The 42nd Fluorine Conference of Japan
Oral Presentations

Technical Program

DateTime No.

Nov. 21

9:20 1O02 C‐F Bond Cleavage of Trifluoromethylarenes by Ni(0)/NHCComplexes
9:40 1O03 Synthesis and complexation of bidentate N‐heterocyclic carbenes
with fluorine‐containing electron withdrawing groups at 4,5position
10:00 1O04 Development of Trifluoromethylation Reactions using FreonTM 23

Subject

Hiroto Imiya, Masato Ohashi, Sensuke Ogoshi

Authors

10:20 1O05 Development of fluorine‐containing luminescent tolane fluorine
atom induced emission enhancement effect
10:40 1O06 De Novo Synthesis of Fluorinated Monosaccharides via Mukaiyama
Aldol Reaction as a Key Reaction
11:00 1O07 Visible‐light perfluoroalkylation using simple amine anddevelopment to radical polymerization
11:20 1O08 Synthesis of PAHs from methylarenes via domino cyclization ofdifluoroalkenes
11:40 1O09 Development of fluoroalkylation reactions of alkenes using
fluorinated acid anhydrides

Morita Masato, Yamada Shigeyuki, Konno Tsutomu

hirano kazuki, okusu satoshi, gondo satoshi, shibata norio

Toshiki Nokami, Kana Kuroda, Shiho Hayashi, Ayana Tsukahara,Keisuke Takayanagi, Toshiyuki Itoh
Miyu Tanaka, Tadashi Kanbara, Tomoko Yajima
Takao Go, Takahashi Hiroki, Ijima Shiori, Fuchibe Kohei, Ichikawa Junji
Shintaro Kawamura, Elena Valverde, Daisuke Sekine, Mikiko Sodeoka

Lunch Break

12:00

13:00 1S13 Characterization and Functionalization of Organic Ferroelectric
Vinylidene Fluoride Molecules
13:40 1O15 Preparation and Properties of Fluoroalkyl End‐capped 2‐
Acrylamido‐2‐methylpropanesulfonic Acid Oligomer/Poly(vinylalcohol) Composites
14:00 1O16 Nitrogen Doping of Single‐Walled Carbon Nanotubes UsingDefluorination
14:20 1O17 Investigations of Si etching process using fluorine gas

Nov. 22

Kodai Fukudome, Kota Ando, Sensuke Ogoshi, Masato Ohashi

Kenji Ishida, Yasuko Koshiba, Tatsuya Fukushima
Shinsuke Katayama, Masato Yasuta, Hideo Sawada

Yokoyama Koji, Yoshinori Sato, Tetsuo Nishida, Yoshinori Sato
Masanari Namie, Fumihiro Nishimura, Jae‐Ho Kim, Susumu Yonezawa

14:40 1O18 Suppression of metal surface corrosion by layered doublehydroxide containing acrylic gel sheet
15:00 1S19 High temperature structure and dynamics of molten fluoride salts

Kota Kamon, Masaki Matsui, Hideshi Maki, Minoru Mizuhata

15:40 1O21 Application of high temperature MAS NMR for the study inorganicfluorides
9:00 2O01 Synthesis of heteroacenes using intramolecular cyclization reaction
catalyzed by fluoride ions
9:20 2O02 Rhodium‐Catalyzed [4 + 2] Cycloaddition of Biphenylene with
Difluoroalkenes: Synthesis of Fluorinated Phenanthrenes
9:40 2O03 Changes of the Fluorescence Properties Induced by Fluorine Atoms
on the Naphthalene Ring

