Silver Paste Plus

Safety Data Sheet
Section 1: Identification of the Substance/Mixture and of the Company/Undertaking
1.1 Product identifier
Product Name
Synonyms•

Silver Paste Plus

• Silver Composition; SPI Supplies® Silver Paste Plus™
• 05063-AB

Product Code

1.2 Relevant identified uses of the substance or mixture and uses advised against
Relevant identified use(s)• Mounting of samples for scanning electron microscopy; mounting of silicon wafers
when producing high temperature thin film superconductor materials; PC board repairs
and other electronic industry applications.

1.3 Details of the supplier of the safety data sheet
Manufacturer• SPI Supplies Division Structure Probe, Inc.
206 Garfield Ave.
West Chester, PA 19380
United States
http://www.2spi.com
SDS@2spi.com
Telephone (General) • 1-(610)-436-5400

1.4 Emergency telephone number
Manufacturer• 1-(800)-424-9300 - Chemtrec• 1-(703)-741-5970 - Worldwide

Manufacturer

Section 2: Hazards Identification
EU/EEC

According to: Regulation (EC) No 1272/2008 (CLP)/REACH 1907/2006 [amended by 2015/830]

2.1 Classification of the substance or mixture
CLP• Flammable Liquids 3 - H226
Hazardous to the aquatic environment Chronic 2 - H411

2.2 Label Elements
CLP

WARNING

Hazard statements • H226 - Flammable liquid and vapour

H411 - Toxic to aquatic life with long lasting effects

Precautionary statements
Prevention • P233 - Keep container tightly closed.
P235 - Keep cool.
Preparation Date: 21/February/2014
Revision Date: 19/December/2016

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Silver Paste Plus

P240 - Ground and/or bond container and receiving equipment.
P241 - Use explosion-proof electrical/ventilating/lighting/equipment.
P242 - Use only non-sparking tools.
P243 - Take precautionary measures against static discharge.
P273 - Avoid release to the environment.
P280 - Wear protective gloves/protective clothing/eye protection/face protection.
Response • P370+P378 - In case of fire: Use appropriate media for extinction.
P303+P361+P353 - IF ON SKIN (or hair): Take off immediately all contaminatedclothing. Rinse skin with water/shower.
P391 - Collect spillage.
Storage/Disposal • P403+P235 - Store in a well-ventilated place. Keep cool.
P501 - Dispose of content and/or container in accordance with local, regional,
national, and/or international regulations.

2.3 Other Hazards
CLP• Heating above the melting point releases metallic oxides which may cause metal fume
fever by inhalation. The symptoms are shivering, fever, malaise and muscular pain.
Repeated exposure to silver can cause argyria/argyrosis, a grey-blue discoloration of
the eyes, nose, throat, skin and internal organs.
According to Regulation (EC) No. 1272/2008 (CLP) this material is consideredhazardous.

United States (US)

According to: OSHA 29 CFR 1910.1200 HCS

2.1 Classification of the substance or mixture
OSHA HCS 2012

• Flammable Liquids 3
Hazards Not Otherwise Classified - Health Hazards - Metal fume fever, and argyria, a
blue-gray discoloration of the skin, mucous membranes, and eyes

2.2 Label elements
OSHA HCS 2012WARNING

Hazard statements • Flammable liquid and vapour
Precautionary statements
Prevention • Keep away from heat, sparks, open flames and/or hot surfaces. - No smoking.
Keep container tightly closed.
Keep cool.
Ground and/or bond container and receiving equipment.
Use explosion-proof electrical/ventilating/lighting/equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Wear protective gloves/protective clothing/eye protection/face protection.
Response • In case of fire: Use to extinguish.
Take off immediately all contaminated clothing.
Storage/Disposal • Store in a well-ventilated place. Keep cool.
Dispose of content and/or container in accordance with local, regional, national, and/orinternational regulations.

