OLFINE PD-003
Safety Data Sheetaccording to JIS Z 7253 : 2019
Issue date: 10/21/2010

Revision date: 3/1/2024

Version: 3.4

1. Chemical product and company identification
Substance name:

OLFINE PD-003

Recommended use of the chemical and restrictions on use
Recommended use:

Additive

Restrictions on use:

General industrial use

Company information
Nissin Chemical Industry Co., Ltd.
101-0047 Japan
5-13，Uchikanda 1-chome，Chiyoda-ku，Tokyo，Japan
T +81-3-3295-3931 - F +81-3-3295-3929

2. Hazards identification
GHS classification
Physical hazards

Explosives

classification not possible

Flammable gases

No classification

Aerosolclassification not possible

Oxidizing gases

No classification

Gases under pressure

No classification

Flammable liquids

classification not possible

Flammable solids

No classification

Self-reactive substances andclassification not possible

mixtures
Pyrophoric liquids

classification not possible

Pyrophoric solids

No classification

Self-heating substances andclassification not possible

mixtures
Substances and mixtures whichclassification not possible

in contact with water emit
flammable gases

Health hazards

Oxidizing liquids

classification not possible

Oxidizing solids

No classification

Organic peroxides

classification not possible

Corrosive to metals

classification not possible

Desensitized explosives

classification not possible

Acute toxicity (oral)classification not possible

Acute toxicity (dermal)

classification not possible

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Acute toxicity (inhalation:gas)

No classification

Acute toxicity

No classification(inhalation:vapours)
Acute toxicity

classification not possible(inhalation:dust/mist)
Skin corrosion/irritation

Category 2

Serious eye damage/eyeCategory 1

irritation
Respiratory sensitization

classification not possible

Skin sensitization

Category 1

Germ cell mutagenicity

classification not possible

Carcinogenicity

classification not possible

Reproductive toxicity

classification not possible

Specific target organ toxicity

Category 1(single exposure)Specific target organ toxicity

Category 3 (Narcosis)(single exposure)Specific target organ toxicity

Category 1(repeated exposure)
Aspiration hazard

classification not possible

Environmental

Hazardous to the aquatic

Category 2

hazards

environment, short–term (acute)Hazardous to the aquatic

Category 2

environment, long–term(chronic)
Hazardous to the ozone layerclassification not possible

Hazardpictograms

GHS Signal word:

DangerHazard statements:

Causes skin irritation. (H315)
May cause an allergic skin reaction. (H317)
Causes serious eye damage. (H318)
May cause drowsiness or dizziness. (H336)
Causes damage to organs (H370)
Causes damage to organs through prolonged or repeated exposure(H372)

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Toxic to aquatic life with long lasting effects. (H411)
Precautionary statements
Prevention:

Do not breathe dust, fume, gas, mist, vapours, spray. (P260)
Wash hands, forearms and face thoroughly after handling. (P264)
Do not eat, drink or smoke when using this product. (P270)
Use only outdoors or in a well-ventilated area. (P271)
Contaminated work clothing should not be allowed out of theworkplace. (P272)
Avoid release to the environment. (P273)
Wear protective gloves, protective clothing, eye protection, faceprotection. (P280)

Response:

IF ON SKIN: Wash with plenty of soap and water. (P302+P352)
IF INHALED: Remove person to fresh air and keep comfortable forbreathing (P304+P340)
If in eyes: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
(P305+P351+P338)
IF exposed or concerned: Call a doctor. (P308+P311)
Immediately call a doctor. (P310)
Call a doctor if you feel unwell. (P312)
Get medical advice/attention if you feel unwell. (P314)
Specific treatment (P321)
If skin irritation or rash occurs: Get medical advice/attention.
(P333+P313)
Take off contaminated clothing and wash it before reuse.
(P362+P364)
Collect spillage. (P391)

Storage:

Store in a well-ventilated place. Keep container tightly closed.
(P403+P233)
Store locked up. (P405)

Disposal:

Dispose of contents/container in accordance withlocal/regional/national/international regulations. (P501)

3. Composition/information on ingredients
Distinction of substance or:

Mixture:Surfactant composition

mixtureGeneric name

Name

Surfactant A

Concentration
(%)
< 50

Reference number in thegazette list
CSCL No

ISHL No

Undisclosed

Undisclosed

CAS-No.

