Safety Data Sheet

According to Regulation (EC) No. 1907 /2006 /REACH)
Trade name: SilOil M90.055/170.03
No.: 6258,6259
Print date: 24.01.2019
Valid from: 09.2018

Version: 2.1.0 (2.0.1)

1.

Identification of the substance / mixture and of the company / undertaking

1.1

Identification of the substance / mixture

1.2

Relevant identified uses of the substance or mixture and uses advised against

1.3

Details of the supplier of the safety data sheet

Product name: SilOil M90.055/170.03
No.: 6258, 6259
Chemical characterization: —EC No: 205-492-2
CAS No: 141-63-9
REACH Registration No: 01-2119970218-33

Relevant identified uses:
Surface treatment, assembling aid, release agent, damperfluid, cooling oil.
Uses advised against:
None known.
Supplier:
Peter HUBER Kältemaschinenbau AG
Street:Werner-von-Siemens-Str. 1
Postal code:
DE-77656 Offenburg

Contact for technical information
Technical Support
Tel.: +49 (0) 781 9603-244
Fax: +49 (0) 781 57211
Email: support@huber-online.com

1.4

Emergency telephone number+49 (0) 2751/524-113+49 (0) 179/6910027+49 (0) 61 31 1924 0 (Giftinfo Mainz, 24 h German and English)+49 (0) 761-19 240 (Vergiftungs-Informationszentrale Freiburg)

2.

Hazards identification

2.1

Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
None.
Classification procedure
Calculation method.

2.2

Label elements

2.3

Other hazards

3.

Composition / information on ingredients

3.1

Substances

Labelling according to Regulation (EC) No. 1272/2008 [CLP]Special rules for supplemental label elements for certain mixtures
EUH210
Safety data sheet available on request.

No information available.

Substance name : dodecamethylpentasiloxane
EC No. : 205-492-2
REACH No. : 01-2119970218-33
CAS No. : 141-63-9
Purity : ≥ 95 - < 100 % [mass]
Seite : 1 / 9Peter Huber Kältemaschinenbau AG · Werner-von-Siemens-Str. 1 · 77656 Offenburg · Tel. +49 781-9603-0 · www.huber-online.com · info@huber-online.com

Safety Data Sheet

According to Regulation (EC) No. 1907 /2006 /REACH)
Trade name: SilOil M90.055/170.03
No.: 6258,6259
Print date: 24.01.2019
Valid from: 09.2018

Version: 2.1.0 (2.0.1)

Hazardous impurities
Dodecamethylcyclohexasiloxane ; REACH registration No. : 01-2119517435-42 ; EC No. : 208-762-8; CAS No. : 540-97-6
Weight fraction :<1%
Classification 1272/2008 [CLP] :NoneThis product contains the following substances of very high concern (SVHC) which are included in the Candidate List
according to Article 59 of REACH
Dodecamethylcyclohexasiloxane ; REACH registration No. : 01-2119517435-42 ; EC No. : 208-762-8; CAS No. : 540-97-6

4.

First aid measures

4.1

Description of first aid measures
General information
Change contaminated, saturated clothing. When in doubt or if symptoms are observed, get medical advice.
Following inhalation
Provide fresh air.
In case of skin contact
After contact with skin, wash immediately with plenty of water and soap.
After eye contact
Rinse immediately carefully and thoroughly with eye-bath or water. In case of eye irritation consult an
ophthalmologist.
After ingestion
Do NOT induce vomiting. Rinse mouth thoroughly with water.
Self-protection of the first aider
No special measures are necessary
Information to physician
Treatment
Treat symptomatically.

4.2

Most important symptoms and effects, both acute and delayed

4.3

Indication of any immediate medical attention and special treatment needed

No information available.

None.

5.

Firefighting measures

5.1

Extinguishing media
Suitable extinguishing media
Carbon dioxide (CO2), alcohol resistant foam, water spray jet Extinguishing powder sand.
Unsuitable extinguishing media
Full water jet.

5.2

Special hazards arising from the substance or mixture

5.3

Advice for firefighters

5.4

Additional information
None.

6.

Accidental release measures

6.1

Personal precautions, protective equipment and emergency procedures

No information available.