2.3 Other hazards
OSHA HCS 2012

Preparation Date: 21/February/2014
Revision Date: 19/December/2016• Under United States Regulations (29 CFR 1910.1200 - Hazard Communication
Standard), this product is considered hazardous.

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Section 3 - Composition/Information on Ingredients
3.1 Substances• Material does not meet the criteria of a substance.

3.2 Mixtures
Composition
Chemical NameClassifications According toRegulation/Directive
EU CLP: Aquatic Chronic 2, H411
OSHA HCS 2012: Hazard Not Otherwise
Classified - Health Hazard - Metal fume fever,
and argyria, a blue-gray discoloration of theskin, mucous membranes, and eyes%

LD50/LC50

60%
TO
70%

NDA

10%
TO
20%

Ingestion/Oral-Rat
LD50 • 8532
mg/kg
Skin-Rabbit LD50 •>5 g/kg

EU CLP: Annex VI, Table 3.1: Flam. Liq. 3,
H226
OSHA HCS 2012: Not Classified

NDA

CAS:65859-05
-4

1%
TO
10%

NDA

EU CLP: Not Classified
OSHA HCS 2012: Not Classified

NDA

Organic solvent

NDA

0.1%
TO
1%

NDA

EU CLP: Acute Tox. 4, H302; Acute Tox. 4,
H312; Aquatic Chronic 3, H412
OSHA HCS 2012: Acute Tox. 4 (Orl); AcuteTox. 4 (Skn)

NDA

TolueneCAS:108-88-3
EC
Number:203625-9
EU Index:601021-00-3<
0.1%

Ingestion/Oral-Rat
LD50 • 636 mg/kg
Skin-Rabbit
LD50 • 14100µL/kg
Inhalation-Rat
LC50 • 49 g/m³ 4Hour(s)

EU CLP: Community Workplace Exposure
Limits
OSHA HCS 2012: Exposure Limits

NDA

Ethylene glycol monobutyl
ether acetate

CAS:112-07-2
EC
Number:203933-3
EU Index:607038-00-2

<
0.1%

NDA

EU CLP: Community Workplace Exposure
Limits
OSHA HCS 2012: Exposure Limits

NDA

Silver

1-Methoxy-2-propanol
acetate2-Propenoic acid, 2-methyl-, polymer with ethyl 2methyl-2-propenoate andmethyl 2-propenoate

Identifiers
CAS:7440-224
EC
Number:231131-3
CAS:108-65-6
EC
Number:203603-9
EU Index:607195-00-7

Comments

NDA

See Section 16 for full text of H-statements.

Section 4 - First Aid Measures
4.1 Description of first aid measures
Inhalation
Skin
Preparation Date: 21/February/2014
Revision Date: 19/December/2016• Move victim to fresh air. Administer oxygen if breathing is difficult. Give artificial
respiration if victim is not breathing. Get medical attention immediately.
• Wash skin with soap and water. Remove and isolate contaminated clothing. If irritation
develops and persists, get medical attention.
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Eye
Ingestion• In case of contact with substance, immediately flush eyes with running water for atleast 20 minutes. If eye irritation persists: Get medical advice/attention.
• Rinse mouth. Do NOT induce vomiting. Never give anything by mouth to an
unconscious person. Obtain medical attention immediately if ingested.

4.2 Most important symptoms and effects, both acute and delayed• Refer to Section 11 - Toxicological Information.

4.3 Indication of any immediate medical attention and special treatment needed
Notes to Physician• All treatments should be based on observed signs and symptoms of distress in thepatient. Consideration should be given to the possibility that overexposure to materials
other than this product may have occurred.

Section 5 - Firefighting Measures
5.1 Extinguishing media
Suitable Extinguishing Media • In case of fire use media as appropriate for surrounding fire.
Unsuitable ExtinguishingMedia• Do not use a direct stream of water.

