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GUARDIAN JOINT SEALANTPRODUCT NAME: GUARDIAN JOINT SEALANTPRODUCT CODE: GU-JOINT-02 & GU-JOINT-05==================SECTION 1-D A T A

S H E E T

HMIS CODES: H F R P
2 0 0 IMANUFACTURER IDENTIFICATION=================

MANUFACTURER'S NAME: UNITED COATING MANUFACTURING COADDRESS: 19011 EAST CATALDO ROAD
GREENACRES, WASHINGTON 99016-9423
INITIAL(FIRST CALL)CHEMTREC(800)424-9300
EMERGENCY PHONE: BACK-UP(800)541-4383DATE PRINTED: 4/15/03
DATE REVISED: APRIL 2003
INFORMATION PHONE : (509) 926-7143==========SECTION 2-HAZARDOUS INGREDIENTS/SARA III INFORMATION=========WEIGHTREPORTABLE COMPONENTS
CAS NUMBER MM HG @ TEMPPERCENT-------------------------------------------------------------------------------ACRYLIC POLYMERMIXTURE
1768F-20C
54
AQUA AMMONIA CAS#1336-21-6, .1%MAX. OSHA STEL 35PPM AS AMMONIA, ACGIH TWA 25PPM AS AMMONIA, STEL 35PPM AS AMMONIA. NO OTHER EXPOSURE LIMITS HAVE BEENESTABLISHED.
CALCIUM CARBONATE471-34-1
N/A N/A26
OSHA PEL-15MG/M3, TOTAL DUST, 5MG/M3, RESPIRABLE DUST.
ACGIH TLV-10 MG/M3, TOTAL DUST CONTAINING NO ASBESTOS AND <1% FREE SILICA.
IF SILICA LEVELS ABOVE 1.0% ARE PRESENT, THE TLV VALUE IS O.1 MG OFRESPIRABLE SILICA PER CU. METER FOR BOTH OSHA PEL AND ACGIH TLV.
WATER
7732-18-5 NO DATANO DATA
5NO OEL'S ESTABLISHED.
CALCIUM CARBONATE1317-65-3 N/A N/A4OSHA PEL - 15 MG/M3 TOTAL DUST, 5 MG/M3 RESPIRABLE DUST.
ACGIH TLV - 10 MG/M3 TOTAL DUST CONTAINING NO ASBESTOS & <1.0% FREE SILICA.
IF SILICA LEVELS ABOVE 1.0% ARE PRESENT, THE TLV VALUE IS 0.1 MG OFRESPIRABLE SILICA PER CU. METER FOR BOTH OSHA PEL AND ACGIH TLV.
ISOBUTANE(ENCAPSULATED IN POLYMER)
75-28-5
N/A N/A
4CALCIUM CARBONATE WITH CRYSTALLINE SILICA<0.1% TLV IS 3MG/M3.
TITANIUM DIOXIDE13463-67-7 N/A N/A2TITANIUM DIOXIDE, 86-97%, CAS#13463-67-7, ACGIH TLV-10MG/M3, TOTAL DUSTTWA, OSHA PEL-15MG/M3, TOTAL DUST, 8 HR TWA, AEL(ACCEPTABLE EXPOSURE LIMIT)
OF 10MG/M3, TOTAL DUST 8 HR TWA, 5MG/M3 RESPIRABLE DUST 8 HR TWA. (AEL IS
THE EXPOSURE LIMIT RECOMMENDED BY THE MANUFACTURER OF THIS CHEMICAL).
ALUMINUM HYDROXIDE, CAS#21645-51-2, 1-5%, NO EXPOSURE LIMITS ESTABLISHED.
PETROLEUM DERIVATIVESMIXTURE<0.0168F/20C
2SOLVENT REFINED HEAVY PARAFFINIC DISTILLATE; CAS# 64741-88-4, OSHA/ACGIH TW
