Publications
Division of New Materials Science
Takigawa group
We have been performing nuclear magnetic resonance experiments on various quantum spin systems and strongly correlated
electron systems to explore novel quantum phases with exotic ordering and fluctuation phenomena. The major achievements
7in the year 2013 include: (1) Investigation by Li-NMR of the magnetic phase transition in the frustrated antiferromagnets
LiInCr4O8 and LiGaCr4O8 with the novel breathing pyrochlore structure, (2) Microscopic examination of the quantum criticaland non-fermi liquid behavior in the valence fluctuating Yb compound alpha- and beta- YbAlB4, (3) Continued investigation of
the magnetic and structural transition in single crystals of volborthite with the distorted Kagome lattice aimed at the full understanding of the phase diagram in magnetic field.
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Iterative deconvolution of quadrupole split NMR spectra: F. Mila and M. Takigawa, Eur. Phys. J. B 86 (2013) 354(1-4).

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Anisotropic spin fluctuations in the quasi one-dimensional frustrated magnet LiCuVO4: K. Nawa, M. Takigawa, M.
Yoshida and K. Yoshimura, J. Phys. Soc. Jpn. 86 (2013) 094709(1-13).
Magnetic Order in the Spin-1/2 Kagome Antiferromagnet Vesignieite: M. Yoshida, Y. Okamoto, M. Takigawa and Z.
Hiroi, J. Phys. Soc. Jpn. 82 (2013) 013702(1-5).
Incomplete Devil`s Staircase in the Magnetization Curve of SrCu2(BO3)2: M. Takigawa, M. Horvatic, T. Waki,
S. Kramer, C. Berthier, F. L. Bertrand, I. Sheikin, H. Kageyama, Y. Ueda and F. Mila, Phys. Rev. Lett. 110 (2013)067210(1-5).

Field-induced incommensurate phase in the strong-rung spin ladder with ferromagnetic legs: H. Yamaguchi, H.
Miyagai, M. Yoshida, M. Takigawa, K. Iwase, T. Ono, N. Kase, K. Araki, S. Kittaka, T. Sakakibara, T. Shimokawa, T.
Okubo, K. Okunishi, A. Matsuo and Y. Hosokoshi, Phys. Rev. B 89 (2014) 220402.

Sakakibara group
We study magnetism and superconductivity of materials having low characteristic temperatures. These include heavy-electron
systems, quantum spin systems and frustrated spin systems. The followings are some selected achievements in the fiscal year
2013. (1) Field and temperature variations of the specific heat C(H,T) of the iron pnictide superconductor KFe2As2 (Tc=3.4K) were examined at temperatures down to 100 mK. Thermodynamic evidence for the presence of line nodes is obtained fromthe square-root H dependence of C/T in the low-T and low-H regime. Under a magnetic field rotated within the tetragonal abplane, a fourfold oscillation is observed in Ce and its sign changes at 0.08 Tc. The results indicate that line nodes exist on the
superconducting gap where the Fermi velocity is parallel to [100] directions. (2) We measured the temperature dependence ofthe magnetization M(T) of a S=1/2 one dimensional Heisenberg antiferromagnet CuPzN (interaction parameter J~10 K) near thesaturation field Hs~14 T where a quantum phase transition from a Luttinger liquid ground state to a fully polarized state occurs.
It is found that M(T) at Hs exhibits a square-root T dependence below ~1 K down to 80 mK, in good agreement with a prediction of the exact solutions.
1.

Anomalous Field-Angle Dependence of the Specific Heat of Heavy-Fermion Superconductor UPt3: S. Kittaka, K. An, T.
Sakakibara, Y. Haga, E. Yamamoto, N. Kimura, Y. Onuki and K. Machida, J. Phys. Soc. Jpn. 82 (2013) 024707(1-5).

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124

Coexistence of Ising and XY Spin Systems on a Single Tb Atom in TbCoGa5: N. Sanada, Y. Amou, R. Watanuki, K.
Suzuki, I. Yamamoto, H. Mitamura, T. Sakakibara, M. Akatsu, Y. Nemoto and T. Goto, J. Phys. Soc. Jpn. 82 (2013)
044713(1-7).
Evidence of a High-Field Phase in PrV2Al20 in a [100] Magnetic Field: Y. Shimura, Y. Ohta, T. Sakakibara, A. Sakaiand S. Nakatsuji, J. Phys. Soc. Jpn. 82 (2013) 043705(1-4).
High-Field Phase Diagram of SmRu4P12 Determined by Ultrasonic Measurements in Pulsed Magnetic Field up to
55 T: M. Yoshizawa, H. Mitamura, F. Shichinomiya, S. Fukuda, Y. Nakanishi, H. Sugawara, T. Sakakibara and K. Kindo,
J. Phys. Soc. Jpn. 82 (2013) 033602(1-5).

ISSP Activity Report 2013

5.

Verification of Anisotropic s-Wave Superconducting Gap Structure in CeRu2 from Low-Temperature Field-AngleResolved Specific Heat Measurements: S. Kittaka, T. Sakakibara, M. Hedo, Y. Onuki and K. Machida, J. Phys. Soc. Jpn.
82 (2013) 123706(1-4).

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Determining the Surface-To-Bulk Progression in the Normal-State Electronic Structure of Sr2RuO4 by Angle-Resolved
Photoemission and Density Functional Theory: C. N. Veenstra, Z. -H. Zhu, B. Ludbrook, M. Capsoni, G. Levy, A.
Nicolaou, J. A. Rosen, R. Comin, S. Kittaka, Y. Maeno, I. S. Elfimov and A. Damascelli, Phys. Rev. Lett. 110 (2013)
097004(1-5).

Long-range order and spin-liquid states of polycrystalline Tb2+xTi2−xO7+y: T. Taniguchi, H. Kadowaki, H. Takatsu, B.
Fåk, J. Ollivier, T. Yamazaki, T. J. Sato, H. Yoshizawa, Y. Shimura, T. Sakakibara, T. Hong, K. Goto, L. R. Yaraskavitch
and J. B. Kycia, Phys. Rev. B 87 (2013) 060408R(1-5).
Quasi-one-dimensional S=1/2 Heisenberg antiferromagnetic chain consisting of the organic radical p-Br-V: K. Iwase,
H. Yamaguchi, T. Ono, Y. Hosokoshi, T. Shimokawa, Y. Kono, S. Kittaka, T. Sakakibara, A. Matsuo and K. Kindo, Phys.
Rev. B 88 (2013) 184431(1-5).
Various regimes of quantum behavior in an S=1/2 Heisenberg antiferromagnetic chain with fourfold periodicity: H.
Yamaguchi, T. Okubo, K. Iwase, T. Ono, Y. Kono, S. Kittaka, T. Sakakibara, A. Matsuo, K. Kindo and Y. Hosokoshi,
Phys. Rev. B 88 (2013) 174410(1-5).

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10. Unconventional Magnetic and Thermodynamic Properties of S=1/2 Spin Ladder with Ferromagnetic Legs: H.
Yamaguchi, K. Iwase, T. Ono, T. Shimokawa, H. Nakano, Y. Shimura, N. Kase, S. Kittaka, T. Sakakibara, T. Kawakami
and Y. Hosokoshi, Phys. Rev. Lett. 110 (2013) 157205(1-5).
11. 高次多極子がもたらす磁場誘起相 : 志村 恭通 , 榊原 俊郎 , 大貫 惇睦 , 固体物理 48 (2013) 721-727.
12. Magnetization steps in Yb2Pt2Pb with the Shastry-Sutherland lattice: Y. Shimura, T. Sakakibara, K. Iwakawa, Y. Onuki
and K. Sugiyama, J. Kor. Phys. Soc. 63 (2013) 551-554.
13. Singlet-triplet crossover in the two-dimensional dimer spin system YbAl3C3: S. Kittaka, T. Sugiyama, Y. Shimura, T.
Sakakibara, S. Matsuda and A. Ochiai, J. Kor. Phys. Soc. 62 (2013) 2088-2092.
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14. Fine-Tuning of Magnetic Interactions in Organic Spin Ladders: H. Yamaguchi, H. Miyagai, T. Shimokawa, K. Iwase, T.
Ono, Y. Kono, N. Kase, K. Araki, S. Kittaka, T. Sakakibara, T. Kawakami, K. Okunishi and Y. Hosokoshi, J. Phys. Soc.
Jpn. 83 (2014) 033707(1-4).
15. Novel Electronic States of Heavy Fermion Compound YbCo2Zn20: F. Honda, Y. Taga, Y. Hirose, S. Yoshiuchi, Y.
Tomooka, M. Ohya, J. Sakaguchi, T. Takeuchi, R. Settai, Y. Shimura, T. Sakakibara, I. Sheikin, T. Tanaka, Y. Kubo and
Y. Onuki, J. Phys. Soc. Jpn. 83 (2014) 044703(1-9).
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16. Possible Evolution of Antiferromagnetism in Zn-Doped Heavy-Fermion Superconductor CeCoIn5: M. Yokoyama, K.
Fujimura, S. Ishikawa, M. Kimura, T. Hasegawa, I. Kawasaki, K. Tenya, Y. Kono and T. Sakakibara, J. Phys. Soc. Jpn.
83 (2014) 033706(1-5).
17. Thermodynamic Study of Nodal Structure and Multiband Superconductivity of KFe2As2: S. Kittaka, Y. Aoki, N. Kase,
T. Sakakibara, T. Saito, H. Fukazawa, Y. Kohori, K. Kihou, C. Ho Lee, A. Iyo, H. Eisaki, K. Deguchi, N. K. Sato, Y.
Tsutsumi and K. Machida, J. Phys. Soc. Jpn. 83 (2014) 013704(1-4).
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Field-induced incommensurate phase in the strong-rung spin ladder with ferromagnetic legs: H. Yamaguchi, H.
Miyagai, M. Yoshida, M. Takigawa, K. Iwase, T. Ono, N. Kase, K. Araki, S. Kittaka, T. Sakakibara, T. Shimokawa, T.
Okubo, K. Okunishi, A. Matsuo and Y. Hosokoshi, Phys. Rev. B 89 (2014) 220402.

19. Measurement of the spin-orbit coupling in superconducting Sr2RuO4 using polarized light and spin-resolved photoemission spectroscopy: Evidence for a breakdown in the singlets and triplets pairing mechanisms: C. N. Veenstra, Z. -H.
Zhu, M. Raichle, B. M. Ludbrook, A. Nicolaou, B. Slomski, G. Landolt, S. Kittaka, Y. Maeno, J. H. Dil, I. S. Elfimov,
M. W. Haverkort and A. Damascelli, Phys. Rev. Lett. 112 (2014) 127002(1-4).
20. Multiband superconductivity with unexpected deficiency of nodal quasiparticles in CeCu2Si2: S. Kittaka, Y. Aoki,
Y. Shimura, T. Sakakibara, S. Seiro, C. Geibel, F. Steglich, H. Ikeda and K. Machida, Phys. Rev. Lett. 112 (2014)
067002(1-5).
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21. Magnetization and Specific Heat of the Caged Compound PrV2Al20: K. Araki, Y. Shimura, N. Kase, T. Sakakibara, A.
Sakai and S. Nakatsuji, J. Phys. Soc. Jpn. (2014), in print.

ISSP Activity Report 2013125

Mori group
We have successfully developed and characterized the functional molecular materials. The major achievements in 2013 are(1) to discover the novel spin liquid state of purely organic single-component crystal κ-H3(Cat-EDT-TTF)2, (2) to develop
the proton-electron coupled molecular conductor with tuning π-electron bandwidth and hydrogen bond, and (3) to clarify theelectronic state between 3/4-filled and effective 1/2-filled band structure by optical measurement for pressure-induced superconductor β-( meso-DMBEDT-TTF)2PF6.
1.

Optical Conductivity Measurement of a Dimer Mott-Insulator to Charge-Order Phase Transition in a Two-Dimensional
Quarter-Filled Organic Salt Compound: R. Okazaki, Y. Ikemoto, T. Moriwaki, T. Shikama, K. Takahashi, H. Mori, H.
Nakaya, T. Sasaki, Y. Yasui and I. Terasaki, Phys. Rev. Lett. 111 (2013) 217801.

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Pyridone derivatives carrying radical moieties: Hydrogen-bonded structures, magnetic properties, and metal coordination: M. Ueda, T. Mochida and H. Mori, Polyhedron 52 (2013) 755-760.

4.

Crystal Architectures and Magnetic Properties of Alkylferrocenium Salts with FnTCNQ(n = 0, 2, 4): Effect of Substituents on the Self-Assembled Structures: T. Mochida, T. Akasaka, Y. Funasako, Y. Nishio and H. Mori, Crystal Growth &Design 13 (2013) 4460.

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Hydrogen bond-promoted metallic state in a purely organic single-component conductor under pressure: T. Isono, H.
Kamo, A. Ueda, K. Takahashi, A. Nakao, R. Kumai, H. Nakao, K. Kobayashi, Y. Murakami and H. Mori, Nat. Commun.
4 (2013) 1344-1349.

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Gapless Quantum Spin Liquid in an Organic Spin-1/2 Triangular-Lattice κ-H3(Cat-EDT-TTF)2: T. Isono, H. Kamo, A.
Ueda, K. Takahashi, M. Kimata, H. Tajima, S. Tsuchiya, T. Terashima, S. Uji and H. Mori, Phys. Rev. Lett. 112 (2014)
177201.

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Biferrocenium salts with magnetite-like mixed-valence iron: coexistence of Fe
E. Nagabuchi, M. Takahashi and H. Mori, Chem. Commun. 50 (2014) 2481.

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Protonation of Pyridyl-Substituted TTF Derivatives: Substituent Effects in Solution and in the Proton-Electron Correlated Charge-Transfer Complexes: S. C. Lee, A. Ueda, A. Nakao, R. Kumai, H. Nakao, Y. Murakami and H. Mori,
Chem. Eur. J. 20 (2014) 1909.

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Charge-Transfer Salts of Biferrocene Derivatives with F2- and F4-Tetracyanoquinodimethane: Correlation Between
Donor–Acceptor Ratios and Cation Valence States: T. Mochida, Y. Funasako, E. Nagabuchi and H. Mori, Crystal
Growth & Design 14 (2014) 1459.

Fabrication of a field effect transistor structure using charge-ordered organic materials α-(BEDT-TTF)2I3 andα′-(BEDT-TTF)2IBr2: M. Kimata, T. Ishihara, A. Ueda, H. Mori and H. Tajima, Synth. Met. 173 (2013) 43-45.

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and Fein the crystal: T. Mochida,

10. Synergistic Spin Transition between Spin Crossover and Spin-Peierls-like Singlet Formation in the Halogen-Bonded
Molecular Hybrid System: [Fe(Iqsal)2][Ni(dmit)2]⋅CH3CN⋅H2O: K. Fukuroi, K. Takahashi, T. Mochida, T. Sakurai, H.
Ohta, T. Yamamoto, Y. Einaga and H. Mori, Angew. Chem. Int. Ed. 53 (2014) 1983.
11. 単成分純有機金属材料で金属伝導は可能か？ : 森 初果 , 上田 顕 , 化学 68 (2013) 64-65.
12. 磁性と伝導性が相関した多重機能性分子性物質の開発 : 森 初果 , 高橋 一志 , まぐね 8 (2013) 148-154.
13. はたらくこと 生きること理工系女性の想い : 森 初果 , 日刊工業新聞 (2013).
14. 化学の力を生かした新しい分子性機能材料の開発 : 森 初果 , 化学 69, No1 (2014) 20-21.
15. 金属状態を示す純有機単成分導体 : 森 初果 , 工業材料 62 No1 (2014) 26-27.

Nakatsuji group
Our group explores novel quantum phases and phase transitions in rare-earth and transition metal based compounds. The
followings are some relevant results obtained in 2013. (1) We have found that the metallic spin ice compound Pr2Ir2O7 exhibits
quantum criticality in a nontrivial semimetallic state. (2) The Fe doping at the Al site in α-YbAlB4 induces an antiferromagnetic
ordering whose ordering temperature goes up to 10 K, which is the highest among the Yb based heavy fermion materials. The
large enhancement of the magnetic ordering indicates that the mixed valence plays an important role. (3) Finally, our successin synthesizing high quality single crystals of PrTr2Al20 allows us to reveal that the superconductivity in PrTi2Al20 and theantiferro-quadrupolar transition in PrV2Al20 can be easily suppressed by disorder. This highlights the importance of high quality
crystals for the study of strong hybridization effects in quadrupolar Kondo systems.

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ISSP Activity Report 2013

1.

Conduction electron spin resonance in AlB2: L. M. Holanda, L. Mendonça-Ferreira, R. A. Ribeiro, J. M. Osorio-Guillén,
G. M. Dalpian, K. Kuga, S. Nakatsuji, Z. Fisk, R. R. Urbano, P. G. Pagliuso and C. Rettori, J. Phys.: Condens. Matter 25(2013) 216001.

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Determination of long-range all-in-all-out ordering of Ir moments in a pyrochlore iridate Eu2Ir2O7 by resonant x-ray
diffraction: H. Sagayama, D. Uematsu, T. Arima, K. Sugimoto, J. J. Ishikawa, E. O’Farrell and S. Nakatsuji, Phys. Rev.
B 87 (2013) 100403(4 pages).

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Magnetic excitations and c-f hybridization effect in PrTi2Al20and PrV2Al20: Y. Tokunaga, H. Sakai, S. Kambe, A. Sakai,
S. Nakatsuji and H. Harima, Phys. Rev. B 88 (2013) 085124.

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Dynamical spin–orbital correlation in the frustrated magnet Ba3CuSb2O9: Y. Ishiguro, K. Kimura, S. Nakatsuji, S.
Tsutsui, A. Q. R. Baron, T. Kimura and Y. Wakabayashi, Nat. Commun. 4 (2013) 2022(1-6).

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Quantum fluctuations in spin-ice-like Pr2Zr2O7: K. Kimura, S. Nakatsuji, J.-J. Wen, C. Broholm, M. B. Stone, E. Nishibori and H. Sawa, Nat. Commun. 4 (2013) 1934(1-6).

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Low temperature transport properties of the quadrupolar Kondo lattice system PrTi2Al20: A. Sakai and S. Nakatsuji, J.
Kor. Phys. Soc. 63 (2013) 398-400.

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Magnetic order induced by Fe doping in the intermediate valence system β-YbAlB4: K. Kuga and S. Nakatsuji, J. Kor.
Phys. Soc. 63 (2013) 549-550.

Evidence of a High-Field Phase in PrV2Al20 in a [100] Magnetic Field: Y. Shimura, Y. Ohta, T. Sakakibara, A. Sakaiand S. Nakatsuji, J. Phys. Soc. Jpn. 82 (2013) 043705(1-4).
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Chemical effects of high-resolution Yb Lγ 4 emission spectra: a possible probe for chemical analysis: H. Hayashi, N.
Kanai, N. Kawamura, Y. H. Matsuda, K. Kuga, S. Nakatsuji, T. Yamashita and S. Ohara, X-Ray Spectrom. 42 (2013)450-455.

10. Mössbauer spectroscopy of Fe-doped valence-fluctuating α-YbAlB4: Y. Sakaguchi, S. Ikeda, H. Kobayashi, K. Kuga, K.
Sone and S. Nakatsuji, J. Kor. Phys. Soc. 62 (2013) 2146-2149.
11. Single-crystal study on the low-temperature magnetism of the pyrochlore magnet Pr2Zr2O7: K. Kimura, S. Nakatsuji
and A. A. Nugroho, J. Kor. Phys. Soc. 63 (2013) 719-721.
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12. Synchrotron X-ray spectroscopy study on the valence state in α- and β-YbAlB4 at low temperatures and high magnetic
fields: Y. H. Matsuda, T. Nakamura, K. Kuga, S. Nakatsuji, S. Michimura, T. Inami, N. Kawamura and M. Mizumaki, J.
Kor. Phys. Soc. 62 (2013) 1778-1781.
13. Quantum criticality in a metallic spin liquid: Y. Tokiwa, J. J. Ishikawa, S. Nakatsuji and P. Gegenwart, Nature Mater. 13(2014) 356.
14. X-ray Photoemission and X-ray Absorption Spectroscopy of Hexagonal Ba3CuSb2O9: T. Sugimoto, T. Mizokawa, H.
Wadati, K. Takubo, A. Damascelli, T. Z. Regier, G. A. Sawatzky, N. Katayama, H. Sawa, K. Kimura and S. Nakatsuji, J.
Kor. Phys. Soc. 63 (2014) 549-550.
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15. Heavy fermion superconductivity under pressure in the quadrupole system PrTi2Al20: K. Matsubayashi, T. Tanaka, J.
Suzuki, A. Sakai, S. Nakatsuji, K. Kitagawa, Y. Kubo and Y. Uwatoko, J. Phys. Soc. Jpn. (2014), in print.
16. Magnetic and Thermal Properties of the Single Crystalline Pr2Zr2O7 in a [111] field: K. Kimura and S. Nakatsuji, J.
Phys. Soc. Jpn. (2014), in print.
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17. Magnetization and Specific Heat of the Caged Compound PrV2Al20: K. Araki, Y. Shimura, N. Kase, T. Sakakibara, A.
Sakai and S. Nakatsuji, J. Phys. Soc. Jpn. (2014), in print.
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18. Magnetization of Yb-based mixed-valent compounds at megagauss fields: T. Terashima, Y. H. Matsuda, K. Kuga, Y.
Matsumoto and S. Nakatsuji, J. Phys. Soc. Jpn. (2014), in print.
19. Sample Dependence of the Quadrupolar Transition in the Nonmagnetic cubic Γ3 Compound PrV2Al20: M. Tsujimoto, A.
Sakai and S. Nakatsuji, J. Phys. Soc. Jpn. (2014), in print.
20. Structural and Magnetic Properties of α-Yb(Al1-xFex)B4 under Hydtostatic Pressure: Y. Sakaguchi, S. Ikeda, K. Kuga, S.
Nakatsuji, N. Hirao, Y. Ohishi and H. Kobayashi, J. Phys. Soc. Jpn. (2014), in print.
21. Superconducting properties of the ferroquadrupolar cubic Γ3 compound PrTi2Al20: A. Sakai, K. Kuga and S. Nakatsuji,
J. Phys. Soc. Jpn. (2014), in print.

ISSP Activity Report 2013127

22. Suppression of the Heavy Fermion State in Magnetic Fields in the Mixed Valent α-YbAlB4: Y. Matsumoto, K. Kentaro
and S. Nakatsuji, J. Phys. Soc. Jpn. (2014), in print.
23. Two magnetic phases in α-YbAl1-xFexB4: K. Kuga, S. Suzuki and S. Nakatsuji, J. Phys. Soc. Jpn. (2014), in print.
24. 銅酸化物における乱れに強い量子液体状態 : 中辻 知 , 澤 博 ,「超伝導現象と高温超伝導体」, 新日本編集企画 ,(NTS 出版社 , 2013), 475-481.

