high precision thermoregulation

Safety Data Sheet Page 1 of 8
according to Regulation (EC) No. 1907/2006

Print Date: 12.10.09

Revision Date: 06.10.09

Trade name: Monoethylene glycol
1. Identification of the substance/preparation and of the company/undertaking:Product details
Use of the substance/preparation
Functional Fluids
Industry sector:
Type of use:

Brine for refrigeration

Supplier:

Peter HUBER Kältemaschinenbau GmbH

Werner-von-Siemens-Str. 1
D-77656 Offenburg / Germany
Tel.: +49 (0)781/9603-0 Fax: +49 (0)781/57211
Emergency telephone:

00800-5121 5121 (24 h)

2. Composition / information on ingredients
Chemical characterization: Monoethylene glycol (1,2-ethane diol) with corrosion inhibitors
Hazardous ingredients
Ethandiol
Concentration:
CAS number:
EINECS number:
Hazard symbols:
R-phrases:

90 – 95%
107-21-1
203-473-3
Xn
22

Disodioum tetraborate, anhydrous
Concentration:< 1,2%CAS number:
1330-43-4
EINECS number:
215-540-4
Hazard symbols:
TR-phrases:
60
61
Sodium nitrite
Concentration:
CAS number:
EINECS number:
Hazard symbols:
R-phrases:< 0,6%
7632-00-0
231-555-9
OT
825N50

The text of the R-phrases is shown in section 16.

PETER HUBER KÄLTEMASCHINENBAU GMBH
Werner-von-Siemens-Strasse 1
D-77656 Offenburg
Tel. +49-781-9603-0
Fax +49-781-57211
www.huber-online.com
info@huber-online.com

Erfüllungsort und Gerichtsstand 77656 Offenburg
Amtsgericht Freiburg HRB 470917
Steuernummer: 14044/00050, Finanzamt Offenburg
USt-IdNr.: DE 811286033
Geschäftsführer: Peter Huber, Daniel Huber, Joe Huber

Sparkasse Offenburg-Ortenau

BW-Bank Stuttgart

BLZ 664 500 50
Konto 5 092
Swift/BIC SOLA DE SI
IBAN DE 17 6645 0050 0000 0050 92

BLZ 600 501 01
Konto 741 3500 626
Swift/BIC SOLA DE ST
IBAN DE 92 6005 0101 7413 5006 26

high precision thermoregulation

Safety Data Sheet Page 2 of 8
according to Regulation (EC) No. 1907/2006

Print Date: 12.10.09

Revision Date: 06.10.09

Trade name: Monoethylene glycol
3. Hazards identification
Harmful if swallowed.

4. First aid measures
General information
Remove soiled or soaked clothing immediately
After inhalation
In the event of symptoms seek medical advice.
After contact with skinIn case of contact with skin wash off immediately with plenty of water
After contact with eyes
In case of contact with eyes rinse thoroughly with plenty of water and seek medical advice
After ingestion
Summon a doctor immediately.

5. Fire-fighting measures
Suitable extinguishing media:

Special hazards from the substance itself,
its combustion products or from its vapours:

Special protective equipment for firefighting:Water spray jet
alcohol-resistant foamcarbon dioxide
dry powder
In case of fires, hazardous combustion gases are formed:
Carbon monoxide (CO)
Nitrous gases (NOx)Use self-contained breathing apparatus

6. Accidental release measures
Personal precautions:

Ensure adequate ventilation.
Wear suitable personal protective equipment.

Environmental precautions:

Do not allow to enter drains or waterways

Methods for cleaning up(taking up:

Pick up with absorbent material (eg. sand, kieselgur, acid binder,sawdust)
Dispose of as prescribed

PETER HUBER KÄLTEMASCHINENBAU GMBH
Werner-von-Siemens-Strasse 1
D-77656 Offenburg
Tel. +49-781-9603-0
Fax +49-781-57211
www.huber-online.com
info@huber-online.com

Erfüllungsort und Gerichtsstand 77656 Offenburg
Amtsgericht Freiburg HRB 470917Steuernummer: 14044/00050, Finanzamt Offenburg
USt-IdNr.: DE 811286033
Geschäftsführer: Peter Huber, Daniel Huber, Joe Huber

Sparkasse Offenburg-Ortenau

BW-Bank Stuttgart

BLZ 664 500 50
Konto 5 092
Swift/BIC SOLA DE SI
IBAN DE 17 6645 0050 0000 0050 92

BLZ 600 501 01
Konto 741 3500 626
Swift/BIC SOLA DE ST
IBAN DE 92 6005 0101 7413 5006 26

high precision thermoregulation

Safety Data Sheet Page 3 of 8
according to Regulation (EC) No. 1907/2006

Print Date: 12.10.09

Revision Date: 06.10.09

Trade name: Monoethylene glycol
7. Handling and storage:
Advice on safe handlingOpen and handle container with care.
Provide good ventilation of working area (locaal exhaust ventilation if necessary).