5.2 Special hazards arising from the substance or mixture
Unusual Fire and Explosion
Hazards

Hazardous Combustion
Products• HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.
Containers may explode when heated.
Many liquids are lighter than water.
Vapors may form explosive mixtures with air.
Most vapors are heavier than air. They will spread along ground and collect in low or
confined areas (sewers, basements, tanks).
Vapors may travel to source of ignition and flash back.
Vapor explosion hazard indoors, outdoors or in sewers.
Runoff to sewer may create fire or explosion hazard.
• Hazardous decomposition products formed under fire conditions.

5.3 Advice for firefighters• Structural firefighters' protective clothing will only provide limited protection.
Wear positive pressure self-contained breathing apparatus (SCBA).
Move containers from fire area if you can do it without risk.
LARGE FIRES: Cool containers with flooding quantities of water until well after fire isout.

Section 6 - Accidental Release Measures
6.1 Personal precautions, protective equipment and emergency procedures
Personal Precautions
Emergency Procedures• CAUTION: Victim may be a source of contamination. Do not walk through spilledmaterial. Use appropriate Personal Protective Equipment (PPE)• As an immediate precautionary measure, isolate spill or leak area for at least 50
meters (150 feet) in all directions. LARGE SPILL: Consider initial downwind evacuation
for at least 300 meters (1000 feet) ELIMINATE all ignition sources (no smoking, flares,
sparks or flames in immediate area). Keep unauthorized personnel away. Stay
upwind. Keep out of low areas. Ventilate closed spaces before entering.

6.2 Environmental precautions• Prevent entry into waterways, sewers, basements or confined areas.

6.3 Methods and material for containment and cleaning up
Containment/Clean-up
MeasuresPreparation Date: 21/February/2014
Revision Date: 19/December/2016• Stop leak if you can do it without risk.
Absorb or cover with dry earth, sand or other non-combustible material and transfer tocontainers.
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Use clean non-sparking tools to collect absorbed material.
A vapor suppressing foam may be used to reduce vapors.
All equipment used when handling the product must be grounded.
LARGE SPILLS: Dike far ahead of liquid spill for later disposal.
LARGE SPILLS: Water spray may reduce vapor; but may not prevent ignition inclosed spaces.

6.4 Reference to other sections• Refer to Section 8 - Exposure Controls/Personal Protection and Section 13 - Disposal
Considerations.

Section 7 - Handling and Storage
7.1 Precautions for safe handling
Handling• Use only in well ventilated areas. Keep away from heat, sparks, and flame. Do not use
sparking tools. Take precautionary measures against static charges. All equipmentused when handling the product must be grounded. Wear appropriate personal
protective equipment, avoid direct contact. Avoid breathing fume, mist, vapours and/or
spray. Avoid contact with skin, eyes, and clothing. Wash thoroughly with soap andwater after handling and before eating, drinking, or using tobacco.

7.2 Conditions for safe storage, including any incompatibilities
Storage• Do not reuse empty container. Store in a tightly closed container. Store in a cool, dry,well-ventilated place. Keep away from sources of ignition – No Smoking.

7.3 Specific end use(s)• This item is not being offered for clinical or diagnostic applications, agricultural uses orfor human or animal consumption. Refer to Section 1.2 - Relevant identified uses.

Section 8 - Exposure Controls/Personal Protection
8.1 Control parameters
Exposure Limits/Guidelines
Result

ACGIH

NIOSH

OSHA

Ceilings Not establishedNot established

300 ppm Ceiling

TWAs

20 ppm TWA

100 ppm TWA; 375 mg/m3 TWA

200 ppm TWA

STELs

Not established

150 ppm STEL; 560 mg/m3 STEL

Not established

Ethylene glycol
monobutyl ether
acetate(112-07-2)

TWAs

20 ppm TWA

5 ppm TWA; 33 mg/m3 TWA

Not established

Silver(7440-22-4)

TWAs

0.1 mg/m3 TWA (dust and fume)0.01 mg/m3 TWA (dust)

