主な研究成果
１．交差分子線法による気相反応の反応動力学
化学反応素がどのように進むかを決めるのは、関与する反応物の原子や分子間の相互作用、またはポテンシャルエネルギー超曲面であるとの考えで、反応の起こる様子を観測し、運動状態をポテンシャルエネルギー面の関連において理解する学問が、反応動力学である。
交差分子線法を用いて A + B-C → A-B + C 型の素反応の動力学を行ってきた。F 原子と一連の不飽和炭化水素との置換反応：例えば、F + C6D6 → C6D5F + D の生成物の角度及び速度分布を測定し、反応中間体内で全ての振動モードにエネルギーが移動するかどうかを論じた[11]。また、回転型質量分析器を用いた研究としては、最も詳しい反応動力学的知見得られた反応系である F + D2 → DF + D によって生成した DF 分子の重心系における微分断面積を求めた[29]。アーク放電によって生成した電子励起原子と分子との衝突によって生成した電子励起分子からの発光強度の衝突エネルギー依存性を求めることによって、励起原子の関与する反応の動力学を明らかにした[27, 30]。

２．シンクロトロン放射を用いた分子および半導体表面の真空紫外光励起化学の研
究分子科学研究所極端紫外光実験施設(UVSOR)の真空紫外光吸収分光法によって気相分子や分子クラスターの吸収スペクトルを測定し、Rydberg 状態を含む豊富な励起状態の帰属を行った[M4]。さらに、気相分子の真空紫外光解離によって生成する励起原子や分子からの発光やその偏光特性を観測して、真空紫外領域における分子の解離励起過程の動力学について明らかにした[89]。半導体材料やダイヤモンド表面のシンクロトロン放射励起によるエッチング反応の波長依存性やエッチャントの圧力依存性の測定を行い[38]、その機構について研究した。特に、SiO2(エッチャント: SF6)[65]やダイヤモンド(エッチャント:O2)[94]の真空
紫外光励起エッチング反応においては、表面層にある原子の内殻励起過程が、エッチング
反応に直接的に効くことを示した。

３．分子−表面相互作用と表面反応動力学の研究
シンクロトロン放射励起表面反応過程の研の過程で、清浄表面における反応研究の必要性を痛感し、分子線−表面反応解析装置を製作した。これを用いて、超熱 Cl2 分子によるSi(111)のエッチング反応による生成物の速度分布及び表面方位依存性を測定し、脱離生成物の同定を行った[86]。また、原子または分子−固体表面衝突散乱による散乱物の散乱角及び速度分布測定を行って、並進−振動エネルギー移動過程を明らかにした[112]。北海道大学
触媒化学研究センター松島龍夫現名誉教授の、清浄表面上に吸着した原子、分子どうしのLangmuir-Hinshelwood 機構による反応（CO(a)の酸化反応や NO の還元反応）生成物の脱離方位角及び速度分布の測定プロジェクトに参画した[71]。この一連の研究によって、生成物

の生成直前の遷移状態の化学種と表面反応場の構造とについて知見を得ることができるよ
うになった[113]。豊田理化学研究所における研究課題では、表面反応物のエネルギーを制御して、反応の PES を直接的に求めるための実験を試みた。これまで、18O(a)/Pt(111)と並進エネルギー1,2 eV の CO 分子との衝突による反応生成物はまだ見出されていない[R22]。今後、CO の衝突エネルギーを、さらに 2.3 eV まで上昇した衝突反応散乱実験を行う予定である。
(注)[]内の文献番号は、業績リストの数に対応する。

