Product Name: PERKINS DEO-ULS 15W-40
Revision Date: 14 Oct 2016
Page 1 of 10______________________________________________________________________________________________________________________SAFETY DATA SHEETSECTION 1

PRODUCT AND COMPANY IDENTIFICATIONPRODUCT
Product Name: PERKINS DEO-ULS 15W-40
Product Description: Base Oil and Additives
Product Code: 202020400820
Intended Use: Diesel engine oil

COMPANY IDENTIFICATION
Supplier:

EXXON MOBIL CORPORATION
22777 Springwoods Village Parkway
Spring, TX 77253 USA
24 Hour Health Emergency609-737-4411
Transportation Emergency Phone
800-424-9300 or 703-527-3887 CHEMTREC
Product Technical Information
800-662-4525
MSDS Internet Addresswww.exxon.com, www.mobil.com

SECTION 2

HAZARDS IDENTIFICATIONThis material is not hazardous according to regulatory guidelines (see (M)SDS Section 15).

Other hazard information:

HAZARD NOT OTHERWISE CLASSIFIED (HNOC): None as defined under 29 CFR 1910.1200.
PHYSICAL / CHEMICAL HAZARDSNo significant hazards.
HEALTH HAZARDS
High-pressure injection under skin may cause serious damage. Excessive exposure may result in eye, skin, or
respiratory irritation.
ENVIRONMENTAL HAZARDSNo significant hazards.

NFPA Hazard ID:
HMIS Hazard ID:

Health:Health:00Flammability: 1
Flammability: 1

Reactivity: 0
Reactivity: 0

NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert
advice. Health studies have shown that chemical exposure may cause potential human health risks which may varyfrom person to person.

Product Name: PERKINS DEO-ULS 15W-40
Revision Date: 14 Oct 2016
Page 2 of 10______________________________________________________________________________________________________________________SECTION 3

COMPOSITION / INFORMATION ON INGREDIENTSThis material is defined as a mixture.
Hazardous Substance(s) or Complex Substance(s) required for disclosure
Name
ALKYL PHENOL
C14-16-18 ALKYL PHENOLZINC ALKYL DITHIOPHOSPHATE

CAS#
125643-61-0
CONFIDENTIA
L
113706-15-3

Concentration*
1 - < 5%
0.1 - < 1%

GHS Hazard Codes
H413
H317

0.1 - < 1%

H303, H315, H318,
H401, H411

* All concentrations are percent by weight unless material is a gas. Gas concentrations are in percent by volume.
As per paragraph (i) of 29 CFR 1910.1200, formulation is considered a trade secret and specific chemical identity andexact percentage (concentration) of composition may have been withheld. Specific chemical identity and exact
percentage composition will be provided to health professionals, employees, or designated representatives inaccordance with applicable provisions of paragraph (i).
SECTION 4

FIRST AID MEASURESINHALATION
Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use
adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek
immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use
mouth-to-mouth resuscitation.
SKIN CONTACT
Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of thebody, regardless of the appearance of the wound or its size, the individual should be evaluated immediately bya physician as a surgical emergency. Even though initial symptoms from high pressure injection may beminimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent
of injury.
EYE CONTACT
Flush thoroughly with water. If irritation occurs, get medical assistance.
INGESTIONFirst aid is normally not required. Seek medical attention if discomfort occurs.

SECTION 5

FIRE FIGHTING MEASURES

EXTINGUISHING MEDIA
Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguishflames.
Inappropriate Extinguishing Media: Straight Streams of Water

Product Name: PERKINS DEO-ULS 15W-40
Revision Date: 14 Oct 2016
Page 3 of 10______________________________________________________________________________________________________________________FIRE FIGHTING
Fire Fighting Instructions: Evacuate area. Prevent runoff from fire control or dilution from entering streams,
sewers, or drinking water supply. Firefighters should use standard protective equipment and in enclosed
spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and toprotect personnel.
Hazardous Combustion Products: Aldehydes, Incomplete combustion products, Oxides of carbon, Smoke,
Fume, Sulfur oxides
FLAMMABILITY PROPERTIES
Flash Point [Method]: >215°C (419°F) [ASTM D-92]
Flammable Limits (Approximate volume % in air): LEL: 0.9
Autoignition Temperature: N/D
SECTION 6