Aydar Rakhmatullin, Frantisek Simko, Mathieu Allix, Emmanuel Veron,
Catherine Bessada
Katsutoshi Sekino, Ryosuke Shiki, Natsuki Takigawa, Naoki Shida,
Hiroki Nishiyama, Ikuyoshi Tomita, Shinsuke Inagi
Kosuke Sano, Yota Watabe, Masafumi Takeishi, Takeshi Fujita, Junji
Ichikawa
Kengo Yamada, Yasuhiro Kubota, Toshiyasu Inuzuka, Tomohiro Agou,
Toshio Kubota, Yohei Miwa, Shoichi Kutsumizu, Hiroaki Wasada,Kazumasa Funabiki
Yukiko Karuo, Minori Sakamoto, Taiga Oka, Atsushi Tarui, Kazuyuki
Sato, Kentaro Kawai, Masaaki Omote
Shoki Hoshikawa, Yukiko Moriiwa, Akio Yanagida, Takashi Matsumoto,Hikaru Yanai
Manami Uedo, Tadashi Kanbara, Tomoko Yajima

10:00 2O04 Development of new nucleophilic fluorinating reagents using
nucleophilic aromatic substitution
10:20 2O05 Solubility‐Control of Fluorescent Dyes by Strongly Acidic Groups
Containing Fluorine Atoms
10:40 2O06 Synthesis of dormant species initiator by photo induced
iodoperfluoroalkylation and application to controlled radical
polymerization
11:00 2O07 Preparation of Hydrophobic Surface of Polymers
with High Dense Perfluoroalkyl Side Chains
11:20 2S08 History of Fluorine Chemistry in the Early Days of Japan

Catherine Bessada, Kelly Machado, Aydar Rakhmatullin, Didier Zanghi

Takuya Matsumoto, Eichi Kannan, Takashi Nishino
Shun‐ichi Kodama

Lunch Break

12:00
13:40 2O15 Unique Interaction between Perfluoroalkane and Interface

Aki Fukumi, Takafumi Shimoaka, Nobutaka Shioya, Takeshi Hasegawa

14:00 2O16 Organofluorine Compounds‐Specific Molecular Structure andInteraction Discussed on Phase Transition Temperatures
14:20 2O17 Corrosion analysis for JLF‐1 steel, a structural material for a nuclear
fusion device, in molten LiF‐NaF‐KF by electrochemical methods
14:40 2O18 Effect of pore blocking on nitrogen adsorption behavior offluorinated activated carbon fibers

Takafumi Shimoaka, Takeshi Hasegawa
Gaku Yamazaki, Yuta Suzuki, Takuya Goto, Takuya Nagasaka, Takashi
WatanabeSugiyama Hironori, Hattori Yoshiyuki

Break

15:00

15:20 2O20 Investigation of electrochemical reaction of fluorine‐graphite
intercalation compound containing copper fluoride for the cathodeof all‐solid‐state fluoride‐ion shuttle battery.
15:40 2O21 Interaction of Fluoride Ion and Hydroxyl Proton in Alkali Metal
Fluoride‐Diol complex Salt
16:00 2O22 Synthesis of fluorine‐containing helicenes
16:20 2O23 Introduction of fluorine‐containing functional groups into aza‐
heterocyclic compounds bydecarboxylative functionalization of carboxylic acid
16:40 2O24 Generation and Reaction of Fluorine‐Substituted Methyllithium
Using Flow Microreactor

1

Yoshiaki Matsuo, Junichi Inamoto, Atsushi Mineshige, Miwa
Murakami, Kazuhiko Matsumoto, RIka Hagiwara
Yuto Tonouchi, Kazuhiko Matsumoto, Rika Hagiwara
Masaki Kohara, Yuuki Tamura, Tomohiro Agou, Hiroki Fukumoto,Toshio Kubota
Ryouta Kawanishi, Lacksany Phongphane, Kosuke Nakada, Kazutaka
Shibatomi
Yusuke Takahashi, Marco Colella, Arianna Tota, Ryosuke Higuma,
Renzo Luisi, Aiichiro Nagaki

Poster Presentations (Nov. 21)
Field

Time No.

