Product Name: UV ink F-200 Light Magenta
SDS No. 037-U040554
First issue: 2007/12/21
Revised: 2019/09/02

Safety Data Sheets
1.

Identification

Product Name

: UV ink F-200 Light Magenta

Order No.

: SPC-0516LM

General Use: Ink for ink jet printer

Product Description: UV Inkjet Ink

SDS Number: 037-U040554

Manufacture
Company Name

: Mimaki Engineering Co., Ltd.

Address: 2182-3 Shigeno-otsu, Tomi-shi, Nagano 389-0512 JAPAN

Telephone No.

: +81-268-64-2413

Importer / Distributor Established in USA
Company Name

: MIMAKI USA, INC.

Address: 150 Satellite Boulevard, suite A, Suwanee, Georgia 30024, U.S.A.

Telephone No.

: +1-678-730-0170

Emergency Telephone No.

: +1 866 928 0789 (within United States only, Toll free)+1 215 207 0061

2.

Hazards Identification[GHS Classification]
Physical Hazards
Flammable Liquids: Not classifiedHealth Hazards
Acute Toxicity – Oral

: Category 4

Skin Corrosion / Irritation: Category 2

Eye Damage / Irritation: Category 2ASensitization – Skin

: Category 1B

Carcinogenicity: Category 2

Toxic to Reproduction: Category 1BSpecific Target Organ Toxicity: Category 2 (kidney/urinary tract/Skin)(Repeated Exposure)
The above list does not include category being non-classifiable or not-applicable.

Page 1 of 15

Safety Data Sheets

Product Name: UV ink F-200 Light Magenta
SDS No. 037-U040554
First issue: 2007/12/21
Revised: 2019/09/02[GHS Label Elements]
SymbolSignal Word
DangerHazard Statements
H302 Harmful if swallowed
H315 Causes skin irritation
H317 May cause an allergic skin reaction
H319 Causes serious eye irritation
H351 Suspected of causing cancer
H360 May damage fertility or the unborn child
H373 May cause damage to organs through prolonged or repeated exposure（kidney/urinary tract/Skin）
Precautionary Statements[Prevention]
P201 Obtain SDS (Safety Data Sheet) and printer's operation manual before use.
P202 Do not handle until all safety precautions have been read and understood.
P260 Do not breathe vapor/mist.
P264 Wash hands and eyes thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P272 Contaminated work clothing should not be allowed out of the workplace.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
[Response]
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feelunwell.
P302+P352 IF ON SKIN: Wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P314 Get medical advice/attention if you feel unwell.
(P301+)P330 (IF SWALLOWED:) Rinse mouth.
P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
P337+P313 If eye irritation persists: Get medical advice/attention.
P362+P364 Take off contaminated clothing and wash before re-use.
[Storage]
P405 Store locked up.
[Disposal]
P501 Dispose of contents/container in accordance with local/regional/national/international
regulation (to be specified).
[Hazards not otherwise classified]
20% of the mixture consists of ingredients of unknown acute oral toxicity.

Page 2 of 15

Safety Data Sheets

Product Name: UV ink F-200 Light Magenta
SDS No. 037-U040554
First issue: 2007/12/21
Revised: 2019/09/02

NFPA Rating (scale 0 – 4)
Health = 2
1

Flammability = 1
Instability = 222Special = None
3.

Composition / Information on IngredientsNo

Chemical Name

Wt%

CAS No.

1

ISOBORNYL ACRYLATE

15 - 255888-33-5

2

ISOOCTYL ACRYLATE

15 - 2529590-42-9

3

TETRAHYDROFURFURYL ACRYLATE

15 - 25

2399-48-6

4

ALIPHATIC URETHANE ACRYLATE

5 - 15Trade Secret

5

1,6-HEXANEDIOL DIACRYLATE

1 - 1013048-33-4

1 - 1075980-60-8

1 - 10119-61-9

1 - 10Trade Secret

67
8

2,4,6-TRIMETHYLBENZOYLDIPHENYLPHOSPHINE
BENZOPHENONEAMINE MODIFIED ACRYLATEOLIGOMER

9

C.I. PIGMENT VIOLET 19

1-5

1047-16-1

10

TETRAHYDROFURFURYL ALCOHOL< 0.5

97-99-4*The specific chemical identity and/or exact percentage (concentration) of this composition has been
withheld as a trade secret.
4.