Undisclosed

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Surfactant B< 80

Undisclosed

Undisclosed

Undisclosed

1,2-Propanediol< 50(2)-234

Existing

57-55-6

ChemicalSubstance
Water

< 10

-

-

7732-18-5

4. First aid measures
First aid measures
First-aid measures general:If you feel unwell, seek medical advice (show the label where
possible). Move out of dangerous area.Take off contaminatedclothing and shoes immediately.Never give anything by mouth toan unconscious person.

First-aid measures after:

inhalation

Remove the sufferers to fresh air places immediately. If breathinghas stopped or is labored, give artificial respiration, and get
medical advices.

First-aid measures after skin:contact

Take off contaminated clothes, shoes and socks. And wash sticking
parts off with soap and plenty of water. If the external changes
are observed or the symptoms such as irritation or itchy appears,
get medical advices immediately.

First-aid measures after eye:

contact

Rinse immediately inner side of eyelid with plenty of water morethan 20 minutes. Remove the contact lenses if possible. Get
medical advices.
If eye irritation persists: Get medical advice/attention.

First-aid measures after:ingestion

Rinse mouth thoroughly with water and get medical attention
immediately.
Never give anything through mouth to a patient if he isunconscious. Turn a patient's head to the side for preventing
suffocation by vomit.

5. Fire fighting measures
Suitable extinguishing media:

Dry chemical, Fire foam, Carbon dioxide (CO2), Water mist.

Unsuitable extinguishing:Nothing in particularFire hazard:

Under fire conditions, hazardous fumes or gas may be present.

Hazardous decomposition:

The hazardous gasses such as carbon mono- and di-oxide andmedia
Fire hazard

products in case of fire

aldehyde group are generated at the Product’s combustion.

Firefighting instructions
Firefighting instructions:

Cut off ignition sources to a fire origin and fight a fire employing a

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suitable fire extinguishing agent.
Cool by water spray around the fire site to prevent the fire
extension.
Personal protection (Emergency response)
Personal protection (Emergency:

response)

As gasses such as carbon dioxide, carbon monoxide, smoke are
generated by high temperature at fire, wear a self-contained
breathing apparatus, etc.

Protection during firefighting:

In the event of fire, wear self-contained breathing apparatus. Use
personal protective equipment.

Other information:

Standard procedure for chemical fires. Use extinguishing measuresthat are appropriate to local circumstances and the surrounding
environment. In the event of fire and/or explosion do not breathe
fumes. Use water spray to cool unopened containers. Collectcontaminated fire extinguishing water separately. This must not
be discharged into drains. Fire residues and contaminated fire
extinguishing water must be disposed of in accordance with local
regulations.

6. Accidental release measures
Personal Precautions, Protective Equipment and Emergency Procedures
General measures:

Clear off ignition sources and work from windward.
Wear suitable protective goggles, boots, gloves, body suits toavoid contact with droplet, etc and inhalation of mist, gas, etc.

For emergency responders
Protective equipment:

Wear suitable protective tools such as goggles, boots, gloves,
body suits and a self-contained breathing apparatus according tocircumstances to avoid inhalation of and direct contact withmaterials in question.

Emergency procedures:

Clear off all of ignition sources immediately.
Work from windward.
Stop release.

Environmental precautions
Environmental precautions:

Take care that the released Products do not inflow into the watercourses nor dirty water flows out to the environment.

Methods and Equipment for Containment and Cleaning up
For containment:

Soak up with inert absorbent material (e.g. sand, silica gel, acidbinder, universal binder, sawdust).Keep in suitable, closed
containers for disposal.

