Product Name: SW-110 ink
SDS No. 037-U146958
First issue: 2021/07/28
Revised:2022/01/18

Safety Data Sheets
1.

Identification

Product Name

: SW-110 ink

Order No.

: SW110-Z-BA

General Use: Ink for ink jet printer

Product Description: UV curable ink

SDS Number: 037- U146958

Manufacture
Company Name

: Mimaki Engineering Co., Ltd.

Address: 2182-3 Shigeno-otsu, Tomi-shi, Nagano 389-0512 JAPAN

Telephone No.

: +81-268-64-2413

Importer / Distributor Established in USA
Company Name

: MIMAKI USA, INC.

Address: 150 Satellite Boulevard NE , suite A, Suwanee, Georgia 30024,
U.S.A.

Telephone No.

: +1-678-730-0170

Emergency Telephone No.

: +1 866 928 0789 (within United States only, Toll free)+1 215 207 0061

2.

Hazards Identification[HCS Classification]
Physical Hazards
Flammable Liquids: Not classifiedHealth Hazards
Acute Toxicity – Oral

: Catgory 4

Skin Corrosion / Irritation: Catgory 2

Eye Damage / Irritation: Catgory 1

Sensitization – Skin

: Catgory 1A

Toxic to Reproduction: Catgory 2

Specific Target Organ Toxicity: Catgory 2 (peripheral nervous system, kidneys,(Repeated Exposure)liver, blood)

Environmental Hazards
Hazardous to the Aquatic: Catgory 2

Environment - Acute Hazard

Page 1 of 13

Product Name: SW-110 ink
SDS No. 037-U146958
First issue: 2021/07/28
Revised:2022/01/18

Safety Data Sheets
Hazardous to the Aquatic: Catgory 2

Environment - Long Term Hazard
The above list does not include category being non-classifiable or not-applicable.
[HCS Label Elements]
SymbolSignal Word
DangerHazard Statements
H302 Harmful if swallowed.
H315 Causes skin irritation.
H319 Causes serious eye damage.
H317 May cause an allergic skin reaction.
H361 Suspected of damaging fertility or the unborn child.
H373 May cause damage to organs through prolonged or repeated exposure(peripheral nervous system, kidneys, liver, blood).
H411 Toxic to aquatic life with long lasting effects.
Precautionary Statements[Prevention]
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P260 Do not breathe dust/fume/gas/mist/vapors/spray.
P264 Wash thoroughly after handling.
P272 Contaminated work clothing should not be allowed out of the workplace.
P270 Do not eat, drink or smoke when using this product.
P273 Avoid release to the environment.
[Response]
P308+P313 IF exposed or concerned: Get medical advice/attention.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER or doctor.
P302+P352 IF ON SKIN: Wash with plenty of soap and water.
P362+P364 Take off contaminated clothing and wash before reuse.
P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feelunwell.
P330 Rinse mouth.
P391 Collect spillage.
[Storage]
Page 2 of 13

Product Name: SW-110 ink
SDS No. 037-U146958
First issue: 2021/07/28
Revised:2022/01/18

Safety Data Sheets
P405 Store locked up.

[Disposal]
P501 Dispose of contents/container in accordance with local/regional/national/international
regulation (to be specified).
Statement(s) of Unknown Acute Toxicity
Oral 62% of the mixture consists of ingredient(s) of unknown acute toxicity.
Statement(s) of Unknown Aquatic Toxicity
0% of the mixture consists of ingredient(s) of unknown acute aquatic toxicity.
0% of the mixture consists of ingredient(s) of unknown chronic aquatic toxicity.
Other Hazards
None known.
NFPA Rating (scale 0 – 4)
Health = 2

1

Flammability = 1

2Instability = 0
Special =3.

0Composition / Information on IngredientsNo

Chemical Name

Wt%

1

Glyceryl polypropylene glycol triether

40-50

25791-96-22Morpholine, 4-(1-oxo-2-propenyl)-30-40

5117-12-4

1-1075980-60-8

1-10

112-35-6

3

Diphenyl-2,4,6-trimethylbenzoyl phosphine
oxide

4

Triethylene glycol monomethyl ether

CAS No.

The chemical identity and/or percentage of composition is being withheld as a trade secret.
4.

First Aid Measures

Inhalation: Remove person to fresh air and keep comfortable for breathing. Giveartificial respiration if not breathing. Call a POISON CENTER or
doctor/physician.

Eye Contact: Flush eyes immediately with large amounts of water. Remove
contact lenses, if present and easy to do. Continue rinsing. Then get
immediate medical attention.

