ISOS-20 / ASiS-9

Oral Program

Monday May 13, 2024
Room A
8:45-9:00

Opening Ceremony
Chair: Hisako Hashimoto

9:00-9:45

1AP01 T. D. Tilley, R. C. Handford, R. Bryant (University of California, Berkeley)
Reactive metal-silicon complexes in bond activations and chemical transformations
Chair: Vladimir Ya. Lee

10:00-10:20

1AI01 A. Chandran,1,2 J. M. Slattery,2 J. M. Lynam,2 M. Grellier1 (1Laboratoire de Chimie
de Coordination, 2University of York)
Ruthenium σ-complexes for chemoselective mono-hydrosilylation of nitriles

10:20-10:40

1AI02 L. Deng (Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences)
Structurally well-defined cobalt-NHC catalysts for hydrosilylation reactions of alkenes andalkynes

10:40-11:10

1AK01 M. Drieß (Technical University Berlin)
Tuning the reactivity of bis-silylenes to engender selective chemical transformations
Chair: Matthias Drieß

11:10-11:25

1AO01 V. Ya. Lee,1 J. Wang,1 T. Sasamori,1 K. Takeuchi,2 N. Fukaya2 (1University ofTsukuba, 2AIST)Electrophilic behavior of the “Nucleophilic” pyramidane: Reactivity of Ge-pyramidane
towards organolithium reagents

11:25-11:45

1AI03 Y. Nakajima,1 K. Iizuka,1 S. Ni,2 S. Sakaki2 (1Tokyo Institute of Technology, 2Kyoto
University)
Oxidative addition of Si–Cl bond to Fe(0) complex with radical character and application
to hydrosilane formation
Lunch

ASiS Special Session

Chair: Soichiro Kyushin

13:20-13:40

1AI04 M. Suginome (Kyoto University)
Toward a new phase of silylene transfer reactions

13:40-14:00

1AI05 H. Liu (Shandong University)
Silsesquioxanes-based functional materials for sustainable development

14:00-14:20

1AI06 H. Sohn (Chosun University)
One-pot synthesis of water-soluble silicon quantum dots and their applications

14:20-14:40

1AI07 H.-W. Fu,1 Y.-J. Guo,1 R.-J. Chein,2 C.-W. Chiu1 (1National Taiwan University,
2
Institute of Chemistry, Academia Sinica)
Synthesis and catalytic applications of chiral tetrylenes

ISOS-20 / ASiS-9

Oral Program

Coffee BreakProfessor Robert West Memorial Session
14:55-16:15

Chair: Kim Baines

J. Michl (University of Colorado Boulder) (online participation)
P. Boudjouk (North Dakota State University) (online participation)
K. Tamao (Toyota Physical and Chemical Research Institute)
A. Sekiguchi (AIST)
M. Drieß (Technical University Berlin)

Chair: Takeaki Iwamoto
16:30-17:15

1AP02 L. Greb (Universität Heidelberg)
Pushing and twisting silicon: ligand control on the electronic, structural and redox
properties of Si(IV)ISOS-20 / ASiS-9

Oral Program

Monday May 13, 2024
Room B
Chair: Tsukasa Matsuo
10:00-10:20

1BI01 M. O. Hight, A. E. Pimentel, T. C. Siu, J. Seo, M. Imex Aguirre Cardenas, T. A.
Su (University of California, Riverside)
Silicon clusters and polycarbosilanes in molecular electronics
Chair: Joseph Furgal

10:20-10:35

1BO01 K. Naka, I. Tokuami, H. Imoto (Kyoto Institute of Technology)
Surface segregation of functional siloxane-based cages in a polymer matrix

10:35-10:50

1BO02 C. Croutxé-Barghorn, L. Halbardier, E. Goldbach, A. S. Schuller, X. Allonas(University of Haute –Alsace)
3D printing of hybrid materials by combination of photo sol-gel process andphotopolymerization

10:50-11:05

1BO03 L. Yang, Y. Cheng, R. Hifumi, I. Tomita (Tokyo Institute of Technology)
Precision synthesis of silicon-containing nanostructured materials through living
coordination polymerization

11:05-11:20

1BO04 Z. He,1 L. Feng,1 J. Xie,2 H. Liu,1 W. W. Yu,1 J. Zhang1 (1Shandong University,
2
Yangzhou University,)
Melt transesterification involving siloxane diol
Chair: Yoshinori Yamanoi

11:20-11:40

1BI02 E. Moyer, S. Sulaiman, N. Hu, K. Liu, A. Garibaldi, E. Guzman (Gelest, Inc.)
In search of viable silicon-based alternatives to PFAS materials

ISOS-20 / ASiS-9

Oral Program

Monday May 13, 2024
Room C
Chair: Jonathan O. Bauer
10:00-10:30

1CK01 S. Inoue (Technische Universität München)
Facile bond activation of small molecules by acyclic silylenes

10:30-10:45

1CO01 J.-L. Kirchhoff, M. Nuss, T. Mairath, C. Strohmann (TU Dortmund)
Better understanding of selective transformation of Si–N,O-functionalizedorganosilanes
Chair: Shigeyoshi Inoue

10:45-11:00

1CO02 L. Sévery, A. Mifleur, T. Cantat (Université Paris-Saclay)
Towards the experimental determination of the thermodynamic hydricity ofhydrosilanes

11:00-11:15

1CO03 Y. Mizuhata, Y. Omatsu, W. Ijichi, N. Tokitoh (Kyoto University)
Syntheses of novel siliconoids and their skeletal transformation reactions

11:15-11:30

1CO04 A. Kawachi, Y. Kowada, S. Hirotani (Hosei University)
Preparation and reactions of boron-substituted silyllithium

