ISSNMEMOIRS OF THE FACULTY OF ENGINEERING OSAKA CITY UNIVERSITY
VOL. 55.
2014

1411-0033‫ޓ‬ᄢ㒋Ꮢ┙ᄢቇ‫ޓ‬ᎿቇㇱᎿቇㇱ⧷ᢥ♿ⷐ81.㧔㧕‫ޓ‬0078䋭6659

MEMOIRSOF THEFACULTY OF ENGINEERINGOSAKA CITY UNIVERSITY

VOL. 55
DECEMBER 2014

PUBLISHED BY THE
GRADUATE SCHOOL OF ENGINEERINGOSAKA CITY UNIVERSITY⷗ᧄࠬࡒThis Memoirs is annually issued. Selected original works of the members of theFaculty of Engineering are compiled herein. Abstracts of paper presented elsewhere
during the current year are also compiled in the latter part of the volume.
All communications with respect to Memoirs should be addressed to:
Dean of the Graduate School of Engineering
Osaka City University
3-3-138, Sugimoto, Sumiyoshi-ku
Osaka 558-8585, Japan

Editors

Kouichi TSUJI
Tatsurou WAKIMOTO
Hideo TAKEUCHI
Tomohito TAKUBO
Eriko SATO
Masumi FUJIMOTO
Toru ENDO

1411-0033‫ޓ‬ᄢ㒋Ꮢ┙ᄢቇ‫ޓ‬ᎿቇㇱᎿቇㇱ⧷ᢥ♿ⷐ81.㧔㧕‫ޓ‬ࠬࡒMEMOIRS OF THE FACULTY OF ENGINEERINGOSAKA CITY UNIVERSITY
VOL. 55

DECEMBER 2014

CONTENTS
Regular Articles ··········································································

1

Physical Electronics and Informatics
Applied Physics and Electronics
Influence of Absorbing Substrates on Laser Oscillation of Quantum-Well Microtube Lasers
Makoto HOSODA and Naoki KATAYAMA ·················································· 1

Urban Engineering
Urban Design and Engineering
Response of Larval and Postlarval Greasyback Prawns to Hypoxia
Susumu YAMOCHI, Ken IKEDA and Kazuma MUTSUTANI ·····························

9

An Analysis on Influence Factors to Use Frequency and WTP of Shopping Support Services
for People in Food Desert
Noboru ISE and Yasuo HINO ································································· 19
Formation of Waterside Spaces with Groins
Yasumasa FUKUSHIMA and Takashi UCHIDA ··········································· 27
Sensitivity Analysis on Influence of Fabrication Tolerance of High Strength Bolted Friction
Type Joint to its Slip Strength
Toshikazu TAKAI, Takashi YAMAGUCHI and Kiyonori YAMASHINA ·················· 35
Study on Applicability of High Durability Friction Grip Joints with High Strength
Countersunk Head Bolts for Steel Bridge Structures
Akiko TABATA and Takashi YAMAGUCHI ·················································· 43

A Path to Creating an Opportunity for Communication using the “Machizukuri Pattern”
Yasutomi SAKUMA ············································································· 51
Approach to Improve Driving Condition on Desert highway from Viewpoint of Road Safety
Zulpikar KERAM and Yasuo HINO ··························································· 57

Abstracts of Papers Published in Other Journals ······································ 63
Mechanical and Physical Engineering
Mechanical Engineering ········································································ 65
Applied Mathematicsg ············································································ 74
Physical Electronics and Informatics
Applied Physics and Electronics ······························································ 75
Electric and Information Engineering ······················································· 88
Applied Chemistry and Bioengineering
Applied Chemistry and Bioengineering ······················································ 92
Urban Engineering
Architecture and Building Engineering ······················································ 113
Urban Design and Engineering ·································································· 115

ISSN

MEMOIRSOF THEFACULTY OF ENGINEERINGOSAKA CITY UNIVERSITY――――――――
VOL. 55――――――――DECEMBER 2014

PUBLISHED BY THE
GRADUATE SCHOOL OF ENGINEERINGOSAKA CITY UNIVERSITY

0078－6659

Influence of Absorbing Substrates on Laser Oscillation of Quantum-Well Microtube Lasers
Makoto HOSODA and Naoki KATAYAMA(Received October 14, 2014)

Synopsis
We evaluated the influence of absorbing substrates on laser oscillation of quantum-well microtube lasers.
We calculated absorption loss of whispering gallery modes propagating in hollow semiconductor microtubes
with a separation distance from the substrate by the finite-difference-time-domain (FDTD) method. Even
under the non-contact condition to the substrate, evanescent waves leaked from the tube-wall are absorbedby the substrate, which is known as the photon-tunneling phenomenon. Our simulation result shows that
separation distances from one micron to several tens of microns decrease the loss to 10-3. When the optical
gain from the quantum well (QW) or quantum dots (Q-dots) in the microtube wall was able to overcome theabove absorption loss, laser oscillation from the QW- and Q-dot-microtubes occurred.
KEYWORDS: Quantum-well microtube, Whispering gallery mode, Photon tunneling
1. Introduction
Since quantum-well microtube proposed and demonstrated as a new type of quantum-well (QW) opticaldevice by Hosoda et al.,1) many studies have been conducted on the systems, e.g. optical devices using
quantum-dots (Q-dots) in microtubes. Recently, Kipp et al. have found sharp optical resonance by a kind ofwhispering gallery mode in a cylindrical optical micro-cavity formed by the microtubes,2) and the physicalbackground of this experimental result has been corroborated by a simulation result from Hosoda et al.3)
Based on these findings, microtubes containing QWs or Q-dots have attracted a lot of attention as highquality factor (Q-factor) cavities, which allow achievement of ultralow threshold semiconductor lasers, andmany studies have concentrated on creating a structure to achieve this. To establish the above characteristics,
mechanical structures of the optical resonators, as well as emission properties of the quantum structures,
have been studied with promising results.4-6) Laser oscillation from these structures by optical excitation has
also been reported.7-9) However, cavity loss by substrate absorption has not yet been clarified.
To increase the Q-factor, decrease of cavity loss is important. One of the losses comes from absorption by
the substrate of light circularly propagating around the cylindrical cavity. In this report, we evaluate opticalloss by leakage of light from the microtube wall to the absorbing substrate, which mechanically supports the
microtube. This estimation is thought to be important for design of current injection microtube lasers, but
those have not been achieved thus far. The evaluation is performed by the finite-difference-time-domain(FDTD) method with realistic values of a QW microtube.
2. Overview of QW microtube
Figure 1 shows the structure and fabrication method of the QW microtube.

Department of Applied Physics−1−

Fig. 1 Fabrication method of QW-microtube. (a) Growth sequence by Molecular-Beam Epitaxy. (b) After growth. (c)Fabrication of microtube by selective etching. (d) Completion of microtube formation.

The sample is fabricated by rolling a thin heterostructure film. First, a multilayered thin semiconductor film
is grown on a (100)-oriented intrinsic GaAs substrate by molecular beam epitaxy. An example of the growthsequence is shown in Fig. 1(a): from the substrate, a 200-nm GaAs buffer layer; a 0.4-nm/0.4-nm x 100
Al0.52Ga0.48As/AlAs digital alloy sacrificial layer; a 7-nm In0.19Ga0.81As strained layer; a 10-nm Al0.75Ga0.25As
bottom barrier; a 2-nm, i.e. 7-monolayer (ML) GaAs QW; a 10-nm Al0.75Ga0.25As top barrier, and a 10-nm
GaAs cap layer.
On this occasion, the InGaAs layer suffers compressive strain, and does not relax since the thickness is lessthan the critical thickness. After growth, the sacrificial layer is selectively etched with HF:H2O (1:10), thenthe upper layer is released from the substrate and rolled up from the cleavage surface due to the strain
relaxation effect of the InGaAs layer, as shown in Figs. 1(c) and (d).
The sample is subsequently soaked in pure water and dried with care to prevent microstructural damage or
sticking due to the surface tension of the water meniscus. Finally, the rolled-up film forms a microtube.
Figure 2 shows the fabricated QW-microtubes. The cross section of the microtube in Fig. (c) indicates thatthese microtubes are perfectly hollow, and the wall thickness is several tens of nanometers. Therefore, it isproved that the quantum structure illustrated in Fig. 1 can be successfully fabricated.

Fig. 2 (Color online) Photograph of microtubes. (a) Optical microscope image of a microtube rolled up from acleavage surface (left side in the image). (b) Optical microscope image of a microtube. Hollow structure can be seen. (c)Vertical SEM image of the microtube 6-microns in diameter in (a).

Figure 3 shows a schematic figure of a kind of whispering galley mode generated in hollow microtubes,
which can be established as described in Ref. 3. Our simulation under the condition of a microtube isolated
from the substrate shows sharp peaks with high Q-factor caused by the resonance of the whispering galley
modes, as shown in Fig. 4. Therefore, a low-threshold laser may be achieved.
However, actual systems shown in Figs. 1 and 2 contact the substrate. This causes decay in the opticalintensity of the mode, which is caused by absorption of light by the substrate. To avoid this problem,
separation of the microtube from the substrate is needed. Since the microtube is supported by the substrateand cannot be detached from it, a method is used that grooves a ditch into the substrate just under the−2−microtube,2) as shown in Fig. 5. However, there has been no report regarding how deep of a groove issufficient to reduce the absorption of light running around the microcavity. Therefore, we evaluated this.

Fig. 3 Schematic figure of optical resonance inhollow cylindrical microcavity.

Fig. 4 Calculated resonance peaks of whispering galley
modes in a QW-microtube.

Fig. 5 Schematic figure of microtube on deep
groove cut on substrate.

Fig. 6 (Color online) Calculated intensity ofwhispering gallery mode in free-standing microtube.

3. Simulation result and discussion
Simulation is done by the FDTD method. By comparing the light intensity in microtubes separated from thesubstrate with finite distance to intensity in a free-standing microtube with infinite distance from thesubstrate, decrease in the optical intensity by absorption was studied.

−3−

Figure 6 shows distribution of the light intensity of a whispering gallery mode established in a free-standing
microtube. The scattering at the upper portion of the tube is caused by a notch in the rolled-up tube.3) Figure
7 shows the simulation condition under finite separation distance. In the rolled-up tube, there are two notchesat the upper and lower positions, as shown in Fig. 7. Under the lower notch, the substrate is positioned with aseparating distance, which is a key parameter in the simulation. The diameter of the tube is 6 microns, andthis is the real diameter of the tube shown in Fig. 2. We adopted the sharp peak at 683.8 nm in Fig. 4 for thewhispering gallery mode in our simulation, since it has a high Q-factor. This emission wavelength is possible
under uniaxial strained QW.1)

Fig. 7 Schematic figure of simulation condition.

Fig. 9 Spatial distribution of light intensity aroundtube wall.

Fig. 8 (Color online) Evolution of light intensity in microtube vs. separation distance from substrate.

Figure 8 shows calculated evolution of light intensity in the microtube. In the calculation, an optical pulse of
longer than 1-ps pulse width is injected from the left side of the microtube, as shown in Fig. 7; then, it runs
around the tube periphery. Since the tube diameter is 6 microns, optical pulse circling the tube periphery−4−

counterclockwise arrives at the bottom of the tube, where the nearest point to the substrate (cf. Fig. 7) iswithin 100 fs. In addition, the pulse going clockwise also arrives there within several hundreds of fs. Whenthe absorption by the substrate occurs at that point, pulse intensity decreases. Therefore, when the separation
distance is short, the light intensity is greatly decreased, as shown in Fig. 8.
Why does the decrease occur under non-zero value of the separation distance? This is because photon
tunneling10) occurs. Since the wall thickness of the microtube is far thinner than the light wavelength, i.e.
42-nm wall thickness versus 683.8-nm light wavelength, the distribution of light intensity going around thetube wall greatly seeps out from the tube wall as evanescent wave.3) The electromagnetic wave soaked out
from the tube wall is influenced by the boundary condition of the propagation. When an absorbing material
exists sufficiently close but is not in contact, this configuration causes absorption, i.e. photon tunneling. The
left side of Fig. 9 shows the distribution of the light intensity around the tube wall at normal propagation. In
contrast, the distribution is changed at a position that comes close to the substrate, as shown in the rightfigure. Evanescent wave soaked from the wall can enter into the substrate in this condition, which means
photon tunneling.10)
Figure 10 shows light absorbed into the substrate under slight separation from the substrate. In this case,Snell’s law also applies, even under the photon tunneling condition, as shown in the figure.

Fig. 10 (Color online) Absorption of light going clockwise in periphery of microtube slightly separated from substrate.
The propagating direction of the absorbed light by photon tunneling adheres to Snell’s law.

−5−

Fig. 11 Absorption rate of separated microtube compared to in-contact one.

Figure 11 shows the absorption rate of separated microtube compared to that of an in-contact one(separation distance = 0) as a function of the separation distance. At distance greater than 3 x 104 nm, i.e.
approx. 50 times the light wavelength propagating in the tube wall, one-thousandth of an improvement in theabsorption loss is achieved compared to the in-contact tube. From this result, separation distance of one
micron to several tens of microns might be sufficient for visible light wavelengths when optical gain from
QW or Q-Dots in microtubes is sufficiently high to be able to overcome the absorption loss, which may
easily generate laser oscillation in QW- and Q-dot-microtube systems.
4. Conclusions
We calculated absorption loss of whispering gallery modes in hollow semiconductor microtubes with finite
separation distance from the substrate. Our simulation result shows that separation greater than 50-times the
optical wavelength is sufficient for easily establishing laser oscillation from the QW- and Q-dot- microtubes.
5. References
1)
2)
3)

M. Hosoda et al., Appl. Phys. Lett. 83, 1017 (2003).
T. Kipp, H. Welsch, C. Strelow, C. Heyn, and D. Heitmann, Phys. Rev. Lett. 96, 077403 (2006).
M. Hosoda and T. Shigaki, Appl. Phys. Lett. 90, 181107 (2007).

−6−

4)

C. Strelow, C. M. Schultz, H. Rehberg, H. Welsch, C. Heyn, D. Heitmann, and T. Kipp, Phys. Rev. B 76,
045303 (2007).
5) V. A. B. Qui~nones, L. Ma, S. Li, M. Jorgensen, S. Kiravittaya, and O. G. Schmidt, Appl. Phys. Lett. 101,
151107 (2012).
6) C. Strelow, C. M. Schultz, H. Rehberg, M. Sauer, H. Welsch, A. Stemmann, C. Heyn, D. Heitmann, andT. Kipp, Phys. Rev. B 85, 155329 (2012).
7) F. Li and Z. Mi, Optics express 17, 19933 (2009).
8) C. Strelow, M. Sauer, S. Fehringer, T. Korn, C. Schüller, A. Stemmann, and T. Kipp, Appl. Phys. Lett. 95,
221115 (2009).
9) H. Junseok, S. Bhowmick, and P. Bhattacharya, IEEE J. Quantum Electron. 48, 927 (2012).
10) R. Y. Chiao and A. M. Steinberg, Progress in Opt. 37, 345 (1997).

−7−

Response of Larval and Postlarval Greasyback Prawns to Hypoxia
Susumu YAMOCHI* , Ken IKEDA** and Kazuma MUTSUTANI***（Received September 30, 2014）
SynopsisLaboratory experiments were carried out using an oxygen and salinity gradient column to clarify the
response to hypoxia of larval and postlarval greasyback prawns. The survival rate of the greasyback prawns
increased in postlarval stage compared to mysis stage. They escaped from hypoxia at dissolved oxygen
concentrations less than 2.1-2.6 mgO2 l-1 for mysis larvae (10 days after hatching), less than 2.1-2.7 mgO2
l-1 for P4 postlarvae (14 days after hatching) and less than 1.2-1.7 mgO2 l- 1 for P15 postlarvae (25 days after
hatching). These results suggested that greasyback prawns strengthen their levels of tolerance to hypoxia incorrespondence to the advancement of life stage from early postlarvae (P5) to late postlarvae (P15).
KEYWORDS: Hypoxia, Avoidance, Survival rate, Greasyback prawn, Larvae, Postlarvae, Oxygen-salinity
gradient column

1. Introduction
Osaka Bay is well known as a rich sea where a total amount of 225 species of fisheries organisms,
together with 15000- 28000 tons of annual fishing catch, have been recorded in recent years. A gradualrestoration of dissolved oxygen (DO) has been observed in the bottom layer of the central and southern partof Osaka Bay, due mainly to a regulation of sewage discharge. However, concentrations of dissolved oxygen
are still low, and below 3.6 mgO2 l-1 at harbor areas of inner Osaka Bay in summer, which is thought to be a
crucial level of dissolved oxygen required for the healthy growth of the marine benthic animals (Yanagi,
1989; Pihl et al., 1991; Kodama et al., 2006).
A committee of the Ministry of the Environment, Japan showed the importance of dissolved oxygen in
the bottom water as an indicator of water quality, and examined its target values to maintain sound marine
benthic biological resources. Yamochi et.al (1998) examined the tolerance to hypoxia of several benthic fish
and crustaceans of Osaka Bay and demonstrated that dissolved oxygen should not drop below 1.6 mlO2 l-1(2.3 mgO2 l-1) for longer than 1 day, and be kept higher than 2.6 mlO2 l-1 (3.7 mgO2 l-1) on average in summer
to maintain sound populations of demersal fishes and crustaceans of the bay.
Greasyback prawn, Metapenaeus ensis is a major fishery species of Osaka Bay and known as a benthic
crustacean highly enduring of hypoxic conditions (Yamochi et.al, 1995). Oda et al. (1997) analyzed therelationship between hypoxia and population dynamics of the juvenile greasyback prawn in Osaka Bay using
a numerical model where they assumed all juveniles of the prawns escaped from hypoxia at a concentrationof 2.1mgO2 l-1. However, there is so far little information on the minimum dissolved oxygen required for thesound habitats for the whole life history of the greasyback prawns, including their larval stage. Therefore, weneed more information on the physiological and/or ecological responses to hypoxia of the larval greasyback
prawns, since the larval stage is expected to be less tolerant to severe oxygen conditions compared to adultsof the same species.
The present paper attempts to clarify the change of tolerance or avoidance to hypoxia in correspondence
to the growth of larval and postlarval greasyback prawns. For this purpose laboratory experiments were done
to examine the survival or avoidance of hypoxia of the mysis and postlarval stage of the greasyback prawns
using an oxygen and salinity gradient glass column.

*
**
***

Professor, Department of Environmental Urban Engineering
Technical expert, Water Department of Osaka City Government
Senior Researcher, Research Institute of Environment, Agriculture and Fisheries, Osaka
Prefecture−9−2. Methods
2.1 . Preparation of oxygen and salinity gradient column
Two liters of filtered seawaters (ca.30 in salinity) were concentrated or diluted to 40 and 20 salinity
respectively, and added into two glass flasks. Seawater with high salinity was ventilated by N2 gas to reducethe concentration of dissolved oxygen (Flask A in Figure1), while those with low salinity were aerated toadjust its concentration (Flask B in Figure1). The two flasks were connected to each other with Tygon tubing
and the seawater in each flask gently stirred, then poured into a glass column of 86cm in height and 5cm indiameter using a roller pump (Furue Science Co., model RP-NB) at a flow rate of 120 ml min-1 (Tanaka,1991). Prior to the addition of seawater to the glass column, the concentration of dissolved oxygen waschecked with an Oxygurd DO meter (Type Handy Polaris). We referred to a glass column with salinity
gradient but with no oxygen gradient as the control column where no ventilation of N2 gas was made, andonly salinity gradient was formed in the column.
2.2. Test organism
Mysis and postlarvae of the greasyback prawns, which were hatched and grown at the Mie Prefectural
Sea Farming Center, were transferred to the laboratory and employed for the experiment (Figure 2). Alllarval and postlarval greasyback prawns were exposed to the seawater for ca.3 hours with gentle aeration
before the experiment. Averaged body length was ca.2 mm for mysis (10 days after hatching), ca.3 mm forP4-stage postlavae (14 days after hatching) and ca.13 mm for P15-stage postlavae (25 days after hatching).
2.3. Observation
Pre-observation was carried out to confirm whether the oxygen and salinity gradient was maintained for
24 hours in a condition without the larvae of greasyback prawns. Dissolved oxygen was monitored atintervals of 3 hours for 24 hours at every 10cm depth of the oxygen and salinity gradient column with an
Oxygurd DO meter. Density was checked at a water temperature of 25 °C using 4 standard density floats of
1.0150, 1.0175, 1.0200 and 1.0225 g cm-3 (Shibayama Scientific Co. LTD.), and was converted into salinity
according to the Manual on Oceanographic Observation (Japan Meteorological Agency, 1999). As shown in
Table 1, the oxygen gradient was kept for 24 hours when no larvae or postlarvae of greasyback prawn wereadded to the column except for lower layers at 6 hours. No clear difference was found in the position of eachdensity float in the column before and after the experiment, which meant that salinity gradient was almost
constant and didn’t change for 24 hours. All of the seawaters used for the experiment were sterilized by
autoclaving at 121°C for 5 min prior to the experiment.

Fig.1:

Schematic diagram of the experimental apparatus.
A: condensed seawater, B: diluted seawater, C: roller pump, D: stirrer, E: flow
meter, F: air pump, G: oxygen and salinity gradient glass column, H:N2 gas,
I: stopper valve−10−Fig. 2：Mysis and postlarva of the greasyback prawn
A: Mysis (10 days after hatching), B:P4 stage postlarva (14 days
after hatching), C:P15 stage postlarva (25 days after hatching)
Table 1： Changes of dissolved oxygen concentration in the oxygen and salinity gradient column.
Depth
(cm)
0
10
20
30
40
50
60
70
Bottom

0
6.3
6.5
5.4
4.7
4.3
3.9
3.5
3.1
2.9

3
6.5
6.7
5.4
4.8
4.1
3.8
3.4
3.2
3.0

6
6.5
6.0
5.3
4.5
4.0
3.4
2.8
1.9
1.7

9
6.5
6.7
5.4
4.8
4.1
3.8
3.4
3.2
3.0

Time (h)
12
6.5
6.7
5.4
4.8
4.1
3.8
3.4
3.2
3.0

15
6.5
6.7
5.4
4.8
4.1
3.8
3.4
3.2
3.0

18
6.5
6.7
5.4
4.8
4.1
3.8
3.4
3.2
3.0

21
6.5
6.7
5.4
4.8
4.1
3.8
3.4
3.2
3.0

24
6.5
6.7
5.4
4.8
4.1
3.8
3.4
3.2
3.0

-1

* Value is shown in mgO2 l .

Fifteen individuals of mysis, P4 and P15-stage larvae of greasyback prawn were added to the surface
layer of the seawater (0-10 cm depth from the surface) on 0.5 hour before the onset of observation. Eachglass column was kept at 25±1 °C with a photoperiod of 12 hours light and 12 hours dark at a photon densityof 90-100 μmol m-2 sec. We observed the number of individuals of the larval or postlarval greasyback prawn
at every 1cm depth from the surface to the bottom of the column at 3 hours intervals and compared withthose of the control one. An overall percentage of distribution of the larval or postlarval greasyback prawns
was calculated by averaging the percentage of distribution of each observation time at layers of 0-30 cm,
30-60 cm and 60 cm-bottom, respectively. Vertical distributions of dissolved oxygen were checked at 8 hours
intervals to confirm the oxygen gradient to be maintained.
3. Results
3.1. Survival rate
Survival rates of the larval and postlarval greasyback prawns in the oxygen and salinity gradient column
were shown in Table 2. We regarded larval and postlarval greasyback prawns as dead in the following case:(1) They lost their mobility and showed no response when touched with a needle in the fresh seawaters.
(2) Their body color has changed from yellowish brown to pink.

−11−In addition, data from 0 to 15 hours were used since dissolved oxygen concentrations remarkably decreased
owing to the effects of decomposition of dead prawns at the bottom of the column after 16 hours. Survival
rate of the mysis-stage larvae decreased to 60.0% when dissolved oxygen concentrations dropped to 0.9-1.6
mgO2 l-1at the bottom of the column (case 4), while the rate was kept at a range of 86.7 to 100% at 1.8-2.0
mgO2 l-1 (case 3), 2.3-2.6 mgO2 l-1 (case 2), 2.8-3.3 mgO2 l-1 (case 1) and 5.8-5.9 mgO2 l-1 (control). The
P4-stage postlarvae showed a high survival rate of 93.3% under dissolved oxygen concentrations of 2.0-2.3
mgO2 l-1 (case 3), 2.1-2.7 mgO2 l-1 (case 2), 2.7.2-3.1 mgO2 l-1 (case 1) and 5.3-5.7 mgO2 l-1 (control) but thesurvival rate remarkably decreased (53.3%) at 1.6-1.7 mgO2 l-1 (case 4). In contrast, the P15-stage postlarvae
endured hypoxic seawaters for 15 hours and showed high survival rates of 86.7-100% even when theyencountered dissolved oxygen concentrations of 0.2-1.7 mgO2 l-1 (case 4), 0.7-2.3 mgO2 l-1 (case 3), 0.3-2.7
mgO2 l-1 (case 2), 1.1-3.1 mgO2 l-1 (case 1) and 1.5-5.7 mgO2 l-1 (control) at the bottom of the column. No
clear difference was observed in the tolerance of hypoxia between the mysis and P4 postlarval stage of thegreasyback prawns.
Table 2: Survival rate of the larval and postlarval greasyback prawns.
Oxygen - salinity gradient column
Case1 Case2 Case3 Case4
Mysis larvae
86.7
100
86.7
86.7
60.0
P4-stage postlarvae
93.3
93.3
93.3
93.3
53.3
P15-stage postlarvae
93.3
100
100
93.3
86.7
* Value is survival rate of 0-15 hours and shown in percentage.
**Initial dissolved oxygen concentaration at the bottom of the column,
Stage

Control

-1

-1

-1

Case1:3.1-3.3 mgO2 l , Case2:2.6-2.7 mgO2 l , Case3:2.0-2.3 mgO2 l ,-1-1

Case4:1.6-1.7 mgO2 l , Control:5.7-5.9 mgO2 l

3.2. Avoidance
1) Mysis
Distributions of the mysis-stage larvae of the greasyback prawns in the oxygen and salinity gradientcolumn were shown in Table 3. Avoidance of the larvae to hypoxia was analyzed based on the results of 0-15
hours of the time course, since dissolved oxygen decreased at the upper or middle layer of the column
between 16 and 24 hours. When dissolved oxygen at the bottom of the column at 0-16 hours was 2.8-3.3
mgO2 l-1(case 1), a 71% of the live larvae distributed at a layer of 0-60 cm from the water surface. In
cases 2 and 3 (dissolved oxygen at the bottom of the column at 0-16 hours was 2.3-2.6 mgO2 l-1 for case 2
and 1.8-2.0 mgO2 l-1 for case 3), a total of 84.6% and 94.0% of the mysis-stage larvae were observed at the
0-60 cm layer. A marked decline of individuals of the surviving larvae was found from 15 to 18 hours in case4, resulting in only a few larvae remained at the end of the experiment. At 0-15 hours of the case 4(dissolved oxygen at the bottom: 0.9-1.6 mgO2 l-1), the percentage of distribution of the live mysis
larvae attained 91.2% at the 0-60 cm layer.
2) P4-stage postlarva
Distributions of the P4-stage postlarvae of the greasyback prawns in the oxygen and salinity gradient column
were depicted in Table 4. As dissolved oxygen decreased in the column after 16 hours as with themysis-stage experiment, avoidance of the P4 postlarvae to hypoxia was analyzed based on the results of 0-15
hours. In the control column, the percentages of distribution of the postlarvae were ca. 60% at the bottom of
the column, while those in the oxygen and salinity gradient column were low and showed 46.6% at dissolved
oxygen concentrations of 2.7-3.1 mgO2 l-1 in case 1, 37.5% at 2.4-2.7 mgO2 l-1 in case 2, 25.6% at 2.0-2.3
mgO2 l-1 in case 3 and 18.8% at 1.6-1.7 mgO2 l-1 in case 4. As a result, the percentage of distribution of theP4-stage postlarvae at the bottom of the column clearly decreased with decreasing dissolved oxygen. In
contrast, they were well observed at a layer of 30-60 cm from the surface in each oxygen and salinity
gradient column where dissolved oxygen concentration ranged between 3.2-5.2 mgO2 l-1 (case 1), 3.6-4.7
mgO2 l-1 (case 2), 3.6-4.4 mgO2 l-1 (case 3),and 2.8-4.7 mgO2 l-1 (case 4).
3) P15-stage postlarva
Table 5 showed distributions of the P15-stage postlarvae of the greasyback prawns in the oxygen and−12−Table 3：Distributions of the mysis-stage larvae of the greasyback prawns.
Depth
(cm)
surface -10
10-20
20-30
30-40
Control
40-50
50-60
60-70
70-bottom
bottomsurface -10
10-20
20-30
30-40
Case1
40-50
50-60
60-70
70-bottom
bottomsurface -10
10-20
20-30
30-40
Case2
40-50
50-60
60-70
70-bottom
bottomsurface -10
10-20
20-30
30-40
Case3
40-50
50-60
60-70
70-bottom
bottomsurface -10
10-20
20-30
30-40
Case4
40-50
50-60
60-70
70-bottom
bottom-1

DO concentration (mg l )
start
8h
16h
24h
6.6
6.6
6.6
5.5
6.1
5.0
6.4
5.8
4.4
6.1
4.3
6.1
5.9
5.9
5.6
6.0
5.6
6.0
5.9
5.9
6.0
5.7
5.9
5.5
5.8
4.7
6.6
6.6
6.3
5.1
6.2
5.1
3.5
5.7
5.4
4.9
3.6
5.1
4.7
3.9
4.8
4.3
4.5
3.7
4.3
3.9
3.9
3.8
3.8
3.6
3.8
3.4
3.3
3.7
3.3
3.0
2.8
3.2
6.5
6.4
5.8
4.7
5.8
3.1
5.0
5.0
4.4
3.3
4.7
3.4
4.2
3.9
4.1
3.3
3.9
3.4
3.3
3.3
3.3
3.3
2.9
3.0
2.6
2.5
2.3
2.5
6.7
6.3
6.3
4.5
5.6
4.1
4.8
4.7
4.1
2.7
4.1
2.5
3.5
3.7
3.5
2.5
3.0
2.5
2.6
2.6
2.6
2.4
2.1
2.4
2.0
1.8
1.8
1.4
6.4
6.3
5.9
4.6
5.7
4.9
3.4
4.8
4.5
4.5
2.9
4.2
4.2
2.6
3.5
3.2
3.6
2.4
2.8
2.8
2.4
2.2
2.3
2.0
2.0
1.9
1.5
1.4
1.6

1.3

0.9

0.7

Salinity
start
21.7
23.5
25.3
27.1
28.9
30.7
32.5
34.2
36.0
21.6
23.6
25.4
27.3
29.1
31.0
32.9
34.7
36.6
22.6
24.3
26.1
27.8
29.5
31.2
32.9
34.6
36.3
22.4
24.3
26.2
28.2
30.1
32.1
34.0
35.8
37.7
23.0
24.7
26.4
28.1
29.8
31.5
33.1
34.8
36.5

: showed dark period

−13−

start
2
0
2
3
2
1
3
0
2
1
1
1
1
4
3
2
1
1
1
4
2
2
3
1
0
0
2
2
4
3
4
2
0
0
0
0
0
2
5
1
4
0
0
0
2

3h
0
1
2
2
3
0
0
4
2
0
1
2
2
3
2
2
1
2
3
2
3
3
2
1
0
0
1
3
3
2
2
3
2
0
0
0
2
2
2
5
0
1
0
0
2

6h
2
1
1
7
1
0
0
0
1
1
1
0
2
1
4
3
0
3
4
1
1
3
0
2
2
0
1
1
0
3
2
2
1
1
2
2
1
0
5
3
1
1
0
0
0

Number of individuals
9h
12h
15h
1
0
1
0
1
0
4
3
2
4
0
2
3
3
3
0
4
4
1
2
1
0
0
0
0
0
0
0
1
1
3
1
2
2
2
3
3
2
1
1
1
0
5
3
3
1
2
4
0
2
1
0
1
0
1
0
0
0
1
1
1
1
3
2
3
2
5
2
0
3
5
4
2
1
1
0
0
0
1
0
2
2
1
1
2
1
1
2
1
2
3
7
0
4
3
6
0
0
3
0
0
0
0
0
0
0
0
0
1
1
0
0
0
1
2
2
2
2
2
3
4
3
2
0
0
1
0
0
0
1
1
0
0
0
0

18h
4
1
2
3
1
0
0
1
0
1
1
2
7
2
0
1
0
0
7
0
3
2
1
0
0
0
0
7
1
2
2
0
1
0
0
0
1
0
1
0
1
0
0
0
0

21h
3
0
2
3
2
1
0
1
0
4
1
4
4
1
0
0
0
0
5
2
0
3
1
0
1
0
0
5
1
4
2
1
0
0
0
0
1
0
1
0
0
1
0
0
0

24
2
2
2
1
2
0
0
1
0
3
4
4
1
1
0
0
0
0
3
2
1
1
0
0
0
0
1
4
2
2
2
1
0
0
0
0
1
1
0
0
0
0
0
0
0

Table 4：Distributions of the P4-stage postlarvae of the greasyback prawns.
Depth
(cm)
surface -10
10-20
20-30
30-40
Control
40-50
50-60
60-70
70-bottom
bottomsurface -10
10-20
20-30
30-40
Case1
40-50
50-60
60-70
70-bottom
bottomsurface -10
10-20
20-30
30-40
Case2
40-50
50-60
60-70
70-bottom
bottomsurface -10
10-20
20-30
30-40
Case3
40-50
50-60
60-70
70-bottom
bottomsurface -10
10-20
20-30
30-40
Case4
40-50
50-60
60-70
70-bottom
bottom-1

DO concentration (mg l )
start
8h
16h
24h
6.6
6.3 5.9
6.5
6.2

5.1

23.8

5.1

25.5

5.5

27.3

5.7

5.5

29.0

5.3

30.7

5.6

5.4

32.4

5.2

34.1

5.3

4.0

6.0
5.8
5.8
5.7
6.6

6.2

6.1
5.6

5.4

5.2
4.5

4.5

4.2
3.6

3.6

3.1

22.1

5.7

6.4
6.1

Salinity
start

5.7

4.8

35.8
21.2

4.8

3.6

23.2

4.1

3.0

25.3

3.6

3.0

27.3

3.6

2.3

29.3

3.2

2.4

31.3

3.5

2.1

33.3

2.8

2.2

35.3

3.1

3.1

2.7

1.2

37.4

6.3

5.9

6.3

5.4

21.9

4.5

23.7

3.6

25.6

3.2

27.4

2.7

29.2

2.6

31.1

2.4

32.9

2.1

34.7

5.5
5.1

4.4

4.8

4.7
4.0

3.7

4.2

3.6
3.2

3.1

3.2

3.0
2.7

2.1

2.4

1.9

36.5

6.4
5.6
5.3
4.4
4.0
3.6
2.9
2.5
2.3
6.1
5.5
5.2
4.7
4.0
3.3
2.5
2.0
1.7

6.4

5.7

21.9

5.2

4.4

3.8

3.8

2.9

2.6

2.4

2.0

6.2

5.6

5.5
4.2
3.8
3.4
2.7
2.4
2.5
1.9
1.5
5.5
3.9
3.6
3.3
2.7
2.3
1.6
1.4
0.8

4.9
4.9

4.3
3.8

4.2

3.4
2.8

2.4

2.0

1.7

1.8
1.6

23.7
25.5
27.3
29.0
30.8
32.6
34.4
36.1
21.6
23.5
25.4
27.2
29.1
30.9
32.8
34.6
36.5

start
0
0
0
0
0
0
0
1
14
0
1
1
0
0
0
1
0
12
0
1
0
0
2
0
2
0
10
0
0
1
1
1
2
1
1
8
1
1
1
1
2
1
1
0
7

: showed dark period

−14−

3h
0
0
0
0
2
0
0
0
13
0
1
2
1
1
0
0
0
10
1
0
1
1
3
1
1
1
6
0
1
3
1
1
2
1
1
5
1
0
2
2
2
1
1
1
2

6h
0
0
0
1
1
4
2
1
6
0
0
1
3
0
1
3
3
4
0
1
4
4
1
1
0
0
4
1
3
0
2
2
1
2
1
2
1
0
3
3
2
1
0
0
2

Number of individuals
9h
12h
15h
0
0
0
0
0
1
0
0
1
0
2
0
3
4
1
4
0
1
2
2
1
1
1
0
5
6
9
0
0
0
0
0
0
5
1
0
6
0
4
0
1
1
0
2
1
1
2
1
0
3
0
3
5
7
0
0
0
2
1
1
3
0
3
2
3
0
1
2
1
1
1
3
1
1
2
0
1
1
5
5
3
0
0
0
0
2
0
0
2
3
2
2
3
3
1
6
2
1
0
1
1
1
2
2
1
4
3
0
0
0
0
1
0
1
1
2
1
2
4
1
5
2
3
1
1
1
0
1
1
0
0
0
2
0
0

18h
0
0
0
0
2
2
3
2
4
0
0
5
1
1
1
1
2
1
0
0
4
2
1
1
0
0
2
1
0
0
3
0
0
2
1
5
2
0
1
2
0
2
0
0
0

21h
0
0
0
0
0
0
0
1
12
0
2
2
3
1
1
0
1
1
0
0
0
2
1
2
0
2
2
1
1
2
0
2
2
0
1
3
0
0
2
0
2
0
0
0
0

24h
0
0
0
0
0
0
1
1
9
0
0
2
2
1
0
0
1
0
0
1
1
0
2
2
0
0
1
0
0
1
0
2
3
1
2
1
0
0
2
1
1
0
0
0
0

Table 5：Distributions of the P15-stage postlarvae of the greasyback prawns.
Depth
(cm)
surface -10
10-20
20-30
30-40
Control
40-50
50-60
60-70
70-bottom
bottomsurface -10
10-20
20-30
30-40
Case1
40-50
50-60
60-70
70-bottom
bottomsurface -10
10-20
20-30
30-40
Case2
40-50
50-60
60-70
70-bottom
bottomsurface -10
10-20
20-30
30-40
Case3
40-50
50-60
60-70
70-bottom
bottomsurface -10
10-20
20-30
30-40
Case4
40-50
50-60
60-70
70-bottom
bottom-1

DO concentration (mg l )
start
8h
16h
24h
6.6
6.2
5.7
5.1
6.5
6.1
5.0
4.4
6.2
5.8
4.8
3.8
6.4
5.7
5.1
3.7
6.1
5.8
5.2
3.7
6.0
5.8
5.4
4.4
5.8
5.8
5.5
1.6
5.8
5.8
2.1
1.3
5.7
5.6
1.5
1.1
6.6
5.5
4.6
4.2
6.1
5.1
4.3
2.6
5.6
4.9
3.8
2.1
5.2
4.7
3.5
1.5
4.5
4.0
3.3
1.1
4.2
3.5
3.1
0.9
3.6
2.9
2.1
0.7
3.1
2.2
1.3
0.4
3.1
1.2
1.1
0.3
6.3
5.3
5.2
4.8
5.5
5.1
5.0
4.5
5.1
4.9
4.4
4.3
4.7
4.6
4.1
3.5
4.0
4.5
3.3
2.8
3.6
3.5
2.3
2.4
3.2
3.2
1.7
0.5
3.0
1.8
1.2
0.5
2.7
1.3
0.3
0.1
6.4
5.2
5.2
5.4
5.6
5.0
4.7
4.8
5.3
4.8
4.1
3.6
4.4
4.4
3.7
2.6
4.0
4.3
3.2
1.8
3.6
3.7
2.6
1.3
2.9
2.8
1.6
1.1
2.5
1.9
1.2
0.7
2.3
1.3
0.7
0.1
6.1
5.3
5.2
5.2
5.5
5.1
4.7
4.3
5.2
4.9
3.9
1.8
4.7
4.5
3.0
1.4
4.0
3.6
2.2
1.1
3.3
3.1
1.5
0.6
2.5
2.1
1.2
0.2
2.0
1.8
0.7
0.1
1.7
1.2
0.2
0.1

Salinity
start
22.1
23.8
25.5
27.3
29.0
30.7
32.4
34.1
35.8
21.2
23.2
25.3
27.3
29.3
31.3
33.3
35.3
37.4
21.9
23.7
25.6
27.4
29.2
31.1
32.9
34.7
36.5
21.9
23.7
25.5
27.3
29.0
30.8
32.6
34.4
36.1
21.6
23.5
25.4
27.2
29.1
30.9
32.8
34.6
36.5

start
0
2
0
0
0
0
0
0
13
0
0
0
2
1
0
2
2
8
1
0
0
0
0
0
0
2
12
0
0
0
0
0
1
0
1
13
2
2
0
1
2
1
0
2
5

3h
1
2
2
1
2
0
0
0
7
1
1
1
1
2
0
1
1
7
4
1
1
0
0
1
4
0
4
3
3
1
0
0
0
0
0
8
2
0
5
1
1
0
0
1
4

6h
0
0
0
2
2
0
3
0
8
0
1
1
0
0
2
0
0
11
1
0
1
1
1
3
2
3
3
1
1
1
1
0
0
3
1
7
0
0
0
0
1
7
0
4
2

Number of individuals
9h
12h
15h
3
0
0
2
0
0
0
2
1
0
2
0
1
0
0
0
0
0
0
1
1
0
2
1
8
7
11
1
0
0
0
0
0
0
1
1
1
2
4
1
3
2
1
2
0
2
3
0
3
1
2
6
3
6
2
0
0
1
0
1
1
1
0
0
0
2
2
3
0
3
1
2
1
0
0
2
0
0
3
10
0
0
0
0
0
0
1
1
0
5
1
3
0
0
1
1
2
2
2
1
3
3
0
0
1
10
5
1
0
0
0
0
0
0
1
0
0
1
1
0
1
3
4
7
5
5
2
2
0
1
0
2
1
2
2

18h
0
0
0
1
0
0
1
2
10
0
0
1
4
1
3
4
2
0
0
0
2
0
0
0
3
0
0
0
0
0
2
1
6
3
1
0
0
0
2
3
2
3
0
0
3

21h
0
0
1
1
0
1
3
2
6
0
0
2
5
5
3
0
0
0
0
1
0
1
1
2
0
0
0
1
1
2
0
2
2
0
1
4
0
0
7
0
2
2
0
1
0

24h
0
0
0
1
1
4
7
1
0
1
3
3
6
2
0
0
0
0
1
1
3
0
0
0
0
0
0
1
1
4
3
4
0
0
0
0
2
0
6
4
0
0
0
0
0

: showed dark period

salinity gradient column. As dissolved oxygen concentrations largely decreased by 16 hours in all oxygenand salinity gradient columns together with the control one, we used data of 0 to 8 hours for analyzing
the avoidance to hypoxia of the P15-stage postlarvae. The percentage of distribution at the bottom of thecolumn showed 57.8% in case 1 (1.2-3.1 mgO2 l-1), 42.2% in case 2 (1.3-2.7 mgO2 l-1) and 62.2% in case 3(1.3-2.3 mgO2 l-1), which had no remarkable difference with the value of 62.2% of the control column(5.6-5.7 mgO2 l-1). However, only 2-5 individuals of the P15 postlarvae were observed at the bottom when
dissolved oxygen decreased between 1.2 and 1.7 mgO2 l-1 in case 4. Although dissolved oxygen strikingly
declined after 8 hours, P15-stage postlarvae survived in the latter half of the experiment except for case 2
where 10 individuals became inactive at 12 hours and died thereafter.

−15−

Table 6：Criteria of avoidance to hypoxia for the mysis or postlarvae of the greasyback prawns.

Stage
Mysis-stage larvae
P4-stage postlarvae
P15-stage postlarvae-1

DO concentration (mgO2l )2.1-2.6
2.1-2.7
1.2-1.7

4. Discussion
Miller et al. (2002) examined the hypoxic tolerance of 13 species of marine and estuarine fishes,
crustaceans and a bivalve and reported that mortality attained 14-22% for crustaceans even in the control test
due to their metamorphosis and molting. They also suggested that the responses to hypoxia can be comparedto each other if the mortality in the control is below these percentages. In the present experiment mysis-stage
greasyback prawns showed a mortality of 13.3% in the control column which is lower than a range describedby Miller et al. (2002). Yamochi et al. (1995) carried out indoor experiments and field surveys on the
hypoxic tolerance of the juvenile greasyback prawn, indicating that they can survive for 24 hours at
dissolved oxygen saturations of 20-27% (1.4-1.9 mgO2 l-1) with LC-50 being less than 7-12% (0.50-0.87
mgO2 l-1) at 25 °C. And the juvenile greasyback prawn can survive at low concentrations of dissolved
oxygen compared with juvenile kuruma prawn Marsupenaeus japonicus, young swimming crab Portunus
trituberculatus, and young common brackish goby Acanthogobius flavimanus. The juvenile greasyback
prawn’s habitat was at the bottom of the mouth of the Yodo river, Osaka, where oxygen saturation decreased
to 12-55% in summer. These findings lead to a conclusion that the greasyback prawns can dominate inhypoxic habitats depending on their excellent ability of tolerance to hypoxic conditions. In the present study,
P15 postlarvae of the greasyback prawns, whose body length were ca.15 mm survived at a rate of 86.7% for
15 hours and 80.0% for 24 hours at highly hypoxic conditions of 0.1-3.1 mgO2 l-1 (Tables 2 and 4). This
well coincided with occurrence of the juvenile greasyback prawns with 25-40 mm body length in the
hypoxic estuary of the Yodo river. Although the mortality sharply increased at 0.7-1.6 mgO2 l-1 for mysis andat 0.8-1.7 mgO2 l-1 for P4 postlarvae, no clear increase in mortality was observed at 0.1-1.7 mgO2 l-1 for P15
postlarvae. This suggests that the greasyback prawns may acquire hypoxic tolerance between P4 and P15
postlarval stage, and they then succeed in occupying their habitats in hypoxic coastal areas or river mouths
owing to their prominent tolerance to low oxygen.
Statistical analysis (χ2 test) was used to determine the concentration of dissolved oxygen where thelarvae or postlarvae started avoiding. In this case, we employed the experimental data of 0-15 hours which
had no large decline of the concentrations of dissolved oxygen. A statistical difference was detected in thevertical distribution of the mysis-stage larvae between case 3 (dissolved oxygen concentration at thebottom:1.8-2.0 mgO2 l-1) and control. In addition, there was a statistical difference of the distribution between
case 3 and control even when data of the 70cm-bottom layer were excluded (P < 0.10). Therefore, the upper
limit of avoidance against hypoxia in the mysis-stage larvae was estimated to be 2.1-2.6 mgO2 l-1. Vertical
distributions of the P4-stage postlarvae were different in case 2, case 3 and case 4 if compared to the control(P < 0.05). This suggests that the upper limit of avoidance in P4-stage larvae was between 2.1-2.7 mgO2 l-1(dissolved oxygen concentrations at the bottom of the column in case 2). After growing into P15-stage
larvae, the statistical difference of vertical distribution (P < 0.05) was only confirmed between case 4(dissolved oxygen concentration at the bottom: 1.2-1.7 mgO2 l-1) and control, but not between case 1, case 2,
case 3 and control when compared the number of individuals of the larvae at the bottom. This indicates that
P15-stage larvae of the greasyback prawns start avoidance to hypoxia at 1.2-1.7 mgO2 l-1. As a conclusion,
the larvae of the greasyback prawns avoid hypoxia at dissolved oxygen concentrations below 2.1-2.6 mgO2
l-1 for mysis larvae, below 2.1-2.7 mgO2 l-1 for P4 postlarvae and below 1.2-－1.7 mgO2 l- 1for P15 postlarvae(Table 6). These results reveal that physiological limit of avoidance to hypoxia of the larval greasyback
prawns becomes low in correspondence to the development of life stage, especially from early postlarvae tolate postlarvae. This also corresponds with the findings that survival rate of the greasyback prawns increasedepending on the stage from early postlarvae (P4) to late postlarvae (P15).

−16−

Ohtomi et al.(2006) reported that the rate of settlement of the larval mantis shrimp Oratosquillaoratoria decreased depending on the hypoxic conditions in Tokyo Bay. Further, Kusakabe et al.(2002)
demonstrated that hypoxic bottom water could affect the distribution of juvenile southern rough shrimp
Trachysalambria curvirostris in August in Osaka Bay. These results lead to a conclusion that the juvenile
greasyback prawns can dominate in hypoxic habitats of inner Osaka Bay owing to their excellent ability oftolerance to hypoxic conditions, but spatial distribution of the greasyback prawns changed and their growth
was inhibited by hypoxia when they were in mysis or early postlarval stage.
Acknowledgements
The authors express their sincere thanks to Mr. H.Yamane of the Mie Prefectural Sea Farming Center,
Japan for his kind support in obtaining the larval greasyback prawns for the present experiment. This
research was conducted based on the financial support of the Ministry of the Environment, Japan and Japan
Society for the Promotion of Science.
References
Kodama, K., Horiguchi, T., Kume, G., Nagayama, S., Shimizu, T., Shiraishi, H., Morita, M. and Shimizu, M.
(2006), “Effects of hypoxia on early life history of the stomatopod Oratosquilla oratoria in a coastalsea”, Marine Ecology Progress Series, 324, 197-206.
Kusakabe, T., Nabeshima, Y. and Ishiwatari, T. (2002), “Settlement of juvenile southern rough shrimp,
Trachysalambyia curvirostris in Osaka Bayˮ, Aquaculture Science, 50(1), 31-36 (in Japanese).
Miller, D.C., Poucher, S.L. and Coiro, L. (2002), “Determination of lethal dissolved oxygen levels forselected marine and estuarine fishes, crustaceans, and a bivalve ˮ, Marine Biology, 140, 287-296.
Oda, K., Ishikawa, K., Kido, K., Nakamura, Y., Yamochi, S. and Taguchi, K. (1997), “Population dynamics
model of Metapenaeus ensis larvae stage in Osaka Bay ˮ , Proceedings of Coastal Engineering, JSCE,
44(2), 1196-1200 (in Japanese).
Ohtomi, J., Furota, T. and Kawazoe, H. (2006), “Change in spatial distribution with development for larval
Japanese mantis shrimp Oratosquilla oratoria (Stomatopoda, Squillidae) in Tokyo Bay, Japanˮ,Nippon Suisan Gakkaishi, 72(3), 382-389 (in Japanese).
Pihl, L., Baden, S.P. and Diaz, R.J. (1991), “Effects of periodic hypoxia on distribution of demersal fish andcrustaceansˮ, Marine Biology, 108, 349-360.
Tanaka, Y. (1990), “Changes in the egg and larval densities of striped beakperch (Pisces; Oplegnathidae)
during development ˮ, Memoirs of the Faculty of Agriculture of Kinki University，23, 19-24.
The Oceanographic Society of Japan (1981), “Manuals for oceanographic observation ˮ, Japan
Meteorological Agency (Ed), 429 p. (in Japanese).
Yamochi, S., Ariyama, H. and Sano, M. (1995), “Occurrence and hypoxic tolerance of thejuvenile Metapenaeus ensis at the mouth of the Yodo river, Osaka ˮ, Fisheries Science, 61(3),391-395.
Yamochi, S., Ariyama, H. and Sano, M. (1998), “Environmental restoration of coastal habitats in the innerpart of Osaka Bay – Quality of seawater, bottom sediment and benthic fauna in the vicinity of aplanned tidal flat at the port of Sakai-Senboku, and response of marbled sole, Pleronectes
yokohamae to hypoxia-ˮ, Umi no kenkyu (Oceanography in Japan ), 7(5), 293-303 (in Japanese).
Yanagi,T.(1989) ,“A summary of symposium o oxygen-deficient water massˮ, Bulletin on Coastal
Oceanography, 26(2), 141-145 (in Japanese).