論文リストList of Publications (正畠宏祐)2009 年 9 月 15 日

1. "4-置換 2, 6-キシレノールの水酸基の赤外吸収スペクトル", 吉田善一, 石部信行,
正畠宏祐, 工業化学雑誌, 68(1965) 808-811.
2. "Infrared spectrum and structure of lithium hexafluoroacetonate-tetramethylethylenediamine adduct", K. Shobatake, K. Nakamoto, J. Chem. Phys., 49 (1968) 4792 4796.
3. "Vibrational spectra of triphenyl compounds of group VA elements", K. Shobatake, C.
Postmus, J. R. Ferraro, K. Nakamoto, Appl. Spectrosc., 23 (1969) 12-16.
4. "Far-infrared assignments for bridging cobalt-halogen stretching vibrations in several
coordination compounds", C. Postmus, J. R. Ferraro, A. Quattrochi, K. Shobatake, K.
Nakamoto, Inorg. Chem., 8 (1969) 1851-1855.
5. "Use of metal isotopes in assigning metal ligand vibrations", K. Nakamoto, K. Shobatake,B. Hutchinson, Chem. Comm., 1451-1452 (1969).
6. "Metal isotope effect on mMetal-ligand vibrations. I. Phosphine complexes", K.
Shobatake, K. Nakamoto, J. Amer. Chem. Soc., 92 (1970) 3332-3335.
7. "Metal isotope effect on metal-ligand vibrations. III. π-Allyl complexes of palladium(II)",K. Shobatake, K. Nakamoto, J. Amer. Chem. Soc., 92 (1970) 3339-3342.
8. "Spectra and structure of sterically hindered lithium phenoxides", K. Shobatake, K.
Nakamoto, Inorg. Chim. Acta, 4 (1970) 485-487.
9. "Unimolecular decomposition of the long-lived complex formed in the reaction F + C4H8",
J. M. Parson, K. Shobatake, Y. T. Lee, S. A. Rice, J. Chem. Phys. 59 (1973) 1402-1415.
10. "Unimolecular decomposition of long-lived complexes of fluorine and substitutedmono-olefins, cyclic olefins, and dienes."K. Shobatake, J. M. Parson, Y. T. Lee, S. A. Rice,J. Chem. Phys., 59 (1973) 1416-1426.
11. "Laboratory angular dependence and the recoil-energy spectrum of the products of thereaction F + C6D6 → D + C6D5F", K. Shobatake, J. M. Parson, Y. T. Lee, S. A. Rice, J.
Chem. Phys., 59 (1973) 1427-1434.
12. "Reactions of F atoms and aromatic and heterocyclic molecules: Energy distribution in thereaction complex", K. Shobatake, Y. T. Lee, S. A. Rice, J. Chem. Phys., 59 (1973)
1435-1448.
13. "ITFITS models for vibration-translation energy partitioning in atom-polyatomic molecule
collisions", K. Shobatake, Y. T. Lee, S. A. Rice, J. Chem. Phys., 59 (1973) 2483-2489.
14. "Substitution reactions of fluorine atoms with unsaturated hydrocarbons: Crossed
molecular beam studies of unimolecular decomposition", J. M. Parson, K. Shobatake, Y. T.
1

