略歴・研究業績
小室貴士

【略歴】
学歴
1999 年 3 月

名古屋大学理学部化学科 卒業

1999 年 4 月

名古屋大学大学院理学研究科物質理学専攻

2001 年 3 月
2001 年 4 月

同上同

上

入学

博士課程（後期課程）

入学修了

名古屋大学大学院理学研究科物質理学専攻

2004 年 3 月

博士課程（前期課程）修了

職歴2004 年 4 月 1 日～2004 年 8 月 31 日

日本学術振興会特別研究員（所属：分子科学研究所）

2004 年 9 月 1 日～2007 年 3 月 31 日

東北大学大学院理学研究科化学専攻

助手

2007 年 4 月 1 日～2021 年 3 月 31 日

東北大学大学院理学研究科化学専攻

助教

2021 年 4 月 1 日～現在

東北大学大学院理学研究科化学専攻

講師【研究業績】
原著論文（査読有） （著者名，題目，掲載誌名，巻，ページ，年）
1.

K. Sato, T. Komuro, H. Hashimoto, and H. Tobita, Bifunctional Rhodium Complex Featuring a Silyl–
1,8-naphthyridine Si,N-Chelate Ligand: Cooperation of Metal and Pendant Base for Capture andBond-weakening of BH3, Chem. Lett., 49, 1431–1434 (2020).

2.

T. Kitano, T. Komuro, K. Sato, and H. Tobita, Synthesis of ruthenium–bis(silyl) chelate complexes
without carbonyl ligands by reactions of a bis(allyl)ruthenium(II) complex withbis(hydrosilyl)xanthene and phosphines, J. Organomet. Chem., 919, 121316 (2020).

3.

T. Komuro, T. Osawa, R. Suzuki, D. Mochizuki, H. Higashi, and H. Tobita, Silyl–pyridine–amine
pincer-ligated iridium complexes for catalytic silane deuteration via room temperature C–D bondactivation of benzene-d6, Chem. Commun., 55, 957–960 (2019).

4.

T. Kitano, T. Komuro, and H. Tobita, Double and Single Hydroboration of Nitriles Catalyzed by a
Ruthenium–Bis(silyl)xanthene Complex: Application to One-Pot Synthesis of Diarylamines andN-Arylimines, Organometallics, 38, 1417–1420 (2019).

5.

小室 貴士, 飛田 博実, キサンテンで連結されたキレート型シリル配位子をもつ金属錯体の合成と特異な触媒作用, 有機合成化学協会誌, 76, 1301–1309 (2018).

6.

I. Kusuma, T. Komuro, and H. Tobita, Diruthenium Complexes with a 1,8-Naphthyridine-basedBis(silyl) Supporting Ligand: Synthesis and Structures of Complexes Containing RuII2(µ-H)2 andRuI2 Cores, Chem. Lett., 47, 400–403 (2018).

7.

T. Kitano, T. Komuro, R. Ono, and H. Tobita, Tandem Hydrosilylation/o-C–H Silylation ofArylalkynes Catalyzed by Ruthenium Bis(silyl) Aminophosphine Complexes, Organometallics, 36,2710–2713 (2017).
1

8.

T. Komuro, T. Kitano, N. Yamahira, K. Ohta, S. Okawara, N. Mager, M. Okazaki, and H. Tobita,
Directed ortho-C–H Silylation Coupled with trans-Selective Hydrogenation of Arylalkynes
Catalyzed by Ruthenium Complexes of a Xanthene-Based Si,O,Si-Chelate Ligand, “Xantsil”,Organometallics, 35, 1209–1217 (2016).

9.

T. Komuro, T. Arai, K. Kikuchi, and H. Tobita, Synthesis of Ruthenium Complexes with aNonspectator Si,O,P-Chelate Ligand: Interconversion between a Hydrido(η2-silane) Complex anda Silyl Complex Leading to Catalytic Alkene Hydrogenation, Organometallics, 34, 1211–1217(2015).