In case of fire toxic gases may be formed.
Special protective equipment for firefighters
Wear a self-contained breathing apparatus and chemical protective clothing.

Take the precautions customary when handling chemicals. Use personal protection equipment. Special danger of slipping by leaking /spilling product.

Seite : 2 / 9Peter Huber Kältemaschinenbau AG · Werner-von-Siemens-Str. 1 · 77656 Offenburg · Tel. +49 781-9603-0 · www.huber-online.com · info@huber-online.com

Safety Data Sheet

According to Regulation (EC) No. 1907 /2006 /REACH)
Trade name: SilOil M90.055/170.03
No.: 6258,6259
Print date: 24.01.2019
Valid from: 09.2018

Version: 2.1.0 (2.0.1)

6.2

Environmental precautions

6.3

Methods and material for containment and cleaning up

6.4

Reference to other sections

6.5

Additional information
No data available.

7.

Handling and storage

7.1

Precautions for safe handlingDo not allow to enter into surface water or drains. Prevent spread over a wide area (e.g. by containment or oil barriers).

For cleaning up
Take up mechanically. Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents).

None.

Avoid contact with skin and eyes.
Protective measures
Use only in well-ventilated areas. Do not breathe gas/fumes/vapour/spray.
Measures to prevent fire
Keep away from sources of ignition. - No smoking. Take precautionary measures against static discharges.

7.2

Conditions for safe storage, including any incompatibilities
Requirements for storage rooms and vessels
Keep / Store only in original container.
Hints on joint storage
Storage class (TRGS 510) : 10
Further information on storage conditions
Protect containers against damage.

7.3

Specific end use(s)8.

Exposure controls / personal protection

8.1

Control parameters

None.

Occupational exposure limit values
Does not contain substances above concentration limits fixing an occupational exposure limit.
Biological limit values
No data available
DNEL/DMEL and PNEC values
DNEL/DMEL

Seite : 3 / 9Peter Huber Kältemaschinenbau AG · Werner-von-Siemens-Str. 1 · 77656 Offenburg · Tel. +49 781-9603-0 · www.huber-online.com · info@huber-online.com

Safety Data Sheet

According to Regulation (EC) No. 1907 /2006 /REACH)
Trade name: SilOil M90.055/170.03
No.: 6258,6259
Print date: 24.01.2019
Valid from: 09.2018

Version: 2.1.0 (2.0.1)

Limit value type :Exposure route :Exposure frequency :Limit value :Limit value type :Exposure route :Exposure frequency :Limit value :Limit value type :Exposure route :Exposure frequency :Limit value :Limit value type :Exposure route :Exposure frequency :Limit value :Limit value type :Exposure route :Exposure frequency :Limit value :Limit value type :Exposure route :Exposure frequency :Limit value :Limit value type :Exposure route :Exposure frequency :Limit value :Limit value type :Exposure route :Exposure frequency :Limit value :Limit value type :Exposure route :Exposure frequency :Limit value :Limit value type :Exposure route :Exposure frequency :Limit value :PNEC
Limit value type :Limit value :Limit value type :Limit value :8.2

DNEL Consumer (systemic)
DermalShort-term (acute)
731 mg/kg/day
DNEL Consumer (systemic)
Inhalation
Short-term (acute)
25 mg/kg/day
DNEL Consumer (systemic)
Oral
Short-term (acute)
7,31 mg/kg/day
DNEL Consumer (systemic)
DermalLong-term
731 mg/kg/day
DNEL Consumer (systemic)
Inhalation
Long-term
25 mg/m3
DNEL Consumer (systemic)
OralLong-term
7,31 mg/kg/day
DNEL worker (systemic)
DermalShort-term (acute)
1449 mg/kg/day
DNEL worker (systemic)
Inhalation
Short-term (acute)
102 mg/m3
DNEL worker (systemic)
DermalLong-term
1449 mg/kg/day
DNEL worker (systemic)
Inhalation
Long-term
102 mg/m3
PNEC (Soil)
3,34 mg/kg
PNEC (Sewage treatment plant)> 1 mg/l