A: 5MG/M3(AS OIL MIST), ACGIH STEL: 10MG/M3(AS OIL MIST). SOLVENT REFINED /DEWAXED HEAVY PARAFFINIC DISTILLATE; CAS# 6472-65-0, OSHA/ACGIH TWA: 5MG/M3(AS OIL MIST), ACGIH STEL: 10MG/M3(AS OIL MIST). THE SUM OF THE TWO COMPONENTS 80-90%.
*** No toxic chemical(s) subject to the reporting requirements of section 313 ofTitle III and of 40 CFR 372 are present. ***THIS MSDS MAY BE USED FOR OTHER COLORS AND CONTAINER SIZES OF THIS PRODUCT.
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GUARDIAN JOINT SEALANT================SECTION 3 HAZARDS IDENTIFICATAION====================POTENTIAL HEALTH EFFECTSEYES:CONTACT MAY RESULT IN IRRITATION
SKIN:SUBSTANCE MAY CAUSE SLIGHT SKIN IRRITATIONINGESTION:SINGLE DOSE ORAL TOXICITY IS LOW. MAY CAUSE IRRITATION.
INHALATION:VAPOR OR SPRAY MIST CAN CAUSE HEADACHE, NAUSEA AND IRRITATION OF THE NOSE,
THROAT AND LUNGS.
==============SECTION 4 FIRST AID MEASURES=====================================
EYES:IMMEDIATELY FLUSH EYES WITH CLEAN, LUKEWARM WATER FOR 15 MINUTES WHILE LIFTINGEYELIDS. REFER TO PHYSICIAN OR OPHTHALMOLOGIST FOR IMMEDIATE FOLLOW-UP.
SKIN:IMMEDIATELY WASH SKIN WITH LOTS OF SOAP AND WATER. REMOVECONTAMINATED CLOTHING AND SHOES AND WASH BEFORE REUSE. GET MEDICAL ATTENTION IF
IRRITATION PERSISTS.
INGESTION:IF SWALLOWED, DO NOT INDUCE VOMITING. DILUTE WITH WATER. NEVER GIVE ANYTHING BYMOUTH TO AN UNCONSCIOUS PERSON.CONSULT A PHYSICIAN.
INHALATION:REMOVE FROM SOURCE OF EXPOSURE AND INTO FRESH AIR. IF NOT BREATHING, GIVEARTIFICIAL RESPIRATION. GET IMMEDIATE MEDICAL ATTENTION.
NOTE TO PHYSICIAN:NONE FOR THIS MATERIAL.
============SECTION 5 FIRE FIGHTING MEASURES====================================FLAMMABLE PROPERTIES:FLASH POINT: >205F/>96C SETA FLASH CLOSED CUP.
LOWER FLAMMABLE LIMITS: N/A
UPPER FLAMMABLE LIMIT: N/AAUTO IGNITION TEMPERATURE: NOT AVAILABLEEXTINGUISHING MEDIA: FOAM, CO2, DRY CHEMICAL, WATER FOG OR SPRAY, AS APPROPRIATEFOR SURROUNDING FIRE.
SPECIAL FIRE FIGHTING PROCEDURES:AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS (PRESSURE DEMAND, NIOSH
APPROVED OR EQUIVALENT) AND FULL PROTECTIVE GEAR.
CONTAIN RUN-OFF. REMAIN UPWIND. USE WATER SPRAY TO COOL CONTAINERS EXPOSED TOFIRE.