11:30-11:45

1CO05 V. S. Ajithkumar, S. S. Sen (CSIR-National Chemical Laboratory)
The tale of hypersilyl tetrylenes as a versatile synthon

ISOS-20 / ASiS-9

Oral Program

Monday May 13, 2024
Room D
Chair: Mikio Yamahiro
10:00-10:20

1DI01 Y. Kaneko,1 K. Sonoda,1 N. Tohnai2 (1Kagoshima University, 2Osaka
University)
Stereoselective preparation of different cyclic tetrasiloxane isomers: Effect of thesuperacid catalyst employed

10:20-10:40

1DI02 H. Imoto, K. Naka (Kyoto Institute of Technology)
Precise molecular design for cage silsesquioxane materials
Chair: Yoshiro Kaneko

10:40-11:00

1DI03 P. Sangtrirutnugul, V. Ervithayasuporn, K. Kwanplod, T. Chaiprasert, K.
Yawananonta (Mahidol University)
The diverse catalytic applications of functionalized polyhedral oligomericsilsesquioxanes

ISOS-20 / ASiS-9

Oral Program

Tuesday May 14, 2024
Room A
Chair: Masaichi Saito
9:00-9:45

2AP01 S. Dehnen (Karlsruhe Institute of Technology)
Multinary clusters based on (heavier) group 14 elements
Chair: Kenkichi Sakamoto

10:00-10:30

2AK01 D. Scheschkewitz (Saarland University at Saarbrücken)
Heavier analogues of vinyl anions: Synthetic workhorses in low-valent main groupchemistry
Chair: David Scheschkewitz

10:30-10:50

2AI01 M. Saito (Saitama University)
A silylium ion incorporated into a σ-delocalized system

Professor William Leigh Memorial Session Chair: Kim Baines & Michael Brook
10:50-10:55

Michael Brook

10:55-11:25

2AK02 L. Albers, L. Bührmann, Z. Dong, N. Geibel, C.-H. Liu, M. Würdemann, T.
Müller (Carl von Ossietzky University Oldenburg)
Silole and germole dianions as precursors for unusual main group element compounds

11:25-11:40

2AO01 K. Sakamoto, T. Sugino, S. Oka, J. Lee, A. Furusawa, S. Nagata, H. Takagi,
K.Inagaki, Y. Sugiyama, K. Nagata, K. Ochiai, R. Miyazawa, S. Kobayashi, S. Nishi,
R. Iwasaki (Shizuoka University)
Synthesis and properties of 9bH-9b-silaphenalene: A silicon-containing antiaromaticcompound

11:40-11:55

Kim Baines

Lunch

Professor Ian Manners Memorial Session

Chair: Kim Baines

13:20-13:30

Kim Baines

13:30-13:50

2AI02 M. Rokni,1,2 K. W. Park,1,2 W. Sheard,1,2 E. M. Leitao1,2 (1The University of
Auckland, 2The MacDiarmid Institute for Advanced Materials and Nanotechnology)
Siloxane cross-linked polysulfides

13:50-14:10

2AI03 C. Jing,1,2 Z. Pan,1,2 Y. Li,1 C. Xu1,2 (1Institute of Chemistry, Chinese Academyof Sciences, 2University of Chinese Academy of Sciences)
Synthesis and application of silicon-containing polymers for 3D printing

14:10-14:25

2AO03 M. Tanabe,1,2 K. Osakada1,3 (1Tokyo Institute of Technology, 2Fukushima
Medical University, 3AIST)ISOS-20 / ASiS-9

Oral Program

Multinuclear Pd and Pt complexes with bridging Si-ligands.
structures, and chemical properties
14:25-14:40

Their bonding,

2AO04 M. Nanjo,1 K. Nagasaki,1 K. Kasahara,1 A. Kitane,1 G. Masuda2 (1Tottori
University, 2Nisshinbo Holdings Inc.)
Synthesis and properties of halogen-free ionic liquids containing silyl-substituted
tetraalkylborates
Coffee Break

Chair: Takahiro Gunji
14:55-15:25

2AK03 M. Unno, N. Takeda, A. Ouali, Y. Liu (Gunma University)
Recent development of double-decker silsesquioxanes

15:25-15:55

2AK04 J. J. R. Arias,1 Z. Zhang,1 Y. Liu,2 M. Takahashi,2 M. Unno,2 N. Yodsin,3 P.
Pimbaotham,4 S. Jungsuttiwong,4 P. Mahalingam,5 J. Azoulay,5 M. Rammo,6 A.
Rebane,7 R. M. Laine1 (1University of Michigan, 2Gunma University, 3Silpakorn
University, 4Ubon Ratchathani University, 5Georgia Institute of Technology, 6National
Institute of Chemical Physics and Biophysics, 7Montana State University)
Conjugation in polysiloxane copolymer via unexpected Si-O-Si dπ-pπ overlap, asecond mechanism?