Lee, S. A. Rice, Faraday Discussions Chem. Soc., 55 (1973) 344-356.
15. "Crossed molecular beam study of the reaction F + {C2H2Cl2} → Cl + {C2H2ClF}", K.
Shobatake, Y. T. Lee, S. A. Rice, J. Chem. Phys., 59 (1973) 6104-6111.
16. "Penning ionization of He(3S) + Ar", Z. F. Wang, A. P. Hickman, K. Shobatake, Y. T. Lee,
J. Chem. Phys., 65 (1976) 1259-1266.
17. "Determination of the long range nonreactive anisotropic potential of H + Cl2 and H + Br2
from nonreactive scattering experiments”, W. Bauer, K. Shobatake, J. P. Toennies, K.
Walaschewski, J. Chem. Phys., 68 (1978) 3413-3424.
18. "Ozone photolysis: A determination of the electronic and vibrational state distributions ofprimary products", R. K. Sparks, L. R. Carlson, K. Shobatake, M. L. Kowalczyk, Y. T. Lee,
J. Chem. Phys., 72 (1980) 1401-1402.
19. "Multiphoton ionization electron spectroscopy of organic molecules", Y. Achiba, K. Sato,K. Shobatake, K. Kimura, J. Photochem., 17 (1981) 53-54.
20. "Photofragmentation of CH3I: Vibrational distribution of the CH3 fragments." R. K.
Sparks, K. Shobatake, L. R. Carlson, Y. T. Lee, J. Chem. Phys., 75 (1981) 3838-3846.
21. "The UVSOR facility at IMS”, I. Koyano, Y. Achiba, H. Inokuchi, E. Ishiguro, R. Kato, K.
Kimura, K. Seki, K. Shobatake, K. Tabayashi, Y. Takagi, K. Tanaka, A. Uchida, M.
Watanabe, Nuclear Instrum. Methods, 195 (1982) 273-276.
22. "Methylene singlet-triplet energy splitting by molecular beam photodissociation of
ketene", C. C. Hayden, D. M. Neumark, K. Shobatake, R. K. Sparks, Y. T. Lee, J. Chem.
Phys., 76 (1982) 3607-3613.
23. "The Mechanism for photofragmentation of H2S revealed by multiphoton ionization
photoelectron spectroscopy", Y. Achiba, K. Sato, K. Shobatake, K. Kimura, J. Chem. Phys.,
77 (1982) 2709-2714.
24. "A photoelectron spectroscopic study of (3+1) resonant multiphoton ionization of NO andNH3", Y. Achiba, K. Sato, K. Shobatake, K. Kimura, J. Chem. Phys., 78 (1983) 5474-5479.
25. "Resonant multiphoton ionization photoelectron spectroscopic study of benzene. Evidence
for fast intramolecular vibrational relaxation within the 1E1u state", Y. Achiba, K. Sato, K.
Shobatake, and K. Kimura; J. Chem. Phys., 79 (1983) 5213-5218.
26. "Chemiluminescence produced in the reaction between N(2D, 2P) atoms and HI and HBr,
in crossed molecular beam", K. Tabayashi, S. Ohshima, K. Shobatake, J. Chem. Phys., 80(1984) 5335-5337.
27. "Arc- heated atomic nitrogen beam source for crossed molecular beam experiments", K.
Tabayashi, S. Ohshima, K. Shobatake, Rarefied Gas Dynamics, 14 (1984) 635-642.
28. "分子線によるセラミック表面のエネルギー交換に関する研究."藤本哲夫, 加藤征三, 正畠宏祐, 日本機会学会雑誌, B51 (1985) 365-369.
229. "Molecular beam studies of the F + D2 and F + HD reaction", D. M. Neumark, A. M.
Wodthe, G. N. Robinson, C. C. Hayden, K. Shobatake, R. K. Sparks, T. P. Schafer, Y. T. Lee,
J. Chem. Phys., 82 (1985) 3067-3077.
30. "Polarization of CN (B2Σ + - X2Σ +) emission produced in collision of Ar(3P0,2) with
BrCN", T. Nagata, T. Kondow, K. Kuchitsu, K. Tabayashi, S. Ohshima, K. Shobatake, J.
Phys. Chem., 89 (1985) 2916 - 2918.
31. "Emission spectra of SiH(A2Δ→ X2Π) and SiCl2(1B1 → 1A1) in the VUV photolyses ofsilane and chlorinated silanes", N. Washida, Y. Matsumi, T. Hayashi, T. Ibuki, A. Hiraya, K.
Shobatake, J. Chem. Phys., 83 (1985) 2769-2774.
32. "Lack of heavy atom effect on the fluorescence lifetimes of 9-cyanoantracene-rare gas
clusters in a supersonic free jet", S. Hirayama, K. Shobatake, K. Tabayashi, Chem. Phys.
Letters, 121 (1985) 229-232.
33. "Fluorescence from ion-pair and Rydberg states of I2", R. J. Donovan, B. V. O'Grady, K.
Shobatake, A. Hiraya, Chem. Phys. Lett., 122 (1985) 612.
34. "Fluorescence lifetimes of 9-methylanthracene in supersonic free jets. A level inversion
between S1 and T2 states upon the phase change from solution to gas", F. Tanaka, S.
Hirayama, S. Yamashita, K. Shobatake; Bull. Chem. Soc. Jpn., 59 (1986) 2011-2012.
35. "Collision energy dependence of the cross sections for the electronic excitation transfer
reactions: Rg(3P0,2) + N2 (X1Σg) → Rg(1S0) + N2(C3Πu), (Rg = Ar, Kr)", K. Tabayashi, K.
Shobatake, J. Chem. Phys., 84 (1986) 4919-4929.
36. "Collision energy dependence of the cross sections for the dissociative excitation
reactions: Rg(3P0,2) + NH3 → Rg + NH(A3Π, c1Π) + H2 (Rg = Ar, Kr)", K. Tabayashi, K.
Shobatake, J. Chem. Phys., 84 (1986) 4930-4937.
37. "CCl2(1B1) radical formation in VUV photolyses of CCl4 and CBrCl3", T. Ibuki, N.
Takahashi, A. Hiraya, K. Shobatake, J. Chem. Phys., 85 (1986) 5717-5722.
38. "Synchrotron radiation-assisted etching of silicon surface", N. Hayasaka, A. Hiraya, K.
Shobatake, Jpn. J. Appl. Phys., 26 (1987) L1110-1111.
39. "Primary processes in the 121.6 nm photolysis of gas phase ethyl bromide", K.-H. Jung,
D.-K. Oh, K. Shobatake, J. Photochem., 39 (1987) 217-228.
40. "Deuterium isotope effect on the cross section for the dissociative excitation process.
Ar(3P0,2) + CH3CN, CD3CN → Ar + CH3, CD3 + CN(B2Σ +)", K. Tabayashi, K. Shobatake,
J. Chem. Phys., 87 (1987) 2404-2406.
41. "Photoexcitation and photofragment fluorescence studies of methanethiol in vacuum
ultraviolet", I. Tokue, A. Hiraya, K. Shobatake, Chem. Phys., 116 (1987) 449-456.
42. "Excess-energy-insensitive fluorescence decay of jet-cooled 9,10-dicyanoanthracene", S.
Hirayama, F. Tanaka, K. Shobatake, Chem. Phys. Lett., 140 (1987) 447- 450.
43. "Photoexcitation of CH3NCO, CH3NCS and CH3SCN in the vacuum ultraviolet: Rydberg
3states and photofragment emission", I. Tokue, A. Hiraya, K. Shobatake, Chem. Phys., 117(1987) 315-324.
44. "Chemiluminescence of NS(B2 Σ) produced by the reaction of N(2D, 2P) with COS and
CS2, in crossed molecular beam", K. Tabayashi, K. Shobatake, J. Chem. Phys., 87 (1987)
7344-7345.
45. "Vacuum ultraviolet fluorescence excitation spectrum of I2", A. Hiraya, K. Shobatake, R. J.
Donovan, A. Hopkirk, J. Chem. Phys., 88(1988) 52-57.
46. "Dissociative excitation processes of water molecule by metastable rare gas atoms: H2O +Rg(3P0,2) → OH(A2Σ+) + H + Rg, (Rg = Ar, Kr)", K. Tabayashi, K. Shobatake, J. Chem.
Phys., 88 (1988) 835-844.
46. "Crossed-beam reactive scattering of F2 plus C6H6: Heat of formation of ipsofluorocyclohexadienyl radical", J. R. Grover, Y. Wen, Y. T. Lee, K. Shobatake, J. Chem.
Phys., 89 (1988) 938-946.
48. “プラズマ混合を用いた分子解離による原子ビームの生成－TOF 法によるＣ原子ビームのキャラクタリゼーション", 田林清彦, 正畠宏祐, 分光研究, 37 (1988)
201-205.
49. "Vibronic-level specific heavy atom effect on the fluorescence decays of the rare gas
complexes of 9-methoxyanthracence", S. Hirayama, F. Tanaka, K. Shobatake, Chem. Phys.
Lett., 153 (1988) 112-117.
50. "Fluorescence decays in a wide variety of van der Waals complexes of 9-cyanoanthracene
in supersonic free jets", S. Hirayama, A. Adachi, F. Tanaka, K. Shobatake, K.-H. Jung, J.
Chem. Soc. Faraday 2, 84 (1988) 1927-1940.
51. "Photoabsorption spectra and photodissociation of S2Cl2 in the vacuum ultraviolet", I.
Tokue, A. Hiraya, K. Shobatake, Chem. Phys. Lett., 153 (1988) 346-350.
52. "Photoexcitation of dimethyl disulfide in the vacuum ultraviolet region: Rydberg statesand photofragment emissions", I. Tokue, A. Hiraya, K. Shobatake, Chem. Phys., 130 (1989)
401-408.
53. " Fluorescence decays of 9,10-dichloro-anthracene and its van der Waals complexes withrare gas atoms in supersonic free jets", F. Tanaka, S. Yamashita, S. Hirayama, A. Adachi, K.
Shobatake, Chem. Phys., 131 (1989) 435-442.
54. "Photoabsorption spectrum and CCl2 (1B1) radical formation via VUV excitation of
C2Cl6", T. Ibuki, A. Hiraya, K. Shobatake, Chem. Phys. Lett., 157 (1989) 521.
55. "Photochemistry of CCl3F and CCl2F2 in the 106-200 nm region", T. Ibuki, A. Hiraya, K.
Shobatake, J. Chem. Phys., 90 (1989) 6290-6295.
56. "He(I) photoelectron spectra and VUV absorption cross sections of Ga(CH3) 3 andIn(CH3)3", T. Ibuki, A. Hiraya, K. Shobatake, Y. Matsumi, M. Kawasaki, Chem. Phys. Lett.,
160 (1989) 152-156.
4

