SAFETY DATA SHEETMAPP GAS (Petroleum Gas, MAPD)

Section 1. Identification
GHS product identifier: MAPP GAS (Petroleum Gas, MAPD)

Other means ofidentification: MAP,MAPP,Methylacetylene-Propadiene, Mixture of Methylacetylene and Propadiene

Product type

: Liquefied gas

Product use: Synthetic/Analytical chemistry.

Synonym
SDS #Supplier's details: MAP,MAPP,Methylacetylene-Propadiene, Mixture of Methylacetylene and Propadiene: 002015: Airgas USA, LLC and its affiliates
259 North Radnor-Chester Road
Suite 100
Radnor, PA 19087-5283
1-610-687-5253

24-hour telephone: 1-866-734-3438

Section 2. Hazards identification
OSHA/HCS status
Classification of thesubstance or mixture: This material is considered hazardous by the OSHA Hazard Communication Standard(29 CFR 1910.1200).
: FLAMMABLE GASES - Category 1
GASES UNDER PRESSURE - Liquefied gas

GHS label elements
Hazard pictograms:

Signal word

: Danger

Hazard statements: Extremely flammable gas.
Contains gas under pressure; may explode if heated.
May cause frostbite.
May displace oxygen and cause rapid suffocation.
May form explosive mixtures with air.

Precautionary statements
GeneralStorage: Read and follow all Safety Data Sheets (SDS’S) before use. Read label before use.
Keep out of reach of children. If medical advice is needed, have product container orlabel at hand. Close valve after each use and when empty. Use equipment rated forcylinder pressure. Do not open valve until connected to equipment prepared for use.
Use a back flow preventative device in the piping. Use only equipment of compatible
materials of construction. Always keep container in upright position. Approachsuspected leak area with caution.
: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
: Leaking gas fire: Do not extinguish, unless leak can be stopped safely. In case ofleakage, eliminate all ignition sources.
: Protect from sunlight. Store in a well-ventilated place.

Disposal: Not applicable.

Prevention
Response

Hazards not otherwiseclassified: Liquid can cause burns similar to frostbite.

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Section 3. Composition/information on ingredients
Substance/mixture: Mixture

Other means ofidentification: MAP,MAPP,Methylacetylene-Propadiene, Mixture of Methylacetylene and Propadiene

Product code

: 002015

Ingredient name%

CAS number

propylene
methyl acetylene
1,2-propadiene
isobutane
N-Butane
Propane37 - 55
27 - 33
13 - 15
2-5
2-5
1-5

115-07-1
74-99-7
463-49-0
75-28-5
106-97-8
74-98-6

Any concentration shown as a range is to protect confidentiality or is due to batch variation.
There are no additional ingredients present which, within the current knowledge of the supplier and in theconcentrations applicable, are classified as hazardous to health or the environment and hence require reportingin this section.
Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures
Description of necessary first aid measures
Eye contact

Inhalation

Skin contact

Ingestion: Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention if irritation occurs.
: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If
not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial
respiration or oxygen by trained personnel. It may be dangerous to the person providing
aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects
persist or are severe. If unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway. Loosen tight clothing such as a collar,tie, belt or waistband.
: Flush contaminated skin with plenty of water. Remove contaminated clothing andshoes. To avoid the risk of static discharges and gas ignition, soak contaminatedclothing thoroughly with water before removing it. Get medical attention if symptoms
occur. In case of contact with liquid, warm frozen tissues slowly with lukewarm waterand get medical attention. Do not rub affected area. Wash clothing before reuse.
Clean shoes thoroughly before reuse.
: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get
medical attention if adverse health effects persist or are severe. Ingestion of liquid cancause burns similar to frostbite. If frostbite occurs, get medical attention. Never give
anything by mouth to an unconscious person. If unconscious, place in recovery position
and get medical attention immediately. Maintain an open airway. Loosen tight clothingsuch as a collar, tie, belt or waistband. As this product rapidly becomes a gas whenreleased, refer to the inhalation section.

Most important symptoms/effects, acute and delayed
Potential acute health effects
Eye contact: Liquid can cause burns similar to frostbite.

Inhalation: No known significant effects or critical hazards.

Skin contact: Dermal contact with rapidly evaporating liquid could result in freezing of the tissues or
frostbite.
: Try to warm up the frozen tissues and seek medical attention.
: Ingestion of liquid can cause burns similar to frostbite.

Frostbite
Ingestion

Over-exposure signs/symptoms
Eye contact: Adverse symptoms may include the following:, frostbite

Inhalation: No specific data.