SubjectAuthors

Analytical and Environmental Chemistry
16:10 P01
17:10 P02
16:10 P03

Efficient Mineralization of Poly(VDF‐co‐MAF) in Low‐temperature
Subcritical Water in the Presence of Potassium Permanganate
Permanganate‐Induced Efficient Mineralization of Fluorinated Ionic
Liquids in Subcritical Water
Complete Mineralization of ETFE in Subcritical Water in thePresence of Potassium Permanganate

Ryo Honma, Hisao Hori, Sanjib Banerjee, Fernando Reis da Cunha,
Bruno Ameduri
Satomi Oishi, Hiroki Kato, Ryuuta Kodama, Hisao Horihamaurajin, takahashitoshiaki, horihisao

Inorganic Chemistry
17:10 P04
16:10 P05
17:10 P06
16:10 P07
17:10 P08
16:10 P09
17:10 P10
16:10 P11
17:10 P12
16:10 P13

Synthesis of lithium transition‐metal fluorides under ambient andhigh‐pressure using solid fluorine sources
Effects of deoxofluorination of graphite oxide with sulfur
tetrafluoride on its structure
Stabilization of alkali metal fluorocomplex salt using organic ligandCurrent efficiency of fluorine gas generation at room temperatureusing Cs[(FH)2.45F] room temperature molten salt containing CuF2
Thermoelectric Properties of π‐Conjugated Nickel Complexes
Containing a Fluorocarbon Polymer
Synthesis of Nitrogen‐Doped Graphite via Fluorination‐
Defluorination Process
Effects of surface fluorination on the formation of Ni‐BN composite
plating film
Preparation and evaluation of copper fluoride powder with highoxidation resistance and high conductivity
Preparation of Ni‐PTFE composite film with high water repellency
and the effect of heat treatment
Preparation and evaluation of Li4Ti5O12 using titanium‐containing
aqueous solution

Moemi Oyanagi, Yoshiyuki Inaguma, Koichiro Ueda
Hiroki Yamamoto, Kazuhiko Matsumoto, Yoshiaki Matsuo, Yuta Sato,
Rika Hagiwara
Shunsuke Sawada, Yuki Haruki, Kazuhiko Matsumoto, Rika Hagiwara
Keita Shima, Takuya Sugimoto, Kazuhiko Matsumoto, Rika Hagiwara
Ueda Kazuki, Nana Toyama, Mika Oku, Masahiro Muraoka, Michihisa
MurataMinori Kokubo, Yoshinori Sato, Tetsuo Nishida, Yoshinori Sato
Yuta Shimpo, Masanari Namie, Yui Nishigaki, Jae‐Ho Kim, Susumu
Yonezawa
Ryosuke Yokochi, Jae‐Ho Kim, Susumu Yonezawa
Yui Nishigaki, Yuta Shinpo, Jae‐Ho Kim, Susumu Yonezawa
Ryota Honda, Hayato Suzuki, Jae‐Ho Kim, Susumu Yonezawa

Organic Chemistry
17:10 P14 In‐Situ Generation of Aryl Trifluoromethyl Ketones from Iodoarenes Ryunosuke Kani, Toshiyasu Inuzuka, Yasuhiro Kubota, Kazumasa
and Tandem Reduction Using the Dual Reactions of Turbo Grignard Funabiki
Reagent
16:10 P15 Catalytic Asymmetric Synthesis of Trifluoromethylated Tetraols
Toshiya Gotoh, Toshiyasu Inuzuka, Yasuhiro Kubota, Kazumasa
Using Organocatalytic Asymmetric Aldol Reaction ofFunabiki
Trifluoroacetaldehyde Hemiacetal
17:10 P16 Syntheses and Property of Hexafluorocyclopentane‐Fussed Furans Takeya Suzuki, Seiya Nemoto, Tomohiro Agou, Hiroki Fukumoto,Toshio Kubota
16:10 P17 Facile synthesis of polyfluoro‐α,ω‐diynes and their [2+2+2]
Shogo Saruwatari, Tomohiro Shirai, Tomohiro Agou, Hiroki Fukumoto,
cycloaddition
Toshio Kubota
17:10 P18 Development of Copper‐Catalyzed Trifluoromethylation ofSichen Yue, Kazuki Komoda, Tsuyuka Sugiishi, Hideki Amii
Haloalkenes
16:10 P19 Synthesis of fluorine‐containing pyrrole using trifluoromethylalkyne Ebinuma Aki, Sugiishi Tsuyuka, Amii Hideki
17:10 P20
16:10 P21