57. "Vacuum ultraviolet absorption spectra of thiirane and thietane", I. Tokue, A. Hiraya, K.
Shobatake, J. Chem. Phys., 91 (1989) 2808-2813.
58. "Synchrotron radiation assisted deposition of carbon films", H. Ohashi, K. Inoue, Y. Saito,
A. Yoshida, H. Ogawa, K. Shobatake, Appl. Phys. Lett., 55 (1989) 1644-1646.
59. "Microscopic solvent effects on the S1-T2 intersystem crossing of 9,10-diphenylanthracene
in supersonic free jets", F. Tanaka, S. Hirayama, K. Shobatake, Chem. Phys. Lett., 164(1989) 335-340.
60. "Electronic relaxation in isomers of 9,10-dimethoxyanthracene and their rare-gas
complexes", S. Hirayama, F. Tanaka, K. Shobatake, J. Phys. Chem., 94 (1990) 1317-1323.
61. "Formation of NH(c1Π), NH(A3Π), and NCO(A2 ) in the VUV photolysis of HNCO", K.
Uno, T. Hikida, A. Hiraya, K. Shobatake, Chem. Phys. Lett., 166 (1990) 475-479.
62. "Photoexcitation of M(CH3)2 (M=Zn, Cd, Hg) compounds in the 106-270 nm region", T.
Ibuki, A. Hiraya, K. Shobatake, J. Chem. Phys., 92 (1990) 2797-2805.
63. "Polystyrene thin film formed by synchrotron radiation chemical vapor deposition", H.
Yamada, M. Nakamura, H. Katoh, T. Hayakawa, S. Morita, S. Hattori, H. Ohashi, K.
Shobatake, J. Appl. Phys., 67 (1990) 2613-2616.
64. " Vacuum ultraviolet photochemistry of CHFCl2 and CHFBr2. Absorption spectra andCHF(1A") radical formation", T. Ibuki, A. Hiraya, K. Shobatake, Y. Matsumi, M. Kawasaki,
J. Chem. Phys., 92 (1990) 4277-4282.
65. "Synchrotron radiation-excited etching of SiO2 with SF6 at 143 and 251Å ”, K. Shobatake,
H. Ohashi, K. Kume, A. Hiraya, N. Hayasaka, H. Okuno, A. Yoshida, Appl. Phys. Lett., 56(1990) 2189-2191.
66. "Natural radiative lifetimes of anthracene derivatives and their dependence on refractive
index", S. Hirayama, Y. Iuchi, F. Tanaka, K. Shobatake, Chem. Phys., 144 (1990) 401-406.
67. "Direct absorption spectra of S2 and S3 states of benzene clusters", A. Hiraya, K.
Shobatake, Chem. Phys. Lett., 178 (1991) 543-546.
68.; "UV and VUV direct absorption spectra of jet-cooled benzene in 130-260 nm", A. Hiraya,
K. Shobatake, J. Chem. Phys., 94 (1991) 7700-7706.
69. "Characterization of silica glasses sintered under Cl2 ambients", K. Awazu, H. Kawazoe,
K. Muta, T. Ibuki, K. Tabayashi, K. Shobatake, J. Appl. Phys., 69 (1991) 1849-1852.
70. "Collision energy dependence of the cross section for production of CN(B2Σ+) in thereaction of Ar(3P0,2) and Kr(3P0,2) with BrCN", T. Nagata, T. Kondow, K. Kuchitsu, K.
Tabayashi, K. Shobatake, J. Chem. Phys., 95 (1991) 1011-1019.
71. "Velocity distribution of desorbing products in the oxidation of carbon monoxide on
palladium (110) surfaces", T. Matsushima, K. Shobatake, K. Nagai, Y. Ohno, K. Tabayashi,
Chem. Phys. Lett., 187 (1991) 277-280.
572. "Reaction diagram of carbon monoxide and oxygen on palladium (100) and angular
distribution of reactive carbon dioxide desorption", Y. Ohno, T. Matsushima, K. Shobatake,
H. Nozoe, Surf. Sci., 273 (1992) 291-300.
73. "Vacuum ultraviolet absorption spectra and photodissociative excitation of CHBr2Cl and
CHBrCl2", T. Ibuki, A. Hiraya, K. Shobatake, J. Chem. Phys., 96 (1992) 8793-8798.
74. "S1-T2 level inversion of 9,10-dimethylanthracene caused by the coordination of one
rare-gas atom", F. Tanaka, S. Hirayama, K. Shobatake, Chem. Phys. Lett., 195 (1992)
243-247.
75. "Anisotropic velocity distribution of desorbing product in carbon monoxide oxidation on
palladium(110)", T. Matsushima, K. Shobatake, Y. Ohno, K. Nagai, K. Tabayashi, J. Chem.
Phys., 97 (1992) 2783 – 2789.
76. "Radiative lifetime and electronic relaxation of 9-cyanoanthracene in rare gas clusters andin rare gas matrices", M. Kono, Y. Kubo, S. Hirayama, K. Shobatake, Chem. Phys. Lett.,
198 (1992) 214 – 219.
77. "Single vibronic level relaxation in photoreactive 9-tert-butylanthracence", S. Hirayama,
M. Kono, Y. Kubo, F. Tanaka, K. Shobatake, J. Phys. Chem., 96 (1992) 10666 – 10571.
78. "Spatial and velocity distributions of product desorption in carbon monoxide oxidation
over palladium (110) and reconstructed platinum (110)(1x2) surfaces", T. Matsushima, K.
Shobatake, Y. Ohno, Surf. Sci., 283 (1993) 101-108.
79. "Mechanisms of synchrotron radiation-excited etching reactions of semiconductormaterials", H. Ohashi, A. Yoshida, K. Tabayashi, K. Shobatake, Appl. Surf. Sci., 69 (1993)
20-26.
80. "Molecular beam study of materials for vacuum technology: II. Interaction of gas
molecules with stainless steel surface (分子線による真空材料の評価(第１報，気体分子とステンレス表面の干渉))", 近藤邦和, 藤本哲夫, 新見智秀, 正畠宏祐, 日本機械学会論文集(Trans. Jpn. Soc. Mech. Eng.), 59(No. 560) B (1993) 1057-1062.
81.; "Molecular beam study of materials for vacuum technology: II. Improvement of surface
characteristics by Ag ion-plating (分子線による真空材料の評価(第２報，銀イオンプレーテｲングによる表面改質))", 近藤邦和, 藤本哲, 新見智秀, 正畠宏祐, 日本機械学会論文集(Trans. Jpn. Soc. Mech. Eng.), 59(No. 562) B (1993) 1946-1952.
82. "A scattering experiment of molecular beams for estimation of the adsorption probability",
T. Fujimoto, T. Ni-imi, K. Shobatake, K. Kondo, Vacuum, 44 (1993) 429-431.
83. "Photodissociation of BrCN in the vacuum ultraviolet region", K. Kanda, S. Katsumata, T.
Nagata, Y. Ozeki, T. Kondow, K. Kuchitsu, A. Hiraya, K. Shobatake, Chem. Phys., 175(1993) 499-411.
84. "Fluorescence excitation spectra and quantum yield in vacuum ultraviolet
photodissociation of CF3CN", Dock-Chil Che, T. Kasai, H. Ohyama, K. Kuwata, K.
6