First Aid Measures

Inhalation: Remove person to fresh air. If you feel unwell, get medical attention.

Eye Contact: Immediately flush with large amounts of water. Remove contactlenses if easy to do. Continue rinsing. Get medical attention.

Skin Contact: Immediately wash with soap and water. Remove contaminatedclothing and wash before reuse. If signs/symptoms develop,get
medical attention.

Ingestion: Rinse mouth. If you feel unwell, get medical attention.

Page 3 of 15

Safety Data Sheets
Most important

Product Name: UV ink F-200 Light Magenta
SDS No. 037-U040554
First issue: 2007/12/21
Revised: 2019/09/02: See Section 11.1. Information on toxicological effects.

symptoms and effects,
both acute and delayed
Indication of Immediate: Not applicable.

Medical Attention andSpecial Treatment
Needed, If Needed
5.

Fire Fighting Measures

Flammable Properties: Flash point >200゜F

Extinguishing Media: Use a fire fighting agent suitable for ordinary combustible material
such as water or foam to extinguish.

Special Hazards Arising: Closed containers exposed to heat from fire may build pressure andfrom the Chemical

explode.

Hazardous Combustion: Carbon monoxide, Carbon dioxide (During Combustion)

Products
Special protective actions: Water may not effectively extinguish fire; however, it should be used

for fire-fighters

to keep fire-exposed containers and surfaces cool and prevent
explosive rupture.

6.

Accidental Release Measures

Personal precautions,: Evacuate area. Ventilate the area with fresh air. For large spill, or

protective equipment andspills in confined spaces, provide mechanical ventilation to disperse

emergency proceduresor exhaust vapors, in accordance with good industrial hygiene
practice. Warning! A motor could be an ignition source and could
cause flammable gases or vapors in the spill area to burn or explode.
Refer to other sections of this SDS for information regarding
physical and health hazards, respiratory protection, ventilation, andpersonal protective equipment.

Environmental: Avoid release to the environment. For larger spills, cover drains andprecautions

build dikes to prevent entry into sewer systems or bodies of water.

Page 4 of 15

Safety Data Sheets

Product Name: UV ink F-200 Light Magenta
SDS No. 037-U040554
First issue: 2007/12/21
Revised: 2019/09/02

Methods and material for: Contain spill. Working from around the edges of the spill inward,

containment and cleaning

cover with bentonite, vermiculite, or commercially available

up

inorganic absorbent material. Mix in sufficient absorbent until it
appears dry. Remember, adding an absorbent material does notremove a physical, health, or environmental hazard. Collect as muchof the spilled material as possible. Place in a closed container
approved for transportation by appropriate authorities. Clean up
residue with an appropriate solvent selected by a qualified andauthorized person. Ventilate the area with fresh air. Read and follow
safety precautions on the solvent label and SDS. Seal the container.
Dispose of collected material as soon as possible.

7.

Handling and Storage

Precautions for Safe

: Avoid skin contact with hot material. For industrial or professional

Handling

use only. Do not handle until all safety precautions have been readand understood. Do not breathe dust/fume/gas/mist/vapors/spray. Do
not get in eyes, on skin, or on clothing. Do not eat, drink or smoke
when using this product. Wash thoroughly after handling.
Contaminated work clothing should not be allowed out of theworkplace. Avoid release to the environment. Wash contaminatedclothing before reuse. Avoid contact with oxidizing agents (eg.
chlorine, chromic acid etc.) Use personal protective equipment(gloves, respirators, etc.) as required.

Conditions for Safe

: Store in a well-ventilated place. Keep container tightly closed. Keep

Storage, including any

cool. Protect from sunlight. Store away from heat. Store away from

Incompatibilities

oxidizing agents.

8.

Exposure Controls / Personal Protection

Exposure Limit Values: If a component is disclosed in section 3 but does not appear in thetable below, an occupational exposure limit is not available for thecomponent.