−17−An Analysis on Influence Factors to Use Frequency and WTP of Shopping Support Services
for People in Food Desert
Noboru ISE* and Yasuo HINO**(Received October 3, 2014)

Synopsis
Recently, the food desert problem has been becoming serious problem in mainly rural areas of Japan,
because it must be improved by local responsibility according to local needs. Although some estimation
methods of the number of people in food desert (PFD) were developed, the estimations of the demand forand profit from shopping support service will be also required. Therefore, this paper mainly aims to gain thefundamental knowledge not only to develop the estimation model of the demand for shopping support
service for PFD but also to evaluate the profit of them at local level, by the factor analysis including
individual attributes and area characteristics.
As a result, some important findings, concerned with influence factors to use frequency and WTP of
shopping support services, came out of this study. These results must be useful information to introduce thesuitable shopping support services for PFD in consideration of local needs.
KEYWORDS: People in food desert, Shopping support service, Use frequency, WTP, Factor analysis
1. Introduction
Recently, the food desert problem become serious in mainly rural areas of Japan, because of recentsocial changes: 1) declining in level of public transport services, 2) declining birth rate and growing
proportion of elderly people, 3) increasing nuclear families and 4) decreasing the number of local
commercial facilities and so on. Therefore, Ministry of Economy, Trade and Industry (METI) and Ministryof Agriculture, Forestry and Fisheries (MAFF) have been making various efforts to solve the food desert
problem, such as estimation of the number of PFD based on original methods and publishing of the shopping
accessibility aid manual and so on. On the other hand, Ise et al. (2013) and Hirai et al. (2012) pointed outthat the estimation methods developed by METI and MAFF are impossible to estimate the number of PFD at
local level, and they had conducted fundamental studies to develop the new estimation method of the number
of PFD.
It can be said that the following matters are essential to decide the shopping support service for local
needs: 1) the number of PFD, 2) the demand for each shopping support service, 3) the profit fromintroducing each of them and 4) discussion with various kind of parties such as local government, local
residents, private companies and academic experts and so on. However, manuals mentioned above are notenough knowledge to do that, because they do nothing but introduce some of pioneering projects.
Kuramochi et al. (2014) developed the discrete choice model to estimate the number of delivery
service users based on the questionnaire survey for elderly people in rural areas. Tanimoto et al. (2012)
determined five choice patterns of shopping support services by combination of two shopping support
services and relative use frequency of them transformed into ordinal scale, and developed the multinomial
probit model to estimate the number of users of “transport support service” and “delivery service”
considering mental and physical functions of elderly people. However, there are some issues in theseresearches: 1) not considering non-elderly people and 2) they cannot estimate the use frequency of shopping
support services for PFD.
Kishino et al. (2011) clarified the relationship between use frequency of shopping support services andsome valuables such as individual attributes, family structure and physical ability and so on. However, some
findings from this research is not enough to estimate the demand of shopping support services because they
analyzed the relationship between use frequency of shopping support services and some valuables separately.
Therefore, this paper mainly aims to gain the fundamental knowledge to develop the model for* Associate Professor, Department of Civil Engineering, National Institute of Technology, Wakayama College** Professor, Department of Civil Engineering, Osaka City University−19−

estimating the demand for each shopping support service for PFD and the profit from introducing each ofthem at local level, from the analysis of factors influencing use frequency and WTP of shopping support
services for PFD considering individual attributes and area characteristics.
2. Outline of Target Town
Hidakagawa town in Wakayama, Japan is the target town in this study, which was created by themunicipal merger between Kawabe town, Nakatsu village, and Miyama village in May 2005, as shown in
Figure 1. This town is located at the center of Wakayama prefecture, which has an area of 331.65 km2 (35kmfrom east to west in width, 10km from north to south in width). Population size is very small (population is10,509 and the number of household is 3,750). The density of population is also very small, but the ratio ofelderly people is 10.4% higher than the national average (20.1%). In addition to the above, this town facessome problems such as decreasing of population and increasing of nuclear families. A railway is located in
the southwest of this town, but there are only two stations. In addition to a few stations, train runs once every
hour. Bus, community bus and share-ride taxi run
in this town, but they run about two to eight times
a day. All these things make it clear that theconditions of public transport in this town are poor.
Miyama village
A lot of local residents pointed out that the
Nakatsu village
conditions of public transport and daily shopping
are poor, in the first long-term comprehensive
development plan of this town.
Kawabe town
As mentioned above, it is very urgent andimportant to support for grocery shopping ofpeople in food desert in this town.
Figure 1. Hidakagawa town as the study field
3. Outline of Questionnaire Survey
The questionnaire survey was conducted from October to November 2013, in order to clarify the factors
influencing use frequency and WTP of shopping support services for PFD. The main questionnaire items areindividual attributes, conditions of public transport, condition of grocery shopping, difficulty with grocery
shopping, user frequency and potential needs of shopping support services as shown in Table 1. The
respondents are local residents except students and pupils, who were randomly sampled in Hidakagawa town.
As a result, 1749 respondents were obtained from distributed 6000 questionnaire sheets.
Table 1. Main items of questionnaire survey
Items
Individual attributes
Conditions of public transport

Conditions of grocery shopping
Difficulty with grocery shopping
Use frequency of shopping support services
Needs of shopping support services

Details Address,  Sex,  Age,  Household composition,
 Certification of care need,  Pain-free walking time, Availability of car and motorbike Walking time to get to the nearest station
 Walking time to get to the nearest stop of bus (including share-ride taxi)
 Type of the nearest grocery store
 Distance from home to the nearest grocery store Conditions of mobile grocery stores and grocery delivery
 Presence of the person who support grocery shopping Difficulty with grocery shopping Use frequency of shopping support services such as “going out”,“mobile grocery store”, and “grocery delivery”
 Needs of improvement of each support for grocery shopping Intention to use each improved support for grocery shopping Willingness to pay for each improved support for grocery shopping−20−

4. Conditions of Public Transport and Present Situation of PFD
4.1. Conditions of public transport
As for the accessibility to the nearest station, all residents in Nakatsu and Miyama villages and a halfof residents in Kawabe town cannot access to the nearest station within 30 minutes on foot, as shown in
Figure 2, because of the location of each residential area (See Figure 1). On the other hand, almost all ofresidents may be able to access to the nearest bus stop within 15 minutes on foot, as shown in Figure 3.
However, from a different angle, about 10 % more of residents must be not able to access to any public
transport within 15 minutes on foot.
Kawabe(n=961)

26.6%

20.7%

Nakatsu(n=415)100.0%

Miyama(n=364)100.0%
0%20%

Within 15 minutes

52.7%

40%

60%

16 to 30 minutes
More than 31 minutes

80%

100%

Figure 2. Walking time to get to the nearest station
Kawabe(n=884)

77.9%

22.1%

Within 15 minutes
More than 16 minutes

Nakatsu(n=411)

90.8%

9.2%

Miyama(n=354)

89.5%

10.5%

0%

20%

40%

60%

80%

100%

Figure 3. Walking time to get to the nearest bus stop
4.2. Ratio and age distribution of PFD
The Figure 4 shows the ratio and age distribution of PFD. PFD is respondents who answered “Usuallydifficult”, “Sometimes difficult” and “Seldom difficult”, to question “Do you have difficulty with grocery
shopping”. As a result, it can be seen that other factors except conditions of public transport may have an
influence on difficulty with grocery shopping, as the ratio of PFD of Nakatsu village is the highest in
Hidakagawa town. On the other hand, it can be said that residents of under 65 years old should be taken into
consideration, in order to estimate the number of PFD and consider some shopping support services for PFD.
Kawabe(n=947)

9%

Nakatsu(n=401)6%

16%

Miyama(n=346)

12%
0%

10%

Under 65 years old
65 to 74 years old
75 years old and over

9%
9%

9%
20%

14%
14%
30%

40%

50%

Figure 4. Ratio and age distribution of PFD
4.3. Use frequency of shopping support services of PFD
The use frequency of each shopping support service of PFD is summarized in Figure 5. In an analysis
of use frequency of “transport support service”, the frequency of go out shopping by local public transport
such as bus and taxi should be focused. However, the number of users of local public transport is very small.
Therefore, all respondents who go out for shopping are included in this analysis, and this result is used forcomparing with use frequency of other shopping support services. In analyses of use frequency of “mobile
vendor” and “home delivery service”, respondents who answered “do not use” or “no service” are notincluded.
According to “go out shopping” of Figure 5, the ratio of those who go out shopping one to three times−21−

a week is 65 %. It is inferred that people in rural area buy a lot of foods at one time, in order to reduceinconvenience of going out shopping.
Go out shopping(n=488)3%
0%

Mobile vendor（n=487）

10% 38%
20%

27%

40%

6%

Home delivery service（n=485）

8%

60%

80%

11%

3%

100%

more than 6 times a week
4 to 5 times a week
2 to 3 times a week
once a week
once every 2 weeks
once every 3 weeks
once a monthmore than 6 times a week
4 to 5 times a week
2 to 3 times a week
once a week
once every 2 weeks
once every 3 weeks
once a month
once every two month
once every three month

6%

16%

0%

10%

20%

30%

Figure 5. Use frequency of each shopping support services for PFD
4.4. Willingness to pay (WTP) for the use of shopping support services for PFD
Figure 6 shows the WTP for the use of each shopping support service for PFD. WTP in this studymeans one-way fare for transport support service, pay-per-use fee for mobile vendor and pay-per-use fee forhome delivery service.
77% of respondents are willing to pay for transport support service, and most of WTP ranges from 100
JPY to 700 JPY. The ratio of respondents who are willing to pay for mobile vendor and home delivery
service is lower than that for transport support service. It might be because users of mobile vendor and homedelivery service can only do shopping and cannot buy some foods from many.
On the other hand, there are a few respondents who are willing to pay more than 1500 JPY for mobile
vendor and home delivery service. It can be said that mobile vendor and home delivery service are very
important for people with limited access to shopping facilities.
Transport support service（n=415）23%

16%

10% 13%

19%

Mobile vendor（n=418）

39%

20%

14%

Home delivery service（n=429）34%22%

17% 11%

0%

20%

40%

60%

80% 100%

0JPY
150JPY
250JPY
350JPY450JPY
600JPY
800JPY
1000JPY
1500JPY
2500JPY

100JPY
200JPY
300JPY
400JPY
500JPY
700JPY
900JPY
1200JPY
2000JPY

Figure 6. WTP for the use of each shopping support service for PFD
5. Analysis of Factors Influencing Use Frequency of Shopping Support services for PFD
In this chapter, factors influencing use frequency of shopping support services for PFD are clarified byusing quantification theory type I.
As mentioned in section 4.3, the frequency of go out shopping by local public transport such as bus
and taxi should be focused, in order to gain the fundamental knowledge to model demand for transport
support service. However, the number of users of local public transport is very small. Therefore, allrespondents who go out shopping are included in this analysis, and this result is used for comparing with use
frequency of other shopping support services.
As shown in Figure 5, options of use frequency setting in this questionnaire survey have different unit
such as “1(time/week)” and “1(time/2weeks)”. And some of them have a range such as “2~3(times/week)”.
Therefore, unit of use frequency was converted to “times/day”. For example, “4~5(times/week)” is converted
into “4.5/7(times/day)” and “1(time/month)” is converted into “1/28(times/day)”. In addition, “less than
1(time/month)” and “do not use” are converted into 0(times/day). In analyses of mobile vendor and homedelivery service, only respondents who can use these services are included. Independent variables using for−22−

these analyses achieve statistical significance based on one-way analysis of variance. And, all results also do
not have problem of “multi-collinearity”.
5.1. Go out shopping
The result of Figure 7 indicates that, those who go out shopping comparatively frequently havefollowing characteristics: 1) under 65 years old, 2) pain-free walking time is more than 21 minutes and 3)
possible to use a car (driving by oneself and others). Therefore, it can be seen that decline in physicalperformance with age makes people decrease the frequency of go out shopping. And, other factors
influencing the frequency of go out shopping are the distance from home to central area of Hidakagawa town,
the distance from home to the nearest grocery store, presence of the people who support grocery shopping
and assortment of foods.
Categorical values

Independent variables
Age
Individual
attributes

Pain-free walking timeCar

Conditions ofpublic transport

Walking time to get to
the nearest station
Type of the nearest grocery store(private store)

Conditions ofgrocery shopping

Distance from home to
the nearest grocery store
People who support grocery shopping

Under 65
65 to74
75and overWithin 10 min
11 min to 20 min
More than 21 min
HavingNot having
Within 20 min
More than 21 min
YesNo
Within 2km
More than 2km
Presence
Absencemultiple correlation
coefficient
0.29-2.0 -1.00

1.0 2.0[times/day]Figure 7. Analysis on factors influencing frequency of go out shopping
5.2. Mobile vendor
Figure 8 makes it clear that factors influencing use frequency of mobile vendor are different fromthose of go out shopping. In other words, the use frequency of mobile vendor increases with age. In addition,
people living in areas poorly served by local public transport and grocery stores, depend strongly on mobile
vendor. Accordingly, mobile vendor is used frequently as a supplement or alternative to go out shopping,because of the decline in physical performance with age and poor local public transport and grocery stores.
Categorical values

Independent variables
Individual
attributes

Age
Car for driving by yourself

Conditions ofpublic transport
Conditions ofgrocery shopping

Walking time to get to
the nearest station
Type of the nearest grocery store(super market or shopping center)Home delivery service

Under 65
65 to74
75and over
HavingNot having
Within 20 min
More than 21 min
Yes
No
Available
Unavailable
multiple correlation
coefficient
0.37-0.15 -1.0 -0.05

Figure 8. Analysis on factors influencing use frequency of mobile vendor−23−

00.05 1.0 0.15
[times/day]

5.3. Home delivery service
Figure 9 makes it clear that factors influencing use frequency of home delivery service are similar withthose of mobile vendor. That is to say, people living in areas poorly served by local public transport andgrocery stores, depend strongly on home delivery service.
Categorical values

Independent variables
Sex
Individual
attributes

Pain-free walking timeCar

Conditions ofpublic transport
Conditions ofgrocery shopping

Walking time to get to
the nearest station
Mobile vendor
People who support grocery shopping

Male
FemaleWithin 10 min
More than 11 min
HavingNot having
Within 15 minMore than 16 min
Available
Unavailable
Presence
Absencemultiple correlation
coefficient
0.29-0.1 -0.05

00.05 1.0[times/day]Figure 9. Analysis on factors influencing use frequency of home delivery service
6. Analysis of Factors Influencing WTP for the Use of Shopping Support Services for PFD
In this chapter, factors influencing WTP for the use of shopping support services for PFD are clarified
by using quantification theory type I. As with the analysis in Chapter 5, Independent variables using for theseanalyses achieve statistical significance based on one-way analysis of variance. And, all results also do nothave problem of “multicollinearity”.
6.1. Transport support service
As shown in Figure 10, those who are willing to pay comparatively high for transport support service,
have following characteristics: 1) independence state, support required and need of nursing care, 2) pain-freewalking time is less than 3 minutes and 3) impossible to use a car (driving by oneself). It is probable that,
although people become dependent on mobile vendor and home delivery service due to decline in physicalperformance with age, they have potential demand for transport support service.
Factors related to accessibility of local public transport and shopping environment, do not achieve
statistical significance. “Residential area” was used as explanatory variable instead of “walking time to get toCategorical values

Independent variables
Residential area
Sex
Individual
attributes

Certification of care needPain-free walking time
Car for driving by yourself* Requiring includes “independence state”, “support
required”, “need of nursing care”.

KawabeNakatsuMiyamaMale
FemaleNot requiring
Requiring*Within 3 minMore than 3 min
HavingNot having
multiple correlation
coefficient
0.29

-100

-50

0.0

50

Figure 10. Analysis on factors influencing WTP for the use of transport support service
−24−

100

[JPY/one-way]the nearest station”, because options of “walking time to get to the nearest station” cannot express in detailthe differences in distance from home to central area of Hidakagawa town. As a result, “residential area”
achieved statistical significance, and transport support service is the most necessary in Miyama village whereis the farthest area from central area of Hidakagawa town.
6.2. Mobile vendor
There are a few explanatory valuables which achieve statistical significance (Figure 11). However,those who are willing to pay comparatively high for mobile vendor, has following characteristics: 1) morethan 60 years old, 2) pain-free walking time is less than 3 minutes and 3) walking time to get to the nearest
station is more than 26 minutes. That is, individual attributes have a great influence on WTP for the use ofmobile vendor, as is case in WTP for the use of transport support service.
Independent variables
Individual
attributes
Conditions ofpublic transport

Age
Pain-free walking time
Walking time to get to
the nearest station

Categorical values
Under 65
65 and overWithin 3 minMore than 3 min
Within 25 minMore than 26 min
multiple correlation
coefficient
0.21

-200

0.0

200

400
600
[JPY/time]

Figure 11. Analysis on factors influencing WTP for the use of mobile vendor
6.3. Home delivery service
There is no explanatory valuable which achieves statistical significance. Therefore, it is said that, otherfactors which do not considered in this research, have an influence on WTP of home delivery service. As aresult of calculating average WTP of each shopping support service, transport support service is 221 JPY,
mobile vendor is 205 JPY and home delivery service is 185 JPY. Hence, average WTP for the use of homedelivery service is the lowest in other average WTP.
From the above, although people become dependent on mobile vendor and home delivery service due
to decline in physical performance with age, they have potential demand for transport support service, as it
was mentioned in 6.1.
7. Conclusion
This study mainly aimed to gain the fundamental knowledge to develop the model for estimating thedemand for each shopping support service for PFD and the profit from introducing each of them at local
level, from the analyses of factors influencing use frequency and WTP of shopping support services for PFD
considering individual attributes and area characteristics.
As a result, all factor analysis except WTP of home delivery service clarified some factors influencing
use frequency and WTP of shopping support services for PFD. Factors influencing the frequency of go out
shopping by using bus and taxi, are not clarified, because the number of users of local public transport isvery small. However, some findings from 5.1 were very useful to compare with other factor analysis about
use frequency.
Other major findings are summarized as follows.
1) There are difficulties for people to go out shopping, because of the decline in physical performance withage and poor local public transport and shopping facilities. And, those who have difficulty to go out
shopping, depend on mobile vendor and home delivery service.
2) As for the WTP for the use of transport support service and mobile vendor, elderly and disabled people
are willing to pay more high than others.
3) Those who decrease in physical performance with age, depend on mobile vendor and home delivery
service. However, they need an improvement of transport support service, because Average WTP for theuse of transport support service is also highest.

−25−

Acknowledgements
This study was supported by JSPS KAKENHI Grant-in-Aid for young Scientists (B) of which number
is 25820253.

1)
2)
3)
4)
5)
6)
7)
8)
9)

References
Ministry of Economy, Trade and Industry, Report of research group to consider the future of logistics forsupporting the infrastructure for local life (2010).
Ministry of Agriculture, Forestry and Fisheries, Present situation and future policy of food desert
problem (2012).
Ministry of Economy, Trade and Industry, Second edition of “Shopping Accessibility Aid Manual”(2011).
Ministry of Agriculture, Forestry and Fisheries, Guidebook for considering shopping support service forpeople in food desert (2014).
N. Ise and M. Shoji, An Analysis on Influencing Factors on Difficulty of Shopping Accessibility by
Considering Individual Attributes and Area Characteristics, Journal of Traffic Engineering, Vol.33,
463-466 (2013).
H. Hirai, M. Minami, Estimation of the Number of People in Food Desert targeting Elderly People inMorioka city Iwate Prefecture, Proceedings of Infrastructure Planning (CD-ROM), Vol.46, 5pages(2012).
H. Kuramochi, K. Tanimoto and S. Tsuchiya, Shopping Support in Rural Depopulated Areas:Focusingon Delivery Services, Journal of Sociotechnology, Vol.11, 33-43 (2014).
K. Tanimoto and K. Onishi, A Consideration on the Choice of Support Services of Daily Life according
to Physical and Mental Function of Elder People, Proceedings of Infrastructure Planning (CD-ROM),
Vol.45, 4pages (2012)
K. Kishino, H. Kita, T. Ochi and H. Yotsutsuji, A Fundamental Analysis on the Methods to Have
Opportunities of Daily Activities in Rural Area, Journal of Traffic Engineering, Vol.31, 393-398 (2011)−26−

Formation of Waterside Spaces with Groins
Yasumasa FUKUSHIMA* and Takashi UCHIDA**(Received October 3, 2014)

Synopsis
River management in recent years involves measures for waterside management emphasizing theenvironment and utilization as well as river improvement and irrigation. This study addresses the formation ofwaterside spaces with groins as a part of waterside management emphasizing the environment and utilization,using typical groin management cases in which planning we have been engaged. This report presents ourknowledge obtained through processes from planning, business implementation, and subsequent degradation by
aging.
KEYWORDS:

River environment, waterside space, waterside management, groin, land–water ecotone

1. Study Background and Objectives
Groins in Japan have been used from ancient times to control streams and mainly to protect riverbanks fromflooding. Groins have been used for securing water transportation routes in modern times since Meiji, represented
by Krippen groins constructed by Dutch engineer Johannis de Rijke. River management in recent years involves
measurements for waterside management focusing on environment and utilization as well as river improvement
and irrigation. Diverse streams generated by groins have contributed to flood control and to the rehabilitation andcreation of excellent river environments.
This study addresses effective planning and maintenance management methods for the formation of awaterside spaces with groins as a part of waterside management, with emphasis on environment and utilization,using three typical groin management cases in which planning we have been engaged. Using them as examples,
we share our knowledge obtained through processes related to planning, business implementation, and subsequent
aging degradation.
2. Tasks in Groin Management Areas
Tasks in the following three areas of waterside management have been promoted by application of groins.
2.1 Case 1: Kizugawa Waterside Plaza 1)
The Waterside Plaza was constructed for environmental learning integrated with protected lowland facilities
in the neighborhood of the Nagarebashi Bridge, downstream of the Kizugawa River of the class-A Yodogawa
River system. The emergence of river banks and loss of land–water ecotones had been advancing by thedevelopment of an ultra-low water channel (Fig. 1). The task was to rehabilitate sand river beaches (large-scale
sandbars) that used to be there.

Fig. 1 View before construction (Case 1).

* Student, Doctor Course of Department of Civil Engineering** Professor, Department of Civil Engineering−27−

2.2 Case 2: Kizugawa Kasagi area 2)This area is located upstream of the Kizugawa River of the class-A Yodogawa River system, at the foot of
Mt. Kasagi, which is designated as a historic site and beauty spot of Japan. The site has been used by aneighboring elementary school for canoe school lessons and fieldwork related to water quality as part ofenvironmental education. Development has been in progress for its use as a "Waterfront Fun School."
A waterside environment that provides safety and environment in harmony is necessary for multi-purpose
usage patterns such as water wildlife observation and canoeing. However, this site had lost a sandbar that once
existed there (Fig. 2). Therefore, it was required that a gentle waterside environment (land–water ecotone) becreated, which would not spoil the landscape but which would secure safety at the time of canoe boarding or
wildlife observation at the waterside.

Fig. 2 View before construction (Case 2).

2.3 Case 3: The Yoshiminegawa River, Kyoto 3)
Nature-friendly river works were advanced on the Yoshiminegawa River of the class-A Yodogawa Riversystem. At the river bend (Fig. 3), which is a planning site, establishment of a land–water ecotone was advanced
for creating waterside utilization or a habitat of a good ecosystem on the inner bank. At the same time, policies forprotecting river banks were required while creating deep water in the water colliding front incorporated with
low-water bed works by crosspiece structures on the upper and lower streams.

Fig. 3 View before construction (Case 3).

3. Measures with Groins and Aging Degradation after Construction
3.1 Measures with groins
Groin construction was conducted as described below, according to the tasks of each construction area.
Table 1 presents project details for each area.
1) Case 1: Kizugawa Waterside Plaza
Plans were made to reclaim a large-scale sandbar with the combination of diverse structures comprising fivesets of impermeable and permeable groins. Specifically, three short impermeable low-water groins werepositioned at the uppermost stream aiming at changing flow direction, and one permeable low-water groin forbuilding up a varied sandbar and one impermeable low-water groin for forming a reliable sandbar were installed
downstream.

−28−

P-(3)–(5)

P-(2)
P-①

Sandbar reclamation area

P-(1) (7 months after construction)

P-(2) (7 months after construction)

P-(1) (28 months after construction)

P-(2) (28 months after construction)

Fig. 4 Project outline and aspect after construction (Case 1).
Table 1 Detailed groin plan in each caseArea name

Kizugawa Waterside Plaza (Case 1)

River name and river
systemKizugawa River,
the Class-A Yodogawa River system

Estimated high-water
discharge
Estimated high-water
inclination
Segment
Groin number
Groin type
Groin structure detailObjective of
installation
Number of groins
Installation angle
Groin crown height
Groin length (ratio toordinary river width)
Year of construction

6,200 m3/s

P-(1)impermeable low water
groin (overflow groin)
Bagged cobbles

Kizugawa Kasagi area
(Case 2)
Kizugawa River,Class-A Yodogawa
River system

Yoshiminegawa River,
Kyoto (Case 3)
Yoshiminegawa River,Class-A Yodogawa
River system

6,200 m3/s

160 m3/s

1/1300

1/220

1/125

Segment 2-1
P-(2)permeable low water
groin
Pile dike + bagged
cobblesP-(3)–(5)impermeable low water
groin (overflow groin)

Segment M
K-(1) - (3)impermeable low water
groin (overflow groin)

Bagged cobbles

Stone-Net™

Segment 1
Y- (1)–(4)impermeable low water
groin (overflow groin)
Natural stone joint
structure
Deep water formation,
river bank protection
470°, inclined
ordinary water level(river bed elevation)
2.0 m (foot protection
width)FY 2009

Sandbar formation

Sandbar formation

Hydraulic jump

Sandbar formation

1 (lowermost stream)
85°, inclined
low-water level + 0.5 m(+1.6 m of river bed)

1 (middle)
85°, inclined
low-water level + 0.5 m(+1.7 m of river bed)

3 (uppermost stream)
85°, inclined
low-water level + 0.5 m(+1.7 m of river bed)

375°, inclined
ordinary water level(+0.5 - 1.0 m of river bed)

74.5 m (1/4.3)

47.9 m (1/6.7)

9.6 m (1/33.3)

10.0 m (1/10)

FY 2005

FY 2005

FY 2005

FY 2010−29−

2) Case 2: Kizugawa Kasagi area
It was planned in this area to install groins as a necessary minimum reversible artifact harmonized with thelandscape. Their environmental effects were to be used to reclaim the original scenery of this area (sandbar). Thenit was intended to recover a waterside environment securing safety and environmental diversity. Specifically, it
was scheduled to place three impermeable groins to encourage the formation of a small-scale sandbar for river
utilization immediately downstream of the groin.
K-(1)
K-(2)
K-(3)

K-(1) (1 month after construction)

K-(1) (18 months after construction)

Fig. 5 Program outline and aspect after construction (case 2).

3) Case 3: Yoshiminegawa River, Kyoto
The project included the installation of four sets of short impermeable groins at a water collision front, andencouraged the creation and sustainment of a deep water area by the scouring effect of groin edges. It was
anticipated that deep water areas created by this formation would induce an ordinary water route to the watercolliding front, which contributes also to sustainment of a land–water ecotone on the opposite bank.

Y - (1)–(4)Y - (1)–(4)Y - (1)–(4) (14 months after construction)

Fig. 6 Construction rendering and aspect after construction (case 3).

−30−

3.2 Aging degradation after groin construction
In response to the tracking result of aging degradation of groins after construction, the circumstances fromconstruction to the present are organized, from the viewpoints of (a) environmental, (b) utilization, and (c) river
improvement aspects.
1) Case 1: Kizugawa Waterside Plaza(a) Environmental aspect
A large-scale sandbar was formed between groins P-(1) and P-(2) and downstream therefrom, where sandbar
formation had been expected, within half a year after groin installation. The sedimentation trend has beensustained since. A sandbar of about +1.0 – 2.0 m high above the groin installation level is stable today.
Regarding the sandbar formation effect by groins, the sedimentation effect of an impermeable groin (P-(1))
developed more quickly than with a permeable groin (P-(2)). However, a more complex sandbar was formed by apermeable groin. Rooting of herbs has progressed on sand accumulated up to near the crown of groins. Willows
have flourished since about five years after installation.
As for the banks, although emergence of the low water channel was remarkable by division from the waterarea before construction, the regeneration of waterside vegetation such as Phragmites japonica is observed today.
(b) Utilization aspect
Because the steep banks, deep water, and fast stream were considered dangerous, almost no river users
ventured around the waterside or water area before construction. However, since a sandbar was formed after
construction, children have come to play in the water, people stroll on the sandbar, and tourists visiting to thewater's edge have become a common sight.
(c) River improvement aspect
Because groins P-(1) and P-(2) were constructed as inclined, aiming at sedimentation, only their edges
showed a prominent scouring effect, although scouring has been observed that causes modification on a revetment
foundation. Groins P-(3)–(5) were also built as inclined, but groins of the minimum length as much as footprotection width have allowed the effects of a scouring section at the groin edge to extend near the bank(revetment foundation protection). This has modified the revetment slightly, but no particular problem has beenreported to date because this is a revetment of gentle slope with high flexibility made of bag bodies. Moreover, thescouring is within the range of the maximum depth.
2) Case 2: Kizugawa Kasagi area(a) Environmental aspect
A sandbar was formed downstream from groins K-(1)–(3), where sandbar formation was intended, within
half a year after groin installation, and a sandbar of about + 1.0 m high above the river bed elevation is stable atpresent. Herb rooting has been observed only on the groin crowns above ordinary water since around half a year
after groin construction. Nevertheless, no trees have grown there yet.
As for the river bank situation, although the water depth had reached nearly one meter from the waterside
immediately before construction, a land–water ecotone has been created by a sandbar. It is sustained today.
(b) Utilization aspect
Steep banks and deep water were regarded as dangerous before construction. However, canoe school lessons
have been held safely since the sandbar was formed.
(c)River improvement aspect
Although all three sets were planned originally to be rockwork groins covered by natural stone anchored towire gauze (Stone-Net™) in the planning phase, it was found that a rockwork groin of natural stones had been
installed instead on the uppermost stream at the time of construction. Its stone-only structure permitted stones tobe washed away within half a year after construction. Nevertheless, no noticeable damage occurred in theremaining two rockwork groins covered by Stone-Net™ even today, more than three years after construction.

−31−

Only the groin edges showed a prominent scouring effect, although no scouring was observed to cause
modification on the revetment foundation.

3) Case 3: The Yoshiminegawa River, Kyoto(a) Environmental aspect
The scouring trend of edges has been sustained at all groins Y-(1)–(4), so that deep water of about - 1.0 m
depth from the groin installation level is stable today, three and a half years after installation. This stability leads
an ordinary water route to the water colliding front side. Therefore, it contributes to sustainment of a land–water
ecotone on the inner bank. Sedimentation effects are evident downstream of groins, except for one set on theuppermost stream, in spite of the minimum groin lengths of as much as the foot protection width.
Moreover, since the groin crown height was set as high as designed river bed level, the groins had been
supposed to be underwater a full year so that no herb rooting had been anticipated. However as deep water formed
and the ordinary water level was lowered more than assumed, herbs have taken root on the groin crown and on the
sandbar between groins, which have not resulted in tree growth causing river flow impediment.
(b) Utilization aspect
Steep banks made the waterside almost inaccessible before construction. However, waterside utilization bycommunity residents has become popular by access via the land–water ecotone on the inner bank after
construction.
(c) River improvement aspect
Inclined groins aiming at creation and sustainment of deep water areas by scouring at groin edges haveproduced a prominent scouring trend around the edges. A groin length as short as the minimum foot protection
width had raised concerns that the effect of the scouring section at the groin edge would extend to the revetment
foundation protection (near the bank). However, the revetment foundation protection of groins (revetment
embedment) was in a sedimentation trend except for one set on the uppermost stream, so that no damage such as
modification of revetment by excessive scouring has been observed.
4. Important Matters in Evaluation, Planning, and Maintenance Management of Groins in Waterside
Space Forming
The effect of groins for waterside space formation is evaluated based on measures with groins and theiraging degradation after construction in the three areas. Points of discussion include important matters from theviewpoint of the structure type and scale in the planning phase, and tasks and important matters in maintenancemanagement.
4.1 Groin typeComparison in the identical area (Case 1) revealed that an impermeable groin shows a greater sedimentation
effect than a permeable groin, and that the latter forms a more complex sandbar than the former, so that the latter
improves waterside diversity to a greater degree. However, herb rooting on a sandbar deposited up to near thecrown (picket top) allows a permeable groin to hold earth and sand even at a flood. Therefore, it was verified thata permeable groin tends to be an impermeable groin not only in terms of geometry but in terms of its effects.
The structure of a permeable groin projected from the river bed tends to catch down-flowing objects, whichmight not be preferred on a landscape, so that maintenance management is necessary, including removal. Because
they also might threaten the safety of facilities at a flood, it is necessary to perform sufficient examination inconsideration of the collision of flowing-down objects and load at the time of complete occlusion, as well as fluid
force by a stream, at the planning phase.
4.2 Groin length
It was verified that the groin length was about 1/10 of ordinary river width as Cases 1 and 2, which suffices
for forming a land–water ecotone by sufficient sandbar sedimentation effects.
Concerns arose that the minimum groin length as long as a foot protection width as Case 3 can hardly−32−anticipate sedimentation effects because the scouring effect of groin edges extends to the river bank. Nevertheless,sandbar formation by sedimentation has been confirmed near the river bank even by the minimum length of groins.
In other words, a groin as long as the foot protection width can promote the formation and sustainment of deep
water and river bank protection at a water collision front simultaneously.

4.3 Groin heightStandard practices give an upward inclination of about 1/10 toward the river bank side so that a groin edge
becomes at ordinary water-level elevation. Planning was carried out based on this in Cases 1 and 2, aimed atformation of a land–water ecotone by the sandbar sedimentation effect. Results confirmed sufficient sandbar
formation effects.
However, because groins are above the ordinary water level, herb rooting proceeds. Trees such as willows
flourish. Because these results raise fears that fallen trees might damage groins during a flood, maintenancemanagement such as cutting trees is also necessary. It is important to plan projects related to sandbar formation
effects and emergence of groin crowns in a tradeoff relation, while taking care of maintenance management.
When aiming at the formation and sustainment of deep water, it is necessary to suppress sedimentation neara groin and to suppress the emergence of groin crowns that impede derivation of a water route. Therefore, it iseffective to make the groin height as high as the river bed level, as was done in Case 3.
4.4 Constituent materials
Groins have been made from stone and wood from ancient times. Rockwork in an impermeable groin andstone packing to a wooden mattress for foot protection in a pile groin require skillful workmanship. Although nochange in using a lot of stone or wood has occurred even today, it has become possible to secure the required
performance without any skillful workmanship using techniques such as bagged cobbles, Stone-Net™, and anatural stone joint structure used in Cases 1–3. Therefore, it is necessary to use such new technologies actively.
5. Conclusion
Documentation by the Kyushu and Tohoku Regional Development Bureaus compiled based on experiences
to date are useful in groin planning. Practically, there are many projects planned in reference to these even in
Kansai district. However, factors surrounding groin planning such as the flow regime, bed materials, andvegetation situation of a river vary among areas. Their effects cannot be compiled uniformly into documentation,
but an analytical method of groins suitable for the area must be applied.
This study has evaluated the formation of a waterside space with groins using typical groin managementcases we have planned. Using them as examples, based on our knowledge obtained through the processes fromplanning, business implementation, and to subsequent aging degradation, we have proposed important mattersrelated to planning and maintenance management. It is expected to be necessary in the future to conduct analyses
and evaluation of the effect and tasks of groins based on the case of each area, and to establish an effective
method for the planning phase or maintenance management.
References
1) Y. Fukushima, K. Kawamura: Establishment of Waterside Plaza by Regeneration of Sandy River, Kinki
Regional Development Bureau, Ministry of Land, Infrastructure and Transport, Proceedings of Regional
Technical Research Conference 2002, pp. environmental/community improvement 22-1 - 22-6, 2002.
2) S. Noumi, Y. Hotta, M. Tsuruhara: Tasks and Measures Related to Improvement and Sustainment of River
Environment, – Case Study on "Waterfront Fun School Project" in Kizugawa Kasagi area –, Technical Report,
Technical meeting 2010, Naigai Engineering Co. Ltd. , 4pp. , 2010.
3) S. Noumi, Y. Fukushima: Planning and Designing of Falling Works with Gentle Slope of Crosspiece Structure,– Application and Effect of Nature-friendly river work onto the Yoshiminegawa River –, Technical Report,
Technical meeting 2008, Naigai Engineering Co. Ltd. , 4pp. , 2008.

−33−

Sensitivity Analysis on Influence of Fabrication Tolerance of High Strength Bolted
Friction Type Joint to its Slip Strength
Toshikazu TAKAI*, Takashi YAMAGUCHI** and Kiyonori YAMASHINA***(Received October 7, 2014)

Synopsis
This study focuses on fabrication tolerance of high strength bolted friction type joint.
Statistical values of fabrication tolerances of the joints related to its slip strength are obtained
from investigations of past researches and studies. The coefficients of variation of thickness
and width of the plates are small. And, the coefficients of variation of yield point, Poisson’s ratio
and thickness of coating are large.
Based on the tolerances, the influence of the tolerances of joint to its slip strength withextremely thick plates is evaluated by FEM sensitivity analysis. This paper cleared
predominant factors of fabrication tolerances affects the slip strength of the joint. And, theinfluence of tolerance to slip strength is approximately 10% in the maximum.
KEYWORDS: Fabrication tolerance, Slip strength, High strength bolted friction type joint,
Sensitivity analysis
1. Introduction
In Japan, design codes of structure are changing from allowable stress design to limit state
design. For example, design code for railways structures1) have already introduced limit state designin 1992, and also performance based design in 2009. Performance based design is partially introduced toJapan specifications for highway bridge2) in 2004, but the specification is still based allowablestress design method. To update the specification, many investigations and researches arebeing carried out.
This study focuses on fabrication tolerance of high strength bolted friction type joint.
Tolerances related to slip strength of the joint are investigated. Based on statisticalcharacteristics obtained the investigation, the influence of the tolerance to slip strength of thejoint is evaluated by FEM analysis. This paper cleared predominant factors of fabrication
tolerances affects slip strength of the joint.
2. Investigation of fabrication tolerance
Fabrication tolerances are obtained from investigations of past researches and studies3)-7).
This study focuses on parameters related to strength of connected member and mechanicalaspect of joints. The former parameters are thickness, width, yield point, Young’s modulus,
Poisson’s ratio and warp of the plate. The latter parameters are slip coefficient of joint, bold
preload and thickness of coating on connected surface.
The tolerances are obtained by referring past researches, so samples used measurements
have various properties. The values are nondimensionlized as Table 1 and totaled. Especially, plate
warp is totaled as positive and negative direction shown in Fig. 1. Mean value and coefficient ofvariation (C.V.) delivered from standard deviation (S.D.) is obtained as statistical values of thetolerance. These values are shown in Table 2.
*Student, Doctor Course of Department of Urban Engineering** Professor, Department of Urban Engineering*** Student, Master Course of Department of Urban Engineering−35−

Table 1 Nondimensionalization of parameters
Tolerance Parameter

Nondimensionalization

yyield point
Young's modulus
Poisson's ratio
thickness of platewidth of plate
plate warp
slip coefficientbolt preload
thickness of coating
2(*1) 200,000 N/mm(*3) 0.45

measured value/lower yield point
measured value/nominal value (*1)
measured value/nominal value (*2)
measured value/design value
measured value/design value
amount of warp/warp measure length
measured value/design slip coefficient (*3)
measured value/normal bolt preload (*4)
measured value/design value

E
ν
t
W
―
μ
N
―
(*2) 0.3(*4) 205 kN(a) Positive value case(b) Negative value caseFig. 1 Measurement method of warp of plates
Table 2 Statistical values obtained from investigation

y5), 6), 7)

E
ν
t
W
―
μ
μ3
N
―

5), 6)
5), 6)
3)
3)
3)

Number ofsamples
13,442
943
459
2,520
1,260
222

3)

27

3)
4)

303
60

Tolerance Parameteryield point
Young's modulus
Poisson's ratio
thickness of platewidth of plate
plate warp
slip coefficientbolt preload
thickness of coating

Referencemeanm
1.15921.00090.92931.00851.01040.00021.5901
1.69550.95601.1148S.D.

0.10780.04750.08950.00560.00480.00110.0751
0.09590.01900.1147

C.V.
9.3%
4.7%
9.6%
0.6%
0.5%
－
4.7%
5.7%
2.0%
10.3%

The largest and smallest number of samples is 13,442 and 27, respectively. The C.V. of
thickness and width of plate are small as 0.5%. However, the C.V. of yield point, Poisson’s ratio
and thickness of coating are large as 10%. And, the C.V. of Young’s modulus, slip coefficient andbolt preload are also large as 5%.
 of slip coefficient is obtained as a slip load of a joint divided by a bolt preload measured atstart of loading to joint. 3 is obtained as the slip load divided by a bolt preload measured at theoccurrence of slip of the joint. The slip coefficient 3 is almost same as friction coefficient. The
difference between the C.V. of  and that of 3 are 1%. These values have the same distribution.
3. Evaluation of influence of fabrication tolerance to slip strength of joint
3.1 FEM model
FEM Analysis is calculated by Abaqus/Standard 6.9. FEM model is made referring past−36−

(a) Overview of FEM model(b) Analytical range
Fig. 2 FEM model

Table 3 Material properties

Bolt, Washer(F10T, JIS)

Plastic strain(μ )016,40035,10052,80004,400
42,9001,000
Stress (MPa)

Plates(SM490Y, JIS)

Stress
(MPa)
355
356
427
457
900
900
1,000

800

Bolt, Washer

600

Plates

400
200
0
0

20,00040,000Strain (μ)

60,000

Table 4 Dimensions of joint for Analysis
High
strengthbolt
Connected/
Spliceplate

Analysis Series
the number of bolts
Bolt grade
Preload
Yield point
Steel grade
WidthThickness

A
3
kN
MPa

mm
mm
mm
Bolt holemm
Yield point
MPa
Joint
the number of friction surface
property
Friction coef.
Bolt pitchmm
Edge lengthmm
Design slip strengthkN
Design yielding strength of platekN
Slip/yielding strength ratio β

75

886
1,345
0.66

C
G
12
3
M22-F10T (JIS)
205
900
SM490Y (JIS)226
50
75 (Connected plate)
38 (Splice plate)
24.5 (diameter)
355
2
0.72
75
40
3,542
886
5,365
679
1.3

I
12

126

3,542
2,702

study8). The model contains the solid element. The size of the element is 5 mm. The shape of the model isshown in Fig. 3. One forth or one eighth part is modelled regarding its symmetry. Stress strain curves areshown in Table 4. The yield behavior of bolt and washer hardly affect slip behavior of joint. So,
stress-strain curves of the bolt and washer are based on nominal values based on JapaneseStandard9). However, yield behavior of connected plate and splice plate affects the slip behavior.
So, the stress-strain curves of plates based on results of coupon tests that are carried out inadvance.
3.2 Dimensions of joint for FEM analysis
Dimensions of joints for analysis are shown in Table 4. These cases are a combination of the−37−

3875 383875 38480905(a) Top-view of series-A(c) Top-view of series-I (partial)
126

75

75 75
2040
40

204075 75 75 75 75 75 75 75 75 75 75 40(b) Side view of series-A(d) Side-view of series-I (partial)
Fig. 3 Examples of joint shape for analysis
Table 5 Conditions given to FEM analysis
SeriesAll Series

Series A
Series C
Series G
Series I

Tolerance parameteryield point
Young's modulus
Poisson's ratio
thickness (conn. pl.)(splice pl.)slip coefficientbolt preload
width of plate
plate warp
width of plate
plate warp
width of plate
plate warp
width of plate
plate warp

y

(MPa)

E
ν
t

(N/mm )
―
(mm)

μ
N
W
―
W
―
W
―
W
―

―
(kN)
(mm)
(mm)
(mm)
(mm)
(mm)
(mm)
(mm)
(mm)

2

m -2
278
181,006
0.246
74.2
37.6
0.652
197
74.3
-1.1
223.8
-1.1
49.5
-4.1
124.8
-4.1

Fig. 4 Measurement point of relative displacement

Input valuem355
200,000
0.3
75
38
0.72
205
75
0
226
0
50
0
126
0

m +2
432
218,994
0.354
75.8
38.4
0.788
213
75.7
1.1
228.2
1.1
50.5
4.1
127.2
4.1

Percentage
m -2
m +2
-21.6%
21.6%
-9.5%
9.5%
-18.0%
18.0%
-1.1%
1.1%
-1.1%
1.1%
-9.4%
9.4%
-3.9%
3.9%
-0.9%
0.9%
―
―
-0.9%
0.9%
―
―
-0.9%
0.9%
―
―
-0.9%
0.9%
―
―

Fig. 5 Example of slip behavior

number of bolts in a line and slip/yield strength ratio . Some cases contain 3 bolts in a line as
not-long joint. And, other cases contain 12 bolts as long joint. A tensile load applied to anot-long joint makes a major slip that occurs at one time. However, a long joint usually havesmaller slip coefficient than not-long joint. In the long joint, partial slip occurs in smaller levelof tensile load applied before the entire major slip occurs. So, the behavior makes the slip
coefficient small. Slip/yield strength ratio  is obtained as a slip strength divided by a yieldstrength of connected or splice plates. In the case  = 0.66, major slip occurs before yielding ofplates. But  = 1.33, yield occurs before major slip. So in later case, slip behavior is usuallyaffected by yield behavior.
The joint consists of extremely thick plates that are connected plate of 75 mm and splice
plates of 38 mm. Thick plates have been used commonly in members of bridges in recent days.
The grade of high strength bolt is F10T M22 whose diameter of bolt shank is 22 mm.

−38−

Table 6 Results of Analysis
SeriesA

C

Tolerance parameter

Slip stregth (kN)

m -2σ
m
858.2
yield pointσyYoung's modulus
E
855.9
Poisson's ratio
ν
861.9
thickness of plate
t
858.4
858.8
width of plate
W
858.4
plate warp―
866.4
slip coefficient
μ780.4bolt preload
N
825.4
2902
yield pointσyYoung's modulus
E
2745
2908
plate warp―
3049
slip coefficient
μ2766
bolt preloadN2851* slope per tolerance of 1.0xS.D. (σ )

m +2σ
858.8
861.3
856.3
858.9
859.1
857.7
936.7
892.3
2909
3059
3166
3038
2964

Regression
Slope* Intercept
0.15
1.4
-1.4
0.12
858.8
0.18
-2.2
39.1
16.7
1.7
78.5
29.2 2908
68.1
28.3

SeriesG

I

Tolerance parameteryield point
Young's modulus
plate warp
slip coefficientbolt preload
yield point
Young's modulus
Poisson's ratio
thickness of platewidth of plate
plate warp
slip coefficientbolt preload

σy
E
―
μ
N
σy
E
ν
t
W
―
μ
N

Slip stregth (kN)

Regression

m -2σ
m
m +2σ
714.2
842.6
819.6
842.2
832.2
764.4
831.5
764.6
885.2
804.6
855.9
2209
2267
2142
2368
2258
2262
2245
2272
2258
2241
2263
2244
2341
2145
2368
2214
2302

Slope* Intercept
32.1
5.7
832.2
16.8
30.1
12.8
14.6
56.7
0.89
6.9
5.4
24.3
55.7
22.2

2258

Italic and gray color indicates a value determined as relative displacement of 0.2 mm.

