N

MATERIAL SAFETY DATA SHEETNANO TEC‖ NOLOCに SI In(REVISiON:

SUPERSEDES:PAGE:NYACOL① ZR100/20 pH 3.0

1/11/2010
1/20/2009

10F4

ChemicaI Product and Company ldentification
Trade Name:NYACOL° ZR100/20 pH 3.O Zirconia Sol

Chemical Name:

Zirconium Oxide,Nitric Acid

Synonym s:

None.

Product Code:

Usei
Manufacturer:

ZR100/20 pH 3.0

Ceramics
NyacoI Nano Technologies,Inc.

Megunko Road,Ashiand,MA O]721U.S,A
Emergency Telephonei
E―2

mail Contacti

infoOnyacol.co m

Composition/1nfOrmation on ingredients

COmDOnentCAS≠

Exっ osure Limits

Percent Bv Weight

Zirconium Oxide:
Nitric Acid:

1314‑23‑47697‑37‑25mg/M3(zr)
2 ppm

20

Water:

7732‑18‑5None.

77

Comoonent

EINECS#

Zirconium Oxide:

215‑227‑2
23可 ‑7可 4‑2RTECS#
ZH8800000
QU5775000
ZC0110000

REACH#
05‑2117294598‑22‑0000
05‑2117294593‑32‑0000

Nitric Acid:

Wateri3.

508‑881‑2220
CHEMTREC: 800‑424‑9300

231‑791‑23None.

Hazard identification
Emergencv Over萌 ew

White translucent liquid.No odor

Ciassification
Symbol:Not harmful.
Not applicable.

Risk PhrasesI
Safety PhrasesINot applicable.
Not applicable.

Keep spilis out of surface vvaters.

Potential Health Effects/Health Hazard identification

Acute ExpOsure:
Eye:irritation.

Skini
Ingestion:
InhalationI

lrritation.
Not available.
Not available.

Chronic ExpOsure:

Not known.

Other Hazards
Known SynergistsI
Exp10sion Hazard:
Fire Hazard:
Corrosion Hazard:

4.

Not ava‖ able.
Not available.
Not available.
Not available.

First Aid Measures
Eye Contact:
Skin Contact:ingestion:

Wash weH with soap and vvater.

inhalation:
First Aid Facilities:

anything by mouth to an unconscious person.
Remove person from exposure source,consuit medical profe5SiOnal.
Eye wash station.Milk of Magnesia or other medical antacid.

Advice to Physicians

None available.

FIush eyes vvith iarge quantities of vvater. If irritation persists get medical attention.
If swa‖ owed seek medical attention immediately. Do notinduce vomiting. civelarge quantities of water with Milk of Magnesia or other medical antacid. Never giveギ

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MATERIAL SAFETY DATA SHEETNANO Tヒ CHNOLOCに SI Inc、REVISiON:

SUPERSEDES:NYACOL① ZR100/20 pH 3.011/11/2010
1/20/2009

PACE:

20F4

ｒ︐Firefighting Measures
Fiammability:

Extingulshing Media:
Protective Equipmenti

Material vvi‖ not burn in a fire.Containers can build pressureif exposed to heat or fire.
AII are acceptable. Cool containers with water spray.
Wear standard fu‖ firefighter turn― out gear(fu‖ bunker gear)and respiratory

protection(SCBA).
Special ExpOsure Hazard

6.

None known.

Accidental Release Measures
Leaks and Spilis

PersonaI Protectioni

Contain sp‖ l orieak with sand,ciay or absorbents. Recover liquid for recycle ordisposal. Do not a‖ ow sp‖ Is into sewers or surface vvaters, PIace absorbents,vvaste

products and contaminated soilinto containers for disposal.
Eye protection and impervious gloves.An approved air― purifying respirator should
be worn if dust or mist is present.

78.

Handling and Storage
Handling:

Avoid generating mist or dust during use.

Storage:

Store in cool dry area. Do not freeze.

Exposure Controis/PersOnaI Protection
Engineering Controli
Respiratory Protection

Use exhaust vent‖ ation to keep airborne concentrations below exposure limits.

When respiratory protection required or concentrations unknown,use approved air―puttfying respirator equipped with dust cartridge.

Skin Protection
Eye Protection:

9.

10.

Clean body― covering clothing,impervious gioves such as neoprene.

Wear approved safety glasses.

Physical and ChenlicaI Properties
Appearancei

White translucent liquid

Odori

None.

PhysicaI State:

Liquid, NYACOL° ZR100/20 pH 3.O is a water― based material.

pH:

3

Boiling Point:]OO° C(212° F)water

Freezing Pointi

O°

Flash Pointi

C(32° F)water
Not applicable.

Vapor Pressure:2260 kPs(17mm Hg)at 20° C water

Oxldizing Properties:

Not an oxidizer.

Solubility in VVateri

Soluble in a‖ proportions.