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GUARDIAN JOINT SEALANT===========SECTION 6 ACCIDENTAL RELEASE MEASURES===============================
SMALL SPILL:
DIKE AND ABSORB WITH INERT MATERIAL SUCH AS SAND AND REMOVE ALL LIQUID WITH THEUSE OF A VACUUM SYSTEM. IF UNABLE TO REMOVE AS A LIQUID, THEN BEGIN TO ABSORBWITH SAND, SAW DUST OR COMMERCIAL ABSORBANT, AND SCOOP UP AND PLACE IN
CONTAINERS FOR PROPER DISPOSAL. KEEP SPILLS AND CLEANING RUNOFF OUT OF THE
MUNICIPAL SEWERS AND OPEN BODIES OF WATER. DECONTAMINATE ALL CLOTHING AND THE
SPILL AREA WITH A DETERGENT AND LARGE AMOUNTS OF WATER.
LARGE SPILL:USE SAME PROCEDURE AS SMALL SPILL.
===========SECTION 7 HANDLING AND STORAGE=====================================HANDLING & STORAGE:KEEP FROM FREEZING. KEEP CONTAINER COOL AND DRY. USE AND STORE THIS PRODUCT WITHADEQUATE VENTILATION. KEEP PRODUCT CONTAINERS TIGHTLY CLOSED WHEN NOT IN USE.
AVOID SUBJECTING THIS PRODUCT TO EXTREME TEMPERATURE VARIATIONS.
OTHER PRECAUTIONS:CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS WHEN EMPTIED. SINCE EMPTIEDCONTAINERS RETAIN PRODUCT RESIDUES (VAPOR, LIQUID, AND/OR SOLID), ALL HAZARDPRECAUTIONS GIVEN IN THE DATA SHEET MUST BE OBSERVED.
===========SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION===================ENGINEERING CONTROLS/PERSONAL PROTECTION:IF CURRENT VENTILATION PRACTICES ARE NOT ADEQUATE DURING MIXINGAND APPLICATION OPERATIONS TO MINIMIZE EXPOSURE, SPRAY OR ROLL
WITH WIND OR FAN CARRYING VAPORS AWAY FROM YOU. TURN OFFHEATING AND/OR AIR CONDITIONING EQUIPMENT TO PREVENTCONTAMINATING BUILDING.
RESPIRATORY PROTECTION:FOLLOW OSHA REGULATION 29 CFR 1910.134 FOR RESPIRATOR USE. WHERE OVERSPRAY ISPRESENT, OR IF CONCENTRATION OF PRODUCT IS NOT KNOWN OR ARE ABOVE THE EXPOSUREGUIDELINES. WHEN COMFORT LEVELS MAY BE EXCEEDED, USE AN APPROVED AIR-PURIFYINGRESPIRATOR EQUIPPED WITH AN AMMONIA/METHYLAMINE CARTRIDGE(S).
SKIN PROTECTION:CHEMICAL RESISTANT GLOVES DETERMINED TO BE IMPERVIOUSUNDER THE CONDITIONS OF USE.
EYE PROTECTION:CHEMICAL GOGGLES, UNLESS A FULL FACE PIECE RESPIRATOR IS USED. DO NOT WEARCONTACT LENSES AS THEY MAY CONTRIBUTE TO THE SEVERITY OF INJURY TO THE EYE. EYE
PROTECTION WORN MUST BE COMPATIBLE WITH RESPIRATORY PROTECTION SYSTEM EMPLOYED.
=============== SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES====================BOILING RANGE: 212F/100C - 2500-3000C
SPECIFIC GRAVITY (H2O=1): .9701
VAPOR DENSITY: LIGHTER THAN AIR
EVAPORATION RATE:COATING V.O.C.: 0.08 lb/gl
COATING V.O.C.: 10 g/l
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GUARDIAN JOINT SEALANTMATERIAL V.O.C.: 0.06 lb/gl
MATERIAL V.O.C.: 7 g/l
SOLUBILITY IN WATER: SOLUBLE; DILUTABLE
APPEARANCE: WHITE LIQUID.
ODOR: ACRYLIC ODOR.
======================SECTION