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Section 4. First aid measures
Skin contact: Adverse symptoms may include the following:, frostbite

Ingestion: Adverse symptoms may include the following:, frostbite

Indication of immediate medical attention and special treatment needed, if necessary
Notes to physician: Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments: No specific treatment.
Protection of first-aiders: No action shall be taken involving any personal risk or without suitable training. It may
be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

See toxicological information (Section 11)

Section 5. Fire-fighting measures
Extinguishing media
Suitable extinguishingmedia: Use an extinguishing agent suitable for the surrounding fire.

Unsuitable extinguishingmedia: None known.

Specific hazards arisingfrom the chemical: Contains gas under pressure. Extremely flammable gas. In a fire or if heated, apressure increase will occur and the container may burst, with the risk of a subsequent
explosion.
: Decomposition products may include the following materials:
carbon dioxidecarbon monoxide

Hazardous thermal
decomposition products

Special protective actions
for fire-fighters

Special protective
equipment for fire-fighters: Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitabletraining. Contact supplier immediately for specialist advice. Move containers from firearea if this can be done without risk. Use water spray to keep fire-exposed containers
cool. If involved in fire, shut off flow immediately if it can be done without risk. If this is
impossible, withdraw from area and allow fire to burn. Fight fire from protected locationor maximum possible distance. Eliminate all ignition sources if safe to do so.
: Fire-fighters should wear appropriate protective equipment and self-contained breathingapparatus (SCBA) with a full face-piece operated in positive pressure mode. For
incidents involving large quantities, thermally insulated undergarments and thick textile
or leather gloves should be worn.

Section 6. Accidental release measures
Personal precautions, protective equipment and emergency procedures
For non-emergency
personnel: Accidental releases pose a serious fire or explosion hazard. No action shall be taken
involving any personal risk or without suitable training. Evacuate surrounding areas.
Keep unnecessary and unprotected personnel from entering. Do not touch or walkthrough spilled material. Shut off all ignition sources. No flares, smoking or flames inhazard area. Avoid breathing gas. Provide adequate ventilation. Wear appropriate
respirator when ventilation is inadequate. Put on appropriate personal protective
equipment.
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For nonemergency personnel".
Environmental precautions: Ensure emergency procedures to deal with accidental gas releases are in place to avoid
contamination of the environment. Avoid dispersal of spilled material and runoff andcontact with soil, waterways, drains and sewers. Inform the relevant authorities if the
product has caused environmental pollution (sewers, waterways, soil or air).

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Section 6. Accidental release measures
Methods and materials for containment and cleaning up
Small spill: Immediately contact emergency personnel. Stop leak if without risk. Use spark-proof
tools and explosion-proof equipment.
: Immediately contact emergency personnel. Stop leak if without risk. Use spark-proof
tools and explosion-proof equipment. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.

Large spill

Section 7. Handling and storage
Precautions for safe handlingProtective measures: Put on appropriate personal protective equipment (see Section 8). Contains gas underpressure. Do not get in eyes or on skin or clothing. Avoid breathing gas. Use only withadequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do
not enter storage areas and confined spaces unless adequately ventilated. Do not
puncture or incinerate container. Use equipment rated for cylinder pressure. Close
valve after each use and when empty. Protect cylinders from physical damage; do notdrag, roll, slide, or drop. Use a suitable hand truck for cylinder movement.
Use only non-sparking tools. Empty containers retain product residue and can be
hazardous. Store and use away from heat, sparks, open flame or any other ignition
source. Use explosion-proof electrical (ventilating, lighting and material handling)equipment.

Advice on general
occupational hygiene: Eating, drinking and smoking should be prohibited in areas where this material ishandled, stored and processed. Workers should wash hands and face before eating,drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.

Conditions for safe storage,
including any
incompatibilities: Store in accordance with local regulations. Store in a segregated and approved area.
Store away from direct sunlight in a dry, cool and well-ventilated area, away fromincompatible materials (see Section 10). Eliminate all ignition sources. Cylinders
should be stored upright, with valve protection cap in place, and firmly secured toprevent falling or being knocked over. Cylinder temperatures should not exceed 52 °C(125 °F). Keep container tightly closed and sealed until ready for use. See Section 10
for incompatible materials before handling or use.