(a) Series-A (3 bolts, β = 0.66)(b) Series-C (12 bolts, β = 0.66)(c) Series-G (3 bolts, β = 1.3)(d) Series-I (12 bolts, β = 1.3)
Fig. 6 Influence of tolerance to slip strength of joint

Tolerance values of parameters given to each FEM models are shown in Table 5. The amount oftolerance is twice as large as S.D. shown in Table 2. A tolerance value is given in each case.
Combinations of tolerance parameters are not considered.
3.3 Definition of slip occurrence in FEM analysis
Slip strength is determined by a tensile load applied to the joint and the relative
displacement measured inner side of the connected surface shown in Fig. 4. The measured point is
5 mm from the edge of the connected plate. As shown by the solid line in Fig. 5, in case maximum tensile
load is obtained before relative displacement reaches 0.2 mm, the slip strength is determined by the
maximum tensile load. On the other hand, as shown by dash line, relative displacement reaches 0.2 mm
before the maximum tensile load is obtained, the slip strength is determined by the tensile load at the relative
displacement reaches 0.2 mm3), 8), 10), 11).
3.4 Evaluations and discussions
Results of FEM analysis are summarized in Table 6. Slip strength is obtained according to the−39−definition of slip occurrence. The slip strengths written with italic letters are determined by the
relative displacement, and others are determined by the maximum tensile load. In all cases ofseries-C and I, that are = 1.3 cases, slip strength is determined by relative displacement.
Yield behavior affects slip behavior in these cases.
Values of regression show expressions determined by linear regression using the results of m
– 2, m and m + 2 cases. The intercept of the regression line is equal to slip strength of m case.
A large value of the slope indicates that the tolerance parameter strongly affects to the slip
strength.
Fig. 6 shows the influence in slip strength per tolerance of twice of S.D. 2. The value isobtained the percentage to the slip strength of mean case m of a value increased two times ofslope.
As shown in Fig. (a), slip strength of joints of series-A is affected strongly by slip coefficient and bolt preload N. These parameters affect over 2% of slip strength. In other series, series-C,
G and I,  and N also affect strongly to the strength. However, the influence of otherparameters of series-A is less than 0.5%. The influence is very small.
In= 1.3 cases, the influence of yield point y is large. The influences of y of series-G and I
are larger than that of series-A and C, respectively.  of the joints equals 1.3. And, yield
behavior of connected and splice plate affects to slip behavior before slip occurs. So, thetolerance of y affects the slip strength strongly.
The influences of Young’s modulus E of series-C and I are larger than that of series-A and G,
respectively. The joints of the series-C and I are long joints and have 12 bolts. Slip strength of
the joints is determined by relative displacement. So, the tolerance of Young’s modulus E
relates to elastic elongation of connected and splice plates affects slip strength strongly.
The influences of  and N of Series-C and I are smaller than those of series-A and G,
respectively. And, of a long joint is usually smaller than that of a not-long joint. Thus, thestress of a cross section of connected and splice plates of long joint is probably smaller than thatof not-long joint.
4. Conclusions
This study focuses on fabrication tolerance of high strength bolted friction type joint. The
tolerances focused are related to slip strength of the joint. Based on the tolerances, theinfluence of the tolerances to strength of the joint is evaluated by FEM analysis. Conclusions
and remarks are as follows;
1) Statistical values of fabrication tolerances of joints related to slip strength of the joint are
obtained from investigations of past researches and studies. The coefficients of variation of
thickness and width of the plates are small as 0.5%. And, the coefficients of variation of yield
point, Poisson’s ratio and thickness of coating are large as 10%.
2) Based on the statistical values of the investigation, FEM analysis is carried out. In all seriesof analysis, tolerances of slip coefficient  and bolt preload N of joints affect strongly to slip
strength of the joint. And, in the cases of  = 1.3 or long joint, tolerances of yield point y andYoung’s modulus E also affect strongly to the strength. The former parameter would be
affected by yield behavior before slip occurs. The latter parameter would be affected byelongation of connected and splice plates of long joint.

1)

5. References
Railway Technical Research Institute, Design Standards for Railway Structures andCommentary, 2009.7 (in Japanese)−40−

Japan Road Association, Specifications for Highway Bridges, 2012.3 (in Japanese)
Public Works Research Institute, Osaka City University, Report on rationalistic design ofhigh strength bolted friction type joint, Cooperative Research Report, No. 428, 2012.1 (inJapanese)4) Jun Murakoshi, Naoki Toyama, Mamoru Sawada, Atsuro Ootake, Takashi Yamaguchi, Xue
PENG, “Research on influence of coating condition of connected surface to slip coefficient ofhigh strength bolted friction type joint”, Proceedings of Annual Conference of the Japan
Society of Civil Engineers, I-341, pp. 681-682, 2012.9 (in Japanese)5) Study Group on Steel Structures in Tokai, “Evaluation of resistant strength of steel
structure member and application for reliability design (No. 1)”, Bridge and Foundation
Engineering, pp.33-41, 1980.11 (in Japanese)
6) Hirofumi Aoki, Masaki Nozawa, “Average and coefficient of variation of mechanicalproperty of steel for structure (No. 1)”, 2336, Summaries of technical paper of annual
meeting Architectural Institute of Japan, pp. 1123-1124, 1980.9 (in Japanese)
7) Hirofumi Aoki, Masaki Nozawa, “Average and coefficient of variation of mechanicalproperty of steel for structure (No. 2)”, 2337, Summaries of technical paper of annual
meeting Architectural Institute of Japan, pp. 1125-1126, 1980.9 (in Japanese)8) Toshikazu Takai, Xue Peng, Honghe Sun, Takashi Yamaguchi “Study on Slip Behaviour ofHigh Strength Bolted Friction Type Joint with Extremely Thick Plates by Using Finite
Element Analysis” IABSE Symposium Report, Rotterdam 2013, RTM-0195, pp. 439-446,
2013.5
9) JIS B1186 bolt Japanese Industrial Standards Committee, Sets of high strength hexagon
bolt, hexagon nut and plain washers for friction grip joints, JIS B 1186, 2013.6 (inJapanese)
10) Xue Peng, Takashi Yamaguchi, Toshikazu Takai, Jun Murakoshi, Mamoru Sawada, “FEA
Study on the Slip Behavior of High Strength Multi Bolted Friction Type Joints with Thick
Plates by Structural Dimensions”, Journal of Japan Society of Civil Engineers, Ser. A1, Vol.
69, No. 3, pp. 452-466, 2013.9 (in Japanese)
11) Xue Peng, Takashi Yamaguchi, Toshikazu Takai, “FEA Study on the Slip Coefficient ofHigh Strength Bolted Friction Type Joint with Thick Plates Considering Structural
Dimensions”, The 12th Japan-Korea Joint Symposium on Steel Bridges, pp. 314-322,
2013.92)
3)−41−

Study on applicability of high durability friction grip joints with high strength countersunk
head bolts for steel bridge structures
Akiko TABATA* and Takashi YAMAGUCHI**(Received October 7, 2014)

Synopsis
The authors focused on the high strength bolted friction grip joints with countersunk head bolts which canfinish the surface of the connection plate flat smoothly and prevent from functional depression due tocorrosion. Firstly we carried out Finite Element Analysis in order to evaluate the contact pressure of double
shear connected friction joints with countersunk heads varying the angle of countersunk head. Secondly, we
have compared the slip strength of the joints which has the optimum countersunk head angle with that of thejoint with the normal high strength bolt through the standard slippage test considering variation of plate
thickness and the yield strength of the base and splice plates. As a result, it has concluded that the slip
strength of the joints with countersunk heads exceeds the required design slip strength which has specified in
JSHB and that its slip coefficients is about 10% lower than that with normal head bolts.
KEYWORDS: Countersunk head bolt; contact pressure; slippage test; slip coefficient; slip to yieldresistance ratio
1. Introduction
High strength bolted friction grip joints have been generally applied to connections of the steel structuresfrom the viewpoint of economical rationality and reliability. The paint on the connection tends to deteriorate
due to rust or shortage of the thickness of the paint at the corner edge. Because corrosion is accelerated at aplace where drainage is poor and water is readily stagnant (See Pic.1). Moreover, asphalt pavement on thesteel deck tends to be damaged by the existence of the bolt heads in it.
Therefore, the authors focused on the high strength bolted friction grip joints with countersunk head (SeePic.2) which can finish the surface of the splice plate flat smoothly and prevent from functional decline due
to corrosion.
However joints with high strength countersunk head bolt has been already applied to the bearing type of theconnection, there is almost no research paying attention to the friction grip joints with countersunk head bolts.
When employing a friction grip joints with countersunk head bolts, it is necessary to verify the performanceof the joint which can satisfy the required functions as a connection.
In this study, firstly we carried out FEA (Finite Element Analysis) varying the angle of countersunk head inorder to evaluate the contact pressure of double shear connected friction joints with countersunk heads. Also,
we have investigated the influence on load transferring mechanism by using countersunk head bolt for
frictional joints. Secondly, we have compared the slip strength of the joints which has the optimum
countersunk head angle with the normal high strength bolts through the standard slippage test focusing on
variation of the plate thickness, the yield strength of the base and the splice plates.

***

Pic.1 Corrosion damage of joint of steel pierPic.2 High strength countersunk head bolt
Student, Doctor Course of Department of Urban Engineering
Professor, Department of Urban Engineering−43−

2. Mechanical Behavior from FEA
2.1Outline of FEA and FE models

D

The axisymmetric FEA was conducted by ABAQUSStandard 6.9[1]. Double shear connected joint are dealt
with in the analysis. .
The countersunk head bolt for FEA is shown in Fig.1. Inorder to evaluate the slip strength with countersunk headbolts, the angle of countersunk head is changed as 60, 70,
80, 90, and 110 degrees. For a comparison, the joint withthe hexagon head bolt shown in Fig.2 is also dealt with.
All of analytical cases in this analysis are tabulated in
Fig.1 and 2.
An example of the FEA model, CD-90 is shown in
Fig.3. The thickness of the splice plate and the base plateis 16mm and 32mm respectively, and the length of the
splice plate and the main plate is 50 and 70 mm
respectively referring to the minimum spacing distance
between bolts specified in Ref. [2] .Diameter of the bolt
hole is 24.5 mm, which is the standard value also
specified in Ref. [2].
A contact boundary which can consider contact, friction,and separation is installed into the analytical surface
between the splice and the base plate.
In order to clarify distribution of the contact pressure
on the contact surface, the area where two surfaces are
expected to be contact has fine mesh division. Friction
coefficient for the contact surface is both 0.5 between
the splice and the base plate, and also between the
splice and countersunk bolt head surface. Design bolt
axial force 205kN for F10T (M22) is installed into thebolt. The steel material is SS400(σy=235MPa), elastic
modulus E is 2×105MPa, and poisson’s ration is 0.3.
The FE model of the joint with hexagon head bolt (HDmodel) is also shown in Fig.4. Dimensions of the splice
plate and the base plate are the same of CD series.

case name

CD-60
CD-70
CD-80
CD-90
CD-110

Angle of
Curvature of
Diameter of Diameter ofThickness ofcountersunk
bolt headbolt neck d bolt head D
bolt head H
head θ
and bolt
（㎜）
（㎜）
（㎜）
(degree）
neck R（㎜）

60
70
80
90
110

22.0
22.0
22.0
22.0
22.0

34.7
37.5
40.5
44.0
53.5

3.0
3.0
3.0
3.0
3.0

11.0
11.0
11.0
11.0
11.0

Fig.1: Countersunk head bolt

case name

Diameterof boltneck
d1（㎜）Diameterof bolt
head
B（㎜）Diameterof bolt
head
C（㎜）

HD

22.0

36.0

41.6

DiameterThicknessof bolt Curvature of bolt
head
R （㎜）
head
D （㎜）
H（㎜）

34.0

3.0

14.0

Fig. 2: Hexagon head bolt

2.2
Analytical results and discussions
2.2.1
Contact pressure distribution
Distribution of contact pressure at the contact surface between the splice and the base plate obtained fromthe FEA is shown in Fig.5. The vertical axis is contact pressure (MPa) and horizontal axis is the distancefrom the hole edge. As shown in Fig.5, it is found that high contact pressure over yield strength occurs
around the hole edge in CD series comparing with that of HD. Its maximum value is that of CD-110. As theangle of countersunk head increase, contact pressure tends to become higher around the hole edge. On theother hands, the existence area of contact pressure of CD series is smaller than that of HD. The minimum
case of the existence area of contact pressure is CD-110. Therefore, the FEA results indicate that contactpressure of CD series is higher than that of HD and is distributed in smaller area.
2.2.2
Shear stress distribution
Fig.6 shows the shear stress distribution on the contact surface. Arrow diagram of nodal force at the contact
surface and the deformation are also shown in Fig.7. To understand deformation characteristics with ease,each displacement is multiplied by 100. It is understood from these two Figures that high shear stress occurs−44−

near the bolt hole edge .due to the friction force by the local deformation of the splice plate.
2.2.3
Maximum stress
An example of stress contours of Von-Mises of CD-90 is depicted in Fig.8. High stress concentration over
the yielding stress between the countersunk head and the shank is observed when the design bolt axial force,
205kN is applied. Maximum stresses of all cases when the design bolt axial force is applied are tabulated inTable 1. It is found that the maximum stress of CD series is higher than that of HD, and that the case that theangle of countersunk head is 90 degrees shows lowest maximum stress. The reason is considered that thestress at the corner part between bolt shank and bolt head depends on the magnitude of the contact force
along the perpendicular direction to the countersunk head and the distance from here to the applied point. It
has concluded that the most suitable angle of the countersunk head is 90 degrees.
axialaxialsymmetricline
symmetric line
Friction coefficient:0.5
ᦶ᧿ಀᩘ0.50
axial symmetricaxial symmetricline
line

Friction ᦶ᧿ಀᩘ0.001
coefficient:0.5

Frictioncoefficient:0.5
ᦶ᧿ಀᩘ0.50
Splice plate width:50mm
㐃⤖ᯈᖜ50mm

ᦶ᧿ಀᩘ0.5
Frictioncoefficient:0.5
Splice plate width:50mm

Splice plate
thickness:16mm

㐃⤖ᯈཌ16mm

Splice plate
thickness:16mm

ẕᯈཌ32mmBase plate
thickness:32mm

Base plate
thickness:32mm

Base plate width:70mmቃ⏺᮲௳ẕᯈᖜ70mmv=0
タィ㍈ຊ205kN
Designbolt axialⲴ㔜ไᚚ
force:205kN㍈ᑐ⛠ᛂຊせ⣲E=200,000[MPa]ν=0.3

E:200,000Mpa
Poisson’s ratio:0.3

タィ㍈ຊ205kN
Designbolt axialⲴ㔜ไᚚ
force:205kN

ቃ⏺᮲௳
v=0

Base plate width:70mm
E:200,000Mpa㍈ᑐ⛠ᛂຊせ⣲E=200,000
Poisson’s
ratio:0.3[MPa]ν=0.3

Fig.4: FEA model for HD

Fig.3: FEA model for CD-90
350

70

CD-70

250

CD-80

200

CD-90

the shear stress 䠄MPa)

Contact pressure 䠄MPa)

CD-60
300

CD-110
150

HD

100
50
0

㻜

㻡

㻝㻜

㻝㻡

㻞㻜

㻞㻡

50

40
30
20
10
0

㻟㻜

㻜

Distance from the hole edge(mm)Fig.5: Contact pressure distribution on the contact
surface

CD-60
CD-70
CD-80
CD-90
CD-110
HD

60

㻡

㻝㻜

㻝㻡

㻞㻜

㻞㻡

Distance from the hole edge(mm)㻟㻜Fig.6: Shear stress distribution on the contact
surface

Table 1: Maximum stresscase name

Fig.8: Stress contours of Mises(CD-90)−45−

M aximum stress3

䠄×10 䠈M Pa䠅

CD-60

1.593

CD-70

1.416

CD-80

1.227

CD-90

1.196

CD-110

1.364

HD

1.056

3. Slippage test
3.1.Outline of the slippage test and specimens
In order to clarify the behaviour of friction joints with high strength countersunk head bolts for steel bridge
structures, we have carried out the standard slippage test taking into account for steel material grade, slip toyield resistance ratio β, and the number of contact surface(double or single shear). Geometricalconfigurations of the specimens for the slippage test are shown in Fig.9. The structural parameters of thespecimens are listed in Table 2. The angle of the countersunk head is fixed 90 degrees based of the analyticalresults described in chapter 2 and in Ref. [3]. Contact surface of the plates are painted by inorganic zinc-rich
paint with more than 75μm thickness. Pic.3 shows the specimen with the countersunk head bolts. Structuralparameters in this experiment are explained in detail as follows;a) Steel material grade (SS400, SM490) : Investigated is influence of local yielding around the bolt holes on
the slip resistance.
b) Slip to yield resistance ratio β : This is for clarification of the difference of mechanical behaviour
between slipping type(β<1.0) and yielding type(β>1.0). βd (See Table2) is the ratio calculated by thefriction coefficient(0.5) and the nominal yield resistance. βe is the ratio calculated by the slip coefficientobtained from the experiment for the specimen of slipping type and yield stress obtained from thematerial test (See Table 3).
c) Number of the contact surface (double or single shear): Difference of behaviour caused by different
number of the contact surface and eccentricity between the base and splice plate is investigated.
In the experiment, bolt axial force for the hexagon head bolt is measured by the strain gauge which glued
on the bolt shank as shown in Pic.4. Bolt axial force for the countersunk head bolt is also measured from thestrain gauges glued on the bolt head in consideration of preventing from stiffness decrease by the holes forthe strain gauge wires as shown in Pic.4. The slippage test is executed by using universal testing machine(1,000kN) of Osaka City University. To clarify the slip behaviour with ease, fixed and slipped sides are set inadvance by changing the bolt axial force. The bolts at fixed side are tightened with 10% higher of the designbolt axial force. Tensile load is applied until the major slip at the slipped side is observed. As shown in
Fig.10, measured are relative displacements between the base plate and the splice plate, applied tensile load
and bolt axial forces. In this experiment, the definition of slip occurrence is when the relative displacement at
δ3 becomes 0.2 mm in accordance with the specification of Architectural Institute of Japan [4].

(a) CD-12M12S、CD-12M12M(b) CD-16M12M(c) CD-32M16M(d) CS-12S16M、CS-12M16M(e) CS-16M22M

Fig.9: Geometrical configurations of the Specimen for slippage test (mm)−46−

Table 2: List of specimens and experimental parameters
Base plate

Splice plate

grade

mm

grade

SM490
SM490
SM490
SM490
SS400
SM490
SM490

12
12
16
32
12
12
16

SS400
SM490
SM490
SM490
SM490
SM490
SM490

12
12
12
16
16
16
22

SM490
SM490
SM490
SM490
SS400
SM490
SM490

12
12
16
32
12
12
16

SS400
SM490
SM490
SM490
SM490
SM490
SM490

12
12
12
16
16
16
22

Slip to yield
Number of Slip to yield
Yield strength
Number of thethe contact resistance ratio resistance ratioof base plate
specimenße
surfacePy （ｋN)
ßdmm

Countersunk head bolt

CD-12M12S
CD-12M12M
CD-16M12M
CD-32M16M
CS-12S16M
CS-12M16M
CS-16M22M

doublesingle

1.39
1.39
1.04
0.52
1.08
0.78
0.57

1.72
1.72
1.28
0.66
1.21
0.96
0.69

3
3
3
3
3
3
3

346
346
466
899
230
309
429

1.39
1.39
1.04
0.52
0.96
0.70
0.52

1.93
1.93
1.43
0.74
1.21
0.96
0.73

3
3
3
3
3
3
3

346
346
466
899
257
346
466

Hexagon head bolt

HD-12M12S
HD-12S12M
HD-16M12M
HD-32M16M
HS-12S16M
HS-12M16M
HS-16M22M

doublesingle(a) surface of countersunk hole

ひずみゲージ(a) Hexagon head(b) Countersunk head
Pic.4: Strain gauges for bolt axial force
measurement(b) After tightened of bolts
Pic.3: Overview of the Specimen

Table
Material

3:

Results

Thicknessofthematerial

Yieldstrength

Tensilestrength

Elastic
modulus

2

2

2

test

Poiison's
ratio

mm

N/mm

N/mm

N/mm

SM490

32

338.2

500.5

2.07×10

5

0.28

SM490

22

344.0

533.6

2.11×10

5

0.29

SM490

16

350.5

526.2

2.10×10

5

0.29

SM490

12

347.0

516.5

2.09×10

5

0.29

434.5

5

0.29

SS400

12

275.8

2.09×10

ひずみゲージ

Fig.10: Dimensions of the specimen andmeasured location of relative displacements
3.2.Experimental Results and discussions
3.2.1.Definition of the slip coefficient
Experimental results are summarized in Table.4. Each obtained slipping resistance force and slip coefficientare tabulated. The slip coefficient μ1 is the ratio of the slipping resistance force divided by the total bolt axial−47−

force before slippage test as shown in the equation (1),
P
(1)
1 
m  n  N1
µ1：slip coefficient
P ：slipping resistance force at δ3=0.2mm(kN)
m：number of the splice platen ：number of the bolt
N1：average of two bolts axial force before slippage
test(kN）
The slip coefficient μ0 is the ratio of the slipping
resistance force divided by design bolt axial force asshown in the equation (2),
P
(2)
0 
mn N0
N0：design bolt axial force (205kN)

Fig.11: Relationship between μ1 and βe

The slip coefficient μ2 is the ratio of the slipping
resistance force divided by total bolts axial force whenslipping occurs as shown in the equation (3),
P
(3)
2 
mn N2
N2：average bolt axial force at slip（kN）
3.2.2.Effectiveness of the steel material grade
In order to clarify the slip resistance under various
steel grades (SS400, and SM490), it is compared withthe slip coefficient of CD-12M12M and CD-12M12S
as yielding type. Also CS-12M16M and CS-12S16M asslipping type are investigated.
As shown in Table.4, slip coefficient of CD-12M12M(µ1=0.46) is approximately 2% higher than that of
Fig.12: Relationship between μ2 and βe
CD-12M12S (µ1=0.45). In addition, CS-12M16M(µ1=0.51) is also approximately 11% higher than thatof CS12S16M (µ1=0.46).
These results indicate that slip coefficients becomes higher by using high strength steel SM490 for the splice
plate with countersunk bolt holes. The improvement of the slip coefficient for the slipping type by using
higher strength steel is more effective than that of the yielding type.
3.2.3. Slip to yield resistance ratio β and number of the contact surface
Fig.11 shows the relationship between slip coefficient µ1 and slip to yield resistance ratio βe. It is observedthat slip coefficient µ1 has a tendency to get lower by increase of βe regardless of bolt type, steel material
grade, and number of the contact surface.
Maximum slip coefficient µ1 is 0.66(CD-32M16M)/0.74(HD-32M16M) for CD/HD series respectively.
These are both slipping type. Minimum slip coefficient µ1 is 0.45(CD-12M12S) /0.48(HD-12M12S) for
CD/HD series respectively. These are both yielding type. It is summarized that slip coefficients µ1 for thecountersunk head specimens are approximately 10% lower than those for hexagon head specimens in spite ofnumber of the contact surface.
The reason is considered that the contact pressure of the joints with countersunk head reduce due to progress−48−

Table 4: Summary of experimental results
Specimen

Slip ResistanceP
kN

Axial force
before test
N1
kN

Axial force atslipping
N2
kN

Slip coefficient（P/N1）

Slip coefficient（P/205kN）

Slip coefficient（P/N2）

μ1

μ0

μ2

Ave.

Ave.

Ave.

decreasing rate of axial
force
Ratio

Ave.

Double shear series
CD-12M12S

HD-12M12S

364.79366.05386.07363.91387.99379.76208.97207.69209.30192.37
195.99197.95186.96186.89182.08178.15168.83
181.39

0.44
0.44
0.46
0.47
0.49
0.48

decreasing rate of slip coefficient （ C/H ）CD-12M12M

HD-12M12M

384.51385.99368.44389.26378.49209.20208.05208.08201.03202.23
invalid189.91183.75190.50183.66186.43

0.46
0.46
0.44
0.48
0.47

decreasing rate of slip coefficient （ C/H ）CD-16M12M

HD-16M12M

422.93460.29474.37469.89484.38473.05210.67214.18211.39198.80201.61
198.95191.31
192.07
187.74181.42
182.43178.15

0.50
0.54
0.56
0.59
0.60
0.59

decreasing rate of slip coefficient （ C/H ）CD-32M16M

579.87593.38588.19594.56

HD-32M16M
602.19218.96220.53228.85202.13
invalid203.97200.45202.19209.69187.59

0.66
0.67
0.64
0.74

189.85

0.74

0.45

0.48

0.44
0.45
0.47
0.44
0.47
0.46

6.2%
0.46

0.48

0.60

0.47

0.55

0.58

0.72

10.8%

11.2%

9.9%

0.50

0.52

0.91
0.88
0.92
0.91
0.92

9.8%

8.2%

0.59

0.66

0.91
0.90
0.89
0.91
0.90
0.90

10.2%

9.6%

9.7%
0.72
0.73
0.70
0.79

0.73
0.73

0.54

0.89
0.90
0.87
0.93
0.86
0.92

2.7%
0.55
0.60
0.63
0.65
0.66
0.66

5.2%
0.71
0.72
0.72
0.73

0.74

decreasing rate of slip coefficient （ C/H ）

0.46

0.50

7.4%
0.51
0.53
0.48
0.53
0.51

2.1%
0.52
0.56
0.58
0.57
0.59
0.58

11.7%
0.66

0.46

0.49
0.49
0.53
0.51
0.57
0.52

2.2%
0.47
0.47
0.45
0.47
0.46

4.2%
0.53

0.45

0.72

0.92
0.92
0.92
0.93

0.79
0.79

1.4%

8.4%

7.1%
0.93

9.2%

Single shear series
CS-12S16M

195.20198.72HS-12S16M

202.30213.53

invalid216.53211.42
invalid202.11200.34171.96167.76

0.45
0.47

0.46

0.48
0.48

0.48

0.57
0.59

0.58

0.79
0.79

20.6%

171.21
162.20

0.50
0.53

0.52

0.49
0.52

0.51

0.59
0.66

0.62

0.85
0.81

17.2%

decreasing rate of slip coefficient （ C/H ）CS-12M16M

HS-12M16M

237.48224.49223.31
234.17219.89213.85228.46218.53214.29203.11
invalid174.41
188.73181.55
181.69178.30

0.54
0.49
0.51
0.55
0.54

decreasing rate of slip coefficient （ C/H ）CS-16M22M

HS-16M22M

264.10252.40247.25257.65215.49236.12222.14212.71
invalidinvalid182.37209.00
196.00189.32

0.61
0.53
0.56
0.61

11.5%
0.51

0.54
5.6%
0.57

0.61

decreasing rate of slip coefficient （ C/H ）

5.9%
0.58
0.55
0.54
0.57
0.54

6.6%

0.56

0.55

7.1%
0.66
0.59
0.61
0.64
0.62

-1.8%
0.64
0.62
0.60
0.63

0.62

0.63
1.6%

0.62

0.63

0.82
0.83
0.83
0.85
0.88

17.6%

13.7%

1.3%
0.72
0.60
0.63
0.68

0.65

0.68

0.85
0.89
0.88
0.89

12.9%

11.0%

4.1%

of local yielding around the countersunk bolt holes by increasing applied tensile load.
Slip coefficients of the double shear series are higher than those of the single shear series regardless of typeof the bolt head. This is caused by that the contact pressure of the single shear joints is lower than that of the
double shear joints because of eccentric bending between the base plate and the splice plate.
Fig.12 shows the relationship between slip coefficient µ2 and slip to yield resistance ratio βe. It can be
confirmed that the slip coefficients µ2 of all specimens are higher than the slip coefficients µ1.
It is also found that the variation of the slip coefficients µ2 under the same slip to yield resistance ratio β is−49−

smaller compared with the variation of the slip coefficients µ1. Because the slip coefficients µ2 are evaluatedby the slipping resistance force and total of bolt axial forces at slip occurrence, these values become higher
and the variation becomes smaller by elimination of the bolt axial force decreasing during load transfer.
It is concluded from the experimental results that the slip strength of the joints with countersunk head bolts
exceeds the design required slip strength which has specified in JSHB by the slip coefficient 0.45.

4. Conclusions
This paper deals with the applicability of high strength bolted friction grip joints with countersunk headbolts for steel bridge structures which can finish the surface of the connection plate flat smoothly and preventfrom functional depression due to corrosion. The main conclusions obtained are as follows,(1) In order to clarify distribution of the contact pressure on the contact surface of the joints withcountersunk heads, the FEA was carried out varying the angle of countersunk head. It has concluded thatthe most desirable angle of the countersunk head is 90 degrees from the viewpoint of distribution of thecontact pressure and stress concentration of the bolt.
(2) In the cases of CD series, the FEA results indicate that high contact pressure over yield strength occurs
around the countersunk edge of the bolt hole and the distributing area is small comparing with HD series.
(3) In order to clarify the behavior of friction joints with countersunk head bolts, the standard slippage test
were executed considering variation of plate thickness and the yielding strength of the base and splice
plates.
(4) It has concluded from the experimental results that the slip strength of the joints with countersunk headbolts exceeds the design slip strength specified in JSHB calculated by the slip coefficient 0.45 and that its
slip strength is about only 10% lower than that with normal head bolts. It is caused by that the contactpressure of the joints with countersunk head reduce due to progress of local yielding around the bolt holes
as increasing applied tensile load.
(5) In order to apply such joints to practical joints of bridge members, further researches on applicability ofthe over-sized holes and multiple arrangements of countersunk bolts and so on are should be required.
5. References
SIMULIA:Abaqus Analysis User’s Manual,Vol.1-5
Japan road association: Specifications for highway bridges, Part2 steel bridges, 2012 (in Japanese)
A Monta, Tanihira T.; Experimental Study on the Shape Improvement and application of High Tension
Countersunk Head Bolts in Friction Grip Joints, JSSC Journal of Constructional Steel, Vol.6, pp.65-76,
1992 (in Japanese)4) Architectural Institute of Japan: Recommendation for Design of Connections in Steel Structures, 2006
(in Japanese)

1)
2)
3)

−50−

A Path to Creating an Opportunity for Communication using the “Machizukuri Pattern”
Yasutomi SAKUMA*(Received October 9, 2014)

Synopsis
In this report, I will discuss how we created a “Machizukuri pattern” in a graduate school class that
could be used to create an opportunity for better communication about the skills and abilities of the local
community.
From the results, the following was clear:
1) There were certain tendencies in those Machizukuri patterns that were selected before the dialogue. “I can
explain” was chosen by many for those patterns involving spatial aspects. “I want to listen” was chosen
by many for intangible, cultural, and historical patterns.
2) There was comparatively little bias in the Machizukuri patterns selected after the dialogue activity.
3) The opportunity for dialogue using the Machizukuri patterns was understood by most, but there were two
people who answered, “It was hard to understand.” In addition, the degree of satisfaction was high.
4) It was indicated that the points in need of improvement were “expression of the Machizukuri pattern” and“method of communication.”
5) It was also indicated that the application possibilities of the Machizukuri pattern are as a “communicationtool” between various people and for “application to a Machizukuri Workshop.”
KEYWORDS: Pattern-Language, Machizukuri Pattern, Workshop
1. Introduction
It is inevitable in a shrinking population that our lives are increasingly supported by limited humanresources. Though new people who desire to accept responsibility appear, the skills and abilities of the local
community are not easily ascertained. Additionally, it is expected that the town hall staff and residents of thelocal community accept responsibility for implementing Machizukuri (community design, community-basedplanning) in a rural area. It is required that those town hall staff members who manage the local community
projects possess some proficiency. Because every person is a member of a local community, they each canmanage its projects. The result of the project depends on personal factors, and the description of theirexpertise is insufficient. As a result, a method is required for describing the capabilities of the local
community’s members.
Therefore, I focus on “pattern-language” in this report. Pattern-language was developed by C. A.
Alexander as a method of creating tools that enable communication between the professional and thelayman1). In Japan, pattern-language has been used to describe town-planning rules, such as the “Design
Code” in Manazuru City, Kanagawa Prefecture (1992); “The standard of Machizukuri,” which was a
voluntary agreement in Kawagoe City, Saitama Prefecture (1988); the “Icoma City Landscape Formation
Master Plan” in Icoma City, Nara Prefecture (2014); and so on. Recently, use of pattern-language has
decreased in the fields of architecture and city planning, but it has begun to garner attention in the field ofsoftware development3). In addition, it is beginning to be applied as a method of describing aptitude in thefields of institutional design and educational design. It is expected that, through use of pattern-language todescribe human action, the non-professionals can communicate on even ground. Therefore, we can create a“Creative Society” in which people take action to create a better future4).
In this report, I discuss how a graduate school class created a Machizukuri pattern to describe theaptitude of local community members, thus creating an opportunity for communication.

*

Lecturer, Department of Urban Engineering, Osaka City University−51−

2. Outline of survey(1) How to create a Machizukuri pattern
I submitted an assignment that requiring the making of three Machizukuri patterns to the classmembers of Urban Design Exercises, Department of Urban Engineering, Graduate school of Engineering,Osaka City University (Figure 1). I provided a format for writing a Machizukuri pattern. It was on May 30,
2014 that I assigned this task, and the due date was July 4, 2014.
Assignment: describe three important topics used for discussion about Urban Planning, Urban
Design, and Community Design, using the method of “Pattern-Language.”
1) You may choose a subject you have experience with, or not. (1)2) You should imagine the subject as if you were involved in a plan or a design.
3) You should think beyond the definitions of “Urban Planning,” “Urban Design,” and“Community Design.” You should think of a series of activities used for approaching aspace.

Figure 1. Instructions given for the task of making three Machizukuri patterns.
The format of a Machizukuri pattern.
1) Title2) Context
3) Problem4) Solution (and an example)
5) Some comments (something you think, your impressions, your name)(These items were laid out in one A4 paper.)Figure 2. Major items of the format for making a Machizukuri pattern.
(2) How to arrange a Machizukuri pattern
I arrange a Machizukuri pattern using the KJ-method(2), which was included in the assignment.
(3) How to create dialogue with a Machizukuri pattern
I had the students talk with their friends using the Machizukuri pattern on the day of the exercise (July18, 2014).
1) First of all, I showed the arranged Machizukuri patterns to the students. The students then read theMachizukuri pattern that they wrote so they would understand them.
2) I then had the students talk with their friend, following the method of Iba5). The students then choose
three patterns for which they thought “I can explain” or “I want to listen.” They then spoke with theirfriend about meaning of the Machizukuri pattern. This took about 5 minutes for each discussion of apattern, and they spoke about three patterns.
3) After the dialogue, I executed a questionnaire survey. The items of the questionnaire survey were as
follows in Figure 3.
1)
2)
3)
4)
5)
6)
7)
8)
9)

For what pattern did you think, “I can explain?” (3 items)
For what pattern did you think, “I want to listen?” (3 items)
For what pattern did you think, “I have explained?” (3 items)
For what pattern did you think, “I have listened?” (3 items)
Was the Machizukuri pattern easy to understand? (5 grade points)
Did you have fun with the Machizukuri pattern dialogue? (5 grade points)
What point of the Machizukuri pattern needs improvement? (free answer)
What do you think of the Machizukuri pattern’s application possibilities? (free answer)
What do you think anything else? (free answer)

Figure 3. Items of the questionnaire survey.
3. Results
3.1. Machizukuri pattern
There were 70 patterns collected from 24 students (one student submitted only one pattern). The names−52−

of these 70 patterns were provided by the students who originated them, so the degree of abstraction for eachpattern varies. I changed the name of some patterns for clarity and arranged them using the KJ-method,
ending up with 44 Machizukuri patterns.
Table 1. Machizukuri patterns arranged by KJ-Method.
No.
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22

Name of Pattern
Management to increase a community’s value
Stimulation to create a community
Autonomy of a community
Imagining a future vision of a community
Making a community rule
Self-determination
Cooperation with a neutral person
Corroboration with various people
Creation with everyone
To expand the persons concerned
Adoption of everyone’s opinion
Having a different point of view
Discussion with people who hold a different position
A series of small successes
Learning a lesson from precedents
Thinking with a new set of values
Welcome the new immigrant
Making a technical term easier
To inform non-residents of something
Corroboration with residents and immigrants
Description of local culture
Forming a new business

No.
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44

Name of Pattern
A satellite officeSuccess of local businessSpace that residents can change
A back alley space
Creating a waterfront space
Deregulation
Discussion of the outdoors
A place of memories
Concentration of functions
Establishment of a symbol
Formation of a compact city
Residence in downtown
Public-built and privately operated
Making an activity baseOpening a station to the local community
Making use of the existing facilities
Regeneration of an “old” new town
To make something oneself
Planning comprehensively
Coexistence between the old and the new
Review in a combined unit
Optimization of a T junction

3.2. Dialogue using a Machizukuri pattern
I had the students talk with their friends, employing the method used by Iba. They spoke with theirfriends about the meanings of the Machizukuri patterns. This took about five minutes for each discussion,and they talked three times.

Figure 4. A scene depicting dialogue using a Machizukuri pattern.
3.3. The Results of the Questionnaire Survey Administered after the Dialogue
After the Machizukuri pattern dialogue activity, I executed a questionnaire survey. I collected 18−53−effective responses, because although there were 19 students present, there was one late comer.
1) “I can explain,” “I want to listen,” “I have explained,” and “I have listened”
Overall, there was great interest in “Space that residents can change”, “Creating a waterfront space”,“Thinking with a new set of values”, “Establishment of a symbol”, and “Coexistence between the old and thenew”.
As for the results of “I can explain,” many students selected “Creating a waterfront space”, “Making useof the existing facilities”, “Thinking with a new set of values”, “Space that residents can change”, and“Regeneration of an ‘old’ new town”. It was determined that many students chose the items that were easiest
to understand, like spatial designs. As for the results of, “I had explained,” many students chose “Creating awaterfront space” and “Space that residents can change”. I was able to confirm that there was almost no
difference in the tendency to answer, “I can explain.”

Figure 5. Machizukuri patterns to which the students answered, “I can explain.” “I want to listen,” “I have
explained,” and “I have listened.”
As for the results of, “I want to listen,” Many students selected “Description of local culture”,“Coexistence between the old and the new”, “Thinking with a new set of values”, “A back alley space”, “Aplace of memories”, “Establishment of a symbol”, and “Optimization of a T junction”. It seems that many
students were interested in the patterns of intangible, local, and historical things, like culture, a small alley, apersonal memory, and so on. As for the results of “I have listened,” students selected “A place of memories”
as the most common answer. However, there was a tendency for the number of answers to show low
distribution.
There was a tendency toward certain items of the questionnaire (“I can explain” and “I want to listen”)
before the dialogue. However, there was no tendency shown in the distribution of the items of thequestionnaire (“I have explained” and “I have heard”) after the dialogue.
2) Was the Machizukuri pattern easy to understand?
There were 16 students who replied that the Machizukuri pattern was “Easy to understand”; 1 student
who replied, “Hard to understand”; and 1 student who replied, “Very hard to understand.” Overall, most of
students reported that they were able to understand the Machizukuri patterns.

−54−

Figure 6. Was the Machizukuri pattern easy to understand?
3) Did you have fun with the Machizukuri pattern dialogue? (5 grade points)
Only 1 student replied, “Very Fun,” and 17 students replied “Fun.” Overall, most of students weresatisfied.

Figure 7. Did you have fun with the Machizukuri pattern dialogue?
4) What point of the Machizukuri pattern needs improvement?
Regarding the points that need improvement, many students selected “Expression of the Machizukuri
pattern,” and “Method of Communication.” Regarding “Expression of the Machizukuri pattern,” it seemedthat the abstraction degree leading to several interpretations of the same pattern is a factor in their confusion.
Regarding “Method of Communication,” it seemed that they were confused about finding their partner in the
dialogue activity.

Figure 8. What point of the Machizukuri pattern needs improvement?

Figure 9. What do you think of the Machizukuri pattern’s application possibilities?

−55−5) What do you think of the Machizukuri pattern’s application possibilities?
Regarding the application possibilities, many students replied that it could be used as a “communicationtool” or for “application to a Machizukuri Workshop.” As a “communication tool,” they proposed that theMachizukuri pattern is effective when people meet for the first time and when someone meets various people.
As an “application to a Machizukuri Workshop,” they proposed that the Machizukuri pattern would be
effective in a meeting of the inhabitants and in the dialogue of a student-managed project.
4. Conclusions
This study yielded some important results, as follows:
1) Machizukuri patterns selected before the dialogue had certain tendencies. Many students chose “I can
explain” for items concerning spatial topics. Many chose “I want to listen” for intangible, cultural, andhistorical patterns, such as those about a small alley or personal memory.
2) Machizukuri patterns selected after the dialogue had comparatively little bias.
3) The opportunity for dialogue using the Machizukuri pattern was understood by most, but there were
two people who answered, “It was hard to understand.” The degree of satisfaction was high.
4) It was indicated that the points in need of improvement were “Expression of the Machizukuri pattern”
and “Method of Communication” regarding how to find a dialogue partner.
5) It was indicated that the application possibilities of the Machizukuri pattern were as a “communicationtool” between various people and for “application to a Machizukuri Workshop.”
Further research should be conducted to accumulate knowledge about the Machizukuri pattern byapplying it at a Machizukuri site.
5. Notes(1) This exercise was held for two hours every two weeks. Some students were in charge of one subject infour exercises.
(2) The KJ-method is a method of analyzing data that was developed by Jiro Kawakita, who is a cultural
anthropologist. This method uses cards to help someone apply broad thinking, and it then helps them use
collective thinking by collecting the cards together and identifying relationships between them.

1)
2)
3)
4)
5)

6. References
Christopher Alexander, Sara Ishikawa, Murray Silverstein, A Pattern Language: Towns, Buildings,
Construction, Oxford University Press (1977).
Christopher Alexander, The Nature of Order, Book One – Four, The Centre for Environmental Structure(2002–2005).
Eto Koichiro, Pattern, Wiki, XP: The Timeless Way to Creation, Gijutsu-Hyohron (2009).
Takashi Iba, Iba Laboratory, Presentation Pattern: As a Creative Media, Keio University Press (2013).
Takashi Iba, Hiroshi Nakano, Koichiro Eto, Yasuto Nakanishi, Heizo Takenaka, Eiichi Hanyuda, Pattern
Language: As a Language for Creative Society, Keio University Press (2013).

−56−

Approach to Improve Driving Condition on Desert highway from Viewpoint of Road Safety
Zulpikar KERAM* and Yasuo HINO**(Received October 9, 2014)

Synopsis
Recently, the environmental problems caused by road construction and the road safety problems caused bydesert climate have been getting more and more obvious. Especially, the road safety must be the mostimportant issue against the desert whether. In this paper, the approach to improve the driving conditions ondesert roads should be proposed from viewpoint of road safety, based on reviewing major results of a seriesof studies. As a result, an appropriate idea to prevent traffic accidents caused by desert weather fromviewpoint of developing road facilities, in consideration of results of a series of studies.
KEYWORDS: Desert highway, Road safety, Desert whether, Road facility, Xinjiang Uygur
1. Introduction
In Xinjiang Uygur Autonomous Region, recently road development has progressed according to increase ofvehicles. The developing areas have been spreading to desert area from the coastal or inland area. Therefore, theenvironmental problems caused by road construction and the road safety problems caused by desert climate havebeen getting more and more obvious.
Uygur has the vast area with complicated geographical features. Then, not only the weather also must bechangeable, the abnormal weather as high temperature, storm, heavy snow, dense fog and so on must become themajor cause of traffic accidents on the desert roads. On the other hand, the provision of road safety facilities was
not yet enough on the desert road. Road safety facilities must be required to make the smoothness of traffic flow
and to prevent the traffic accidents, by consideration of weather condition as well as road and traffic condition.
Then authors have tried to reveal the influences of desert weather to occurrence of traffic accidents and the
problems to solve in concerns with road safety on desert road. Therefore, in this paper, the approach to improvethe driving conditions on desert roads should be proposed from viewpoint of road safety, based on reviewing
major results of a series of studies.
2. Influence of desert environment on traffic safety
In desert area, high temperature, dust cloud and storm in summer season and lower temperature and blizzard
must become the bad influence to road safety. Here, these whether condition were reviewed by analyzing someactual data on some desert roads in Uygur, in order to reveal the influence of these weather condition to theoccurrence of traffic accidents.
2.1 Whether in summer season1)(1) Influence of hot-arid climate
The annual mean temperature of Taklamakan Desert is 10-11℃, and the normal temperature of summer inthe desert road section is 35℃. On the other hand, the average temperature of pavement surface reaches 50-60℃,
in addition the temperature of tire surface sometimes exceed 70℃2), 3). As the high temperature weather may be acause of accidents because of increasing the damage of tires, drivers must not only maintain the tire condition but
also manage the distance of continuously driving.
(2) Influence by dust storm and black blizzard4)
It is understood that the dust cloud, dust storm and the black blizzard happen frequently in the vicinity ofthe desert road from March through September based on the report of Xinjiang Uygur Autonomous Region
Weather Bureau (Photo 1)5). Somewhere, the sand dust of visible degree (view) 10km or less is generated in thesedesert roads according to the data during ten years of the Weather Bureau. As for the black blizzard of 1km or less,* Student, Doctor Course of Dept. of Urban Engineering** Professor, Department of Urban Engineering−57−

there are seven days under the 500m or less view and 29 days under the 1km view in a year (Table 1).
Although these conditions are assumed to give the bad influence to safe driving, the safe running standard
concerning the visible degree corresponding to the desert road is not enacted in China.
Table 1Dust-sandstorm occurrence dates(1999-2008)(day)4)

Dust storm (visibility<1km)

Dust cloud (visibility<10km)

Black blizzard

Photo 1 Condition of dust storm and fling sand4)
2.2 Whether in winter season 5)(1) Influence by lower temperature
Although the accident of five months (November-March) in winter is about 30 percent, lower in comparisonof the monthly average (40 percent), drivers must take care of the slipping accident by the road surface freezing atnighttime, because of temperature change of day and night (Photo 2).
(2) Influence by snowstorm and snowfall
The drifting snow is a phenomenon that the fallen snow is blown up from the surface by grace of the wind,
and the view decreases under 50m (Photo 3). In addition, the view of the strong wind and the heavy snow might
become 10m or less. These conditions force drivers to be difficult to judge the road situation. In addition, because
the snowfall made by snowstorm reduce the road width, drivers have to try safer driving.
【drifting snow】

Photo 2 Condition of road surface freezing5)【decrease of view】

Photo 3 Drafting snow and condition of decreasing view5)(3) Major problems caused by lower temperature and fallen snow
As mentioned above, the specific winter whether condition like lower temperature and fallen snow must be−58−

causes of particular traffic accident in the north region of Xinjiang Uygur Autonomous Region. Therefore,
nevertheless the road administrator should secure a safe and smooth traffic function in winter, road safety facilities
to prevent the traffic accidents in winter have not been provided, because of the financial deficit for road extension
and technological problems for road maintenance.
In concerns of these problems, the Xinjiang Traffic Science Academy and the Hokkaido Development Pubic
Works Research Institute established the manual meeting on the road technology in winter from 2007. In near
future, these results must help to improve the road safety on desert road in winter season.
3. Influence of driving behavior and road condition
3.1 Excessive speed
The common cause of traffic accidents in both summer and winter must be the excessive speed, because oflong straight section (Table 2). Especially, the excessive speed increases the risk of accidents in the curve section.
Table 2
Car Types
Small carCargo car
Bus
Total

Condition of excessive speed

Flat sections(16:40～17:40)
G216 K495+500 80km/h
Speeding
Observed
Speeding
rate (%)
data
92
51
55.4
67
7
10.4
3
1
33.3
162
59
36.4

Slope section(15:00～16:00)
G216 K457+300 80km/h
Observed
Speeding
Speeding
data
rate (%)
69
33
47.8
48
6
12.5
5
3
60
122
42
34.4

3.2 Road condition6), 7）
The road condition as well as abnormal whether may influence to occurrence of traffic accidents. Especially,in the straight section which consists of the long part of the desert road, many accidents may occur caused byinattentive driving and speeding. And in the curve section, the fatal accidents must occur often by the combination
whether condition and speeding. As shown in Table 3, the comparison of accident rate by vehicle-distance shows
the characteristics of traffic accidents according to road conditions. From this table, it is clear that the accident rateon desert road section considerably higher than the rate of intersections in Urumqi city. Therefore, it must benecessary to establish the suitable warning signs against the excessive speed according to the road feature.
Table 3Comparison of accident frequencies according to road section7)

Section

Road condition

456～466
481～486534～539

Number of Percentage
Accidents(%)

hundred million accident rate
(number/million vehicles km)

Straight
Straight
Straight
Sub total
486～513
Bump or Curve539～545 Cross or change
Sub total

6
3
3
12
15
8
23

8.8
4.4
4.4
17.6
22
11.7
33.8

249.07124.53124.53498.13622.66332.09954.75Intersection of inner city road(mal baziri ~ kizil bayrak)

28

48.3

85.34

4. Situation and problem of road safety facilities6).
In a series of studies, although the influence of whether condition to occurring traffic accidents on the desert
roads must be revealed, the condition of establishing the road safety facilities was not considered. As some roadsafety facilities play the important role to prevent the traffic accident by giving the warning information to drivers,
the planning of setting facilities must be important issues of the desert road construction. However, the problemsof the lack of revenue because of long section of road.
Then, the survey was executed to investigate the condition of road safety facilities as the warning sign androad marks for curve section. In his chapter, some urgent issues in concern of road sign, road marks and service orparking areas to solve were shown based on the results of survey, in following sections.

−59−4.1 Road sign
It becomes clear that the rate of setting up necessary road signs and adequate road markings wererespectively 58% and 50%, in 24 sections of K261-K405 of Aral~Hotan road (Table 4). And as for road markings,
a half of them was provided as the dotted lines instead of solid lines as the central line and no overtaking line incurve and/or uneven sections. As these results were limited within onsite surveys, it must be necessary to build the
database and to realize the deepen analyses based on the data base. However, above all, some problems revealedby these surveys must be improves immediately.
Table 4
Challenges Aral~Hotan desert road Continuous music section6)
Road
signs

Number

Percentage
(%)

Road
Marking

Number

Percentage
(%)

Being
Nothing

14
10

58
42

Solid line
Dotted line

12
12

50
50

4.2 Service and parking Area
The road standard of China3) provided that the service and parking arear must be set up respectively at
50km and 10km interval on the average. Especially, in the service area, the provision of the lavatory, the gas
station and the stalls. However, there are some sections without no service area during 100km and more between
Aral and Hotan (Table 5).
Table 5Interval of service and parking area on Araru-Hotan road6)

Section of no services
hotan~tawakol
K0~K42
tawakol~kizil muna
K42~K147
kizil muna~aral
K147~K268
aral~hotan
K268~K399

Distance(km)
42
105
121
131

4.3 Communications equipment
In 70% of the 236km section of G314 and G216 which are a part of Aral~Hotan road, drivers cannot use thecommunication service because of no equipment, based on the survey in 2009(Table 6). The distance of this noservice section may be equivalent to 30% of whole section of Aral~Hotan road.
Therefore, other survey reported that it took 13 hours and more to be rescued after occurring traffic accident.
Thus, as the delay of setting up the communication equipment may occur the secondary victims, it can be said thatthe installation of the communication equipment as telephone plant of the wireless telecommunications base andcable facilities must be the pressing issue.
Table 6 Blank District of communication signals Alar~hotan desert road6)
No equipment
Section
K51~K56
K80~K96
K112~K146
K161~K214
K169~K214
K228~K293
total distance(km)Distance of noequipment(km)
5
16
20
22
34
65
162

Communication
Service
K57~K73
K74~K79
K97~K103~K111
K147~K152~K161
K184~K188~K195
K215~K227
total distance(km)Distance ofservice (km)
16
5
14
14
13
12
74

4.4 Problems of road safety facilities from viewpoint of driving characteristics 8)
The in-depth data is necessary in the research of the relations between bad weather and traffic accident.
Though in this study, some investigations of the transportation facility according to the cause of a traffic accident
in the region, the influence on drivers by bad weather in winter and summer and the problems of the lack ofcommunication equipment were referred, the relativity of the direct influence on the driver by such factors was
not able to be clarified only by the questionnaire survey result.
Then, a test of influence to drivers’ psychological and physiological condition by such factors was executedon the desert road. As a result, the risk of traffic accident may rise by two hours or more driving on the desert road
(Figure 1). That is, these results show that the traffic safety facilities on the desert road must be prepared andmaintained in consideration of the road network, road conditions, traffic situation and weather condition overall.

