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Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03.

Issue date 07/26/2017

Reviewed on 07/26/2017* 1 Identification· Product Identifier· Trade name: Spade Drill, H.S.S. Cutting Tools· Relevant identified uses of the substance or mixture and uses advised against:
Use with coolant or enclosed machine with ventilation· Product Description Cutting Tool
· Application of the substance / the mixture: Cutting tool used to drill a hole or similar into a work piece· Details of the Supplier of the Safety Data Sheet:· Manufacturer/Supplier:
Allied Machine & Engineering Corp.
120 Deeds Drive
Dover, Ohio 44622-0036
Phone: 330-343-4283
Fax: 330-602-3400
www.alliedmachine.com· Emergency telephone number: Ron Sundall 330-343-4283

2 Hazard(s) Identification· Classification of the substance or mixture:
GHS08 Health hazard
Resp. Sens. 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
Carc. 2
H351 Suspected of causing cancer.
STOT RE 1
H372 Causes damage to organs through prolonged or repeated exposure.
GHS07
Skin Irrit. 2
Skin Sens. 1

H315 Causes skin irritation.
H317 May cause an allergic skin reaction.

Eye Irrit. 2B

H320 Causes eye irritation.

· Label elements:· GHS label elements
The product is classified and labeled according to the Globally Harmonized System (GHS).
· Hazard pictograms:

GHS08· Signal word: Danger· Hazard-determining components of labeling:
CobaltNickel· Hazard statements:
H315+H320 Causes skin and eye irritation.
H334
May cause allergy or asthma symptoms or breathing difficulties if inhaled.
(Contd. on page 2)

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Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03.

Issue date 07/26/2017

Reviewed on 07/26/2017

Trade name: Spade Drill, H.S.S. Cutting Tools
H317
May cause an allergic skin reaction.
H351
Suspected of causing cancer.
H372
Causes damage to organs through prolonged or repeated exposure.
· Precautionary statements:
P201
Obtain special instructions before use.
P202
Do not handle until all safety precautions have been read and understood.
P260
Do not breathe dust/fume/gas/mist/vapors/spray.
P261
Avoid breathing dust/fume/gas/mist/vapors/spray.
P264
Wash thoroughly after handling.
P270
Do not eat, drink or smoke when using this product.
P272
Contaminated work clothing must not be allowed out of the workplace.
P280
Wear protective gloves/protective clothing/eye protection/face protection.
P284[In case of inadequate ventilation] wear respiratory protection.
P302+P352
IF ON SKIN: Wash with plenty of water.
P304+P341
If inhaled: If breathing is difficult, remove person to fresh air and keep comfortable forbreathing.
P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P308+P313
IF exposed or concerned: Get medical advice/attention.
P314
Get medical advice/attention if you feel unwell.
P321
Specific treatment (see supplementary first aid instructions on this Safety Data Sheet).
P332+P313
If skin irritation occurs: Get medical advice/attention.
P333+P313
If skin irritation or rash occurs: Get medical advice/attention.
P337+P313
If eye irritation persists: Get medical advice/attention.
P342+P311
If experiencing respiratory symptoms: Call a POISON CENTER/doctor.
P362+P364
Take off contaminated clothing and wash it before reuse.
P363
Wash contaminated clothing before reuse.
P405
Store locked up.
P501
Dispose of contents/container in accordance with local/regional/national/international
regulations.
· Unknown acute toxicity:
40 % of the mixture consists of component(s) of unknown toxicity.
· Classification system:· NFPA ratings (scale 0 - 4)

1

0

Health = 1
Fire = 0
Reactivity = 00· HMIS-ratings (scale 0 - 4)
HEALTH

*1

FIRE

0

REACTIVITY 0

Health = *1
Fire = 0
Physical Hazard = 0· Hazard(s) not otherwise classified (HNOC): None known

3 Composition/Information on Ingredients· Non-hazardous components:
CAS: 7440-62-2
Vanadium
RTECS: YW 1355000(Contd. on page 3)

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Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03.

