VINYBLAN HD-065
Safety Data Sheetaccording to JIS Z 7253 : 2019
Issue date: 5/9/2006

Revision date: 3/1/2024

Version: 3.6

1. Chemical product and company identification
Substance name:

VINYBLAN HD-065

Recommended use of the chemical and restrictions on use
Recommended use:

Coating agent, Binder

Restrictions on use:

General industrial use

Company information
Nissin Chemical Industry Co., Ltd.
101-0047 Japan
5-13，Uchikanda 1-chome，Chiyoda-ku，Tokyo，Japan
T +81-3-3295-3931 - F +81-3-3295-3929

2. Hazards identification
GHS classification
Physical hazardsExplosives

classification not possible

Flammable gases

No classification

Aerosolclassification not possible

Oxidizing gases

No classification

Gases under pressure

No classification

Flammable liquids

classification not possible

Flammable solids

No classification

Self-reactive substances andclassification not possible

mixtures
Pyrophoric liquids

classification not possible

Pyrophoric solids

No classification

Self-heating substances andclassification not possible

mixtures
Substances and mixtures whichclassification not possible

in contact with water emit
flammable gases

Health hazards

Oxidizing liquids

classification not possible

Oxidizing solids

No classification

Organic peroxidesclassification not possible

Corrosive to metals

classification not possible

Desensitized explosives

classification not possible

Acute toxicity (oral)classification not possible

Acute toxicity (dermal)

classification not possible

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Acute toxicity (inhalation:gas)

No classification

Acute toxicity

No classification(inhalation:vapours)
Acute toxicity

classification not possible(inhalation:dust/mist)
Skin corrosion/irritation

classification not possible

Serious eye damage/eyeclassification not possible

irritation
Respiratory sensitization

classification not possible

Skin sensitization

classification not possible

Germ cell mutagenicityCategory 1B

Carcinogenicity

classification not possible

Reproductive toxicity

classification not possible

Specific target organ toxicity

classification not possible(single exposure)Specific target organ toxicity

classification not possible(repeated exposure)
Aspiration hazard

classification not possible

Environmental

Hazardous to the aquaticclassification not possible

hazards

environment, short–term (acute)Hazardous to the aquaticclassification not possible

environment, long–term(chronic)
Hazardous to the ozone layerclassification not possible

Hazardpictograms

GHS Signal word:

DangerHazard statements:

May cause genetic defects. (H340):

Obtain special instructions before use. (P201)

Precautionary statements
Prevention

Do not handle until all safety precautions have been read andunderstood. (P202)
Wear protective gloves, protective clothing, eye protection, faceprotection. (P280)
Avoid release to the environment. (P273)

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Response:

IF exposed or concerned: Get medical advice/attention.
(P308+P313)
Get medical advice/attention if you feel unwell. (P314)

Storage:

Store locked up. (P405)
Store in a well-ventilated place. Keep cool. (P403+P235)

Disposal:

Dispose of contents/container in accordance withlocal/regional/national/international regulations. (P501)

3. Composition/information on ingredients
Distinction of substance or:

Mixture:Colloidal dispersion of Alkyl acrylate based copolymer in water

mixtureGeneric name

Name

Reference number in theConcentrationgazette list(%)

CAS-No.

CSCL No

ISHL No< 15

Undisclosed

Undisclosed

Undisclosed

Silica(amorphous)< 10

Undisclosed

Undisclosed

Undisclosed

Methanol< 0.3(2)-201

Existing

67-56-1

Alkyl acrylate based
copolymer

ChemicalSubstance
2-Pyrrolidinone, 1-< 0.3(5)-113methyl-8-(1)-1014872-50-4( 8-(1)1013 ),8-(1)2246

Water< 90--7732-18-5

4. First aid measures
First aid measures
First-aid measures after:

inhalation
First-aid measures after skin

Remove the sufferers to fresh air places and keep themselves rest
in an easy-to- breath position. Get medical advices immediately.

