Vacseal® Vacuum Leak Sealant With Brush, Original Formula Clear

Safety Data Sheet
Section 1: Identification of the Substance/Mixture and of the Company/Undertaking
1.1 Product identifier
Product Name
Synonyms
Product Code•

Vacseal® Vacuum Leak Sealant With Brush, Original Formula
Clear• Vacseal® Vacuum Leak Sealant, Original• 05049-AB; 05052-AB; 05053-AB; 05053GAL-AB

1.2 Relevant identified uses of the substance or mixture and uses advised against
Relevant identified use(s)• Temporary repairs for leaks in high vacuum and ultrahigh vacuum equipment to allow
continued operation until “permanent” repairs can be scheduled.

1.3 Details of the supplier of the safety data sheet
Manufacturer• SPI Supplies Division Structure Probe, Inc.
206 Garfield Ave.
West Chester, PA 19380
United States
http://www.2spi.com
SDS@2spi.com
Telephone (General) • 1-(610)-436-5400

1.4 Emergency telephone number
Manufacturer
Manufacturer• 1-(800)-424-9300 - Chemtrec• 1-(703)-741-5970 - Worldwide

Section 2: Hazards Identification
EU/EEC
According to: Regulation (EC) No 1272/2008 (CLP)/REACH 1907/2006 [amended by 2015/830]

2.1 Classification of the substance or mixture
CLP• Flammable Liquids 2 - H225
Aspiration 1 - H304
Skin Irritation 2 - H315
Eye Irritation 2 - H319
Specific Target Organ Toxicity Single Exposure 3: Narcotic Effects - H336
Germ Cell Mutagenicity 2 - H341
Carcinogenicity 1B - H350
Specific Target Organ Toxicity Repeated Exposure 2 - H373
Hazardous to the aquatic environment Chronic 3 - H412

2.2 Label Elements
CLP

DANGER

Preparation Date: 10/October/2014
Revision Date: 20/December/2016

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Vacseal® Vacuum Leak Sealant With Brush, Original Formula Clear

Hazard statements • H225 - Highly flammable liquid and vapour

H304 - May be fatal if swallowed and enters airways
H315 - Causes skin irritation
H319 - Causes serious eye irritation
H336 - May cause drowsiness or dizziness
H341 - Suspected of causing genetic defects.
H350 - May cause cancer.
H373 - May cause damage to organs through prolonged or repeated exposure.
H412 - Harmful to aquatic life with long lasting effects

Precautionary statements
Prevention • P201 - Obtain special instructions before use.
P202 - Do not handle until all safety precautions have been read and understood.
P233 - Keep container tightly closed.
P235 - Keep cool.
P240 - Ground and/or bond container and receiving equipment.
P241 - Use explosion-proof electrical/ventilating/lighting/equipment.
P242 - Use only non-sparking tools.
P243 - Take precautionary measures against static discharge.
P260 - Do not breathe mist, vapours and/or spray.
P264 - Wash thoroughly after handling.
P271 - Use only outdoors or in a well-ventilated area.
P273 - Avoid release to the environment.
P280 - Wear protective gloves/protective clothing/eye protection/face protection.
P281 - Use personal protective equipment as required.
Response • P370+P378 - In case of fire: Use appropriate media for extinction.
P304+P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position
comfortable for breathing.
P312 - Call a POISON CENTER or doctor/physician if you feel unwell.
P303+P361+P353 - IF ON SKIN (or hair): Take off immediately all contaminatedclothing. Rinse skin with water/shower.
P321 - Specific treatment, see supplemental first aid information.
P362 - Take off contaminated clothing and wash before reuse.
P332+P313 - If skin irritation occurs: Get medical advice/attention.
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P337+P313 - If eye irritation persists: Get medical advice/attention.
P301+P310 - IF SWALLOWED: Immediately call a POISON CENTER or
doctor/physician.
P310 - Immediately call a POISON CENTER or doctor/physician.
P331 - Do NOT induce vomiting.
P308+P313 - IF exposed or concerned: Get medical advice/attention.
P314 - Get medical advice/attention if you feel unwell.
Storage/Disposal • P403+P233 - Store in a well-ventilated place. Keep container tightly closed.
P235 - Keep cool.
P405 - Store locked up.
P501 - Dispose of content and/or container in accordance with local, regional,
national, and/or international regulations.

