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独立行政法人日本原子力研究開発機構〒319-1195

研究技術情報部

研究技術情報課

茨城県那珂郡東海村白方白根 2 番地 4

電話 029-282-6387, Fax 029-282-5920, E-mail:ird-support@jaea.go.jp
This report is issued irregularly by Japan Atomic Energy Agency
Inquiries about availability and/or copyright of this report should be addressed toIntellectual Resources Section, Intellectual Resources Department,
Japan Atomic Energy Agency
2-4 Shirakata Shirane, Tokai-mura, Naka-gun, Ibaraki-ken 319-1195 Japan
Tel +81-29-282-6387, Fax +81-29-282-5920, E-mail:ird-support@jaea.go.jp© Japan Atomic Energy Agency, 2008

JAEA-Data/Code 2008-010
ౣಣℂ᛽಴ಽ㔌Ꮏ⒟ࠪࡒࡘ࡟࡯࡚ࠪࡦࠦ࡯࠼ PARC ߩ㐿⊒ᣣᧄේሶജ⎇ⓥ㐿⊒ᯏ᭴ේሶജၮ␆Ꮏቇ⎇ⓥㇱ㐷 Άᢱ࡮᧚ᢱᎿቇ࡙࠾࠶࠻ᵤᐈ 㕏ብ‫ ୖᦺޔ‬ବ⧷‫ޔ‬᫪↰ ᵏᴦ
㧔2008 ᐕ 2 ᦬ 22 ᣣฃℂ㧕ࡇࡘ࡟࠶ࠢࠬᴺߦࠃࠆ૶↪ᷣΆᢱౣಣℂࡊࡠ࠮ࠬߩࠪࡒࡘ࡟࡯࡚ࠪࡦߩߚ߼ߩ᛽಴ಽ㔌⸘▚ࠦ࡯࠼ PARC ࠍᢛ஻ߒߚ‫ޕ‬PARC ߪ‫ޔ‬ౣಣℂᣉ⸳ౝߦ⸳⟎ߐࠇࠆⶄᢙߩㅪ⚿ߐࠇߚࡄ࡞ࠬࠞ࡜ࡓ෸
߮ࡒࠠࠨ࠮࠻࡜ࠍᮨᡆߔࠆߎߣ߇น⢻ߢ‫ޔ‬ฦ᛽಴ེౝߩ࠙࡜ࡦ‫ޔࡓ࠙࠾࠷ࡊࡀޔࡓ࠙࠾࠻࡞ࡊޔ‬ᩭಽⵚ↢ᚑ‛╬ߩ⒖ⴕ᜼േࠍㆊᷰ⸘▚෸߮ቯᏱ⸘▚ߦࠃߞߡࠪࡒࡘ࡟࡯࡚ࠪࡦߔࠆߎߣ߇ߢ߈ࠆ‫ޕ‬ᧄႎ๔ߢߪ‫ޔ‬PARC ߢណ↪ߐࠇߡ޿ࠆ‛⾰⒖േ‫ޔ‬ൻቇ෻ᔕ╬ߩฦ⸘▚ࡕ࠺࡞ߦߟ޿ߡ߹ߣ߼ࠆ
ߣߣ߽ߦ‫౉ޔ‬಴ജࡈࠔࠗ࡞ߩ૞ᚑ଀‫⚿▚⸘ޔ‬ᨐߩ଀ࠍ␜ߒߚ‫ޕ‬

ේሶജ⑼ቇ⎇ⓥᚲ㧔㚢࿷㧕㧦‫ޥ‬319-1195 ⨙ၔ⋵㇊⃗㇭᧲ᶏ᧛⊕ᣇ⊕ᩮ 2㧙4i

JAEA-Data/Code 2008-010

Development of a Computer Code, PARC, for Simulation of
Liquid-Liquid Extraction Process in Reprocessing

Yasuhiro TSUBATA, Toshihide ASAKURA and Yasuji MORITA

Division of Fuels and Material Engineering
Nuclear Science and Engineering Directorate
Japan Atomic Energy Agency
Tokai-mura, Naka-gun, Ibaraki-ken( Received February 22, 2008 )A computer code PARC was developed for simulating liquid-liquid extraction process in the PUREX
reprocessing plant. PARC is able to predict transient behavior and profiles at equilibrium of uranium,
plutonium, neptunium and fission products in several units of pulsed columns and mixer-settlers, which areconnected each other in the PUREX plant.
In this report, mathematical models of mass transfer and chemical reactions employed in PARC aredescribed and an example of PUREX simulation is given.

Keywords: PUREX, Fuel Reprocessing, Mixer-settler, Pulsed Column, Uranium, Plutonium,
Neptunium, Fission Products, Simulation Program

ii

⋡ ᰴ
1.

ߪߓ߼ߦ ···························································································································

1

2.

PARC ߩ᭎ⷐ ····················································································································

2

2.1 ⸘▚ኻ⽎ ·······················································································································

2

2.2 ⸘▚ᯏ⢻ ·······················································································································

3ၮᧄࡕ࠺࡞ ·······················································································································

6

3.1 ࡄ࡞ࠬࠞ࡜ࡓ ···············································································································

6

3.1.1

‛⾰෼ᡰᑼ ···········································································································

6

3.1.2

ࠪࡖࡈ࠻ㇱߦ߅ߌࠆၮᧄࡕ࠺࡞ߩᏅಽ⴫⃻ ·····················································

7

3.1.3

਄ਅಽ⋧࠲ࡦࠢౝᏅಽᑼ ···················································································· 11

3.1.4

ㅒᷙวଥᢙ

3.1.5

‛⾰⒖േࡕ࠺࡞

3.1.6

ಽᢔ⋧ࡎ࡯࡞࠼ࠕ࠶ࡊ

3.1.7

ಽᢔ⋧ᶧṢᓘ ········································································································ 163.

··········································································································· 12···································································································· 13························································································ 15

3.2 ࡒࠠࠨ࠮࠻࡜ ··············································································································· 17
3.2.1‛⾰෼ᡰᑼ ··········································································································· 17

3.2.2ࡒࠠࠨ࠮࠻࡜ౝㇱߦ߅ߌࠆᏅಽᑼ ····································································· 17

3.2.3ࡒࠠࠨ࠮࠻࡜ਔ┵ߦ߅ߌࠆᏅಽᑼ ····································································· 18

3.2.4‛⾰⒖േࡕ࠺࡞ ···································································································· 19

3.3 ࠲ࡦࠢ ··························································································································· 21
3.3.1‛⾰෼ᡰᑼ ··········································································································· 21

3.3.2Ꮕಽᑼ ··················································································································· 21

3.4 ‛ᕈ୯ ··························································································································· 23
3.4.1

ኒᐲ ······················································································································· 23

3.4.2☼ᐲ ······················································································································· 24

3.4.3⇇㕙ᒛജ ··············································································································· 25

4.

ൻቇ⒳ ······························································································································· 29

5.

ൻቇ෻ᔕㅦᐲ ··················································································································· 31
5.1 ᳓⋧ߦ㑐ߔࠆൻቇ෻ᔕㅦᐲᑼ ···················································································· 31
5.2 ᦭ᯏ⋧ߦ㑐ߔࠆൻቇ෻ᔕㅦᐲᑼ ················································································ 38

6.

ಽ㈩Ყ ······························································································································· 41

7.

PARC ߩേ૞ⅣႺߣታⴕᣇᴺ ························································································· 508.

౉ജࡈࠔࠗ࡞ߩᦠᑼ ········································································································ 52
8.1 ౉ജ࠺࡯࠲ߩో૕᭴ᚑ ································································································ 52
8.1.1ၮᧄ᭴ㅧ ··············································································································· 52

8.1.2

ࠦࡔࡦ࠻ߩ⸥ㅀᣇᴺ ···························································································· 53

8.2 ࠠ࡯ࡢ࡯࠼࠺࡯࠲ ········································································································ 54

iii

8.3 ൻቇ෻ᔕߩ౉ജ ··········································································································· 55
8.3.1

ࠗࡦ࠲࡯ࡊ࡝࠲ߩ౉ജ࠺࡯࠲ߩ᭴ㅧߣ⒳㘃 ····················································· 55

8.3.2

ൻቇᑼ෸߮Ớᐲߩ⸥ㅀᣇᴺ ················································································ 55

8.3.3

ൻቇ෻ᔕᑼ ··········································································································· 56

8.3.4 cond ㇱ ·················································································································· 56
8.3.5 case ㇱ ··················································································································· 59
8.3.6

੍⚂⺆෸߮⚵ㄟ㑐ᢙ································································································ 62

8.3.7

ቯᢙ ······················································································································· 63

8.4 ૏⟎࠺࡯࠲ ··················································································································· 65
8.4.1

૏⟎࠺࡯࠲ߩᦠᑼ ································································································ 65

8.4.2

౉ജ࠺࡯࠲ ··········································································································· 66

಴ജࡈࠔࠗ࡞ߩᦠᑼ ········································································································ 88

9.

9.1 ਥⷐ಴ജ㧔".out" ࡈࠔࠗ࡞㧕 ····················································································· 88
9.1.1౉ജ࠺࡯࠲ߩࠛࠦ࡯ࡃ࠶ࠢ ················································································ 88

9.1.2ࡄ࡞ࠬࠞ࡜ࡓߦ㑐ߔࠆ಴ജ ················································································ 88

9.1.3ࡒࠠࠨ࠮࠻࡜ߦ㑐ߔࠆ಴ജ ················································································ 92

9.1.4

᳓⋧࠲ࡦࠢߦ㑐ߔࠆ಴ജ ···················································································· 96

9.1.5

᦭ᯏ⋧࠲ࡦࠢߦ㑐ߔࠆ಴ജ ················································································ 98

9.2 ࡝ࠬ࠲࡯࠻಴ജ㧔".rst"ࡈࠔࠗ࡞㧕 ············································································ 101
9.2.1

౒ㅢ࠺࡯࠲ ··········································································································· 101

9.2.2

ࡄ࡞ࠬࠞ࡜ࡓߩỚᐲߦ㑐ߔࠆ಴ജ ····································································· 101

9.2.3

ࡒࠠࠨ࠮࠻࡜ߩỚᐲߦ㑐ߔࠆ಴ജ ····································································· 102

9.2.4

᳓⋧࠲ࡦࠢߩỚᐲߦ㑐ߔࠆ಴ജ ········································································ 103

9.2.5

᦭ᯏ⋧࠲ࡦࠢߩỚᐲߦ㑐ߔࠆ಴ജ ····································································· 103

9.2.6

ࡄ࡞ࠬࠞ࡜ࡓߩಽ㈩Ყߦ㑐ߔࠆ಴ജ ································································· 104

9.2.7

ࡒࠠࠨ࠮࠻࡜ߩಽ㈩Ყߦ㑐ߔࠆ಴ജ ································································· 104

9.3 ⚻ᤨ಴ജ㧔".trn"ࡈࠔࠗ࡞㧕 ······················································································· 104
9.4 ෼᧤⁁ᘒ಴ജ㧔".cnv"ࡈࠔࠗ࡞㧕 ·············································································· 105
10. PARC ߦࠃࠆ⸘▚ታⴕ଀ ································································································ 106⻢ㄉ··································································································································· 120ෳ⠨ᢥ₂··································································································································· 120

ઃ㍳··································································································································· 124iv

Contents
1.

Introduction

2.

Outline of PARC

3.

·······················································································································

1···············································································································

2

2.1 Object of Calculation ·····································································································

2

2.2 Function of Calculation ··································································································

3

Basic Calculation Model ····································································································

6

3.1

Pulsed Column···········································································································

6

3.1.1

Mass Balance Equation ··························································································

6

3.1.2

Differential Equation for Column Parts ··································································

7

3.1.3

Differential Equation for Settling Parts ·································································· 11

3.1.4

Axial Mixing Coefficient ······················································································· 12

3.1.5

Mass Transfer Model ····························································································· 13

3.1.6 Dispersed Phase Holdup ························································································· 15
3.1.7
3.2

Drop Size ··············································································································· 16

Mixer-Settlers············································································································ 17

3.2.1

Mass Balance Equation ·························································································· 17

3.2.2

Differential Equation for Inside Part ······································································· 17

3.2.3

Differential Equation for End Part ·········································································· 18

3.2.4

Mass Transfer Model ····························································································· 19

3.3

Vessels······················································································································· 21

3.3.1

Mass Balance Equation ·························································································· 21

3.3.2

Differential Equation ······························································································ 21

3.4

Properties of Liquids ·································································································· 23

3.4.1

Density ··················································································································· 23

3.4.2 Viscosity ················································································································ 24
3.4.3 Interfacial Tension ································································································· 25
4.

Chemicals·························································································································· 29

5.

Chemical Reaction Rates··································································································· 31

5.1 Aqueous Phase ··············································································································· 31
5.2 Organic Phase ················································································································ 38
6.

Distribution Ratio ·············································································································· 41

7.

Operating System and Execution Method ·········································································· 50

8.

Format of Input File ··········································································································· 52
8.1 Structure of Input File ······································································································ 52
8.1.1

Fundamental Structure ··························································································· 52

8.1.2

Description of Comments  ····················································································· 53

8.2 Keyword Data ················································································································ 54v

8.3 Description of Chemical Reactions ················································································ 55
8.3.1

Structure of Interpreter Input  ················································································ 55

8.3.2

Description of Chemical Formula and Concentrations ··········································· 55

8.3.3

Description of Reaction Formula ············································································ 56

8.3.4

Cond Part ··············································································································· 56

8.3.5

Case Part ················································································································ 59

8.3.6

Reserved Words and Functions ·············································································· 62

8.3.7

Description of Constants ························································································ 63

8.4 Position Data ·················································································································· 65

9.

8.4.1

Format of Position Data ························································································· 65

8.4.2

Description of Position Data ··················································································· 66

Format of Output Files······································································································· 88

9.1 Major Output (".out" File) ······························································································ 88
9.1.1

Echo of Input Data ································································································· 88

9.1.2 Pulsed Columns ······································································································ 88
9.1.3 Mixer Settlers ········································································································· 92
9.1.4

Aqueous Solution Vessels ······················································································ 96

9.1.5

Organic Solution Vessels ······················································································· 98

9.2 Restart Output (".rst" Files) ···························································································· 101
9.2.1

Common Output ····································································································· 101

9.2.2

Concentrations in Pulsed Columns ········································································· 101

9.2.3

Concentrations in Mixer Settlers ············································································ 102

9.2.4

Concentrations in Aqueous Solution Vessels ·························································· 103

9.2.5

Concentrations in Organic Solution Vessels ··························································· 103

9.2.6

Distribution Ratio in Pulsed Columns ···································································· 104

9.2.7

Distribution Ratio in mixer Settlers ········································································ 104

9.3 Transient Output (".trn" File) ························································································· 104
9.4 Convergence State Output (".cnv" File) ········································································· 105
10. An Example of Calculation of PUREX Process
Acknowledgements
References································································· 106··················································································································· 120································································································································· 120

Appendix ··································································································································· 124vi㧝 ߪߓ߼ߦ
 PUREX ᴺࠍណ↪ߒߚ૶↪ᷣΆᢱߩౣಣℂᣉ⸳ߢߪ‫ޔ‬ਥⷐߥᎿ⒟ߢ޽ࠆಽ㔌࡮ಽ㈩Ꮏ⒟‫࡜࠙ޔ‬ࡦ♖⵾Ꮏ⒟‫⵾♖ࡓ࠙࠾࠻࡞ࡊޔ‬Ꮏ⒟╬ߦࡄ࡞ࠬࠞ࡜ࡓဳ෶ߪࡒࠠࠨ࠮࠻࡜ဳ᛽಴ེ߇ណ↪ߐࠇ⸳⟎ߐࠇߡ޿ࠆ‫ޕ‬ౣಣℂᣉ⸳ߩ⸳⸘‫ޔ‬ㆇォ▤ℂ‫ޔ‬቟ోᕈ⏕଻ߦᒰߚߞߡߪ‫ޔ‬ฦ᛽಴ེౝߩ᡼኿ᕈ‛⾰ߩ⒖ⴕ᜼േࠍᛠីߔࠆߎߣ߇㊀ⷐߢ޽ࠆ‫ޕ‬ ᣣᧄේሶജ⎇ⓥ㐿⊒ᯏ᭴㧔એਅ‫ޟޔ‬ේሶജᯏ᭴‫ޕ߁޿ߣޠ‬㧕ߢߪ‫ޔ‬PUREX ᴺߦࠃࠆౣಣℂࡊࡠ࠮ࠬౝߩ࠙࡜ࡦ‫ޔࡓ࠙࠾࠷ࡊࡀޔࡓ࠙࠾࠻࡞ࡊޔ‬ᩭಽⵚ↢ᚑ‛㧔FP㧕╬ߩ⒖ⴕ᜼േࠍࠪࡒࡘ࡟
࡯࡚ࠪࡦߔࠆߚ߼ߩ⸘▚ࠦ࡯࠼ߣߒߡ PARC㧔Program for Advanced Extraction Process with
Radiation Effect Calculation㧕ࠍᢛ஻ߒߡ߈ߚ‫ޕ‬PARC ߢߪ‫ⶄޔ‬ᢙߩࡄ࡞ࠬࠞ࡜ࡓ෸߮ࡒࠠࠨ࠮࠻࡜
ࠍ⋧੕ߦㅪ⚿ߒߚࡊ࡜ࡦ࠻ߩࠪࡒࡘ࡟࡯࡚ࠪࡦ⸃ᨆ߇น⢻ߢ޽ࠆ‫▚⸘ޕ‬ኻ⽎ߣߢ߈ࠆൻቇᚑಽߪ‫ޔ‬᳓⚛ࠗࠝࡦ, U(IV), U(VI), Pu(III), Pu(IV), Pu(VI), Np(IV), Np(V), Np(VI), Zr, Tc, HNO2 ╬‫ޔ‬29 ൻቇ⒳ߢ޽ࠆ‫ޕ‬PARC ߪ‫߇ࠩ࡯࡙ޔ‬ᜰቯߔࠆฦൻቇ⒳ߦߟ޿ߡ‫㉄ޔ‬ൻㆶర෻ᔕ╬ߩ෻ᔕㅦᐲ‫ޔ‬᳓⋧࡮᦭ᯏ⋧㑆ߩ‛⾰⒖േࠍ⸘▚ߒ‫ޔ‬ฦᤨೞߦ߅ߌࠆฦ᛽಴ེߩฦᲑߩỚᐲಽᏓࠍ಴ജߔࠆᯏ⢻ࠍᜬߞߡ޿ࠆ㧔ㆊᷰ⸘▚ᯏ⢻㧕‫ޔߚ߹ޕ‬ㆊᷰ⸘▚ߩ⚿ᨐࠍၮߦߒߡ‫ޔ‬Ꮏ⒟ో૕߇ᐔⴧߦ೔㆐ߒߚ⁁ᘒࠍ▚಴ߔࠆߎߣ߇ߢ߈ࠆ㧔ቯᏱ⸘▚ᯏ⢻㧕‫ޕ‬ PARC ߩᄢ߈ߥ․㐳ߩ৻ߟߦࠗࡦ࠲ࡊ࡝࠲ᯏ⢻߇޽ࠆ‫ߩߎޕ‬ᯏ⢻ߪ‫ޔ‬PARC ߦᣢߦ⚵ߺㄟ߹ࠇߡ޿ࠆൻቇ⒳ߩቯ⟵‫ޔ‬ൻቇ෻ᔕᑼ‫ޔ‬ൻቇ෻ᔕㅦᐲߩ⸘▚ᑼ‫ޔ‬ಽ㈩෻ᔕߩ⸘▚ᑼࠍ‫ࠆࠃߦࠩ࡯࡙ޔ‬ᜰቯߦᓥߞߡ߶߷છᗧߦᄌᦝߔࠆߎߣ߇น⢻ߣߥࠆ߽ߩߢ޽ࠆ‫ޕ‬ᓥ᧪ߩౣಣℂࡊࡠ࠮ࠬࠪࡒࡘ࡟
࡯࡚ࠪࡦߢߪ‫߇ࠩ࡯࡙ޔ‬ൻቇ෻ᔕࡕ࠺࡞ߩᄌᦝࠍᬌ⸛ߔࠆ㓙ߦߪ‫ޔ‬ᄌᦝߩߟߤ࠰࡯ࠬࡊࡠࠣ࡜ࡓ
ࠍ⋥ធᡷᄌߒౣࠦࡦࡄࠗ࡞ߔࠆ૞ᬺ߇ᔅⷐߣߥࠆߚ߼‫ࠣࡦࡒ࡜ࠣࡠࡊޔ‬෸߮ᢙ୯⸘▚ᛛⴚߦ㑐ߔࠆ⍮⼂߇ዋߥ߆ࠄߕᔅⷐߢ޽ߞߚ‫ޕ‬PARC ߩࠗࡦ࠲ࡊ࡝࠲ᯏ⢻ࠍ೑↪ߔࠆߎߣߢ‫ࠣࡠࡊࠬ࡯࠰ޔ‬࡜ࡓߩ✬㓸૞ᬺ߇ਇⷐߣߥࠆ‫ޔߚ߹ޕ‬ᾘ㔀ߥࡈࠔࠗ࡞▤ℂ૞ᬺ㧔ࡊࡠࠣ࡜ࡓߩࡃ࡯࡚ࠫࡦ▤ℂ㧕
ࠍૐᷫൻߔࠆߎߣ߇ߢ߈ࠆ‫ޕ‬
 PARC ߩ࠰࡯ࠬࡊࡠࠣ࡜ࡓߪ‫ ߡోߪߢ⁁⃻ޔ‬C ⸒⺆ߢ⸥ㅀߐࠇ‫▚⸘ޔ‬ᯏࡂ࡯࠼࠙ࠛࠕ‫࡟ࡍࠝޔ‬࡯࠹ࠖࡦࠣࠪࠬ࠹ࡓ‫․ޔ‬ቯߩ࡜ࠗࡉ࡜࡝ߦଐሽߒߥ޿᳢↪⊛ߥ߽ߩߣߥߞߡ޿ࠆߩߢ‫ߪࠩ࡯࡙ޔ‬ᅢߺߩಣℂ♽ࠍㆬᛯߔࠆߎߣ߇ߢ߈ࠆ‫ޕ‬ ᒰᯏ᭴ߢߪ‫ߢ߹ࠇߎޔ‬ේሶജ⑼ቇ⎇ⓥᚲ࡮Άᢱࠨࠗࠢ࡞቟ోᎿቇ⎇ⓥᣉ⸳㧔NUCEF㧕ߦ߅޿ߡ૶↪ᷣΆᢱࠍ↪޿ߚ᛽಴ಽ㔌⹜㛎ࠍታᣉߒߡ߈ߡ߅ࠅ‫ޔ‬᛽಴ེߩㆇォ᧦ઙߩᬌ⸛෸߮⹜㛎⚿ᨐߩ⸃ᨆߦ⸘▚ࠦ࡯࠼ࠍᵴ↪ߒߡ߈ߚ㧝㧕‫੹ޕ‬ᓟߪ‫ޔ‬PARC ߇‫ޔ‬ౣಣℂᣉ⸳ߩㆇォ᧦ઙߩวℂൻ‫ޔ‬቟ోᕈะ਄ߩᬌ⸛‫ߪߦࠄߐޔ‬ᣂߚߥ᛽಴ಽ㔌ࡊࡠ࠮ࠬߩ⎇ⓥ㐿⊒ߦነਈߔࠆߎߣ߇ᦼᓙߐࠇࠆ‫ޕ‬ ᧄႎ๔ߢߪ‫ޔ‬PARC ߢ↪޿ࠄࠇߡ޿ࠆ‛⾰෼ᡰ‫ޔ‬ಽ㈩ᐔⴧ‫ޔ‬ൻቇ෻ᔕㅦᐲ╬ߩฦ⸘▚ࡕ࠺࡞ߦߟ޿ߡ⺑᣿ߒߡ޿ࠆ‫ޔߚ߹ޕ‬઒ᗐࡊ࡜ࡦ࠻ࠍᗐቯߒߚࠪࡒࡘ࡟࡯࡚ࠪࡦ⸘▚⚿ᨐߩ଀ࠍ޽ࠊߖߡ
␜ߒߚ‫ޔ߅ߥޕ‬PARC ߪๆ෼✢㊂ߩ⹏ଔ߿ഠൻ‛ߩ↢ᚑ╬ߩ᡼኿✢ߩᓇ㗀ࠍ⹏ଔߢ߈ࠆᯏ⢻߽᦭ߒߡ޿ࠆ߇‫ߛ߹ޔ‬ᢛ஻߇ቢోߢߥ޿ㇱಽ߽޽ࠅ‫ޔ‬೎ㅜႎ๔ߔࠆߎߣߣߒᧄႎߢߪኻ⽎ᄖߣߔࠆ‫ޕ‬1㧞 㧼㧭㧾㧯ߩ᭎ⷐ PARC ߇ኻ⽎ߣߔࠆࡊࡠ࠮ࠬ߅ࠃ߮ PARC ߩਥⷐߥ⸘▚ᯏ⢻ߦߟ޿ߡએਅߦ␜ߔ‫ޕ‬㧞㧚㧝 ⸘▚ኻ⽎
PARC ߇ኻ⽎ߣߔࠆౣಣℂࡊࡠ࠮ࠬߪ‫(࡞࠴ࡉ࡝࠻㉄ࡦ࡝ޔ‬TBP)ࠍ᛽಴೷‫ޔ‬n㧙࠼࠺ࠞࡦࠍᏗ㉼೷ߣߔࠆ PUREX ᴺߢ޽ࠆ‫ޔ࡜࠻࠮ࠨࠠࡒޔࡓ࡜ࠞࠬ࡞ࡄޕ‬᳓⋧ߩ࠲ࡦࠢ‫᦭ޔ‬ᯏ⋧ߩ࠲ࡦࠢ㧔એਅ‫ޕ߁޿ߣޠ࠻ࡦࡀ࡯ࡐࡦࠦޟޔ‬㧕ߩ⚵ߺวࠊߖ߆ࠄᚑࠆᄙᲑะᵹ᛽಴ࠪࠬ࠹ࡓߩ⸃ᨆ߇น⢻ߢ޽ࠆ‫ޕ‬㧔㧝㧕ൻቇ⒳ PARC ߢߪ‫▚⸘ޔ‬ኻ⽎ߣߔࠆൻቇ⒳ߣߒߡ‫ޔ‬એਅߩ 29 ᚑಽߩቯ⟵߇⚵ߺㄟ߹ࠇߡ޿ࠆ㧔㧠┨ෳᾖ㧕‫ޕ‬ ᳓⚛ࠗࠝࡦ‫(ࡦ࡜࠙ޔ‬VI)‫(ࡓ࠙࠾࠻࡞ࡊޔ‬IV)‫(ࡓ࠙࠾࠻࡞ࡊޔ‬III)‫(ࡦ࡜࠙ޔ‬IV) ‫ޔ‬⎣㉄ࡅ࠼ࡠࠠࠪ࡞ࠕࡒࡦ㧔HAN㧕‫ޔࡦࠫ࡜࠼ࡅ㉄⎣ޔ‬੝⎣㉄‫ޔࡓ࠙࠴ࡀࠢ࠹ޔࡓ࠙࠾ࠦ࡞ࠫޔ‬ࡀࡊ࠷࠾࠙ࡓ(IV)‫(ࡓ࠙࠾࠷ࡊࡀޔ‬V)‫(ࡓ࠙࠾࠷ࡊࡀޔ‬VI)‫ࠫࠕޔ‬ൻ᳓⚛‫ޔ‬iso-ࡉ࠴࡞ࠕ࡞࠺ࡅ࠼‫ޔ‬n-ࡉ࠴࡞ࠕ࡞࠺ࡅ࠼‫ޔ‬iso-㈼㉄‫ޔ‬n-㈼㉄‫(ࡓ࠙࠾࠹࡞ޔࡓ࠙ࠪ࠮ޔ⚛࡛࠙ޔ‬III)‫ޔ‬ࡊ࡞࠻࠾࠙ࡓ(VI)‫(ࡓ࠙ࠫ࠽ࡃޔ‬IV)‫(ࡓ࠙ࠫ࠽ࡃޔ‬V)‫࡞࠴ࡉࠫ㉄ࡦ࡝ޔ‬㧔DBP㧕‫ޔ‬࡝ࡦ㉄ࡕࡁࡉ࠴࡞㧔MBP㧕‫ޔ㉄ࡦ࡝ޔ‬ᩭಽⵚ↢ᚑ‛㧔FP㧕‫ޔ‬ㆊ㉄ൻ᳓⚛
 PARC ߩ․ᓽߩ৻ߟߣߒߡ‫ޔ‬ൻቇ⒳ߩㆬᛯᯏ⢻߇޽ࠆ‫ޔߪࠩ࡯࡙ޕ‬਄⸥ൻቇ⒳ߩਛ߆ࠄ‫▚⸘ޔ‬ኻ⽎ߣߒߚ޿ൻቇ⒳ࠍ౉ജ⸳ቯߦࠃࠅㆬᛯߔࠆߎߣ߇น⢻ߢ޽ࠆ‫ޕ‬ㆬᛯ⸳ቯߦၮߠ޿ߡ‫ޔ‬㑐ㅪߔࠆൻቇ෻ᔕᑼ‫ޔ‬෻ᔕㅦᐲ⸘▚ᑼ‫ޔ‬ಽ㈩Ყ⸘▚ᑼߩਛ߆ࠄᔅⷐߥ߽ߩߩㆬᛯ߇⥄േ⊛ߦߥߐࠇࠆ‫ޕ‬ᧄᯏ⢻ࠍ೑↪ߒߡኻ⽎ߣߒߥ޿ൻቇ⒳ࠍ㒰ᄖߔࠆߎߣߦࠃߞߡ‫ⴕޔ‬೉⸘▚ߩ⽶⩄߇シᷫߐࠇ⸘▚ㅦᐲߩะ਄߇ᦼᓙߢ߈ࠆ㧔8.4.2.1 ▵(3)ෳᾖ㧕‫ޕ‬㧔㧞㧕ൻቇ෻ᔕ
 PARC ߦߪ PUREX ࡊࡠ࠮ࠬߦ߅޿ߡ㊀ⷐߣ⠨߃ࠄࠇࠆൻቇ෻ᔕࡕ࠺࡞߇ቯ⟵ߐࠇ⚵ߺㄟ߹ࠇߡ޿ࠆ‫ޕ‬એਅߦਥⷐߥൻቇ෻ᔕࠍ␜ߔ㧔㧡┨ෳᾖ㧕‫ޕ‬ࡊ࡞࠻࠾࠙ࡓ(IV)ߩ࠙࡜ࡦ(IV)ߦࠃࠆㆶర
ࡊ࡞࠻࠾࠙ࡓ(IV)ߩ⎣㉄ࡅ࠼ࡠࠠࠪ࡞ࠕࡒࡦߦࠃࠆㆶర
ࡊ࡞࠻࠾࠙ࡓ(III)ߩౣ㉄ൻ
࠙࡜ࡦ(IV)ߩ㉄ൻ࠙࡜ࡦ(IV)ߩⓨ᳇ߦࠃࠆ㉄ൻ੝⎣㉄ߩࡅ࠼࡜ࠫࡦߦࠃࠆಽ⸃