Section 8. Exposure controls/personal protection
Control parameters
Occupational exposure limits
Ingredient name

Exposure limits

propylene

ACGIH TLV (United States, 3/2019).
TWA: 500 ppm 8 hours.
ACGIH TLV (United States, 1/2005).
TWA: 500 ppm 8 hours. Form: All forms
ACGIH TLV (United States, 3/2019).
Explosive potential.
TWA: 1640 mg/m³ 8 hours.
TWA: 1000 ppm 8 hours.
NIOSH REL (United States, 10/2016).
TWA: 1650 mg/m³ 10 hours.
TWA: 1000 ppm 10 hours.
OSHA PEL (United States, 5/2018).
TWA: 1650 mg/m³ 8 hours.
TWA: 1000 ppm 8 hours.
OSHA PEL 1989 (United States, 3/1989).
TWA: 1650 mg/m³ 8 hours.
TWA: 1000 ppm 8 hours.

methyl acetylene

1,2-propadiene
isobutane

Date of issue/Date of revision

None.
NIOSH REL (United States, 10/2016).
TWA: 1900 mg/m³ 10 hours.
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Section 8. Exposure controls/personal protection
TWA: 800 ppm 10 hours.
ACGIH TLV (United States, 3/2019).
Explosive potential.
STEL: 1000 ppm 15 minutes.
NIOSH REL (United States, 10/2016).
TWA: 1900 mg/m³ 10 hours.
TWA: 800 ppm 10 hours.
OSHA PEL 1989 (United States, 3/1989).
TWA: 1900 mg/m³ 8 hours.
TWA: 800 ppm 8 hours.
ACGIH TLV (United States, 3/2019).
Explosive potential.
STEL: 1000 ppm 15 minutes.
NIOSH REL (United States, 10/2016).
TWA: 1800 mg/m³ 10 hours.
TWA: 1000 ppm 10 hours.
OSHA PEL (United States, 5/2018).
TWA: 1800 mg/m³ 8 hours.
TWA: 1000 ppm 8 hours.
OSHA PEL 1989 (United States, 3/1989).
TWA: 1800 mg/m³ 8 hours.
TWA: 1000 ppm 8 hours.
ACGIH TLV (United States, 3/2019). Oxygen
Depletion [Asphyxiant]. Explosive potential.

N-Butane

PropaneAppropriate engineering
controls

Environmental exposure
controls: Use only with adequate ventilation. Use process enclosures, local exhaust ventilation orother engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
: Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In somecases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.

Individual protection measures
Hygiene measures

Eye/face protection

Skin protection
Hand protection

Date of issue/Date of revision: Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
: Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,gases or dusts. If contact is possible, the following protection should be worn, unlessthe assessment indicates a higher degree of protection: safety glasses with sideshields.
: Chemical-resistant, impervious gloves complying with an approved standard should beworn at all times when handling chemical products if a risk assessment indicates this isnecessary. If contact with the liquid is possible, insulated gloves suitable for low
temperatures should be worn. Considering the parameters specified by the glove
manufacturer, check during use that the gloves are still retaining their protective
properties. It should be noted that the time to breakthrough for any glove material may
be different for different glove manufacturers. In the case of mixtures, consisting ofseveral substances, the protection time of the gloves cannot be accurately estimated.

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Section 8. Exposure controls/personal protection
Body protection

Other skin protection

Respiratory protection

Thermal hazards: Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear antistatic protective clothing. For the greatest protection from static discharges, clothingshould include anti-static overalls, boots and gloves.
: Appropriate footwear and any additional skin protection measures should be selectedbased on the task being performed and the risks involved and should be approved by aspecialist before handling this product.
: Based on the hazard and potential for exposure, select a respirator that meets theappropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
: If there is a risk of contact with the liquid, all protective equipment worn should besuitable for use with extremely low temperature materials.

Section 9. Physical and chemical properties
Appearance
Physical state: Gas. [Liquefied gas]

Color

: Not available.

Odor
Odor threshold: Not available.
: Not available.

pH: Not available.

Melting point
Boiling point
Critical temperature: -102.7°C (-152.9°F) This is based on data for the following ingredient: Methyl Acetylene.
Weighted average: -151.01°C (-239.8°F): Not available.
: Lowest known value: 91.85°C (197.3°F) (Propylene).

Flash point: Not available.

Evaporation rate

: Not available.

Flammability (solid, gas)

: Not available.

Lower and upper explosive(flammable) limits
Vapor pressure
Vapor density: Lower: 2%
Upper: 13%: Not available.
: Highest known value: 2.1 (Air = 1) (n-butane). Weighted average: 1.51 (Air = 1)

Gas Density (lb/ft 3): Weighted average: 0.11

Relative density: Not applicable.

Solubility: Not available.

Solubility in water: Not available.

Partition coefficient: noctanol/water: Not available.

Auto-ignition temperature: Not available.

Decomposition temperature: Not available.

Viscosity: Not applicable.

Flow time (ISO 2431): Not available.