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Methods for cleaning up:

When the releasing materials are small, cover with dry sand, dirt,
sawdust and/or the like, rake up with shovels or brooms andrecover into the containers being stoppled tightly.
When the releasing materials are large, vacuum and recover witha pump, etc.
Clean up the surroundings of the releasing area with water after
recovery and recover the contaminated water as well.

Prevention Measures for:

Secondary Accidents

Remove immediately all ignition source and prepare fire extinguishagents. Use safe tools which do not spark.

7. Handling and storage
Handling
Technical measures:

Emergency showers and eye wash stations should be readily
accessible.

Precautions for safe handling:

Comply with practice rules established by the Government.
As the Product has fear of precipitating or solidifying under low
temperature(not exceeding 15℃), the Product is applied after
warming, melting and stirring well in the case.

Prevents handling of:incompatible substances or

Wear suitable personal protecting tools, if there are dangers of
inhalation of vapor and mist or contact to skin or eye(s).

mixtures
Local and general ventilation:

Handle the Product at the area installing local exhaust orwhole
ventilation facilities.

Storage
Storage conditions:

Store with a tight stopper at cool and dark places.

Material used in:

Keep oil tins dry because oil tins

packaging/containers
Technical measures

may form rust by wet with water and so on.
:

Store the Product at a well ventilated place where is isolated fromthermal sources and strong oxidizers.

Incompatible materials:

Strong oxidizers (perchlorates, nitrates, peroxides). Reactive
metals. (sodium,calcium, zinc, etc.). Dehydrating agent.

8. Exposure controls / Personal protection equipment
OLFINE PD-003
Japan - Occupational Exposure Limits
Japan administration level

No data available

Exposure limits (JSOH)

No data available

Exposure limits (ACGIH)

No data available

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Appropriate engineering controls:

Install sufficient general ventilators and local exhaust equipments, Express
the place clearly where safety shower(s) and hand and eye washer(s) are
equipped.

Protective equipment
Materials for protective clothing: Use personal protective equipment against chemicals depending on
the concentration and quantity of the hazardous substance andspecific to place of work. For special applications, we recommend
clarifying the resistance to chemicals of the aforementioned
protective equipment with the manufacturer.

Respiratory protection: Use an air respirator at an emergency, It is needless under normal
conditions at well ventilated place.

Hand protection: Wear protective gloves.(Neoprene Nitrile rubber)

Eye protection: goggles style protective glasses

Skin and body protection: protective clothing, Choose appropriate protective clothes
according to the concentration of the dangerous substance and thework circumstance.

Environmental exposure: Do not flush into surface water or sanitary sewer system. Prevent

controls

further leakage or spillage if safe to do so. If the productcontaminates rivers and lakes or drains inform respective
authorities. Avoid release to the environment. Refer to special
instructions/ Safety data sheets.

9. Physical and chemical properties
Physical state:

LiquidColour:Colorless～Light yellow,clear

Odour

:

characteristic odor

pH:

No data available

Relative evaporation rate:

No data available

Melting point:

No data available

Freezing point:

No data available

Boiling point:

No data available

Flash point:

None (Cleveland open-cup test)

Auto-ignition temperature:

No data available

Decomposition temperature:

No data available

Flammability:

No data available

Vapour pressure:

No data available

Relative vapour density at:

No data available(butylacetate=1)

20°C

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OLFINE PD-003
Relative density:

0.99 – 1.03

Density:

No data available

Relative gas density:

No data available

Solubility:

No data available

Partition coefficient n-:

No data available

Explosive limits (vol %):No data available

Explosive limits (g/m³):

No data available

Viscosity, kinematic:

No data available

Minimum ignition energy:

No data available

Particle size:

No data available

octanol/water (Log Pow)

10. Stability and reactivity
Reactivity:

No data available

Chemical stability:

Prevent high temperature atmosphere, by which the degradation of
the product is accelerated.