0.01 mg/m3 TWA

Toluene(108-88-3)

8.2 Exposure controls
Engineering
Measures/Controls• Good general ventilation should be used. Ventilation rates should be matched toconditions. If applicable, use process enclosures, local exhaust ventilation, or otherengineering controls to maintain airborne levels below recommended exposure limits.
If exposure limits have not been established, maintain airborne levels to an acceptablelevel. Use explosion-proof electrical/ventilating/lighting/equipment.
Personal Protective Equipment
Respiratory• Follow the OSHA respirator regulations found in 29 CFR 1910.134. Use a
NIOSH/MSHA approved respirator if exposure limits are exceeded or symptoms areexperienced.
Eye/Face• Wear safety goggles.
Preparation Date: 21/February/2014
Revision Date: 19/December/2016

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Skin/Body• Wear appropriate gloves.
• Controls should be engineered to prevent release to the environment, including
procedures to prevent spills, atmospheric release and release to waterways. Follow
best practice for site management and disposal of waste.

Environmental Exposure
Controls

Key to abbreviations
ACGIH = American Conference of Governmental Industrial Hygiene
NIOSH = National Institute of Occupational Safety and Health
OSHA = Occupational Safety and Health Administration

STEL = Short Term Exposure Limits are based on 15-minute exposures
TWA = Time-Weighted Averages are based on 8h/day, 40h/week exposures

Section 9 - Physical and Chemical Properties
9.1 Information on Basic Physical and Chemical Properties
Material Description
Physical Form

LiquidAppearance/Description

Grey viscous liquid with acrylic-like
odor.

Color

Grey

Odor

Acrylic-like odor.

Odor Threshold

Data lacking

General Properties
Boiling Point

Data lacking

Melting Point/Freezing Point

Data lacking

Decomposition Temperature

Data lacking

pH

Data lacking

Specific Gravity/Relative Density

Data lacking

Density

3 g/mL

Water Solubility

Slightly Soluble

Viscosity

Data lacking

Explosive Properties

Data lacking

Oxidizing Properties:

Data lacking

Vapor Pressure

Data lacking

Vapor Density

Data lacking

Evaporation Rate

Data lacking

Volatility

Flammability
Flash Point

51 °C(123.8 °F) CC (Closed Cup)

UEL

Data lacking

LEL

Data lacking

Autoignition

Data lacking

Flammability (solid, gas)

Data lacking

Environmental
Octanol/Water Partition coefficient

Data lacking

9.2 Other Information• No additional physical and chemical parameters noted.

Section 10: Stability and Reactivity
10.1 Reactivity• No dangerous reaction known under conditions of normal use.

10.2 Chemical stability• Stable under normal temperatures and pressures.

10.3 Possibility of hazardous reactions• Hazardous polymerization will not occur.

10.4 Conditions to avoid• Keep away from heat, sparks and flame.

10.5 Incompatible materials
Preparation Date: 21/February/2014
Revision Date: 19/December/2016

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• Acids, bases, and strong oxidizing agents.

10.6 Hazardous decomposition products• Under fire conditions: Carbon monoxide, carbons dioxide, unburned hydrocarbons,metal oxides.

Section 11 - Toxicological Information
11.1 Information on toxicological effects
Components
Silver (60% TO
70%)744022-4

Multi-dose Toxicity: Ingestion/Oral-Rat TDLo • 8400 mg/kg 28 Day(s)-Intermittent; Blood:Changes in serum
composition (e.g., TP, bilirubin cholesterol); Blood:Changes in erythrocyte (RBC) count;
Biochemical:Enzyme inhibition, induction, or change in blood or tissue levels:Phosphatases