Issue date 07/26/2017

Reviewed on 07/26/2017

Trade name: Spade Drill, H.S.S. Cutting Tools
CAS: 7439-98-7
Molybdenum
RTECS: QA 4680000
CAS: 7440-44-0
CarbonRTECS: FF 5250100· Chemical characterization: Mixtures· Description: Mixture of substances listed below with non-hazardous additions.
· Dangerous Components:
CAS: 7439-96-5
Manganese
RTECS: OO 9275000
Water-react. 1, H260
CAS: 7440-21-3
SiliconFlam. Sol. 2, H228;
Acute Tox. 4, H302; Eye Irrit. 2B, H320
CAS: 7440-02-0
NickelCarc. 2, H351; STOT RE 1, H372;
Skin Sens. 1, H317
CAS: 7440-47-3
Chromium
RTECS: GB 4200000
CAS: 7440-48-4
Cobalt
RTECS: GF 8750000
Resp. Sens. 1, H334; Carc. 2, H351;
Skin Sens. 1, H317; Aquatic Chronic 4,H413; Combustible Dust
CAS: 7439-89-6
Iron
RTECS: NO 4565500
Flam. Sol. 2, H228;
Skin Irrit. 2, H315; STOT SE 3, H335; Eye Irrit. 2B, H320;
Combustible Dust
· Additional information:
In order for this product to constitute a physical hazard or a health hazard it would have to be subjected tosubsequent operations such as heating to above 2600º F, cutting and/or grinding which may cause some of
the ingredients to change to a form, which could affect exposed workers.

4 First-Aid Measures· Description of first aid measures:· After inhalation: Supply fresh air; consult doctor if symptoms persist.
· After skin contact:
Wash with soap and water.
If skin irritation occurs, consult a doctor.
· After eye contact:
Rinse opened eye for at least 15 minutes under running water. If symptoms persist, consult a doctor.
· After swallowing:
Seek medical attention if large quantities of material have been ingested. (Ingestion of significant amounts ofmetal is unlikely).
· Information for doctor:· Most important symptoms and effects, both acute and delayed:
Excessive inhalation of metallic fumes and dust may be irritating to respiratory passages. Excessive
inhalation of fumes from many metals can produce an acute reaction known as “metal fume fever.” Symptoms
consist of chills and fever, a metallic taste in the mouth, and dryness and irritation of the throat. The
symptoms come on a few hours after excessive exposures and usually last from 12 to 48 hours. Long-term
effects from metal fume fever have not been noted. Iron oxide, copper and manganese have been associatedwith causing metal fume fever.
· Indication of any immediate medical attention and special treatment needed:
No further relevant information available.
(Contd. on page 4)

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Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03.

Issue date 07/26/2017

Reviewed on 07/26/2017

Trade name: Spade Drill, H.S.S. Cutting Tools

5 Fire-Fighting Measures· Extinguishing media:· Suitable extinguishing agents: Use fire fighting measures that suit the environment.
· Special hazards arising from the substance or mixture:
Solid tool steel product is not a fire hazard. Dust generated from grinding operations may ignite if allowed toaccumulate, and subjected to an ignition source.
· Advice for firefighters:· Protective equipment:
As in any fire, wear self-contained breathing apparatus pressure-demand (NIOSH approved or equivalent)
and full protective gear to prevent contact with skin and eyes.
* 6 Accidental Release Measures· Personal precautions, protective equipment and emergency procedures: Not required.
· Environmental precautions: No special measures required.
· Methods and material for containment and cleaning up:
Dispose contaminated material as waste according to section 13.
· Reference to other sections:
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
· Protective Action Criteria for Chemicals· PAC-1:
7440-44-0 Carbon
7439-96-5 Manganese
7440-21-3 Silicon
7440-02-0 Nickel
7440-47-3 Chromium
7440-62-2 Vanadium7439-98-7 Molybdenum
7440-48-4 Cobalt
7439-89-6 Iron