UEL: 7.0

ACCIDENTAL RELEASE MEASURESNOTIFICATION PROCEDURES
In the event of a spill or accidental release, notify relevant authorities in accordance with all applicableregulations. US regulations require reporting releases of this material to the environment which exceed theapplicable reportable quantity or oil spills which could reach any waterway including intermittent dry creeks. The
National Response Center can be reached at (800)424-8802.
PROTECTIVE MEASURES
Avoid contact with spilled material. See Section 5 for fire fighting information. See the Hazard Identification
Section for Significant Hazards. See Section 4 for First Aid Advice. See Section 8 for advice on the minimum
requirements for personal protective equipment. Additional protective measures may be necessary, dependingon the specific circumstances and/or the expert judgment of the emergency responders.
For emergency responders: Respiratory protection: respiratory protection will be necessary only in special
cases, e.g., formation of mists. Half-face or full-face respirator with filter(s) for dust/organic vapor or Self
Contained Breathing Apparatus (SCBA) can be used depending on the size of spill and potential level of
exposure. If the exposure cannot be completely characterized or an oxygen deficient atmosphere is possible oranticipated, SCBA is recommended. Work gloves that are resistant to hydrocarbons are recommended.
Gloves made of polyvinyl acetate (PVA) are not water-resistant and are not suitable for emergency use.
Chemical goggles are recommended if splashes or contact with eyes is possible. Small spills: normal antistatic
work clothes are usually adequate. Large spills: full body suit of chemical resistant, antistatic material isrecommended.
SPILL MANAGEMENTLand Spill: Stop leak if you can do it without risk. Recover by pumping or with suitable absorbent.
Water Spill: Stop leak if you can do it without risk. Confine the spill immediately with booms. Warn othershipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist
before using dispersants.
Water spill and land spill recommendations are based on the most likely spill scenario for this material;
however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction
and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be
consulted. Note: Local regulations may prescribe or limit action to be taken.
ENVIRONMENTAL PRECAUTIONSProduct Name: PERKINS DEO-ULS 15W-40
Revision Date: 14 Oct 2016
Page 4 of 10______________________________________________________________________________________________________________________

Large Spills: Dike far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways,
sewers, basements or confined areas.

SECTION 7

HANDLING AND STORAGE

HANDLING
Avoid contact with used product. Prevent small spills and leakage to avoid slip hazard. Material can accumulate
static charges which may cause an electrical spark (ignition source). When the material is handled in bulk, anelectrical spark could ignite any flammable vapors from liquids or residues that may be present (e.g., duringswitch-loading operations). Use proper bonding and/or ground procedures. However, bonding and grounds
may not eliminate the hazard from static accumulation. Consult local applicable standards for guidance.
Additional references include American Petroleum Institute 2003 (Protection Against Ignitions Arising out of
Static, Lightning and Stray Currents) or National Fire Protection Agency 77 (Recommended Practice on Static
Electricity) or CENELEC CLC/TR 50404 (Electrostatics - Code of practice for the avoidance of hazards due tostatic electricity).
Static Accumulator: This material is a static accumulator.
STORAGE
The type of container used to store the material may affect static accumulation and dissipation. Do not store inopen or unlabelled containers.
SECTION 8

EXPOSURE CONTROLS / PERSONAL PROTECTION

Exposure limits/standards for materials that can be formed when handling this product: When mists/aerosols
can occur the following are recommended: 5 mg/m³ - ACGIH TLV (inhalable fraction), 5 mg/m³ - OSHA PEL.
NOTE: Limits/standards shown for guidance only. Follow applicable regulations.
No biological limits allocated.

