Product Name: Antifreeze
SDS No. 037-O042470
First issue: 2011/07/05
Revised: 2019/11/25

Safety Data Sheets
1.

Product and Company Identification

Product Name

: Antifreeze

Product Code: SPC-0394

General Use: General cold and heat medium(Food factory), ice storage
refrigerant

Product Description: Antifreeze

MSDS Number: 037-O042470

Manufacture
Company Name

: Mimaki Engineering Co., Ltd

Address: 2182-3 Otsu, Shigeno, Tomi-shi, Nagano 389-0512 Japan

Telephone No.

: +81-268-64-2413

Importer/Distributor Established in USA
Company Name

: MIMAKI USA. INC.

Address: 150 Satellite Boulevard NE , suite A, Suwanee, Georgia 30024,U.S.A.

Telephone No.

: +1-678-730-0170

Emergency Telephone No.

: +1 866 928 0789 (within United States only, Toll free)+1 215 207 0061

2.

Hazards Identification[HCS Classification]
Physical Hazards
Flammable Liquids: Not classifiedHealth Hazards
Acute Toxicity – Oral

: Not classified

Acute Toxicity – Dermal: Not classified

Skin Corrosion / Irritation: Not classified

Eye Damage / Irritation: Not classified

Sensitization – Respiratory: Not classified

Sensitization – Skin

: Not classified

Germ Cell Mutagenicity: Not classified

Specific Target Organ Toxicity: Not classified(Single Exposure)
Page 1 of 11

Product Name: Antifreeze
SDS No. 037-O042470
First issue: 2011/07/05
Revised: 2019/11/25

Safety Data Sheets
Specific Target Organ Toxicity: Not classified(Repeated Exposure)Environmental Hazards
Hazardous to the Aquatic: Not classified

Environment - Acute Hazard
Hazardous to the Aquatic: Not classified

Environment - Long Term Hazard
The above list does not include category being non-classifiable or not-applicable.
[HCS Label Elements]
SymbolNone
Signal Word
None
Hazard StatementsNone
Precautionary Statements
None
3.

Composition / Information On Ingredients

No4.

Chemical Name

Wt%

CAS No.

1

Propylene glycol

55~60%

57-55-62

Additive

3~7%

Trade Secret3

Water

35~40%

7732-18-5

First Aid Measures

Inhalation: Immediately remove victim to fresh air.
Keep victim warm by covering with a blanket and rest.
If breathing is weak or stopped, loosen clothing and maintain an
open airway and then, give artificial respiration.
If unconscious but breathing or if conscious but breathing isdifficult, it is effective to give oxygen. It is recommended to conduct
under doctor’s guidance.
Never administer a dose without doctor’s instructions.
Page 2 of 11

Safety Data Sheets

Product Name: Antifreeze
SDS No. 037-O042470
First issue: 2011/07/05
Revised: 2019/11/25

Never give anything by mouth to victim.
Immediately get medical attention.
Eye Contact: Remove contact lenses, if present and easy to do. Continue rinsing.
Rinse eyes with clean water for at least 15 minutes and get medical
attention form an ophthalmologist immediately. Hold eyelids open
and away from eyeballs with fingers to ensure that all surfaces areflushed thoroughly.

Skin Contact: Remove contaminated clothing, shoes, etc. promptly. Cut it off
necessary. Flush affected area with water or lukewarm water andwash off with soap. If visual change occurs or pain persists, getmedical attention.
If contact with hot liquid, immediately wash with water andsufficiently cool with ice water.
Immediately get medical attention.

Ingestion

If conscious, induce vomiting by giving more than two cups of milkor water and get medical attention immediately.
Never give water, etc to an unconscious person.
Keep victim warm and get medical attention immediately.

Expected acute and: If swallowed, it can cause diarrhea, vomit.

delayed symptoms, mostIf in eyes, it can cause inflammation.

important sign and

If on skin, it can cause inflammation.

symptoms

If inhaled mist, it can cause nausea.

5.

Fire Fighting Measures

Extinguishing Media: Use water (water fog), dry powder, and alcohol-resistant foam.

Unsuitable extinguishing: Don’t use fire hose.

media
Special risk/hazard: Containers may explode when heated.