6 mg/m3
3 mg/m3
45 mg/m3
4.5 mg/m3
1.5 mg/m3
3 mg/m3
30 mg/m3
0.18 mg/m3
3.2 mg/m3· PAC-2:
7440-44-0 Carbon
7439-96-5 Manganese
7440-21-3 Silicon
7440-02-0 Nickel
7440-47-3 Chromium
7440-62-2 Vanadium7439-98-7 Molybdenum
7440-48-4 Cobalt
7439-89-6 Iron

330 mg/m3
5 mg/m3
100 mg/m3
50 mg/m3
17 mg/m3
5.8 mg/m3
330 mg/m3
2 mg/m3
35 mg/m3· PAC-3:
7440-44-0 Carbon
7439-96-5 Manganese

2,000 mg/m3
1,800 mg/m3(Contd. on page 5)

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Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03.

Issue date 07/26/2017

Reviewed on 07/26/2017

Trade name: Spade Drill, H.S.S. Cutting Tools
7440-21-3 Silicon
7440-02-0 Nickel
7440-47-3 Chromium
7440-62-2 Vanadium7439-98-7 Molybdenum
7440-48-4 Cobalt
7439-89-6 Iron

630 mg/m3
99 mg/m3
99 mg/m3
35 mg/m3
2,000 mg/m3
20 mg/m3
150 mg/m3

7 Handling and Storage· Handling· Precautions for safe handling:
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of dust.
· Information about protection against explosions and fires: Protect against electrostatic charges.
· Conditions for safe storage, including any incompatibilities:· Storage· Requirements to be met by storerooms and receptacles: Store in the original container.
· Information about storage in one common storage facility: Not required.
· Further information about storage conditions: None.
· Specific end use(s): No further relevant information available.
* 8 Exposure Controls/Personal Protection· Additional information about design of technical systems: No further data; see section 7.
· Control parameters:· Components with occupational exposure limits:
The following constituents are the only constituents of the product which have a PEL, TLV or otherrecommended exposure limit.
At this time, the remaining constituent has no known exposure limits.
7439-96-5 Manganese
PEL Ceiling limit value: 5 mg/m³
as Mn
REL Short-term value: 3 mg/m³
Long-term value: 1 mg/m³
fume, as Mn
TLV Long-term value: 0.02* 0.1** mg/m³
as Mn; *respirable **inhalable fraction
7440-21-3 Silicon
PEL Long-term value: 15* 5** mg/m³*total dust **respirable fraction
REL Long-term value: 10* 5** mg/m³*total dust **respirable fraction
TLV TLV withdrawn
7440-02-0 Nickel
PEL Long-term value: 1 mg/m³(Contd. on page 6)

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Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03.

Issue date 07/26/2017

Reviewed on 07/26/2017

Trade name: Spade Drill, H.S.S. Cutting Tools
REL Long-term value: 0.015 mg/m³
as Ni; See Pocket Guide App. A
TLV Long-term value: 1.5* mg/m³
elemental, *inhalable fraction
7440-47-3 Chromium
PEL Long-term value: 1 mg/m³
REL Long-term value: 0.5* mg/m³*metal+inorg.compds.as Cr;See Pocket Guide App. C
TLV Long-term value: (0.5) 0.5* mg/m³*inhalable fraction, as Cr(0)7439-98-7 Molybdenum
PEL Long-term value: 15* mg/m³*Total dust, as Mo
TLV Long-term value: 10* 3** mg/m³
as Mo; *inhalable fraction ** respirable fraction
7440-48-4 Cobalt
PEL Long-term value: 0.1* mg/m³
as Co; *for metal dust and fume
REL Long-term value: 0.05 mg/m³
as Co; metal dust & fumeTLV Long-term value: (0.02) NIC-0.02* mg/m³*inh. fraction; NIC-Skin, DSEN, RSEN (BEI)· Ingredients with biological limit values:
7440-48-4 Cobalt
BEI 15 µg/L
urine
end of shift at end of workweek
Cobalt (background)
1 µg/Lblood
end of shift at end of workweek
Cobalt (background, semi-quantitative)· Additional information: The lists that were valid during the creation of this SDS were used as basis.
· Exposure controls:
Ventilation must be adequate to maintain the ambient workplace atmosphere below the exposure limit(s)outlined in the SDS. Where acceptable concentrations cannot be maintained by general mechanicalventilation, local exhaust ventilation is recommended.
· Personal protective equipment:· General protective and hygienic measures:
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
· Breathing equipment:
NIOSH/OSHA or EN approved respiratory protection is recommended for use in airborne
concentrations exceeding exposure limits.
(Contd. on page 7)

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Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03.

