at the Core/Shell Interface on the Temperature Dependence of the Stokes
Shift and the Photoluminescence Decay Time in CdTe/CdS type-II Quantum DotsTaichi WATANABE, Kohji TAKAHASHI, Kunio SHIMURA and DaeGwi KIM
Phys. Rev. B Vol. 96, 035305 (7 pages) (2017)
We have systematically investigated the temperature dependence of absorption, photoluminescence (PL), and PL
decay profiles in CdTe-core and CdTe/CdS type-II quantum dots (QDs). In CdTe/CdS QDs, Stokes shifts and PL
decay time become larger with an increase in temperature above 120 K, while those in CdTe-core QDs are almost
independent of temperature. The unusual temperature dependence of Stokes shifts and PL decay time in
CdTe/CdS QDs is understood by considering carrier localization at the core/shell interface at low temperatures
and thermal-energy-assisted detrapping from localized-exciton to type-II-exciton states at higher temperatures.
Furthermore, a phenomenological rate equation model is developed to explain the experimentally observed
temperature-dependent PL decay time.
doi: 10.1103/PhysRevB.96.035305
Control of Multiple Exciton Generation and Electron-Phonon Coupling by Interior Nano Space inHyper-Structured Quantum Dot Superlattice”
I-Ya CHANG, DaeGwi KIM and Hyeon-Deuk KIM
ACS Appl. Mater. Interfaces, in press
Possibility of precisely manipulating interior nano space, which can be adjusted by ligand attaching down tosubnanometer regime, in hyper-structured quantum dot superlattice (QDSL) induces a new kind of collective
resonant couplings among QDs and opens new opportunities for developing advanced optoelectric andphotovoltaic devices. Here, we report the first real-time dynamics simulations of the multiple exciton generation(MEG) in one-, two- and three-dimensional (1D, 2D, and 3D) hyper-structured H-passivated Si QDSL accounting
for thermally fluctuating band energies and phonon dynamics obtained by finite-temperature ab initio molecular
dynamics simulations. We computationally demonstrated that the MEG was significantly accelerated especially inthe 3D QDSL compared to the 1D and 2D QDSL. The MEG acceleration in the 3D QDSL became almost 1.9
times in comparison with the isolated QD case. The dimension-dependent MEG acceleration was attributed not
only to the static density of states but also to the dynamical electron-phonon couplings depending on thedimensionality of the hyper-structured QDSL, effectively controlled by the interior nano space. Suchdimension-dependent modifications originated from the short range quantum resonance among component QDs
and were intrinsic to the hyper-structured QDSL. We propose that photoexcited dynamics including the MEG
process can be effectively controlled by only manipulating the interior nano space of the hyper-structured QDSL
without changing component QD size, shape, compositions, ligand, etc.

－68－Electric and Information Engineering
Portrait and Landscape Mode Convertible Stereoscopic Display Using Parallax Barrier
Yusuke MINAMI, Goro HAMAGISHI, Kayo YOSHIMOTO and Hideya TAKAHASHI
Proc. IS&T Int. Symp. Electronic Imaging 2017 Stereoscopic Display and Applications XXVIII, San
Francisco, Jan. 31, pp.106-112 (2017)
We propose a tablet type stereoscopic display. It features moire free and low crosstalk ratio. The proposedsystem consists of parallax barriers, a tablet type liquid crystal display (LCD) and stereo cameras. A tablet
type display has two display modes, portrait and landscape. It is necessary to realize same viewing distanceboth portrait and landscape modes. Therefore, it is difficult to observe high quality stereoscopic image byusing tablet type display. In proposed system, the same parallax barriers are used both portrait and landscapemodes. Therefore, viewing distance of the system is constant regardless of whether the LCD is portrait orlandscape. We constructed the prototype system to verify the effectiveness of the proposed system. We used
15.6 inch 4K display as an LCD for tablet. By realizing new stereoscopic image arrangement that wasdifferent from between in portrait and landscape modes, we can see stereoscopic images with the slanted
barriers with the same specifications. We confirmed that viewing distance is constantly 207.375 mm andmoire patterns are not generated on its image. Additionally, max crosstalk ratio is 6.56 % at portrait modeand 14.00 % at landscape mode.
Analysis of Retinal Images for Retinal Projection Type Super Multi-view 3D Head-mounted Display
Takashi EMOTO, Tadayuki KONDA, Kayo YOSHIMOTO and Hideya TAKAHASHI
Proc. IS&T Int. Symp. Electronic Imaging 2017 Stereoscopic Display and Applications XXVIII, San
Francisco, Feb. 1, pp.188-193 (2017)
In the augmented reality technology, what a viewer sees needs to be augmented by 3D information inaccordance with the real object. Thus, we have previously proposed a retinal projection type super multiview HMD which provides a viewer with natural 3D images. However, the proposed HMD has two
problems. One is whether the blurred retinal image of the real 3D object is equal to the superimposedparallax images of the virtual 3D image. The other one is the restricted depth range of 3D images. When theparallax difference is large and corresponding pixels of parallax images do not overlap each other, we cannot
use the superimposed parallax images instead of the blurred image. In this paper, we theoretically consider
above problems and verify the effectiveness of the super multi-view HMD. By simulation the light intensity
distributions of retinal images, we confirmed that the superimposed parallax images was equal to the blurred
image. Moreover, from the range of the suitable parallax difference, we verified the depth range of the 3D
image by the proposed HMD was more than 113 mm in front of the pupil.
Evaluation of Endoscopic Entire 3D Image Acquisition of the Digestive Tract Using a Stereo
Endoscope
Kayo YOSHIMOTO, Kenji WATABE (Osaka University), Tetsuji FUJINAGA (Osaka University), Hideki
IIJIMA (Osaka University), Masahiko TSUJII (Osaka University), Hideya TAKAHASHI, Tetsuo
TAKEHARA (Osaka University) and Kenji YAMADA (Osaka University)
Proc.SPIE Advanced Biomedical and Clinical Diagnostic and Surgical Guidance Systems XV, San Francisco,Feb. 14, Vol.10054, CD-ROM (2017).
Because the view angle of the endoscope is narrow, it is difficult to get the whole image of the digestive tract
at once. If there are more than two lesions in the digestive tract, it is hard to understand the 3D positional
relationship among the lesions. Virtual endoscopy using CT is a present standard method to get the wholeview of the digestive tract. Because the virtual endoscopy is designed to detect the irregularity of the surface,it cannot detect lesions that lack irregularity including early cancer. In this study, we propose a method of
endoscopic entire 3D image acquisition of the digestive tract using a stereo endoscope. The method is asfollows: 1) capture sequential images of the digestive tract by moving the endoscope, 2) reconstruct 3D
surface pattern for each frame by stereo images, 3) estimate the position of the endoscope by image analysis,4) reconstitute the entire image of the digestive tract by combining the 3D surface pattern. To confirm thevalidity of this method, we experimented with a straight tube inside of which circles were allocated at equal
distance of 20 mm. We captured sequential images and the reconstituted image of the tube revealed that the
distance between each circle was 20.2 ± 0.3 mm (n=7). The results suggest that this method of endoscopic－69－

entire 3D image acquisition may help us understand 3D positional relationship among the lesions such as
early esophageal cancer that cannot be detected by virtual endoscopy using CT.
A Novel Approach on Infant Facial Pain Classification using Multi Stage Classifier and GeometricalTextural Features Combination
Yosi Kristian (ITS), Hideya Takahashi, I Ketut Eddy Purnama (ITS), Kayo Yoshimoto, Esther Irawati
Setiawan (ITS), Elizeus Hanindito (ITS) and Mauridhi Hery Purnomo (ITS)
IAENG International Journal of Computer Science, vol.44, no.1, pp.112-121 (2017).
Infants are unable to communicate pain, they cry to express their pain. In this paper we describe the mosteffective feature for infant facial pain classification. The image dataset was classified by medical doctors andnurses based on cortisol hormone difference and FLACC (Face, Legs, Activity, Cry, Consolability)
measurement. In this paper we try a number of features based on Action Unit (AU) for infant facial painclassification and discover that the best features are combination between geometrical and textural features.
We trained our own Active Shape Model (ASM) and extracted the geometrical features based on landmark
points found by our ASM. The textural features are extracted using Local Binary Patterns (LBP) frommultiple facial patches. We also experiment with two stage pain classification preceded by a cry detection
system, and concluded that this scenario combined with geometrical and textural feature produce a very highF1 score for infant facial pain classification.
A Fundamental Study on Vessel Depth Estimation Based on Refocusing Using Light Field Imaging
Kayo YOSHIMOTO, Hideya TAKAHASHI and Kenji YAMADA (Osaka University)
International Journal of Applied Biomedical Engineering, vol.9, no.1, pp.1-6 (2016).
Venipuncture is a medical practice which is ordinarily performed in hospital. However, it is a difficult
procedure as the occurrence of many failure of the puncture and sometimes medical accidents such as nerve
damage and blood vessel damage are reported. This is caused by the difficulty of visually identification of
the blood vessel. Although the depth information of the blood vessel is also important, the existing system inclinical practice can visualize vessels only by two dimensional images. In this paper, to estimate the three
dimensional position of the blood vessel, we propose the system based on refocusing using light fieldimaging. This method can obtain cross-sectional information of blood vessel emphasized using near infrared
light at each depth. We finally confirm the validity of the proposed method by using blood vessel simulated
object and human finger.
Aerial Volumetric Image Display Based on Retroreflective Imaging and Optical Scanning with a
Slanted Rotating Mirror
Daisuke MIYAZAKI, Rina TAMAKI and Takaaki MUKAIThe 23rd International Display Workshops, Fukuoka, Dec. 7-9, 3DSA7 - 1 (2016)
Imaging based on retroreflection can provide aerial image formation with a wide view angle and lowdistortion in spite of high numerical aperture. A floating volumetric display technology based on
retroreflection with a dihedral corner reflector array and optical scanning with a slanted rotating mirror aredescribed.
Floating Three-Dimensional Display with a Lenticular Sheet and a Dihedral Corner Reflector Array
Yuma TOKUBO, Daisuke MIYAZAKI and Takaaki MUKAI
Information Photonics 2017, Yokohama, April 19, IP-21PM-1-6 (2017)
In a conventional autostereoscopic display with a lenticular sheet, blurring of a three-dimensional (3D)
image increases as the depth distance of the 3D image from the display increases. In addition, the 3D image
position changes depending on observing position. In this report, we propose an aerial 3D display combined
multiview dispay with a lenticular sheet and floating image formation with a dihedral corner reflector array.
This method can form a 3D image at a fixed position in the air with the simple composition. By combining a
motion sensor for human hands, the interaction between an aerial image and a user is allowed, and an
intuitive interface can be achieved.
Pulsed Power Network with Power Sources and Consumers Operated on Exhibition Table
Hisayoshi SUGIYAMA－70－

2017 14th IEEE Annual Consumer Communications & Networking Conference (CCNC), Las Vegas, USA,
Jan. 8, pp.571-572 (2017)
A mini-scaled pulsed power network operation is demonstrated. This scheme of smart grid was proposed in
my previous papers and the basic operation was already demonstrated. In this exhibition, an advanced
performance of the pulsed power network is demonstrated where electric pulses are autonomouslytransmitted among users according to current demands of consumers through pre-reserved transmission paths.
Reliability of the decentralized control is also demonstrated against power router failures.
Influence of Packetized Electric Power Transmission on Radio Wave Environment
Hisayoshi SUGIYAMA
2017 IEEE International Conference on Consumer Electronics - Taiwan (ICCE-TW), Taipei, Taiwan, June12, pp.195-196 (2017)
Influence of packetized electric power transmission on radio wave environment is investigated. In contrast toconventional power transmission with continuous electric current of low frequency sine wave, packetized
power transmission may affect surrounding field with high frequency radio noises. In this paper, based on
the analysis of electric field strength around a power line, the radio noises generated by various packetized
power transmissions are evaluated. Pulse trains in synchronized frame structure of pulsed power network is
adopted as the power packet signals. As the results, though the total of generated radio power exceeds that ofconventional power transmissions, peak strength of electric field rather falls behind the conventional one.

Localized Pulsed Power Network for Distributed Generations and Consumers

Hisayoshi SUGIYAMA
2017 EMN Europe Meetings of Smart Grid Technology, Barcelona, Spein, Sep. 11, (2017)
As one of the upcoming smart grids, pulsed power network is proposed to distribute electric power
effectively over the consumers. In this scheme, time axis is equally divided into frames synchronized overthe network, and each frame is subdivided into N power slots. Power transmission is decomposed into a
series of electric pulses at specified power slots in successive frames. These power slots are pre-reserved
throughout the power transmission path by associated nodes with decentralized algorithm. Intermediate
power routers directly relays the power transmission without additional relay loss. This scheme of pulsed
power network has affinity with distributed generations and high reliability based on decentralized system
control. With this scheme, localized power network can be established where consumers are supplied power
only by distributed generations. This localized power network is applicable to communities remote from bulk
power generations and to isolated areas such as large ships or space stations.
This paper introduces the scheme of pulsed power network and proposes a system operation procedure forthe localized systems. The proposed procedure satisfies the inherent requirements of the power network.
First, the establish of a new power transmission path is triggered by a consumer demand occurring. Second,the consumer can receive power from multiple generations simultaneously. Overview of the proposed
procedure and simulation results are described.
Pulsed Power Network with Inherent Operating Procedure and Multiple Relaying of Power Routers
Hisayoshi SUGIYAMA, Mami CHATANI, Ryousuke SIMIZU and Kenji YASUI2017 IEEE Global Conference on Consumer Electronics (GCCE), Nagoya, Japan, Oct. 24, (2017)
Pulsed power network is one of the alternatives of smart grid systems. This scheme is applicable especiallyto localized power grid where only distributed generations supply power to consumers. In this demonstration,a miniature model of the localized pulsed power network is constructed and performed with two distributed
generations, four consumers, and eight power routers. This model is operated with inherent procedure for
effective power distribution over consumers and with multiple relaying of power routers for enhanced powertransmission capacity.
Power Transmission Procedure for Localized Pulsed Power Network with Distributed Generations
and Consumers
Hisayoshi SUGIYAMA
2017 IEEE Global Conference on Consumer Electronics (GCCE), Nagoya, Japan, Oct. 24, (2017)
A power transmission procedure is proposed for localized pulsed power networks that consist of distributed－71－generations and consumers. The pulsed power network has affinity with distributed generations and highreliability based on decentralized system control. With this scheme, power networks can be operated where
consumers are supplied power by distributed generations only. With the proposed procedure, as the inherent
requirements of the power networks, the establish of a new power transmission path is triggered by aconsumer demand occurring, and the consumer can receive power from multiple generations simultaneously.
Simulations confirm the system performance.