Exposure controls

Personal protection equipment
Eye / face protection
Eye glasses with side protection
Skin protection
Hand protection
The quality of the protective gloves resistant to chemicals must be chosen as a function of the specific working place concentrationand quantity of hazardous substances.
Suitable material: Butyl caoutchouc (butyl rubber) NBR (Nitrile rubber)
Breakthrough time (maximum wearing time): 480 minutes. Check leak tightness / impermeability prior to use.
For special purposes, it is recommended to check the resistance to chemicals of the protective gloves mentioned above together withthe supplier of these gloves.
Respiratory protection
Usually no personal respirative protection necessary. Respiratory protection necessary at: aerosol or mist formation.
Suitable respiratory protection apparatus
Combination filtering device (EN 14387) A
Seite : 4 / 9Peter Huber Kältemaschinenbau AG · Werner-von-Siemens-Str. 1 · 77656 Offenburg · Tel. +49 781-9603-0 · www.huber-online.com · info@huber-online.com

Safety Data Sheet

According to Regulation (EC) No. 1907 /2006 /REACH)
Trade name: SilOil M90.055/170.03
No.: 6258,6259
Print date: 24.01.2019
Valid from: 09.2018

Version: 2.1.0 (2.0.1)

General health and safety measures
Avoid contact with skin, eyes and clothes. Remove contaminated, saturated clothing. Wash hands before breaks andafter work. Keep away from food, drink and animal feeding stuffs.

8.3

Additional information

9.

Physical and chemical properties

9.1

Information on basic physical and chemical properties

No data available.

Appearance
Physical state:
Colour:Odour:

Liquid.
Different according to colour.
Light.

Safety relevant basis data
( 1 bar / 1 Pa )Solidifying point:
Melting point/melting range:
Freezing point:
Initial boiling point and boiling range:
Decomposition temperature:
Flash point:
Ignition temperature:
Lower explosion limit:
Upper explosion limit:(50°C)
Vapour pressure:(25°C)
Density:(20°C)
Solvent separation test:(20°C)
Fat solubility:
Solubility in water:(20°C)pH:
log P O/W:
(25°C)
Kinematic viscosity:
Odour threshold:(20°C)
Relative vapour density:
Evaporation rate:
Vapourisation rate:
Not applicable
Flammable solids:
Not applicable
Flammable gases:
Not applicable
Oxidising liquids:
Not applicable
Explosive properties:
Not determined
Corrosive to metals:

9.2

approx.

approx.

approx.

Not determined
Not applicableNot determined
Not applicableNot determined
87°C
Not determined
Not determined
Not determined
Not determined
0,87g/cm3
Not determined
Not applicable
Insoluble
Not applicableNot determined
2mm2/sNot determined
Not determined
Not determined
Not determined

Other information
No data available.

10. Stability and reactivity
10.1 Reactivity
No dangerous reactions known.

10.2 Chemical stability

The product is chemically stable under recommended conditions of storage, use and temperature.

10.3 Possibility of hazardous reactions
No dangerous reactions known.

10.4 Conditions to avoid

Keep away from sources of ignition - No smoking. Take precautionary measures against static discharges.
Seite : 5 / 9Peter Huber Kältemaschinenbau AG · Werner-von-Siemens-Str. 1 · 77656 Offenburg · Tel. +49 781-9603-0 · www.huber-online.com · info@huber-online.com

BrookfieldSafety Data Sheet

According to Regulation (EC) No. 1907 /2006 /REACH)
Trade name: SilOil M90.055/170.03
No.: 6258,6259
Print date: 24.01.2019
Valid from: 09.2018

Version: 2.1.0 (2.0.1)

10.5 Incompatible materials
Oxidizing agent.

10.6 Hazardous decomposition products

Measurements have shown the formation of small amounts of formaldehyde at temperatures above about 150 °C (302°F)
through oxidation.