Molecular weight: 42 g/mol

Section 10. Stability and reactivity
Reactivity: No specific test data related to reactivity available for this product or its ingredients.

Chemical stability: The product is stable.

Possibility of hazardous
reactions: Hazardous reactions or instability may occur under certain conditions of storage or use.

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Section 10. Stability and reactivity
Conditions to avoid: Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition.

Incompatible materials: Oxidizers

Hazardous decomposition
products: Under normal conditions of storage and use, hazardous decomposition products should
not be produced.

Hazardous polymerization: May Occur.
Conditions to Avoid: Elevated tempertures and pressures. Polymerization catalysts,
such as metal alkyls, can cause uncontrolled polymerization. Contamination withoxygen can cause propadiene to form hazardous peroxides.
INHIBITORS/STABILIZERS
An ihibitor is added to the MAPD mixture to prevent potential unstable peroxide
formation. Butanes (iso and/or normal) are also added to the MAPD mixture to prevent
potential concentration of the methylacetylene and propadiene from reaching
concentration levels that would render the mixture unstable in case of weathering off(evaporation of light components).

Section 11. Toxicological information
Information on toxicological effects
Acute toxicity
Product/ingredient nameResultSpecies

Dose

Exposureisobutane
N-Butane

LC50 Inhalation Vapor
LC50 Inhalation Vapor

Rat
Rat

658000 mg/m³
658000 mg/m³

4 hours
4 hours

Irritation/Corrosion
Not available.
Sensitization
Not available.
Mutagenicity
Not available.
Carcinogenicity
Not available.
Classification
Product/ingredient name

OSHA

IARC

NTP

propylene-

3-

Reproductive toxicity
Not available.
Teratogenicity
Not available.
Specific target organ toxicity (single exposure)
Not available.
Specific target organ toxicity (repeated exposure)
Not available.
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Section 11. Toxicological information
Aspiration hazard
Not available.
Information on the likely
routes of exposure: Not available.

Potential acute health effects
Eye contact: Liquid can cause burns similar to frostbite.
Inhalation: No known significant effects or critical hazards.

Skin contact: Dermal contact with rapidly evaporating liquid could result in freezing of the tissues or
frostbite.
: Ingestion of liquid can cause burns similar to frostbite.

Ingestion

Symptoms related to the physical, chemical and toxicological characteristics
Eye contact: Adverse symptoms may include the following:, frostbite
Inhalation
Skin contact
Ingestion: No specific data.
: Adverse symptoms may include the following:, frostbite: Adverse symptoms may include the following:, frostbite

Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate: Not available.
effects
Potential delayed effects: Not available.

Long term exposure
Potential immediate: Not available.
effects
Potential delayed effects : Not available.
Potential chronic health effects
Not available.
General: No known significant effects or critical hazards.

Carcinogenicity: No known significant effects or critical hazards.

Mutagenicity: No known significant effects or critical hazards.

Teratogenicity: No known significant effects or critical hazards.

Developmental effects: No known significant effects or critical hazards.

Fertility effects: No known significant effects or critical hazards.

Numerical measures of toxicity
Acute toxicity estimates
Not available.

Section 12. Ecological information
Toxicity
Not available.
Persistence and degradability
Not available.

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Section 12. Ecological information
Bioaccumulative potential
Product/ingredient name

LogPow

BCF

Potential

propylene
methyl acetylene
1,2-propadiene
isobutane
N-Butane
Propane

1.77
0.94
1.45
2.8
2.89
1.09

-

low
low
low
low
low
low

Mobility in soil
Soil/water partition
coefficient (KOC): Not available.

Other adverse effects: No known significant effects or critical hazards.

Section 13. Disposal considerations
Disposal methods: The generation of waste should be avoided or minimized wherever possible. Disposalof this product, solutions and any by-products should at all times comply with therequirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated tothe sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Empty Airgas-owned pressure vessels should be returned to Airgas. Waste packaging
should be recycled. Incineration or landfill should only be considered when recycling is
not feasible. This material and its container must be disposed of in a safe way. Empty
containers or liners may retain some product residues. Do not puncture or incineratecontainer.

Section 14. Transport information
DOT

TDG

MexicoIMDG

IATA

UN number

UN1060UN1060UN1060UN1060UN1060

UN proper
shipping nameMethyl Acetylene
andPropadiene
mixtures,stabilized

Methyl Acetylene
andPropadiene
mixtures,stabilized

Methyl Acetylene
andPropadiene
mixtures,stabilized

Methyl Acetylene
andPropadiene
mixtures,stabilized

Methyl Acetylene
andPropadiene
mixtures,stabilized

Transport
2.1
hazard class(es)

2.1

2.1

2.1

2.1

Packing group

-

-

-

-

-

Environmental
hazards

No.