−60−

Driver's safety level

5. Idea and problem of traffic safety facilities improvement 9)
The road facilities of China must be planned to develop according to the Standard of Traffic Safety Facility
Design in China10). However, it is also reported that there are many risk of traffic accidents because a lot ofsections were in completed the adequate safety facilities on the desert roads. Such condition may increase thepossibility of the accidents in bad weather. Especially, the lack of communication equipment may become aserious problem which not to be able to be rescued after occurring accident.
Above all, as some important findings came out of this study, here, some concrete ideas obtained in thisstudy are summarized.
0.204
0.202
0.2
0.198
0.196
0.194
0.192
0.19
0.188
0.186
0.184

y = -0.0021x2 + 0.0058x + 0.1958
R² = 0.7241
0.5

1

1.5
2
2.5
3
Continuous driveng hour(h)3.54Figure 1 Safety driving level by driving hour8)(1) Telecommunication system
As there were many sections with no service of communication in G314 and G216 as a part of Takaramakan
and Ara-Hotan road, the environment of communication facilities has been improved, such as, the available areaof communication has been expanded to 45km after setting up of communication tower in 2009, 23 relay stations
have been introduced and the GPS systems were introduced to the long distance buses. However, in order toprevent the secondary accident and to reduce the damage, some improvement measures are necessary, as follows.
1) Provision of emergency telephone booth by 25km was essential issue.
2) Introduction of a helicopter to rescue injured persons at the serious accident must be investigated.
3) Consideration of the communication system among drivers may be desirable.
(2) Correspondence to abnormal whether condition in summer and winterIn summer, there are a lot of days that not only exceed 30℃ but also the sand storm and the sand dust are
generated around the desert road. Moreover, it is not few days with the snowstorm and snowfall in winter. Suchbad weather gives the serious influence of road safety. Then, a part of ideas and methods to improve the roadsafety facilities are described according to the report and the survey in 2009, as follows.
1) The parking and/or service area must be prepared by 15km.
2) The prevent facilities for strong wind and snowstorm must be at least set up at some specified points whichwere considered to increase risk of traffic accident.
(3) Province of communication and safety education
The safety education should be essential to understand the necessity of road safety, because the rationalityof personal behavior must be acknowledged each other even though transport modes are different. Then, as for the
influence by bad natural environment and whether of the desert area, the education with following contents may
be necessary.
1) Relation between whether condition and occurrence of accident.
2) Necessity of first aid and rescue.
3) Influence of vehicle trouble to occurrence of accident and importance of maintenance.
(4) Safety for driving on long straight section
As the driver becomes careless to road environments because of monotonous driving on the long straightsection, it is necessary to introduce some warning facilities as the high brightness road marking with lower bumps,
to warm to driver both by visual sensation and vibration.

−61−

(5) Safety against black blizzard caused by dust storm
The black blizzard caused by dust storm are generated on 1/3 of one year in the desert area section. As suchbad weather gives the bad influence to driving and may become the serious cause of accident, the drastic measures
must be introduced as soon as possible, as follows.
1) Developing the measurement equipment of eyesight and the information system of visual condition to drivers.
2) Introducing the glance guidance facilities such as delineator and luminous facilities.
3) Enforcement of education for accidental risk caused by such bad weather.
(6) Introduction of ITS to secure the safer road environment on desert roadIn order to introduce some improvements for road safety, the intelligent transport (traffic) system (ITS)
should be necessary and effective. ITS is an integrating effective road traffic system which is consisted of thecomputer processing technology, the information technology, the data communication transmission technology,
the electronic automatic control technology, as the whole traffic management system. However, to introduce the
ITS, it must be essential to develop the data base of various information concerned road and driving environment,
as well as, to develop the latest technology both of computer and telecommunication. Therefore, first of all, somedeveloped systems in some developed countries must be helpful.
6. Conclusions
Some of roads in the desert area have the long distances with the bad whether such as higher temperature,storm, snowfall and Black blizzard, as well as the complicated geographical features. On the other hand, as theprovince of road safety facilities against such bad driving conditions were insufficient, the setting up theirfacilities must be essential to prevent the traffic accidents.
In this paper, some approaches to improve the driving environment on the desert road in the near futurewere proposed, based on reviewing the major results of a series of studies concerned with the relation between
driving conditions between road and whether conditions, which were essential to consider the improvement ofroad safety facilities.
However, as there may be many issues to solve in order to realize the better driving conditions in the desert
road, the more deepen analyses will be required based on the results of this study.

7. References
1) Zulpikar KERAM and Yasuo HINO, Influences on Road Safety by Desert Weather in Uighur, Japan Society ofTraffic Engineers, Papers on Traffic Engineering, No. 31，pp. 25-28(2011) (in Japanese)
2) Xinjiang Desert Institute and Lanzhou Desert Research Institute, Comprehensive Evaluation Study of the Tarim
Desert Road Environment Influence "R", Korla, Tarim Petroleum Exploration and Development Command
Unit, 1994 (in Chinese)
3) Kerem ROZI, Liu LIHUA, Hu XINMIN, Jang Yan and Zulpikar KERAM et all, Desert Road Security Process
and Facility, Technical Report of Xinjiang Communication Science Research Institute, 2011 (in Chinese)
4) Xinjiang Bureau of Meteorology, Weather Statistics Data, 1999-2008 (in Chinese)
5) Zulpikar KERAM and Yasuo HINO, Analysis on the Influence of Winter Weather on Traffic Accidents in the
North Desert Region of UYGUR, Japan Society of Civil Engineers, Proceedings of Infrastructure Planning,
No.44, 4pages (CD-ROM) (2011) (in Japanese)
6) Zulpikar KERAM and Yasuo HINO, Review on Road Safety Facilities of Arterial Road in the Gobi Desert of
Uighur, Japan Society of Civil Engineers, Proceedings of Infrastructure Planning, No.45, 4pages(CD-ROM)(2012) (in Japanese)
7) Xinjiang Communication Science Research Institute, Road Safety Evaluation Summary Report, 2007
8) Zulpikar KERAM and Yasuo HINO, An Investigation on Accident Prevention from Viewpoint of Physiological
Change Caused By Long-time Driving and Accident Occurrence Interval on Roads at Desert Area, Japan
Society of Civil Engineers, Proceedings of Infrastructure Planning, No.50, 6pages (CD-ROM)(2014) (inJapanese)
9) Zulpikar KERAM and Yasuo HINO, An Investigation on Improvement of Road Safety Facilities to cope with
the Impact caused by Desert Climate, Traffic Science Society, Proceedings of Annual Meeting, pp.29-30 (2012)(in Japanese)
10) Design Standard of Road Safety Facilities, JTG81-2006, Vol.16, 2006 (in Chinese)−62−

Abstracts of Papers
Published in Other Journals

Mechanical and Physical Engineering
Mechanical Engineering
Effects of Introducing Solar Heat to Absorption Cooling System, -Feasibility Study of Solar Thermal
Energy Utilization to Plant FactoryNobuya NISHIMURA, Tametoshi MATSUBARA (OSAKA GAS CO.,LTD.), Hiroyuki IYOTA, Yosuke
SHIRAYANAGI and Yuuma YAMAGA
Trans.of the Jpn Soc. Refrigerating and Air Conditioning Engineers, Vol.31, No.2, pp.317-329 (2014)(in Japanese)
This paper presents the feasibility of solar thermal energy utilization to plant factory. Performance andoperation characteristics of the solar driven absorption chiller heater of 352 kilowatt refrigeration
capacity were investigated by using long term demonstration test data of June 2009 to October 2013.
Effects of solar insolation to the absorption chiller heater performance were examined by changes of air
conditioning load ratio and solar position. As a result, it was demonstrated that the COP in case ofparallel operation by solar energy and town gas becomes 20 to 50 percent higher than that case ofanother operation modes. Also, Seasonal performance of the system is calculated based on theappearance frequency (weight) of the outdoor temperature. The air-conditioning load ratio was sortedout for every outdoor temperature based on the data measured during 5 seasons from 2009 to 2013 toobtain the averaged COP value. COP takes the maximum value at the air-conditioning load ratio of 30%
and decreased at both higher and lower ratios than that.
Thermal Evaluation of a Solar Assisted Absorption Air-Conditioning System
Nobuya NISHIMURA, Tametoshi MATSUBARA (OSAKA GAS CO.,LTD.), Yosuke SHIRAYANAGI and
Yuuma YAMAGA
Proc. of Grand Renewable Energy 2014 (GRE2014) international conference, Tokyo, Jul.28-Aug.1, (onCD-ROM)
This paper presents the thermal evaluation results on a solar-assisted absorption air conditioning system of
352 kilowatt refrigeration capacity from June 2009 to October 2013. About 70 to 90 degree Celsius hot water
were made by three types of solar collectors, including two different (vacuum tube and flat plate) types.
Daily average performances about the solar collector and the absorption chiller heater were investigatedexperimentally. As a result, it was found out that the seasonal performance (IPLV) throughout the fourcooling period was 1.39, which is 12-26% larger compared to the case in which solar heat is not used.
Evaluation of Shutter Speed of Digital Cameras for Color Measurement
Hideki SAKAI and Hiroyuki IYOTA
Proceedings of the 2nd Asia Color Association Conference (ACA2014), pp.196-199 (Sep., 2014, Taipei,
Taiwan)We measured the shutter speed of digital cameras and confirmed that the indicated values of the shutter
speed of the cameras are not reliable. However, errors are systematic. It is probably caused by the fact thatthe decimal round numbers such as 3, 15 and 30 seconds are usually used as the indicated values, but inside
the computer-controlled digital cameras, the binary round numbers such as 3.2, 16 and 32 are actually usedinstead. The measured values give close agreement with these binary round numbers. In any case, themechanism of recent models' shutter, especially electrical ones, is a black box for users. Thus, the actual
values must be measured and by using these actual (corrected) values of shutter speed, we can improve thecolor measurement accuracy of digital cameras.
Development of Food Appearance Monitoring System for Oven Cooking
Taiki MATSUMOTO, Shuhei NOMURA, Hiroyuki IYOTA and Hideki SAKAI
Proceedings of the 2nd Asia Color Association Conference (ACA2014), pp.200-203 (Sep., 2014, Taipei,
Taiwan)We propose a color measurement method using a charge-coupled device (CCD) camera that can monitor awide area. A commercially available oven (steam convection oven) is used as the cooking apparatus. Toast(sliced white bread) is used as the food material. Photographic images of the food material are recorded
during oven cooking under two conditions (i.e., hot air and superheated steam). The lightness and chroma of
the food surface are analyzed from the recorded images, and their history during oven baking is applied forevaluating the color of baked food. The results show that the use of a CCD camera to measure color change−65−can optimize the cooking procedure in an oven. Further, we propose a new evaluation index based on therecorded images showing the color of baked food.
Accuracy of Color Measurement by Using Digital Cameras and the Standard Color Chart
Hideki SAKAI, Saya YOSHIKAWA and Hiroyuki IYOTA
Proceedings of the 1st Asia Color Association Conference (ACA2013), pp. 248-251 (11-14 Dec. 2013,
Thanyaburi, Thailand)
We examined five different digital cameras and evaluated their accuracies of color measurement.
Commercially available digital cameras are not intended for use in color measurement. Thus, users have tocalibrate the camera system by themselves for the purpose. We adopted the image correction method, inwhich, samples are photographed with some standard color charts side by side in one photo and thephotographed images are color-corrected using the colorimetric data of the color charts. This method has anadvantage that the measurement accuracy does not depend on the camera used; Users can freely replace thecameras. Using the X-rite ColorChecker 24-color chart as standard colors, we examined how the accuracy ofcolor measurement depends on the camera used. As a result, we showed that the expected accuracy is lessthan 5 in the CIE L*a*b* color difference unit within the color gamut of the standard colors, irrespective of
the camera.
Characterization of Baked Color of Cookie, Toast and Chicken: A Model of Light-Colored Food
Shuhei NOMURA, Hiroyuki IYOTA and Hideki SAKAI
Proceedings of the 1st Asia Color Association Conference (ACA2013), pp. 252-255 (11-14 Dec. 2013,
Thanyaburi, Thailand)
Producing delicious-looking food is one of the features required of cooking equipment. For optimizing thetechnical advantages of oven cooking, color changes of light-colored food during oven cooking werecharacterized based on time-series colorimetric data. Three types of food materials were used as samples:
toast (sliced white bread), plain cookie, and raw chicken meat pate. The colorimetric data were measured insitu using an optical fiber and a spectrometer under various conditions, with two types of steam ovens.
Prediction expressions for the chroma and lightness (quantitative attributes) history of the food surface
during oven baking were developed. The profiles of changes in the chroma and lightness for each material
and under each set of heating conditions were investigated using the measured data and calculated values.
The profiles, prediction method, and “browning index” defined in this study can be applied for optimizing
automatic oven operation using the preferences index.
A Study on Water Retention Control for a Humidity Sensor at High Temperature
T. TSUJIOKA, H. IYOTA, M. OHMORI, M. TANAKA and H. KITAMURA
Abstracts Book of Symposium on Temperature and Thermal Measurements in Industry and
Science(TEMPMEKO 2013) , p.408 (Oct. 2013, Funchal, Madeira, Portugal)
The authors develop a new prototype of the humidity sensor, using newly developed porous ceramic material
for wet-bulb temperature measurement, having a heat resistance, with suitable porosity, formed into acylindrical shape with a water supply hole. The water flow rate inside the hole is controlled by a pinch valve
between a water tank and the sensor. The valve is opened and closed by a proposed water retention control
algorithm. Suitable control algorithm is quite important, because excess water supply causes lowering the
wet-bulb temperature, resulting in a decrease in measurement accuracy. The water retention control is basedon two capacitance sensors; one is placed on the surface of the ceramic and the other is placed inside theceramic, as moisture sensors. Excess supply of water can be detected by the first capacitance sensor on thesurface, and short supply of water can be detected by the second surface capacitance sensor inside theceramic. The authors implement the proposed water retention control algorithm to a microcontroller withvalve motor drivers, thermocouple amplifiers and capacitance detection circuits. The microcontroller
monitors moisture levels by the capacitance sensors and controls the pinch valve, for increasing reliability,
for sustained long time measurement of humidity sensing at high temperature. Some experimental
evaluations of the developed humidity sensor are also made in the conditions up to 200 degrees Celsius, from0 to 100% humidity. The experimental results show the proposed water retention control is effective andsuitable for long time measurement with high accuracy and high reliability.
Wide-Range Psychrometric Chart for Improved Utilization of Superheated Steam and Humid Air
H. IYOTA, T. INOUE, J. YAMAGATA and T. TSUJIOKA
Abstracts Book of Symposium on Temperature and Thermal Measurements in Industry and−66−

Science(TEMPMEKO 2013) , p.255 (Oct. 2013, Funchal, Madeira, Portugal)
We propose a wide-range psychrometric chart using the steam mole fraction as the vertical ordinate.
Adiabatic saturated lines and the relationship among the wet-bulb, dry-bulb, and dew point temperatures of
the humid air including superheated steam were figured on the proposed chart. In addition, we compared thetheoretical adiabatic saturated temperatures with the experimentally measured wetted material temperatures.
Wetted spherical gauze was used as a wet-bulb probe for measurements in the calibrating apparatus
consisting of a boiler, an air blower, flow meters, and heaters, at temperatures ranging from 150 to 250°C,
and the steam mole fraction ranging from 0.01 (approximately room air) to 1.0 (pure superheated steam).
The results show that the steam mole fraction of the heating media including pure superheated steam can bepredicted based on wetted-material temperature measurement using the proposed chart, the maximum errorof the predicted value of the steam mole fraction was less than 0.09.
Development of a Device That Uses Steam Condensation Heat to Disinfect Rice Seeds
Takahiro NODA, Yasuyuki HIDAKA, Hiroyuki IYOTA, Toru NAKAMURA, Akihiko OCHI, Kazuhiko
SAKAI, Toshiyuki MORIKAWA, Tetsuo YABU, Jun ISOTA, Shigeru HOSHINO and Tsutomu ARIE
Book of abstracts of the 11th Conference of the European Foundation for Plant Pathology, p.88, (8-13
September 2014, Krakow, POLAND)
To increase efficiency and reduce costs associated with chemical-free, environment-friendly disinfection ofrice seeds, we developed a device that uses steam condensation heat to disinfect rice seeds. Compared to theconventional aerated steam treatment, the high-temperature and short treatment administered using thedevice can be adjusted for rice seeds. To sterilize seed-borne pathogens that mainly exist around the husk
layer and to not injure the rice kernel, which has organs necessary for seed germination, the device focusedon surface heating by steam condensation. An optimum heating condition was designed by controlling thehumidity of the heating media and regulating the heating time. Disinfection against rice seed-borne diseases
caused by bacteria, fungi, and nematodes was evaluated under the optimal condition (maximum heating
Without affecting germination). Under the optimal condition, this treatment was almost as effective as theconventional hot water treatment (60°C, 10 min). We observed that the artificial inoculation method toprepare infected seeds was greatly influenced by the extent of disinfection achieved using the physical seedtreatments. In addition, heat tolerance of naturally infected and stunted seeds was lower than that of healthy
seeds. We are currently developing a disinfection device for practical use on the basis of these findings.
Influence of Spanwise Vorticity on Dissimilarity between Turbulent Momentum and Heat Transfer
Kenji KATOH, Akira SAKAI, Ryousuke FUJII, Tatsuro WAKIMOTO and Genta KAWAHARA(Osaka
Univ.).
Trans. of Jpn Soc. Mech. Engrs., Ser. B, Vol. 79, No. 806, pp. 2019-2029 (2013) (in Japanese)
The influence of transverse vorticity on the dissimilarity between turbulent heat flux and Reynolds stress wasinvestigated by use of direct numerical simulation data for a channel flow. The theoretical relations regarding
to Reynolds stress obtained from Lagrangian momentum equation shows that the correlation v(∂p/∂x)
between wall-normal velocity v and streamwise pressure gradient fluctuation (∂p/∂x) has an important effecton the dissimilarity. The correlation v(∂p/∂x) would be negative near the transverse clockwise vortex in theflow field because v and (∂p/∂x) have a different sign to each other around the vortex. The numerical resultsof turbulent flow and temperature field demonstrate a strong correlation between the strength of dissimilarity(difference between turbulent heat flux and Reynolds stress), -v(∂p/∂x) and the transverse clockwise vorticity.
The dissimilarity would be mainly caused by the reduction of Reynolds stress near the vortex region, where
the streamwise velocity fluctuation of fluid particle is accelerated (or decelerated) on the ejection (or sweep)side due to the pressure field around the vortex. The strength of dissimilarity increases remarkably where thering-shaped vortex stands up from the wall and bends to the spanwise direction in the lag-law region.
Experimental Investigation on the Effect of Accelerating Motion of Contact Line on the Dynamic
Contact Angle
Takahiro ITO(Nagoya Univ.), Shoji HIRUTA, Ryota SHIMURA(Toyohashi Univ. of Technology), Kenji
KATOH, Tatsuro WAKIMOTO, Yasufumi YAMAMOTO(Kansai Univ.) and Susumu NODA(Toyohashi
Univ. of Technology)
Transaction of the JSME, Vol. 80, No. 809, pp. 1-12 (2014) (in Japanese)
The dynamic contact angle, the angle between the surfaces of the liquid and the solid at a moving contact
line, is one of the primary conditions for the dynamics of the liquid surface confined by solid wall. It has
been commonly modeled as a function of the velocity of the contact line relative to the solid surface under−67−

steady state condition. Some situations, such as the impact of a drop on a solid surface or sudden release of acontact line stuck on an edge of solid, however, involve a transient motion of the contact line, which would
lead to a deviation of the dynamic contact angle from the steady one. In this study, dynamic contact angle foran accelerating or decelerating contact line advancing on glass surface is measured in two experimental
systems different with other, i.e. one with a rapid meniscus formation after contact of a descending rod withthe liquid surface, and the other with accelerating advance of liquid column in a circular tube. The
experimental results revealed that the contact angle is increased with the (positive) acceleration of the contactline relative to the solid and vice versa. The critical condition for the appearance of the deviation of thecontact angle brought with the acceleration is also discussed.
Modeling of the Dynamic Wetting Behavior in a Capillary Tube Considering the Macroscopic–
Microscopic Contact Angle Relation and Generalized Navier Boundary Condition
Yasufumi YAMAMOTO(Kansai Univ.), Katsunori TOKIEDA(Kansai Univ.), Tatsuro WAKIMOTO,
Takahiro ITO (Nagoya Univ.) and Kenji KATOH
International Journal of Multiphase Flow, Vol. 59, pp. 106-112 (2014)
In this study, dynamic wetting phenomena in a capillary tube were studied by using numerical simulations
based on the front-tracking method employing the generalized Navier boundary condition (GNBC) and by
experimental measurements. For the GNBC, based on molecular dynamics simulations, the microscopic
dynamic contact angle is estimated from the grid-scale contact angle using Cox’s macroscopic–microscopic
relation. The experimentally measured correlation between the apparent dynamic contact angle and themoving velocity of the contact line is well reproduced by the present simulation technique considering Cox’s
macroscopic–microscopic relation. Thus, we found that the dynamics of wetting are well described by
combining molecular-scale behavior and macroscopic–microscopic relations.
Adhesive Force due to a Thin Liquid Film between Two Smooth Surfaces (Wringing Mechanism ofGage Blocks)
Kenji KATOH and Tatsuro WAKIMOTO
J. of JSEM, Vol. 14, Special Issue, pp. 36-41 (2014)
It is well known as the wringing phenomenon of gage blocks that a strong adhesive force appears between
two smooth surfaces when a thin liquid film is applied on the interface. A theoretical and experimental study
is conducted to discuss the wringing mechanism. The liquid film may be separated into a large number ofsmall puddles when two surfaces are rubbed together. One can expect a large adhesive force due to theresultant of surface tension acting on the circumference of each puddle. Numerical results for oil distribution
between two surfaces show that the total perimeter length of liquid film reaches 10500 m on the surface of
3cm2, which leads to 1.0×106 (N/m2) for the adhesive force. The adhesive forces measured experimentallyroughly agree with the theoretical value. A simple model is proposed to explain the adhesive force
dependence on the velocity of pulling apart two surfaces.
A Study on Removal of Infinitesimal Particles on a Wall by High Speed Air Jet(Numerical Simulation of Hydrodynamic Removal Force)
Sanghyeon SONG, Kazuhiko SOEMOTO(Shinko Co. Ltd.), Tatsuro WAKIMOTO, Kenji KATOH
J. of JSEM, Vol. 14, Special Issue, pp. 94-100 (2014)
A cleaning device equipped with a special nozzle containing triangular cavities is developed to add
high-frequency turbulence to the impinging jet flow. In order to clarify the removal mechanism of fineparticles adhered to a wall by van der Waals force, a numerical simulation is performed to estimate various
removal forces acting on the particle. Here we examine the effect of the force due to a pressure gradientfluctuation of the impinging jet on removal performance. The numerical results show that viscous drag has
the greatest influence, while the pressure gradient force is enhanced by the cavities and has a remarkableeffect on the removal of particles larger than 1.5 μm. The numerical results qualitatively correspond to thetendency of measured removal rates for 1.6 μm particles.
A study on the Removal of Infinitesimal Particles on a Wall by High-Speed Air Jet―Measurements of Adhesive Force and Particle Removal Rate―
Kenji KATOH, Sanghyeon SONG, Tatsuro WAKIMOTO and Kazuhiko SOEMOTO
Journal of Fluid Science and Technology, Vol. 9, No. 3, 13pages (2014)
We investigated the mechanism for the removal of fine particles from a solid wall using a high-speed
impinging air jet. In general, it is difficult to remove fine particles of the order of micrometers by the−68−impingement of simple air flow because they strongly adhere to the surface by van der Waals forces andremain immersed in the viscous sublayer. To overcome this, we developed high-speed air jet nozzles withtriangular cavities that add strong velocity and pressure fluctuations to the high-speed air flow. The
experimental results showed that the cavity nozzle enhances the removal performance for particles larger
than 1 μm. The effect of the pressure fluctuation induced in the jet flow on the removal performance isdiscussed from the experimental results. First, the adhesive force was measured experimentally from thecentrifugal force acting on particles with 5–25 μm diameters set on a rotating disk. Based on a simple
theoretical consideration regarding the balance of moments acting on a particle, we estimated the effects ofhydrodynamic removal forces such as drag, lift, and pressure gradient fluctuation against measured adhesive
forces. The theoretical estimation showed that drag plays a major role, and the force of the pressure gradientcould be effective for the removal of large particles. The proposed model is able to explain the experimental
results indicating that the removal rates for 3-μm-sized particles are improved by the air flow velocity
fluctuations generated by the cavity nozzle.
Effects of Surface Contamination and Cleaning with Hypochlorite Wipes on the Antibacterial Activityof Copper-Alloyed Antibacterial Stainless Steel
H. KAWAKAMI, T. HAYASHI, H. NISHIKUBO, A. MORIKAWA, S. SUZUKI (Nisshin Steel Co., Ltd.), Y.
SATO and Y. KIKUCHI
Biocontrol Sci., Vol. 19, pp. 73-78 (2014)
Effects of surface contamination and cleaning with hypochlorite wipes on the antibacterial activity ofcopper-alloyed stainless steel were studied. The antibacterial activity of copper alloyed stainless steel
decreased with the increase in the amount of surface contaminant, and the bacterial counts from specimens
contaminated with a contaminant, e.g. 1.6×10-2 μg/mm2 of bovine serum albumin, were not significantly
different from those from ordinary stainless steel specimens. The once contaminated surface could regain its
antibacterial activity when it was sufficiently wiped clean with sterile wipes loaded with sodium hypochlorite
solution.
Antimicrobiability of Cu Contained Stainless Steels
S. SUZUKI（Nisshin Steel Co., Ltd.）, K. MIYAKUSU（Nisshin Steel Co., Ltd.）, Y. SATO, Y. KIKUCHI
and H. KAWAKAMI
Tetsu-to-Hagané, Vol. 100, pp. 1021-1028 (2014) (in Japanese)
Antimicrobial ability of Cu contained stainless steels was investigated. Antimicrobial ability increased withelute fraction of Cu ion from stainless steel surface into antimicrobial test medium. It is necessary to promoteeluting fraction of Cu ion, that is, to achieve giving antimicrobial ability to Cu contained stainless steel that
sub-micron order or larger size ε-Cu phases are dispersed in stainless steel, surface of stainless steel has highelectrode potential and dissolved oxygen exist in the test medium.
Position Estimation of Small Robotic Fish Based on Camera Information and Gyro Sensors
Yogo TAKADA, Keisuke KOYAMA and Takahiro USAMI
Robotics, Vol. 3, Issue 2, pp.149-162 (2014)
Robotic fish are ideal for surveying fish resources and performing underwater structural inspections. If arobot is sufficiently fishlike in appearance and does not use a screw propeller, real fish will not be easily
surprised by it. However, it is comparatively difficult for such a robot to determine its own position in water.
Radio signals, such as those used by GPS, cannot be easily received. Moreover, sound ranging is impracticalbecause of the presence of rocks and waterweed in places where fish spend a lot of time. For practicalapplications such as photographing fish, a robotic fish needs to follow the target fish without losing
awareness of its own position, in order to be able to swim autonomously. We have developed a robotic fish
named FOCUS (FPGA Offline Control Underwater Searcher) which is equipped with two CMOS cameras
and a field-programmable gate array (FPGA) circuit board for data processing. The forward-facing camera isused to track red objects, since this is the color of the fish of interest. In addition, using visual information
obtained with the bottom-facing camera, the robot can estimate its present position. This is achieved by
performing real-time digital image correlation using the FPGA. However, until now, the position estimation
accuracy has been poor due to the influence of yaw and roll. In the present study, the position estimation
method has been greatly improved by taking into account the yaw and roll values measured using gyro
sensors.
Robotic Fish−69−

Yogo TAKADA, Keisuke KOYAMA and Takahiro USAMI
Journal of Robotics and Mechatronics, Vol. 26, No.3, Development Report, pp.391-393 (2014)
Based on our robotic fish studies since 2003, this paper introduces a FPGA offline control underwater
searcher (FOCUS) and a bream robot equipped with advanced mechanism (BREAM). The performance ofthe first FOCUS prototype, built in 2011, is now being improved. FOCUS has 2 cameras and fieldprogrammable gate arrays (FPGAs) with high arithmetic processing capabilities. The appearance of the
FOCUS is so cute. The two FOCUS types now available are an autonomous underwater vehicle (AUV) and aremotely operated vehicle (ROV). BREAM, in contrast, is an entertainment robot prototype designed for
Asutamuland Tokushima exhibition. BREAM has four joints based on analytical computational fluid
dynamics (CFD) results showing that robotic fish with multiple joints achieve better propulsion performance
than that with single joint. Two of the four joints are used for propulsion and two are used for turning theprototype. RC-FOCUS is also exhibited at Asutamuland Tokushima, together with BREAM.
Improving Accuracy of Acoustic Source Localization in Anisotropic Plates
Hayato NAKATANI, Tribikram KUNDU and Nobuo TAKEDA
Ultrasonics, Vol. 54, No. 7, pp. 1776-1788 (2014)
The acoustic source localization technique for anisotropic plates proposed by the authors in an earlier
publication (Kundu et al., Ultrasonics, 52, pp.740-746, 2012) is improved in this paper by adopting somemodifications. The improvements are experimentally verified on anisotropic flat and curved composite plates.
Difficulties associated with the original technique were first investigated before making any modification. It
was noted that the accuracy of this technique depends strongly on the accuracy of the measured timedifference of arrivals (TDOA) at different receiving sensors placed in close proximity in a sensor cluster. The
sensor cluster is needed to obtain the direction of the acoustic source without knowing the material propertiesof the plate. Two modifications are proposed to obtain the accurate TDOA. The first one is to replace therecorded full time histories by only their initial parts – the first dip and peak – for the subsequent signal
processing. The second modification is to place the sensors in the sensor cluster as close as possible. It isshown that the predictions are improved significantly with these modifications. These modifications are thenapplied to another sensor cluster based technique called the beamforming technique, to see if similar
improvements are achieved for that technique also with these modifications.
Mechanical Properties in Quasi-Isotropic CFRP Laminates with Small Ply Orientation Angle
Mismatch
Hayato NAKATANI, Nurul Nabihah A. HAMID and Shinji OGIHARA
Proc. of the Japan International SAMPE Symposium and Exhibition (JISSE-13), Nagoya, Japan, Nov. 11-13,
paper No. 1401 (USB Memory) (2013)
Mechanical properties and damage behaviour are evaluated for the quasi-isotropic (QI) laminates with fibreorientation angle mismatch of 15° (15QI) and the conventional QI laminates with 45° mismatch (45QI) madeby using thin prepregs under in-plane tensile, out-of-plane indentation and impact loading. Compared to thedirection dependent tensile strength of the 45QI, the 15QI laminates show nearly isotropic tensile strength
because fibre strength effectively contributes to the tensile strength under suppressed delamination which isdue to the low interlaminar shear stress derived by small fibre mismatch and suppressed matrix cracking
achieved by the thin ply. Localized damage has been exhibited in the 15QI laminates under out-of-plane
indentation and drop-weight impact, however absorbed energy during the impact event is comparable
between the 15QI and the conventional 45QI laminates. The isotropy in tensile strength and the localized
damage under out-of-plane loading achieved by the QI laminates with small fibre orientation mismatch canoffer us a large variety of structural designs of composites.
Effect of Distribution Media on Resin Flow during VaRTM Process for FRPs
Hayato NAKATANI, Kentarou ADACHI and Katsuhiko OSAKA
Proc. of the 16th U.S.-Japan Conference on Composites Materials, San Diego, CA, USA, Sep. 8-10, Paper
No. 726 (CD-ROM 12-pp.) (2014)
Multipoint measurements for resin flow during vacuum assisted resin transfer molding (VaRTM) process forfibre reinforced polymer composites are carried out by using embedded fibre optic sensors. These sensors
monitor changes in intensity of Fresnel reflected light at the end of optical fibres due to the arrivals of resin.
The resin flow in fibre preform is divided into two main flows; one is in-plane flow where resin proceeds infibre preform directly from resin inlet, and the other is out-of-plane flow where resin is infused into fibre−70−

preform in through-thickness direction via a distribution medium that is incorporated into the preform as asurface layer. By simultaneously infusing epoxy resin into two glass fibre preforms with or without a
distribution medium that are separated by a plastic film and stacked together, time of arrivals of the resin
flow in each fibre preform are obtained from output changes of fibre optic sensors. Flow rate of resin in eachpreform is calculated from the time difference of arrivals. The flow rate in the preform with the distribution
medium is related to resin amount impregnated both in in-plane and out-of-plane flow in contrast to only inin-plane flow for that without the medium. By subtracting the resin amount infused only through in-planeflow from that contains two flows, the amount from the out-of-plane flow can be evaluated. Ratio ofimpregnated resin amount through out-of-plane / in-plane flow is also calculated at different measured
regions. As a result, the out-of-plane flow via the distribution medium is found to be dominant especially atoutlet side of the resin flow. Further investigations using multiple distribution media are also carried out.
Impact Induced Damage in CFRP / Thin Titanium Films Hybrid Laminates
Hayato NAKATANI, Yuhei NEKOSHIMA and Shinji OGIHARA
Proc. of the 11th International Conference on Durability Analysis of Composite Systems (DURACOSYS-2014),
Tokyo, Japan, Sep. 15-17, Paper No. Or07 (USB memory), (2014)
Fibre-metal laminates (FMLs) that consist of carbon / epoxy composites and thin titanium films are subjected
to drop-weight impact to assess their improved damage tolerance ability compared to that of conventional
carbon / epoxy composite laminates. The thin titanium films 50 μm in thickness used here are expected to
not show their strength but suppress damage propagation in the composites by their existence during theimpact loading. Hence volume fraction of metal layer in the hybrid laminates is suggested to be less than
10 %. The low velocity impact tests are conducted for the CFRP / thin titanium films hybrid laminates[45/0/Ti/-45/90]2S using a drop-weight tower under impact energy of 4, 6, 8, 10, 14 and 16 J/mm. The
maximum load during the impact event increases linearly with applied impact energy before they reach aplateau with more than 10 J/mm of impact energy. Higher level of the plateau for the hybrid laminatescompared to the CFRP laminates indicates their excellent load capacity without suffering severe damage. Bycross-sectional observation, crack propagation in the hybrid laminates is found to be suppressed by thetitanium films as opposed to the through-thickness cracking in the CFRP laminates. It is also shown thatlower densities of matrix cracking and fibre breakage are achieved for the hybrid laminates. Interfacialdelamination between CFRP plies and titanium films is considered to absorb the impact energy, this results indamage suppression in CFRP plies.
Effects of Initial Stresses on Piezoelectric Properties of PZT Disks Analyzed by Nonlinear
Electroelastic Theory
Naoki TAKAI, Shinya MOTOGI and Tomohiro YAMASAKI
Trans. Jpn. Soc. Mech. Eng., Ser. A, Vol.79, No.807, pp.1632-1647 (2013)(in Japanese)
The effects of applied stresses on dynamic characteristics of piezoelectric ceramics are analyzed based on the
nonlinear electroelastic theory. Piezoelectric ceramics are used in many electric devices as functional
elements, where mechanical constraint is usually applied. Estimation of piezoelectric properties underapplied stresses is important in designing the devices. However, applied stresses cannot be considered in
the basic equations in the linear piezoelectric theory, and the effects of the applied stresses cannot be
predicted. In this study, we introduce additional terms related to the dissipation effects, specifically, electric
conduction and internal viscosity resistance, and nonlinearity of elastic properties into electroelastic theory.
As well, considered nonlinear effects are elastic, piezoelectric and dielectric constants up to 3rd order.
Frequency dependence of admittance of PZT disks is measured under applied compressions, showing thatapplied stresses have certain influences on either of thickness and radial vibrations of PZT. Assuming
proper material constants, experimental results can be well explained by the nonlinear electroelastic theory.
Relationship between Composition Gradient and Microhardness in Ni-Cu Alloy Films Fabricated byElectrodeposition
Y. KANEKO and K. UEMORI
Functionally Graded Mater., Vol. 27 pp.50-56 (2013)
Vickers microhardness of composition-gradient Ni-Cu alloy films having different gradients was measured.
The composition-gradient films were fabricated by electrodeposition technique. Since content ofelectrodeposited Ni-Cu alloy depends on applied electrochemical potential, production of thecomposition-gradient microstructure is achieved by changing the potential continuously. By stacking thecomposition-gradient layers with positive and negative gradients alternately, we obtained relatively thick−71−

Ni-Cu films having high composition gradient. In the present study, two kinds of the Ni-Cu films with thegradients dc/dx of 310-3nm-1 and 1.210-2nm-1 were prepared. Vickers microhardensses of the films with
dc/dx=310-3nm-1 and 1.210-2nm-1 were Hv167 and Hv277, respectively. To understand the increase in thehardness, we estimated misfit dislocation density from the values of the composition gradients. In thethree-dimensional dislocation model, the dislocation densities of these films were estimated to be
6.11014m-2 and 2.41015m-2. These dislocation densities are consistent with the hardness values, assumingthat strength of the composition-gradient Ni-Cu films owes to dislocation hardening.
EBSD Analysis of Microstructure Evolution of Pure Iron Subjected to Sliding Wear and Related
Change in Vickers Microhardness
Y. KANEKO and T. SUGIMOTO
Mater.Trans., Vol.55, pp. 85-92 (2014)
Sliding wear tests were carried on pure iron to investigate evolution of microstructure below worn surface.
After the wear tests, grain boundary formation and lattice rotation were analyzed with electron backscatter
diffraction (EBSD) method. In the vicinity of the worn surface, submicron grains separated by high-angle
grain boundaries were generated. Below the submicron grain region, dominant microstructures were twokinds of low-angle grain boundaries which were horizontal and inclined to the worn surface, respectively. At
deeper area from the worn surface, continuous lattice rotation was detected. To correlate the microstructureand strength, Vickers microhardness was measured over a cross section of the wear-affected zone. In thesubmicron grain and the low-angle grain boundary regions, the microhardness was proportional to thereciprocal square root of boundary spacing. In the lattice rotation region, we calculated
geometrically-necessary (GN) dislocation density from gradient of lattice rotation. The microhardness value
in the lattice rotation region showed good correlation with the square root of the GN dislocation density.
Low-Cycle Fatigue of Fe-20%Cr Alloy Processed by Equal-Channel Angular Pressing
Y. KANEKO, R. TOMITA and A. VINOGRADOVIOP Conf. Series: Mater.Sci.Eng., Vol. 63, pp.012160 (2014)
Low-cycle fatigue properties were investigated on Fe-20%Cr ferritic stainless steel processed by equal
channel angular pressing (ECAP). The Fe-20%Cr alloy bullets were processed for one to four passes via
Route-Bc. The ECAPed samples were cyclically deformed at the constant plastic strain amplitude εpl of
5×10-4 at room temperature in air. After the 1-pass ECAP, low-angle grain boundaries were dominantly
formed. During the low-cycle fatigue test, the 1-pass sample revealed the rapid softening which continued
until fatigue fracture. Fatigue life of the 1-pass sample was shorter than that of a coarse-grained sample.
After the 4-pass ECAP, the average grain size reduced down to about 1.5 μm. At initial stage of the low-cycle
fatigue tests, the stress amplitude increased with increasing ECAP passes. At the samples
processed for more than 2 passes, the cyclic softening was relatively moderate. It was found that fatigue lifeof the ECAPed Fe-20%Cr alloy excepting the 1-pass sample was improved as compared to thecoarse-grained sample, even under the strain controlled fatigue condition.
Micro-, Meso- to Macroscopic Modeling of Deformation Behavior of Semi-Crystalline Polymer
M. UCHIDA and N. TADA
Int. J. Plasticity, Vol. 49, pp. 164-184 (2013)
To represent the elasto-viscoplastic deformation behavior of semi-crystalline polymer (SCP), which has acomplicated hierarchical structure, a micro-, meso- to macroscopic computational model was developed. A
laminar composite model and FE-based homogenization method were used to relate the mechanicalbehaviors in micro- to mesoscopic andmeso- to macroscopic scales of the material. Using the proposed model, elasto-viscoplastic deformation
behaviors of high density polyethylene under several macroscopic boundary conditions werecomputationally investigated. Material’s parameters used in the constitutive equations for microstructure of
SCP were defined by fitting the calculated stress–strain relation into the experimental data. Then, the effects
of deformation mode and crystallinity on deformation behavior of SCP were investigated. Obtained stress–
strain relations represented the experimentally observed characteristics such as an anisotropic strain
hardening rate depending on the deformation mode and an increase in the Young’s modulus and the flow
stress with the crystallinity. Then, the neck propagation process in the uniaxial tension with different strain
rate was investigated. The present model represented a development of macroscopic non-uniform
deformation characterized by the mechanical response of micro- to mesoscopic deformation.

−72−

Establishment of Deformation Simulation Procedure by Finite Element Method Based on
Second-Order Homogenization Using Characteristic Displacement Function for Macroscopic Strain
Gradient
M. UCHIDA and N. TADA
Trans. Jpn. Soc. Mech. Eng., Ser. A, Vol.79, No.806, pp. 1486-1503 (2013)
To evaluate effect of a relative scale of microstructure to macrostructure, a simulation procedure using
second-order homogenization based finite element method was proposed. In this method, a microscopic
characteristic displacement function for macroscopic strain gradient was added to the conventional first orderhomogenization method. Then, a procedure to solve a macroscopic boundary problem was established basedon the principle of virtual work in macroscopic scale represented by the microscopic characteristic
displacement function. To validate the proposed second-order homogenization method, computational
simulations of deformation behavior of cavitated rubber (void) blended amorphous polymer were performed
using the proposed second-order homogenization. From the result of bending deformation where tension orcompression was given to upper side or lower side of the macroscopic model, the material containing larger
void required a larger energy for the bending of the model. With decrease in the void size, the energy
converged to that predicted by first-order homogenization method. Basically, the deformation behavior
predicted by proposed homogenization model was qualitatively and quantitatively similar to that predictedby full scale model. The proposed model is expected to be applied for computational prediction of thescale-dependent deformation in various cases because the model does not limit the form of constitutive
equation, shape of the unit cell and deformation mechanisms and structure of the material.
Non-Destructive Detection of Crack in HDPE Plate by Nanometric Change in Surface Profile
N. TADA, M. UCHIDA and Y. MATSUKAWA
Proc. ASME PVP2013, pp. PVP2013-97732 (2013)
When a mechanical load is given to a cracked material, an undulation appears in surface profile around thecrack. The undulation is caused by stress-strain concentration at the crack tip and its release near the crack
center. If the load is very small and within the elastic deformation range, the material recovers the original
shape after unloading and no damage remains. Therefore, this surface undulation by a small mechanical load
can be used for detection of crack on the material surface. In this study, non-destructive crack detection
method by nanometric change in surface profile is proposed, and the experiment and related finite element
analyses were carried out for notched high-density polyethylene (HDPE) plates. Nonuniform height change
by a small mechanical load around the notch on the surface of HDPE plate was measured by a laser scanningmicroscope. The height change distribution agreed with the analytical result.
Thermodynamic Analysis using First-Principles Calculations of Phases and Structures of
LixNi0.5Mn1.5O4 (0≦x≦1)
Ippei KISHIDA , Kengo ORITA, Atsutomo NAKAMURA and Yoshiyuki YOKOGAWA
Journal of Power Sources, Vol. 241, pp. 1-5 (2013)
LiNi0.5Mn1.5O4, which has a spinel framework structure, is a promising candidate for the cathode material of
next-generation lithium-ion batteries with high energy density. We investigate the structural transition in
LixNi0.5Mn1.5O4 (0≦x≦1) through first-principles calculations using the projector augmented wave methodwith the generalized gradient approximation. We calculate all the unique Li-site occupation configurations ina unit cell to obtain the total energies and the most stable structures for various compositions.
Thermodynamic analysis shows that Li0.5Ni0.5Mn1.5O4 with x=0.5 is the only stable phase for 0 < x < 1. The
decomposition energy is lower than 0.1 eV for 0 < x < 0.5, but is distinctly higher for 0.5 < x < 1. The
decomposition energy reaches 0.39 eV at x=0.75. The ratios of the structures at room temperature arecalculated from Boltzmann factors by using the energy differences between structures. The crystal structureof the unit cell changes gradually from x = 0 to 0.5, but changes markedly from x = 0.5 to 1. This
first-principles study provides a general evaluation of the variation in the crystal structure with thecomposition of the bulk material, which affects the cyclability of the electrode.

−73−Applied Mathematics
Backward Uniqueness for Heat Equations with Coefficients of Bounded Variation in Time
Shigeo TARAMA
Electron. J. Diff. Equ., Vol. 2013, No. 189, pp. 1-14 (2013)
We consider heat equations with bounded coefficients satisfying Lipschitz condition with respect to spacevariables. We show, by using Carleman estimates, the backward uniqueness under the condition thatcoefficients are of bounded variation in the time variable, where we consider coefficients as functions of thetime variable with values in the space of uniformly bounded continuous functions of space variables.