17:10 P22
16:10 P23
17:10 P24
16:10 P25
17:10 P26

16:10 P27
17:10 P28
16:10 P29
17:10 P30
16:10 P31
17:10 P32
16:10 P33

Catalytic Trifluoromethylation by Use of Benzimidazoline
Derivatives
Enantioselective Friedel‐Crafts alkylation reaction of heterocyclic
compounds with α‐ trifluoromethylated β‐nitrostyrenes catalyzed
by chiral metal phosphate
Synthesis of Polyvinyl Ethers Containing a Fluoroalkyl Group

Nanami Kamiyama, Taisuke Ishikawa, Tatsuhiro Uchikura, TakahikoAkiyama
Sosuke Yokohama, Mio Kaneko, Ignacio Ibanez Sanchez, Tatsuhiro
Uchikura, Takahiko Akiyama

Synthesis of HF Complexes Using Amines and Strong Organic Bases
and Their Application to Anodic Benzylic Fluorination[3+2]cycloaddition reaction of 2‐monofluoromethyl‐N‐tosyl
aziridine with aldehydes
Cross‐coupling reaction of (Z) ‐2‐bromo‐2‐CF3‐vinyl benzyl sulfideand its synthetic application
Ring‐Opening Fluorination of an Epoxide Using Various HF
Complexes
Investigation of Addition of Cu–N, and Cu–S to Tetrafluoroethylene
and Following Coupling Reaction
Fluorination of Boron Ketoiminates as an Aggregation‐InducedEmission Fluorophore: Synthesis and Characterization
Synthesis of CF2 Substituted Fluorescent Coumarin Core Bearing
Push‐pull System and its fluorescence Performance

Kaito Santa, Musashi Asano, Keiichi Muraoka, Toshiki Tajima

Masaki Ueda, Yamada Shigeyuki, Kubota Toshio, Hukumoto Hiroki,Agou Tomohiro, Tsutomu Konno
Novel Introduction of Perfluoropolyether Unit into AromaticsMachiko Kawazoe, Masaki Ueda, Shigeyuki Yamada, Tsutomu Konno,
Shinya Takano, and Takashi Nomura
Development of simple synthetic methods for unique
Yoshitaka Nomura, Yasuhiro Hirata, Masashi Takahashi, Noriakiorganofluorine building block and the biological activity evaluation Miyake, Mihoko Noro, Yasuhisa Matsukawa, Yoshitomi Morizawa
Makoto Matsuura, Yoshichika Kuroki, Yosuke Kishikawa, Shuhei
Efficient synthesis of a wide range of fluorine‐containing
compounds utilizing highly selective reductive addition reaction
Sumino, Misae Uno, Takahide Fukuyama, Ilhyong Ryu
Selective Synthesis of Cyclic Compounds with a Tetrafluoroethylene Suguru Morishitabara, Shigeyuki Yamada, Tsutomu Konno
Group Based on Highly Controlled Cyclization Process

2Keiichi Sato Takeshi Hanamoto
Genki Ikeda Takeshi Hanamoto
Keiichi Muraoka, Toshiki Tajima
Denise Eimi Sunagawa, Naoyoshi Ishida, Masato Ohashi
Kazuyuki Sato, Akira Kawasaki, Yukiko Karuo, Atsushi Tarui, Kentaro
Kawai, Masaaki Omote
A. Tarui, K. Tsututani, S. Emi, K. Sato, H. Hashiguti, Y. Karuo, K. Sato, K.
Kawai, K. Tani, M. OmoteFieldTime No.