Ohgushi group
Our group is focused on an exploratory synthesis and characterization of oxides, chalcogenides, and intermetallics. The majorachievements in the fiscal year 2013 are (1) finding of new superconductivity in anti-post-perovskite compounds, and (2) elucidation of orbital states of iridium oxides by means of resonant x-ray diffraction.
1.

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Complex orbital state stabilized by strong spin-orbit coupling in a metallic iridium oxide IrO2: Y. Hirata, K. Ohgushi,
J.-I. Yamaura, H. Ohsumi, S. Takeshita, M. Takata and T. Arima, Phys. Rev. B 87 (2013) 161111(1-5).

3.

Magnetoelasticity in ACr2O4 spinel oxides (A = Mn, Fe, Co, Ni, and Cu): V. Kocsis, S. Bordács, D. Varjas, K. Penc, A.
Abouelsayed, C. A. Kuntscher, K. Ohgushi, Y. Tokura and I. Kézsmárki, Phys. Rev. B 87 (2013) 064416(1-9).

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Resonant X-ray Diffraction Study of the Strongly Spin-Orbit-Coupled Mott Insulator CaIrO3: K. Ohgushi, J.-I.
Yamaura, H. Ohsumi, K. Sugimoto, S. Takeshita, A. Tokuda, H. Takagi, M. Takata and T.-H. Arima, Phys. Rev. Lett.
110 (2013) 217212(1-5).

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Observation of Phonon-Assisted Magnon Absorption in Spin–Orbit Coupling Induced Mott Insulator Sr2IrO4: Y.
Hirata, H. Tajima and K. Ohgushi, J. Phys. Soc. Jpn. 82 (2013) 035002(1-2).

Mechanism of Enhanced Optical Second-Harmonic Generation in the Conducting Pyrochlore-Type Pb2Ir2O7-x Oxide
Compound: Y. Hirata, M. Nakajima, Y. Nomura, H. Tajima, Y. Matsushita, K. Asoh, Y. Kiuchi, A. G. Eguiluz, R. Arita,
T. Suemoto and K. Ohgushi, Phys. Rev. Lett. 110 (2013) 187402(1-5).

Hydrostatic pressure (8GPa) dependence of electrical resistivity of BaCo2As2 single crystal: C. Ganguli, K. Matsubayashi, K. Ohgushi, Y. Uwatoko, M. Kanagaraj and S. Arumugam, Mat. Res. Bull. 48 (2013) 4329-4331.
Suppression of Intersite Charge Transfer in Charge-Disproportionated Perovskite YCu3Fe4O12: H. Etani, I. Yamada, K.
Ohgushi, N. Hayashi, Y. Kusano, M. Mizumaki, J. Kim, N. Tsuji, R. Takahashi, N. Nishiyama, T. Inoue, T. Irifune and
M. Takano, J. Am. Chem. Soc. 135 (2013) 6100-6106.
5d 遷移金属パイロクロア酸化物における低温磁気構造の研究 : 山浦 淳一 , 大串 研也 , 広井 善二 , 日本結晶学会誌 55 (2013) 116-120.
Control of Bond-Strain-Induced Electronic Phase Transitions in Iron Perovskites: I. Yamada, H. Etani, K. Tsuchida, S.
Marukawa, N. Hayashi, T. Kawakami, M. Mizumaki, K. Ohgushi, Y. Kusano, J. Kim, N. Tsuji, R. Takahashi, N. Nishiyama, T. Inoue, T. Irifune and M. Takano, Inorg. Chem. 52 (2013) 13751-13761.

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B-Site Deficiencies in A-site-Ordered Perovskite LaCu3Pt3.75O12: M. Ochi, I. Yamada, K. Ohgushi, Y. Kusano, M.
Mizumaki, R. Takahashi, S. Yagi, N. Nishiyama, T. Inoue and T. Irifune, Inorg. Chem. 52 (2013) 3985-3989.

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2+

11. Pd -Incorporated Perovskite CaPd3B4O12(B = Ti, V): K. Shiro, I. Yamada, N. Ikeda, K. Ohgushi, M. Mizumaki, R.
Takahashi, N. Nishiyama, T. Inoue and T. Irifune, Inorg. Chem. 52 (2013) 1604-1609.
12. Superconductivity in anti-post-perovskite vanadium compounds: B. Wang and K. Ohgushi, Sci. Rep. 3 (2013) 3381.
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13. NMR study of successive magnetic transitions in the A-site ordered perovskite LaMn3Cr4O12: Y. Kawasaki, S. Takase,Y. Kishimoto, T. Ohno, I. Yamada, K. Shiro, R. Takahashi, K. Ohgushi, N. Nishiyama, T. Inoue and T. Irifune, J. Kor.
Phys. Soc. 63 (2013) 640-643.
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14. High-pressure effects in anti-post-perovskite superconductors V3PnNx (Pn = P, As): B. S. Wang, J. -G. Cheng, K.
Matsubayashi, Y. Uwatoko and K. Ohgushi, Phys. Rev. B 89 (2014) 144510 (1-4).
15. Magnetoelectric responses from the respective magnetic R and Fe subsystems in the noncentrosymmetric antiferromagnets RFe3(BO3)4 (R = Eu, Gd, and Tb): T. Kurumaji, K. Ohgushi and Y. Tokura, Phys. Rev. B 89 (2014) 195126 (1-13).

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16. Pseudogap formation above the superconducting dome in iron pnictides: T. Shimojima, T. Sonobe, W. Malaeb, K.
Shinada, A. Chainani, S. Shin, T. Yoshida, S. Ideta, A. Fujimori, H. Kumigashira, K. Ono, Y. Nakashima, H. Anzai, M.
Arita, A. Ino, H. Namatame, M. Taniguchi, M. Nakajima, S. Uchida, Y. Tomioka, T. Ito, K. Kihou, C. H. Lee, A. Iyo,
H. Eisaki, K. Ohgushi, S. Kasahara, T. Terashima, H. Ikeda, T. Shibauchi, Y. Matsuda and K. Ishizaka, Phys. Rev. B 89
(2014) 045101(1-10).
17. CaIrO3: a Spin-Orbit Mott Insulator Beyond the jeff = 1/2 Ground State: M. Moretti Sala, K. Ohgushi, A. Al-Zein, Y.
Hirata, G. Monaco and M. Krisch, Phys. Rev. Lett. 112 (2014) 176402.
18. ポストペロブスカイト型化合物 CaIrO3 の磁気構造 : 大串 研也 , 大隅 寛幸 , 山浦 淳一 , 有馬 孝尚 , 日本結晶学会誌 56 (2014) 36.

Division of Condensed Matter Theory
K. Ueda group
When a simple lattice is depleted in a periodic manner, electronic states of a tight binding model on such a depleted lattice
sometimes shows a peculiar feature like a flat band or a Dirac cone. A typical example is the triangular lattice: the honeycomb
lattice is obtained by the one third depletion and the kagome lattice by the one quarter depletion. In 2013, we concentrated on
the quantum phase transitions of the Hubbard model on the one fifth depleted square lattice. This structure exists in nature in
CaV4O9 and in some iron pnictide compound. At quarter filling the Dirac cone at the gamma point coincides with the Fermi
energy and furthermore the Dirac cone touches with an almost flat band forming an SU(3) multiplet. We have shown thatquantum phase transitions around the symmetric point is controlled by the SU(3) Dirac electrons. At half filling the effective
theory in the strong coupling limit is a Heisenberg model which shows quantum phase transitions from the dimer singlet to theantiferromagnetic phase and further onto the plaquette singlet phase. Quantum phase transitions of the Hubbard model on thislattice have been investigated by using the cluster dynamical mean field theory.
1.

SU(3) Dirac Electrons in the 1/5-Depleted Square-Lattice Hubbard Model at 1/4-Filling: Y. Yamashita, M. Tomura, Y.
Yanagi and K. Ueda, Phys. Rev. B 88 (2013) 195104(1-7).

Takada group
Employing several techniques including the Green's-function approach, the density-matrix renormalization group, quantum
Monte Carlo simulations, band-structure calculations, and several types of variational approaches, we are studying various
aspects of quantum many-body problems in condensed matter physics, based mainly on the first-principles Hamiltonian. This
year we have studied the following issues: (1) In order to better reproduce the electron-density profile obtained by the diffusion
Monte Carlo method for the system of a single atom embedded in the electron gas with arbitrary densities, we have improved on
the GGA-PBE version of the exchange-correlation energy functional in the density functional theory. In making this improvement, we have paid special attention to fulfilling the cusp theorem at the atom site. The improved functional will be applied to awide range of topics in the future, including the phase diagram of the solid hydrogen under high pressures. (2) A further analysis
is made for an electron-like elementally excitation (pseudoelectron) in the Luttinger liquid in competition with the spinon
and holon excitations by using the powerful self-consistent numerical GWΓ scheme. (3) Mechanisms of superconductivity
are considered in the low-density system in the framework of the kp perturbation theory with application to the n-type doped
SrTiO3. We have considered the effects of various issues such as the ferroelectric soft-phonon exchange, the plasmon contribution, the band multiplicity and the spin-orbit interaction.
1.

第１原理からの超伝導理論 : 高田 康民 , 物性研究 電子版 Vol.3, No.1 (2013) 031203(1-29).

2.

Structural evolution of the one-dimensional spectral function from the low- to the high-energy limit: H. Maebashi and Y.
Takada, Phys. Rev. B 89 (2014) 201109(R) (1-5).

3.

Theory for Reliable First-Principles Prediction of the Superconducting Transition Temperature: Y. Takada, in: Carbonbased New Superconductors: Toward high-Tc superconductivity (ISBN 978-981-4303-30-9 (Hardcover), 978-981-430331-6 (eBook)), Ch 8, edited by J. Haruyama, (Pan Stanford Publishing Pte. Ltd., 2014), 38page.

Oshikawa group
We studied a wide range of fundamental problems in condensed matter theory and statistical mechanics. In particular, we investigated the effects of quantum particle statistics on the ground-state energy. In the case of free particles, a ground state of bosons
is given by a Bose-Einstein Condensation of all the particles into the lowest-energy single-particle state. In contrast, the ground

ISSP Activity Report 2013129

state of fermions is given by putting the particles to lowest-energy single-particle state, but with the restriction that no more than
one particle can occupy an identical state (Pauli exclusion principle). Thus the ground-state energy for the identical Hamiltonian
would be higher in the case of fermions, compared to the case of bosons. However, the comparison becomes not trivial when
the particles are interacting. In fact, we established several examples in which the hard-core bosons have a higher ground-stateenergy than the corresponding fermions. We have also provided a novel understanding how the particle statistics affects theground-state energy: Fermi statistics introduces a sort of frustration among hoppings of many particles. When there is no otherfrustration among hoppings, we proved that the bosons have a lower ground-state energy than the corresponding fermions, evenin the presence of interactions. On the other hand, when frustration is introduced through phases of hopping amplitudes, theeffects may partially cancel with each other, resulting in a reversal of the ground-state energy.
1.

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Dimensional crossover in layered f-electron superlattices: Y. Tada, R. Peters and M. Oshikawa, Phys. Rev. B 88 (2013)
235121 (1-7).
Electron spin resonance shifts in S=1 antiferromagnetic chains: S. C. Furuya, Y. Maeda and M. Oshikawa, Phys. Rev. B
87 (2013) 125122 (1-10).
Entanglement spectra between coupled Tomonaga-Luttinger liquids: Applications to ladder systems and topologicalphases: R. Lundgren, Y. Fuji, S. Furukawa and M. Oshikawa, Phys. Rev. B 88 (2013) 245137 (1-14).
Hole statistics and superfluid phases in quantum dimer models: C. A. Lamas, A. Ralko, M. Oshikawa, D. Poilblanc and
P. Pujol, Phys. Rev. B 87 (2013) 104512(1-20).
Response to a twist in systems with Zp symmetry: The two-dimensional p-state clock model: Y. Kumano, K.
Hukushima, Y. Tomita and M. Oshikawa, Phys. Rev. B 88 (2013) 104427 (1-6).
Ground-State Energies of Spinless Free Fermions and Hard-Core Bosons: W. Nie, H. Katsura and M. Oshikawa, Phys.
Rev. Lett. 111 (2013) 100402 (1-5).
Quantum criticality in an asymmetric three-leg spin tube: A strong rung-coupling perspective: Y. Fuji, S. Nishimoto, H.
Nakada and M. Oshikawa, Phys. Rev. B 89 (2014) 054425 (1-13).
Valence bond distribution and correlation in bipartite Heisenberg antiferromagnets: D. Schwandt, F. Alet and M.
Oshikawa, Phys. Rev. B 89 (2014) 104416 (1-14).

Tsunetsugu group
We have investigated novel phases of non-Kramers doublets realized in the heavy fermion compound PrIr2Zn20 and related
2materials. Non-Kramers doublet is a ground state of f electron configuration protected by cubic symmetry of the crystalline
field. Based on a microscopic model and an effective field theory, we have used symmetry arguments and mean-field approachto study possible symmetry breaking at low temperatures with and without magnetic field. We have found various antiferro
quadrupole ordered phases depending on the magnetic field direction. The most important ingredient is the presence of a unique
Z3 anisotropy in the order parameter space, and in particular, the zero-field order corresponds to the spontaneous breaking of Z3
× Z2 symmetry. This also results in unusual divergence of quadrupole susceptibility in several channels near the critical point.
This may be related to observed singularity in ultrasound measurements. We have also numerically studied doublon dynamics
near the Mott metal-insulator transition. It has been long believed that the Mott transition is a binding-unbinding transition of
doublons and holons, but this point has been directly examined only by equal-time correlations. We have performed large-scalecomputations of cluster dynamical mean-field theory for the half-filled Hubbard model on the triangular lattice, and calculated
dynamical correlations of doublons and holons on the same site and also between nearest-neighbor sites. The results show
drastic changes in their dynamics between the metallic and insulating phases. In particular, the doublon-holon pair correlation shows fluctuations up to a very long time in the metallic phase, while the correlation decays very quickly in the insulatingphase. This supports the binding-unbinding transition picture of the Mott transition. (Reference: Toshihiro Sato and Hirokazu
Tsunetsugu, arXiv:1404.6598) Quantum impurities coupled to Tomonaga-Luttinger liquids are interesting physical systems
including an impurity in quantum wire, a spin coupled to a two-dimensional topological insulator etc. We have developed a new
method of quantum Monte Carlo simulation with continuous time formulation. This is base on the duality between electrons andbosons, and this results in the advantage of negative sign free nature. The new method is applied to various problems and scaling
properties of correlation functions are examined. (Reference: K. Hattori and A. Rosch, arXiv: 1405.3300)
1.

Continuous-Time Quantum Monte Carlo Approach for Impurity Anderson Models with Phonon-Assisted Hybridizations: K. Hattori, J. Phys. Soc. Jpn. 82 (2013) 064709 (5 pages).

2.

Exotic disordered phases in the quantum J1-J2 model on the honeycomb lattice: H. Zhang and C. A. Lamas, Phys. Rev.
B 87 (2013) 024415 (10 pages).

3.

p-wave superconductivity near a transverse saturation field: K. Hattori and H. Tsunetsugu, Phys. Rev. B 87 (2013)064501 (5 pages).

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4.

Antiferro Quadrupole Orders in Non-Kramers Doublet Systems: K. Hattori and H. Tsunetsugu, J. Phys. Soc. Jpn. 83(2014) 034709 (19 pages).

Kohmoto group
Energy versus magnetic field (Hofstadter butterfly diagram) in twisted bilayer graphene is studied theoretically. If we take theusual Landau gauge, we cannot take a finite periodicity even when the magnetic flux through a supercell is a rational number.
We show that the periodic Landau gauge, which has the periodicity in one direction, makes it possible to obtain the Hofstadterbutterfly diagram. Since a supercell can be large, magnetic flux through a supercell normalized by the flux quantum can be afractional number with a small denominator, even when a magnetic field is not extremely strong. As a result, quantized Hall
conductance can be a solution of the Diophantine equation which cannot be obtained by the approximation of the linearizedenergy dispersion near the Dirac points.
1.

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Periodic Landau gauge and quantum Hall effect in twisted bilayer graphene: Y. Hasegawa and M. Kohmoto, Phys. Rev.
B 88 (2013) 125426(1-8).
The Spectral Shift Function and the Friedel Sum Rule: M. Kohmoto, T. Koma and S. Nakamura, Ann. Henri Poincaré
14 (2013) 1413-1424.

Sugino group
We have advanced the first-principles molecular dynamics approach to the electrochemical interfaces. This was done by
improving the effective screening medium (ESM) method. With the method, new results was obtained regarding the planar andparticle catalysts and the mechanism of the reactions. We have continued to develop a many-body Green's function approachto the spectroscopy and began to obtain promising results. Progress has been made on the tensor network approach to obtainaccurate density matrix of molecules.
1.

Improved modeling of electrified interfaces using the effective screening medium method: I. Hamada, O. Sugino, N.
Bonnet and M. Otani, Phys. Rev. B 88 (2013) 155427.

2.

Nonadiabatic couplings from time-dependent density functional theory: Formulation by the Kohn-Sham derivative
matrix within density functional perturbation theory: C. Hu, T. Tsukagoshi, O. Sugino and K. Watanabe, Phys. Rev. B
87 (2013) 035421(1-7).

3.

Reply to “Comment on ‘Nonadiabatic couplings from the Kohn-Sham derivative matrix: Formulation by time-dependent density-functional theory and evaluation in the pseudopotential framework’”: C. Hu, O. Sugino, H. Hirai and Y.
Tateyama, Phys. Rev. A 88 (2013) 056502.

4.

First-Principles Investigation on Structural and Optical Properties of M @C60 (Where M = H, Li, Na, and K): Y.
Noguchi, O. Sugino, H. Okada and Y. Matsuo, J. Phys. Chem. C 117 (2013) 15362.

5.

白金電極上における水素発生反応の第一原理的理解に向けて : I. Hamada and O. Sugino, J. Surf. Sci. Soc. Jpn. 34(2013) 638.

6.

Microscopic understanding of the electrochemical interfaces: O. Sugino, AIP Conf. Proc. 1568 (2013) 43.

7.

Electronic structures of oxygen-deficient Ta2O5: Y. Yang, H.-H. Nahm, O. Sugino and T. Ohno, AIP Advances 3 (2013)
042101(1-8).

8.

Effect of thermal motion on catalytic activity of nanoparticles in polar solvent: N. Bonnet, O. Sugino and M. Otani, J.
Chem. Phys. 140 (2014) 044703.

9.

Performance of Tamm-Dancoff approximation on nonadiabatic couplings by time-dependent density functional theory:
C. Hu, O. Sugino and K. Watanabe, J. Chem. Phys. 140 (2014) 054106.

+

10. First-principles thermodynamic description of hydrogen electroadsorption on the Pt(111) surface: T. T. T. Hanh, Y.
Takimoto and O. Sugino, Surf. Sci. 625 (2014) 104.

Kato group
The main research subject in our laboratory is theory of nonequilibrium properties in nanoscale devices. We have performed (1)evaluation of coherence in single-photon and single-electron generation quantum, (2) exact calculation of transport properties in
the Anderson impurity at high bias voltages, and (3) Kondo-like phenomena in heat transport through a local two-state system.

ISSP Activity Report 2013

131

1.

Properties of a Single Photon Generated by a Solid-State Emitter: Effects of Pure Dephasing: E. Iyoda, T. Kato, T. Aoki,
K. Edamatsu and K. Koshino, J. Phys. Soc. Jpn. 82 (2013) 014301(1-10).

2.

Relaxor Behavior and Morphotropic Phase Boundary in a Simple Model: Y. Tomita and T. Kato, J. Phys. Soc. Jpn. 82(2013) 063002(1-5).

3.

Exact interacting Green's function for the Anderson impurity at high bias voltages: A. Oguri and R. Sakano, Phys. Rev.
B 88 (2013) 155424(1-12).

4.

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5.

Kondo Signature in Heat Transfer via a Local Two-State System: K. Saito and T. Kato, Phys. Rev. Lett. 111 (2013)
214301(1-5).

6.

1/(N − 1) expansion approach to full-counting statistics for the SU(N) Anderson model: A. Oguri and R. Sakano, J. Kor.
Phys. Soc. 63 (2013) 423-427.

7.

Dephasing in single-electron generation due to environmental noise probed by Hong-Ou-Mandel interferometry: E.
Iyoda, T. Kato, K. Koshino and T. Martin, Phys. Rev. B 89 (2014) 205318(1-8).

8.

メゾスコピック系の物理―基礎から最近の話題まで―（第 58 回物性若手夏の学校 : 講義）: 加藤 岳生 , 物性研究・
電子版 3 (2014) 031201(1-26).

Experimental Verification of Comparability between Spin-Orbit and Spin-Diffusion Lengths: Y. Niimi, D. Wei, H.
Idzuchi, T. Wakamura, T. Kato and Y. Otani, Phys. Rev. Lett. 110 (2013) 016805.

Division of Nanoscale ScienceIye group
Thermoelectric effect and high frequency conduction in GaAs/AlGaAs 2DEG subjected to periodic potential modulation (lateralsuperlattice) has been investigated. Commensurability oscillation in thermoelectric power is observed in one-dimensional lateralsuperlattice sample. AC conductivity in the quantum Hall plateau region of a hexagonal lateral superlattice sample exhibits a
few characteristic resonance peaks.
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4.

Commensurability oscillations in the rf conductivity of unidirectional lateral superlattices: measurement of anisotropic
conductivity by coplanar waveguide: A. Endo, T. Kajioka and Y. Iye, J. Phys. Soc. Jpn 82 (2013) 054710(1-7).

5.

Diffusion Thermopower of Quantum Hall States Measured in Corbino Geometry: S. Kobayakawa, A. Endo and Y. Iye, J.
Phys. Soc. Jpn 82 (2013) 053702(1-4).

6.

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Control of magnetic anisotropy in (Ga,Mn)As with etching depth of specimen boundaries: Y. Hashimoto, Y. Iye and S.
Katsumoto, J. Cryst. Growth 378 (2013) 381.
Suppression of Andreev current due to transverse current flow in an InAs two-dimensional electrons: Y. Takahashi, Y.
Hashimoto, Y. Iye and S. Katsumoto, J. Cryst. Growth 378 (2013) 400.
Spin Hall reduction of Josephson effect in InAs two-dimensional electrons: T. Nakamura, Y. Takahashi, Y. Hashimoto,D. H. Yun, S. W. Kim, Y. Iye and S. Katsumoto, Phys. Status Solidi C 10 (2013) 1473.

Mechanical modification of magnetic anisotropy in (Ga,Mn)As: Y. Hashimoto, Y. Iye and S. Katsumoto, in: AIP
Conference Proceedings "International Conference on Physics of Semiconductors", edited by T. Ihn (AIP, 2013), 347.

Katsumoto group
The two-electron tunneling process to a side-coupled quantum dot has been applied to detect spin polarization in the target
device. The method is most powerful among so far developed and the device voltage dependence can be measured. We haverevealed that the polarization mechanism at so called 0.5 plateau is the Stern-Gelach type spin-filter while that at 1.0 plateau isthe spin rotation predicted a decade ago.
1.