Fire Fighting Instructions: Eliminate all sources of ignition form fire area.
For initial fire, use water (water fog), dry powder, etc. for fightingfire.
For large fire, it is effective to use foam (alcohol-resistant foam), etc
to shut off air supply.
Pouring water can be dangerous by expanding fire.
Cool surrounding facilities, etc. with water spray.
Page 3 of 11

Safety Data Sheets

Product Name: Antifreeze
SDS No. 037-O042470
First issue: 2011/07/05
Revised: 2019/11/25

Prohibit unnecessary personnel from entering fire area.
Immediately remove moveable container to a safe area.
Protection for fire-fighters: Wear safety glasses, protective clothing, and respiratory protection
for the situation during fire fighting.
Extinguish fire form upwind.

6.

Accidental Release Measures

Personal precautions,: Prohibit unnecessary personnel from entering spilled area

protective equipment andseparated by rope, etc.

emergency measures

Wear suitable protective equipment during clean-up to prevent
contact with water drop or inhalation of gas.
Work from upwind and evacuate from downwind.

Precautions for the: Since it is related to soil and water contamination, recover spills asenvironment

much as possible.

Recovery/neutralization: For large spills, dike with earth and sand, etc. to prevent spreading
and sweep into an empty container and dispose of in a safe place. Be
tender of discharging into sewers, drains, etc. Be sure to wear
protective equipment during clean-up.
For small spills, absorb with dry sand, earth, sawdust, wastes, etc
and collect into an empty container that can be closed.

Method for containment: Stop leakage, if it can be done without risk.

and clean-up

In case of running off, prevent spread of the liquid and scoop orabsorb with a proper absorbent.
If inevitable, use a chemical.
When using a chemical, it should meet the technical standards set
by the Ordinance of the Ministry of Transport.

Preventive measure of: Immediately eliminate all source of ignition nearby.

secondary disaster

Request cooperation by giving notice to relevant agencies.

7.

Handling And Storage

Handling: Keep good working environment.

Technical measures:

Prevent spills, overflow, scattering and generation of vapors.
Prohibit the use of sources of fire, sparks and arcs around thehandling place.
Page 4 of 11

Safety Data Sheets

Product Name: Antifreeze
SDS No. 037-O042470
First issue: 2011/07/05
Revised: 2019/11/25

Prohibit the use near sources of ignition of high temperature.
Repair machinery containing residues after completely removing
them in a safe place.
Take precautionary measures against static discharge and wear
conductive working clothes, shoes, etc.
Since vapors are heavier than air, it is likely to stay in low areas.
So, pay attention to ventilation and sources of fire, etc.
Handle at room temperature and pay attention to mixing withwater or impurities.
If it is possible to contact with skin or eyes, wear protective
equipment.
If mist is generated, do not breathe mist by wearing respirators,etc.
Use a pump, etc. to take out the product from a container.
Use a thin tube and do not suck it with mouth.
Do not weld, heat, puncture or cut containers. It can cause ignitionof residues following explosion.
Local exhaust or general: See ‘Section 8.Exposure Controls and Personal Protective

ventilation

Equipment’.

Avoid to contact: See ‘Section 10. Stability and Reactivity’.

Precaution for safe

: Obtain special instruction before use.

handling

Do not handle until all safety precautions have been read andunderstood.
Pay attention to sources of fire.
Wash hands and eyes thoroughly after handling.
If on clothing, change clothing.
Use only outdoors or in a well-ventilated area.
Do not eat or smoke when using this product.
Do not put pressure to an empty container. It can cause ruptureof a container.
Do not drink.
Keep out of the reach of children.

Storage: Avoid heat, sparks, open flames and static built -up.

Technical measure

Be sure to keep container tightly closed.

Incompatible materials: See ‘Section 10. Stability and Reactivity’.

Storage condition: Keep container in a well-ventilated area.
Protect from direct sunlight.
Page 5 of 11

Safety Data Sheets

Product Name: Antifreeze
SDS No. 037-O042470
First issue: 2011/07/05
Revised: 2019/11/25

Keep away from oxidizing agents.
Safe container and: Use container without damage, corrosion, cracks, etc.

packaging material

Do not handle a container in a violent manner such as turning over,
impacting or dragging it.
Keep used container at a certain designated place.

8.

Exposure Controls / Personal Protection

Controlled exposure level: No regulation.