10.7 Additional information
No data available.

11. Toxicological information
11.1 Information on toxicological effects

Acute effects
Acute oral toxicity
Parameter:
LD50
Exposure route:
Oral
Species:Rat
Effective dose:> 5000 mg/kg
By analogy.
Acute dermal toxicity
Parameter:
LD50
Exposure route:DermalSpecies:Rat
Effective dose:> 2000 mg/kg
By analogy.
Acute inhalation toxicity
The product has not been tested.
Specific symptoms in animal studies
The product has not been tested.
Irritant and corrosive effects
Primary irritation to the skin
The product has not been tested.
Irritation to eyes
The product has not been tested.
Irritation to respiratory tract
The product has not been tested.
Sensitisation
In case of skin contact
The product has not been tested.
In case of inhalation
The product has not been tested.
Repeated dose toxicity (subacute, subchronic, chronic)
The product has not been tested.
Subacute oral toxicity
Parameter :NOAEL(C) ( Dodecamethylcyclohexasiloxane ; CAS No. : 540-97-6 )Exposure route :OralSpecies :Rat
Effective dose :1000 mg/kg
CMR effects (carcinogenicity, mutagenicity and toxicity for reproduction)
Carcinogenicity
The product has not been tested.
Germ cell mutagenicity
The product has not been tested.
Reproductive toxicity
The product has not been tested.
Seite : 6 / 9Peter Huber Kältemaschinenbau AG · Werner-von-Siemens-Str. 1 · 77656 Offenburg · Tel. +49 781-9603-0 · www.huber-online.com · info@huber-online.com

Safety Data Sheet

According to Regulation (EC) No. 1907 /2006 /REACH)
Trade name: SilOil M90.055/170.03
No.: 6258,6259
Print date: 24.01.2019
Valid from: 09.2018

Version: 2.1.0 (2.0.1)

STOT-single exposure
The product has not been tested.
STOT-repeated exposure
The product has not been tested.
Aspiration hazard
The product has not been tested.

11.2 Toxicokinetics, metabolism and distribution
The product has not been tested.

11.3 Other adverse effects
No data available.

11.4 Additional information
No data available.

12. Ecological information
12.1 Toxicity

Aquatic toxicity
Acute (short-term) fish toxicity
The product has not been tested.
Chronic (long-term) fish toxicity
The product has not been tested.
Acute (short-term) daphnia toxicity
The product has not been tested.
Chronic (long-term) daphnia toxicity
The product has not been tested.
Acute (short-term) algae toxicity
The product has not been tested.
Acute (long-term) algae toxicity
The product has not been tested.
Bacteria toxicity
The product has not been tested.
Terrestrial toxicity
The product has not been tested.
Toxicity to terrestrial plants
The product has not been tested.
Effects in sewage plants
Technically correct releases of minimal concentrations to adapted biological sewage plants, will not disturb the biodegradability ofactivated sludge.

12.2 Persistence and degradability

Abiotic degradation
The product can be eliminated from water by abiotic processes, e.g. adsorption on activated sludge.
Biodegradation
Parameter :Biodegradation
Evaluation parameter :Biodegradation
Degradation rate :0%
Test durarion :28 dEvaluation :Not readily biodegradable (according to OECD criteria)
Method :OECD 310
Not readily biodegradable (according to OECD criteria).

12.3 Bioaccumulative potential

The product has not been tested.

12.4 Mobility in soil
The product has not been tested.
Seite : 7 / 9Peter Huber Kältemaschinenbau AG · Werner-von-Siemens-Str. 1 · 77656 Offenburg · Tel. +49 781-9603-0 · www.huber-online.com · info@huber-online.com

Safety Data Sheet

According to Regulation (EC) No. 1907 /2006 /REACH)
Trade name: SilOil M90.055/170.03
No.: 6258,6259
Print date: 24.01.2019
Valid from: 09.2018

Version: 2.1.0 (2.0.1)

12.5 Results of PBT and vPvB assessment

Dodecamethylcyclohexasiloxane (D6) meets the current EU REACH Annex XIII criteria for vPvB and has been added to thecandidate list for Substances of very high concern (SVHC). However, D6 does not behave similarly to known PBT/vPvB
substances. The silicones industries interpretation of the available data is that the weight of scientific evidence from fieldstudies shows that D6 is not biomagnifying in aquatic and terrestrial food webs. D6 in air will degrade by naturally
occurring reactions in the atmosphere. Any D6 in air that does not degrade by these reactions is not expected to deposit
from the air to water, to land, or to living organisms.

12.6 Other adverse effects
No data available.

12.7 Additional ecotoxicological information
No data available.

13. Disposal considerations
13.1 Waste treatment methods

Waste disposal according to directive 2008/98/EC, covering waste and dangerous waste. Consult the appropriate local waste disposal
expert about waste disposal.
Product / Packaging disposal
Waste treatment options
Appropriate disposal / Product
The allocation of waste identity numbers/waste descriptions must be carried out according to the EEC, specific to the industry andprocess.
Appropriate disposal / Package
Handle contaminated packages in the same way as the substance itself.