ENGINEERING CONTROLSThe level of protection and types of controls necessary will vary depending upon potential exposure conditions.
Control measures to consider:
No special requirements under ordinary conditions of use and with adequate ventilation.
PERSONAL PROTECTION
Personal protective equipment selections vary based on potential exposure conditions such as applications,handling practices, concentration and ventilation. Information on the selection of protective equipment for use
with this material, as provided below, is based upon intended, normal usage.
Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at alevel which is adequate to protect worker health, an approved respirator may be appropriate. Respirator
selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types ofProduct Name: PERKINS DEO-ULS 15W-40
Revision Date: 14 Oct 2016
Page 5 of 10______________________________________________________________________________________________________________________

respirators to be considered for this material include:
No special requirements under ordinary conditions of use and with adequate ventilation.
For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode.
Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate,
gas/vapor warning properties are poor, or if air purifying filter capacity/rating may be exceeded.
Hand Protection: Any specific glove information provided is based on published literature and glove
manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions.
Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use
conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material
include:No protection is ordinarily required under normal conditions of use.
Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or
manufacturer data. The types of clothing to be considered for this material include:
No skin protection is ordinarily required under normal conditions of use. In accordance with goodindustrial hygiene practices, precautions should be taken to avoid skin contact.
Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after
handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned.
Practice good housekeeping.
ENVIRONMENTAL CONTROLS
Comply with applicable environmental regulations limiting discharge to air, water andsoil. Protect the environment by applying appropriate control measures to prevent or limit
emissions.
SECTION 9

PHYSICAL AND CHEMICAL PROPERTIES

Note: Physical and chemical properties are provided for safety, health and environmental considerations only
and may not fully represent product specifications. Contact the Supplier for additional information.
GENERAL INFORMATION
Physical State: Liquid
Color: Brown
Odor: Characteristic
Odor Threshold: N/D
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION
Relative Density (at 15 °C): 0.867
Flammability (Solid, Gas): N/A
Flash Point [Method]: >215°C (419°F) [ASTM D-92]
Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0
Autoignition Temperature: N/D
Boiling Point / Range: > 316°C (600°F)
Decomposition Temperature: N/D
Vapor Density (Air = 1): N/D
Vapor Pressure: < 0.013 kPa (0.1 mm Hg) at 20 °C

Product Name: PERKINS DEO-ULS 15W-40
Revision Date: 14 Oct 2016
Page 6 of 10______________________________________________________________________________________________________________________

Evaporation Rate (n-butyl acetate = 1): N/D
pH: N/A
Log Pow (n-Octanol/Water Partition Coefficient): > 3.5
Solubility in Water: Negligible
Viscosity: 109 cSt (109 mm2/sec) at 40 °C | 14.1 cSt (14.1 mm2/sec) at 100°C
Oxidizing Properties: See Hazards Identification Section.
OTHER INFORMATION
Freezing Point: N/D
Melting Point: N/A
Pour Point:-27°C (-17°F)
DMSO Extract (mineral oil only), IP-346:

SECTION 10< 3 %wt

STABILITY AND REACTIVITY

REACTIVITY: See sub-sections below.
STABILITY: Material is stable under normal conditions.
CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition.
MATERIALS TO AVOID: Strong oxidizers
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures.
POSSIBILITY OF HAZARDOUS REACTIONS: Hazardous polymerization will not occur.
SECTION 11

TOXICOLOGICAL INFORMATIONINFORMATION ON TOXICOLOGICAL EFFECTS
Hazard Class

Conclusion / Remarks

Inhalation
Acute Toxicity: No end point data formaterial.
Irritation: No end point data for material.
Ingestion

Minimally Toxic. Based on assessment of the components.

Acute Toxicity: No end point data formaterial.
Skin

Minimally Toxic. Based on assessment of the components.

Acute Toxicity: No end point data formaterial.
Skin Corrosion/Irritation: No end point data
for material.
Eye

Minimally Toxic. Based on assessment of the components.