Skin Contact: Wash with plenty of soap and water. If skin irritation or rash occurs:
Get medical advice/attention. Take off contaminated clothing andPage 3 of 13

Safety Data Sheets

Product Name: SW-110 ink
SDS No. 037-U146958
First issue: 2021/07/28
Revised:2022/01/18

wash before re-use.
Ingestion: If swallowed, get medical attention. If vomiting occurs, keep headlower than hips to help prevent aspiration. Rinse mouth.

Most Important Symptoms/Effects
Acute: Harmful if swallowed, skin irritation, eye damage, allergic skinreaction.

Delayed: allergic skin reaction, reproductive effects, peripheral nerve systemdamage, kidney damage, liver damage, blood disorders.

Indication of Immediate: Treat symptomatically and supportively.

Medical Attention andSpecial Treatment
Needed, If Needed
5.

Fire Fighting Measures

Flammable Properties: Flash Pont: >93 °C

Extinguishing Media: carbon dioxide, regular dry chemical, water spray, alcohol resistantfoam.

Unsuitable Extinguishing: Do not scatter spilled material with high-pressure water streams.

Media
Special Hazards Arising: Irritating fumes and gases may be released upon thermal processing

from the Chemicalor during combustion.

Hazardous Combustion: oxides of carbon, oxides of nitrogen.

Products
Fire Fighting Measures: Move container from fire area if it can be done without risk. Do not
scatter spilled material with high-pressure water streams. Coolcontainers with water spray until well after the fire is out. Stay awayfrom the ends of tanks. Avoid inhalation of material or combustion
by-products.

Special Protective: Wear full protective fire fighting gear including self contained

Equipment andbreathing apparatus (SCBA) for protection against possible exposure.

Precautions for
Firefighters
6.

Accidental Release Measures

Page 4 of 13

Safety Data Sheets
Personal Precautions,

Product Name: SW-110 ink
SDS No. 037-U146958
First issue: 2021/07/28
Revised:2022/01/18: Wear personal protective clothing and equipment, see Section 8.

Protective Equipment
and Emergency
Procedures
Methods and Materials: Eliminate all ignition sources if safe to do so. Stop leak if possible

for Containment andwithout personal risk. Reduce vapors with water spray.

Cleaning Up

Small spills: Absorb with sand or other non-combustible material.
Collect spilled material in appropriate container for disposal.
Large spills: Dike for later disposal. Keep unnecessary people away,
isolate hazard area and deny entry. Stay upwind and keep out of low
areas.

Environmental: Avoid release to the environment.

Precautions
7.

Handling and Storage

Precautions for Safe

: Obtain special instructions before use. Do not handle until all safety

Handling

precautions have been read and understood. Do not breathe vapor or
mist. Use only outdoors or in a well-ventilated area. Avoid contact witheyes, skin and clothing. Do not eat, drink, or smoke when using thisproduct. Wear protective gloves/clothing and eye/face protection. Wash
thoroughly after handling. Contaminated work clothing should not beallowed out of the workplace.

Conditions for Safe

: Store locked up.

Storage, including any

Store and handle in accordance with all current regulations andIncompatibilities

standards. Keep separated from incompatible substances.

Incompatible Materials: acids, bases, metals, oxidizing materials, metal oxides.

8.

Exposure Controls / Personal Protection

Exposure Limit Values: The following constituents are the only constituents of the productwhich have a PEL, TLV or other recommended exposure limit. At thistime, the other constituents have no known exposure limits.

ACGIH - Threshold Limit: Biological Exposure Indices (BEI)

ValuesThere are no biological limit values for any of this product's
Page 5 of 13

Product Name: SW-110 ink
SDS No. 037-U146958
First issue: 2021/07/28
Revised:2022/01/18

Safety Data Sheetscomponents.
Exposure Controls
Occupational Exposure Controls
Appropriate: Provide local exhaust or process enclosure ventilation system.

Engineering Controls

Ensure adequate ventilation.

Individual Protection Measures, such as Personal Protective Equipment
Respiratory Protection: Consult with a health and safety professional for specific respirators
appropriate for your use.

Glove

: Wear appropriate chemical resistant gloves.

Recommendations

Eye /Face: Wear splash resistant safety goggles with a faceshield.

Protection

Skin Protection

Protective Materials: Wear appropriate chemical resistant clothing.

: Provide an emergency eye wash fountain and quick drench showerin the immediate work area.

9.

