Raise3D Premium PVA+_SDS

June.2021

Version 1.1

Raise3D Premium PVA+ Safety Data Sheet

Section 1: PRODUCT AND COMPANY IDENTIFICATION
1.1 Trade name:Raise3D Premium PVA+ 3D Printing Filament
1.2 Use of the product:
3D Printer Filament
1.3 Supplier information
Supplier:
Raise 3D Technologies, Inc.
Address:
43 Tesla, Irvine, CA 92618
Emergency phone number: In case of toxicological emergency, contact your doctor.

Section 2: HAZARDS IDENTIFICATION
2.1 Classification of the substance or mixture classification (REGULATION (EC) No 1272/2008)
This product is not classified according to Regulation (EC) 1272/2008 and Directive 67/548/EEC.
2.2 Label elements
Not applicable.
2.3 Other hazards
Skin sensitization material (Category 1) is contained less than 0.1%.

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Section 3: COMPOSITION / INFORMATION ON INGREDIENTS
Mixtures
Chemical Name%

Cas No./EC No

Polyvinyl Alcohol Compound>96-Aliphatic polyol<20-Calcium distearate<2

1592-23-0

Methanol (impurity)*<167-56-1
200-659-6*Classification: Flam. Liq. 2; H225, Acute Tox. 3; H301, Acute Tox. 3; H311, Acute Tox. 3; H331,STOT SE 1; H370

Section 4: FIRST AID MEASURES
4.1 Description of first aid measures
4.1.1 General advice:
If you feel unwell, seek medical advice (show the label where possible). Never give anything by mouth toan unconscious person. Take off contaminated clothing and shoes immediately.
4.1.2 If inhaled:
If breathed in, move person into fresh air.
4.1.3 In case of skin contact:
If on skin, rinse well with water. If skin irritation persists, call a physician.
4.1.4 In case of eye contact:
If easy to do, remove contact lens, if worn. In the case of contact with eyes, rinse immediately with plentyof water and seek medical advice.
4.1.4 If swallowed:
Rinse mouth with water. Induce vomiting immediately and call a physician. If a person vomits when lying
on his back, place him in the recovery position.
4.2 Most important symptoms and effects, both acute and delayed
no data available
4.3 Indication of any immediate medical attention and special treatment needed
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no data available.

Section 5: FIRE FIGHTING MEASURES
5.1 Extinguishing media
Suitable extinguishing media:
Water fog, Dry chemical
Unsuitable extinguishing media:
Do not use a solid water stream as it may scatter and spread fire.
5.2 Special hazards arising from the substance or mixture
Specific hazards during firefighting:Do not use a solid water stream as it may scatter and spread fire. Exposure to decomposition products
may be a hazard to health.
5.3 Advice for fire fighters
Special protective equipment for firefighters:
Wear self-contained breathing apparatus for firefighting if necessary. Use personal protective equipment.
Further information:
Standard procedure for chemical fires. Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment. In the event of fire and/or explosion do not breathe
fumes.

Section 6: ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures
Avoid dust formation. Avoid breathing dust. Ensure adequate ventilation, especially in confined areas.
6.2 Environmental precautions
no data available.
6.3 Methods and materials for containment and cleaning up
Avoid dust formation. Collect dust or particulates using a vacuum cleaner with a HEPA filter. Do not use
compressed air when cleaning.

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Section 7: HANDING AND STORAGE
7.1 Handling
Advice on safe handling:
For personal protection see section 8. Avoid creating dust. Do not breathe dust. Avoid contact with skinand eyes.
Advice on protection against fire and explosion:
Normal measures for preventive fire protection.
Dust explosion class:No data available.
7.2 Conditions for safe storage, including any incompatibilities
Requirements for storage areas and containers:
store spool in the original vacuumized and sealed bag in a dry, cool and ventilated place.
Further information on storage conditions:
After opening the vacuumized bag, Protect from moisture.
Advice on common storage:
Keep away from oxidizing agents and strongly acid or alkaline materials. Keep away from food, drink andanimal feeding stuffs.
Storage temperature:> 0 °C and <= 40 °C
Other data:
No decomposition if stored and applied as directed.

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Section 8: EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters
Components

CAS No.

Type

Value

Methanol (impurity)

67-56-1

STEL

333 mg/m3

Detail

250 ppm
TWA:

266 mg/m3
200 ppm

Aliphatic polyol-PEL

5 mg/m3

Respirable

15 mg/m3

fraction. Total
dust.

Dust

-PEL

5 mg/m3

Respirable

15 mg/m3

fraction. Total
dust.

8.2 Exposure controls
Use local exhaust ventilation to maintain airborne concentrations below the TLV. Suitable respiratory
equipment should be used in cases of insufficient ventilation or where operational procedures demand it.
For guidance on engineering control measures refer to publications such as the ACGIH current edition of'Industrial Ventilation, a manual of Recommended Practice.
8.3 Personal protective equipment
Engineering measures
Provide sufficient ventilation for operations causing dust formation. During thermoplastic reprocessing atelevated temperatures, where risk of mist emission from the aliphatic polyol component exists, provide
sufficient ventilation. Follow occupational exposure limit values for dusts or mists, where applicable.
Ventilate as needed to control airborne dust or mist. Use explosion-proof electrical equipment if airborne
dust or mist levels are high.
Personal protective equipment
Respiratory protection:
In case of dust: Use a NIOSH/MSHA approved air purifying respirator as needed to control exposure.
Consult with respirator manufacturer to determine respirator selection, use, and limitations. Use positive
pressure, air-supplied respirator for uncontrolled releases or when air purifying respirator limitations may
be exceeded. Follow respirator protection program requirements (OSHA 1910.134 and ANSI Z88.2) for
all respirator use. In case of risk of inhalation of mists during thermoplastic reprocessing at elevated