Robustness of spin filtering against current leakage in a Rashba-Dresselhaus-Aharonov-Bohm interferometer: S.
Matityahu, A. Aharony, O. Entin-Wohlman and S. Katsumoto, Phys. Rev. B 87 (2013) 205438(1-8).

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132

Adiabatic measurements of magneto-caloric effects in pulsed high magnetic fields up to 55 T: T. Kihara, Y. Kohama,
Y. Hashimoto, S. Katsumoto and M. Tokunaga, Rev. Sci. Instrum. 84 (2013) 074901(1-7).

ISSP Activity Report 2013

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Effect of transverse current on Andreev bound state: Y. Takahashi, Y. Hashimoto, D. H. Yun, S. W. Kim, T. Nakamura,Y. Iye and S. Katsumoto, in: AIP Conference Proceedings, "International Conference on Physics of Semiconductors",edited by T. Ihn (AIP, 2013), 345.

8.

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量子の匠 : 勝本 信吾 , ( 丸善 , 東京 , 2014).

Control of magnetic anisotropy in (Ga,Mn)As with etching depth of specimen boundaries: Y. Hashimoto, Y. Iye and S.
Katsumoto, J. Cryst. Growth 378 (2013) 381.
Suppression of Andreev current due to transverse current flow in an InAs two-dimensional electrons: Y. Takahashi, Y.
Hashimoto, Y. Iye and S. Katsumoto, J. Cryst. Growth 378 (2013) 400.
Spin Hall reduction of Josephson effect in InAs two-dimensional electrons: T. Nakamura, Y. Takahashi, Y. Hashimoto,D. H. Yun, S. W. Kim, Y. Iye and S. Katsumoto, Phys. Status Solidi C 10 (2013) 1473.
Heat-pulse measurements of specific heat in 36 ms pulsed magnetic fields: Y. Kohama, Y. Hashimoto, S. Katsumoto,
M. Tokunaga and K. Kindo, Meas. Sci. Technol. 24 (2013) 115005(1-9).

Mechanical modification of magnetic anisotropy in (Ga,Mn)As: Y. Hashimoto, Y. Iye and S. Katsumoto, in: AIP
Conference Proceedings "International Conference on Physics of Semiconductors", edited by T. Ihn (AIP, 2013), 347.

Otani group
We have studied on three topics including spin Hall effect, spin diffusion length, and magnonic crystals. Firstly we have applied
our non-local spin injection technique to 5d iridium oxide, and succeeded in detecting a very large inverse spin Hall resistivity
at room temperature which guarantees this material as a good spin current detector. Secondly we experimentally confirmed thatweak antilocalization measurements can be employed as a complementary method for determining the spin diffusion lengths
of noble metals. Thirdly in collaboration with Indian group lead by Prof. Barman in Bose Center Kolkata, we have performed
all-optical time-resolved magneto-optical Kerr microscope measurements and found that the anisotropic propagation of spinwaves are tunable by arranging different symmetries in the form of artificial ferromagnetic nanodot lattices. The observations
are important for further development in magnonic crystal based devices.
1.

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2.

Configurational anisotropic spin waves in cross-shaped Ni80Fe20 nanoelements: B. K. Mahato, B. Rana, R. Mandal, D.
Kumar, S. Barman, Y. Fukuma, Y. Otani and A. Barman, Appl. Phys. Lett. 102 (2013) 192402.

3.

Impact of interface properties on spin accumulation in dual-injection lateral spin valves: H. Idzuchi, S. Karube, Y.
Fukuma, T. Aoki and Y. Otani, Appl. Phys. Lett. 103 (2013) 162403.

4.

Spin injection properties in trilayer graphene lateral spin valves: Y. P. Liu, H. Idzuchi, Y. Fukuma, O. Rousseau, Y. Otani
and W. S. Lew, Appl. Phys. Lett. 102 (2013) 033105.

5.

Tunable Magnonic Spectra in Two-Dimensional Magnonic Crystals with Variable Lattice Symmetry: S. Saha, R.
Mandal, S. Barman, D. Kumar, B. Rana, Y. Fukuma, S. Sugimoto, Y. Otani and A. Barman, Adv. Funct. Mater. 23(2013) 2378.

6.

5d iridium oxide as a material for spin-current detection: K. Fujiwara, Y. Fukuma, J. Matsuno, H. Idzuchi, Y. Niimi, Y.
Otani and H. Takagi, Nat. Commun. 4 (2013) 3893.

7.

Propagation of nonlinearly generated harmonic spin waves in microscopic stripes: O. Rousseau, M. Yamada, K. Miura,
S. Ogawa and Y. Otani, J. Appl. Phys. 115 (2014) 053914.

8.

Effect of anisotropic spin absorption on the Hanle effect in lateral spin valves: H. Idzuchi, Y. Fukuma, S. Takahashi, S.
Maekawa and Y. Otani, Phys. Rev. B 89 (2014) 081308(R).

9.

Extrinsic spin Hall effects measured with lateral spin valve structures: Y. Niimi, H. Suzuki, Y. Kawanishi, Y. Omori, T.
Valet, A. Fert and Y. Otani, Phys. Rev. B 89 (2014) 054401.

Experimental Verification of Comparability between Spin-Orbit and Spin-Diffusion Lengths: Y. Niimi, D. Wei, H.
Idzuchi, T. Wakamura, T. Kato and Y. Otani, Phys. Rev. Lett. 110 (2013) 016805.

10. Spin Injection into a Superconductor with Strong Spin-Orbit Coupling: T. Wakamura, N. Hasegawa, K. Ohnishi, Y.
Niimi and Y. Otani, Phys. Rev. Lett. 112 (2014) 036602.

ISSP Activity Report 2013133

Komori group
Electronic structures of Pt-induced nanowires on the Ge(001) surface were studied by ARPES. Two one-dimensional (1D)
metallic surface bands are clearly identified at temperatures much lower than its structural transition temperature. This 1D
system exhibits neither Peierls instability nor Luttinger liquid behaviors. The elastic-scattering vectors within the topological surface state (TSS) of a topological insulator Bi1.5Sb0.5Te1.7Se1.3 were studied using quasiparticle interference patterns
measured by STM. The results are compared by the surface band obtained using time-resolved ARPES. The scattering in the
TSS is effectively prohibited in a wide angular range of 100-180°.
——
1. Selective doping in a surface band and atomic structures of the Ge(111) (√ 3 × √ 3 ) R30º–Au surface: K. Nakatsuji, Y.
Motomura, R. Niikura and F. Komori, J. Phys.: Condens. Matter 25 (2013) 045007 (9).
2.

Fabrication and characterization of strain-driven self-assembled CrN nanoislands on Cu(001): P. Krukowski, T. Iimori,K. Nakatsuji, M. Yamada and F. Komori, J. Appl. Phys. 113 (2013) 174309 (5).

3.

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Growth and structure of CrN nanoislands on Cu(001) studied by scanning tunneling microscopy and X-ray photoemission spectroscopy: P. Krukowski, T. Iimori, K. Nakatsuji, M. Yamada and F. Komori, Thin Solid Films 531 (2013)251-254.

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Fermi gas behavior of a one-dimensional metallic band of Pt-induced nanowires on Ge(001): K. Yaji, I. Mochizuki, S.
Kim, Y. Takeichi, A. Harasawa, Y. Ohtsubo, P. Le Fevre, F. Bertran, A. Taleb-Ibrahimi, A. Kakizaki and F. Komori, Phys.
Rev. B 87 (2013) 241413R (5).
Graphene nanoribbons on vicinal SiC surfaces by molecular beam epitaxy: T. Kajiwara, Y. Nakamori, A. Visikovskiy,
T. Iimori, F. Komori, K. Nakatsuji, K. Mase and S. Tanaka, Phys. Rev. B 87 (2013) 121407R (1-4).

Systematic study of surface magnetism in Si(111)-Fe system grown by solid phase epitaxy: In situ schematic magnetic
phase diagram of Si(111)-Fe: A. N. Hattori, K. Hattori, K. Kataoka, E. Takematsu, A. Ishii, F. Komori and H. Daimon, J.
Magn. Magn. Mater. 363 (2014) 158-165.
Robust Protection from Backscattering in the Topological Insulator Bi1.5Sb0.5Te1.7Se1.3: S. Kim, S. Yoshizawa, Y.
Ishida, K. Eto, K. Segawa, Y. Ando, S. Shin and F. Komori, Phys. Rev. Lett. 112 (2014) 136802(1-5).
Observing hot carrier distribution in an n-type epitaxial graphene on a SiC substrate: T. Someya, H. Fukidome,
Y. Ishida, R. Yoshida, T. Iimori, R. Yukawa, K. Akikubo, Sh. Yamamoto, S. Yamamoto, T. Yamamoto, T. Kanai, K.
Funakubo, M. Suemitsu, J. Itatani, F. Komori, S. Shin and I. Matsuda, Appl. Phys. Lett. 104 (2014) 161103(1-4).
Scanning tunneling microscopic and spectroscopic studies on a crystalline silica monolayer epitaxially formedon hexagonal SiC(000-1) surfaces: H. Tochihara, T. Shirasawa, T. Suzuki, T. Miyamachi, T. Kajiwara, K. Yagyu, S.
Yoshizawa, T. Takahashi, S. Tanaka and F. Komori, Appl. Phys. Lett. 104 (2014) 051601(1-4).

10. エピタキシャルグラフェンの電子状態 : 中辻 寛 , 小森 文夫 ,「ポストシリコン半導体 - ナノ成膜ダイナミクスと基板・界面効果 -」, ６章２．
２, 財満 鎮明 , (NTS, 東京都文京区湯島 2-16-16, 2013), 334-345.

Yoshinobu group
We conducted several research projects in the fiscal year 2013. (1) The adsorption and activation of CO2 on Cu(997) studied
by SR-PES and IRAS. (2) The adsorption and decomposition of formic acid on Cu(111) studied by SR-PES and IRAS. (3)Spectroscopic characterization and transport properties of the Si(111) native oxide surface with tetrafluorotetracyanoquinodimethane. (4) Electronic structure of alufa-sexithiophene ultra thin films grown on passivated Si(001) surfaces.
1.

Energy level alignment of cyclohexane on Rh(111): the importance of interfacial dipole and final-state screening: T.
Koitaya, K. Mukai, S. Yoshimoto and J. Yoshinobu, J. Chem. Phys. 138 (2013) 044702 (9 pages).

2.

巻頭言「君たちは何のために研究するのか？」: 吉信 淳 , 表面科学 34 (2013) 403.

3.

Site-specific chemical states of adsorbed CO on Pt(997): a high resolution XPS study: S. Shimizu, H. Noritake, T.
Koitaya, K. Mukai, S. Yoshimoto and J. Yoshinobu, Surf. Sci. 608 (2013) 220-225.

4.

Spectroscopic Characterization and Transport Properties of Aromatic Monolayers Covalently Attached to Si(111)
Surfaces: Y. Harada, T. Koitaya, K. Mukai, S. Yoshimoto and J. Yoshinobu, J. Phys. Chem. C 117 (2013) 7497-7505.

5.

Quantitative analysis of chemical interaction and doping of the Si(111) native oxide surface with tetrafluorotetracyanoquinodimethane: S. Yoshimoto, M. Furuhashi, T. Koitaya, Y. Shiozawa, K. Fujimaki, Y. Harada, K. Mukai and J. Yoshinobu, J. Appl. Phys. 115 (2014) 143709.

134

ISSP Activity Report 2013

6.

†

7.

Aqueous-Phase Oxidation of Epitaxial Graphene on the Silicon Face of SiC(0001): Md. Zakir Hossain, M. B. A. Razak,
S. Yoshimoto, K. Mukai, T. Koitaya, J. Yoshinobu, H. Sone, S. Hosaka and M. C. Hersam, J. Phys. Chem. C 118 (2014)
1014.

8.

Structure and Photo-Induced Charge Transfer of Pyridine Molecules Adsorbed on TiO2(110): A NEXAFS and CoreHole-Clock Study: H. Kondoh, Y. Higashi, M. Yoshida, Y. Monya, R. Toyoshima, K. Mase, K. Amemiya, F. Tsukioka,
M. Nagasaka, Y. Iwasawa, H. Orita, K. Mukai and J. Yoshinobu, Electrochemistry 82 (2014) 341.

9.

Interface state and energy level alignment of F4-TCNQ sandwiched between a pentacene film and the ethyleneterminated Si(100) surface: S. Yoshimoto, K. Kameshima, T. Koitaya, Y. Harada, K. Mukai and J. Yoshinobu, Organic
Electronics 15 (2014) 356.

Electronic structure of α-sexithiophene ultrathin films grown on passivated Si(001) surfaces: K. Hiraga, H. Toyoshima,
H. Tanaka, K. Inoue, S. Ohno, K. Mukai, J. Yoshinobu and M. Tanaka, Appl. Surf. Sci. 307 (2014) 520.

10. 淡青評論「東京大学憲章を読んでみませんか」: 吉信 淳 , 学内広報 1450 (2014) 12.
11. 「現代ケイ素化学 - 体系的な基礎概念と応用に向けて」のうち第 24 章「ケイ素単結晶表面の修飾」（p.377-p.388）．:
吉良 満夫 , 玉尾皓平 ( 編集 ), 吉信淳（部分執筆）, ( 化学同人 , 京都市 , 2013).
12. 絶対微小 日常生活を量子論で理解する : マイケ ル・D・フェイヤー著 , 丑田 公規 , 吉信淳 訳 , ( 化学同人 ,Kyoto, 2013).
13. 「水素の事典」のうち 5 章 1-a（p.86-p.89）を分担執筆．: 水素エ ネルギー協会編 , ( 朝倉書店 , 東京 , 2014).

Hasegawa group
We studied the superconducting proximity effect in real space by using low-temperature scanning tunneling microscopy andspectroscopy aiming at the observation of peculiar superconducting states, such as Fulde–Ferrell–Larkin–Ovchinnikov (FFLO)
states and odd-frequency superconductivity. So far, we observed the spatial distribution of superconductivity around an interface between Pb islands and a two-dimensional (2D) diffusive normal metal, and found that the surface steps in the 2D normal
metal working as a potential barrier exhibit a significant role on the proximity effect; through the real-space mapping of superconductivity in nano-meter spatial resolution, we observed the steps blocking the propagation of the proximity and enhancing it
in confined area between the steps and the super/normal interface. The enhancement is explained with reflectionless tunneling,
quantum interference phenomenon between the incident electrons and retro-reflected holes formed by the Andreev reflection at
the interface. On a 2D surface superconductor, which can be formed by depositing 1 monolayer In or Pb on Si(111) substrate,
we also observed Josephson vortices at the step edges, indicating weakened superconductivity there.
1.

Trapping and squeezing of vortices in voids directly observed by scanning tunneling microscopy and spectroscopy: T.
Tominaga, T. Sakamoto, H. Kim, T. Nishio, T. Eguchi and Y. Hasegawa, Phys. Rev. B 87 (2013) 195434.

2.

†

Microscopic origin of the π states in epitaxial silicene: A. Fleurence, Y. Yoshida, C. -C. Lee, T. Ozaki, Y. YamadaTakamura and Y. Hasegawa, Appl. Phys. Lett. 104 (2014) 021605 (4 pages).

Lippmaa group
High-temperature growth studies of magnetite Fe3O4 showed that it is possible to fabricate self-organized arrays of strainfree and uniformly oriented nanoscale pyramids. We hope to use such nanopyramid arrays for studying the multiferroic
coupling in magnetite. Nanoscale composite materials based on a ferromagnetic spinel, CoFe2O4 and a ferroelectric perovskite,
Bi5Ti3FeO15 were characterized in collaboration with our joint-use partners. Saturation magnetism and spin dilution was studied
in Pr0.8Ca0.2MnO3 to develop a suitably weak ferromagnet for use in superconductor - ferromagnet tunnel junctions. Workproceeded on the development of light-element oxide films with the mapping of the growth mechanisms of BeO.
1.

Nonmagnetic Sc Substitution in a Perovskite Ferromagnetic Insulator Pr0.8Ca0.2MnO3: T. Harada, R. Takahashi and M.
Lippmaa, J. Phys. Soc. Jpn. 82 (2013) 014801(1-5).

2.

Spectroscopic studies on the electronic and magnetic states of Co-doped perovskite manganite Pr0.8Ca0.2Mn1−yCoyO3
thin films: K. Yoshimatsu, H. Wadati, E. Sakai, T. Harada, Y. Takahashi, T. Harano, G. Shibata, K. Ishigami, T. Kadono,
T. Koide, T. Sugiyama, E. Ikenaga, H. Kumigashira, M. Lippmaa, M. Oshima and A. Fujimori, Phys. Rev. B 88 (2013)
174423.

3.

Epitaxial Bi5Ti3FeO15–CoFe2O4 Pillar–Matrix Multiferroic Nanostructures: A. Imai, X. Cheng, H. L. Xin, E. A. Eliseev,
A. N. Morozovska, S. V. Kalinin, R. Takahashi, M. Lippmaa, Y. Matsumoto and V. Nagarajan, ACS Nano 7 (2013)11079-11086.

ISSP Activity Report 2013

135

4.

Pulsed laser deposition of epitaxial BeO thin films on sapphire and SrTiO3: T. Peltier, R. Takahashi and M. Lippmaa,
Appl. Phys. Lett. 104 (2014) 231608(1-4).

5.

Spontaneous Growth of Strain-Free Magnetite Nanocrystals via Temperature-Driven Dewetting: R. Takahashi, H.
Misumi, T. Yamamoto and M. Lippmaa, Crystal Growth & Design 14 (2014) 1264-1271.

6.

Combinatorial Nanoscience and Technology for Solid-state Materials: H. Koinuma, R. Takahashi, M. Lippmaa, S.-Y.
Jeong, Y. Matsumoto, T. Chikyo and S. Suzuki, in: Handbook of Advanced Ceramics, Ch 11.1.11, edited by S. Somiya,(Academic Press, Amsterdam, 2013), 1103-1124.

Division of Physics in Extreme Conditions
Uwatoko group
The present antiferromagnetic state TN=7.5 K of EuBi3 with the AuCu3-type cubic structure is found to be stable underpressures up to 8 GPa, where the Neel temperature increases with increasing pressure, being TN=16.5 K at 8 GPa. We havestudied the effect of pressure on the superconducting transition temperature of YFe4P12 and LaFe4P12 up to 8 GPa throughelectrical resistivity measurements in a cubic anvil apparatus. TSC of both compounds increase to 9.3 K and 8.0 K withincreasing pressure, but the slopes decreases gradually with increasing pressure, respectivily. In contrast, the TSC of YRu4P12
and LaRu4P12 monotonically decreases with pressure. The distinct pressure dependences of both TSC cannot be explained solely
from a structural point of view. The pressure dependence of the electrical resistivity of BaCo2As2 single crystal as a functionof temperature was measured up to 8 GPa. A hybrid-type piston-cylinder pressure cell for the electron spin resonance (ESR)
measurement has been developed that the pressure reaches 2.1 GPa. The cylinder of this pressure cell consists of a NiCrAl
inner cylinder and a CuBe outer sleeve, and all inner parts are made of zirconium oxide which has good transmittance to themillimeter and submillimeter waves. We have also developed a transmission-type high-field ESR system having two different
modulation methods for this pressure cell.
1.

†

2.

Change in Unusual Magnetic Properties by Rh Substitution in CeRu2Al10: R. Kobayashi, Y. Ogane, D. Hirai, T.
Nishioka, M. Matsumura, Y. Kawamura, K. Matsubayashi, Y. Uwatoko, H. Tanida and M. Sera, J. Phys. Soc. Jpn. 82(2013) 093702(1-5).

3.

†

4.

†

5.

Microscopic Evidence of a Crossover to a Low-Temperature Intermediate Valence State in YbCo2Zn20: T. Mito, H.
Hara, T. Ishida, K. Nakagawara, T. Koyama, K. Ueda, T. Kohara, K. Ishida, K. Matsubayashi, Y. Saiga and Y. Uwatoko,
J. Phys. Soc. Jpn. 82 (2013) 103704 (1-4).

6.

†

7.

†

8.

†

9.

Dielectric properties of single crystal spinels in the series FeV2O4, MnV2O4, and CoV2O4 in high magnetic fields: A.
Kismarahadja, J. S. Brooks, H. D. Zhou, E. S. Choi, K. Matsubayashi and Y. Uwatoko, Phys. Rev. B 87 (2013) 054432(1-10).

136

AC Susceptibility of the Dipolar Spin Ice Dy2Ti2O7: Experiments and Monte Carlo Simulations: H. Takatsu, K. Goto,
H. Otsuka, R. Higashinaka, K. Matsubayashi, Y. Uwaoko and H. Kadowaki, J. Phys. Soc. Jpn. 82 (2013) 104710(1-5).

Fermi Surface and Magnetic Properties of Antiferromagnet EuBi3: A. Nakamura, Y. Hiranaka, M. Hedo, T. Nakama, Y.
Tatetsu, T. Maehira, Y. Miura, A. Mori, H. Tsutsumi, Y. Hirose, K. Mitamura, K. Sugiyama, M. Hagiwara, F. Honda, T.
Takeuchi, Y. Haga, K. Matsubayashi, Y. Uwatoko and Y. Onuki, J. Phys. Soc. Jpn. 82 (2013) 124708(1-6).

Magnetic and Fermi Surface Properties of EuGa4: A. Nakamura, Y. Hiranaka, M. Hedo, T. Nakama, Y. Miura, H.
Tsutsumi, A. Mori, K. Ishida, K. Mitamura, Y. Hirose, K. Sugiyama, F. Homda, R. Settai, T. Takeuchi, M. Hagiwara,
T. D. Matsuda, E. Yamamoto, Y. Haga, K. Matsubayashi, Y. Uwatoko, H. Harima and Y. Onuki, J. Phys. Soc. Jpn. 82(2013) 104703 (1-10).

Pressure and Substitution Effects on Transport and Magnetic Properties of Y1-xRxCo2 Systems with Static Magnetic
Disorder: M. Takeda, A. Teruya, S. Watanabe, S. Hirakawa, Y. Hiranaka, A. Nakamura, Y. Takaesu, K. Uchima, M.
Hedo, T. Nakama, K. Yagasaki, K. Matsubayashi, Y. Uwatoko and A. T. Burkov, J. Phys. Soc. Jpn. 82 (2013) 014708(1-6).
Two-Dimensional Monopole Dynamics in the Dipolar Spin Ice Dy2Ti2O7: H. Takatau, K. Goto, H. Otsuka, R. Higashinaka, K. Matsubayashi, Y. Uwatoko and H. Kadowaki, J. Phys. Soc. Jpn. 82 (2013) 073707(1-5).
Magnetic properties of spinel CuCrZrS4 under pressure: M. Ito, N. Kado, K. Matsubayashi, Y. Uwatoko, N. Terada, S.
Ebisu and S. Nagata, J. Magn. Magn. Mater. 331 (2013) 98-101.