SubjectAuthors

17:10 P34

CsF‐Catalyzed Pentafluoroethylation of Aromatic Acyl Fluorides
Using Tetrafluoroethylene
Synthesis of fluorinated polyxylylene analogues by reductive
coupling polymerization using Ni (0)Development of Cascade‐type aldol reaction using Krapcho
Decarboxylation
Asymmetric Dearomatizing Fluorination of Indole Derivatives underPhase‐Transfer Catalysis
Synthesis of novel fluorine‐containing amino acids and theirapplication to cell penetrating peptides
Construction of quaternary carbon centers containing a CF3 groupby N‐heterocyclic carbene‐catalyzed 1,6‐addition reactions ofaldehydes to p‐quinone methides generated in situ
Cooperative action of cohesive force between perfluoroalkyl chainsand H‐bonding between dipeptide parts on the molecularaggregation of ammonium amphiphiles
Formation of Helical Superstructure Induced by Axial Chirality of a
Perfluoroalkyl Chain
Generation of Monofluoroalkyl Radicals using Strongly Reducing
Organic Photoredox Catalyst: New Synthetic Methods of β‐Fluoroketones
Synthesis of Trifluoromethyl Group Substituted 1,3‐Enynes by thePalladium‐Catalyzed Alkynylation of 2,3,3‐Trifluoroallylic
Carbonates with Terminal Alkynes
Reactivity of persistent perfluoroalkyl radicalNaoyoshi Ishida, Denise Eimi Sunagawa, Masato Ohashi, Sensuke
Ogoshi
Hideki Ito, Anna Shigaki, Takuya Tsuruta, Sensuke Ogoshi

16:10 P35
17:10 P36
16:10 P37
17:10 P38
16:10 P39

17:10 P40

16:10 P41
17:10 P42

16:10 P43

17:10 P44
16:10 P45

Reactions of 4‐bromo‐4,4‐difluorocrotonate with glycine imines

17:10 P46

Synthesis and Physical Properties of Fluorine‐Substituted Mimics ofNatural Chlorophyll‐aIntroduction Reaction of Fluorined Carboxyl Groupsvia Silver‐Catalyzed Ligand Coupling of Diaryliodonium(III) Salts
Reactivity of Triflylated Carbanion: Selectivity in C–C Bond Forming
Reaction with Vinyl Carbocation
Electrochemical fluorination of π‐extended Tellurophenes

16:10 P47
17:10 P48
16:10 P49
17:10 P50
16:10 P51
17:10 P52

Chlorodifluoromethylation reaction using chlorodifluoroacetic
anhydride
Synthesis of Fluorinated Cyclic Ethers by Intramolecular Radical
Cyclization Reaction
Application of 14N‐decoupled HOESY for 19F‐mediated amidehydrogen bonds

Physical Chemistry, Materials Chemistry, Polymer Chemistry, Pharmacy
16:10 P53 Vibration Generator Characterization of Unimorph Cantilever
Devices Using Piezoelectric Fluorinated Polymer Films
17:10 P54 Effect of Fluorination of Pseudo‐cyclic Ether Phospholipid onMembrane Properties and Structure and Function of Membrane
Protein16:10 P55 Controlled Radical Copolymerization of α‐Trifluoromethylstyrenes
17:10 P56
16:10 P57
17:10 P58
16:10 P59
17:10 P60

16:10 P61
17:10 P62
16:10 P63
17:10 P64

16:10 P65
17:10 P66

Hiroshi Shimomura, Atsuhi Tarui, Yukiko Karuo, Kentaro, Kawai.
Masaaki Omote
Hiromichi Egami, Ryo Hotta, Minami Otsubo, Taiki Rouno, Kenji
Yamashita, Tomoki Niwa, Yoshitaka Hamashima
Toshiki Mikami, Kohsuke Aikawa, Jumpei Morimoto, Shinsuke Sando,Kyoko Nozaki, Takashi Okazoe
Kyu Terashima, Tomoko Kawasaki‐Takasuka, Takashi Yamazaki

Kousuke Fujimoto, Takafumi Shimoaka, Takeshi Hasegawa, Norihiro
YamadaAmi Fukushi, Kousuke Fujimoto, Takafumi Shimoaka, Takeshi
Hasegawa, Norihiro Yamada
Ryo Taniguchi, Naoki Noto, Takashi Koike, Munetaka Akita

