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MATERIAL SAFETY DATA SHEET

Effective Date 2012/7/12

1. Identification* Product name

Color YUKAHIKARU Dark Brown* Reference number* Company* Company address* Section concerned* Person in change* Phone No.
* FAX No.
* Emergency contact* Product kind
* Principal use

23802
Washin Paint Co.,Ltd.
2100-18 Kamiyoshiba Satte-shi Saitama-ken 340-0121 Japan
Production engineering department
Takeyuki Kawashima
0480-48-2021
0480-48-2024
0480-48-2021
Resin Wax
Floor coating

2. Hazards identification[ Classification ]Hazards
Flammable liquids
Acute toxicity Oral
Acute toxicity Dermal
Acute toxicity Gasas
Acute toxicity Vapours
Acute toxicity Mists
Skin corrosion/irritation
Serious eye damage/eye irritation
Respiratory sensitization
Skin sensitization
Germ cell mutagenicity
Carcinogenicity
Reproductive toxicity
Specific target organ systemic toxicity
Single exposure
Specific target organ systemic toxicity
Repeated exposure

Aspiration hazard

Category
Hazard statement
Not classified

23802

Signal word

Not classified
Not classified
Not classification object
Not classified
Not classified
Not classified
Not classified
Not classified
Not classified
Category 1
May csuse genetic defects.
Not classified

DangerCategory 1
May damage fertility or the unborn child.
Not classified

DangerNot classified
Not classified

Hazardous to aquatic environment
Not classified
AcuteHazardous to aquatic environment
Not classified
Chronic* If the signal word "Danger" applies, the signal word "Worning" should not appear.
* For the details with "Specific target organ systemic toxicity", refer to "11.Toxicological information".

2/5 page[ Symbol ]Health hazard[ Precautionary statement ]( Prevention )* Obtain and understand special instructions before use.
* Don't eat, drink or smoke when using this product.
* Wear protective gloves and eye/face protection when it needs.
* Wash hands thoroughly and gargle after handling.

( Response )* In case of fire, use carbon dioxide/powder/foams for extinction.
* If in eyes: Rince cautiously with water, get medical advice/attention.
* If on skin or cloth: Wash with plenty of soap and water. Take off contaminated clothing and exchange it.
* If skin irritation occurs, seek medical advice/attention.
* If exposed or concerned: Get medical attention/advice.
( Strage )* Store container in the place which well-ventilated and cool.
( Disposal )* Don't dispose contents/container to the river and the sewage.
* Dispose contents/container in accordance with local/regional/national regulation.
3. Composition/information on ingradients
Property
MixtureProduct kind
Resin Wax
Chemical nameethanol−−−−

Weight
(%)
0〜1−
−−
−

CAS No.

Chemical structure

64-17-5−−−−

C2H5OH−−−−

Notice duty
○−
−
−
−

4. First-aid measures( When swallowing )* Without making vomit by force, be rested and have a medical attention.
* The vomit doesn't make swallow. Get medical attention.
( When inhaling )* Remove to fresh air and keep at rest in a position comfortable for breathing.
Seek medical advice/attention if you feel unwell.
( When adhering to the skin )* Wipes up quickly with cloth and washes it off sufficiently using plenty of water and soap.
Don't use organic solvent, thinner and so on.
* If you get damage or feel pain, seek medical advice/attention.
( When entering eyes )* Wash for more than 15 minutes with a plenty of water at once.
* Get a medical attention as fast as possible.
5. Fire-fighting measures( Suitable extinguishing media )* Water ( ○ ), Carbon dioxide ( ○ ), Foams ( ○ ), Powder ( ○ ), Dry sand ( ○ ), Other (( Specific hazards arising from the chemical )* This substance is not inflammable but the dry material is inflammable.
* When burning, there is possibility to make carbon monoxide occur.

),

23802

23802
3/5 page( Specific extinguishing method )* Tell Fire Service the place and the dangerous/hazardous property.
* Prevent outflow being in water pipe or watercourse.
* Wear respiratory-protective-equipment and protective-glove.
* Remove combustibles quickly from the surrounding area.
* Uses the suitable extinguishing media.
* Do fire fighting from the windward.
( Special protective equipmemt and precautions for fire-fighters )* Wear respiratory-protective-equipment, chemical-defense clothes/glove/boots,/glasses/mask as occasion demands.
6. Accidental release measures( Personal precautions, protective equipment and emargency prosedures )* Wear protective equipments ( gloves, protective mask, apron and goggles ).
( Environmental precautions )* Prevent outflow being in water pipe or watercourse.
* When water pipe or watercourse are polluted, contact organs concerned.
( Methods and materials for containment and cleaning up )* Collects outflow to the container which can be shut, and move it to the safe place.
* Prevent outflow using dry sand, earth or other imcombustible material, and make absorb residue to collect it.
* It may use water sprayer to absorb the diffusion of vapour.
* Dispose wastes based on the regurations concerned.
7. Handling and storage( Handring: Technical measure )* Handle this based on the related laws ( Industrial Safety and Health Law, Fire Defense Law, etc. ).
* Forrow the operation-standard, keep working atmosphere below TLV, promote ventilation.
* After handling, wash hands with soap water. It should wash work clothing separately.
( Handring: Notice )* Avoid contact with strong oxidizing reagent.
* It has a fear of causing a reaction by heating, acidic material and alkaline material.
* Use the container which has no damage, no corrosion and no breakage.
* Gather used containers to the decided safekeeping place.
( Storage )* Store container tightly closed in the place which well-ventilated and cool.
8. Exposure controls/personal protection
Standard control concentration, threshold limit value etc.
( Control parameters e.g. occupational exposure limit values or biological limit values )Standard control Tthreshold
ACGIH
Chemical name
PRTR
concentration
limit value( TWA )
ethanol−−
1000ppm−−−−−−−−−−
−
−
−
−
−
−
−
−
−
−
−
〔Equipment measure〕* Set up safe shower, bathroom and face washing near the work area, and display the position.
* Show the signs such like "NO UNAUTHORIZED ENTRY".
( Protection measure )* As occasion demands, wear following guards appropriately.
air-supplied respirator, air SCBA, oxygen SCBA, chemical-cartridge respirator,
protective glasses, protective gloves, protective boots, protective clothing,* Check protective equipments regularly by the check list.
* Don't eat, drink or smoke when using this product.
* Wash hands with soap before eat, drink or smoke.
* The person who showed the symptom of the asthma once should not contact this chemical
because he may cause the same symptom.
* Contact lens bring about special harm.
Don't use soft contact lens because it absorbs irritant and has possibility to concentrate them.
* Wear chemical-proof type protective gloves and antistatic protective shoes.