15:55-16:15

2AI04 M. Wong Chi Man (Institut Charles Gerhardt Montpellier)
Sol-gel processing of new styryl-substituted cage silsesquioxanes: T8, T8-F, T10, T12
and an unprecedented t18 cage

Chair: Shigehiro Yamaguchi
16:30-17:15

2AP02 C. Cui, Y. Ding, L. Guo, W. Jin, M. Tian, J. Zhang (Nankai University)
Synthesis and reactivity of NHB-substituted low-valent silicon compounds

ISOS-20 / ASiS-9

Oral Program

Tuesday May 14, 2024
Room B
Chair: Shabana Khan
10:00-10:20

2BI01 N. Nakata (Saitama University)
Strong σ-donating N-heterocyclic silylenes supported by iminophosphonamides

10:20-10:40

2BI02 M. P. Müller, P. Hädinger, A. Hinz (Karlsruhe Institute of Technology)
Modular access to acyclic silylenes: Effects of heteroatom substitution

10:40-10:55

2BO01 A. Pöcheim, R. Zitz, J. Hlina, J. Baumgartner, C. Marschner (Graz Universityof Technology)
Silylated and germylated rare earth elements
Chair: Georgii Nikonov

10:55-11:10

2BO02 T. Kodama, K. Uchida, M. Tobisu (Osaka University)
Synthesis, electronic structure, and reactivity of germylenes
phenalenyl-based ligand

bearinga

11:10-11:25

2BO03 A. Kostenko, F. J. Kiefer, T. Eisner, S. Inoue (Technische Universität
München)
The divergent reactivity of disilenes toward Lewis bases

11:25-11:55

2BK01 H. Ito (Hokkaido University)
General synthesis of silylboranes and their application to iterative oligosilane
synthesis
Lunch

Chair: Makoto Ogawa
13:20-13:40

2BI03 N. Fukaya (AIST)
From silica to alkoxysilanes on the way to CO2 utilization

13:40-13:55

2BO04 Y. Chen,1 M. Melendez-Zamudio2, Y.-G. Yu2, L. Gellé2, M. A. Brook2(1EnRoute Interfaces Inc., 2McMaster University)
Waste tire rubber in silicones: Reducing the carbon footprint without sacrificing
silicone properties

13:55-14:10

2BO05 R. Miyamoto, K. Kanamori, H. Nakagawa, H. Tanaka, H. Kaji (Kyoto
University)
Application of large monolithic silica: Supersaturated halogen-free purification forsustainable liquid chromatography

14:10-14:25

2BO06 E. Mejía (Leibniz Institute for Catalysis)
Development and applications of silica-supported heterogeneous catalysts made fromagricultural bio-waste

ISOS-20 / ASiS-9
14:25-14:40

Oral Program

2BO07 Y. Boiko,1 V. Kyshkarova,2 V. Tomina,1 M. Vaclavikova,2 I. Melnyk2 (1NAS of
Ukraine, 2Institute of Geotechnics SAS)
Silica/Pectin hybrid material as efficient sorbent for lead(II) ions removal from
aqueous solutions
Coffee Break

Chair: Akiyoshi Takehira
14:55-15:15

2BI04 B. Arkles,1 K. Pannell,2 A. Thomas,3 L. Clemintino,3 D. Segarnick3 (1Catemer
Inc., 2University of Texas, 3Rutgers, The State University of New Jersey)
Silacrown ethers: Development as ion transport agents and potential therapeutics forchannelopathy diseases

15:15-15:30

2BO08 Z. J. Raczywolski,1 E. Livermore,1,2 J. Dargacz,1 P. M. Zelisko1 (1Brock
University, 2Cardiff University)
Silicon-Containing Lipid Structures

15:30-15:45

2BO09 L. Brewitz, E. Salah, C. J. Schofield (University of Oxford)
The effect of silicon incorporation on the potency of nirmatrelvir and derivatives
Chair: Atsushi Kawachi

15:45-16:05

2BI05 T. F. Fässler, K. Frankiewicz, B. Frank (Technical University of Munich)Variable Si to Ge ratios in polyhedral nine-atom clusters ─ Cluster dynamics andisomerization processes

16:05-16:20

2BO10 J. O. Bauer, A. Falk (University of Regensburg)
Studies on dihydrogen release from phosphine sulfide- and amino-functionalized
silicon-based systems

ISOS-20 / ASiS-9

Oral Program

Tuesday May 14, 2024
Room C
Chair: Ikuyoshi Tomita
10:00-10:15

2CO01 S. Ito, Y. Ito, K. Tanaka (Kyoto University)
Near-infrared emissive conjugated polymers composed of square-pyramidal
five-coordinated silicon formazanates

10:15-10:30

2CO02 J. Furgal, M. Rashed, C. Sims, E. Chandler, M. Fyfe (Bowling Green State
University)
Photoresponsive R-alkoxysilane/siloxane systems and their applications in surface
treatment, 3D printing, and coatings

10:30-10:45

2CO03 M. Gon, S. Saotome, K. Tanaka (Kyoto University)
Development of paintable hybrid polymers showing thermally-stable white-lightemission based on POSS

10:45-11:00

2CO04 S. Bouveyron,1 J. Delorme,2 R. Mirgalet,2 D. Blanc,2 J. Raynaud,1 V. Monteil1(1Lyon 1 University, 2Elkem Silicones France)
New cobalt catalysts for alkene hydrosilylation and crosslinking of silicones
Chair: Makoto Tanabe

11:00-11:15

2CO05 T. Takasuga, A. Kuwayama, T. Matsumoto, A. Mori, T. Nishino (Kobe
University)
Lowering of surface free energy by introducing siloxane side chain to polythiophene

11:15-11:30

2CO06 J. Seo, T. C. Siu, I. T. Tran, S. Mau, A. Saran, J. Hernandez, N. Q. Nguyen, A.
Gonzalez, T. A. Su (University of California, Riverside)
Radical dimerization of sterically hindered saturated silicon clusters

11:30-11:45

2CO07 S.-M. Kang, J. K. Lee, H. Kweon, B.-S. Bae (KAIST)
Synthesis of low Dk/Df thermosetting phenyl functionalized siloxane polymer forhigh frequency transmission system

11:45-12:00

2CO08 T. Hirai, T. Mure, H. Sakai, S. Fujii, Y. Nakamura (Osaka Institute ofTechnology)
Preparation of chiral silica using linear polysiloxane with preferred-handed helicalconformation
Lunch