1-Methoxy-2propanol acetate(10% TO 20%)10865-6

Acute Toxicity: Ingestion/Oral-Rat LD50 • 8532 mg/kg; Skin-Rabbit LD50 • >5 g/kg

GHS Properties

Classification

Acute toxicity

EU/CLP • Data lacking
OSHA HCS 2012 • Data lacking

Skin corrosion/Irritation

EU/CLP • Data lacking
OSHA HCS 2012 • Data lacking

Serious eye damage/Irritation

EU/CLP • Data lacking
OSHA HCS 2012 • Data lacking

Skin sensitization

EU/CLP • Data lacking
OSHA HCS 2012 • Data lacking

Respiratory sensitization

EU/CLP • Data lacking
OSHA HCS 2012 • Data lacking

Aspiration Hazard

EU/CLP • Data lacking
OSHA HCS 2012 • Data lacking

Carcinogenicity

EU/CLP • Data lacking
OSHA HCS 2012 • Data lacking

Germ Cell Mutagenicity

EU/CLP • Data lacking
OSHA HCS 2012 • Data lacking

Toxicity for Reproduction

EU/CLP • Data lacking
OSHA HCS 2012 • Data lacking

STOT-SE

EU/CLP • Data lacking
OSHA HCS 2012 • Data lacking

STOT-RE

EU/CLP • Data lacking
OSHA HCS 2012 • Data lacking

Potential Health Effects
Inhalation
Acute (Immediate)
Chronic (Delayed)• No data available• No data available

Skin
Preparation Date: 21/February/2014
Revision Date: 19/December/2016

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Acute (Immediate)
Chronic (Delayed)• No data available• No data available

Eye
Acute (Immediate)
Chronic (Delayed)• No data available• No data available

Ingestion
Acute (Immediate)
Chronic (Delayed)• No data available• No data available

Other
Chronic (Delayed)• Repeated exposure to silver can cause argyria/argyrosis, a grey-blue discoloration of
the eyes, nose, throat, skin and internal organs.

11.2 Other information• Heating above the melting point releases metallic oxides which may cause metal fume
fever which is an influenza like illness. Symptoms include headache, metallic taste in
the mouth, cough, thirst, throat irritation, shortness of breath, fever, sweating and painin the limbs. This illness is not permanent and recovery usually occurs within 24-48
hours after onset.
Key to abbreviations
LD = Lethal DoseTD = Toxic Dose

Section 12 - Ecological Information
12.1 Toxicity
Components

Silver (60%
TO 70%)

Aquatic Toxicity-Fish: 96 Hour(s) LC50 Pimephales promelas (Fathead Minnow) 0.00213 mg/L Comments: Influenceof Water Quality Parameters on Silver Toxicity: Preliminary Result
14 Day(s) NOEC Oryzias latipes (Japanese Medaka) 0.05 mg/L Comments: Silver Nanoparticles Cause Oxidative
Damage and Histological Changes in Medaka (Oryzias latipes) After 14 Days of Exposure
7440-22Aquatic Toxicity-Crustacea: 7 Day(s) NOEC Water Flea 0.0011 mg/L Comments: The Effects of Silver on Green Algae-4
and Prospects for Trophic Transfer
48 Hour(s) EC50 Water Flea 0.00024 mg/L Comments: Metal Toxicity Tests
Aquatic Toxicity-Algae and Other Aquatic Plant(s): 96 Hour(s) EC50 Chroomonas sp. (Cryptomonad) 0.0014 mg/L
Comments: Silver Transport and Impact in Estuarine and Marine Systems• Toxic to aquatic life with long lasting effects.

12.2 Persistence and degradability• Material data lacking.

12.3 Bioaccumulative potential• Material data lacking.

12.4 Mobility in Soil
• Material data lacking.

12.5 Results of PBT and vPvB assessment• No PBT and vPvB assessment has been conducted.

12.6 Other adverse effects• No studies have been found.
Preparation Date: 21/February/2014
Revision Date: 19/December/2016

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Section 13 - Disposal Considerations
13.1 Waste treatment methods
Product waste• Dispose of content and/or container in accordance with local, regional, national, and/orinternational regulations.
• Dispose of content and/or container in accordance with local, regional, national, and/orinternational regulations.

