FE-1025/EN rev B

Safety Data Sheetaccording to Regulation (EC) No. 1907/2006 (REACH)
bbb

AIRFLOW ERYTHRITOLTOOTHPASTE
Version number: 3.0
Replaces version of: 2020-10-20 (2)Revision: 2022-01-31
First version: 2019-02-26

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1

1.2

Product identifier
Trade name

AIRFLOW ERYTHRITOL TOOTHPASTE

Registration number (REACH)

Not relevant (mixture)

CAS number

not relevant (mixture)

Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses

1.3

Cleansing of teeth

Details of the supplier of the safety data sheet
Dr. Wittmann GmbH & Co. KG
Rieslingstraße 864673 Zwingenberg
Germany

Telephone: ++49 (0) 6251 – 770769- 0
Telefax: ++49 (0) 6251 – 770769- 99

e-mail (competent person)

sdb@csb-compliance.com

Please do not use this e-mail address to ask for the latest safety data sheet. For this purpose contact
Dr. Wittmann GmbH & Co. KG.
National contact

1.4

Verkauf

Emergency telephone number
As above or nearest toxicological information centre.

SECTION 2: Hazards identification

2.1

Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008 (CLP)This mixture does not meet the criteria for classification in accordance with Regulation No 1272/2008/
EC.

2.2

Label elements
Labelling according to Regulation (EC) No 1272/2008 (CLP)
Signal word

Not required.

Pictograms

Not required.

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AIRFLOW ERYTHRITOLTOOTHPASTE
Supplemental hazard information

2.3

EUH208

Contains L-menthan-3-one. May produce an allergic reaction.

EUH210

Safety data sheet available on request.

Other hazards
Special danger of slipping by leaking/spilling product.
Results of PBT and vPvB assessment
This mixture does not contain any substances that are assessed to be a PBT or a vPvB.

SECTION 3: Composition/information on ingredients

3.1

Substances
Not relevant (mixture).

3.2

Mixtures
Description of the mixture
Hazardous ingredients
Name of substance

Identifier

Wt%

Classification acc. to GHS

Sulfonic acids, C14-16(even numbered)-alkanehydroxy and C14-16(even numbered)-alkene, sodium salts

CAS No68439-57-6

1–3

Skin Irrit. 2 / H315
Eye Irrit. 2 / H319

≤ 0.3

Acute Tox. 3 / H301
Skin Irrit. 2 / H315
Eye Irrit. 2 / H319

≤ 0.1995

Skin Irrit. 2 / H315
Skin Sens. 1B / H317

Pictograms

EC No
931-534-0
REACH Reg. No
01-2119513401-57xxxx

sodium fluoride

CAS No7681-49-4
EC No
231-667-8
Index No009-004-00-7
REACH Reg. No
01-2119539420-47XXXX

L-menthan-3-one

CAS No14073-97-3
EC No
237-926-1

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AIRFLOW ERYTHRITOLTOOTHPASTE
Hazardous ingredients
Name of substance

Identifier

Wt%

Classification acc. to GHS

pin-2(10)-ene

CAS No127-91-3≤ 0.0125

Flam. Liq. 3 / H226
Asp. Tox. 1 / H304
Aquatic Chronic 2 / H411

≤ 0.0012

Flam. Liq. 3 / H226
Skin Irrit. 2 / H315
Skin Sens. 1 / H317
Asp. Tox. 1 / H304
Aquatic Acute 1 / H400
Aquatic Chronic 1 / H410

Pictograms

EC No
204-872-5
pin-2(10)-ene

CAS No127-91-3
EC No
242-060-2

Name of substanceSpecific Conc. Limits

M-Factors

ATE

Exposure route

Sulfonic acids, C14-16(even numbered)-alkanehydroxy and C14-16(even numbered)-alkene, sodium salts

Skin Irrit. 2; H315: C ≥ 5 %

-

-

-

sodium fluoride--

148.5 mg/kg

oral

for full text of H-phrases: see SECTION 16

SECTION 4: First aid measures

4.1

Description of first aid measures
General notes
In all cases of doubt, or when symptoms persist, seek medical advice.
Following inhalation
Provide fresh air.
Following skin contact
Wash with plenty of water.
Following eye contact
Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
Following ingestion
Rinse mouth. Do not induce vomiting.
Get medical advice/attention if you feel unwell.
Notes for the doctor
None.

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AIRFLOW ERYTHRITOLTOOTHPASTE
4.2

Most important symptoms and effects, both acute and delayed
These information are not available.

4.3

Indication of any immediate medical attention and special treatment needed
None.