Page 5 of 15

Product Name: UV ink F-200 Light Magenta
SDS No. 037-U040554
First issue: 2007/12/21
Revised: 2019/09/02

Safety Data Sheets
Ingredient

CAS No.

AgencyLimit type

Additional
Comments

BENZOPHENONE

119-61-9

AIHA

TWA:0.5 mg/m3

1,6-HEXANEDIOL

13048-33-4

AIHA

TWA:1 mg/m3

Dermal(0.11 ppm)

Sensitizer

DIACRYLATETETRAHYDROFURFURYL

2399-48-6

ACRYLATE

Manufacturer

TWA:0.1 ppm

determined(0.64mg/m3);
STEL:0.3 ppm(1.91mg/m3)

ISOOCTYL ACRYLATE

29590-42-9

AIHA

TWA:37.5 mg/m3(5 ppm)Manufacturer

TWA:5 ppm

determined
TETRAHYDROFURFURYL

97-99-4

AIHA

ALCOHOL

TWA:2 mg/m3(0.5ppm)

ACGIH : American Conference of Governmental Industrial Hygienists
AIHA : American Industrial Hygiene Association
CMRG : Chemical Manufacturer's Recommended Guidelines
OSHA : United States Department of Labor - Occupational Safety and Health Administration
TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit
CEIL: Ceiling
Exposure Controls
Occupational Exposure Controls
Appropriate: Use general dilution ventilation and/or local exhaust ventilation to

Engineering Controls

control airborne exposures to below relevant Exposure Limits and/or
control dust/fume/gas/mist/vapors/spray. If ventilation is notadequate, use respiratory protection equipment.

Personal Protection
Respiratory: An exposure assessment may be needed to decide if a respirator isProtection

required. If a respirator is needed, use respirators as part of a full
respiratory protection program. Based on the results of the exposure
assessment, select from the following respirator type(s) to reduce
inhalation exposure:Half facepiece or full facepiece air-purifying
respirator suitable for organic vapors and particulates
Page 6 of 15

Product Name: UV ink F-200 Light Magenta
SDS No. 037-U040554
First issue: 2007/12/21
Revised: 2019/09/02

Safety Data Sheets

For questions about suitability for a specific application, consult withyour respirator manufacturer.
Skin/Hand: Select and use gloves and/or protective clothing approved to relevant

Protection

local standards to prevent skin contact based on the results of an
exposure assessment. Selection should be based on use factors suchas exposure levels, concentration of the substance or mixture,
frequency and duration, physical challenges such as temperature
extremes, and other use conditions. Consult with your glove and/or
protective clothing manufacturer for selection of appropriatecompatible gloves/protective clothing. Note: Nitrile gloves may beworn over polymer laminate gloves to improve dexterity.
Gloves made from the following material(s) are recommended:
Polymer laminate
If this product is used in a manner that presents a higher potential
for exposure (eg. spraying, high splash potential etc.), then use ofprotective coveralls may be necessary. Select and use body protection
to prevent contact based on the results of an exposure assessment.
The following protective clothing material(s) are recommended:
Apron - polymer laminate

Eye Protection: Select and use eye/face protection to prevent contact based on the
results of an exposure assessment. The following eye/faceprotection(s) are recommended: Indirect Vented Goggles

9.

Physical and Chemical Properties

Appearance- Physical State: Liquid- Color: Magenta

Odor: Acrylate Odor,

pH: Not Applicable

Boiling Point / Boiling Range: >200゜F

Melting Point / Melting Range: Not available

Decomposition Temperature: Not available

Flash Point: >200゜F [Test Method: Closed Cup]Auto ignition temperature: Not available

Flammability (Solid, Gas)

: Not Applicable
Page 7 of 15

Safety Data Sheets

Product Name: UV ink F-200 Light Magenta
SDS No. 037-U040554
First issue: 2007/12/21
Revised: 2019/09/02

Explosive Properties: Not available

Oxidizing Properties: Not available

Upper / Lower Flammability or: Not available

Explosive Limits
Vapor Pressure: < 10 mmHg [@ 20 ºC]

Specific Gravity: 1.04 [Ref Std: WATER=1]

Solubility: Not available

Water Solubility: Negligible

Partition Coefficient (n-octanol / Water): Not available

Viscosity: Not available

Vapor Density: > 1 [Ref Std: AIR=1]

Evaporation Rate

: Not available

VOC: Not available

10. Stability and Reactivity
Reactivity: This material may be reactive with certain agents under certain
conditions - see the remaining headings in this section.