－72－

Applied Chemistry and Bioengineering
Photocatalytic Water Oxidation by Persulphate with a Ca2+ Ion-Incorporated Polymeric Cobalt
Cyanide Complex Affording O2 with 200% Quantum Efficiency
Yusuke YAMADA, Kohei OYAMA, Tomoyoshi SUENOBU and Shunichi FUKUZUMI
Chem. Commun., Vol. 53, pp. 3418-3421 (2017)
Incorporation of a small amount of Ca2+ ions into a polymeric cobalt cyanide complex to form
Cax[CoII(H2O)2]1.5-x[CoIII(CN)6] resulted in a significant enhancement of activity for photocatalytic wateroxidation in a buffer solution (pH 7.0) containing [Ru(bpy)3]2+ (bpy = 2,2’-bipyridine) as a photocatalyst andNa2S2O8 as an electron acceptor to achieve a quantum efficiency of 200%.
Dual Function Photocatalysis of Cyano-Bridged Heteronuclear Metal Complexes for Water Oxidation
and Two-Electron Reduction of Dioxygen to Produce Hydrogen Peroxide as a Solar Fuel
Yusuke ARATANI, Tomoyoshi SUENOBU, Kei OHKUBO, Yusuke YAMADA and Shunichi FUKUZUMI
Chem. Commun., Vol. 53, pp. 3473-3476 (2017)
The photocatalytic production of hydrogen peroxide from water and dioxygen under visible light irradiation
was made possible by using polymeric cyano-bridged heteronuclear metal complexes (MII[RuII(CN)4(bpy)];
MII = NiII, FeII and MnII), where the photocatalytic two-electron reduction of O2 and water oxidation were
catalysed by the Ru and MII moieties, respectively.
Heterogeneous Catalase-Like Activity of Gold(I)–Cobalt(III) Metallosupramolecular Ionic Crystals
Mihoko YAMADA, Nobuhito YOSHINARI, Naoto KUWAMURA, Toru SAITO, Satoshi OKADA, Sai P.
MADDALA, Koji HARANO, Eiichi NAKAMURA, Kohei YAMAGAMI, Keisuke YAMANAKA, Akira
SEKIYAMA, Tomoyoshi SUENOBU, Yusuke YAMADA and Takumi KONNO
Chem. Sci., Vol. 8, pp. 2671-2676 (2017)
Unique heterogeneous catalase-like activity was observed for metallosupramolecular ionic crystals[AuI4CoIII2(dppe)2(D-pen)4]Xn ([1]Xn; dppe: 1,2-bis(diphenylphosphino)ethane; D-pen: D-penicillaminate;
Xn: (Cl–)2, (ClO4–)2, (NO3–)2 or SO42–) consisting of AuI4CoIII2 complex cations, [1]2+, and inorganic anions, X
or X2 . Treatment of the ionic crystals with an aqueous H2O2 solution led to considerable O2 evolution with ahigh turnover frequency of 1.4 x 105 h–1 for the heterogeneous cobalt complexes, which was dependent on
their size and shape as well as the arrangement of cationic and anionic species. These dependencies wererationalized by the presence of cobalt(II) centers on the crystal surface and their efficient exposure on the(111) plane rather than the (100) plane based on morphological and theoretical studies.
Synthesis of CuPd Alloy Nanoparticles with High Efficacy for Aqueous Phase Catalytic Reduction of
Nitroaromatics and Hexavalent Chromium
Himadri SAIKIA, Biraj J. BOTRAH, Yusuke YAMADA and Pankaj BHARALI
J. Colloid Interface Sci., Vol. 486, pp. 46-57 (2017)
We report a surfactant-free, economically feasible chemical route to synthesize bimetallic CuPd alloy
nanoparticles under hydrothermal conditions. The structural and morphological characterizations of thenanoparticles are carried out by XRD, SEM/EDX, TEM, XPS and BET surface area analysis. The synthetic
strategy comprises of 9:1 molar composition of Cu2+ and Pd2+ salt in the aqueous solution. The size of thenanoparticles is found within 3-4 nm with very notable specific surface area of 298 m2g−1. The synthesized
nanoparticles exhibit excellent catalytic performance towards the aqueous phase reduction of 4-nitrophenol
and 4-nitroaniline in the presence of NaBH4 as a reducing agent and the conversion of toxic Cr(VI) to lesstoxic Cr(III) at room temperature. The bimetallic CuPd alloy nanoparticles are found to be catalytically more
active and exhibit good recyclability corresponding to the monometallic Cu and Pd.
Utilization of Polymeric Cyano-Bridged Metal Complexes as Heterogeneous Catalysts
Yusuke YAMADA
Bull. Jpn. Soc. Coord. Chem., Vol. 68, pp. 16-28 (2016) (in Japanese)
Recent reports on utilization of polymeric cyano-bridged metal complexes, which have reticular structuresutilizing MC–CN–MN coordination networks, as heterogeneous catalysts have been reviewed. Among the－73－

complexes, the most widely investigated ones contain zinc ions at MN sites acting as Lewis acid, wherepolymerization of epoxide such as propylene oxide, esterification of fatty acids, and hydrolysis of glycerides
are catalyzed. Another class of complexes containing redox active transition metals such as iron (II), cobalt(II) and copper (II) at MN sites, catalyze oxidation and reduction reactions. Some complexes thermally
oxidize benzene and styrene to phenol and styrene oxide with hydrogen peroxide, respectively. Additionally,some complexes can also photocatalyze Fenton reaction to decompose organic dyes with hydrogen peroxide,
benzene oxidation to phenol with molecular oxygen, and water oxidation to evolve dioxygen together with aphotosensitizer. All the complexes allow the improvements to achieve highly active catalysts based on
atomic insights with various manners.
Efficient Photocatalytic Production of Hydrogen Peroxide from Water and Dioxygen with Bismuth
Vanadate and Cobalt(II) Chlorin Complex
Kentaro MASE, Masaki YONEDA, Yusuke YAMADA and Shunichi FUKUZUMIACS Energy Lett., Vol. 1, pp. 913-919 (2016)
Efficient photocatalytic production of H2O2 as a promising solar fuel from H2O and O2 in water has beenachieved by the combination of bismuth vanadate (BiVO4) as a durable photocatalyst with a narrow band
gap for the water oxidation and a cobalt chlorin complex (CoII(Ch)) as a selective electrocatalyst for thetwo-electron reduction of O2 in a two-compartment photoelectrochemical cell separated by a Nafion
membrane under simulated solar light illumination. The concentration of H2O2 produced in the reaction
solution of the cathode cell reached as high as 61 mM, when surface- modified BiVO4 with iron(III)oxide(hydroxide) (FeO(OH)) and CoII(Ch) were employed as a water oxidation catalyst in the photoanodeand as an O2 reduction catalyst in the cathode, respectively. The highest solar energy conversion efficiency
was determined to be 6.6% under simulated solar illumination adjusted to 0.05 sun after 1 h of photocatalytic
reaction (0.89% under 1 sun illumination). The conversion of chemical energy into electric energy was
conducted using H2O2 produced by photocatalytic reaction by an H2O2 fuel cell, where open-circuit potential
and maximum power density were recorded as 0.79 V and 2.0 mW cm−2, respectively.
Hydrogen Peroxide Used as a Solar Fuel in One-Compartment Fuel Cells
Shunichi FUKUZUMI and Yusuke YAMADA
ChemElectroChem, Vol. 3, pp. 1978-1989 (2016)
Clean and highly efficient production of solar fuels as well as effective methods to store solar fuels have long
been sought to solve global energy and environmental issues. Among solar fuels such as gaseous hydrogenand carbon monoxide, aqueous hydrogen peroxide (H2O2) is an ideal chemical for energy storage, because
endothermic H2O2 decomposition produces only water and oxygen. In addition, H2O2 can be transported inplastic containers with a high energy density. H2O2 can be converted into electricity by using H2O2 fuel cells
without a membrane and composed of an anode and a cathode, and they can selectively catalyze H2O2
oxidation or reduction. The one-compartment structure without a membrane is more promising to develop
low-costing fuel cells than a two-compartment structure with expensive membranes. This article provides a
focused review of recent developments and future perspectives of H2O2 fuel cells without membranes,
combined with H2O2 production from seawater and dioxygen in the air by utilizing solar energy.
An Effective Preparation Method of Composite Photocatalysts for Hydrogen Evolution Using an
Organic Photosensitizer and Metal Particles Assembled on Alumina-Silica
Yusuke YAMADA, Hideyuki TADOKORO and Shunichi FUKUZUMICatal. Today, Vol. 278, pp. 303-311 (2016)
Composite catalysts for photocatalytic hydrogen (H2) evolution were prepared by loading an organic electron
donor–acceptor linked dyad [2-phenyl-4-(1-naphthyl)quinolinium ion, QuPh+–NA] as an organic
photosensitizer and Pt or Cu particles as H2-evolution catalysts on alumina-silica. The composite catalysts
loading Pt particles were prepared by two different methods; first, Pt particles were deposited by reduction of
PtCl62− owing to photocatalysis of QuPh+–NA supported on alumina-silica (PD method), and second,
alumina-silica was impregnated with the PtCl62− and calcined, and then QuPh+–NA was loaded on thePt/alumina-silica by a cation exchange method (IMP method). When a composite catalyst was prepared by
the IMP method, a high Pt-loading amount of 4.2 wt% was necessary to achieve the highest H2-evolution
rate of 0.27 mol h−1. On the other hand, a composite catalyst prepared by the PD method exhibited three－74－

times faster H2 evolution (0.83 mol h−1) even though the loading amount of Pt was as low as 0.4 wt%. The
activity of composite catalysts prepared by the PD method highly depends on the electric charges ofprecursors for Pt particles. A composite catalyst prepared with positively charged Pt(NH3)42+ as a precursorof Pt particles exhibited low catalytic activity with the H2-evolution rate of 0.10 mol h−1, which issignificantly lower than the rate (0.27 mol h−1) for the composite catalyst prepared with PtCl62−. However,such precursor-dependence was not observed for composite catalysts employing Cu particles as an
H2-evolution catalyst, because the Cu precursors are more labile than the Pt precursors in a reaction solution.
The electrostatic interaction between the precursors of metal particles and negatively charged surfaces ofalumina-silica should be taken into account to construct efficient H2-evolution catalysts.
Development and Evaluation of Full Field Type EDXRF Imaging Instrument
Yuki TAKIMOTO, Masaki YAMANASHI, Francesco Paolo ROMANO and Kouichi TSUJI
Adv. X-Ray. Chem. Anal., Japan, Vol. 48, pp. 159-168 (2017) (in Japanese)
Energy dispersive X-ray fluorescence (EDXRF) is a nondestructive method for simultaneously analyzing
multi elemental composition. To obtain a 2D elemental image, scanning type XRF imaging with a micro
X-ray beam has been applied. In this case, the spatial resolution is very high. However, the drawback of thismethod is a long measurement time if a measurement area is large. In contrast, a full field type imaging
technique is expected to obtain a large elemental image in a short time. Then, EDXRF imaging instrumentwith an X-ray CCD camera was evaluated as one of the tools to obtain information about elemental
distribution of a specimen. This work describes the performance of the present EDXRF imaging instrument
regarding such as spatial resolution and limit of detection. Finally, XRF images of practical samples weretried to be obtained.
Application of Principal Component Analysis for Improvement of X-Ray Fluorescence Images
Obtained by Polycapillary-Based Micro-XRF Technique
Shota AIDA, Tsuyoshi MATSUNO, Takeshi HASEGAWA and Kouichi TSUJI
Nucl. Instrum. Methods Phys. Res., Sect. B, Vol. 402, pp. 267-273 (2017)
Micro X-ray fluorescence (micro-XRF) analysis is repeated as a means of producing elemental maps. In
some cases, however, the XRF images of trace elements that are obtained are not clear due to highbackground intensity. To solve this problem, we applied principal component analysis (PCA) to XRF spectra.
We focused on improving the quality of XRF images by applying PCA. XRF images of the dried residue ofstandard solution on the glass substrate were taken. The XRF intensities for the dried residue were analyzed
before and after PCA. Standard deviations of XRF intensities in the PCA-filtered images were improved,
leading to clear contrast of the images. This improvement of the XRF images was effective in cases where
the XRF intensity was weak.
In-Situ Observation of Corrosion Process of Steel Sheet in a Solution by Confocal Micro XRF
Technique
Ryohei HOSOMI, Jigi CHIN, Takashi DOI, Koji AKIOKA and Kouichi TSUJI
Bunseki Kagaku, Vol. 66, pp. 713-718 (2017) (in Japanese)
X-ray fluorescence (XRF) analysis is the technique which can carry out element analysis with
non-destructive and non-contact. In our laboratory, a confocal micro-XRF method has been developed. This
instrument can detect X-ray fluorescence which appeared in specific micro space by attaching thepolycapillary X-ray lens to the X-ray tube and the detector. In this paper, we applied this technique for in-situ
observation of corrosion process of steel sheet in a solution. In our research, we made up the sample cell for
in-situ observation at solid-liquid interfaces. The steel sheet was immersed in water solution in the sample
cell. As a result, coating blister occurred on the surface of the steel sheet. The corrosion process of the steel
sheet could be observed by acquiring the elemental mapping images near the solid -liquid interface.
X-Ray Fluorescence Imaging
Kouichi TSUJI
In Introduction to Analytical Techniques for Iron and Steel Part III, The Iron and Steel Institute of Japan, pp.
113-119 (2017) (in Japanese)A non-destructive elemental imaging is important for environmental, forensic, and material sciences. To－75－

obtain XRF elemental images, two approaches have been studied; scanning and projection types. Advantages
and drawbacks of both techniques are discussed. In the scanning XRF technique, production of micro X-ray
beam is important. A polycapillary optics is useful for this purpose, especially in the laboratory. XRF
analysis is performed as the sample stage is moved to the fixed micro X-ray beam, leading to XRF elemental
mapping. By applying confocal setup, 3D elemental analysis is also possible. The drawback of the scanning
type XRF imaging would be a long acquisition time, although elemental images with high spatial resolution
are obtained. A projection type XRF imaging has also been studied. WD-XRF imaging spectrometer wasdeveloped by using WDS spectrometer, a straight polycapillary optics, and X-ray CCD camera. The
advantage of WD-XRS is a high energy-resolution, approximately 40 eV. Rapid elemental imaging isachieved in a short time less than 1 s by using highly sensitive 2D X-ray detector.
Perspective of Analytical Chemistry Applied to Various Fields
Kouichi TSUJI
Perspective and topics of 77th discussion on analytical chemistry, The Japan Society for Analytical
Chemistry p. 2 (2017) (in Japanese)
X-Ray Technology
Kouichi TSUJI
In Kirk-Othmer Encyclopedia of Chemical Technology, John Wiley & Sons, Inc., total pages 36, in press(2017)
Analytical X-ray instruments are used to characterize materials in several ways. There are analytical
instruments that can produce images of the internal structure of objects that are opaque to visible light. There
are instruments used to determine chemical composition of an object, the crystalline phases of solids, and thecomplete atomic and molecular structure of a single crystal. The determination of particle size, structural
information for fivers and polymers and the study of stress, texture, and thin films are applications that are
growing in importance and can be examined with X-ray instruments. This article gives information on thecharacterization, generation, and properties of X-rays, and principles of X-ray diffraction. Small moleculeand macromolecule single-crystal structure determinations are discussed. These techniques are comparedwith powder diffraction. X-ray reflectometers, position sensitive detectors, and area detectors are some of thespecial instruments designed to measure properties of the new and exotic materials being manufactured.
Details on X-ray fluorescence spectrometry and X-ray radiography are also given.
Photocatalytic Reduction of CO2 by Pt-Loaded TiO2 in the Mixture of Sub- and Supercritical Water
and CO2
Noritsugu KOMETANI, Shoutarou HIRATA and Masaaki CHIKADA
J. Supercrit. Fluids, Vol. 120, pp. 443-447 (2017)
Photocatalytic reduction of CO2 by Pt-loaded TiO2 in the mixture of CO2 and water has been examined as afunction of temperature and pressure up to 400 °C and 30 MPa. The abrupt increase in the yields of CO, CH4,HCOOH and HCHO was observed as temperature was elevated from 300 to 400 °C at a constant pressure of
30 MPa. This is attributed to the formation of uniform single phase mixture of water and CO2 under
supercritical condition, leading to the enhanced efficiency of CO2 reduction. In contrast, the yield of H2
produced by water reduction showed a monotonous increase with temperature because of the thermal
acceleration of photocatalytic reaction. It is suggested that the control of the phase state of reaction medium
has a key role in the determination of conversion efficiency for the photocatalytic reduction of CO2 withwater.
Catalytic Enantioselective Aza-Diels-Alder Reactions of Unactivated Acyclic 1,3-Dienes with Aryl-,
Alkenyl-, and Alkyl-Substituted Imines
Yasuo HATANAKA, Shuuto NANTAKU, Yuhki NISHIMURA, Tomoyuki OTSUKA and Tohru
SEKIKAWA
Chem. Commun., Vol. 53, pp. 8996-8999 (2017)
Catalytic enantioselective aza-Diels-Alder reaction of unactivated acyclic dienes with aryl-, alkenyl-, andalkyl-substituted imines is described. With 5-10 mol % loadings of new Brønsted acid catalyst, theaza-Diels-Alder reaction of unactivated acyclic dienes proceeded to give the corresponding aza-Diels-Alder－76－

adducts in high yields (up to 98%) with excellent enantioselectivity (up to 98% ee). Preliminary DFT
calculations suggest that the reaction proceeds through a chiral ion pair intermediate.
Effect of Solvents on the Crystal Formation of Poly(vinylidene fluoride) Film Prepared by aSpin-coating Process
Takashi NISHIYAMA, Takayuki SUMIHARA, Eriko SATO and Hideo HORIBE
Polym. J., Vol. 49, pp. 319-325 (2017)
The effect on the solvent evaporation rate and solvent type on the crystal formation of poly(vinylidene
fluoride) (PVDF) prepared by spin-coating was evaluated over time. In the much-solvent-remaining state,
the crystalline phase of PVDF changed in the order of α, γ and β with the increasing dipole moment of thesolvent.
Inthealmost-all-solvent-evaporated
state,
thecrystalline
structureof
PVDF/hexamethylphosphoramide with a higher dipole moment was dominantly dependent on theevaporation rate and varied in the order of β, γ and α with the increasing solvent evaporation rate. However,
PVDF/triethyl phosphate, having a lower dipole moment, always formed the α phase, regardless of theevaporation rate. The PVDF a phase in the concentrated solution state is difficult to transform into the β andγ phases because the potential energy of each PVDF crystalline phase in the spin-coating method is strongly
affected by both the polymer-solvent electrostatic interactions and the evaporation conditions. From theresults of the crystal transition behavior, it was experimentally supported that the potential energy of the
PVDF crystalline structure increases in the order of α, γ and β.
Decomposition Processes of Photoresist Polymers by H Atoms Produced on Hot Wire Surfaces
Hironobu UMEMOTO, Teruto KATO, Masayuki TAKIGUCHI, Seiji TAKAGI and Hideo HORIBE
Thin Solid Films, Vol. 635, pp. 27-31 (2017)
Mass spectrometry was used to identify the decomposition products of two typical photoresist polymers,
Novolak and polymethylmethacrylate, by H atoms produced on hot wire surfaces. The production of CH4
and CO was confirmed for both polymers. Other possible products are C3H8, C4H10 or C4H8, and some esters
such as CH3COOC2H5. The production of CO2, C2H4, C2H6, alcohols, and aromatics are minor. The possible
decomposition mechanisms are discussed on the basis of density functional calculations of the energetics.
Pressure Dependence of Photoresist Removal Rate Using Hydrogen Radicals
Masashi YAMAMOTO, Tomohiro SHIROI, Shiro NAGAOKA, Tomokazu SHIKAMA, Hironobu
UMEMOTO, Keisuke OHDAIRA, Seiji TAKAGI, Takashi NISHIYAMA and Hideo HORIBE
J. Photopolym. Sci. Tech., Vol. 30, pp. 297-301 (2017)
Photoresists play a key role in lithography processes for the fabrication of electronic devices, but must be
removed after processing. The removal method using hydrogen radicals, which are produced on a tungsten
hot-wire catalyst, is effective to resolve some environmental and industrial problems in usual methods.
However, the removal rate is enhanced just by decreasing Hydrogen pressure but the rate limitations notclarified in present study, we examined the removal rate dependence on the pressure and revealed that theupper limitation of the enhancement is achieved at 0.50 Pa was 8.3 times higher than that at 20 Pa when thesurface temperature was 250 °C.
Degradation of Hydrophilic Polymers in Aqueous Solution by Using Ozone Microbubble
Takashi NISHIYAMA, Kohei MATSUURA, Eriko SATO, Noritsugu KOMETANI and Hideo HORIBE
J. Photopolym. Sci. Tech., Vol. 30, pp. 285-289 (2017)
Polyethylene grycol (PEG) in aqueous solution was decomposed by treating O3 microbubbles and O3 water.
The molecular weight of PEG treated with O3 microbubbles became lower, and the PEG degradation wasenhanced in alkaline condition. PEG in aqueous solution was efficiently decomposed by reactive oxygen
species generated by O3 decomposition, and O3 microbubbles promoted the O3 decomposition in theinterface of O3 gas and surrounding water in which OH anion localized. PEG in aqueous solution was
decomposed to inorganic oxygen by advanced oxidation process (AOP) of O3 microbubbles and H2O2, andthe reduction rate of total organic carbon (TOC) was over 70%.
Dissolution Promotion Effect of Addition of Low Molecular Compounds to Positive Tone Chemically
Amplified Photoresist System－77－