Exposure Controls
Permissible exposure: The Japanese Occupational Hygiene Society (2009): Notlevel(Threshold limits,established.

biological exposure indices,

ACGIH (2009): Not established.

etc)
Occupational Exposure Controls
Engineering Controls: If mist and vapor is generated, use enclosure of sources or local
exhaust ventilation.
Provide safety shower, basin and eye wash facilities near the place
where the product is handled and indicate the location clearly.

Personal Protection
Respiratory Protection:: Wear gas mask for toxic gas, if necessary.

Hand Protection: Wear impermeable rubber gloves.

Eye Protection: Wear ordinary glass with side shields or safety goggles.

Skin Protection:: Wear long-sleeved working clothes.
Take off wet clothing and wash before reuse.

Page 6 of 11

Product Name: Antifreeze
SDS No. 037-O042470
First issue: 2011/07/05
Revised: 2019/11/25

Safety Data Sheets

General hygiene: Check protective equipment on a regular based on a checklist.

consideration

Do not eat or smoke during work.
Wash hands with soap before eating or smoking.

9.

Physical And Chemical Properties

Appearance- Physical state: liquid- Color: Red clearOdor: Almost odorless

pH

: 8~9

Melting Point / Freezing Point: ≦-40 degrees C

Boiling Point: 107 degrees C/101kPa

Flash Point: None.

Ignition temperature: None.

Explosive limits: Lower: None.

Explosive limits: Upper: None.

Vapor pressure: 1.7kPa/20 degrees C

Vapor density(Air=1): No data.

Specific gravity(Density): 1.05g/cm3(20 degrees C)

Solubility: Soluble in water, low alcohols, acetone

Partition coefficient(n-octanol/water): No data.

Auto-ignition temperature: No data.

Decomposition temperature: No data.

10. Stability And Reactivity
Stability: Stable

Possibilty of hazardous: Explosion/ignition at room temperature hardly occurs, but ifreactionsmoisture is evaporated at high temperature, it is easy toignite/burn.
It can react with strong acids, strong oxidizing agents violently.

Conditions to avoid: No data. (No hazardous reactions under normal handlingcondition.)
Page 7 of 11Product Name: AntifreezeSDS No. 037-O042470
First issue: 2011/07/05
Revised: 2019/11/25

Safety Data Sheets
Incompatible materials: Strong acids, strong oxidizing agents.

Hazardous decomposition: No data.

products
11. Toxicological Information
Acute Toxicity: (Annex) Acute toxicity(Oral, dermal, inhalation)
Content

Oral

Dermal

(%)
1.Propylene glycol

55~60%

2. Additive

3.Water

3~7%35~40%

Total
Oral

Inhalation

Inhalation

Inhalation(Gas)(Vapor)(Dust, mist)

Not

Not

Not

Classificati

Classificati

classifiedclassified

applicableon noton notpossiblepossibleClassifica

ClassificaNot

Classificati

Classificati

tion nottion notapplicable

on noton notpossiblepossiblepossiblepossible

Not

Not

Not

Not

Not

classifiedclassified

applicableclassifiedclassified

100%: It contains acute toxicant (oral) on Annex.
Acute toxicity (oral) estimation, ATEmix=33,333mg/kg is
calculated by GHS criteria.
The product as a mixture is classified as ‘Acute toxicity (Oral): Not
classified’.

Dermal: It contains acute toxicant (dermal) on Annex.
Acute toxicity (dermal) estimation, ATEmix=37,500mg/kg is
calculated by GHS criteria.
The product as a mixture is classified as ‘Acute toxicity (Dermal):
Not classified’.

Inhalation: It contains acute toxicant (inhalation) on Annex.
The product as a mixture is not possible to classify for acutetoxicity(inhalation).

Serious eye damage/eye: It contains eye irritants classified below.

irritation-Not classified: Water, propylene glycol
The product as a mixture is classified as ‘Serious eye damage/eyePage 8 of 11

Safety Data Sheets

Product Name: Antifreeze
SDS No. 037-O042470
First issue: 2011/07/05
Revised: 2019/11/25

irritation: Not classified’.
Serious eye damage/eye irritation of 3~7% of this mixture isunknown.
Skin corrosion/irritation: It contains skin irritants classified below.
-Not classified: Water, Propylene glycol.
The product as a mixture is classified as ‘Skin corrosion/irritation:
Not classified’.
Skin corrosion/irritation of 3~7% of this mixture is unknown.