10. Y. Kanno, T. Komuro, and H. Tobita, Direct Conversion of a Si–C(aryl) Bond to Si–Heteroatom
Bonds in the Reactions of η3-α-Silabenzyl Molybdenum and Tungsten Complexes with2-Substituted Pyridines, Organometallics, 34, 3699–3705 (2015). (ACS Editor’s Choice)
11. T. Komuro, K. Furuyama, T. Kitano, and H. Tobita, Synthesis of a 14-electron iridium(III) complex
with a xanthene-based bis(silyl) chelate ligand (xantsil): A distorted seesaw-shapedfour-coordinate geometry and reactions leading to 16-electron complexes, J. Organomet. Chem.,
751, 686–694 (2014).
12. Y. Kanno, T. Komuro, and H. Tobita, Insertion of carbon monoxide into an aldehyde C=O doublebond induced by an (η3-α-silabenzyl)carbonylmolybdenum complex, RSC Adv., 4, 19068–19071(2014).
13. T. Watanabe, M. F. Itoh, T. Komuro, H. Okada, T. Sakai, Y. Ono, K. Kawachi, Y. Kasama, and H.
Tobita, Iridium and Platinum Complexes of Li+@C60, Organometallics, 33, 608−611 (2014).
14. T. Komuro, Y. Kanno, and H. Tobita, Synthesis, Structure, and Reactions of a(η3-α-silabenzyl)molybdenum Complex: A Synthetic Equivalent of Coordinatively Unsaturated
Silyl Complex, Organometallics, 32, 2795–2803 (2013).
15. E. Suzuki, T. Komuro, Y. Kanno, and H. Tobita, (η3-α-Silabenzyl)tungsten Complexes: An
Isolable Intermediate for Interconversion between a Silylene Complex and a Silyl Complex
through 1,2-Aryl Migration, Organometallics, 32, 748–751 (2013).
16. T. Komuro, S. Okawara, K. Furuyama, and H. Tobita, Silane(silyl) and Bis(silyl)hydrido
Manganese Complexes with Different Mn···H···Si Interaction: Observation of Gradual Si–H BondActivation on the Metal Center, Chem. Lett., 41, 774–776 (2012). (Editor’s Choice)
17. H. Okada, T. Komuro, T. Sakai, Y. Matsuo, Y. Ono, K. Omote, K. Yokoo, K. Kawachi, Y. Kasama,
S. Ono, R. Hatakeyama, T. Kaneko, and H. Tobita, Preparation of endohedral fullerenecontaining lithium (Li@C60) and isolation as pure hexafluorophosphate salt ([Li+@C60][PF6–]),
RSC Adv., 2, 10624–10631 (2012).
18. T. Komuro, R. Begum, R. Ono, and H. Tobita, Synthesis and characterisation of hydridomolybdenum and tungsten complexes having a hemilabile tridentate Si,Si,O-ligand: observationof stepwise hydrosilylation of a nitrile to form an N-silylimine on the metal centre, Dalton Trans.,
40, 2348–2357 (2011).
19. S. Aoyagi, E. Nishibori, H. Sawa, K. Sugimoto, M. Takata, Y. Miyata, R. Kitaura, H. Shinohara, H.
Okada, T. Sakai, Y. Ono, K. Kawachi, K. Yokoo, S. Ono, K. Omote, Y. Kasama, S. Ishikawa, T.
Komuro, and H. Tobita, A layered ionic crystal of polar Li@C60 superatoms, Nat. Chem., 2, 678–
683 (2010).

2

20. E. Suzuki, T. Komuro, Y. Kanno, M. Okazaki, and H. Tobita, Facile 1,2-Migration of a MethylGroup on a {Dimethoxy(methyl)silyl}tungsten Complex: Formation of a Base-Stabilized(Dimethoxysilylene)(methyl) Complex, Organometallics, 29, 5296–5300 (2010).
21. T. Komuro and H. Tobita, Thermal reaction of a ruthenium bis(silyl) complex having alutidine-based Si,N,Si ligand: formation of a µ-silyl(µ-silylene) diruthenium complex involving a3c–2e Ru–Si–C interaction, Chem. Commun., 46, 1136–1137 (2010).
22. E. Suzuki, T. Komuro, Y. Kanno, M. Okazaki, and H. Tobita, Synthesis and Characterization of
κ2C,N-N-Silyliminoacyl Tungsten Complexes Cp*(CO)2W{κ2C,N-C(R)=NSiR´3} [R = Me, Et, i-Pr,t-Bu; R´3 = (p-Tol)2Me, (p-Tol)3, Et3; Cp* = η5-C5Me5]: Thermally Induced Carbon–Carbon Bond
Cleavage of Their Iminoacyl Ligands, Organometallics, 29, 1839–1848 (2010).
23. E. Suzuki, T. Komuro, M. Okazaki, and H. Tobita, Synthesis and Characterization ofDMAP-Stabilized Aryl(silylene) Complexes and (Arylsilyl)(DMAP) Complexes of Tungsten:
Mechanistic Study on the Interconversion between These Complexes via 1,2-Aryl Migration,
Organometallics, 28, 1791–1799 (2009).
24. T.
Komuro,
K.
Mori,
andH.
Tobita,Synthesis
andStructuresofAlkynylchlorocyclotriphosphazenes
and
Their
Cluster-forming
Reactionswith
Octacarbonyldicobalt, Heterocycles, 77, 1171–1183 (2009).
25. M. Okazaki, T. Yoshitomi, J. Naito, A. Sato, T. Komuro, and H. Tobita, Recombination of an Fe–Si–P
Linkagetoan
Fe–P–Si
Linkagethroughan
IsolableIntermediate
Phosphasilaferracyclopropane, J. Am. Chem. Soc., 130, 17674–17675 (2008).
26. H. Tobita, N. Yamahira, K. Ohta, T. Komuro, and M. Okazaki, New hydrosilylation reaction ofarylacetylene accompanied by C–H bond activation catalyzed by a xantsil ruthenium complex,
Pure Appl. Chem., 80, 1155–1160 (2008).
27. M. Okazaki, N. Yamahira, J. J. G. Minglana, T. Komuro, H. Ogino, and H. Tobita,[Ru(xantsil)(CO)(η6-toluene)]: Synthon for a Highly Unsaturated Ruthenium(II) Complex throughFacileDissociationoftheToluene
Ligand[xantsil=(9,9-dimethylxanthene-4,5-diyl)bis(dimethylsilyl)], Organometallics, 27, 918–926 (2008).
28. J. J. G. Minglana, M. Okazaki, K. Hasegawa, L.-S. Luh, N. Yamahira, T. Komuro, H. Ogino, andH. Tobita, Iron, Ruthenium, and Osmium Complexes Supported by the Bis(silyl) Chelate Ligand(9,9-Dimethylxanthene-4,5-diyl)bis(dimethylsilyl): Synthesis, Characterization, and Reactivity,
Organometallics, 26, 5859–5866 (2007).
29. M. Okazaki, H. Kimura, T. Komuro, H. Okada, and H. Tobita, Synthesis, Structure, andProperties of Three- and Six-Membered Metallacycles Composed of Iron, Germanium, and SulfurAtoms, Chem. Lett., 36, 990–991 (2007).
30. E. Suzuki, T. Komuro, M. Okazaki, and H. Tobita, Three- and Five-Membered W/C/N
Metallacycles Formed by Incorporation of Acetonitrile Molecules into Silyltungsten Intermediates,
Organometallics, 26, 4379–4382 (2007).
31. R. Begum, T. Komuro, and H. Tobita, The First Resonance Hybrid of Silyl–Carbene and Pyridyl–
Silylene
Complexes:
FormationbyAryl
C–H
Bond
ActivationofDMAP[4-(Dimethylamino)pyridine] on a Silylene Complex, Chem. Lett., 36, 650–651 (2007).
32. T. Komuro, H. Kawaguchi, J. Lang, T. Nagasawa, and K. Tatsumi, [MoFe3S4]3+ and [MoFe3S4]2+
Cubane Clusters Containing a Pentamethylcyclopentadienyl Molybdenum Moiety, J. Organomet.
Chem., 692, 1–9 (2007).
3