Physical and Chemical Properties

Appearance- Physical State: liquid- Color: clear , light yellow

Odor: peculiar odorpH

: Not available

Boiling Point / Boiling Range: Not available

Melting Point / Melting Range: Not available

Decomposition Temperature: Not available
Page 6 of 13

Product Name: SW-110 ink
SDS No. 037-U146958
First issue: 2021/07/28
Revised:2022/01/18

Safety Data Sheets
Flash Point: >93 °C

Auto ignition temperature: Not available

Flammability (Solid, Gas)

: Not available

Explosive Properties: Not available

Oxidizing Properties: Not available

Upper / Lower Flammability or: Not available

Explosive Limits
Vapor Pressure: Not available

Specific Gravity (water=1): 1.07 (25 °C )Water Solubility: Not available

Partition Coefficient (n-octanol / Water): Not available

Viscosity: 66 ±3 mPa・s (25 °C )Vapor Density: Not available

Evaporation Rate

: Not available

10. Stability and Reactivity
Reactivity: No reactivity hazard is expected.

Chemical Stability: Stable under normal conditions of use.

Possibility of Hazardous: Will not polymerize.

Reactions
Conditions to Avoid: Avoid flames, sparks, and other sources of ignition. Avoid contact
with incompatible materials.

Incompatible Materials: oxidizing materials, strong acids, strong bases.

Hazardous: oxides of carbon, oxides of nitrogen.

Decomposition
11. Toxicological Information
Information on Likely Routes of Exposure
Inhalation: irritation, organ damage.

Ingestion: harmful if swallowed, irritation, organ damage

Skin Contact: irritation, allergic skin reaction.

Eye Contact: eye damage.

Acute and Chronic Toxicity
Page 7 of 13

Safety Data Sheets

Product Name: SW-110 ink
SDS No. 037-U146958
First issue: 2021/07/28
Revised:2022/01/18

Component Analysis -: The components of this material have been reviewed in various

LD50/LC50

sources and the following selected endpoints are published.
Glyceryl polypropylene glycol triether (25791-96-2)
Oral LD50 Rat 2830 µL/kg
Dermal LD50 Rabbit >20 mL/kg
Triethylene glycol monomethyl ether (112-35-6)
Oral LD50 Rat 11300 µL/kg
Product Toxicity Data - Acute Toxicity Estimate
Oral: 500 mg/kg

Immediate Effects: Harmful if swallowed, skin irritation, eye damage, allergic skinreaction.

Delayed Effects: allergic skin reaction, reproductive effects, peripheral nerve systemdamage, kidney damage, liver damage, blood disorders.

Irritation/Corrosivity: skin irritation, eye damage.

Data
Respiratory: No information available for the product.

Sensitization
Dermal Sensitization: May cause an allergic skin reaction.

Germ Cell: No information available for the product.

Mutagenicity
Tumorigenic Data

: No information available for the product.

Carcinogenicity: No information available for the product.
: Component Carcinogenicity
None of this product's components are listed by ACGIH, IARC, NTP,DFG or OSHA.

Reproductive Toxicity: Available data characterizes components of this product asreproductive hazards.

Specific Target Organ: No target organs identified.

Toxicity - Single
Exposure
Specific Target Organ: peripheral nervous system, kidneys, liver, blood.

Toxicity - Repeated
Exposure
Aspiration Hazard: Not expected to be an aspiration hazard.

Medical Conditions: No information available for the product.

Aggravated by Exposure
Page 8 of 13

Product Name: SW-110 ink
SDS No. 037-U146958
First issue: 2021/07/28
Revised:2022/01/18

Safety Data Sheets
12. Ecological Information

Handling is noted because it might influence the environment when leaking and abandoning it.
Especially, note that the product doesn't flow directly to ground, the river, and the drain ditch.
Ecotoxicity: Product Acute toxicity data: L(E)C50: >1 to <= 10 mg/L (estimated)

Component Analysis -: Triethylene glycol monomethyl ether (112-35-6)

Aquatic Toxicity

Fish: LC50 96 h Brachydanio rerio >5000 mg/L [static ];LC50 96 h Pimephales promelas >10000 mg/L [static ]Algae: EC50 72 h Desmodesmus subspicatus >500 mg/L IUCLID
Invertebrate: EC50 48 h Daphnia magna >500 mg/L IUCLID

Persistence and: No information available for the product.

Degradability
Bioaccumulation: No information available for the product.

Mobility: No information available for the product.

Other Toxicity: No information available for the product.

13. Disposal Considerations
Disposal Methods: Comply with all USA, national and local regulations.
Do not dump this product into sewers, on the ground or into any bodyof water.

Component Waste: The U.S. EPA has not published waste numbers for this product's

Numbers

components.