2.3 Other Hazards
CLP• According to Regulation (EC) No. 1272/2008 (CLP) this material is consideredhazardous.

United States (US)

According to: OSHA 29 CFR 1910.1200 HCS

2.1 Classification of the substance or mixture
Preparation Date: 10/October/2014
Revision Date: 20/December/2016

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Vacseal® Vacuum Leak Sealant With Brush, Original Formula Clear

OSHA HCS 2012

• Flammable Liquids 2Aspiration 1
Skin Irritation 2
Eye Irritation 2
Specific Target Organ Toxicity Single Exposure 3: Respiratory Tract Irritation
Specific Target Organ Toxicity Single Exposure 3: Narcotic Effects
Germ Cell Mutagenicity 2
Carcinogenicity 1A
Reproductive Toxicity 1B
Specific Target Organ Toxicity Repeated Exposure 2

2.2 Label elements
OSHA HCS 2012

DANGER

Hazard statements • Highly flammable liquid and vapour

May be fatal if swallowed and enters airways
Causes skin irritation
Causes serious eye irritation
May cause respiratory irritation
May cause drowsiness or dizziness
Suspected of causing genetic defects.
May cause cancer.
May damage fertility or the unborn child.
May cause damage to organs through prolonged or repeated exposure.

Precautionary statements
Prevention • Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Keep away from heat, sparks, open flames and/or hot surfaces. - No smoking.
Keep container tightly closed.
Keep cool.
Ground and/or bond container and receiving equipment.
Use explosion-proof electrical/ventilating/lighting/equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Do not breathe mist, vapours and/or spray.
Wash thoroughly after handling.
Use only outdoors or in a well-ventilated area.
Wear protective gloves/protective clothing/eye protection/face protection.
Response • In case of fire: Use to extinguish.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
Call a POISON CENTER/doctor if you feel unwell.
If on skin: Wash with plenty of water .
Specific treatment, see supplemental first aid information.
Take off contaminated clothing and wash before reuse.
If skin irritation occurs: Get medical advice/attention.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses,
if present and easy to do. Continue rinsing.
If eye irritation persists: Get medical advice/attention.
IF SWALLOWED: Immediately call a POISON CENTER/doctor .
Immediately call a POISON CENTER or doctor/physician.
Do NOT induce vomiting.
IF exposed or concerned: Get medical advice/attention.
Get medical advice/attention if you feel unwell.
Storage/Disposal • Store in a well-ventilated place. Keep container tightly closed.
Keep cool.
Store locked up.
Dispose of content and/or container in accordance with local, regional, national, and/or
Preparation Date: 10/October/2014
Revision Date: 20/December/2016

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international regulations.

2.3 Other hazards
OSHA HCS 2012

• Under United States Regulations (29 CFR 1910.1200 - Hazard Communication
Standard), this product is considered hazardous.

Section 3 - Composition/Information on Ingredients
3.1 Substances• Material does not meet the criteria of a substance.

3.2 Mixtures
Composition
ChemicalName

Identifiers%

Ethylene,trichloro-

CAS:79-01-6
EC
Number:201167-4
EU Index:602027-00-9

30%
TO
60%

XyleneCAS:1330-20-7
EC
Number:215535-7
EU Index:601022-00-9

15%
TO
30%

Silicone
Polymers

Proprietary

15%
TO
25%

Ethylbenzene

CAS:100-41-4
EC
Number:202849-4
EU Index:601023-00-4

5%
TO
15%

LD50/LC50

Classifications According to Regulation/Directive

Comments

EU CLP: Annex VI, Table 3.1: Carc. 1B, H350; Muta. 2,
H341; Eye Irrit. 2, H319; Skin Irrit. 2, H315; STOT SE 3:
Narc., H336; Aquatic Chronic 3, H412
OSHA HCS 2012: Flam. Liq. 4; Carc. 1A; Muta. 2; Eye
Irrit. 2; Skin Irrit. 2; STOT SE 3: Narc.; Repr. 2; Asp. Tox.
1

NDA

EU CLP: Annex VI, Table 3.1: Flam. Liq. 3, H226; AcuteTox. 4, H312; Acute Tox. 4, H332; Skin Irrit. 2, H315
OSHA HCS 2012: Flam. Liq. 3; Acute Tox. 4 (Inhl); Skin
Irrit. 2; Eye Irrit. 2; Repr. 1B (Inhl); STOT SE 3: Narc.;
STOT SE 3: Resp. Irrit.

NDA

NDA

EU CLP: Not Classified
OSHA HCS 2012: Not Classified

NDA

Ingestion/Oral-Rat
LD50 • 3500 mg/kg
Skin-Rabbit LD50 •17800 µL/kg

EU CLP: Annex VI, Table 3.1: Flam. Liq. 2, H225; AcuteTox. 4, H332; STOT RE 2, H373 (Ears, Inhl); Asp. Tox. 1,
H304
OSHA HCS 2012: Flam. Liq. 2; Acute Tox. 4 (Inhl); Eye
Irrit. 2; Carc. 2 (Inhl); Repr. 2 (Inhl); STOT SE 3: Narc.;
STOT SE 3: Resp. Irrit. (Inhl); STOT RE 2 (Ear, Inhl); Asp.
Tox. 1

NDA

Skin-Rabbit LD50 •>20 g/kg
Inhalation-Rat LC50 •140700 mg/m³ 1
Hour(s)Ingestion/Oral-Rat
LD50 • 4920 mg/kg
Ingestion/Oral-Rat
LD50 • 4300 mg/kg
Inhalation-Rat LC50 •5000 ppm 4 Hour(s)Skin-Rabbit LD50 •>1700 mg/kg

See Section 16 for full text of H-statements.