ISSP Activity Report 2013

10. High-pressure synthesis of the BaIrO3 perovskite: A Pauli paramagnetic metal with a Fermi liquid ground state: J. G.
Cheng, T. Ishii, H. Kojitani, K. Matsubayashi, A. Matsuo, X. Li, Y. Shirako, J. S. Zhou, J. B. Goodenough, C. Q. Jin, M.
Akaogi and Y. Uwatoko, Phys. Rev. B 88 (2013) 205114(1-7).
11. Pressure dependence of the superconducting transition temperature of the filled skutterudite YFe4P12: J. G. Cheng, J.
S. Jhou, K. Matsubayashi, P. P. Kong, Y. Kubo, Y. Kawamura, C. Sekine, C. Q. Jin, J. B. Goodenough and Y. Uwatoko,
Phys. Rev. B 88 (2013) 024514(1-8).
†

12. Development of a Low-Temperature Insert for Precise Magnetization Measurement below T = 2 K with a Superconducting Quantum Interference Device Magnetometer: Y. Sato, S. Makiyama, Y. Sakamoto, T. Hasuo, Y. Inagaki, T.
Fujiwara, H. S. Suzuki, K. Matsubayashi, Y. Uwatoko and T. Kawae, Jpn. J. Appl. Phys. 52 (2013) 106702 (1-6).
13. Possible Kondo Physics near a Metal-Insulator Crossover in the A-Site Ordered Perovskite CaCu3Ir4O12: J. G. Cheng,
J. S. Zhou, Y. F. Yang, H. D. Zhou, K. Matsubayashi, Y. Uwatoko, A. MacDonald and J. B. Goodnough, Phys. Rev. Lett.
111 (2013) 176403(1-5).
14.

†*High Field Magnetization of TbPd2Ge2 Single Crystal: T. Shigeoka, T. Hasegawa, T. Fujiwara, A. Kondo, K. Kindo
and Y. Uwatoko, J. Low Temp. Phys. 170 (2013) 248-254.

†

15. Magnetic penetration depth and flux-flow resistivity measurements on NaFe0.97Co0.03As single crystals: T. Okada, H.
Takahashi, Y. Imai, K. Kitagawa, K. Matsubayashi, Y. Uwatoko and A. Maeda, Physica C 494 (2013) 109-112.
*

16. Hydrostatic pressure (8GPa) dependence of electrical resistivity of BaCo2As2 single crystal: C. Ganguli, K. Matsubayashi, K. Ohgushi, Y. Uwatoko, M. Kanagaraj and S. Arumugam, Mat. Res. Bull. 48 (2013) 4329-4331.
†

17. Magnetic and Structural Properties of Mn1.8Co0.2Sb under High Magnetic Fields: H. Orihashi, M. Hiroi, Y. Mitsui, K.
Takahashi, K. Watanabe, K. Matsubayashi, Y. Uwatoko and K. Koyama, Mater. Trans. 54 (2013) 969-973.
†

18. Low energy excitations inside the vortex core of LiFe(As, P) single crystals investigated by microwave-surface impedance: T. Okada, H. Takahashi, Y. Imai, K. Kitagawa, K. Matsubayashi, Y. Uwatoko and A. Maeda, Physica C: Superconductivity 484 (2013) 27.
†

19. Development of Hybrid-Type Pressure Cell for High-Pressure and High-Field ESR Measurement: K. Fujimoto, T.
Sakurai, S. Okubo, H. Ohta, K. Matsubayashi, Y. Uwatoko and Y. Koike, Applied Magnetic Resonance 44 (2013)893-898.
†

20. Magnetic properties of Mn2Sb1-xGex(0.05 ≤ｘ≤0.2) in high magnetic fields: D. Shimada, H. Orihashi, D. Mitsunaga, M.
Ito, M. Hiroi, K. Koyama, R. Onodera, K. Takahashi, K. Matsubayashi and Y. Uwatoko, J. Kor. Phys. Soc. 63 (2013)743-746.
†

21. Phase diagram and transport properties of Y1−xNdxCo2 pseudo-binary alloys: A. T. Burkov, M. Takeda, A. Teruya, S.
Watanabe, S. Hirakawa, Y. Hiranaka, A. Nakamura, M. Hedo, T. Nakama, K. Yagasaki, Y. Takaesu, K. Uchima and Y.
Uwatoko, J. Kor. Phys. Soc. 62 (2013) 2080-2083.
†

22. Successive magnetic transitions of PrRh2 single crystals: Y. Okawara, J. W. Cui, T. Fujiwara, T. Shigeoka, K. Matsubayashi, Y. Uwatoko, S. Kimura and K. Watanabe, J. Kor. Phys. Soc. 63 (2013) 743-746.
23. Pressure Effect on the Structure and Superconducting Transition Temperature of Filled Skutterudites LaT4P12 (T=Fe,
Ru): Y. Kawamura, T. Kawaai, J. Hayashi, C. Sekine, H. Gotou, J. Cheng, K. Matsubayashi and Y. Uwatoko, J. Phys.
Soc. jpn. 82 (2013) 114702(1-4).
†

24. Development of High-Field ESR System Using SQUID Magnetometer and its Application to Measurement under High
Pressure: T. Sakurai, K. Fujimoto, S. Okubo, H. Ohata and Y. Uwatoko, Journal of Magnetics 18 (2013) 168-172.
*

25. High-pressure effects in anti-post-perovskite superconductors V3PnNx (Pn = P, As): B. S. Wang, J. -G. Cheng, K.
Matsubayashi, Y. Uwatoko and K. Ohgushi, Phys. Rev. B 89 (2014) 144510 (1-4).
26. Long-range antiferromagnetic order in the frustrated XY pyrochlore antiferromagnet Er2Ge2O7: X. Li, W. M. Li, K.
Matsubayashi, Y. Sato, C. Q. Jin, Y. Uwatoko, T. Kawae, A. M. Hallas, C. R. Wiebe, A. M. Arevalo-Lopez, J. P. Attfield,
J. S. Gardner, R. S. Freitas, H. D. Zhou and J. -G. Cheng, Phys. Rev. B 89 (2014) 064409 (1-7).
†

27. Magnetic Field Effect on Magnetic and Electrical Properties ofMn2-xCuxSb: Y. Matsumoto, H. Orihashi, K. Matsubayashi, Y. Uwatoko, M. Hiroi and K. Koyama, IEEE Transactions on Magnetics 50 (2014) 1000704(1-4).
*

28. Heavy fermion superconductivity under pressure in the quadrupole system PrTi2Al20: K. Matsubayashi, T. Tanaka, J.
Suzuki, A. Sakai, S. Nakatsuji, K. Kitagawa, Y. Kubo and Y. Uwatoko, J. Phys. Soc. Jpn. (2014), in print.

ISSP Activity Report 2013137

Osada group
In an organic Dirac fermion system α-(BEDT-TTF)2I3, the ν=0 quantum Hall state is realized under magnetic fields resulting
from the breaking of four-fold (spin and valley) degeneracy of the singular n=0 Landau level.. The recent NMR measurement
has suggested the possible transition from the quantum Hall ferromagnetic (QHF) phase to the quantum Hall insulator (QHI)
phase around 15 T. To check this possibility, we have performed high-field transport measurement up to 31T using the NHMFL
at Tallahassee, USA. The interlayer resistance shows the saturating behavior up to high fields, which reflects the surface transport via helical edge state of the QHF phase. We can see no anomaly in the saturating region, especially around 15T. This resultmeans that the QHF state survives up to 31T with no QHF-QHI transition.

1.

Angle-Dependent Magnetoresistance Oscillations and Charge Density Wave in the Organic Conductor α-(BEDTTTF)2KHg(SCN)4: K. Uchida, R. Yamaguchi, T. Konoike, T. Osada and W. Kang, J. Phys. Soc. Jpn. 82 (2013)
043714(1-4).

2.

Anomalous Thermoelectric Transport and Giant Nernst Effect in Multilayered Massless Dirac Fermion System: T.
Konoike, M. Sato, K. Uchida and T. Osada, J. Phys. Soc. Jpn. 82 (2013) 073601(1-4).

3.

†

4.

強磁場下電気伝導に現れるサイクロトロン共鳴 : 長田 俊人 , 熊谷 篤 , 内田 和人 , 鴻池 貴子 , 固体物理 48 (2013)65-73.

5.

角度依存シュタルクサイクロトロン共鳴とその応用 : 鴻池 貴子 , パリティ 28(4) (2013) 42-45.

6.

角度依存シュタルクサイクロトロン共鳴法の開発 : 長田 俊人 , パリティ 28(1) (2013) 20-23.

7.

有機ディラック電子系における量子ホール状態 : 田嶋 尚也 , 佐藤 光幸 , 鴻池 貴子 , 長田 俊人 , 固体物理 49(2014) 229-240.

Stereoscopic study of the angle-dependent magnetoresistance oscillations across the charge-density-wave transitionof the organic conductor α-(BEDT-TTF)2KHg(SCN)4: W. Kang, T. Osada, T. Konoike and K. Uchida, Phys. Rev. B 88
(2013) 195105(1-9).

Yamashita group
As the first year of Yamashita group, we developed a new probe for thermal-Hall measurement which can be used in VTI systemwith 16 T magnet. With this probe, we successfully started the study of thermal-transport measurement of a kagom&eacute;material, Volborthite, to find if there is a thermal-Hall effect due to spinons. Developments of the measurement systems forstudies under ultra-low temperatures, on the other hand, did not work out due to malfunctions of dilution refrigerators inheritedfrom Ishimoto and Tajima groups.

Materials Design and Characterization Laboratory
Hiroi group
Spinodal decomposition is a ubiquitous phenomenon leading to phase separation from a uniform solution. We show that aspinodal decomposition occurs in a unique combination of two rutile compounds of TiO2 and VO2, which are chemically andphysically distinguished from each other: TiO2 is a wide-gap insulator with photo catalytic activities and VO2 is assumed to bea strongly correlated electron system which exhibits a dramatic metal-insulator transition at 342 K. The spinodal decomposition
takes place below 830 K at a critical composition of 34 mol% Ti, generates a unidirectional composition modulation along thec axis with a wavelength of approximately 6 nm, and finally results in the formation of self-assembled lamella structures madeup of Ti-rich and V-rich layers stacked alternately with 30-50 nm wavelengths. A metal-insulator transition is not observed inquenched solid solutions with intermediate compositions but emerges in the thin V-rich layers as the result of phase separation.
Interestingly, the metal-insulator transition remains as sharp as in pure VO2 even in such thin layers and takes place at significantly reduced temperatures of 310-340 K, which is probably due to a large misfit strain induced by lattice matching at thecoherent interface.
1.

*

2.

Magnetic Properties of the Spin-1/2 Deformed Kagome Antiferromagnet Edwardsite: H. Ishikawa, Y. Okamoto and Z.
Hiroi, J. Phys. Soc. Jpn. 82 (2013) 063710.

138

Magnetic Order in the Spin-1/2 Kagome Antiferromagnet Vesignieite: M. Yoshida, Y. Okamoto, M. Takigawa and Z.
Hiroi, J. Phys. Soc. Jpn. 82 (2013) 013702(1-5).

ISSP Activity Report 2013

3.

Pressure Effects on Rattling and Superconductivity in the Einstein Solids: Y. Ikeda, Y. Kawasaki, T. Shinohara, S. Araki,
T. C. Kobayashi, A. Onosaka, Y. Okamoto, J.-I. Yamaura and Z. Hiroi, J. Phys. Soc. Jpn. 82 (2013) 063707.

4.

Understanding of the Temperature–Pressure Phase Diagram of β-Pyrochlore Oxides: A Role of Anhamonicity on Superconductivity: T. Isono, D. Iguchi, T. Matsubara, Y. Machida, B. Salce, J. Flouquet, H. Ogusu, J.-I. Yamaura, Z. Hiroi andK. Izawa, J. Phys. Soc. Jpn. 82 (2013) 114708.

5.

YCr6Ge6 as a Candidate Compound for a Kagome Metal: Y. Ishii, H. Harima, Y. Okamoto, J.-I. Yamaura and Z. Hiroi, J.
Phys. Soc. Jpn. 82 (2013) 023705(1-4).

6.

Breathing Pyrochlore Lattice Realized in A-Site Ordered Spinel Oxides LiGaCr4O8 and LiInCr4O8: Y. Okamoto, G. J.
Nilsen, J. Paul Attfield and Z. Hiroi, Phys. Rev. Lett. 110 (2013) 097203(1-5).

7.

*

8.

*

9.

†*

10.

†*

5d 遷移金属パイロクロア酸化物における低温磁気構造の研究 : 山浦 淳一 , 大串 研也 , 広井 善二 , 日本結晶学会誌 55 (2013) 116-120.
Spinodal Decomposition in the TiO2–VO2 System: Z. Hiroi, H. Hayamizu, T. Yoshida, Y. Muraoka, Y. Okamoto, J.-I.
Yamaura and Y. Ueda, Chem. Mater. 25 (2013) 2202.
Iseite, Mn2Mo3O8, a new mineral from Ise, Mie Prefecture, Japan: D. Nishio-Hamane, N. Tomita, T. Minakawa and S.
Inaba, Journal of Mineralogical and Petrological Sciences 108 (2013) 37-41.
Synthesis of LiNi0.5Mn1.5O4 and 0.5Li2MnO3–0.5LiNi1/3Co1/3Mn1/3O2 hollow nanowires by electrospinning: E.
Hosono, T. Saito, J. Hoshino, Y. Mizuno, M. Okubo, D. Asakura, K. Kagesawa, D. Nishio-Hamane, T. Kudo and H.
Zhou, CrystEngComm 15 (2013) 2592-2597.

*

11. Electronic State of CeFe4As12 Investigated by Using Single Crystals Grown under High Pressure of 4 GPa: Y. Ogawa,
H. Sato, M. Watanabe, T. Namiki, S. Tatsuoka, R. Higashinaka, Y. Aoki, K. Kuwahara, J.-I. Yamaura and Z. Hiroi, J.
Phys. Soc. Jpn. 83 (2014) 034710.
*

12. Kagome–Triangular Lattice Antiferromagnet NaBa2Mn3F11: H. Ishikawa, T. Okubo, Y. Okamoto and Z. Hiroi, J. Phys.
Soc. Jpn. 83 (2014) 043703(1-5).

Kawashima group
We have been investigating quantum spin/boson systems and frustrated systems by means of large-scale numerical simulation. We also develop new numerical techniques. Our group's achievements of 2013 include: (1) clarifying the apparent deconfined critical behavior of the SU(N) J-Q Heisenberg model with a strong corrections to scaling, (2) lattice rotational symmetry
breaking in flustrated spin systems, and (3) highly parallelized code for the molecular dynamics simulation of mixed-phase fluid
dynamics.
1.

Mott Transition of Bose–Fermi Mixtures in Optical Lattices Induced by Attractive Interactions: A. Masaki and H. Mori,
J. Phys. Soc. Jpn. 82 (2013) 074002(1-4).

2.

*

3.

Second-order phase transition in the Heisenberg model on a triangular lattice with competing interactions: R. Tamura, S.
Tanaka and N. Kawashima, Phys. Rev. B 87 (2013) 214401(1-5).

4.

†*

5.

Visibility pattern of Bose–Fermi mixtures in one-dimensional incommensurate lattices: A. Masaki and H. Mori, Philosophical Magazine Letters 93 (2013) 422(9pages).

6.

Fermion-induced decoherence of bosons in optical lattices: A. Masaki and H. Mori, J. Phys.: Conf. Ser. 454 (2013)
012048(1-4).

7.

Huge-scale molecular dynamics simulation of multibubble nuclei: H. Watanabe, M. Suzuki and N. Ito, Computer
Physics Communications 184 (2013) 2775(8pages).

8.

*

Possibility of deconfined criticality in SU(N) Heisenberg models at small N: K. Harada, T. Suzuki, T. Okubo, H.
Matsuo, J. Lou, H. Watanabe, S. Todo and N. Kawashima, Phys. Rev. B 88 (2013) 220408(1-4).

Various regimes of quantum behavior in an S=1/2 Heisenberg antiferromagnetic chain with fourfold periodicity: H.
Yamaguchi, T. Okubo, K. Iwase, T. Ono, Y. Kono, S. Kittaka, T. Sakakibara, A. Matsuo, K. Kindo and Y. Hosokoshi,
Phys. Rev. B 88 (2013) 174410(1-5).

Kagome–Triangular Lattice Antiferromagnet NaBa2Mn3F11: H. Ishikawa, T. Okubo, Y. Okamoto and Z. Hiroi, J. Phys.
Soc. Jpn. 83 (2014) 043703(1-5).

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139

9.

Parallelized Quantum Monte Carlo Algorithm with Nonlocal Worm Updates: A. Masaki-Kato, T. Suzuki, K. Harada, S.
Todo and N. Kawashima, Phys. Rev. Lett. 112 (2014) 140603(1-5).

10. Phase Transitions with Discrete Symmetry Breaking in Antiferromagnetic Heisenberg Models on a Triangular Lattice:
R. Tamura, S. Tanaka and N. Kawashima, JPS Conf. Proc. --- Proceedings of the 12th Asia Pacific Physics Conference(APPC12) 1 (2014) 012125(1-5).

Noguchi group
We have studied the structure formation of surfactant membranes under shear flow. We found that shear can induce a rolledlamellae structure, which structure factor agrees with those of intermediate states during lamellar-to-onion transition measured
by time-resolved scatting experiments. We revealed that entropy reduction of membrane fluctuations can induce aggregation ofbinding proteins in multilamellar membranes. We also studied the effects of anchored polymers on membranes and dynamics ofdeformable active particles.
1.

Dynamics of a deformable active particle under shear flow: M. Tarama, A. M. Menzel, B. T. Hagen, R. Wittkowski, T.
Ohta and H. Loewen, J. Chem. Phys. 139 (2013) 104906.

2.

Spatiotemporal heterogeneity of local free volumes in highly supercooled liquid: H. Shiba and T. Kawasaki, J. Chem.
Phys. 139 (2013) 184502.

3.

Structure formation in binary mixtures of lipids and detergents: Self-assembly and vesicle division: H. Noguchi, J.
Chem. Phys. 138 (2013) 024907(1-9).

4.

Structure formation of surfactant membranes under shear flow: H. Shiba, H. Noguchi and G. Gompper, J. Chem. Phys.
139 (2013) 014702.

5.

Oscillatory motions of an active deformable particle: M. Tarama and T. Ohta, Phys. Rev. E 87 (2013) 062912.

6.

Mechanical properties and microdomain separation of fluid membranes with anchored polymers: H. Wu, H. Shiba and
H. Noguchi, Soft Matter 9 (2013) 9907.

7.

Effects of anchored flexible polymers on mechanical properties of model biomembranes: H. Wu and H. Noguchi, AIP
Conf. Proc. 1518 (2013) 649-653.

8.

Hierarchical heterogeneous glassy dynamics of configuration changes and vibration modes: T. Kawasaki, H. Shiba and
A. Onuk, AIP Conf. Proc. 1518 (2013) 784-791.

9.

Structure formation of lipid membranes: Membrane self-assembly and vesicle opening-up to octopus-like micelles: H.
Noguchi, AIP Conf. Proc. 1518 (2013) 566-570.

10. 脂質膜の構造形成の粗視化シミュレーション : 野口 博司 , 生物物理 53 (2013) 11-14.
11. Entropy-driven aggregation in multilamellar membranes: H. Noguchi, EPL 102 (2013) 68001.
12. 粒子描像の流体力学計算手法 I: 野口 博司 , 分子シミュレーション研究会会誌 “アンサンブル ” 15 (2013) 265-268.
13. Morphological variation of a lipid vesicle confined in a spherical vesicle: A. Sakashita, M. Imai and H. Noguchi, Phys.
Rev. E 89 (2014) 040701.
14. Multiscale modeling of blood flow: from single cells to blood rheology: D. A. Fedosov, H. Noguchi and G. Gompper,
Biomech. Model. Mechanobiol. 13 (2014) 239-258.
15. 界面活性剤系の構造形成の粗視化分子シミュレーション : 芝隼 人 , 野口 博司 , 分子シミュレーション研究会会誌“アンサンブル ” 16 (2014) 59-65.
16. 粒子描像の流体力学計算手法 II: 野口 博司 , 分子シミュレーション研究会会誌 “アンサンブル ” 16(2) (2014)
118-121.

Materials Synthesis and Characterization group
1.

140

†*

Iseite, Mn2Mo3O8, a new mineral from Ise, Mie Prefecture, Japan: D. Nishio-Hamane, N. Tomita, T. Minakawa and S.
Inaba, Journal of Mineralogical and Petrological Sciences 108 (2013) 37-41.

ISSP Activity Report 2013

2.

†

3.

†*

4.

†

5.

†

6.

Minohlite, a new copper-zinc sulfate mineral from Minoh, Osaka, Japan: M. Ohnishi, N. Shimobayashi, D. NishioHamane, K. Shinoda, K. Momma and T. Ikeda, Mineral. Mag. 77 (2013) 335.

7.

†

8.

*

9.

†

Takanawaite-(Y), a new mineral of the M-type polymorph with Y(Ta,Nb)O4 from Takanawa Mountain, Ehime Prefecture, Japan: D. Nishio-Hamane, T. Minakawa and Y. Ohgoshi, Journal of Mineralogical and Petrological Sciences 108(2013) 335.
Synthesis of LiNi0.5Mn1.5O4 and 0.5Li2MnO3–0.5LiNi1/3Co1/3Mn1/3O2 hollow nanowires by electrospinning: E.
Hosono, T. Saito, J. Hoshino, Y. Mizuno, M. Okubo, D. Asakura, K. Kagesawa, D. Nishio-Hamane, T. Kudo and H.
Zhou, CrystEngComm 15 (2013) 2592-2597.
VGCF-core@LiMn0.4Fe0.6PO4-sheath heterostructure nanowire for high rate Li-ion batteries: K. Kagesawa, E. Hosono,
M. Okubo, J. Kikkawa, D. Nishio-Hamane, T. Kudo and H. Zhou, CrystEngComm 15 (2013) 6638.
3+

Spin transition and substitution of Fe in Al-bearing post-Mg-perovskite: K. Fujino, D. Nishio-Hamane, Y.
Kuwayama, N. Sata, S. Murakami, M. Whitaker, A. Shinozaki, H. Ohfuji, Y. Kojima, T. Irifune, N. Hiraoka, H. Ishii andK.-D. Tsuei, Physics of the Earth and Planetary Interiors 217 (2013) 31.