SECTION 5: Firefighting measures

5.1

Extinguishing media
Suitable extinguishing media
water spray, alcohol resistant foam, fire extinguishing powder, carbon dioxide (CO2)
Unsuitable extinguishing media
water jet

5.2

Special hazards arising from the substance or mixture
Hazardous decomposition products: Section 10.
Hazardous combustion products
carbon monoxide (CO), carbon dioxide (CO2), gas/ vapor, toxic

5.3

Advice for firefighters
Keep containers cool with water spray.
In case of fire and/or explosion do not breathe fumes.
Co-ordinate firefighting measures to the fire surroundings.
Do not allow firefighting water to enter drains or water courses.
Collect contaminated firefighting water separately.
Fight fire with normal precautions from a reasonable distance.
Special protective equipment for firefighters
use suitable breathing apparatus

SECTION 6: Accidental release measures

6.1

Personal precautions, protective equipment and emergency procedures
For non-emergency personnel
Ventilate affected area.
Wearing of suitable protective equipment (including personal protective equipment referred to under
Section 8 of the safety data sheet) to prevent any contamination of skin, eyes and personal clothing.
For emergency responders
Wear breathing apparatus if exposed to vapours/dust/spray/gases.

6.2

Environmental precautions
Keep away from drains, surface and ground water.
Retain contaminated washing water and dispose of it.
If substance has entered a water course or sewer, inform the responsible authority.

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AIRFLOW ERYTHRITOLTOOTHPASTE
6.3

Methods and material for containment and cleaning up
Advice on how to clean up a spill
Collect spillage.
Absorbent material (e.g. sand, diatomaceous earth, acid binder, universal binder, sawdust, etc.).
Appropriate containment techniques
Use of adsorbent materials.
Other information relating to spills and releases
Place in appropriate containers for disposal.
Ventilate affected area.

6.4

Reference to other sections
Hazardous combustion products: see section 5.
Personal protective equipment: see section 8.
Incompatible materials: see section 10.
Disposal considerations: see section 13.

SECTION 7: Handling and storage

7.1

Precautions for safe handling
Avoid contact with eyes.
Measures to prevent fire as well as aerosol and dust generation
Use local and general ventilation.
Keep away from sources of ignition - No smoking.
Specific notes/details
None.
Measures to protect the environment
Avoid release to the environment.
Advice on general occupational hygiene
Do not eat, drink and smoke in work areas.
Wash hands after use.
Preventive skin protection (barrier creams/ointments) is recommended.
Remove contaminated clothing and protective equipment before entering eating areas.

7.2

Conditions for safe storage, including any incompatibilities
Flammability hazards
None.
Incompatible substances or mixtures
Incompatible materials: see section 10.
Protect against external exposure, such asheat, frost

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AIRFLOW ERYTHRITOLTOOTHPASTE
Consideration of other advice
Keep away from food, drink and animal feeding stuffs.
Ventilation requirements
Provision of sufficient ventilation.
Packaging compatibilities
Keep only in original container.

7.3

Specific end use(s)No information available.

SECTION 8: Exposure controls/personal protection

8.1

Control parameters
Occupational exposure limit values (Workplace Exposure Limits)
Country

Name of agent

CAS NoIdentifier

TWA
[ppm]

TWA
[mg/m³]

STEL
[ppm]

STEL
[mg/m³]

Notation

SourceEU

fluorine, inorganic compounds

-

IOELV

-

2.5

-

-

-

2000/39/EC

GB

fluorides, inorganic

-

WEL

-

2.5

-

-

F

EH40/2005

GB

cycloalkanes(>C7)

127-91-3

WEL

-

800

-

-

-

EH40/2005

GB

glycerol

56-81-5

WEL

-

10

-

-

mist

EH40/2005

GB

propane-1,2-diol

57-55-6

WEL

-

10

-

-

particle

EH40/2005

GB

propane-1,2-diol

57-55-6

WEL

150

474

-

-

vp

EH40/2005

GB

silica, amorphous

7631-869

WEL

-

6

-

-

i

EH40/2005

GB

silica, amorphous

7631-869

WEL

-

2.4

-

-

r

EH40/2005

NotationF

calculated as F (fluorine)iinhalable fraction

mist

as mists

particle

as airborne particlesr

respirable fraction

STEL

short-term exposure limit: a limit value above which exposure should not occur and which is related to a 15minute period (unless otherwise specified)

TWA

time-weighted average (long-term exposure limit): measured or calculated in relation to a reference period of
8 hours time-weighted average (unless otherwise specified)vp

as vapours and particulates

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AIRFLOW ERYTHRITOLTOOTHPASTE
Relevant DNELs of components of the mixture
Name of sub-CAS NostanceEnd-

ThresholProtection

point

d levelgoal, route of
exposure

Used in

Exposure time

Sulfonic acids, C1416 (evennumbered)-alkanehydroxy and C1416 (evennumbered)-alkene,
sodium salts

