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Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910.1200(g) revised in 2012 and GHS Rev 03.

Issue date 09/08/2020*

Reviewed on 09/08/2020

1 Identification· Product Identifier· Trade Name: All Cemented Carbide Grade Inserts, Drills, & Solid Carbide Products· Relevant identified uses of the substance or mixture and uses advised against:
Use with coolant or enclosed machine with ventilation.
· Product Description: All Cemented Carbide Grade Inserts, Drills, & Solid Carbide Products .
· Application of the substance / the mixture: Cutting tool used to drill a hole or something similar.
· Details of the Supplier of the Safety Data Sheet:· Manufacturer/Supplier:
Allied Machine & Engineering Corp.
120 Deeds Drive
Dover, Ohio 44622-0036
Phone: 330-343-4283
Fax: 330-602-3400
www.alliedmachine.com· Emergency telephone number: 330-343-4283

2 Hazard(s) Identification· Classification of the substance or mixture:
Health hazard
Resp. Sens. 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
Carc. 1B
H350 May cause cancer. Route of exposure: Inhalation.
Repr. 1
H360 May damage fertility or the unborn child.
STOT RE 1
H372 Causes damage to the respiratory system through prolonged or repeated exposure.
Route of exposure: Inhalation.

Skin Irrit. 2
Eye Irrit. 2A
Skin Sens. 1
STOT SE 3

H315 Causes skin irritation.
H319 Causes serious eye irritation.
H317 May cause an allergic skin reaction.
H335 May cause respiratory irritation.

· Label elements:· Hazard pictograms:· Signal word: Danger· Hazard-determining components of labeling:
Tungsten Carbide
CobaltDiamondnickel· Hazard statements:
H315 Causes skin irritation.
(Contd. on page 2)

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Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910.1200(g) revised in 2012 and GHS Rev 03.

Issue date 09/08/2020

Reviewed on 09/08/2020

Trade Name: All Cemented Carbide Grade Inserts, Drills, & Solid Carbide Products
H319 Causes serious eye irritation.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H317 May cause an allergic skin reaction.
H350 May cause cancer. Route of exposure: Inhalation.
H360 May damage fertility or the unborn child.
H335 May cause respiratory irritation.
H372 Causes damage to the respiratory system through prolonged or repeated exposure. Route of exposure:
Inhalation.
· Precautionary statements:
P201
Obtain special instructions before use.
P202
Do not handle until all safety precautions have been read and understood.
P260
Do not breathe dust/fume/gas/mist/vapors/spray.
P261
Avoid breathing dust/fume/gas/mist/vapors/spray.
P264
Wash thoroughly after handling.
P270
Do not eat, drink or smoke when using this product.
P271
Use only outdoors or in a well-ventilated area.
P272
Contaminated work clothing must not be allowed out of the workplace.
P280
Wear protective gloves/protective clothing/eye protection/face protection.
P284[In case of inadequate ventilation] wear respiratory protection.
P302+P352
If on skin: Wash with plenty of water.
P304+P340
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P304+P341
If inhaled: If breathing is difficult, remove person to fresh air and keep comfortable forbreathing.
P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P308+P313
IF exposed or concerned: Get medical advice/attention.
P312
Call a poison center/doctor if you feel unwell.
P321
Specific treatment (see supplementary first aid instructions on this Safety Data Sheet).
P314
Get medical advice/attention if you feel unwell.
P362+P364
Take off contaminated clothing and wash it before reuse.
P332+P313
If skin irritation occurs: Get medical advice/attention.
P333+P313
If skin irritation or rash occurs: Get medical advice/attention.
P337+P313
If eye irritation persists: Get medical advice/attention.
P342+P311
If experiencing respiratory symptoms: Call a poison center/doctor.
P363
Wash contaminated clothing before reuse.
P403+P233
Store in a well-ventilated place. Keep container tightly closed.
P405
Store locked up.
P501
Dispose of contents/container in accordance with local/regional/national/international
regulations.
· Unknown acute toxicity:
This value refers to knowledge of known, established toxicological or ecotoxicological values.
126 % of the mixture consists of component(s) of unknown toxicity.
· Classification system: NFPA/HMIS Definitions: 0-Least, 1-Slight, 2-Moderate, 3-High, 4-Extreme· NFPA ratings (scale 0 - 4)

2

0

Health = 2
Fire = 0
Reactivity = 00· HMIS-ratings (scale 0 - 4)
HEALTH

*2

FIRE

0

REACTIVITY 0

Health = *2
Fire = 0
Physical Hazard = 0(Contd. on page 3)

51.1.17

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Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910.1200(g) revised in 2012 and GHS Rev 03.