2੝⎣㉄ߩ⎣㉄ࡅ࠼ࡠࠠࠪ࡞ࠕࡒࡦߦࠃࠆಽ⸃
࠹ࠢࡀ࠴࠙ࡓߩ⸅ᇦ૞↪ߦࠃࠆࡆ࠼࡜ࠫࡦߩಽ⸃
ࡀࡊ࠷࠾࠙ࡓߩ㉄ൻ‫ޔ‬ㆶర෻ᔕࡀࡊ࠷࠾࠙ࡓߣࡊ࡞࠻࠾࠙ࡓߩ㉄ൻ‫ޔ‬ㆶర෻ᔕࡀࡊ࠷࠾࠙ࡓߩਇဋൻ෻ᔕ                ╬㧔㧟㧕ಽ㈩Ყ ࠙࡜ࡦ(VI)‫(ࡓ࠙࠾࠻࡞ࡊޔ‬IV)╬ߦ㑐ߒߡߪ‫ ߚ߈ߡࠇࠄ޿↪ߊ⦟ߢ߹ࠇߎޔ‬Richardson ߦࠃࠆ⋧㑐ᑼ 2) ╬ࠍෳ⠨ߣߒߡ޿ࠆ‫ߩ╬ࡓ࠙࠴ࡀࠢ࠹ޔࡓ࠙࠾ࠦ࡞ࠫޔࡓ࠙࠾࠷ࡊࡀޔߚ߹ޕ‬ൻቇ⒳ߦ
ߟ޿ߡߪ‫ޔ‬ᢥ₂⸥タߩ߽ߩ‫ޔ‬ᢥ₂ߩታ㛎୯߆ࠄ⋧㑐ᑼࠍዉ಴ߒߚ߽ߩ‫ߚ߹ޔ‬ේሶജ⑼ቇ⎇ⓥᚲ
NUCEF ߢߩ⹜㛎⚿ᨐ߆ࠄዉ಴ߒߚ߽ߩ߇฽߹ࠇࠆ‫ޕ‬㧔㧠㧕ࠦࡦࡐ࡯ࡀࡦ࠻ ࠦࡦࡐ࡯ࡀࡦ࠻ߩ୘ᢙ㧔ncomp㧕ߪછᗧߢ޽ࠅ೙㒢ߪߥ޿‫ᤨ⚻ߒߛߚޕ‬಴ജࡈࠔࠗ࡞㧔*.trn ࡈࠔࠗ࡞㧕߳ߩ಴ജᯏ⢻㧔8.4.2.1 ▵(23)㨪(24)ෳᾖ㧕ࠍ૶↪ߔࠆ႐วߦߪ‫ޔ‬಴ജᦠᑼߩ㑐ଥߢ 99 ୘એਅ㧔2 ᩴߩᱜᢛᢙ୘㧕ߦ೙㒢ߐࠇࠆ‫ޕ‬ ࠦࡦࡐ࡯ࡀࡦ࠻㑆ߩ᳓⋧෸߮᦭ᯏ⋧ߩᵹࠇߩធ⛯ߪછᗧߦᜰቯߢ߈ࠆ‫ߒߛߚޕ‬ฦ⋧⁛⥄ߩ㈩▤࡞࡯ࡊߪሽ࿷ߒߥ޿ߣߒߡ޿ࠆ‫ޕ‬᛽಴ེ߳ߩࡈࠖ࡯࠼෸߮ઁߩࠦࡦࡐ࡯ࡀࡦ࠻߆ࠄߩᵹ౉ߦߟ޿
ߡߪ‫ޔ‬છᗧ୘ᢙߩࡔ࠶ࠪࡘ߳ߩછᗧ୘ᢙߩᵹ౉㗄㧔࠰࡯ࠬ㗄㧕ߩ⸳ቯ߇น⢻ߢ޽ࠆ㧔8.4.2.1 ▵(6)ෳᾖ㧕‫ޕ‬
㧔㧡㧕ࡔ࠶ࠪࡘ ࡄ࡞ࠬࠞ࡜ࡓ෸߮ࡒࠠࠨ࠮࠻࡜ߩࡔ࠶ࠪࡘᢙ㧔MSH‫ߩࡓ࡜ࠞࠬ࡞ࡄޔ‬㋦⋥ᣇะߩಽഀ୘ᢙ޽ࠆ
޿ߪࡒࠠࠨ࠮࠻࡜ߩᲑᢙ㧔࿑ 3.1 ෸߮ 3.3 ෳᾖ㧕‫ޕ‬㧕ߪછᗧߢ޽ࠅ೙㒢ߪߥ޿‫ᤨ⚻ߒߛߚޕ‬಴ജࡈࠔࠗ࡞㧔*.trn ࡈࠔࠗ࡞㧕߳ߩ಴ജᯏ⢻㧔8.4.2.1 ▵(23)㨪(24)ෳᾖ㧕ࠍ૶↪ߔࠆ႐วߦߪ‫ޔ‬಴ജᦠᑼߩ㑐ଥߢ 999 ୘એਅ㧔3 ᩴߩᱜᢛᢙ୘㧕ߦ೙㒢ߐࠇࠆ‫ޕ‬ ᳓⋧࠲ࡦࠢ‫᦭ޔ‬ᯏ⋧࠲ࡦࠢߪⶄᢙࡔ࠶ࠪࡘߩಽഀ߇ቯ⟵ߐࠇߡ߅ࠄߕ‫ࡘࠪ࠶ࡔޔ‬ᢙߪᏱߦ 1 ߣቯ⟵ߒߡ޿ࠆ‫ޕ‬㧔㧢㧕ࠦࡦࡐ࡯ࡀࡦ࠻᷷ᐲ ࠦࡦࡐ࡯ࡀࡦ࠻Ფߦ⇣ߥࠆㆇォ᷷ᐲ㧔T㧕ࠍ⸳ቯน⢻ߢ޽ࠆ‫ޕ‬᷷ᐲߩ⚻ᤨᄌൻߪߥ޿߽ߩߣߒ
ߡ޿ࠆ‫ߩߎޕ‬᷷ᐲ⸳ቯߪ‫ޔ‬෻ᔕㅦᐲ߿ಽ㈩Ყߩ⸘▚ߦ↪޿ࠄࠇࠆ‫ޕ‬㧞㧚㧞 ⸘▚ᯏ⢻㧔㧝㧕ㆊᷰ⸘▚ᯏ⢻෸߮ቯᏱ⸘▚ᯏ⢻ PARC ߩㆊᷰ⸘▚ᯏ⢻ߣߪ‫ޔ‬᳓⋧෸߮᦭ᯏ⋧ߩ㈩▤ߦࠃߞߡ⋧੕ߦㅪ⚿ߐࠇߚࠦࡦࡐ࡯ࡀࡦ࠻
ౝߩฦൻቇ⒳㧔࡙࡯ࠩ߇ㆬᛯߒߚൻቇ⒳㧕ߦߟ޿ߡ‫ࠍࡊ࠶࠹ࠬࡓࠗ࠲ޔ‬ㅴ߼ߥ߇ࠄൻቇ෻ᔕ‫ޔ‬ಽ

3

㈩ᐔⴧ⸘▚ࠍታⴕߒ‫ޔ‬᳓⋧෸߮᦭ᯏ⋧ߩൻቇ⒳Ớᐲࠍ࡙࡯ࠩ߇ᜰቯߔࠆ࠲ࠗࡒࡦࠣߢ಴ജߔࠆᯏ
⢻ߢ޽ࠆ‫ޕ‬ ߹ߚቯᏱ⸘▚ᯏ⢻ߣߪ‫ޔ‬ฦࠦࡦࡐ࡯ࡀࡦ࠻ౝߩฦൻቇ⒳ߩỚᐲ߇‫ᤨޔ‬㑆ࠍ⚻ߡ߽ᄌൻߖߕ቟ቯ
ߒߚ⁁ᘒ㧔ቯᏱ⁁ᘒ㧕ࠍ▚಴ߔࠆᯏ⢻ߢ޽ࠆ‫ޔ߅ߥޕ‬ቯᏱ⸘▚ࠍታⴕߔࠆ㓙ߦߪ‫߼ߓ߆ࠄ޽ޔ‬චಽ㐳޿ᤨ㑆ߩㆊᷰ⸘▚ࠍታⴕߒߘߩᦨ⚳⚿ᨐ߇ቯᏱ⁁ᘒߦචಽㄭߠ޿ߡ޿ࠆߎߣࠍ⏕⹺ߒߡ߅ߊ
ᔅⷐ߇޽ࠆ‫ޕ‬ቯᏱߦㄭߠ޿ߡ޿ߥ޿⁁ᘒߢቯᏱ⸘▚ࠍታⴕߒߚ႐ว‫ޔ‬Ṷ▚ߦ໧㗴߇↢ߓߡ⇣Ᏹ⚳ੌߔࠆน⢻ᕈ߇޽ࠆߚ߼ߢ޽ࠆ‫ޕ‬
 PARC ߢߪ‫ޔ‬4 ⒳㘃ߩ⸘▚ࡄ࠲࡯ࡦࠍታⴕߔࠆߎߣ߇ߢ߈ࠆ㧔8.4.2.1 ▵(15)ෳᾖ㧕‫ޔߪࠩ࡯࡙ޕ‬Ԙㆊᷰ⸘▚ߩߺታⴕ‫ޔ‬ԙㆊᷰ⸘▚ߩᓟߦቯᏱ⸘▚ߩታⴕ‫ޔ‬Ԛㆊᷰ⸘▚ĺቯᏱ⸘▚ĺㆊᷰ⸘▚‫ޔ‬ԛㆊᷰ⸘▚ĺቯᏱ⸘▚ĺㆊᷰ⸘▚ĺቯᏱ⸘▚ߩ߁ߜ߆ࠄ⸘▚ࡄ࠲࡯ࡦࠍㆬᛯߢ߈ࠆ‫ޕ‬㧔㧞㧕࡝ࠬ࠲࡯࠻⸘▚ᯏ⢻
PARC ߆ࠄ಴ജߐࠇߚ⸘▚⚿ᨐ㧔޽ࠆᤨೞߦ߅ߌࠆฦࠦࡦࡐ࡯ࡀࡦ࠻ౝߩỚᐲᖱႎ㧕ࠍೋᦼỚᐲߣߒߡ‫ࠍࡦ࡚ࠪ࡯࡟ࡘࡒࠪߡߒ⛯⛮ޔ‬ታᣉߔࠆᯏ⢻ߢ޽ࠆ‫౉ߩࡦࠗࡔޔߪߢ▚⸘࠻࡯࠲ࠬ࡝ޕ‬ജࡈࠔࠗ࡞ߢߪߥߊ‫࡞ࠗࠔࡈߩઁޔ‬㧔࡝ࠬ࠲࡯࠻ࡈࠔࠗ࡞㧔*.rst ࡈࠔࠗ࡞‫ޔ‬8.4.2.1 ▵(19), (20)෸
߮ 9.2 ▵ෳᾖ㧕╬㧕ߦ฽߹ࠇࠆỚᐲ࠺࡯࠲ࠍ⺒ߺㄟࠎߢೋᦼ୯ߣߒߡ⸘▚ࠍ㐿ᆎߔࠆ‫ߩߎޕ‬ᯏ⢻ߦࠃߞߡ⸘▚ᤨ㑆ߩ⍴❗‫ߩࡉ࡚ࠫ▚⸘ޔ‬ಽഀታⴕ߇น⢻ߣߥࠆ‫ޕ‬㧔㧟㧕቟ቯᕈ
⸘▚ߢߪቢో㒶⸃ᴺࠍ↪޿ߡ޿ࠆ‫ޕ‬ᄢ߈ߥᤨ㑆ೞߺߦ߽߆߆ࠊࠄߕᝄേߩߥ޿቟ቯߥ⸃ᨆ߇น
⢻ߣߥࠅ‫ᤨ▚⸘ޔ‬㑆ࠍ⍴❗ߢ߈ࠆ‫ޕ‬㧔㧠㧕ࠗࡦ࠲ࡊ࡝࠲ᯏ⢻ PARC ߩ․㐳ߩ৻ߟߦ‫࠲࡝ࡊ࠲ࡦࠗޟ‬ᯏ⢻‫ߩߎޕࠆ޽߇ޠ‬ᯏ⢻ࠍᵴ↪ߔࠆߎߣߦࠃࠅ‫ޔ‬ᣢߦቯ⟵ߐࠇࡊࡠࠣ࡜ࡓൻߐࠇߡ޿ࠆൻቇ⒳‫ޔ‬ൻቇ෻ᔕᑼ㧔᳓⋧෸߮᦭ᯏ⋧㧕‫ޔ‬෻ᔕㅦᐲ⸘▚ᑼ㧔᳓⋧෸߮᦭ᯏ⋧㧕෸߮ಽ㈩Ყ⸘▚ᑼࠍ‫౉ࠩ࡯࡙ޔ‬ജߦࠃߞߡ߶߷છᗧߦᄌᦝ‫ޔ‬ขᶖ߇น⢻ߣߥࠆ‫ࠄߐޕ‬ߦᧂቯ⟵ߩᣂߒ޿ൻቇ⒳‫ޔ‬ൻቇ෻ᔕࠍቯ⟵ߔࠆߎߣ߇น⢻ߣߥࠆ‫࡜ࠣࡠࡊࠬ࡯࠰ߡߞࠃߦࠇߎޕ‬ࡓߩ✬㓸૞ᬺࠍⴕ߁ߎߣߥߊ᭽‫ߩ࡞࠺ࡕߥޘ‬ዉ౉߇น⢻ߣߥࠆ‫ޕ‬ ᣂߚߦ⠨ᘦߒߚ޿⸘▚ᑼ╬ߪ‫ޔ‬PARC ߩ౉ജࡈࠔࠗ࡞ਛߦ⋥ធ⸥ㅀߔࠆ㧔8.2 ▵ෳᾖ㧕‫ޕ‬PARC
߇౉ജࡈࠔࠗ࡞ࠍ⺒ߺㄟߺ‫౉ޔ‬ജࡈࠔࠗ࡞ߦ⸥ㅀߐࠇߚᢥሼ೉ࠍಽഀߒ‫ޔ‬᭴ᢥ⸃ᨆࠍⴕ߁‫ޕ‬᭴ᢥ⸃ᨆߦᒰߚߞߡߪ‫ ࠆࠇࠄ޿↪ߊࠃߢ࡜ࠗࡄࡦࠦޔ‬LL (1) ᭴ᢥ⸃ᨆᴺ 3) ࠍ↪޿ߡ‫ޔ‬ᢥሼ೉ਛߦ⃻ࠇࠆ੍⚂⺆㧔"Pu", "Np", "ELSE" ╬㧕‫ޔ‬᜝ᒐߩኻᔕ‫ޔ‬྾ೣṶ▚‫᧦ޔ‬ઙᢥ╬ߩᢥᴺ᭴ㅧߩ⹺⼂╬ࠍⴕ߁‫ޕ‬߹ߚ‫ޔ‬᭴ᢥ⸃ᨆ⚿ᨐࠍ߽ߣߦ‫⥄ޔ‬േᓸಽᴺ 4) ࠍ↪޿ߡⴕ೉⸘▚ߦᔅⷐߥ Jacobian ⴕ೉ࠍ⥄േ⊛ߦ↢ᚑߒ‫ޔ‬ᣢሽߩ⸘▚ᑼߣߣ߽ߦ⸘▚ࠍታⴕߔࠆ‫ޕ‬

4ࠗࡦ࠲ࡊ࡝࠲౉ജ଀㧝㧔ൻቇ෻ᔕᑼ෸߮෻ᔕㅦᐲ⸘▚ᑼߩቯ⟵ߩㅊട㧕  2W +8

0R 8+

*1 2W 8+

0R 8

*

  '.5'  F=Z2W +8 ?FV =Z2W +8 ? =Z0R 8+ ?=Z*?



ߎߩ଀ߢߪ‫(ࡓ࠙࠾࠻࡞ࡊޔ‬IV)ߣࡀࡊ࠷࠾࠙ࡓ(VI)ߩൻቇ෻ᔕ߇ᣂߚߦቯ⟵ߐࠇ‫ޔ‬ᣢሽߩ෻ᔕߣ
ߣ߽ߦ⸘▚ࠍታⴕߔࠆ‫ޕ‬ࠗࡦ࠲ࡊ࡝࠲౉ജ଀㧞㧔෻ᔕㅦᐲߩᄌᦝ㧕  4:
ߎߩ଀ߢߪ‫ޔ‬PARC ߦᣢ⸳ߩ‫(ࡓ࠙࠾࠻࡞ࡊޟ‬IV)ߩ࠙࡜ࡦ(IV)ߦࠃࠆㆶర෻ᔕ㧔᳓⋧㧕‫ߩޠ‬෻ᔕ
ㅦᐲࠍ 0 ߣߒߡ߅ࠅ‫ߩߎޔ‬෻ᔕ߇⿠ߎࠄߥ޿ߣߒߚ⸘▚ࠍታⴕߔࠆ㧔8.2 ▵ෳᾖ㧕‫ޕ‬㧔㧡㧕ࡊࡠࠣ࡜ࡒࡦࠣ⸒⺆
PARC ߩోߡߩ࠰࡯ࠬࡊࡠࠣ࡜ࡓߪ‫ޔ‬C ⸒⺆ߦࠃߞߡ⸥ㅀߐࠇߡ޿ࠆ‫ޕ‬C ⸒⺆ࠍ↪޿ࠆߎߣߢ‫ޔ‬ࡐࠗࡦ࠲ᄌᢙߩ೑↪߿ࡔࡕ࡝ߩേ⊛⏕଻ߩᯏ⢻ࠍ೑↪ߒߚ೨⸥ࠗࡦ࠲ࡊ࡝࠲ᯏ⢻ߩታⵝ߇
FORTRAN ╬ߦᲧߴߡኈᤃߣߥࠆ‫ޕ‬C ⸒⺆ߦߟ޿ߡߪᄙߊߩෳ⠨ᦠ 5) ߇޽ࠆ‫ߚ޽ߦ࡞ࠗࡄࡦࠦޕ‬ߞߡߪ‫ޔ‬Microsoft Visual C++ ╬ߩᏒ⽼ߩࠦࡦࡄࠗ࡜߇೑↪น⢻ߢ޽ࠆ‫ޕ‬5㧟 ၮᧄࡕ࠺࡞
PARC ߢࡕ࠺࡞ൻ߇น⢻ߥ᛽಴ེߪ‫ࡓ࡜ࠞࠬ࡞ࡄޔ‬෸߮ࡒࠠࠨ࠮࠻࡜ߩ 2 ⒳㘃ߢ޽ࠆ‫ޔߚ߹ޕ‬᳓⋧࠲ࡦࠢ߅ࠃ߮᦭ᯏ⋧࠲ࡦࠢߩࡕ࠺࡞ൻ߇น⢻ߢ޽ࠆ‫ޕ‬એਅߦၮᧄ⸘▚ࡕ࠺࡞ࠍ␜ߔ‫ޕ‬㧟㧚㧝 ࡄ࡞ࠬࠞ࡜ࡓ
ࡄ࡞ࠬࠞ࡜ࡓߩၮᧄࡕ࠺࡞ߢߪ‫࠻ࡈࡖࠪߪࡓ࡜ࠞࠬ࡞ࡄޔ‬ㇱ෸߮਄ਅಽ⋧࠲ࡦࠢߢ᭴ᚑߐࠇࠆ
㧔࿑ 3.1㧕‫౉ޕ‬ജࡈࠔࠗ࡞ߦ߅޿ߡࡄ࡞ࠬࠞ࡜ࡓߩ㋦⋥ᣇะߩಽഀᢙ㧔MSH㧕ࠍ N ߣ⸳ቯߒߚ႐
ว‫ޔ‬ਅㇱಽ⋧࠲ࡦࠢ߇ࡔ࠶ࠪࡘ⇟ภ㧝‫ޔ‬਄ㇱಽ⋧࠲ࡦࠢ߇ࡔ࠶ࠪࡘ⇟ภ N ߣቯ⟵ߐࠇ‫࠻ࡈࡖࠪޔ‬ㇱߪ(N-2)୘ߩࡔ࠶ࠪࡘߦಽഀߐࠇࠆ‫࠻ࡈࡖࠪ߈ߣߩߎޕ‬ㇱߩಽഀߪ㐳ߐᣇะߦဋ╬޽ࠆ޿ߪਇဋ
╬ߥಽഀ߇น⢻ߢ޽ࠆ‫ޕ‬ੑ⋧ߪฦ‫ޘ‬਄ਅᣇะߦᵹࠇะᵹធ⸅ߔࠆߣߔࠆ‫࠻ࡈࡖࠪޕ‬ㇱߢߪ‫ޔ‬᳓⋧ߣ᦭ᯏ⋧߇ࠛࡑ࡞࡚ࠫࡦߩᒻߢሽ࿷ߔࠆߣߒߡ߅ࠅ᳓⋧ಽᢔ෶ߪ᦭ᯏ⋧ಽᢔߩ޿ߕࠇ߆ㆇォ᧦ઙࠍㆬᛯߢ߈ࠆ‫ߩࠬ࡞ࡄޔߚ߹ޕ‬ශടߦߣ߽ߥ߁ㅪ⛯⋧෸߮ಽᢔ⋧ߩㅒᷙวߩലᨐࠍ⠨ᘦߒߡ߅ࠅ‫ޔ‬ㅒᷙวଥᢙࠍ↪޿ߚࡕ࠺࡞ߣߥߞߡ޿ࠆ‫࠻ࡈࡖࠪޕ‬ㇱߢߩಽᢔ⋧ᶧṢᓘ‫ޔ‬ㅒᷙวଥᢙ‫ޔ‬ಽᢔ⋧ࡎ࡯࡞࠼ࠕ࠶ࡊߩ▚಴ߦߪ Kumar 6-8) ࠄߦࠃࠆ perforated plate ဳࡄ࡞ࠬࠞ࡜ࡓߦ㑐ߔࠆታ㛎ᑼࠍ↪
޿ߡ޿ࠆ‫ޔ߅ߥޕ‬baffle plate ဳࡄ࡞ࠬࠞ࡜ࡓߦ㑐ߒߡߪ‫ޔ‬PARC ߢߪ⋥ធ⊛ߦᛒ߁ߎߣߪߢ߈ߥ
޿߇‫ߡߒߣ଀৻ޔ‬೨↰ࠄߦࠃࠆ SAFE ࠦ࡯࠼ 9-10) ߢណ↪ߐࠇߡ޿ࠆ baffle plate ဳࡄ࡞ࠬࠞ࡜ࡓ↪
ߩࡕ࠺࡞߇ෳ⠨ߦߥࠆߣᕁࠊࠇࠆ‫ޕ‬߹ߚ‫࡞࠺ࡕޔ‬ൻߩㇺว߆ࠄ‫ޔ‬਄ㇱ෸߮ਅㇱಽ⋧࠲ࡦࠢߦߪ‫ߦ౒ޔ‬ੑ⋧߇⋧ಽ㔌ߒߚ⁁ᘒߢሽ࿷ߔࠆߣߒ‫ޔ‬ੑ⋧ߩ૕Ⓧഀวߪ࠲ࡦࠢᲤߦ࿕ቯ୯㧔phi1‫ޔ‬phi2㧕ࠍᜰቯߔࠆߎߣߣߒߡ޿ࠆ㧔8.4.2.3.2▵(2)ෳᾖ㧕‫ޕ‬᳓⋧-᦭ᯏ⋧㑆ߩಽ㈩ᐔⴧߦࠃࠆ‛⾰⒖േߦߟ޿ߡߪ‫ߣ࡜࠻࠮ࠨࠠࡒޔ‬ห᭽‫⾰‛ޔ‬⒖േㅦᐲࠍ⠨ᘦߒߚࡕ࠺࡞ߢ޽ࠅ‫✚ޔ‬᜝‛⾰⒖േଥᢙࠍ↪޿ߡࡕ࠺࡞ൻߒߡ޿ࠆ‫✚ޕ‬᜝‛⾰⒖േଥᢙߪࠪࡖࡈ
࠻ㇱ෸߮਄ਅಽ⋧࠲ࡦࠢߦ߅޿ߡ⸳ቯߐࠇࠆ‫ޕ‬㧟㧚㧝㧚㧝 ‛⾰෼ᡰᑼ‛⾰෼ᡰᑼߪએਅߩࠃ߁ߦߥࠆ.‫ߒߛߚޕ‬ൻቇ⒳ߦ㑐ߔࠆᷝሼߪ⋭⇛ߒߡ޽ࠆ‫ޕ‬ 㧔᳓⋧㧕

wx
wt

1
w § wx · 1 w
u a x  M a  ¦  r ( x ) Ra  S a¨ Ea ¸ Iawz © wz ¹ I a wz

>

@

(3.1)