68439-57-6

DNEL

152.2 mg/m³

human, inhalatory

worker (industry)

chronic - systemic effects

Sulfonic acids, C1416 (evennumbered)-alkanehydroxy and C1416 (even68439-57-6

DNEL

2,158 mg/
kg bw/dayhuman, dermal

worker (industry)

chronic - systemic effects

sodium fluoride

7681-49-4

DNEL

2.5 mg/m³

human, inhalatory

worker (industry)

chronic - local effects

sodium fluoride

7681-49-4

DNEL

0.36 mg/
kg bw/dayhuman, dermal

worker (industry)

chronic - systemic effects

L-menthan-3-one

14073-97-3

DNEL

26.1 mg/m³

human, inhalatory

worker (industry)

chronic - systemic effects

L-menthan-3-one

14073-97-3

DNEL

7.4 mg/kg
bw/dayhuman, dermal

worker (industry)

chronic - systemic effects

pin-2(10)-ene

127-91-3

DNEL

5.69 mg/m³

human, inhalatory

worker (industry)

chronic - systemic effects

pin-2(10)-ene

127-91-3

DNEL

0.8 mg/kg
bw/dayhuman, dermal

worker (industry)

chronic - systemic effects

pin-2(10)-ene

127-91-3

DNEL

54 µg/cm²

human, dermal

worker (industry)

chronic - local effects

pin-2(10)-ene

127-91-3

DNEL

5.69 mg/m³

human, inhalatory

worker (industry)

chronic - systemic effects

pin-2(10)-ene

127-91-3

DNEL

0.8 mg/kg
bw/dayhuman, dermal

worker (industry)

chronic - systemic effects

pin-2(10)-ene

127-91-3

DNEL

54 µg/cm²

human, dermal

worker (industry)

chronic - local effects

numbered)-alkene,
sodium salts

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AIRFLOW ERYTHRITOLTOOTHPASTE
Relevant PNECs of components of the mixture
Name of substance

CAS NoEndpointThreshold level

Environmental compartment

Sulfonic acids, C14-16 (evennumbered)-alkane hydroxy andC14-16 (even numbered)-alkene, sodium salts

68439-57-6

PNEC

0.024 mg/l

freshwater

Sulfonic acids, C14-16 (evennumbered)-alkane hydroxy andC14-16 (even numbered)-alkene, sodium salts

68439-57-6

PNEC

0.002 mg/l

marine water

Sulfonic acids, C14-16 (evennumbered)-alkane hydroxy andC14-16 (even numbered)-alkene, sodium salts

68439-57-6

PNEC

4 mg/lsewage treatment plant(STP)

Sulfonic acids, C14-16 (evennumbered)-alkane hydroxy andC14-16 (even numbered)-alkene, sodium salts

68439-57-6

PNEC

0.767 mg/kg

freshwater sediment

Sulfonic acids, C14-16 (evennumbered)-alkane hydroxy andC14-16 (even numbered)-alkene, sodium salts

68439-57-6

PNEC

0.077 mg/kg

marine sediment

Sulfonic acids, C14-16 (evennumbered)-alkane hydroxy andC14-16 (even numbered)-alkene, sodium salts

68439-57-6

PNEC

1.21 mg/kg

soil

sodium fluoride

7681-49-4

PNEC

0.9 mg/l

freshwater

sodium fluoride

7681-49-4

PNEC

51 mg/lsewage treatment plant(STP)

sodium fluoride

7681-49-4

PNEC

11 mg/kg

soil

L-menthan-3-one

14073-97-3

PNEC

0.031 mg/l

freshwater

L-menthan-3-one

14073-97-3

PNEC

0.003 mg/l

marine water

L-menthan-3-one

14073-97-3

PNEC

2 mg/lsewage treatment plant(STP)

L-menthan-3-one

14073-97-3

PNEC

0.558 mg/kg

freshwater sediment

L-menthan-3-one

14073-97-3

PNEC

0.056 mg/kg

marine sediment

L-menthan-3-one

14073-97-3

PNEC

0.093 mg/kg

soil

pin-2(10)-ene

127-91-3

PNEC

1.004 µg/l

freshwaterpin-2(10)-ene

127-91-3

PNEC

0.1 µg/l

marine water

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AIRFLOW ERYTHRITOLTOOTHPASTE
Relevant PNECs of components of the mixture
Name of substance