Serious Eye Damage/Irritation: No end point
data for material.
Sensitization

May cause mild, short-lasting discomfort to eyes. Based on
assessment of the components.

Respiratory Sensitization: No end point data
for material.
Skin Sensitization: No end point data for

Not expected to be a respiratory sensitizer.

Negligible hazard at ambient/normal handling temperatures.

Negligible irritation to skin at ambient temperatures. Based on
assessment of the components.

Not expected to be a skin sensitizer. Based on assessment of theProduct Name: PERKINS DEO-ULS 15W-40
Revision Date: 14 Oct 2016
Page 7 of 10______________________________________________________________________________________________________________________

material.
Aspiration: Data available.
Germ Cell Mutagenicity: No end point data
for material.
Carcinogenicity: No end point data formaterial.
Reproductive Toxicity: No end point data
for material.
Lactation: No end point data for material.
Specific Target Organ Toxicity (STOT)
Single Exposure: No end point data formaterial.
Repeated Exposure: No end point data formaterial.

components.
Not expected to be an aspiration hazard. Based on physicochemical properties of the material.
Not expected to be a germ cell mutagen. Based on assessment of
the components.
Not expected to cause cancer. Based on assessment of thecomponents.
Not expected to be a reproductive toxicant. Based on assessmentof the components.
Not expected to cause harm to breast-fed children.
Not expected to cause organ damage from a single exposure.
Not expected to cause organ damage from prolonged or repeatedexposure. Based on assessment of the components.

OTHER INFORMATION
For the product itself:
Component concentrations in this formulation would not be expected to cause skin sensitization, based on tests of thecomponents or similar formulations.
Diesel engine oils: Not carcinogenic in animals tests. Used and unused diesel engine oils did not produce any
carcinogenic effects in chronic mouse skin painting studies.
Oils that are used in gasoline engines may become hazardous and display the following properties: Carcinogenic inanimal tests. Caused mutations in vitro. Possible allergen and photoallergen. Contains polycyclic aromatic compounds(PAC) from combustion products of gasoline and/or thermal degradation products.
Contains:
Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames
test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of
immune cells, oil deposition and minimal granuloma formation. Not sensitizing in test animals.

The following ingredients are cited on the lists below: None.

1 = NTP CARC
2 = NTP SUSSECTION 12--REGULATORY LISTS SEARCHED-3 = IARC 1
5 = IARC 2B
4 = IARC 2A
6 = OSHA CARCECOLOGICAL INFORMATION

The information given is based on data available for the material, the components of the material, and similar materials.
ECOTOXICITY
Material -- Not expected to be harmful to aquatic organisms.
MOBILITY
Base oil component -- Low solubility and floats and is expected to migrate from water to the land. Expected toProduct Name: PERKINS DEO-ULS 15W-40
Revision Date: 14 Oct 2016
Page 8 of 10______________________________________________________________________________________________________________________

partition to sediment and wastewater solids.
PERSISTENCE AND DEGRADABILITY
Biodegradation:
Base oil component -- Expected to be inherently biodegradable
BIOACCUMULATION POTENTIAL
Base oil component -- Has the potential to bioaccumulate, however metabolism or physical properties may
reduce the bioconcentration or limit bioavailability.

SECTION 13

DISPOSAL CONSIDERATIONS

Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicablelaws and regulations, and material characteristics at time of disposal.

DISPOSAL RECOMMENDATIONS
Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised
incineration at very high temperatures to prevent formation of undesirable combustion products.
REGULATORY DISPOSAL INFORMATIONRCRA Information: The unused product, in our opinion, is not specifically listed by the EPA as a hazardous
waste (40 CFR, Part 261D), nor is it formulated to contain materials which are listed as hazardous wastes. It
does not exhibit the hazardous characteristics of ignitability, corrositivity or reactivity and is not formulated withcontaminants as determined by the Toxicity Characteristic Leaching Procedure (TCLP). However, used productmay be regulated.
Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue andcan be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should becompletely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken
for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance withgovernmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE
SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION.
THEY MAY EXPLODE AND CAUSE INJURY OR DEATH.
SECTION 14