Tabayashi, K. Shobatake, Chem. Lett., (1994)133 - 134.
85. "Absorption spectra of alkali cyanide vapor", H. Yasumatsu, T. Kondow, K. Suzuki, K.
Tabayashi, K. Shobatake, J. Phys. Chem., 98 (1994) 1407 - 1410.
86. "Velocity distributions of nascent SiCln (n = 2, 3, and 4) products formed from thereaction of Si(111) a with Cl2 beam", H. Yoshikawa K. Shobatake, Chem. Phys. Lett., 223(1994) 341 - 346.
87. "Energy and state selective electronic relaxation of anthracene derivatives and their vander Waals complexes __ an attempt to link dynamics in gas phase and solution", S.
Hirayama, F. Tanaka, K. Shobatake, Trends in Photochemistry and Photobiology, 3 (1994)
549 - 579.
88. "Photo-CVD of Al2O3 thin films using a D2 lamp", Y. Fukushima, J. Saraie, K. Tabayashi,
K. Shobatake, Appl. Surf. Sci., 79/80 (1994) 361 - 365.
89. "Photodissociative excitation processes of XeF2 in the vacuum ultraviolet region 105 - 180
nm", M. Kono, K. Shobatake, J. Chem. Phys., 102 (1995) 5966-5977.
90 "Absorption spectrum of C60 in the gas phase: Formation and recombination ofelectron-hole pair", H. Yasumatsu, T. Kondow, H. Kitagawa, K. Tabayashi, K. Shobatake, J.
Chem. Phys., 104 (1995) 899 - 902.
91. "Effects of clustering of rare-gas atoms on the rate of S1-T2 intersystem crossing for
9-methylanthracene", F. Tanaka, Y. Tanaka, S. Hirayama, M. Kono, and K. Shobatake,Chem. Phys. Lett. , 252 (1996) 258 – 262.
92. "Synchrotron radiation excited etching of silicon surface studied by velocity distribution
measurements of desorbed species", H. Ohashi, K. Shobatake, J. Electron Spectry. Related
Phenomena, 80 (1996) 73-76.
93. "Synchrotron radiation etching of diamond surfaces in the low pressure atmosphere of O2and SF6", E. Ishiguro, H. Ohashi, T. Sasano, K. Shobatake, J. Electron Spectry. Related
Phenomena, 80 (1996) 77 - 80.
94. "Synchrotron radiation excited etching of diamond", H. Ohashi, E. Ishiguro, T. Sasano, K.
Shobatake, Appl. Phys. Lett., 68 (1996) 3713 - 3715.
95. "Photoabsorption and fluorescence cross sections of SiCl4 in the vacuum ultraviolet region
105 - 165 nm", T. Ibuki, M. Kono, K. Shobatake, J. Chem. Phys., 105 (1997) 4853 -4859.
96. "Comparative study on the photodynamics of chloromethyl-anthrascenes in a supersonicfree jet and solution", F. Tanaka, K. Morimoto, H. Kubo, Y. Yada, S. Hirayama, M. Kono, K.
Shobatake, J. Chem. Soc., Faraday Trans., 93 (1997) 3013- 3019.
97. "Photodissociation spectroscopy of ICN in the vacuum ultraviolet region", K. Kanda, S.
Katsumata, T. Nagata, T. Kondow, A. Hiraya, K. Tabayashi, K. Shobatake, Chem. Phys.,
218 (1997) 199-209.
98. ”気体分子による気体分子－固体表面相互作用の解析（第１報，気体分子の In-plane7