Packaging waste

Section 14 - Transport Information
14.1 UN
number

14.2 UN proper
shipping name14.3 Transport hazard
class(es)14.4 Packing
group

14.5 Environmental
hazards

DOT

UN1263

Paint related material

3

III

NDA

IMO/IMDG

UN1263

PAINT RELATED MATERIAL

3

III

NDA

IATA/ICAO

UN1263

Paint related material

3

III

NDA

14.6 Special precautions foruser
14.7 Transport in bulk
according to Annex II of
Marpol and the IBC Code• None specified.
• Data lacking.

Section 15 - Regulatory Information
15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixtureSARA Hazard Classifications • Acute, Fire
Inventory
ComponentCAS

EU EINECS

EU ELNICS

TSCA

1-Methoxy-2propanol acetate108-65-6

Yes

No

Yes

2-Propenoic acid, 2methyl-, polymer
with ethyl 2-methyl65859-05-4
2-propenoate andmethyl 2propenoate

No

No

Yes

Ethylene glycol
monobutyl ether
acetate112-07-2

Yes

No

Yes

Silver

7440-22-4

Yes

No

Yes

Toluene108-88-3

Yes

No

Yes

United States
Labor

U.S. - OSHA - Process Safety Management - Highly Hazardous Chemicals• Silver• Toluene• 1-Methoxy-2-propanol acetate
Preparation Date: 21/February/2014
Revision Date: 19/December/2016

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7440-22-4
108-88-3
108-65-6

Not Listed
Not Listed
Not Listed

Format: EU CLP/REACH Language: English (US)EU CLP, OSHA HCS 2012

Silver Paste Plus

• Ethylene glycol monobutyl ether acetate• 2-Propenoic acid, 2-methyl-, polymer with ethyl 2-methyl-2-propenoate and methyl 2propenoate
U.S. - OSHA - Specifically Regulated Chemicals• Silver• Toluene• 1-Methoxy-2-propanol acetate• Ethylene glycol monobutyl ether acetate• 2-Propenoic acid, 2-methyl-, polymer with ethyl 2-methyl-2-propenoate and methyl 2propenoate

112-07-2

Not Listed

65859-05-4

Not Listed

7440-22-4
108-88-3
108-65-6
112-07-2

Not Listed
Not Listed
Not Listed
Not Listed

65859-05-4

Not Listed

7440-22-4
108-88-3
108-65-6
112-07-2

Not Listed

65859-05-4

Not Listed

Environment
U.S. - CAA (Clean Air Act) - 1990 Hazardous Air Pollutants• Silver• Toluene• 1-Methoxy-2-propanol acetate• Ethylene glycol monobutyl ether acetate• 2-Propenoic acid, 2-methyl-, polymer with ethyl 2-methyl-2-propenoate and methyl 2propenoate

Not Listed
Not Listed

U.S. - CERCLA/SARA - Hazardous Substances and their Reportable Quantities• Silver7440-22-4• Toluene108-88-3• 1-Methoxy-2-propanol acetate• Ethylene glycol monobutyl ether acetate• 2-Propenoic acid, 2-methyl-, polymer with ethyl 2-methyl-2-propenoate and methyl 2propenoate

108-65-6
112-07-2

1000 lb final RQ (no reportingof releases of this hazardous
substance is required if thediameter of the pieces of thesolid metal released is >100µm); 454 kg final RQ (noreporting of releases of thishazardous substance isrequired if the diameter of thepieces of the solid metal
released is >100 µm)
1000 lb final RQ; 454 kg final
RQ
Not Listed
Not Listed