Vanadoallanite-(La): a new epidote-supergroup mineral from Ise, Mie Prefecture, Japan: M. Nagashima, D. NishioHamane, N. Tomita, T. Minakawa and S. Inaba, Mineral. Mag. 77 (2013) 2739.
Electronic State of CeFe4As12 Investigated by Using Single Crystals Grown under High Pressure of 4 GPa: Y. Ogawa,
H. Sato, M. Watanabe, T. Namiki, S. Tatsuoka, R. Higashinaka, Y. Aoki, K. Kuwahara, J.-I. Yamaura and Z. Hiroi, J.
Phys. Soc. Jpn. 83 (2014) 034710.
Magnetic properties of Mn–Bi melt-spun ribbons: T. Saito, R. Nishimura and D. Nishio-Hamane, J. Magn. Magn.
Mater. 349 (2014) 9.

†

10. Successive phase transitions driven by orbital ordering and electron transfer in quasi-two-dimensional CrSe2 with atriangular lattice: S. Kobayashi, H. Ueda, D. Nishio-Hamane, C. Michioka and K. Yoshimura, Phys. Rev. B 89 (2014)054413.
11. Iwateite, Na2BaMn(PO4)2, a new mineral from the Tanohata mine, Iwate Prefecture, Japan: D. Nishio-Hamane, T.
Minakawa and H. Okada, Journal of Mineralogical and Petrological Sciences 109 (2014) 34.
†

12. Magnetic properties of SmCo5−xFex (x=0–4) melt-spun ribbon: T. Saito and D. Nishio-Hamane, J. Alloys Compd. 585(2014) 423.
†

13. Electrochemical properties of LiMnxFe1−xPO4 (x = 0, 0.2, 0.4, 0.6, 0.8 and 1.0)/vapor grown carbon fiber core–sheath
composite nanowire synthesized by electrospinning method: K. Kagesawa, E. Hosono, M. Okubo, D. Nishio-Hamane,
T. Kudo and H. Zhou, Journal of Power Sources 248 (2014) 615.
†

14. Electrically Conductive and Mechanically Elastic Titanium Nitride Ceramic Microsprings: S. Yang, X. Chen, K.
Yamamoto, M. Iitake, D. Nishio-Hamane, H. Sakai and M. Abe, J. Nanosci. Nanotech. 14 (2014) 4292.
†

15. Ultrafast hydrothermal synthesis of Pr-doped Ca0.6Sr0.4TiO3 red phosphor nanoparticles using corrosion resistantmicrofluidic devices with Ti-lined structure under high-temperature and high-pressure condition: K. Sue, T. Ono, Y.
Hakuta, H. Takashima, D. Nishio-Hamane, T. Sato, M. Ohara, M. Aoki, Y. Takebayashi, S. Yoda, T. Hiaki and T. Furuya,
Chemical Engineering Journal 239 (2014) 360.

Neutron Science Laboratory
Shibayama group
Shibayama group has been exploring the structure and dynamics of soft matter, especially polymer gels, micelles, and phenolic
resin, utilizing a combination of small-angle neutron scattering (SANS), neutron spin echo (NSE), and dynamic light scattering(DLS). The objectives are to elucidate the mysterious relationship between the structure and variety of novel properties/functions of polymer gels/resins. The highlights of 2012 include (1) structural analysis of high performance ion-gel comprising
tetra-PEG networks, (2) atomistic molecular dynamics study of cross-linked phenolic resins, (3) rubber elasticity for incomplete
polymer networks, (4) kinetic study for AB-type coupling reaction of tetra-arm polymers, (5) optimization of the thickness ofa ZnS/(LiF)-Li-6 scintillator for a high-resolution detector installed on a focusing small-angle neutron scattering spectrometer(SANS-U), and so on.
1.

Self-oscillating micelles: T. Ueki, M. Shibayama and R. Yoshida, Chem. Commun. 49 (2013) 6947.

ISSP Activity Report 2013

141

2.

Gelation process of Tetra-PEG ion-gel investigated by time-resolved dynamic light scattering: H. Asai, K. Nishi, T.
Hiroi, K. Fujii, T. Sakai and M. Shibayama, Polymer 54 (2013) 1160.

3.

Communication: Collective dynamics of room-temperature ionic liquids and their Li ion solutions studied by highresolution inelastic X-ray scattering: K. Fujii, M. Shibayama, T. Yamaguchi, K. Yoshida, T. Yamaguchi, S. Seki, H.
Uchiyama, A. Q. R. Baron and Y. Umebayashi, J. Chem. Phys. 138 (2013) 151101.

4.

Correlation between Local and Global Inhomogeneities of Chemical Gels: M. Asai, T. Katashima, U.-I. Chung, T. Sakai
and M. Shibayama, Macromolecules 46 (2013) 9772.

5.

SANS and DLS Study of Tacticity Effects on Hydrophobicity and Phase Separation of Poly(N -isopropylacrylamide):
K. Nishi, T. Hiroi, K. Hashimoto, K. Fujii, Y.-S. Han, T.-H. Kim, Y. Katsumoto and M. Shibayama, Macromolecules 46(2013) 6225.

6.

Solvation Structure of Poly(ethylene glycol) in Ionic Liquids Studied by High-energy X-ray Diffraction and Molecular
Dynamics Simulations: H. Asai, K. Fujii, K. Nishi, T. Sakai, K. Ohara, Y. Umebayashi and M. Shibayama, Macromolecules 46 (2013) 2369.

7.

Structural Study on the UCST-Type Phase Separation of Poly(N -isopropylacrylamide) in Ionic Liquid: H. Asai, K.
Fujii, T. Ueki, S. Sawamura, Y. Nakamura, Y. Kitazawa, M. Watanabe, Y.-S. Han, T.-H. Kim and M. Shibayama, Macromolecules 46 (2013) 1101.

8.

Br nsted Basicity of Solute Butylamine in an Aprotic Ionic Liquid Investigated by Potentiometric Titration: K. Fujii, K.
Hashimoto, T. Sakai, Y. Umebayashi and M. Shibayama, Chem. Lett. 42 (2013) 1250.

9.

Dynamic light scattering microscope: Accessing opaque samples with high spatial resolution: T. Hiroi and M.
Shibayama, Opt. Express 21 (2013) 20260.
13

10. Gelation and cross-link inhomogeneity of phenolic resins studied by C-NMR spectroscopy and small-angle X-ray
scattering: A. Izumi, T. Nakao and M. Shibayama, Soft Matter 9 (2013) 4188.
11. Specific Solvation of Benzyl Methacrylate in 1-Ethyl-3-methylimidazolium Bis(trifluoromethanesulfonyl)amide Ionic
Liquid: M. Matsugami, K. Fujii, T. Ueki, Y. Kitazawa, Y. Umebayashi, M. Watanabe and M. Shibayama, Anal. Sci. 29(2013) 311.
12. Acid–base property of protic ionic liquid, 1-alkylimidazolium bis(trifluoromethanesulfonyl)amide studied by potentiometric titration: K. Hashimoto, K. Fujii and M. Shibayama, Journal of Molecular Liquids 188 (2013) 143.
13. Small-Angle Neutron Scattering Study on Aggregation of 1-Alkyl-3-methylimidazolium Based Ionic Liquids in
Aqueous Solution: T. Kusano, K. Fujii, M. Tabata and M. Shibayama, J Solution Chem 42 (2013) 1888.
14. Multiscale Dynamics of Inhomogeneity-Free Polymer Gels: T. Hiroi, M. Ohl, T. Sakai and M. Shibayama, Macromolecules 47 (2014) 763.
15. Small-Angle Neutron Scattering Study on Defect-Controlled Polymer Networks: K. Nishi, H. Asai, K. Fujii, Y.-S. Han,
T.-H. Kim, T. Sakai and M. Shibayama, Macromolecules 47 (2014) 1801.
16. SANS および SAXS によるフェノール樹脂硬化物の構造解析 : 和泉 篤士 , 中尾 俊夫 , 岩瀬 裕希 , 柴山 充弘 , 波
紋 24 (2014) 11-14.
17. 中性子散乱を用いた構造解析手法(2014) 1-10.

概説とエラストマー・高分子ゲル解析への応用 : 柴山 充弘 , ゴム協会編

18. SANS studies on catalyst ink of fuel cell: M. Shibayama, T. Matsunaga, T. Kusano, K. Amemiya, N. Kobayashi and T.
Yoshida, J. Appl. Polym. Sci. 131 (2014) 1-7.
19. 中性子による材料評価・構造解析 : 柴山 充弘 , 表面科学 33 (2013) 258-263.
20. 小角 X 線散乱法によるフェノール樹脂ゲル化メカニズムの解析 : 和泉 篤士 , 中尾 俊夫 , 柴山 充弘 , ネットワーク
ポリマー 34 (2013) 330-335.
21. 溶液中での重水素化ノボラックのコンフォメーション : 和泉 篤士 , 中尾 俊夫 , 柴山 充弘 , ネットワークポリマー 33(2013) 204-208.
22. 水面をかけ抜けるには？ : 東 昭 , 柴山 充弘 , 増淵 雄一 , ニュートンプレス(2013) 90-95.

23. 中性子小角散乱を用いた分子集合体の解析 : 草野 巧巳 , 柴山 充弘 , Colloid & Interface Communication 39 (2014)16-18.

142

ISSP Activity Report 201324. Fabrication, Structure, Mechanical Properties, and Application of Tetra-PEG Hydrogels Oren Scherman and Xian Jun
Loh, Eds.: M. Shibayama and T. Sakai, in: Polymeric and Self Assembled Hydrogels: Fundamentals to Applications,
Chapt. 2, edited by RSC Publishing, (RSC Publishing, 2013), 2-38.
25. Computer simulation of network formation in natural rubber (NR): T. Nakao and S. Kohjiya, in: Chemistry, Manufacture and Applications of Natural Rubber, Kohjiya S. and Ikeda, Y. Eds., edited by S. Kohjiya and Y. Ikeda, (Woodhead,
Cambridge, UK, 2014), 216-246.

Yoshizawa groupA systematic study on spin dynamics in two-dimensional transition-metal oxides has been carried out with use of the highresolution chopper spectrometer installed at BL12 in the Material and Life Science Facility, J-PARC. In the highly hole-doped
region in the layered nickelate, it shows a checkerboard-type spin-charge ordering, and the nature of the excitation spectrachanges its character and approaches to the metal-like behavior. Spin fluctuations in several quantum spin systems were alsostudied.
1.

†*

2.

Structural and magnetic properties in the quantum S=1/2 dimer system Ba3(Cr1-xVx)2O8 with site disorder: T. Hong, L.
Y. Zhu, X. Ke, V. O. Garlea, Y. Qiu, Y. Nambu, H. Yoshizawa, M. Zhu, G. E. Granroth, A. T. Savici, Z. Gai and H. D.
Zhou, Phys. Rev. B 87 (2013) 144427(1-9).

3.

Magnetic structure of the conductive triangular-lattice antiferromagnet PdCrO2: H. Takatsu, G. Nénert, H. Kadowaki, H.
Yoshizawa, M. Enderle, S. Yonezawa, Y. Maeno, J. Kim, N. Tsuji, M. Takata, Y. Zhao, M. Green and C. Broholm, Phys.
Rev. B 89 (2014) 104408.

Long-range order and spin-liquid states of polycrystalline Tb2+xTi2−xO7+y: T. Taniguchi, H. Kadowaki, H. Takatsu, B.
Fåk, J. Ollivier, T. Yamazaki, T. J. Sato, H. Yoshizawa, Y. Shimura, T. Sakakibara, T. Hong, K. Goto, L. R. Yaraskavitch
and J. B. Kycia, Phys. Rev. B 87 (2013) 060408R(1-5).

Yamamuro group
Our laboratory is studying chemical physics of complex condensed matters by using neutron scattering, X-ray diffraction,
calorimetric, dielectric, and viscoelastic techniques. Our target materials are glasses, liquids, and various disordered systems.
This year, there were two important outcomes in the study of ionic liquids. The first one, which was found in the quasielastic
neutron scattering (QENS) and viscoelastic measurements, is that the inter-ionic motion is directly associated with the glasstransitions in imidazolium-bases ionic liquids. The second one is that the origin of the low-Q diffraction peak, which is atypical property of the ionic liquids, is a local structure similar to that of a liquid-crystalline (SmA) phase. This was obtained
from differential scanning calorimetry (DSC) and X-ray diffraction experiments. In the QENS study of a porous coordination
polymer MIL-53, we have found that protons are carried by both water and ammonia molecules which are more mobile thanthose in bulk states. Other than these topics, we have made some progresses in the studies on palladium hydrides and vapordeposited simple molecular glasses.
1.

Phase Transition and Dynamics of Water Confined in Hydroxyethyl Copper Rubeanate Hydrate: T. Yamada, T. Yamada,
M. Tyagi, M. Nagao, H. Kitagawa and O. Yamamuro, J. Phys. Soc. Jpn. 82 (2013) SA010 (8 pages).

2.

Hyperfine structure of magnetic excitations in a novel Tb based single molecule magnet studied by high-resolution
neutron spectroscopy: M. Kofu, T. Kajiwara, M. Nakano, K. Nakajima, S. Ohira-Kawamura, T. Kikuchi, Y. Inamura andO. Yamamuro, Phys. Rev. B 88 (2013) 064405 (7 pages).

3.

Heterogeneous Slow Dynamics of Imidazolium Based Ionic Liquids Studied by Neutron Spin Echo: M. Kofu, M.
Nagao, T. Ueki, Y. Kitazawa, Y. Nakamura, S. Sawamura, M. Watanabe and O. Yamamuro, J. Phys. Chem. B 117 (2013)2773-2781.

4.

Mode distribution analysis of quasi-elastic neutron scattering and application to liquid water: T. Kikuchi, K. Nakajima,
S. Ohira-Kawamura, Y. Inamura, O. Yamamuro, M. Kofu, Y. Kawakita, K. Suzuya, M. Nakamura and M. Arai, Phys.
Rev. E 87 (2013) 062314 (8 pages).

5.

Magnetic relaxations in a Tb-based single molecule magnet studied by quasielastic neutron scattering: M. Kofu, T.
Kajiwara, J. S. Gardner, G. G. Simeoni, M. Tyagi, K. Nakajima, S. Ohira-Kawamura, M. Nakano and O. Yamamuro,Chem. Phys. 427 (2013) 147-152.

6.

Linear trinuclear Zn(II)–Ce(III)–Zn(II) complex which behaves as a single-molecule magnet: S. Hino, M. Maeda, K.
Yamashita, Y. Kataoka, M. Nakano, T. Yamamura, H. Nojiri, M. Kofu, O. Yamamuro and T. Kajiwara, Dalton Trans. 42(2013) 2683-2686.

ISSP Activity Report 2013

143

7.

Thermal behaviour, structure and dynamics of low-temperature water confined in mesoporous organosilica by differential scanning calorimetry, X-ray diffraction and quasi-elastic neutron scattering: M. Aso, K. Ito, H. Sugino, K. Yoshida,
T. Yamada, O. Yamamuro, S. Inagaki and T. Yamaguchi, Pure and Appl. Chem. 85 (2013) 289-305.

8.

Relationship between the local dynamics and gas permeability of polyacetylenes containing polymethylated indan/tetrahydronaphtalene moieties: R. Inoue, T. Kanaya, Y. Hu, T. Masuda, K. Nishida and O. Yamamuro, Polymer 55 (2014)
182-186.

9.

Proton Dynamics of Two Dimensional Oxalate-Bridged Coordination Polymers: S. Miyatsu, M. Kofu, A. Nagoe, T.
Yamada, M. Sadakiyo, T. Yamada, H. Kitagawa, M. Tyagi, V. Garcia Sakai and O. Yamamuro, Phys. Chem. Chem. Phys.
(2014), accepted for publication.

10. 連載講座「中性子散乱による原子・分子のダイナミクスの観測」III 原子・分子のダイナミクス「液体・非晶質・表面／界面」: 山室 修 , RADIOISOTOPES 62 (2013) 691-701.

Masuda group
Recently the discovery of the multiferroics, i.e., enhanced simultaneous orders in magnetism and dielectricity,revived the studyof the magnetoelectric effect. A number of studies had revealed its mechanism and clarified the relationships between dielectric and magnetic structures in homogeneous systems. Next challenge would be to find and study a new magnetoelectric effectin inhomogeneous system. A remarkable example in an inhomogeneous system is a magnet having relaxor property, relaxor
magnet. In 2013 our group studied a new relaxor magnet, LuFeCoO4, by combination of bulk properties measurements andneutron diffraction technique. Our study reveals a novel relationship between PNRs and magnetic correlation, and establishes
the magnetic and dielectric phase diagrams of the relaxor magnet.
1.

Quantum-Phase-Transition-Induced Multiferroics and Higgs Mode in Integer Spin Systems in Noncentrosymmetric
Lattice with Strong Single-Ion Anisotropy: M. Matsumoto, M. Soda and T. Masuda, J. Phys. Soc. Jpn. 82 (2013)
093703.

2.

63,65

3.

三軸分光器入門 : 益田 隆嗣 , 波紋 23 (2013) 223-229.

4.

Spin-Nematic Interaction in the Multiferroic Compound Ba2CoGe2O7: M. Soda, M. Matsumoto, M. Mansson, S. OhiraKawamura, K. Nakajima, R. Shiina and T. Masuda, Phys. Rev. Lett. 112 (2014) 127205.

5.

1 次元フラストレート強磁性鎖のスピン密度波と Bond Nematic 相関 : 萩原 雅人 , 益田 隆嗣 , 波紋 23 (2013)14-18.

Cu Nuclear Resonance Study of the Coupled Spin Dimers and Chains Compound Cu2Fe2Ge4O13: J. Kikuchi, S.
Nagura, K. Murakami, T. Masuda and G. J. Redhammer, J. Phys. Soc. Jpn. 82 (2013) 034710(1-10).

International MegaGauss Science Laboratory
Takeyama group
The electro-magnetic flux compression techniques have been established to generate magnetic fields over 700 T by employing
a new type of primary coil (a copper lined iron coil). In such a high magnetic field, a measurement of the magnetic field should
be reconsidered. In pulse magnet operation, the magnetic field has been determined by a pick-up coil, wound around a thin rod,
converted from the detected induced voltage from dφ /dt (φ, a magnetic flux), followed by a certain process of calibration. We
have found recently that the pick-up coil is not a reliable method anymore in such an extremely high magnetic fields. A Faraday
rotation angle of quartz and the other glasses was measured up to a peak field and is calibrated with the signals from the pick-up
coil. The present study revealed that the conventional pick-up coil method underestimated the values of the peak fields at least
10 %, so that 730 T ever reported could possibly reach 800 T.
1.

Band-edge exciton states in a single-walled carbon nanotube revealed by magneto-optical spectroscopy in ultrahighmagnetic fields: W. Zhou, T. Sasaki, D. Nakamura, H. Liu, H. Kataura and S. Takeyama, Phys. Rev. B 87 (2013)
241406(1-4).

2.

*

144

Cyclotron resonance in ferromagnetic InMnAs and InMnSb: G. Khodaparast, Y. H. Matsuda, D. Saha, G. Sanders,C. Stanton, H. Saito, S. Takeyama, T. Merritt, C. Feeser, B. Wessels, X. Liu and J. Furdyna, Phys. Rev. B 88 (2013)
235204(11pages).

ISSP Activity Report 2013

3.

Magnetic superfluid state in the frustrated spinel oxide CdCr2O4 revealed by ultrahigh magnetic fields: A. Miyata, S.
Takeyama and H. Ueda, Phys. Rev. B 87 (2013) 214424(1-6).

4.

Magneto-photoluminescence of charged excitons from MgxZn1−xO/ZnO heterojunctions: T. Makino, Y. Segawa, A.
Tsukazaki, H. Saito, S. Takeyama, S. Akasaka, K. Nakahara and M. Kawasaki, Phys. Rev. B 87 (2013) 085312(1-7).

5.

*

6.

*

7.

*

8.

†*

9.

*

Precise measurement of a magnetic field generated by the electromagnetic flux compression technique: D. Nakamura,
H. Sawabe, Y. H. Matsuda and S. Takeyama, Rev. Sci. Instrum. 84 (2013) 044702 (10 pages).
Magnetization of SrCu2(BO3)2 in Ultrahigh Magnetic Fields up to 118 T: Y. H. Matsuda, N. Abe, S. Takeyama, H.
Kageyama, P. Corboz, A. Honecker, S. R. Manmana, G. R. Foltin, K. P. Schmidt and F. Mila, Phys. Rev. Lett. 111(2013) 137204 (5 pages).
Magnetization Studies of Field-Induced Transitions by Using a Single-Turn Coil Technique: N. Abe, Y. H. Matsuda, S.
Takeyama, K. Sato, H. Kageyama and Y. Nishiwaki, J. Low Temp. Phys. 170 (2013) 452-456.
Magneto-Absorption in the α Phase of Solid Oxygen at Megagauss Magnetic Fields: T. Nomura, Y. H. Matsuda, J. L.
Her, S. Takeyama, A. Matsuo, K. Kindo and T. C. Kobayashi, J. Low Temp. Phys. 170 (2013) 372-376.
Precision of an Ultra-high Magnetic Field Generated by the Electro-magnetic Flux Compression: D. Nakamura, Y. H.
Matsuda and S. Takeyama, J. Low Temp. Phys. 170 (2013) 457-462.

10. Exciton-phonon bound complex in single-walled carbon nanotubes revealed by high-field magneto-optical spectroscopy: W. Zhou, T. Sasaki, D. Nakamura, H. Saito, H. Liu, H. Kataura and S. Takeyama, Appl. Phys. Lett. 103 (2013)
233101.
11. Survey of exciton-phonon sidebands by magneto-optical spectroscopy using highly specified (6,5) single-walled carbon
nanotubes: W. Zhou, T. Sasaki, D. Nakamura, H. Saito, H. Liu, H. Kataura and S. Takeyama, Appl. Phys. Lett. 103(2013) 021117(1-4).
12. Infrared cyclotron resonances of Dirac electrons in SiC epitaxial graphene in ultra-high magnetic fields: H. Saito, D.
Nakamura, S. Takeyama and H. Hibino, AIP Conf. Proc. 1566 (2013) 145.
*

13. Magneto-optical study of Dirac fermion in quartz CVD-grown graphene above 100 T: D. Nakamura, H. Saito, W.
Zhou, Y. H. Matsuda, S. Takeyama, K. Yagi, K. Hayashi and S. Sato, AIP Conf. Proc. 1566 (2013) 169-170.
14. Magneto-optical survey of 1st and 2nd sub-bands in chirality specific (6, 5) single-walled carbon nanotube up to 190 T:
T. Sasaki, W. Zhou, D. Nakamura, H. Liu, H. Kataura and S. Takeyama, AIP Conf. Proc. 1566 (2013) 171.
15. Canted 2:1:1 Magnetic Supersolid Phase in a Frustrated Magnet MgCr2O4 as a Small Limit of the Biquadratic Spin
Interaction: A. Miyata, H. Ueda and S. Takeyama, J. Phys. Soc. Jpn. 83 (2014) 063702(1-4).
16. Note: Experimental evidence of three-dimensional dynamics of an electromagnetically imploded liner: D. Nakamura, H.
Sawabe and S. Takeyama, Rev. Sci. Instrum. 85 (2014) 036102.