Kazuma TAKAMORI, Takashi NISHIYAMA, Eriko SATO and Hideo HORIBE
J. Photopolym. Sci. Tech., Vol. 30, pp. 281-284 (2017)
Three-component chemically amplified photoresists which are consisted of a base resin, a photo acidgenerator and a dissolution inhibitor are promising because the high sensitivity and the high resolution canbe satisfied at the same time. We studied about the dissolution promotion effect of hydroquinone (HQ) in the
exposed area. HQ is a model compound of the photo induced product of the dissolution inhibitor. We
disclosed that HQ depressed a glass transition temperature (Tg) of the base resin and the sensitivity was
improved by enhancing the dissolution rate in the exposed area. It is expected that the dissolution rate waspromoted when the post exposure bake temperature exceeded Tg because the acid diffuse more easily.
Analysis of Resist Removal Phenomenon Using Laser Irradiation
Tomosumi KAMIMURA, Hirouki KURAMAE, Takayuki YAMASHIRO, Kosuke NUNO, Yuji UMEDA,
Shingo TSUJIMOTO, Ryosuke NAKAMURA, Takashi NISHIYAMA and Hideo HORIBE
J. Photopolym. Sci. Tech., Vol. 30, pp. 291-295 (2017)
Resist removal phenomenon with laser irradiation was analyzed by using a finite element (FE) method. Laser
irradiation in the water can improve the resist removal effect as compared with that of normal atmosphereirradiation. A two-dimensional (2-D) micro-FE model was constructed based on the boundary surface
between the Si wafer, resist and water during laser radiation. In the normal atmosphere, any effective stress
did not occur along the x-axis direction in the resist. In contrast, for the laser irradiation in the water, large
stress in the resist is thought to improve the resist removal efficiency.
Photoresist Removal Using H Radicals Generated by Iridium Hot-Wire Catalyst
Masashi YAMAMOTO, Shiro NAGAOKA, Hironobu UMEMOTO, Keisuke OHDAIRA, Takashi
NISHIYAMA and Hideo HORIBE
Int. J. Polym. Sci., Vol. 2017, 2983042 (5 pages) (2017)
We examined an environmentally friendly photoresist removal method using H radicals produced bydecomposing hydrogen on a hor iridium catalyst. We examined the relationship between photoresist removal
rate and its surface temperature using thin film interference and the removal properties using H radicals
produced by the Ir catalyst. Decomposition behavior at polymer surface by radicals may be analyzed infurther detail from the aspect of kinetics. Additionally, we investigated the oxygen addition effects on theremoval rate. The photoresist removal rate increased with the oxygen additive amount and then decreased
more gradually than in the case of using W filament. The increasing behavior was similar but there was alarge difference between W and Ir catalyst in the decreasing behavior.
Dismantlable Adhesion Properties of Reactive Acrylic Copolymers Resulting from Cross-linking and
Gas Evolution
Eriko SATO, Shusei. IKI Keisuke YAMANISHI, Hideo HORIBE and Akikazu MATSUMOTO
J. Adhes., Vol. 93, pp. 811-822 (2017)
The acrylic copolymers involving 2-hydroxyethyl acrylate (HEA) and tert-butyl acrylate (tBA) units asreactive units behave as pressure-sensitive adhesive type dismantlable adhesive materials. In order toclarify the individual role of HEA and tBA units on dismantlability, the 180° peel behavior after thedismantling treatment, i.e., heating in the presence of given amount of acid catalysts, was systematicallyinvestigated using the acrylic copolymers involving different amounts of the reactive units. It was revealed
that transesterification of HEA units resulted in an increase in the cohesive force and modulus due to anincrease in the molecular weight and cross-linking. Deprotection of tBA units, i.e., transformation of tBA toacrylic acid (AA) unit with isobutene evolution, promoted cross-linking by the esterification of AA units andtended to reduce a cohesive force by forming voids in the adhesive layer due to the evolution of isobutene
gas. Interfacial failure in the peel tests corresponded with a high degree of cross-linking and increased
modulus of the adhesive. Conversely, cohesive failure was associated with reduced cohesive strength of theadhesive layer and a low peel strength.
Coumarin-containing Polymers as Thermo- and Photo-responsive Polymers: Copolymerization with
Solvophilic or Solvophobic Comonomers to Control Themoresponsive Behavior
Eriko SATO, Ryota NAKANISI, Takashi NISHIYAMA and Hideo HORIBE－78－

Chem. Lett., Vol. 46, pp. 108-110 (2017)
The lower critical solution temperature of thermo- and photo-responsive polymers, which involve coumarinunits having functions for the dual-responsivity in chloroform, was controlled by the copolymerization.
The cloud points of the copolymers of 7-methacryloyloxycoumarin with methacrylic acid and methyl
methacrylate as solvophobic and solvophilic comonomers, respectively, were tuned below room temperature
to nearly the boiling point of chloroform. The photodimerization of the coumarin units in the copolymer
resulted in a decrease of the cloud points, i.e., photoresponsivity.
Photocuring of Radically Polymerizable Hyperbranched Polymers Having Degradable Linkages
Eriko SATO, Yoji YAMASHITA, Takashi NISHIYAMA and Hideo HORIBE
J. Photopolym. Sci. Technol., Vol. 30, pp. 241-246 (2017)
Hyperbranched polymers having a number of reductive disulfide bonds and radically reactive vinyl groups
were synthesized by the bulk radical homopolymerization of bis(2-methacryloyloxyethyl)disulfide (disulfide
based dimethacrylate, DSDMA) as a divinyl monomer in the presence of methyl 2-(bromomethyl)acrylate as
an addition-fragmentation chain transfer agent. The resulting hyperbranched polymers (HB-DSDMAs) were
photocured by irradiated at 365 nm in the presence of 2,2-dimethoxy-2-phenylacetophenone as a photoradical initiator. The photocured HB-DSDMA exhibited high transparency in the visible region and good
solvent resistance for various organic solvents. Reduction of the disulfide groups smoothly proceeded in thepresence of tributylphosphine as a reductant, and the cured HB-DSDMAs were completely solubilized.
HB-DSDMAs were also photocured by irradiation at 254 nm due to the homolysis of the disulfide groups
with subsequent initiation of the radical polymerization.
Control of Adhesive Strength of Acrylate Polymers Containing 1-Isobutoxyethyl and Isobornyl Esters
in Response to Dual Stimuli for Dismantlable Adhesion
Yusuke FUKAMOTO, Eriko SATO, Haruyuki OKAMURA, Hideo HORIBE and Akikazu MATSUMOTO
Appl. Adhes. Sci., Vol. 5, 6 (11 pages) (2017)
Background: To develop an adhesion system satisfying both constant adhesion strength during use and quick
debonding ability during a dismantling process.
Methods: Adhesive properties were investigated for the random and block copolymers consisting of
1-isobutoxyethyl acrylate (iBEA), 2-ethylhexyl acrylate (2EHA), and 2-hydroxyethyl acrylate (HEA) as thedismantlable pressure-sensitive adhesives in the presence of a photoacid generator in response to dual
external stimuli of photoirradiation and post baking.
Results: The use of LED combined with a new photoacid generator SIN-11 was enable us to achieve a rapid
dismantling process during UV irradiation within several minutes. The protection of the ester alkyl groupin the iBEA repeating unit to give an acrylic acid unit was suppressed by the introduction of isobornyl
acrylate (IBoA) as the additional unit into the copolymer of iBEA, 2EHA, and HEA. While IBoA-containing
block copolymer showed a constant adhesive strength during photoirradiation as the single external stimulus,
deprotection was immediately induced by the subsequent heating, leading to a significant decrease in theadhesive strength.
Conclusion: The copolymer including the iBEA and IBoA units was revealed to function as the highly
sensitive adhesive materials for dual-locked dismantlable adhesion.
Thermal Degradation Behavior of Polymers Containing a tert-Butoxycarbonyl Group in the Side
Chain and Application to Dismantlable Adhesion Materials
Fumiya SUZUKI, Eriko SATO and Akikazu MATSUMOTO
J. Adhes. Soc. Jpn., Vol. 53, pp. 4-9 (2017) (in Japanese)In this study, we carried out the thermolysis of poly[p-(tert-butoxycarbonyloxy)styrene] (PBSt) prepared byradical polymerization and investigated the reaction mechanism for the formation of poly(p-hydroxystyrene)accompanying the elimination of isobutene and carbon dioxide from the tert-butoxycarbonyl (Boc) group in
the side chain. We also discussed the reaction conditions for the quantitative transformation of the protectedfunctional groups in the side chain of the polymer. The adhesion of aluminum plates using a copolymer ofp-(tert-butoxycarbonyloxy)styrene and glycidyl methacrylate(P(BSt-co-GMA)) with a diamine cross-linker
was carried out. The lap shear test revealed that high adhesion strength was observed for the thermally cured
specimen at 100 °C for 4 h, and that the strength drastically decreased after heating at 150 °C for 1 h, due to－79－the decomposition of the Boc group in the copolymer.
Synthesis of Functional Hyperbranched Polymers by Radical Polymerization of Divinyl Monomers
Eriko SATO
In Kinosei Monoma No Erabikata, Tsukaikata Jireishu, Technical Information Institute, pp. 69-74 (508 pages
in total) (2017) (in Japanese)
Precise Synthesis of Reactive Polymers and Their Application to Interfacial Functional Materials
Eriko SATOThe 97th CSJ Annual Meeting, CSJ Award Lecture for Outstanding Young Women Chemists, Keio
University, March 16th, 2017, Abstracts, 1 A2-34 (2 pages)
Synthesis of Well-defined Reactive Polymers and Their Application to Advanced Adhesive Materials
Eriko SATOThe 63th Annual Kobe Polymer Research Symposium, Kansai Branch of the Society of Polymer Science,
Japan, Award Lecture for Young Scientist, Kobe, July 14th, 2017, Abstracts, pp. 12-13 (in Japanese)
Precise Synthesis of Reactive Polymers and Their Application to Interfacial Functional Materials
Eriko SATO
International Union of Materials Research Societies-The 15th International Conference on Advanced
Materials, Invited Lecture, Kyoto, August 28th, 2017, Abstracts, B4-I28-003 (1 page)
Optical Properties and Solvatofluorochromism of Fluorene Derivatives Bearing S,S-Dioxidized
Thiophene
Tatsumoto NAKAHAMA, Daichi KITAGAWA, Hikaru SOTOME, Shoji ITO, Hiroshi MIYASAKA andSeiya KOBATAKE
Photochem. Photobiol. Sci., Vol. 15, pp. 1254-1263 (2016)
Fluorene derivatives having phenylthiophene (FPT) or benzothiophene (FBT), and their S,S-dioxidized
compounds (FPTO2, FPTO4, FBTO2 and FBTO4) were prepared by oxidation of the thiophene rings in
FPT and FBT with m-chloroperoxybenzoic acid. FPT and FBT exhibited similar optical properties forabsorption maximum wavelength, fluorescence maximum wavelength and fluorescence quantum yield.
However, the absorption and fluorescence spectra of FPTO2 were largely shifted toward longer wavelength
in comparison with those of FPT, and their fluorescence quantum yields dramatically decreased with theoxidation. In contrast, the absorption and fluorescence spectra and the fluorescence quantum yield of FBTO2and FBTO4 were similar to those of FBT. Moreover, FPTO2 and FBTO2 showed large
solvatofluorochromism. Such solvent dependent properties are ascribed to the charge-transfer character ofthe molecules.
Polymorphs of a Diarylethene That Exhibits Strong Emission and Direct Visualization of Polymorphic
Phase Transition Process by Fluorescence Color Change
Daichi KITAGAWA, Tatsumoto NAKAHAMA, Katsuya MUTOH, Yoichi KOBAYASHI, Jiro ABE, Hikaru
SOTOME, Shoji ITO, Hiroshi MIYASAKA and Seiya KOBATAKE
Dyes Pigm., Vol. 139, pp. 233-238 (2017)
Luminescent solid-state materials with high fluorescence quantum yield have attracted much attention inapplication to organic optoelectronics. In the course of study of photochromic diarylethene crystals, it was
found that two polymorphic forms of a diarylethene are obtained by recrystallization from acetone andn-hexane solutions. Both polymorphic crystals exhibited strong emission whose fluorescence quantum yield(> 0.5) is much higher than that in n-hexane solution (0.017). Furthermore, the thermodynamic solid-statepolymorphic phase transition was found and the process was directly visualized by a fluorescence color
change.
Solvent Effect of Fluorescence On/Off Switching of Diarylethene Linked to Excited-State
Intramolecular Proton Transfer Fluorophore
Tatsumoto NAKAHAMA, Takayoshi MUKAIYAMA, Daichi KITAGAWA and Seiya KOBATAKE－80－

Res. Chem. Intermed., Vol. 43, pp. 5321-5336 (2017)
Efficient fluorescence on/off switching of a dyad consisting of a photochromic diarylethene and afluorescence dye based on excited state intramolecular proton transfer (ESIPT) was designed anddemonstrated. Diarylethenes linked to (2-(2-methoxy-5-methylphenyl)benzothiazol-6-yl)- and(2-(2-hydroxy-5-methylphenyl)benzothiazol-6-yl)-9,9-dioctylfluorene moieties (1a and 2a, respectively)
exhibited fluorescence on/off switching upon alternating irradiation with ultraviolet and visible light invarious solvents. The fluorescence on/off contrast of 2a was found to be higher than that of 1a in n-hexane
because the overlap integral between the absorption spectrum of the diarylethene closed-ring form and thefluorescence spectrum of 2a is larger than that of 1a. Diarylethene 2a exhibited green fluorescence with large
Stokes shift in n-hexane, which is ascribed to the ESIPT process from the enol form to the keto form. In
contrast, the fluorescence of 2a in N,N-dimethylsulfoxide (DMSO) was mainly observed as blue
fluorescence from enol form, while diarylethene 1a exhibited blue fluorescence in n-hexane and DMSO. The
fluorescence on/off contrast of 2a in n-hexane was higher than that in DMSO because of the difference in the
spectral overlaps in n-hexane and DMSO.
Fluorescence On/Off Switching in Polymers Bearing Diarylethene and Fluorene in Their Side Chains
Tatsumoto NAKAHAMA, Daichi KITAGAWA, Hikaru SOTOME, Shoji ITO, Hiroshi MIYASAKA andSeiya KOBATAKE
J. Phys. Chem. C, Vol. 121, pp. 6272-6281 (2017)
A diarylethene-fluorene dyad connected by an ester bond (DE-FL) and random and alternating copolymers
with diarylethene and fluorene moieties in their side chains (poly(DE1x-co-FL1y) and poly(DE1-alt-FL2))
were synthesized, and their fluorescence on/off switching properties were investigated. All compounds
exhibited reversible photochromism and fluorescence on/off switching in a solution upon alternating
irradiation with ultraviolet and visible light. Although the fluorescence intensity of DE-FL linearly decreased
with increasing photocyclization conversion of the diarylethene, the fluorescence intensity of poly(DE1x-coFL1y) at the same molar fraction of diarylethene/fluorene significantly decreased with photocyclization
conversion. Moreover, the fluorescence intensity of the polymers in the photostationary state was much
lower than that of DE-FL. These results indicate that the fluorescence on/off switching properties of thepolymers were improved by introducing diarylethene and fluorene moieties into their side chains. Moreover,it was revealed that the monomer sequences and the molar fractions of the diarylethene and fluorene moieties
affected the fluorescence on/off switching properties of the copolymers.
Thiophene-S,S-Dioxidized Diarylethenes for Light-Starting Irreversible Thermosensors That Can
Detect a Rise in Heat at Low Temperature
Daichi KITAGAWA, Koki TANAKA and Seiya KOBATAKE
J. Mater. Chem. C, Vol. 5, pp. 6210-6215 (2017)
Diarylethenes having trimethylsilyl and triethylsilyl groups at the reactive positions and their S,S-dioxidized
diarylethenes were synthesized and their optical and thermal properties were investigated. Upon irradiation
with ultraviolet light, the diarylethenes and thiophene-S,S-dioxidized diarylethenes underwent photochromic
reactions from the colorless open-ring isomer to the colored closed-ring isomer. The photogenerated
closed-ring isomers were found to undergo thermal bleaching reactions to produce colorless byproducts. In
particular, the thiophene-S,S-dioxidized diarylethene having a triethylsilyl group at the reactive positions
underwent the thermal bleaching reaction even at −40 °C. Such materials could be used as light-starting
irreversible thermosensors that can detect a rise in heat at low temperature.
Wavelength-Selective and High-Contrast Multicolour Fluorescence Photoswitching in a Mixture of
Photochromic Nanoparticles
Sanae ISHIDA, Tuyoshi FUKAMINATO, Daichi KITAGAWA, Seiya KOBATAKE, Sunnam KIM,
Tomonari OGATA and Seiji KURIHARA
Chem. Commun., Vol. 53, pp. 8268-8271 (2017)
Wavelength-selective and high-contrast multicolor fluorescence photoswitching between white-, orange-,cyan-, and dark-colors was successfully demonstrated in a mixture of two distinguishable emission coloredphotochromic nanoparticles composed of different pairs of a photoswitching unit and a fluorescence unit.