Atsushi Mochizuki, Yuji Hoshino, Hiroaki Tsuji, Motoi KawatsuraAzusa Sato, Maksym V. Ponomarenko, Taizo Ono, Alicja Wzorek,Midori Okada, Gerd‐Volker Roeschenthaler, Vadim A. Soloshonok
Yuko Nakamura, Modori Okada, Hikaru Yanai, Takeo Taguchi
Kohei Nakano, Shin Ogasawara, Hitoshi Tamiaki
Keina Komiyama, Kotaro Kikushima, Mina Saito, Yasuyuki Kita,
Toshifumi Dohi
Hikaru Yanai, Yuuki Fujimoto, Takashi Matsumoto, Irene Martn‐Mejas,
Cristina Aragoncillo, Pedro Almendros
Naoki Shida, Hiroki Nishiyama, Feng Zheng, Ikuyoshi Tomita, Shinsuke
Inagi
Yuma Aoki, Shintaro Kawamura, Cassandra J. Henderson, Daisuke
Sekine, Shu Kobayashi, Mikiko Sodeoka
Ofuji Yu, Kanbara Tadashi, Yajima Tomoko
Keiko Hasumi, Hiroaki Utsumi, Hiroaki Sasakawa

Yasuko Koshiba, Akiko Kobayashi, Shohei horike, Tatsuya Fukushima,Isaku Kanno, Kenji Ishida
Rui Kawahara, Toshiyuki Takagi, Hiroshi Takahashi, Takashi Kikukawa,
Hideki Amii, Masashi Sonoyama
Yuriko Ito, Tadashi Kanbara, Tomoko Yajima

Development of Novel Perfluoropolyether‐containing Block
Copolymers and Their Characteristics
Mechanical Property and Skeletal Conformation in Crystalline
Regions of Tetrafluoroethylene‐Vinyl Alcohol Copolymers
Development of fluorinated polymer utilizing reactivity oftrifluorovinyl group
Evaluation of photophysical property for enediyne‐typeluminophores with hexafluorocyclopentene‐based bent core
Evaluation of physical properties for light‐emitting liquid‐crystalline
polymers bearing polyfluorinated bistolane‐based side‐chain

Shota Shibutani, Kenji Adachi, Sadahito Aoshima

Effect of substitution pattern of fluorine‐containing tolane on
physical properties
Influence of Center Alkylene Chain Length of Fluorine‐ContainingDimer and Orientation Direction of Ester Group on Gelation Ability
Electroreductive Synthesis of Perfluoropolyphenylene Films andTheir Structural Analysis
Post‐functionalization of Octafluorobiphenyl‐containing π‐
Conjugated Polymers Based on Nucleophilic Aromatic Substitution
Reaction
Electrochemical properties of gel electrolyte using fluorinatedgelator
Influence of Fluoroalkyl Chain Length on Gelation Ability of Low
Molecular Weight Organic Compounds Having Fluorine Substituent
at Both Terminal Position

Shigeyuki Yamada, Tsuyoshi Tanaka, Tsutomu Konno

3Hitomu Mushiaki, Takuya Matsumoto, Takashi NishinoKazuto Yoshinari, Tomohiro Shirai, Tomohiro Agou, Hiroki Fukumoto,Toshio Kubota
Shigeyuki Yamada, Akito Nishizawa, Tsutomu Konno
Shigeyuki Yamada, Mitsuda Akira, Tsutomu Konno

Ryoichiro Yoshihara, Koutaro Kanetada, Yuki Morita, Hiroaki Okamoto
Keita Tomioka, Wataru Ito, Toshiki Tajima
Kazuyuki Ninomiya, Takanobu Nishikawa, Naoki Shida, Hiroki
Nishiyama, Ikuyoshi Tomita, Shinsuke Inagi
Takumi Sugiura, Junya Yamaguchi, Yuki Morita, Hiroaki Okamoto
Daiki Mizobe, Yuki Murata, Yuki Morita, Hiroaki Okamoto