Raise3D Industrial PPA Support_SDS

Nov.2021

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Raise3D Industrial PPA Support Safety Data Sheet

Section 1: PRODUCT AND COMPANY IDENTIFICATION
1.1 Trade name:Raise3D Industrial PPA Support 3D Printing Filament
1.2 Use of the product:
3D Printing Filament
1.3 Supplier information
Supplier:
Raise 3D Technologies, Inc.
Address:
43 Tesla, Irvine, CA 92618
Emergency phone number: In case of toxicological emergency, contact your doctor.

Section 2: HAZARDS IDENTIFICATION
2.1 Classification of the substance or mixture classification (REGULATION (EC) No 1272/2008)
This product does not meet the criteria for classification in any hazard class according to Regulation (EC)No 1272/2008 on classification, labelling and packaging of substances and mixtures.
REGULATION (EC) No 1272/2008
Hazard classes/ Hazard categories

Hazard codes

N/A

N/A

2.2 Label elements
Hazard Pictograms: No hazard pictogram is used.
Signal Word(S): No signal word is used.
Hazard Statement: Not applicable.
Precautionary statement: Not applicable.
2.3 Other hazards
Not available.

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Section 3: COMPOSITION/ INFORMATION ON INGREDIENTS
Substance/ Mixture: Mixture
Ingredient(s):Chemical Name

Registrati

Cas No.

EC No.

Concentration

Classification

27135-32-6

N.A.

>80%

Not Classifiedon No.
Polyphthalamide

N/Apolymer

1-5% of the mixture consists of component (s) of unknown toxicity.
1-5% of components with unknown hazards to the aquatic environment.

Section 4: FIRST AID MEASURES
4.1 Description of first aid measures
In all cases of doubt, or when symptoms persist, seek medical attention.
4.1.1 General advice:If you feel unwell, seek medical advice (show the label where possible). Never give anything by mouth toan unconscious person. Take off contaminated clothing and shoes immediately.
4.1.2 If inhaled:
None expected to require first aid measures. If breathed in, remove victim to fresh air and keep at rest in aposition comfortable for breathing. If you feel unwell, seek medical attention.
4.1.3 In case of skin contact:
None expected to require first aid measures. Wash thoroughly with soap and water. Get medical attention
in the unlikely event that irritation persists.
4.1.4 In case of eye contact:
None expected to require first aid measures. Flush with running water for at least 15 minutes. If irritation
persists get medical attention.
4.1.5 If swallowed:
Immediate first aid is not likely to be required. A physician or poison control center can be contacted foradvice.
4.2 Most important symptoms and effects, both acute and delayed
The product is not classified as harmful to human health effect.
4.3 Indication of any immediate medical attention and special treatment needed
Symptomatic treatment.

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Section 5: FIRE FIGHTING MEASURES
5.1 Extinguishing media
Suitable extinguishing media:
Use extinguishers suitable for surrounding fire.
Unsuitable extinguishing media:
Not available.
5.2 Special hazards arising from the substance or mixture
Specific hazards during firefighting:No specific fire or explosion hazard. In case of fire, the following can be released: carbon monoxide,carbon dioxide.
5.3 Advice for fire fighters
Special protective equipment for firefighters:
Wear self-contained breathing apparatus for firefighting if necessary. Use personal protective equipment.
Further information:
Standard procedure for chemical fires. Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment. In the event of fire and/or explosion do not breathe
fumes.

Section 6: ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures
6.1.1 For non-emergency personnel:
Use personal protective equipment. Ensure adequate ventilation. Evacuate personnel to safe areas.
6.1.2 For emergency responders:
Avoid skin and eye contact. Refer to section 8 of SDS for personal protection details.
6.2 Environmental precautions
Avoid disposing into drainage/sewer system or directly into the aquatic environment.
6.3 Methods and materials for containment and cleaning up
Sweep up and shovel into suitable containers. Clean up affected area.
6.4 Reference to other sections
See Section 7 for information on safe handling.