－81－Efficient Cycloreversion Reaction of a Diarylethene Derivative in Higher Excited States Attained by
Off-Resonant Simultaneous Two-Photon Absorption
Hikaru SOTOME, Tatsuhiro NAGASAKA, Kanako UNE, Chiaki OKUI, Yukihide ISHIBASHI, Kenji
KAMADA, Seiya KOBATAKE, Masahiro IRIE and Hiroshi MIYASAKA
J. Phys. Chem. Lett., Vol. 8, pp. 3272-3276 (2017)
Off-resonant excitation of the closed-ring isomer of a photochromic diarylethene derivative at 730 nm
induced the efficient cycloreversion reaction with a yield of ~20%, while the reaction yield was only 2%
under one-photon excitation at 365 nm. Excitation wavelength dependence of the one-photon cycloreversion
reaction yield under steady-state irradiation in a wide wavelength range showed that the specific electronic
state leading to the large cycloreversion reaction yield, which is originally forbidden in the optical transition
but partially allowed owing to the low symmetry of the molecule, is spectrally overlapped with the electronic
state accessible by the allowed one-photon optical transition in the UV region. Femtosecond transientabsorption spectroscopy also revealed that the off-resonant two-photon excitation preferentially pumped themolecule into the specific state, leading to the 10-fold enhancement of the cycloreversion reaction.
Synthesis and Optical Properties of Fluorescent Switchable Silica Nanoparticles Covered with
Copolymers Consisting of Diarylethene and Fluorene Derivatives
Katsuya SHIMIZU and Seiya KOBATAKE
ChemistrySelect, Vol. 2, pp. 5445-5452 (2017)
Silica nanoparticles covered with random copolymers consisting of diarylethene monomer (DE) and fluorene
monomer (FL) (SNP-poly(DE-co-FL)) were designed and synthesized by reversible addition-fragmentation
chain transfer (RAFT) copolymerization of DE and FL initiated from a RAFT agent immobilized on thesurface of silica nanoparticle. SNP-poly(DE-co-FL) and silica-free polymer (poly(DE-co-FL)), which aresoluble in tetrahydrofuran, underwent reversible photoisomerization of DE moieties upon alternating
irradiation with ultraviolet and visible light. They exhibited fluorescence ON/OFF switching between
fluorescence ON state of FL in the open-ring form of DE and fluorescence OFF state by an efficient
Förster/fluorescence resonance energy transfer from the excited FL not only in the same polymer chain but
also in the surrounding polymer chains to the closed-ring form of DE. Diarylethene-fluorene dyad (DE-FL)
was synthesized to compare with fluorescence ON/OFF switching efficiencies of SNP-poly(DE-co-FL) andpoly(DE-co-FL). The closed-ring isomers of DE in DE-FL, poly(DE-co-FL), and SNP-poly(DE-co-FL) were
found to quench fluorescence of 0.78, 6.3, and 15.6 FL moieties, respectively. Thus, fluorescence switchingefficiency of SNP-poly(DE-co-FL) was 2.5 times higher than poly(DE-co-FL) and 20 times higher thanDE-FL. Furthermore, the closed-ring isomer of DE in SNP-poly(DE-co-FL) was found to quench 6.3 FL
moieties in the same polymer chain and 9.3 FL moieties in four polymer chains in the neighborhood.
Dependence of Photoinduced Bending Behavior of Diarylethene Crystals on Ultraviolet Irradiation
Power
Akira HIRANO, Takuya HASHIMOTO, Daichi KITAGAWA, Kenji KONO and Seiya KOBATAKE
Cryst. Growth Des., Vol. 17, pp. 4819-4825 (2017)
The photoinduced bending behavior of diarylethene crystals upon irradiation with various ultraviolet (UV)light intensities was investigated. The bending velocity of the photoinduced bending crystals was estimatedfrom the curvature of the bending crystal. The initial velocity of curvature change (Vinit) increased inproportion to the power of the incident UV light even when the crystal thickness was different, whichsuggests that the local strain caused by photoisomerization makes a cumulative contribution to the bending
behavior. Moreover, for all UV light intensities, the relationship between Vinit and the crystal thickness waswell explained by the easily handled Timoshenko bimetal model. This result provides a validated method forthe quantitative evaluation of the photoinduced bending velocity in various molecular crystals.
Mechanical Behavior of Molecular Crystals Induced by Combination of Photochromic Reaction andReversible Single-Crystal-to-Single-Crystal PhaseTransition
Daichi KITAGAWA, Kaito KAWASAKI, Rika TANAKA and Seiya KOBATAKE
Chem. Mater., Vol. 29, pp. 7524-7532 (2017)
A unique mechanical behavior of a molecular crystal induced by combination of a photochromic reaction
and a reversible single-crystal-to-single-crystal (SCSC) phase transition is reported herein. A crystal of a－82－

diarylethene having octyl group at both sides was found to undergo a reversible thermodynamic SCSC phasetransition accompanying a change in crystal length, which was clarified by DSC measurement, X-ray
crystallographic analysis, and direct microscopic observation of the crystal length. Furthermore, upon
irradiation with ultraviolet light, the diarylethene crystal exhibited an unusual photomechanical behavior.
The mechanism of the behavior was proposed based on photoisomerization of the diarylethene from theopen-ring isomer to the closed-ring isomer and a reversible thermodynamic SCSC phase transition, which
was well-supported by thermal bending behavior of a photoirradiated crystal.
Restricted Diffusion and Spatial Distribution Measurement of Guest Molecules in Polymer Thin Films
as Revealed by Three-Dimensional Single-Molecule Tracking
Shoji ITO, Kengo HIRATSUKA, Yuhei TAGA, Satoshi TAKEI, Daichi KITAGAWA, Seiya KOBATAKE
and Hiroshi MIYASAKA
J. Spectrosc. Soc. Jpn., Vol. 65, pp. 255-257 (2016) (in Japanese)
Restricted diffusion and spatial distribution measurement of guest dyes in thin film of poly(2-hydroxyethyl
acrylate) on glass substrates have been introduced in Japanese.
Introduction of Our Laboratory
Seiya KOBATAKE
Newsletter, The Technical Association of Photopolymers, Japan, Vol. 78, pp. 3-4 (2017) (in Japanese)
Recent research topics in our laboratory has been introduced in Japanese.
Photoresponsive Molecular Crystals for Light-Driven Micromachines
Daichi KITAGAWA and Seiya KOBATAKE
Photochemistry, Vol. 48, pp. 54-59 (2017) (in Japanese)
Various types of photomechanical motion have drawn much attention because there is a potential to create
photomechanical actuators from molecular-scale to macro-scale. To construct photoactuators, it is necessary
to utilize a molecular assembly with a small free volume. Photochromic compounds undergo photoreversible
isomerization between the original colorless isomer and the photogenerated colored isomer upon alternating
irradiation with UV and visible light. Among many known photochromic compounds, diarylethenes undergophotochromic reactions even in the crystalline phase. The present review introduces recent development instudy of photomechanical crystals including crystal shape changes, bending velocity, dependence of thebending behavior on irradiation wavelength, the behavior in mixed crystal, new types of photomechanicalmotion, and applications. These photomechanical behaviors are based on geometrical structure changes in
the crystalline phase, and can be applied to macro-sized light-driven actuators.
Unusual Photoinduced Bending Behavior of Photochromic Diarylethene Crystals
Seiya KOBATAKE, Daichi KITAGAWA, Rika TANAKA and Kaito KAWASAKI
8th International Symposium on Photochromism (ISOP 2016), Oral Presentation, O-5, East China Universityof Science and Technology, Shanghai, China, November 4-7 (2016)
The unusual photoinduced bending behavior of photochromic diarylethene crystals has been presented in
English.
Photoinduced Rapid and Explosive Fragmentation of Diarylethene Crystals Having Urethane Bonding
Daichi KITAGAWA, Tomohiro OKUYAMA, Rika TANAKA and Seiya KOBATAKE
8th International Symposium on Photochromism (ISOP 2016), Poster Presentation, P-4, East China
University of Science and Technology, Shanghai, China, November 4-7 (2016)
The photoinduced rapid and explosive fragmentation of diarylethene crystals having urethane bonding has
been presented in English.
The Effect of Monomer Sequence for the Fluorescence On/Off Switching Properties in Polymers
Bearing Diarylethene and Fluorene in Side Chains
Tatsumoto NAKAHAMA, Daichi KITAGAWA, Hikaru SOTOME, Syoji ITO, Hiroshi MIYASAKA andSeiya KOBATAKE
8th International Symposium on Photochromism (ISOP 2016), Poster Presentation, P-28, East China－83－

University of Science and Technology, Shanghai, China, November 4-7 (2016)
The effect of monomer sequence for the fluorescence ON/OFF switching properties in polymers bearing
diarylethene and fluorene in the side chain has been presented in English.
Synthesis and Characterization of Fluorescence Switchable Silica Nanoparticle Covered with
Copolymers Consisting of Diarylethene and Fluorene Derivatives
Katsuya SHIMIZU and Seiya KOBATAKE
8th International Symposium on Photochromism (ISOP 2016), Poster Presentation, P-79, East China
University of Science and Technology, Shanghai, China, November 4-7 (2016)
Synthesis and characterization of fluorescence switchable silica nanoparticle covered with copolymers
consisting of diarylethene and fluorene derivatives have been presented in English.
Organic Crystalline Materials Accompanying Coloration, Bending, and Twisting upon
Photoirradiation
Seiya KOBATAKE
6th CSJ Chemistry Festa 2016, the Chemical Society of Japan, Invited Lecture, C2-02, Tower Funabori,
November 14-16 (2016) (in Japanese)
Photochromism, photomechanical bending, and novel photomechanical behavior of diarylethene crystals
have been presented in Japanese.
Photomechanical Behavior of Photochromic Diarylethene Single Crystals
Daichi KITAGAWA and Seiya KOBATAKE
Symposium on Soft Robots: Mechanical Materials, Invited Lecture, Nishiwaseda Campus, Waseda
University, May 27 (2017) (in Japanese)
Photomechanical behavior of diarylethene crystals has been presented in Japanese. The crystalline materials
showing the photoreversible shape change are useful for application to photoactuators.
Photoinduced Electron Transfer from Aromatic Amino Acids to the Excited Isoalloxazine in Single
Mutated Flavin Mononucleotide Binding Proteins: Effect of the Dimer Formation on the Rate and theElectrostatic Energy Inside the Proteins
Nadtanet NUNTHABOOT, Kiattisak LUGSANANGARM, Arthit NUEANGAUDOM, Somsak
PIANWANIT, Sirirat KOKPOL, Fumio TANAKA, Seiji TANIGUCHI, Haik CHOSROWJAN, Takeshi
NAKANISHI and Masaya KITAMURA
Comput. Theor. Chem., Vol. 1108, pp. 1-9 (2017)
Conformational changes in the single mutated flavin mononucleotide binding proteins (FBP), E13K (Glu13
of wild type FBP is replaced by Lys), E13R (Glu13 replaced by Arg), E13T (Glu13 replaced by Thr) andE13Q (Glu13 replaced by Gln) upon dimer formations were studied through the phenomena of photoinduced
electron transfer (ET) from tryptophan 32 (Trp32) and tryptophan 106 (Trp106) to the excited isoalloxazine(Iso*). The ET rates were obtained with atomic coordinates of the proteins determined by a method ofmolecular dynamics simulation (MDS) and an ET theory using the reported experimental fluorescencedecays of the FBPs. The value of the net electrostatic energy (NetES) between the photo-products and ionicgroups inside the proteins increased in magnitude upon the dimer formation in every mutated FBP.
Dependencies in the logarithmic ET rate (ln Rate) on the donor-acceptor distances (Rc) could not beapproximated with simple linear nor parabolic functions in most ET donors, which are ascribed to therelatively greater values of the NetES in the dimers compared to the energy terms of the standard free energygap (SFEG), solvent reorganization energy (SROE) and the electrostatic energy between the photo-products(ESDA) in total free energy gap (GT) in the ET rates. The NetES vs Rc relations displayed two distinctgroups in Trp32KB, Trp32QA and Trp32QB. The ln Rate vs Rc relations in these donors displayed different
behaviors between the two groups.
Localized Solvent Effects on the Crystal Habit of tert-Butoxycarbonyl-L-asparagine (BocASN)
Masaru HIRANO, Koichi IGARASHI and Hiroshi OOSHIMA
J. Chem. Eng. Jpn., Vol. 50, pp. 207-212 (2016)
Solvent selection is one of the most important factors for the control of crystal habits. However, this－84－

relationship is poorly understood. The aim of this study was to determine the solvent selectivity to obtain adesired crystal habit using tert-butoxycarbonyl-L-asparagine (BocASN) as a model compound. The [110],[100], and [001] faces were dominant for the BocASN crystals obtained from acetone and ethanol. However,the [011], [100], and [001] faces were dominant for those obtained from methanol. The interactions between
the solvent molecules and the functional groups exposed on the crystal surface were examined. The
solvent-surface interactions on each surface of the BocASN crystal were dependent on the type of solvent.
The different solvent-surface interactions along the a-, b-, and c-axes affected the growth rate and aspectratio of the crystal. The analysis of the solvent-surface interactions is useful to predict the crystal habit.
Cooling Crystallization Using a mL-Scale Continuous Crystallizer Equipped with a High Speed
Agitator for Production of Uniform Small Crystals
Koichi IGARASHI and Hiroshi OOSHIMA
J. Chem. Eng. Jpn., Vol. 49, pp. 805-808 (2016)
A mL-scale continuous crystallizer has been newly developed to produce small crystals with a narrow size
distribution. The crystallizer is composed of a stainless-steel mixing vessel with an inner working volume of
7.9 mL and a high-speed agitator that can agitate the crystallization solution up to 24,000 rpm. In previous
work, the crystallizer was used for the drowning-out crystallization of glycine and L-alanine. The crystals
obtained with the novel crystallizer were small and uniform in size, comparing with those obtained with aconventional beaker-scale semi-batch and continuous MSMPR type crystallizers. In this study, the coolingcrystallization of l-alanine was attempted using the mL-scale crystallizer. The undersaturated hot solution of
L-alanine and the water-immiscible coolant liquid was introduced into the crystallizer and were intensely
agitated. The solution was dispersed as small droplets into the coolant liquid and rapidly cooled. The crystals
obtained by the mL-scale cooling crystallizer are small and uniform in size as well as the drowning-out
crystallization.
Water Solubilization of Fullerene Derivatives by β-(1,3-1,6)-D-Glucan and Their Photodynamic
Activities toward Macrophages
Atsushi IKEDA, Tatsuya IIZUKA, Naotake MAEKUBO, Kazuyuki NOBUSAWA, Kouta SUGIKAWA,
Kazuya KOUMOTO, Toshio SUZUKI, Takeshi NAGASAKI and Motofusa AKIYAMA
Chem. Asian J., Vol. 12, pp. 1069-1074 (2017)
Anionic and neutral fullerene derivatives were dissolved in water by using β-(1,3-1,6)-D-glucan(β-1,3-glucan) as a solubilizing agent. In the water-solubilized complexes, the concentrations of fullerene
derivatives were ≈0.30 mm and the average particle sizes were ≈90 nm. The β-1,3-glucan-complexedfullerene derivative with a carboxylic acid was found to have higher photodynamic activity toward
macrophages under visible-light irradiation (λ>610 nm) than other β-1,3-glucan-complexed fullerene
derivatives. This result suggests that carboxylic acid moieties in the complex enhance the binding affinity
with β-1,3-glucan receptors on the surface of macrophages when the β-1,3-glucan is recognized. In contrast,
all β-1,3-glucan-complexed fullerene derivatives showed no photodynamic activity toward HeLa cells under
the same conditions.
Formation of β-(1,3-1,6)-D-Glucan-Complexed [70]Fullerene and its Photodynamic Activity towards
Macrophages
Atsushi IKEDA, Motofusa AKIYAMA, Kouta SUGIKAWA, Kazuya KOUMOTO, Yuta KAGOSHIMA,
Jiawei LI, Toshio SUZUKI and Takeshi NAGASAKI
Org. Biomol. Chem., Vol. 15, pp. 1990-1997 (2017)[70]Fullerene was dissolved in water by complexation with β-1,3-glucan using a mechanochemical
high-speed vibration milling apparatus. The photodynamic activity of β-1,3-glucan-complexed C70 was
highly dependent on the expression level of dectin-1 on the cell surfaces of macrophages. The photodynamic
activity increased as a result of a synergistic effect between β-1,3-glucan-complexed 1′-acetoxychavicolacetate and the C70 complex.
Photoresponsive Gene Delivery System: Photoregulation of Intracellular Trafficking Using
Photoresponsive Liposome
Takeshi NAGASAKI and Tsutomu HAMADA－85－

