Lithium-Thionyl Chloride (Li-SOCl2) Battery 1/6
Document Number: RD-ER-202401-001
Issued date:05 December 2023
Effective date:06 Decembe 2023

MATERIAL SAFETY DATA SHEET
1. Product and Company Identification
Product Category: Lithium-Thionyl Chloride (Li-SOCl2) Battery
Nominal Voltage: 3.6 V
Product NameType

CLASS 9(UN)Lithium(gr.)

ER14250

0.31

ER14250C

0.31

ER14250V

0.31

ER14335

0.43

ER14505

0.69

ER14505X

0.69

ER14505V

0.67

ER17505

0.93

ER18505

0.98

ER18505V

0.98

ER14250M

0.19

ER14335M

0.34

ER14505M

0.51

ER17505M

0.72

ER18505M0.90

ER22G68（BEL）

0.10

ER32L65（1/10D）

0.25

ER32L100（1/6D）

0.44

ER18600.07

ER2450T

0.14

EF651615（LTC-3PN）

0.10

EF651620（LTC-5PN）

0.14

EF651625（LTC-7PN）

0.19

EF702338（LTC-16PN）

0.41

ER26500

Class 92.20

ER26500C

Class 92.20

ER26500V

Class 92.20

ER34615Class 9

4.92

ER34615CClass 9

4.92

ER34615V

Class 9

4.92

ER34615E

Class 94.40

ER341245Class 99.07
EVE Energy Co., Ltd Safety and Reliability Lab

Lithium-Thionyl Chloride (Li-SOCl2) Battery 2/6
Document Number: RD-ER-202401-001
Issued date:05 December 2023
Effective date:06 Decembe 2023

ER26500M

Class 91.55ER34615M

Class 93.36

ES-261520/W

Class 92.20ES-261550/W

Class 92.20ES-341520/W

Class 9

4.92

ES-341550/W

Class 9

4.92

ES-341520/W DD

Class 99.07

ES-341550/W DD

Class 99.07

Supplier’s Name:

EVE Energy Co., Ltd
EVE Industrial Park, Xikeng Industrial Zone, Huihuan Town, Huizhou, Guangdong,

Supplier’s Address:

China.

Post Code:

516006Emergency Telephone:(+86) -752-2606966

Fax:(+86) -752-2606033
Note: The battery is neither substance nor mixture but product and having no risk to life and healthunder normal use or transportation because ingredients of battery is not leaked out by virtue ofhermetical sealing with metal case.
This sheet notifies possible risk of our battery under abnormal use but mainly aim to provide
information about ingredients, notification of handling and transportation regulations as a
useful reference.

2. Hazards identification
The important hazards andadverse

effectsoftheNo information available

chemical productChemical product – specifichazards

No information available
Chemical contents are seal in metal can. Therefore, risk of exposure never occurs

Outline of an anticipatedemergency

unless battery is mechanically or electrically abused.
Risk of explosion by fire is anticipated if batteries are dispose of in fire or heated
above 100 degree Celsius. Stacking or jumbling of batteries may cause external
short circuits, heat generation, in some case, allowing fire or explosion.

Note: our battery is not classified in accordance with the GHS classification.
3. Composition/Information on Ingredient

EVE Energy Co., Ltd Safety and Reliability Lab

Lithium-Thionyl Chloride (Li-SOCl2) Battery 3/6
Document Number: RD-ER-202401-001
Issued date:05 December 2023
Effective date:06 Decembe 2023

Chemical Name

Molecular Formula

CAS No.

Weight(%)

Lithium

Li7439-93-2

3.5~5.0

CarbonC

1333-86-4

3~6

Polytetrafluoroethylene(C2F4)n9002-84-0≤0.5

Thionyl Chloride

SOCl27719-09-7

40~45

Aluminum Chloride

AlCl37446-70-0

1~5Lithium Chloride

LiCl7447-41-8≤0.5

Stainless Steel

N/A

N/A

30~36.5

GlassNa2O.CaO.6SiO2

N/A

0.05~0.5

Nickel

Ni7440-02-0≤14. First-aid measures

Inhalation

If ingredient leaked out from inside of a battery and if inhaled it, move to a place
where fresh air is provided. Refer for medical attention.
If ingredient leaked out from inside of a battery and stuck on skin, wash the contact

Skin contact

areas off immediately with plenty of water and soap. If appropriate procedures are nottaken, this may cause sores on the skin. Refer for medical attention.
If ingredient leaked out from inside of a battery and came into eyes, flush the eyes

Eyes contact

with plenty of water for at least 15 minutes immediately without rubbing. Take amedical treatment. If appropriate procedures are not taken, this may cause an eyeirritation.

Swallowing

In case of swallowing of battery, immediately refer for medical attention.

5. Fire-fighting Measures
Fire extinguishing agent:
Dry chemical, alcohol-resistant foam, powder, atomized water, carbon dioxide and dry sand areeffective.
Extinguishing method:
Escape batteries to safe place prevent from ignition by spreading fire.
Because of packing material of battery is paper, use water extinguisher, CO2 extinguisher or powderextinguisher as normal extinguisher.
Since vapor, generated from burning batteries may make eyes, nose and throat irritate, be sure toextinguish the fire on the windward side. Wear the respiratory protection equipment in some cases.
6. Accidental Release Measures
Chemical contents are sealed in metal can. But if the battery is mechanically or electrically abused,contents may leak out. In such case, take action as shown below.
Personal precautions: Temporary inhalation of odor and attaching of electrolyte to skin does notcause serious health hazard. Be sure the ventilation and washing out ofelectrolyte quickly.
EVE Energy Co., Ltd Safety and Reliability Lab

Lithium-Thionyl Chloride (Li-SOCl2) Battery 4/6
Document Number: RD-ER-202401-001
Issued date:05 December 2023
Effective date:06 Decembe 2023

Environmental precautions: Clean up it quickly. Specific environmental precaution is notnecessary.
Method and materials for containment and methods and materials for cleaning up:
Contain and collect spillage and place in container for disposal according to local regulations.
7. Handling and Storage
Do not charge, short-circuit, disassemble, deform, heat above 100℃ or incinerate.
Do not pile up or mingle battery with each other.
Handing

Do not place battery on metal case, metal plate or antistatic material.
In case of multi cell application, replace all batteries to new at once when replacing usedbatteries.
Be sure to store batteries in well-ventilated, dry and cool conditions.
Keep away from water, rain, snow, frost or dew condensation.
Do not store batteries near source of heat or nozzle of hot air.