Disposal of: Empty containers may contain product residue. Dispose inContaminatedaccordance with all applicable regulations.

Packaging
14. Transport Information
Check a thing without a leak in a container.
Perform prevention of collapse of cargo surely.
Marine Pollutants: Yes (As a product)

IATA Information: Shipping Name: ENVIRONMENTALLY HAZARDOUS
SUBSTANCE, LIQUID, N.O.S. , ( Contains:
DIPHENYL(2,4,6-TRIMETHYLBENZOYL)PHOSPHINE OXIDE )Hazard Class: 9
Page 9 of 13

Safety Data Sheets

Product Name: SW-110 ink
SDS No. 037-U146958
First issue: 2021/07/28
Revised:2022/01/18

UN#: UN3082
Packing Group: III
Required Label(s): 9
Marine pollutant
ICAO Information: Shipping Name: ENVIRONMENTALLY HAZARDOUS
SUBSTANCE, LIQUID, N.O.S. , ( Contains:
DIPHENYL(2,4,6-TRIMETHYLBENZOYL)PHOSPHINE OXIDE )Hazard Class: 9
UN#: UN3082
Packing Group: III
Required Label(s): 9
Marine pollutant

IMDG Information: Shipping Name: ENVIRONMENTALLY HAZARDOUS
SUBSTANCE, LIQUID, N.O.S. , ( Contains:
DIPHENYL(2,4,6-TRIMETHYLBENZOYL)PHOSPHINE OXIDE )Hazard Class: 9
UN#: UN3082
Packing Group: III
Required Label(s): 9
Marine pollutant

US DOT Information: Shipping Name: ENVIRONMENTALLY HAZARDOUS
SUBSTANCE, LIQUID, N.O.S. , ( Contains:
DIPHENYL(2,4,6-TRIMETHYLBENZOYL)PHOSPHINE OXIDE )Hazard Class: 9
UN/NA #: UN3082
Packing Group: III
Required Label(s): 9
Marine pollutant

International Bulk

: This material contains one or more of the following chemicals

Chemical Coderequired by the IBC Code to be identified as dangerous chemicals inbulk.
Glyceryl polypropylene glycol triether (25791-96-2)
IBC Code: Category Z

Remarks: Single or inner packaging less than 5 L (liquid) or 5 kg net (solids) is
excepted from Dangerous Goods regulations.
Refer to ICAO/IATA A197, IMDG 2.10.2.7, ADR SP 375.
Page 10 of 13

Product Name: SW-110 ink
SDS No. 037-U146958
First issue: 2021/07/28
Revised:2022/01/18

Safety Data Sheets
15. Regulatory Information
U.S. Federal: This material contains one or more of the following chemicals

Regulations

required to be identified under SARA Section 302 (40 CFR 355
Appendix A), SARA Section 313 (40 CFR 372.65), CERCLA (40 CFR
302.4), TSCA 12(b), and/or require an OSHA process safety plan.
Morpholine, 4-(1-oxo-2-propenyl)- 5117-12-4
TSCA 12b: Section 5 , 1 % de minimus concentration EPA: P-95-0169

SARA Section 311/312: Acute toxicity; Reproductive Toxicity; Skin Corrosion/Irritation;(40 CFR 370 Subparts B

Respiratory/Skin Sensitization; Serious Eye Damage/Eye Irritation;

and C) reportingSpecific Target Organ Toxicity.

categories
U.S. State Regulations: None of this product's components are listed on the state lists from
CA, MA, MN, NJ or PA.

California Proposition 65: WARNING
This product can expose you to chemicals including Propyleneoxide, which is known to the State of California to cause
cancer. For more information go to www.P65Warnings.ca.gov.

Canada Regulations: Canadian WHMIS Ingredient Disclosure List (IDL)
The components of this product are either not listed on the IDL or arepresent below the threshold limit listed on the IDL.

Component Analysis – Inventory
Glyceryl polypropylene glycol triether (25791-96-2)
US

Yes

CA

DSL

EU

No

AU

Yes

PH

Yes

JP -

JP -

KR KECI -KR KECI -KR - REACH

CN

NZ

MX

TW

ENCS

ISHL

Annex 1

Annex 2

CCA

Yes

Yes

Yes

No

No

Yes

Yes

No

Yes

CN

NZ

MX

TW

Morpholine, 4-(1-oxo-2-propenyl)- (5117-12-4)
US

Yes

CA

NSL

EU

ELN

AU

Yes

PH

Yes

JP -

JP -

KR KECI -KR KECI -KR - REACH

ENCS

ISHL

Annex 1

Annex 2

CCA

Yes

Yes

No

Yes

No

Yes

Yes

No

Yes

KR - REACH

CN

NZ

MX

TW

Diphenyl-2,4,6-trimethylbenzoyl phosphine oxide (75980-60-8)
US

CA

EU

AU

PH

JP -

JP -

KR KECI -KR KECI -Page 11 of 13

Product Name: SW-110 ink
SDS No. 037-U146958
First issue: 2021/07/28
Revised:2022/01/18