Rev. Laser Eng., Vol. 45, in press (in Japanese)
Since light as a stimulus can be controlled both temporally and spatially, photo-irradiation improves both theendosomal escape of exogenous DNA and DNA release from the complexes with carriers. When aphoto-responsive cationic lipid formed a cell-sized giant vesicle, we observed the photo-isomerization effectof azobenzene on its shape change. Photoswitching the membrane line tension induced reversible transitions
between a closed sphere and an opened disk with a bilayer pore. In a transfection experiment using aphotoresponsive cationic lipid, UV irradiation improved the transfection efficiency. After the lipoplexes
passed through the plasma membrane by endocytosis, trans to cis isomerization of azobenzene moiety
destabilized the vesicle membrane, thus accelerating not only the membrane fusion of the photo-responsive
lipid vesicles but also the endosomal escape of the exogenous DNA.
Displaying a Recombinant Protein on Flocs Self-Produced by Escherichia coli through Fused
Expression with Elongation Factor Ts
Yoshihiro OJIMA, Shota NUNOGAMI, Masayuki AZUMA and Masahito TAYA
Enzyme Microb. Technol., in press (DOI:10.1016/j.enzmictec.2017.08.010)
The utility of engineering flocculation is wildly recognized in applied and environmental microbiology. We
previously reported self-produced flocculation of Escherichia coli cells by overexpressing the native bcsB
gene that encodes a component of the cellulose synthesis pathway. Further experiments clarified that the
spontaneous E. coli flocs were proteinous, and elongation factor Ts (Tsf) was the main component. In thisstudy, we demonstrated successful expression of a fusion protein consisting of Tsf and green fluorescence
protein (GFP) on E. coli flocs. Interestingly, the percentage of Tsf-GFP in total floc protein reachedapproximately 15% (w/w). The proposed design of a fusion protein with Tsf enables displaying a
recombinant target protein on the floc structure.
Quantitative Evaluation of Recombinant Protein Packaged into Outer Membrane Vesicles ofEscherichia coli Cells
Yoshihiro OJIMA, Kyota YAMAGUCHI and Masahito TAYA
Biotechnol. Prog., in press (DOI:10.1002/btpr.2536)
Outer membrane vesicles (OMVs) are spherical bilayered proteolipids released from the cell surfaces ofbacteria, which have gained traction in the biotechnology fields. Bacterial cellular machinery can be
genetically engineered to produce and package heterologous enzymes into OMVs, producing nanocarriers
and nanoparticle catalysts. However, the productivity or efficiency of packaging the target protein into
OMVs has not been quantitatively evaluated. In this study, we packaged green fluorescence protein (GFP)
into the OMVs of Escherichia coli through N-terminal fused expression to outer membrane protein W(OmpW). The OMV productivity and amount of OmpW-GFP packaged in the OMVs were quantitatively
compared between two hypervesiculating mutant strains ΔnlpI and ΔdegP. Both strains increased the OMV
production, but the ΔnlpI strain additionally enhanced the packaging of OmpW-GFP into OMVs. It was
further confirmed that Spr, a peptidoglycan endopeptidase, plays an important role in the enhanced
packaging of OmpW-GFP into OMVs through the increased OmpW-GFP expression on the ΔnlpI cells.
Finally, the amount of OmpW-GFP released in the OMV fraction of both mutants was determined in terms of
the OMV productivity and the packaging efficiency of OmpW-GFP into OMVs.
Design and Fabrication of Devices for Investigating Cell-Sheet Stretch
Yang LIU, Yoshihiro OJIMA, Masanobu HORIE, Eiji NAGAMORI and Hideaki FUJITA
BioChip J., in press (DOI:10.1007/s13206-017-1301-1)
Recently, many efforts have been made to investigate the cell stretch response through focal adhesions,which are usually utilized by cells cultured on elastic materials. However, not all stretch sensing is mediatedthrough focal adhesions but from cell-cell contacts such as adherence junctions. To unveil the details of thestretch-sensing mechanism through cell-cell contacts, we developed a cell-sheet extension device forvisualizing dynamic changes of individual living cells induced by external mechanical stretch. A cell-sheet is
an ideal observation object, as it can be comprised merely of cells without any mechanical influences fromexternal matrices while maintaining normal cell-cell adhesions as in the in vivo situation. Two microfluidic
extension devices were designed and fabricated using a silicone elastomer, which were capable of extending
a cell-sheet made from Caco-2 cells up to 1.3- and 1.5-fold from its original state. Based on the obtained－86－results, we expected that such cell-sheet extension systems can be useful tools for understanding themechanisms of cellular stretch sensing through cell-cell contacts in living cells.
Flocculation of Real Sewage Sludge Using Poly-γ-glutamic Acid Produced by Bacillus sp. Isolated fromSoil
Tao LIU, Kyouhei YAMASHITA, Yoshihiro FUKUMOTO, Taro TACHIBANA and Masayuki AZUMAJ. Chem. Eng. Jpn., Vol. 50, pp. 201-206 (2017)
In order to promote farmland utilization of the sewage sludge, a flocculant suitable for the agriculture
application is required. In general an inorganic flocculant such as aluminium sulfate has been used at a large
sewage disposal plant. However there is concern that aluminium is accumulated when it is returned tofarmland, and therefore a biodegradable flocculant instead of the inorganic flocculant is required. To obtainbiodegradable flocculants produced by microorganisms, microorganisms were isolated from soils andsewage sludges, and flocculation activity of those culture broths was evaluated. Here real sewage sludge wasused for the evaluation because practical use was regarded as important. As a result the strains, V13 andRK14, were selected, and those were identified as Bacillus megaterium and Bacillus licheniformis,
respectively. It was also found that the flocculations were caused by poly-γ-glutamic acid (γ-PGA). γ-PGA
from RK14 cells had considerably high molecular weight compared with the commercial γ-PGA, and theenantiomeric composition was different from that of PGA from other B. licheniformis. In order to obtainmutants with high γ-PGA productivity, RK14 cells were treated with ethyl methanesulfonate, and a mutant(RK14-46) was selected. The culture medium suitable for γ-PGA production by RK14-46 cells was totallydifferent from that by RK-14 cells. The γ-PGA production reached to 21.1 g/L when RK14-46 cells were
cultured in the optimum semi-synthetic medium at 30°C for 2 days. Besides, the combination of γ-PGA
obtained from RK14-46 cells and chitosan, a cationic flocculant, was very effective for flocculation of real
sewage sludge.
Identification and Characterization of D-Succinylase, and a Proposed Enzymatic Method for D-Amino
Acid Synthesis
Yosuke SUMIDA, Sachio IWAI, Yoshiaki NISHIYA, Shinya KUMAGAI, Toshihide YAMADA and
Masayuki AZUMA
Adv. Synth. Catal., Vol. 358, pp. 2041-2046 (2016)
Chiral amino acids are important intermediates for the pharmaceutical industry. We have developed a novel
one-pot enzymatic method for D-amino acid synthesis by the dynamic kinetic resolution of
N-succinyl-DL-amino acids using D-succinylase (DSA) and N-succinylamino acid racemase (NSAR, EC
4.2.1.113). The DSA from Cupriavidus sp. P4-10-C, which hydrolyzes N-succinyl-D-amino acids
enantioselectively to their corresponding damino acids, was identified for the first time by screening soil
microorganisms. Subsequently, the DSA gene was cloned and overexpressed in Escherichia coli. DSA wasshown to comprise two subunits with molecular masses of 26 kDa and 60 kDa. Additionally, the NSAR genefrom Geobacillus stearothermphilus NCA1503, which racemizes N-succinylamino acids, was also cloned
and overexpressed in E. coli. The highly purified DSA and NSAR prepared from each recombinant E. coli
were characterized and used for D-amino acid synthesis. A one-pot enzymatic method converted 100 mM
N-succinyl-DL-phenylalanine to D-phenylalanine in 91.1% conversion with 86.7% ee. This novel enzymatic
method may be useful for the industrial production of many d-amino acids.
ARHGEF10 Directs the Localization of Rab8 to Rab6-Positive Executive Vesicles
Satoshi SHIBATA, Tsubasa KAWANAI, Takayuki HARA, Asuka YAMAMOTO, Taro CHAYA, Yasunori
TOKUHARA, Chinami TSUJI, Manabu SAKAI, Taro TACHIBANA and Shinobu INAGAKIJ. Cell Sci., Vol. 129, pp. 3620-3634 (2016)
The function of ARHGEF10, a known guanine nucleotide exchange factor (GEF) for RhoA with proposedroles in various diseases, is poorly understood. To understand the precise function of this protein, we raised a
monoclonal antibody against ARHGEF10 and determined its localization in HeLa cells. ARHGEF10 was
found to localize to vesicles containing Rab6 (of which there are three isoforms, Rab6a, Rab6b andRab6c), Rab8 (of which there are two isoforms, Rab8a and Rab8b), and/or the secretion marker neuropeptide
Y (NPY)-Venus in a Rab6-dependent manner. These vesicles were known to originate from the Golgi andcontain secreted or membrane proteins. Ectopic expression of an N-terminal-truncated ARHGEF10 mutant－87－led to the generation of large vesicle-like structures containing both Rab6 and Rab8. Additionally, smallinterfering (si)RNA-mediated knockdown of ARHGEF10 impaired the localization of Rab8 to these
exocytotic vesicles. Furthermore, the invasiveness of MDA-MB231 cells was markedly decreased byknockdown of ARHGEF10, as well as of Rab8. From these results, we propose that ARHGEF10 acts inexocytosis and tumor invasion in a Rab8-dependent manner.
Testis-Specific Histone Variant H3t Gene Is Essential for Entry into Spermatogenesis
Jun UEDA, Akihito HARADA, Takashi URAHAMA, Shinichi MACHIDA, Kazumitsu MAEHARA,
Masashi HADA, Yoshinori MAKINO, Jumpei NOGAMI, Naoki HORIKOSHI, Akihisa OSAKABE,
Hiroyuki TAGUCHI, Hiroki TANAKA, Hiroaki TACHIWANA, Tatsuma YAO, Minami YAMADA, Takashi
IWAMOTO, Ayako ISOTANI, Masahito IKAWA, Taro TACHIBANA, Yuki OKADA, Hiroshi KIMURA,
Yasuyuki OHKAWA, Hitoshi KURUMIZAKA and Kazuo YAMAGATA
Cell Rep., Vol. 18, pp. 593-600 (2017)
Cellular differentiation is associated with dynamic chromatin remodeling in establishing a cell-type-specificepigenomic
landscape.
Here,
we
find
that
mouse testis-specific andreplication-dependent histone H3 variant H3t is essential for
very
early
stagesof spermatogenesis. H3tgene deficiency leads to azoospermia because of the loss of haploid germ cells.
When differentiating spermatogonia emerge in normal spermatogenesis, H3t appears and replaces the
canonical H3 proteins. Structural and biochemical analyses reveal that H3t-containing nucleosomes are more
flexible than the canonical nucleosomes. Thus, by incorporating H3t into the genome during spermatogonial
differentiation, male germ cells are able to enter meiosis and beyond.
Application of Monoclonal Antibodies Against Mouse Dermokine
Kiyoshi HIGASHI, Cai-Xia WANG, Chikako YOKOYAMA, Keita YAMADA, Koichi SAITO and Taro
TACHIBANA
Monoclon Antib Immunodiagn Immunother., Vol. 36, pp. 15-19 (2017)
Dermokine is
one
of
the
most
highlyexpressed
proteins
indifferentiating
keratinocytes. Mouse dermokine has been reported to be encoded by 22 exons, and its expression leads tothree transcripts, β, γ, and α, which are transcribed from two different transcriptional start sites. The α
isoform represents the carboxyl-terminal domain of the β isoform, whereas the γ isoform lacks this domain.
To reveal the distributions and expression levels of each isoform in mice, we generated
rat monoclonal antibodies against dermokine-β/γ and dermokine-β/α. In immunofluorescence studies, theexpression levels of dermokine in the cytosol of the cultured mouse keratinocytes were significantly elevatedby high levels of extracellular calcium. In Western blot analyses, the expression levels of dermokine-β
and dermokine-α were increased in the presence of high calcium. Finally, we developeda monoclonal antibody-based sensitive sandwich enzyme-linked immunosorbent assay (ELISA) and showedthat the secreted dermokine-β into the culture medium from mouse keratinocytes was significantly increased
in a manner dependent on the extracellular calcium concentration. These dermokine-specific antibodies haveallowed us to gain new insights into the role of each dermokine isoform in cutaneous homeostasis.
Septin 9_i2 Is Downregulated in Tumors, Impairs Cancer Cell Migration and Alters Subnuclear Actin
Filaments
Pascal VERDIER-PINARD, Danièle SALAUN, Habib BOUGUENINA, Shun SHIMADA, Matthieu
POPHILLAT, Stéphane AUDEBERT, Emilie AGAVNIAN, Sergiu COSLET, Emmanuelle
CHARAFE-JAUFFRET, Taro TACHIBANA and Ali BADACHE
Sci. Rep., Vol. 7, 44976 (18 pages) (2017)
Functions of septin cytoskeletal polymers in tumorigenesis are still poorly defined. Their role in theregulation of cytokinesis and cell migrationwere proposed to contribute to cancer associated aneuploidy andmetastasis. Overexpression of Septin 9 (Sept9) promotes migration of cancer cell lines. SEPT9 mRNA andprotein expression is increased in breast tumors compared to normal and peritumoral tissues andamplification of SEPT9 gene was positively correlated with breast tumor progression. However, theexistence of multiple isoforms of Sept9 is a confounding factor in the analysis of Sept9 functions. In thepresent study, we analyze the protein expression of Sept9_i2, an uncharacterized isoform, inbreast cancer cell lines and tumors and describe its specific impact on cancer cell migration and Sept9－88－

cytoskeletal distribution. Collectively, our results showed that, contrary to Sept9_i1, Sept9_i2 did notsupport cancer cell migration, and induced a loss of subnuclear actin filaments. These effects were dependent
on Sept9_i2 specific N-terminal sequence. Sept9_i2 was strongly down-regulated in breast tumors compared
to normal mammary tissues. Thus our data indicate that Sept9_i2 is a negative regulator of breast
tumorigenesis. We propose that Sept9 tumorigenic properties depend on the balance between Sept9_i1 and
Sept9_i2 expression levels.
Crystal Structure and Characterization of Novel Human Histone H3 Variants, H3.6, H3.7, and H3.8
Hiroyuki TAGUCHI, Yan XIE, Naoki HORIKOSHI, Kazumitsu MAEHARA, Akihito HARADA, Jumpei
NOGAMI, Koichi SATO, Yasuhiro ARIMURA, Akihisa OSAKABE, Tomoya KUJIRAI, Takeshi IWASAKI,
Yuichiro SEMBA, Taro TACHIBANA, Hiroshi KIMURA, Yasuyuki OHKAWA and Hitoshi
KURUMIZAKA
Biochemistry, Vol. 56, pp. 2184-2196 (2017)
Non-allelic histone variants are considered as epigenetic factors that regulate genomic DNA functions ineukaryotic
chromosomes.
In
thisstudy,
we
identified
three
new human histone H3 variants (named H3.6, H3.7, and H3.8), which were previously annotated as
pseudogenes. H3.6 and H3.8 conserve the H3.3-specific amino acid residues, but H3.7 shares the specificamino acid residues with H3.1. We successfully reconstituted the nucleosome containing H3.6 in vitro anddetermined its crystal structure. In the H3.6 nucleosome, the H3.6-specific Val62 residue hydrophobicallycontacts the cognate H4 molecule, but its contact area is smaller than that of the corresponding H3.3 Ile62
residue. The thermal stability assay revealed that the H3.6 nucleosome is substantially unstable, as comparedto the H3.3 nucleosome. Interestingly, mutational analysis demonstrated that the H3.6 Val62 residue is fully
responsible for the H3.6 nucleosome instability, probably because of the weakened hydrophobic interaction
with H4. We also reconstituted the nucleosome containing H3.8, but its thermal stability was quite low. In
contrast, purified H3.7 failed to form nucleosomes in vitro. The identification and characterization ofthese novel human histone H3 variants provide important new insights into understanding the epigenetic
regulation of the human genome.