Storage

Do not store batteries in direct sunshine.
Take care not to get wet packing by dew condensation when packing is removed from cold
to warm and humid condition.
Enough number of fire fighting apparatuses should be installed in warehouse

8. Exposure Controls and Personal Protection
There is no need of personal protective equipment on regular handling and storage. In the event,
however, a large amount of electrolyte should be released by mechanical or electrical abuse, use theprotection as shown below.
Respiratory protection: Mask (with a filter preferably)
Hand protection: Synthetic rubber gloves
Eye protection: Goggles or glasses
9. Physical and Chemical Properties
State：Solid
Shape: Cylindrical、Prismatic
10. Stability and Reactivity
Stability: Stable on regular handling
Conditions to Avoid: External short circuit of battery, deformation by crush, exposure at hightemperature of more than 100 degree C (may cause heat generation andignition), direct sunlight, high humidity.
Materials to avoid: Substances that cause short circuit.
11. Toxicological Information
Inhalation, skin contact and eye contact are possible when the battery is opened. Exposure to internal
contents, the corrosive fumes will be very irritating to skin, eyes and mucous membranes.
EVE Energy Co., Ltd Safety and Reliability Lab

Lithium-Thionyl Chloride (Li-SOCl2) Battery 5/6
Document Number: RD-ER-202401-001
Issued date:05 December 2023
Effective date:06 Decembe 2023

Overexposure can cause symptoms of non-fibrotic lung injury and membrane irritation.
12. Ecological Information
Persistence and degradability

No information available

Mobility in soil

No information available

13. Disposal Considerations
Dispose of batteries in accordance with applicable federal, state and local regulations.
For safety precaution, battery should be insulated in proper manner; covering both terminals by tape,wrapping of battery in insulative bag or packing battery in original package is recommended in orderto prevent ignition due to short-circuit.
14. Transport Information
Lithium metal cells and batteries are given UN numbers as shown in the below table.
For the international transport of lithium batteries, they must comply with these regulations: theInternational Maritime Dangerous Goods (IMDG) Code by International Maritime Organization (IMO),
Dangerous Goods Regulations (DGR) by International Air Transport Association (IATA) and TechnicalInstructions for the Safe Transport of Dangerous Goods by Air (TI) by International Civil Aviation
Organization (ICAO). These regulations are based on the UN Recommendations on the Transport ofDangerous Goods, Manual of Tests and Criteria.
Lithium batteries which meet the requirements of UN38.3 (UN Manual of Tests and Criteria, Part Ⅲ,
subsection 38.3) could be transported by air and by sea as ordinary goods, otherwise should betransported according to Class 9, Packing Group Ⅱ hazardous goods.
For transported air, Lithium-metal Cells/Batteries must comply with Section IA or Section IB of PI968
accordingly.
Cells and batteries must be packed in inner packagings that completely enclose the cell or battery thenplaced in a strong outer packaging.
Each package must be capable of withstanding a 1.2 m drop test in any orientation without:-damage to cells or batteries contained therein;-shifting of the contents so as to allow battery to battery (or cell to cell) contact;-release of contents.
The goods are primary lithium batteries. Each package must be marked indicating that it contains
lithium batteries and that special procedures should be followed in the event that the package isdamaged. Each shipment must be accompanied with a document indicating that the packages containlithium batteries and that special procedures should be followed in the event a package is damaged.
UN No.

Proper Shipping Name/Description

3090

Lithium metal batteries

3091

Lithium metal batteries contained in equipment

EVE Energy Co., Ltd Safety and Reliability Lab

Lithium-Thionyl Chloride (Li-SOCl2) Battery 6/6
Document Number: RD-ER-202401-001
Issued date:05 December 2023
Effective date:06 Decembe 2023

3091

Lithium metal batteries packed with equipment

Related regulations: Following regulations shall be cited and considered.
Transportations

Related organization / Issue documents

Air transport(by airplane)

ICAO (International Civil Aviation Organization) / TI (Technical Instruction)
IATA (International Air Transport Association) / DGR (Dangerous GoodsRegulations)

Maritime transport(by ship)

IMO (International Maritime Organization) / IMDG Code (International Maritime
Dangerous Goods Code)Land transport(Intra-European)

RID (International Carriage of Dangerous Goods by Rail) , ADR (InternationalCarriage of Dangerous Goods by Road)

USA / UNUSDOT (US Department of Transportation) / DOT 49 CFR (US law)
UN: Recommendations on the transport of dangerous goods: Manual of Tests andCriteria: Part III, Subsection 38.3

15. Regulatory Information
Environment-related law of batteries: EU nations have applicable law in accordance withNew EU Battery Regulations (EU) 2023/1542 and other some countries, China, Korea, Brazil, someprovinces of USA and Canada or so have similar law.
16. Other informationReference⚫ IATA Dangerous Goods Regulations, 65th edition
This sheet refers to normal use of the product in question. EVE Corp. makes no warranty expressed orimplied.

EVE Energy Co., Ltd Safety and Reliability Lab