Possibility of hazardous:

reactions

In case of mix and contact with strong oxidizer, it may cause
hazards such as fire or explosion.

Conditions to avoid:

Heat. Fire

Incompatible materials:

Reactive metals. (sodium,calcium, zinc, etc.). Strong oxidizer(perchlorates, nitrates, peroxides etc.). Peroxides. Dehydrating
agents. Materials reacted with hydroxyl compounds.

Hazardous decomposition:

products

The hazardous gasses such as carbon mono- and di-oxide andaldehyde group are generated at the Product’s combustion. Heating
above 65 C in the presence of strong base can produce flammablehydrocarbon residue.

11. Toxicological information
Acute toxicity (oral):(as a product)

No data available

Acute toxicity (dermal):(as a product)

No data available

Acute toxicity (gas) -:(as a product)

No data available:(as a product)

No data available:(as a product)

No data available:(as a product)

No data available

Description
Acute toxicity (vapour) Description
Acute toxicity (dust, mist) –Description
Acute toxicity (mist) Description

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Skin corrosion/irritation:(as a product)

There are no available data about this product.
There contain hazardous to skin materials
belonging to the following Category.Category
2: Suafactant B (<80%). Concentration limitsof Category 2 is ≧10%. So,this product iscorrespond to Skin corrosion/irritation
Category 2 of GHS.

Serious eye damage/irritation: (as a product)

There are no available data about this product.
There contain eye irritating materials
belonging to the following Category. Category
1: Surfactant A (＜50 %) Surfactant B (＜80%)

Concentration limits of Category 1 is ≧3%. So,this product is correspond to Serius
eye damage /eye irritation Category 1 of GHS.
Respiratory sensitization:(as a product)

No data available

Skin sensitization:(as a product)

There are no available data about this product.
But, there contain Skin Sensitizer materials
belonging to the following
Category.Category1 :Surfactant A (＜50%)
Concentration limits of Category 1 is ≧1.0%
So, this product is correspond to Skin
Sensitizer Category 1 of GHS.

Germ cell mutagenicity:(as a product)

No data available

Carcinogenicity:(as a product)

No data available

Reproductive toxicity:(as a product)

No data available

STOT-single exposure:(as a product)

There are no available data about this product.
There contain Specific target organ toxicity(single exposure) materials belonging to thefollowing Category. Category 1 and Category
3: Propylene glycol(<50%) Concentration
limits of Category 1 is ≥10%. So, this productis correspond to Specific target organ toxicity(single exposure) Category 1 and Category 3.

STOT-repeated exposure:(as a product)

There are no available data about this product.
There contain Specific target organ toxicity(repeated exposure) materials belonging to thefollowing Category. Category 1: Propylene
glycol(<50%) Concentration limits of Category
1 is ≥10%. So, this product is correspond toSpecific target organ toxicity (repeatedexposure) Category 1.

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Aspiration hazard:(as a product)

No data available

12. Ecological information
Ecotoxicity
Ecotoxicity: (as a product)

No data available

Hazardous to the aquatic: (as a product)

There are no available data about thisenvironment, short–term

product. There contain Hazardous to the(acute)aquatic environment (acute) materials
belonging to the following
Category.Category 2: Surfactant B(＜80%).
Category 3: Surfactant A(＜
50 %).Concentration limits of Category 2 is≧25%. So,this product is correspond to
Hazardous to the aquatic environment(acute) Category 2 of GHS.

Hazardous to the aquatic: (as a product)

There are no available data about thisenvironment, long–term

product. There contain Hazardous to the(chronic)

aquatic environment (chronic) materials
belonging to the following
Category.Category 2: Surfactant B(＜
80%). Category 3: Surfactant A(＜50%).
Concentration limits of Category 2 is ≧25%.
So,this product is correspond to Hazardous
to the aquatic environment (chronic)
Category 2 of GHS.