Safety Data Sheets
Yes

DSL

EIN

Yes

Yes

ENCS

ISHL

Annex 1

Annex 2

CCA

Yes

Yes

Yes

No

No

Yes

Yes

Yes

Yes

CN

NZ

MX

TW

Yes

Yes

Yes

Yes

Triethylene glycol monomethyl ether (112-35-6)
US

Yes

CA

DSL

EU

EIN

AU

Yes

PH

Yes

JP -

JP -

KR KECI -KR KECI -KR - REACH

ENCS

ISHL

Annex 1

Annex 2

CCA

Yes

Yes

Yes

No

No

Further information
There is a component in this product subject to a SNUR. CAS #: 5117-12-4. However, if used as an
ink for a 3D printer, SNUR does not apply to this substance.
16. Other Information
Key / Legend
ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road
Transport; AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada;
CA/MA/MN/NJ/PA - California/Massachusetts/Minnesota/New Jersey/Pennsylvania*; CAS Chemical Abstracts Service; CERCLA - Comprehensive Environmental Response, Compensation,and Liability Act; CFR - Code of Federal Regulations (US); CLP - Classification, Labelling, andPackaging; CN - China; CPR - Controlled Products Regulations; DFG - Deutsche
Forschungsgemeinschaft; DOT - Department of Transportation; DSD - Dangerous SubstanceDirective; DSL - Domestic Substances List; EC – European Commission; EEC - European
Economic Community; EIN - European Inventory of (Existing Commercial Chemical Substances);
EINECS - European Inventory of Existing Commercial Chemical Substances; ENCS - Japan
Existing and New Chemical Substance Inventory; EPA - Environmental Protection Agency; EU European Union; F - Fahrenheit; IARC - International Agency for Research on Cancer; IATA International Air Transport Association; ICAO - International Civil Aviation Organization; IDL Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG International Maritime Dangerous Goods; ISHL - Japan Industrial Safety and Health Law;IUCLID - International Uniform Chemical Information Database; JP - Japan; Kow Octanol/water partition coefficient; KR KECI Annex 1 - Korea Existing Chemicals Inventory(KECI) / Korea Existing Chemicals List (KECL); KR KECI Annex 2 - Korea Existing Chemicals
Inventory (KECI) / Korea Existing Chemicals List (KECL) , KR - Korea; LD50/LC50 - Lethal
Dose/ Lethal Concentration; LEL - Lower Explosive Limit; LLV - Level Limit Value; LOLI - List
Of LIsts™ - ChemADVISOR’s Regulatory Database; MAK - Maximum Concentration Value in the
Workplace; MEL - Maximum Exposure Limits; MX – Mexico; NDSL – Non-Domestic Substance
Page 12 of 13

Safety Data Sheets

Product Name: SW-110 ink
SDS No. 037-U146958
First issue: 2021/07/28
Revised:2022/01/18

List (Canada); NFPA - National Fire Protection Agency; NIOSH - National Institute for
Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National
Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration;
PEL- Permissible Exposure Limit; PH - Philippines; RCRA - Resource Conservation and Recovery
Act; REACH- Registration, Evaluation, Authorisation, and restriction of Chemicals; RID European Rail Transport; SARA - Superfund Amendments and Reauthorization Act; STEL Short-term Exposure Limit; TCCA – Korea Toxic Chemicals Control Act; TDG - Transportation ofDangerous Goods; TLV - Threshold Limit Value; TSCA - Toxic Substances Control Act; TW –Taiwan; TWA - Time Weighted Average; UEL - Upper Explosive Limit; UN/NA - United Nations/North American; US - United States; VLE - Exposure Limit Value (Mexico); VN NCI (Draft) Vietnam National Chemicals Inventory (NCI) (Draft); WHMIS - Workplace Hazardous Materials
Information System (Canada). .
Disclaimer
This information is furnished without warranty, express or implied, except that it is accurate to
the best knowledge of Mimaki Engineering Corporation.
It relates only to the specific material designated herein, and does not relate to use in combination
with any other material or process.
Mimaki Engineering Corporation assumes no legal responsibility for use or reliance upon thisinformation.

Page 13 of 13