Issue date 07/26/2017

Reviewed on 07/26/2017

Trade name: Spade Drill, H.S.S. Cutting Tools· Protection of hands:
Protective gloves· Penetration time of glove material:
The exact break-through time has to be determined and observed by the manufacturer of the protective
gloves.
· Eye protection:
Safety glasses

9 Physical and Chemical Properties· Information on basic physical and chemical properties· General Information· Appearance:
Solid
Form:
Grey
Color:· Odor:Odorless· Odor threshold:Not determined.
· pH-value:

Not applicable.

· Change in condition
Melting point/Melting range:
Boiling point/Boiling range:

Not determined.
Not determined.

· Flash point:

None· Flammability (solid, gaseous):

Not determined.

· Ignition temperature:
Decomposition temperature:

Not determined.

· Auto igniting:

Product is not self-igniting.

· Danger of explosion:

Product does not present an explosion hazard.

· Explosion limits:
Lower:
Upper:

Not determined.
Not determined.

· Vapor pressure:

Not applicable.

· Density:
Relative density:
Vapor density:
Evaporation rate:

Not determined.
Not applicable.
Not applicable.

· Solubility in / Miscibility with:
Water:

Insoluble.

· Partition coefficient (n-octanol/water): Not determined.

(Contd. on page 8)

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Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03.

Issue date 07/26/2017

Reviewed on 07/26/2017

Trade name: Spade Drill, H.S.S. Cutting Tools· Viscosity:
Dynamic:
Kinematic:· Other information:

Not applicable.
Not applicable.
No further relevant information available.

10 Stability and Reactivity· Reactivity: No further relevant information available.
· Chemical stability: Stable under normal conditions.
· Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
· Possibility of hazardous reactions: No known hazardous reactions· Conditions to avoid: Avoid exposure to generated dust and/or fumes.
· Incompatible materials: Reacts with strong acids to generate hydrogen gas.
· Hazardous decomposition products: Metallic Oxides* 11 Toxicological Information· Information on toxicological effects:· Acute toxicity:· LD/LC50 values that are relevant for classification:
7439-96-5 Manganese
Oral
LD50
9,000 mg/kg (Rat)
7440-21-3 Silicon
Oral
LD50
3,160 mg/kg (Rat)
7440-47-3 Chromium
Inhalative LC50/96 hours 14.3 mg/l (Cyprinus carpio)
7440-48-4 Cobalt
Oral
LD50
6,170 mg/kg (Rat)7439-89-6 Iron
Oral
LD50
7,500 mg/kg (Rat)· Primary irritant effect:· On the skin:
Irritant to skin and mucous membranes.
May cause an allergic skin reaction.
· On the eye:Irritating effect.
Causes serious eye irritation.
· Sensitization:
Sensitization possible through inhalation.
Sensitization possible through skin contact.
· Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for
preparations:HarmfulIrritant· Carcinogenic categories:· IARC (International Agency for Research on Cancer):
7440-02-0 Nickel

2B(Contd. on page 9)45.2.1

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Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03.