－89－

Urban Engineering
Architecture and Building Engineering
Comparison Study of Elasto Plastic Behavior on Static and Dynamic Responses
Yoshiya TANIGUCHI, Tomoya MATSUI and Susumu YOSHINAKA
Proc. of the IASS Annual Symposium 2016 “Spatial Structures in the 21st Century”, Tokyo Japan, Sep 29-30,
ID1129In this paper, the relationships between static load-carrying capacity and seismic resistant capacity are focused on,that is, the comparison study is carried out about elasto plastic behavior of both responses. The purpose is toestablish an evaluation method of allowable maximum earthquake acceleration, which may bring a structure into
an ultimate state. The both elasto plastic behavior is analyzed for single layer lattice domes under vertical loading,which is a static vertical uniform load and a vertical seismic motion. The relationships between equivalentvelocity of static absorbed energy and vertical deformations are focused on as a static elasto plastic behavior. The
other relationships is the maximum earthquake input acceleration and the equivalent velocity of strain energy ofdomes as a dynamic elasto plastic behavior. Consequently, the change of slopes between the elastic and plastic
ranges is concerned with each other.
Effect of Joints Eccentricity of Web Members on Load-carrying Capacity for Parallel Chord Truss Beams
Ryosuke TAKAOKA, Yoshiya TANIGUCHI and Susumu YOSHINAKA
Proc. of the IASS Annual Symposium 2016 “Spatial Structures in the 21st Century”, Tokyo Japan, Sep 29-30,
ID1232
It is well known that, to prevent flexural moments in truss members, they should be connected without joint
eccentricity. Joints should be strong enough to transmit axial forces. Various industrialized joints have beendeveloped for use in steel structures. We have studied a new jointing system for timber lattice structures. In
designing timber structures, most designers wish to conceal steel jointing systems. Simpler jointing systems could
be devised if some joint eccentricity were allowable. This study considers the effect of joint eccentricity on theload bearing capacity of parallel chord truss beams. A numerical study was carried out with the parameter of web
member eccentricity to demonstrate the lowering of buckling loads and peak loads.
Experimental Study on New Jointing System for Timber Lattice Structures by Direct Contact of Member
Cross Sections in the Fiber Direction
Hitoshi OKUYAMA, Yoshiya TANIGUCHI and Yuki TANIGUCHI
Proc. of the IASS Annual Symposium 2016 “Spatial Structures in the 21st Century”, Tokyo Japan, Sep 29-30,
ID1255It may be important to use timbers from thinning, to maintain forest in a good condition. The timbers fromthinning are usually irregular goods because of their shorter length or smaller cross section. Lattice structures havebeen often adopted in overcoming this disadvantage. Former timber lattice structures may mostly stand on thetechnology of industrial steel truss systems. In this paper, a new concept is introduced in the transmission ofmember axial forces. The compressive member axial forces are directly delivered by the contact of cross sections,that is, timbers are mutually contacted through cross sections. The other tensile and shear forces are mainly
delivered by steel plates hidden in timbers with drift pins. This basic technology itself is not innovative, however,it may be sufficient to abandon the conventional manner in realizing timber lattice structures with a screw jointing
system.

Settings of Tuning Ratios of Tuned Mass Dampers with Initial Displacement
Susumu YOSHINAKA, Keita KOZURU and Yoshiya TANIGUCHI
Journal of Structural and Construction Engineering (Transactions of AIJ), AIJ, 738, pp. 1177-1187, (2017)(in Japanese)
In order to control the transient response more effectively, we propose TMDs (Tuned mass dampers) withinitial displacement. In our previous study, we formulated the equation for initial conditions to release initial
TMD displacement. By using this equation, the structural response of the first mode with the lowest modal
damping is eliminated on a two-degrees-of-freedom model. In this paper, we study the effect of the settingsof TMDs tuning ratios on the control performance. And we study the causes focusing on the interrelationshipbetween a main mass and two TMDs on the complex plane and the TMD power flow.

－90－Uncertainties in the Estimation of Local Peak Pressures on Low-Rise Buildings by Using the Gumbel
Distribution Fitting Approach
Eri GAVANSKI, Kurt R. GURLEY (Univ. of Florida) and Gregory A. KOPP (Univ. of Western Ontario)
J. of Struct. Eng., 142(11), pp.1-14 (2016)

The lack of a standard accepted method to estimate local peak pressure coefficients from windtunnel data can lead to inconsistent definitions and interpretations, particularly since cost and time
constraints associated with wind tunnel tests of low-rise buildings necessitate that relatively short(equivalent full-scale) test durations be used. This paper focuses on a Gumbel distribution fitting
method widely used in practice. Since the sources of uncertainty on estimated peaks include the useof short duration records (in practice) and the assumption that the observed peaks from wind tunnelpressure data are Gumbel distributed, this is quantified in detail in terms of the parameters
determining the required minimum record length. It is shown that 15 observed peaks can lead to
local peak pressure estimates with adequate precision for many design scenarios. However, theconversion of peak coefficients from a short duration to those of a longer duration requires anincrease in the number of observed peaks to maintain precision.
Fragility Assessment of Roof-to-Wall Connection Failures for Wood-Frame Houses in High Winds
Eri GAVANSKI and Gregory A. KOPP (Univ. of Western Ontario)
ASCE-AME J. of Risk Uncertainty Eng. Syst., Part A; Civ. Eng., 3(4): 04017013 (2017)
The Enhanced-Fujita Scale (EF-scale) is used to identify tornado intensity. It uses several Damage Indicators(DIs), each of which has descriptions of the Degrees-of-Damage (DOD) along with associated wind speeds.
Recent research has indicated that for wood-frame, one- and two-family houses, differences in the structuraldetails result in significant variations in the wind speeds estimated to cause specific levels of damage, particularly
with respect to the performance of roofs. This suggests that a single damage indicator for this class of structure
may be inadequate. In order to examine this point in detail, the paper focuses on failures of theroof-to-wall-connections (RTWCs) in wood-frame houses, which are frequently damaged in tornadic wind events.
Fragility analyses were conducted using an extensive wind-tunnel-based dataset for the determination of thestatistics of wind loads and full-scale house test data for the toe-nailed RTWC resistances. The wind load data
came from wind tunnel simulations of the atmospheric boundary layer, which, as discussed in the paper, are likely
to provide upper-bound failure wind speeds for tornadoes. The results indicate that the roof shape and the capacityof RTWCs (i.e., number/type of connections) are the primary factors affecting the failure winds for houses withdominant openings. Recommendations for modifications to the EF-Scale to account for these are provided.
Evaluation of Typhoon Induced Wind Risk on Japanese Residential Houses due to Climate Change
Eri GAVANSKI, Kazuyoshi NISHIJIMA (Univ. of Kyoto) and Takashi MARUYAMA (Univ. of Kyoto)
Proc. of 6th U.S.- Japan Workshop on Wind engineering –Windstorm hazard reduction of critical infrastructure-,
Tokyo, May 12-16, (2016)
This paper presents a reliability-based vulnerability model for Japanese residential houses under typhoon windloads. Although vulnerability models for residential house have been studies especially in US, such model has notbeen developed in Japan where the characteristics of residential houses such as employed cladding components isdifferent from those in US. Our focus in the developing the vulnerability model is to consider the regional
difference of residential houses in order to estimate their wind risk with more accuracy. Although there are many
reginal characteristic of residential houses to be considered, the current study deals with only the difference inroof tile fastener wind resistance as a starting point. Furthermore, using the developed vulnerability model withthe wind speeds estimated from the probabilistic typhoon model under present and future climates, the annual
expected monetary consequence due to typhoon wind load is evaluated for several Japanese regions and its
difference due to climate change is evaluated.
Households’s Air-Conditioners Evaluation and Use under Electricity Shortage after the Disaster in 2011
-Thermal Control Use during Summer in Apartment Houses in Osaka City
Xiaoyong LIN and Noriko UMEMIYATransaction of AIJ, 81(727), pp.785-794, (2016) (in Japanese)
Electricity conservation was requested by government in the national interest after the earthquake that occurred in
Tohoku on March 11. Electric utility in Kansai asked businesses and households to reduce summer electricity
consumption by up to 10 percent and 9 percent was reduced in households in 2012. This study clarifies how the－91－

electricity consumption was reduced by questionnaire survey of apartments in Osaka city. 1) Electricity charges
were lower in 2011 by 23.0% in August. The cooling charge was lower by 43.3%. The mean setting temperature
was 26.0°C in 2004 and 27.5°C in 2011. Subjective degree of air conditioner use did not differ. Difference ofregression estimates of cooling charge for mean setting temperatures between 2004 and 2011 was similar to thedifference of mean cooling charge between in 2004 and in 2011. 2) Satisfaction with AC and orientation to AC
was higher and awareness of cooling cost was lower in 2011. Consciousness of the environment was not rather
lower in 2011. Residents depended on AC more greatly in 2011. 3) No relation was found between evaluation ofthermal environment indoors and cooling charge in 2011.
Air-Conditioner Use Effects on Thermal Environment and Sleep Quality in Bedrooms during Summer-Analysis of University Students in Osaka
Noriko UMEMIYA, Yoshiki TACHIBANA, Tomohiro KOBAYASHI and Yusuke NAKAYAMA
Proceedings of 9th Windsor Conference, 7-4, pp.1-8, Windsor, UK, April 7-10, (2016)
Analyses of thermal environment, thermal control behaviors, thermal sensations, and sleep quality yielded thefollowing results indicating air conditioner (AC) use effects on sleep quality in 11 bedrooms during three periodsof summer. 1) Outside temperatures were higher on AC use days but room temperatures during sleep were kept
almost identical (25.7°C). 2) Sleep quality as evaluated by the OSA score was higher on AC use days. However, it
was hotter and less acceptable on AC use days, although thermal comfort was not different. 3) On AC non-use
days, the relation between thermal comfort and thermal sensation was stronger. Thermally acceptable ranges were
wider on non-use days. 4) Relation between the OSA score and the degree of sound sleep was weaker on AC use
days. The OSA score was more strongly related to thermal acceptability on AC use days than non-use days. 5)
Differences in sleep quality were smaller between AC use days and non-use days than between the surveyed
periods. Lower sleep quality in mid-summer was caused not by AC, but by higher room temperatures.
Relation between Constitutions and Thermal Control Use during Summer
Noriko UMEMIYA, Bing ZHANG and Tomohiro KOBAYASHI
Proceedings of the 5th International Conference on Human-Environment System, TC4-4, pp.1-8, Nagoya, Japan,
Oct 29-Nov 2, (2016)
Relation between thermal control use in summer and respondents’ constitutions such as heat and cold resistance,
tendency of catching cold, and bad circulation were investigated by questionnaire surveys carried out for Osaka
apartment dwellers. 1-a) Males reporting a strong constitution do not use air conditioners, set the highest
temperatures, and open windows the most. 1-b) Females reporting weaker constitutions do not use fans. 1-c)
Occupied younger females who are ‘tolerant to heat’ use air conditioners and fans the most. 1-d) Occupied
younger males who are intolerant to heat use air conditioners, close windows the most, and set the lowest
temperatures. 1-e) Occupied younger women with bad circulation do not use air conditioners much, but set thetemperature high. 2) Females who are intolerant of heat report the highest costs for air conditioners, whereas
females who report weaker constitutions also report the lowest costs. 3) Frequency of air conditioners use isrelated to heat tolerance and age. Younger respondents use air conditioners frequently.
Lighting Styles and Electric Charge in Apartments
Noriko UMEMIYA, Shuta TAKAYAMA, Tomohiro KOBAYASHI and Yuya KOBAYASHI
Proceedings of the 9th Conference of China, Japan and Korea, pp.139-142, Busan, Korea, Aug 18-19, (2016)
Questionnaire survey of lighting use and electric bill was carried out for more than three hundred family typeapartments in Osaka to compare electric energy consumption against daytime and night time lighting styles.
Lighting use in daytime and nighttime, electric bill in natural ventilation season, and basic attributes of apartments,
family rooms and respondents were asked. Results show the followings: 1) 74.5 % had more than two lighting
devices in family rooms. Two were 50.5 % and dominant. But only 8-15 % used them for nighttime local lighting.
2) 49.7 % rarely used daytime artificial lighting, whether 14.6 % used daytime lighting during family rooms stay.
Frequency of nighttime local lighting use was lower for behaviors of eating, reading and working. 3) Electric billof ‘rarely daytime lighting’ apartments was 12.0 % lower than that of ‘almost lighting during stay’ apartments. 4)
Electric bill of night time ‘single lighting’ apartments was lower than other night time lighting style apartments, if
lighting was used during stay. This tendency was true regardless of the stay duration. On the other hand, electricbill on night time ‘single lighting’ apartments was the highest, if daytime lighting was rarely used and if stay
duration was shorter. 5) If daytime lighting was rarely used and if stay duration was longer, electric bill depended
on the behaviours when local lighting was used. It was highest for relaxing and lowest for eating.

－92－

Urban Design and Engineering
Autonomous Cane and Verbal Map Describing Vast Space for Improving Visually-impaired People’s
Daily Mobility
Yumie SAWADA, Takashi UCHIDA and Yukinori SAMIZO
Japan Society of Traffic Engineers, Papers on Traffic Engineering, No. 36，pp. 139-144 (2016) (in Japanese)
An Empirical Study on Verbal Map Guidelines for Visually-impaired People Navigation considering
Daily Mobility Needs
Mei TAKAHASHI and Takashi UCHIDA
Journal of Japan Society of Civil Engineers, Ser. D3, Vol.72, No.5, pp.I_1085-I_1094 (2016) (in Japanese)
Unlike sighted people, visually-impaired people cannot use a high performance pedestrian navigation system.
The purpose of this study is to revise verbal map guidelines that show rules for describing features in a town
to enhance everyday mobility. Therefore, this study figures out feature information visually-impaired people
use in everyday life.
This study presents a review of earlier studies and related studies, and make a speech augmented reality (AR)application. Then, two kinds of field experiments are conducted. The first experiment is a monitor
experiment and has visually-impaired people use a smartphone which implemented a speech AR applicationin everyday life. The second experiment is a site experiment and has them use a pedestrian navigation system
and walk in a course we set according to it. Finally, from the hearing result of those experiments, verbal map
guidelines are revised.
Study on the Effect that the Relationship and Evaluation for the Community Bus Gives Support
Awareness to Business
Yusuke KURASHIMA and Takashi UCHIDA
Journal of Japan Society of Civil Engineers, Ser. D3, Vol.72, No.5, pp.I_721-I_729 (2016) (in Japanese)
For the purpose of the acquisition of the new user and the increase in user, various use promotion measures
are carried out by the community bus. Today, the measure for the purpose of bringing up attachment andsupport awareness for the bus is worked on. In such situation, it is that following two are important. First,
evaluate a measure transversely and clarify the difference of the evaluation. Next, clarify about therelationship with the actual situation of the use and the evaluation and the attachment and support awarenessto a bus.
In this study, we took up community bus "Taco-bass" of Akashi-shi, Hyogo as an example. We clarified theinfluence that the relation with the community bus such as the evaluation for various use promotion
measures or the use of the bus, or the situation of the movement limitation, gave to support awareness, andshowed consideration for the breeding of the support awareness.
Causal Analyses of Attitudes of Residents along the Medium and Small Size River for the Posterior
Evaluation of the Nature-Friendly Environment and the Water Amenity
Yasumasa FUKUSHIMA and Takashi UCHIDA
Journal of Japan Society of Civil Engineers, Ser. D3, Vol.72, No.5, pp.I_241-I_249 (2016) (in Japanese)
In recent years the development of the urban river has been focusing on efforts for the environment and thewater amenity besides the flood control and the water utilization. In the waterfront development the
stakeholders/agents such as local governments, inhabitants, planners, and bodies concerned are mutually
involved, in some cases however, the residents along the river have failed to value and then water amenity
has made little progress.
This paper takes a case of the waterfront development of the small size river in an emerging built-up area.
Going through several years after the project implementation, we take hold of the actual condition and theattitudes of residents by means of questionnaire survey to the inhabitants. This study performs respective
analyses on the relationship between the factors towards the smooth implementation of the enterprise and theconsensus formation and in urban riverside development considering development methods in order topromote the utilization with high evaluations from the inhabitants as concrete strategies.
Questionnaire Survey of Riverfront Residents after Nature-oriented Water Amenity Development
Project of a Minor River in a Built-up Area