CAS NoEndpointThreshold level

Environmental compartment

pin-2(10)-ene

127-91-3

PNEC

3.26 mg/l

sewage treatment plant(STP)

pin-2(10)-ene

127-91-3

PNEC

0.337 mg/kg

freshwater sedimentpin-2(10)-ene

127-91-3

PNEC

0.034 mg/kg

marine sedimentpin-2(10)-ene

127-91-3

PNEC

0.067 mg/kg

soil

pin-2(10)-ene

127-91-3

PNEC

1.004 µg/l

freshwaterpin-2(10)-ene

127-91-3

PNEC

0.1 µg/l

marine waterpin-2(10)-ene

127-91-3

PNEC

3.26 mg/l

sewage treatment plant(STP)

pin-2(10)-ene

127-91-3

PNEC

0.337 mg/kg

freshwater sedimentpin-2(10)-ene

127-91-3

PNEC

0.034 mg/kg

marine sedimentpin-2(10)-ene

127-91-3

PNEC

0.067 mg/kg

soil

pin-2(10)-ene: PNEC Oral - Predators - Secondary poisoning - 13,1 mg/kg
pin-2(10)-ene: PNEC Oral - Predators - Secondary poisoning - 13,1 mg/kg

8.2

Exposure controls
Appropriate engineering controls
General ventilation.
Individual protection measures (personal protective equipment)
Eye/face protection
Wear eye/face protection.
Hand protection
Protective gloves
Material

Material thickness

Breakthrough times of the glove
material

no information available

no information available

no information available

Wear suitable gloves.
Chemical protection gloves are suitable, which are tested according to EN 374.
Check leak-tightness/impermeability prior to use.
In the case of wanting to use the gloves again, clean them before taking off and air them well.

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AIRFLOW ERYTHRITOLTOOTHPASTE
Respiratory protection
In case of inadequate ventilation wear respiratory protection.
Environmental exposure controls
Use appropriate container to avoid environmental contamination.
Keep away from drains, surface and ground water.

SECTION 9: Physical and chemical properties

9.1

Information on basic physical and chemical properties
Physical stateliquid(paste)Colournot determined

Odourcharacteristic

Melting point/freezing point

not determined

Boiling point or initial boiling point and boilingrange

not determined

Flammability

this material is combustible, but will not ignite
readily

Lower and upper explosion limit

not determinedFlash point

not determined

Auto-ignition temperature

not determined

Decomposition temperature

not relevant

pH (value)

not determined

Kinematic viscosity

not determined

Dynamic viscosity

not determined

Solubility(ies)
Water solubility

miscible in any proportion

Partition coefficient n-octanol/water (log value) not determined
Vapour pressure

not determined

Density and/or relative density
Density

1.2 g/cm³ at 20 °C

Relative vapour density

information on this property is not available

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AIRFLOW ERYTHRITOLTOOTHPASTE

Particle characteristics

not relevant(liquid)9.2

Other information
Information with regard to physical hazard
classeshazard classes acc. to GHS (physical hazards):
not relevant

Other safety characteristics

there is no additional information

SECTION 10: Stability and reactivity

10.1

Reactivity
This material is not reactive under normal ambient conditions.

10.2

Chemical stability
The material is stable under normal ambient and anticipated storage and handling conditions of temperature and pressure.
See below "Conditions to avoid".

10.3

Possibility of hazardous reactions
This information is not available.

10.4

Conditions to avoid
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

10.5

Incompatible materials
There is no additional information.

10.6

Hazardous decomposition products
Reasonably anticipated hazardous decomposition products produced as a result of use, storage, spill
and heating are not known.
Hazardous combustion products: see section 5.

SECTION 11: Toxicological information

11.1

Information on hazard classes as defined in Regulation (EC) No 1272/2008
Classification procedure
If not otherwise specified the classification is based on:
Ingredients of the mixture (additivity formula).

Classification according to GHS (1272/2008/EC, CLP)
This mixture does not meet the criteria for classification in accordance with Regulation No 1272/2008/
EC.
Acute toxicity
Test data are not available for the complete mixture.
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AIRFLOW ERYTHRITOLTOOTHPASTE
Acute toxicity of components of the mixture
Name of substance

CAS NoExpos-

End-

ure
route

point

Value

Species

MethodSourceSulfonic acids, C14-16(even numbered)-alkanehydroxy and C14-16(even numbered)-alkene,
sodium salts

68439-57-6

oral

LD50

2,079
mg
/kg

rat

OECD
Guideline
401

ECHA

Sulfonic acids, C14-16(even numbered)-alkanehydroxy and C14-16(even numbered)-alkene,
sodium salts

68439-57-6

inhalation:
dust/
mist

LC50

>52 mg/l/
4h

rat

OECD
Guideline
403

ECHA

Sulfonic acids, C14-16(even numbered)-alkanehydroxy and C14-16(even numbered)-alkene,
sodium salts