−74−

Physical Electronics and Informatics
Applied Physics and Electronics
Effects of thermal annealing process on the electrical properties of p+-Si/n-SiC heterojunctions
J. LIANG, S. NISHIDA, M. ARAI (New Japan Radio Co. Ltd.), and N. SHIGEKAWA
Appl. Phys. Lett., 104, 161604 [4 pages] (2014).
The effects of thermal annealing process on the interface in p+-Si/n-SiC heterojunctions fabricated by using
surface-activated bonding are investigated. It is found by measuring their current-voltage (I-V) characteristics thatthe reverse-bias current and the ideality factor decreased to 2.98106 mA/cm2 and 1.03, respectively, by annealing
the junctions at 1000 °C. Observation by using transmission electron microscopy indicates that an amorphouslayer with a thickness of 6 nm is formed at the unannealed interface, which vanishes after annealing at 1000 °C.
No structural defects at the interface are observed even after annealing at such a high temperature.
Fabrication of nitride/Si tandem cell structures with low environmental burden by surface activatedbonding
N. SHIGEKAWA, J. LIANG, N. WATANABE (NTT Photonics Laboratories), and A. YAMAMOTO (Univ. of
Fukui)
Phys. Status Solidi C, 11, No. 3–4, pp. 644–647 (2014).
Group-III nitride on Si tandem solar cell structures, which are free from materials with high impacts onthe
environment such as group-III arsenides or phosphides, were successfully fabricated using the surface activatedbonding of nitride-based sub cells, which had been grown on (0001) GaN substrates, and (111) Si based sub cells.
The backsides of the GaN substrates had been polished and their averaged roughness was smaller than 1 nm prior
to bonding. The open-circuit voltage (VOC) of the tandem cells was almost equal to the sum of VOC of therespective sub cells, while the conversion efficiency was limited by the properties of the nitride-based top cells.
Nitride-on-(100) Si tandem cells were also fabricated and the enhancement in VOC was observed.
I-V characteristics in Surface-Activated Bonding (SAB) based Si/SiC junctions at raised ambient
temperatures
S. NISHIDA, J. LIANG, M. MORIMOTO, N. SHIGEKAWA, and M. ARAI (New Japan Radio Co., Ltd.)
Materials Science Forum, 778-780, pp. 718-721 (2014).
The physical and electrical properties of p+-Si/n-4H-SiC and n+-Si/n-4H-SiC heterojunctions fabricated by using
surface-activated bonding (SAB) were investigated by scanning electron microscopy (SEM), current-voltage (I-V)
and breakdown characteristics measurements at raised ambient temperatures. The I-V characteristics for thereverse bias voltages of the two junctions were compared with the expectations based on Frenkel-Poole, andtrap-assisted tunneling models. The results of calculations using the trap-assisted tunneling model were close to
the measurements.
Surface-activated-bonding-based InGaP-on-Si double-junction cells
N. SHIGEKAWA, M. MORIMOTO, S. NISHIDA, and J. LIANG
Jpn. J. Appl. Phys., 53, 04ER05 [4 pages] (2014).
InGaP-on-Si double-junction cells were fabricated by the surface activated bonding of InGaP-based top cell layersgrown on GaAs substrates to Si-based bottom cells and the selective etching of GaAs substrates. The open-circuit
voltage of the double-junction cells in the tandem operation was close to the sum of the open-circuit voltages of
the top and bottom cells. The efficiency in the tandem operation of the n-on-p InGaP/(100)-Si double-junction
cells was higher than the efficiencies of the respective subcells.
Demonstration of Nitride-on-Phosphide Hybrid Tandem Solar Cells by Using Surface-Activated Bonding
N. SHIGEKAWA, J. LIANG, and N. WATANABE (NTT Photonics Laboratories)
Proc. 39th IEEE Photovoltaic Specialists Conference, pp. 2470-2473 (2013).
Group-III nitride-on-phosphide hybrid tandem solar cells were fabricated using surface-activated bonding. The
bottom surface of nitride top cells grown on GaN substrates was bonded on the top surface of InGaP-based bottom
cells grown on n-GaAs substrates. Their tandem-cell operation was successfully demonstrated by confirming thatthe open-circuit voltage (VOC) of tandem cells was enhanced. It was also found that the electrical properties of thebonding interface do not induce fatal effects on the performance of the tandem cells.
Phase separation of thick (>1 μm) InxGa1-xN (x > 0.3) grown on AlN/Si(111): Simultaneous emergence of−75−

metallic In–Ga and GaN-rich InGaN
A. YAMAMOTO (Univ. of Fukui), Md. T. HASAN (Univ. of Fukui), A. MIHARA (Univ. of Fukui), N.
NARITA (Univ. of Fukui), N. SHIGEKAWA, and M. KUZUHARA (Univ. of Fukui)Appl. Phys. Express, 7, 035502 [4 pages] (2014).
0.3–2-μm-thick InxGa1-xN (x > 0.3) films are grown at 650 °C on AlN/Si(111) substrates by metal organic vapor
phase epitaxy. When the thickness of an epitaxial InGaN film exceeds >1 μm, peaks of GaN-rich InGaN(0002)
and metallic In(101) appear in the X-ray diffraction profiles. The InN composition >0.03 in the GaN-rich InGaN
film is in agreement with the solubility of InN in GaN at 650 °C. The metallic In contains a small amount (>0.03
at. %) of Ga. These results clearly show that the epitaxial InGaN film is phase-separated into GaN-rich and
InN-rich InGaN. The latter is changed into metallic In–Ga owing to its thermal instability at 650 °C.
Output characteristics of piezoelectric lead zirconate titanate detector using high-energy heavy-ion beam
S. TAKECHI, M. SEKIGUCHI, T. MIYACHI (Chiba Institute of Technology), M. KOBAYASHI (Chiba
Institute of Technology), M. HATTORI (Tokyo Institute of Technology), O. OKUDAIRA (JAXA), H. SHIBATA(Osaka University), M. FUJII (Famscience), N. OKADA (Honda Electronics), T. MURAKAMI (NIRS), and Y.
UCHIHORI (NIRS)
Nucl. Instrum. Methods Phys. Res., Sect. A Vol. 737, pp. 52-55 (2014).
A radiation detector fabricated using piezoelectric lead zirconate titanate (PZT) has been studied by irradiating itwith a 400 MeV/n xenon (Xe) beam. The beam diameter was controlled to change the irradiation conditions. It
was found that the magnitude of the output observed from the PZT detector may be related to the number of Xeions per unit area per unit time within the limits of the experimental conditions.
Variation in resonant frequency of piezoelectric lead–zirconate–titanate element undergoing high-level
radiation
M. KOBAYASHI (Chiba Institute of Technology), T. MIYACHI (Chiba Institute of Technology), S. TAKECHI,
T. MITSUHASHI, Y. MIURA, H. SHIBATA (Osaka University), N. OKADA (Honda Electronics), M.
HATTORI (Tokyo Institute of Technology), O. OKUDAIRA (JAXA), M. FUJII (Famscience), T. MURAKAMI(NIRS), and Y. UCHIHORI (NIRS)
Jpn. J. Appl. Phys. Vol. 53, 066602 (6 pages) (2014).
A piezoelectric lead–zirconate–titanate (PZT) element was exposed to a 400MeV/n xenon beam and the radiation
effect on the element was studied as a variation of resonant and antiresonant frequencies by the resonance method.
A possible effect of heating the element on the resonant frequency was avoided by using data obtained while thetemperature of the element was kept constant. Consequently, the variation of the resonant frequency was
empirically represented by a simple function of the amount of accumulated energy in the element. We therefore
discuss the piezoelectric PZT element as a potential detector for high-level radiation. We point out that apiezoelectric equation including the heat term is required to explain the experimental results.
Effects of annealing on GaAs/Si bonding interfaces for hybrid tandem solar cells
L. CHAI, J. LIANG, S. NISHIDA, M. MORIMOTO, and N. SHIGEKAWA
Abstract of 2014 IEEE International Workshop on Low Temperature Bonding for 3D Integration, p. 51 (2014).
DOI: 10.1109/LTB-3D.2014.6886190
Effects of annealing on bonding interfaces of III–V-on-Si hybrid tandem solar cells were investigated. We
observed amorphous layer at the interfaces prior to the annealing. We also investigated the effects of the annealingon the current-voltage characteristics of n+-GaAs/n++-Si and p+-GaAs/n++-Si junctions.
Annealing temperature dependence of SAB based Si/Si junctions
M. MORIMOTO, J. LIANG, S. NISHIDA, L. CHAI, K. TAKEMURA, AND N. SHIGEKAWA
Abstract of 2014 IEEE International Workshop on Low Temperature Bonding for 3D Integration, p. 52 (2014).
DOI: 10.1109/LTB-3D.2014.6886191
Effects of annealing on SAB based Si/Si junctions were investigated by TEM observation and current-voltage (I–V) measurement. We observed amorphous like layer at the Si/Si interface prior to the annealing, which seemed tovanish after the annealing at 1000 °C. The I–V characteristics of Si/Si junctions showed that the current decreased
when the junctions were annealed at comparatively lower temperatures. The current increased when the junctions
were annealed at higher temperatures.
Investigation on the effects of annealing process on the electrical properties of n+-Si/n-SiC junctions
J. LIANG, S. NISHIDA, T. HAYASHI, M. MORIMOTO, N. SHIGEKAWA, AND M. ARAI (New Japan Radio−76−

Co., Ltd.)
Abstract of 2014 IEEE International Workshop on Low Temperature Bonding for 3D Integration, p. 53 (2014).
DOI: 10.1109/LTB-3D.2014.6886192
The effects of annealing process on the electrical properties of n+-Si/n-SiC junctions fabricated by using
surface-activated bonding are investigated. It is found by measuring their current-voltage (I–V) characteristics thatthe reverse-bias current decreases and activation energy increases with increasing annealing temperature to
700 °C.
Annealing characteristics of p+-Si/n-4H-SiC junctions by using surface-activated bonding
S. NISHIDA, J. LIANG, T. HAYASHI, M. MORIMOTO, N. SHIGEKAWA, and M. ARAI (New Japan Radio
Co., Ltd.)
Abstract of 2014 IEEE International Workshop on Low Temperature Bonding for 3D Integration, p. 54 (2014).
DOI: 10.1109/LTB-3D.2014.6886193
The effects of annealing on p+-Si/n-4H-SiC heterojunctons fabricated by using surface-activated bonding (SAB)
were investigated by current-voltage (I–V) and capacitance-voltage (C-V) measurements. I–V characteristics were
improved and the flat-band voltages extracted from C-V characteristics were smaller by annealing at higher
temperatures.
Fabrication and characterization of Si/10-μm mesa-etched Si junctions by surface activated bonding
K. TAKEMURA, M. MORIMOTO, S. NISHIDA, J. LIANG, and N. SHIGEKAWA
Extended Abstract of 2014 IEEE International Meeting for Future of Electron Devices, Kansai (IMFEDK) [2pages] (2014), DOI: 10.1109/IMFEDK.2014.6867078
Si/mesa-etched Si p-n junction was fabricated by the reactive ion etching and the surface activated bonding. The
SEM observation of their cross section indicated that the height of the mesa was approximately 13 μm. Theircapacitance-voltage and current-voltage characteristics were also measured.
Improvement in electrical properties in SAB-based n+-Si/n-4H-SiC junctions by annealing
T. HAYASHI, J. LIANG, S. NISHIDA, M. MORIMOTO, N. SHIGEKAWA, andM. ARAI (New Japan Radio
Co., Ltd.)
Extended Abstract of 2014 IEEE International Meeting for Future of Electron Devices, Kansai (IMFEDK) [2pages] (2014), DOI: 10.1109/IMFEDK.2014.6867070
The effects of annealing on n-Si/n-4H-SiC junctions made by the surface activated bonding were investigated.
Both the forward and reverse characteristics were improved by annealing at higher temperatures.
Electrical properties of Si/Si interfaces by using surface-activated bonding
J. LIANG, T. MIYAZAKI, M. MORIMOTO, S. NISHIDA, and N. SHIGEKAWA
J. Appl. Phys. Vol.114, 183703 [6 pages] (2013).
Electrical properties of n-Si/n-Si, p-Si/n-Si, and p--Si/n+-Si junctions fabricated by using
surface-activated-bonding are investigated. The transmission electron microscopy/energy dispersive X-ray
spectroscopy of the n-Si/n-Si interfaces reveals no evidence of oxide layers at the interfaces. From thecurrent-voltage (I-V) and the capacitance-voltage (C-V) characteristics of the p-Si/n-Si and p--Si/n+-Si junctions,
it is found that the interface states, likely to have formed due to the surface activation process using Ar plasma,
have a more marked impact on the electrical properties of the p-Si/n-Si junctions. An analysis of the temperaturedependence of the I-V characteristics indicates that the properties of carrier transport across the bonding interfaces
for reverse-bias voltages in the p-Si/n-Si and p--Si/n+-Si junctions can be explained using the
trap-assisted-tunneling and Frenkel-Poole models, respectively.
Band structures of Si/InGaP heterojunctions by using surface activated bonding
J. LIANG, M. MORIMOTO, S. NISHIDA, and N. SHIGEKAWA
Phys. Status Solidi C Vol. 10, No. 11, pp. 1644–1647 (2013).
The band structure of p-Si/n-InGaP heterojunctions fabricated by using surface-activated bonding (SAB) wasinvestigated by measuring their current-voltage (I-V) and capacitance-voltage (C-V) characteristics. The I-V
characteristics of p-Si/n-InGaP junctions showed rectifying properties similarly to p-Si/n-GaAs junctions. The
conduction band discontinuity of the p-Si/n-InGaP junctions was determined to be 0.41 eV from C-V
measurements, which indicated that the Si/InGaP junctions revealed the type-I band line-up in contrast to the
Si/GaAs junctions.

−77−Marked suppression of In incorporation in heavily Si-doped InxGa1−xN (x~0.3) grown on
GaN/α-Al2O3(0001) template
A. YAMAMOTO (Univ. of Fukui), A. MIHARA (Univ. of Fukui), N. SHIGEKAWA, and N. NARITA (The
Kansai Electric Power Co.)
Appl. Phys. Lett., 103, 082113 [4 pages] (2013).
InxGa1-xN (x~0.3) films doped with Si up to 1022cm-3 are grown on GaN/α-Al2O3(0001) templates by themetal-organic vapor phase epitaxy using monomethylsilane (MMSi) as a Si source. The In composition in InGaN
is markedly decreased with increasing MMSi flow rate; In compositions are 0.32 and 0.12 for 0 and 4.3 mol/min
flow rates, respectively. The sum of concentrations of Si and In in InGaN is independent on MMSi flow rate and
the Ga incorporation is not affected by the Si doping, suggesting that Si atoms are preferably incorporated into
sites where In atoms should be incorporated.
Surface-activating-bonding-based low resistance Si/III-V junctions
J. LIANG, S. NISHIDA, M. MORIMOTO, and N. SHIGEKAWAIEE Elec. Lett., Vol. 49 (13) pp. 830-832 (2013).
The electrical properties of pn junctions, with various semiconductor materials with different doping
concentrations fabricated by using surface-activated-bonding (SAB), were investigated by measuring theircurrent-voltage (I-V) characteristics. The I-V characteristics of p+-GaAs/n++-Si, p+-GaAs/n+-Si, p+-Si/n+-Si,
p++-Si/n+-InGaP, and p+-Si/n+-InGaP junctions showed ohmic-like properties. The interface resistance and theresultant electrical loss decreased with increasing impurity concentration at the interface. These results
demonstrate the significance of SAB for fabricating tandem solar cells.
A Comparative Study on Metalorganic Vapor Phase Epitaxial InGaN with Intermediate In Compositions
Grown on GaN/Sapphire Template and AlN/Si(111) Substrate
A. YAMAMOTO (Univ. of Fukui), A. MIHARA (Univ. of Fukui), Y. ZHENG (Univ. of Fukui), and N.
SHIGEKAWA
Jpn. J. Appl. Phys., Vol. 52 08JB19 [4 pages] (2013).
The growth of InGaN with intermediate In compositions on GaN/sapphire template and AlN/Si(111) substrate has
been comparatively studied. By using an metalorganic vapor phase epitaxy (MOVPE) system with a horizontal
reactor, InGaN films are grown at a temperature of 600–800 ºC in the pressure of 150 Torr. By optimizing growthtemperature and trimethylindium/(trimethylindium + triethylgallium) molar ratio, single crystalline InxGa1-xN withx = 0-1 are successfully grown on both substrates. The films grown at a relatively high temperature (700 ºC)
with In compositions of 0.3 or less show phase separation when their thickness exceeds a critical value (0.25–0.4m), while the samples grown at 600 ºC with In compositions of 0.35–0.5 show no phase separation even if the
thickness is increased to 0.7 m. To evaluate the crystalline quality of grown films, FWHM of X-ray rocking
curve (XRC) for InGaN(0002), tilt, is measured. There is no marked difference in tilt data between films grown
on GaN/α-Al2O3(0001) and AlN/Si(111). For the samples grown at 600 ºC with In contents of 0.35–0.5, tilt data
are drastically increased and widely scattered suggesting the existence of important unknown parameters thatgovern crystalline quality of InGaN grown at a relatively low temperature.
Observation of Negative Differential Resistance in a GaN/AlGaN/GaN: Possible Tunneling Junction Using
Polarization
N. WATANABE (NTT Photonics Laboratories), H. YOKOYAMA (NTT Photonics Laboratories), and N.
SHIGEKAWA
Jpn. J. Appl. Phys., Vol. 52 08JN03 [3 pages] (2013).
We report an anomalous current–voltage behavior in an n-type GaN/undoped InGaN/undoped GaN/undoped
AlGaN/n-type GaN diode grown by metalorganic chemical vapor deposition. The tunneling-junction-like bandprofile of the undoped GaN/undoped AlGaN/n-type GaN (GAG) structure is formed by a spontaneous and piezo
polarization effect. We observe negative-differential resistance (NDR) behavior in the diode with the GAG
structure. The NDR behavior suggests a possible tunneling junction consisting in the GAG structure.
MOVPE growth of InxGa1-xN (x~0.5) on Si(111) substrates with a pn junction on the surface
A. YAMAMOTO (Univ. of Fukui) A. MIHARA (Univ. of Fukui), D. HIRONAGA (Univ. of Fukui), K. SUGITA(Univ. of Fukui), A. G. BHUIYAN (Univ. of Fukui), A. HASHIMOTO (Univ. of Fukui), N. SHIGEKAWA, and
N. WATANABE (NTT Photonics Laboraties)
Phys. Status Solidi C Vol. 10, No. 3, pp. 437–440 (2013).
This paper reports the MOVPE growth of InxGa1-xN (x~0.5) on Si(111) with a pn junction on the surface. By−78−

optimizing growth temperature and TMI/(TMI+TEG) molar ratio, InGaN films with In content up to 0.5 aresuccessfully grown without phase separation and metallic In incorporation. No significant differences in tilt
fluctuation in grown InGaN are found among three different substrates; GaN/α-Al2O3(0001) template, p-Si(111)and n-Si(111) with a p-type layer on the surface. The tilt fluctuation increases with increasing In content in InGaN
and shows the maximum at around In composition 0.5. The n-InGaN/p-Si structures show good ohmic
characteristics and the resistance obtained from the slope of I-V curves is markedly reduced with increasing In
content in InGaN. The Si pn junction beneath the In0.42Ga0.58N layer behaves well as a solar cell with an InGaN
filter. For both n-InGaN/p-Si and n-InGaN/pn-Si structures, the presence of an AlN interlayer between theepilayer and the substrate does not have a significant contribution to the series resistance.
Electrical Properties of p-Si/n-GaAs Heterojunctions by Using Surface-Activated Bonding
J. LIANG, T. MIYAZAKI, M. MORIMOTO, S. NISHIDA, N. WATANABE (NTT Photonics Laboratories), and
N. SHIGEKAWA
Appl. Phys. Express Vol. 6, 021801 [3 pages] (2013).
The electrical properties of p-Si/n-GaAs heterojunctions fabricated by using surface-activated bonding (SAB)
were investigated by measuring their current–voltage (I–V) and capacitance–voltage (C–V) characteristics. The I–
V characteristics showed rectifying properties. Their flat-band voltage obtained from C–V measurements wasaround 1.6 V. Observation by using field-emission-scanning electron microscopy and energy dispersive X-ray
spectroscopy revealed neither structural deficits nor oxide layers at the interfaces. These results suggest that the
SAB-based Si/GaAs heterojunctions are applicable for fabricating novel devices.
Study of Deterioration in a Piezoelectric Lead Zirconate Titanate Radiation Detector throughMeasurement of the Electromechanical Coupling Factor with 400 MeV/n Zenon Ions
M. KOBAYASHI (Chiba Institute of Technology), T. MIYACHI (Chiba Institute of Technology), S. TAKECHI,
M. SEKIGUCHI, H. SHIBATA (Osaka University), N. OKADA (Honda Electronics), M. HATTORI (Tokyo
Institute of Technology), O. OKUDAIRA (JAXA), M. FUJII (Famscience), T. MURAKAMI (NIRS), and Y.
UCHIHORI (NIRS)
Jpn. J. Appl. Phys. Vol. 52, 126604 (5 pages) (2013).
The variation of the electromechanical coupling factor (ECF) was measured by bombarding a piezoelectric leadzirconate titanate (PZT) element with 400 MeV/n xenon ions. The element was exposed to energies up to 104 J,
during which time the ECF was observed by the resonance method. The ECF gradually decreased with the energy
accumulated during irradiation, and its behavior was scaled with an empirical formula. This decrease suggests thatthe piezoelectric quality deteriorated; hence, the sensitivity of the PZT radiation detector was considered to be
degraded as well. The variation ultimately originated in resonance-associated processes. A potential detector
suitable for use in severe-radiation environments was discussed.
Type II band lineup in SAB-Based GaAs/Si heterojunctions
M. MORIMOTO, J. LIANG, S. NISHIDA, T. MIYAZAKI, and N. SHIGEKAWA
Extended Abstract of 2013 IEEE International Meeting for Future of Electron Devices, Kansai (IMFEDK), pp.
48-49 (2013). DOI: 10.1109/IMFEDK.2013.6602234
The electrical properties of GaAs/Si heterojuctions fabricated by using surface-activated bonding wereexperimentally investigated. The results of measurements suggested that the heterostructures revealed type-IIband lineup.
Characteristics of TiO2 surfaces etched by capacitively coupled radio frequency N2 and He plasmas
R. KAWAKAMI, M. NIIBE, Y. NAKANO, M. KONISHI, Y. MORI, H. TAKEUCHI, T. SHIRAHAMA,
T.YAMADA, and K. TOMINAGA.
Journal of Physics: Conference Series Vol. 441, 012038 (6 pages) (2013).
We have investigated characteristics of anatase TiO2 thin film surfaces etched by a capacitively coupled obtainedwith use of the N2 plasma is compared with that obtained with use of the He plasma. The experimental O/Ti ratioat the surface etched by the N2 plasma increases as a function of etching time. The increase in the experimental
O/Ti ratio is independent of a change in gas pressure. The above-mentioned experimental results agree with thesimulation result that the Ti atoms at the surface are preferentially removed by N2+ ions. The experimental O/Ti
ratio at the surface etched by the He plasma also increases, which does not agree with the simulation result that
the O atoms are preferentially removed by He+ ions. The O-1s XPS spectra of the surface etched by the He plasmashow the peak associated with oxygen and water adsorbed by the surface. In the case where the component of the−79−

adsorbed oxygen and water in each spectrum is subtracted, the experimental O/Ti ratio at the surface etched by the
He plasma shows a decrease. This is consistent with the simulation result. The adsorption of oxygen and water
seems to be caused by ambient air. Morphology of the surface etched by the N2 plasma is almost similar to that of
the as-grown surface regardless of the changes both in etching time and in gas pressure. In contrast, morphologyof the surface etched by the He plasma changes as the etching time increases. This result is independent of the gaspressure.
DOI: 10.1088/1742-6596/441/1/012038
Surface damage of 6H-SiC originating from Argon plasma irradiation
R. KAWAKAMI, M. NIIBE, H. TAKEUCHI, M. KONISHI, Y. MORI, T. SHIRAHAMA, T. YAMADA, and K.
TOMINAGA
Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms
Vol. 315, pp. 213-217 (2013).
Damage characteristics of SiC surfaces etched by capacitively coupled radio frequency Ar plasmas at various gas
pressures have been studied from the viewpoint of synergy effect of Ar plasma ion and plasma-induced ultraviolet(UV) light irradiations. In the absence of UV light emission at the low gas pressure of 10 mTorr, morphology ofthe etched SiC surface is similar to that of the as-grown surface regardless of an increase in etching time. In
contrast, the experimental Si/C ratio at the surface decreases with an increase in etching time, which agrees withthe simulation that Si atoms at the surface are preferentially removed by Ar+ ions impinging on the surface. The
agreement indicates that the physical etching effect, which originates from the Ar+ impact, contributes to thedecrease in the Si/C ratio. In the presence of the UV light emission, the surface morphology at the high gaspressure of 50-100 mTorr depends on the etching time. The surface morphology changes as the etching timeincreases to 200 min. The experimental etch depth at the etching time of 200 min does not agree with that of thesimulation. The experimental etch depth is much higher than the simulated one. The difference connecting withthe gas pressures can be related to the factor whether the UV light is emitted from the plasma: the result at thehigh gas pressure suggests the contribution of the synergy effect caused by the following possible phenomenon:
Si-C bonding at the surface is weakened.
DOI: 10.1016/j.nimb.2013.05.084
Comparison in Internal Strain Sensitivity between Polariscopy and Raman Scattering Spectroscopy in a(110)-oriented ZnTe Single Crystal
H. TAKEUCHI
Physica Status Solidi C Vol. 11, pp. 1194 -1197 (2014).
We present the experimental fact that, in a (110)-oriented ZnTe single crystal, polariscopy is highly sensitive tothe internal strain, comparing with Raman scattering spectroscopy. We utilized X-ray topography and X-ray
diffraction analysis to thoroughly investigate the crystal structure that is intimately associated with the internalstrain. The two X-ray structure analyses clarified that the misalignment from the [110] direction is formed in someregions. We obtained the following main result: The polariscopic analysis detects the internal strain formed by themisalignment, whereas the Raman scattering measurement is insensitive to the internal strain. We, therefore,
conclude that polariscopy has the strain-detection sensitivity higher than the Raman scattering spectroscopy. We
have confirmed that the polariscopic analysis can detect the internal strain less than 0.5% in the ZnTe crystal.
DOI: 10.1002/pssc.201300608
Correlation between the intra-atomic Mn3+ photoluminescence and antiferromagnetic transition in an
YMnO3 epitaxial film
M. NAKAYAMA, Y. FURUKAWA, K. MAEDA, T. YOSHIMURA, H. UGA, and N. FUJIMURA
Appl. Phys. Express Vol.7, 023002 (4 pages) (2014)
We have investigated the temperature dependence of the intra-atomic Mn3+ photoluminescence (PL) in a
multiferroic YMnO3 epitaxial film grown by pulsed laser deposition. The most significant result is that thetemperature dependence of the Mn3+ PL intensities is highly correlated with that of the magnetic spin orderoriginating from the antiferromagnetic transition. In contrast, the decay times of the Mn3+ PL bands are
independent of temperature; namely, the transition probabilities are not affected by the antiferromagnetictransition. The above results suggest that the electron transfer process to the Mn3+ excited state from theconduction band is dominated by the magnetic spin order.
DOI: 10.7567/APEX.7.023002−80−

High-sensitivity polarization modulation reflectance spectroscopy of cavity polaritons in a ZnO microcavity
T. HASEGAWA, R. KISHIMOTO, Y. TAKAGI, T. KAWASE, D. KIM, and M. NAKAYAMA
Appl. Phys. Express Vol.7, 032003 (4 pages) (2014)
We report that polarization modulation reflectance (PMR) spectroscopy is highly sensitive to the cavity polaritons
in a ZnO microcavity with HfO2/SiO2 distributed Bragg reflectors. We demonstrate that the cavity-polariton
dispersion, even in the energy region of strong absorption by exciton continuum states, is clearly observed by
PMR spectroscopy. The PMR spectra were quantitatively analyzed by a transfer-matrix method taking into
account three types of excitons labeled A, B, and C. Line-shape analysis of the PMR spectra indicates that theanisotropy of the excitonic transitions is considerable in treating the cavity polariton in the ZnO microcavity.
DOI: 10.7567/APEX.7.032003
Observation of bound and antibound states of cavity polariton pairs in a CuCl microcavity
S. MATSUURA, Y. MITSUMORI, H. KOSAKA, K. EDAMATSU, K. MIYAZAKI, D. KIM, M.
NAKAYAMA,G. OOHATA, H. OKA, H. AJIKI, and H. ISHIHARA
Phys. Rev. B Vol. 89, 035317 (2014)
We observed the antibound state, as well as the bound state, for cavity polariton pairs in a planar CuClmicrocavity by spectrally resolved four-wave mixing. We obtained dispersion curves of the bound and antiboundstates by changing the incident angle of the pump pulses corresponding to the cavity detuning. The dispersion
curve for the bound state suggests that the bound state is mainly composed of a bare biexciton and is weakly
coupled to the cavity photons. The dephasing time of the bound state was faster than that of a bare biexciton in athin sample, supporting the hypothesis that the bound state is coupled to the cavity photons. On the other hand, theantibound state consists of two lower polaritons having the same spin. The clear observation of the antibound state
can be qualitatively explained by the phase-space filling, which reduces the Rabi splitting.
DOI: 10.1103/PhysRevB.89.035317
Photon-field-shape effects on Rabi splitting energies in ZnO microcavities
M. KAWAKAMI, T. KAWASE, D. KIM, and M. NAKAYAMA
Opt. Materials Vol. 36, 1622–1626 (2014)
We have investigated the photon-field-shape effect on the Rabi splitting energies in ZnO microcavities with
HfO2/SiO2 distributed Bragg reflectors (DBRs). The thickness of the ZnO active layer was fixed to /2corresponding to a half of an effective resonant wavelength of the lowest-lying exciton. The photon-field shape
was tuned to a node type or an antinode type by changing the order of the refractive indices in the DBRs. We
obtained the cavity-polariton dispersions from angle-resolved reflectance spectra measured at 10 K. The Rabi
splitting energies were evaluated from the analysis of the cavity-polariton dispersions with a phenomenological
Hamiltonian for the strong coupling between the three kinds of excitons peculiar to ZnO labeled A, B, and C andthe cavity photon. It was found that the Rabi splitting energies in the antinode-type microcavity are almost a halfof those in the node-type microcavity. We semi-quantitatively analyzed the photon-field-shape effect, taking
account of the overlap between the exciton and photon-field envelope functions.
DOI: 10.1016/j.optmat.2013.11.029
Photoluminescence characteristics of polariton condensation in a CuBr microcavity
M. NAKAYAMA, K. MURAKAMI, Y. FURUKAWA, and D. KIM
Appl. Phys. Lett. Vol.105, 021903 (4 pages) (2014)
We have investigated the photoluminescence (PL) properties of a CuBr microcavity at 10 K, including the
temporal profiles, from the viewpoint of cavity-polariton condensation. The excitation energy density dependenceof the PL intensity (band width) of the lower polariton branch at an in-plane wave vector of k//=0 exhibits athreshold-like increase (decrease). A large blueshift in the PL energy of 10 meV caused by the cavity-polariton
renormalization is correlated with the excitation energy density dependence of the PL intensity. The estimateddensity of photogenerated electron-hole pairs at the threshold is two orders lower than the Mott transition density.
These results consistently demonstrate the occurrence of cavity-polariton condensation. In addition, we found that
the PL rise and decay times are shortened dramatically by the cavity-polariton condensation, which reflects thebosonic final state stimulation in the relaxation process and the intrinsic cavity-polariton lifetime in the decay
process.
DOI: 10.1063/1.4890216−81−

Polariton Characteristics of Photoluminescence Dynamics of Exciton–Exciton Scattering in GaAs/AlAs
Multiple Quantum Wells
Y. FURUKAWA, H. TAKEUCHI, and M. NAKAYAMA
J. Phys. Soc. Jpn. Vol. 83, 054709 (6 pages) (2014)
We have investigated the photoluminescence (PL) dynamics of exciton–exciton scattering, the so-called P
emission, at 10K in GaAs (d nm)/AlAs (d nm) multiple quantum wells (MQWs) with d = 10 and 20. It was foundthat the decay rate of the P emission systematically increases with a decrease in detection energy. In contrast, thedecay rate hardly depends on an excitation power, which suggests that exciton–exciton collisions do not affect the
decay rate. We demonstrate that the energy dependence of the decay rate p-1(E) in each MQW is consistently
scaled by that of the group velocity, vg(E), of a photon-like polariton in the lower polariton branch that is the final
state for the P emission: p-1(E) = A vg(E). This fact provides us clear evidence for the polariton characteristics of
the PL dynamics of exciton–exciton scattering.
DOI: 10.7566/JPSJ.83.054709
Radiation of Terahertz Electromagnetic Waves from Coherent Longitudinal Optical Phonons in Multiple
Quantum Wells
M. NAKAYAMA
J. Nanoelectronics and Optoelectronics Vol. 8, pp.415–424 (2013)
The radiation of terahertz electromagnetic waves from coherent longitudinal optical (LO) phonons in multiple
quantum wells (MQWs) under illumination of a femtosecond pulse laser is reviewed from the viewpoint of theenhancement mechanism at room temperature, which is essential in applications to optoelectronics in a terahertz
region. Two enhancement mechanisms in MQWs are focused on. One is that the impulsive quantum interference
between the heavy-hole (HH) and light-hole (LH) excitons acts as a driving force to the coherent GaAs-like LO
phonon in GaAs/AlAs MQWs under a condition that the splitting energy between the HH and LH excitons
resonates with the LO-phonon energy. The other is that a piezoelectric field due to the lattice-mismatch strain
along a [11n] direction produces an initial polarization of the GaAs-like LO phonon via an electric susceptibility,
which results in considerable enhancement of the intensity of the terahertz radiation from the coherent LO phonon,in (11n)-oriented GaAs/In0.1Al0.9As strained MQWs.
DOI: 10.1166/jno.2013.1501
Thickness dependence of photoluminescence-decay profiles of exciton-exciton scattering in ZnO thin films
S. WAKAIKI, H. ICHIDA, T. KAWASE, K. MIZOGUCHI, D. KIM, M. NAKAYAMA, and Y. KANEMATSU
Eur. Phys. J. B Vol. 86 387 (4 pages) (2013)
We have investigated the photoluminescence (PL) dynamics of ZnO thin films under intense excitation conditions
using an optical-Kerr-gating method. The PL bands originating from exciton-exciton scattering (P emission) andbiexciton (M emission) have been observed at 10 K. The ultrashort gating time of 0.6 ps has enabled us to obtain
precise information of the temporal profiles of the peak energies and the intensities of the P- and M-PL bands. We
have found that the decay time of the P emission becomes longer with increasing film thickness, while that of theM emission is independent of the film thickness. Although the decay time of the P emission is an increasing
function of the film thickness, the relation is not in proportion, which is contrary to the predicted proportionality
based on a simple model of photon-like polariton propagation.
DOI: 10.1140/epjb/e2013-30631-5
Voltage-controllable terahertz radiation from coherent longitudinal optical phonons in a p-i-n diodestructure of GaAs
M. NAKAYAMA, S. ASAI, H. TAKEUCHI, O. ICHIKAWA, and M. HATA
Appl. Phys. Lett. Vol. 103, 141109 (4 pages) (2013)
We propose and demonstrate the voltage-controllable terahertz radiation from coherent longitudinal optical (LO)phonons in a p-i-n diode of GaAs at room temperature under illumination of a femtosecond pulse laser. It was
found that the intensity of the terahertz radiation is continuously and drastically enhanced by an increase inreverse bias voltage (electric field strength) from 0 (22) to 8.0V (140 kV/cm). The analysis of theelectric-field-strength dependence of the intensity indicates that the initial polarization of the LO phonon inducedby the electric field dominates the enhancement and that the second-order electric susceptibility is considerable.
DOI: 10.1063/1.4823595
Geometrical Excess Entropy Production in Nonequilibrium Quantum Systems
T. YUGE, T. SAGAWA, A. SUGITA and H. HAYAKAWA−82−

J. Stat. Phys. Vol. 153, pp 412-441 (2003)
For open systems described by the quantum Markovian master equation, we study a possible extension of theClausius equality to quasistatic operations between nonequilibrium steady states (NESSs). We investigate theexcess heat divided by temperature (i.e., excess entropy production) which is transferred into the system during
the operations. We derive a geometrical expression for the excess entropy production, which is analogous to the
Berry phase in unitary evolution. Our result implies that in general one cannot define a scalar potential whose
difference coincides with the excess entropy production in a thermodynamic process, and that a vector potential
plays a crucial role in the thermodynamics for NESSs. In the weakly nonequilibrium regime, we show that thegeometrical expression reduces to the extended Clausius equality derived by Saito and Tasaki (J. Stat. Phys.
145:1275, 2011). As an example, we investigate a spinless electron system in quantum dots. We find that one candefine a scalar potential when the parameters of only one of the reservoirs are modified in a non-interacting
system, but this is no longer the case for an interacting system.
Typical Pure States and Nonequilibrium Processes in Quantum Many-Body Systems
T. MONNAI and A. SUGITA
J. Phys. Soc. Jpn. Vol. 83, 094001 (5 pages) (2014)
We show that it is possible to calculate equilibrium expectation values of many-body correlated quantities such as
the characteristic functions and probability distributions with the use of only a single typical pure state. It alsomeans that we can apply the pure state approach to Heisenberg operators and their spectral fluctuation, and hence
to nonequilibrium processes starting from equilibrium. In particular, we can accurately analyze the full statistics ofentropy production in nonequilibrium mesoscopic systems. In this way, we can access the full information onhigher-order fluctuations in the large deviation regime far from equilibrium.
The gas distributions of He and Ne at metal surface in the field ion microscope
K. SAITO, and A. KOBAYASHI
Proc. 7th Int. Symp. Surf. Sci. (ISSS-7), Shimane Nov.3-6, 3PN-74 (2013)
For investing the mechanism of image formation in the field ion microscope (FIM), it is important to understandthe image gas dynamics microscopically in the vicinity of specimen surface. Particularly concerned with FIM
imaging in inert gas mixtures, it is well known that the addition of a trace of Ne to He image gas gives rise tostrong flickering effects in FIM images with rapid variations in the intensity of individual image spots, and theeffect is due to the results of alternative change between He field adsorption and Ne field adsorption at thecorresponding surface atom site. In order to examine the details of Ne atom condensation near the surface, we
demonstrate 2-dimentional gas dynamics in a mixed system of He and Ne in the presence of the electric field
based on a classical gas kinetics model with parameters such as polarizabilities, masses and dimensions
corresponding to each of He and Ne atoms. Coefficients which correspond to the rebound of He and Ne atoms at
specimen surface are also taken into account to involve the thermal accommodation effect. With these four factors,
we calculate the trajectories of He and Ne atoms that randomly travel and repeatedly collide each other in space
while receiving dipole attractive force from the specimen surface, and we examine how these four factors affect
the gas dynamics and eventually result in the superiority of Ne gas concentration near the surface.
Three-Dimensionally Integrated Micro-solution Plasma: Numerical Feasibility Study And Practical
Applications
T. SHIRAFUJI, A. NOMURA, and Y. HIMENO
Plasma Chem. Plasma Process., Vol. 34, pp. 523-534 (2014).
This paper describes effects of design parameters for a three-dimensionally integrated micro-solution plasma (3D
IMSP) reactor, which generates a large amount of microplasma in gas bubbles flowing with a liquid medium
through a porous dielectric material. Electric fields in gas bubbles are calculated by solving Maxwell’s equations
under the electro-quasi-static approximation. The calculated electric fields in the bubbles can be high enough for
igniting electrical discharge in the bubbles even if the bubbles are surrounded by electrically conductive liquid.
We show importance of higher permittivity of a dielectric-reactor tube and a higher voltage-rise rate for obtaining
higher electric fields in the bubbles. Using a proto type 3D IMSP reactor, we demonstrate synthesis of gold
nanoparticles and decomposition of methylene blue molecules in aqueous solution.
DOI: 10.1007/s11090-014-9544-2
Numerical Simulation of Electric Double Layer in Contact with Dielectric Barrier Discharge
T. SHIRAFUJI, A. NAKAMURA, and F. TOCHIKUBO (Tokyo Metropolitan Univ.)
JPS Conf. Proc., Vol. 1, 015058 (4 pages) (2014).

−83−

A Numerical study has been carried out for understanding behavior of electric double layer (EDL) in liquid incontact with atmospheric dielectric barrier discharge (DBD) plasma of Ar gas. In the case of liquid with low ion
concentration like de-ionized water, amount of liquid-phase ions generated by electron or ion irradiation from the
DBD plasma is higher by approximately one order of magnitude than that in the pure EDL formed only withpotential difference between the top and bottom of the liquid Effects of molecular weight of the ions in liquid areinvestigated. If the molecular weight of the ions larger, residence time of the ions at the liquid surface becomes
longer. If the molecular weight of positive and negative ions is different, heavier ions becomes dominant at theliquid surface. These characteristics are pronounced by employing higher frequency voltage, which implies
possibility of preferential reactions at the plasma-liquid interface.
DOI: 10.7566/JPSCP.1.015058
Numerical Simulation of Electric Double Layer in Contact with Dielectric Barrier Discharge -Effects of Ion
Transport Parameters in Liquid T. SHIRAFUJI, A. NAKAMURA, and F. TOCHIKUBO (Tokyo Metropolitan Univ.)
Jpn. J. Appl. Phys., Vol. 53, 03DG04 (6 pages) (2014).
The spatiotemporal distribution of charged particles has been investigated through numerical simulation of
charged particle behavior in gas and liquid phases in the dielectric barrier discharge of Ar gas in contact with aliquid. In the case of a liquid with a low ion concentration such as deionized water, the amount of liquid-phaseions generated by electron or ion irradiation from gas-phase plasma is higher by approximately one order ofmagnitude than that in the pure electric double layer formed only with the potential difference between the top andbottom of the liquid. When the molecular weight of the ions is larger, the residence time of the ions at the liquidsurface becomes longer. If the molecular weight of positive and negative ions is different, heavier ions become
dominant at the liquid surface. These characteristics are pronounced by employing a higher frequency voltage,
which implies the possibility of preferential reactions at the plasma-liquid interface.
DOI: 10.7567/JJAP.53.03DG04
Time-resolved Optical Emission Spectroscopy on Three-dimensionally Integrated Micro-solution Plasmas
T. SHIRAFUJI, Y. OGURA, and Y. HIMENO
Jpn. J. Appl. Phys., Vol. 53, 010211 (6 pages) (2014).
Time-averaged and time-resolved optical emission spectroscopy (OES) has been performed on
three-dimensionally integrated micro-solution plasma (3D IMSP). In comparison with that of conventional
solution plasma generated in pure water vapor bubbles, the OES spectrum of our 3D IMSP, which is generated in
Ar gas bubbles surrounded with water, shows more pronounced optical emission of OH radicals than of H and O
radicals. In addition, time-resolved OES shows that the optical emission of OH radicals is sustained even after theemission of H and Ar almost disappears. The mechanisms of these phenomena are discussed by considering thedissociative recombination of H2O+ and/or H3O+ with low-temperature electrons.
DOI: 10.7567/JJAP.53.010211
Gold Nanoparticles Synthesis by Using Three-dimensionally Integrated Micro-solution Plasmas
T. SHIRAFUJI, J. UEDA, A. NAKAMURA, S.-P. CHO (Nagoya Univ.), N. SAITO (Nagoya Univ.), and O.
TAKAI (Kanto Gakuin Univ.)
Jpn. J. Appl. Phys., Vol. 52, 126202 (5 pages) (2013).
Three-dimensionally integrated micro-solution plasmas (3D IMSPs), in which microplasmas are generated in gas
bubbles in an aqueous solution held in a porous dielectric material, have been applied to gold nanoparticle
synthesis. Conventional solution plasma processes require additional chemicals to increase the electricalconductivity of the aqueous solution for generating plasmas. In contrast to this, 3D IMSPs have been found to
generate plasmas without such a procedure when the aqueous solution has a low electrical conductivity as in thecase of HAuCl4 for gold nanoparticle synthesis. The gold nanoparticle synthesis has been confirmed through theobservation of optical absorption due to the plasmon resonance at 550 nm, and also through the characterization of
their size, crystallinity, and composition by transmission electron microscopy and energy dispersive X-ray
spectroscopy
DOI: 10.7567/JJAP.52.126202
Generation of Three-dimensionally Integrated Micro-solution Plasmas And Its Application to
Decomposition of Methylene Blue Molecules in Water
T. SHIRAFUJI and Y. HIMENO
Jpn. J. Appl. Phys., Vol. 52, 11NE03 (5 pages) (2013).

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Integrated micro-solution plasma was generated in gas bubbles in porous dielectric materials filled with agas/liquid mixed medium. Methylene blue aqueous solution (3.8 mg/L, 150 mL) was treated with the integrated
micro-solution plasma. The decomposition of methylene blue molecules was confirmed through the reduction in
the optical absorption coefficient at 665 nm for methylene blue molecules, and through the fact that the absorption
coefficient at 665 nm did not recover even after stirring in air. The decomposition efficiency of the integrated
micro-solution plasma was 15.7-fold higher than that of conventional solution plasma.
DOI: 10.7567/JJAP.52.11NE03
Functionalization of Multiwalled Carbon Nanotubes by Solution Plasma Processing in Ammonia Aqueous
Solution and Preparation of Composite Material with Polyamide 6
T. SHIRAFUJI, Y. NOGUCHI (Nagoya Univ.), T. YAMAMOTO (Nagoya Univ.), J. HIEDA (Tohoku Univ.), N.
SAITO (Nagoya Univ.), O. TAKAI (Kanto Gakuin Univ.), A. TSUCHIMOTO (Toyo Jushi Corp.), K. NOJIMA(Toyo Jushi Corp.), and Y. OKABE (Toyo Jushi Corp.)
Jpn. J. Appl. Phys., Vol. 52, 125101 (6 pages) (2013).
Solution plasma processing (SPP) has been performed on multiwalled carbon nanotubes (MWCNTs) in ammonia
aqueous solution. The MWCNTs, which do not disperse in aqueous solution, uniformly dispersed after the SPP.
Only 2 h was required to obtain 10 g of the dispersed MWCNTs, while 7 days and additional chemicals wererequired for 185 mg in a previous study. The X-ray photoelectron spectroscopy and Fourier-transform infrared
spectroscopy of the SPP-treated MWCNTs revealed that nitrogen- and oxygen-containing groups are formed on
the MWCNTs. Serious damage to the MWCNT structure was not observed in the Raman spectrum ortransmission electron microscopy images of the SPP-treated MWCNTs. The composite materials prepared using
polyamide 6 with the SPP-treated MWCNTs showed better tensile, bending, and impact strength than those
prepared with non-treated MWCNTs.
DOI: 10.7567/JJAP.52.125101
Decomposition of Methylene Blue Molecules in Aqueous Solution by Using Three-dimensionally Integrated
Micro Solution Plasmas and Improvement of Its Energy Efficiency
T. SHIRAFUJI, Y. HIMENO, N. SAITO (Nagoya Univ.), and O. TAKAI (Kanto Gakuin Univ.)
J. Photopolym. Sci. Technol., Vol. 26, pp. 507-511 (2013).
Three-dimensionally integrated micro solution plasmas were generated in gas bubbles in porous dielectricmaterials filled with gas/liquid mixed medium. The methylene blue molecules in aqueous solution were
decomposed by the treatment with the three-dimensionally integrated micro solution plasmas. Decomposition
efficiency was 16 times higher than conventional solution plasma in the case of applied voltage of 5 kV. Withdecreasing applied voltage from 5 to 2 kV, the decomposition efficiency was improved up to 360% in comparison
to that of 5 kV, while reduction in the decomposition rate was 40%.
DOI: 10.2494/photopolymer.26.507
Numerical Investigation of Electric Field in Gas Bubbles Surrounded with Conductive Liquid And
Dielectric Material
T. SHIRAFUJI and A. NAKAMURA
Trans. Mater. Res. Soc. Jpn., Vol. 38, pp. 321-323 (2013).
We propose a structure of integrated micro solution plasmas, in which a number of microplasmas can begenerated in a liquid medium, and we can expect efficient plasma-liquid interaction. It consists of a non-isolated
porous dielectric material filled with a gas-liquid mixed medium. Since the bubbles in this structure are
surrounded with conductive liquid, electrical discharges in the bubbles are not expected if we use liquid with
infinite electrical conductivity. However, numerical simulation has revealed that the electric field in the bubbles
can be high enough to ignite atmospheric pressure discharge in it if the liquid has finite electrical conductivity, forexample 200 μS/cm for typical tap water, and that the concept of the integrated micro solution plasmas is feasibleone.
DOI: 10.14723/tmrsj.38.321
Plasmas in Contact with Liquid: “Plasma Electrochemistry”
T. SHIRAFUJI, N. SAITO (Nagoya Univ.), O. TAKAI (Kanto Gakuin Univ.), F. TOCHIKUBO (Tokyo
Metropolitan Univ.), K. YASUOKA (Tokyo Inst. Technol.), T. KANEKO (Tohoku Univ.), T. ISHIJIMA(Kanazawa Univ.), K. TAKAHASHI (Kanazawa Univ.), N. TAKEUCHI (Tokyo Inst. Technol.), and N. SHIRAI(Tokyo Metropolitan Univ.)
J. Surf. Sci. Soc. Jpn., Vol. 34, pp. 547-552 (2013) (in Japanese).

−85−This paper describes historical overview and recent activity on “plasma electrochemistry”, which involves
materials processing with plasmas in contact with liquids. Nano-materials synthesis and organic-pollutant
decomposition are the most active application areas. The most important part of the plasma electrochemistry is theplasma/liquid interface. The physicochemical processes near the plasma/liquid interface have been graduallyclarified through experiments and numerical simulations. These are briefly described in this paper together with
future issues for understanding effects of electric double layer and nano-scale steep density gradient.
DOI: 10.1380/jsssj.34.547
Numerical Simulation of Spatiotemporal Behavior of Electric Double Layer in Aqueous Solution in Contact
with Gas-phase Plasma Sheath
T. SHIRAFUJI and A. NAKAMURA
Proc. 21st International Symposium on Plasma Chemistry (ISPC 21), ID545 (4 pages), Aug. 4-9, 2013, Cairns,
Australia.
Numerical simulation of electric double layer in contact with a dielectric barrier discharge has been performed.
Preferential appearance of positive or negative ions has been observed on the top surface of the liquid. This meansthat the preferential interaction can be realized between gas-phase plasma species and liquid phase ions.
Three-Dimensional Integration of Micro Solution Plasmas and Its Application to Material Processing in
Large Volume Liquid
T. SHIRAFUJI
Proc. 21st International Symposium on Plasma Chemistry (ISPC 21), ID315 (4 pages), Aug. 4-9, 2013, Cairns,
Australia.
Three-dimensionally integrated micro solution plasma (3D IMSP), in which micro-plasmas are generated in Ar
gas bubbles in aqueous solution being held in a porous dielectric material, has been proposed. Electric field in the
bubbles is calculated with numerical simulation and is confirmed to be high enough for igniting electricaldischarge in the bubbles even if the bubbles are surrounded with electrically conductive liquid. A proto typereactor for generating the 3D IMSPs has capability of generating large volume plasma in liquid. The 3D IMSP
reactor is applied to material processing, in which the 3D IMSP is found to be able to synthesize gold
nanoparticles and to decompose organic substance in water.
Decomposition of Acetic Acid Molecules on Three-dimensionally Integrated Micro Solution Plasma in
Ar/H2O Mixture
Y. HIMENO and T. SHIRAFUJI
Proc. 8th International Conference on Reactive Plasmas and 31st Symposium on Plasma Processing, 5A-AM-O2(2 pages), Feb. 3-7, 2014, Fukuoka, Japan.
Three-dimensionally integrated micro-solution plasma (3D IMSP) was generated in gas bubbles in porous
dielectric materials filled with gas/liquid medium. We have used this method to decompose acetic acid which is
known as a persistent organic substance. The liquid after the 3D IMSP treatment has been characterized with
Fourier transform infrared spectroscopy, in which we have observed changes in the IR absorption bands
corresponding to OH (3700-3500 cm-1) and CO (1200-1300 cm-1) bonds of acetic acid molecules.
Optical Emission Spectroscopy on 3D Integrated Micro-solution Plasma
Y. OGURA, Y. HIMENO, and T. SHIRAFUJI
Proc. 8th International Conference on Reactive Plasmas and 31st Symposium on Plasma Processing,
5P-PM-S09-P22 (2 pages), Feb. 3-7, 2014, Fukuoka, Japan.
We have performed time-averaged and time-resolved optical emission spectroscopy in order to investigate themechanism of radical generation in 3D Integrated Micro-Solution Plasma, which is ignited in a large number ofAr bubbles surrounded by aqueous solution. We have found that the duration of optical emission of OH(A) is
longer than Hα. The causes of this difference are discussed with considering contribution of metastable excited
Ar.
Chemical Vapor Deposition of SiO Thin Films Using an Atmospheric Pressure Helium Plasma Jet And
Hexamethyldisiloxane
R. TAGA, D. USA, and T. SHIRAFUJI
Proc. 8th International Conference on Reactive Plasmas and 31st Symposium on Plasma Processing,
5P-PM-S09-P23 (2 pages), Feb. 3-7, 2014, Fukuoka, Japan.