No.

No.

No.

No.

“Refer to CFR 49 (or authority having jurisdiction) to determine the information required for shipment of the
product.”
Additional information
TDG Classification

Date of issue/Date of revision: Product classified as per the following sections of the Transportation of Dangerous
Goods Regulations: 2.13-2.17 (Class 2).
Explosive Limit and Limited Quantity Index 0.125
ERAP Index 3000
Passenger Carrying Road or Rail Index Forbidden: 6/10/2021

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Section 14. Transport information
Special precautions for user : Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in theevent of an accident or spillage.
Transport in bulk according
to IMO instruments: Not available.

Section 15. Regulatory information
U.S. Federal regulations

Clean Air Act Section 112(b) Hazardous Air
Pollutants (HAPs): TSCA 8(a) CDR Exempt/Partial exemption: Not determined
Clean Air Act (CAA) 112 regulated flammable substances: Propylene; Methyl
Acetylene; Propadiene; Isobutane; n-butane; propane: Not listed

Clean Air Act Section 602
Class I Substances: Not listed

Clean Air Act Section 602
Class II Substances: Not listed

DEA List I Chemicals(Precursor Chemicals): Not listed

DEA List II Chemicals(Essential Chemicals): Not listed

SARA 302/304
Composition/information on ingredients
No products were found.
SARA 304 RQ: Not applicable.

SARA 311/312
Classification: Refer to Section 2: Hazards Identification of this SDS for classification of substance.

SARA 313
Product name

CAS number%

Form R - Reporting
requirements

Propylene

115-07-1

37 - 55

Supplier notification

Propylene

115-07-1

37 - 55SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include
copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.
State regulations
Massachusetts
New York
New Jersey

Pennsylvania: The following components are listed: PROPYLENE; PROPENE; PROPYNE; METHYL
ACETYLENE; ISOBUTANE; BUTANE; PROPANE: None of the components are listed.
: The following components are listed: PROPYLENE; 1-PROPENE; METHYL
ACETYLENE; 1-PROPYNE; PROPADIENE; 1,2-PROPADIENE; Isobutane; PROPANE,
2-METHYL-; BUTANE; PROPANE: The following components are listed: 1-PROPENE; 1-PROPYNE; PROPANE,
2-METHYL-; BUTANE; PROPANE

California Prop. 65
This product does not require a Safe Harbor warning under California Prop. 65.
International regulations
Chemical Weapon Convention List Schedules I, II & III Chemicals
Not listed.
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Section 15. Regulatory information
Montreal Protocol
Not listed.
Stockholm Convention on Persistent Organic Pollutants
Not listed.
Rotterdam Convention on Prior Informed Consent (PIC)
Not listed.
UNECE Aarhus Protocol on POPs and Heavy Metals
Not listed.
Inventory list
Australia: All components are listed or exempted.

Canada: All components are listed or exempted.

China: Not determined.

Europe: All components are listed or exempted.

Japan
New Zealand: Japan inventory (ENCS): Not determined.
Japan inventory (ISHL): Not determined.
: All components are listed or exempted.

Philippines: All components are listed or exempted.

Republic of Korea: All components are listed or exempted.

Taiwan: All components are listed or exempted.

Thailand: Not determined.

Turkey: Not determined.

United States: Not determined.

Viet Nam: All components are listed or exempted.

Section 16. Other information
Hazardous Material Information System (U.S.A.)/

Health1

Flammability

4Physical hazards

3

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS®
ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service
mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS®
Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.
National Fire Protection Association (U.S.A.)
Flammability

4
Health11Instability/Reactivity
SpecialReprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency
Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is
not the complete and official position of the National Fire Protection Association, on the referenced subject
which is represented only by the standard in its entirety.

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Section 16. Other information
Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to
be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards ofchemicals. The user is referred to certain limited number of chemicals with recommended classifications in
NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA
or not, anyone using the 704 systems to classify chemicals does so at their own risk.
Procedure used to derive the classification
Classification

Justification

FLAMMABLE GASES - Category 1
GASES UNDER PRESSURE - Liquefied gas

Expert judgment
Expert judgment

History
Date of printing: 6/10/2021

Date of issue/Date ofrevision
Date of previous issue: 6/10/2021

Version: 1.02

Key to abbreviations: ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations: Not available.

References
Notice to reader: 10/22/2018

To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of theinformation contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.

Date of issue/Date of revision: 6/10/2021

Date of previous issue: 10/22/2018

Version: 1.02

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