68439-57-6

dermal

LD50

6,300
mg
/kg

rabbitOECD
Guideline
402

ECHA

sodium fluoride

7681-49-4

oral

LD50

148.5
mg/
kg

rat, female

EPA OPPTS
870.1100ECHA

sodium fluoride

7681-49-4

oral

LD50

223 mg/rat, maleEPA OPPTS
870.1100

ECHA

rat

EPA OPPTS
870.1200

ECHAkg

sodium fluoride

7681-49-4

dermalLD50>2,000mg/kg

Skin corrosion/irritation
Classification could not be established because:
Data are lacking, inconclusive, or conclusive but not sufficient for classification.
Serious eye damage/eye irritation
Classification could not be established because:
Data are lacking, inconclusive, or conclusive but not sufficient for classification.
Respiratory or skin sensitisation
Contains L-menthan-3-one. May produce an allergic reaction.
Germ cell mutagenicity
Classification could not be established because:
Data are lacking, inconclusive, or conclusive but not sufficient for classification.
Carcinogenicity
Classification could not be established because:
Data are lacking, inconclusive, or conclusive but not sufficient for classification.

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AIRFLOW ERYTHRITOLTOOTHPASTE
Reproductive toxicity
Classification could not be established because:
Data are lacking, inconclusive, or conclusive but not sufficient for classification.
Specific target organ toxicity - single exposure
Classification could not be established because:
Data are lacking, inconclusive, or conclusive but not sufficient for classification.
Specific target organ toxicity - repeated exposure
Classification could not be established because:
Data are lacking, inconclusive, or conclusive but not sufficient for classification.
Aspiration hazard
Shall not be classified as presenting an aspiration hazard.

11.2

Information on other hazards
There is no additional information.
Endocrine disrupting properties
None of the ingredients are listed.

SECTION 12: Ecological information

12.1

Toxicity
Aquatic toxicity (acute)
Test data are not available for the complete mixture.
Aquatic toxicity (acute) of components of the mixture
Name of substance

CAS NoEndpoint

Exposure
time

Value

Species

MethodSourceSulfonic acids,
C14-16 (evennumbered)-alkane hydroxy
and C14-16(even
numbered)-alkene, sodium
salts

68439-57-6

LC50

96 h

4.2 mg/l

zebra fish
(Danio rerio)

OECD
Guideline
203

ECHA

Sulfonic acids,
C14-16 (evennumbered)-alkane hydroxy
and C14-16(even
numbered)-alkene, sodium
salts

68439-57-6

EC50

48 h

4.53 mg/l

daphnia magna

OECD
Guideline
202

ECHA

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AIRFLOW ERYTHRITOLTOOTHPASTE
Name of substance

CAS NoEndpoint

Exposure
time

Value

Species

MethodSourceSulfonic acids,
C14-16 (evennumbered)-alkane hydroxy
and C14-16(even
numbered)-alkene, sodium
salts

68439-57-6

ErC50

72 h

5.2 mg/l

algae (Skeletonema costatum)

DIN EN ISO
10253

ECHA

sodium fluoride

7681-49-4

EC50

96 h

26 – 48 mg/l

trichoptera
aquatic larvae

US Environmental Protection
Agency,440/5-86001

ECHA

sodium fluoride

7681-49-4

EbC50

48 h

43 mg/l

algae

-

ECHA

L-menthan-3one

14073-97-3

LC50

96 h

>28 mg/l

zebra fish
(Danio rerio)OECD 203

ECHA

L-menthan-3one

14073-97-3

EC50

48 h

30.6 mg/l

daphnia magna

EU Method
C.2

ECHA

L-menthan-3one

14073-97-3

ErC50

72 h

58 mg/lalgae(pseudokirchneriella subcapitata)

OECD 201

ECHA

Aquatic toxicity (chronic)
Test data are not available for the complete mixture.
Aquatic toxicity (chronic) of components of the mixture
Name of substance

CAS NoEndpoint

Exposure
time

Value

Species

MethodSourceSulfonic acids,
C14-16 (evennumbered)-alkane hydroxy
and C14-16(even
numbered)-alkene, sodium
salts

68439-57-6

NOEC

72 h

3.2 mg/l

algae (Skeletonema costatum)

DIN EN ISO
10253

ECHA

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AIRFLOW ERYTHRITOLTOOTHPASTE
Name of substance

CAS NoEndpoint

Exposure
time

Value

Species

MethodSourceSulfonic acids,
C14-16 (evennumbered)-alkane hydroxy
and C14-16(even
numbered)-alkene, sodium
salts

68439-57-6

NOEC

21 d

6.3 mg/l

daphnia magna

OECD
Guideline
211

ECHA

Sulfonic acids,
C14-16 (evennumbered)-alkane hydroxy
and C14-16(even
numbered)-alkene, sodium
salts

68439-57-6

growth rate
(ErCx) 3.9%

72 h

-

algae (Skeletonema costatum)