 㧔᦭ᯏ⋧㧕wy
wt

1w § wy · 1 w
u o y  M o  ¦  r ( y ) Ro  S o¨ Eo ¸ Iowz © wz ¹ I o wz

>

@

6

(3.2)

ߎߎߢ
t 㧦ᤨ㑆
z 㧦ゲᣇะᐳᮡx 㧦᳓⋧Ớᐲy 㧦᦭ᯏ⋧Ớᐲĳ 㧦ࡎ࡯࡞࠼ࠕ࠶ࡊ
E 㧦ㅒᷙวଥᢙ
U 㧦ߺ߆ߌᵹㅦ 㧔ᵹ㊂/ోᢿ㕙Ⓧ㧕
M 㧦ੑ⋧㑆‛⾰⒖േ㊂
R 㧦ൻቇ෻ᔕ㊂S 㧦ࠞ࡜ࡓㅜਛ߆ࠄߩᵹ౉㊂ߢ޽ࠆ‫ޔߚ߹ޕ‬ᷝሼߪa 㧦᳓⋧o 㧦᦭ᯏ⋧
ߢ޽ࠆ‫ޕ‬
 Ⓧ Ȇr(x)෸߮ Ȇr(y)ߪ‫ޔ‬ൻቇ෻ᔕᑼߩᏀㄝߦ⃻ࠇࠆൻቇ⒳ߩỚᐲߩ㑐ᢙߩⓍߢ޽ࠆ‫ޕ‬r(x)෸߮ r(y)ߪᰴߩࠃ߁ߥ㑐ᢙߣߒߡ޿ࠆ㧔࿑ 3.2㧕‫ߩߎޕ‬㑐ᢙߪ‫ޔ‬Ṷ▚ߩ቟ቯൻߩߚ߼ߦዉ౉ߒߚ߽ߩߢ޽ࠆ‫ޕ‬r ( x)­1° G x (0 d x d G )°®
° 1 (G d x)
°
¯

‫ޓ‬

(3.3)

r ( y)­1° G y (0 d y d G )°®
° 1 (G d y )
°
¯

‫ޓ‬

(3.4)

 ߎߎߢ‫ޔ‬x ෸߮ y ߪỚᐲ‫ޔ‬į ߪቯᢙߢ޽ࠆ‫ޕ‬㧟㧚㧝㧚㧞 ࠪࡖࡈ࠻ㇱߦ߅ߌࠆၮᧄࡕ࠺࡞ߩᏅಽ⴫⃻㧔㧝㧕ࠪࡖࡈ࠻ㇱߦ߅ߌࠆᏅಽ⴫⃻ ࡄ࡞ࠬࠞ࡜ࡓߩၮᧄࡕ࠺࡞ࠍᏅಽߦࠃࠅ⴫⃻ߔࠆߣᰴߩࠃ߁ߦߥࠆ‫ߩߡߴߔޕ‬㊂ߪࡔ࠶ࠪࡘਛ
ᄩߢቯ⟵ߐࠇߡ޿ࠆ߽ߩߣߒ‫ޔ‬⒖ᵹ㗄ߦߪ㘑਄Ꮕಽࠍ↪޿ߚ‫ޕ‬7 㧔᳓⋧㧕

x

n 1
i

x
't

n
i

ª
º
«
n 1
n 1
n 1
n 1 »
1 « 2( xi 1  xi ) 2( xi  xi 1 ) »'z i 1 'z i »'z i « 'z i 'z i 1
« E EE
E a ,i »¼
a
i
a
i
a
i
,
,
1
,
1


¬

‫ޓޓޓޓޓޓ‬1
U a ,i 1  xin11  U a ,i  xin 1 ‫ޓ‬ M an,i 1'z i  I a ,i>@ 'z  I1  A ¦ F‫ޓޓޓޓޓޓ‬ ¦  r ( xin 1 ) Ran,i 1 fa ,i 1 / 2

i

(3.5)

 x f ,i 1 / 2a ,i 㧔᦭ᯏ⋧㧕

y

n 1
i

y
't

n
i

ª
º
«
n 1
n 1 »n 1
n 1
1 « 2( y i 1  y i ) 2( y i  y i 1 ) »'z i 1 'z i »'z i « 'z i 'z i 1
« E EE o ,i 1 E o ,i »¼o ,i 1¬ o ,i‫ޓޓޓޓޓޓ‬1
U o ,i  y in 1  U o ,i 1  y in11  M on,i 1'z i  I o ,i>@ 'z  I1  A ¦ F‫ޓޓޓޓޓޓ‬ ¦  r ( y in 1 ) Ron,i 1 fo ,i 1 / 2

i

(3.6)

 y f ,i 1 / 2

o ,i

ߎߎߢ
i 㧦ࡔ࠶ࠪࡘ⇟ภn 㧦ᤨ㑆ࠬ࠹࠶ࡊ⇟ภ
xf 㧦ࠪࡖࡈ࠻ㇱࡔ࠶ࠪࡘ߳ߩᵹ౉Ớᐲ㧔᳓⋧㧕 ઁߩࠦࡦࡐ࡯ࡀࡦ࠻߆ࠄߩᵹࠇߦߟ޿ߡߪ n+1 ࠍ‫ߩ࠼࡯ࠖࡈߚߒ┙⁛ޔ‬႐วߪ n ߩ୯ࠍ↪޿ࠆ‫ޕ‬

yf 㧦ࠪࡖࡈ࠻ㇱࡔ࠶ࠪࡘ߳ߩᵹ౉Ớᐲ㧔᦭ᯏ⋧㧕 ઁߩࠦࡦࡐ࡯ࡀࡦ࠻߆ࠄߩᵹࠇߦߟ޿ߡߪ n+1 ࠍ‫ߩ࠼࡯ࠖࡈߚߒ┙⁛ޔ‬႐วߪ n ߩ୯ࠍ↪޿ࠆ‫ޕ‬
f

F 㧦ࠪࡖࡈ࠻ㇱࡔ࠶ࠪࡘ߳ߩᵹ౉ᵹ㊂A 㧦ᵹ〝ᢿ㕙Ⓧ
ߢ޽ࠆ‫ޕ‬
㧔㧞㧕ࠪࡖࡈ࠻ㇱߣಽ⋧࠲ࡦࠢߩႺ⇇ߢߩᏅಽ⴫⃻ એਅߢߪ‫࠻ࡈࡖࠪޔ‬ㇱߩ㜞ߐ߇ H ߩ႐ว‫࠻ࡈࡖࠪޔ‬ㇱߣਅㇱಽ⋧࠲ࡦࠢߣߩႺ⇇ࠍ z = 0‫ޔ‬਄ㇱಽ⋧࠲ࡦࠢߣߩႺ⇇ࠍ z = H ߣ⴫⃻ߔࠆ㧔࿑ 3.1㧕‫࠻ࡈࡖࠪޕ‬ㇱߩႺ⇇᧦ઙߪᰴߩࠃ߁ߦ⴫ߐࠇࠆ‫ޕ‬ߚߛߒ‫ޔ‬ᷝሼ in ߪ౉ญߩ㊂ߢ޽ࠆߎߣࠍ␜ߔ‫ޕ‬8 㧔᳓⋧㧕ª wx º« wz »¬ ¼z 00(3.7)ª wx º [(U a x) in  (U a x) z H 0 ]
 Ia « Ea »¬ wz ¼ z H 0

0

(3.8)

 㧔᦭ᯏ⋧㧕ª wy º [(U o y ) z 0  (U o y ) in ] 0¬ wz »¼ z 0
ª wy º0‫ޓ‬«¬ wz »¼
z H

Io « E o(3.9)(3.10) ᜛ᢔ㗄ߣ⒖ᵹ㗄ߦኻߒߡ‫ ࡘࠪ࠶ࡔޔ‬N ෶ߪࡔ࠶ࠪࡘ 1 ߢ౉ญߩ㊂ߦኻߒߡⓍಽࠍⴕ߁ߣ
㧔᳓⋧㧕

ª
¬

Ia « E awx ºª wx ºIa«¬ Ea wz »¼ 1  (U a x) N  1 0  (U a x) N  1
wz »¼ N  1 0
N
2
2
2

(3.11)

2

㧔᦭ᯏ⋧㧕

ª
¬

Io « Eowy ºª wy ºIo«¬ Eo wz »¼ 1  (U o y ) 3  (U o y ) 1 0
wz »¼ 30
2
2
2

(3.12)

2

ᑼ(3.8)‫(ޔ‬3.9) ࠃࠅ(U a x)in(U o y )inª¬Ia « E awx º (U a x) 1
N  0wz »¼ N  1 0
2

(3.13)

2ª wy ºIo « Eo »  (U o y ) 1
0¬ wz ¼ 1 0
2

(3.14)

2

ߢ޽ࠅ(3.13)‫(ޔ‬3.14)ࠍ(3.11)‫(ޔ‬3.12)ߦઍ౉ߒߡ

ª wx º(U a x)in  Ia « Ea »
 (U a x) 1
N
¬ wz ¼ N  1
2(3.15)ª wy º(U o y ) in  Io « Eo »  (U o y ) 3¬ wz ¼ 3
2(3.16)

22ߣߥࠆ‫ޕ‬
߹ߚ‫ޔ‬᳓⋧ߣ᦭ᯏ⋧ߩ಴ญߦኻߒߡ᜛ᢔ㗄ߣ⒖ᵹ㗄ߩⓍಽࠍⴕ߁ߣ

9

㧔᳓⋧㧕

ª
¬

Ia « E awx ºª wx º Ia « Ea »  (U a x) 3  (U a x) 1»
wz ¼ 3¬ wz ¼ 1
2
2
2(3.17)

2

㧔᦭ᯏ⋧㧕

ª
¬

Io « E owy ºª wy º Io « E o » (U o y ) 1  (U o y ) 1»
NN
wz ¼ N  1¬ wz ¼ N  1
2
2
2(3.18)

2ߢ޽ࠆ‫(ߢߎߎޕ‬3.7)‫(ޔ‬3.10)ࠃࠅ

ª wx º«¬ wz »¼ 1

x 1 ѳ x1‫ޓ‬0,(3.19)

2

2ª wy º«¬ wz »¼ 1
N

y

0,

2

N

1
2

ѳ yN ‫ޓ‬(3.20)

ߢ޽ࠅ‫(ޔ‬3.19) (3.20)ࠍ‫(ޔ‬3.17)(3.18)ߦઍ౉ߒߡwx º
 (U a x) 3  (U a x)1
wz »¼ 32

(3.21)ª wy º Io « E o » (U o y ) N  (U o y ) 1
N¬ wz ¼ N  1
2(3.22)ª¬Ia « Ea22ߣߥࠆ‫ޕ‬
એ਄߆ࠄ‫࠻ࡈࡖࠪޔ‬ㇱߩ਄ਅ┵ߦ߅ߌࠆᏅಽᑼ㧔㘑਄Ꮕಽ㧕ߪᰴߩࠃ߁ߦߥࠆ‫ޕ‬㧔ਅ┵㧕

x1n 1  x1n't

1 2( x2n 1  x1n 1 )1
(U a , 2  x2n 1  U a ,1  x1n 1 )  M an,11'z1  Ia ,1'z1 'z1  'z 2
Ea ,1 Ea , 2

y1n 1  y1n't¦ >  r(x@ 'z  I1  A ¦ F  x

n 1
n 1
1 ) Ra ,1 

f

1

a,

a ,1

3
2

f,

3
2

1 2( y2n 1  y1n 1 )1
(U o ,1  y1n 1  U o , in  yinn 1 )  M on,11'z1  Io ,1'z1 'z1  'z2
Eo ,1 Eo , 2
¦ >  r( y(3.23)@ 'z  I1  A ¦ F  y

n 1
n 1
1 ) Ro , i 

f

1

o,

o ,1

10

1
2

f,

1
2

(3.24)

㧔਄┵㧕

xNn 1  xNn'ty Nn 1  y Nn't

1 2( xNn 1  xNn 11 )1(U a ,in  xinn 1  U a , N  x Nn 1 )  M an,N1'z N 'z N 1  'z N 'z N  Ia , N
Ea , N 1 Ea , N



¦ >  r(x

@ 'z I1  A ¦ F

n 1
n 1
N ) Ra , N Nfa, N 

a, N

1
1 x
f ,N 
2
2

1 2( y Nn 1  y Nn 11 )1(U o , N  y Nn 1  U o , N 1  y Nn 11 )  M an,N1'z N 'z N 1  'z N 'z N  Io , N
Eo , N 1 Eo , N¦ >  r( y@ 'z  I1  A ¦ F

n 1
n 1
N ) Ro , N Nfo, N 

o, N(3.25)(3.26)1
1 yf ,N 
22ߎߎߢ㧦 ࠪࡖࡈ࠻ㇱߩࡔ࠶ࠪࡘಽഀᢙ

N

Uo,in 㧦 ਅㇱಽ⋧࠲ࡦࠢߦ߅ߌࠆ᦭ᯏ⋧ㅦᐲ㧦 ਅㇱಽ⋧࠲ࡦࠢߦ߅ߌࠆ᦭ᯏ⋧Ớᐲ

yinUa,in 㧦 ਄ㇱಽ⋧࠲ࡦࠢߦ߅ߌࠆ᳓⋧ㅦᐲ㧦 ਄ㇱಽ⋧࠲ࡦࠢߦ߅ߌࠆ᳓⋧Ớᐲxinߢ޽ࠆ‫ޕ‬

㧟㧚㧝㧚㧟 ਄ਅಽ⋧࠲ࡦࠢౝᏅಽᑼ
㧔ਅㇱಽ⋧࠲ࡦࠢ㧕
n 1
n
xout
 xout't1
n 1( A  U a ,1  x1n 1  AFL  xout
)  E b  ab ( yin*n 1  yinn 1 )
Va ,b

>

‫ޓޓޓޓޓ‬ ¦  r(xyinn 1  yinn
't



n 1
out

n 1
a , out)R@1
F f1  x 1
¦
a,
f,
Va ,b
2
2

1
OFD  yinn 1  E b  ab ( yin*n 1  yinn 1 )
Vo ,b

>

‫ޓޓޓޓޓ‬ ¦  r( y

n 1
in

n 1
o , in)R@(3.28)

1Fo ,fb  y f ,b
¦
Vo ,b

ߎߎߢ
AFL 㧦 ਅㇱಽ⋧࠲ࡦࠢߦ߅ߌࠆ᳓⋧ᵹ㊂
OFD 㧦 ਅㇱಽ⋧࠲ࡦࠢߦ߅ߌࠆ᦭ᯏ⋧ᵹ㊂ 㧔 =Va,b㧦 ᳓⋧૕Ⓧ㧔࡙࡯ࠩ౉ജߦࠃࠆ࿕ቯ୯㧕11(3.27)

¦F 㧕
f
o,b

Vo,b

㧦 ᦭ᯏ⋧૕Ⓧ㧔࡙࡯ࠩ౉ജߦࠃࠆ࿕ቯ୯㧕ȕb㧦 ᦭ᯏ⋧ၮḰߩ✚᜝‛⾰⒖േଥᢙ㧔࡙࡯ࠩ౉ജߦࠃࠆ࿕ቯ୯㧕ab㧦 න૏૕Ⓧ㧔᳓⋧+᦭ᯏ⋧㧕޽ߚࠅߩ⇇㕙Ⓧ㧔࡙࡯ࠩ౉ജߦࠃࠆ࿕ቯ୯㧕ߢ޽ࠆ‫ޕ‬
㧔਄ㇱಽ⋧࠲ࡦࠢ㧕

xinn 1  xinn
't



1
n 1
* n 1)
AFD  xinn 1  E t  at  ( yout youtVa ,t ¦[( r ( x

n 1)
in

n 1
n
yout
 yout'tn 1
a , in)R(3.29)1)] ¦ Faf,t  x f ,t
Va ,t

1
n 1
n 1
* n 1
 A  U o , N  y Nn 1 )  E t  at ( yout yout(OFL  yout)
Vo ,t ¦[( r ( y

n 1
out

n 1
o , out)) R(3.30)

1
Fo f, N 1 / 2  y f , N 1 / 2
]
¦
Vo ,t

ߎߎߢ
AFD 㧦 ਄ㇱಽ⋧࠲ࡦࠢߦ߅ߌࠆ᳓⋧ᵹ㊂ 㧔 =

¦F 㧕
f
a ,t

OFL 㧦 ਄ㇱಽ⋧࠲ࡦࠢߦ߅ߌࠆ᦭ᯏ⋧ᵹ㊂Va,t㧦 ᳓⋧૕Ⓧ㧔࡙࡯ࠩ౉ജߦࠃࠆ࿕ቯ୯㧕Vo,t㧦 ᦭ᯏ⋧૕Ⓧ㧔࡙࡯ࠩ౉ജߦࠃࠆ࿕ቯ୯㧕ȕt㧦 ᦭ᯏ⋧ၮḰߩ✚᜝‛⾰⒖േଥᢙ㧔࡙࡯ࠩ౉ജߦࠃࠆ࿕ቯ୯㧕a㧦 න૏૕Ⓧ㧔᳓⋧+᦭ᯏ⋧㧕޽ߚࠅߩ⇇㕙Ⓧ㧔࡙࡯ࠩ౉ജߦࠃࠆ࿕ቯ୯㧕ߢ޽ࠆ‫ޕ‬

㧟㧚㧝㧚㧠 ㅒᷙวଥᢙ
ࡄ࡞ࠬශടߦ઻߁ࠪࡖࡈ࠻ㇱߢߩゲᣇะ㧔㋦⋥ᣇะ㧕ߩㅒᷙวߦߟ޿ߡߪ‫ޔ‬ㅒᷙวଥᢙࠍ↪޿ߚ⴫⃻ࠍߣߞߡ޿ࠆ‫ޕ‬ㅪ⛯⋧ߩㅒᷙวଥᢙ Ec ߩ▚಴ߦߪ‫ޔ‬Kumar ࠄ߇ឭ᩺ߒߚ perforated plate ဳࡄ࡞ࠬࠞ࡜ࡓߢߩផ▚ࡕ࠺࡞ 7) ࠍណ↪ߒߚ‫ޔ߅ߥޕ‬PARC ߢߪಽᢔ⋧ߩㅒᷙวଥᢙ Ed ߦ߽หߓ୯
ࠍ↪޿ߡ޿ࠆ‫ޕ‬

Ec 'U

Pc

§V P ·
K1 exp K 2M  ¨ d c ¸
© V ¹

K1

46.15

K2

­0.80 ‫ޓ‬®
¯ 0.34

0.11§ Pc ·¨¨ ¸¸© Pd ¹

 0.37

º
ª
Pc
«
0.5 »
«¬ V 'Uh »¼

0.61§ d0 ·
¨ ¸
© h ¹

0.36

1.05

§ 'Uh ·¨¨ * * ¸¸©U h ¹(3.31)(3.32)

Af  2 Af m
Af ! 2 Af m

(3.33)

12

M­ª Af  Af º 3 ª Af  Af º 2
m
m
°«
»
» «
Af m ¼ ¬Af m ¼°¬°®
°
Af  2  Af m
°
°¯
Af m

Af m

§ V 'U 1 / 4D ·¸
9.69 u 10  ¨¨ P 3/ 4 ¸
d©
¹Af  2 Af m
(3.34)

Af ! 2 Af m

0.33

3

(3.35)

h*= 0.05(3.36)

ȡ*= 998(3.37)

Ed= Ec(3.38)

ߎߎߢA

㧦ࡄ࡞ࠬᝄ᏷㧔̪㧕㧔ਔᝄ᏷‫ߜࠊߥߔޔ‬ᝄ᏷ߩ 2 ୚㧕[m]d0㧦⋡⋁᧼ߩⓣ⋥ᓘ㧔̪㧕

[m]

Ec

㧦ㅪ⛯⋧ㅒᷙวଥᢙ

[m2 s-1]Ed㧦ಽᢔ⋧ㅒᷙวଥᢙ

[m2 s-1]f㧦ࡄ࡞ࠬᝄേᢙ㧔̪㧕

[s-1]

h

㧦ࡊ࡟࡯࠻㑆㓒㧔̪㧕[m]h* 㧦ᮡḰࡊ࡟࡯࠻㑆㓒

[m]

Vd

㧦ಽᢔ⋧ߺ߆ߌᵹㅦ

[m s-1]Ӡȡ 㧦⋧㑆ኒᐲᏅ[kg m-3]ȝc㧦ㅪ⛯⋧☼ᐲ

[Pa࡮s]

ȝd㧦ಽᢔ⋧☼ᐲ

[Pa࡮s]

ȡc㧦ㅪ⛯⋧ኒᐲ

[kg m-3]ȡd㧦ಽᢔ⋧ኒᐲ

[kg m-3]ȡ*㧦20͠ ߦ߅ߌࠆ᳓ߩኒᐲ

[kg m-3]ı㧦⇇㕙ᒛജ

[N m-1]ߢ޽ࠆ‫ޔ߅ߥޕ‬㧔̪㧕ࠍઃߒߚࡄ࡜ࡔ࡯࠲ߪ࡙࡯ࠩ౉ജߦࠃࠆ࿕ቯ୯ߢ޽ࠆ‫ޕ‬㧟㧚㧝㧚㧡 ‛⾰⒖േࡕ࠺࡞
 ൻቇ⒳ߩಽ㈩ᐔⴧߦࠃࠆ᳓⋧ߣ᦭ᯏ⋧㑆ߩ‛⾰⒖േߦߟ޿ߡߪ‫ޔ‬᳓⋧㧙᦭ᯏ⋧㑆ߩ‛⾰⒖േㅦᐲࠍ⠨ᘦߔࠆߎߣߣߒ‫ޔ‬PARC ߢߪ✚᜝‛⾰⒖േଥᢙࠍ↪޿ߚࡕ࠺࡞ࠍណ↪ߒߡ޿ࠆ‫ޕ‬PULCO ࠦ
࡯࠼ 11) ߩࠃ߁ߦᶧṢߩㆇേࠍ⹦⚦ߦ⴫⃻ߒߚࡕ࠺࡞ߢߪߥߊ‫✚ޔ‬᜝‛⾰⒖േଥᢙߪฦൻቇ⒳ߩಽ
㈩Ყߦߩߺଐሽߔࠆߣߔࠆ Petrich ߩ⚻㛎⊛ࡕ࠺࡞ 12) ࠍෳ⠨ߦߒߡ޿ࠆ‫ޕ‬