Issue date 09/08/2020

Reviewed on 09/08/2020

Trade Name: All Cemented Carbide Grade Inserts, Drills, & Solid Carbide Products· Hazard(s) not otherwise classified (HNOC): None known

3 Composition/Information on Ingredients· Non-hazardous components:
12069-89-5 Molybdenum Carbide
0-15%
12011-99-3 Niobium Carbide
0-12%· Chemical characterization: Substance· Description: Mixture of substances listed below with non-hazardous additions.
· Dangerous Components:
CAS: 12070-12-1
Tungsten Carbide
65-97%
RTECS: YO 7250000
Carc. 1B, H350
CAS: 7782-40-3
Diamond0-50%
Skin Irrit. 2, H315; STOT SE 3, H335; Eye Irrit. 2B, H320
0-50%
CAS: 10043-11-5
Boron Nitride
Skin Irrit. 2, H315; STOT SE 3, H335; Eye Irrit. 2B, H320
CAS: 12070-06-3
Tantalum Carbide
0-50%
CAS: 7440-48-4
Cobalt
2-30%
RTECS: GF 8750000
Resp. Sens. 1, H334; Muta. 2, H341; Carc. 1B, H350; Repr. 1B, H360;
Skin Sens. 1, H317; Aquatic Chronic 4, H413; Combustible Dust
CAS: 7440-02-0
nickel0-20%
Carc. 2, H351; STOT RE 1, H372;
Skin Sens. 1, H317; Aquatic Acute3, H402
CAS: 12070-08-5
Titanium Carbide
0-13%
Skin Irrit. 2, H315; STOT SE 3, H335; Eye Irrit. 2B, H320
CAS: 12012-35-0
Chromium Carbide
0-5.1%
CAS: 7440-47-3
Chromium
0-3%
RTECS: GB 4200000
CAS: 1303-86-2
diboron trioxide
0-2%
RTECS: ED 7900000
Repr. 1B, H360
0-2%
CAS: 1309-37-1
Ferric oxide
RTECS: NO 7400000
Skin Irrit. 2, H315; Eye Irrit. 2A, H319; STOT SE 3, H335
CAS: 7439-98-7
Molybdenum
0-2%
RTECS: QA 4680000
CAS: 7440-67-7
Zirconium
0-2%
RTECS: ZH 7070000
Pyr. Sol. 1, H250; Water-react. 1, H260
· Additional information:
The exact percentages of the ingredients of this mixture are considered to be proprietary and are withheld inaccordance with the provisions of paragraph (i) of §1910.1200 of 29 CFR 1910.1200 Trade Secrets.
The finished product may be coated with any one or more of the following material(s):Material
Aluminum Oxide
Titanium Aluminum Nitride
Titanium Nitride
Titanium Carbonitride
Aluminum Chromium Nitride

CAS #1344-28-1
108398-79-4
25583-20-4
12627-33-7
880098-18-0(Contd. on page 4)

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Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910.1200(g) revised in 2012 and GHS Rev 03.

Issue date 09/08/2020

Reviewed on 09/08/2020

Trade Name: All Cemented Carbide Grade Inserts, Drills, & Solid Carbide Products

4 First-Aid Measures· Description of first aid measures· General information:
Symptoms of poisoning may occur after exposure to dust, fumes or particulates; seek medical attention if
feeling unwell.
· After inhalation: In case of unconsciousness place patient stably in the side position for transportation.
· After skin contact:
Immediately wash with water and soap and rinse thoroughly.
If skin irritation occurs, consult a doctor.
Wash with soap and water.
· After eye contact:
Rinse opened eye for at least 15 minutes under running water. If symptoms persist, consult a doctor.
If easy to do so, remove contact lenses if worn.
If eye irritation occurs, consult a doctor.
· After swallowing:
Wash out mouth with water provided person is conscious. Never give anything by mouth to an unconscious
person. Get medical attention.
If swallowed and symptoms occur, consult a doctor.
· Information for doctor· Most important symptoms and effects, both acute and delayed: No further relevant information available.
· Indication of any immediate medical attention and special treatment needed:
No further relevant information available.