−86−SiO thin films, which are usually deposited by plasma CVD in low pressure, have been deposited using an
atmospheric pressure plasma jet (APPJ) and hexamethlydisiloxane (HMDSO). Although particles are generated
on the surface of thin films deposited, generation of particles is suppressed by properly configuring the APPJ andthe nozzle that supplies HMDSO. Film composition is also affected by the configuration of the jet and nozzle.
Time-resolved Optical Emission Spectroscopy on Micro-solution Plasma in a Single Bubble in a Capillary
Tube
R. TASHIRO, K. OBANA, and T. SHIRAFUJI
Proc. 8th International Conference on Reactive Plasmas and 31st Symposium on Plasma Processing,
5P-PM-S09-P24 (2 pages), Feb. 3-7, 2014, Fukuoka, Japan.
Three-dimensionally integrated micro-solution plasma (3D IMSP) was generated in gas bubbles in porous
dielectric materials filled with gas/liquid medium. We have performed time-resolved OES. It has revealed thatemission intensity of OH showed a unique time-dependence, in which the 2nd maximum appeared after the 1st
main peak. In order to understand details of the 3D IMSP, we performed investigation of microplasma in a single
bubble by time-resolved OES. We could not see the 2nd peak in the case of the single bubble, but long tail wasobserved after the 1st peak.
On The Contribution of Electrons, Ar(3P), H2O+, and H3O+ to Production of OH(A) in a Micro DBD of
Ar/H2O
T. SHIRAFUJI and T. MURAKAMI (Tokyo Institute of Technology)
Proc. 8th International Conference on Reactive Plasmas and 31st Symposium on Plasma Processing, 6A-PM-O4(2 pages), Feb. 3-7, 2014, Fukuoka, Japan.
Numerical simulation of a micro DBD of Ar/H2O gas mixture has been performed for understanding behavior of
OH(A) in 3D IMSP. During the discharge ignition sequence in 0-200 ns, major OH(A) production reactions are
dissociation of H2O by high-Te electrons and metastable excited Ar. After the main discharge, OH(A) production
becomes dominated by the dissociative recombination of H3O+ and low-Te electrons.
Coherent time-domain detection of terahertz pulses generated from noncollinear phasematched,picosecond terahertz parametric oscillator
Y. TADOKORO, Y. TAKIDA, H. KUMAGAI, S. NASHIMA, and M. HANGYO
Applied Physics Express, Vol. 7, pp. 022701(3pages) (2014).
With a photoconductive antenna, we demonstrate time-domain detection of terahertz (THz) pulses generated froma noncollinear phase-matched, picosecond THz parametric oscillator. Since time-domain detection enables us todetect THz waves sensitively, the dynamic range of the power spectrum is ~1000 times improved in comparison
with that of a pyroelectric detector. Furthermore, multiple THz pulses are observed because of the time delay
between arrayed Si prism couplers. When a single, larger Si prism coupler or a trapezoidal MgO:LN crystal isemployed instead, single monocycle THz pulses are observed.
Metal mesh device sensor immobilized with a trimethoxysilane-containing glycopolymer for label-freedetection of proteins and bacteria
H. SETO, S. KAMBA, T. KONDO, M. HASEGAWA, S. NASHIMA, Y. EHARA, Y. OGAWA, Y.
HOSHINO, and Y. MIURAACS Applied Material and Interfaces, Vol. 6, No. 15, pp. 13234-13241 (2014).
Biosensors for the detection of proteins and bacteria have been developed using glycopolymer-immobilized metal
mesh devices. The trimethoxysilane-containing glycopolymer was immobilized onto a metal mesh device using
the silane coupling reaction. The surface shape and transmittance properties of the original metal mesh device
were maintained following the immobilization of the glycopolymer. The mannose-binding protein (concanavalinA) could be detected at concentrations in the range of 10-9 to 10-6 mol L-1 using the glycopolymer-immobilized
metal mesh device sensor, whereas another protein (bovine serum albumin) was not detected. A detection limit of
1 ng mm-2 was achieved for the amount of adsorbed concanavalin A. The glycopolymer-immobilized metal meshdevice sensor could also detect bacteria as well as protein. The mannose-binding strain of Escherichia coli was
specifically detected by the glycopolymer-immobilized metal mesh device sensor. The glycopolymer-immobilized
metal mesh device could therefore be used as a label-free biosensor showing high levels of selectivity andsensitivity toward proteins and bacteria.

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Electric and Information Engineering
Volumetric display using rotating prism sheets arranged in a symmetrical configuration
Yuki MAEDA, Daisuke MIYAZAKI, Takaaki MUKAI and Satoshi MAEKAWA (Univ. of Hyogo)
Opt. Express Vol.21, 27074-27086 (2013).
A volumetric display that creates a distortion-free three-dimensional (3D) image in midair is described. The
proposed system consists of rotating prism sheets used as an optical scanner and a dihedral corner reflector
array (DCRA), which is a distortion-free imaging element. Two prism sheets are arranged in a symmetricalconfiguration to reduce an unnatural motion parallax caused by optical aberrations. A cross-section of the 3D
image is formed by the DCRA in midair and moved by the rotating prism sheets to create a 3D displayable
space. A 3D volume image was displayed without image distortion or unnatural motion parallax.
Floating multi-view image formation with micro-mirror array imaging element
Daisuke MIYAZAKI
The 3rd Japan-Korea Workshop on Digital Holography and Information Photonics, Session 2- 3 (2013).
A volumetric display that creates a distortion-free three-dimensional (3D) image in midair is described. The
proposed system consists of rotating prism sheets used as an optical scanner and a dihedral corner reflector
array (DCRA), which is a distortion-free imaging element. Two prism sheets are arranged in a symmetricalconfiguration to reduce an unnatural motion parallax caused by optical aberrations. A cross-section of the 3D
image is formed by the DCRA in midair and moved by the rotating prism sheets to create a 3D displayable
space. A 3D volume image was displayed without image distortion or unnatural motion parallax.
Floating volumetric display using an imaging element that consists of a 90° prism sheet and a linear
Fresnel lens
Yuki MAEDA, Daisuke MIYAZAKI, Takaaki MUKAI and Satoshi. MAEKAWA (Univ. of Hyogo)
Proc. Soc. Photo-Opt. Instrum. Eng., Vol. 9011, 90111N (2014).
We propose a floating volumetric display system using a novel imaging element whose aperture is large andcan be made easily at low cost. Diffuse rays in a horizontal direction for an observer are formed by a 90º
prism sheet, which has a shape of an array of 90º V-grooves, as a result of twice total internal reflection. On
the other hand, the diffuse rays in a longitudinal direction for the observer are formed by a linear Fresnel lens.
A formed image by the proposed imaging element does not distort in the horizontal direction because therays in the horizontal direction converge by retroreflection. The proposed imaging element can be produced
easier than a conventional distortion-free imaging element and display a larger floating image. A floating
three-dimensional image was displayed by a volumetric display system based on optical scanning of an
inclined image plane. A position of a two-dimensional real image formed by the proposed imaging element
was moved by an optical scanner at a faster rate than the duration time of persistence of vision. A stack of
moved images created the floating three-dimensional volume image.
Multi-user autostereoscopic display based on direction-controlled illumination using a slanted
cylindrical lens array
Daisuke MIYAZAKI, Yui HASHIMOTO, Takahiro TOYOTA, Kenta OKODA, Tetsuro OKUYAMA(Panasonic), Toshikazu OHTSUKI (Panasonic), Akio NISHIMURA (Panasonic), and Hiroyuki YOSHIDA(Panasonic)
Proc. Soc. Photo-Opt. Instrum. Eng., Vol. 9011, 90111G (2014).
This research aims to develop an auto-stereoscopic display, which satisfies the conditions required forpractical use, such as, high resolution and large image size comparable to ordinary display devices for
television, arbitrary viewing position, multiple viewer availability, suppression of nonuniform luminancedistribution, and compact system configuration. In the proposed system, an image display unit is illuminatedwith a direction-controlled illumination unit, which consists of a spatially modulated parallel light source anda steering optical system. The steering optical system is constructed with a slanted cylindrical array andvertical diffusers. The direction-controlled illumination unit can control output position and horizontal angleof vertically diffused light. The light from the image display unit is controlled to form narrow exit pupil. A−88−viewer can watch the image only when an eye is located at the exit pupil. Auto-stereoscopic view can beachieved by alternately switching the position of an exit pupil at viewer's both eyes, and alternately
displaying parallax images. An experimental system was constructed to verify the proposed method. The
experimental system consists of a LCD projector and Fresnel lenses for the direction-controlled illumination
unit, and a 32 inch full-HD LCD for image display.
Optical design for heterogeneous imaging based on retro reflection using parallel roof mirror arrays
Yuki MAEDA, Daisuke MIYAZAKI, and Satoshi. MAEKAWA (Univ. of Hyogo)
JSAP-OSA Joint Symposia 2014, Information Photonics, 20a-C4-3 (2014).
Floated integral imaging display viewable from surrounding area
Daisuke MIYAZAKI, Go MIYAZAKI, Yuki MAEDA, and Takaaki MUKAI
Imaging and Applied Optics 2014, OSA Technical Digest, DW2B.5 (2014).
A full-parallax auto-stereoscopic display method that enables formation of a floating three-dimensional
image viewable from a surrounding area is proposed. This method utilizes integral imaging, a rotating mirror
scanner, and a hemisphere concave mirror.
Wide-Viewing Angle Three-dimensional Display Using Multiple LCDs
Hirofumi YABU, Joji KANDA, and Hideya TAKAHASHIICIC Express Letters Part B, Vol.5, 1, pp.195-200 (2014).
We propose an omnidirectional three-dimensional (3D) display system. This is a tool for communication
around a 3D image among a small number of people. This 3D display system consists of multiple basic 3D
display units. The basic unit consists of an LCD, a lenticular lens array sheet, and a relay lens. In this basic
unit, the light rays from an LCD pass through a lenticular lens sheet and observed directly. Thus, the spatial
density distribution of projected light rays is partial. To average the spatial density of projected light rays, weuse a relay lens. To increase the viewing angle, we aligned multiple basic units in a circle, and displayed 3D
images at the center of the circle. To verify the effectiveness of the proposed 3D display, we constructed theprototype system. This prototype consists of 3 basic units. They are aligned 18.5-degree apart in a circle andthe radius is 613.2 mm. The shape of the maximum size of displayed 3D images is a cylinder and the radius
is 25 mm, the height is 50 mm. The viewing angle of a 3D image is 55.5-degree. This paper describes theprinciple of proposed 3D display system, and also describes the experimental results.
Silicone Rubber Membrane Tactile Sensor for Endoscope Based on Image Processing
Yuma KITANOUMA, Hideya TAKAHASHI, Kayo YOSHIMOTO (Osaka University), and Kenji
YAMADA (Osaka University)
ICIC Express Letters Part B, Vol.5, 1, pp.279-284 (2014).
We propose the silicone rubber membrane tactile sensor for an endoscope. The proposed system consists ofthe transparency silicon rubber membrane and the image sensor. Our proposed system can estimate thestiffness of the target object by measuring the deformation of the silicone rubber which includes markers
inside. When the silicone rubber is deformed by contacting with the target object, the position of each marker
shifts. By using the displacement information of markers measured by the imaging device, the system canmeasure the deformation of the silicone rubber. The purpose of this study is to evaluate the proposed system.
At first, we introduce the approximated models of the silicone and the object. We formulate the stiffness ofthe object, the deformation of silicone, and the whole object. To verify the effectiveness of the proposedsystem, we constructed the prototype system.
Retinal projection type super multi-view head-mounted display
Hideya TAKAHASHI, Yutaka ITO, Seigo NAKATA, and Kenji YAMADA (Osaka University)
Proc.SPIE-IS&T Electronic Imaging, Vol.9012, pp. 90120L-1-90120L-6 (2014).
We propose a retinal projection type super multi-view head-mounted display (HMD). The smooth motion
parallax provided by the super multi-view technique enables a precise superposition of virtual 3D images on
the real scene. Moreover, if a viewer focuses one’s eyes on the displayed 3D image, the stimulus for theaccommodation of the human eye is produced naturally. Therefore, although proposed HMD is a monocular
HMD, it provides observers with natural 3D images. The proposed HMD consists of an image projection−89−optical system and a holographic optical element (HOE). The HOE is used as a combiner, and also works as
a condenser lens to implement the Maxwellian view. Some parallax images are projected onto the HOE, andconverged on the pupil, and then projected onto the retina. In order to verify the effectiveness of the
proposed HMD, we constructed the prototype HMD. In the prototype HMD, the number of parallax images
and the number of convergent points on the pupil is three. The distance between adjacent convergent points
is 2 mm. We displayed virtual images at the distance from 20 cm to 200 cm in front of the pupil, andconfirmed the accommodation. This paper describes the principle of proposed HMD, and also describes theexperimental result.
Evaluation of the three-dimensional endoscope system for assessing the gastrointestinal motility
Kayo YOSHIMOTO (Osaka University), Kenji YAMADA (Osaka University), Kenji WATABE (Osaka
University), Maki TAKEDA (Osaka University), Takahiro NISHIMURA (Osaka University), Michiko
KIDO (Osaka University), Toshiaki Nagakura (Osaka Electro-Communication University), Hideya
TAKAHASHI, Tsutomu NISHIDA (Osaka University), Hideki IIJIMA (Osaka University), Masahiko
TSUJII (Osaka University), Tetsuo TAKEHARA (Osaka University), and Yuko OHNO (Osaka University)
Proc.SPIE-BiOS2014 Advanced Biomedical and Clinical Diagnostic System XII, Vol.8935, pp.
89351G-1-89351G -6 (2014).
This paper described evaluation of the three-dimensional endoscope system for assessing the gastrointestinal
motility. Gastrointestinal diseases are mainly based on the morphological or anatomical abnormity. However,sometimes the gastrointestinal symptoms are apparent without visible abnormalities. Such diseases are called
functional gastrointestinal disorder, for example, functional dyspepsia, and irritable bowel syndrome. One of
the major factors of these diseases is the gastrointestinal dysmotility. Assessment procedures for motor
function are either invasive, or indirect. We thus propose a three-dimensional endoscope system forassessing the gastrointestinal motility. To assess the dynamic motility of the stomach, three-dimensional
endoscopic imaging of stomach lining is performed. Propagating contraction waves are detected bysubtracting estimated stomach geometry without contraction waves from one with contraction waves. After
detecting constriction waves, their frequency, amplitude, and speed of propagation can be calculated. In thisstudy, we evaluate the proposed system. First, we evaluate the developed three-dimensional endoscope
system by a flat plane. This system can measure the geometry of the flat plane with an error of less than 10
percent of the distance between endoscope tip and the object. Then we confirm the validity of a prototype
system by a wave simulated model. The detected wave is approximated by a Gaussian function. In theexperiment, the amplitude and position of the wave can be measure with 1 mm accuracy. These results
suggest that the proposed system can measure the speed and amplitude of contraction. In the future, we
evaluate the proposed system in vivo experiments.
Gastric contraction imaging system using a three-dimensional endoscope
Kayo YOSHIMOTO (Osaka University), Kenji YAMADA (Osaka University), Kenji WATABE (Osaka
University), Maki TAKEDA (Osaka University), Takahiro NISHIMURA (Osaka University), Michiko
KIDO (Osaka University), Toshiaki Nagakura (Osaka Electro-Communication University), Hideya
TAKAHASHI, Tsutomu NISHIDA (Osaka University), Hideki IIJIMA (Osaka University), Masahiko
TSUJII (Osaka University), Tetsuo TAKEHARA (Osaka University), and Yuko OHNO (Osaka University)
IEEE Journal of Translational Engineering in Health and Medicine, Vol.2, 1, pp.1-8 (2014).
Objective: This paper presents a gastric contraction imaging system for assessment of gastric motility using athree-dimensional endoscope. Gastrointestinal diseases are mainly based on morphological abnormalities.
However, gastrointestinal symptoms are sometimes apparent without visible abnormalities. One of the major
factors for these diseases is abnormal gastrointestinal motility. For assessment of gastric motility, a gastricmotility imaging system is needed. Method: To assess the dynamic motility of the stomach, the proposedsystem measures three-dimensional gastric contractions derived from a three-dimensional profile of thestomach wall obtained with a developed three-dimensional endoscope. After obtaining contraction waves,their frequency, amplitude, and speed of propagation can be calculated using a Gaussian function. Results:
The proposed system was evaluated for three-dimensional measurements of several objects with known
geometries. The results showed that the surface profiles could be obtained with an error of less than 10
percent of the distance between two different points on images. Subsequently, we evaluated the validity of a
prototype system using a wave simulated model. In the experiment, the amplitude and position of waves−90−

could be measured with 1-mm accuracy. Conclusions: The present results suggest that the proposed system
can measure the speed and amplitude of contractions. Clinical Impact: This system has low invasiveness andcan assess the motility of the stomach wall directly in a three-dimensional manner. Our method can be used
for examination of gastric morphological and functional abnormalities.

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Applied Chemistry and Bioengineering
Applied Chemistry and Bioengineering
Characterization of Lithium Insertion Electrodes by Precision Dilatometer: Area-Specific Deformationof Single Electrode
Masatoshi NAGAYAMA, Kingo ARIYOSHI, Yuki YAMAMOTO and Tsutomu OHZUKU
J. Electrochem. Soc., Vol. 161, pp. A1388-A1393 (2014)
A dilatometric method to characterize the electrodes in lithium and lithium-ion batteries is described in termsof the deformation of electrodes. A precision dilatometer consists of a main body and a flexible bag cell, in
which a counter electrode is selected to be the zero-strain insertion electrode of lithium titanium oxide (LTO:
Li[Li1/3Ti5/3]O4). Change in thickness of the cell consisting of a target electrode and an LTO electrode ismeasured in a sub-micron scale as a function of area-specific capacity stored or delivered electricity in mAh
cm−2, and the area-specific deformation in μm / (mAh cm−2) is defined as a common measure to evaluate thedeformation or swelling of the electrodes. The method is applied to the electrodes of lithium metal, LTO, andLiNi1/3Mn1/3Co1/3O2. A dilatometer shows ± 4.8 μm / (mAh cm−2) for a lithium metal electrode and nearly 0
μm / (mAh cm−2) for an LTO electrode, indicating that the dilatometer works well to measure the electrode
thickness. A LiNi1/3Mn1/3Co1/3O2 electrode is shown to be dimensionally highly stable, i.e., nearly 0 μm /(mAh cm−2), when it operates under an upper restriction of 4.15 V vs. Li.
Characterization of Lithium Insertion Electrodes: A Method to Measure Area-Specific Impedance ofSingle ElectrodeKensuke NAKURA, Kingo ARIYOSHI, Fujika OGAKI, Kenji TAKAOKA, and Tsutomu OHZUKU
J. Electrochem. Soc., Vol. 161, pp. A841-A846 (2014)
A basic concept on the area-specific impedance (ASI) of a single lithium insertion electrode is described inorder to characterize lithium insertion electrodes. A common electrode selected to measure the ASI is thezero-strain lithium insertion material of lithium titanium oxide (LTO). The ASI of a single LTO electrode inΩcm2 is measured in the state of charge (SOC) ranging from 0 to 100% by using the zero-volt lithium-ion
cell of LTO with a symmetric parallel-plate electrode configuration. Because the ASI of an LTO electrode isempirically known to be independent of SOC ranging from 10 to 90% with a margin of 5%, the impedanceof a cell having any combination with the LTO electrode can be measured at any SOC of a target electrode.
Consequently, the ASI of every lithium insertion electrode can be obtained by the impedance measurements.
Significance of determining the ASI of a single lithium insertion electrode is described in terms ofpolarization and power dissipation generating heat in a full cell, and the methods to characterize lithium
insertion electrodes in a basic research are discussed.
Scanning removal of ion-implanted novolak resist by using a laser irradiation
T. KAMIMURA, Y. KUROKI, T. KIRIYAMA, H. MURAOKA, K. KAWASAKI, T. MURAKAMI, Y.
HARADA, H. KURAMAE, and H. HORIBE
J. Photopolym. Sci. Technol., Vol. 27(2), pp. 237-241 (2014)
Laser resist stripping for the ion-implanted novolak resist was successfully performed without occurring
laser damage to the Si wafer. In order for the advanced laser resist stripping method to be successful, it isimportant for the pulsed laser beam to pass though the ion-implanted resist and absorb into the Si wafer
surface. The novolak resists which are implanted with B, P, and As ions, respectively, were irradiated with apulsed 532 nm laser. Regardless of the implanted ion species and density, more than 74 % of the laser power
was found to absorb into the Si wafer surface. For the laser irradiation of 1 pulse, the ion-implanted resist
with a density of 5.0×1013 atoms/cm2 was completely stripped in the same way as that of a non-implanted
resist. The optical absorption of the resist surface increased as the density of the ion-implantation increased.
In case of the ion-implanted resist with a density of 5.0×1015 atoms/cm2, the resist was stripped by 20 pulses−92−irradiation without occurring laser-induced surface damage. A scanning removal of the highly ion-implanted
resist was also successfully stripped by using an optimized irradiation condition. A highly ion-implanted
resist was continuously stripped by the scanning laser irradiation with 20 pulses.;High removal rate of cross-linked SU-8 resist using hydrogen radicals generated by tungsten hot-wirecatalyze
A. KONO, Y. ARAI, T. MARUOKA, M. YAMAMOTO, Y. GOTO, S. TAKAHASHI, T. NISHIYAMA, and
H. HORIBE
Thin Solid Films, Vol. 562, pp. 632-637 (2014)
This paper discusses the removal of chemically amplified negative-tone i-line resist SU-8 using hydrogenradicals generated by the catalytic decomposition of H2 molecules in H2/N2 mixed gas (H2:N2 = 10:90 vol.%)using a tungsten hot-wire catalyzer. SU-8 resists with exposure doses from 7 to 280 mJ/cm2 were removed byhydrogen radicals, although the SU-8 removal rate was independent of the exposure dose. The SU-8 removal
rate increased with both substrate and catalyzer temperature, in addition to a decrease in the distance between
the catalyzer and substrate. A high removal rate for cross-linked SU-8 with an exposure dose of 14 mJ/cm2 ofapproximately 4 μm/min was achieved with a catalyzer to substrate distance of 20 mm, and catalyzer andinitial substrate temperatures of 2400 and 165 °C, respectively.
Reaction mechanism of polymer removal using wet ozone
Y. GOTO, Y. ANGATA, E. TSUKAZAKI, S. TAKAHASHI, K. KOIKE, T. YAMAGISHI, and H. HORIBE
Jpn. J. Appl. Phys., Vol. 53, p. 02BB04 (2014)
We evaluated the removal of polymers with various chemical structures using wet ozone, and investigated
the reaction mechanism between wet ozone and polymers using fourier-transform infrared (FT-IR) and insitu FT-IR. The removal rate of poly(vinyl phenol) (PVP), which has a carbon–carbon double bond (C=C) inthe side chain was lower than that of the novolak resin, which has C=C in the main chain. Poly(methyl
methacrylate) (PMMA), which has no C=C, was not removed. It was considered that the ozone reaction is anelectrophilic reaction, and the wet ozone should react with C=C with ease. The removal rate of PVP withrinsing was higher than that without rinsing. This result indicates that the reaction products remain on the Si
wafer. However, in the novolak resin, there was no difference between with and without rinsing. It wasconsidered that the main chain of the novolak resin was decomposed to gas by the reaction with wet ozone.
In the FT-IR measurement of PVP, the peak intensity of C=O stretching of carboxylic acid increased withincreasing wet ozone processing time. However, in the novolak resin, there was no difference between withand without rinsing. Moreover, the peak intensity of the C=O stretching of carboxylic acid did not increase
with increasing wet ozone processing time after 10 s of wet ozone processing time. From the result of in situ
FT-IR, in the removal of the novolak resin using wet ozone, the main chain of the novolak resin was
decomposed, and the reaction products of the wet ozone and novolak resin (low-molecular-weight carboxylicacid) should change to CO2.
Sensitivity of a chemically amplified three-component resist containing a dissolution inhibitor for
extreme ultraviolet lithography
H. HORIBE, K. ISHIGURO, T. NISHIYAMA, A. KONO, K. ENOMOTO, H. YAMAMOTO, M. ENDO,
and S. TAGAWA
Polym. J., Vol. 46, pp. 234-238 (2014)
A chemically amplified three-component resist was prepared by adding a dissolution inhibitor as the third
component in an X-ray resist, and its sensitivity and resolution were evaluated for the application in extreme
ultraviolet (EUV) lithography. The chemically amplified three-component resist, which consists of a baseresin, a photo-acid generator (PAG) and a dissolution inhibitor, achieved high sensitivity with an exposure
dose below 10 mJ cm−2. Furthermore, the chemically amplified three-component resist exhibited higher
resolution and sensitivity than a resist without a dissolution inhibitor. The dissolution inhibitor was converted−93−to a dissolution promoter containing carboxylic groups by exposure to EUV light, and it acted as a plasticizerin the resist, resulting in facile diffusion of the protons generated from the PAG. Thus, novel EUV resists
with high sensitivity and resolution could be designed utilizing chemically amplified three-component resist
containing a dissolution inhibitor.
UV-Light Irradiation Effect on Photocatalytic Polymer Sheet Prepared by Solvent Casting Process
S. SONE, M. MAEDA, and H. HORIBE
KOBUNSHI RONBUNSHU, Vol. 70(9)，pp. 496‒501 (2013) (in Japanese)
TiO2 doped poly vinylidene fluoride (PVDF) sheet was prepared by solvent casting process. Both PVDF andTiO2 powders were dissolved in N,N-dimethylformamide (DMF) solution and then spin-coated on the Si or
glass substrate. The flexible TiO2 doped PVDF sheets are transparent and have PVDF II-type crystallinity.
The TiO2 particles distribute in the PVDF sheet with cohesion. Photocatalytic pigment degradation wasobserved when the sheet was irradiated by UV-light. After 840 hours UV-light irradiation, remarkable change
in XRD patterns and FT-IR spectra of the TiO2 doped PVDF sheets was not observed, however, the sheets
became cloudy because the sub-micrometer surface roughness were formed due to local photocatalytic
decomposition of PVDF structure. As a result, the photocatalytic rate of pigment decreased because of
UV-light scattering.
A High Speed Photoresist Removal Process Using Multibubble Microwave Plasma under a Mixture ofMultiphase Plasma Environment
T. ISHIJIMA, K. NOSAKA, Y. TANAKA, Y. UESUGI, Y. GOTO, and H. HORIBE
Appl. Phys. Lett., Vol. 103(14), pp. 142101/1-142101/5 (2013)This paper proposes a photoresist removal process that uses multibubble microwave plasma produced inultrapure water. A non-implanted photoresist and various kinds of ion-implanted photoresists such as B, P,
and As were treated with a high ion dose of 5 × 1015 atoms/cm2 at an acceleration energy of 70 keV; thisresulted in fast removal rates of more than 1 μm/min. When the distance between multibubble microwave
plasma and the photoresist film was increased by a few millimeters, the photoresist removal rates drasticallydecreased; this suggests that short-lived radicals such as OH affect high-speed photoresist removal.
Organotellurium-Mediated Living Radical Polymerization (TERP) of Acrylates Using DitellurideCompounds and Binary Azo Initiators for the Synthesis of High-Performance Adhesive Block
Copolymers for On-Demand Dismantlable Adhesion
Tadashi INUI, Keisuke YAMANISHI, Eriko SATO, and Akikazu MATSUMOTO
Macromolecules, Vol. 46(20), pp. 8111-8120 (2013)
We report the organotellurium-mediated living radical polymerization (TERP) using diphenylditelluride(DT-Ph) and di-n-butylditelluride (DT-Bu) in the presence of a binary azo initiator system consisting of
2,2’-azobis(isobutyronitrile) (AIBN) and 2,2’-azobis(4-methoxy-2,4-dimethylvaleronitrile) (AMVN) withdifferent decomposition rates for the facile synthesis of high-molecular-weight block copolymers containinga polar side group. The block copolymers containing the poly(tert-butyl acrylate) (PtBA) sequence as thereactive segment and the random copolymer sequences of n-butyl acrylate (nBA) or 2-ethyhexyl acrylate(2EHA) with 2-hydroxyethyl acrylate (HEA) as the adhesive segment were synthesized. The concurrent useof the binary initiators was revealed to effectively increase both the polymerization reactivity and themolecular weight of the polymers along with a narrow molecular weight distribution. The produced block
copolymers exhibited high performance for the dismantlable adhesion responsible for the dual external
stimuli consisting of photoirradiation and postbaking in the presence of a photoacid generator.
One-Step Synthesis of Thermally Curable Hyperbranched Polymers by Addition-Fragmentation
Chain Transfer Using Divinyl Monomers
Eriko SATO, Izumi UEHARA, Hideo HORIBE, and Akikazu MATSUMOTO−94−

Macromolecules, Vol. 47(3), pp. 937-943 (2014)
Free radical bulk and solution polymerizations of a divinyl monomer, ethylene glycol dimethacrylate(EGDMA), in the presence of methyl 2-(bromomethyl)acrylate as an addition-fragmentation chain transfer
agent were investigated to synthesize thermally curable hyperbranched polymers by a one-step reaction.
Soluble polymers were obtained up to high conversion of EGDMA, and the molecular weight and molecularweight distribution of the polymers increased with increasing EGDMA conversion. 1H NMR and
MALDI-MS analyses revealed that the soluble polymers were obtained after the consumption of aconsiderable amount of the pendant methacryloyl groups, and one polymer chain contained a number of end
groups indicating the formation of hyperbranched polymers. The isolated hyperbranched polymers
underwent thermal curing above 110 °C without curing agents, and the polymers having a large number of
pendant methacryloyl groups resulted in a significant increase in glass transition temperature, i.e., fromaround room temperature to above 210 °C.
High-Molecular-Weight and Polar Acrylate Block Copolymers as High-Performance Dismantlable
Adhesive Materials in Response to Photoirradiation and Postbaking
Tadashi INUI, Eriko SATO, and Akikazu MATSUMOTO
RSC Adv., Vol. 4(47), pp. 24719-24728 (2014)
We synthesized high-molecular-weight acrylate block copolymers as high-performance dismantlable
adhesives consisting of a poly(tert-butyl acrylate) (PtBA) sequence as the reactive segment and a random
copolymer sequence of n-butyl acrylate (nBA) or 2-ethylhexyl acrylate (2EHA) with 2-hydroxyethyl acrylate(HEA) as the adhesive segment, using an organotellurium-mediated living radical polymerization (TERP).
The adhesion strength of PtBA/P2EHA and PtBA/PnBA block copolymers containing polar HEA repeating
units in their soft segments was sufficiently high for use as a pressure-sensitive adhesive. A quick change in
the adhesion properties was observed in response to the dual external stimuli of photoirradiation andpostbaking during the dismantling process. We discuss the adhesion strength and failure mode as a functionof the HEA content, the sequence structure of the copolymers, and the external stimulus conditions.
Dismantling Behavior of Pressure Sensitive Adhesives Using Acrylic Block and Random Copolymers
in Response to Photoirradiation and Postbaking
Eriko SATO, Kentaro TANIGUCHI, Tadashi INUI, Keisuk. YAMANISHI, Hideo HORIBE, and Akikazu
MATSUMOTO
J. Photopolym. Sci. Technol., Vol. 27(4), pp. 531-534 (2014)
Synthesis, Thermal, Optical, and Mechanical Properties of Sequence-Controlled Poly(1-adamantyl
acrylate)-block-Poly(n-butyl acrylate) Containing Polar Side Group
Yoshinori NAKANO, Eriko SATO, and Akikazu MATSUMOTO
J. Polym. Sci., Part A: Polym. Chem., Vol. 52(20), pp. 2899-2910 (2014)
We prepared the sequence-controlled block copolymers including poly(1-adamantyl acrylate) (PAdA) andpoly(n-butyl acrylate) sequences as the hard and soft segments, respectively, by theorganotellurium-mediated living radical polymerization. The thermal, optical, and mechanical properties of
the adamantane-containing block copolymers with polar 2-hydroxyethyl acrylate (HEA) and acrylic acid(AA) repeating units were investigated. The microphase-separated structures of the block copolymers wereconfirmed by the differential scanning calorimetry and atomic force microscopy observations as well as
dynamic mechanical measurements. The - and -dispersions due to the main-chain and side groupmolecular motions, respectively, of the hard and soft segments were observed. Their transition temperatures
and activation energies increased due to the formation of intermolecular hydrogen bonding by the
introduction of the HEA and AA repeating units. The effects of the hydrogen bonding on their tensile
elasticity, strength, and strain were also evaluated.

−95−

Molecular Interaction of Polymer Side-Chains and Thermoresponsive Properties in Organic Solvent
Eriko SATO
Annual Review of Research Group on Supramolecules, Vol. 34, pp. 6-7 (2013) (in Japanese)
Design of Dismantlable Adhesives Using Reactive Polymers
Eriko SATO and Akikazu MATSUMOTO
Fine chemical, Vol. 43, pp. 5-11 (2014) (in Japanese)
Enhancement of Performance and Functionality of Dismantlable Adhesives by Design of Reactive
Polymer Materials
Eriko SATO
The 135th Regular Meeting of Workshop on Pressure-Sensitive Adhesion, The Adhesion Society of Japan,
Invited Lecture, Tokyo, November 29, 2013 (in Japanese)
Design of Property Changeable Polymer Materials: Functionalization at Interface
Eriko SATO
The 146th Regular Meeting of Tokai Branch of The Society of Polymer Science, Invited Lecture, Nagoya,
December 12, 2013 (in Japanese)
Design of Functional Adhesives Using Reactive Polymers
Eriko SATO
Seibutsu Kougaku Settyaku Nentyaku Renkei Kenkyuukai (Cooperative Workshop on Biology, Engineering,
and adhesives), Invited Lecture, Hiroshima, February 6, 2014 (in Japanese)
Property Transformation of Reactive Polymers and Application to Functional Materials
Eriko SATOThe Regular Meeting of the Consortium of Dismantlable Adhesion, Invited Lecture, Osaka, May 9, 2014 (inJapanese)
Controlled Synthesis of Reactive Polymers and Their Application to Functional Adhesives
Eriko SATO
5th World Congress on Adhesion and Related Phenomena (WCARP-V), Invited Lecture, Nara, November 11,
2014, Proceedings, pp. 39-40
Fundamental Characteristics of Hybrid X-ray Focusing Optics for Micro X-ray Fluorescence Analysis
Shintaro KOMATANI, Kazuo NAKAMACHI, Kazuhiko NAKANO, Sumito OHZAWA, Hiroshi
UCHIHARA, Atsushi BANDO and Kouichi TSUJI
Nucl. Instrum. Methods Phys. Res., Sect. B, Vol. 309, pp. 260-263 (2013)
We developed a hybrid X-ray focusing optics, which consisted of a polycapillary X-ray lens (PCXL) and atungsten conical pinhole (WCP) for micro X-ray fluorescence (μ-XRF) analysis. A single PCXL produced an
X-ray micro beam with a spot size of 12 μm. We developed a WCP by using a laser-ablation technique withan input diameter of 39 μm, an output diameter of 2.5 μm, and a thickness of 0.5 mm in a conical shape. Thishybrid X-ray optics gave a small spot size of 2.8 μm with a small divergent angle of 12 mrad.
Elemental Depth Profiling of Forensic Samples by Confocal 3D-XRF Method
Seiji EMOTO, Kazunori OTSUKI, Kazuhiko NAKANO and Kouichi TSUJI
Advances in X-ray Analysis, Vol. 56, pp. 217-224 (2013)
We report the feasibility of discrimination of leather samples related to forensic science byapplying confocal 3D-XRF method. The laboratory made confocal 3D-XRF has a spatial−96−

resolution of about 14μm at an energy of 11.4 keV. The characteristic elemental depth profiles
and of multilayered leather samples were nondestructively obtained by using confocal 3D-XRF.
Elemental depth profiles showed a layered structure obtained at a certain position on thesample. We tried to classify leather samples (natural, synthetic, and artificial) by cluster
analysis concerning maximum intensity and maximum depth. The cluster analysis regarding
maximum depth and maximum intensity suggested the possibility of discrimination of leather
samples.
Micro X-ray Beam Produced with a Single Glass Capillary for XRF Analysis
Shintaro KOMATANI, Shintaro HIRANO, Tomoki AOYAMA, Yoshihiro YOKOTA, Hideo UEDA andKouichi TSUJI
Advances in X-ray Analysis, Vol. 56, pp. 225-233 (2013)
XRF analysis is available for the quantification of elements and provides a great advantage in materialscience. Although XRF analysis has the advantage of nondestructive analysis, SEM-EDS gives elemental
maps with a spatial resolution of a fewer micrometers. Thus, the developments and applications of
micro-XRF analysis are important research trends of XRF analysis. A single glass capillary lens is theeffective X-ray optics for micro-XRF in the laboratory. Actually, a beam diameter of 10 micrometers isavailable with commercial instruments such as X-ray analytical microscope. In the author's research group, acombination of a single glass capillary and a conical pinhole was studied for improving a spatial resolution ina micro XRF analysis.
In this study, another approach is discussed. We used a micro-focused X-ray tube (focal spot size: 50 x 50
micrometers, Mo anode, 50 kV, 0.5 mA) and a single glass straight capillary evaporated with Au and a small
metal ball (400 μm). The center part of X-rays emitted from the X-ray tube was stopped by the metal ball,while the outer part of X-rays was totally reflected on the inner wall of the single capillary. A focused X-ray
beam had 107.5 μm in diameter, and was observed at a distance of 43 mm from the output of the glass
capillary.
Moreover, the divergence angle of the beam was 6 mrad. This long working distance with low divergenceangle will be a practically useful advantage of this X-ray optic.
Wavelength Dispersive X-ray Fluorescence Imaging using a High-sensitivity Imaging Sensor
Takashi OHMORI, Shuichi KATO, Makoto DOI, Takashi SHOJI and Kouichi TSUJI
Spectrochim. Acta, Part B, Vol. 83-84, pp. 56-60 (2013)
A new wavelength-dispersive X-ray fluorescence (WD-XRF) imaging spectrometer equipped with ahigh-sensitivity imaging sensor was developed in our laboratory. In this instrument, a straight polycapillary
optic was applied instead of a Soller slit as well as a 2D imaging X-ray detector instead of X-ray counters,
which are used in conventional WD-XRF spectrometers. Therefore, images of elemental distribution wereavailable after a short exposure time. Ni Kα images and Cu Kα images were clearly obtained atcorresponding diffraction angles for a short exposure time of 10 s. By optimizing the spectrometer, the timerequired for imaging is reduced, leading to XRF image movies. It is difficult to distinguish two peaks (Ti Kα(4.508 keV) and Ba Lα (4.465 keV)) due to the poor energy resolution of EDXRS. However, Ti and Ba
images could be successfully observed by the WD-XRF imaging spectrometer. The energy resolution of thedeveloped spectrometer was 25 eV at the Ti Kα peak.
Depth-selective Elemental Imaging of MicroSD Card by Confocal Micro-XRF Analysis
Takashi NAKAZAWA and Kouichi TSUJI
X-Ray Spectrom., Vol. 42, pp. 123-127 (2013)
A semiconductor device, a microSD card, was measured by using two XRF instruments. 2D elemental
images were obtained using a micro-XRF system with a spatial resolution of 10mm. Elemental distributionsof the near-surface region of the sample were clearly shown. Titanium was observed in the resin constituting−97−

the sample. Nickel and gold were observed on a terminal and localization of the sample. Elemental
distribution of copper reflected the circuit structure of the measurement area that was in the neighborhood of
the sample surface. Moreover, the elemental depth distributions of the sample were measured by using a
confocal micro-XRF instrument. The confocal micro-XRF instrument was constructed in the laboratory with
fine-focus polycapillary x-ray optics. The depth resolution of the developed spectrometer was 13.7 mm at anenergy of Au Lb (11.4 keV). The elemental images obtained at near-surface by confocal micro-XRF were thesame as the results obtained from 2D micro-XRF. However, different Cu images were obtained at a depth ofseveral tens of micrometers. This indicates that microSD cards consist of a few different Cu-circuit structure
designs. The elemental depth distributions of each circuit structure of the semiconductor device were clearlyshown by confocal micro-XRF.
Development of a High Resolution Confocal Micro-XRF Instrument Equipped with a Vacuum
Chamber
Takashi NAKAZAWA and Kouichi TSUJI
X-Ray Spectrom., Vol. 42, pp. 374-379 (2013)
A confocal micro-X-ray fluorescence (micro-XRF) instrument equipped with a vacuum chamber was newly
developed. The instrument is operated under a vacuum condition to reduce the absorption of XRF in theatmosphere. Thin metal layers were developed to evaluate the confocal volume, corresponding to depth
resolution. A set of thin metal layers (Al, Ti, Cr, Fe, Ni, Cu, Zr, Mo, and Au) was prepared by a magnetron
sputtering technique. The depth resolutions of the new instrument were varied from 56.0 to 10.9 µm for anenergy range from 1.4 to 17.4 keV, respectively. The lower limit of detection (LLD) was estimated bycomparison with a glass standard reference material NIST SRM 621). The LLDs obtained by a conventional
micro-XRF were compared with the LLDs obtained by a confocal micro-XRF instrument. The LLDs were
improved in the measurement under confocal configuration because of the reduction of background intensity.
Finally, layered materials related to forensic investigation were measured. The confocal micro-XRF
instrument was able to nondestructively obtain the distribution of light elements that cannot be detected bymeasurement in air.
SEM Observation of Inclusions in Steel Samples after Fast Surface Cleaning by Glow Discharge
Kouichi TSUJI and Kenichi SHIMIZUISIJ International, Vol. 53, pp. 1936-1938 (2013)
SEM (scanning electron microscopy) is a useful technique for the observation of the surface morphology ofvarious materials. Compared to TEM (transmission electron microscope), one of the advantages of SEM iseasy sample preparation, although the spatial resolution of SEM is normally less than that of TEM. To
improve the spatial resolution of SEM observation, it is well known that a low accelerating voltage SEM isan effective technique. We have proposed the application of glow discharge surface treatment before
high-resolution SEM observation. An rf-glow discharge was applied with Ar gas for a steel sample just for 6
sec., leading to surface cleaning, that is, removing the surface oxidation or contamination layer. Besides thesurface cleaning, a glow discharge sputtering modified the surface of the steel sample depending on crystal
orientation. This surface modification was useful for high-resolution SEM observation. The surface of thesteel sample was observed by FE (field emission)-SEM with a low accelerating voltage. A fine structure ofgrains and inclusions in the sample was clearly observed. The density of the inclusions was roughly
determined as being 4 × 104/cm2.
X-Ray Elemental Imaging in Depth by Combination of FE-SEM-EDS and Glow Discharge Sputtering
Fumiya ONOUE and Kouichi TSUJIISIJ International, Vol. 53, pp. 1939-1942 (2013)
SEM-EDS is a powerful tool for fast, nondestructive x-ray elemental analysis of a localized region.
Elemental mapping is also possible by scanning the electron beam. Since the penetration depth of the−98−

electron beam is about a few μ m, SEM-EDS is useful for determining elemental composition near thesurface of the sample. To obtain information regarding the depth of the sample, the surface layer must be
removed. For this purpose, we attempted to use glow discharge sputtering. A commercially available rf glow
discharge sputtering device (Horiba, Tensec) enables fast sputtering in an area 4 mm in diameter. The
combination of SEM-EDS and glow discharge sputtering would be useful for observation of the distributionof inclusions buried in metal samples. Al2O3 particles were mixed with Cu powders, and then pressed into adisk, which was measured. The same area of the sample was analyzed by FE-SEM-EDS and sputtered. The
result indicated the possibility of 3D distribution analysis of inclusions in the sample.
Elemental Depth Analysis of Corroded Paint-Coated Steel by Confocal Micro-XRF Method
Kazuhiko NAKANO, Koji AKIOKA, Takashi DOI, Masahiro ARAI, Hideki TAKABE and Kouichi TSUJIISIJ International, Vol. 53, pp. 1953-1957 (2013)
A confocal micro-XRF method combined with two individual polycapillary lenses was applied to steel sheetscoated with anti-corrosive paint in order to nondestructively observe 3D elemental distribution of paint steels
and corroded paint-coated steels. Nondestructive depth analysis and 3D elemental mapping of the painted
steel sheets were demonstrated under the confocal XRF configuration. Three different painted steel sheets
were prepared by cation electrodeposition coating for automotive onto flat steel sheets modified with a zinc
phosphate conversion coating. These painted sheets were then caused to corrode by means of accelerated
exposure to a salt bath (5 mass% NaCl) at 55°C for 240 hours. Depth elemental profiles of Ti, Zn, and Fe
obtained by confocal micro-XRF measurements were in excellent agreement with that of the preparedsample. Elemental depth profiles and maps of the corroded painted sheets showed some blisters caused bycrevice corrosion, which started from the site of a scratch. The distributions of Ti and Fe were approximately
homogeneous in both the paint layer and the steel substrate, while the distributions of Zn, Mn, Ca, and Cl
were heterogeneous.
X-ray Fluorescence Imaging
Kouichi TSUJI
Journal of the Spectroscopical Society of Japan, Vol. 62, pp. 119-127 (2013) (in Japanese)
X-ray Fluorescence (XRF) analysis is a powerful tool for elemental analysis of solid and liquid samples.
Compared to other instrumental analytical methods, such as SEM-EDS, XRF analysis has an advantage of
nondestructive analysis at ambient air pressure. XRF analysis at small region is possible with advanced x-ray
focusing optics in the laboratory. This micro-XRF technique with scanning the sample gives us elemental
images. The spatial resolution of micro-XRF depends on the size of the x-ray beam. The drawback of
micro-XRF for elemental imaging would be its long acquisition time for a large sample with high-resolution.
On the other hand, projection type XRF imaging has been studied using a two-dimensional x-ray detector.
The advantage of this projection type technique is a fast elemental imaging. ln this paper, scanning type andprojection type XRF imaging techniques will be discussed showing recently developed instruments based on
wavelength dispersive and energy dispersive x-ray spectrometers.
Development and Evaluation of Micro XRF Instrument with Hybrid X-Ray Optics
Junki MATSUYA and Kouichi TSUJI
Advances in X-Ray Chemical Analysis, Japan, Vol. 44, pp. 111-119 (2013) (in Japanese)
We developed a micro-XRF instrument with a hybrid X-ray optic in order to obtain an intense micro X-ray
beam in laboratory. The hybrid X-ray optic consists of the polycapillary X-ray lens and the Zr pinhole. The
Zr pinhole, which was inserted between the X-ray tube and the polycapillary X-ray lens, was useful for
reducing the spot size of micro X-ray beam. In addition, the divergence of micro X-ray beam was reduced byapplying the Zr pinhole with a diameter of 400 μm. Moreover, SB ratio of X-ray fluorescence was also
improved by using the Zr pinhole.