－93－

Yasumasa FUKUSHIMA and Takashi UCHIDA
Osaka City University, Memoirs of the Faculty of Engineering, Vol. 57, pp.11-25 (2016)
Recent municipal river development emphasizes environment and water amenity as well as flood control andwater utilization. A waterfront development project involves multiple subjects such as a commissioning
entity, riverfront residents, a planner, and agencies concerned. However, riverfront residents occasionallyevaluate the project too little to encourage waterfront utilization. Therefore, examination based on a posterior
situation is important for future improvement.
This study assesses waterside development in a minor river in an emerging built-up area. The actual
conditions of and estimation of water amenity are comprehended using questionnaire survey of the riverfront
residents at the project area several years after the completion. The analysis specifically examines theirinvolvement in waterfront development. This study is expected to contribute fundamental data for
examination and discussion of a development procedure highly appreciated by riverfront residents andeffective for promotion of utilization, as concrete measures for smooth project performance and consensus
building in the waterfront development of a municipal river.
A Study on Bus Services to Support the Promotion of Additional Trips and Consumption by
Accompanied Activity
Yusuke TAKAHASHI, Yasuo HINO and Takashi NISHIKAWA
Japan Society of Civil Engineers，Proceedings of Infrastructure Planning, No. 54，pp.1524-1529 (2016) (inJapanese)
The accompanied activities of elderly persons who should perform the key role of prosperity in the aging
society may be making the increase of outside activities and additional trips and the consumption. Therefore,
the suitable bus services must be investigated to promote the accompanied activities. In this study, theactual condition of the accompanied activities and the promotion effects of two types of bus services
conducted in Kawachi-nagano city of Osaka Prefecture were investigated by two types of questionnaire
surveys for general persons at the main rail station and bus passengers. As a result, some interesting findings
came out of these surveys as followings. At first, in general, the accompanied activities made increasing theadditional trips and consumption. And secondly, the introduced bus services made increasing the outside
activities all the more. These results may provide the important information to investigate the more effective
bus services to promote the prosperity in the aging society.
A Study on Practice of Road Safety Education at School and Home by Using Instructor System for
BicycleYasuyuki TAKEDA, Yasuo HINO, Ryo NAKANISHI, Akira TOYOSHIMA and Tadashi SETOYAMAJapan Society of Civil Engineers，Proceedings of Infrastructure Planning, No. 54，pp.1903-1907 (2016) (inJapanese)
Recently, although the number of road accidents has been decreasing, the accident rate of the bicycle ride has
been increasing. However, the gradual and continuous education at school for road safety may be notrealized, because the almost of them must be depend on the police. Then, in this study, some questionnaire
surveys for the road safety association of Osaka, some teachers and members of PTA were executed, in order
to investigate the possibility of educating the responsible persons and coordinators between school and home,by using the instructor system for road safety for bicycle. As a result, an approach and processes to realize
the intensive education at both school and home were proposed.
Trial Implementation of Danish Cycling Game for Children in Japan and its Evaluation from a
Developmental and Learning Perspective
Nagahiro YOSHIDA, Syuta HOSHIRO and Madoka YANO
Japan Society of Civil Engineers，Proceedings of Infrastructure Planning, No. 55，2 pages (CD-ROM)(2017)(in Japanese)
Issues of Children’s Bicycle Safety Education: A Comparison of the Program between Different
Organizers
Syuta HOSHIRO and Nagahiro YOSHIDA
Japan Society of Civil Engineers，Proceedings of Infrastructure Planning, No. 55，6 pages (CD-ROM)(2017)(in Japanese)－94－

Traffic-Conflict Analysis for the Installation of Bicycle Pavement Markings in Residential Roads
Takuma EDA and Nagahiro YOSHIDA
Japan Society of Civil Engineers，Proceedings of Infrastructure Planning, No. 55，3 pages (CD-ROM)(2017)(in Japanese)
A Study on Identifying Barriers and Potential Opportunities of Adaptive Cycles for People with
Travel Difficulties
Takuya KONISHI and Nagahiro YOSHIDA
Japan Society of Civil Engineers，Proceedings of the annual meeting in Kansai，2 pages (CD-ROM) (2017) (inJapanese)
An Analysis on Motorcycle Driving Behavior of High School and University Students in Phnom
Penh, the Kingdom of Cambodia
Toshiki KOYANAGI, Nagahiro YOSHIDA and Yuto KITAMURA
Japan Society of Traffic Engineers，Proceedings of the 37th annual conference(research paper)，pp.701-704，(2017) (in Japanese)
In recent years, the motorcycle is widely used in developing countries so serious traffic accidents
involving motorcycles have increased in some countries. Especially in Cambodia, the number ofcasualties in traffic accidents has increased about approximately 2.5 times during 2005-2014 as aserious social problem. Under these situations, JICA tried to improve a traffic problem by the
implementation of traffic engineering and the traffic enforcement program, but there is not enoughsupport to deliver traffic educational program especially for younger generation. Therefore, in thisstudy, a questionnaire survey for motorcycle user in high schools and universities was conducted toanalyze the effect of demographic factors on their driving behaviors and the relationship between
driving attitudes and behaviors for safety educational purpose. In addition, the video observation
was also conducted to get verifications and to understand their driving behavior under the actual
traffic environment.

Prediction of settlement of dredged clay containing prefabricated vertical drains and the history ofreclamation in the disposal pond at Kobe Airport
Okada Hirohisa (Kobe City Construction Bureau), Oshima Akihiko and Shibuya Satoru (Kobe University)
Journal of Geotechnical Engineering, Vol. 12, No. 1, pp. 19-31 (2017) (in Japanese)
In order to dispose of dredged clay effectively, it is important to plan the dredged clay disposal based on thesettlement prediction in advance and to understand accurately the acceptable quantity of dredged clay in thedisposal pond. However, it is still a great challenge to understand properly the consolidation characteristicsof the dredged clay for the settlement prediction. The purpose of this paper is, in the disposal pond at Kobe
airport, to calculate the settlement of the clay using the volume ratio f represented uniformly by logf for the
consolidation characteristics of clay (compressibility, permeability and consolidation velocity) and tocompare the calculation with the measurements of various properties. Soil improvement was done in thedisposal pond by the vertical drain using the difference in the water head after the dredged clay was disposedof several times, and then additional dredged clay was disposed of. The authors performed calculations withthe proposed consolidation method against the bed of dredged clay with the complex complicated disposal
history. It is reported that the results agree mostly with the measured settlement, pore water pressure and thewater content at the site.
Concentrations of the Naturally-derived Heavy Metals and its Geochemical Characteristics of the
Alluvial Clays in Osaka Area
Hiroko Ito (Geo-Research Institut), Harue Masuda (Faculty of Science), Akihiko Oshima, Naoko Kitada(Geo-Research Institut) and Teruyuki Fujiwara (Geo-Research Institut)
Proceedings of 12th Environment Geotechnical Engineering Symposium, JGS, pp. 443–448 (2017) (in Japanese)
A Study on Wave Absorption and Flow Characteristics in the Vicinity if a Permeable Breakwater Consistsof Vertically-slotted Walls
Takashi YAMANO, Yusuke NAKAHARA, Takaaki SHIGEMATSU and Ryuichi FUJIWARA
Journal of Japan Society of Civil Engineers, Ser. B2 (Coastal Engineering), Vol. 72, No. 2, I_901-I_906 (2016)－95－

(in Japanese)
The measure against erosion of sandy beaches on the ocean is one of urgent national issues in view of thepredicted sea level rise. Some of the authors have been studied a permeable breakwater with slotted walls
supported by piles for last several years. Although the characteristics of wave attenuation of the breakwater withvertical slits has been examined by numerical calculation so far, enough validity has not been verified yet. In thisstudy, comparison between calculated results by CADMAS-SURF/3D and experimental results on wave
attenuation and flow in the vicinity of the permeable breakwater is presented. As a result, it is shown that the
CADMAS-SURF/3D is a useful tool to design the permeable breakwater in practical use. According to the resultsof the calculation and PIV measurements, it is implied that upward flow in front and back of the breakwater will
be direct relation with local scour and the vertical circulation flow in the chambers of the permeable breakwater
will affect sand transfer.
A Study on Properties of Turbulent Flow Induced by a Horizontally-Oscillating Circular Cylinder
Hiroshi MATSUMOTO and Takaaki SHIGEMATSU
Journal of Japan Society of Civil Engineers, Ser. B2 (Coastal Engineering), Vol. 72, No. 2, I_919-I_924 (2016)(in Japanese)
The flow induced by a horizontally-oscillating circular cylinder in stationary fluid was measured by the PTV
technique and the relationship of turbulent flow and mean flow was investigated on the basis of the measured data.
Transverse velocity of time-mean flow was large in the area that vortexes shed from a circular cylinder distributed.
Although turbulent intensity was small in the area that vortexes shed from a circular cylinder did not distribute,the one was large in the area that vortexes shed from a circular cylinder distributed. In the area that time-mean
turbulent energy was large, transverse velocity of time-mean flow was also large. It was suggested that turbulence
induced by vortexes shed from a circular cylinder contributed to occurrence of mean flow generated around acircular cylinder.
A Numerical Study on Inundation Properties in Maritime Urban Space Induced by Severe Storm Surge
and River Flooding
Shota MORI and Takaaki SHIGEMATSU
Journal of Japan Society of Civil Engineers, Ser. B2 (Coastal Engineering), Vol. 72, No. 2, I_1645-I_1650 (2016)(in Japanese)
A numerical simulation model, which can calculate spread of inundation area on the ground and in the space ofsubway track by a severe storm surge and river flooding simultaneously, is developed and described in detail.
Based on the calculation results, quantitative analysis of characteristics of simultaneous occurrence of inundation
due to storm surge and river flooding are presented. Moreover, evacuation activities appropriate to occasion ofwater disaster are also referred.
Performance Evaluation of a Wave Generation System Using Vertically-Slotted Breakwater for Irregular
Wave
Shinji MORIMOTO, Takaaki SHIGEMATSU, Daichi UEJIMA, Kenji KATOH, Tatsuro WAKIMOTO and Sin'ya
YOSHIOKA
Journal of Japan Society of Civil Engineers, Ser. B2 (Coastal Engineering), Vol. 72, No. 2, I_1537-I_1542 (2016)(in Japanese)
Authors have been developed a wave generation system using the vertically slotted breakwater and savonius-typewater mills for several years. It has been already found from a series of a hydraulic experiment that the wave
generation system have a superior wave attenuation function for wide range wave frequency rather than thepresent breakwater and that rotational velocity of a water mill can be estimated by using water velocity through aslit. However, the knowledge for the irregular wave has never been obtained at all. Hence, in order to obtain theknowledge for the irregular wave, hydraulic experiment was carried. It is found out that attenuation function will
be superior by introducing water mills into the chamber. The estimation formula of the power of a water mill fromwaves is also introduced.
Sensitivity of Storm Surge Height and Inundation Area on Climate Change in Osaka Bay
Yoko SHIBUTANI, Sota NAKAJYO, Sooyoul KIM, Nobuhito MORI and Hajime MASE
Journal of Japan Society of Civil Engineers, Ser. B2 (Coastal Engineering), Vol. 72, No. 2, I_217-I_222 (2016)(in Japanese)
Impact of climate change on tropical cyclones has been assessed for coastal disasters. In this study, we have－96－

carried out a sensitivity tests of storm surge simulations to climate change considering typhoon characteristics andsea level rises in the Osaka bay. The results indicated that the maximum surge height with the worst track is 1.0m
higher than the 2nd Typhoon Muroto maximum surge height with the 2nd Muroto track. There are less flooding
compared to that of the original track, but the the inundation area is increased signifisantly under the futureclimate condition. The changes of inundation area due to climate change will be increased about 160 % incomparison with historical run. In addition, we estimated its return period as 21 years based on stochastic tropical
cyclone model.
Basic Study on Real-time Prediction of ABIKI around West Kyushu Coast by Using Neural Network Model
Sota NAKAJO, Ryuta YAMAGUCHI, Takaomi HOKAMURA and Sooyoul KIM
Journal of Japan Society of Civil Engineers, Ser. B2 (Coastal Engineering), Vol. 72, No. 2, I_181-I_186 (2016)(in Japanese)
Real-time prediction of unusual sea level fluctuation, called as ”Abiki”, is important from viewpoint of disasterprevention. Atmospheric pressure fluctuation with small amplitude is regarded as one of important factor of Abiki.
However, actual real-time prediction of the distribution is difficult. In this study, we developed neural networkmodel for prediction of Abiki and investigated the relationship between the reproducibility and parameters of ourbasic model. It was shown the importance of information of pressure fluctuation and wind direction from ourmodel again. Then the potential of improvement of our model by using multispot measurement was also shown.
Sediment Stratigraphy Observed by MASW Survey along an Array Comprised of Supralittoral,
Mediolittoral, and Infralittoral Zones
Yoichi WATABE, Takashi KANEKO, Shinji SASSA, Yuji HASHIMOTO and Sota NAKAJOJournal of Japan Society of Civil Engineers, Ser. B2 (Coastal Engineering), Vol. 72, No. 2, I_1699-I_1704 (2016)(in Japanese)
The Okoshiki Coast in Uto City, Kumamoto Prefecture, Japan, is a beautiful sandy tidalflat with rhythmicalvariation of multi-bar-trough structure. To investigate the sediment stratigraphy, multi-channel analysis of surface
waves (MASW) was applied to this sandflat; however, the conventional method using geophones was only
applicable to exposed regions in supralittoral and mediolittoral zones. In this study, MASW array was extended
from mediolittoral to infralittoral zones by using hydrophones instead of geophones. Sediment stratigraphy was
successfully evaluated by using geophones in supralittoral and mediolittoral zones during exposed periods andusing hydrophones in mediolittoral and infralittoral zones during submerged periods. In the MASW survey usinghydrophones conducted on a boat, it must be noted that the shear wave velocity structure at shallower depth isinfluenced by the offset distance between the shot point and the nearest hydrophone.
Long-term Projection of Storm Surge Change by Neural Network Based on Stochastic Tropical Cyclone
Model
Shiori IWABE, Nobuhito MORI, Sota NAKAJO, Tomohiro YASUDA and HAJIME MASE
Journal of Japan Society of Civil Engineers, Ser. B2 (Coastal Engineering), Vol. 72, No. 2, I_1465-I_1470 (2016)(in Japanese)
A long-term assessment of storm surge using the stochastic typhoon model (STM) is one of the secured
methodology with the large number of samples of the reproducibility is desired if we can estimate storm surge
from STM. This study has improved statistical maximum storm surge model, which uses only typhoon
information, in the three major bays using artificial neural network (NN). In order to estimate long-term changes
in storm surge characteristics under future climate conditions, NN uses STM and climate database for Policy
Decision making for Future climate change (d4PDF). The long-term impact assessments of storm surge using
several scenarios are compared.
Stochastic Tropical Cyclone Model and Its Application
Sota NAKAJO, Nobuhito MORI, Tomohito YASUDA and Hajime MASE
The Proc. of the 26th Ocean Engineering Symposium, March 6-7, (2017)
Stochastic tropical cyclone model is one of useful tools for assessment of extreme disaster event from limited
observation tropical cyclone data. In this paper, overview of an example of stochastic tropical cyclone model andits validation results have been shown. Probability density function of tropical cyclone properties and its change
rate have shown overview of development and dissipation process of tropical cyclone in West North Pacific Ocean
and North Atlantic Ocean. Good reproducibility of stochastic tropical cyclone model has been shown bycomparison of global distribution of average minimum SLP and time series of minimum SLP of tropical cyclone－97－