5 Fire-Fighting Measures· Extinguishing media· Suitable extinguishing agents:
For powder fires smother with dry sand, dry dolomite, ABC type fire extinguisher, or flood with water.
· For safety reasons unsuitable extinguishing agents: No further relevant information.
· Special hazards arising from the substance or mixture:
Moderate fire hazard when it is in the form of a dust (powder) and burns rapidly when heated in flame.
Chromium is attacked vigorously by fused potassium chlorate producing vivid incandescence. Pyrophoric
chromium unites with nitric oxide with incandescence. Incandescent reaction with nitrogen oxide or sulfur
dioxide.
Special Remarks on Explosion Hazards:
Powdered Chromium metal +fused ammonium nitrate may react violently or explosively. Powdered Chromium
will explode spontaneously in air.
Hard cemented carbide product is not a fire hazard, under normal conditions of use. Dusts generated in
grinding operations may be sensitive to static discharge or ignite if allowed to accumulate, and subjected to an
ignition source. Dusts may present a fire or explosion hazard under rare favoring conditions of particle size,
dispersion, concentration, and strong ignition source. However, this is not expected to be a problem undernormal handling conditions.
· Advice for firefighters· Special protective equipment for firefighters:
As in any fire, wear self-contained breathing apparatus pressure-demand (NIOSH approved or equivalent) andfull protective gear to prevent contact with skin and eyes.
For a powder fire confined to a small area, use a respirator approved for toxic dusts and fumes. For a large
fire, firefighters should use self-contained breathing apparatus.
(Contd. on page 5)

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Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910.1200(g) revised in 2012 and GHS Rev 03.

Issue date 09/08/2020

Reviewed on 09/08/2020

Trade Name: All Cemented Carbide Grade Inserts, Drills, & Solid Carbide Products· Additional information:
At temperatures above 200°C Zirconium reacts exothermically with the following: fluorine, chloride, bromide,
iodine, halocarbons, carbon tetrachloride, carbon, tetra fluoride and Freon’s.
Oxides of aluminum, cobalt, titanium, and tungsten; carbon dioxide, and carbon monoxide. See Section IV for
specific hazard identification.

6 Accidental Release Measures· Personal precautions, protective equipment and emergency procedures: Not required.
· Environmental precautions: Do not allow product to reach sewage system or any water course.
· Methods and material for containment and cleaning up:
Dispose of contaminated material as waste according to section 13.
Ensure adequate ventilation.
Dispose of the collected material according to regulations.
Clean up using methods which avoid dust generation such as vacuum (with appropriate filter to prevent
airborne dust levels which exceed the PEL or TLV), wet dust mop or web clean-up.
· Reference to other sections:
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
· Protective Action Criteria for Chemicals· PAC-1:
12070-12-1 Tungsten Carbide
11 mg/m³
7782-40-3 Diamond
6.3 mg/m³
12070-06-3 Tantalum Carbide
11 mg/m³
7440-48-4 Cobalt
0.18 mg/m³
7440-02-0 nickel
4.5 mg/m³
12070-08-5 Titanium Carbide
30 mg/m³
7440-47-3 Chromium
1.5 mg/m³
1303-86-2 diboron trioxide
30 mg/m³
1309-37-1 Ferric oxide
15 mg/m³
7439-98-7 Molybdenum
30 mg/m³
7440-67-7 Zirconium
10 mg/m³
7440-58-6 hafnium
1.5 mg/m³
1344-28-1 Aluminium Oxide
15 mg/m³· PAC-2:
12070-12-1 Tungsten Carbide
7782-40-3 Diamond
12070-06-3 Tantalum Carbide
7440-48-4 Cobalt
7440-02-0 nickel
12070-08-5 Titanium Carbide
7440-47-3 Chromium
1303-86-2 diboron trioxide
1309-37-1 Ferric oxide7439-98-7 Molybdenum
7440-67-7 Zirconium

120 mg/m³
69 mg/m³
120 mg/m³
2 mg/m³
50 mg/m³
330 mg/m³
17 mg/m³
100 mg/m³
360 mg/m³
330 mg/m³
83 mg/m³(Contd. on page 6)

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Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910.1200(g) revised in 2012 and GHS Rev 03.