:contact

Take off contaminated clothes, shoes and socks. And wash sticking
parts off with soap and plenty of water. If the external changes
are observed or the symptoms such as irritation or itchy appears,
get medical advices immediately.

First-aid measures after eye:contact

Rinse immediately inner side of eyelid with plenty of water morethan 20 minutes. Remove the contact lenses if possible. Get
medical advices.

First-aid measures afteringestion:

Rinse mouth thoroughly with water and get medical attention
immediately.

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Never give anything through mouth to an unconscious person.

5. Fire fighting measures
Suitable extinguishing media:

Water and alkali salt, Fire foam, Water, Dry chemical

Unsuitable extinguishing:Nothing in particular:This product itself is not a flammable compound. But dry film aftermedia
Fire hazard
Fire hazard

evaporating water is flammable.
Hazardous decomposition:

products in case of fire

The hazardous gasses such as carbon mono- and di-oxide andaldehyde group are generated at the Product’s combustion.

Firefighting instructions
Firefighting instructions:

Cut off ignition sources to a fire origin and fight a fire employing asuitable fire extinguishing agent.
Cool by water spray around the fire site to prevent the fireextension.

Personal protection (Emergency response)
Personal protection (Emergency:response)

Wear suitable protective tools such as goggles, boots, gloves, andbody suits as well as a self-contained breathing apparatus to
avoid direct contact. Fight a fire from the windward.

Other information:

One of the general procedures for chemical fires may be applied.
Use appropriate extinguishing measures considering the local
circumstances and environments. Never inhale such smoke, etc.
as are generated at fire and/or explosion. Use water spray to cool
unopened containers. Recover the water contaminated with fire
extinguishing agents separately. Never discharge this water intodrains. Fire residues and contaminated fire extinguishing watermust be disposed of complying with local regulations.

6. Accidental release measures
Personal Precautions, Protective Equipment and Emergency Procedures
General measures:

Wear a self-contained breathing apparatus and suitable chemical
protective clothes and tools, and work from windward.

For emergency responders
Protective equipment:

Wear suitable protective tools such as goggles, boots, gloves,
body suits and a self-contained breathing apparatus according tocircumstances to avoid inhalation of and direct contact withmaterials in question.

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Emergency procedures:

Clear off all of ignition sources immediately.
Work from windward.
Stop release.

Environmental precautions
Environmental precautions:

Never release this products to waters and soil.
If the products spill into rivers, lakes or marshes、inform the firestation or authorities of the local governments.

Methods and Equipment for Containment and Cleaning up
For containment:

When the releasing materials are large, prevent spreading bycover with banking and the like and vacuum and recover with apump,etc.
When the releasing materials are small, recover as mortar aftermix with perlite, dirt, sawdust and/or the like.

Methods for cleaning up:

Clean up the surroundings of the releasing area with water after
recovery and recover the contaminated water as well.

Prevention Measures for:

Secondary Accidents

If the products spill into rivers, lakes or marshes、inform to the firestations, authorities relating environment disruption, River Bureau,
Water Supply Bureau, etc. of local governments, if necessary.

Other information:

Take care of slip as released area becomes easy to slip.

:As polyvalent metal ions such as iron, copper, zinc, aluminum, etc.

7. Handling and storage
Handling
Technical measures

may cause collering, gelling, etc, pay care and attention for choiceof storage installations, pipework, blenders and the like.
Use in well-ventilated areas.
Precautions for safe handling:

Wear suitable personal protecting tools such as protecting gloves,protecting glasses, etc. according to circumstances to avoid tocontact with skin or eye(s).
Never treat containers roughly such as overturning, falling,dragging, impacting and the like.

Prevents handling of:

No information.

:

Wash hands at the end of each work shift before eating, smoking

incompatible substances ormixtures
Hygiene measuresor using the toilet.
Never eat, drink nor smoke during work.
Local and general ventilation:

In case of the work with generation of spray mist or vapor, install
local air exhausters.