−99−

Catalytic Hydrothermal Oxidation of p-Chlorophenol with Cu or Fe-Grafted TiO2. Enhanced
Decomposition by Fenton-Type Reaction
Ai SHIMOKAWA, Hiroki HONDA, Kyohei NAKAO, and Noritsugu KOMETANIJournal of Chemical Engineering of Japan, Vol. 46, No. 12, pp. 821–826 (2013)
Catalytic hydrothermal oxidation of p-chlorophenol has been examined using two types of reactor systems,
i.e., a flow-type reactor system in which the catalyst powder was suspended in the reaction mixtures and afixed-bed reactor system in which the sintered catalyst was packed in the reactor. Cu- or Fe-grafted TiO2 was
employed as a catalyst and hydrogen peroxide was used as an oxidizing reagent. The decomposition
efficiency of p-chlorophenol treated by the flow-type reactor system is considerably enhanced with the helpof Cu-grafted TiO2 at reaction temperatures around 200°C; whereas, little effect is observed at any
temperature for Fe-grafted TiO2. It is suggested that the Fenton-type reaction catalyzed by Cu ions containedin the Cu-grafted TiO2 and/or dissolved out in the solution undergoes substantial acceleration at hightemperatures, leading to the increased generation of OH· radicals that can effectively oxidize p-chlorophenol.
On the other hand, it appears that the Fe-ion-catalyzed Fenton reaction is suppressed in the hydrothermal
environment. The prolonged treatment of p-chlorophenol using the fixed-bed reactor system, that is moresuitable for practical use than the flow-type one, has also been performed with Cu-grafted TiO2 catalyst at areaction temperature of 200°C. The result demonstrates that it is possible to treat p-chlorophenol
continuously for up to 36 h without significant loss of the catalytic activity.
Spectroscopic Study of Solvation Properties of Room-Temperature Ionic Liquids and Solvent Effect on
Bimolecular Fluorescence Quenching Reaction at High Pressures
Noritsugu KOMETANI and Yoshinori MINAMIKAWA
Review of High Pressure Science & Technology, Vol. 23, No. 4, pp. 332-338 (2013)
The solvation properties of some room-temperature ionic liquids (RTILs) and the solvent effect onbimolecular fluorescence quenching reaction have been examined at high pressures ranging from 0.1 to 300
MPa. It is found that Kamlet-Taft parameters (π*, β) are sensitive to the type of anions, but not so dependent
on the type of imidazolium cations consisting of RTILs. The pressure dependence of microviscosity is foundto obey the empirical power-law equation. It is revealed that the rate constant for bimolecular fluorescencequenching reaction is significantly higher than theoretical rate constant of diffusion estimated frommicroviscosity, suggesting the occurrence of microscopic free space within RTILs which may facilitate thesolute diffusion.
In Situ Observation of Heat- and Pressure-Induced Gelation of Methylcellulose by Fluorescence
Measurement
L. SU, Z. WANG, K. YANG (Zhengzhou Univ. of Light Industry), Y. MINAMIKAWA, N. KOMETANI, and
K. NISHINARI (Hubei Univ. of Technology)
International Journal of Biological Macromolecules, Vol. 64, pp. 409-414 (1014)
In situ observation of heat- and pressure-induced gelation of methylcellulose (MC) aqueous solution has
been studied by using dynamic viscoelastic and fluorescence measurements. The storage modulus G’decreased gradually first on heating, and then leveled off in the temperature range from 25°C to
75°C.Methylcellulose solutions were subjected to pressures up to 450 MPa by using a high pressure cell. It
was indicated that the microviscosity showed a dramatic change in the vicinity of the phase transition point.
The T vs. P phase diagram of methylcellulose aqueous solution was constructed, and it indicated that themelting point was an increasing function of pressure. In situ microscopic observation of pressure-induced
gelation of methylcellulose aqueous solution was also performed with a microscope, and it could be seen thatgel phase of the sample disappeared and sol formed gradually. Pressure-released study by fluorescencemeasurement also showed that the phase transition of MC solution was reversible.
CrystalThickness

Dependenceof

Photoinduced−100−

CrystalBendingof

1,2-Bis(2-methyl-

5-(4-(1-naphthoyloxymethyl)phenyl)-3-thienyl)perfluorocyclopentene
Daichi KITAGAWA and Seiya KOBATAKE
J. Phys. Chem. C, Vol. 117(40), pp. 20887−20892 (2013)
The photoinduced crystal bending of a photochromic diarylethene derivative, 1,2-bis(2-methyl5-(4-(1-naphthoyloxymethyl)phenyl)-3-thienyl)perfluorocyclopentene (1a), has been particularly
investigated. The rod-like crystal of 1a shows reversible photoinduced bending upon alternating irradiation
with ultraviolet (UV) and visible light. The photoinduced crystal bending can be repeated over 80 cycles.
The rod-like crystal of 1a shows different bending behavior depending on the faces irradiated with UV light.
This is ascribed to the molecular orientation viewed from the faces. Furthermore, we found that the bending
speed depends on the crystal thickness and the curvature change against the crystal thickness is well fitted to
Timoshenko’s bimetal model. These findings provide a new useful strategy to design for thephotomechanical actuators.
Alkyl Substituent Effects in Photochemical and Thermal Reactions of Photochromic
Thiophene-S,S-Dioxidized Diarylethenes
Hiroaki SHOJI, Daichi KITAGAWA, and Seiya KOBATAKENew J. Chem., Vol. 38(3), pp. 933−941 (2014)
Thiophene-S,S-dioxidized diarylethenes introducing various alkyl groups at the reactive positions were
newly synthesized. The diarylethenes showed reversible photochromism, whereas the photocycloreversion
reaction was suppressed by thiophene-oxidation. The diarylethene closed-ring isomers with secondary alkyl
groups at the reactive positions were found to undergo thermal bleaching reactions to produce byproducts.
The thermal bleaching reactions were accelerated by introducing a more bulky substituent at the reactive
positions. The relationship between the rate constant of the thermal bleaching reactions and the bulkiness ofthe substituent at the reactive positions can be correlated using a steric substituent constant. Moreover, it wasnoted that introduction of a methyl group at the 4-position of the thiophene in the oxidized diarylethenes
accelerates the thermal byproduct formation. The rate of the thermal bleaching reactions was found todepend on the difference in the ground state energy between the closed-ring isomer and one of the
byproducts, as can be estimated by theoretical calculation of the energy level. Such materials can be used inapplication such as light-starting irreversible thermosensors.
Thermodynamic Phase Transition Through Crystal-to-Crystal Process of Photochromic 1,2-Bis(5phenyl-2-propyl-3-thienyl)perfluorocyclopentene
Daichi KITAGAWA and Seiya KOBATAKE
Chem. –Asian J., Vol. 9(1), pp. 289−293 (2014)
A photochromic diarylethene, 1,2-bis(5-phenyl-2-propyl-3-thienyl)perfluorocyclopentene (1a), was found tohave two polymorphic crystal forms, - and -crystals. From X-ray crystallographic analysis, the spacegroups of - and -crystals are P21/c and C2/c, respectively. The difference between two crystal forms is
ascribed to orientation of two of four molecules in the unit cell. The thermodynamic phase transition from to -forms occurred via a crystal-to-crystal process, as confirmed by differential scanning calorimetry
measurement, optical microscopic observation in reflection mode and under crossed nicols, and powder
X-ray diffraction profile. The movement of the molecules in the crystal was evaluated by the change of faceindices before and after the phase transition.
Crystal Thickness Dependence of Photoinduced Crystal Bending of 1-(5-Methyl-2-(4-(p-vinylbenzoyloxymethyl)phenyl)-4-thiazolyl)-2-(5-methyl-2-phenyl-4-thiazolyl)perfluorocyclopentene
Daichi KITAGAWA and Seiya KOBATAKE
Photochem. Photobiol. Sci., Vol. 13(5), pp. 764−769 (2014)Rod-like crystals of 1-(5-methyl-2-(4-(p-vinylbenzoyloxymethyl)phenyl)-4-thiazolyl)-2-(5-methyl-2-phenyl4-thiazolyl)perfluorocyclopentene with lengths of over 1 mm showed photoreversible bending over 100−101−cycles upon irradiation with alternating ultraviolet (UV) and visible light. The crystals bent toward theincident light due to a contraction of the crystal length and a gradient of the crystal thickness, which dependon the extent of photoisomerization. It was observed that the bending speed depends on the crystal thickness,and the curvature change on changing the crystal thickness agrees well with Timoshenko’s bimetal model, as
well as with the observation that crystals of 1,2-bis(2-methyl-5-(4-(1-naphthoyloxymethyl)phenyl)3-thienyl)perfluorocyclopentene bend away from the incident light due to an expansion of the crystal lengthand a gradient of the crystal thickness, which depend on the extent of photoisomerization. It was revealed
that Timoshenko’s bimetal model can be applied to photoinduced crystal bending behaviors caused by bothcontraction and expansion. These findings are very useful for evaluating and designing photomechanicalactuators.
Photoresponsive Molecular Machinery of Photochromic Diarylethene Crystals
Seiya KOBATAKE and Daichi KITAGAWA
Joint Congress of Asian Crystallization Technology Symposium-2014 (ACTS-2014) and 11th International
Workshop on Crystal Growth of Organic Materials (CGOM11), Invited Oral Communication, OC-CGOM-31,
Nara, Japan, June 17−20, 2014; Abstract, CD-ROM, OC-CGOM-31 (2014)
Some diarylethene derivatives are designed and synthesized for study on the photoinduced crystal shapechanges. Upon irradiation with UV light to the diarylethene crystals, the molecules in the crystals underwent
a photocyclization reaction that transforms the initial open-ring isomers into the photogenerated closed-ringisomers. The rod-like crystal of diarylethene 1a showed the crystal bending away from the incident UV light.
The bent crystal returned to the initial straight crystal by irradiation with visible light. The bending speed
depended on the crystal thickness and the curvature change against the crystal thickness was well fitted to
Timoshenko’s bimetal model. The rod-like crystal of diarylethene 2a bent toward the incident UV light. The
bending speed also depended on the crystal thickness and the curvature change against the crystal thickness
was well fitted to Timoshenko’s bimetal model. Furthermore, we have found specific crystal ribbon
deformation of diarylethene 3a. This crystal reversibly changed from the straight thin crystal to the spiral
crystal. Such deformation depends on the crystal packing. These materials can be potentially applied fornovel organic solid devices, and it is possible not only to become a new organic device but also to open a
new possibility as the crystal materials.
Polymorphism and Phase Transition between Polymorphic Forms of Photochromic Diarylethene
Crystals
Daichi KITAGAWA and Seiya KOBATAKE
Joint Congress of Asian Crystallization Technology Symposium-2014 (ACTS-2014) and 11th International
Workshop on Crystal Growth of Organic Materials (CGOM11), Poster Presentation, PC-22, Nara, Japan,
June 17−20, 2014; Abstract, CD-ROM, PC-22 (2014)
Diarylethene 1a was found to have two polymorphic crystal forms, - and -crystals. From X-ray
crystallographic analysis, the space groups of - and -crystals were determined to be P21/c and C2/c,
respectively. The difference between two crystal forms is ascribed to the orientation of two of four moleculesin the unit cell. The thermodynamic phase transition from - to -forms occurred via a crystal-to-crystal
process, as confirmed by differential scanning calorimetry measurements, optical microscopic observationsin the reflection mode and under crossed Nicols, and powder X-ray diffraction measurements. The
movement of the molecules in the crystal was evaluated by analyzing the change of face indices before andafter the phase transition. A photochromic diarylethene crystal of 2a was found to undergo a thermodynamic
phase transition from plate-like -crystal to needle-like -crystal at 180 C. The phase transition involves
melting of the initial -crystal and growth of the -crystal. The phase transition temperature decreased withthe presence of the closed-ring isomer (2b) in the crystal because of the decrease in the melting temperature.
Upon irradiation with ultraviolet (UV) light, compound 2a in the -crystal was converted into 2b to an
extent of 20%. Consequently, the -crystal containing 20% of 2b underwent the phase transition−102−

accompanied by melting of the crystal and growth of the -crystal even at 170 C. Photomicropatterning by
the phase transition upon irradiation with UV light using a photomask, followed by heating at 170 C, wassuccessfully accomplished with a resolution in the microcrystalline pattern of about 20 m.
Photoresponsive Molecular Machinery of Photochromic Diarylethene Crystals
Seiya KOBATAKE and Daichi KITAGAWA
Joint Congress of Asian Crystallization Technology Symposium-2014 (ACTS-2014) and 11th International
Workshop on Crystal Growth of Organic Materials (CGOM11), Poster Presentation, PC-49, Nara, Japan,
June 17−20, 2014; Abstract, CD-ROM, PC-49 (2014)
Some diarylethene derivatives are designed and synthesized for study on the photoinduced crystal shapechanges. Upon irradiation with UV light to the diarylethene crystals, the molecules in the crystals underwent
a photocyclization reaction that transforms the initial open-ring isomers into the photogenerated closed-ringisomers. The rod-like crystal of diarylethene 1a showed the crystal bending away from the incident UV light.
The bent crystal returned to the initial straight crystal by irradiation with visible light. The bending speed
depended on the crystal thickness and the curvature change against the crystal thickness was well fitted to
Timoshenko’s bimetal model. The rod-like crystal of diarylethene 2a bent toward the incident UV light. The
bending speed also depended on the crystal thickness and the curvature change against the crystal thickness
was well fitted to Timoshenko’s bimetal model. Furthermore, we have found specific crystal ribbon
deformation of diarylethene 3a. This crystal reversibly changed from the straight thin crystal to the spiral
crystal. Such deformation depends on the crystal packing. These materials can be potentially applied fornovel organic solid devices, and it is possible not only to become a new organic device but also to open a
new possibility as the crystal materials.
Photoinduced Bending Behavior of Diarylethene Crystals
Daichi KITAGAWA and Seiya KOBATAKEXXVth IUPAC Symposium on Photochemistry, Poster Presentation, P151, Bordeaux, France, July 13−18,
2014; Abstract, CD-ROM, P151 (2014)
We have focused on the quantitative evaluation of photoinduced crystal bending among various diarylethene
derivatives. All of diarylethenes 1−5 showed the photoinduced crystal bending behavior caused by expansion
and contraction of the photoreacted crystal surface and the dependence on the crystal thickness in theirbending speed. The correlation between the initial speed of the curvature change and the crystal thickness inall of the diarylethene crystals can be explained by Timoshenko’s bimetal model. When the thickness ofphotoreacted layer (h2) in bimetal model is the same among different crystals, the bending speed can becompared quantitatively using the value of actuation strain . In most cases, it cannot be discussed because
the h2 values are different. Then, we focused on the relationship between h2 and  in the same crystal. As aresult, it was theoretically and experimentaly clarified that the value of  is proportional to 1/h2. By using
this relationship, the effect of h2 on the value of  can be normalized. In other words, the slope of a line
through the origin in the relationship between  and 1/h2 is the unique value in each crystal. The relative
bending speed was determined to be 1.00 (1), 0.65 (2), 1.22 (3), 1.98 (4), and 2.96 (5). The values mean therelative potential capability of the photoinduced crystal bending speed in the diarylethene crystals.
Photoresponsive Bending and Twisting of Photochromic Diarylethene Crystals
Seiya KOBATAKE and Daichi KITAGAWA
XXVth IUPAC Symposium on Photochemistry, Poster Presentation, P171, Bordeaux, France, July 13−18,
2014; Abstract, CD-ROM, P171 (2014)
Diarylethene derivatives are designed and synthesized for study on the photoinduced crystal shape changes.
Upon irradiation with UV light to the diarylethene crystals, the molecules in the crystals underwent a
photocyclization reaction that transforms the initial open-ring isomers into the photogenerated closed-ringisomers in the crystalline phase. The rod-like crystal of diarylethene 1a showed the crystal bending away−103−

from the incident UV light. The bent crystal returned to the initial straight crystal by irradiation with visible
light. The bending speed depended on the crystal thickness and the curvature change against the crystal
thickness was well fitted to Timoshenko’s bimetal model. The rod-like crystal of diarylethene 2a bent toward
the incident UV light. The bending speed also depended on the crystal thickness and the curvature change
against the crystal thickness was well fitted to Timoshenko’s bimetal model. Furthermore, we have foundspecific crystal ribbon deformation of diarylethene 3a. This crystal reversibly changed from the straight thincrystal to the spiral twisting crystal. Such deformation depends on the crystal packing. These materials canbe potentially applied for novel organic solid devices, and it is possible not only to become a new organic
device but also to open a new possibility as the crystal materials.
Preparation and Photoinduced Bending Behavior of Diarylethene Microfibers
Hajime TSUJIOKA and Seiya KOBATAKEXXVth IUPAC Symposium on Photochemistry, Poster Presentation, P238, Bordeaux, France, July 13−18,
2014; Abstract, CD-ROM, P238 (2014)
When the microfiber was irradiated with ultraviolet light from the left side, the microfiber was found to bebent in the direction toward the incident light. The bent fibers did not return to the initial-shaped fibers by
irradiation with visible light. To examine the preparation condition of the microfibers, the microfibers wereprepared by stretching each of the melting viscous at 95 °C and 125 °C. The bending speed was increased by
the preparation at 95 °C compared to 125 °C. When the microfiber was observed by polarizing microscopy
under crossed Nicols, the birefringence was confirmed. From observations of the birefringence, thismicrofiber was found to be optically positive uniaxial material. The birefringence means that thediarylethene molecules were oriented in the microfiber. This orientation was improved by the preparation at
95 °C compared to 125 °C. These results suggest that the orientation of molecules relates to photoinduced
bending behavior of microfibers. This molecular orientation in the microfiber was not disturbed by UV
irradiation, but was disturbed by visible light irradiation after UV light irradiation.
Amazing Catalytic Activity of Epi-Quinine-Derived 3,5-Bis(trifluoromethyl)benzamide in Asymmetric
Nitro-Michael Reaction of Furanones
Tohru SEKIKAWA, Takayuki KITAGUCHI, Hayato KITAURA, Tatsuya MINAMI, and Yasuo HATANAKA
J. Am. Chem. Soc., accepted
Unusually high catalytic activity of novel epi-quinine-derived 3,5-bis(CF3)benzamide in the asymmetricnitro-Michael reaction is described. With 0.1-5 mol % loadings of this catalyst, the addition of
5-substituted 2(3-H)furanones to a wide range of nitroalkenes involving traditionally challenging substrates,
-alkyl nitroalkenes smoothly proceeded, giving the Michael adducts in high yields (> 90%) with excellent
diastereo- and enantioselectivity (> 98 : 2 dr, syn major; 90-98% ee). DFT calculation was carried out toaccount the high catalytic activity.
Bell-Shaped Dependence of the Rate of Ultrafast Photoinduced Electron Transfer from AromaticAmino Acids to the Excited Flavin on the Donor–Acceptor Distance in FMN Binding Proteins
Nadtanet NUNTHABOOT, Kiattisak LUGSANANGARM, Somsak PIANWANIT, Sirirat KOKPOL, Fumio
TANAKA, Seiji TANIGUCHI, Haik CHOSROWJAN, Takeshi NAKANISHI, and Masaya KITAMURA
Comput. Theor. Chem., Vol. 1030, pp. 9–16 (2014)
Flavin mononucleotide (FMN)-binding proteins (FBP) from Desulfovibrio vulgaris, Miyazaki F, contain
FMN as a cofactor. Upon photo-excitation of the FBP, photoinduced electron transfer (ET) takes place fromtryptophan (Trp)32, tyrosine (Tyr)35 and Trp105 residues to the excited isoalloxazine ring (Iso∗) of FMN.
The ultrafast fluorescence dynamics of the wild type, and the E13K, E13R, E13T and E13Q substitution
isoforms of FBP were simultaneously analyzed with molecular dynamics simulation structures andKakitani-Mataga ET theory, to obtain the time-dependent ET rates. A bell-shaped behavior of the logarithmic
ET rates (InkET) from Trp32 and Trp106 to Iso∗ versus the centre-to-centre donor–acceptor distances (Rc) was−104−

obtained in the time domain of sub-ps to ps in all five FBP isoforms. The InkET from Tyr35 to Iso∗ linearlydecreased with the Rc distance, which were much slower than those of Trp32 and Trp105. These findings
suggest that the nuclear term in the ET theory is important in the ultrafast time domain, whereas theelectronic coupling term may be dominant in slower ET rates.
Crystallization Behavior of Ibuprofen under Microwave Irradiation
K. IGARASHI, S. KIHARA and H. OOSHIMA
Journal of Chemical Engineering of Japan, Vol. 46, pp. 797–801 (2013)
The batch cooling crystallization of the organic compound, ibuprofen, was carried out under 2.45 GHz
microwave irradiation. n-Hexane containing a small amount of acetone (5 mol%) and FluorinertTM, which
did not absorb microwave, were selected as the solvent and coolant circulating through the jacket of
crystallizer, respectively. The ibuprofen-hexane solution was cooled from 40 to −1°C under microwave
irradiation and no irradiation. When the solution was not irradiated to the solution, ibuprofen crystals
appeared at 35°C. On the other hand, when irradiation with 300 W microwave was carried out, nucleation
did not occur even when the solution temperature reached to −1°C. At that time, the supersaturation ratio
was 9.5. Thus, crystal nucleation of ibuprofen was inhibited by the microwave irradiation. The effect of
microwave irradiation continued for at least 100 min after the irradiation was stopped at −1°C. By adding asmall amount of crystals to the highly supersaturated solution, small crystals with a narrow size distribution
were produced.
Structure of supersaturated solution and crystal nucleation induced by diffusion
H. OOSHIMA, K. IGARASHI, H. IWASA, R. YAMAMOTO
Journal of Crystal Growth, Vol. 373, pp. 2-6 (2013)
The effect of a seed crystal on nucleation of L-alanine from a quiescent supersaturated solution wasinvestigated. When a seed crystal was not used, nucleation did not occur at least for 5 h. When a seed crystal
was introduced into the supersaturated solution with careful attention to avoid convection of the solution,fine crystals appeared at the place far from the seed crystal. At that time, there was no convection at the placethat fine crystals appeared. Namely, there was no possibility that those fine crystals came from the surface of
seed crystal. We supposed that nucleation was induced by directional diffusion of solute molecules causedby growth of the seed crystal. In order to prove this hypothesis, we designed an experiment using anapparatus composed of two compartments divided by a dialysis membrane that L-alanine molecules could
freely permeate. Two supersaturated solutions having a supersaturation ratio of 1.2 and a smaller ratio wereplaced in the two compartments in the absence of seed crystals. This apparatus allowed the directional
diffusion of solute molecules between two solutions. Nucleation occurred within 30 min. The frequency of
nucleation among 7-times repeated experiments was in proportion to the difference of supersaturation ratio
between the two solutions. This result poses a new mechanism of the secondary nucleation that thedirectional diffusion caused by growth of existing crystals induces nucleation.
Effect of a Small Amount of Water on Crystallization of Ergosterol
K. NAKAHASHI, K. IGARASHI, and H. OOSHIMA
Joint Congress of ACTS-2014 and CGOM11, Nara, Japan (2014)
Many of organic or inorganic compounds crystallize as a hydrate or a solvate form. In industrial
crystallization, the control of hydrate is important as well as control of polymorphs. For example, in thecooling crystallization of Ergosterol (ERG) from the hexane solution, two types of precipitates may appear,
namely mono hydrate crystal and globular amorphous form. In the case that enough amount of water exists
in the solution (> 1173 ppm), the needle-like monohydrate crystals can be obtained. However, the watercontent is insufficient, only amorphous form precipitates. Fig.1 shows SEM images of the ERG mono
hydrate crystals and amorphous. In this study, the effect of the water content in the solution on the coolingcrystallization of ERG mono hydrate was investigated. Though water hardly dissolves in hexane (~ 20 ppm),−105−

more water can dissolve in the ERG-hexane solutions. It means that the water molecules interact with the
ERG molecules in hydrophobic environment. To control the activity of water in the solution, a small amountof 2-propanol (IPA) was added to the solution. Fig. 2 shows XRD profiles of crystals obtained from thesolution with different content of IPA. The XRD of crystals decreased increase of the IPA content. It
suggested that the water molecules interact with the IPA molecules instead of the ERG molecules. Theinteraction between water and IPA molecules was investigated by Isothermal titration calorimetry.
Development of a novel fines dissolver to produce uniform large crystals
K. IGARASHI, M. ARIMOTO, H. OOSHIMA
Joint Congress of ACTS-2014 and CGOM11, Nara, Japan (2014)
In the industrial crystallization, there are many characteristics of product crystals that must be well controlled.
Crystal size distribution (CSD) is one of the most important characteristics of crystals. In many cases, large
crystals with a narrow CSD are preferred to make filtration easy. Various methods have been attempted toobtain uniform large crystals. As an effective solution, we have proposed the WWDJ-batch crystallizer,
which can dissolve undesirable fine crystals on the heated inner wall of the head space of crystallizer. In thepresent paper, we propose a novel batch crystallizer suitable for production of large and uniform crystals.
The crystallizer is composed of a jacketed-glass vessel, a newly developed fines-dissolver equipped with an
induction-heating (IH) system, and an agitation propeller (Fig.1). The fines-dissolver is a connected body ofa stainless-steel cylinder and a circular truncated cone at lower side. It was set on a coaxial rotation rod withan agitation propeller. The rotation speed of the dissolver and the agitation propeller can be individuallycontrolled. The lower end of the dissolver is placed in crystallization solution at a given depth from solution
level. To heat the fines-dissolver, the IH coil sealed from crystallization slurry is put around thefines-dissolver. The rotating fines-dissolver was directly heated by a high-frequency alternating current flows
through the IH coil. The slurry is lifted up along the inner wall of the heated fines-dissolver by thecentrifugal force, and is returned to the crystallization phase from the top of the dissolver. Fine crystals in thelifted slurry can be expected to partially dissolve. The surviving large crystals are also expected to growfurther, at the expense of fine crystals, after returning to the crystallization phase. Using the novel crystallizer,
cooling crystallization of glycine was performed by controlling the temperature from 50 to 25˚C at the initialconcentration of glycine of 268 mg/ml. The performance of the crystallizer was compared with that of aconventional batch cooling crystallization without the fines-dissolver. The average particle size obtained in aconventional crystallization was 622 µm. On the other hand, when the novel crystallizer was used, theaverage size of crystals was 1544 µm.
Kojic Acid-Appended Carborane/Hydroxypropyl--Cyclodextrin Complex: A Novel Boron Carrierfor Melanoma Targeting
Riku KAWASAKI, Takeshi NAGASAKI, Jiawei LI, Hideki AZUMA, Shin-ichiro MASUNAGA, Mitsunori
KIRIHATA, Yoshihide HATTORI and Naoyuki KADONOKURRI Progress Report 2011, pp. 107 (2012)
Metastatic melanoma remains s highly lethal cancer. BNCT has been attracted great deal of attention as apotentially useful modality for this disease. The delivery of 10B compounds deeply inside the tumor cells and,possibly, close the nucleus is also an important requirement in order to improve the efficacy of BNCT. Kojicacid is well known to work as an excellent whitening agent for melanocytes by a strong tyrosinase inhibition.
This fact suggests that kojic acid possess a specific affinity for melanocytes. In this paper, we evaluate kojic
acid-appended o-carborane (CKA) as BNCT boron agent for melanoma. It was found that CKA has
melanoma affinity based on possessing of kojic acid moiety although detail mechanism is unclear yet. In
B16BL6 cells, CKA was interestingly localized in the nucleus.
Intracellular Distribution
Carcinoma-Bearing Miceof

BSH-Appended

Polyamine

−106−

at

Tumor

Tissue

of

Colon

26

Masayuki UMANO, Jiawei LI, Hideki AZUMA, Takeshi NAGASAKI, Hironobu YANAGIE, Mitsunori
KIRIHATA, Koji ONO, Shin-ichiro MASUNAGA and Yoshinori SAKURAIKURRI Progress Report 2011, pp. 274 (2012)
The neutron irradiation experiment by using polyion complex nanoparticle composed of
mercaptoundecahydrododecaborane-appended high molecular weight polyamine (BPP) showed suppressive
effect for the tumor growth in colon 26 carcinoma-bearing mice. Although the boron concentration at tumor
tissue was less than 10 ppm, the sufficient BNCT effect was observed. Here, we report the intracellular
distribution of fluorescently labeled BPP and BSH residues introduced into the polymeric carrier using an
immunostaining with anti-BSH antibody. BPP remain at perinuclear regions. The intracellular distribution inwhich BSH is close to genome DNA might contribute higher BNCT efficacy by BPP complex.
Kojic Acid-Appended Carborane/Hydroxypropyl--Cyclodextrin Complex for BNCT of Murine
Melanoma
Riku KAWASAKI, Takeshi NAGASAKI, Jiawei LI, Hideki AZUMA, Shin-ichiro MASUNAGA, Mitsunori
KIRIHATA and Yoshihide HATTORIKURRI Progress Report 2012, pp. 153 (2013)
Kojic acid is well known to work as an excellent whitening agent for melanocytes by a strong tyrosinase
inhibition. This fact suggests that kojic acid possess a specific affinity for melanocytes. Previously, we foundthat kojic moiety functionalized not only to accumulate selectively into melanoma cells, but also to localize
nuclei. As these results indicated that CKA was promising to be a boron agent for melanoma BNCT, herein,
we evaluated CKA as BNCT agent in vivo. When 1500 ppm of 10B solutions was used, average survival rate
were 19 and 22 days with L-BPA/fructose and CKA/HP-β-CD complex, respectively. Moreover, longsurvival rates (25 days) were observed with 4500 ppm of 10B solutions of CKA/HP-β-CD complex. CKA is
promising to be an efficient boron agent toward melanoma BNCT.
Mechanism Involved in Tumor Tissue of Colon 26 Carcinoma-Bearing Mice Irradiated with Neutronin the Presence of BSH-Appended Polyamine
Takeshi NAGASAKI, Riku KAWASAKI, Masashi Sakuramoto, Hideki AZUMA, Hironobu YANAGIE,
Yoshihide HATTORI, Mitsunori KIRIHATA, Koji ONO, Shin-ichiro MASUNAGA and Yoshinori
SAKURAIKURRI Progress Report 2012, pp. 259 (2013)
Since BSH-appended polymeric 10B carrier has anionic zeta-potential, polyion complexes with cationicpolymer afford nanoparticles suitable for safe and effective delivery into tumor tissues due to EPR effect.
The neutron-irradiation experiment was carried out with the complex in colon 26 carcinoma-bearing mice.
Significant depression effect for the tumor proliferation was observed. Herein, mechanism of tumor growth
suppression was assessed using well-characterized TUNEL assay. Obtained results indicated that BNCT with
BSH-appended polyamine induced apoptosis of tumor cells in vivo.
Carborane-Kojic Acid Conjugate for Melanoma-Targeting Boron Neutron Capture Therapy
Takeshi NAGASAKI, Riku KAWASAKI, Koji ONO, Shin-ichiro MASUNAGA, Yoshinori SAKURAI and
Mitsunori KIRIHATA
2013 Material Research Society Fall Meeting & Exhibit, Poster Presentation, Boston, MA, USA, December
1-6, 2013; Preprints.
Melanoma-targeted Boron Delivery by Kojic Acid-appended Carborane/Cyclodextrin Complexes for
BNCT of Malignant Melanoma
Takeshi NAGASAKI, Riku KAWASAKI, Yoshihide HATTORI, Yoshinori SAKURAI, Hiroki TANAKA,
Shin-ichiro MASUNAGA, Koji ONO and Mitsunori KIRIHATA
The 6th Trilatereal BNCT Meeting between Taiwan and Japan, Invited Lecture, Taipei, Taiwan, December−107−13, 2013; Preprints.
Stimuli-responsive Drug Delivery System: Photoresponsive Gene Delivery System for Gene Therapy
and Boron Delivery System for Neutron Capture Therapy
Takeshi NAGASAKI
7th KIFEE International Symposium on Environment, Energy and Materials, Invited Lecture, Kyoto, Japan,
March 16-19, 2014; Preprints.
Boron-containing Rare Earth Oxides Nanoparticles for Boron Neutron Capture Therapy
Takeshi NAGASAKI, Riku KAWASAKI, Shin-ichiro MASUNAGA, Yoshinori SAKURAI and Koji
TOMITA
2014 Material Research Society Spring Meeting & Exhibit, Poster Presentation, San Francisco, CA, USA,
April 21-24, 2014; Preprints.
Kojic Acid Modified o-Carborane/Hydroxypropyl-β-Cyclodextrin Complex as Novel BNCT Drug for
MelanomaTakeshi NAGASAKI, Riku KAWASAKI, Yoshinori SAKURAI, Shin-ichiro MASUNAGA, Koji ONO and
Mitsunori KIRIHATA
16th International Congress on Neutron Capture Therapy, Oral Presentation, Helsinki, Finland, July 14-19,
2014; Preprints.
Application of Novel Boron-containing Nanoparticles to BNCT
Koji TOMITA and Takeshi NAGASAKIIsotope News, Vol. 718, pp. 9-15 (2014) (in Japanese)
The Synergistic Effect of 1'-Acetoxychavicol Acetate and Sodium Butyrate on the Death of Human
Hepatocellular Carcinoma Cells
Rie KATO, Isao MATSUI-YUASA, Hideki AZUMA and Akiko KOJIMA-YUASA.
Chem. Biol. Interact., Vol. 212, pp. 1-10 (2014)
It has been suggested that the combined effect of natural products may improve the effect of treatment
against the proliferation of cancer cells. In this study, we evaluated the combination of 1'-acetoxychavicolacetate (ACA), obtained from Alpinia galangal, and sodium butyrate, a major short chain fatty acid, on thegrowth of HepG2 human hepatocellular carcinoma cells and found that treatment had a synergistic inhibitory
effect. The number of HepG2 cells was synergistically decreased via apoptosis induction when cells weretreated with both ACA and sodium butyrate. In ACA- and sodium butyrate-treated cells, intracellular reactive
oxygen species (ROS) levels and NADPH oxidase activities were increased significantly. The decrease incell number after combined treatment of ACA and sodium butyrate was diminished when cells werepretreated with catalase. These results suggest that an increase in intracellular ROS levels is involved incancer cell death. AMP-activated protein kinase (AMPK), a cellular energy sensor, plays an essential role incontrolling processes related to tumor development. In ACA- and sodium butyrate-treated cells, AMPK
phosphorylation was induced significantly, and this induction improved when cells were pretreated withcatalase. These results suggest that the increase in intracellular ROS is involved in the increase of AMPK
phosphorylation. In normal hepatocyte cells, treatment with ACA and sodium butyrate did not decrease cellnumbers or increase ROS levels. In conclusion, combined treatment with ACA and sodium butyrate
synergistically induced apoptotic cell death via an increase in intracellular ROS and phosphorylation of
AMPK. Our findings may provide new insight into the development of novel combination therapies against
hepatocellular carcinoma.
Preparation of keratin hydrogel/hydroxyapatite composite and its evaluation as a controlled drug−108−release carrier
R. NAKATA, A. TACHIBANA, T. TANABE
Mater. Sci. Eng. C, Vol. 41, pp. 59-64 (2014)
Infection after artificial joint replacement is a serious problem, which requires the re-implantation of
prosthesis. To aim at developing bone filling materials having both osteoconductivity and ability as asustained drug release carrier, composites of wool keratin or carboxymethylated (CM) keratin hydrogels withhydroxyapatite were prepared and evaluated as a sustained drug release carrier. CM-keratin was prepared by
the reaction of keratin extracted from wool with iodoacetic acid. Hydrogels were obtained by dropping
keratin or CM-keratin solution into CaCl2 solution. The composites were obtained by immersing hydrogelsin simulated body fluid (SBF). The introduction of carboxymethyl groups to keratin facilitated the depositionof hydroxyapatite on hydrogel. After 7 days immersion in SBF, 4 – 5 times higher amount of hydroxyapatite
was accumulated on CM-keratin hydrogel than that on keratin hydrogel. When salicylic acid was loaded on
keratin and CM-keratin hydrogels, a good sustained release was observed; that is, 90% of drug was released
up to 14 days after 60 and 45% of initial burst in 1 day. On the other hand, initial release within 1 day was
suppressed by forming composite with hydroxyapatite and the release was almost ceased at 3 days when
60% of drug was released. Although further improvement to prolong drug release might be necessary,
CaKHA and CaCMKHA are expected to be a promising novel type of bone filling materials which has both
osteoconductivity and sustained drug release ability.
Long DNA passenger strand highly improves the activity of RNA/DNA hybrid siRNAs
H. IDA, K. FUKUDA, A. TACHIBANA, T. TANABE.
J. Biosci. Bioeng., Vol. 117, pp. 401-406. (2014)
Small interfering RNAs (siRNAs) are potent tools in biomedical research, which can reduce the expression
level of target proteins through RNAi pathway. They are composed of 19-25 bp double strand RNA(dsRNAs), therefore, stimulate dsRNAs dependent interferon responses in a non-specific manner. This
problem has prevented siRNAs from being applied as new therapeautic agents. In the present paper, we tried
to circumvent interferon responses using RNA/DNA hetero siRNAs (HsiRNAs) composed of RNA guideand DNA passenger strands. It was previously reported that siRNAs which were partially substituted with
DNA had RNAi activity and that DNA substitution often caused the activity loss. In our results, HsiRNAs, inwhich the passenger strand of siRNAs were exchanged with DNA also showed much lower activity than thatof parental siRNAs. Here, we found that attachment of 5' flanking sequence to DNA passenger strand
improved the activity of HsiRNAs. Furthermore, the effective HsiRNAs induced much lower interferon
responses than parental siRNAs. Thus, HsiRNAs with 5' flanking sequence are expected to be novel siRNAdrug candidates.
Binding affinity of ssDNA is improved by attachment of dsDNA regions
H. IDA, A. TACHIBANA, T. TANABE.
J Biosci Bioeng., Vol. 118, pp. 239-241. (2014)
LidNA, a microRNA inhibitor consisting of a microRNA binding ssDNA region sandwiched between
dsDNA regions had higher affinity to target oligonucleotides than that without dsDNA region. Thisenhancement in affinity was found to be owing to the suppressed mobility of ssDNA region by the presenceof dsDNA regions.
Isolation and characterization of baker's yeast capable of strongly activating a macrophage
Y. TAKADA, Y. NISHINO, C. ITO, H. WATANABE, K. KANZAKI, T. TACHIBANA, M. AZUMAFEMS Yeast Res., Vol. 14(2), pp. 261-269. (2014)
A physiological function of the -glucans which constitute the cell wall of Saccharomyces cerevisiae is toactivate immune cells. Here, we focused on the immunostimulation ability of S. cerevisiae itself to give thisability to fermented foods including yeast. Previously, we found that in S. cerevisiae the deletion of MCD4−109−

gene causes exposure of -glucans on the cell surface and that the mcd4 deletion mutant strongly enhances
immunity in vitro and in vivo. However, this is not a practical strain but a genetically modified strain with anantibiotic resistance gene, and growth was very slow. The aim of this study was to acquire a practical strain
capable of strongly activating a macrophage. The parental strain y-21 was mutated with ethyl
methanesulfonate, and the resulting strain was screened. Two mutants (AP-57 and AQ-37) were obtained.
AQ-37 had the same fermentation capacity as y-21. In addition, a mutation point of AQ-37 was identified,suggesting that the mutation of NDD1 gene affects the cell wall structure and confers a high ability for
macrophage stimulation. The obtained yeast may activate immune cells in materials to which the yeast is
added.
Isolation of diploid baker's yeast capable of strongly activating immune cells and analyses of the cellwall structure
Y. TAKADA, A. MIZOBUCHI, T. KATO, E. KASAHARA, C. ITO, H. WATANABE, K. KANZAKI, S.
KITAGAWA, T. TACHIBANA, M. AZUMA
Biosci Biotechnol Biochem., Vol. 78(5), pp. 911-915. (2014)
Diploid baker's yeast capable of strongly activating a mouse macrophage was constructed based on haploidmutant AQ-37 obtained previously. The obtained strain BQ-55 activated also human immune cells. To clarify
a factor for the activation, the cell wall structure, especially the -glucan structure, was analyzed, suggestingthat the length of branching, -1,6-glucan, may be one of the factors.
Cell wall structure suitable for surface display of proteins in Saccharomyces cerevisiae
H. MATSUOKA, K. HASHIMOTO, A. SAIJO, Y. TAKADA, A. KONDO, M. UEDA, H. OOSHIMA, T.
TACHIBANA, M. AZUMA
Yeast., Vol. 31(2), pp. 67-76. (2014)
A display system for adding new protein functions to the cell surfaces of microorganisms has been developed,
and applications of the system to various fields have been proposed. With the aim of constructing a cellsurface environment suitable for protein display in Saccharomyces cerevisiae, the cell surface structures ofcell wall mutants were investigated. Four cell wall mutant strains were selected by analyses using a GFP
display system via a GPI anchor. -Glucosidase and endoglucanase II were displayed on the cell surface inthe four mutants, and their activities were evaluated. mnn2 deletion strain exhibited the highest activity forboth the enzymes. In particular, endoglucanase II activity using carboxymethylcellulose as a substrate in the
mutant strain was 1.9-fold higher than that of the wild-type strain. In addition, the activity of endoglucanase
II released from the mnn2 deletion strain by Zymolyase 20T treatment was higher than that from thewild-type strain. The results of green fluorescent protein (GFP) and endoglucanase displays suggest that theamounts of enzyme displayed on the cell surface were increased by the mnn2 deletion. The enzyme activityof the mnn2 deletion strain was compared with that of the wild-type strain. The relative value (mnn2 deletionmutant/wild-type strain) of endoglucanase II activity using carboxymethylcellulose as a substrate was higher
than that of -glucosidase activity using p-nitrophenyl--glucopyranoside as a substrate, suggesting that thecell surface environment of the mnn2 deletion strain facilitates the binding of high-molecular-weightsubstrates to the active sites of the displayed enzymes.
A milliliter-scale yeast-based fuel cell with high performance
K. KANESHIRO, K. TAKANO, Y. TAKADA, T. WAKISAKA, T. TACHIBANA, M. AZUMABiochemical Engineering Journal, Vol. 83, pp. 90-96. (2014)
Microbial fuel cells are attracting attention as one of the systems for producing electrical energy fromorganic compounds. We used commercial baker’s yeast (Saccharomyces cerevisiae) for a glucose fuel cellbecause the yeast is a safe organism and relatively high power can be generated in the system. In the present
study, a milliliter (mL)-scale dual-chamber fuel cell was constructed for evaluating the power generated by avariety of yeasts and their mutants, and the optimum conditions for high performance were investigated.

−110−When carbon fiber bundles were used as an electrode in the fuel cell, high volumetric power density was
obtained. The maximum power produced per volume of anode solution was 850 W/m3 under optimum
conditions. Furthermore, the power was examined using seven kinds of yeast. In Kluyveromyces marxianus,
not only the power but also the power per consumed glucose was high. Moreover, as fuel for the fuel cell.
The fuel cell powered by K. marxianus may prove to be helpful for the effective utilization of woody
biomass.
Expression of the Clustered NeuAcα2-3Galβ O-Glycan Determines the Cell Differentiation State of theCells
K. HIGASHI, K. ASANO, M. YAGI, K. YAMADA, T. ARAKAWA, T. EHASHI, T. MORI, K. SUMIDA, M.
KUSHIDA, S. ANDO, M. KINOSHITA, K. KAKEHI, T. TACHIBANA, K. SAITO
J. Biol. Chem., Vol. 289(37), pp. 25833-25843. doi: 10.1074/jbc.M114.550848. (2014)
Human embryonic stem cells (hESCs) are pluripotent stem cells from early embryos, and their self-renewal
capacity depends on the sustained expression of hESC-specific molecules and the suppressed expression ofdifferentiation-associated genes. To discover novel molecules expressed on hESCs, we generated a panelof monoclonal antibodies against undifferentiated hESCs and evaluated their ability to mark cancer cells, aswell as hESCs. MAb7 recognized undifferentiated hESCs and showed a diffuse band with molecular mass of>239 kDa in the lysates of hESCs. Although some amniotic epithelial cells expressed MAb7 antigen, its
expression was barely detected in normal human keratinocytes, fibroblasts, or endothelial cells. The
expression of MAb7 antigen was observed only in pancreatic and gastric cancer cells, and its levels were
elevated in metastatic and poorly differentiated cancer cell lines. Analyses of MAb7 antigen suggested thatthe clustered NeuAcα2-3Galβ O-linked oligosaccharides on DMBT1 (deleted in malignant brain tumors 1)
were critical for MAb7 binding in cancer cells. Although features of MAb7 epitope were similar with thoseof TRA-1-60, distribution of MAb7 antigen in cancer cells was different from that of TRA-1-60 antigen.
Exposure of a histone deacetylase inhibitor to differentiated gastric cancer MKN74 cells evoked theexpression of MAb7 antigen, whereas DMBT1 expression remained unchanged. Cell sorting followed by
DNA microarray analyses identified the down-regulated genes responsible for the biosynthesis of MAb7
antigen in MKN74 cells. In addition, treatment of metastatic pancreatic cancer cells with MAb7 significantly
abrogated the adhesion to endothelial cells. These results raised the possibility that MAb7 epitope is a novel
marker for undifferentiated cells such as hESCs and cancer stem-like cells and plays a possible role in theundifferentiated cells.
DBZ, a CNS-specific DISC1 binding protein, positively regulates oligodendrocyte differentiation
S. SHIMIZU, Y. KOYAMA, T. HATTORI, T. TACHIBANA, T. YOSHIMI, H. EMOTO, Y. MATSUMOTO,
S. MIYATA, T. KATAYAMA, A. ITO, M. YOHYAMA
Glia., Vol. 62, pp. 709-724. (2014)
Recent studies have shown changes in myelin genes and alterations in white matter structure in a wide rangeof psychiatric disorders. Here we report that DBZ, a central nervous system (CNS)-specific member of the
DISC1 interactome, positively regulates the oligodendrocyte (OL) differentiation in vivo and in vitro. In
mouse corpus callosum (CC), DBZ mRNA is expressed in OL lineage cells and expression of DBZ protein
peaked before MBP expression. In the CC of DBZ-KO mice, we observed delayed myelination during theearly postnatal period. Although the myelination delay was mostly recovered by adulthood, OLs withimmature structural features were more abundant in adult DBZ-KO mice than in control mice. DBZ was alsotransiently upregulated during rat OL differentiation in vitro before myelin marker expression. DBZ
knockdown by RNA interference resulted in a decreased expression of myelin-related markers and a low
number of cells with mature characteristics, but with no effect on the proliferation of oligodendrocyte
precursor cells. We also show that the expression levels of transcription factors having a negative-regulatoryrole in OL differentiation were upregulated when endogenous DBZ was knocked down. These results
strongly indicate that OL differentiation in rodents is regulated by DBZ.

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N-ethylmaleimide-sensitive factor interacts with the serotonin transporter and modulates its
trafficking: implications for pathophysiology in autism
K. IWATA, H. MATSUZAKI, T. TACHIBANA, K. OHNO, S. YOSHIMURA, H. TAKAMURA, K.
YAMADA, S. TATSUZAKI, K. NAKAMURA, K. J. TSUCHIYA, K. TASTUMOTO, M TSUJII, T.
SUGIYAMA, T. KATAYAMA, N. MORI
Mol. Autism 5:33. doi: 10.1186/2040-2392-5-33. (2014)
Changes in serotonin transporter (SERT) function have been implicated in autism. SERT function is
influenced by the number of transporter molecules present at the cell surface, which is regulated by various
cellular mechanisms including interactions with other proteins. Thus, we searched for novel SERT-binding
proteins and investigated whether the expression of one such protein was affected in subjects with autism.
Generation of a monoclonal antibody for INI1/hSNF5/BAF47
A. HARADA, M. HAYASHI, Y. KUNIYOSHI, Y. SEMBA, S. SUGAHARA, T. TACHIBANA, Y.
OHKAWA, M. FUJITA
Monoclon Antib Immunodiagn Immunother, Vol. 33(1), pp. 49-51. doi: 10.1089/mab.2013.0065. (2014)
INI1/hSNF5/BAF47, which has an SNF5 domain, belongs to the SWI/SNF family. This family is known as
ATP-dependent regulators of gene expression by remodeling chromatin structure during cell differentiation.
However, the detailed function of INI1/hSNF5/BAF47 is unclear. Here we report the generation of a specificmonoclonal antibody for INI1/hSNF5/BAF47 by the mouse iliac lymph node method. The obtained
antibodyrecognized two isoforms of INI1/hSNF5/BAF47 in immunoblotting and precisely recognized thenuclear localization of INI1/hSNF5/BAF47 in immunostaining. This antibody can contribute to further
elucidation of the mechanisms of gene expression regulation by INI1/hSNF5/BAF47 during celldifferentiation.
Production of a monoclonal antibody for C/EBPβ: the subnuclear localization of C/EBPβ in mouse
L929 cells
A. HARADA, E. OKAZAKI, S. OKADA, T. TACHIBANA, Y. OHKAWA
Monoclon Antib Immunodiagn Immunother, Vol. 33(1), pp. 34-37. doi: 10.1089/mab.2013.0069. (2014)
The CCAAT/enhancer-binding protein (C/EBP)β belongs to the C/EBP family of proteins that possesses abasic leucine zipper DNA-binding domain. These proteins bind DNA by dimerization and play a role in thetranscriptional regulation of various cells. There are six different types of C/EBPs, and some form isoforms
through the use of alternative translation initiation sites. The functional analysis of the C/EBP family istherefore difficult to achieve. Here we report on the production of specific monoclonal antibodies againstmouse C/EBPβ using a rat medial iliac lymph node method. Immunoblotting using C/EBPβ monoclonal
antibodies identified two types of isoforms, while immunostaining revealed a subnuclear localization for
C/EBPβ. Use of this antibody should contribute to the further elucidation of the transcriptional regulatory
function of C/EBPβ.
Generation of a monoclonal antibody against the extracellular domain of IGF-1R
Y. NAKADATE, S. YOSHIMURA, N. NAKATANI, M. AZUMA, T. TACHIBANA
Monoclon Antib Immunodiagn Immunother, Vol. 33(2), pp. 126-128. doi: 10.1089/mab.2013.0083. (2014)
Type I insulin-like growth factor receptor (IGF-1R) is a receptor tyrosine kinase that is involved in thetransformation of cells, cancer proliferation, and metastatic events in various types of cancer. The present
study reports on the generation of a mouse monoclonal antibody (MAb) to IGF-1R using the mouse lymph
node method. MAb 1B1, which reacts specifically with the extracellular domain of IGF-1R, was obtainedusing flow cytometry (FCM) screening using MCF-7 cells. Using immunostaining, MAb 1B1 detected
IGF-1R mainly on the plasma membrane of MCF-7 cells. MAb 1B1 would be useful in FCM and
immunofluorescence assays to detect IGF-1R-expressing cells for basic and clinical research.

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Urban Engineering
Architecture and Building Engineering
A Study on Conditions to Release Initial Displacement for Tuned Mass Dampers with Initial
Displacement
Susumu YOSHINAKA and Yoshiya TANIGUCHI
Journal of Structural and Construction Engineering (Transactions of AIJ), AIJ, No. 703, pp. 1247-1257(2014) (in Japanese)
We propose tuned mass dampers with initial displacement that are possible to control impulsive seismic
responses effectively. In our previous study, we focused on the considerably high modal damping ratio of thesecond mode compared to the first mode and proposed the design formulas for high control performance
under impulse loading. The proposed design formulas are based on the principle that by giving the specific
TMD initial displacement under the specific structural initial condition the structural response of the firstmode can be eliminated. In this paper, we introduce a formula for initial conditions to release initialdisplacement by the theoretical solution and study about TMD initial displacement and structural conditions
by using the complex plane. Next, we propose a design method that can change initial structural conditions.
Estimation of the Global Optimality for Multiple Tuned Mass Damper Systems Using Order Statistics
Makoto YAMAKAWA (Tokyo Denki University), Susumu YOSHINAKA, Yoshikazu ARAKI (Kyoto
University), Koji UETANI (Setsunan University) and Ken'ichi KAWAGUCHI (Institute of Industrial
Science, the University of Tokyo)
Proceedings of the 11th World Congress on Computational Mechanics (WCCM XI), Barcelona, Spain, July
20-25, pp. 4362-4372 (2014)
In the design of passive tuned mass damper (TMD) on the vibration control performance of spatial structures,
we have to decide the both of a spatial arrangement and characteristics. To find an optimum design of thesystem is formulated as Mixed-Integer Programming (MIP) problem. It is difficult to obtain the exact global
optimum solution in general form. We present a method which can guarantee to find a near-optimal solution
with pre-assigned accuracy. The key concept of the method is random search based on prediction by order
statistics. Through a numerical example, we investigate the applicability and effectiveness of the method tothe design of TMD systems.
Mood States and Light Environment Evaluation
Noriko UMEMIYA, Tetsuro ARAI, Tomoko IWATA and Tamami SUZUKI
Proceedings of CIE Centenary Conference „Towards a New Century of Light“, Paris, pp. 1180-1185 (2013).
The light environment in a climate chamber was evaluated at two levels of lighting. Differences in
evaluations offered by 440 student subjects were analyzed. Results revealed the following. 1) The lightenvironment evaluation related to brightness, brightness for writing, uniformity of lighting, glare, color,
comfort, preference, and performance changed according to the level of lighting for all subjects. 2) Profilesof Mood States response patterns were classifiable into five groups. In low vigor Pattern 3, most evaluations
did not change according to the illuminance level.
Relation between School Building Configuration and Heat Mitigation Effects of Lawns in Urban
Regions
Noriko UMEMIYA, Takayuki HARADA, Masato TOKUDA, Tatsuya SAKANE and Satoshi HIRATA
Proceedings of the 13th International Building Performance and Simulation Association Conference,
Building Simulation 2013, Chambery, pp. 742-746 (2013)
Results of this study show how heat mitigation effects of planting elementary school lawns in urban regions
differ according to eight school building configurations and two surrounding building models. Results show
the following. 1) Heat mitigation effects with high-rise buildings (MODEL_H) are higher than those withnormal height buildings (MODEL_N) for eight school building configurations. 2) For MODEL_H, withhigher surrounding buildings, enclosure-type school building configurations show high heat mitigation
effects of lawns in terms of temperature differences. 3) School building configurations with no west-facing
school buildings show high heat mitigation effects of lawns for the new effective temperature for outdoors−113−

(OUT_SET*) both for Model_H and Model_L.
Faults and Claims about Thermal Environments in Relation to Energy Saving Measures in Smaller
Office Buildings
Noriko UMEMIYA, Taiji OBUCHI and Ryota MATSUIJournal of Civil Engineering and Architecture, 8(4), pp.413-424 (2014)
Building equipment, energy-saving systems, and claims of inappropriate indoor thermal environments wereanalyzed in relation to the floor area using responses to a questionnaire survey of service managers of 157
buildings built in Osaka, Kyoto and Hyogo prefectures in Kinki area of Japan. Results show the following:(1) In smaller buildings (< 5,000 m2), setting temperatures are higher in summer and lower in winter, effectsof “uncomfortable radiation from windows” are greater, energy-saving systems decrease indoor thermal
comfort, but claims of “hot” and “cold” are fewer; (2) Claims of “hot” and “cold” are unrelated to the setting
temperature and whether the air-conditioning control system is central or local; (3) the adoption rates of
mitigation of dress codes (“COOL-BIZ” and “WARM-BIZ”) are higher than those of temperature mitigationof air conditioning.