Issue date 09/08/2020

Reviewed on 09/08/2020

Trade Name: All Cemented Carbide Grade Inserts, Drills, & Solid Carbide Products
7440-58-6 hafnium
1344-28-1 Aluminium Oxide

17 mg/m³
170 mg/m³· PAC-3:
12070-12-1 Tungsten Carbide
7782-40-3 Diamond
12070-06-3 Tantalum Carbide
7440-48-4 Cobalt
7440-02-0 nickel
12070-08-5 Titanium Carbide
7440-47-3 Chromium
1303-86-2 diboron trioxide
1309-37-1 Ferric oxide7439-98-7 Molybdenum
7440-67-7 Zirconium
7440-58-6 hafnium
1344-28-1 Aluminium Oxide

730 mg/m³
1,100 mg/m³
730 mg/m³
20 mg/m³
99 mg/m³
2,000 mg/m³
99 mg/m³
620 mg/m³
2,200 mg/m³
2,000 mg/m³
500 mg/m³
99 mg/m³
990 mg/m³

7 Handling and Storage· Handling· Precautions for safe handling:
Avoid creating and breathing dust/fume/gas/mist/vapors/spray.
Ensure good ventilation/exhaustion at the workplace.
Open and handle receptacle with care.
Prevent formation of dust.
· Information about protection against explosions and fires: Keep protective respiratory device available.
· Conditions for safe storage, including any incompatibilities· Storage· Requirements to be met by storerooms and receptacles: Store in a cool, dry place.
· Information about storage in one common storage facility: Not required.
· Further information about storage conditions: Keep receptacle tightly sealed.
· Specific end use(s): No further relevant information available.

8 Exposure Controls/Personal Protection· Additional information about design of technical systems: No further data; see section 7.
· Control parameters:· Components with occupational exposure limits:
The following constituents are the only constituents of the product which have a PEL, TLV or otherrecommended exposure limit.
At this time, the other constituents have no known exposure limits.
12070-12-1 Tungsten Carbide
REL
Short-term value: 10 mg/m³
Long-term value: 5 mg/m³
as W
TLV
Long-term value: 3* mg/m³
as W; * respirable fraction(Contd. on page 7)

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Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910.1200(g) revised in 2012 and GHS Rev 03.

Issue date 09/08/2020

Reviewed on 09/08/2020

Trade Name: All Cemented Carbide Grade Inserts, Drills, & Solid Carbide Products
12070-06-3 Tantalum Carbide
TWA
Short-term value: 10 mg/m³
7440-48-4 Cobalt
PEL
Long-term value: 0.1* mg/m³
as Co; *for metal dust and fume
REL
Long-term value: 0.05 mg/m³
as Co; metal dust & fume
TLV
Long-term value: 0.02* mg/m³*inh. fraction; DSEN, RSEN, BEI
7440-02-0 nickel
PEL
Long-term value: 1 mg/m³
REL
Long-term value: 0.015 mg/m³
as Ni; See Pocket Guide App. A
TLVLong-term value: 1.5* mg/m³
elemental, *inhalable fraction
12012-35-0 Chromium Carbide
OSHA TWA Short-term value: 0.5 mg/m³
Long-term value: 1.0 mg/m³
7440-47-3 Chromium
PEL
Long-term value: 1 mg/m³
REL
Long-term value: 0.5* mg/m³*metal+inorg.compds.as Cr;See Pocket Guide App. C
TLVLong-term value: 0.003* 0.5** mg/m³
inh. fraction, *as Cr(III),**metal
1303-86-2 diboron trioxide
PEL
Long-term value: 15* mg/m³*total dust
REL
Long-term value: 10 mg/m³
TLV
Long-term value: 10 mg/m³
1309-37-1 Ferric oxide
PEL
Long-term value: 10* mg/m³
*Fume
REL
Long-term value: 5 mg/m³
Dust & fume, as Fe
TLVLong-term value: 5* mg/m³*as respirable fraction
7439-98-7 Molybdenum
PEL
Long-term value: 15* mg/m³*Total dust, as Mo
TLVLong-term value: 10* 3** mg/m³
as Mo; *inhalable fraction ** respirable fraction
7440-67-7 Zirconium
PEL
Long-term value: 5 mg/m³
as Zr
REL
Short-term value: 10 mg/m³
Long-term value: 5 mg/m³
as Zr(Contd. on page 8)

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Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910.1200(g) revised in 2012 and GHS Rev 03.