13㧔㧝㧕ࠪࡖࡈ࠻ㇱߦ߅ߌࠆ‛⾰⒖േ
Petrich ߩ⚻㛎⊛ࡕ࠺࡞ߪ‫ޔ‬ታ㛎࠺࡯࠲߆ࠄࠞ࡯ࡉࡈࠖ࠶࠹ࠖࡦࠣߦࠃߞߡᓧࠄࠇߚ߽ߩߢ‫ޔ‬ᰴᑼߢ⴫ߐࠇࠆ 12)‫ޕ‬dCdrop / dt

E

S  E Cdrop, t f  Cdrop ,t§ dC ·D ¨ cont ¸¨ dCdrop ¸©
¹

J(3.39)

Į = 0.0038 r 0.0009 cm s-1
Ȗ = 0.63 r 0.16
 ߎߎߢ‫ޔ‬
Ccont 㧦ㅪ⛯⋧ਛỚᐲ[mol dm-3]

Cdrop 㧦ಽᢔ⋧ਛỚᐲ[mol dm-3]

ȕ㧦✚᜝‛⾰⒖േଥᢙ㧔ಽᢔ⋧ၮḰ㧕 [cm s-1]S㧦ಽᢔ⋧૕Ⓧ޽ߚࠅಽᢔ⋧⴫㕙Ⓧ[cm-1]

ߢ޽ࠆ‫ޕ‬
PARC ߢߪ‫ޔ‬Petrich ࡕ࠺࡞ࠍෳ⠨ߦ‫࠻ࡈࡖࠪޔ‬ㇱߢߩ᦭ᯏ⋧ၮḰߩ✚᜝‛⾰⒖േଥᢙ ȕ ߇ᰴᑼߢ⴫ߐࠇࠆߣߒߡ޿ࠆ‫ޕ‬E§ dCaq ·¸
0.0038 ¨¨ dCorg ¸
©
¹

0.63

(3.40)

ߎߎߢ‫ޔ‬
Caq 㧦᳓⋧Ớᐲ[mol dm-3]

Corg 㧦᦭ᯏ⋧Ớᐲ[mol dm-3]

ȕ㧦✚᜝‛⾰⒖േଥᢙ㧔᦭ᯏ⋧ၮḰ㧕 [cm s-1]ߢ޽ࠆ‫ߩߢߎߎޕ‬ᓸಽߪᐔⴧ✢਄ߩᓸಽߢ޽ࠆ‫ޕ‬ᑼ(3.1)‫(ޔ‬3.2)ߢߩ‛⾰⒖േ㗄 M ߪᰴߩࠃ߁ߦߥࠆ‫ޕ‬Ms  E ( y*  y)

y*

Dx

(3.41)ߎߎߢs 㧦 ฦ⋧න૏૕Ⓧ޽ߚࠅߩធ⸅⇇㕙Ⓧ [cm-1]
y 㧦 ᦭ᯏ⋧ਛߩỚᐲ[mol dm-3]

D 㧦 ಽ㈩Ყ

[-]x 㧦 ᳓⋧ਛߩỚᐲ[mol dm-3]

ߢ޽ࠆ‫ޕ‬
න૏૕Ⓧ㧔᳓⋧߅ࠃ߮᦭ᯏ⋧ߩว⸘㧕޽ߚࠅߩធ⸅⇇㕙Ⓧ a [m-1] ߪᰴᑼߢਈ߃ࠄࠇࠆ‫ޕ‬

14

a

6

Id

(3.42)dpߎߎߢǾd 㧦 ಽᢔ⋧ࡎ࡯࡞࠼ࠕ࠶ࡊ [-]dp

㧦 ಽᢔ⋧ᶧṢᓘ[m]ߢ޽ࠆ‫ޕ‬✚᜝‛⾰⒖േଥᢙߩࡕ࠺࡞ൻߦߟ޿ߡߪ‫੹ޔ‬ᓟ߽ᬌ⸛߇ᔅⷐߣ⠨߃ࠄࠇࠆ‫ޕ‬㧔㧞㧕਄ਅಽ⋧࠲ࡦࠢߦ߅ߌࠆ‛⾰⒖േಽ⋧࠲ࡦࠢߦ߅ߌࠆ‛⾰⒖േࡕ࠺࡞ߩ⠨߃ᣇߪ‫ޔ‬ᑼ(3.41)ߣห᭽ߢ޽ࠆ‫✚ߒߛߚޕ‬᜝‛⾰⒖േଥᢙ‫ޔ‬᳓⋧෸߮᦭ᯏ⋧ߩฦࡎ࡯࡞࠼ࠕ࠶ࡊ‫ޔ‬ੑ⋧ߩធ⸅⇇㕙Ⓧߪ‫౉ࠩ࡯࡙ޔ‬ജߦࠃߞߡ࿕ቯ୯ࠍਈ
߃ࠆߎߣߣߒߡ޿ࠆ‫౉ޕ‬ജ૞ᚑߦᒰߚߞߡߪ‫ޔ‬ᮨᡆߒࠃ߁ߣߔࠆࡄ࡞ࠬࠞ࡜ࡓߩ᭴ㅧ߿ㅪ⛯⋧㧛ಽᢔ⋧ߩㆬᛯࠍ⠨ᘦߔࠆߎߣ߇ᦸ߹ߒ޿‫ޕ‬㧟㧚㧝㧚㧢 ಽᢔ⋧ࡎ࡯࡞࠼ࠕ࠶ࡊ
ࠪࡖࡈ࠻ㇱߦ߅ߌࠆಽᢔ⋧ߩࡎ࡯࡞࠼ࠕ࠶ࡊ₸ߩ▚಴ߦߪ‫ޔ‬Kumar ࠄ 8) ߦࠃࠆ perforate plateဳࡄ࡞ࠬࠞ࡜ࡓߢߩផ▚ࡕ࠺࡞ࠍណ↪ߒߚ‫ޕ‬Id

k1 exp>k 2 Af  ( Af ) m @ Vd0.86 Vc  Vd

Af m

§ V'U 1 / 4D ·¸
k3 ¨¨
3/ 4 ¸
© Pd
¹

0.28

 'U 0.30 U 0.93 P d0.77D 0.56 h 0.56

0.33(3.44)

k1 = 1.99106, k2 = 44.31, k3 = 9.6910-3ߎߎߢA 㧦 ࡄ࡞ࠬᝄ᏷㧔̪㧕㧔ਔᝄ᏷‫ߜࠊߥߔޔ‬ᝄ᏷ߩ 2 ୚㧕[m]f㧦 ࡄ࡞ࠬᝄേᢙ㧔̪㧕

[s-1]

h

㧦 perforate plate ߩ㑆㓒㧔̪㧕[m]Vc 㧦 ㅪ⛯⋧ߺ߆ߌᵹㅦ

[m s-1]

Vd 㧦 ಽᢔ⋧ߺ߆ߌᵹㅦ

[m s-1]Į 㧦 ⋡⋁᧼ߩ free area ഀว㧔̪㧕 [ - ]Ǿd 㧦 ಽᢔ⋧ࡎ࡯࡞࠼ࠕ࠶ࡊ₸[-]ȝd 㧦 ಽᢔ⋧☼ᕈ₸[Pa࡮s]

ȡd 㧦 ಽᢔ⋧ኒᐲ[kg m-3]ǻȡ 㧦 ᳓⋧㧙᦭ᯏ⋧㑆ߩኒᐲᏅ[kg m-3]

ı[N m-1]㧦 ⇇㕙ᒛജ

(3.43)

ߢ޽ࠆ‫ޔ߅ߥޕ‬㧔̪㧕ࠍઃߒߚࡄ࡜ࡔ࡯࠲ߪ࡙࡯ࠩ౉ജߦࠃࠆ࿕ቯ୯ߢ޽ࠆ‫ޕ‬15㧟㧚㧝㧚㧣 ಽᢔ⋧ᶧṢᓘࠪࡖࡈ࠻ㇱߦ߅ߌࠆಽᢔ⋧ᶧṢᓘߩ▚಴ߦߪ‫ޔ‬Kumar ࠄ 6) ߦࠃࠆ perforated plate ဳࡄ࡞ࠬࠞ࡜
ࡓߢߩផ▚ࡕ࠺࡞ࠍណ↪ߒߚ‫ޕ‬

0.18

dp

V
'U g

§
·
¨
¸
0.20
0.34
§ Pd g1 / 4 ·§ Pd ·¨¸
h0.40
0.16  D ¨
 ¨¨ ¸¸¸  ¨¨ 1 / 4 3 / 4 ¸¸UVV© Pc ¹c©
¹¨¸¨ Ug ¸c©
¹ª§
A f 2 ·º¨¸¸» «0.23  exp¨  29.66
g
D
©
¹¼
¬

ߎߎߢ
A 㧦 ࡄ࡞ࠬᝄ᏷㧔̪㧕㧔ਔᝄ᏷‫ߜࠊߥߔޔ‬ᝄ᏷ߩ 2 ୚㧕[m]dp 㧦 ᶧṢᓘ

[m]
㧔̪㧕

[s-1]

f

㧦 ࡄ࡞ࠬᝄേᢙg㧦 ㊀ജടㅦᐲ

[m s-2]h㧦 perforate plate ߩ㑆㓒㧔̪㧕[m]Į 㧦 ⋡⋁᧼ߩ free area ഀว㧔̪㧕[-]ȝc 㧦 ㅪ⛯⋧☼ᐲ[Pa࡮s]

ȝd 㧦 ಽᢔ⋧☼ᐲ[Pa࡮s]

ȡc 㧦 ㅪ⛯⋧ኒᐲ[kg m-3]ǻȡ 㧦 ᳓⋧ߣ᦭ᯏ⋧ߩኒᐲᏅ[kg m-3]

ı[N m-1]㧦 ⇇㕙ᒛജ

ߢ޽ࠆ‫ޔ߅ߥޕ‬㧔̪㧕ࠍઃߒߚࡄ࡜ࡔ࡯࠲ߪ࡙࡯ࠩ౉ജߦࠃࠆ࿕ቯ୯ߢ޽ࠆ‫ޕ‬16(3.45)

㧟㧚㧞 ࡒࠠࠨ࠮࠻࡜
㧟㧚㧞㧚㧝 ‛⾰෼ᡰᑼࡒࠠࠨ࠮࠻࡜ߩၮᧄ⸘▚ࡕ࠺࡞ߪ‫ޔ‬᳓⋧෸߮᦭ᯏ⋧ߩᵹࠇߦߟ޿ߡߪ Revised-MIXSET ╬ߩᓥ᧪ߩࡒࠠࠨ࠮࠻࡜⸘▚ࠦ࡯࠼ 13-15) ߣ߶߷ห᭽ߢ޽ࠆ㧔࿑ 3.3㧕‫ޕ‬Ბౝߩ࡝ࠨࠗࠢ࡞ࡈࡠ࡯ߦߟ޿
ߡߪ‫ޔ‬PARC ߢߪ᳓⋧࡝ࠨࠗࠢ࡞ߩߺࠍ⠨ᘦߒߡ޿ࠆ‫ࠨࠠࡒޕ‬ㇱ෸߮࠮࠻࡜ㇱߩ᳓⋧෸߮᦭ᯏ⋧ߩࡎ࡯࡞࠼ࠕ࠶ࡊߪ࡙࡯ࠩ౉ജߦࠃࠅ࿕ቯߔࠆߎߣߣߒߡ޿ࠆ‫ࠨࠠࡒޕ‬ㇱߩࡎ࡯࡞࠼ࠕ࠶ࡊߪ‫ޔ‬ࠦࡦࡐ࡯ࡀࡦ࠻Ფߦ࡙࡯ࠩ߇࿕ቯ୯㧔phi1㧕ࠍਈ߃‫࡜࠻࠮ߩ࡜࠻࠮ࠨࠠࡒߚ߹ޔ‬ㇱߩࡎ࡯࡞࠼ࠕ
࠶ࡊߪ‫౒ߦ࡜࠻࠮ࠨࠠࡒߩߡోޔ‬ㅢߩ࿕ቯ୯㧔phiS‫ޔ‬8.4.2.1 ▵(27)ෳᾖ‫ޕ‬㧕ࠍਈ߃ࠆߎߣߣߒߚ‫ޕ‬㧔ࡒࠠࠨㇱ᳓⋧㧕

d
xm ,i
dt

Far,i
F
1
r
 m ( Fa ,i  Fa ,i ) xm ,i  m xs ,i  a ,mi 1 xs ,i 1  M ma ,i
Va ,i
Va ,i
Va ,i

(3.46)1 ¦ ( r ( xm,i )) Rma ,i  m ¦ Faf,i x f ,i
Va ,i

>

@

㧔ࡒࠠࠨㇱ᦭ᯏ⋧㧕dym , i
dt



Fo ,i
m
o ,i

V

ym , i 

Fo ,i 1mo ,iV

@ V1 ¦ F y>

ys ,i 1  M mo ,i  ¦ ( r ( ym ,i )) Rmo ,i 

f
o ,i

m
o ,i

f ,i

(3.47)

㧔࠮࠻࡜ㇱ᳓⋧㧕dxs , idt

1
1( Fa ,i  Far,i ) xm ,i  s ( Fa ,i  Far,i ) xs ,i  ¦ ( r ( xs ,i )) Rsa ,i
s
Va ,i
Va ,i

>

@

(3.48)

㧔࠮࠻࡜ㇱ᦭ᯏ⋧㧕dys , i
dt

Fo ,i
s
o ,i

V

ym , i 

Fo ,i
Vos,i

>

ys ,i  ¦ ( r ( ys ,i )) Rso ,i@(3.49)

㧟㧚㧞㧚㧞 ࡒࠠࠨ࠮࠻࡜ౝㇱߦ߅ߌࠆᏅಽᑼ
㧔ࡒࠠࠨㇱ᳓⋧㧕

xmn ,i1  xmn ,i't

Far,i n 1 Fa ,i 1 n 11r
n 1
 m ( Fa ,i  Fa ,i ) xm,i  m xs ,i  m xs ,i 1
Va ,i
Va ,i
Va ,i
M

n 1
ma , i> ¦ ( r ( x

n 1
m,i

n 1
ma , i)) R@

1
 m ¦ Faf,i x f ,i
Va ,i

17

(3.50)

㧔ࡒࠠࠨㇱ᦭ᯏ⋧㧕ymn ,i1  ymn ,i
't



Fo ,i
m
o ,i

V

ymn ,i1 Fo ,i 1mo ,iV

@ V1 ¦ F y

>

n 1
n 1
n 1
ysn,i 11  M mo
, i  ¦ ( r ( ym , i )) Rmo , i 

f
o ,i

m
o ,i

f ,i

(3.51)

㧔࠮࠻࡜ㇱ᳓⋧㧕㨤ns ,i 1  xsn,i't

1
1( Fa ,i  Far,i ) xmn ,i1  s ( Fa ,i  Far,i ) xsn,i 1  ¦ ( r ( xsn,i 1 )) Rsan ,i1
s
Va ,i
Va ,i

>

@

(3.52)

㧔࠮࠻࡜ㇱ᦭ᯏ⋧㧕ysn,i 1  ysn,i

Fo ,i

't

s
o ,i

V

ymn ,i1 

Fo ,i
s
o ,i

V

>

ysn,i 1  ¦ ( r ( ysn,i 1 )) Rson ,i1@

(3.53)

㧟㧚㧞㧚㧟 ࡒࠠࠨ࠮࠻࡜ਔ┵ߦ߅ߌࠆᏅಽᑼ
㧔㧝㧕᦭ᯏ⋧౉ญᲑ㧔ࡒࠠࠨㇱ᳓⋧㧕

x mn ,11  x mn ,1't

Far,1 n 1 Fa , 2 n 1
1
r
n 1
n 1
 m ( Fa ,1  Fa ,1 ) x m,1  m x s ,1  m x s , 2  M ma
,1
Va ,1
Va ,1
Va ,1

>

 ¦ ( r ( x

n 1
m ,1

)) R

n 1
ma ,1

@

(3.54)1 m ¦ Faf,1 x f ,1
Va ,1㧔ࡒࠠࠨㇱ᦭ᯏ⋧㧕

ymn,11  ymn ,1't

Fo ,1 n1
1
n 1
n 1
n 1
ym ,1  M mo
Ff y
,1  ¦ ( r ( ym ,1 )) Rmo ,1 m ¦ o ,1 f ,1
m
Vo ,1
Vo ,1

>

@

(3.55)

㧔࠮࠻࡜ㇱ᳓⋧㧕

x sn,11  x sn,1't

1
1
( Fa ,1  Far,1 ) x mn ,11  s ( Fa ,1  Far,1 ) x sn,11  ¦ ( r ( x sn,11 )) Rsan ,11
s
Va ,1
Va ,1

>

@

(3.56)

㧔࠮࠻࡜ㇱ᦭ᯏ⋧㧕

y sn,11  y sn,1

Fo ,1

't

s
o ,1

V

y mn ,11 

Fo ,1
V

s
o ,1

>

y sn,11  ¦ ( r ( y sn,11 )) Rson ,11㧔㧞㧕᳓⋧౉ญᲑ


18@(3.57)

㧔ࡒࠠࠨㇱ᳓⋧㧕

x mn , N1  x mn , N



't

1
V

m
a,N

r
a, N

( Fa , N  F

)x

n 1
m, N



>

Far, N
V

m
a,N

n 1
x sn,N1  M ma
,N

(3.58)

1@ V ¦F xn 1 ¦ ( r ( x mn , N1 )) Rma
,N 

m
a, N

f
a,N

f ,N

㧔ࡒࠠࠨㇱ᦭ᯏ⋧㧕ymn , N1  ymn , N'tFo , Nmo, NVymn , N1 

Fo , N 1
m
o, N

V

>

 ¦ ( r ( y

n 1
m, N

n 1
ysn,N11  M mo,Nn 1
mo , N)) R@(3.59)1 m ¦ Fo,f N y f , N
Vo , N㧔࠮࠻࡜ㇱ᳓⋧㧕

xsn,N1  xsn, N

1

't

s
a, N

( Fa , N  Far, N ) xmn , N1 

V

1
s
a, N

V

>

( Fa , N  Far, N ) xsn,N1  ¦ ( r ( xsn,N1 )) Rsan ,1N

@ (3.60)㧔࠮࠻࡜ㇱ᦭ᯏ⋧㧕

y sn,N1  y sn, N

Fo , N

't

s
o,N

V

ymn, N1 

Fo , Nso,NV>y sn,N1  ¦ ( r ( y sn,N1 )) Rson,1N@(3.61)

㧟㧚㧞㧚㧠 ‛⾰⒖േࡕ࠺࡞
ࡒࠠࠨ࠮࠻࡜ߢߩಽ㈩ᐔⴧߦࠃࠆੑ⋧㑆ߩ‛⾰⒖േߪ‫ࠨࠠࡒޔ‬ㇱߩߺߢߥߐࠇࠆࡕ࠺࡞ߣߥߞ
ߡ޿ࠆ‫ࠨࠠࡒޕ‬ㇱߢߩ‛⾰⒖േ⸘▚ߦᒰߚߞߡߪ‫ߣࡓ࡜ࠞࠬ࡞ࡄޔ‬ห᭽‫✚ޔ‬᜝‛⾰⒖േㅦᐲࠍ⠨ᘦߒߚࡕ࠺࡞ߣߒߡ޿ࠆ㧔3.1.5 ▵ෳᾖ㧕‫ޕ‬ ࡒࠠࠨㇱߢߩන૏૕Ⓧ㧔᳓⋧෸߮᦭ᯏ⋧ߩว⸘㧕޽ߚࠅߩੑ⋧ធ⸅⇇㕙Ⓧ a [m-1] ߪᰴᑼ 16)ߢਈ߃ࠄࠇࠆ‫ޕ‬aKI d § d R3 N 2 ȡc ·¨
C d R ¨©

ı

0 .6

¸¸
¹

(3.62)

C 1  9Id

(3.63)

K(3.64)

100

 ߎߎߢ
a

㧦න૏૕Ⓧ㧔᳓⋧෸߮᦭ᯏ⋧ߩว⸘㧕޽ߚࠅߩធ⸅⇇㕙ⓍǾd 㧦ಽᢔ⋧ࡎ࡯࡞࠼ࠕ࠶ࡊ㧔̪㧕

19

K

㧦ᢥ₂ 16) ߩࡕ࠺࡞ߢߪ K = 100 ߣߥࠆ‫ޕ‬K ߪ࡙࡯ࠩ౉ജߦࠃߞߡᄌᦝ߇น⢻ߢ޽ࠆ‫ޕ‬dR㧦ᡬᜈ⠢ߩ⋥ᓘ㧔̪㧕N㧦ᡬᜈ⠢ߩ࿁ォㅦᐲ㧔̪㧕ȡc㧦ㅪ⛯⋧ኒᐲı㧦⇇㕙ᒛജߢ޽ࠆ‫ޕ‬ฦ㊂ߪ‫ޔ‬0.6 ਸ਼ߒߡ޿ࠆࠞ࠶ࠦౝ㧔Weber ᢙ㧕߇ᱜߒߊήᰴరߣߥࠆࠃ߁ㆡᒰߥන૏ࠍߣ
ࠆ߽ߩߣߔࠆ‫ޔ߅ߥޕ‬㧔̪㧕ࠍઃߒߚࡄ࡜ࡔ࡯࠲ߪ࡙࡯ࠩ౉ജߦࠃࠆ࿕ቯ୯ߢ޽ࠆ‫ޕ‬20㧟㧚㧟 ࠲ࡦࠢ㧟㧚㧟㧚㧝 ‛⾰෼ᡰᑼ࠲ࡦࠢߩ⸃ᨆࡕ࠺࡞ࠍએਅߦ␜ߔ‫ޕ‬PARC ߢᮨᡆߢ߈ࠆ࠲ࡦࠢߪ‫ޔ‬᳓⋧ߩߺߩ࠲ࡦࠢ‫᦭ޔ‬ᯏ⋧ߩߺߩ࠲ࡦࠢߩੑ⒳㘃ߢ޽ࠆ‫ࠢࡦ࠲ߩߢ࡞࠺ࡕᧄޕ‬ౝߩᶧ㊂㧔૕Ⓧ㧕ߪ৻ቯߢ޽ࠅ‫ޔ‬ᄌൻߒߥ޿
ߣߒߡ޿ࠆ‫ࠢࡦ࠲ޔߚ߹ޕ‬ౝߢߩൻቇ෻ᔕߪ⠨ᘦߐࠇߡ޿ࠆ‫ޕ‬㧔᳓⋧࠲ࡦࠢ㧕

dx
dt



1
1
Fa x  ¦ ( r ( x)) Ra 
Faf x f
¦
Va
Va

>

@

y=0

(3.65)(3.66)

㧔᦭ᯏ⋧࠲ࡦࠢ㧕

dy
dt



1
1
Fo y  ¦ ( r ( y )) Ro  ¦ Fo f y f
Vo
Vo

>

@

x=0

(3.67)(3.68)ߎߎߢx 㧦 ᳓⋧Ớᐲy 㧦 ᦭ᯏ⋧ỚᐲV 㧦 ࠲ࡦࠢߩኈⓍ㧔= ࠲ࡦࠢߩᶧ㊂㧔৻ቯ㧕㧕R 㧦 ൻቇ෻ᔕ㊂F 㧦 ᵹ㊂ߢ޽ࠆ‫ޕ‬ᷝሼߪ‫ޔ‬a 㧦 ᳓⋧o 㧦 ᦭ᯏ⋧f 㧦 ࡈࠖ࡯࠼߹ߚߪઁࠦࡦࡐ࡯ࡀࡦ࠻߆ࠄߩᵹ౉
ߢ޽ࠆ‫ޕ‬

㧟㧚㧟㧚㧞 Ꮕಽᑼ㧔᳓⋧࠲ࡦࠢ㧕x n 1  x n't
y n 1



1
1
Fa x n 1  ¦ [( r ( x n 1 )) Ran 1 ]  ¦ Faf x f
Va
Va

0

(3.69)(3.70)

21㧔᦭ᯏ⋧࠲ࡦࠢ㧕x n 10y n 1  y n't(3.71)



1
1
Fo y n 1  ¦ [( r ( y n 1 )) Ron 1 ]  ¦ Fo f y f
Vo
Vo

22

(3.72)

㧟㧚㧠 ‛ᕈ୯ࡄ࡞ࠬࠞ࡜ࡓߦ߅ߌࠆᶧṢᓘ‫ޔ‬ㅒᷙวଥᢙ‫ࠆߌ߅ߦ࡜࠻࠮ࠨࠠࡒߚ߹ޔࡊ࠶ࠕ࠼࡞࡯ࡎޔ‬ੑ⋧ߩធ⸅⇇㕙Ⓧߩ▚಴ߦᔅⷐߣߥࠆ᳓⋧෸߮᦭ᯏ⋧ߩṁᶧኒᐲ‫☼ޔ‬ᐲ‫⇇ޔ‬㕙ᒛജߪએਅߩࠃ߁ߦ▚಴ߔࠆ‫ޕ‬
ߎࠇࠄߩ‛ᕈ୯ߪ‫౉ࠩ࡯࡙ޔ‬ജߦࠃߞߡฦࠦࡦࡐ࡯ࡀࡦ࠻Ფߦ⸳ቯߒ‫࠻ࡦࡀ࡯ࡐࡦࠦޔ‬ౝߢߪ৻ቯߣߒߡᛒࠊࠇࠆ‫ޕ‬㧟㧚㧠㧚㧝 ኒᐲࡄ࡞ࠬࠞ࡜ࡓߦ߅ߌࠆᶧṢᓘ‫ޔ‬ㅒᷙวଥᢙ‫ࠆߌ߅ߦ࡜࠻࠮ࠨࠠࡒߚ߹ޔࡊ࠶ࠕ࠼࡞࡯ࡎޔ‬ੑ⋧ߩធ⸅⇇㕙Ⓧߩ▚಴ߦᔅⷐߣߥࠆ᳓⋧෸߮᦭ᯏ⋧ߩṁᶧኒᐲߪએਅߩࠃ߁ߦ▚಴ߔࠆ 17) ‫ޕ‬㧔㧝㧕᳓⋧ኒᐲ

UT 1.0125  U 25  0.000145  T  0.0005  T  U 25  0.0036(3.73)

