Producing Incompatible Functional Materials by fusing High Molecules
and Inorganic Nanoparticles-- The development of super-hybrid materials -A project team led by Professor Tadafumi Adschiri at WPI Advanced Institute forMaterials Research (WPI-AIMR), Institute of Multidisciplinary

Research for

Advanced Materials, and New Industry Creation Hatchery Center, Tohoku University,
has developed a technology of interface control on the molecular or nano level between
polymers and nanoparticles. The new technology helps develop incompatible functions
at the same time, such as processability of polymers, and properties of inorganic
materials including a high refractive index and high thermal conductivity. The project
has been conducted with the aid of New Energy and Industrial Technology
Development Organization (NEDO.)
Super-hybrid materials are incompatible functional materials that maintain anddevelop both properties of high molecules and ceramics. Polymers have processability,transparency, and flexibility. Ceramics have various properties including a refractiveindex, high-thermal conductivity, a high dielectric constant, ultraviolet and infrared ray
absorption, fluorescence, and an electromagnetic property. When polymers andceramics mix, the mixture usually loses processability and transparency just as clay. It
has seemed to be impossible to maintain and develop each property at the same time.
Polymers and ceramics are like oil and water. They cannot mix at the nano size or on
the molecular level although it is possible at the micrometer size. Each interface has aneffect on the overall function, which deteriorates each property. A key to a solution tobring out each property is a technology to control interface between polymers andinorganic nanoparticles.
The group led by Professor Adschiri has developed a technology to synthesis
organic-inorganic hybrid nanoparticles to whose surface organic molecules bind. The
group has focused on that organic molecules and inorganic molecules form uniform
phase, and that water molecules serve as catalyst in supercritical water as a reaction
field. The newly synthesized hybrid manoparticles are a key to the production ofsuper-hybrid materials because they have organic molecules on the surface to bedispersed in high concentrations into organic solvent or polymers. The new technology
has been developing in collaboration with Japan Chemical Innovation Institute（JCII,）
and continuous synthesis at 0,1 t/year has been successful.

The JCII team has achieved high thermal conductivity while maintaining formability
by using the above technology. The new technology synthesizes organically-modified
boron nitride nanoparticles and alumina nanoparticles, and disperses them in highconcentration in resin. A size of power device and semiconductor material has beensmaller, and those power output has been increasing. Heat value per unit volume has
also been increasing significantly, and to promote heat release performance is an
important function of devices. The new technology has been developed to help highthermal conductivity by high filling, and particle array by shearing. The team has
succeeded in improving thermal conductivity to 35W/m/K at a maximum from several
W/m/K and in maintaining 300℃

heat resistance. The new technology is expected tocontribute to application to power generator, electric vehicle, and hybrid vehicle, and toreducing emissions of CO2.
The JCII team has also developed hybrid materials that maintain processability andflexibility of high molecules while dispersing titania and zirconia with a high refractive
index in high concentrations into high molecules. The newly developed materials also
maintain transparency while developing a high refractive index. The project team hasdeveloped two-stage polymerization method that is Tohoku University’s originaltechnology, and produced compatible inorganic monomers, which brought about highrefractive index of 1.7 and more than 90% of light transparence.
Ten chemical companies involved in the project has started to develop high thermal
conductivity film materials and high refractive index materials for application. They
have tried to further develop a technology to scale up a process of supercritical synthesis.
The new technology can be a new industrial infrastructure, and expected to be applied
to various fields including flexible antireflection film, highly processable lens materials,LED sealant, and optical memory materials.
The above technology has been presented at SuperGreen 2009, an international
conference organized by Professor Tadafumi Adschiri, at Sakura Hall on Katahira
campus, Tohoku University through October 15 to October 17, 2009.

[Contact]
Professor Tadafumi Adschiri
WPI Advanced Institute for Materials Research (WPI-AIMR,) Tohoku University
Tel: +81-22-217-5629
E-mail: ajiri@tagen.tohoku.ac.jp