65859-05-4

Not Listed

7440-22-4
108-88-3
108-65-6
112-07-2

Not Listed
Not Listed
Not Listed
Not Listed

65859-05-4

Not Listed

7440-22-4
108-88-3
108-65-6
112-07-2

Not Listed
Not Listed
Not Listed
Not Listed

65859-05-4

Not Listed

U.S. - CERCLA/SARA - Radionuclides and Their Reportable Quantities• Silver• Toluene• 1-Methoxy-2-propanol acetate• Ethylene glycol monobutyl ether acetate• 2-Propenoic acid, 2-methyl-, polymer with ethyl 2-methyl-2-propenoate and methyl 2propenoate
U.S. - CERCLA/SARA - Section 302 Extremely Hazardous Substances EPCRA RQs• Silver• Toluene• 1-Methoxy-2-propanol acetate• Ethylene glycol monobutyl ether acetate• 2-Propenoic acid, 2-methyl-, polymer with ethyl 2-methyl-2-propenoate and methyl 2propenoate
U.S. - CERCLA/SARA - Section 302 Extremely Hazardous Substances TPQs
Preparation Date: 21/February/2014
Revision Date: 19/December/2016

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• Silver• Toluene• 1-Methoxy-2-propanol acetate• Ethylene glycol monobutyl ether acetate• 2-Propenoic acid, 2-methyl-, polymer with ethyl 2-methyl-2-propenoate and methyl 2propenoate

7440-22-4
108-88-3
108-65-6
112-07-2

Not Listed
Not Listed
Not Listed
Not Listed

65859-05-4

Not Listed

U.S. - CERCLA/SARA - Section 313 - Emission Reporting• Silver7440-22-4• Toluene108-88-3• 1-Methoxy-2-propanol acetate• Ethylene glycol monobutyl ether acetate• 2-Propenoic acid, 2-methyl-, polymer with ethyl 2-methyl-2-propenoate and methyl 2propenoate

108-65-6
112-07-2

1.0 % de minimis
concentration
1.0 % de minimis
concentration
Not Listed
Not Listed

65859-05-4

Not Listed

7440-22-4
108-88-3
108-65-6
112-07-2

Not Listed
Not Listed
Not Listed
Not Listed

65859-05-4

Not Listed

7440-22-4
108-88-3
108-65-6
112-07-2

Not Listed
Not Listed
Not Listed
Not Listed

65859-05-4

Not Listed

U.S. - California - Proposition 65 - Developmental Toxicity• Silver7440-22-4• Toluene108-88-3• 1-Methoxy-2-propanol acetate• Ethylene glycol monobutyl ether acetate• 2-Propenoic acid, 2-methyl-, polymer with ethyl 2-methyl-2-propenoate and methyl 2propenoate

108-65-6
112-07-2

Not Listeddevelopmental toxicity,
1/1/1991
Not Listed
Not Listed

65859-05-4

Not Listed

U.S. - California - Proposition 65 - Maximum Allowable Dose Levels (MADL)• Silver7440-22-4• Toluene108-88-3• 1-Methoxy-2-propanol acetate• Ethylene glycol monobutyl ether acetate• 2-Propenoic acid, 2-methyl-, polymer with ethyl 2-methyl-2-propenoate and methyl 2propenoate

108-65-6
112-07-2

Not Listed
7000 µg/day MADL (level
represents absorbed dose)
Not Listed
Not Listed

65859-05-4

Not Listed

7440-22-4
108-88-3

Not Listed
Not Listed

U.S. - CERCLA/SARA - Section 313 - PBT Chemical Listing• Silver• Toluene• 1-Methoxy-2-propanol acetate• Ethylene glycol monobutyl ether acetate• 2-Propenoic acid, 2-methyl-, polymer with ethyl 2-methyl-2-propenoate and methyl 2propenoate

United States - California
Environment
U.S. - California - Proposition 65 - Carcinogens List
• Silver• Toluene• 1-Methoxy-2-propanol acetate• Ethylene glycol monobutyl ether acetate• 2-Propenoic acid, 2-methyl-, polymer with ethyl 2-methyl-2-propenoate and methyl 2propenoate