U 25 1.0012  0.3177 xU 6  0.22 xPU 4  0.03096 xH(3.74)

ߎߎߢ‫ޔ‬ȡT㧦T [͠] ߦ߅ߌࠆ᳓⋧ኒᐲ[g cm-3]

ȡ25

㧦25 ͠ߦ߅ߌࠆ᳓⋧ኒᐲ[g cm-3]

xU6

㧦࠙࡜ࡦ(VI)ߩ᳓⋧Ớᐲ㧔̪㧕[mol dm-3]

xPU4

㧦ࡊ࡞࠻࠾࠙ࡓ(IV)ߩỚᐲ㧔̪㧕[mol dm-3]xH

㧦H+ߩ᳓⋧Ớᐲ㧔̪㧕[mol dm-3]

T㧦ṁᶧ᷷ᐲ㧔̪㧕[͠]ߢ޽ࠆ‫ޔ߅ߥޕ‬㧔̪㧕ࠍઃߒߚࡄ࡜ࡔ࡯࠲ߪ࡙࡯ࠩ౉ജߦࠃࠆ࿕ቯ୯ߢ޽ࠆ‫ޕ‬xU6 , xPU4 ෸߮ xH ߪ‫ޔ‬ࠦࡦࡐ࡯ࡀࡦ࠻Ფߦઍ⴫Ớᐲࠍਈ߃ࠆߎߣߣߒߚ‫ޕ‬㧔㧞㧕᦭ᯏ⋧ኒᐲUT

U 25  0.318 yU 6  0.028 y H  8 u 10 4 (T  25)(3.75)

U 25

0.972  F  (1  F )  0.750(3.76)

ߎߎߢȡT㧦T [͠]ߦ߅ߌࠆ᦭ᯏ⋧ኒᐲ[g cm-3]

ȡ25

㧦25 ͠ߦ߅ߌࠆ᦭ᯏ⋧ኒᐲ[g cm-3]yU6㧦࠙࡜ࡦ(VI)ߩ᦭ᯏ⋧Ớᐲ㧔̪㧕[mol dm-3]

23

yH

㧦H+ߩ᦭ᯏ⋧Ớᐲ㧔̪㧕[mol dm-3]F㧦᦭ᯏ⋧ਛߩ TBP ߩ૕Ⓧಽ₸㧔̪㧕

[-]

㧦ṁᶧ᷷ᐲ

T

㧔̪㧕

[͠]

ߢ޽ࠆ‫ޔ߅ߥޕ‬㧔̪㧕ࠍઃߒߚࡄ࡜ࡔ࡯࠲ߪ࡙࡯ࠩ౉ജߦࠃࠆ࿕ቯ୯ߢ޽ࠆ‫ޕ‬yU6 , yPU4 ෸߮ yH ߪ‫ޔ‬ࠦࡦࡐ࡯ࡀࡦ࠻Ფߦઍ⴫Ớᐲࠍਈ߃ࠆߎߣߣߒߚ‫ޕ‬㧟㧚㧠㧚㧞 ☼ᐲࡄ࡞ࠬࠞ࡜ࡓߦ߅ߌࠆᶧṢᓘ‫ޔ‬ㅒᷙวଥᢙ‫ࠆߌ߅ߦ࡜࠻࠮ࠨࠠࡒߚ߹ޔࡊ࠶ࠕ࠼࡞࡯ࡎޔ‬ੑ⋧ߩធ⸅⇇㕙Ⓧߩ▚಴ߦᔅⷐߣߥࠆṁᶧߩ☼ᐲߪએਅߩࠃ߁ߦ▚಴ߔࠆ 17) ‫ޕ‬㧔㧝㧕᳓⋧☼ᐲlog10 P

>0.9527  0.2426 x  0.0100 x  (0.0089  0.0023x )  x @  4
2
U6

U6

U6

H

(3.77)

ߎߎߢ
ȝ

㧦᳓⋧☼ᐲ

xU6

㧦࠙࡜ࡦ(VI)ߩ᳓⋧Ớᐲ

xH

㧦H+ߩ᳓⋧Ớᐲ㧔̪㧕[Pa s][mol dm-3]

㧔̪㧕[mol dm-3]

ߢ޽ࠆ‫ޔ߅ߥޕ‬㧔̪㧕ࠍઃߒߚࡄ࡜ࡔ࡯࠲ߪ࡙࡯ࠩ౉ജߦࠃࠆ࿕ቯ୯ߢ޽ࠆ‫ޕ‬xU6 ෸߮ xH ߪ‫ࠦޔ‬ࡦࡐ࡯ࡀࡦ࠻Ფߦઍ⴫Ớᐲࠍਈ߃ࠆߎߣߣߒߚ‫ޕ‬㧔㧞㧕᦭ᯏ⋧☼ᐲP

P 25͠  33 u 104  yU 6

log10 P 25

(3.78)>F  (1.345  0.36  F )  (1  F )  log10 14@  4(3.79)

ߎߎߢȝ㧦᦭ᯏ⋧☼ᐲ

[Pa s]

ȝ25

㧦᷷ᐲ 25͠ߦ߅ߌࠆṁᇦ☼ᐲ[Pa s]

㧔࠙࡜ࡦ╬߇฽߹ࠇߡ޿ߥ޿ TBP ෸߮ n-࠼࠺ࠞࡦߩߺ߆ࠄߥࠆṁᇦ㧕yU6㧦࠙࡜ࡦ(VI)ߩ᦭ᯏ⋧Ớᐲ㧔̪㧕[mol dm-3]F㧦᦭ᯏ⋧ਛߩ TBP ߩ૕Ⓧಽ₸㧔̪㧕[-]ߢ޽ࠆ‫ޔ߅ߥޕ‬㧔̪㧕ࠍઃߒߚࡄ࡜ࡔ࡯࠲ߪ࡙࡯ࠩ౉ജߦࠃࠆ࿕ቯ୯ߢ޽ࠆ‫ޕ‬yU6 ߪ‫ࡀ࡯ࡐࡦࠦޔ‬ࡦ࠻Ფߦઍ⴫Ớᐲࠍਈ߃ࠆߎߣߣߒߚ‫ޕ‬24㧟㧚㧠㧚㧟 ⇇㕙ᒛജࡄ࡞ࠬࠞ࡜ࡓߦ߅ߌࠆᶧṢᓘ‫ޔ‬ㅒᷙวଥᢙ‫ࠆߌ߅ߦ࡜࠻࠮ࠨࠠࡒߚ߹ޔࡊ࠶ࠕ࠼࡞࡯ࡎޔ‬ੑ⋧ߩធ⸅⇇㕙Ⓧߩ▚಴ߦᔅⷐߣߥࠆṁᶧߩ⇇㕙ᒛജߪએਅߩࠃ߁ߦ▚಴ߔࠆ 17)‫ޕ‬ı= 4.8 10-2 [N m-1]

(3.80)⇇㕙ᒛജߪ‫ޔ‬ᢥ₂ 17)ߦ଀␜ߐࠇߚ߽ߩࠍ⃻⁁⚵ߺㄟࠎߢ޿ࠆ‫ޕ‬ធ⸅ߔࠆṁᶧߩ⒳㘃ߦࠃߞߡ⇣ߥࠆ႐วߦߪ 18-19)‫ߩ࡜࠻࠮ࠨࠠࡒ߫߃଀ޔ‬ធ⸅⇇㕙Ⓧߩࡕ࠺࡞㧔3.2.4 ▵㧕ߩ K ୯ࠍ⺞ᢛߔࠆߎߣ
ߢኻᔕߢ߈ࠆ‫ޕ‬

25

OFL
᦭ᯏ⋧಴ญ
xin, yout᳓⋧ࡈࠖ࡯࠼᳓⋧౉ญ਄ㇱಽ⋧࠲ࡦࠢ 㧔ࡔ࠶ࠪࡘ N㧕

AFD

z=H
xN, y Nࡔ࠶ࠪࡘ N-1

z = H-0

Ua

䉲䊞䊐䊃ㇱ

᳓⋧

ࡔ࠶ࠪࡘ i+1

Ma

᦭ᯏ⋧

‛⾰⒖േ

ࡔ࠶ࠪࡘ iMoࡔ࠶ࠪࡘ i-1xyUo
S oz , yoz᳓⋧ࡈࠖ࡯࠼

᦭ᯏ⋧ࡈࠖ࡯࠼

S az , xaz

z = +0x1, y1ࡔ࠶ࠪࡘ N-1

z=0
OFD᦭ᯏ⋧ࡈࠖ࡯࠼

xout , yin
᦭ᯏ⋧౉ญ
AFL
᳓⋧಴ญ

ਅㇱಽ⋧࠲ࡦࠢ 㧔ࡔ࠶ࠪࡘ 1㧕࿑㧟㧚㧝 PARC ߢߩࡄ࡞ࠬࠞ࡜ࡓߩࡕ࠺࡞

26

r(x)

1

㧜

x

Ǭ

㱐䋺ቯᢙ

࿑㧟㧚㧞 ൻቇ෻ᔕ㗄ߦଥࠆ r(x) 㑐ᢙFaf,i , x f ,i Fo ,fi , y f ,i
䉶䊃䊤ㇱ

䊚䉨䉰ㇱ

Vom,i

s
o ,i 1Vy s ,i 1䉶䊃䊤ㇱVos,i 1y m ,i

Fo ,i 1y s ,i 1

ma ,i

Fo ,i 1V
Fa ,i 1

Fa ,i 1xm ,i
s
a ,i 1

V

Far,i 1

xs ,i 1

Far,i 1

Vas,i 1
xs ,i 1

Vos,i
Fo ,i  2

y s ,i

Vom,i 1ym,i 1

Far,i

Vam,i 1

Fa ,i

xm,i 1
䊚䉨䉰ㇱ

Fo ,i

Vom,i 1ym,i 1sa ,iV

Vam,i 1x s ,i䉶䊃䊤ㇱ䊚䉨䉰ㇱ

Faf,i 1 , x f ,i 1
Fo ,fi 1 , y f ,i 1
Ბ⇟ภ

㫀㪄㪈Ბ

Fa ,i  2

xm ,i 1㫀Ბ

Faf,i 1 , x f ,i 1
Fo ,fi 1 , y f ,i 1

᳓⋧䈱ᵹ䉏

㫀㪂㪈Ბ

᦭ᯏ⋧䈱ᵹ䉏

࿑㧟㧚㧟 PARC ߢߩࡒࠠࠨ࠮࠻࡜ߩࡕ࠺࡞

27

Fo , yf,1

Fa , xf,1
Fa , xf,2

Fo , yf,2Fa , xf,3Fo , yf,3Fa , xFo , yVa , x

Vo , y᳓⋧࠲ࡦࠢ᦭ᯏ⋧࠲ࡦࠢ
Va , Vo 㧦৻ቯ࿑㧟㧚㧠 PARC ߢߩ᳓⋧࠲ࡦࠢ෸߮᦭ᯏ⋧࠲ࡦࠢߩࡕ࠺࡞

㧠 ൻቇ⒳PARC ߢߪ‫ޔ‬᳓⋧‫᦭ޔ‬ᯏ⋧౒ߦ⴫ 4.1 ߦ␜ߔ 29 ൻቇ⒳߇ቯ⟵ߐࠇߡ޿ࠆ‫ޕ‬એਅߩൻቇ⒳߆ࠄ࡙
࡯ࠩ߇છᗧߦ⸘▚ኻ⽎ߣߔࠆൻቇ⒳ࠍㆬᛯߔࠆߎߣ߇ߢ߈ࠆ㧔8.4.2.1 ▵(3)ෳᾖ㧕‫࠲ࡦࠗޔߚ߹ޕ‬ࡊ࡝࠲ᯏ⢻ߩ೑↪ߦࠃࠅߎࠇࠄએᄖߩൻቇ⒳ߩㅊട߽น⢻ߢ޽ࠆ‫ޕ‬⴫㧠㧚㧝 PARC ߢᛒ߁ߎߣ߇ߢ߈ࠆ 29 ൻቇ⒳

ൻቇ⒳
ID
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29

ൻቇ⒳ฬ⒓
᳓⚛ࠗࠝࡦ
࠙࡜ࡦ(VI)ࡊ࡞࠻࠾࠙ࡓ(IV)ࡊ࡞࠻࠾࠙ࡓ(III)࠙࡜ࡦ(IV)⎣㉄ࡅ࠼ࡠࠠࠪ࡞ࠕ
ࡒࡦ㧔HAN㧕⎣㉄ࡅ࠼࡜ࠫࡦ
੝⎣㉄ࠫ࡞ࠦ࠾࠙ࡓ
࠹ࠢࡀ࠴࠙ࡓ
ࡀࡊ࠷࠾࠙ࡓ(IV)ࡀࡊ࠷࠾࠙ࡓ(V)ࡀࡊ࠷࠾࠙ࡓ(VI)ࠕࠫൻ᳓⚛
iso-ࡉ࠴࡞ࠕ࡞࠺ࡅ࠼
n-ࡉ࠴࡞ࠕ࡞࠺ࡅ࠼
iso-㈼㉄
n-㈼㉄
࡛࠙⚛
࠮ࠪ࠙ࡓ
࡞࠹࠾࠙ࡓ(III)ࡊ࡞࠻࠾࠙ࡓ(VI)ࡃ࠽ࠫ࠙ࡓ(IV)ࡃ࠽ࠫ࠙ࡓ(V)࡝ࡦ㉄ࠫࡉ࠴࡞㧔DBP㧕
࡝ࡦ㉄ࡕࡁࡉ࠴࡞
㧔MBP㧕࡝ࡦ㉄ᩭಽⵚ↢ᚑ‛㧔FP㧕
㧔ᵈ㧠㧕

ㆊ㉄ൻ᳓⚛

න૏ᄌ឵
ଥᢙ
㧔ᵈ㧝㧕

㧙
238.03239.0
239.0
238.03⎣㉄ᩮỚᐲ߳ߩ
ነਈ㧔ᵈ㧞㧕
xNO3
CN
1
1
2
2
4
4
3
3
4
4

ࡈ࡝࡯TBP Ớᐲ⸘▚ߢ⠨ᘦߔࠆ TBP㈩૏ᢙ㧔ᵈ㧟㧕

1 ෸߮ 2
2
2
2
2

㧙

0

1

0

㧙
㧙
91.22
98.0
237.0
237.0
237.0
㧙
㧙
㧙
㧙
㧙
126.9
132.9
101.1
239.0
50.94
50.94
㧙

0
0
0
0
4
1
2
0
0
0
0
0
0
0
0
0
0
0
0

1
0
0
0
4
1
2
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
2
2
2
0
0
0
0
0
0
0
0
0
0
0
0

㧙

0

0

0

㧙

0

0

0

㧙

0

0

0

㧙

0

0

0

29

㧔ᵈ㧝㧕 ‫ޟ‬න૏ᄌ឵ଥᢙ‫߇ޠ‬ቯ⟵ߐࠇߡ޿ࠆൻቇ⒳㧔࠙࡜ࡦ‫╬ࡓ࠙࠾࠷ࡊࡀޔࡓ࠙࠾࠻࡞ࡊޔ‬㧕ߦߟ޿ߡߪ‫౉ޔ‬಴ജࡈࠔࠗ࡞ߦ߅ߌࠆỚᐲ⴫⸥ߩන૏ߪ g dm-3 ߣߔࠆ‫౉ޕ‬ജࡈࠔࠗ࡞ߦ⸥ㅀߐࠇߚỚᐲ⸳ቯߪ‫ޔ‬න૏ᄌ឵ଥᢙߢ㒰ߐࠇ‫ޔ‬න૏߇ mol dm-3 ߦᄌ឵ߐࠇߚ਄ߢൻቇ෻ᔕㅦᐲ╬‫ޔ‬ฦ⒳⸘▚ࠍⴕ߁‫ޕ‬಴ജᤨߦߪ mol
dm-3 ߆ࠄ g dm-3 ߦౣᄌ឵ߐࠇߡ⴫␜ߐࠇࠆ‫ޔ╬ࡦࡒࠕ࡞ࠪࠠࡠ࠼ࡅ㉄⎣ޕ‬ଥᢙߩᰣ߇ "㧙"ߣߥߞߡ޿
ࠆൻቇ⒳ߪ‫ޔ‬g ߣ mol ߩ㑆ߩන૏ᄌ឵ࠍⴕࠊߥ޿ൻቇ⒳ߢ޽ࠅ‫ޔ‬ᓥߞߡ౉ജࡈࠔࠗ࡞ਛߢߩỚᐲᜰቯߩන૏ߪ mol dm-3 ߣߔࠆ‫ޕ‬㧔ᵈ㧞㧕 ಽ㈩Ყߩ⸘▚ߦᒰߚߞߡ⎣㉄ᩮߩỚᐲࠍ↪޿ࠆ႐ว‫ߩߘޔ‬ൻቇ⒳ߩỚᐲࠍ⠨ᘦߔࠆ߆ߤ߁߆ࠍ⴫ߔ‫ޕ‬
PARC ߢߪ‫"ޔ‬xNO3" ෸߮ "CN" ߥࠆੑ⒳㘃ߩỚᐲᄌᢙࠍ଻ᜬߒߡ߅ࠅ‫ޔ‬ฦ‫ޘ‬ቯ⟵߇⇣ߥߞߡ޿ࠆ㧔5.1▵ෳᾖ㧕‫ޕ‬㧔ᵈ㧟㧕 ಽ㈩Ყߩ⸘▚ߦᒰߚߞߡࡈ࡝࡯TBP Ớᐲࠍ↪޿ࠆ႐ว‫࡯࡝ࡈޔ‬TBP Ớᐲߩ▚಴ߦᒰߚߞߡߘߩൻቇ⒳ߩỚᐲࠍ⠨ᘦߔࠆ߆ߤ߁߆ࠍ⴫ߔ㧔ᑼ(6.1)╬ෳᾖ㧕‫ޕ‬㧔ᵈ㧠㧕 ߎߎߢ޿߁‫ޟ‬ᩭಽⵚ↢ᚑ‛㧔FP㧕‫ޔߪߣޠ‬PARC ߦᧂቯ⟵ߩ FP ൻቇ⒳ࠍ߹ߣ߼ߡ৻ߟߩൻቇ⒳ߢ޽ࠆ
߆ߩࠃ߁ߦ✚⒓ߒߡቯ⟵ߒߚ߽ߩ‫ޕ‬዁᧪⊛ߥᯏ⢻᜛ᒛࠍᗐቯߒߚቯ⟵ߢ޽ࠆ‫ޕ‬30㧡 ൻቇ෻ᔕㅦᐲ
PARC ࠦ࡯࠼ߢߪ‫ޔ‬એਅߩൻቇ෻ᔕᑼ෸߮෻ᔕㅦᐲᑼ߇ቯ⟵ߐࠇ⚵ߺㄟ߹ࠇߡ޿ࠆ‫ࠗޔߚ߹ޕ‬ࡦ࠲ࡊ࡝࠲ᯏ⢻ࠍ೑↪ߔࠆߎߣߢ‫ޔ‬ฦ෻ᔕㅦᐲᑼߩᄌᦝ‫ࠄࠇߎޔ‬એᄖߩ෻ᔕߩㅊടቯ⟵߇น⢻ߢ޽ࠆ‫ޔߚ߹ޕ‬ේሶജᯏ᭴߇߹ߣ߼ߚ‫ޟ‬ౣಣℂࡊࡠ࠮ࠬ࡮ൻቇࡂࡦ࠼ࡉ࠶ࠢ‫ޠ‬19) ߇ෳ⠨ߣߥࠆ‫ޕ‬㧡㧚㧝 ᳓⋧ߦ㑐ߔࠆൻቇ෻ᔕㅦᐲᑼ
᳓⋧ਛߩൻቇ෻ᔕᑼߪએਅߩߣ߅ࠅߢ޽ࠆ‫ޕ‬RX ߢᆎ߹ࠆቯᢙߪ‫ߡߒߣ࠲࡯࠺࠼࡯ࡢ࡯ࠠޔ‬ቯ⟵ߐࠇߡ߅ࠅ‫߇ࠩ࡯࡙ޔ‬૞ᚑߔࠆ౉ജࡈࠔࠗ࡞ߦ߅޿ߡછᗧߦᄌᦝ߇น⢻ߢ޽ࠆ㧔8.2 ▵ෳᾖ㧕‫ޕ‬㧔㧝㧕ࡊ࡞࠻࠾࠙ࡓ(IV)ߩ࠙࡜ࡦ(IV)ߦࠃࠆㆶర෻ᔕ 13) 20)
U4+ + 2 Pu4+ + 2 H2O ĺ UO22+ + 2 Pu3+ + 4 H+

dxPU 4
dt

(5.1)

x x
 RX 0101  U 4 2 PU 4
xH

[mol dm-3 min-1](5.2)

RX0101 = 1.5×102
ߎߎߢ‫ޔ‬
xH, xPU4, xU4㧦ฦ‫ޔޘ‬H+, Pu(IV), U(IV)ߩ᳓⋧Ớᐲ [mol dm-3]
ߢ޽ࠆ‫ޕ‬એਅห᭽ߣߔࠆ‫ޕ‬㧔㧞㧕ࡊ࡞࠻࠾࠙ࡓ(IV)ߩ⎣㉄ࡅ࠼ࡠࠠࠪ࡞ࠕࡒࡦߦࠃࠆㆶర෻ᔕ 2) 13) 21)
2 Pu4+ + 2 NH3OH+ ĺ 2 Pu3+ + 4 H+ + 2 H2O + N2

dxPU 4dt

22
k1  xPU
4  x HAN
22
4xPU
3  x H  1  E1 x NO 3

(5.3)
[mol dm-3 min-1](5.4-a)k1=RX0201 exp(-RX0202/T)(5.4-b)ȕ1=RX0203 exp(-RX0204/T)(5.4-c)RX0201=2×1033RX0202=22100
RX0203=31650
RX0204 = 2625
T : ᷷ᐲ

[K]

xNO3 = xH + 2 xU + 4 xPU4 + 3 xPU3 + 4 xU4 +4 xNP4 + xNP5 +2 xNP6

31

(5.4-d)㧔㧟㧕ࡊ࡞࠻࠾࠙ࡓ(III)ߩ㉄ൻ෻ᔕ 13)
2 Pu3+ + 3 H+ + NO3- ĺ 2 Pu4+ + HNO2 + H2O
(i)

(5.5)

-4

xNO2 㧨 10 ߩߣ߈

dxPU 3dt

 RX 0301 xPU 3  x1H.8[mol dm-3 min-1](5.6-a)[mol dm-3 min-1](5.6-b)[mol dm-3 min-1](5.6-c)RX0301 = 5.1×10-3(ii) 10-4 ҇ xNO2 㧨 2.3×10-2 ߩߣ߈

dxPU 3dt

0.44  log10 x H
10 1.3 log10 x H  RX 0302  xPU 3  xNO
2RX0302 = 0.54(iii) 2.3×10-2 ҇ xNO2 ߩߣ߈

dxPU 3dt

 RX 0303  xPU 3

RX0303 = 5.5×10-2
㧔㧠㧕࠙࡜ࡦ(IV)ߩ㉄ൻ෻ᔕ 13) 22)
U4+ + NO3- + H2O ĺ UO22+ + H+ + HNO2(5.7)(i) xH 㧨 0.8 ߩߣ߈

dxU 4
dt

0.38
2.7
 RX 0401  xU 4  xNO
2  xH[mol dm-3 min-1](5.8-a)[mol dm-3 min-1](5.8-b)(ii) 0.8 ҇ xH ߩߣ߈

dxU 4
dt

0.38
 RX 0402  xU 4  xNO
2RX0401 = 2.5×10-2
RX0402 = 1.3×10-2
㧔㧡㧕࠙࡜ࡦ(IV)ߩⓨ᳇ߦࠃࠆ㉄ൻ෻ᔕ 13) 23) 24)
2 U4+ + O2 + H2O ĺ 2 UO22+ + 4 H+

dxU 4
dt

(5.9)

x
 RX 0501 U 4
xH[mol dm-3 min-1](5.10)

RX0501 = 2.5×10-4
㧔㧢㧕੝⎣㉄ߩࡅ࠼࡜ࠫࡦߦࠃࠆಽ⸃ 13) 25)
N2H5+ + HNO2 ĺ H+ + 2 H2O + HN3(5.11)

32

dx NO 2
dt[mol dm-3 min-1]

 RX 0601 xH  x NO 2  xHYD

(5.12)

RX0601 = 3.7×104
㧔㧣㧕੝⎣㉄ߩ⎣㉄ࡅ࠼ࡠࠠࠪ࡞ࠕࡒࡦߦࠃࠆಽ⸃ 13) 26)
HNO2 + NH3OH+ ĺ H+ + 2 H2O + N2O

dxNO 2dt(5.13)[mol dm-3 min-1]

 k1  xNO 2  xHAN  xH

(5.14)

k1 = RX0701 exp(-RX0702 / T)
RX0701 = 7.59×1011
RX0702 = 6350
㧔㧤㧕᡼኿✢ߦࠃࠆ⎣㉄߆ࠄߩ੝⎣㉄ߩ↢ᚑ⃻⁁ߢߪ‫ޔ‬෻ᔕㅦᐲߪ 0 ߦ࿕ቯߒߡ޿ࠆ‫ޕ‬
HNO3 ĺ HNO2

dx NO 2dt

(5.15)[mol dm-3 min-1]

0(5.16)

㧔㧥㧕᡼኿✢ߦࠃࠆ੝⎣㉄ߩಽ⸃⃻⁁ߢߪ‫ޔ‬෻ᔕㅦᐲߪ 0 ߦ࿕ቯߒߡ޿ࠆ‫ޕ‬
HNO2 + H2O ĺ NO3- + H+ + H2

dx NO 2dt

(5.17)[mol dm-3 min-1]

0(5.18)

㧔㧝㧜㧕࠹ࠢࡀ࠴࠙ࡓߩ⸅ᇦ૞↪ߦࠃࠆࡅ࠼࡜ࠫࡦߩಽ⸃෻ᔕ 27) 28)

dxHYD
dt
a

§x ·
 a  xTC  ¨ HYD ¸© 0.1 ¹0.66

[mol dm-3 min-1]§ RX 1002 ·RX 1001  exp¨ 
¸
RT ¹
©

(5.19-a)(5.19-b)