Section 4 - First Aid Measures
4.1 Description of first aid measures
Inhalation

Skin
Preparation Date: 10/October/2014
Revision Date: 20/December/2016• Move victim to fresh air. Administer oxygen if breathing is difficult. Give artificial
respiration if victim is not breathing. Do not use mouth-to-mouth method if victim
inhaled the substance; give artificial respiration with the aid of a pocket mask
equipped with a one-way valve or other proper respiratory medical device. Get medical
attention immediately.
• Wash skin with soap and water. Remove and isolate contaminated clothing. If irritation
develops and persists, get medical attention.
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Eye
Ingestion• In case of contact with substance, immediately flush eyes with running water for atleast 20 minutes. If eye irritation persists: Get medical advice/attention.
• Do NOT induce vomiting. Never give anything by mouth to an unconscious person.
Obtain medical attention immediately if ingested.

4.2 Most important symptoms and effects, both acute and delayed• Refer to Section 11 - Toxicological Information.

4.3 Indication of any immediate medical attention and special treatment needed
Notes to Physician• All treatments should be based on observed signs and symptoms of distress in thepatient. Consideration should be given to the possibility that overexposure to materials
other than this product may have occurred.

Section 5 - Firefighting Measures
5.1 Extinguishing media
Suitable Extinguishing Media • Dry Chemical, CO2, water foam, "alcohol" foam, water spray to cool fire-exposedcontainers and disperse vapor.
Unsuitable Extinguishing• Do not use a direct stream of water.
Media

5.2 Special hazards arising from the substance or mixture
Unusual Fire and Explosion
Hazards

Hazardous Combustion
Products• HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.
Containers may explode when heated.
Many liquids are lighter than water.
Vapors may form explosive mixtures with air.
Most vapors are heavier than air. They will spread along ground and collect in low or
confined areas (sewers, basements, tanks).
Vapors may travel to source of ignition and flash back.
Vapor explosion hazard indoors, outdoors or in sewers.
Runoff to sewer may create fire or explosion hazard.
• No data available

5.3 Advice for firefighters• Structural firefighters' protective clothing will only provide limited protection.
Wear positive pressure self-contained breathing apparatus (SCBA).
Move containers from fire area if you can do it without risk.
LARGE FIRES: Cool containers with flooding quantities of water until well after fire isout.

Section 6 - Accidental Release Measures
6.1 Personal precautions, protective equipment and emergency procedures
Personal Precautions
Emergency Procedures• CAUTION: Victim may be a source of contamination. Do not walk through spilledmaterial. Use appropriate Personal Protective Equipment (PPE)• As an immediate precautionary measure, isolate spill or leak area for at least 50
meters (150 feet) in all directions. LARGE SPILL: Consider initial downwind evacuation
for at least 300 meters (1000 feet) ELIMINATE all ignition sources (no smoking, flares,
sparks or flames in immediate area). Keep unauthorized personnel away. Stay
upwind. Keep out of low areas. Ventilate closed spaces before entering.

6.2 Environmental precautions• Prevent entry into waterways, sewers, basements or confined areas.

6.3 Methods and material for containment and cleaning up
Containment/Clean-up
MeasuresPreparation Date: 10/October/2014
Revision Date: 20/December/2016• Stop leak if you can do it without risk.
Absorb or cover with dry earth, sand or other non-combustible material and transfer toPage 5 of 14

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containers.
Use clean non-sparking tools to collect absorbed material.
A vapor suppressing foam may be used to reduce vapors.
All equipment used when handling the product must be grounded.
LARGE SPILLS: Dike far ahead of liquid spill for later disposal.
LARGE SPILLS: Water spray may reduce vapor; but may not prevent ignition inclosed spaces.

6.4 Reference to other sections• Refer to Section 8 - Exposure Controls/Personal Protection and Section 13 - Disposal
Considerations.

Section 7 - Handling and Storage
7.1 Precautions for safe handling
Handling• Use only in well ventilated areas. Keep away from heat, sparks, and flame. Do not use
sparking tools. Take precautionary measures against static charges. All equipmentused when handling the product must be grounded. Wear appropriate personal
protective equipment, avoid direct contact. Do not breathe mist, vapours and/or spray.
Avoid contact with skin, eyes, and clothing. Wash thoroughly with soap and water
after handling and before eating, drinking, or using tobacco.

7.2 Conditions for safe storage, including any incompatibilities
Storage• Store in a tightly closed container. Store in a cool, dry, well-ventilated place. Keepaway from heat, sparks, and flame.

7.3 Specific end use(s)• This item is not being offered for clinical or diagnostic applications, agricultural uses orfor human or animal consumption. Refer to Section 1.2 - Relevant identified uses.