DIN EN ISO
10253

ECHA

sodium fluoride

7681-49-4

NOEC

21 d

3.7 mg/l

daphnia magna

-

ECHA

sodium fluoride

7681-49-4

NOEC

21 d

4 mg/lrainbow trout(Oncorhynchus
mykiss)-ECHA

sodium fluoride

7681-49-4

NOEC

7d

50 mg/l

algae

-

ECHA

pin-2(10)-ene

127-91-3EC503h

326 mg/l

activatedsludge of a predominantly domestic sewage

OECD
Guideline
209

ECHA

pin-2(10)-ene

127-91-3

growth (EbCx) 10%3h

38 mg/lactivatedsludge of a predominantly domestic sewage

OECD
Guideline
209

ECHA

pin-2(10)-ene

127-91-3

growth (EbCx) 20%

3h79 mg/lactivatedsludge of a predominantly domestic sewage

OECD
Guideline
209

ECHA

pin-2(10)-ene

127-91-3

growth (EbCx) 80%

3h1,337 mg/l

activatedsludge of a predominantly domestic sewage

OECD
Guideline
209

ECHA

pin-2(10)-ene

127-91-3EC503h

326 mg/l

activatedsludge of a predominantly domestic sewage

OECD
Guideline
209

ECHA

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AIRFLOW ERYTHRITOLTOOTHPASTE

12.2

Name of substance

CAS NoEndpoint

Exposure
time

Value

Species

MethodSourcepin-2(10)-ene

127-91-3

growth (EbCx) 10%3h

38 mg/lactivatedsludge of a predominantly domestic sewage

OECD
Guideline
209

ECHA

pin-2(10)-ene

127-91-3

growth (EbCx) 20%

3h79 mg/lactivatedsludge of a predominantly domestic sewage

OECD
Guideline
209

ECHA

pin-2(10)-ene

127-91-3

growth (EbCx) 80%

3h1,337 mg/l

activatedsludge of a predominantly domestic sewage

OECD
Guideline
209

ECHA

Persistence and degradability
Degradability of components of the mixture
Name ofsubstance

CAS NoProcess

Degradation
rate

Time

MethodSourceSulfonic acids,
C14-16 (evennumbered)-alkane hydroxy
and C14-16(even
numbered)-alkene, sodium
salts

68439-57-6

carbon dioxide generation

80 %

28 d

OECD 301B

ECHA

Sulfonic acids,
C14-16 (evennumbered)-alkane hydroxy
and C14-16(even
numbered)-alkene, sodium
salts

68439-57-6

DOC removal

96 %

28 d

-

ECHA

pin-2(10)-ene

127-91-3

oxygen depletion

76 %

28 d

OECD
Guideline 301
DECHA

pin-2(10)-ene

127-91-3

oxygen depletion

76 %

28 d

OECD
Guideline 301

ECHA

D

Biodegradation
Test data are not available for the complete mixture.
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Persistence
No data available.

12.3

Bioaccumulative potential
Test data are not available for the complete mixture.
Bioaccumulative potential of components of the mixture

12.4

Name of substance

CAS NoLog KOW

Sulfonic acids, C14-16 (evennumbered)-alkane hydroxy and C1416 (even numbered)-alkene, sodium
salts

68439-57-6-1.3 (pH value: 5.43, 20 °C)

L-menthan-3-one

14073-97-3

3.05 (25 °C)

pin-2(10)-ene

127-91-3

4.425 (25 °C)

pin-2(10)-ene

127-91-3

4.425 (25 °C)

Mobility in soil
No data available.

12.5

Results of PBT and vPvB assessment
This mixture does not contain any substances that are assessed to be a PBT or a vPvB.

12.6

Endocrine disrupting properties
None of the ingredients are listed.

12.7

Other adverse effects
Data are not available.

Remarks
Wassergefährdungsklasse, WGK (water hazard class): 2

SECTION 13: Disposal considerations

13.1

Waste treatment methods
This material and its container must be disposed of as hazardous waste.
Directive 2008/98/EC on wastes.
Waste code (EU): 18 01 06 Chemicals consisting of or containing hazardous substances.
Sewage disposal-relevant information
Do not empty into drains.
Waste treatment of containers/packagings
Completely emptied packages can be recycled.
Handle contaminated packages in the same way as the substance itself.
Packaging containing residues of or contaminated by hazardous substances.
Waste code (EU): 15 01 02 Plastic packaging.

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Remarks
Please consider the relevant national or regional provisions.