Chair: Huie Zhu
13:20-13:35

2CO10 N. D. Vu,1 A. Boulegue-Mondière,2 N. Durand,2 J. Raynaud,1 V. Monteil1(1CNRS-Université Lyon 1-CPE Lyon, 2 Elkem Silicones)
Low-temperature chemical recycling of any silicone waste to produce chlorosilanes

13:35-13:50

2CO11 D. C. Webster, D. Boucher, M. Safaripour (North Dakota State University)
Studies of miscibility of silicone oils in model silicone elastomers

ISOS-20 / ASiS-9

Oral Program

Chair: Dean C. Webster
13:50-14:05

2CO12 A. Camacho-Ramírez,1 M. Meléndez-Zamudio,2 G. Palestino,3 J. Cervantes,1
A. Guerra-Contreras1 (1University of Guanajuato, 2McMaster University,
3
Autonomous University of San Luis Potosí)Encapsulation and controlled release of curcumin by silicone amphiphilic copolymers
micelles

14:05-14:20

2CO13 J. Wolf,1,2 P. M. Danner,1,2 J. von Szczepanski,1,2 D. M. Opris1,2 (1EMPA, 2
ETH Zurich)End-functionalized high dielectric permittivity polysiloxanes for solvent-freeprocessing
Coffee Break

Chair: Norihisa Fukaya
14:55-15:15

2CI01 M. Ogawa (Vidyasirimedhi Institute of Science and Technology)
Surface modification of functional particle with silane coupling reagents

15:15-15:30

2CO14 V. Tomina,1 N. Stolyarchuk,1 V. Kyshkarova,2 M. Vaclavikova,2 O.
Semeshko,2 I. Melnyk2 (1NAS of Ukraine, 2Institute of Geotechnics SAS)
Spherical silica-based adsorbents with functionalized surfaces for industrial water
treatment

Chair: Ichiro Imae
15:30-15:45

2CO15 Y. Zuo (University of Jinan)
Polysiloxane-based materials for bioimaging

15:45-16:00

2CO16 M. Y. Wu, X. Y. Xu, Y. X. Guo, Y. H. Zhu, X. L. Cai, W. F. Yu, R. X. Shi, Q. Z.
Zhu (Shandong University)
Linear-nonlinear rheological study of macro-nano Ag in-situ filled
polydimethylsiloxane

16:00-16:20

2CI02 Y. Liu,1 Z. Zheng,1 N. Yagafarov,1 R. Akashi,1 N. Adachi,1 M. Tokuda,1 M.
Katano,1 A. Endo,1 T. Chaiprasert,1 A. Ouali,2 N. Takeda,1 M. Unno1 (1Gunma
University, 2Univ. Montpellier, CNRS, ENSCM)
Advancing Janus tricyclic ladder-/cyclic siloxanes synthesis

ISOS-20 / ASiS-9

Oral Program

Tuesday May 14, 2024
Room D
Chair: Takashi Hamada
10:00-10:15

2DO01 J. Cao, S. Feng (Shandong University)
Preparation and application of multifunctional silicone sponges

10:15-10:30

2DO02 Y. Y. Hu, W. F. Yu, M. Y. Wu, X. Y. Xu, Y. X. Guo, Y. H. Zhu, X. L. Cai, R. X.
Shi, Q. Z. Zhu (Shandong University)
Improved selective extraction of 3,3’-dichlorobenzidine by molecularly imprinted
polysiloxane microspheres

10:30-10:45

2DO03 T. Wu, F. Zhou, G. Lai, Q. Chen (Hangzhou Normal University)
Preparation and properties of a silicone material with antimicrobial and antistatic
properties

10:45-11:00

2DO04 K. Matsukawa,1 M. Monda,2 Y. Noguchi,2 Y. Miyaji2 (1Kyoto Institute ofTechnology, 2Sakamoto Yakuhin Kogyo Co., Ltd.)
Flexible and surface functional coatings prepared by sol-gel hybrids withpolyglycerol-silane coupling agents
Chair: Kimihiro Matsukawa

11:00-11:15

2DO05 T. Gunji, C. Kamegai, H. Fujioka, K. Yamamoto (Tokyo University of
Science)
Preparation and characterization of proton-conductive polysilsesquioxanes

11:15-11:30

2DO06 Q. Zhu (Shandong University)
Design and synthesis of functional polysilsesquioxane materials

11:30-11:45

2DO07 T. Hamada,1,2 Y. Nakanishi,2,3 K. Okada,2,3 S. Mineoi,2,3 J. Ohshita2 (1Nagoya
University, 2Hiroshima University, 3Mazda Motor Corporation)
Polysilsesquioxane-based thermal insulating material
Lunch

Chair: Yoshiyuki Mizuhata
13:20-13:40

2DI01 S. Ishida, S, Honda, D. Yanagisawa, T. Iwamoto (Tohoku University)
Oxidation chemistry of silicon-silicon multiple bonded compounds

13:40-13:55

2DO08 M. Ludwig, S. Stigler, S. Inoue (Technische Universität München)
Alumanyl silanides: Reactivity of a polarized silicon aluminium bond with multiple
bond character
Chair: Shintaro Ishida

13:55-14:10

2DO09 K. Ota, R. Ohno, N. Nishimura, T. Matsuo (Kindai University)
Synthesis and reduction of aryl cyclotrisilenylium ion

ISOS-20 / ASiS-9

Oral Program

14:10-14:25

2DO10 K. Uchida,1 I. Uematsu,1 T. Iwamoto,2 E. Kwon,2 S. Yoshida,2 R. Kato,3 H.
Fukui3 (1Toshiba Corporation, 2Tohoku University, 3Kioxia Corporation)
Structures and reactions of explosive silanes and its hydrolyzed product