Issue date 09/08/2020

Reviewed on 09/08/2020

Trade Name: All Cemented Carbide Grade Inserts, Drills, & Solid Carbide Products
TLV

Short-term value: 10 mg/m³
Long-term value: 5 mg/m³
as Zr· Ingredients with biological limit values:
7440-48-4 Cobalt
BEI 15 µg/L
urine
end of shift at end of workweek
Cobalt (background)
1 µg/Lblood
end of shift at end of workweek
Cobalt (background, semi-quantitative)· Additional information: The lists that were valid during the creation of this SDS were used as basis.
· Exposure controls:· Personal protective equipment· General protective and hygienic measures:
Use adequate exhaust ventilation to prevent inhalation of dust particles.
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing and wash before reuse.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Avoid contact with the eyes and skin.
· Breathing equipment:
NIOSH/OSHA or EN approved respiratory protection is recommended for use in airborne
concentrations exceeding exposure limits.
· Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
· Material of gloves:
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality
and varies from manufacturer to manufacturer. As the product is a preparation of several substances, theresistance of the glove material cannot be calculated in advance and has therefore to be checked prior to theapplication.
· Penetration time of glove material:
The exact break-through time has to be determined and observed by the manufacturer of the protective
gloves.
· Eye protection:
Tightly sealed goggles· Limitation and supervision of exposure into the environment: None
(Contd. on page 9)51.1.17

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Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910.1200(g) revised in 2012 and GHS Rev 03.

Issue date 09/08/2020

Reviewed on 09/08/2020

Trade Name: All Cemented Carbide Grade Inserts, Drills, & Solid Carbide Products

9 Physical and Chemical Properties· Information on basic physical and chemical properties· General Information· Appearance:
Form:
Solid
Color:
Gray to black to bright metallic. Some grades are gold colored.
· Odor:Odorless· Odor threshold:Not determined.
· pH-value:

Not applicable.

· Change in condition
Melting point/Melting range:
Boiling point/Boiling range:

Not determined.
Not determined.

· Flash point:

None· Flammability (solid, gaseous):

Not determined.

· Ignition temperature:

Not applicable· Decomposition temperature:

Not determined.

· Auto igniting:

Product is not self-igniting.

· Danger of explosion:

Product does not present an explosion hazard.

· Explosion limits:
Lower:
Upper:

Not determined.
Not determined.

· Vapor pressure:

Not applicable.

· Density:
Relative density:
Vapor density:
Evaporation rate:

Not determined.
Not applicable.
Not applicable.

· Solubility in / Miscibility with:
Water:

Insoluble.

· Partition coefficient (n-octanol/water): Not determined.
· Viscosity:
Dynamic:
Kinematic:

Not applicable.
Not applicable.

· Solvent content:
VOC content:· Other information:

0.00 %
No further relevant information available.

10 Stability and Reactivity· Reactivity: No further relevant information available.
· Chemical stability: Stable under normal conditions.
· Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
· Possibility of hazardous reactions: No dangerous reactions known.
· Conditions to avoid: Strong Acids(Contd. on page 10)51.1.17

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Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910.1200(g) revised in 2012 and GHS Rev 03.

Issue date 09/08/2020

Reviewed on 09/08/2020

Trade Name: All Cemented Carbide Grade Inserts, Drills, & Solid Carbide Products· Incompatible materials:
Avoid Strong Acids. Contact of dust with strong oxidizers may cause fire or explosions.
· Hazardous decomposition products: Toxic chromium oxide fumes.