Section 8 - Exposure Controls/Personal Protection
8.1 Control parameters
Exposure Limits/Guidelines
Result

ACGIH

NIOSH

OSHA

Ethylbenzene(100-41-4)

TWAs

20 ppm TWA

100 ppm TWA; 435 mg/m3 TWA

100 ppm TWA; 435 mg/m3 TWA

STELs

Not established

125 ppm STEL; 545 mg/m3 STEL

Not established

Xylene(1330-20-7)

TWAs

100 ppm TWA

Not established

100 ppm TWA; 435 mg/m3 TWA

STELs

150 ppm STEL

Not establishedNot establishedCeilings Not establishedNot established

200 ppm Ceiling

TWAs

10 ppm TWA

Not established

100 ppm TWA

STELs

25 ppm STEL

Not establishedNot established

Ethylene, trichloro(79-01-6)

8.2 Exposure controls
Engineering
Measures/Controls• Good general ventilation should be used. Ventilation rates should be matched toconditions. If applicable, use process enclosures, local exhaust ventilation, or otherengineering controls to maintain airborne levels below recommended exposure limits.
If exposure limits have not been established, maintain airborne levels to an acceptablelevel. Use explosion-proof electrical/ventilating/lighting/equipment.
Personal Protective Equipment
Respiratory• Follow the OSHA respirator regulations found in 29 CFR 1910.134. Use a
NIOSH/MSHA approved respirator if exposure limits are exceeded or symptoms areexperienced.
Eye/Face• Wear chemical splash safety goggles.
Preparation Date: 10/October/2014
Revision Date: 20/December/2016

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Skin/Body
Environmental Exposure
Controls
Additional Protection
Measures• Wear appropriate gloves. Wear long sleeves and/or protective coveralls.
• Controls should be engineered to prevent release to the environment, including
procedures to prevent spills, atmospheric release and release to waterways. Follow
best practice for site management and disposal of waste.
• An eyewash station and emergency shower must be available to the work station.

Key to abbreviations
ACGIH = American Conference of Governmental Industrial Hygiene
NIOSH = National Institute of Occupational Safety and Health
OSHA = Occupational Safety and Health Administration

STEL = Short Term Exposure Limits are based on 15-minute exposures
TWA = Time-Weighted Averages are based on 8h/day, 40h/week exposures

Section 9 - Physical and Chemical Properties
9.1 Information on Basic Physical and Chemical Properties
Material Description
Physical Form

LiquidAppearance/Description

Colorless to pale yellow liquid withsolvent odor.

Color

Colorless to pale yellow.

Odor

Solvent odor.

Odor Threshold

Data lacking

General Properties
Boiling Point> 100 °C(> 212 °F)

Melting Point/Freezing Point

Data lacking

Decomposition Temperature

Data lacking

pH

Data lacking

Specific Gravity/Relative Density= 1.01 @ 25 °C(77 °F) Water=1(Trichloroethylene)

Water Solubility

Data lacking

Viscosity

105 Centistoke (cSt, cS) or
mm2/sec

Explosive Properties

Data lacking

Oxidizing Properties:

Data lacking
Vapor Density

Data lacking

Volatility
Vapor Pressure

Data lacking

Evaporation Rate

Data lacking

Flammability
Flash Point

62 °F(16.6667 °C) PMCC (PenskyMartins Closed Cup)

UEL

Data lacking

LEL

Data lacking

Autoignition

Data lacking

Flammability (solid, gas)

Data lacking

Environmental
Octanol/Water Partition coefficient

Data lacking

9.2 Other Information• No additional physical and chemical parameters noted.

Section 10: Stability and Reactivity
10.1 Reactivity• No dangerous reaction known under conditions of normal use.

10.2 Chemical stability• Stable under normal temperatures and pressures.

10.3 Possibility of hazardous reactions
Preparation Date: 10/October/2014
Revision Date: 20/December/2016

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Vacseal® Vacuum Leak Sealant With Brush, Original Formula Clear• Hazardous polymerization will not occur.

10.4 Conditions to avoid• Keep away from heat, sparks and flame.

10.5 Incompatible materials• Oxidizing material can cause a reaction.

10.6 Hazardous decomposition products• Carbon oxides and traces of incompletely burned carbon compounds.

Section 11 - Toxicological Information
11.1 Information on toxicological effects
Components

Ethylene,trichloro- (30%
TO 60%)