RX1001 = 2.8333×1011
RX1002 = 71000
R = 8.3145
T 㧦 ᷷ᐲ [K]33㧔㧝㧝㧕ࡀࡊ࠷࠾࠙ࡓ(V)ߩ㉄ൻ෻ᔕ 29) 30) 31)
2 NpO2+ + NO3- + 3 H+ ĺ 2 NpO22+ + HNO2 + H2O

dx NP 5dt

 RX 1101  C N2

x1H.3  x NO 2  x NP 5
x NO 2  x NP 5

(5.20)[mol dm-3 min-1](5.21-a)

RX1101 = 1.8×10-3
CN = xH + 2 xU6 + 4 xPU4 + 3 xPU3 + 4 xU4 + xHAN + xHYD + 4 xNP4 + xNP5 +2 xNP6

(5.21-b)㧔㧝㧞㧕ࡀࡊ࠷࠾࠙ࡓ(IV)ߩ㉄ൻ෻ᔕ 29) 31)
2 Np4+ + NO3- + 3 H2O ĺ 2 NpO2+ + HNO2 + 5 H+

dx NP 4dt

 0.5
 RX 1201  x NP 4  x NP 5  x NO
2

(5.22)[mol dm-3 min-1](5.23)

RX1201 = 1.910-3㧔㧝㧟㧕ࡀࡊ࠷࠾࠙ࡓ (VI)ߩ࠙࡜ࡦ(IV)ߦࠃࠆㆶర෻ᔕ 32)
2 NpO22+ + U4+ + 2H2O ĺ 2 NpO2+ + UO22+ + 4 H+

dxNP 6dt(5.24)[mol dm-3 min-1]

 RX 1301  xNP 6  xU 4

(5.25)

RX1301 = 14.4
㧔㧝㧠㧕ࡀࡊ࠷࠾࠙ࡓ(V) ߩ࠙࡜ࡦ(IV)ߦࠃࠆㆶర෻ᔕ
2 NpO2+ + U4+ + 4 H+ ĺ 2 Np4+ + UO22+ + 2H2O

(5.26)

ᰴߩԘ෶ߪԙߩ෻ᔕࠍ࡙࡯ࠩ౉ജߦࠃߞߡㆬᛯน⢻ߣߒߚ‫ޕ‬Ԙ

REACT ࠦ࡯࠼ߩᑼ 33) 34) 35)

dx NP 5dt·
§ RX 1402
 RX 1401  x NP 5  xU 4  ¨¨ RX 1403  x H ¸¸
2
¹
© xH

RX 1401 = 4.5
RX 1402 = 1.6
RX 1403 = 1.4234[mol dm-3 min-1](5.27)

ԙ

Advanced-MIXSET ࠦ࡯࠼ߩᑼ 36) 37)

dxNP 5dt

 RX 1404  xNP 5  xU 4  RX 1405  xNP 4  xU 4

[mol dm-3 min-1](5.28)

RX 1404 = 0.1
RX 1405 = 0.62㧔㧝㧡㧕ࡀࡊ࠷࠾࠙ࡓ(VI)ߩ⎣㉄ࡅ࠼ࡠࠠࠪ࡞ࠕࡒࡦߦࠃࠆㆶర෻ᔕ 38)
2 NpO22+ + 2 NH3OH+ ĺ 2 NpO2+ + 4 H+ + N2 + 2 H2O(5.29)

xNP 6  xHAN
xH

(5.30)

dxNP 6dt

 RX 1501 [mol dm-3 min-1]

RX1501 = 92.1
㧔㧝㧢㧕ࡀࡊ࠷࠾࠙ࡓ(VI)ߩࡅ࠼࡜ࠫࡦߦࠃࠆㆶర෻ᔕ 39)
2 NpO22+ + 2 N2H5+ ĺ 2 NpO2+ + 2 H+ + N2 + 2 NH4+dxNP 6dt

 RX 1601 

xNP 6 xHYD
x1H.3

(5.31)[mol dm-3 min-1](5.32)

RX1601 = 8.3
㧔㧝㧣㧕ࡀࡊ࠷࠾࠙ࡓ(IV)ߩࡊ࡞࠻࠾࠙ࡓ(IV)ߦࠃࠆ㉄ൻ෻ᔕ 40)
Pu4+ + Np4+ + 2H2O ĺ Pu3+ + NpO2+ + 4H+

dxNP 4dt

 RX 1701 (5.33)

xNP 4 xPU 4
xH4[mol dm-3 min-1](5.34)

RX 1701 = 70.0㧔㧝㧤㧕ࡀࡊ࠷࠾࠙ࡓ(VI)ߩࡊ࡞࠻࠾࠙ࡓ(III)ߦࠃࠆㆶర෻ᔕ 41)
Pu3+ + NpO22+ ĺ Pu4+ + NpO2+

dxNP 6dt

 xPU 3 xNP 6 ( RX 1801 (5.35)

RX 1802)xH[mol dm-3 min-1](5.36)

RX1801 = 2130.0
RX1802 = 186.0㧔㧝㧥㧕ࡀࡊ࠷࠾࠙ࡓ(V)ߩࡊ࡞࠻࠾࠙ࡓ(III)ߦࠃࠆㆶర෻ᔕ 29) 33) 34) 42)
Pu3+ + NpO2+ + 4H+ ĺ Pu4+ + Np4+ + 2H2O

(5.37)

35

dxNP 5dt

 RX 1901 

xPU 3 xNP 5
x1H.3[mol dm-3 min-1](5.38)

RX1901 = 5.98×10-2
㧔㧞㧜㧕ࡀࡊ࠷࠾࠙ࡓߩਇဋൻ෻ᔕ
Ԙࡀࡊ࠷࠾࠙ࡓ(VI)෸߮ࡀࡊ࠷࠾࠙ࡓ(IV)ߩ↢ᚑ 40)
2 NpO2+ + 4H+ ĺ NpO22+ + Np4+ + 2 H2O

dxNP 5dt(5.39)

2
 RX 2001  xH2  xNP
5[mol dm-3 min-1](5.40)

RX2001 = 1.6×10-3
ԙࡀࡊ࠷࠾࠙ࡓ(V)ߩ↢ᚑ 33) 34) 43) 44) 45)
NpO22+ + Np4+ + 2 H2O ĺ 2 NpO2+ + 4H+

dxNP 4dt(5.41)

 RX 2002  xNP 4  xNP 6 ( RX 2003  RX 2004  C N )[mol dm-3 min-1](5.42-a)

RX2002=2.5
RX2003=2.16
RX2004=12.5
CN = xH + 2 xU6 + 4 xPU4 + 3 xPU3 + 4 xU4 + xHAN + xHYD + 4 xNP4 + xNP5 +2 xNP6

(5.42-b)㧔㧞㧝㧕ࡀࡊ࠷࠾࠙ࡓ(VI)ߩ iso-ࡉ࠴࡞ࠕ࡞࠺ࡅ࠼ߦࠃࠆㆶర෻ᔕ 46)
NpO22+ + iso-C3H7CHO + H2O ĺ NpO2+ + iso-C3H7COOH + H+

dxNP 6dt

 RX 2101  exp( RX 2102 / T )  xNP 6  xIBAL  xH

(5.43)[mol dm-3 min-1](5.44)

RX2101 = 6.0×106
RX2102 = 4.1×103
㧔㧞㧞㧕ࡀࡊ࠷࠾࠙ࡓ(VI)ߩ n-ࡉ࠴࡞ࠕ࡞࠺ࡅ࠼ߦࠃࠆㆶర෻ᔕ 46)
NpO22+ + n-C3H7CHO + H2O ĺ NpO2+ + n-C3H7COOH + H+

dxNP 6dt

 RX 2201  exp( RX 2202 / T )  xNP 6  xNBAL  xH

RX2201 = 4.2×104
RX2202 = 3.4×103

36(5.45)[mol dm-3 min-1](5.46)

㧔㧞㧟㧕ࡊ࡞࠻࠾࠙ࡓ(IV)ߩ iso-ࡉ࠴࡞ࠕ࡞࠺ࡅ࠼ߦࠃࠆㆶర෻ᔕ 47)
Pu4+ + iso-C3H7CHO + H2O ĺ Pu3+ + iso-C3H7COOH + H+

dxPU 4dt(5.47)[mol dm-3 min-1]

 RX 2301  xPU 4  xIBAL  xH

(5.48)

RX2301 = 3.8
㧔㧞㧠㧕ࡃ࠽ࠫ࠙ࡓ(V)ߦࠃࠆࡀࡊ࠷࠾࠙ࡓ(V)ߩ㉄ൻ෻ᔕ 48)
NpO2+ + VO2+ + 2H+ ĺ NpO22+ + VO2+ + H2O

dxNP 5dt

 RX 2401  exp((5.49)RX 2402)  xH2  xV 5  xNP 5
RT[mol dm-3 min-1](5.50)

RX2401 = 1.5884×109
RX2402 = 4.6492×104
㧔㧞㧡㧕TBP ߩൻቇഠൻ෻ᔕ 49)
DBP ĺ MBP ĺ H3PO4(5.51)

dxDBP
dtk2  xDBP

[mol dm-3 min-1](5.52)

dxMBP
dt

k2  xDBP  k3  xMBP

[mol dm-3 min-1](5.53)

dxPO 4dt

k3  xMBP[mol dm-3 min-1](5.54)

k2 = F2 (xH)
F2 (xH) :(5.55-a)એਅߩ㧟ὐ㧔xH=0.5, 3.0, 6.0㧕ߢߩ෻ᔕㅦᐲࠍ✢ဳౝᝌߔࠆ‫ޕ‬F2 (0.5) 3.08 u 1013  exp(1.344 u 104) / 60.0 [min-1]
T(5.55-b)

F2 (3.0) 3.67 u 1013  exp(1.299 u 104) / 60.0 [min-1]
T(5.55-c)

1.083 u 104) / 60.0 [min-1]
T(5.55-d)F2 (6.0) 1.64 u 1011  exp(k3 = F3 (xH)
F3 (xH) :(5.56-a)એਅߩ㧟ὐ㧔xH=0.5, 3.0, 6.0㧕ߢߩ෻ᔕㅦᐲࠍ✢ဳౝᝌߔࠆ‫ޕ‬F3 (0.5) 8.21 u 1011  exp(1.244 u 104) / 60.0 [min-1]
T(5.56-b)

F3 (3.0) 1.28 u 1012  exp(1.213 u 104) / 60.0 [min-1]
T(5.56-c)37

1.098 u 104
7.87 u 10  exp() / 60.0 [min-1]
T10

F3 (6.0)(5.56-d)㧔㧞㧢㧕⎣㉄ߩ᡼኿✢ಽ⸃዁᧪⊛ߥ᜛ᒛࠍ⠨ᘦߒߚ߽ߩߢ‫ߢ⁁⃻ޔ‬෻ᔕㅦᐲߪ 0 ߦ࿕ቯߒߡ޿ࠆ‫ޕ‬dx NO 2dt

0[mol dm-3 min-1](5.57)

dx H 2O 2dt

0[mol dm-3 min-1](5.58)

㧔㧞㧣㧕੝⎣㉄ߩ᳇⋧߳ߩಽ⸃዁᧪⊛ߥ᜛ᒛࠍ⠨ᘦߒߚ߽ߩߢ‫ߢ⁁⃻ޔ‬෻ᔕㅦᐲߪ 0 ߦ࿕ቯߒߡ޿ࠆ‫ޕ‬dx NO 2dt

[mol dm-3 min-1]

0(5.59)

㧡㧚㧞 ᦭ᯏ⋧ߦ㑐ߔࠆൻቇ෻ᔕㅦᐲᑼ
᦭ᯏ⋧ਛߩൻቇ෻ᔕᑼߪએਅߩߣ߅ࠅߢ޽ࠆ‫ޕ‬RY ߢᆎ߹ࠆቯᢙߪ‫ߡߒߣ࠲࡯࠺࠼࡯ࡢ࡯ࠠޔ‬ቯ⟵ߐࠇߡ߅ࠅ‫߇ࠩ࡯࡙ޔ‬૞ᚑߔࠆ౉ജࡈࠔࠗ࡞ߦ߅޿ߡછᗧߦᄌᦝ߇น⢻ߢ޽ࠆ㧔8.2 ▵ෳᾖ㧕‫ޕ‬㧔㧝㧕ࡊ࡞࠻࠾࠙ࡓ(IV)ߩ࠙࡜ࡦ(IV)ߦࠃࠆㆶర෻ᔕ 13) 20)
U4+ + 2 Pu4+ + 2 H2O ĺ UO22+ + 2 Pu3+ + 4 H+

dy PU 4dt

 RY 0101 (5.60)yU 4 y PU 4y H2[mol dm-3 min-1](5.61)

RY0101 = 6.5
㧔㧞㧕ࡊ࡞࠻࠾࠙ࡓ(III)ߩౣ㉄ൻ෻ᔕ 13) 20)
2 Pu3+ + 3 H+ + NO3- ĺ 2 Pu4+ + HNO2 + H2O

dy PU 3dt

(5.62)

 RY 0201  y PU 3  y NO 2  y H3.1

[mol dm-3 min-1]

RY0201 = 1.5×10-1

38(5.63)

㧔㧟㧕࠙࡜ࡦ(IV)ߩ੝⎣㉄ߦࠃࠆ㉄ൻ෻ᔕ 13) 22)U4+ + NO3- + H2O ĺ UO22+ + H+ + HNO2(i)

(5.64)yH ҇ 0.34 ߩߣ߈

dyU 4
dt

0.49
 RY 0301  yU 4  y NO
2[mol dm-3 min-1](5.65-a)[mol dm-3 min-1](5.65-b)

RY0301 = 1.6×10-2 ,(ii) 0.34 < yH ߩߣ߈

dyU 4
dt

0.49
 RY 0302  yU 4  y H0.63  y NO
2

RY0302 = 4.0×10-2
㧔㧠㧕࠙࡜ࡦ(IV)ߩⓨ᳇ߦࠃࠆ㉄ൻ෻ᔕ 13) 23)
2 U4+ + O2 + H2O ĺ 2 UO22+ + 4 H+

dyU 4
dt

 RY 0401 (5.66)

yU 4
yH0.86[mol dm-3 min-1](5.67)

RY0401 = 3.2×10-3
㧔㧡㧕TBP ߩൻቇഠൻ෻ᔕ 49)
TBP ĺ DBP ĺ MBP ĺ H3PO4(5.68)

dy DBPdt

k1  T0  k 2  y DBP[mol dm-3 min-1](5.69)

dyMBP
dt

k2  yDBP  k3  yMBP

[mol dm-3 min-1](5.70)

dyPO 4dt

k3  yMBP[mol dm-3 min-1](5.71)

T0 㧦 TBP Ớᐲ
k1 = F1 (yH) / e(5.72-a)F1 (yH) 㧦 એਅߩ㧟ὐ㧔xH=0.5, 3.0, 6.0㧕ߢߩ෻ᔕㅦᐲࠍ✢ဳౝᝌߔࠆ‫ޕ‬

5.69 u1012  exp(1.244 u104
) / 60.0 [min-1]
T(5.72-b)

F1 (3.0) 7.05 u 1013  exp(1.289 u 10 4
) / 60.0 [min-1]
T(5.72-c)

1.042 u 10 4
) / 60.0 [min-1]
T(5.72-d)F1 (0.5)

F1 (6.0) 1.11u 1011  exp(e = 2.71839

k2 = F2 (yH) / e(5.73-a)F2 (yH) 㧦 એਅߩ㧟ὐ㧔xH=0.5, 3.0, 6.0㧕ߢߩ෻ᔕㅦᐲࠍ✢ဳౝᝌߔࠆ‫ޕ‬F2 (0.5) 3.08 u 1013  exp(1.344 u 10 4
) / 60.0 [min-1]
T(5.73-b)

F2 (3.0) 3.67 u 1013  exp(1.299 u 10 4
) / 60.0 [min-1]
T(5.73-c)

F2 (6.0) 1.64 u 1011  exp(1.083 u 104) / 60.0 [min-1]
T(5.73-d)k3 = F3 (yH) / e(5.74-a)F3 (yH) 㧦 એਅߩ㧟ὐ㧔xH=0.5, 3.0, 6.0㧕ߢߩ෻ᔕㅦᐲࠍ✢ဳౝᝌߔࠆ‫ޕ‬F3 (0.5) 8.21u1011  exp(1.244 u10 4) / 60.0 [min-1]
T(5.74-b)

F3 (3.0) 1.28 u1012  exp(1.213 u10 4) / 60.0 [min-1]
T(5.74-c)

1.098 u10 4) / 60.0 [min-1]
T(5.74-d)F3 (6.0) 7.87 u1010  exp(40㧢 ಽ㈩Ყ
PARC ߦ⚵ߺㄟ߹ࠇߡ޿ࠆฦൻቇ⒳ߩಽ㈩Ყߩ▚಴ᑼߪએਅߩߣ߅ࠅߢ޽ࠆ‫ޕ‬D ߢᆎ߹ࠆቯᢙ
㧔DH01, DH02, DU601 ╬㧕ߪ‫ߡߒߣ࠲࡯࠺࠼࡯ࡢ࡯ࠠޔ‬ቯ⟵ߐࠇߡ߅ࠅ‫࠲࡝ࡊ࠲ࡦࠗޔ‬ᯏ⢻ࠍ೑↪ߔࠆߎߣߢછᗧߦᄌᦝ߇น⢻ߢ޽ࠆ㧔8.2 ▵ෳᾖ㧕‫ޔߚ߹ޕ‬ේሶജᯏ᭴߇߹ߣ߼ߚ‫ޟ‬ౣಣℂࡊࡠ࠮ࠬ࡮ൻቇࡂࡦ࠼ࡉ࠶ࠢ‫ޠ‬19) ߇ෳ⠨ߣߥࠆ‫ޕ‬㧔㧝㧕᳓⚛ࠗࠝࡦߩಽ㈩Ყ
Richardson ߦࠃࠆࡕ࠺࡞ࠍෳ⠨ߣߒߡ޿ࠆ 2) 13) 50)‫ޕ‬DH

K1, H  T f  K 2, H  T f2

(6.1-a)

K1, H

0.82
3.44
 DH 04  F( DH 01  xNO)  e DH 05W
3  DH 02  x NO 3 )  (1  DH 03  e(6.1-b)K 2, H

K1, H(6.1-c)

W

1
1
 

T 298

T :

ṁᶧ᷷ᐲ

[K]

F:

᦭ᯏ⋧ਛߩ TBP ࡈ࡜࡚ࠢࠪࡦ

[-]

Tf :

ࡈ࡝࡯TBP Ớᐲ[mol/L]xNO 3

xH  2 xU 6  4 xPU 4  3 xPU 3  4 xU 4  4 xNP 4  xNP 5  2 xNP 6

DH01 = 0.135

DH02 = 0.0052

DH03 = 0.54

DH04 = 15(6.1-d)DH05 = 340㧔㧞㧕࠙࡜ࡦ(VI)ߩಽ㈩Ყ
Richardson ߦࠃࠆࡕ࠺࡞ࠍෳ⠨ߣߒߡ޿ࠆ 2) 13) 50)‫ޕ‬

DU 6

K 2,U 6

K 2,U 6  T f2

(6.2-a)

.57
3.9
7.3
( DU 601  x1NO
3  DU 602  x NO 3  DU 603  x NO 3 ) ( DU 604  F  0.17  DU 605)  e DU 606W
DU601 = 3.7

DU602 = 1.4

DU603 = 0.011

DU604 = 4

DU 605 = 3

DU 606 = 2500

41

(6.2-b)㧔㧟㧕ࡊ࡞࠻࠾࠙ࡓ(IV)ߩಽ㈩Ყ
Richardson ߦࠃࠆࡕ࠺࡞ࠍෳ⠨ߣߒߡ޿ࠆ 2) 13) 50)‫ޕ‬

DPU 4

K 2, PU 4

K 2, PU 4  T f2

(6.3-a)

.57
3.9
7.3
( DPU 401  x1NO
3  DPU 402  x NO 3  DPU 403  x NO 3 ) ( DPU 404  F  0.17  DPU 405)
 ( DPU 406  DPU 407  F

1.25(6.3-b) DPU 408  x

2
NO 3

)e

DPU401 = 3.7

DPU402 = 1.4

DPU 403 = 0.011

DPU 404 = 4

DPU 405 = 3

DPU 406 = 0.2

DPU 407 = 0.55

DPU 408 = 0.0074

 DPU 409 W

DPU 409 = 200㧔㧠㧕ࡊ࡞࠻࠾࠙ࡓ(III)ߩಽ㈩Ყ
Richardson ߦࠃࠆࡕ࠺࡞ࠍෳ⠨ߣߒߡ޿ࠆ 2) 13) 50)‫ޕ‬

DPU 3
K 2, PU 3

K 2, PU 3  T f2

(6.4-a).8
7
DPU 301  x1NO
3  DPU 302  F  x NO 3 ,(6.4-b)

DPU301 = 0.04
DPU302 = 0.000156
㧔㧡㧕࠙࡜ࡦ(IV)ߩಽ㈩Ყ
Revised-MIXSET ߩࡕ࠺࡞ࠍෳ⠨ߣߒߡ޿ࠆ 13) 23)‫ޕ‬

DU 4

K 2,U 4  T f2

(6.5-a)K 2,U 4e  DU 401 DU 402 x NO 3

(6.5-b)DU401 = 3.336
DU402 = 1.9331

42㧔㧢㧕੝⎣㉄ߩಽ㈩Ყ
ቲᓼࠄߦࠃࠆ⹜㛎࠺࡯࠲ 51) ߆ࠄዉ಴ߒߚ‫ޕ‬

DNO 2

K1, NO 2  T f(6.6-a)K1, NO 2

DN 0201  xH0.280  DN 0202  xH0.543(6.6-b)

DN0201 = 24.8
DN0202 = 3.209
㧔㧣㧕ࠫ࡞ࠦ࠾࠙ࡓߩಽ㈩Ყ
Alcock ߩ࠺࡯࠲╬ 52) 53) ߆ࠄዉ಴ߒߚ‫ޕ‬

DZR

K 2, ZR  T f2

(6.7-a)K 2, ZR

exp( DZR01  DZR02  xNO 3 )(6.7-b)

DZR01 = 5.19
DZR02 = 1.85
㧔㧤㧕࠹ࠢࡀ࠴࠙ࡓߩಽ㈩Ყ
Kolarik ߦࠃࠆࡕ࠺࡞ 54) ࠍෳ⠨ߣߒߚ‫ޕ‬DTC

DTC ,0  DTC ,U  DTC , PU  DTC , ZR

(6.8-a)DTC , 0

KTC  T ,(6.8-b)

KTC

N1
N2

(6.8-c)N1

DTC 03 exp( DTC 04W )DTC 01  exp( DTC 02  W )  xNO
3

N2

DTC 07  exp( DTC 08W )1  DTC 05  exp( DTC 06  W )  xNO
3
DTC 11 exp( DTC 12 W )
 DTC 09  exp( DTC10  W )  xNO
3

T

DTC13  exp( DTC14  W )  T fDTC15EXP ( DTC16W )43(6.8-d)(6.8-e)(6.8-f)

DTC ,UyU2 6
 DTC17  exp( DTC18  W )yU 6  yPU 4
 (1  DTC19  exp( DTC 20  W )  x

1.343NO 3(6.8-g))

DTC , PU2
yPU
 0.7074
 DTC 21  exp( DTC 22  W )  xNO
3
yU 6  yPU 4(6.8-h)DTC , ZR

0.707
DTC 23  exp( DTC 24  W )  yZR  xNO
3(6.8-i)

DTC01 = 2.324

DTC02 = 8070

DTC03 = 0.848

DTC04 = 230

DTC05 = 0.157

DTC06 = 3240

DTC07 = 4.69

DTC08 = 410

DTC09 = 1.72

DTC10 = 3150

DTC11 = 1.95

DTC12 = 160

DTC13 = 0.845

DTC14 = 350

DTC15 = 1.92

DTC16 = 3300

DTC17 = 0.331

DTC18 = 1060

DTC19 = 4.87

DTC20 = 980

DTC21 = 5.0×6.62

DTC22 = 1060

DTC23 = 1670

DTC24 = 2810

㧔㧥㧕ࡀࡊ࠷࠾࠙ࡓ(IV)ߩಽ㈩Ყ
Petrich ߦࠃࠆಽ㈩࠺࡯࠲㓸 55) ࠃࠅዉ಴ߒߚ‫ޕ‬࡙࡯ࠩ౉ജߦࠃࠅ‫ޔ‬એਅߩԘ෶ߪԙߩ޿ߕࠇ߆ࠍㆬᛯน⢻ߣߥߞߡ޿ࠆ‫ޕ‬Np(VI)ߩಽ㈩Ყ⸘
▚ᑼߩㆬᛯߣㅪേߒߡ޿ࠆߎߣߦᵈᗧ㧔8.4.2.1 ▵(28)‫ޔ‬8.3.5 ▵ෳᾖ㧕‫ޕ‬Ԙ ࡈ࡝࡯TBP Ớᐲߩ㧟ਸ਼ߦᲧ଀ߔࠆᑼ

DNP 4
K 3, NP 4

K 3, NP 4  T f3

(6.9-a)0.867
DNP 401  exp( DNP 402  xNO 3 )  xNO
3(6.9-b)

DNP401 = 0.132
DNP402 = 1.87
ԙ ࡈ࡝࡯TBP Ớᐲߩ㧞ਸ਼ߦᲧ଀ߔࠆᑼ

DNP 4

K 2, NP 4  T f2

K 2, NP 4

10 DNP 403 DNP 404 x NO 3  DNP 405 x NO 3

(6.10-a)2(6.10-b)

44

DNP403 = 1.176724
DNP404 = 1.055994
DNP405 = 0.04123843
㧔㧝㧜㧕ࡀࡊ࠷࠾࠙ࡓ(V)ߩಽ㈩Ყ
Advanced-MIXSET 36) ߩࡕ࠺࡞ࠍෳ⠨ߣߒߚ‫ޕ‬