SECTION 14: Transport information

14.1

UN number or ID number

not assigned

14.2

UN proper shipping name

-

14.3

Transport hazard class(es)

-

14.4

Packing group

-

14.5

Environmental hazards

-

14.6

Special precautions for user

-

14.7

Maritime transport in bulk according to IMO instruments

SECTION 15: Regulatory information

15.1

Safety, health and environmental regulations/legislation specific for the substance or
mixtureRelevant provisions of the European Union (EU)
Restrictions according to REACH, Annex XVIINameName acc. to inventory

CAS NoRestriction

pin-2(10)-ene

this product meets the criteria for classification in accordance with Regulation
No 1272/2008/EC-

R3

pin-2(10)-ene

flammable / pyrophoric-

R40

L-menthan-3-one

this product meets the criteria for classification in accordance with Regulation
No 1272/2008/EC-

R3

pin-2(10)-ene

this product meets the criteria for classification in accordance with Regulation
No 1272/2008/EC-

R3

pin-2(10)-ene

flammable / pyrophoric-

R40

LegendR3

1. Shall not be used in:- ornamental articles intended to produce light or colour effects by means of different phases, for example in ornamental lamps and ashtrays,- tricks and jokes,- games for one or more participants, or any article intended to be used as such, even with ornamental aspects,
2. Articles not complying with paragraph 1 shall not be placed on the market.
3. Shall not be placed on the market if they contain a colouring agent, unless required for fiscal reasons, or perfume, or both, if they:

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Legend- can be used as fuel in decorative oil lamps for supply to the general public, and,- present an aspiration hazard and are labelled with R65 or H304,
4. Decorative oil lamps for supply to the general public shall not be placed on the market unless they conform to
the European Standard on Decorative oil lamps (EN 14059) adopted by the European Committee for Standardisation (CEN).
5. Without prejudice to the implementation of other Community provisions relating to the classification, packaging and labelling of dangerous substances and mixtures, suppliers shall ensure, before the placing on themarket, that the following requirements are met:(a) lamp oils, labelled with R65 or H304, intended for supply to the general public are visibly, legibly and indelibly marked as follows: ‘Keep lamps filled with this liquid out of the reach of children’; and, by 1 December
2010, ‘Just a sip of lamp oil - or even sucking the wick of lamps - may lead to life-threatening lung damage’;(b) grill lighter fluids, labelled with R65 or H304, intended for supply to the general public are legibly and indelibly marked by 1 December 2010 as follows: ‘Just a sip of grill lighter may lead to life threatening lungdamage’;(c) lamp oils and grill lighters, labelled with R65 or H304, intended for supply to the general public are packaged
in black opaque containers not exceeding 1 litre by 1 December 2010.
6. No later than 1 June 2014, the Commission shall request the European Chemicals Agency to prepare a dossier,in accordance with Article 69 of the present Regulation with a view to ban, if appropriate, grill lighter fluids andfuel for decorative lamps, labelled R65 or H304, intended for supply to the general public.
7. Natural or legal persons placing on the market for the first time lamp oils and grill lighter fluids, labelled with
R65 or H304, shall by 1 December 2011, and annually thereafter, provide data on alternatives to lamp oils andgrill lighter fluids labelled R65 or H304 to the competent authority in the Member State concerned. Member
States shall make those data available to the Commission.
R40

1. Shall not be used, as substance or as mixtures in aerosol dispensers where these aerosol dispensers are intended for supply to the general public for entertainment and decorative purposes such as the following:- metallic glitter intended mainly for decoration,- artificial snow and frost,- ‘whoopee’ cushions,- silly string aerosols,- imitation excrement,- horns for parties,- decorative flakes and foams,- artificial cobwebs,- stink bombs.
2. Without prejudice to the application of other Community provisions on the classification, packaging and labelling of substances, suppliers shall ensure before the placing on the market that the packaging of aerosol dispensers referred to above is marked visibly, legibly and indelibly with:‘For professional users only’.
3. By way of derogation, paragraphs 1 and 2 shall not apply to the aerosol dispensers referred to Article 8 (1a) of
Council Directive 75/324/EEC (2).
4. The aerosol dispensers referred to in paragraphs 1 and 2 shall not be placed on the market unless they conform to the requirements indicated.

List of substances subject to authorisation (REACH, Annex XIV) / SVHC - candidate list
None of the ingredients are listed.

Seveso Directive
Not assigned.

Directive on the restriction of the use of certain hazardous substances in electrical andelectronic equipment (RoHS)
None of the ingredients are listed.

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Regulation on the marketing and use of explosives precursors
None of the ingredients are listed.

Regulation on substances that deplete the ozone layer (ODS)
None of the ingredients are listed.

Regulation concerning the export and import of hazardous chemicals (PIC)
None of the ingredients are listed.

Regulation on persistent organic pollutants (POP)None of the ingredients are listed.

15.2

Chemical Safety Assessment
No Chemical Safety Assessment has been carried out for this mixture by the supplier.

SECTION 16: Other information

Indication of changes (revised safety data sheet)
Indication of changes: Section 1, 3, 8, 13Abbreviations and acronyms
Abbr.

Descriptions of used abbreviations

2000/39/EC

Commission Directive establishing a first list of indicative occupational exposure limit values in implementation of Council Directive 98/24/EC

Acute Tox.