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9. Physical and chemical properties( Physical state: Liquid )Indicate in the product nameColourOdour
Slight resin odour
100 ℃ (ref.)Boiling point
Vapour pressure No data

1.02Density
7-9PHSolbilityNo data
Partiton coefficient n-octanol/water
No data23802

Flash point
Not
Ignition point
No data
Flammability or explosive limits
Lower
No dataUpper
No data

10. Stability and reactivity( Chemical stability )* The product seems to be stable.
* It has a possibility of the dangerous/harmful reaction.
* It reacts to the oxidizing materials.
* No other reactions were informed.
( Conditions to avoid )* Heating, Contact with the avoidance, Ignition source.
* Degradation product which has dangerous/hazardous property.
* Vapour of organic solvent.
* Heat, light, metal powder and peroxide.
11. Toxicological information
Chemical nameethanol−−−−
Chemical nameethanol−−−−
Chemical nameethanol−−−−
Chemical name

Acute toxicity
Oral
Not classified
Acute toxicity
Mists
Not classified-Dermal--Skin corrosion/
irritation
Not classified-

Serious eyedamage/eye irritation

Germ cellmutagenicity
Classification not possible Category 1B
Skin sensitization

Gasas

Classification not possible Not applicable

Category 2A-2B
Carcinogenicity
Not classified-

Specific target organ systemic toxicity
Single exposure
Repeated exposure
Category 3
Category 1, 2-VapoursNot classified
Respiratory
sensitizationClassification not possible

Reproductivetoxicity
Category 1A
Aspiration hazard

Classification not possible
ethanol−−−−* Specific target organ systemic toxicity: Category 1, 2: >= 1%, Category 3: >= 20%. ( JPMA: Self-standard )* Hazards information is peculiar to the chemicals. It doesn't change according to the content.

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12. Ecological information
Hazardous to aquatic environment
Acute
Chronic
ethanol
Not classified
Not classified−−−−* Hazards information is peculiar to the chemicals. It doesn't change according to the content.
Chemical name* Residual property/resolvability* Creature accumulation characteristics* Movement degree in the soil

There are not data as a mixture.
There are not data as a mixture.
There are not data as a mixture.

13. Disposal consideration* Requests disposal to the agency who has solid-waste-treatment license.
* When disposing container, dispose after removing a content fully.
* Dispose of contents/container in accordance with local/regional/national regulation.
14. Transport information( National regulation )* There is not special regulation.
( International regulation )Not* UN number* UN proper shipping name It doesn't correspond to the danger according to the UN recommendation.
( Special precautions )* In case of transportation, carry "transportation notice" or "Yellow Card".
* Confirm container tightly closed and no leaking before transportation.
* In case of transportation, fix a container tightly and use buffering one as occasion demands.
15. Regulatory information* Industrial Safety and Health Law
Dangerous goods
Ordinance on the Prevention of Organic Solvent Poisoning
Ordinance on Prevention of Lead Poisoning
Ordinance on Prevention of Hazards due to Specified Chemical Substances* Pollutant Release and Transfer Register Law* Poisonous and Deleterious Substances Control Law* Fire Defense Law* Ship Safety Law* Offensive Odor Control Low

Not applicableNot applicableNot applicableNot applicableNot listed
Not applicableNot applicableNot applicableNot listed

16. Other information( Main reference )* National Institute of Tecnology and Evaluation Opend data
* Japan Paint Manufacturers Association
Raw material data base
The guide book for the creating MSDS and label [ mixture ( paint ) ]Model MSDS and label samples [ mixture ( paint ) ]* Japan Industrial Safety and Health AssociationThe OJT text for the MSDS of mixture ( chemicals ) by GHS compatible* "YOZAI Pocket Book"* "KIKEN BOSAI KYUKYU BINRAN"* International Chemical Safety Cards ( ICSC )* MSDS of raw materials( Notice )* This information is based on our current knowledge and is intended to describe the productfor the purposes of health, safety and environmental requirements only.
* It should not therefore be construed as guaranteeing any specific property of the product.
* In case of use, set a safe conditions for handling.
* All chemicals have possibility of unknown hazards, so it needs a due attention for handling.
* Applicable scope of this document is only in Japan.

23802