Storage

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Storage conditions

Storage temperature must be kept not less than 5°C and never:exceed 35°C.
Store indoor, preventing from sunlight and freezing.
Avoid dust, water, etc. coming into opened containers in use.
Material used in:

Use the containers having water resistance and durability, andpackaging/containers

avoid from contact with metals as possible.
In case of translocation, use stainless or polyethylene containers
to prevent corrosion.

Technical measures:

Keep containers stoppled tightly after use to prevent forming film.

Incompatible materials:

Strong oxidizers. Reactive metals. (sodium,calcium, zinc, etc.).
Dehydrating agent.

8. Exposure controls / Personal protection equipment
Methanol (67-56-1)
USA - ACGIH - Occupational Exposure Limits
ACGIH OEL TWA

200 ppmACGIH OEL STEL

250 ppm
Skin - potential significant contribution to overall exposure by the cutaneous

ACGIH chemical categoryroute

USA - ACGIH - Biological Exposure Indices
15 mg/l Parameter: Methanol - Medium: urine - Sampling time: end of shift

BEI(background, nonspecific)

Japan - Occupational Exposure Limits
Japan administration level

200ppmExposure limits (JSOH)

200ppm(260mg/m3)(skin)

Exposure limits (ACGIH)

TWA 200 ppm,STEL 250 ppm (Skin)

2-Pyrrolidinone, 1-methyl- (872-50-4)
USA - ACGIH - Biological Exposure Indices
100 mg/l Parameter: 5-Hydroxy-N-methyl-2-pyrrolidone - Medium: urine -BEI

Sampling time: end of shift

Japan - Occupational Exposure Limits
Exposure limits (JSOH)

Appropriate engineering controls

1ppm(4mg/m3)(skin):Install sealing equipments or local exhaust equipments at indoor work,
Express the place clearly where safety shower(s) and hand and eye
washer(s) are equipped.

Protective equipment
Respiratory protection: It is needless under normal conditions at well ventilated place, Incase of insufficient ventilation, wear suitable respiratory equipment

Hand protection: Impermeable protect gloves.

Eye protection: goggles style protective glasses

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Skin and body protection: Protective boots, protective clothes.

9. Physical and chemical properties
Physical state:

LiquidColour:

milkyOdour:

No data available

pH:

No data available

Melting point:

No data available

Freezing point:

No data available

Boiling point:≈ 100 °C

Flash point

:

None

Auto-ignition temperature:

No data available

Decomposition temperature:

No data available

Flammability:

No data available

Vapour pressure:

No data available

Relative vapour density at:

No data available

Relative density:

No data available

Density:

No data available

Relative gas density:

No data available

Solubility:

Miscible with water

Partition coefficient n-:

No data available

Explosive limits (vol %):No data available

Explosive limits (g/m³):

No data available

Viscosity, kinematic:

No data available

Particle size:

No data available

20°C

octanol/water (Log Pow)

10. Stability and reactivity
Reactivity:

No reactivity with water

Chemical stability:

Stable under room temperature.

Possibility of hazardous:

No information

Conditions to avoid:No information

Incompatible materials:

No information

Hazardous decomposition:

The hazardous gasses such as carbon mono- and di-oxide andreactions

products

aldehyde group are generated at the Product’s combustion.

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11. Toxicological information
Acute toxicity (oral):(as a product)

No data available

Acute toxicity (dermal):(as a product)

No data available

Acute toxicity (gas) -:(as a product)

No data available:(as a product)

No data available:(as a product)

No data available:(as a product)

No data available

Skin corrosion/irritation:(as a product)

No data available

Serious eye damage/irritation: (as a product)

No data available

Respiratory sensitization:(as a product)

No data available

Skin sensitization:(as a product)

No data available

Germ cell mutagenicity:(as a product)

There are no available data about this product.