DNP 5
K1, NP 5

K1, NP 5  T f(6.11-a).41
DNP501  x1NO3

(6.11-b)

DNP501 = 0.0234
㧔㧝㧝㧕ࡀࡊ࠷࠾࠙ࡓ(VI)ߩಽ㈩Ყ
Petrich ߦࠃࠆಽ㈩࠺࡯࠲㓸 55) ࠃࠅዉ಴ߒߚ‫ޕ‬࡙࡯ࠩ౉ജߦࠃࠅ‫ޔ‬એਅߩ㧞⒳㘃ߩ߁ߜ޿ߕࠇ߆ࠍㆬᛯน⢻ߣߥߞߡ޿ࠆ‫ޕ‬Np(VI)ߩಽ㈩Ყ
⸘▚ᑼߩㆬᛯߣㅪേߒߡ޿ࠆߎߣߦᵈᗧ㧔8.4.2.1 ▵(28)ෳᾖ㧕‫ޕ‬Ԙ ࡈ࡝࡯TBP Ớᐲߩ 3 ਸ਼ߦᲧ଀ߔࠆᑼ

DNP 6
K 3, NP 6

K 3, NP 6  T f3

(6.12-a)

0.834
DNP 601  exp( DNP 602  xNO 3 )  xNO
3(6.12-b)

DNP601 = 2.10
DNP602 = 1.56
ԙ ࡈ࡝࡯TBP Ớᐲߩ 2 ਸ਼ߦᲧ଀ߔࠆᑼ

DNP 6

K 2, NP 6  T f2

K 2, NP 6

10 DNP 603 DNP 604 x NO 3  DNP 605 x NO 3

(6.13-a)2(6.13-b)

DNP603 = 0.01279311
DNP604 = 0.844549
DNP605 = 0.03396187

45㧔㧝㧞㧕ࠕࠫൻ᳓⚛ߩಽ㈩Ყ
Kelmers ࠄߦࠃࠆ࠺࡯࠲ 19) 56) ࠍෳ⠨ߦߒߚ‫ޕ‬

DHN 3

K1, HN 3  T f(6.14-a)

K1, HN 3

DHN 301(6.14-b)

DHN301 = 9㧔㧝㧟㧕iso-ࡉ࠴࡞ࠕ࡞࠺ࡅ࠼ߩಽ㈩Ყ
ౝጊߦࠃࠆࡕ࠺࡞ 57) ࠍෳ⠨ߦߒߚ‫ޕ‬

DIBAL
K 0, IBAL

K 0,IBAL(6.15-a)4
3
2
DIBAL01  xNO
3  DIBAL02  x NO 3  DIBAL  x NO 3

 DIBAL04  xNO 3  DIBAL05
DIBAL01 = 0.00175

DIBAL02 = 0.04555

DIBAL03 = 0.4214

DIBAL04 = 1.799(6.15-b)

DIBAL05 = 4.892
㧔㧝㧠㧕n-ࡉ࠴࡞ࠕ࡞࠺ࡅ࠼ߩಽ㈩Ყ
ౝጊߦࠃࠆࡕ࠺࡞ 57) ࠍෳ⠨ߦߒߚ‫ޕ‬

DNBAL
K 0, NBAL

K 0, NBAL(6.16-a)4
3
2
DNBAL01  xNO
3  DNBAL 02  x NO 3  DNBAL 03  x NO 3

 DNBAL04  xNO 3  DNBAL05
DNBAL01 = 0.00175

DNBAL02 = 0.04555

DNBAL03 = 0.4214

DNBAL04 = 1.799(6.16-b)

DNBAL05 = 4.892
㧔㧝㧡㧕iso-㈼㉄ߩಽ㈩Ყ

DIBAC

K1, IBAC  T f(6.17-a)46

K1, IBAC

DIBAC 01

(6.17-b)

DIBAC01 = 0.001
㧔㧝㧢㧕n-㈼㉄ߩಽ㈩Ყ

DNBAC

K1, NBAC  T f(6.18-a)

K1, NBACDNBAC 01

(6.18-b)

DNBAC01 = 0.001
㧔㧝㧣㧕࡛࠙⚛ߩಽ㈩Ყ
ේሶജᯏ᭴ NUCEF ߦ߅ߌࠆ᛽಴ಽ㔌⹜㛎⚿ᨐࠃࠅዉ಴ߒߚ‫ޕ‬DI

K 0, I(6.19-a)

K 0, I

exp( DI 01  xNO 3  DI 02)(6.19-b)

DI01 = 0.1336
DI02 = 0.1208
㧔㧝㧤㧕࠮ࠪ࠙ࡓߩಽ㈩Ყ
ේሶജᯏ᭴ NUCEF ߦ߅ߌࠆ᛽಴ಽ㔌⹜㛎⚿ᨐࠃࠅዉ಴ߒߚ‫ޕ‬DCS

K 2,CS  T f2

(6.20-a)

K 2,CSexp( DCS 01  xNO 3  DCS 02)(6.20-b)

DCS01 = 0.514
DCS02 = 0.504㧔㧝㧥㧕࡞࠹࠾࠙ࡓ(III)ߩಽ㈩Ყ
ේሶജᯏ᭴ NUCEF ߦ߅ߌࠆ᛽಴ಽ㔌⹜㛎⚿ᨐࠃࠅዉ಴ߒߚ‫ޕ‬

DRU 3

K 2, RU 3  T f2

(6.21-a)47

K 2, RU 3

2
exp( DRU 301  xNO
3  DRU 302  x NO 3  DRU 303)

(6.21-b)

DRU301 = 0.133
DRU 302 = 0.414
DRU 303 = 0.228㧔㧞㧜㧕ࡊ࡞࠻࠾࠙ࡓ(VI)ߩಽ㈩Ყ
A.Kumar ߩ࠺࡯࠲ 58) ߆ࠄዉ಴ߒߚ‫ޕ‬

DPU 6
K 2, PU 6

K 2, PU 6  T f2

(6.22-a)2exp( DPU 601  xNO
3  DPU 602  x NO 3  DPU 603)

(6.22-b)

DPU601 = 0.918
DPU 602 = 0.194
DPU 603 = 0.462㧔㧞㧝㧕ࡃ࠽ࠫ࠙ࡓ(IV)ߩಽ㈩Ყ

DV 4

K 0,V 4

(6.23-a)

K 0,V 4

DV 401(6.23-b)

DV401 = 0.0001
㧔㧞㧞㧕ࡃ࠽ࠫ࠙ࡓ(V)ߩಽ㈩Ყ

DV 5

K 0,V 5

(6.24-a)

K 0,V 5

DV 501(6.24-b)

DV501 = 0.0001
㧔㧞㧟㧕࡝ࡦ㉄ࠫࡉ࠴࡞㧔DBP㧕ߩಽ㈩Ყ
Hardy ߩࡕ࠺࡞ 59)ࠍෳ⠨ߦߒߚ‫ޕ‬48

D DBP (­K
D½)  ®1  2 K 2  ( d )  xDBP  KTBP  T f ¾
M ¯
M
¿

Kd

ĳ = 1+ Ka / xH

(6.25-a)(6.25-b)

K2 = 6.03×105
Kd = 0.0110
Ka = 0.1
Į = 1.31
KTBP = 2130
㧔㧞㧠㧕࡝ࡦ㉄ࡕࡁࡉ࠴࡞㧔MBP㧕ߩಽ㈩Ყ
Hardy ߩࡕ࠺࡞ 59)ࠍෳ⠨ߦߒߚ‫ޕ‬DMBPa  yDDBP  b  T f

E(6.26)

a = 0.120
Į = 1.25
b = 0.377
ȕ = 1.83㧔㧞㧡㧕࡝ࡦ㉄ߩಽ㈩Ყ
DPO4 = 1.0(6.27)

㧔㧞㧢㧕ᩭಽⵚ↢ᚑ‛㧔FP㧕ߩಽ㈩Ყ
DFP = 10 -3(6.28)

㧔㧞㧣㧕ㆊ㉄ൻ᳓⚛ߩಽ㈩Ყ
DH2O2 = 10 -3(6.29)

49㧣 㧼㧭㧾㧯ߩേ૞ⅣႺߣታⴕᣇᴺ
PARC ߪ Microsoft Windows㧔ࠦࡑࡦ࠼ࡊࡠࡦࡊ࠻㧕, UNIX, Linux ╬‫ޔ‬C ࡊࡠࠣ࡜ࡓ߇േ૞น⢻ߥ⸘▚ᯏⅣႺߢേ૞ߔࠆ‫ޕ‬એਅߦታⴕ଀ࠍ⚫੺ߔࠆ‫ޕ‬Windows ߩ႐ว‫↢ࠇߐ࡞ࠗࡄࡦࠦޔ‬ᚑߐࠇߚታⴕᒻᑼࡈࠔࠗ࡞ฬࠍ PARC.exe ‫౉ߚ߹ޔ‬ജࡈࠔࠗ࡞ࠍ example1.inp ߣߒߚ႐ว‫ޔ‬PARC ࠍታⴕߔࠆߦߪࠦࡑࡦ࠼ࡊࡠࡦࡊ࠻ߦ߅޿ߡᰴߩࠦࡑࡦ
࠼࡜ࠗࡦࠍ౉ജߔࠇ߫ࠃ޿‫ߢߎߎޕ‬ታⴕᒻᑼࡈࠔࠗ࡞ฬ෸߮౉ജࡈࠔࠗ࡞ฬߪ‫ޔ‬ᔅⷐߦᔕߓࡈ࡞
ࡄࠬߢᜰቯߒߡ߽⦟޿‫ޕ޿⦟߽ߡ޿↪ࠍ࡞ࠗࠔࡈ࠴࠶ࡃߚ߹ޕ‬  2#4%GZGGZCORNGKPR GPVGT ⸘▚ߦⷐߔࠆᤨ㑆ߪ‫ޔ‬CPU ᕈ⢻╬ߩ⸘▚ᯏⅣႺߩઁ‫ޔ‬ਥߦ࠲ࠗࡓࠬ࠹࠶ࡊߩ⸳ቯ㧔⚦߆ߐ㧕߿ㆬᛯൻቇ⒳ߩ୘ᢙߦࠃߞߡᓇ㗀ࠍฃߌࠆ‫ޕ‬ ⸘▚ߩታⴕㅜਛ෸߮⚳ੌᓟߦ޿ߊߟ߆ߩࡈࠔࠗ࡞߇⥄േ⊛ߦ↢ᚑߐࠇࠆ‫ޕ‬࿑ 7.1 ߦ౉಴ജࡈࠔ
ࠗ࡞ߩ᭎ⷐࠍ␜ߔ‫ޕ‬PARC ߦࠃߞߡ↢ᚑߐࠇࠆࡈࠔࠗ࡞ߪోߡ࠹ࠠࠬ࠻ᒻᑼߢ޽ࠆ‫ࠨ࡞ࠗࠔࡈޕ‬ࠗ࠭ߪ‫ޔ‬᛽಴ེߩ୘ᢙ㧔ncomp㧕‫ޔ‬Ბᢙ㧔MSH㧕‫ޔ‬ൻቇ⒳ᢙ㧔nspe㧕‫ޔ‬಴ജ࿁ᢙ㧔nRFile㧕ߦࠃߞߡᄌൻߔࠆ‫ޕ‬ታⴕ߇ᱜᏱߦ⚳ੌߒߚ႐วߦߪ‫ޔ‬ᮡḰ಴ജ෸߮ࠛ࡜࡯಴ജߦ  

0QTOCN'PFߣ಴ജߐࠇࠆ‫ޕ‬50౉ജ䊐䉜䉟䊦
example1.inp

ᮡḰ಴ജ

౉ജ
PARCታⴕᒻᑼ
(PARC.exe)಴ജexample1.out

example1.trn

ਥⷐ಴ജ䊐䉜䉟䊦

⚻ᤨ಴ജ䊐䉜䉟䊦TRNLBLᜰቯ䈮ᓥ䈦䈩↢ᚑ䈘䉏䉎䇯
䋨8.4.2.1▵(24) ෳᾖ䋩

example1T1001.rst

example1T1002.rst

example1T1003.rst

䊥䉴䉺䊷䊃಴ജ䊐䉜䉟䊦
RTIMEᜰቯ䈮ᓥ䈦䈩↢ᚑ䈘䉏䉎䇯
䋨8.4.2.1▵(15),(22) ෳᾖ䋩
nRFile୘䈱䊐䉜䉟䊦䈏↢ᚑ䈜䉎䇯䈢䈣䈚ᜰቯᤨೞ䈫DtMax䈮䉋䉎䉺䉟䊛䊜䉾䉲䊠ᜰቯ䈮䉋䈦䈩಴ജ䈏䉴䉨䉾䊒䈘䉏䉎႐ว䈏䈅䉎䇯䊶䊶䊶
example1S2.rst

example1.err

example1.wkቯᏱ⸘▚䈱⚿ᨐ಴ജ䊐䉜䉟䊦
iTranᜰቯ䈪ቯᏱ⸘▚䈱ታⴕ䉕ᜰቯ䈚䈢႐ว䈮↢ᚑ䈜䉎
䋨8.4.2.1▵(14) ෳᾖ䋩䇯⸘▚ᤨ䈮⇣Ᏹ䈏⊒↢䈚䈢႐ว䈮䉣䊤䊷䊜䉾䉶䊷䉳╬䉕಴ജ䈜䉎䇯౉ജ䊐䉜䉟䊦䈱⺒䉂ㄟ䉂ᤨ䈮૞ᚑ䈘䉏䉎૞ᬺ↪䊐䉜䉟䊦

example1.wk2

example1.cnv

࿑㧣㧚㧝 PARC ߦଥࠆ౉಴ജࡈࠔࠗ࡞

51㧤 ౉ജࡈࠔࠗ࡞ߩᦠᑼ
㧤㧚㧝 ౉ജ࠺࡯࠲ߩో૕᭴ᚑ
㧤㧚㧝㧚㧝 ၮᧄ᭴ㅧPARC ߩ౉ജࡈࠔࠗ࡞ߪ‫࠻ࠬࠠ࠹ޔ‬ᒻᑼߩࡈࠔࠗ࡞ߢ޽ࠆ‫࡞ࠗࠔࡈޕ‬૞ᚑߦᒰߚߞߡߪ‫ޔ‬
Microsoft Windows ઃዻߩ‫ࡕࡔޟ‬Ꮽ‫ޕࠆ߈ߢ߇ߣߎࠆ޿↪ࠍ࠲ࠖ࠺ࠛ࠻ࠬࠠ࠹ߩ╬ޠ‬౉ജ࠺࡯࠲ߪ‫ߡోޔ‬ඨⷺߩ⧷ᢙሼ‫⸥ޔ‬ภߢ⸥ㅀߔࠆ㧔߭ࠄ߇ߥ߿ṽሼ╬ߩోⷺᢥሼߪ⹺⼂ߒߥ޿‫ޕ‬㧕߹ߚ․ߦᢿࠄߥ޿㒢ࠅ‫౉ޔ‬ജ࠺࡯࠲ߢߪࠕ࡞ࡈࠔࡌ࠶࠻ߩᄢᢥሼߣዊᢥሼࠍ඙೎ߔࠆ‫ޕ‬౉ജࡈࠔࠗ࡞ߦ⸥ㅀߔࠆ౉ജ࠺࡯࠲ߪ‫ޔ‬ᄢ߈ߊ㧞ߟߩ㗔ၞߦಽߌࠄࠇ‫౉ߡߞࠃߦ࠼࡯ࡢ࡯ࠠޔ‬ജౝኈࠍ⹺⼂ߔࠆ‫࠲࡯࠺࠼࡯ࡢ࡯ࠠޟ‬ㇱ‫࡞ࠗࠔࡈߣޠ‬ਛߩ૏⟎ߦࠃߞߡ౉ജౝኈࠍ⹺⼂ߔࠆ‫ޟ‬૏⟎࠺࡯࠲ㇱ‫ࠄ߆ޠ‬ᚑࠆ‫"ޔߪ࠲࡯࠺࠼࡯ࡢ࡯ࠠޕ‬begin1"෸߮"end1"ߢ࿐߹ࠇࠆㇱಽߦ౉ജߔࠆ߽ߩ
ߢ޽ࠅ‫ߚ߹ޔ‬૏⟎࠺࡯࠲ߪ‫"ޔ‬begin2"෸߮"end2"ߢ࿐߹ࠇࠆㇱಽߦ౉ജߔࠆ߽ߩߢ޽ࠆ㧔8.2 ▵એ㒠ෳᾖ㧕‫ ࠄࠇߎޕ‬2 ߟߩ㗔ၞߪ‫౉ޔ‬ജࡈࠔࠗ࡞ਛߢᰴߩࠃ߁ߦ㈩⟎ߐࠇࠆ‫ޕ‬߹ߚ‫ޔ‬૏⟎࠺࡯࠲ߩਛߦ‫"ޔ‬begin3"෸߮"end3"ߢ࿐߹ࠇࠆㇱಽ߇ሽ࿷ߔࠆ႐ว߇޽ࠆ㧔8.4.2.1 ▵(9)-(11)ෳᾖ㧕‫ޕ‬  DGIKP  ࠠ࡯ࡢ࡯࠼࠺࡯࠲

  GPF  DGIKP  ૏⟎࠺࡯࠲  

DGIKP

  

GPF

  GPF  DGIKP  ૏⟎࠺࡯࠲  

DGIKP

  

GPF

  GPF  DGIKP  ࠠ࡯ࡢ࡯࠼࠺࡯࠲

  GPFࠠ࡯ࡢ࡯࠼࠺࡯࠲ߪ‫ޔ‬㧔"begin1", "end1"ࠍ฽߼ߡ㧕1 ߟߩⴕߦⶄᢙߩ࠺࡯࠲ࠍਗߴߡᦠ޿ߡ߽ࠃ
޿‫ߪ࠲࡯࠺࠼࡯ࡢ࡯ࠠޔߚ߹ޕ‬㧔"begin1", "end1"ࠍ฽߼ߡ㧕ᔅߕߒ߽౉ജߔࠆᔅⷐߪߥ޿‫"ޕ‬begin2"
෸߮ "end2" ߪ‫౉ޔ‬ജ࠺࡯࠲ߦ฽߹ࠇࠆᔅⷐ߇޽ࠅ‫ޔ‬ฦ‫ޔޘ‬1 ⴕࠍභ᦭ߔࠆ‫ᦨߩ࠲࡯࠺ోޕ‬ᓟߦ

52ߪᔅߕ "." 㧔ඨⷺࡇ࡝ࠝ࠼㧕ࠍ⟎߆ߥߌࠇ߫ߥࠄߥ޿‫ޕ‬ ࿑ 8.1 ߦ᭴ᢥࠣ࡜ࡈࠍ␜ߔ‫ޕ‬౉ജ࠺࡯࠲ߢߪ‫ޔ‬0 ୘એ਄ߩ‫ޟ‬ⓨ⊕‫ ߪࠄࠇߎޕࠆࠇߐ⸵߽ⴕࠆߥࠄ߆ߺߩޠ‬PARC ߩࡊ࡝ࡊࡠ
࠮࠶ࠨߦࠃߞߡขࠅ㒰߆ࠇࠆ‫ޕ‬㧤㧚㧝㧚㧞 ࠦࡔࡦ࠻ߩ⸥ㅀᣇᴺ
PARC ౉ജ࠺࡯࠲ౝߩࠦࡔࡦ࠻ߪ‫ޔ‬C ⸒⺆߿ C++⸒⺆ߩࡊࡠࠣ࡜ࡓߦ߅ߌࠆࠦࡔࡦ࠻ߣ㘃ૃߒߡ޿ࠆ‫"ޕ‬/*" ߢᆎ߹ࠅ "*/" ߢ⚳ࠊࠆᢥሼ೉ߪࠦࡔࡦ࠻ߣߺߥߐࠇࠆ‫ߺ⺒ߪ࠻ࡦࡔࠦޕ‬㘧߫ߐࠇ‫ޔ‬
PARC ߩ⸘▚ߦߪᓇ㗀ࠍਈ߃ߥ޿‫࠻ࡦࡔࠦߩߎޕ‬ㇱಽߪ‫ޔ‬ⓨ⊕ 1 ᢥሼߦ⟎߈឵߃ࠄࠇߚ਄ߢ⺒ߺㄟ߹ࠇࠆ‫ⴕߪ࠻ࡦࡔࠦߩߎޕ‬ਛߩߤߎߦ޿ߊࠄ޽ߞߡ߽ࠃ޿‫ⶄ߇࠻ࡦࡔࠦߩߟߣ߭ޔߒߛߚޕ‬ᢙⴕߦ߹ߚ߇ࠆߎߣߪ⸵ߐࠇߥ޿‫࠻ࠬࡀߩ࠻ࡦࡔࠦߩߎޔߚ߹ޕ‬㧔ࠦࡔࡦ࠻ߩਛߦ "/*" ෸߮ "*/" ߢ࿐߹ࠇࠆㇱಽ߇౉ࠇሶ⁁ߦሽ࿷ߔࠆߎߣ㧕߽⸵ߐࠇߥ޿‫ޕ‬ ࿑ 8.2 ߦࠦࡔࡦ࠻ࠍ⹺⼂ߔࠆ᳿ቯᕈ᦭㒢ࠝ࡯࠻ࡑ࠻ࡦ(Determinstic Finite Automaton, DFA) 60) ࠍ␜ߔ‫ޕ‬⸵นߐࠇࠆࠦࡔࡦ࠻ߩ଀
  DGIKP   EQOOGPVKPRWVFCVCD[,#'#KP&GE   GPFⶄᢙⴕߦ߹ߚ߇ࠆࠦࡔࡦ࠻㧔⸵นߐࠇߥ޿଀㧕   EQOOGPV㧔ᡷⴕᢥሼ㧕   ࠦࡔࡦ࠻ߩࡀࠬ࠻㧔⸵นߐࠇߥ޿଀㧕   EQOOGPV EQOOGPV   ߹ߚ‫"ޔ‬/*" ෸߮ "/*" ߢ࿐߻ࠦࡔࡦ࠻ߩઁߦ‫"ޔ‬//" ߦࠃߞߡࠦࡔࡦ࠻ߩవ㗡ࠍ␜ߔߎߣ߽น⢻ߢ޽ࠆ‫ߩߎޕ‬႐ว‫"ޔ‬//"ࠃࠅⴕᧃ߹ߢ߇ࠦࡔࡦ࠻ߣ⷗ߥߐࠇࠆ‫ޕ‬53 ⸵นߐࠇࠆࠦࡔࡦ࠻ߩ଀
  DGIKP  EQOOGPVKPRWVFCVCD[,#'#KP&GE

  GPF㧤㧚㧞 ࠠ࡯ࡢ࡯࠼࠺࡯࠲
5 ┨ߦ␜ߒߚ෻ᔕㅦᐲᑼߩਛߢ RX xxxx‫ޔ‬RY xxxx ߥࠆฬ⒓ߢ␜ߒߚቯᢙ‫ ߚ߹ޔ‬6 ┨ߩಽ㈩Ყ⸘
▚ᑼߩਛߢ D xxxx ߥࠆฬ⒓ߢ␜ߒߚቯᢙฬߪ‫ޔ‬PARC ߩౝㇱߢࠠ࡯ࡢ࡯࠼ߣߒߡ⸳ቯߐࠇߡ޿ࠆ‫ޕ‬࡙࡯ࠩߪ‫ ࠍޠ࠲࡯࠺࠼࡯ࡢ࡯ࠠޟޔ‬PARC ߦ౉ജࡈࠔࠗ࡞ߦ⸥ㅀߔࠆߎߣߢ‫ޔ‬PARC ߦ⚵ߺㄟ߹ࠇߡ޿ࠆ෻ᔕㅦᐲᑼ߿ಽ㈩Ყ⸘▚ᑼࠍᄌᦝߔࠆߎߣ߇น⢻ߢ޽ࠆ‫ޕ‬"begin1"෸߮"end1"ߢ࿐߹ࠇߚ㗔ၞߦ‫ޔ‬એਅߩࠃ߁ߦቯᢙฬ㧔ࠠ࡯ࡢ࡯࠼㧕෸߮ᣂߚߥቯᢙࠍ⸥
ㅀߔࠆ‫ޕ‬
  DGIKP  ࠠ࡯ࡢ࡯࠼ቯᢙࠠ࡯ࡢ࡯࠼ቯᢙ  ࠠ࡯ࡢ࡯࠼ቯᢙ  㨯㨯㨯  ࠠ࡯ࡢ࡯࠼ቯᢙ  GPFࠠ࡯ࡢ࡯࠼ߢᜰቯߐࠇߚቯᢙ߳ߩᢙ୯ߩઍ౉ߦߪ "=" ࠍ↪޿ࠆ‫" ; "ߩߢߎߎޕ‬㧔࠮ࡒࠦࡠࡦ㧕ߩᗧ๧ߪ‫ = ࠼࡯ࡢ࡯ࠠ"ޔ‬ቯᢙ" ߣ޿߁‫ޟ‬ᢥ‫ⶄࠍޠ‬ᢙ⟎ߊ႐วߦ‫ࠍࠄࠇߘޔ‬඙ಾࠆߚ߼ߦ⟎ߊ߽ߩߢ޽ࠅ‫ޔ‬ᢥߩ⚳ੌࠍ␜ߔ߽ߩߢߪߥ޿‫ޕ‬ᓥߞߡ‫ᦨޔ‬ᓟߩᢥߣ"end1"ߩ㑆ߦߪ" ; "ߪ⟎߆ߥ޿㧔࿑
8.1㧕‫ ߪࠇߎޕ‬PASCAL ⸒⺆ߩᢥᴺߣห᭽ߢ޽ࠆ‫ޕ‬ቯᢙߩ⴫⸥ߦߟ޿ߡߪ 8.3.7 ▵ෳᾖ‫ޕ‬ ଀  DGIKP  4:4:  4;G  &*&*
  GPF  DGIKP  㧔૏⟎࠺࡯࠲㧕  GPF