Chemical Stability: Stable under normal conditions of use.

Possibility of Hazardous: Hazardous polymerization will not occur.

Reactions
Conditions to Avoid: HeatIncompatible Materials: Strong oxidizing agents

Hazardous: None known.

Decomposition
Refer to section 5.2 for hazardous decomposition products during combustion
11. Toxicological Information
Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough,sneezing, nasal discharge, headache, hoarseness, and nose and throat
pain. May cause additional health effects (see below).

Page 8 of 15

Product Name: UV ink F-200 Light Magenta
SDS No. 037-U040554
First issue: 2007/12/21
Revised: 2019/09/02

Safety Data Sheets
Skin Contact: Skin Irritation: Signs/symptoms may include localized redness,swelling, itching, dryness, cracking, blistering, and pain. Allergic
Skin Reaction (non-photo induced): Signs/symptoms may include
redness, swelling, blistering, and itching. May cause additional
health effects (see below).

Eye Contact: Severe Eye Irritation: Signs/symptoms may include significant
redness, swelling, pain, tearing, cloudy appearance of the cornea, andimpaired vision.

Ingestion: Harmful if swallowed. Gastrointestinal Irritation: Signs/symptoms
may include abdominal pain, stomach upset, nausea, vomiting anddiarrhea. May cause additional health effects (see below).

Additional Health Effects:
Prolonged or repeated: Kidney/Bladder Effects: Signs/symptoms may include changes in

exposure may cause

urine production, abdominal or lower back pain, increased protein intarget organ effects

urine, increased blood urea nitrogen (BUN), blood in urine, andpainful urination.
Dermal Effects: Signs/symptoms may include redness, itching, acne,or bumps on the skin.

Reproductive/Developme: Contains a chemical or chemicals which can cause birth defects or

ntal Toxicity

other reproductive harm.

Carcinogenicity: Contains a chemical or chemicals which can cause cancer.

Ingredient

CAS No.

Class Description

Regulation

BENZOPHENONE

119-61-9

Grp. 2B: Possible

International Agency forhuman carc.

Research on Cancer

Toxicological Data

: If a component is disclosed in section 3 but does not appear in a tablebelow, either no data are available for that endpoint or the data are
not sufficient for classification.

Acute Toxicity
Name

Route
Ingestion

Overall productSpeciesValue
No data available;
calculated
ATE 300 - 2,000
mg/kg

Page 9 of 15

Safety Data Sheets

Product Name: UV ink F-200 Light Magenta
SDS No. 037-U040554
First issue: 2007/12/21
Revised: 2019/09/02

DermalRabbit

LD50 > 2,000 mg/kg

Ingestion

Rat

LD50 > 5,000 mg/kg

DermalRabbit

LD50 > 5,000 mg/kg

Ingestion

Rat

LD50 4,350 mg/kg

Ingestion

Rat

LD50 551 mg/kg

DermalRabbit

LD50 3,636 mg/kg

Ingestion

Rat

LD50 > 5,000 mg/kg

DermalProfessional

LD50 estimated to be

judgement> 5,000 mg/kg

Ingestion

Rat> 5,000 mg/kg

DermalRabbit

LD50 3,535 mg/kg

Ingestion

Rat

LD50 1,900 mg/kg

DermalRat

LD50 > 2,000 mg/kg

Ingestion

Rat

LD50 > 5,000 mg/kg

Name

SpeciesValue

ISOOCTYL ACRYLATE

Human

Minimal irritation

ISOBORNYL ACRYLATE

RabbitMinimal irritation

TETRAHYDROFURFURYL ACRYLATE

RabbitIrritant

1,6-HEXANEDIOL DIACRYLATE

RabbitIrritant

ISOOCTYL ACRYLATEISOBORNYL ACRYLATETETRAHYDROFURFURYL ACRYLATE
1,6-HEXANEDIOL DIACRYLATE
2,4,6-TRIMETHYLBENZOYLDIPHENYLPHOSPHINE
BENZOPHENONE
C.I. PIGMENT VIOLET 19