Acute Toxicity: Ingestion/Oral-Rat LD50 • 4920 mg/kg; Inhalation-Rat LC50 • 140700 mg/m³ 1 Hour(s); Skin-Rabbit LD50 •>20 g/kg;
Irritation: Eye-Rabbit • 20 mg 24 Hour(s) • Moderate irritation; Skin-Rabbit • 2 mg 24 Hour(s) • Severe irritation;
Multi-dose Toxicity: Ingestion/Oral-Mouse TDLo • 22.4 mg/kg 32 Week(s)-Continuous; Liver:Hepatitis (hepatocellularnecrosis), diffuse; Skin and Appendages:After systemic exposure:Dermatitis, other; Immunological Including
Allergic:Autoimmune; Inhalation-Mouse TCLo • 500 ppm 4 Week(s)-Intermittent; Liver:Hepatitis (hepatocellularnecrosis), zonal; Endocrine:Other changes; Immunological Including Allergic:Decrease in humoral immune
response; Inhalation-Rat TCLo • 500 ppm 182 Day(s)-Intermittent; Kidney, Ureter, and Bladder:Interstitial nephritis;
79Kidney, Ureter, and Bladder:Renal function tests depressed;
01-6
Mutagen: Sperm Morphology • Inhalation-Mouse • 100 ppm;
Reproductive: Ingestion/Oral-Rat TDLo • 1140 mg/kg (14D pre-21D post); Reproductive Effects:Specific Developmental
Abnormalities:Central nervous system; Ingestion/Oral-Rat TDLo • 76 mg/kg (multigenerations); Reproductive
Effects:Specific Developmental Abnormalities:Hepatobiliary system; Reproductive Effects:Specific Developmental
Abnormalities:Urogenital system; Reproductive Effects:Effects on Newborn:Growth statistics (e.g., reduced
weight gain);
Tumorigen / Carcinogen: Inhalation-Rat TCLo • 150 ppm 7 Hour(s) 2 Year(s)-Intermittent; Tumorigenic:Carcinogenic
by RTECS criteria; Lungs, Thorax, or Respiration:Tumors; Skin and Appendages:Other:Tumors

Xylene (15%TO 30%)

Acute Toxicity: Ingestion/Oral-Rat LD50 • 4300 mg/kg; Liver:Other changes; Kidney, Ureter, and Bladder:Otherchanges; Inhalation-Rat LC50 • 5000 ppm 4 Hour(s); Inhalation-Man LCLo • 10000 ppm 6 Hour(s); Behavioral:Generalanesthetic; Lungs, Thorax, or Respiration:Cyanosis; Blood:Other changes; Inhalation-Human TCLo • 200 ppm; Sense
Organs and Special Senses:Olfaction:Other changes; Sense Organs and Special Senses:Eye:Conjunctive
irritation; Lungs, Thorax, or Respiration:Other changes; Skin-Rabbit LD50 • >1700 mg/kg;
1330
Irritation: Eye-Rabbit • 5 mg 24 Hour(s) • Severe irritation; Skin-Rabbit • 500 mg 24 Hour(s) • Moderate irritation;-20Reproductive: Inhalation-Rabbit TCLo • 1 g/m³ 24 Hour(s)(7-20D preg); Reproductive Effects:Effects on
7
Fertility:Abortion; Inhalation-Rat TCLo • 50 mg/m³ 6 Hour(s)(1-21D preg); Reproductive Effects:Effects on Fertility:Postimplantation mortality; Reproductive Effects:Effects on Embryo or Fetus:Fetotoxicity (except death, e.g., stunted
fetus); Reproductive Effects:Specific Developmental Abnormalities:Craniofacial (including nose andtongue); Inhalation-Rat TDLo • 200 ppm 6 Hour(s)(4-20D preg); Reproductive Effects:Specific Developmental
Abnormalities:Musculoskeletal system; Reproductive Effects:Effects on Newborn:Behavioral

Ethylbenzene(5% TO 15%)

Acute Toxicity: Ingestion/Oral-Rat LD50 • 3500 mg/kg; Inhalation-Guinea Pig LCLo • 2500 ppm 8 Hour(s);Behavioral:Coma; Inhalation-Human TCLo • 21700 mg/m³; Behavioral:Antipsychotic; Inhalation-Mouse TCLo • 600 ppm 6
Minute(s); Lungs, Thorax, or Respiration:Respiratory depression; Skin-Rabbit LD50 • 17800 µL/kg;
Irritation: Eye-Rabbit • 500 mg • Severe irritation; Skin-Rabbit • 15 mg 24 Hour(s)-Open • Mild irritation;
Multi-dose Toxicity: Inhalation-Rat TCLo • 550 ppm 8 Hour(s) 5 Day(s)-Intermittent; Sense Organs and Special
Senses:Ear:Change in acuity; Sense Organs and Special Senses:Ear:Changes in cochlear structure or function;
Mutagen: Specific locus test • Intraperitoneal-Mouse • 754 µmol/L; Micronucleus test • Unreported Route-Hamster •Embryo (Somatic cell) • 25 mg/L; Sister chromatid exchange • Unreported Route-Human • Lymphocyte (Somatic cell) • 10
mmol/L; Mutation in Mammalian Somatic Cells • Unreported Route-Mouse • Lymphocyte (Somatic cell) • 80 mg/L;
Reproductive: Inhalation-Rabbit TCLo • 1 g/m³ 24 Hour(s)(7-20D preg); Reproductive Effects:Effects on
100- Fertility:Abortion; Inhalation-Rat TCLo • 96 ppm 7 Hour(s)(1-19D preg); Reproductive Effects:Specific Developmental
41-4 Abnormalities:Musculoskeletal system; Inhalation-Rat TCLo • 1000 ppm (6-20D preg); Reproductive Effects:Effects
on Embryo or Fetus:Fetotoxicity (except death, e.g., stunted fetus); Inhalation-Rat TCLo • 600 mg/m³ 24 Hour(s)(715D preg); Reproductive Effects:Effects on Fertility:Post-implantation mortality; Reproductive Effects:Effects on