Other information: It should not be allowed for the product to be run into drains,water courses or the soil.

Persistence and degradability
Persistence and degradability:(as a product)

No data available

Biochemical oxygen demand:(as a product)

No data available:(as a product)

No data available

Bioaccumulative potential:(as a product)

No data available

Partition coefficient n-:(as a product)

No data available(BOD)
Chemical oxygen demand(COD)
Bioaccumulative potential

octanol/water (Log Pow)

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Mobility in soil
Mobility in soil:

(as a product)

No data available

Partition coefficient n-:(as a product)

No data available:(as a product)

No data available

Ozone

:

(as a product)

No data available

Other adverse effects:

No additional information available

octanol/water (Log Pow)
Ecology - soil
Hazardous to the ozone layer

13. Disposal considerations
Ecological information:

Farm out to professional disposal treating traders incompliance with requirements of the nation and local
governments.

Contaminated container and:Farm out disposal of the contents and packaging materials to
professional disposal treating traders in compliance withpackagingrequirements of the nation and local governments.
In case of disposal of empty container, dispose after complete
removal in the container.

14. Transport information
International Regulations
Transport by sea(IMDG)
UN-No. (IMDG):

Proper Shipping Name (IMDG)

3082
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.

Packing group (IMDG):

III

Transport hazard class(es)

:

9

:

9

(IMDG)
Danger labels (IMDG):Class (IMDG):

9Special provisions (IMDG):

274, 335, 969

Limited quantities (IMDG):

5L

Excepted quantities (IMDG):

E1

Packing instructions (IMDG):

LP01, P001

Special packing provisions

:

PP1

:

IBC03

:

T4

(IMDG)
IBC packing instructions(IMDG)
Tank instructions (IMDG)

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OLFINE PD-003
Tank special provisions (IMDG):

TP1, TP29

Stowage category (IMDG):

A

MFAG-No:

171

Air transport(IATA)
UN-No. (IATA): 3082

Proper Shipping Name (IATA): Environmentally hazardous substance, liquid, n.o.s.

Packing group (IATA): III

Transport hazard class(es): 9(IATA)
Danger labels (IATA): 9Class (IATA): 9

PCA Excepted quantities (IATA): E1

PCA Limited quantities (IATA): Y964

PCA limited quantity max net: 30kgG

quantity (IATA)
PCA packing instructions (IATA): 964

PCA max net quantity (IATA): 450LCAO packing instructions (IATA): 964

CAO max net quantity (IATA): 450LSpecial provisions (IATA): A97, A158, A197

ERG code (IATA): 9L

Regulations in Japan
Regulatory information by sea:

Conform to the provisions of the Ship Safety Law.

Regulatory information by air:

Conform to the provisions of the Civil Aeronautics Law.

MFAG-No:

171

Other information:

At transportation, make sure of no leakage of packings, load
the products without broken bags, falling, injury, etc, andprevent load
collapses surely.

15. Regulatory information
REACH SVHC:No SVHC substances exceeding the threshold level arecontained.

16. Other information
Data sources:

Ref. 1.“Safety Data Sheet” by Raw Material Manufacturers.
2.GHS Sixth Revised Edition. 3.NITE GHS Results of the

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Classification.
Other information:

The Products was developed for general industries’ use. When
applying to specific uses, it is hoped to confirm its safety by
yourselves prior to the use. The description of this SDS isbased upon materials, information and data which can beprocured at present. However, we do not warrant any
guarantee regarding the contents, physical and chemical
properties, hazards and the like.

DISCLAIMER OF LIABILITY The information in this SDS was obtained from sources which we believe
are reliable. However, the information is provided without any warranty, express or implied, regarding
its correctness. The conditions or methods of handling, storage, use or disposal of the product are
beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume
responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way
connected with the handling, storage, use or disposal of the product. This SDS was prepared and is to
be used only for this product. If the product is used as a component in another product, this SDS
information may not be applicable

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