14:25-14:40

2DO11 F. J. Kiefer, S. Inoue (Technische Universität München)
Activation of carbonyl compounds by silylated disilenes
Coffee Break

Chair: Masaaki Nakamoto
14:55-15:15

2DI02 S. Khan (IISER Pune)
N-Heterocyclic silylene supported copper(I) aryl complexes: Multitasking Cu(I)synthon

15:15-15:30

2DO12 Q. Li, X. Li, H. Sun (Shandong University)
Synthesis of [PSi(silylene)P]-pincer cobalt complexes and their catalytic activity foralkene hydrosilylation reactions

Chair: Norio Nakata
15:30-15:45

2DO13 K. Mashima, H. Tsurugi (Osaka University)
Organosilicon compounds as unique salt-free reducing reagents of metal compounds

15:45-16:00

2DO14 Q. Fan, H. Sun, X. Li (Shandong University)
Effects of silylene ligands on performance of unsaturated bond hydrosilylation
catalyzed by cobalt complexes

16:00-16:15

2DO15 K. Tomer, J. Rump, P. Palui, A. C. Filippou (University of Bonn)
Rh-Si triple bonds: The bis(silylidyne) complex [Rh(SiTbb)2(PMe3)2]+

ISOS-20 / ASiS-9

Oral Program

Wednesday May 15, 2024
Room A
Chair: Tsukasa Matsuo
9:00-9:45

3AP01 T. Kato (Université de Toulouse, CNRS)
Highly unsaturated cationic Si(II)-complexes: Applications and perspectives
Chair: Jan Tillmann

10:00-10:30

3AK01 M. A. Brook, M. E. Noman, C. Fu, E. Donahue-Boyle, K. E. Silverthorne, A.
Li (McMaster University)
Silicone elastomers at end of life: Improving circularity

10:30-10:50

3AI01 A. Sarkar, D. Dasgupta, T. Dalavoy, A. Kandikkal, K. Mukherjee, B. Falk, S.
Nair, K. M. Lewis (Momentive Performance Materials Inc.)
Unexpected swelling of a fatty acid modified silicone gel in water caused bycooperativity of hydrogen bonding
Chair: Masafumi Unno

10:50-11:10

3AI02 J. Tillmann (Wacker Chemie AG)
Direct process for synthesis of methylchlorosilanes (MCS) is not enough to meet thedemand of building blocks for the supply chain of a modern silicone producer

11:10-11:30

3AI03 K. M. Lewis, L. M. S. Negi, R. Hebbar, T. Dalavoy, R. Farhan, V. Rohith, D.
Dasgupta, A. Sarkar (Momentive Performance Materials, Inc.)
Controlling the distribution of alkyl side chains on siloxane backbones to enhancecooperativity, non-covalent interactions, and mechanical properties
Chair: Masashi Kunitake

11:30-11:45

3AO01 H. Zhu,1,2 Y. Yoshida,2 M. Mitsuishi2 (1Shanghai Optoelectronic Innovation
Center, 2Tohoku University)
Novel polysiloxanes derived from metal-free catalysis

11:45-12:00

3AO02 T. Miyata, Y. Inoue, M. Togawa, A. Kawamura (Kansai University)
Amphiphilic liquid crystalline polysiloxane self-assemblies

ISOS-20 / ASiS-9

Oral Program

Wednesday May 15, 2024
Room B
Chair: Christoph Marschner
10:00-10:20

3BI01 T. Sasamori, Y. Pan, H. Ueno (University of Tsukuba)
Generation of bis(ferrocenyl)silylenes

10:20-10:40

3BI02 F. Lips (Universität Münster)Synthesis and reactivity of amino-substituted silicon ring and cluster compounds
Chair: Takahiro Sasamori

10:40-10:55

3BO01 T. Kuwabara,1 S. Ito,2 K. Kobayashi,1 Y. Ishii2 (1Ochanomizu University,
2
Chuo University)
Hyperconjugative antiaromaticity of dianionic dibenzosilepins

10:55-11:10

3BO02 B. Peerless, S. Wei, Y. Lohse, J. Rienmüller, S. Dehnen (Karlsruhe Institute ofTechnology)
Insight into the redox behavior of anionic pseudo-tetrahedral p-block clusters

11:10-11:30

3BI03 H. Hashimoto (Tohoku University)
Neutral silylyne complexes with M≡Si triple bonds: cooperativity in the reactions
with small molecules

11:30-12:00

3BK01 A. C. Filippou, K. Tomer, T. Deckstein, P. Palui, J. Rump (University of Bonn)
Ditetrylynes as Ylidyne Transfer Reagents in Transition Metal ChemistryISOS-20 / ASiS-9

Oral Program

Wednesday May 15, 2024
Room C
Chair: Dengxu Wang
10:00-10:20

3CI01 I. Shin,1 Y.-Z. Yan,1,2 C.-S. Ha1 (1Pusan National University, 2Hainan
University)
Polysilsesquioxane as a nanofiller for polymer base hybrid nanomaterials

10:20-10:35

3CO02 J. Castets,1 L. Roach,1 E. Morvan,2 D. Montero,3 M. Treguer-Delapierre,1 G. L.
Drisko1 (1CNRS, 2CNRS, INSERM, 3Sorbonne Université)
Engineering pore structure in silica thin films via precursor reactivity
Chair: Chang-Sik Ha

10:35-10:50

3CO03 D. Wang, S. Feng, H. Liu (Shandong University)
Cyclosiloxane-linked fluorescent porous polymers for multifunctional chemicalsensors