と Out-of-plane における散乱挙動），山西伸宏，松本洋一郎, 青木功, 正畠宏祐, 日本機械学会論文集（Ｂ編）65 (630 号) (1999-2)27 -33.
99. "Modification of a high vacuum, crossed molecular beam scattering system to perform
angle-resolved, gas-surface scattering studies under ultrahigh vacuum conditions", H.
Yoshikawa, H. Ohashi, K. Tabayashi, M. Suzui, T. Horigome, K. Hayakawa, S. Kato, K.
Shobatake, K. Ito, T. Fujimoto, Rev. Sci. Instrum., 70 (1999) 1806 - 1815.
100. "Multistage gas-surface interaction model for the direct simulation Monte Carlo method",N. Yamanishi, Y. Matumoto, K. Shobatake, Phys. Fluid, 11 (1999) 3540- 3552.
101. "Photodissociation spectroscopy of ClCN in the vacuum ultraviolet region", K. Kanda,
M. Kono, T. Nagata, A. Hiraya, K. Tabayashi, K. Shobatake, Chem. Phys., 255 (2000)
369-378.
102. “Removal of dioxins in fly ash by vacuum heat treatment I. Temperature dependence”, K.
Shobatake, K. Yamanaka, K. Takeuchi, T. Seki, T. Imura, T. Abe, K. Sawabe,
Organohalogen Compounds, 54 (2001) 230-233.
103. “Removal of dioxins in fly ash by vacuum heat treatment II. Temperature dependence
and the outcome of OCDD”, T. Abe, K. Takeuchi, Y. Misaka, H. Hattori, M. Itoh, K. Ohba,
M. Watanabe, T. Imura, K. Sawabe, K. Shobatake, Organohalogen Compounds, 58 (2002)
149-152.
104. “Identification of desorption products from the thermal reaction of AlN with XeF2 vapor
using molecular beam mass spectrometry and a time-of-flight technique”, M. Watanabe, T.
Iida, K. Akiyama, S. Narita, T. Ishikawa, H. Sakai, K. Sawabe, K. Shobatake, Jpn. J. Appl.
Phys., 42 (2003) L356-L358.
105. “X-ray photoelectron spectroscopy of polycrystalline AlN surface exposed to the reactive
environment of XeF2”, M., Y. Mori, T. Ishikawa, T. Iida, K. Akiyama, H. Sakai, K. Sawabe,
K. Shobatake, Appl. Surf. Sci., 217 (2003) 82-87.
106. “Thermal desorption behavior of AlF3 formed on Al2O3”, M. Watanabe, T. Iida, K.
Akiyama, T. Ishikawa, H. Sakai, K. Sawabe, K. Shobatake, Jpn. J. Appl. Phys., 42 (2003)
L680-L682.
107. “Dechlorination/hydrogenation reactions of dioxins in activated carbon heated undervacuum”, Y. Misaka, K. Ohba, T. Abe, M. Watanabe, T. Imura, J. Kumagai, E. Fujimori, K.
Sawabe, K. Shobatake, Organohalogen Compounds, 63 (2003) 272-275.
108. “Surface characterization of 3C-SiC exposed to XeF2”, M. Watanabe, Y. Mori, H. Sakai,
T. Iida, S. Koide, E. Maeta, K. Sawabe, K. Shobatake, Jpn. J. Appl. Phys., 43 (2004)
L346-L348.
109. “Trampoline motions in Xe–graphite (0001) surface scattering”, Y. Watanabe, M.
Hashinokuchi, K. Sawabe, K. Shobatake, H. Yamaguchi, Y. Matsumoto, S. Maruyama,
Chem. Phys. Lett., 413 (2005) 331-334.
110. “Thermal reaction of polycrystalline AlN with XeF2“, M. Watanabe, Y. Mori, T. Ishikawa,
H. Sakai, T. Iida, K. Akiyama, S. Narita, K. Sawabe, K. Shobatake, J. Vac. Sci. Tech., A 23
8