10STABILITY & REACTIVITY DATA===============STABILITY: STABLE
CONDITIONS TO AVOIDINCOMPATIBILITY (MATERIALS TO AVOID)NONE KNOWN.
HAZARDOUS DECOMPOSITION OR BYPRODUCTSTHERMAL DECOMPOSITION MAY YIELD ACRYLICMONOMER, CARBON MONOXIDE AND CARBON DIOXIDE. UNIDENTIFIED ORGANIC COMPOUNDS INFUMES AND SMOKE MAY BE FORMED DURING COMBUSTION.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR.
==================== SECTION 11 TOXICOLOGICAL INFORMATION======================EYE:INCONSEQUENTIAL IRRITATION
SKIN:SKIN IRRITATION- RABBIT: PRACTICALLY NON-IRRITATING. DERMAL LD50-RABBIT: >5000
mg/kg.
INGESTION:INFORMATION IS BASED ON THE TOXICITY PROFILES FOR A NUMBER OF ACRYLIC EMULSIONSTHAT ARE COMPOSITIONALLY SIMILAR TO THIS PRODUCTTYPICAL DATA ARE:PRACTICALLY NON-IRRITATINGINHALATION:IT IS POSSIBLE TO BREATHE VAPORS EMANATING FROM THIS MATERIAL UNDER CERTAINCONDITIONS OF HANDLING AND USE. BREATHING SMALL AMOUNTS OF VAPOR DURING NORMALHANDLING IS NOT LIKELY TO CAUSE HARMFUL EFFECTS. BREATHING LARGE AMOUNTS MAY BEHARMFUL. SYMPTOMS USUALLY OCCUR AT AIR CONCENTRATIONS HIGHER THEN THERECOMMENDED EXPOSURE LIMITS.
SUBCHRONIC:EYE AND SKIN IRRITATION.
CHRONIC/CARCINOGENICITY:NO DATA.
TERATOLOGY:NO DATA.
REPRODUCTION:NO DATA.
MUTAGENICITY:NO DATA.
==================SECTION 12 ECOLOGICAL INFORMATION========================ECOTOXICOLOGICAL INFORMATION: NO DATA AVAILABLE
CHEMICAL FATE INFORMATION: NO DATA.
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D A T AS H E E TGUARDIAN JOINT SEALANTSECTION 13 DISPOSAL CONSIDERATIONS:==========================================INSTRUCTIONS: WHATEVER CANNOT BE SAVED FOR REUSE SHOULD BE MANAGED IN AN APPROPRAND APPROVED WASTE DISPOSAL FACILITY. CONSULT APPROPRIATE NATIONAL, STATE AND
LOCAL REGULATORY AGENCIES TO ASCERTAIN PROPER DISPOSAL PROCEDURES.
================SECTION 14 TRANSPORT INFORMATION============================SHIPPING INFORMATION:
DOT INFORMATION - 49 CFR 172.101
DOT DESCRIPTION: NOT REGULATED================SECTION 15 REGULATORY INFORMATION===========================(NOT MEANT TO BE ALL INCLUSIVE-SELECTED REGULATIONS REPRESENTED)US REGULATIONS:STATUS OF SUBSTANCES LISTS:THE CONCENTRATIONS SHOWN IN SECTION II ARE MAXIMUM CEILING LEVELS (WEIGHT %)TO BE USED FOR CALCULATIONS FOR REGULATIONS.
FEDERAL EPA: COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION & LIABILITY ACTOF 1980 (CERCLA) REQUIRES NOTIFICATION OF THE NATIONAL RESPONSE CENTER OFRELEASE OF QUANTITIES OF HAZARDOUS SUBSTANCES EQUAL TO OR GREATER THANTHE REPORTABLE QUANTITIES (RQ'S) IN 40 CFR 302.4.
COMPONENTS PRESENT THAT COULD REQUIRE REPORTING UNDER THE STATUTE ARE:NONE KNOWN
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986(SARA) TITLE IIIREQUIRES EMERGENCY PLANNING BASED ON THE THRESHOLD QUANTITIES (TPQ'S)
AND RELEASE REPORTING BASED ON REPORTABLE QUANTITIES (RQ'S) IN 40 CFR 355(USED FOR SARA 302, 304, 311, AND 312)
COMPONENTS PRESENT THAT COULD REQUIRE REPORTING UNDER THE STATUTE ARE:NONE KNOWNREQUIRES SUBMISSION OF ANNUAL REPORTS OF RELEASE OF TOXIC CHEMICALSTHAT APPEAR IN 40 CFR 372(FOR SARA 313). THIS INFORMATION MUST BE INCLUDEDIN ALL MSDS'S THAT ARE COPIED AND DISTRIBUTED FOR THIS MATERIAL.
COMPONENTS THAT COULD REQUIRE REPORTING UNDER THE STATUTE: SEE SECTION IITHE COMPONENTS OF THIS PRODUCT ARE LISTED OR EXCLUDED FROM LISTING ON THEUS TOXIC SUBSTANCE CONTROL ACT (TSCA) CHEMICAL SUBSTANCE INVENTORY.
THE REMAINING PERCENTAGE OF UNSPECIFIED INGREDIENTS, IF ANY, ARE NOT CONTAINEDIN ABOVE DE MINIMIS CONCENTRATIONS AND/OR ARE BELIEVED TO BE NON-HAZARDOUSUNDER THE OSHA HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200), AND MAYCONSIST OF PIGMENTS, FILLERS, DEFOAMERS, WETTING AGENTS, RESINS, DRYERS,ANTI-BACTERIAL AGENTS, WATER AND/OR SOLVENTS IN VARYING CONCENTRATIONS.
INTERNATIONAL REGULATIONS:CANADIAN WHMIS:DOES NOT CLASSIFY AS HAZARDOUS.
CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA):NONE KNOWNEINECS:Page 5 of 6M A T E R I A LS A F E T Y

D A T AS H E E TGUARDIAN JOINT SEALANTNO INFORMATION.
STATE REGULATIONS:CALIFORNIA:CALIFORNIA PROPOSITION 65: THE FOLLOWING STATEMENT IS MADE IN ORDER TO COMPLYTHE CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986. THISPRODUCT CONTAINS THE FOLLOWING SUBSTANCE(S) KNOWN TO THE STATE OF CALIFORNIAA: CAUSE CANCER:NONE KNOWN
B: CAUSE REPRODUCTIVE HARM:NONE KNOWNPENNYSYLVANIA:NONE KNOWNNEW JERSEY:NONE KNOWNOTHER:NONE KNOWN=================SECTION 16OTHER INFORMATION===========================THE INFORMATION CONTAINED HEREIN IS FURNISHED WITHOUT WARRANTY OF ANY KIND.
USERS SHOULD CONSIDER THESE DATA ONLY AS A SUPPLEMENT TO OTHER INFORMATIONGATHERED BY THEM & DETERMINE THE SUITABILITY & COMPLETENESS OF INFORMATION FROMALL SOURCES TO ASSURE PROPER USE & DISPOSAL OF THESE MATERIALS & THE SAFETY &HEALTH OF EMPLOYEES & CUSTOMERS.

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