33. R. Begum, T. Komuro, and H. Tobita, Group 6 metal complexes with a hemilabile tridentate
xantsil ligand and facile insertion of tBuCN into a W–Si bond [xantsil =(9,9-dimethylxanthene-4,5-diyl)bis(dimethylsilyl)], Chem. Commun., 432–433 (2006).
34. T. Komuro, T. Matsuo, H. Kawaguchi, and K. Tatsumi, Synthesis of a Vanadium(III)
Tris(arylthiolato) Complex and Its Reactions with Azide and Azo Compounds: Formation of aSulfenamide Complex via Cleavage of an Azo N=N Bond, Inorg. Chem., 44, 175–177 (2005).
35. T. Komuro, T. Matsuo, H. Kawaguchi, and K. Tatsumi, Synthesis and structural characterizationof silanethiolato complexes having tert-butyldimethylsilyl and trimethylsilyl groups, Dalton Trans.,
1618–1625 (2004).
36. T. Komuro, T. Matsuo, H. Kawaguchi, and K. Tatsumi, Coordination Chemistry of Silanedithiolato
Ligands Derived from Cyclotrisilathiane: Synthesis and Structures of Complexes of Iron(II),Cobalt(II), Palladium(II), Copper(I), and Silver(I), Inorg. Chem., 42, 5340–5347 (2003).
37. T. Komuro, T. Matsuo, H. Kawaguchi, and K. Tatsumi, Unusual Coordination Modes ofArylthiolates in Mo{η5-SC6H3-2,6-(SiMe3)2}{η7-SC6H3-2,6-(SiMe3)2}, J. Am. Chem. Soc., 125,2070–2071 (2003).
38. T. Komuro, T. Matsuo, H. Kawaguchi, and K. Tatsumi, Copper and Silver Complexes Containing
the S(SiMe2S)22– Ligand: Efficient Entries into Heterometallic Sulfido Clusters, Angew. Chem. Int.
Ed., 42, 465–468 (2003). (Hot Paper)
39. T. Komuro, H. Kawaguchi, and K. Tatsumi, Synthesis and Reactions of Triphenylsilanethiolato
Complexes of Manganese(II), Iron(II), Cobalt(II), and Nickel(II), Inorg. Chem., 41, 5083–5090(2002).
40. T. Komuro, T. Matsuo, H. Kawaguchi, and K. Tatsumi, Palladium dimethylsilanedithiolato
complex: a precursor for Ti–Pd and Ti–Pd2 heterometallic complexes, Chem. Commun., 988–989(2002).

解説記事
1.

小室 貴士, リン鉱石からリン化合物への新しい道筋, 化学, Vol. 73, No. 10, pp. 64–65 (2018).

2.

小室 貴士, シリルキレート配位子を持つ金属錯体触媒を用いたC–H結合および小分子の変換に関する最近の展開, Bull. Jpn. Soc. Coord. Chem., 70, 36–39 (2017).

3.

小室 貴士, メタンの C–H ホウ素化, Organometallic News (有機金属ハイライト), No. 2, p. 73(2016).

受賞 （受賞年月，受賞名称）
2018 年 3 月, International Congress on Pure & Applied Chemistry (ICPAC) 2018 Lecture Award4