(2005) 1638-1646.
111. “Thermal reaction of polycrystalline SiC with XeF2“, M. Watanabe, Y. Mori, T. Ishikawa,
H. Sakai, T. Iida, S. Koide, E. Maeta, K. Sawabe, K. Shobatake, J. Vac. Sci. Tech., A 23
(2005) 1647-1656.
112. “Energy transfer in hyperthermal Xe - graphite surface scattering”, Y. Watanabe, H.
Yamaguchi, M. Hashinokuchi, K. Sawabe, S. Maruyama, Y. Matsumoto, K. Shobatake, Eur.
Phys. J., D 38 (2006) 103-110.
113. “Spatial distributions of desorbing products in steady-state NO and N2O reductions on
Pd(110)”, Y. Ma, T. Matsushima, K. Shobatake, A. Kokalj, J. Chem. Phys., 124 (2006)
144711-1-11.
114. “Removal of PCDDs/DFs and dl-PCBs in MWI fly ash by heating under vacuum”, Y.
Misaka, K. Yamanaka, K. Takeuchi, K. Sawabe, K. Shobatake, Chemosphere, 64 (2006)
619-627.
115. “Dechlorination/hydrogenation and destruction reactions of PCDDs in OCDD-added fly
ash heated under vacuum”, Y. Misaka, T. Abe, K. Takeuchi, K. Ohba, K. Sawabe, K.
Shobatake, Chemosphere, 65 (2006) 419-426.
116. “The collimation angle shift of desorbing product N2 in a steady- state N2O+CO reaction
on Rh(110)”, T. Matsushima, O. Nakagoe, K. Shobatake, A. Kokalj, J. Chem. Phys. 125(2006) 133402-1-10.
117. “Adsorption structure of thiophene on Si(100)-(2×1) studied by scanning tunnelingmicroscopy and density functional theory”, N. Isobe, T. Shibayama, Y. Mori, K. Shobatake,
K. Sawabe, Chem. Phys. Lett., 443 (2007) 347-351.
118. “Surface reaction dynamics and energy partitioning”, T. Matsushima, K. Shobatake, (inpress) in J. Mol. Catal. A (Temkin Memorial Issue).

9

総説・解説・報告書
R1.「分子線法による素反応過程の研究」, 正畠宏祐, 日本物理学会誌, 36 (1981)
105-112.
R2.「気相での化学反応はどのように進むか？－交差分子線法による研究－」, 正畠宏祐, 化学の領域, 37 (1983) 940-949.
R3.「UVSOR と分子科学」, 井口洋夫, 正畠宏祐, 渡辺誠, 加速器科学, 1 (1986) 15-31.
R4.「シンクロトロン放射分光学, 第６講 化学的立場からの気体実験」, 小谷野猪之助, 正畠宏祐, 分光研究, 35 (1986) 493-517.
R5.「1986 ノーベル化学賞.-- 化学反応をミクロなレベルでとらえる」, 正畠宏祐, 化
学 42 (1987) 9-13.
R6.「1986 年ノーベル化学賞, 化学反応動力学－化学反応の様子を可視化する」, 正畠
宏祐, 現代化学, 1987 (1987) 12-17.
R7.「1988 年の化学

反応中間体の寿命を測る」, 正畠宏祐, 化学, 43 (1988) 60-61.