Description
Acute toxicity (vapour) Description
Acute toxicity (dust, mist) –Description
Acute toxicity (mist) Description

But, there contain Germ cell mutagenicity
materials belonging to the following
Category.Category 1B: 2-Pyrrolidinone, 1methyl- (<0.3%) Concentration limits ofCategory 1B is ≧0.1%. So,this product iscorrespond to Germ cell mutagenicity Category
1B of GHS.
Carcinogenicity:(as a product)

No data available

Reproductive toxicity:(as a product)

No data available

STOT-single exposure:(as a product)

No data available

STOT-repeated exposure:(as a product)

No data available

Aspiration hazard:(as a product)

No data available

12. Ecological information
Ecotoxicity
Ecotoxicity: (as a product)

No data available

Hazardous to the aquatic: (as a product)

No data available

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Hazardous to the aquatic: (as a product)

No data available

Persistence and degradability:(as a product)

No data available

Biochemical oxygen demand:(as a product)

No data available:(as a product)

No data available

Bioaccumulative potential:(as a product)

No data available

Partition coefficient n-:(as a product)

No data available

Mobility in soil:(as a product)

No data available

Partition coefficient n-:(as a product)

No data available:(as a product)

No data available

Ozone:(as a product)No data available

Other adverse effects:

No additional information available

environment, long–term(chronic)
Persistence and degradability(BOD)
Chemical oxygen demand(COD)
Bioaccumulative potential

octanol/water (Log Pow)
Mobility in soil

octanol/water (Log Pow)
Ecology - soil
Hazardous to the ozone layer

13. Disposal considerations
Ecological information:

Farm out to professional disposal treating traders incompliance with requirements of the nation and local
governments.

Contaminated container and:packaging

Farm out dispose of the contents and packing materials to
professional disposal treating traders in compliance withrequirements of the nation and local governments.
In case of disposal of empty container, dispose after complete
removal in the container.

14. Transport information
International Regulations
Transport by sea(IMDG)
UN-No. (IMDG)
Proper Shipping Name (IMDG): Not applicableNot applicable

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Packing group (IMDG): Not applicable

Transport hazard class(es): Not applicable(IMDG)
Air transport(IATA)
UN-No. (IATA): Not applicable

Proper Shipping Name (IATA): Not applicable

Packing group (IATA): Not applicable

Transport hazard class(es): Not applicable(IATA)

Regulations in Japan
Other information:

At transportation, make sure of no leakage of packings, load
the products without broken bags, falling, injury, etc, andprevent load
collapses surely, See "7 Handling and storage"

15. Regulatory information
REACH SVHC:

Contains a substance on the REACH candidate list inconcentration ≥ 0.1%: 1-Methyl-2-pyrrolidone (NMP) (EC 212828-1, CAS 872-50-4)

16. Other information
Data sources:

Ref. 1.“Safety Data Sheet” by Raw Material Manufacturers.
2.GHS Sixth Revised Edition. 3.NITE GHS Results of theClassification.

Other information:

The Products was developed for general industries’ use. When
applying to specific uses, it is hoped to confirm its safety by
yourselves prior to the use. Prior to use or handle of thisproducts, keep all people who handle this product informed of
the information of this SDS and other information concerning
safety and disasters. The description of this SDS is based uponmaterials, information and data which can be procured atpresent. However, we do not warrant any guarantee regarding
the contents, physical and chemical properties, hazards andthe like.

DISCLAIMER OF LIABILITY The information in this SDS was obtained from sources which we believe
are reliable. However, the information is provided without any warranty, express or implied, regarding
its correctness. The conditions or methods of handling, storage, use or disposal of the product arebeyond our control and may be beyond our knowledge. For this and other reasons, we do not assume
responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way

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connected with the handling, storage, use or disposal of the product. This SDS was prepared and is to
be used only for this product. If the product is used as a component in another product, this SDS
information may not be applicable

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