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See Section 8 for information on personal protection equipment.
See Section 13 for information on disposal.

Section 7: HANDING AND STORAGE
7.1 Handling
Advice on safe handling:
Ensure good ventilation/ exhaustion at the workplace. Wash thoroughly after handling.
Advice on general occupational hygiene:
Do not eat, drink and smoke in work areas. Wash hands after use. Remove contaminated clothing andprotective equipment before entering eating areas.
Advice on protection against fire and explosion:
Normal measures for preventive fire protection.
Dust explosion class:No data available.
7.2 Conditions for safe storage, including any incompatibilities
Requirements for storage areas and containers:
Store spool in a dry, cool and ventilated place.
Further information on storage conditions:
Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be
carefully resealed and kept upright to prevent leakage.
Advice on common storage:
Keep away from oxidizing agents and strongly acid or alkaline materials. Keep away from food, drink andanimal feeding stuffs.
Storage temperature:> 0°C and <= 40°C
Other data:
No decomposition if stored and applied as directed.

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Section 8: EXPOSURE CONTROLS/ PERSONAL PROTECTION
8.1 Occupational exposure limits:
8.1.1 Occupational exposure limits:
Not available.
8.1.2 Additional exposure limits under the conditions of use:
Not available.
8.1.3 DNEL/ DMEL and PNEC-Values:
Not available.
8.2 Biological limit values
No biological exposure limits noted for the ingredient(s).
8.3 Appropriate engineering controls:
Use adequate ventilation to keep airborne concentrations low.
8.4 Individual protection measures, such as personal protective equipment:
Eye/ Face protection: No special requirements.
Hand protection: No special requirements.
Body protection: No special requirements.
Respiratory protection: No special requirements.
Thermal hazards: Wear suitable protective clothing to prevent heat.
8.5 General hygiene considerations:
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking andusing the lavatory and at the end of the working period.
8.6 Environmental exposure controls:
Avoid discharge into the environment. Dispose of rinse water in accordance with local and nationalregulations.

Section 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties
Appearance: Solid.
Colour: Purple.
Odour: Odorless.
Odour threshold: Not available.

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pH: Not available.
Melting point/ range (°C): 218°C.
Boiling point/ range (°C): Not available.
Flash point (°C): Not available.
Evaporation rate: Not available.
Flammability limit - lower (%): Not available.
Flammability (solid, gas): Not available.
Ignition temperature (°C): Not available.
Upper/ lower explosive limits:
Not available.
Vapour pressure (20°C): Not available.
Vapour density: Not available.
Relative Density: 1.26.
Bulk density (kg/m3): Not available.
Water solubility (g/l): Insoluble.
n-Octanol/Water (log Po/w): Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Viscosity, dynamic (mPa.s): Not available.
Explosive properties: Not available.
Oxidising properties: Not available.
9.2. Other information:
Fat solubility(solvent-oil to be specified) etc: Not available.
Surface tension: Not available.
Dissociation constant in water( pKa): Not available.
Oxidation-reduction Potential: Not available.

Section 10: STABILITY AND REACTIVITY
10.1 Reactivity:
The substance is stable under normal storage and handling conditions.
10.2 Chemical stability:
Stable at room temperature in closed containers under normal storage and handling conditions.
10.3 Possibility of hazardous reactions:
No dangerous reactions known.
10.4 Conditions to avoid:
Incompatible materials.

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10.5 Incompatible materials:
Materials to avoid: Strong oxidizing agents.
10.6 Hazardous decomposition products
Carbon oxides.

Section 11: TOXICOLOGICAL INFORMATION11.1 Information on toxicological effects
Acute toxicity:
ATEmix(oral): Not available.
ATEmix(Dermal): Not available.
ATEmix(inhalation): Not available.
LD50(Oral, Rat): 2 301 mg/kg bw.
LD50(Dermal, Rabbit): > 5 000 mg/kg bw.
LC50(Inhalation, Rat): Not available.
Skin corrosion/Irritation: Not classified.
Serious eye damage/irritation: Not classified.
Respiratory or skin sensitization: Not classified.
Germ cell mutagenicity: Not classified.
Carcinogenicity: Not classified.
Reproductive toxicity: Not classified.
STOT-single exposure: Not classified.
STOT-repeated exposure: Not classified.
Aspiration hazard: Not classified.