R8.「分子科学における SOR 分光 － UVSOR は今－」, 渡辺誠, 正畠宏祐, 三谷洋
興, 日本物理学会誌, 43 (1988) 775-782.
R9.「分子線」, 正畠宏祐, 学術月報, 41 (1988) 52.
R10.「反応における共鳴現象－－遷移状態スペクトロスコピー」, 正畠宏祐, 化学, 44(1989) 72-73.
R11. 「9-メトキシアントラセンの希ガスクラスターの形成と光解離ダイナミックス」,
平山 鋭, 田中富士雄, 正畠宏祐, 日本化学会誌, 1989 (1989) 1217-1224.
R12.「1990 の化学－表面反応の動力学」, 正畠宏祐, 化学, 45 (1990) 62-63.
13.「放射光励起エッチング反応」, 正畠宏祐, 放射光, 3 (1990) 27-39.
R14.「光化学と分光計測.
(1990) 187-202.

第３講

分子線技術」, 正畠宏祐, 篠原久典, 分光研究, 39

R15.「夢の光源 SOR」, 正畠宏祐, 化学, 45 (1990) 608.
R16.「振動および結合選択した H2O 分子の反応」, 正畠宏祐, 化学, 47 (1992) 150.
R17.「状態から状態への化学の進歩」, 正畠宏祐, 化学, 48 (1993) 146-147.
R18.「分子線法による表面反応動力学の研究」, 正畠宏祐, 大橋治彦, 表面科学, 16(1995) 2 – 5.
10

R19.「Eley-Rideal 機構によって進む触媒反応生成物は観測できるか」正畠宏祐，豊田研究報告，59 (2006) 57-68.
R20.「触媒表面反応を統べる分子間相互作用を決定する実験的研究」，正畠宏祐，豊田研究報告，60 (2007) 61-69.
R21.「気相分子と固体表面吸着種との直接反応による生成物の探索」，正畠宏祐，豊田研究報告，61 (2008) 57-67.
R22.「気相分子と固体表面吸着種との直接反応による生成物の探索－2」，正畠宏祐，
豊田研究報告，62 (2009) 27-34.

11

単行本等
M1. "Molecular beam studies of reaction dynamics of F + H2, D2", P. K. Sparks, C. C. Hayden,
K. Shobatake, D. M. Neumark, Y. T. Lee, (1980) 91-105, Horizons of Quantum Chemistry,K. Fukui and B. Pullman, eds., D. Reidel, Holland.
M2. 「化学反応素過程とその測定法」, 正畠宏祐, 半導体技術, Vol. 20, 超ＬＳＩ技術,
No. 7 (1983) 3-28. プロセスの基礎, 西沢潤一編, 半導体研究振興会工業調査会,
M3.「気体の巨視的性質」, (1991) 20-37. 放送大学教材：物質の科学・化学基礎, 田丸
謙二編, 放送大学教育振興会.
M4. "Absorption and Fluorescence Studies of Molecules and Molecular Clusters," K.
Shobatake, A. Hiraya, K. Tabayashi, T. Ibuki, (1991) 503-562. Vacuum Ultraviolet
Photoionization and Photodissociation of Molecules and Clusters, C. Y. Ng, ed. (World
Scientific Pub., Singapore).
M5. 「表面光化学反応と半導体プロセス技術への応用」, 正畠宏祐, 宇理須恒雄,(1991) 181-196.シンクロトロン放射光 化学への基礎的応用, 市村禎二郎, 旗野嘉彦, 井口洋夫編, 学会出版, 東京．
M6. "Photodissociation dynamics of ethylene sulfide and allene at 193 nm studied bytime-of-flight mass spectroscopy", K. Tabayashi, K. Shobatake, J. SPIE-Internl. Soc.
Optical Eng., 1638 (1992) 185-196. Optical Methods for Time- and State-Resolved
Chemistry.
M7. 「分子線」, 正畠宏祐, (1993) 125 – 149. 実験化学講座, 第４版, No. 11, 反応と速度, 日本化学会編, 丸善, 東京.
M8. 「分子線」，正畠宏祐, (1993) 107 – 130. 実験化学講座, 第４版, No. 8, 分光 III, 日
本化学会編丸善, 東京.
M9. "Dynamics and Energy Transfer in Scattering of Xe, O2 and Cl2 from Graphite Surface",
K. Shobatake, K. Ito, H. Yoshikawa, T. Ogi, H. Ariga, H. Ohashi, T. Fujimoto, Springer
Series in Solid-State Sciences 121, (1996)112-120. Elementary Processes in Excitations
and Reactions on Solid Surfaces, A. Okiji, H. Kasai, and K. Makoshi, eds., Springer,
Tokyo.
M10. "Diamond", H. Ohashi, K. Shobatake, McGraw-Hill Year Book of Science and Technology,(1999) 128-131.

M11.「化学の基礎 ― 化学結合の理解」, 正畠宏祐, (2004) , 化学同人, 京都市.

12