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temperatures, use suitable respiratory equipment with combined filter for organic gases and particles(type A2P2 or comparable).
Hand protection: Rubber gloves
Eye protection: Goggles
Skin and body protection: Apron
Hygiene measures:Handle in accordance with good industrial hygiene and safety practice. General industrial hygiene
practice. Do not breathe dust. Avoid contact with skin, eyes and clothing. When using do not eat, drink orsmoke. Wash hands before breaks and at the end of workday. Wash contaminated clothing before reuse.
Environmental exposure controls:
no data available

Section 9: PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Appearance: Solid Filament
Odour: Sligth vinegar
Colour: Yellow to pale yellow
Odour threshold: No information available
pH: 5.0-7.0Melting/freezing point: 150-230 °C / Initial boiling point and boiling range: Not applicableFlash point: >200 °C
Evaporation rate: Not applicable
Flammability (solid, gas): No information available
Upper/lower flammability or explosive limits
UEL: No data available
LEL: 35 g/m3
Vapour pressure: Not applicable
Vapour density: Not applicable
Relative density: 1.19 – 1.31 g/cm3
Solubility(ies): Unlimited solubility 100.00 g/L
Partition coefficient (n-octanol/water): Not available
Auto-ignition temperature: 520 °C
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Viscosity: Not applicable
Explosive properties: Dust explosion risk at fine dust
Oxidizing properties:
Oxidizing potential: not oxidizing

Section 10: STABILITY AND REACTIVITY
10.1 Reactivity:
The product is stable and non-reactive under normal conditions of use, storage and transport.
10.2 Chemical stability:
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions:
No decomposition if stored and applied as directed. Dust can form an explosive mixture in air.
10.4 Conditions to avoid:
Avoid elevated temperatures for prolonged periods of time. While printing, keep away from sparks andopen flame.
10.5 Incompatible materials:
Materials to avoid: Oxidizing agents, Acids, Bases
10.6 Hazardous decomposition products
Build-up of dangerous/toxic fumes possible in cases of fire/high temperature.

Section 11: TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects
Component: Methanol (impurity) CAS 67-56-1
Acute toxicity
Acute oral toxicity: LD50 Oral: > 2,000 mg/kg
Acute inhalation toxicity: Acute toxicity estimate: > 20 mg/L
Test atmosphere: vapor
Exposure time: 4h7

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Method: Calculation method
Acute dermal toxicity:
Acute toxicity estimate: > 2,000 mg/kg
Method: Calculation method
Acute toxicity (other routes of administration)
methanol:Species: rabbit
No skin irritation
Skin corrosion/irritation
Prolonged skin contact may cause temporary irritation
Serious eye damage/eye irritation
Direct contact with eyes may cause temporary irritation
Respiratory or skin sensitationNot expected to cause respiratory or skin sensitation
Germ cell mutagenicity
No data available to indicate product or any components present at greater than 0,1% are mutagenic orgenotoxic
Carcinogenicity
Not classified as to carcinogenicity to humans
Reproductive toxicity:
Based on available data, the classification criteria are not met
Teratogenicity: no data available
STOT - single exposure: Not classified
STOT - repeated exposure: Not classified
Aspiration hazard: Not a aspiration hazard

Section 12: ECOLOGICAL INFORMATION

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12.1 Toxicity
The product is not classified as environmentally hazardous.
Components: Test results
Methanol (Impurity)(67-56-1)
EC50 Algae: 22000 mg/l 96 hours
EC50 Daphnia magna: > 10000mgl/48 hours
LC50 Fish: 15400 mg/l 96 hours
12.2 Persistence and degradability
No data is available on the degradability.
12.3 Bioaccumulative potential
No data available.
12.4 Mobility in soil
No data available.
12.5 Other adverse effects
No data available.
12.6 Mobility in soil
Additional ecological information:
If the PVA filament is dissolved in water, the effluent can be disposed of through the drain, but only if thiseffluent is eventually treated in a waste water treatment plant.

Section 13: DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods
Disposal method
Disposal:
In accordance with local and national regulations. Waste codes should be assigned by the user basedon the application for which the product was used.

Section 14: TRANSPORT INFORMATION
14.1 UN number
Not regulated as a hazardous material.

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14.2 UN proper shipping nameNot applicable.
14.3 Transport hazard class(es)Not applicable.
14.4 Packing GroupNot applicable.
14.5 Environmental hazards
No additional data is available.
14.6 Special precautions for user
No data available.
14.7 Transport in bulk according to Annex II of MARPOL73/78 and the IBC CodeNot evaluated.

Section 15: REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixtureRegulation (EC) No. 1907/2006, REACH Article 59(1). Candidate ListNot listed.
15.2 Chemical Safety Assessment
no data available

Section 16: OTHER INFORMATION
Revision information
Date of this revision: June 11, 2021
Declare to reader
Information is referenced from other manufacturers.
For abbreviations and acronyms, see: ECHA Guidance on information requirements and chemical safetyassessment, chapter R.20 (Table of terms and abbreviations).
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This safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006 and Regulation(EC) No. 2015/830. Label element according to Regulation (EC) No 1272/2008.
The information above is believed to be accurate and represents the best information currently available
to us. However, we make no warranty of merchantability or any other warranty, express or implied, withrespect to such information, and we assume no liability resulting from its use. This shall not constitute aguarantee for any specific product features and shall not establish a legally valid contractual relationship.

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