Section 12: ECOLOGICAL INFORMATION
12.1 Toxicity
Acute (short-term) toxicity:
LC50(96h, Fish): 4 630 mg/L.
LC50(48h, Crustacea): 2 400 mg/L.
EC50(72h, Algae/ aquatic plants): 2 900 mg/L.
Chronic (long-term) toxicity:
NOEC(Fish): Not available.
NOEC(Crustacea): Not available.
EC50(Algae/ aquatic plants): Not available.

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12.2 Persistence and degradability
No data is available on the degradability.
12.3 Bioaccumulative potential
No data available.
12.4 Mobility in soil
No data available.
12.5 Results of PBT and vPvB assessment
No data available.
12.6 Other adverse effects
No data available.

Section 13: DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods
Disposal method
Disposal:
The material should be disposed of by incineration in a chemical incinerator in compliance with nationaland regional requirements.
Contaminated packaging:Since emptied containers may retain product residue, follow label warnings even after container isemptied.

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Section 14: TRANSPORT INFORMATIONLand transport

InlandSea transport

Air transport(ADR/RID)

waterways(IMDG)(ICAO/IATA)(ADN)
UN number

Not regulated

Not regulated

Not regulated

Not regulated

UN Proper shipping

Not regulated

Not regulated

Not regulated

Not regulated

Not regulated

Not regulated

Not regulated

Not regulated

Packing group

Not regulated

Not regulated

Not regulated

Not regulated

Environmental hazards

NoNo

No

No

Special precautions forSee section 2.2

See section 2.2

See section 2.2

See section 2.2

Not regulated

Not regulated

Not regulated

Not regulated

nameTransport hazard
Class(es)userTransport in bulk
according to Annex II ofMarpol and the IBC
CodeSection 15: REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture:Relevant information regarding authorization:
Not applicable.
Relevant information regarding restriction:
Not applicable.
Other EU regulations:
Employment restrictions concerning young person must be observed.
For use only by technically qualified individuals.
Other National regulations:Not applicable15.2 Chemical safety assessment

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Version 1.0Section 16: OTHER INFORMATION
Revision information
Date of this revision: October 25, 2021
16.1 Indication of changes:
Version 1.0 Amended by (EU) 2015/830
16.2 Abbreviations and acronyms:
ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road.
RID: Regulation for rail International transportation of Dangerous goods.
ADN: European Agreement concerning the International Carriage of Dangerous Goods by Inland
Waterways.
IMDG: Code international maritime dangerous goods code.
ICAO-TI: International Civil Aviation Organization The International Civil Aviation Covenant.
IATA: International Air Transport Association.
LC50: median lethal concentration.
EC50: The effective concentration of substance that causes 50% of the maximum response.
NOEC: No Observed Effect Concentration.
DNEL: Derived no-effect level.
PNEC: Predicted no-effect concentration.
16.3 Key literature references and sources for data
ECHA Registered substances data.
16.4 Training instructions
Not applicable.
16.5 Further information
This information is based upon the present state of our knowledge. This SDS has been compiled and issolely intended for this product.
16.6 Declare to reader
Information is referenced from other manufacturers.
For abbreviations and acronyms, see: ECHA Guidance on information requirements and chemical safetyassessment, chapter R.20 (Table of terms and abbreviations).
This safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006 and Regulation(EC) No. 2015/830. Label element according to Regulation (EC) No 1272/2008.

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The information above is believed to be accurate and represents the best information currently available
to us. However, we make no warranty of merchantability or any other warranty, express or implied, withrespect to such information, and we assume no liability resulting from its use. This shall not constitute a
guarantee for any specific product features and shall not establish a legally valid contractual relationship.

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