14. Transport information
14.1 UN number
No dangerous goods in sense of this transport regulation.

14.2 UN proper shipping name

No dangerous good in sense of these transport regulations.

14.3 Transport hazard class(es)No dangerous good in sense of these transport regulations.

14.4 Packing group
No dangerous good in sense of these transport regulations.

14.5 Environmental hazards

No dangerous good in sense of these transport regulations.

14.6 Special precautions for user
None.

15.

Regulatory information

15.1 Safety, health and environmental regulations / legislation specific for the substance or mixture
National regulations
Technische Anleitung Luft (TA-Luft)Sum organic substances class III : 95 - 100 %Water hazard class (WGK)Class : 1 (Slightly hazardous to water) Classification according to AwSV.

15.2 Chemical safety assessment
No information available.
Seite : 8 / 9Peter Huber Kältemaschinenbau AG · Werner-von-Siemens-Str. 1 · 77656 Offenburg · Tel. +49 781-9603-0 · www.huber-online.com · info@huber-online.com

Safety Data Sheet

According to Regulation (EC) No. 1907 /2006 /REACH)
Trade name: SilOil M90.055/170.03
No.: 6258,6259
Print date: 24.01.2019
Valid from: 09.2018

Version: 2.1.0 (2.0.1)

16. Other information
16.1 Indication of changes

02. Label elements · 02. Labelling according to Regulation (EC) No. 1272/2008 [CLP] · 03. Hazardous ingredients

16.2 Abbreviations and acronyms

REACH - Registration, Evaluation, Authorisation of Chemicals
GHS - Globally Hamonised System of Classifikation and Labeling
CLP - Classification, Labeling and Packaging of Substances and Mixtures
CAS - Chemical Abstract Service
TWA - Time Weighted Average
DNEL / DMEL - Derived No Effect Level
PNEC - Predicted No Effect Concentration
STP - Sewage Treatment Plant
TRGS - Technical Rules for Hazardous Substances (German Regulations)
STEL - Short-term Exposure Limit
TLV - threshold limit value
AGW - Occupational threshold limit value
RCP - Reciprocal Calculation Procedure
ATE - Acute Toxicity Estimate
MAK - Treshold limit values Germany
LD50 - Lethal Dosie, 50%
LC50 - Lethal concentration, 50%
OECD - Organization for Economic Cooperation and Development
NOAEL - No Observed Adverse Effect Level
EC50 - half maximal effective concentration
NOEC - No Observed Effect Concentration
PBT - Persistent, Bioaccumulative, Toxic
vPvB - very Persistent, very Bioaccumulative
ADR / RID - European Agreement concerning the International Carriage of Dangerous Goods by Road (Accord européen relatif autransport international des marchandises Dangereuses par Route)/Regulations Concerning the International Transport of Dangerous
Goods by Rail (Règlement concernant le transport International ferroviaire de marchandises Dangereuses)
IMDG - International Maritime Dangerous Goods CodeICAO - International Civil Aviation Association
IATA - International Air Transport Association
VwVws - German administrative regulation on the classification of substances hazardous to water into water hazard Classes.

16.3 Key literature references and sources for data
None.

16.4 Classification for mixtures and used evaluation method according to regulation (EC) 1272/2008[CLP]
No information available.

16.5 Relevant H- and EUH-phrases (Number and full text)
None.

16.6 Training advice
None.

16.7 Additional information
None.

The above information describes exclusively the safety requirements of the product and is based on our present-day knowledge. The
information is intended to give you advice about the safe handling of the product named in this safety data sheet, for storage, processing,transport and disposal. The information cannot be transferred to other products. In the case of mixing the product with other products or in thecase of processing, the information on this safety data sheet is not necessarily valid for the new made-up material.
Seite : 9 / 9Peter Huber Kältemaschinenbau AG · Werner-von-Siemens-Str. 1 · 77656 Offenburg · Tel. +49 781-9603-0 · www.huber-online.com · info@huber-online.com