8. Exposure controls / personal protection:
Occupational exposure controls
Exposure limit values
Ethylene glycol
CAS number:
107-21-1
Directive on indicative exposure limits (amended)
EU OEL – Directive on indicative on indicative exposure limits
Revision:
08/06/2000
Notations
Skin
Ethylene glycol
CAS number:
107-21-1
Directive on indicative exposure limits (amended)
EU OEL – Directive on indicative exposure limits
Revision:
08/06/2000Limit values time-weighted average – 8 hours
Values:52 mg/m3
20 ppmEthylene glycol
CAS number:
107-21-1
Directive on indicative exposure limits (amended)
EU OEL – Directive on indicative exposure limits
Revision:
08/06/2000
Limit values short-term – 15 min.
Values:
104 mg/m3^ 40 ppm
General protective measures
Do not ihale vapours
Avoid contact with eyes and skinHygiene measures
Keep away from foodstuff and beverages.

PETER HUBER KÄLTEMASCHINENBAU GMBH
Werner-von-Siemens-Strasse 1
D-77656 Offenburg
Tel. +49-781-9603-0
Fax +49-781-57211
www.huber-online.com
info@huber-online.com

Erfüllungsort und Gerichtsstand 77656 Offenburg
Amtsgericht Freiburg HRB 470917
Steuernummer: 14044/00050, Finanzamt Offenburg
USt-IdNr.: DE 811286033
Geschäftsführer: Peter Huber, Daniel Huber, Joe Huber

Sparkasse Offenburg-Ortenau

BW-Bank Stuttgart

BLZ 664 500 50
Konto 5 092
Swift/BIC SOLA DE SI
IBAN DE 17 6645 0050 0000 0050 92

BLZ 600 501 01
Konto 741 3500 626
Swift/BIC SOLA DE ST
IBAN DE 92 6005 0101 7413 5006 26

high precision thermoregulation

Safety Data Sheet Page 4 of 8
according to Regulation (EC) No. 1907/2006

Print Date: 12.10.09

Revision Date: 06.10.09

Trade name: Monoethylene glycol
Respiratory protection:

Hand protection:

Use respiratory protection in case of insufficient exhaust ventilation or
prolonged exposure
Full mask to standard DIN EN 136
Filter A (organic gases and vapours) to standard DIN EN 141
The use of filter apparatus presupposes that the environment atmospherecontains at least 17% oxygen by volume, and does not exceed themaximum gas concentration, usually 0.5% by volume. Relevant guidelines tobe considered include EN 136/141/143/371/372 as well as other nationalregulations.
For long-term exposure:
Butyl rubber gloves
Minimum breakthrough time / gloves: 480 min
Minimum thickness / gloves 0,7 mm
For short-term exposure (splash protection):
Nitrile rubber gloves.
Minimum breakthrough time / gloves: 30 min
Minimum thickness / gloves 0,4 mm
These types of protective gloves are offered by various manufactures.
Please note the manufacturers´ detailed statements, epecially about theminimum thickness and the minimum breakthrough time. Consider also theparticular working conditions under which the gloves are being used.

Eye protection:

Depending on the risk, wear sufficient eye protection (safety glasses withside protection or goggles, and if necessary, face shield.)

9. Physical and chemical properties:
Form:
Colour:Odour:
Pourpoint:
Flash point:
Flash point:

Ignition temperature:
Oxidizing properties:
Self-ignition temperature:

Liquidyellow
slightly perceptible
approx. -70°C
Method: ASTM D 1120
No flash point – Measure made up to the boling point.
approx. 119°C
Method: DIN 51758 (closed cup)
Information applies to the solvent
approx. 410°CMethod: DIN 51794
Not applicable
not self-igniting

PETER HUBER KÄLTEMASCHINENBAU GMBH
Werner-von-Siemens-Strasse 1
D-77656 Offenburg
Tel. +49-781-9603-0
Fax +49-781-57211
www.huber-online.com
info@huber-online.com