Kindo group
A new user coil has been installed. The coil can generate a short pulsed field with duration of 4 ms. 75 T field can be used every
half hour. A new long-pulse magnet has been installed. The magnet can generate a long pulsed field with duration of about 1
sec. The maximum field of 36 T can be generated. Heat capacity measurement under the long pulsed field can be carried out.
1.

†

2.

Collapse of Magnetic Order of the Quasi One-Dimensional Ising-Like Antiferromagnet BaCo2V2O8 in Transverse
Fields: S. Kimura, K. Okunishi, M. Hagiwara, K. Kindo, Z. He, T. Taniyama, M. Itoh, K. Koyama and K. Watanabe, J.
Phys. Soc. Jpn. 82 (2013) 033706(1-4).

3.

†

4.

†*

Antiferromagnetic ordering in Sr2CrO4: M. Rani, H. Sakurai, S. Okubo, K. Takamoto, R. Nakata, T. Sakurai, H. Ohta,
A. Matsuo, Y. Kohama, K. Kindo and J. Ahmad, J. Phys.: Condens. Matter 25 (2013) 226001(1-5).

Crystal Structure and Magnetic Properties of the Verdazyl Biradical m-Ph-V2 Forming a Ferromagnetic Alternating
Double Chain: K. Iwase, H. Yamaguchi, T. Ono, T. Shimokawa, H. Nakano, A. Matsuo, K. Kindo, H. Nojiri and Y.
Hosokoshi, J. Phys. Soc. Jpn. 82 (2013) 074719(1-6).
High-Field Phase Diagram of SmRu4P12 Determined by Ultrasonic Measurements in Pulsed Magnetic Field up to 55
T: M. Yoshizawa, H. Mitamura, F. Shichinomiya, S. Fukuda, Y. Nakanishi, H. Sugawara, T. Sakakibara and K. Kindo, J.
Phys. Soc. Jpn. 82 (2013) 033602(1-5).

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145

5.

†

6.

Metamagnetic Behavior and Effect of Pressure on the Electronic State in Heavy-Fermion Compound YbRh2Zn20: F.
Honda, T. Takeuchi, S. Yasui, Y. Taga, S. Yoshiuchi, Y. Hirose, Y. Tomooka, K. Sugiyama, M. Hagiwara, K. Kindo, R.
Settai and Y. Onuki, J. Phys. Soc. Jpn. 82 (2013) 084705(1-10).

7.

†

8.

*

9.

†

Marked Change in the Ground State of CeRu2Al10 Induced by Small Amount of Rh Substitution: A. Kondo, K. Kindo,
K. Kunimori, H. Nohara, H. Tanida, M. Sera, R. Kobayashi, T. Nishioka and M. Matsumura, J. Phys. Soc. Jpn. 82(2013) 054709(1-5).

Spin-Dependent Molecular Orientation of O2–O2 Dimer Formed in the Nanoporous Coordination Polymer: A. Hori, T.
C. Kobayashi, Y. Kubota, A. Matsuo, K. Kindo, J. Kim, K. Kato, M. Takata, H. Sakamoto, R. Matsuda and S. Kitagawa,J. Phys. Soc. Jpn. 82 (2013) 084703(6).
Temperature and Magnetic Field Dependent Yb Valence in YbRh2Si2 Observed by X-ray Absorption Spectroscopy: H.
Nakai, T. Ebihara, S. Tsutsui, M. Mizumaki, N. Kawamura, S. Michimura, T. Inami, T. Nakamura, A. Kondo, K. Kindo
and Y. H. Matsuda, J. Phys. Soc. Jpn. 82 (2013) 124712 (5pages).
Crystal structure and magnetic properties of honeycomb-like lattice antiferromagnet p-BIP-V2: H. Yamaguchi, S.
Nagata, M. Tada, K. Iwase, T. Ono, S. Nishihara, Y. Hosokoshi, T. Shimokawa, H. Nakano, H. Nojiri, A. Matsuo, K.
Kindo and T. Kawakami, Phys. Rev. B 87 (2013) 125120(1-8).

†

10. High magnetic field study of the Tm2Fe17 and Tm2Fe17D3.2 compounds: O. Isnard, A. V. Andreev, M. D. Kuz'min, Y.
Skourski, D. I. Gorbunov, J. Wosnitza, N. V. Kudrevatykh, A. Iwasa, A. Kondo, A. Matsuo and K. Kindo, Phys. Rev. B
88 (2013) 174406(1-10).
11.

†*

12.

†*

Quasi-one-dimensional S=1/2 Heisenberg antiferromagnetic chain consisting of the organic radical p-Br-V: K. Iwase,
H. Yamaguchi, T. Ono, Y. Hosokoshi, T. Shimokawa, Y. Kono, S. Kittaka, T. Sakakibara, A. Matsuo and K. Kindo, Phys.
Rev. B 88 (2013) 184431(1-5).
Various regimes of quantum behavior in an S=1/2 Heisenberg antiferromagnetic chain with fourfold periodicity: H.
Yamaguchi, T. Okubo, K. Iwase, T. Ono, Y. Kono, S. Kittaka, T. Sakakibara, A. Matsuo, K. Kindo and Y. Hosokoshi,
Phys. Rev. B 88 (2013) 174410(1-5).

†

13. Magnetization Process and Collective Excitations in the S=1/2 Triangular-Lattice Heisenberg Antiferromagnet
Ba3CoSb2O9: T. Susuki, N. Kurita, T. Tanaka, H. Nojiri, A. Matsuo, K. Kindo and H. Tanaka, Phys. Rev. Lett. 110(2013) 267201(5).
14.

†*

15.

†*

High Field Magnetization of TbPd2Ge2 Single Crystal: T. Shigeoka, T. Hasegawa, T. Fujiwara, A. Kondo, K. Kindo
and Y. Uwatoko, J. Low Temp. Phys. 170 (2013) 248-254.
Magneto-Absorption in the α Phase of Solid Oxygen at Megagauss Magnetic Fields: T. Nomura, Y. H. Matsuda, J. L.
Her, S. Takeyama, A. Matsuo, K. Kindo and T. C. Kobayashi, J. Low Temp. Phys. 170 (2013) 372-376.

*

16. Observation of Field-induced Anomaly in High-field Magnetization on a Complex Spin-Driven Multiferroic
Compound, LiCu2−zZnzO2: J. L. Her, H. C. Hsu, Y. H. Matsuda, K. Kindo and F. C. Chou, J. Low Temp. Phys. 170(2013) 285-290.
†

17. Present Status and Future Plan at High Magnetic Field Laboratory in Osaka University: M. Hagiwara, T. Kida, K.
Taniguchi and K. Kindo, J. Low Temp. Phys. 170 (2013) 531-540.
18.

†*

Magnetic field hysteresis under various sweeping rates for Ni-Co-Mn-In metamagnetic shape memory alloys: X. Xu,
T. Kihara, M. Tokunaga, A. Matsuo, W. Ito, R. Y. Umetsu, K. Kindo and R. Kainuma, Appl. Phys. Lett. 103 (2013)
122406(1-4).

†

19. Itinerant electron magnetism of η-carbides Co6M6C and Ni6M6C (M=Mo and W): T. Waki, D. Furusawa, Y. Tabata, C.
Michioka, K. Yoshimura, A. Kondo, K. Kindo and H. Nakamura, J. Alloys Compd. 554 (2013) 21-24.
20.

†*

Optical imaging and magnetocaloric effect measurements in pulsed high magnetic fields and their application to Ni–
Co–Mn–In Heusler alloy: T. Kihara, I. Katakura, M. Tokunaga, A. Matsuo, K. Kawaguchi, A. Kondo, K. Kindo, W. Ito,
X. Xu and R. Kainuma, J. Alloys Compd. 577 (2013) S722-S725.

†

21. Magnetoresistance and Transformation Hysteresis in the Ni50Mn34.4In15.6 Metamagnetic Shape Memory Alloy: R. Y.
Umetsu, K. Endo, A. Kondo, K. Kindo, W. Ito, X. Xu, T. Kanomata and R. Kainuma, Mater. Trans. 54 (2013) 291.
†

22. Magnetic properties of the frustrated magnet Cu5(PO4)3(OH)4 on a peculiar spin network composed of pentagons andtriangles: H. Kikuchi, Y. Nguyen Thi Tinh, Y. Fujii, A. Matsuo and K. Kindo, J. Kor. Phys. Soc. 62 (2013) 2037-2040.

146

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*

23. Heat-pulse measurements of specific heat in 36 ms pulsed magnetic fields: Y. Kohama, Y. Hashimoto, S. Katsumoto,
M. Tokunaga and K. Kindo, Meas. Sci. Technol. 24 (2013) 115005(1-9).
†

24. Spin Frustration and Field-Induced Transitions of Modified Pyrochlore Fluorides ACr2F6 (A = Rb and Cs): H. Ueda, A.
Matsuo, K. Kindo and K. Yoshimura, J. Phys. Soc. Jpn. 83 (2014) 014701(1-6)
25.

†

Unconventional spin freezing in the highly two-dimensional spin-l/2 kagome antiferromagnet
Cd2Cu3(OH)6(SO4)24H2O: Evidence of partial order and coexisting spin singlet state on a distorted kagome lattice:
M. Fujihala, X.-G. Zheng, H. Morodomi, T. Kawae, A. Matsuo, K. Kindo and I. Watanabe, Phys. Rev. B 89 (2014)
100401(1-5).

Tokunaga group
By measuring the resistance of thin-film thermometers deposited on the sample surface, we succeeded in rapid temperaturemonitoring of the sample with the response time shorter than 0.1 ms. With using this technique, we developed a measurement
system of magneto-caloric effects in pulsed high magnetic fields up to 55 T. This technique provides us of novel thermodynamic
information of various kind of phase transitions induced in high magnetic fields and also direct information of the entropy infrustrated magnets.
1.

Giant Magnetoresistance Effect in the Metal–Insulator Transition of Pyrochlore Oxide Nd2Ir2O7: K. Matsuhira, M.
Tokunaga, M. Wakeshima, Y. Hinatsu and S. Takagi, J. Phys. Soc. Jpn. 82 (2013) 023706(1-4).

2.

High-Field Magnetization of Quasi-One-Dimensional Ising-Like Antiferromagnet TlCoCl3: Y. Nishiwaki, M. Tokunaga,
N. Todoroki and T. Kato, J. Phys. Soc. Jpn. 82 (2013) 104717(1-5).

3.

Metamagnetic Transition and Its Related Magnetocapacitance Effect in Phthalocyanine-Molecular Conductor Exhibiting
Giant Magnetoresistance: N. Hanasaki, T. Tateishi, H. Tajima, M. Kimata, M. Tokunaga, M. Matsuda, A. Kanda, H.
Murakawa, T. Naito and T. Inabe, J. Phys. Soc. Jpn. 82 (2013) 094713(1-5).

4.

Thermal Transport and Magnetotransport Properties of CuCr1-xMgxO2 with a Spin-3/2 Antiferromagnetic Triangular
Lattice: T. Okuda, S. Oozono, T. Kihara and M. Tokunaga, J. Phys. Soc. Jpn. 82 (2013) 014706(1-7).

5.

Magnetic control of electric polarization in the noncentrosymmetric compound (Cu,Ni)B2O4: N. D. Khanh, N. Abe, K.
Kubo, M. Akaki, M. Tokunaga, T. Sasaki and T. Arima, Phys. Rev. B 87 (2013) 184416(1-5).

6.

Shubnikov–de Haas oscillations in the bulk Rashba semiconductor BiTeI: C. Bell, M. S. Bahramy, H. Murakawa, J. G.
Checkelsky, R. Arita, Y. Kaneko, Y. Onose, M. Tokunaga, Y. Kohama, N. Nagaosa, Y. Tokura and H. Y. Hwang, Phys.
Rev. B 87 (2013) 081109(R)(1-5).

7.

†*

8.

Field-Induced Magnetostructural Transitions in Antiferromagnetic Fe1+yTe1-xSx: M. Tokunaga, T. Kihara, Y. Mizuguchi
and Y. Takano, J. Low Temp. Phys. 170 (2013) 340-345.

9.

High Magnetic Field Dependence of Magnetodielectric Properties in Sr2CoSi2O7 Crystal: M. Akaki, T. Tadokoro, T.
Kihara, M. Tokunaga and H. Kuwahara, J. Low Temp. Phys. 170 (2013) 291-295.

10.

†*

Adiabatic measurements of magneto-caloric effects in pulsed high magnetic fields up to 55 T: T. Kihara, Y. Kohama,
Y. Hashimoto, S. Katsumoto and M. Tokunaga, Rev. Sci. Instrum. 84 (2013) 074901(1-7).

Magnetic field hysteresis under various sweeping rates for Ni-Co-Mn-In metamagnetic shape memory alloys: X. Xu,
T. Kihara, M. Tokunaga, A. Matsuo, W. Ito, R. Y. Umetsu, K. Kindo and R. Kainuma, Appl. Phys. Lett. 103 (2013)
122406(1-4).

11. Detection of Berry's Phase in a Bulk Rashba Semiconductor: H. Murakawa, M. S. Bahramy, M. Tokunaga, Y. Kohama,
C. Bell, Y. Kaneko, N. Nagaosa, H. Y. Hwang and Y. Tokura, Science 342 (2013) 1490-1493.
12. Spin Frustration from cis -Edge or -Corner Sharing Metal-Centered Octahedra: R. Gautier, K. Oka, T. Kihara, N.
Kumar, A. Sundaresan, M. Tokunaga, M. Azuma and K. R. Poeppelmeier, J. Am. Chem. Soc. 135 (2013) 19268-19274.
13.

†*

Optical imaging and magnetocaloric effect measurements in pulsed high magnetic fields and their application to Ni–
Co–Mn–In Heusler alloy: T. Kihara, I. Katakura, M. Tokunaga, A. Matsuo, K. Kawaguchi, A. Kondo, K. Kindo, W. Ito,
X. Xu and R. Kainuma, J. Alloys Compd. 577 (2013) S722-S725.

14. Optical Microscopic Study on NiCoMnAl Metamagnetic Shape Memory Alloy by In Situ Observation under a PulsedHigh Magnetic Field: X. Xu, I. Katakura, T. Kihara, M. Tokunaga, W. Ito, R. Y. Umetsu and R. Kainuma, Mater. Trans.
54 (2013) 357-362.

ISSP Activity Report 2013147

15. Anisotropic magnetic properties in Åkermanite Sr2MSi2O7 (M=Co, Mn) crystals: M. Akaki, T. Tadokoro, H. Kuwahara,
T. Kihara and M. Tokunaga, J. Kor. Phys. Soc. 62 (2013) 1812-1814.
16. Magnetotransport property of the hole-doped delafossite CuCr0.97Mg0.03O2 with a Spin-3/2 antiferromagnetic triangularsublattice: T. Okuda, S. Oozono, T. Kihara and M. Tokunaga, J. Kor. Phys. Soc. 62 (2013) 2168-2172.
*

17. Heat-pulse measurements of specific heat in 36 ms pulsed magnetic fields: Y. Kohama, Y. Hashimoto, S. Katsumoto,
M. Tokunaga and K. Kindo, Meas. Sci. Technol. 24 (2013) 115005(1-9).

Y. Matsuda group
The magnetization process of SrCu2(BO3)2 shows exotic multi-plateau structure, indicating the crystallization of the excitedtriplet dimers with the several factional fillings in the sea of the singlet dimers. We have succeeded in observing the magnetization curve of SrCu2(BO3)2 in ultrahigh magnetic fields of up to 118 Tesla. The long predicted 1/2 plateau has been clearlyobserved at the field range from 84 to 108 Tesla for the first time. A destructive way of magnetic field generation, singleturn coil method (STC), was used for the experiment. In addition to the magnetization measurement, the cyclotron resonancein ferromagnetic semiconductors and magneto-absorption spectroscopy in solid oxygen have been performed at very highmagnetic fields over 100 Tesla. The synchrotron x-ray spectroscopy on Yb-based heavy fermion compounds YbRh2Si2 andYbAlB4 revealed that the valence instability was affected by a strong magnetic field, suggesting the importance of the charge
degree of freedom for understanding their exotic properties at very low temperatures.
1.

*

2.

X-ray Diffraction and Absorption Spectroscopy in Pulsed High Magnetic Fields: Y. H. Matsuda and T. Inami, J. Phys.
Soc. Jpn. 82 (2013) 021009 (17 pages).

3.

*

4.

*

5.

*

6.

*

7.

†*

8.

*

9.

*

Temperature and Magnetic Field Dependent Yb Valence in YbRh2Si2 Observed by X-ray Absorption Spectroscopy: H.
Nakai, T. Ebihara, S. Tsutsui, M. Mizumaki, N. Kawamura, S. Michimura, T. Inami, T. Nakamura, A. Kondo, K. Kindo
and Y. H. Matsuda, J. Phys. Soc. Jpn. 82 (2013) 124712 (5pages).

Cyclotron resonance in ferromagnetic InMnAs and InMnSb: G. Khodaparast, Y. H. Matsuda, D. Saha, G. Sanders,C. Stanton, H. Saito, S. Takeyama, T. Merritt, C. Feeser, B. Wessels, X. Liu and J. Furdyna, Phys. Rev. B 88 (2013)
235204(11pages).
Precise measurement of a magnetic field generated by the electromagnetic flux compression technique: D. Nakamura,
H. Sawabe, Y. H. Matsuda and S. Takeyama, Rev. Sci. Instrum. 84 (2013) 044702 (10 pages).
Magnetization of SrCu2(BO3)2 in Ultrahigh Magnetic Fields up to 118 T: Y. H. Matsuda, N. Abe, S. Takeyama, H.
Kageyama, P. Corboz, A. Honecker, S. R. Manmana, G. R. Foltin, K. P. Schmidt and F. Mila, Phys. Rev. Lett. 111(2013) 137204 (5 pages).
Magnetization Studies of Field-Induced Transitions by Using a Single-Turn Coil Technique: N. Abe, Y. H. Matsuda, S.
Takeyama, K. Sato, H. Kageyama and Y. Nishiwaki, J. Low Temp. Phys. 170 (2013) 452-456.
Magneto-Absorption in the α Phase of Solid Oxygen at Megagauss Magnetic Fields: T. Nomura, Y. H. Matsuda, J. L.
Her, S. Takeyama, A. Matsuo, K. Kindo and T. C. Kobayashi, J. Low Temp. Phys. 170 (2013) 372-376.
Observation of Field-induced Anomaly in High-field Magnetization on a Complex Spin-Driven Multiferroic
Compound, LiCu2−zZnzO2: J. L. Her, H. C. Hsu, Y. H. Matsuda, K. Kindo and F. C. Chou, J. Low Temp. Phys. 170(2013) 285-290.
Precision of an Ultra-high Magnetic Field Generated by the Electro-magnetic Flux Compression: D. Nakamura, Y. H.
Matsuda and S. Takeyama, J. Low Temp. Phys. 170 (2013) 457-462.

10. Structural and electrical characteristics of high-κ ErTixOy gate dielectrics on InGaZnO thin-film transistors: F.-H. Chen,
J.-L. Her, Y.-H. Shao, W.-C. Li, Y. H. Matsuda and T.-M. Pan, Thin Solid Films 539 (2013) 251-255.
11. Effect of surface roughness on electrical characteristics in amorphous InGaZnO thin-film transistors with high-κ Sm2O3
dielectrics: F.-H. Chen, M.-N. Hung, J.-F. Yang, S.-Y. Kuo, J.-L. Her, Y. H. Matsuda and T.-M. Pan, Journal of Physics
and Chemistry of Solids 74 (2013) 570-574.
*

12. Magneto-optical study of Dirac fermion in quartz CVD-grown graphene above 100 T: D. Nakamura, H. Saito, W.
Zhou, Y. H. Matsuda, S. Takeyama, K. Yagi, K. Hayashi and S. Sato, AIP Conf. Proc. 1566 (2013) 169-170.
*

13. Chemical effects of high-resolution Yb Lγ 4 emission spectra: a possible probe for chemical analysis: H. Hayashi, N.
Kanai, N. Kawamura, Y. H. Matsuda, K. Kuga, S. Nakatsuji, T. Yamashita and S. Ohara, X-Ray Spectrom. 42 (2013)450-455.

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14. Synchrotron X-ray spectroscopy study on the valence state in α- and β-YbAlB4 at low temperatures and high magnetic
fields: Y. H. Matsuda, T. Nakamura, K. Kuga, S. Nakatsuji, S. Michimura, T. Inami, N. Kawamura and M. Mizumaki, J.
Kor. Phys. Soc. 62 (2013) 1778-1781.
15. Structural and electrical characteristics of high-κ Er2O3 and Er2TiO5 gate dielectrics for a-IGZO thin-film transistors:
F.-H. Chen, J.-L. Her, Y.-H. Shao, Y. H. Matsuda and T.-M. Pan, Nanoscale Res Lett 8 (2013) 18 (5 pages).
*

16. Magnetization of Yb-based mixed-valent compounds at megagauss fields: T. Terashima, Y. H. Matsuda, K. Kuga, Y.
Matsumoto and S. Nakatsuji, J. Phys. Soc. Jpn. (2014), in print.

Center of Computational Materials Science
Akai group
We have developed methodologies that enable us to calculate electronic structure of wide range of systems such as strongly
correlated systems and systems in non-equlibrium states. One of them is a scheme of first-principles calculation of the
non-equilibrium Green's function of tunnelling junctions in the framework of the Korringa-Kohn-Rostoker (KKR) Green's
function method is developed. Another is the optimized effective potential (OEP) method applied to static RPA scheme. The
latter includes an elaboration that dissolves a well-known difficulty arising from the indefiniteness inherent in the theory of
OEP. One of main topics we are now working on is the theory of permanent magnet. This year we have developed the theory ofmagnetic anisotropy of Sm-Fe-N magnet, in particular discussing the role of N that experimentally is is known to be importantto realize the uni-axial magnetic anisotropy of this system.
1.

Basic and applications of Moessbauer spectrometry and the electronics structure of matters: H. Akai, ISOTOPES 63(2014) 163-174.

2.

鉄の事典 : 赤井 久純 , ( 朝倉書店 , 東京 , 2014) in print.

Todo group
We study novel phases and critical phenomena in strongly correlated many-body systems, such as quantum magnets and BoseHubbard model, by using the state-of-the-art computational physics techniques like the quantum Monte Carlo method. We also
develop new computational algorithms for quantum many-body systems, such as the tensor-network method, study the parallelization technique for supercomputers, and develop open-source software for next-generation parallel simulations: (1) Analysis
of quantum phases and quantum phase transitions by local Z2 Berry phase (2) Critical phenomena of long-range interacting spinmodel (3) Quantum phase transition of SU(N) J-Q model (4) Irreversible Markov chain Monte Carlo (5) Simulation method forsystems with strong spatial anisotropy (6) Parallelization of worm algorithm quantum Monte Carlo method (7) Parallel exact
diagonalization package “Rokko".
1.