11 Toxicological Information· Information on toxicological effects:· Acute toxicity:· LD/LC50 values that are relevant for classification:
7782-40-3 Diamond
Oral
LD50
10,000 mg/kg (Mouse)
7440-48-4 Cobalt
Oral
LD50
6,170 mg/kg (Rat)
7440-47-3 Chromium
Inhalative LC50/96 hours 14.3 mg/l (Cyprinus carpio)
1309-37-1 Ferric oxide
Oral
LD50
>5,000 mg/kg (Rat)7439-98-7 Molybdenum
Oral
LD50
>5,000 mg/kg (Rat)
DermalLD50>2,000 mg/kg (Rat)Inhalative LC50/4 h
800 mg/l (Trout)>5.84 mg/l (Rat)· Primary irritant effect:· On the skin:
Irritant to skin and mucous membranes.
May cause an allergic skin reaction.
· On the eye: Irritating effect.
· Sensitization:
Sensitization possible through inhalation.
Sensitization possible through skin contact.
· Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for
preparations:HarmfulIrritant· Carcinogenic categories:· IARC (International Agency for Research on Cancer):Group 1 - Carcinogenic to humans
Group 2A - Probably carcinogenic to humans
Group 2B - Possibly carcinogenic to humans
Group 3 - Not classifiable as to its carcinogenicity to humans
Group 4 - Probably not carcinogenic to humans
12070-12-1 Tungsten Carbide
7440-48-4 Cobalt
7440-02-0 nickel
7440-47-3 Chromium
1309-37-1 Ferric oxide

2A
2B
2B
3
3
(Contd. on page 11)51.1.17

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Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910.1200(g) revised in 2012 and GHS Rev 03.

Issue date 09/08/2020

Reviewed on 09/08/2020

Trade Name: All Cemented Carbide Grade Inserts, Drills, & Solid Carbide Products· NTP (National Toxicology Program):
7440-48-4 Cobalt
7440-02-0 nickel

R
R· OSHA-Ca (Occupational Safety & Health Administration):
None of the ingredients are listed.

12 Ecological Information· Toxicity:· Aquatic toxicity:
7440-02-0 nickel
EC50 1 mg/l (Water flea)
7440-47-3 Chromium
EC50 0.07 mg/l (Water flea)· Persistence and degradability: No further relevant information available.
· Behavior in environmental systems:· Bioaccumulative potential: No further relevant information available.
· Mobility in soil: No further relevant information available.
· Additional ecological information:· General notes:
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
· Results of PBT and vPvB assessment:· PBT: Not applicable.
· vPvB: Not applicable.
· Other adverse effects: No further relevant information available.

13 Disposal Considerations· Waste treatment methods· Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Observe all federal, state and local environmental regulations when disposing of this material.
· Uncleaned packaging· Recommendation: Disposal must be made according to official regulations.

14 Transport Information· UN-Number:· DOT, ADR/ADN, ADN, IMDG, IATA
· UN proper shipping name:· DOT, ADR/ADN, ADN, IMDG, IATA
· Transport hazard class(es):Non-Regulated Material
Non-Regulated Material· DOT, ADR/ADN, ADN, IMDG, IATA
· Class:
Non-Regulated Material· Packing group:· DOT, ADR/ADN, IMDG, IATA
Non-Regulated Material· Environmental hazards:
Not applicable.
· Special precautions for user:
Not applicable.
· Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code:Not applicable.
(Contd. on page 12)51.1.17

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Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910.1200(g) revised in 2012 and GHS Rev 03.

Issue date 09/08/2020

Reviewed on 09/08/2020

Trade Name: All Cemented Carbide Grade Inserts, Drills, & Solid Carbide Products· UN "Model Regulation":

Non-Regulated Material

15 Regulatory Information· Safety, health and environmental regulations/legislation specific for the substance or mixture:· SARA (Superfund Amendments and Reauthorization):· Section 355 (extremely hazardous substances):
None of the ingredients are listed.
· Section 313 (Specific toxic chemical listings):
7440-48-4 Cobalt
7440-02-0 nickel
7440-47-3 Chromium
1344-28-1 Aluminium Oxide· TSCA (Toxic Substances Control Act):
12070-12-1 Tungsten Carbide
7782-40-3 Diamond
10043-11-5 Boron Nitride
12070-06-3 Tantalum Carbide
7440-48-4 Cobalt
7440-02-0 nickel
12069-89-5 Molybdenum Carbide
12070-08-5 Titanium Carbide
12011-99-3 Niobium Carbide
12012-35-0 Chromium Carbide
7440-47-3 Chromium
1303-86-2 diboron trioxide
1309-37-1 Ferric oxide7439-98-7 Molybdenum
7440-67-7 Zirconium
7440-58-6 hafnium
1344-28-1 Aluminium Oxide
25583-20-4 Titanium nitride