Skin Corrosion/Irritation

Serious Eye Damage/Irritation
Name

SpeciesValue

ISOOCTYL ACRYLATE

Similar health

Mild irritanthazards
ISOBORNYL ACRYLATE

RabbitMild irritant

TETRAHYDROFURFURYL ACRYLATE

RabbitSevere irritant

1,6-HEXANEDIOL DIACRYLATE

RabbitModerate irritant

BENZOPHENONE

RabbitMild irritant

Page 10 of 15

Product Name: UV ink F-200 Light Magenta
SDS No. 037-U040554
First issue: 2007/12/21
Revised: 2019/09/02

Safety Data Sheets
Skin Sensitization
Name

SpeciesValue

ISOOCTYL ACRYLATE

Mouse

Sensitizing

ISOBORNYL ACRYLATE

Mouse

Sensitizing

TETRAHYDROFURFURYL ACRYLATE

Human andSome positive data exist, but the dataanimalare not sufficient for classification

Guinea pig

Sensitizing

1,6-HEXANEDIOL DIACRYLATE
Respiratory Sensitization

For the component/components, either no data are currently available or the data are not sufficientfor classification
Germ Cell Mutagenicity
Name

Route

ISOOCTYL ACRYLATEISOBORNYL ACRYLATEIn Vitro

1,6-HEXANEDIOL DIACRYLATE

Value
Some positive data exist, but the data
are not sufficient for classification

Carcinogenicity
Name

Route

SpeciesValue

BENZOPHENONE

Ingestion

Multiple

Carcinogenic

animalspecies
Reproductive and/or Developmental Effects
Name
ISOOCTYL ACRYLATEBENZOPHENONE
2,4,6-TRIMETHYLBENZOYLDIPHENYLPHOSPHINE

Route
Ingestion

Ingestion
Ingestion

Value

Spec

Test

Exposureies

ResultDuration

Rat

NOAEL

duringdevelopmental data

1,000

organogenesi

exist, but the data are

mg/kg/daysSome positive

not sufficient for

Rab

NOAEL 25

duringclassificationbit

mg/kg/daygestation

Toxic to male

Rat

NOAEL

90 daysreproduction

100
mg/kg/dayPage 11 of 15

Product Name: UV ink F-200 Light Magenta
SDS No. 037-U040554
First issue: 2007/12/21
Revised: 2019/09/02

Safety Data Sheets
Specific Target Organ Toxicity - single exposure
Name

Route

TargetValue

Species

Test

Organ(s)ISOOCTYL

ISOBORNYLTETRAHYDROFURF
URYL ACRYLATE
1,6-HEXANEDIOLDIACRYLATE

Rat

system depression

Inhalation

ACRYLATE

NOAEL

central nervous

Ingestion

ACRYLATE

ResultInhalation
Inhalation

mg/kg
official

respiratory
irritation

Some positiveclassifica

data exist,

tion

C.I. PIGMENT

Ingestion

available

but the data

Notirritation

are not

available

respiratory

sufficient for

irritation

classificatio

Not

Human

Available

Human

skin

Not

and

Available

animal

VIOLET 19

Not

respiratoryn
Dermal

5,000

central nervous

Not

Rat

system depression

Available

Specific Target Organ Toxicity - repeated exposure
Name

Route

TargetValue

SpeciesOrgan(s)endocrine
ISOOCTYLACRYLATE

Ingestion

Ingestion

NYLPHOSPHINE

Ingestion

Duration

NOAEL

90 daysliver | kidney

mg/kg/day(Rat, 90

Some positive
data exist, butskin | blood |the data areliver |kidney

not sufficient

and/orfor

bladderclassification

heart |BENZOPHENONE

Result600

bladder

BENZOYLDIPHE

Exposuresystem |and/or

2,4,6-TRIMETHYL

Rat

Test

days)
Rat

NOAEL

90 days

1,000
mg/kg/day(Rat, 90
days)
Rat

NOAEL

hematopoieti

850

c system |mg/kg/day

14 weeks

Page 12 of 15

Product Name: UV ink F-200 Light Magenta
SDS No. 037-U040554
First issue: 2007/12/21
Revised: 2019/09/02