U.S. - California - Proposition 65 - No Significant Risk Levels (NSRL)• Silver• Toluene
Preparation Date: 21/February/2014
Revision Date: 19/December/2016

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• 1-Methoxy-2-propanol acetate• Ethylene glycol monobutyl ether acetate• 2-Propenoic acid, 2-methyl-, polymer with ethyl 2-methyl-2-propenoate and methyl 2propenoate
U.S. - California - Proposition 65 - Reproductive Toxicity - Female• Silver• Toluene• 1-Methoxy-2-propanol acetate• Ethylene glycol monobutyl ether acetate• 2-Propenoic acid, 2-methyl-, polymer with ethyl 2-methyl-2-propenoate and methyl 2propenoate
U.S. - California - Proposition 65 - Reproductive Toxicity - Male• Silver• Toluene• 1-Methoxy-2-propanol acetate• Ethylene glycol monobutyl ether acetate• 2-Propenoic acid, 2-methyl-, polymer with ethyl 2-methyl-2-propenoate and methyl 2propenoate

108-65-6
112-07-2

Not Listed
Not Listed

65859-05-4

Not Listed

7440-22-4
108-88-3
108-65-6
112-07-2

Not Listed
Not Listed
Not Listed
Not Listed

65859-05-4

Not Listed

7440-22-4
108-88-3
108-65-6
112-07-2

Not Listed
Not Listed
Not Listed
Not Listed

65859-05-4

Not Listed

15.2 Chemical Safety Assessment• No Chemical Safety Assessment has been carried out.

15.3 Other Information• WARNING: This product contains a chemical known to the State of California tocause birth defects or other reproductive harm.

Section 16 - Other Information
Relevant Phrases (code & full text)• H302 - Harmful if swallowed
H312 - Harmful in contact with skinH412 - Harmful to aquatic life with long lasting effects
Revision Date
• 19/December/2016
Preparation Date
Disclaimer/Statement of
Liability

Preparation Date: 21/February/2014
Revision Date: 19/December/2016• 21/February/2014• Caution! Do not use SPI Supplies products or materials in applications involving
implantation within the body; direct or indirect contact with the blood pathway; contact
with bone, tissue, tissue fluid, or blood; or prolonged contact with mucous
membranes. Products offered by SPI Supplies are not designed or manufactured foruse in implantation in the human body or in contact with internal body fluids ortissues. SPI Supplies will not provide to customers making devices for suchapplications any notice, certification, or information necessary for such medical device
use required by US FDA (Food and Drug Administration) regulation or any otherstatute. SPI Supplies and Structure Probe, Inc. make no representation, promise,express warranty or implied warranty concerning the suitability of these materials foruse in implantation in the human body or in contact with internal body tissues of
fluids. The information and recommendations set forth above are taken from sources
believed to be accurate as of the date hereof, however SPI Supplies and Structure
Probe, Inc. make no warranty with respect to the accuracy of the information or thesuitability of the recommendations, and assume no liability to any user thereof. The
information contained in this sheet does not constitute a hazard assessment andshould not be used in place of the user's own assessment of work place risks asrequired by other health and safety legislation. Be aware of the Structure Probe, Inc.
Copyright Policy. Structure Probe, Inc. grants a nonexclusive license to makeunlimited copies of this safety sheet for internal use only. Quite obviously, thisPage 12 of 13

Format: EU CLP/REACH Language: English (US)EU CLP, OSHA HCS 2012

Silver Paste Plus

information would pertain only to this material when purchased from SPI Supplies as
product from other sources, with other ingredients and impurity levels could havesubstantially different properties.
Key to abbreviations
NDA = No Data Available

Preparation Date: 21/February/2014
Revision Date: 19/December/2016

Page 13 of 13

Format: EU CLP/REACH Language: English (US)EU CLP, OSHA HCS 2012