ACTIVE
ACTIVE
ACTIVE
ACTIVE
ACTIVE
ACTIVE
ACTIVE
ACTIVE
ACTIVE
ACTIVE
ACTIVE
ACTIVE
ACTIVE
ACTIVE
ACTIVE
ACTIVE
ACTIVE
ACTIVE· Hazardous Air Pollutants
7440-48-4 Cobalt· California Proposition 65:
WARNING: This product can expose you to chemicals including the listed chemicals which are
known to the State of California to cause cancer, birth defects and/or other reproductive harm. For
more information, go to www.P65Warnings.ca.gov.
· Chemicals known to cause cancer:
7440-48-4 Cobalt
7440-02-0 nickel· Chemicals known to cause reproductive toxicity for females:
None of the ingredients are listed.
(Contd. on page 13)

51.1.17

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Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910.1200(g) revised in 2012 and GHS Rev 03.

Issue date 09/08/2020

Reviewed on 09/08/2020

Trade Name: All Cemented Carbide Grade Inserts, Drills, & Solid Carbide Products· Chemicals known to cause reproductive toxicity for males:
None of the ingredients are listed.
· Chemicals known to cause developmental toxicity:
None of the ingredients are listed.
· New Jersey Right-to-Know List:
12070-12-1 Tungsten Carbide
7440-48-4 Cobalt
7440-02-0 nickel
7440-47-3 Chromium
1303-86-2 diboron trioxide
1309-37-1 Ferric oxide7439-98-7 Molybdenum
7440-67-7 Zirconium
7440-58-6 hafnium
1344-28-1 Aluminium Oxide· New Jersey Special Hazardous Substance List:
7440-48-4 Cobalt
7440-02-0 nickel
7440-47-3 Chromium
7440-67-7 Zirconium
7440-58-6 hafnium

CA, F3CAF3
F4, R1F3, R3· Pennsylvania Right-to-Know List:
7440-48-4 Cobalt
7440-02-0 nickel
7440-47-3 Chromium
1303-86-2 diboron trioxide
1309-37-1 Ferric oxide7439-98-7 Molybdenum
7440-67-7 Zirconium
7440-58-6 hafnium
1344-28-1 Aluminium Oxide· Pennsylvania Special Hazardous Substance List:
7440-48-4 Cobalt
7440-02-0 nickel
7440-47-3 Chromium
1344-28-1 Aluminium Oxide· Carcinogenic categories:· EPA (Environmental Protection Agency):
10043-11-5 Boron Nitride
7440-47-3 Chromium
1303-86-2 diboron trioxide

E
ES
ES
E

I (oral)D
I (oral)(Contd. on page 14)

51.1.17

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Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910.1200(g) revised in 2012 and GHS Rev 03.

Issue date 09/08/2020

Reviewed on 09/08/2020

Trade Name: All Cemented Carbide Grade Inserts, Drills, & Solid Carbide Products· TLV (Threshold Limit Value established by ACGIH):
7440-48-4 Cobalt
7440-02-0 nickel
7440-47-3 Chromium
1309-37-1 Ferric oxide7439-98-7 Molybdenum
7440-67-7 Zirconium
1344-28-1 Aluminium Oxide