Preparation Date: 10/October/2014
Revision Date: 20/December/2016

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Embryo or Fetus:Fetal death; Reproductive Effects:Specific Developmental Abnormalities:Musculoskeletal
system;Tumorigen / Carcinogen: Inhalation-Mouse TCLo • 750 ppm 6 Hour(s) 2 Year(s)-Intermittent;
Tumorigenic:Carcinogenic by RTECS criteria; Lungs, Thorax, or Respiration:Bronchiogenic carcinoma;
Liver:Tumors; Inhalation-Rat TCLo • 750 ppm 6 Hour(s) 2 Year(s)-Intermittent; Tumorigenic:Carcinogenic by RTECS
criteria; Kidney, Ureter, and Bladder:Tumors; Inhalation-Rat TCLo • 23400 mg/kg 104 Week(s)-Intermittent;
Tumorigenic:Equivocal tumorigenic agent by RTECS criteria; Kidney, Ureter, and Bladder:Kidney tumors;
Reproductive Effects:Tumorigenic Effects:Testicular tumors

GHS Properties

Classification

Acute toxicity

EU/CLP • Data lacking
OSHA HCS 2012 • Data lacking

Skin corrosion/Irritation

EU/CLP • Skin Irritation 2
OSHA HCS 2012 • Skin Irritation 2

Serious eye damage/Irritation

EU/CLP • Eye Irritation 2
OSHA HCS 2012 • Eye Irritation 2

Skin sensitization

EU/CLP • Data lacking
OSHA HCS 2012 • Data lacking

Respiratory sensitization

EU/CLP • Data lacking
OSHA HCS 2012 • Data lacking

Aspiration Hazard

EU/CLP • Aspiration 1
OSHA HCS 2012 • Aspiration 1

Carcinogenicity

EU/CLP • Carcinogenicity 1B; May cause cancer
OSHA HCS 2012 • Carcinogenicity 1A

Germ Cell Mutagenicity

EU/CLP • Germ Cell Mutagenicity 2
OSHA HCS 2012 • Germ Cell Mutagenicity 2

Toxicity for Reproduction

EU/CLP • Data lacking
OSHA HCS 2012 • Toxic to Reproduction 1B

STOT-SE

EU/CLP • Specific Target Organ Toxicity Single Exposure 3: Narcotic Effects
OSHA HCS 2012 • Specific Target Organ Toxicity Single Exposure 3: Narcotic Effects;
Specific Target Organ Toxicity Single Exposure 3: Respiratory Tract Irritation

STOT-RE

EU/CLP • Specific Target Organ Toxicity Repeated Exposure 2
OSHA HCS 2012 • Specific Target Organ Toxicity Repeated Exposure 2

Potential Health Effects
Inhalation
Acute (Immediate)
Chronic (Delayed)• May cause respiratory irritation. May affect the central nervous system. Symptoms
may include dizziness, drowsiness, lethargy, coma and death.
• Exposure to relatively low concentrations of ethylbenzene for several days to weeks
resulted in potentially irreversible damage to the inner ear and hearing of animals.

Skin
Acute (Immediate)
Chronic (Delayed)• Causes skin irritation.
• Repeated exposure may cause skin dryness or cracking.

EyeAcute (Immediate)
Chronic (Delayed)• Causes serious eye irritation.
• No data available

Ingestion
Acute (Immediate)
Preparation Date: 10/October/2014
Revision Date: 20/December/2016• Material may be aspirated into lungs during ingestion and/or subsequent vomiting.
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Mutagenic Effects

Aspiration of this material will cause severe lung injury, chemical pneumonitis,
pulmonary edema or death.
• No data available• Repeated and prolonged exposure may cause mutagenic effects.

Carcinogenic Effects• Repeated and prolonged exposure may cause cancer.

Chronic (Delayed)

Carcinogenic Effects
CAS

IARC

NTP

Ethylene, trichloro-

79-01-6

Group 1-Carcinogenic

Reasonably Anticipated to be Human Carcinogen

Ethylbenzene

100-41-4

Group 2B-Possible Carcinogen

Not Listed

Reproductive Effects• Repeated and prolonged exposure may cause reproductive effects.