arrived at local bay. Two examples of application of stochastic tropical cyclone model have been shown.
Properties of tracks of tropical cyclone which would cause heavy rain at Tone River basin was shown and its
return period was calculated. The necessary conditions of tropical cyclone properties which would cause severe
storm surge event at Yatsushiro Bay was shown and return period was also calculated. Both examples show tracksof tropical cyclone which caused extreme event is not so unusual. However, probability of fulfilling all conditionsof TC tracks, minimum SLP and translation speed was very small.
Impact Assessment of Climate Change on Coastal Hazards in Japan
Nobuhito MORI, Mark KJERLAND, Sota NAKAJO, Yoko SHIBUTANI and Tomoya SHIMURA
Hydrological Research Letters 10(3), 101-105, (2016)
Understanding future changes of ocean waves and storm surges is important for assessing and mitigating theimpact of climate on coastal, marine and ocean environments and on engineering problems. This paper reviews
the latest research results of climate change impacts on coastal hazards in Japan. First, future changes of wave
climate and storm surges based on MRI-AGCM ensemble experiments are summarized. Second, the applicationsof coastal hazard projections to coastal structures and beach profiles are summarized as a series of climate impact
assessment projects. There are clear increases in extreme values of wave heights and storm surges in the tropical
cyclone dominant regions around the middle latitudes of the Western North Pacific including Japan. The influenceof future climate change on caisson breakwaters is discussed considering sea level rise, extreme wave conditions
and storm surges targeting the Pacific side of Japan.
Characteristics of CO2 Absorption and Emission in the High Water Temperature Seasons at the North Salt
Marsh of Osaka Nanko Bird Sanctuary
Toshiyuki TANAKA, Toru ENDO, Noriaki IKADA and Susumu YAMOCHI
Journal of Japan Society of Civil Engineers, Ser.B2 (Coastal Engineering), Vol.72, No.1, pp.1-11 (2016) (inJapanese)
Field investigations were conducted at the north salt marsh of Osaka Nanko bird sanctuary (ca. 43100 m2) in highwater temperature seasons of 2012-2014 and the amount of net CO2 absorption was estimated along with thecharacteristic of CO2 absorption and emission on the surface of the sediment. Gross CO2 absorption flux was
closely related to sediment temperature, chlorophyll a and photon flux density, while CO2 emission flux changed
depending on the sediment temperature and groundwater level. The groundwater level was thought to beindispensable for estimating the flux of CO2 emission on the sediment. For instance, when it was supposed
groundwater level was equal to tidal level, the CO2 emission flux from the sediment reached 29 tons. It showed
2.1 times higher than the value which was estimated by using actual ground water level. Using the relationship of
CO2 flux with sediment temperature, chlorophyll a, photon flux density and groundwater level, the total CO2
absorption and/or emission of the north salt marsh of Osaka Nanko bird sanctuary was estimated as ca. 23 tons forabsorption and ca. 14 tons for emission in May to September, 2014. These results suggest that a net of 9 tons CO2
was absorbed and this salt marsh plays the role of a CO2 sink in the high temperature season of a year.
Evaluation Method of CO2 Exchange at the Intertidal Flat, the Sea Surface and the Sea Bottom of an
Artificial Salt Marsh in Urban Coastal Zone
Toru ENDO, Yusuke NAKANO and Noriaki IKADA
Journal of Japan Society of Civil Engineers, Ser. B2 (Coastal Engineering), Vol.72, No.2, pp.1447-1452 (2016)(in Japanese)
In order to examine the evaluation method of CO2 exchanges of the artificial salt marsh in urban coastal area, CO2
exchange of the intertidal flat and the sea surface were reviewed based on the measurement data by chamber
method at Osaka Nanko bird sanctuary in 2014-2015. Furthermore, the sea bottom CO2 emission was measured
by conducting laboratory experiment using the sediment. After the gross photosynthesis rate of microalgae on theintertidal flat was approximated by three type models, it was suggested that CO2 absorption rate of the intertidal
flat is able to estimate by the sediment temperature and the light intensity. It was thought that CO2 emission of theintertidal flat is able to be expressed as a function of the sediment temperature. On the other hand, it is found thatthe measurement data by chamber method and the estimation data by bulk equation must be used selectively
according to wind condition in order to estimate the air-sea CO2 exchange. Finally, it was thought that the sea
bottom CO2 emission is desirable to estimated from the data of time variation of DIC concentration of the sea
water.
A Research on the Dynamics of the Refractory Organic Carbon in the Sediment of an Artificial Salt Marsh－98－

Naoto NISHIO, Toru ENDO and Susumu YAMOCHI
Journal of Japan Society of Civil Engineers, Ser. B2 (Coastal Engineering), Vol.72, No.2, pp.1315-1320 (2016)(in Japanese)
Biodegradability tests were conducted and refractory organic carbon in the sediment of an artificial salt marsh wasseasonally examined because of increasing demands for the knowledge of carbon storage at the salt marsh. The
results revealed that 45.9 - 77.0% of the sedimentary organic carbon were refractory organic carbon at theintertidal area, while the refractory organic carbon increased up to 92.5 - 98.3% at the submerged area. A roughestimation of carbon storage at the upper 5 cm of the sediment was 9.5 ton C for intertidal area and 27.6 ton C for
submerged area of the north salt marsh of Osaka Nanko bird sanctuary.
Seasonal Changes on Characteristics of sediment and Carbon Dioxide Absorption / Emission Rate at mud
river Mouth Tidal Flat
Sosuke OTANI, Taiki KAWASAKI, Toru ENDO and Kazuyuki HIGASHI
Journal of Japan Society of Civil Engineers, Ser. B3 (Ocean Engineering), Vol.73, No.2, pp.630-635 (2017) (inJapanese)
To elucidate relationships between CO2 absorption and emission rates and properties of sediment at Yodo Rivermouth tidal flat was conducted in this study. Similarly, CO2 fluxes (CO2 absorption and emission rate) were alsomeasured using light and dark chamber. Chemical properties of sediment such as Chl.a, ORP, AVS fluctuated andmaximal values were different season throughout the year. There is a negative correlation only between ORP andsoil temperature. The CO2 absorption rate fluctuated 0.0675 to 6.63 mg CO2/m2 /min, the CO2 emission rate was
0.038 to 2.82 mg CO2/m2 /min, respectively. They showed maximal values in summer season and were positively
strongly correlated with soil temperature, Emission rate in water surface was three times higher than emission rate
in sediment. Moreover, it is suggested that macrobenthos respiration contributed to emission rate in sediment.
Effects of Light, Temperature and Ground Water Level on the CO2 Flux of the Sediment in the High Water
Temperature Seasons at the Artificial North Salt Marsh of Osaka Nanko Bird Sanctuary, Japan
SusumuYAOMOCHI, Toshiyuki TANAKA, Yuri OTANI and Toru ENDO
Ecological Engineering, Vol.98, pp.330-338 (2017)
Field investigations and indoor experiment were carried out to clarify the effect of temperature and chlorophyll aconcentration of the sediment, photon flux density, and ground water level on the absorption and emission of CO2
from the surface sediment of the artificial salt marsh. The flux of CO2 absorption was closely related to sedimenttemperature, chlorophyll a and photon flux density. On the other hand, flux of CO2 emission changed dependingon the sediment temperature and ground water level. The ground water level was thought to be indispensable for
estimating CO2 emission from the sediment of the intertidal zone of the salt marsh. Using equations of CO2 flux
with sediment temperature, chlorophyll a, photon flux density and ground water level, the total CO2 absorption
and emission of the artificial north salt marsh of Osaka Nanko bird sanctuary was estimated as ca.23 tons (4.3
g-CO2/m2/day) for absorption and ca.14 tons (2.6 g-CO2/ m2/day) for emission in May to September 2014. These
results suggest that a net of 9 tons of CO2 (1.7 g-CO2/m2/day) was absorbed, and that this salt marsh performs thefunction of a CO2 sink in high temperature seasons.
Fraction of Phosphorus Composition in Sewage Sludge and its State Change by Acid Treatment
Hizuru WAKAYAMA, Yoshinori KANJO, Masafumi OHTA, Mayu SHIRAI and Satoshi MIZUTANIJournal of Japan Society of Civil Engineers, Ser. G (Environmental Research), Vol.72, No.7, III_243-III_248(2016) ( in Japanese)
In order to recover the phosphorus from sewage sludge and to prevent from the trouble at incineration plants
caused by phosphorus in sludge, fractionation analysis of phosphorus in sewage sludge of eleven municipal
sewage treatment plants and acid treatments were performed. The results of fractionation analysis showed that
phosphate fractions and particulate phosphate fraction in digested sludge ranged 73 to 89% and 24 to 62%,
respectively. The results of acid treatments showed that particulate phosphate fraction could be dissolved tophosphate ion thoroughly at the pH condition of 2 with sulfuric acid, 5 with citric acid, or 4 with acetic acid.
Judging from these results, dissolved fraction of phosphorus in digested sludge will be able to increase more thandoubled using with acid treatment.
Relationship between the Distributions of Refuges, Population and Estimated Earthquake Intensity inOsaka City during the Uemachi Fault Earthquake
Kazuki NISHIMURA, Yoshinori KANJO and Satoshi MIZUTANI－99－

Annual Journal of Urban Disaster Reduction Research, Vol.3, pp.31-35 (2016) (in Japanese)
Distribution of Phosphorus Composition in Sewage Digested Sludge and Effects of Acid Extraction
Conditions on Phosphorus Recovery
Yoshinori KANJO, Hizuru WAKAYAMA, Mayu SHIRAI and Satoshi MIZUTANIProceeding of the 7th Forum on Studies of the Environmental & Public Health Issues in the Asian Mega-cities(EPAM2016), pp.114-115 (2016)
In order to develop the new recovery method of phosphorus in sewage sludge, the distribution of phosphorus
composition in sewage digested sludge and effects of acid extraction condition on phosphorus recovery asmagnesium ammonium phosphate (MAP) or hydoroxyapatite (HAP). According to the fractionation analysis ofphosphorus contents in 12 sewage digested sludge, the distributions of P-PO4-P and D-PO4-P were obtained, andit suggested that soluble fractions of phosphorus in these digested sludge after acid treatment reached to around80%. The results of MAP/HAP formation experiments suggested that formation of MAP from these supernatant of
the digested sludge was affected negatively by citric acid and acetic acid, and recovery of phosphorus as HAP was
suitable for these digested sludge.
Basic Study of Heavy Metals and Chelating Agent Behaviour from Chemical-Treated Incineration Fly Ash
in Leaching Test
Satoshi MIZUTANI，Yutaro UEDA, Shota MATSUDAIRA, Hirofumi SAKANAKURA (National Institute forEnvironmental Studies) and Yoshinori KANJO
Proceeding of the9th International Conference on Combustion, Incineration/Pyrolysis, Emission and Climatechange (i-CIPEC 2016), September 20-23, Kyoto, Japan (2016)
The unevenness of chemical treated MSWI-FA and the behavior of Pb and chelating agent during agitation timeof batch type leaching test are studied. Fly ash sampled from stoker-type incinerator in Japan was used, and it was
chemical treated with a chelating agent with dithiocarbamic group belonging to piperazine series in our laboratory.
To confirm the unevenness of chemical treated fly ash, multiple experiments for 16 portions of treated fly ash
were performed. The variation of the leaching test results was very small and the unevenness of the treated fly ash
is negligible. Because a good positive correlation can be observed between chelating agent concentration and
TOC concentration, TOC can be used as an alternative indicator for chelating agent concentration. The behaviorof Pb and TOC in the leachate during agitation time in JLT-13 was studied. During the agitation time in theleaching test, chelating agent were spiked and time trend of Pb concentration and chelating agent concentration
are observed. When the chemical agent was added, both of Pb and TOC concentration decreased. The factsuggests the stabilizing reaction of chelating agent for heavy metals during agitation time in leaching test.
Heavy Metal Leaching Behaviour from Chemical-stabilized Fly Ash by Column Test under Three Kinds ofFlow Rate Condition
Yutaro UEDA, Satoshi MIZUTANI, Hirofumi SAKANAKURA (National Institute for Environmental Studies)
and Yoshinori KANJO
Proceeding of the 9th International Conference on Combustion, Incineration/Pyrolysis, Emission and Climatechange (i-CIPEC 2016), September 20-23, Kyoto, Japan (2016)
Column leaching tests for both chemical-treated and water-treated fly ash with three kinds of flow rate condition
for 60 days were performed and leaching concentration change over time is observed. Fly ash sampled fromstoker-type incinerator with dry system, Ca(OH)2 injection, for acid gas treatment in Japan, were used forexperiments. The ash is stabilized in our laboratory by chelating agent, which is the agent with dithiocarbamic
group belonging to piperazine series. For comparison, the water-stabilized fly ash is also prepared by addition of
only distilled water and kneading. Column experiment is a down-flow test, and the flow rates of leachant are
three patterns: 1) Continuous condition, 2) Semi-continuous condition and 3) Intermittent condition. Unsteadyleaching of Pb was observed at the initial stage, first several days. Then the concentration slightly increased but
remained on the same level. After 60 days, the leaching concentration and cumulative leaching ratios fromchemical-treated fly ash were lower in 1- 2 orders of magnitude than water-treated one. The clear correlation
between the flow rates and leaching quantity were not observed. These facts suggested that the Pb leaching iscontrolled not only by advection flow of leachant but by diffusion.
Total Organic Carbon (TOC) in Leachate from Municipal Solid Waste Incineration Fly Ash in Japan
Satoshi MIZUTANI, Katsunori MATOZAKI, Hirofumi SAKANAKURA (National Institute for Environmental
Studies) and Yoshinori KANJO－100－

Proceeding of the 4th 3R International Scientific Conference on Material Cycles and Waste Management, New
Delhi, India, March 8-10, (2017)
TOC in the leachate from four kinds of MSWI fly ash and from two kinds of reactive slaked lime were measured.
Higher level of TOC was detected in the leachate from the fly ash from incinerators with dry-acid gas treatment
system. The leachates from reactive slaked limes also show high level of TOC. On the contrary, calcium
hydroxide did not show the leaching of TOC. Therefore the origin of the organic carbon in fly ash is addedorganic materials in order to enhance reactivity of lime with acid gas. The contents of TOC in the two kinds of thereactive slaked lime were 1,260 and 5,680 mg/kg respectively and showed very wide range.
Utilization and Issue of Leaching Tests in Geo-environmental Engineering
Yasutaka WATANABE (Central Research Institute of Electric Power Industry), Tetsuo YASUTAKA (National
Institute of Advanced Industrial Science and Technology), Yukari IMOTO (National Institute of Advanced
Industrial Science and Technology), Koichi KAWAMURA (Kokusai Kogyo Co., Ltd.), Shinji MIYAGUCHI(OYO Corp.), Mitsuhiro Sumikura (Shimizu Corp.), Hirofumi SAKANAKURA (National Institute forEnvironmental Studies), Satoshi MIZUTANI, Kei HIRATA (MC Evolve Technologies Corp.) and ResearchCommittee on Developing a New Geo-environmental Management and Standard for Social Imprementation(Japanese Geotechnical Society)
Proceedings of the 12th Japan National Symposium on Environmental Geotechnology, September 25-26,
Nagasaki, Japan (2017) (in Japanese)
The best form of the batch type leaching test as a compliance test for environmental geotechnology was discussed.
Questionary investigation for specialists and review of scientific papers were performed. In order to increase therepeatability and reproducibility of the results, four kinds of operational steps, that is 1. sampling, 2. sample
preparation, 3. leaching procedure, 4. leachate preparation, were focused on this study. Based on the answers, thedifferent elements and the existing problems were marshalled and summarized.
Hazardous materials used in a large ship: A survey of an example of an inventory of hazardous materials(IHM) for a vessel
Satoshi MIZUTANI and Hiroshi HASEGAWA (Kanazawa Univ.)
Proceeding of the 8th Forum on Studies of Environmental and Public Health Issues in Asian Mega-cities(EPAM2017), September 1-2, Seoul, Korea (2017)
Contamination of sea and seashore by hazardous materials from shipbreaking industry in Asian countries is often
reported. In order to prevent such environmental contamination and to protect industrial health and safety forlabors, preparation of inventory of hazardous materials (IHM) is required for the merchant vessel bigger than 500
Gross Tonnage in accordance with Hong Kong International Convention for the Safe and Environmentally Sound
Recycling of Ships. In this study, the contents and systems of IHM for a vessel are summarized firstly. Secondary,based on the examples of IHM of a large ship, hazardous materials used in the ship is summarized. IHM is a listof the hazardous materials used in a ships structure, equipment and machinery and hull. In a case of a certain car
carrier vessel (28406 GT), more than 500 kg of asbestos and more than 80 kg of HCFC are used. Regarding
heavy metals, tin and lead were indicated. More than 100 kg of TBT is used as paints and coating systems. On thecontrary, approximately 440 kg of lead is used in lead-acid storage batteries in a navigation bridge deck.

－101－

ISSN

Faculty of Engineering are compiled herein. Abstracts of paper presented elsewhere
during the current year are also compiled in the latter part of the volume.
All communications with respect to Memoirs should be addressed to:
Dean of the Graduate School of Engineering
Osaka City University
3-3-138, Sugimoto, Sumiyoshi-ku
Osaka 558-8585, Japan
Editors

MEMOIRS OF THE FACULTY OF ENGINEERING OSAKA CITY UNIVERSITYThis Memoirs is annually issued. Selected original works of the members of the0078－6659

MEMOIRSOF THEFACULTY OF ENGINEERINGOSAKA CITY UNIVERSITY

VOL. 58
DECEMBER 2017

Yoshinori KANJO
Makoto UCHIDA
Masafumi MURAJI
Hisayoshi SUGIYAMA
Takeshi NAKANISHIEri GAVANSKI

VOL. 58.
2017

1711-0100 大阪市立大学 工学部
1-4
工学部英文紀要VOL.57（2016）

PUBLISHED BY THE
GRADUATE SCHOOL OF ENGINEERINGOSAKA CITY UNIVERSITY

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