Issue date 07/26/2017

Reviewed on 07/26/2017

Trade name: Spade Drill, H.S.S. Cutting Tools
7440-47-3 Chromium
7440-48-4 Cobalt

32B· NTP (National Toxicology Program):
7440-02-0 Nickel
7440-48-4 Cobalt

RR· OSHA-Ca (Occupational Safety & Health Administration):
None of the ingredients are listed.
* 12 Ecological Information· Toxicity:· Aquatic toxicity:
7439-96-5 Manganese
EC50 40 mg/l (Water flea)
7440-02-0 Nickel
EC50 1 mg/l (Water flea)
7440-47-3 Chromium
EC50 0.07 mg/l (Water flea)· Persistence and degradability: No further relevant information available.
· Behavior in environmental systems:· Bioaccumulative potential: No further relevant information available.
· Mobility in soil: No further relevant information available.
· Additional ecological information:· General notes:
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
· Results of PBT and vPvB assessment:· PBT: Not applicable.
· vPvB: Not applicable.
· Other adverse effects: No further relevant information available.

13 Disposal Considerations· Waste treatment methods:· Recommendation:
Observe all federal, state and local environmental regulations when disposing of this material.
· Uncleaned packagings· Recommendation: Disposal must be made according to official regulations.

14 Transport Information· UN-Number:· DOT, ADR/ADN, ADN, IMDG, IATA
· UN proper shipping name:· DOT, ADR/ADN, ADN, IMDG, IATA
· Transport hazard class(es):· DOT, ADR/ADN, ADN, IMDG, IATA
· Class:

Non-Regulated Material
Non-Regulated Material

Non-Regulated Material(Contd. on page 10)

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Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03.

Issue date 07/26/2017

Reviewed on 07/26/2017

Trade name: Spade Drill, H.S.S. Cutting Tools· Packing group:· DOT, ADR/ADN, IMDG, IATA
Non-Regulated Material· Environmental hazards:
Not applicable.
· Special precautions for user:
Not applicable.
· Transport in bulk according to Annex II of
Not applicable.
MARPOL73/78 and the IBC Code:· UN "Model Regulation":
Non-Regulated Material* 15 Regulatory Information· Safety, health and environmental regulations/legislation specific for the substance or mixture:· SARA (Superfund Amendments and Reauthorization):· Section 355 (extremely hazardous substances):
None of the ingredients are listed.
· Section 313 (Specific toxic chemical listings):
7439-96-5 Manganese
7440-02-0 Nickel
7440-47-3 Chromium
7440-62-2 Vanadium
7440-48-4 Cobalt· TSCA (Toxic Substances Control Act):All ingredients are listed or exempt from listing.
· California Proposition 65:· Chemicals known to cause cancer:
7440-02-0 Nickel
7440-48-4 Cobalt· Chemicals known to cause reproductive toxicity for females:
None of the ingredients are listed.
· Chemicals known to cause reproductive toxicity for males:
None of the ingredients are listed.
· Chemicals known to cause developmental toxicity:
None of the ingredients are listed.
· New Jersey Right-to-Know List:
7439-96-5 Manganese
7440-21-3 Silicon
7440-02-0 Nickel
7440-47-3 Chromium
7440-62-2 Vanadium7439-98-7 Molybdenum
7440-48-4 Cobalt· New Jersey Special Hazardous Substance List:
7439-96-5 Manganese
7440-21-3 Silicon
7440-02-0 Nickel

F3, R1F3CA(Contd. on page 11)45.2.1

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Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03.

Issue date 07/26/2017

Reviewed on 07/26/2017

Trade name: Spade Drill, H.S.S. Cutting Tools
7440-47-3 Chromium
7440-48-4 Cobalt

F3CA, F3· Pennsylvania Right-to-Know List:
7439-96-5 Manganese
7440-21-3 Silicon
7440-02-0 Nickel
7440-47-3 Chromium
7440-62-2 Vanadium7439-98-7 Molybdenum
7440-48-4 Cobalt· Pennsylvania Special Hazardous Substance List:
7439-96-5 Manganese
7440-02-0 Nickel
7440-47-3 Chromium
7440-62-2 Vanadium
7440-48-4 Cobalt

E
ES
ES
E
E

· Carcinogenic categories:· EPA (Environmental Protection Agency):
7439-96-5 Manganese
7440-47-3 Chromium

D
D· TLV (Threshold Limit Value established by ACGIH):
7440-02-0 Nickel
7440-47-3 Chromium
7439-98-7 Molybdenum
7440-48-4 Cobalt

A5
A4
A3
A3

· NIOSH-Ca (National Institute for Occupational Safety and Health):
7440-02-0 Nickel· GHS label elements
The product is classified and labeled according to the Globally Harmonized System (GHS).
· Hazard pictograms:

GHS08· Signal word: Danger· Hazard-determining components of labeling:
CobaltNickel· Hazard statements:
H315+H320 Causes skin and eye irritation.
H334
May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H317
May cause an allergic skin reaction.
H351
Suspected of causing cancer.
(Contd. on page 12)45.2.1

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Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03.