Long-Range Order of the Three-Sublattice Structure in the S =1 Heisenberg Antiferromagnet on a Spatially Anisotropic
Triangular Lattice: H. Nakano, S. Todo and T. Sakai, J. Phys. Soc. Jpn. 82 (2013) 043715.

2.

*

3.

Monte Carlo simulation with aspect-ratio optimization: Anomalous anisotropic scaling in dimerized antiferromagnets:
S. Yasuda and S. Todo, Phys. Rev. E 88 (2013) 061301.

4.

Path-integral Monte Carlo method for the local Z2 Berry phase: Y. Motoyama and S. Todo, Phys. Rev. E 87 (2013)
021301(1-5).

5.

Geometric allocation approaches in Markov chain Monte Carlo: S. Todo and H. Suwa, J. Phys.: Conf. Ser. 473 (2013)
012013.

6.

詳細つりあいを満たさないマルコフ連鎖モンテカルロ法とその一般化 : 諏訪 秀麿 , 藤堂 眞治 , 数理解析研究所 講究録 1848 (2013) 93.

7.

Numerical Analysis of Quantum Phase Transitions with Dynamic Control of Anisotropy: S. Yasuda and S. Todo, JPS
Conf. Proc. 1 (2014) 012127.

8.

Path-Integral Monte Carlo for the Gauge-Fixed Berry Connection and the Local Z2 Berry Phase: Y. Motoyama and S.
Todo, JPS Conf. Proc. 1 (2014) 012130.

Possibility of deconfined criticality in SU(N) Heisenberg models at small N: K. Harada, T. Suzuki, T. Okubo, H.
Matsuo, J. Lou, H. Watanabe, S. Todo and N. Kawashima, Phys. Rev. B 88 (2013) 220408(1-4).

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9.

Loop Algorithm: S. Todo, in: Strongly Correlated Systems: Numerical Methods (Springer Series in Solid-State
Sciences), Ch 6, edited by A. Avella and F. Mancini, (Springer-Verlag, Berlin, 2013), 153-184.

Laser and Synchrotron Research Center
Suemoto group
To study ultrafast spin dynamics in canted ferromagnets, terahertz pump-Faraday probe experiments were performed on orthoferrites and several new aspects were revealed as follows. (1) Extremely long coherence time and beating phenomena were
found in spin precession modes. (2) Dynamics of magnetic anisotropy parameters modified by optical excitation was observed.
(3) Resonance enhancement of the spin precession by using a metamaterial structure (split ring resonator) was demonstrated. As
for the photoinduced phase transition, femtosecond dynamics in a novel nanocrystalline titanium oxide was studied and ultrafast phase change was confirmed, which guarantees usefulness of this material for optical storage. Newtons's ring in soft x-ray
region (at 13.9 nm) was firstly observed during the laser ablation process, suggesting an extremely thin and flat expansion front.
1.

†

2.

*

3.

*

4.

Terahertz Time-Domain Observation of Spin Reorientation in Orthoferrite ErFeO3 through Magnetic Free Induction
Decay: K. Yamaguchi, T. Kurihara, Y. Minami, M. Nakajima and T. Suemoto, Phys. Rev. Lett. 110 (2013) 137204 1-5.

5.

Dielectric probe for scattering-type terahertz scanning near-field optical microscopy: T. Kurihara, K. Yamaguchi, H.
Watanabe, M. Nakajima and T. Suemoto, Appl. Phys. Lett. 103 (2013) 151105.

6.

High-power THz wave generation in plasma induced by polarization adjusted two-color laser pulses: Y. Minami, T.
Kurihara, K. Yamaguchi, M. Nakajima and T. Suemoto, Appl. Phys. Lett. 102 (2013) 041105(1-4).

7.

Longitudinal THz wave generation from an air plasma filament induced by a femtosecond lase: Y. Minami, T. Kurihara,
K. Yamaguchi, M. Nakajima and T. Suemoto, Appl. Phys. Lett. 102 (2013) 151106(1-3).

8.

†

9.

†

Dynamics of pulsed laser ablation in high-density carbon dioxide including supercritical fluid state: K. Urabe, T. Kato,
S. Stauss, S. Himeno, S. Kato, H. Muneoka, M. Baba, T. Suemoto and K. Terashima, J. Appl. Phys. 114 (2013) 143303.
Access to hole dynamics in graphite by femtosecond luminescence and photoemission spectroscopy: T. Suemoto, S.
Sakaki, M. Nakajima, Y. Ishida and S. Shin, Phys. Rev. B 87 (2013) 224302(1-5).

Mechanism of Enhanced Optical Second-Harmonic Generation in the Conducting Pyrochlore-Type Pb2Ir2O7-x Oxide
Compound: Y. Hirata, M. Nakajima, Y. Nomura, H. Tajima, Y. Matsushita, K. Asoh, Y. Kiuchi, A. G. Eguiluz, R. Arita,
T. Suemoto and K. Ohgushi, Phys. Rev. Lett. 110 (2013) 187402(1-5).

Pulsed laser ablation plasmas generated in CO2 under high-pressure conditions up to supercritical fluid: T. Kato, S.
Stauss, S. Kato, K. Urabe, M. Baba, T. Suemoto and K. Terashima, Appl. Phys. Lett. 101 (2013) 224013(1-4).
Probing of local structures of thermal and photoinduced phases in rubidium manganese hexacyanoferrate by resonant
Raman spectroscopy: R. Fukaya, A. Asahara, S. Ishige, M. Nakajima, H. Tokoro, S.-I. Ohkoshi and T. Suemoto, J.
Chem. Phys. 139 (2013) 084303(1-7).

†

10. The synthesis of rhodium substituted ε-iron oxide exhibiting super high frequency natural resonance: A. Namai, M.
Yoshikiyo, S. Umeda, T. Yoshida, T. Miyazaki, M. Nakajima, K. Yamaguchi, T. Suemoto and S. Ohkoshi, Journal of
Materials Chemistry C 1 (2013) 5200-5206.
*

11. Gain-switching dynamics in optically pumped single-mode InGaN vertical-cavity surface-emitting lasers: S. Chen, A.
Asahara, T. Ito, J. Zhang, B. Zhang, T. Suemoto, M. Yoshita and H. Akiyama, Optics Express 22 (2014) 4196-4201.
*

12. Spectral dynamics of picosecond gain-switched pulses from nitride-based vertical-cavity surface-emitting lasers: S.
Chen, T. Ito, A. Asahara, M. Yoshita, W. Liu, J. Zhang, B. Zhang, T. Suemoto and H. Akiyama, Sci. Rep. 4 (2014) 4325.

Shin group
We studied high Tc Fe-pnictide superconductors using 7-eV laser. High resolution photoemission study with polarization dependence is very powerful for the study of the superconducting mechanism. Orbital fluctuation mechanism is also important inaddition to the spin fluctuation mechanism.
1.

150

Bulk-Sensitive Angle-Resolved PhotoemissionSpectroscopy on TTF-TCNQ: K. Koizumi, K. Ishizaka, T. Kiss, M.
Okawa, R. Kato and S. Shin, J. Phys. Soc. Jpn. 82 (2013) 025004(1-2).

ISSP Activity Report 2013

2.

*

3.

Quantifying covalency and metallicity in correlated compounds undergoing metal-insulator transitions: A. Chainani,
A. Yamamoto, M. Matsunami, R. Eguchi, M. Taguchi, Y. Takata, S. Shin, Y. Nishino, M. Yabashi, K. Tamasaku and T.
Ishikawa, Phys. Rev. B 87 (2013) 045108(1-10).

4.

†*

5.

†*

6.

Existence of Orbital Order and its Fluctuation in Superconducting Ba(Fe1-xCox)2As2 Single Crystals Revealed by
X-ray Absorption Spectroscopy: YK. Kim, WS. Jung, GR. Han, KY. Choi, CC. Chen, TP. Devereaux, A. Chainani, J.
Miyawaki, Y. Takata, Y. Tanaka, M. Oura, S. Shin, A. P. Singh, H. G Lee, JY. Kim and C. Kim, Phys. Rev. Lett. 111(2013) 217001(1-5).

7.

†*

8.

Strongly Spin-Orbit Coupled Two-Dimensional Electron Gas Emerging near the Surface of Polar Semiconductors:
M. Sakano, M. S. Bahramy, A. Katayama, T. Shimojima, H. Murakawa, Y. Kaneko, W. Malaeb, S. Shin, K. Ono, H.
Kumigashira, R. Arita, N. Nagaosa, H. Y. Hwang, Y. Tokura and K. Ishizaka, Phys. Rev. Lett. 110 (2013) 107204(1-5).

9.

*

10.

†*

11.

*

Access to hole dynamics in graphite by femtosecond luminescence and photoemission spectroscopy: T. Suemoto, S.
Sakaki, M. Nakajima, Y. Ishida and S. Shin, Phys. Rev. B 87 (2013) 224302(1-5).

Anomalous Doping Variation of the Nodal Low-Energy Feature of Superconducting (Bi,Pb)2(Sr, La)2CuO6+δ Crystals
Revealed by Laser-Based Angle-Resolved Photoemission Spectroscopy: T. Kondo, Y. Nakashima, W. Malaeb, Y. Ishida,
Y. Hamaya, T. Takeuchi and S. Shin, Phys. Rev. Lett. 110 (2013) 217006(1-5).
Anomalous Dressing of Dirac Fermions in the Topological Surface State of Bi2Se3, Bi2Te3, and Cu-Doped Bi2Se3: T.
Kondo, Y. Nakashima, Y. Ota, Y. Ishida, W. Malaeb, K. Okazaki, S. Shin, M. Kriener, S. Sasaki, K. Segawa and Y. Ando,Phys. Rev. Lett. 110 (2013) 217601(1-5).

Selective Probing of the OH or OD Stretch Vibration in Liquid Water Using Resonant Inelastic Soft-X-Ray Scattering:
Y. Harada, T. Tokushima, Y. Horikawa, O. Takahashi, H. Niwa, M. Kobayashi, M. Oshima, Y. Senba, H. Ohashi, KT.
Wikfeldt, A. Nilsson, LGM. Pettersson and S. Shin, Phys. Rev. Lett. 111 (2013) 193001(1-5).

Resonant inelastic X-ray scattering of liquid water: A. Nilsson, T. Tokushima, Y. Horikawa, Y. Harada, M. P. Ljungberg,
S. Shin and L. G. M. Pettersson, J. Electron Spectrosc. Relat. Phenom. 188 (2013) 84-100.
Surface electronic structure of the topological Kondo-insulator candidate correlated electron system SmB6: M.
Neupane, N. Alidoust, S. -Y. Xu, T. Kondo, Y. Ishida, D. J. Kim, C. Liu, I. Belopolski, Y. J. Jo, T. -R. Chang, H. -T. Jeng,
T. Durakiewicz, L. Balicas, H. Lin, A. Bansil, S. Shin, Z. Fisk and M. Z. Hasan, Nat. Commun. 4 (2013) 2991(1-7).
液体水分子の内殻電子励起ダイナミクスと局所構造 : 原田 慈久 , 徳島 高 , 堀川 裕加 , 丹羽 秀治 , 木内 久雄 ,小林 正起 , 尾嶋 正治 , 辛 埴 , しょうとつ 10 (2013) 14-20.

12. Evidence for excluding the possibility of d-wave superconducting-gap symmetry in Ba-doped KFe2As2: Y. Ota, K.
Okazaki, Y. Kotani, T. Shimojima, W. Malaeb, S. Watanabe, C. -T. Chen, K. Kihou, C. H. Lee, A. Iyo, H. Eisaki, T.
Saito, H. Fukazawa, Y. Kohori and S. Shin, Phys. Rev. B 89 (2014) 081103(1-5).
13.

†*

Observation of a giant Kerr rotation in a ferromagnetic transition metal by M-edge resonant magneto-optic Kerr effect:
Sh. Yamamoto, M. Taguchi, M. Fujisawa, R. Hobara, S. Yamamoto, K. Yaji, T. Nakamura, K. Fujikawa, R. Yukawa, T.
Togashi, M. Yabashi, M. Tsunoda, S. Shin and I. Matsuda, Phys. Rev. B 89 (2014) 064423(1-6).

*

14. Pseudogap formation above the superconducting dome in iron pnictides: T. Shimojima, T. Sonobe, W. Malaeb, K.
Shinada, A. Chainani, S. Shin, T. Yoshida, S. Ideta, A. Fujimori, H. Kumigashira, K. Ono, Y. Nakashima, H. Anzai, M.
Arita, A. Ino, H. Namatame, M. Taniguchi, M. Nakajima, S. Uchida, Y. Tomioka, T. Ito, K. Kihou, C. H. Lee, A. Iyo,
H. Eisaki, K. Ohgushi, S. Kasahara, T. Terashima, H. Ikeda, T. Shibauchi, Y. Matsuda and K. Ishizaka, Phys. Rev. B 89
(2014) 045101(1-10).
15.

†*

Ultrafast photoinduced transition of an insulating VO2 thin film into a nonrutile metallic state: R. Yoshida, T.
Yamamoto, Y. Ishida, H. Nagao, T. Otsuka, K. Saeki, Y. Muraoka, R. Eguchi, K. Ishizaka, T. Kiss, S. Watanabe, T.
Kanai, J. Itatani and S. Shin, Phys. Rev. B 89 (2014) 205114(1-7).

*

16. Robust Protection from Backscattering in the Topological Insulator Bi1.5Sb0.5Te1.7Se1.3: S. Kim, S. Yoshizawa, Y.
Ishida, K. Eto, K. Segawa, Y. Ando, S. Shin and F. Komori, Phys. Rev. Lett. 112 (2014) 136802(1-5).
17. Selective Probing of the OH or OD Stretch Vibration in Liquid Water Using Resonant Inelastic Soft-X-Ray Scattering:
Y. Harada, T. Tokushima, Y. Horikawa, O. Takahashi, H. Niwa, M. Kobayashi, M. Oshima, Y. Senba, H. Ohashi, KT.
Wikfeldt, A. Nilsson, LGM. Pettersson and S. Shin, Phys. Rev. Lett. 111 (2014) 193001(1-5).
18. レーザー光電子分光による分子性導体の電子構造の観測 : 石坂 香子 , 小泉 健二 , 木須 孝幸 , 辛 埴 , 固体物理
49 (2014) 153-162.

ISSP Activity Report 2013

151

*

19. Observing hot carrier distribution in an n-type epitaxial graphene on a SiC substrate: T. Someya, H. Fukidome,
Y. Ishida, R. Yoshida, T. Iimori, R. Yukawa, K. Akikubo, Sh. Yamamoto, S. Yamamoto, T. Yamamoto, T. Kanai, K.
Funakubo, M. Suemitsu, J. Itatani, F. Komori, S. Shin and I. Matsuda, Appl. Phys. Lett. 104 (2014) 161103(1-4).
20.

†*

Solvation dependence of valence electronic states of water diluted in organic solvents probed by soft X-ray spectroscopy: T. Tokushima, Y. Horikawa, O. Takahashi, H. Arai, K. Sadakane, Y. Harada, Y. Takata and S. Shin, Phys. Chem.
Chem. Phys. 16 (2014) 10753.

21. Superconductivity in an electron band just above the Fermi level: possible route to BCS-BEC superconductivity: K.
Okazaki1, Y. Ito, Y. Ota, Y. Kotani, T. Shimojima, T. Kiss, S. Watanabe, C. -T. Chen, S. Niitaka, T. Hanaguri, H. Takagi,
A. Chainani and S. Shin, Sci. Rep. 4 (2014) 4109(1-6).
22. Development of a single-shot CCD-based data acquisition system for time-resolved X-ray photoelectron spectroscopy atan X-ray free-electron laser facility: M. Oura, T. Wagai, A. Chainani, J. Miyawaki, H. Sato, M. Matsunami, R. Eguchi,
T. Kiss, T. Yamaguchi, Y. Nakatani, T. Togashi, T. Katayama, K. Ogawa, M. Yabashi, I. Y. Tanaka, Y. Kohmura, K.
Tamasaku, S. Shin and T. Ishikawa, J.Syn.Rad. 21 (2014) 183-192.
23. The electronic structure of carbonate ion in aqueous solution studied by soft X-ray emission spectroscopy: Y. Horikawa
A. Yoshida, O. Takahashi, H. Araia, T. Tokushima, T. Gejo and S. Shin, J.Mol.Liq 189 (2014) 9-12.
24.

†*

New soft X-ray beamline BL07LSU at SPring-8: S. Yamamoto, Y. Senba, T. Tanaka, H. Ohashi, T. Hirono, H. Kimura,
M. Fujisawa, J. Miyawaki, A. Harasawa, T. Seike, S. Takahashi, N. Nariyama, T. Matsushita, M. Takeuchi, T. Ohata, Y.
Furukawa, K. Takeshita, S. Goto, Y. Harada, S. Shin, H. Kitamura, A. Kakizaki, M. Oshima and I. Matsuda, J Synchrotron Rad 21 (2014) 352-365.

Takahashi group
We have been studying the structure and phase transition of surfaces and interfaces with diffraction techniques. Topologicalinsulators attract much attention due to potential applications such as spintronics and quantum computing. The structure of aBi(001)/Bi2Te3(001) heteroepitaxial film grown on Si(111) was studied with atomic layer resolution by using X-ray crystal
truncation rod scattering in combination with a novel structure analysis method. We revealed the Bi thin film is heavily distorted
due to the interaction with the substrate Bi2Te3, resulting in the topological phase transition of the Bi film. We could also get
quantitative information on the structural inhomogeneity at the interface between both Bi/Bi2Te3 and Bi2Te3/Si(111).
1.

Structure of a Bi/Bi2Te3 heteroepitaxial film studied by x-ray crystal truncation rod scattering: T. Shirasawa, J. Tsunoda,
T. Hirahara and T. Takahashi, Phys. Rev. B 87 (2013) 075449(1-5).

2.

A method for measuring the specular X-ray reflectivity with millisecond time resolution: W. Voegeli, T. Matsushita, E.
Arakawa, T. Shirasawa, T. Takahashi and Y. F. Yano, J. Phys.: Conf. Ser. 425 (2013) 092003(1-4).

3.

†*

4.

Determination of atomic positions in silicene on Ag(111) by low-energy electron diffraction: K. Kawahara, T. Shirasawa, R. Arafune, C. -L. Lin, T. Takahashi, M. Kawai and N. Takagi, Surf. Sci. 623 (2014) 25-28.

Scanning tunneling microscopic and spectroscopic studies on a crystalline silica monolayer epitaxially formedon hexagonal SiC(000-1) surfaces: H. Tochihara, T. Shirasawa, T. Suzuki, T. Miyamachi, T. Kajiwara, K. Yagyu, S.
Yoshizawa, T. Takahashi, S. Tanaka and F. Komori, Appl. Phys. Lett. 104 (2014) 051601(1-4).

5. 「グラフェン／ SiC(000-1) 界面構造の研究」角田 潤一 , 新領域物質系 (2013).
6.

Structure and transport properties 1 of Cu doped Bi2Se3 films: T. Shirasawa, M. Sugiki, T. Hirahara, M. Aitani, T. Shirai,
S. Hasegawa and T. Takahashi, Phys. Rev. B (2014), accepted for publication.

Akiyama group
In 2013, we started experimental and theoretical study on energy conversion efficiencies and sub-cell internal luminescence
yields of tandem solar cells on the basis of a detailed-balance relation. We applied this key relation to the study of intrinsic
radiative lifetime of one-dimensional excitons, and fluorescent radiation thermometry at cryogenic temperatures. We also started
collaboration on the photoluminescence emission of photoexcited undoped GaAs quantum wells induced by an intense singlecycle terahertz pulse. We intensively studied spectral dynamics in short-pulse generation via gain switching of semiconductor
lasers, such as Fabry-Perot GaAs or InGaAs lasers, InGaN VCSELs, and InGaAsP DFB lasers. We developed and characterized double-core-slab-waveguide semiconductor lasers for end optical pumping. We studied the effect of site-directed mutant
luciferase on quantitative green and orange/red emission intensities in firefly bioluminescence, and firefly oxyluciferin inenzymatic environment on the basis of stability monitoring. Intensive studies were made with TD-DFT theoretical calculations
on electronic states for luciferin and oxyluciferin.

152

ISSP Activity Report 2013

1.

Transient hot-carrier optical gain in a gain-switched semiconductor laser: T. Ito, S. Chen, M. Yoshita, T. Mochizuki, C.
Kim, H. Akiyama, L. N. Pfeiffer and K. W. West, Appl. Phys. Lett. 103 (2013) 082117.

2.

†

3.

Fluorescent Radiation Thermometry at Cryogenic Temperatures Based on Detailed Balance Relation: T. Mochizuki,
T. Ihara, M. Yoshita, S. Maruyama, H. Akiyama, L. N. Pfeiffer and K. W. West, Appl. Phys. Express 6 (2013) 056602(1-3).

4.

Dynamics of short-pulse generation via spectral filtering from intensely excited gain-switched 155-μm distributedfeedback laser diodes: S. Chen, M. Yoshita, A. Sato, T. Ito, H. Akiyama and H. Yokoyama, Opt. Express 21 (2013)
10597-10605.

5.

Gain-switched pulses from InGaAs ridge-quantum-well lasers limited by intrinsic dynamical gain suppression: S. Chen,
M. Yoshita, T. Ito, T. Mochizuki, H. Akiyama and H. Yokoyama, Opt. Express 21 (2013) 7570-7576.

6.

Double-core-slab-waveguide semiconductor lasers for end optical pumping: T. Nakamura, T. Mochizuki, C. Kim, S.
Chen, M. Yoshita and H. Akiyama, Applied Physics Express 6 (2013) 062702.

7.

Impact of Site-Directed Mutant Luciferase on Quantitative Green and Orange/Red Emission Intensities in Firefly Bioluminescence: Y. Wang, H. Akiyama, K. Terakado and T. Nakatsu, Sci. Rep. 3 (2013) 2490.

8.

Intrinsic radiative lifetime derived via absorption cross section of one-dimensional excitons: S. Chen, M. Yoshita, A.
Ishikawa, T. Mochizuki, S. Maruyama, H. Akiyama, Y. Hayamizu, L. N. Pfeiffer and K. W. West, Sci. Rep. 3 (2013)
1941.

9.

Theoretical Study of Firefly Luciferin p K a Values-Relative Absorption Intensity in Aqueous Solutions: M. Hiyama, H.
Akiyama, K. Yamada and N. Koga, Photochem Photobiol 89 (2013) 571.

Electroluminescence of GaNAs/GaAs MQWs p–i–n junctions grown by RF-MBE using modulated nitrogen radical
beam source: N. Ohta, K. Arimoto, M. Shiraga, K. Ishii, M. Inada, S. Yanai, Y. Nakai, H. Akiyama, T. Mochizuki, T.
Takahashi, N. Takahashi, H. Miyagawa, N. Tsurumachi, S. Nakanishi and S. Koshiba, J. Cryst. Growth 378 (2013) 150.