Key to abbreviations
LC = Lethal Concentration
LD = Lethal Dose
TC = Toxic Concentration
TD = Toxic Dose

Section 12 - Ecological Information
12.1 Toxicity
CAS
Vacseal® Vacuum Leak Sealant With
Brush, Original Formula Clear

NDA

Aquatic Toxicity-Fish: 4 Day(s) LC50 16 mg/L Comments: Ethylene, trichloro- (79-016)
14 Day(s) NOEC 3.1 mg/L Comments: Ethylene, trichloro- (79-01-6)
Aquatic Toxicity-Algae and Other Aquatic Plant(s): 3 Day(s) EC50 Green Algae
35.1-38.2 mg/L Comments: Ethylene, trichloro- (79-01-6)• Harmful to aquatic life with long lasting effects.

12.2 Persistence and degradability• Material data lacking.

12.3 Bioaccumulative potential• Material data lacking.

12.4 Mobility in Soil
• Material data lacking.

12.5 Results of PBT and vPvB assessment• No PBT and vPvB assessment has been conducted.

12.6 Other adverse effects• No studies have been found.

Section 13 - Disposal Considerations
13.1 Waste treatment methods
Product waste
Packaging waste

Preparation Date: 10/October/2014
Revision Date: 20/December/2016• Dispose of content and/or container in accordance with local, regional, national, and/orinternational regulations.
• Dispose of content and/or container in accordance with local, regional, national, and/orinternational regulations.

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Vacseal® Vacuum Leak Sealant With Brush, Original Formula Clear

Section 14 - Transport Information
14.1 UN
number

14.2 UN proper
shipping name14.3 Transport hazard
class(es)14.4 Packing
group

14.5 Environmental
hazards

DOT

UN1866

Resin Solution, flammable

3

II

NDA

IMO/IMDG

UN1866

Resin Solution, flammable

3

II

NDA

IATA/ICAO

UN1866

Resin Solution, flammable

3

II

NDA

14.6 Special precautions foruser
14.7 Transport in bulk
according to Annex II of
Marpol and the IBC Code• None specified.
• Data lacking.

Section 15 - Regulatory Information
15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixtureSARA Hazard Classifications • Acute, Chronic, Fire
Inventory
Component

CAS

Canada DSL

Canada NDSLEU EINECS

EU ELNICS

TSCA

Ethylbenzene

100-41-4

Yes

No

Yes

No

Yes

Ethylene, trichloro-

79-01-6

Yes

No

Yes

No

Yes

Xylene1330-20-7

Yes

No

Yes

No

Yes

CanadaLabor
Canada - WHMIS 1988 - Classifications of Substances• Ethylbenzene• Xylene• Ethylene, trichloro-

100-41-4
1330-20-7
79-01-6

B2, D2A, D2B
B2, D2A, D2B
D1B, D2A, D2B

Canada - WHMIS 1988 - Ingredient Disclosure List
• Ethylbenzene• Xylene• Ethylene, trichloro-

100-41-4
1330-20-7
79-01-6

0.1 %Not Listed
1%

Canada - CEPA - Priority Substances List
• Ethylbenzene

100-41-4• Xylene

1330-20-7• Ethylene, trichloro-

79-01-6

Not Listed
Priority Substance List 1(substance not considered
toxic)
Priority Substance List 1(substance considered toxic)

Environment

United States
Labor
U.S. - OSHA - Process Safety Management - Highly Hazardous Chemicals• Ethylbenzene
Preparation Date: 10/October/2014
Revision Date: 20/December/2016

Page 11 of 14

100-41-4

Not Listed

Format: EU CLP/REACH Language: English (US)EU CLP, OSHA HCS 2012

Vacseal® Vacuum Leak Sealant With Brush, Original Formula Clear• Xylene• Ethylene, trichloro-

1330-20-7
79-01-6

Not Listed
Not Listed

U.S. - OSHA - Specifically Regulated Chemicals• Ethylbenzene• Xylene• Ethylene, trichloro-

100-41-4
1330-20-7
79-01-6

Not Listed
Not Listed
Not Listed

100-41-4
1330-20-7
79-01-6(listed under Ethyl benzene)(isomers and mixtures)

Environment

U.S. - CAA (Clean Air Act) - 1990 Hazardous Air Pollutants• Ethylbenzene• Xylene• Ethylene, trichloroU.S. - CERCLA/SARA - Hazardous Substances and their Reportable Quantities

1000 lb final RQ; 454 kg final
RQ
100 lb final RQ; 45.4 kg final
RQ
100 lb final RQ; 45.4 kg final
RQ• Ethylbenzene

100-41-4• Xylene

1330-20-7• Ethylene, trichloro-

79-01-6

U.S. - CERCLA/SARA - Radionuclides and Their Reportable Quantities• Ethylbenzene• Xylene• Ethylene, trichloro-

100-41-4
1330-20-7
79-01-6

Not Listed
Not Listed
Not Listed

U.S. - CERCLA/SARA - Section 302 Extremely Hazardous Substances EPCRA RQs• Ethylbenzene• Xylene• Ethylene, trichloro-