Density:1240 Kg/M3

Specific Gravity:

1.24

Volatile by Weighti

80%

Viscosity:<15 cP

Explosion Limitsi

Not apphcable.

Partition Coefficienti

Not ava‖ able.

EvapOration Rate:

SIOW(ButyI Acetate=1)

Stability and Reactivity
ChenlicaI Stability:

Stable.

Conditions To Avoid:

Neutralization by basic materials

incompatib‖ ity With Other
Matettalsi

Not available

Hazardous Decomposition
Productsi

Nitric acid,oxides of nitrogen

HazardousPolymerization:W‖ i not occur.

でN
11MATERIAL SAFETY DATA SHEETNANO TECHNOLOGIES,inc

13.

NYACOL① ZR100/20 pH 3.0

11/11/2010
1/20/2009

30F4

Toxicological infor!￢ ation
Matettal

12

REVISiON:SUPERSEDES:
PAGE:

LD50.Rati Oral

Zirconium Oxide:>8800 mg/k9

Nitric Acid:>90 mL/kg

Water:

None reported

Eye Effects:

Not ava‖ able.

Skin Effects:

Not available.

inhalation Effects:

Not ava‖ able.

Ingestion Effects:

Not available.

Ecological information
Ecotoxicity:

Not available.

Persistencei

Not available.

DispOsai considerations
Disposal Considerations:

Neutralize、 /vith lime or 50da aSh. Solids should be put in a landfi‖

United Stateschemical waste.
Untreated ZR1 00/20 pH 3.O may be an unlisted hazardous waste vvith theapproved fo「characteristics of corrosivity,D002.

14.

Transport information¨

ShipDin9 Name

Hazard Class

Packinq Croup

U.N.Number

U.S.D.O.T.:

Not applicable.
Not applicable.
Not applicable.
Not applicable.

Not applicableNot applicableNot applicableNot applicableNot applicable.
Not applicablel
Not applicable.
Not applicable.

Not applicableNot applicableNot applicable

ICAO/1ATA:

IMO/1MDG:
ADR:
15.

Not apphcableRegulatory inforlmation
U.S.Federal Requlations
EPA TSCA Inventory:A‖ ingredients listed.

SARA Section 31 3:

This product contains the following toxic chemicals sutteCt tO the reporting

requirements of Section 313 ofthe Emergency PIanning and Community Right―to―Know Act of1986 and of 40 CFR 372:

Chemical Name
Nitric Acid
D.O.T.Regulations:

CAS#7697‑37‑2

Percent Bv Wetgh二3

See Section 1 4.

U.S.State Re(】 ulations
California Proposition 65

No ingredients listed.

StateRight̲to̲Know Lavvs

Section 2 ofthis MSDS Iists aH components of ZR1 00/20 pH 3.0.

Canadian Regulations
Domestic Substance ListiA‖ ingredients IIsted.

WHMIS:

Zirconiunl dioxidei Uncontro‖ ed
Nitric acidi E,disclosure 0 1.0%

Transportation ofDangerous Coods:
Contro‖ ed ProductsRegulationsi

Does not meet dangerous goods criteria
This MSDS contains a‖ the information items specified in Schedule l,Column 3 of
the Contro‖ ed Products Regulations in a 1 6‑heading format.

EC Re9ulations
Classificationi

Not harmful.

Symboli

Not applicable.
Not applicable.
Not applicable.

Risk Phrases:
Safety Phrases:

N16.

MATERIAL SAFETY DATA SHEETNANO TECHNOLOCに 5̀1に

REViSiON:SUPERSEDES:NYACOL① ZR100/20 pH 3.0

11/11/2010
1/20/2009

PAGE:

40F4

Other information

None

NFPA704Hazard Rating

Health― 可,Flammab‖ ity‑0,Reactivity‑0,Special―

HMIS° Hazard Ratingi

Health‑1,Flammability‑0,Reactivity‑0

Recommended Use

ZR100/20 pH 3.O is recommended for use in ceramics. Other uses have not been

Protective Equipment― B: Eye Protection,Cioves
investigated and may have other hazards. For industrial use only,not for food,drugor home use.
Work Alert:

Workers using ZR1 00/20 pH 3.O should read and understand this MSDS and betrained in the proper use of this material.

MSDS Prepared By:

David L.Catone
TechnicaI Service and Product Deveiopment Manager
NyacoI Nano Technologies,Inc.

Telephone: 508‑881‑2220 U.S.A.
Revision Date

November ll,2010

Supersedes:

January 20,2009

information herein is accurate to the best of our knowiedge. Suggestions are made without warranty or guaranteeof resuits. Before using,the user should determine the suitability of the products for the intended use,and theuser assumes the risk and liability in connection therevvith. We do not suggest violation of any existing patents orgive permission to practice any patented invention without license.

NYACOL° is a registered trademark of NyacoI Nano Technologies,Inc.

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