TRANSPORT INFORMATIONLAND (DOT): Not Regulated for Land Transport
LAND (TDG): Not Regulated for Land Transport
SEA (IMDG): Not Regulated for Sea Transport according to IMDG-CodeMarine Pollutant: No

Product Name: PERKINS DEO-ULS 15W-40
Revision Date: 14 Oct 2016
Page 9 of 10______________________________________________________________________________________________________________________AIR (IATA): Not Regulated for Air Transport
SECTION 15

REGULATORY INFORMATIONOSHA HAZARD COMMUNICATION STANDARD: This material is not considered hazardous in accordance with
OSHA HazCom 2012, 29 CFR 1910.1200.
Listed or exempt from listing/notification on the following chemical inventories: AICS, DSL, IECSC, PICCS,
TSCA
Special Cases:
Inventory
KECI
TCSI

StatusRestrictions Apply
Restrictions Apply

SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302

SARA (311/312) REPORTABLE HAZARD CATEGORIES: None.
SARA (313) TOXIC RELEASE INVENTORY: This material contains no chemicals subject to the supplier notification
requirements of the SARA 313 Toxic Release Program.

The following ingredients are cited on the lists below:
Chemical Name
MAGNESIUM LONG CHAIN
ALKARYL SULFONATE
ZINC ALKYLDITHIOPHOSPHATE

1 = ACGIH ALL
2 = ACGIH A1
3 = ACGIH A2
4 = OSHA Z
5 = TSCA 4CAS Number

List Citations
6113706-15-3

15--REGULATORY LISTS SEARCHED-6 = TSCA 5a2
11 = CA P65 REPRO
7 = TSCA 5e
12 = CA RTK
8 = TSCA 6
13 = IL RTK
9 = TSCA 12b
14 = LA RTK
10 = CA P65 CARC
15 = MI 293

Code key: CARC=Carcinogen; REPRO=Reproductive
SECTION 16

OTHER INFORMATION

N/D = Not determined, N/A = Not applicable

16 = MN RTK
17 = NJ RTK
18 = PA RTK
19 = RI RTKProduct Name: PERKINS DEO-ULS 15W-40
Revision Date: 14 Oct 2016
Page 10 of 10______________________________________________________________________________________________________________________KEY TO THE H-CODES CONTAINED IN SECTION 3 OF THIS DOCUMENT (for information only):
H303: May be harmful if swallowed; Acute Tox Oral, Cat 5
H315: Causes skin irritation; Skin Corr/Irritation, Cat 2
H317: May cause allergic skin reaction; Skin Sensitization, Cat 1
H318: Causes serious eye damage; Serious Eye Damage/Irr, Cat 1
H401: Toxic to aquatic life; Acute Env Tox, Cat 2
H411: Toxic to aquatic life with long lasting effects; Chronic Env Tox, Cat 2
H413: May cause long lasting harmful effects to aquatic life; Chronic Env Tox, Cat 4

THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS:
Section 01: Product Intended Use information was modified.
Section 15: Inventory - Header information was added.
Section 15: National Chemical Inventory Listing information was modified.
Section 15: Special Cases - Header information was added.
Section 15: Special Cases Table information was added.
Section 15: Status - Header information was added.
----------------------------------------------------------------------------------------------------------------------------------------------------The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate
and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current
available from ExxonMobil. The information and recommendations are offered for the user's consideration andexamination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer
repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is
included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided tohandlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, republication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used forconvenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any
affiliates in which they directly or indirectly hold any interest.
----------------------------------------------------------------------------------------------------------------------------------------------------Internal Use Only
MHC: 0B, 0B, 0, 0, 0, 0

PPEC: A

DGN: 7164358XUS (1024931)----------------------------------------------------------------------------------------------------------------------------------------------------Copyright 2002 Exxon Mobil Corporation, All rights reserved