10:50-11:05

3CO04 T. Hayashi, K. Kuroda, A. Shimojima (Waseda University)
Incorporation of cage germoxanes into siloxane-based materials for tuning their porecharacteristics

11:05-11:20

3CO05 M. Pérez, A. Medina, B. Ruiz, J. Guerra (Universidad de Guanajuato)
Synthesis of nanozeolites and their evaluation as a remineralizing agent in restorative
dentistryISOS-20 / ASiS-9

Oral Program

Wednesday May 15, 2024
Room D
Chair: Chuan He
10:00-10:20

3DI01 R. Shintani (Osaka University)
Copper-catalyzed silylfunctionalization of alkynes

10:20-10:35

3DO01 N. Nishina,1 M. Hamamura,1 K. Kimoto,1 T. Bürgi2 (1Shizuoka University,
2
University of Geneva)
Super-efficient hydrosilylation of alkynes catalyzed by gold clusters

10:35-10:50

3DO02 S. Ito, K. Sekine, D. Akaishi (Tokyo Institute of Technology)
Copper-catalyzed enantioselective hydrosilylation of gem-difluorocyclopropenes

10:50-11:05

3DO03 A. Vivien,1 L. Veyre,1 R. Mirgalet,2 C. Camp,1 C. Thieuleux1 (1Université deLyon, 2Elkem Silicones)
Original non-noble metal nanoparticles and structurally simple complexes aspromising catalysts for olefin hydrosilylation reactions
Chair: Ryo Shintani

11:05-11:20

3DO04 M. Morisue, W. Nakamura, M. Nakamura, N. Ohono (Kyoto Institute ofTechnology)
Hiyama-type Sonogashira cross-coupling reaction driven by siloxane formation

11:20-11:35

3DO05 Y. Naganawa,1 H. Kameo,2 Y. Nakajima1,3 (1AIST, 2Osaka Metropolitan
University, 3Tokyo Institute of Technology)
Selective synthesis of monochlorosilanes via palladium-catalyzed cross-coupling ofpolychlorosilanes with alkylaluminum reagents

ISOS-20 / ASiS-9

Oral Program

Thursday May 16, 2024
Room A
Chair: Keiji Kabeta
9:00-9:45

4AP01 B. Arkles,1,2 A. E. Kaloyeros2 (1Temple University, 2Kalark Nanostructure
Sciences, Inc.)
Near-zero thickness silicon-based thin film chemistry and processes
Chair: Hideyuki Nakano

10:00-10:30

4AK01 M. Wagner, M. Bamberg, B. Köstler (Goethe-Universität Frankfurt)News from silafullerane and Si,Ge-heteroadamantane clusters

10:30-10:50

4AI01 G. L. Drisko,1 M. Parker,1 M. L. De Marco,1 C. Cibaka-Ndaya,1 J. G.-C.
Veinot,2 I. L. Roiban,3 M. Gonidec,1 P. Rosa1 (1Univ. Bordeaux, CNRS, 2University ofAlberta, 3Univ. Lyon)
The chemistry behind creating optically resonant nanoparticles
Chair: Kazuo Tanaka

10:50-11:10

4AI02 Y. T. Park (Keimyung University)
Synthesis and electrochemical properties of silole-containing materials for lithium-ion
batteries

11:10-11:30

4AI03 M. L. Tang,1 K. Wang,1 N. Nguyen,2 J. Brennan,3 R. Frontiera,3 T. Su2(1University of Utah, 2University of California, Riverside, 3University of Minnesota)
Silicon nanocrystals for photon upconversion: tuning the electronic coupling withmolecular triplet acceptors
Lunch

Chair: Yoichiro Kuninobu
13:20-13:50

4AK02 L. Fensterbank (Collège de France)
Organosilicon derivatives for radical chemistry and organometallic catalysis

13:50-14:05

4AO01 J. Shimokawa, K. Hitoshio, H. Saito, H. Yorimitsu (Kyoto University)
Unveiling the potential of dioxasilepanyl: a seven-membered dialkoxysilyl group andits distinctive synthetic utility
Chair: Jun Shimokawa

14:05-14:20

4AO02 A. V. Arzumanyan (Russian Academy of Sciences)
Catalytic approaches for synthesis of functional organosilicon compounds

14:20-14:40

4AI04 Y. Kuninobu (Kyushu University)
Synthesis of silicon-containing π-conjugated molecules based on C–H and Si–H
transformations
Coffee BreakISOS-20 / ASiS-9

Oral Program

Chair: Katsuhiko Tomooka
14:55-15:10

4AO03 T. Kawashima,1 H. Arii2 (1Gunma University, 2University of Miyazaki)
Reactions of silyl cations generated from 4- and 5-hydrosilyl-1-methyl-1H-indoles
with alkynes

15:10-15:30

4AI05 C. He (Southern University of Science and Technology)
Catalytic asymmetric dehydrogenative coupling toward Si-stereogenic silanes
Chair: Hajime Ito

15:30-16:00

4AK03 K. Tomooka (Kyushu University)
Chemistry of chiral silicon molecules

16:00-16:15

4AO04 I. K. Goncharova, A.V. Arzumanyan (Russian Academy of Sciences)[M]-/Organo-catalyzed aerobic Si–H- and C–H-functionalization as the green way forthe preparation of functionalized organosilicon compounds
Chair: Michinori Suginome

16:30-17:15

4AP02 T. Hiyama (Chuo University)
Silicon-based cross coupling reactionISOS-20 / ASiS-9