10. Theoretical study for absorption spectra of oxyluciferin in aqueous solutions: M. Hiyama, H. Akiyama, Y. Wang and N.
Koga, Chemical Physics Letters 577 (2013) 121.
11. Large enhancement of the photoluminescence emission of photoexcited undoped GaAs quantum wells induced byan intense single-cycle terahertz pulse: K. Shinokita, H. Hirori, K. Tanaka, T. Mochizuki, C. Kim, H. Akiyama, L. N.
Pfeiffer and K. W. West, Phys. Rev. Lett 111 (2013) 067401.
12. Theoretical Study of Fluorescence Spectra Utilizing the pKa Values of Acids in Their Excited States: M. Hiyama, H.
Akiyama, K. Yamada and N. Koga, Photochem. Photobiol 90 (2013) 35-40.
13. Low Threshold Lasing of GaN-Based VCSELs With Sub-Nanometer Roughness Polishing: W.-J. Liu, S.-Q. Chen, X.-L.
Hu, Z. Liu, J.-Y. Zhang, L.-Y. Ying, X.-Q. Lv, H. Akiyama, Z.-P. Cai and B.-P. Zhang, IEEE Photon. Technol. Lett. 25(2013) 2014.
14. Mode imaging and loss evaluation of semiconductor waveguides: T. Mochizuki, C. Kim, M. Yoshita, T. Nakamura, H.
Akiyama, L. N. Pfeiffer and K. W. West, Rev. Sci. Instrum. 85 (2014) 053109.
15. Robust red-emission spectra and yields in firefly bioluminescence against temperature changes: T. Mochizuki, Y. Wang,
M. Hiyama and H. Akiyama, Appl. Phys. Lett. 104 (2014) 213704.
16. Spectroscopic Study of Firefly Oxyluciferin in an Enzymatic Environment on the Basis of Stability Monitoring: Y.
Wang, Y. Hayamizu and H. Akiyama, J. Phys. Chem. B 118 (2014) 2070–2076.
*

17. Gain-switching dynamics in optically pumped single-mode InGaN vertical-cavity surface-emitting lasers: S. Chen, A.
Asahara, T. Ito, J. Zhang, B. Zhang, T. Suemoto, M. Yoshita and H. Akiyama, Optics Express 22 (2014) 4196-4201.
18. Gain switching of a double-core-waveguide semiconductor laser via traveling-wave optical pumping: H. Nakamae, T.
Nakamura, T. Ito, T. Mochizuki, C. Kim, S. Chen, M. Yoshita and H. Akiyama, Appl. Phys. Express 7 (2014) 062701.
*

19. Spectral dynamics of picosecond gain-switched pulses from nitride-based vertical-cavity surface-emitting lasers: S.
Chen, T. Ito, A. Asahara, M. Yoshita, W. Liu, J. Zhang, B. Zhang, T. Suemoto and H. Akiyama, Sci. Rep. 4 (2014) 4325.
20. Impact of Sub-cell Internal Luminescence Yields on Energy Conversion Efficiencies of Tandem Solar Cells: A designprinciple: L. Zhu, C. Kim, M. Yoshita, S. Chen, S. Sato, T. Mochizuki, H. Akiyama and Y. Kanemitsu, Applied Physics
Letters 104 (2014) 031118.

ISSP Activity Report 2013

153

I. Matsuda group
Developments and experiments of the advanced spectroscopies have been carried out by using vacuum ultraviolet (VUV) andsoft X-rays (SX). At SPring-8 BL07LSU, picosecond-time-resolved SX photoemission spectroscopy measurements have been
carried out to trace relaxation of photo-excited carriers at metal oxide surfaces. Analyses of the carrier life time have directly
revealed the electron-hole recombination process. At Kashiwa campus, dynamics of the Dirac Fermion in a graphene layer
is studied by femtosecond-time-resolved VUV photoemission spectroscopy. The transient electron temperature has indicatedgeneration of the cascade carrier multiplication in the femtosecond-time scale. As a part of the undulator development at
SPring-8 BL07LSU, phase shifters with electromagnetic coils were mechanically adjusted and installed in the electron storage
ring. The phase shifters will be used to make fast polarization switching of the beamline.
1.

Time-resolved photoelectron spectroscopies using synchrotron radiation: Past, present, and future: S. Yamamoto and I.
Matsuda, J. Phys. Soc. Jpn. 82 (2013) 021003(1-18).

2.

Electronic structure of the hydrogen-adsorbed SrTiO3(001) surface studied by polarization-dependent photoemission
spectroscopy: R. Yukawa, S. Yamamoto, K. Ozawa, M. D’Angelo, M. Ogawa, M. G. Silly, F. Sirotti and I. Matsuda,
Phys. Rev. B 87 (2013) 115314(1-6).

3.

Oscillatory relaxation of surface photovoltage on a semiconductor surface: M. Ogawa, S. Yamamoto, R. Yukawa, R.
Hobara, L. -C. Huang, R. -Y. Liu, S. -J. Tang and I. Matsuda, Phys. Rev. B 87 (2013) 235308(1-4).

4.

Relaxations of the surface photovoltage effect on the atomically controlled semiconductor surfaces studied by timeresolved photoemission spectroscopy: M. Ogawa, S. Yamamoto, K. Fujikawa, R. Hobara, R. Yukawa, Sh. Yamamoto, S.
Kitagawa, D. Pierucci, M. G. Silly, C. -H. Lin, R. -Y. Liu, H. Daimon, F. Sirotti, S. -J. Tang and I. Matsuda, Phys. Rev.
B 88 (2013) 165313(1-9).

5.

Structure of silicene on a Ag(111) surface studied by reflection high-energy positron diffraction: Y. Fukaya, I.
Mochizuki, M. Maekawa, K. Wada, T. Hyodo, I. Matsuda and A. Kawasuso, Phys. Rev. B 88 (2013) 205413(1-4).

6.

金属超薄膜内に閉じ込められた電子系のフェルミ面トポロジー制御 - 量子効果で銀細工 : 永村 直佳 , 小河 愛実 ,松田 巌 , 固体物理 48 (2013) 13-19.

7.

Anisotropic electronic conduction in metal nanofilms grown on a one-dimensional surface superstructure: N. Nagamura,
R. Hobara, T. Uetake, T. Hirahara, K. Kobayashi, I. Matsuda and S. Hasegawa, Phys. Rev. B 89 (2014) 125415(1-5).

8.

†*

9.

*

Observation of a giant Kerr rotation in a ferromagnetic transition metal by M-edge resonant magneto-optic Kerr effect:
Sh. Yamamoto, M. Taguchi, M. Fujisawa, R. Hobara, S. Yamamoto, K. Yaji, T. Nakamura, K. Fujikawa, R. Yukawa, T.
Togashi, M. Yabashi, M. Tsunoda, S. Shin and I. Matsuda, Phys. Rev. B 89 (2014) 064423(1-6).
Observing hot carrier distribution in an n-type epitaxial graphene on a SiC substrate: T. Someya, H. Fukidome,
Y. Ishida, R. Yoshida, T. Iimori, R. Yukawa, K. Akikubo, Sh. Yamamoto, S. Yamamoto, T. Yamamoto, T. Kanai, K.
Funakubo, M. Suemitsu, J. Itatani, F. Komori, S. Shin and I. Matsuda, Appl. Phys. Lett. 104 (2014) 161103(1-4).

10. Non-linear kinetic model for oscillatory relaxation of the photovoltage effect on a Si(111)7x7 surface: M. Ogawa, R. -Y.
Liu, C. -H. Lin, S. Yamamoto, R. Yukawa, R. Hobara, S. -J. Tang and I. Matsuda, Surf. Sci. 624 (2014) 70-75.
11. 反射高速陽電子回折（RHEPD）
による Ag(111) 表面上のシリセンの構造決定 : 深谷 有喜 , 望月 出海 , 前川 雅樹 ,和田 健 , 兵頭 俊夫 , 松田 巌 , 河裾 厚男 , PF News 32 (2014) 10-14.
12. 表面電子化合物 : 松田 巌 , 深谷 有喜 , PF News 31 (2014) 33-37.
†

13. Electron–Hole Recombination Time at TiO2 Single-Crystal Surfaces: Influence of Surface Band Bending: K. Ozawa,M. Emori, S. Yamamoto, R. Yukawa, S. Yamamoto, R. Hobara, K. Fujikawa, H. Sakama and I. Matsuda, J. Phys. Chem.
Lett. 5 (2014) 1953.
14. Rashba effects within the space charge layer of a semiconductor: C.-H. Lin, T.-R. Chang, Ro. -Ya. Liu, C.-M. Cheng,
K.-D. Tsuei, H. -T. Jeng, C.-Y. Mou, I. Matsuda and S. -J. Tang, New. J. Phys. 16 (2014) 045003(1-12).
15.

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New soft X-ray beamline BL07LSU at SPring-8: S. Yamamoto, Y. Senba, T. Tanaka, H. Ohashi, T. Hirono, H. Kimura,
M. Fujisawa, J. Miyawaki, A. Harasawa, T. Seike, S. Takahashi, N. Nariyama, T. Matsushita, M. Takeuchi, T. Ohata, Y.
Furukawa, K. Takeshita, S. Goto, Y. Harada, S. Shin, H. Kitamura, A. Kakizaki, M. Oshima and I. Matsuda, J Synchrotron Rad 21 (2014) 352-365.

16. 量子井戸 : 松田 巌 , 「表面科学会教科書シリーズ 62013), 88.

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問題と解説で学ぶ表面科学」, 松井文彦 , ( 共立出版 ,Kobayashi group
We have demonstrated a precision spectroscopy in VUV region by using VUV frequency comb.
1.

vuv frequency-comb spectroscopy of atomic xenon: A. Ozawa and Y. Kobayashi, Phys. Rev. A 87 (2013) 022507(1-4).

2.

6-GHz, Kerr-lens mode-locked Yb:Lu2O3 ceramic laser for comb-resolved broadband spectroscopy: M. Endo, A. Ozawa
and Y. Kobayashi, Opt. Lett. 38 (2013) 4502.

3.

10-MHz, Yb-fiber chirped-pulse amplifier system with large-scale transmission gratings: Y. Kobayashi, N. Hirayama, A.
Ozawa, T. Sukegawa, T. Seki, Y. Kuramoto and S. Watanabe, Optics Express 21 (2013) 12865.

4.

Static FBG strain sensor with high resolution and large dynamic range by dual-comb spectroscopy: N. Kuse, A. Ozawa
and Y. Kobayashi, Optics Express 21 (2013) 11141.

5.

光源としての光コム (2)6.

紫外光周波数コム発生と精密分光への応用 : 小澤 陽 , 小林 洋平 , OplusE 35 (2013) 1132.

7.

デュアルコム分光 FT-IR にかわる高速広帯域精密分光 : 久世 直也 , 小澤 陽 , 小林 洋平 , 日本物理学会 69 (2014)
29.

VUV 領域および高繰り返しコム : 小林 洋平 , 分光研究 62 (2013) 185.

Itatani group
The Itatani group worked mainly on (i) the generation of soft-X-ray high harmonics using a BIBO-based optical parametricchirped pulse amplifier at 1.6 µm and (ii) the generation of intense THz pulses and their application to coherent control of small
molecules. Regarding the BIBO-based source, we measured high harmonic spectra up to 330 eV with various experimental
parameters such as backing pressures and carrier-envelope phases of the driver pulses. We observed clear CEP-dependences
up to the backing pressure of 3 atm, which showed a potential to increase the photon flux of soft-X-ray attosecond pulses. As
for the THz generation, we controlled the rotational wavepackets in jet-cooled HBr molecules to achieve molecular orientation (alignment with head-and-tail discrimination). We observed clear signature of molecular orientation by a newly-developed
velocity-map imaging apparatus. This is the first clear demonstration of molecular orientation by using intense THz pulses.
1.

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2.

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3.

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4.

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Orientation of jet-cooled polar molecules with an intense single-cycle THz pulse: K. Kitano, N. Ishii, N. Kanda, Y.
Matsumoto, T. Kanai, M. Kuwata-Gonokami and J. Itatani, Phys. Rev. A 88 (2013) 061405.
Ultrafast photoinduced transition of an insulating VO2 thin film into a nonrutile metallic state: R. Yoshida, T.
Yamamoto, Y. Ishida, H. Nagao, T. Otsuka, K. Saeki, Y. Muraoka, R. Eguchi, K. Ishizaka, T. Kiss, S. Watanabe, T.
Kanai, J. Itatani and S. Shin, Phys. Rev. B 89 (2014) 205114(1-7).
Observing hot carrier distribution in an n-type epitaxial graphene on a SiC substrate: T. Someya, H. Fukidome,
Y. Ishida, R. Yoshida, T. Iimori, R. Yukawa, K. Akikubo, Sh. Yamamoto, S. Yamamoto, T. Yamamoto, T. Kanai, K.
Funakubo, M. Suemitsu, J. Itatani, F. Komori, S. Shin and I. Matsuda, Appl. Phys. Lett. 104 (2014) 161103(1-4).
Carrier-envelope phase-dependent high harmonic generation in the water window using few-cycle infrared pulses: N.
Ishii, K. Kaneshima, K. Kitano, T. Kanai, S. Watanabe and J. Itatani, Nat. Commun. 5 (2014) 3331.

Harada group
1) Operando soft X-ray RIXS spectroscopy for electronic structure analysis of catalytic reactions:: We have developed a novel
electrochemical cell system for operando soft X-ray emission spectroscopy for analysis of catalytic reactions. We have applied
the system to identify the active site for oxygen reduction reaction in polymer electrolyte fuel cells cathode catalysts. We haveobserved the electronic structure of iron in an iron phthalocyanine-based cathode catalyst under various working conditions
and found that an oxidized iron site exists and is active for oxygen adsorption, which is not expected from ex situ results inwhich a metallic iron site dominates. 2) Development of the soft X-ray RIXS system around sample manipulation:: In order toextend the public use of the soft X-ray emission spectroscopy station we have realized precise temperature control of liquids inothe range of -5 ∼ 80 C within ±1K accuracy using an originally developed thermal shielding, and surface cleaning by neutralized ion sputtering and annealing at more than 1000 K by electron bombardment. We also have implemented a liq. He sample
cooling system down to 35 K. All these systems are now in operation and open to public. 3) Pioneering work on soft X-ray
vibrational RIXS of liquids: Ultrahigh resolution resonant inelastic soft X-ray scattering was applied to observe multiple vibrational excitations in liquid water. By tuning X-ray excitation energy to a particular structure in the X-ray absorption spectrum
we have successfully obtained vibrational frequencies well correlate with the OH stretching mode of a particular configurationof water. This enables element- and site-specific vibrational spectroscopy that is not accessible by the conventional IR or Raman
spectroscopy.

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1.

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2.

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3.

Probing carbon edge exposure of iron phthalocyanine-based oxygen reduction catalysts by soft X-ray absorption
spectroscopy: H. Niwa, M. Saito, M. Kobayashi, Y. Harada, M. Oshima, S. Moriya, K. Matsubayashi, Y. Nabae, S.
Kuroki, T. Ikeda, K. Terakura, J.-I. Ozaki and S. Miyata, Journal of Power Sources 223 (2013) 30-35.

4.

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5.

Operando soft X-ray emission spectroscopy of iron phthalocyanine-based oxygen reduction catalysts: H. Niwa, H.
Kiuchi, J. Miyawaki, Y. Harada, M. Oshima, Y. Nabae and T. Aoki, Electrochemistry Communications 35 (2013) 57-60.

6.

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7.

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8.

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9.

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Selective Probing of the OH or OD Stretch Vibration in Liquid Water Using Resonant Inelastic Soft-X-Ray Scattering:
Y. Harada, T. Tokushima, Y. Horikawa, O. Takahashi, H. Niwa, M. Kobayashi, M. Oshima, Y. Senba, H. Ohashi, KT.
Wikfeldt, A. Nilsson, LGM. Pettersson and S. Shin, Phys. Rev. Lett. 111 (2013) 193001(1-5).
Resonant inelastic X-ray scattering of liquid water: A. Nilsson, T. Tokushima, Y. Horikawa, Y. Harada, M. P. Ljungberg,
S. Shin and L. G. M. Pettersson, J. Electron Spectrosc. Relat. Phenom. 188 (2013) 84-100.

液体水分子の内殻電子励起ダイナミクスと局所構造 : 原田 慈久 , 徳島 高 , 堀川 裕加 , 丹羽 秀治 , 木内 久雄 ,小林 正起 , 尾嶋 正治 , 辛 埴 , しょうとつ 10 (2013) 14-20.

Unveiling the impurity band induced ferromagnetism in the magnetic semiconductor (Ga,Mn)As: M. Kobayashi,
I. Muneta, Y. Takeda, Y. Harada, A. Fujimori, J. Krempaský, T. Schmitt, S. Ohya, M. Tanaka, M. Oshima and V. N.
Strocov, Phys. Rev. B 89 (2014) 205204(1-8).
Electronic Excitations of a Magnetic Impurity State in the Diluted Magnetic Semiconductor (Ga,Mn)As: M.
Kobayashi, H. Niwa, Y. Takeda, A. Fujimori, Y. Senba, H. Ohashi, A. Tanaka, S. Ohya, P. N. Hai, M. Tanaka, Y. Haradaand M. Oshima, Phys. Rev. Lett. 112 (2014) 107203(1-7).
Solvation dependence of valence electronic states of water diluted in organic solvents probed by soft X-ray spectroscopy: T. Tokushima, Y. Horikawa, O. Takahashi, H. Arai, K. Sadakane, Y. Harada, Y. Takata and S. Shin, Phys. Chem.
Chem. Phys. 16 (2014) 10753.
New soft X-ray beamline BL07LSU at SPring-8: S. Yamamoto, Y. Senba, T. Tanaka, H. Ohashi, T. Hirono, H. Kimura,
M. Fujisawa, J. Miyawaki, A. Harasawa, T. Seike, S. Takahashi, N. Nariyama, T. Matsushita, M. Takeuchi, T. Ohata, Y.
Furukawa, K. Takeshita, S. Goto, Y. Harada, S. Shin, H. Kitamura, A. Kakizaki, M. Oshima and I. Matsuda, J Synchrotron Rad 21 (2014) 352-365.

†

10. Iron-Nitrogen Coordination in Modified Graphene Catalyzes a Four-Electron-Transfer Oxygen Reduction Reaction: K.
Kamiya, H. Koshikawa, H. Kiuchi, Y. Harada, M. Oshima, K. Hashimoto and S. Nakanishi, ChemElectroChem (2014),
accepted for publication.

Wadati group
Our main experimental techniques are synchrotron-based x-ray spectroscopy and scattering. We studied the orbital and magnetic
phase transitions in Pr0.5Ca0.5MnO3 epitaxial thin films by resonant soft x-ray scattering and observed three phase transitions,one of which is absent in bulk Pr0.5Ca0.5MnO3. We also studied the valence of Bi in Bi-based new-type superconductors by
x-ray absorption spectroscopy and obtained evidence for the scenario of electron doping for the emergence of superconductivity.
1.

Antiferromagnetic Order of the Co2+ High-Spin State with a Large Orbital Angular Momentum in La1.5Ca0.5CoO4: J.
Okamoto, H. Nakao, Y. Yamasaki, H. Wadati, A. Tanaka, M. Kubota, K. Horigane, Y. Murakami and K. Yamada, J. Phys.
Soc. Jpn. 83 (2014) 044705.

2.

Insulator-to-Superconductor Transition upon Electron Doping in a BiS2 -Based Superconductor Sr1−xLaxFBiS2: H.
Sakai, D. Kotajima, K. Saito, H. Wadati, Y. Wakisaka, M. Mizumaki, K. Nitta, Y. Tokura and S. Ishiwata, J. Phys. Soc.
Jpn. 83 (2014) 014709.

3.

Revealing orbital and magnetic phase transitions in Pr0.5Ca0.5MnO3 epitaxial thin films by resonant soft x-ray scattering:
H. Wadati, J. Geck, E. Schierle, R. Sutarto, F. He, D. G. Hawthorn, M. Nakamura, M. Kawasaki, Y. Tokura and G. A.
Sawatzky, New J. Phys. 16 (2014) 033006.

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Kondo group
We use angle-resolved photoemission spectroscopy (ARPES) with ultrahigh energy resolution, achieved by using laser
photon source, and study the nonconventional superconductors, heavy fermions, strongly correlated systems, topologicalquantum phases, and quantum well states. The main findings in 2013 are as follows: (1) Formation of Gapless Fermi Arcs andFingerprints of Order in the Pseudogap State of Cuprate Superconductors. (2) Anomalous Dressing of Dirac Fermions in the
Topological Surface State. (3) Significant doping Variation of the Nodal Low-Energy Feature of Superconducting Bi2Sr2CuO6+δ
(Bi2201) crystals.
1.

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2.

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3.

Formation of Gapless Fermi Arcs and Fingerprints of Order in the Pseudogap State of Cuprate Superconductors.: T.
Kondo, A. D. Palczewski, Y. Hamaya, T. Takeuchi, J. S. Wen, Z. J. Xu, G. Gu and A. Kaminski, Phys. Rev. Lett. 111(2013) 157003(1-5).

4.

†*

5.

Fermi Surface and Pseudogap Evolution in a Cuprate Superconductor.: Y. He, Y. Yin, M. Zech, A. Soumyanarayanan, M.
M. Yee, T. Williams, M. C. Boyer, K. Chatterjee, W. D. Wise, I. Zeljkovic, T. Kondo, T. Takeuchi, H. Ikuta, P. Mistark,
R. S. Markiewicz, A. Bansil, S. Sachdev, E. W. Hudson and J. E. Hoffman, Science 344 (2014) 608-611.

Anomalous Doping Variation of the Nodal Low-Energy Feature of Superconducting (Bi,Pb)2(Sr, La)2CuO6+δ Crystals
Revealed by Laser-Based Angle-Resolved Photoemission Spectroscopy: T. Kondo, Y. Nakashima, W. Malaeb, Y. Ishida,
Y. Hamaya, T. Takeuchi and S. Shin, Phys. Rev. Lett. 110 (2013) 217006(1-5).
Anomalous Dressing of Dirac Fermions in the Topological Surface State of Bi2Se3, Bi2Te3, and Cu-Doped Bi2Se3: T.
Kondo, Y. Nakashima, Y. Ota, Y. Ishida, W. Malaeb, K. Okazaki, S. Shin, M. Kriener, S. Sasaki, K. Segawa and Y. Ando,Phys. Rev. Lett. 110 (2013) 217601(1-5).

Surface electronic structure of the topological Kondo-insulator candidate correlated electron system SmB6: M.
Neupane, N. Alidoust, S. -Y. Xu, T. Kondo, Y. Ishida, D. J. Kim, C. Liu, I. Belopolski, Y. J. Jo, T. -R. Chang, H. -T. Jeng,
T. Durakiewicz, L. Balicas, H. Lin, A. Bansil, S. Shin, Z. Fisk and M. Z. Hasan, Nat. Commun. 4 (2013) 2991(1-7).

ISSP Activity Report 2013157