100-41-4
1330-20-7
79-01-6

Not Listed
Not Listed
Not Listed

U.S. - CERCLA/SARA - Section 302 Extremely Hazardous Substances TPQs
• Ethylbenzene• Xylene• Ethylene, trichloro-

100-41-4
1330-20-7
79-01-6

Not Listed
Not Listed
Not Listed

U.S. - CERCLA/SARA - Section 313 - Emission Reporting
0.1 % de minimis
concentration
1.0 % de minimis
concentration
0.1 % de minimis
concentration• Ethylbenzene

100-41-4• Xylene

1330-20-7• Ethylene, trichloro-

79-01-6

U.S. - CERCLA/SARA - Section 313 - PBT Chemical Listing• Ethylbenzene• Xylene• Ethylene, trichloro-

100-41-4
1330-20-7
79-01-6

Not Listed
Not Listed
Not Listed

100-41-4
1330-20-7

carcinogen, 6/11/2004
Not Listed

United States - California
Environment
U.S. - California - Proposition 65 - Carcinogens List
• Ethylbenzene• Xylene
Preparation Date: 10/October/2014
Revision Date: 20/December/2016

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Vacseal® Vacuum Leak Sealant With Brush, Original Formula Clear• Ethylene, trichloro-

79-01-6

carcinogen, 4/1/1988

U.S. - California - Proposition 65 - Developmental Toxicity• Ethylbenzene• Xylene

100-41-4
1330-20-7• Ethylene, trichloro-

79-01-6

Not Listed
Not Listeddevelopmental toxicity,
1/31/2014

U.S. - California - Proposition 65 - Maximum Allowable Dose Levels (MADL)• Ethylbenzene• Xylene• Ethylene, trichloro-

100-41-4
1330-20-7
79-01-6

Not Listed
Not Listed
Not Listed

U.S. - California - Proposition 65 - No Significant Risk Levels (NSRL)
54 µg/day NSRL (inhalation);
41 µg/day NSRL (oral)
Not Listed
14 µg/day NSRL (oral); 50µg/day NSRL (inhalation)• Ethylbenzene

100-41-4• Xylene

1330-20-7• Ethylene, trichloro-

79-01-6

U.S. - California - Proposition 65 - Reproductive Toxicity - Female• Ethylbenzene• Xylene• Ethylene, trichloro-

100-41-4
1330-20-7
79-01-6

Not Listed
Not Listed
Not Listed

U.S. - California - Proposition 65 - Reproductive Toxicity - Male• Ethylbenzene• Xylene

100-41-4
1330-20-7• Ethylene, trichloro-

79-01-6

Not Listed
Not Listed
male reproductive toxicity,
1/31/1415.2 Chemical Safety Assessment• No Chemical Safety Assessment has been carried out.

15.3 Other Information• WARNING: This product contains a chemical known to the State of California tocause cancer, birth defects or other reproductive harm.

Section 16 - Other Information
Relevant Phrases (code & full text)• H226 - Flammable liquid and vapour
H312 - Harmful in contact with skin
H332 - Harmful if inhaled
Revision Date
• 20/December/2016
Preparation Date
Disclaimer/Statement of
Liability

Preparation Date: 10/October/2014
Revision Date: 20/December/2016• 10/October/2014• Caution! Do not use SPI Supplies products or materials in applications involving
implantation within the body; direct or indirect contact with the blood pathway; contact
with bone, tissue, tissue fluid, or blood; or prolonged contact with mucous
membranes. Products offered by SPI Supplies are not designed or manufactured foruse in implantation in the human body or in contact with internal body fluids ortissues. SPI Supplies will not provide to customers making devices for suchapplications any notice, certification, or information necessary for such medical device
use required by US FDA (Food and Drug Administration) regulation or any otherstatute. SPI Supplies and Structure Probe, Inc. make no representation, promise,

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Vacseal® Vacuum Leak Sealant With Brush, Original Formula Clear

express warranty or implied warranty concerning the suitability of these materials foruse in implantation in the human body or in contact with internal body tissues of
fluids. The information and recommendations set forth above are taken from sources
believed to be accurate as of the date hereof, however SPI Supplies and Structure
Probe, Inc. make no warranty with respect to the accuracy of the information or thesuitability of the recommendations, and assume no liability to any user thereof. The
information contained in this sheet does not constitute a hazard assessment andshould not be used in place of the user's own assessment of work place risks asrequired by other health and safety legislation. Be aware of the Structure Probe, Inc.
Copyright Policy. Structure Probe, Inc. grants a nonexclusive license to makeunlimited copies of this safety sheet for internal use only. Quite obviously, thisinformation would pertain only to this material when purchased from SPI Supplies as
product from other sources, with other ingredients and impurity levels could havesubstantially different properties.
Key to abbreviations
NDA = No Data Available

Preparation Date: 10/October/2014
Revision Date: 20/December/2016

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