Oral Program

Thursday May 16, 2024
Room B
Chair: Ryan J. Trovitch
10:00-10:15

4BO01 S. Marl, K. Klier, A. Rüppel, R.-U. Giesen, H.-P. Heim (University of Kassel)
Determination of the cross-linking system of high consistency silicone elastomers
using TGA and FTIR

10:15-10:35

4BI01 A. Shimojima (Waseda University)
Design of novel silicone-based elastomers utilizing silica-based nanoparticles
Chair: Atsushi Shimojima

10:35-10:55

4BI02 R. J. Trovitch (Arizona State University)
Promise and limitations of silane diamine and siloxane diamine copolymers

10:55-11:10

4BO02 D. A. Bellido-Aguilar, M. Safaripour, K. VanDonselaar, L.-S. C. Ndunagum,
M. Nazem Salimi, D. C. Webster, A. B. Croll (North Dakota State University)
The adhesion of silicone elastomers to glass and ice

11:10-11:25

4BO03 K. Kanamori, R. Ueoka, R. Miyamoto (Kyoto University)
Silicone-based aerogels that show mechanical flexibility
Lunch

Chair: Yujia Liu
13:20-13:35

4BO04 D. Kawaguchi, H. Lu (The University of Tokyo)
Surface reconstruction of a cross-linked poly(dimethylsiloxane) film associated with
CO2 exposure

13:35-13:50

4BO05 M. Kunitake, A. Mori, A. Pathak, S. Watanabe (Kumamoto University)
Recycling of necklace-shaped polydimethylsiloxanes based on reversible dimerizationof anthracene units

13:50-14:05

4BO06 J. Noguchi, K. Takashima, K. Kubo, S. Kume, T. Mizuta (Hiroshima
University)
Depolymerization reaction of silicone grease catalyzed by phosphido-bridged
binuclear Pd(I) complex
Chair: Daisuke Kawaguchi

14:05-14:20

4BO07 K. Kitazawa, Y. Tabata (Shin-Etsu Chemical Co., Ltd.)
Novel addition curing system to build cross-linked organopolysiloxane utilizing
cyclotrimerization of alkynes

14:20-14:35

4BO08 T. Otake, O. Tamura (Momentive Performance Materials Japan LLC)
Silicone optical bonding for automotive display
Coffee BreakISOS-20 / ASiS-9

Oral Program

Chair: Tsutomu Mizuta
14:55-15:15

4BI03 N. W. Kinzel,1 M. Cypryk,2 J. Kurjata,2 M. Kwiatkowska,2 G. Mielniczak,2 U.
Mizerska,2 K. Piórecka,2 S. Rubinsztajn2 (1Wacker Chemie AG, 2PAS)
Cationic Cp*Ge(II) species as alkoxysil(ox)ane coupling catalysts

15:15-15:30

4BO09 S. Milenin,1,2 K. Bezlepkina,1,2 I. Belikova,1,3 V. Aristova,1,3 K. Klokova,1,2 K.
Bakanov,1,2 S. Ardabevskaia,1,2 F. Drozdov,1,2 D. Migulin,1 A. Muzafarov1,4 (1Tula
State Lev Tolstoy Pedagogical University, 2Enikolopov Institute of Synthetic
Polymeric Materials of Russian Academy of Sciences, 3Mendeleev University ofChemical Technology of Russia, 4RAS)
CuAAC strategy for the preparation of functional organosilicon monomers andpolymers

Chair: Niklas Kinzel
15:30-15:45

4BO10 F. V. Drozdov, A.I. Ryzhkov, P. D. Shkinev, S. A. Milenin, S. N.
Ardabievskaya, K. A. Bezlepkina, G. V. Cherkaev, A. M. Muzafarov (Russian
Academy of Sciences)
Functional siloxanes - new approaches to synthesis and prospects for their application

15:45-16:00

4BO11 A. Khmelnitskaia, A. Kalinina, S. Ponomarenko, A. Muzafarov (Enikolopov
Institute of Synthetic Polymeric Materials)
Synthesis of vinyl-containing PDMS in an active medium

ISOS-20 / ASiS-9

Oral Program

Thursday May 16, 2024
Room C
Chair: Kazushi Mashima
10:00-10:15

4CO01 M. Scheer, A. E. Seitz, M. Eckhardt, M. Piesch, S. Reichl, C. Riesinger(University of Regensburg)
Pathways to Si-containing group 15 element cages and cycles

10:15-10:30

4CO02 Y. Suga, Y. Sunada (The University of Tokyo)
Carbon–heteroatom double bonds cleavage by iron disilyl complexes

10:30-10:45

4CO03 N. S. Willeit, W. Klein, P. Coburger, E. Fritz-Langhals, T. F. Fässler (Technical
University of Munich)
Functionalized [Ge9Ni0] clusters as homogeneous single-site catalysts
Chair: Manfred Scheer

10:45-11:00

4CO04 K. Nagata, H. Omura, H. Tobita, H. Hashimoto (Tohoku University)
Photoinduced one-pot synthesis of a chromium germylyne complex and its formation
mechanism11:00-11:15

4CO05 C. Fontanilla,1 K. Nagata,1 Y. Shimizu,2 S. Mori,2 H. Hashimoto1 (1Tohoku
University, 2Ibaraki University)
Molybdenum−germanium triple−bonded complex as catalyst for hydroboration ofcarbonyl substrates

11:15-11:30

4CO06 G. I. Nikonov (Brock University)
Si(0) complex with ambiphilic reactivity
Lunch

Chair: Dmitry Bravo-Zhivotovskii
13:20-13:35

13:35-13:50

4CO07 Y. Tu, Y. Inagaki, W. Setaka (Tokyo Metropolitan University)
Simultaneous synthesis and characterization of disilabicycloalkanes
tetrasilatricycloalkanes

and4CO08 T. Asakawa, K. Sugamata, M. Minoura (Rikkyo University)
Synthesis and properties of a linear 2-germapropadiene
Chair: Alexander Hinz