Erfüllungsort und Gerichtsstand 77656 Offenburg
Amtsgericht Freiburg HRB 470917
Steuernummer: 14044/00050, Finanzamt Offenburg
USt-IdNr.: DE 811286033
Geschäftsführer: Peter Huber, Daniel Huber, Joe Huber

Sparkasse Offenburg-Ortenau

BW-Bank Stuttgart

BLZ 664 500 50
Konto 5 092
Swift/BIC SOLA DE SI
IBAN DE 17 6645 0050 0000 0050 92

BLZ 600 501 01
Konto 741 3500 626
Swift/BIC SOLA DE ST
IBAN DE 92 6005 0101 7413 5006 26

high precision thermoregulation

Safety Data Sheet Page 5 of 8
according to Regulation (EC) No. 1907/2006

Print Date: 12.10.09

Revision Date: 06.10.09

Trade name: Monoethylene glycol
Flammability
Lower explosion limit:
Upper explosion limit:
Combustion number:
Evaporation rate:
Vapour pressure:
Density:
Bulk density:
Vapour density in relation
to air:Solubility in water:
Soluble in ...:
pH value:
Octanol/water partition
coefficient (log Pow):Viscosity (dynamic):
Viscosity (kinematic):
Further information:

3% (V)
Data relate to solvent
not tested.
Not applicable
not tested< 0,01 kPa (20°C)
Method: Calculated by Syracuse.
approx. 1,13 g/cm3 (20°C)
Method: DIN 51757
Not applicable
not tested(20°C)
Miscible in all proportions
fat
Not tested
7,7 – 8,3 (20°C, 300 g/l)
Method: DIN 19268
Not applicableapprox. 26 mPa.s (23°C)
Method: calculated
approx. 23 mm2/s (20°C)
Method: DIN 51562
The product is hygroscopic.

10. Stability and reactivityThermal decomposition:

approx. 260°C
Method: DSC

Hazardous reactions:

Reactions with alkalies
Reactions with oxidising agents

PETER HUBER KÄLTEMASCHINENBAU GMBH
Werner-von-Siemens-Strasse 1D-77656 Offenburg
Tel. +49-781-9603-0
Fax +49-781-57211
www.huber-online.com
info@huber-online.com

Erfüllungsort und Gerichtsstand 77656 Offenburg
Amtsgericht Freiburg HRB 470917
Steuernummer: 14044/00050, Finanzamt Offenburg
USt-IdNr.: DE 811286033
Geschäftsführer: Peter Huber, Daniel Huber, Joe Huber

Sparkasse Offenburg-Ortenau

BW-Bank Stuttgart

BLZ 664 500 50Konto 5 092
Swift/BIC SOLA DE SI
IBAN DE 17 6645 0050 0000 0050 92

BLZ 600 501 01
Konto 741 3500 626
Swift/BIC SOLA DE ST
IBAN DE 92 6005 0101 7413 5006 26

high precision thermoregulation

Safety Data Sheet Page 6 of 8
according to Regulation (EC) No. 1907/2006

Print Date: 12.10.09

Revision Date: 06.10.09

Trade name: Monoethylene glycol
11. Toxicological information
Acute oral toxicity:

Acute inhalation toxicity:
Acute dermal toxicity:
Irritant effect on skin:

Irritant effect on eyes:

Sensitization:
Mutagenicity:
Remarks:

LD50 4.000 mg/kg (rat)
Source: IUCLID
Information based on the main component
not tested
not tested
non-irritant (rabbit)
Source: IUCLID
Data relate to main component
slightly irritant (rabbit eye)
Source: IUCLID
Data relate to main component
not tested
not tested
Vapours and mists cause irritation/burns to eyes and the respiratory tract
There is a possibility of kidney damage
Poisoning affects the central nervous system
The product was classified on the basis of the calculation procedure of thedangerous
Preparations Directive (1999/45/EC).

12. Ecological information
Biodegradability:> 90%Good degradability
Method: Zahn-Wellens test
By analogy with a similar product.
LC0
1.000 mg/l (golden orfe)
LL50 > 100 mg/l (96 h, Zebra fish (Danio rerio))
Method: OECD 203
By analogy with a similar product.
If handled correctly it causes no disturbance in treatment plants.
The product was classified according to the calculation method of the EU
dangerous
Preparations Directive

Fish toxicity:

Remarks:

PETER HUBER KÄLTEMASCHINENBAU GMBH
Werner-von-Siemens-Strasse 1D-77656 Offenburg
Tel. +49-781-9603-0
Fax +49-781-57211
www.huber-online.com
info@huber-online.com