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Urban Design and Engineering
An Analysis on Influencing Factors on Difficulty of Shopping Accessibility by Considering Individual
Attributes and Area Characteristics
Noboru ISE and Yasuo HINO
Osaka City University, Memoirs of the Faculty of Engineering, Vol. 54, pp. 37-45(2013)
Ministry of Economy, Trade and Industry (METI) forecasted that the number of people in food desert (PFD),
who have difficulty of shopping accessibility, may be about six million in Japan. However, this forecasting
method would not be suitable for forecasting the number of PFD at local level, because of lack of taking
consideration into the factors such as individual attributes and area characteristics. Therefore, this paper
mainly aims to gain the fundamental knowledge to develop the model for forecasting the number of PFD at
local level, from the analysis on influencing factors on difficulty for shopping accessibility by considering
individual attributes and area characteristics. As a result in this study, some major findings related to
shopping accessibility came out as follows; 1) some influencing factors on difficulty of shopping
accessibility were revealed, 2) shopping accessibility aids such as mobile shopping and delivery service had
the complementary role of improving the shopping access problem, 3) actual conditions of needs for
shopping accessibility aids were clear, 4) both average WTP (Willingness to Pay) and average usage
frequency of each aids for shopping by PFD were revealed. These findings may be useful to develop theforecasting model for not only the number of PFD but also the shopping behavior among some specialized
shopping styles.
Introduction and Evaluation of Some Trial Bus Services to Support Elderly Persons
Yasuo HINO, Kazuo MUKAI, Kazuya MIZUKAMI and Junichi MORITA
Japan Society of Traffic Engineers, Papers on Traffic Engineering, No. 34，pp. 478-484(2014) (in Japanese)
Activity of residents in town must be one of the important factors to develop the future city planning, in
population decrease with both aging declining birthrate. Therefore, some suitable support services formobility of aged persons to provide the opportunity of going out with accompanying person. In this study,
new trials of bus services to improve the mobility of aged persons were introduced and evaluated based on
the questionnaire surveys for bus passengers and residents. Their new bus services were “free charge foraccompanied person on Sunday”, “cut in fare of regular route bus to adjust the fare of small bus of sameroute” and “free place of getting on and off the bus”. These services were introduced to aim to mainly
support the mobility of aged persons. As a result, some important findings to evaluate the utility of these
services and investigate the future approaches to realize the purpose came out of some analyses of surveys.
Furthermore, these results must be a precedent of valid bus services to realize the active town planning.
Evaluation of Road Space based on Analysis of Influence Factors from viewpoint of Pedestrians
Tatsuya OGIHARA and Yasuo HINO
Japan Society of Civil Engineers, Proceedings of Infrastructure Planning, No.46，4pp (CD-ROM)(2013) (inJapanese)
Recently, the improvement of urban environment has been essential factor in comprehensive plan at many
cities. Therefore, various keywords like “creation of new environment” were proposed in such plan.
However, as the understandings of urban environment may be different according to values, it must be noteasy to not only define the meaning of urban environment, but also fix the composing factors to it. In thisstudy, the activity, attachment, land scape as well as urban environment, which must be differently evaluatedaccording to values of persons, conditions of road, traffic situation and so on, were defined as thefundamental four indicators to evaluate the road space in urban area. Then the evaluation to each indicatorand the relations among them were analyzed based on the data of questionnaire to pedestrians, in order tofind some key factors influenced to each evaluation. As a result, some important findings came out asfollows; four indicators were related respectively, traffic conditions must as well as road conditions as roadwidth, degree of tree planting and road side conditions influenced to evaluation. That is, the road space forurban environment must be improved by improving some factors mentioned above, in addition, its
improvement may influence well to all indicators.
Important Issues and Better Prospect of Road Safety Education from viewpoint of Traffic Accidents
Involved children – Mainly Behavior and Consciousness of Risk for Bicycle Use Yasuo HINO
Traffic Safety Education, Vol.49，No.9，pp.6-18 (2014) (in Japanese)−115−

The reports of traffic accident of children have kept in news, nevertheless the number of accidents involved
children has not increased. This must be considered to show that the safety of children should be the one ofgreatest concern of society. How do we prevent children from traffic accident? A few number of road safety
event by cooperation of police office in each primary school. Usually, parents may teach children how to ridebicycle. However, it must not be understandable for both teachers and parents to understand how to teachchildren for road safety. In this study, the features and problems of traffic accidents involved children, theconsciousness for road safety of children, parents and teachers, and the conditions and problems of roadsafety educations were evaluated by using the data of questionnaire for all concerns. In addition, the roadsafety education reflected the useful findings came out of surveys must be necessary to prevent children from
accidents as a better prospect.
Verbal Map Guidelines of Audio-AR Application for Visually-impaired People
Mei TAKAHASHI, Kazuyuki NEKI and Takashi UCHIDA
Japan Society of Traffic Engineers, Papers on Traffic Engineering, No. 33，pp. 509-514(2013) (in Japanese)
A typical smartphone has a global positioning system (GPS) function and a web access function.
Furthermore, augmented reality (AR) applications of smartphones have become commonplace. Such phones
may enable visually-impaired people to use navigation system by using “verbal maps” instead of graphicalmaps. This paper describes outline of guidelines of “verbal map” that explains feature information tovisually-impaired people using audio guidance. An example of verbal map sequence adopted in real town isalso shown.
A Formulation of Long-term Trip Mode Choice Game considering Altruistic Attitudes andBus-captive People.
Masaki OCHI and Takashi UCHIDA
Japan Society of Traffic Engineers, Papers on Traffic Engineering, No. 33，pp. 433-438(2013) (in Japanese)
This paper formulates collective decision concerning transportation system by using game-theory. The
players choose their long-term (for some decades) mode among transportation alternatives including
public-supported transport system. The players are classified and characterized into 4 types considering
altruistic attitudes and captivity to bus. This formulation reflects real situation of “transportation poor”
problems. Numerical examples are explained to show that the formulation is useful to examine public
policies of transportation system.
Citizen Awareness of Community Buses from the Public Support Perspective
Yusuke KURASHIMA and Takashi UCHIDA
Japan Society of Traffic Engineers, Papers on Traffic Engineering, No. 33，pp. 569-574(2013) (in Japanese)
Study on the Process of Review and Improvement of the Community Bus for Continuation and
Improvement of the Civic Will
Yusuke KURASHIMA and Takashi UCHIDA
Japan Society of Civil Engineers, Proceedings of Infrastructure Planning, No.48, 4pp. (CD-ROM) (2013) (inJapanese)
LIFECYCLE ANALYSIS OF REPLACEABLE BRIDGES
Masahiro UTSUMI and Takashi UCHIDA
Japan Society of Civil Engineers, Proceedings of Infrastructure Planning, No.48, 4pp. (CD-ROM) (2013) (inJapanese)
This paper describes an optimization technique of repair and replacement for deteriorated bridges. In
addition, a new concept of bridges called “ECO-Bridges” is introduced. The genetic algorithm (GA) that issearch algorithm based on the mechanics of natural selection and natural genetics is adopted in order tosearch optimal maintenance planning with both of the minimum maintenance costs and minimum externalcost. By applying this algorithm both to existing bridges and Eco-Bridges, it has been verified that employed
optimization system is effective for examining superior type of bridges under various conditions.
An Empirical Study of Verbal Map Guidelines for Visually-impaired people to Enhance Daily
Mobility
Mei TAKAHASHI, Takashi UCHIDA
Osaka City University, Memoirs of the Faculty of Engineering, Vol. 54, pp. 37-45(2013)−116−

This study is to revise verbal map guidelines for a pedestrian navigation system. The guidelines show rules
for describing features in a town to enhance everyday mobility. The paper presents a review of earlier
studies and explains the concept of an audio augmented reality (AR) application for visually-impaired people.
Then, field experiments are conducted to assess methods to encourage visually-impaired people to use audio
guidance through courses and to advance hearing research. Outlines, results, and consideration of theexperiments are presented. Finally, verbal map guidelines are revised. This study was conducted as a part ofa Grant in Aid for Scientific Research during Heisei 24-26 year (Scientific Research B, 24360209) “Practical
Use Study of the Town Walk Support Navigation System Fused in Audio AR and RFID for
Visually-impaired people”
An Experimental Study on Characteristics of Cyclist’s Eye Movement and Behavior on Bicycle
Facilities
Takanori OKAWA, Nagahiro YOSHIDA, Yasuo HINO and Takashi UCHIDA
Japan Society of Civil Engineers, Journal of JSCE, Division D3, Vol. 69, No.5，pp. I_571-I_578 (2013) (inJapanese)
Bicycle lanes with legal control have been introduced on carriageway as a governmental pilot project since2008 in Japan. However the facility design standard for cyclists on roadways is not determined yet while
many standards remain the same as for cars/drivers. There are few researches on cyclists’ specific eye
movement and behavior with road conditions. The amount of information on road should be minimized to
avoid confusion, but required to be an informative road space for bicyclists even without driving license.
Therefore, some empirical experiments have been conducted to understand differences of cyclist’s eye
movement and behavior on various types of facilities.
Study on Ultimate Strength and Deformation of Compression Chord Member considering Gusset
Plate in a Truss Bridge
Masahide MATSUMURA, Junpei YOSHIYAMA and Takashi YAMAGUCHI
Journal of Structural Engineering, Vol. 59A, JSCE, pp.169-179 (2013) (in Japanese)
Investigated in this study is the ultimate strength of a compression chord member in a truss bridge, which isdesigned according to the Specification for Highway Bridges in Japan. An adequate modeling method of themember, and the support condition of the member considering gusset plates at the end of the member arechecked through FEM analysis. It is revealed that the ultimate strength and deformation of the member in thetruss bridge is very much similar to those of a fixed supported column in compression. Also proposed is an
economic and rational design of the truss bridge.
Strengthening Effects of Eccentric Compression Steel Columns bonded CFRP Plate of High Elastic
Modulus
Masahide MATSUMURA, Shinya KODA, Nobuhiro HISABE (Mitsubishi Plastics Inc.) and Takashi
YAMAGUCHI
Journal of Structural Engineering, Vol. 59A, JSCE, pp.190-198 (2013) (in Japanese)
In conventional strengthening techniques for existing steel structures, steel plates are additionally welded orbolted to the existing steel members to reduce working stress. Here, FRP materials can be alternatives of
conventional techniques in terms of easier applicability. Among the FRPs, CFRP strips of high elastic
modulus provide higher strengthening effects. Then, carried out in this paper are loading tests of eccentricand more effective compression steel columns adhered the CFRP strips separately onto the flange plates. It is
concluded that strengthening effect of the CFRP strips for bending not for axial loading decreases when the
CFRP strips are separately adhered onto the flange plates of the steel columns subjected to predominantcompression axial force.
Structural Rationalization of the Undersurface Retrofitting Method with Splice Plates andMortar-filling into the Trough Ribs for Existing Orthotropic Steel Decks
Yoshio TAMBA (Hanshin Expressway Technology Center), Satoshi KIMURA (Yokogawa Bridge Corp.),
Takashi YAMAGUCHI, Hiroki SUGIYAMA (Hanshin Expressway Co., Ltd.), Akiko TABATA (Hanshin
Expressway Co., Ltd.), and Yoshihiko TAKADA(Hanshin Expressway Co., Ltd.)
Journal of Structural Engineering, Vol. 59A, JSCE, pp.767-780 (2013) (in Japanese)−117−

The undersurface retrofitting method (installation of splice plates between the trough ribs and filling ofmortar into the trough ribs) for existing orthotropic steel decks is proposed. This retrofitting method does not
require the traffic restriction. In this study, FEM analysis and static load test are carried out in order torationalize this retrofitting method by evaluating the bolt pitch and the stress reduction effect. As a result, weunderstand that it is possible to apply the bolt pitch of 300(mm) to this retrofitting method and that theadhesives between the orthotropic steel deck and the splice plate are important.
Study on Mechanical Property of High Durability Friction Grip Joints with High Strength
Countersunk Head Bolts for Steel Bridge Structures
Akiko TABATA (Hanshin Expressway Co., Ltd.), Hidesada KANAJI (Hanshin Expressway Co., Ltd.),
Yoshihide KURONO and Takashi YAMAGUCHI
Journal of Structural Engineering, Vol. 59A, JSCE, pp.808-819 (2013) (in Japanese)
The authors focused on the high strength bolted friction grip joints with countersunk head bolts which canfinish the surface of the connection plate flat smoothly and prevent from functional depression due tocorrosion. In this study, we have compared the slip strength of the joints which has the optimum countersunk
head angle with that of the joint with the normal high strength bolt through the standard slippage test
considering variation of plate thickness and the yield strength of the base and splice plates. It was concluded
from the experimental result that the slip strength of the joints with countersunk head bolts exceeds thedesign slip strength specified in JSHB calculated by the slip coefficient 0.45 and that its slip coefficient isabout 10% lower than that with normal head bolts. It is caused by that the contact pressure of the joints withcountersunk head reduces due to local yielding around the bolt holes.
Small-sized Steel Bellows as Energy Absorbing and Displacement Restraining Device for Bridge
Masahide MATSUMURA
Proceedings of the 6th Taiwan-Japan workshop on structural and bridge engineering, pp.119-123, (2013)
Characterization of Mechanical Properties of Welding Materials using Fabrication of Steel Bridges
Kuniaki MINAMI (Japan Railway Construction, Transport and Technology Agency) and Takashi
YAMAGUCHI
Journal of JSCE, Ser.A1 (SE/EE), Vol.69, No.3, JSCE, pp.452-466, (2013) (in Japanese)
Recently, many kinds of welding materials were widely used in fabrication of steel bridges. It wasconsidered that the quality of these welding materials has been remarkably improved. However, thestatistical characteristics of the material are not clarified. In this paper, we have investigated the 638 of
welding materials on the basis of the mill sheet in order to clarify their quality. Investigated items were
tensile strength, yield strength, Charpy-absorbed-energy, elongation and yield ratio, and these mechanicalproperties were shown. We also showed improvement in the quality, comparing with the conventional steel
data and welding procedure tests date, which were SM490Y, SMA490W, SM570Q and SMA570W.
Study on Slip Behaviour of High Strength Bolted Friction Type Joint with Extremely Thick Plates byUsing Finite Element Analysis
Toshikazu TAKAI, Xue PENG, Honghe SUN and Takashi YAMAGUCHI
IABSE Conference Rotterdam 2013, Vol. 99, 8pages (on CDROM), Rotterdam (2013)
High strength bolted friction type joints are commonly used to join members of steel bridge structures.
Recently, such joints have become larger, because members of bridges tend to be large to seek structural
simplicity. Since large members consist of extremely thick plates, large size joints are needed with manybolts in a line, containing thick plates including splice plates. It is of concern that many bolts and thick plates
affect the slip behaviour of such large size joints. So, FEA focused on joints with many bolts and thick plates
is carried out. Based on the results, it is clear that a non-uniform distribution of friction force exists. And, it
is also shown that a certain combination of thicknesses of connected plates and splice plates has the large
capacity of slip resistance. It is concluded that such results can be explained by the influence of theadditional bending moment due to thick plates.
Study on Applicability of High Durability Friction Grip Joints with High Strength Countersunk Head
Bolts for Steel Bridge Structures−118−

Akiko TABATA (Hanshin Expressway Co., Ltd.), Hidesada KANAJI (Hanshin Expressway Co., Ltd.),
Yoshihide KURONO and Takashi YAMAGUCHI
IABSE Conference Rotterdam 2013, Vol. 99, 8pages (on CDROM), Rotterdam (2013)
The authors focused on the high strength bolted friction grip joints with countersunk head bolts which canfinish the surface of the connection plate flat smoothly and prevent from functional depression due tocorrosion. Firstly we carried out Finite Element Analysis in order to evaluate the contact pressure of double
shear connected friction joints with countersunk heads varying the angle of countersunk head. Secondly, we
have compared the slip strength of the joints which has the optimum countersunk head angle with that of thejoint with the normal high strength bolt through the standard slippage test considering variation of plate
thickness and the yield strength of the base and splice plates. As a result, it was concluded that the slip
strength of the joints with countersunk heads exceeds the required design slip strength which has specified in
JSHB and that its slip coefficients is about 10% lower than that with normal head bolts.
Experimental Study on Ultimate Strength and Ductility of Steel Short Column with Longitudinal
Stiffeners made of SBHS700
Keita HAMAMURA (Osaka University), Kiyoshi ONO (Osaka University), Masahide MATSUMURA,
Takahiro TARUI (Osaka University) and Shinya KODA
Proceedings of the 16th Symposium on Performance-based Seismic Design Method for Bridges, pp.391-394,
JSCE (2013) (in Japanese)
SBHS700 indicates higher yield strength and higher yield ratio like high strength steel. Focused on in thisstudy is a hybrid stiffened plate, in which longitudinal stiffeners made of SBHS700 and flange and web
plates made of SS400. Then compression test of short and rectangular steel hollow column with the hybrid
stiffened plates are conducted. It is concluded that the use of the hybrid stiffened plate can be expects almost
the same ultimate strength and higher ductility compared with non-hybrid stiffened plate.
Experimental Study on Rapture Characteristics of Knock-off Steel Side Block as Displacement
Restrainers
Takahiro KANATA and Masahide MATSUMURA
Proceedings of the 16th Symposium on Performance-based Seismic Design Method for Bridges, pp.309-316,
JSCE (2013) (in Japanese)
Steel side block with slit, which is designed to break when seismic fore corresponding to the ultimate shear
force the cross section with the slit is subjected, is developed and proposed as a trigger to control restricting
condition of superstructure. In this study, breaking tests are carried out to understand how shape of the slit
influences on breaking characteristics of the steel side block with slit. Then it is revealed that the proposed
shape of the slit can provide stable break load with less fluctuation and the braking displacement iscalculated based on braking mechanism of the side block.
FEA Study on the Slip Behavior of High Strength Multi Bolted Friction Type Joints with Thick Platesby Structural Dimensions
Xue PENG, Takashi YAMAGUCHI, Toshikazu TAKAI, Jun MURAKOSHI (Public Works ResearchInstitute) and Mamoru SAWADA (Public Works Research Institute)
Journal of JSCE, Ser.A1 (SE/EE), Vol.69, No.3, JSCE, pp.452-466, (2013) (in Japanese)
Resent years, from the viewpoint of rational structural members of steel bridges, the high strength bolted
friction type joints tend to be large. Since the slip behavior of high strength multi bolted friction type joints
with thick plates is not clear, the slip strength tests for such joints had been carried out. And from theexperimental results, it can be found that slip coefficient varies depending on the number of rows of bolts ina line. In this study, in order to clarify the slip behavior of such joints, FE analysis has been conducted withvarious structural dimensions, such as slip/yielding strength ratio, section shape of the connected plate etc.
As a result, the slip coefficient of the joint with many bolts in a line becomes low because each frictional
force per one bolt is unequal, and the plate width effects on the slip strength more significantly than otherstructural dimensions.
Analytical Study on Mechanical Behavior of Friction Grip Joints with High Strength Countersunk
Head Bolts and Its Geometrical Configurations−119−

Akiko TABATA (Hanshin Expressway Co., Ltd.), Hidesada KANAJI (Hanshin Expressway Co., Ltd.),
Yoshihide KURONO and Takashi YAMAGUCHI
Steel Construction Engineering, Vol.20, No.79, JSSC, pp.19-28, (2013) (in Japanese)
The authors focused on the high strength bolted friction grip joints with countersunk head bolts which canfinish the surface of the connection plate flat smoothly and prevent from functional depression due tocorrosion. In this study, we carried out FE analysis varying the angle of countersunk head in order toevaluate the contact pressure of double shear connected friction joints with countersunk heads. Also, we haveinvestigated the influence on load transferring mechanism by using countersunk head bolt for frictional joints.
It has concluded that the most desirable angle of the countersunk head is 90 degrees. CD series's slip strengthis about only 4% lower than that with normal head bolts.
Fundamental Study on Structural Soundness Evaluation of Existing Arch Bridge by using SOM
Yoshinori IKEDA, Takashi YAMAGUCHI, Takeshi KITAHARA (Kanto Gakuin University), Kunitomo
SUGIURA (Kyoto University) and Kouji MORIWAKA
Steel Construction Engineering, Vol.20, No.79, JSSC, pp.53-66, (2013) (in Japanese)
The authors focused on the high strength bolted friction grip joints with countersunk head bolts which canfinish the surface of the connection plate flat smoothly and prevent from functional depression due tocorrosion. In this study, we carried out FE analysis varying the angle of countersunk head in order toevaluate the contact pressure of double shear connected friction joints with countersunk heads. Also, we haveinvestigated the influence on load transferring mechanism by using countersunk head bolt for frictional joints.
It has concluded that the most desirable angle of the countersunk head is 90 degrees. CD series's slip strengthis about only 4% lower than that with normal head bolts.
Slippage Test of Frictional High Strength Bolted Joints with Adhesives for Corroded Damaged Steel
Members
Yoshio TAMBA (Hanshin Expressway Technology Center), Shinya YUKITO, Takashi YAMAGUCHI,
Haruyuki SAKODA (Hanshin Expressway Technology Center) , Akito HIGATANI (Hanshin Expressway
Co., Ltd.) and Akiko TABATA (Hanshin Expressway Co., Ltd.)
Proceedings of the 13th East Asia-Pacific Conference on Structure Engineering and Construction(EASEC-13), 8pages (on CDROM), Sapporo, JAPAN (2013)
In this study, FE analysis for the girder ends with corrosion has been carried out in order to understand thecollapse process and to evaluate its ultimate strength. At first, the strength of the girder end with various
corroded damages is evaluated based on the current design standards, “Specifications for Highway Bridges
in Japan”. Secondly, these collapse mechanism are analyzed from the analytical results, such as shapes of thedeformation mode, stress distribution, and load-deflection relationships and so on. Finally, we hadsummarized a flow diagram of a process of failure mode and the limit strength such as elastic, full-plastic
and ultimate limit states taking into account for local buckling.
Strength Evaluation for a Corroded Damaged Steel Gilder End Considering Its Collapse Mechanism
Makoto USUKURA (Tokyo Consultants Co., Ltd.), Takashi YAMAGUCHI, Yasuo SUZUKI (Utsunomiya
University) and Yukiko MITSUGI (Ishikawa National College of Technology)
Proceedings of the 13th East Asia-Pacific Conference on Structure Engineering and Construction(EASEC-13), 8pages (on CDROM), Sapporo, JAPAN (2013)
In this study, FE analysis for the girder ends with corrosion has been carried out in order to understand thecollapse process and to evaluate its ultimate strength. At first, the strength of the girder end with various
corroded damages is evaluated based on the current design standards, “Specifications for Highway Bridges
in Japan”. Secondly, these collapse mechanism are analyzed from the analytical results, such as shapes of thedeformation mode, stress distribution, and load-deflection relationships and so on. Finally, we hadsummarized a flow diagram of a process of failure mode and the limit strength such as elastic, full-plastic
and ultimate limit states taking into account for local buckling.
Fundamental Study on the Dynamic Behavior of Sliding Bearing with Trigger for Bridge Structures
Takahiro KANATA, Masahide MATSUMURA, Yasuyuki NAKANISHI (NEWJEC Inc.) and Takashi
YAMAGUCHI−120−

Proceedings of the 13th East Asia-Pacific Conference on Structural Engineering, 8pages (on CDROM)(2013)
Isolation rubber bearings are widely used for damage mitigation of structures. However, isolation anddamping effects tend to be optimized against the short-period earthquake grand motions defined by theSpecifications for Highway Bridges in Japan. That is, as the isolation effects of the rubber bearings show
strong frequency dependence, applicability against a long-period earthquake grand motion is not clear, forinstance. Then the authors have focused on combination use of low friction and elastic sliding bearings,
triggers and displacement restrainers for bridge bearings. Fundamental responses of the proposed bearings
are checked through shaking table tests in this study and also discussed are analysis procedure of the
proposed bearings with the trigger in the seismic response analysis. Application example of the proposed
bearings to a viaduct is simulated through seismic response analysis. It is concluded that the analytical results
show good agreement with the experimental results when considering the changes in the vibration modes anddamping conditions before/after releasing the displacement of the superstructure by the triggers and the
maximum displacement is approximately computed even when without considering them in the seismic
response analysis.
An Experimental Study on Mechanical Properties of SBHS700 and Application of SBHS700 to
Stiffened Plates
Keita HAMAMURA (Osaka University), Kiyoshi ONO (Osaka University), Masahide MATSUMURA,
Takahiro TARUI (Osaka University) and Shinya KODA
Proceedings of the 13th East Asia-Pacific Conference on Structural Engineering, 6pages (on CDROM)(2013)
Higher yield strength steel plates for bridges, SBHS, has been standardized by Japanese Industrial Standard(JIS). However, there is not enough information on the mechanical properties of SBHS700 compared with
SM490 and SM570. In this study, tensile tests of SBHS700 were conducted to earn the information onmechanical properties and stress-strain relationship. Moreover, axial compressive tests were conducted withthe stiffened box section test specimens whose stiffeners are made of SBHS700. According to the axial
compressive tests, the ultimate strength and the ductility of hybrid stiffened plates by applying SBHS700
were investigated.
Cyclic Loading Test of Small-sized Steel Bellows made of Different Steel Materials subjected to Axial
Displacement
Masahide MATSUMURA, Kentaro TANAKA (Setsunan University), Hiroshi ZUI (Setsunan University)
and Takashi YAMAGUCHI
Proceedings of Constructional Steel, Vol.21, JSSC, pp.125-130 (2013) (in Japanese)
Steel bellows as energy absorbing bridge connectors, having been investigated by the authors, show stablehysteresis loop and energy absorbing capacity when subjected to axial displacement. In this paper, cyclic
behaviors of small sized steel bellows by bended in the same shape and made of different steel materials areinvestigated through cyclic loading test subjecting a larger axial displacement. Also discussed is a simplified
stress-strain relationship of steel materials of the steel bellows considered in FEM analysis to approximate
the load-displacement relationships and energy absorbing capacities of the steel bellows. It is concluded thata method considering the yield stress increase by bending process of steel plate is effective in the analysis of
the steel bellows but against a larger displacement where tensile load greatly increases due to strain
hardening.
Effect of Ultimate Strength Behavior due to the Support Eccentricity of the Girder End withCorrosion of Highway Bridges
Makoto USUKURA (Tokyo Consultants Co., Ltd.), Yasuo SUZUKI (Utsunomiya University), Takashi
YAMAGUCHI and Yukiko MITSUGI (Ishikawa National College of Technology)
Proceedings of Constructional Steel, Vol.21, JSSC, pp.193-200 (2013) (in Japanese)
In recent years, it has been well known that some of steel bridges are deteriorated by corrosion at the girder
ends. On the other hand, it is reported that the support is moved by the earthquake. If the phenomenon ofboth events is occurred, it is expected that the ultimate strength of the girder ends decline. In this study, FE
analysis for the girder ends with corrosion has been carried out in order to understand effect of ultimate−121−

strength behavior due to the eccentricity of the support of the girder end with corrosion of a plate girder for
Highway Bridges.
Discussion on A Design Method for a Emergency Crack Repair by Using High-strength Bolted CoverPlatesChao Pan, Takashi YAMAGUCHI, Akihisa KONDO (SOGO Engineering Inc.) and Yukiko MITSUGI(Ishikawa National College of Technology)
Proceedings of Constructional Steel, Vol.21, JSSC, pp.216-223 (2003) (in Japanese)
High-strength bolted cover plates often use for an emergency crack repair, designed as a friction-type joint.
A friction-type joint should be designed must not slip in service for a structural connection. Actually, even if
the friction-type joint slipped, it still has the shear and bearing resistance. So a design for the emergency
crack repair may consider the shear and bearing resistance for repairing crack, and it is discussed based on a
performance for a design method.
Considerations on Seismic Behavior of Steel Bridge Piers installed Isolation Bearing with Triggers
Masahide MATSUMURA, Takahiro KANATA, Yasuyuki NAKANISHI (NEWJEC Inc.) and Takashi
YAMAGUCHI
Proceedings of Constructional Steel, Vol.21, JSSC, pp.437-440 (2003) (in Japanese)
Resent year, from the viewpoint of rational fabrication of the steel bridges, there are some applications using
Side blocks are installed besides isolating bearings for restricting displacement of superstructure. The authors
consider an adoption of trigger type of steel side blocks, which restrict the displacement of superstructure
against a small and medium earthquake grand motion and release it against strong earthquake grand motions,in order to obtain isolation effect even in the transverse direction of the bridge axis. In this study, thefundamental behavior of the proposed bearing system is examined by shaking table test, analysis procedure
to approximate the response is proposed, and installation effects of the trigger type of steel side blocks into
an isolated viaduct on bridge pier response is computed through dynamic response analysis.
Compression Tests of Steel Columns bonded CFRP Strips of High Elastic Modulus focusing on
Adhesive Length
Masahide MATSUMURA, Shinya KODA, Nobuhiro HISABE (Mitsubishi Plastics Inc.) and Takashi
YAMAGUCHI
Proceedings of the 7th International Symposium on Steel Structures, ISSS, Jeju, Korea, pp.92-93 (2013)
Presented in this paper is strengthening technique of steel columns using CFRP strips as alternatives of steel
plates bolted in conventional one. As both the axial and flexural rigidity can be improved more effectively
when the elastic modulus of the strips is higher, so applications of the CFRP strips of high elastic modulus tosteel columns are focused on in this study. Then carried out are compression tests of pin-connected steel
column specimens adhered the CFRP strips with different adhesive patterns onto the flange plates. It is
concluded that improvements of the initial stiffness and enhancement of the elastic range can be obtained by
the adhered CFRP strips unless the debonding does not occur.
Study on Dynamic Behavior of Isolated Viaduct with Triggers; Modeling and Analysis Procedure
Masahide MATSUMURA, Takahiro KANATA, Yasuyuki NAKANISHI (NEWJEC Inc.) and Takashi
YAMAGUCHI
Proceedings of the 7th International Symposium on Steel Structures, ISSS, Jeju, Korea, pp.264-265 (2013)
Bridge isolation using isolation rubber bearings effectively reduces damages of bridge pier and foundationand is widely used in Japan. Here as the isolation effects are required only against a strong earthquake, theauthors propose combination use of the isolation bearings and triggers, which restrict the displacement ofsuperstructure against a small and medium earthquake grand motion and release it against a strong
earthquake grand motion. In the study, combination use of sliding bearings and the triggers are examined.
Then, modeling and analysis procedure of a vibration system with the trigger is verified through shaking
table test. And the break characteristics of the trigger are varied in seismic response analysis targeted a
viaduct. It is concluded that the break load of the trigger greatly influences on the maximum displacement of
the bridge pier and the trigger will be used for the maximum displacement control of the pier.

−122−

An Experimental Study on Seismic Performance of Hybrid Steel Piers with Vertical Ribs Made from
SBHS700
Kiyoshi ONO (Osaka University), Masahide MATSUMURA and Seiji OKADA (IHI Infrastructure System
Co., Ltd.)US-Japan Bridge Workshop, 10pages (2013)
Some methods for evaluating the seismic performance of steel bridge piers have been already proposed in
the previous studies. Steel bridge piers are sometimes required to have seismic performance that ductility isimproved with restraining increase in ultimate strength but it is difficult to fulfill such seismic performanceby the proposed methods in previous studies. By the way, "Higher yield strength steel plates for bridges" hasbeen standardized in Japanese industrial Standard (JIS). The major feature of higher yield strength steel
plates for bridges, SBHS, is high yield strength and high weldability. Among SBHS, SBHS700 has thehighest yield strength and the highest tensile strength. There is possibility of fulfilling the seismic
performance of steel bridge piers which has been difficult to gain so far by applying SBHS700 to them.
Therefore, the purpose of this study is to investigate material properties of SBHS700 and the seismic
performance of hybrid steel bridge piers whose vertical ribs are made from SBHS700.
Prediction of Liquefaction and Countermeasure due to Groundwater Lowering Method in Osaka andWakayama plains
Akihiko OSHIMA, Yuji HAYASHI, Teruyuki HAMADA and Mari KASUGAI
Journal of the Society of Materials Science Japan, Vol.63, No. 8, pp.614-619, 2014 (in Japanese)
The influence of groundwater rising for the liquefaction potential in Osaka and Wakayama plains was
examined using GIS in which a digital database of underground information provided by Kansai
Geo-informatics Database was introduced. The detailed geotechnical properties were calculated and given to
Holocene sandy and clayey deposits that are representative value in each digital mesh of 250m×250m areas.
Then, liquefaction safety assessments were carried out by estimating pumping possible quantity of Holocene
sandy deposits and considering negative effect of them against consolidation settlement problem that will
occur in Holocene clayey deposits underneath. The efficacy of groundwater lowering method againstliquefaction of Holocene sandy deposits was verified.
Comparison of Various Sounding Tests on General Site Investigations
Symposium of Ground Investigation Method for Small Buildings, Architectural Institute of Japan, pp.7-16,
2013 (in Japanese)
Akihiko OSHIMA
Shaking Model Tests on Mitigation of Liquefaction-Induced Ground Flow by New Configuration ofEmbedded Columns
Naoki TAKAHASHI, Derakhshani ALI, Rasouli ROUZBEH, Ikuo Towhata and Suguru YAMADA
Proc. of the 18th International Conference on Soil Mechanics and Geotechnical Engineering, Paris, pp.
1623-1626, 2013.
Traditionally, countermeasures against seismic liquefaction aimed to prevent significant development ofexcess pore water pressure. Although this aim was achieved by a variety of measures, the limitation has been
understood as well in the recent times. The limitation is typically found in lifelines and transportation lines(road embankment) together with river levees for which financial requirement is more strict and also residual
deformation is allowed to occur to a certain extent. In this regard, the present study addresses installation of
stable cement-mixed soil columns in liquefaction-prone subsoil so that ground deformation may beconstrained during earthquakes and lateral flow of liquefied sand may be reduced. For its validation, twotypes of shaking-table model tests have been conducted in 1-G environments.
A Study on Effect of Discharge of Thermal Water on Structure of Water Temperature in an Enclosed
Bay
Takaaki SHIGEMATSU and Masatoshi MAEKAWA
Proceedings of the Twenty-third (2013) International Offshore and Polar Engineering, pp. 1314-1320(2013)
Numerical simulation is carried out to evaluate effect of urban heat release into an enclosed sea on the watertemperature. To improve the condition of releasing the thermal effluent, the resolution near release point wasmade higher using two-way nesting method. As a result, it is found that the effect was not influenced by only−123−

conditions of release but tidal range, tidal elevation, and wind condition. Moreover, it is found that sea
surface temperature in Osaka Bay strongly depends on wind stress.
An Experimental Study on Development of a Breakwater Using Circular Cylinder Array
Kotaro TAKATA, Takaaki SHIGEMATSU, Kenji KATOH, Tatsuro WAKIMOTO and Shinya YOSHIOKA
Journal of Japan Society of Civil Engineers, Ser. B2 (Coastal Engineering), Vol. 69, No. 2, pp.
I_996-I_1000 (2013)
In this study, a new type breakwater with a submerged circular cylinder array was developed. Laboratory
experiments were carried out for investigation on effect of the height of submerged circular cylinder array on
wave absorber function. Experimental results were compared with theoretical solutions. For the other type ofa new breakwater with rotatable circular cylinder array, the characteristics of wave absorption were
investigated.
An Experimental Study on Microscopic Flow Over and Inside Porous Medium Placed on Oscillatory
Flow
Yuya OKADA, Takaaki SHIGEMATSU and Sota NAKAJOJournal of Japan Society of Civil Engineers, Ser. B2 (Coastal Engineering), Vol. 69, No. 2, pp. I_036-I_040(2013)In order to investigate interaction between upper and inside flow of a porous medium, the microscopic
structure of upper and inside flow of the porous medium placed in oscillatory flow was measured by theParticle Tracking Velocimetry (PTV) with the refractive index matching method. The strong shear flow wasobserved in the vicinity of the porous medium and the depth of shear flow varied with the phase of theoscillatory flow. The depth of non-dimensional shear flow was almost constant and it independent with the
Reynolds number. Besides, the phase difference of oscillatory flow between upper and inside flow of theporous medium was observed.
An Experimental Study on Properties of Turbulence induced by Oscillatory Flow Over Porous
MediumYuya OKADA, Takaaki SHIGEMATSU and Sota NAKAJOJournal of Japan Society of Civil Engineers, Ser. B2 (Coastal Engineering), Vol. 69, No. 2, pp. I_041-I_045(2013)The internal and external fluid flows induced by oscillatory flow over a porous medium were measured by
the Particle Tracking Velocimetry (PTV) with matching the refraction index method using two high-speed
cameras. The characteristics of spatial variance of velocity components were shown in detail with the timephase variance. Further, the properties of the turbulent quantities such as turbulent kinematic energy and the
Reynolds’ stress were presented and the relationship among the turbulence properties, the Reynolds’ number,and the KC number was discussed.
The Evaluation of Sewage Temperature and Flow Rate for Estimating Sewage Temperature and Flow
Rate in Sewer Line
Masahito MIKE, Minako NABESHIMA, Masatoshi NISHIOKA, Koichi SAWABE, Masaki NAKAO,
Yoshinori KANJO
Journal of the Society of Heating, Air-Conditioning and Sanitary Engineers of Japan, No.202, pp.11-21,
2014 (in Japanese)
In order to promote the opportunity of using heat energy of sewage, it is required to estimate sewage
temperature and sewage flow rate near domestic and industrial the buildings. In this study, we measured the
sewage temperature and flow rate at 17 locations in three different sewer lines in Osaka city. As the result,
we observed that the trend of the hourly sewage flow rate and the hourly ratio of house water consumption
are similar in the sewage lines corresponding to large housing ratios. Analyzed the correlation of the monthly
average sewage temperature and air temperature, we obtained highly accurate regression equation.
Proposal for Estimating Sewage Flow on Sunny Days in Sewer Line using Sewage Heat
Masahito MIKE, Minako NABESHIMA, Masatoshi NISHIOKA, Koichi SAWABE, Masaki NAKAO andYoshinori KANJO
Journal of the Society of Heating, Air-Conditioning and Sanitary Engineers of Japan, No.204, pp.47-55,
2014 (in Japanese)−124−In order to increase the opportunity of using sewage heat from sewer lines, the sewage flow in sewer lines
near buildings needs to be estimated. We determined the sewage characteristics by measuring the sewage
flow of a sewer line in Osaka City, and proposed a method to estimate the sewage flow in a sewer line. Thismethod can be applied to combined sewage on sunny days, and it can be estimate the sewage flow in an
optional area by referring to a known source at sewage plants. The Sewage flow is calculated by multiplying
the known sewage flow by the ratio of the estimated total floor area of buildings in the catchment area to themeasured total floor area of such buildings. The estimation method can be applied to a separate sewer systemand combined sewer system on a sunny day. The estimated values were approximately 0.7 - 1.1 of themeasured data. We proposed a method for estimating the hourly flow rate in a single regression model. The
explanatory variable of this model is the residential floor area ratio.
Reducing Excess Sludge from Bread Plant Wastewater Treatment: Combined Process of Contact
Oxidation and Aerobic Digestion
Shojiro OSUMI, Katsutoshi NAKAYAMA, Akihito KUMAMI, Yoshinori KANJO
Journal of Environmental Conservation Engineering, Vol.43, No.3, pp.162-171, 2014 (in Japanese)
Seeking to reduce the amount of excess sludge at a bread plant, we designed the following process first,
wastewater, including oil, is treated by contact oxidation; then it is separated into supernatant and floating
scum by pressurized floatation. After aerobic digestion of the scum, the supernatant and the treated scum are
mixed and discharged as sewage. If the mixed fluid suits for the standard for discharge into sewage, excess
sludge disposal is not necessary. We tested whether the above system was workable or not. We conducted
experiments on continuous contact oxidation for 230 days and continuous aerobic digestion of scum for 60days, which resulted in a BOD removal ratio of 97% and a BOD to SS conversion ratio of 0.13
g-SS/g-removed BOD by contact oxidation and a SS degradation ratio of 58.9% by aerobic digestion of thescum. We also showed that it is possible to express the results of the batch-wise aerobic digestion experimentwith a model based on the first-order reaction supposing the existence of easily degradable. persistent, andundegradable compounds in the sludge. Finally, we calculated the material balance of the entire system andshowed that the wastewater from the bread plant where we tested, including 1,200 mg/L of BOD and 450
mg/L of SS, could be treated by the process we designed with no excess sludge disposal required. This
treated water includes 80 mg/L of BOD and 99 mg/L of SS and could be discharged into sewers.
Recovery of the Rare Metals from Various Waste Ashes with the Aid of Temperature and UltrasoundIrradiation Using Chelants
Hiroshi HASEGAWA, Ismail M. M. RAHMAN, Yuji EGAWA, Hikaru SAWAI, Zinnat A. BEGUM,
Teruya MAKI, Satoshi MIZUTANIWater Air Soil Pollut. 225, 2112, (2014)
The incineration fly ash (IFA), molten fly ash (MFA), thermal power plant fly ash (TPP-FA), andnonferrous metal processing plant ash (MMA) have been screened in terms of the following rare-termed
metal contents: B, Ce, Co, Dy, Eu, Ga, Gd, Hf, In, Li, Lu, Mn, Nb, Nd, Ni, Pr, Rb, Sb, Se, Sm, Sr, Ta, Tb,
Te, Ti, Tm, V, W, Y, and Yb. The pseudo-potential for recycling of the waste ashes, as compared to the
cumulative concentration in the crust (mg kg−1), was determined as follows: MMA>IFA>MFA>TPP-FA.
The comparison with the crude ore contents indicates that the MMA is the best resource for reprocessing.
The recovery of the target metals using aminopolycarboxylate chelants (APCs) has been attempted atvarying experimental conditions and ultrasound-induced environment. A better APC-induced extraction
yield can be achieved at 0.10 mol L−1 concentration of chelant, or if the system temperature was maintained
between 60 to 80 °C. Nevertheless, the mechanochemical reaction induced by the ultrasound irradiation has
been, so far, the better option for rare metal dissolution with chelants as it can be conducted at a minimum
chelant concentration (0.01 mol L−1) and at room temperature (25±0.5 °C).
Selective Separation of Tri- and Pentavalent Arsenic in Aqueous Matrix with a
Macrocycle-Immobilized Solid-Phase Extraction System
Ismail M. M. RAHMAN, Zinnat A. BEGUM, Yoshiaki FURUSHO, Satoshi MIZUTANI, Teruya MAKI,
Hiroshi HASEGAWA
Water Air Soil Pollut, 224, 1526, 2013−125−

A simple flow-based method was developed for the selective separation of arsenic species (+3 and +5) using
a macrocycle-immobilized solid phase extraction (SPE) system, commonly known as molecular recognition
technology (MRT) gel. Arsenic species in solution or in the eluent were subsequently quantified withgraphite furnace atomic absorption spectrometry. The separation behaviors of As(III) and As(V) on MRT–SPE were investigated. It was found that As(V) can be selectively collected on the SPE system within therange of pH 4 to 9, while As(III) was passed through the MRT–SPE. The retention capacity of the MRT–
SPE material for As(V) was found to be 0.25±0.04 mmol g−1. The detection limit of the method for As(V)was 0.06 μg L−1, and the relative standard deviation was 2.9 % (n=10, C=1 μmol L−1). Interference from thematrix ions was studied. In order to validate the developed method, certified reference materials of effluent
wastewater and groundwater samples were analyzed, and the determined values were in good agreementwith the certified values. The proposed method was successfully applied to the speciation analysis of tri- andpentavalent arsenic in natural water samples showing satisfactory recoveries (≥ 98.7 %).
Effect of Extraction Variables on the Biodegradable Chelant-Assisted Removal of Toxic Metals from
Artificially Contaminated European Reference Soils
Zinnat A. BEGUM, Ismail M. M. RAHMAN, Hikaru SAWAI, Satoshi MIZUTANI, Teruya MAKI, Hiroshi
HASEGAWA
Water Air Soil Pollut, 224, 1381, (2013)
Development of aminopolycarboxylate chelants (APCs) having enhanced biodegradability is gaining
increasing focus to replace the EDTA and its homologs with those used widely for the ex situ treatment ofcontaminated soils and are potential eco-threats. The paper reports the chelant-assisted extraction of the toxic
metals (Cd, Cu, Pb, and Zn) fromthe metal-spiked European reference soils (Eurosoil 1 and Eurosoil 4) using
biodegradable APCs, namely EDDS, GLDA, and HIDS. The effects of chelant-to-metal molar ratio, solution
pH, and metal/chelant stability constants were evaluated, and compared with that of EDTA. The selectivity
aptitude of the biodegradable chelants towards the toxic metals was assumed from the speciation calculations,and a proportionate correlation was observed at neutral pH. Pre- and post-extractive solid phase distributionsof the target metals were defined using the sequential extraction procedure and dissolution of metals from thetheoretically immobilized fraction was witnessed. The effect of competing species (Al, Ca, Fe, Mg, and Mn)concentrations was proven to be minimized with an excess of chelant in solution. The highlight of theoutcomes is the superior decontamination ability of GLDA, a biodegradable APC, at minimum chelant
concentration in solution and applicability at a wide range of pH environments.
Validity Verification of Measurement Method of Carbon Dioxide Concentration in Water using
Water-resistant Breathable Tube
Toru ENDO, Toshiyuki TANAKA, Sosuke OTANI, Tetsuro FUJITA and Susumu YAMOCHI
Journal of Japan Society of Civil Engineers, Ser. B2 (Coastal Engineering), Vol. 69, No. 2, pp.
I_1251-I_1255 (2013) (in Japanese)
A carbon dioxide meter with water-resistant breathable tube was developed in order to measure CO2
concentration in water. Laboratory experiments were conducted for verification of the effectiveness of thismethod. After measuring the time variations of CO2 concentration in water aerating by air pump or adding
carbonic water, it was confirmed that this method was useful to evaluate the carbon cycle in coastal zone.
Furthermore, the CO2 production from sediment by decomposition of organic matter was confirmed bymeasuring the time variations of CO2 and DO concentrations in the water above sediment at the same time.
A Study on Mitigation of Density Stratification with Jet by Using Visualization Experiments
Tetsuya KOJO and Toru ENDO
Journal of Japan Society of Civil Engineers, Ser. B2 (Coastal Engineering), Vol. 69, No. 2, pp.
I_1226-I_1230 (2013) (in Japanese)
Mitigation of density stratification with jet was evaluated by using visualization experiments. First, wedeveloped a simple and high accuracy image analysis method to estimate the spatial distribution of density ofwater. Then, we experimented on various types of stratified field changing Froude number of the jet. We
verified that entrainment by jet and internal wave breakings are important to consider water mixing indensity stratified fields. Furthermore, we de ned the practical parameter including both the impact on thefield and the potential energy of the field. The parameter has a linear relation to the volume of new layer
formed after water mixing.

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A Method for Preventing the Outbreak of Green Tides at the Osaka Nanko Bird Sanctuary
Ryo SHIMANAMI, Toru ENDO and Susumu YAMOCHI
Journal of Japan Society of Civil Engineers, Ser. B2 (Coastal Engineering), Vol. 69, No. 2, pp.
I_1161-I_1165 (2013) (in Japanese)
Field surveys and laboratory experiments were carried out to prevent the outbreak of green tides at the northpond of Osaka Nanko bird sanctuary. Dense blooms of green algae, Ulva pertusa, Ulva ohnoi andRhizoclonium riparium were frequently observed in 2005-2012 and the most dominant species graduallychanged from Ulva pertusa to Ulva ohnoi, which is partly due to temperature increase and low salinity at a
growing season. Laboratory experiments revealed that photosynthesis was inhibited when they were exposed
to air for 6 hours at 35℃ followed by a low salinity of 20psu. These results suggest the possibility ofcontrolling green tides of Ulva pertusa and Ulva ohnoi by a combination of exposure to air with low salinity
in summer.
The Problem and Improvement on the Quantification Method of CO2 Absorption at an Artificial Tidal
FlatToshiyuki TANAKA, Tetsuro FUJITA and Susumu YAMOCHI
Journal of Japan Society of Civil Engineers, Ser. B2 (Coastal Engineering), Vol. 69, No. 2, pp.
I_1176-I_1180 (2013) (in Japanese)
CO2 concentrations were measured with light and dark chambers at an artificial tidal flat of Osaka Nanko
bird sanctuary in the spring and summer of 2012 to examine the effect of benthic microalgae, macrobenthosand bacteria. CO2 emission rate from the sediment was almost constant during a measuring interval in thedark chamber, while its absorption rate markedly decreased with time in the light chamber. The rapid
decrease of CO2 absorption rate was thought to be caused by low CO2 concentration in the light chamber inaccompanied with increasing photosynthetic activity of the benthic microalgae. To measure the absorption of
CO2 with a difference less than 40ppm from the atmosphere level, a ventilation rate of 10L air/min is
indispensable for the light chamber along with a bottom area below 450cm2.
A Research on the Fluctuation of CO2 Flux from the Sediment of a Tidal Flat in accompanied withTidal Change
Tetsuro FUJITA, Toru ENDO, Toshiyuki TANAKA and Susumu YAMOCHI
Journal of Japan Society of Civil Engineers, Ser. B2 (Coastal Engineering), Vol. 69, No. 2, pp.
I_1181-I_1185 (2013) (in Japanese)
Field surveys and indoor experiments were conducted at the north tidal flat of Osaka Nanko bird sanctuary in2012 in order to measure the amount of discharge of the carbon dioxide (CO2) which is an index of theamount of organic matter decomposition. The field survey revealed that CO2 flux increased with decrease of
the groundwater level when the bottom sediment emerged. The CO2 flux in the submerged period showed
0.2-1.2 mgCO2/m2/min which was less than 1/5 to 1/40 of the emerged period. In addition, the result of fieldsurveys together with indoor experiments suggested that CO2 flux changed depending on the flood tide or
falling tide as well as the groundwater level.

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ISSN

MEMOIRS OF THE FACULTY OF ENGINEERING OSAKA CITY UNIVERSITY
VOL. 55.
2014

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