A3
A5
A4
A4
A3
A4
A4

· NIOSH-Ca (National Institute for Occupational Safety and Health):
7440-02-0 nickel· GHS label elements
The product is classified and labeled according to the Globally Harmonized System (GHS).
· Hazard pictograms:· Signal word: Danger· Hazard-determining components of labeling:
Tungsten Carbide
CobaltDiamondnickel· Hazard statements:
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H317 May cause an allergic skin reaction.
H350 May cause cancer. Route of exposure: Inhalation.
H360 May damage fertility or the unborn child.
H335 May cause respiratory irritation.
H372 Causes damage to the respiratory system through prolonged or repeated exposure. Route of exposure:
Inhalation.
· Precautionary statements:
P201
Obtain special instructions before use.
P202
Do not handle until all safety precautions have been read and understood.
P260
Do not breathe dust/fume/gas/mist/vapors/spray.
P261
Avoid breathing dust/fume/gas/mist/vapors/spray.
P264
Wash thoroughly after handling.
P270
Do not eat, drink or smoke when using this product.
P271
Use only outdoors or in a well-ventilated area.
P272
Contaminated work clothing must not be allowed out of the workplace.
P280
Wear protective gloves/protective clothing/eye protection/face protection.
P284[In case of inadequate ventilation] wear respiratory protection.
P302+P352
If on skin: Wash with plenty of water.
P304+P340
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P304+P341
If inhaled: If breathing is difficult, remove person to fresh air and keep comfortable forbreathing.
P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
(Contd. on page 15)

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Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910.1200(g) revised in 2012 and GHS Rev 03.

Issue date 09/08/2020

Reviewed on 09/08/2020

Trade Name: All Cemented Carbide Grade Inserts, Drills, & Solid Carbide Products
P308+P313
P312
P321
P314
P362+P364
P332+P313
P333+P313
P337+P313
P342+P311
P363
P403+P233
P405
P501

IF exposed or concerned: Get medical advice/attention.
Call a poison center/doctor if you feel unwell.
Specific treatment (see supplementary first aid instructions on this Safety Data Sheet).
Get medical advice/attention if you feel unwell.
Take off contaminated clothing and wash it before reuse.
If skin irritation occurs: Get medical advice/attention.
If skin irritation or rash occurs: Get medical advice/attention.
If eye irritation persists: Get medical advice/attention.
If experiencing respiratory symptoms: Call a poison center/doctor.
Wash contaminated clothing before reuse.
Store in a well-ventilated place. Keep container tightly closed.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international
regulations.
· National regulations:None of the ingredients are listed.
· Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

16 Other Information
The information and recommendations in this safety data sheet are, to the best of our knowledge, accurate asof the date of issue. Nothing herein shall be deemed to create warranty, expressed or implied, and shall notestablish a legally valid contractual relationship. It is the responsibility of the user to determine applicability ofthis information and the suitability of the material or product for any particular purpose.
· Date of last revision/ revision number: 09/08/2020 / 6· Abbreviations and acronyms:
ADR: The European Agreement concerning the International Carriage of Dangerous Goods by Road
ADN: The European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety and Health
OSHA: Occupational Safety & Health Administration
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
BEI: Biological Exposure Limit
Pyr. Sol. 1: Pyrophoric solids – Category 1
Water-react. 1: Substances and mixtures which in contact with water emit flammable gases – Category 1
Skin Irrit. 2: Skin corrosion/irritation – Category 2
Eye Irrit. 2A: Serious eye damage/eye irritation – Category 2A
Eye Irrit. 2B: Serious eye damage/eye irritation – Category 2B
Resp. Sens. 1: Respiratory sensitisation – Category 1
Skin Sens. 1: Skin sensitisation – Category 1
Muta. 2: Germ cell mutagenicity – Category 2
Carc. 1B: Carcinogenicity – Category 1B
Carc. 2: Carcinogenicity – Category 2
Repr. 1: Reproductive toxicity – Category 1
Repr. 1B: Reproductive toxicity – Category 1B(Contd. on page 16)

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Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910.1200(g) revised in 2012 and GHS Rev 03.

Issue date 09/08/2020

Reviewed on 09/08/2020

Trade Name: All Cemented Carbide Grade Inserts, Drills, & Solid Carbide Products
STOT SE 3: Specific target organ toxicity (single exposure) – Category 3
STOT RE 1: Specific target organ toxicity (repeated exposure) – Category 1
Aquatic Acute 3: Hazardous to the aquatic environment - acute aquatic hazard – Category 3
Aquatic Chronic 4: Hazardous to the aquatic environment - long-term aquatic hazard – Category 4· * Data compared to the previous version altered.
SDS created by MSDS Authoring Services www.msdsauthoring.com+1-877-204-9106