Respiratory or skin

: It contains respiratory sensitizers classified below.

sensitization-Not classified: Water, propylene glycol
The product as a mixture is classified as ’Respiratory sensitization:
Not Classified’.
Respiratory sensitization of 3~7% of this mixture is unknown.
It contains skin sensitizers classified below.
-Not classified: Water, propylene glycol
The product as a mixture is classified as ’Skin sensitization: Notclassified’.
Skin sensitization of 3~7% of this mixture is unknown.

Germ cell mutagenicity:It contains germ cell mutagens classified below.
-Not classified: Water, propylene glycol
The product as a mixture is classified as ‘Germ cell mutagenicity:
Not classified’.
Germ cell mutagenicity of 3~7% of this mixture is unknown.

Carcinogenicity: Classification is not possible due to lack of data.

Reproductive toxicity: Classification is not possible due to lack of data.

Specific target organ: It contains specific target organ toxicants(singletoxicity (single exposure)exposure)classified below.
-Not classified: Water, propylene glycol
The product as a mixture is classified as ‘Specific target organ
toxicity (single exposure): Not classified’.

Specific target organ: It contains specific target organ toxicants(repeatedtoxicity (repeatedexposure)classified below.

exposure)-Not classified: Water:The product as a mixture is classified as ‘Specific target organ
toxicity(repeated exposure): Not classified’.

Aspiration hazard: Classification is not possible due to lack of data.
Page 9 of 11Safety Data Sheets

Product Name: Antifreeze
SDS No. 037-O042470
First issue: 2011/07/05
Revised: 2019/11/25

12. Ecological Information
Ecotoxicity: It contains hazardous substances(acute)to aquatic environment
classified below.
-Not classified: Water, propylene glycol
The estimation of hazards to aquatic environment (acute)
LC50=166.7mg/L is calculated by GHS criteria.
The product as a mixture is classified as ‘Hazards to aquaticenvironment (Acute): Not classified’.
Hazards to aquatic environment (Acute) of 3~7% of this mixture isunknown.
It contains hazardous substances (chronic) to aquatic environment
classified below.
-Not classified: Water, propylene glycol
The product as a mixture is classified as ‘Hazards to aquaticenvironment (Chronic): Not classified’.
Hazards to aquatic environment (Chronic) of 3~7% of this mixture
is unknown.

Persistence/degradability: No data.

Bio-accumulation: No data.

Mobility in soil

: No data.

Other adverse effects: No data.

Environment criteria: No data.

13. Disposal Considerations
Residual wastes: Dispose the waste according to national and local regulations.
Do not dump.

Contaminated container: Contaminated or empty container packaging are to be disposedand packages

according to national and local regulations.

Comply with all USA, national and local regulations.
Do not dump this product into sewers, on the ground or into any body of water.
14. Transport Information

Page 10 of 11

Safety Data Sheets

Product Name: Antifreeze
SDS No. 037-O042470
First issue: 2011/07/05
Revised: 2019/11/25

US DOT Information: Not regulated as a hazardous material for transport.

TDG Information: Not regulated as dangerous goods for transport.

IATA Information: Not regulated as dangerous goods for transport.

ICAO Information: Not regulated as dangerous goods for transport.

IMDG Information: Not regulated as dangerous goods for transport.

Special precautions: Load the containers in a manner that they are certain not to resultin direct sunlight exposure, damage, corrosion, leak, while beingtransport.
Load the containers in manner that they are not to fall apart while
being transport.
Do not place heavy load on top of the container.
Check a thing without a leak in a container.
Perform prevention of collapse of cargo surely.

15. Regulatory Information
US federal regulations: All components are active on the TSCA Inventory List.

16. Other Information
References

1) The Japanese Occupational Hygiene Society recommendation onpermissible exposure level, etc (OELs)
2) Thresholds limit values for chemical substances and physicalagents and biological exposure indices. ACGIH
3) Material Safety Data Sheet (Propylene glycol), Japan
Petrochemical Industry Association (1998)

This information is furnished without warranty, express or implied, except that it is accurate tothe best knowledge of Mimaki Engineering Corporation.
It relates only to the specific material designated herein, and does not relate to use incombination with any other material or process.
Mimaki Engineering Corporation assumes no legal responsibility for use or reliance upon thisinformation.

Page 11 of 11