Issue date 07/26/2017

Reviewed on 07/26/2017

Trade name: Spade Drill, H.S.S. Cutting Tools
H372
Causes damage to organs through prolonged or repeated exposure.
· Precautionary statements:
P201
Obtain special instructions before use.
P202
Do not handle until all safety precautions have been read and understood.
P260
Do not breathe dust/fume/gas/mist/vapors/spray.
P261
Avoid breathing dust/fume/gas/mist/vapors/spray.
P264
Wash thoroughly after handling.
P270
Do not eat, drink or smoke when using this product.
P272
Contaminated work clothing must not be allowed out of the workplace.
P280
Wear protective gloves/protective clothing/eye protection/face protection.
P284[In case of inadequate ventilation] wear respiratory protection.
P302+P352
IF ON SKIN: Wash with plenty of water.
P304+P341
If inhaled: If breathing is difficult, remove person to fresh air and keep comfortable forbreathing.
P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P308+P313
IF exposed or concerned: Get medical advice/attention.
P314
Get medical advice/attention if you feel unwell.
P321
Specific treatment (see supplementary first aid instructions on this Safety Data Sheet).
P332+P313
If skin irritation occurs: Get medical advice/attention.
P333+P313
If skin irritation or rash occurs: Get medical advice/attention.
P337+P313
If eye irritation persists: Get medical advice/attention.
P342+P311
If experiencing respiratory symptoms: Call a POISON CENTER/doctor.
P362+P364
Take off contaminated clothing and wash it before reuse.
P363
Wash contaminated clothing before reuse.
P405
Store locked up.
P501
Dispose of contents/container in accordance with local/regional/national/international
regulations.
· National regulations:None of the ingredients are listed.
· Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

16 Other Information
The information and recommendations in this safety data sheet are, to the best of our knowledge, accurate asof the date of issue. Nothing herein shall be deemed to create warranty, expressed or implied, and shall notestablish a legally valid contractual relationship. It is the responsibility of the user to determine applicability ofthis information and the suitability of the material or product for any particular purpose.
· Date of preparation / last revision: 07/26/2017 / 3· Abbreviations and acronyms:

ADR: The European Agreement concerning the International Carriage of Dangerous Goods by Road
ADN: The European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety and Health(Contd. on page 13)

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Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03.

Issue date 07/26/2017

Reviewed on 07/26/2017

Trade name: Spade Drill, H.S.S. Cutting Tools
OSHA: Occupational Safety & Health Administration
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
BEI: Biological Exposure Limit
Flam. Sol. 2: Flammable solids – Category 2
Water-react. 1: Substances and mixtures which in contact with water emit flammable gases – Category 1
Acute Tox. 4: Acute toxicity – Category 4
Skin Irrit. 2: Skin corrosion/irritation – Category 2
Eye Irrit. 2B: Serious eye damage/eye irritation – Category 2B
Resp. Sens. 1: Respiratory sensitisation – Category 1
Skin Sens. 1: Skin sensitisation – Category 1
Carc. 2: Carcinogenicity – Category 2
Carc. 2: Carcinogenicity – Category 2
STOT SE 3: Specific target organ toxicity (single exposure) – Category 3
STOT RE 1: Specific target organ toxicity (repeated exposure) – Category 1
Aquatic Chronic 4: Hazardous to the aquatic environment - long-term aquatic hazard – Category 4· * Data compared to the previous version altered.
SDS created by MSDS Authoring Services www.msdsauthoring.com+1-877-204-9106