Erfüllungsort und Gerichtsstand 77656 Offenburg
Amtsgericht Freiburg HRB 470917
Steuernummer: 14044/00050, Finanzamt Offenburg
USt-IdNr.: DE 811286033
Geschäftsführer: Peter Huber, Daniel Huber, Joe Huber

Sparkasse Offenburg-Ortenau

BW-Bank Stuttgart

BLZ 664 500 50
Konto 5 092
Swift/BIC SOLA DE SI
IBAN DE 17 6645 0050 0000 0050 92

BLZ 600 501 01
Konto 741 3500 626
Swift/BIC SOLA DE ST
IBAN DE 92 6005 0101 7413 5006 26

high precision thermoregulation

Safety Data Sheet Page 7 of 8
according to Regulation (EC) No. 1907/2006

Print Date: 12.10.09

Revision Date: 06.10.09

Trade name: Monoethylene glycol
13. Disposal considerations
Product:

In according with local authority regulations, take to special waste incineration plant

14. Transport information
ADR:
ADNR:
RID:
IATA:
IMDG:

not restricted
not restricted
not restricted
not restricted
not restricted

15. Regulatory information
Labelling in accordance with EC-Directives
Hazard warning labelling compulsory
Classification according to the calculation procedure of the Dangerous Preparations Directive (1999/45/EC).
Hazard symbols
XnHarmful
Hazardous component(s) to be indicated on label
Ethanediol
R-phrases
22

Harmful if swallowed

S-phrases
224/25

Keep out of the reach of children
Avoid contact with skin and eyes

Chemical Safety Assessment
No Chemical Safety Assessment (CSA) is yet available for the substance, or for the component substances,
contained in this product.

16. Other information
Text of the R-phrases assigned to the ingredients/components mentioned in section 3:
22
Harmful if swallowed
25
Toxic if swallowed
50
Very toxic to aquatic organisms
60
May impair fertility
61
May cause harm to the unborn child
8Contact with combustible material may cause fire

PETER HUBER KÄLTEMASCHINENBAU GMBH
Werner-von-Siemens-Strasse 1D-77656 Offenburg
Tel. +49-781-9603-0
Fax +49-781-57211
www.huber-online.com
info@huber-online.com

Erfüllungsort und Gerichtsstand 77656 Offenburg
Amtsgericht Freiburg HRB 470917
Steuernummer: 14044/00050, Finanzamt Offenburg
USt-IdNr.: DE 811286033
Geschäftsführer: Peter Huber, Daniel Huber, Joe Huber

Sparkasse Offenburg-Ortenau

BW-Bank Stuttgart

BLZ 664 500 50
Konto 5 092
Swift/BIC SOLA DE SI
IBAN DE 17 6645 0050 0000 0050 92

BLZ 600 501 01
Konto 741 3500 626
Swift/BIC SOLA DE ST
IBAN DE 92 6005 0101 7413 5006 26

high precision thermoregulation

Safety Data Sheet Page 8 of 8
according to Regulation (EC) No. 1907/2006

Print Date: 12.10.09

Revision Date: 06.10.09

Trade name: Monoethylene glycol
Decimal notation: “Thousands” places are identified with a dot (example: 2.000 mg/kg means “two thousandmg/kg”). Decimal places are identified with a comma (example: 1,35 g/cm3).
The data are based on the current state of our knowledge, and are intended to describe the product with regard tothe requirements of safety. The data should not be taken to imply any guarantee of a particular or generalspecification. It is the responsibility of the user of the product to ensure to his satisfaction that the product issuitable for the intended purpose and method of use. We do not accept responsibility for any harm caused by theuse of this information. In all cases, our general conditions of sale apply.

PETER HUBER KÄLTEMASCHINENBAU GMBH
Werner-von-Siemens-Strasse 1D-77656 Offenburg
Tel. +49-781-9603-0
Fax +49-781-57211
www.huber-online.com
info@huber-online.com

Erfüllungsort und Gerichtsstand 77656 Offenburg
Amtsgericht Freiburg HRB 470917
Steuernummer: 14044/00050, Finanzamt Offenburg
USt-IdNr.: DE 811286033
Geschäftsführer: Peter Huber, Daniel Huber, Joe Huber

Sparkasse Offenburg-Ortenau

BW-Bank Stuttgart

BLZ 664 500 50
Konto 5 092
Swift/BIC SOLA DE SI
IBAN DE 17 6645 0050 0000 0050 92

BLZ 600 501 01
Konto 741 3500 626
Swift/BIC SOLA DE ST
IBAN DE 92 6005 0101 7413 5006 26