Safety Data Sheets
liver|immunesystemBENZOPHENONE

Ingestion

kidney and/or

May cause

bladderdamage toorgans though

1,6-HEXANEDIOLDIACRYLATE

Dermalskin

Rat

LOAEL 75

14 weeks

mg/kg/day
Mouse

LOAEL 70

prolonged or

mg/kg/dayrepeated(Mouse, 80

exposure

weeks)

80 weeksAspiration Hazard
For the component/components, either no data are currently available or the data are not sufficientfor classification
12. Ecological Information
Handling is noted because it might influence the environment whenleaking and abandoning it.
Especially, note that the product doesn't flow directly to ground, theriver, and the drain ditch.
Ecotoxicity: Please contact the address or phone number listed on the first page of
the SDS for additional chemical fate information on this material
and/or its components.

Persistence and: Not available

Degradability
Bioaccumulation: Not available

Mobility: Not available

Other Toxicity: Not available

13. Disposal Considerations
Disposal methods: Dispose of contents/ container in accordance with thelocal/regional/national/international regulations.
Dispose of waste product in a permitted industrial waste facility. As adisposal alternative, incinerate in a permitted waste incineration
facility. Proper destruction may require the use of additional fuelPage 13 of 15

Safety Data Sheets

Product Name: UV ink F-200 Light Magenta
SDS No. 037-U040554
First issue: 2007/12/21
Revised: 2019/09/02

during incineration processes. Empty drums/barrels/containers used
for transporting and handling hazardous chemicals (chemical
substances/mixtures/preparations classified as Hazardous as per
applicable regulations) shall be considered, stored, treated &disposed of as hazardous wastes unless otherwise defined byapplicable waste regulations. Consult with the respective regulating
authorities to determine the available treatment and disposal
facilities.
Do not dump this product into sewers, on the ground or into any bodyof water.
EPA Hazardous Waste: Not regulated

Number (RCRA)
14. Transport Information
Check a thing without a leak in a container.
Perform prevention of collapse of cargo surely.
UN Number: UN3082

Shipping: Environmentally hazardous substance, liquid, n.o.s. (ISOOCTYLNameACRYLATE, ISOBORNYL ACRYLATE)

Hazardous Class or:9

Division
Packing Group (PG)

: III

Remarks: Single or inner packaging less than 5 L (liquid) or 5 kg net (solids) is
excepted from Dangerous Goods regulations.
Refer to ICAO/IATA A197, IMDG 2.10.2.7, ADR SP 375.

15. Regulatory Information
U.S. Federal Regulations
SARA TitleⅢ: Immediate Hazard: Yes

Section 311/312

Delayed Hazard: Yes
Fire: No
Pressure: No
Reactive: No

This material contains a chemical which requires export notification under TSCA Section 12[b]:Page 14 of 15

Product Name: UV ink F-200 Light Magenta
SDS No. 037-U040554
First issue: 2007/12/21
Revised: 2019/09/02

Safety Data Sheets
Ingredient

CAS No.

Regulation

StatusToxic Substances Control Act
BENZOPHENONE

119-61-9(TSCA) 4 Test Rule

ApplicableChemicals
U.S. State Regulations
California Proposition 65: WARNING
This product can expose you to chemicals including
Benzophenone, Toluene, which are known to the State ofCalifornia to cause cancer/ birth defects or other reproductive
harm. For more information go to www.P65Warnings.ca.gov

Chemical Inventories: The components of this product are in compliance with the chemical
notification requirements of TSCA.

16. Other Information
This information is furnished without warranty, express or implied, except that it is accurate to
the best knowledge of Mimaki Engineering Corporation.
It relates only to the specific material designated herein, and does not relate to use incombination with any other material or process.
Mimaki Engineering Corporation assumes no legal responsibility for use or reliance upon thisinformation.

Page 15 of 15