13:50-14:05

4CO09 C.-H. Liu, T. Müller (Carl von Ossietzky University Oldenburg)
Silole and germole anions substituted with stabilized silylenes

14:05-14:20

4CO10 M. Murai (Nagoya University)
Si, Ge, and Sn-bridged -conjugated carbocations: Azulene-fusing strategy fordesigning near-infrared dyes

ISOS-20 / ASiS-9

Oral Program

4CO11 D. Bravo-Zhivotovskii, Y. Goldshtein, Y. Glagovsky, Y. Apeloig(Technion-Israel Institute of Technology)
Elimination of lithium silanolate from heavy enolates as an efficient route to
Li(R)E=C(R'2) (E=Si, Ge) reagents
Coffee Break

Chair: Maxim Bermeshev
14:55-15:15

4CI01 K. Hanaoka (Keio University)
Development of far-red to near-infrared Si-rhodamines and their application to
fluorescence probes

15:15-15:30

4CO12 M. Haas, M. Drusgala, T. Lainer, G. Glotz, G. Gescheidt (Graz University ofTechnology)
Synthesis and photochemical investigation of novel acyl-metalloids

Chair: Masahito Murai
15:30-15:45

4CO13 K. M. Frankiewicz, T. F. Fässler (Technical University of Munich)Anything but static - unexpected dynamic behaviour of uncharged mixed silicon
germanium Zintl type clusters

15:45-16:00

4CO14 P. Lezhnin, M. Guseva, D. Alentiev, E. Bermesheva, M. Bermeshev (RAS)
Bis-silylation of norbornadiene as a versatile and simple approach to the preparationof Si-substituted norbornene-type monomers

ISOS-20 / ASiS-9

Oral Program

Thursday May 16, 2024
Room D
Chair: Louis Gabriel Fensterbank
10:00-10:20

4DI01 D. Zhao (Nankai University)
Synthesis and applications of silicon-containing small molecules

10:20-10:35

4DO01 D. Hayashi, T. Tsuda, R. Shintani (Osaka University)
Palladium-catalyzed skeletal rearrangement of silylaryl triflates via C–Pd/C–Si bondexchange

10:35-10:50

4DO02 M. Majumdar (Indian Institute of Science Education and Research)
Reductively disilylated N-heterocycles as versatile reagent in material syntheses andorganic transformations
Chair: Dongbing Zhao

10:50-11:05

4DO03 K. Igawa,1 A. Kuroo,3 D. Yoshihiro,3 T. Kakigi,3 Y. Abe,3 K. Tomooka2(1Kumamoto University, 2,3Kyushu University)
Synthetic application of silacyclopentenols as versatile chiral-pool for chiral silacycles

11:05-11:20

4DO04 J. Walkowiak, A. Franczyk, K. Stefanowska, T. Sokolnicki (Adam Mickiewicz
University)
Sustainable and highly selective approaches to saturated and unsaturated organosiliconcompounds

11:20-11:35

4DO05 Y. Kawasaki,1 K. Igawa,2 K. Tomooka1 (1Kyushu University, 2Kumamoto
University)
Synthesis of silylalkene and its ozone oxidation
Lunch

Chair: Eka Lutfi Septiani
13:20-13:40

4DI02 H. Nakano (Kindai University)
Silicon and germanium nanosheets for nanodevices

13:40-13:55

4DO06 P. D. Lickiss,1 S. Tian,1 M. Abbas,1 R. P. Davies,1 A. J. P. White1, P. Horton2(1Imperial College, 2University of Southampton)
Metal-organic framework construction using Si and Ge linkers
Chair: Paul Lickiss

13:55-14:10

4DO07 J. G. C. Veinot, K. O’Connor, A. Rubletz (University of Alberta)
Friend or foe: Unraveling the SiO evolution reaction and how it impacts siliconquantum formation

14:10-14:25

4DO08 E. L. Septiani, T. Hirano, T. Ogi (Hiroshima University)
Silica coating on soft-magnetic metal particles prepared by one-step aerosol process

ISOS-20 / ASiS-9
14:25-14:40

Oral Program

4DO09 K. L. A. Cao, T. Ogi (Hiroshima University)
Innovative synthesis of carbon−coated SiOx particles as anode materials forlithium-ion batteries
Coffee Break

Chair: Jonathan Veinot
14:55-15:10

4DO10 M. A. Parker,1 M. L. De Marco,1 A. Ghoridi,2 D. Portehault,2 P. Rosa,1 M.
Gonidec,1 G. L. Drisko1 (1Univ. Bordeaux, 2Sorbonne Université)
Redox reaction between a silicon Zintl phase and coordination complex to form
silicon particles of tunable size

15:10-15:25

4DO11 M. I. Aguirre Cardenas, T. C. Siu, A. E. Pimentel, M. O. Hight, M. G.
Shimono, S. Thai, V. Carta, T. A. Su (University of California, Riverside)
Synthesis of silicon-germanium and germanium adamantanes

15:25-15:40

4DO12 C. Yom, N. Garcia, C. Trochez, Q. Johnson, B. P. S. Chauhan (William
Paterson University of New jersey)
Pt-nanoparticle catalyzed ring-opening polymerization of strained cyclic silanes

ISOS-20 / ASiS-9

Oral Program

Friday May 17, 2024
Room A
Chair: Norihiro Tokitoh
9:00-9:45

5AP01 K. M. Baines (Western University)
From Kipping to Kim and lessons learned along the way

9:45-10:00

Closing Ceremony