Acute toxicity

ADN

Accord européen relatif au transport international des marchandises dangereuses par voies de navigation intérieures (European Agreement concerning the International Carriage of Dangerous Goods
by Inland Waterways)

ADR

Accord relatif au transport international des marchandises dangereuses par route (Agreement concerning the International Carriage of Dangerous Goods by Road)

Aquatic Acute

Hazardous to the aquatic environment - acute hazard

Aquatic Chronic

Hazardous to the aquatic environment - chronic hazard

Asp. Tox.

Aspiration hazard

ATE

Acute Toxicity Estimate

CAS

Chemical Abstracts Service (service that maintains the most comprehensive list of chemical substances)

CLP

Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures

DGR

Dangerous Goods Regulations (see IATA/DGR)

DNELDerived No-Effect Level

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Abbr.

Descriptions of used abbreviations

EbC50≡ EC50: in this method, that concentration of test substance which results in a 50 % reduction ineither growth (EbC50) or growth rate (ErC50) relative to the control

EC50

Effective Concentration 50 %. The EC50 corresponds to the concentration of a tested substance causing 50 % changes in response (e.g. on growth) during a specified time interval

EC No

The EC Inventory (EINECS, ELINCS and the NLP-list) is the source for the seven-digit EC number, an
identifier of substances commercially available within the EU (European Union)

EH40/2005

EH40/2005 Workplace exposure limits (http://www.nationalarchives.gov.uk/doc/open-government-licence/)

EINECS

European Inventory of Existing Commercial Chemical Substances

ELINCS

European List of Notified Chemical Substances

ErC50≡ EC50: in this method, that concentration of test substance which results in a 50 % reduction ineither growth (EbC50) or growth rate (ErC50) relative to the control

Eye Dam.

Seriously damaging to the eye

Eye Irrit.

Irritant to the eye

Flam. Liq.

Flammable liquid

GHS"Globally Harmonized System of Classification and Labelling of Chemicals" developed by the United
Nations

IATA

International Air Transport Association

IATA/DGR

Dangerous Goods Regulations (DGR) for the air transport (IATA)

IMDGInternational Maritime Dangerous Goods Codeindex NoThe Index number is the identification code given to the substance in Part 3 of Annex VI to Regulation (EC) No 1272/2008

IOELV

Indicative occupational exposure limit value

LC50

Lethal Concentration 50%: the LC50 corresponds to the concentration of a tested substance causing
50 % lethality during a specified time interval

LD50

Lethal Dose 50 %: the LD50 corresponds to the dose of a tested substance causing 50 % lethality during a specified time interval

log KOW

n-Octanol/water

NLP

No-Longer Polymer

NOEC

No Observed Effect Concentration

PBT

Persistent, Bioaccumulative and Toxic

PNEC

Predicted No-Effect Concentrationppm

Parts per million

REACH

Registration, Evaluation, Authorisation and Restriction of Chemicals

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Abbr.

Descriptions of used abbreviations

RID

Règlement concernant le transport International ferroviaire des marchandises Dangereuses (Regulations concerning the International carriage of Dangerous goods by Rail)Skin Corr.

Corrosive to skin

Skin Irrit.

Irritant to skin

Skin Sens.

Skin sensitisation

STEL

Short-term exposure limit

SVHC

Substance of Very High Concern

TWA

Time-weighted averagevPvB

Very Persistent and very Bioaccumulative

WEL

Workplace exposure limit

Key literature references and sources for data
Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures.
Regulation (EC) No. 1907/2006 (REACH).
Transport of dangerous goods by road, rail and inland waterway (ADR/RID/ADN).
International Maritime Dangerous Goods Code (IMDG).
Dangerous Goods Regulations (DGR) for the air transport (IATA).

Classification procedure
Physical and chemical properties.
Health hazards.
Environmental hazards.
The method for classification of the mixture is based on ingredients of the mixture (additivity formula).

List of relevant phrases (code and full text as stated in section 2 and 3)
Code

Text

H226

Flammable liquid and vapour.

H301

Toxic if swallowed.

H304

May be fatal if swallowed and enters airways.

H315

Causes skin irritation.

H317

May cause an allergic skin reaction.

H319

Causes serious eye irritation.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

H411

Toxic to aquatic life with long lasting effects.

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Responsible for the safety data sheet

C.S.B. GmbH
Düsseldorfer Str. 113
47809 Krefeld, Germany

Telephone: +49 (0) 2151 - 652086 - 0
Telefax: +49 (0) 2151 - 652086 - 9
e-Mail: info@csb-compliance.com
Website: www.csb-compliance.com

Disclaimer
This information is based upon the present state of our knowledge.
This SDS has been compiled and is solely intended for this product.

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