54

㧤㧚㧟 ൻቇ෻ᔕߩ౉ജ
PARC ߢߪ‫ޔ‬ᣢߦ⚵ߺㄟ߹ࠇߚൻቇ෻ᔕࡕ࠺࡞ߦട߃‫౉ࠩ࡯࡙ޔ‬ജߦࠃߞߡᣂⷙߩൻቇ⒳‫ޔ‬ൻቇ෻ᔕᑼ‫ޔ‬෻ᔕㅦᐲᑼ‫ޔ‬ಽ㈩Ყ⸘▚ᑼࠍቯ⟵ߒߡ⸘▚ࠍታⴕߔࠆߎߣ߇น⢻ߢ޽ࠆ‫ޕ‬ᣂⷙߦㅊടߔࠆൻቇ⒳෸߮⸘▚ᑼߪ‫ޔ‬એਅߩᦠᑼߦᓥ޿‫౉ޔ‬ജࡈࠔࠗ࡞ߩ‫ޟ‬૏⟎࠺࡯࠲ㇱ‫ޠ‬㧔"begin2"෸߮"end2"ߢ࿐߹ࠇߚㇱಽ㧕ߦ⸥ㅀߔࠆ㧔8.4.2.1 ▵ෳᾖ㧕‫ޕ‬
PARC ߪ‫࠲࡝ࡊ࡯࠲ࡦࠗޔ‬ᯏ⢻ࠍ஻߃ߡ߅ࠅ‫౉ߩࠩ࡯࡙ޔ‬ജࠍ᭴ᢥ⸃ᨆߒ‫ޔߒ㉼⸃ޔ‬ᣢߦ⚵ߺㄟ߹ࠇߚ⸘▚ᑼߣ૬ߖߡ⸘▚ࠍታⴕߔࠆߎߣ߇น⢻ߢ޽ࠆ‫ޕ‬㧤㧚㧟㧚㧝 ࠗࡦ࠲࡯ࡊ࡝࠲ߩ౉ജ࠺࡯࠲ߩ᭴ㅧߣ⒳㘃
 ࠗࡦ࠲࡯ࡊ࡝࠲ߩ౉ജ࠺࡯࠲ߪᰴߩ㧟ߟߩㇱಽ߆ࠄᚑࠆ‫ޕ‬Ԙ ൻቇ෻ᔕᑼ 㧔ሽ࿷ߒߥ޿႐ว߽޽ࠆ㧕ԙ cond㧦᧦ઙߩ⸥ㅀㇱԚ case㧦⸘▚ᑼߩ⸥ㅀㇱ㧤㧚㧟㧚㧞 ൻቇᑼ෸߮Ớᐲߩ⸥ㅀᣇᴺ
㧔㧝㧕ൻቇᑼ
ൻቇ⒳ߩ⼂೎ߦߪൻቇᑼࠍ↪޿ࠆ‫ޕ‬ర⚛ߩ⼂೎ߦߪర⚛⸥ภࠍ↪޿ࠆ‫࠶ࡌࠔࡈ࡞ࠕߪߢߎߎޕ‬࠻ߩᄢᢥሼߣዊᢥሼࠍ඙೎ߔࠆ‫"ޔߪࡓ࠙࠾࠻࡞ࡊޔ߫߃଀ޕ‬PU" ߢߪߥߊ"Pu"ߣ⸥ㅀߔࠆ‫ޕ‬ൻቇ⒳ߩଔᢙߪ‫ޔ‬ዊ᜝ᒐ "()" ਗ߮ߦࡠ࡯ࡑᢙሼ㧔+‫ޔ‬++‫ޔ‬+++‫ޔ‬8+╬㧕ߢ⴫ߔ‫ⶄޕ‬ᢙߩේሶࠍ⴫ߔਅઃߩᢙሼߪ‫ࠕࡆ࡜ࠕޔ‬ᢙሼࠍ↪޿ߡ⴫ߔ‫ޕ‬PARC ߪ‫ޔ‬ᣣᧄ⺆ⅣႺߦ․᦭ߥోⷺᢥሼ߿
․ᱶᢥሼ㧔ΥΦ╬㧕ࠍ⹺⼂ߒߥ޿ߩߢ‫ޔ‬᜝ᒐ߿ࡠ࡯ࡑᢙሼߪඨⷺᢥሼߢ౉ജߔࠆ㧔⴫ 8.1㧕‫ޕ‬㧔㧞㧕Ớᐲ
ൻቇ⒳ߩỚᐲ㧔૕Ⓧࡕ࡞Ớᐲ [mol dm-3]㧕ߪ‫ޔ‬ᄢ᜝ᒐ "[]"ߢ࿐ࠎߢ⴫⸥ߔࠆ‫ޕ‬᳓⋧Ớᐲߣ᦭ᯏ⋧Ớᐲࠍ඙೎ߔࠆߚ߼ߦൻቇᑼߩ೨ߦ"x"෶ߪ"y"㧔ዊᢥሼ㧕ࠍઃߔ‫ޕ‬᳓⋧ߢߪ "[x ൻቇᑼ]"‫᦭ޔ‬ᯏ⋧ߢߪ "[y ൻቇᑼ]" ߣ⴫⸥ߔࠆ‫ޕ‬⸵นߐࠇࠆ଀ ⸵นߐࠇߥ޿଀

=Z*?=[7 8+ ?
=Z*?=Z*?㧔ⓨ⊕ࠍᝌ౉ߒߡߪߥࠄߥ޿㧕55

㧔㧟㧕࡙࡯ࠩߦࠃࠆൻቇ⒳ߩㅊട
ᣂⷙߦൻቇ⒳ࠍㅊടߔࠆ႐วߦߪ‫߿⺆⚂੍ޔ‬ᣢቯ⟵ߩൻቇ⒳㧔U, Pu ╬㧕ߩ⴫⸥ᴺ㧔⴫ 8.1㧕ߣหߓߦߥࠄߥ޿ࠃ߁ߦ⼂೎ሶࠍ⸳ቯߔࠆᔅⷐ߇޽ࠆ‫ߩߟ৻ޕ‬ൻቇ⒳ࠍ⴫ߔᢥሼ೉ߩ㐳ߐߪ‫ޔ‬ඨⷺ
16 ᢥሼએౝߦ೙㒢ߐࠇߡ޿ࠆ‫ޕ‬߹ߚ‫ޔ‬ᣂⷙൻቇ⒳߇ xNO3 ߹ߚߪ CN ߩ▚಴ߦነਈߔࠆ߆ߤ߁߆ࠍᜰቯߔࠆᔅⷐ߇޽ࠆ‫ ޕ‬xNO3 ෸߮ CN ߪ‫ޔ‬5.1 ▵(2)߿(11)ߦ޽ࠆࠃ߁ߦ޿ߕࠇ߽ṁᶧਛߩ⎣㉄ᩮߩࡕ࡞Ớᐲࠍ⴫ߒߡ߅ࠅ‫ޔ‬෻ᔕㅦᐲ෸߮ಽ㈩Ყߩ▚಴ߦ↪޿ࠄࠇࠆ‫ޔߢ⁁⃻ޕ‬ਔ⠪ߪቯ⟵߇⇣ߥߞߡ߅ࠅ૶޿ಽߌ߇ߥߐࠇߡ޿ࠆ‫ޕ‬㧔㧠㧕⸘▚ኻ⽎ߣߥࠄߥ޿ൻቇ⒳
 H2O , NO3- ߪ‫౉ߩ߳࠲࡝ࡊ࠲ࡦࠗޔ‬ജߪฃߌઃߌࠆ߇‫ߚߒ┙⁛ޔ‬ൻቇ⒳ߣߒߡߩỚᐲ⸘▚ߪⴕࠊߥ޿‫౉࠲࡝ࡊ࠲ࡦࠗޕ‬ജߢߪ "H2O", "NO3" ߣ⴫⸥ߔࠆ‫ޕ‬ ⎣㉄ᩮࠍ⴫⸥ߔࠆߦߪ‫ ⺆⚂੍ޔ‬CN ‫ޔ‬xNO3 ࠍ↪޿ࠆߎߣ߇ߢ߈ࠆ‫ߩߎޕ‬႐ว‫"ޔ‬CN", "xNO3"ߣ⴫⸥ߔࠆ㧔೨▵ෳᾖ㧕‫ޕ‬㧤㧚㧟㧚㧟 ൻቇ෻ᔕᑼ ൻቇ෻ᔕᑼߩฝㄝ෸߮Ꮐㄝߪⶄᢙߩൻቇᑼࠍ '㧗' ߢ⚿ࠎߢ⴫⸥ߔࠆ‫ޕ‬Ꮐㄝߣฝㄝߩ㑆ߪ"  "㧔ඨⷺߩࡑࠗ࠽ࠬ෸߮‫ޟ‬ᄢߥࠅ‫ߢޠ‬⍫ශࠍ⴫ߔ㧕ߢ⚿߱‫ޕ‬ൻቇᑼߩᏀߦߪᱜߩᢛᢙࠍᦠߊߎߣ߇
ߢ߈ࠆ‫ޕ‬ൻቇ෻ᔕᑼߪⶄᢙⴕߦࠊߚࠆߎߣ߇ߢ߈‫ޔ‬ᑼߩᦨᓟߦߪ ' ; '㧔࠮ࡒࠦࡠࡦ㧕ࠍ⟎ߊ‫ޕ‬ ൻቇᑼ‫ 'ޔ‬+ '‫ߩ ' ; 'ޔ"  "ޔ‬㑆ߦߪⶄᢙ୘ߩࠬࡍ࡯ࠬࠍ⟎ߊߎߣ߇ߢ߈ࠆ‫ޕ‬
଀ U4+ + 2 Pu4+ + 2 H2O ψ UO22+ + 2 Pu3+ + 4H+ ߩ႐ว  7 +8  2W +8  *1 7 8+  2W +++  *㧤㧚㧟㧚㧠 cond ㇱ㧔㧝㧕᭴ㅧcond ㇱߪⶄᢙ୘ߩ᧦ઙᑼࠍਗߴߚ߽ߩߢ޽ࠆ‫ޕ‬ฦ᧦ઙᑼߪⶄᢙⴕߦࠊߚࠆߎߣ߇น⢻ߢ‫ ޔ‬㧔࠮ࡒࠦࡠࡦ㧕ߦࠃߞߡߘߩ⚳ࠊࠅࠍ␜ߔ‫ᦨޕ‬ᓟߩ᧦ઙᑼߪ‫ޔ‬ᑼߩઍࠊࠅߦ੍⚂⺆ ELSE ࠍ⟎ߊߎߣ߇ߢ߈ࠆ‫ޕ‬଀߃߫‫ޔ‬㧔H+ Ớᐲ㧨0.5 mol dm-3㧕 ߆ߟ 㧔U(VI)Ớᐲ㧪0.1 mol dm-3㧕ߩ႐วߪ㨪 ߣ޿ߞߚ᧦ઙ
ߩ⴫⸥ߪਅ⸥ߩࠃ߁ߦߥࠆ‫ޕ‬56 ଀㧝 ᧦ઙᑼߩ଀
 

=Z*?.6 #0& =Z7 8+ ?)6 C1, C2, C3 ࠍฦ‫᧦ߩߟ৻ޘ‬ઙᑼ㧔⺰ℂᑼ㧕ߣߒߡ‫଀ޔ‬㧞ߩࠃ߁ߦ cond ㇱߦਗߴߡ⴫⸥ߒߚ႐ว‫ޔ‬ ଀㧞  C1  C2  C3
ߎࠇࠍ FORTRAN 61) 㘑ߦ⴫⸥ߔࠆߣ‫ޔ‬ᰴߩࠃ߁ߥ IF㨪THEN ᢥߩਗ߮ߣ⸃㉼ߐࠇࠆ‫ޕ‬
IF (C1) THEN …
ELSE IF (C2) THEN …
ELSE IF (C3) THEN  …
END IF ߹ߚ‫଀ޔ‬㧟ߩࠃ߁ߦ⴫⸥ߒߚ႐ว‫ޔ‬
଀㧟
C1 
C2 
'.5'ᰴߩ IF㨪THEN ᢥߩਗ߮ߣ⸃㉼ߐࠇࠆ‫ޕ‬  IF (C1) THEN …
ELSE IF (C2) THEN
 …
ELSE
 …

57

END IF Case ㇱߦ౉ജߐࠇࠆ⸘▚ᑼߩㆡ↪▸࿐ߦ೙㒢߇ή޿‫᧦ߜࠊߥߔޔ‬ઙᑼ߇ሽ࿷ߒߥ޿႐วߪ‫ޔ‬ᰴߩࠃ߁ߦ ELSE ߩߺࠍ㧝୘⟎ߊ‫ޕ‬ ଀  '.5'㧧ĺ cond ㇱߪߎߩⴕߩߺ

 F=Z0R 8 ?FV =Z0R 8 ? =Z7 +8 ? #ĺ case ㇱ㧔㧞㧕ᢥᴺ᧦ઙᑼߢߪ‫ޔ‬ታᢙဳߩઁߦ‫ޔ‬ᢛቯᢙࠍ↪޿ࠆߎߣ߇ߢ߈ࠆ‫ޕ‬ᢛቯᢙߪ‫ޔ‬ቯᢙ୯ߩ⴫⃻ߦ↪޿ࠄࠇࠆ߶߆‫ޔ‬ᢛᢙ 0 ߪ㧔FORTRAN ߢ޿߁㧕⺰ℂቯᢙ ".FALSE." ߩઍࠊࠅߦ↪޿‫ ߚ߹ޔ‬0 ߢߥ޿ᢛᢙߪ⺰ℂቯᢙ ".TRUE." ߩઍࠊࠅߦ↪޿ࠆߎߣ߇ߢ߈ࠆ‫ޕ‬PARC ߢߪ ".FALSE." ෸߮ ".TRUE."ߪ⋥ធ૶߁ߎߣ߇ߢ߈ߥ޿‫ޕ‬cond ㇱߩᢥᴺߪ߶߷ FORTRAN ߣหߓߢ޽ࠅ‫ޔ‬એਅߩࠃ߁ߥฦ⒳Ṷ▚ሶ߇૶߃ࠆ‫ޕ‬Ṷ▚ሶߩఝవ㗅૏෸߮⚿วᕈߪ FORTRAN ߣหߓߢ޽ࠆ‫ޕ‬Ԙ ▚ⴚṶ▚ሶ  ᱜᢙࠍ⴫ߔන㗄Ṷ▚ሶ  

⽶ᢙࠍ⴫ߔන㗄Ṷ▚ሶ

 

ട▚

  

ᷫ▚

  

ਸ਼▚

  

㒰▚ߴ߈ਸ਼㧔⚵ㄟ㑐ᢙߣߒߡ߽ขࠅ਄ߍߚ㧕ԙ 㑐ଥṶ▚ሶ  .6ዊߐ޿㧔㧨‫ޔ‬less than㧕  )6ᄢ߈޿㧔㧪‫ޔ‬greater than㧕  .'ዊߐ޿߆╬ߒ޿ 㧔҇‫ޔ‬less than or equal to㧕  )'ᄢ߈޿߆╬ߒ޿ 㧔҈‫ޔ‬greater than or equal to㧕  '3╬ߒ޿㧔㧩‫ޔ‬equal to㧕  0'╬ߒߊߥ޿

㧔ҁ‫ޔ‬not equal to㧕Ԛ ⺰ℂṶ▚ሶ  016

ุቯ58

  #0&⺰ℂⓍ  14⺰ℂ๺ ᰴߩᑼߪᧄࠦ࡯࠼ߢߪᢥᴺ㆑෻ߦߥࠅ‫ࡓ࡜ࠣࡠࡊޔ‬ታⴕ߇஗ᱛߐࠇࠆߩߢᵈᗧ߇ᔅⷐߢ޽ࠆ‫ޕ‬  )6
ߎߩ౉ജߪ‫ޔ‬"4.""GT" ".2"ߩࠃ߁ߦಽ⸃ߒߡ⸃㉼ߐࠇࠆ‫"ޕ‬GT"ߪ⸃㉼ߢ߈ߥ޿ߚ߼‫ޕࠆߥߣ࡯࡜ࠛޔ‬ᢛᢙߣᢛᢙߩᲧセߢߪ‫ޔ‬ਅ⸥ߩࠃ߁ߦ ".GT. " ߩ೨ᓟߦ඙ಾࠅࠍ⴫ߔⓨ⊕㧔ਅ✢ㇱ㧕ࠍ౉ࠇߥߌࠇ߫ߥࠄߥ޿‫ߩߎޕ‬႐ว‫ޔ‬"4"".GT." "2"ߣ⸃㉼ߐࠇࠆ‫ޕ‬  )6 cond ㇱߢߪ‫ޔ‬Ớᐲ╬ߩᄌᢙߪోߡ୚♖ᐲታᢙဳߣ⸃㉼ߔࠆ‫ޕ‬㧤㧚㧟㧚㧡 case ㇱ㧔㧝㧕᭴ㅧcase ㇱߢߩ෻ᔕㅦᐲ߿ಽ㈩Ყߩ⸘▚ᑼߩቯ⟵ߪ‫ޔ‬ታⴕߒߚ޿㗅ᐨߦਗߴߚ޿ߊߟ߆ߩઍ౉ᢥߩ
ਗ߮ߢ⴫⸥ߐࠇࠆ‫ᦨޕ‬ᓟߩᢥߪ⋡⊛ߣߔࠆ⸘▚ᑼߩ⸥ㅀߦߥߞߡ޿ߥߌࠇ߫ߥࠄߥ޿‫ߢߎߎޕ‬ઍ౉ᢥߩਔㄝߦหߓᄌᢙ߇⃻ࠇߚࠅ‫ޔ‬หߓਛ㑆ᄌᢙ߇ 2 ᐲએ਄ቯ⟵ߐࠇߡߪߥࠄߥ޿‫ޕ‬ฦઍ౉ᢥߪ
ⶄᢙߩⴕߦࠊߚߞߡ⸥ㅀน⢻ߢ‫ߩߟ৻ޔ‬ᢥߩ⚳ࠊࠅࠍ 㧔࠮ࡒࠦࡠࡦ㧕ߦࠃߞߡ␜ߔ‫ᦨޕ‬ೋߩઍ౉ᢥ߆ࠄ⋡⊛ߩ⸘▚ᑼߩ⸥ㅀ߹ߢࠍ case ࡉࡠ࠶ࠢߣ๭߱ߎߣߦߔࠆ‫ޕ‬਄⸥ case ㇱߦ߅޿ߡ࡙࡯ࠩ߇౉ജน⢻ߥ⸘▚ᑼߪ‫ޔ‬ᰴߩ㧠ߟߩ࠲ࠗࡊߦಽ㘃ߐࠇࠆ‫ޕ‬ಽ㈩Ყߦ
㑐ߔࠆ⸘▚ᑼߣߒߡ d1 ဳ‫ޔ‬d2 ဳࠍ‫ޔ‬ൻቇ෻ᔕㅦᐲߦ㑐ߔࠆ⸘▚ᑼߣߒߡ rx ဳ‫ޔ‬ry ဳࠍᗐቯߒߡ
޿ࠆ‫ޕ‬d1㧦⎣㉄ᩮߛߌߩ㑐ᢙߢ޽ࠆ⷗߆ߌߩᐔⴧቯᢙ㧔Richardson ဳߩᑼ㧕d2㧦᳓⋧ߣ᦭ᯏ⋧ਔ⋧ߩỚᐲߩ㑐ᢙߢ޽ࠆಽ㈩Ყ⸘▚ᑼrx 㧦᳓⋧ߩỚᐲߩ㑐ᢙߢ޽ࠆ᳓⋧ߩൻቇ෻ᔕㅦᐲᑼ
ry 㧦᦭ᯏ⋧ߩỚᐲߩ㑐ᢙߢ޽ࠆ᦭ᯏ⋧ߩൻቇ෻ᔕㅦᐲᑼ

59 ଀ ৻ߟߩ case ࡉࡠ࠶ࠢߩ଀㧔rx ࠲ࠗࡊ㧕  #=Z*?   =Z*?
  F=Z0R 8 ?FV =Z0R 8 ? =Z7 +8 ? # cond ㇱߩ᧦ઙᑼ㧔C1, C2, C3 , ...㧕ߩ୘ᢙߣ case ࡉࡠ࠶ࠢ㧔ࡉࡠ࠶ࠢ 1, 2, 3, ...㧕ߩ୘ᢙߪ৻⥌ߒߡ޿ߥߌࠇ߫ߥࠄߥ޿‫ޕ‬ ଀C1㧧cond ㇱ

C2㧧
C3㧧
㧔case ࡉࡠ࠶ࠢ 1㧕㧔case ࡉࡠ࠶ࠢ 2㧕

case ㇱ

㧔case ࡉࡠ࠶ࠢ 3㧕਄⸥ߩ଀ߩ႐ว‫ޔ‬ᰴߩࠃ߁ߦ⸃㉼ߐࠇࠆ‫ޕ‬
IF (C1) THEN
㧔case ࡉࡠ࠶ࠢ 1㧕
ELSE IF (C2) THEN
㧔case ࡉࡠ࠶ࠢ 2㧕
ELSE IF (C3) THEN
㧔case ࡉࡠ࠶ࠢ 3㧕
END IF㧔㧞㧕ᢥᴺ
case ㇱߢߪᏀㄝ = ฝㄝ ;ߥࠆ╬ᑼߩᒻߢಽ㈩Ყ߿෻ᔕㅦᐲߩ⸘▚ᑼࠍ⸥ㅀߔࠆ‫▚⸘ޕ‬ᑼߩᏀㄝߩ⴫⸥ߪߘߩ⒳㘃㧔㧠⒳㘃㧕
ߦᔕߓߡએਅԘ㨪ԛߩࠃ߁ߦ᳿߹ߞߡ޿ࠆ‫ޕ‬case ㇱߢߪਛ㑆ᄌᢙߩ૶↪߇⸵ߐࠇࠆߚ߼‫ⶄޔ‬ᢙߩ⸘▚ᑼ߇৻⥸ߦሽ࿷ߔࠆ‫ޕ‬એਅߩᒻᑼߩᏀㄝࠍᜬߟ╬ᑼߪ‫ޔ‬case ㇱߩᦨᓟㇱಽߦ౉ജߔࠆ‫ޕ‬60 Ԙ d1 ဳ  Richardson ဳߩಽ㈩Ყ⸘▚ᑼߢ޽ࠅ‫ߩߌ߆ߺޔ‬ᐔⴧቯᢙࠍ
 K0[ൻቇᑼ]‫ޔ‬K1[ൻቇᑼ]‫ޔ‬K 2[ൻቇᑼ]‫ޔ‬K 3[ൻቇᑼ]ߣ⴫⸥ߔࠆ‫ޕ‬K 0‫ޔ‬K 1‫ޔ‬K 2‫ޔ‬K 3 ߪฦ‫࡯࡝ࡈޘ‬TBP Ớᐲ㧔Tf㧕ߩ 0 ਸ਼‫ޔ‬1 ਸ਼‫ޔ‬2 ਸ਼‫ޔ‬3 ਸ਼ߦᲧ଀ߔࠆᑼߢ޽ࠅ‫ޔ‬0 ਸ਼‫ޔ‬1 ਸ਼‫ޔ‬2 ਸ਼‫ޔ‬3 ਸ਼ߩᑼࠍ೎‫౉ߦޘ‬ജߔࠇ߫ PARC ౝㇱߢߘࠇࠄߩ๺ࠍߣߞ
ߡಽ㈩Ყ⸘▚ᑼߣߒߡ↪޿ࠆ‫࡯࡝ࡈޔߒߛߚޕ‬TBP ߩỚᐲߩ⸘▚ߦߪ Richardson ဳߩᑼߩ߁ߜ
ࡈ࡝࡯TBP ߩ 0 ਸ਼‫ޔ‬1 ਸ਼‫ޔ‬2 ਸ਼ߦᲧ଀ߔࠆᑼߩߺ߇↪޿ࠄࠇ‫ޔ‬3 ਸ਼ߦᲧ଀ߔࠆᑼߪήⷞߐࠇࠆ‫ޕ‬  ଀ -=0R +8 ? ̖-=0R +8 ? ̖-=0R +8 ? ̖   ߎߩ଀ߢߪ‫ޔ‬Np(IV)ߩಽ㈩Ყ⸘▚ᑼߪ‫ޔ‬એਅߩࠃ߁ߦ⸃㉼ߐࠇࠆ‫ޕ‬ D[Np(IV)] = K0[Np(IV)]㧗K1[Np(IV)]࡮Tf + K2[Np(IV)]࡮Tf 2
 ԙ d2 ဳ ৻⥸⊛ߥᒻᑼߩಽ㈩Ყߢ޽ࠅ‫ޔ‬Ꮐㄝߪ   &=ൻቇᑼ? ߩࠃ߁ߦ⴫⸥ߔࠆ‫ߩߌ߆⷗ߪࠇߎޕ‬ᐔⴧቯᢙߢߪߥߊಽ㈩Ყ⥄૕ࠍ⴫ߔ‫ޕ‬ ଀ &=6E? ̖ Ԛ rx ဳ  ᳓⋧ߩൻቇ෻ᔕㅦᐲᑼߢ޽ࠅ‫ޔ‬Ꮐㄝߪ   F=Z ൻቇᑼ?FV ߩࠃ߁ߦ⸥ㅀߔࠆ‫ޕ‬d ෸߮ dt ߪ⧷ሼዊᢥሼߢ౉ജߔࠆ‫ޕ‬ⓨ⊕ߪ౉ࠇߥ޿‫ޕ‬ ⸵นߐࠇࠆ଀  F=Z0R +8 ?FV ̖㧕  ⸵นߐࠇߥ޿଀ F=Z0R +8 ?FV F=Z0R +8 ?FV 㧔ⓨ⊕ߩᝌ౉㧔ਅ✢ㇱ㧕 ԛ ry ဳ ᦭ᯏ⋧ߩൻቇ෻ᔕㅦᐲᑼߢ޽ࠅ‫ޔ‬Ꮐㄝߪ61  F=[ ൻቇᑼ?FV ߩࠃ߁ߦ⸥ㅀߔࠆ‫ޕ‬d ෸߮ dt ߪ⧷ሼዊᢥሼߢ౉ജߔࠆ‫ޕ‬ⓨ⊕ߪ౉ࠇߥ޿‫ޕ‬  ⸵นߐࠇࠆ଀  F=[2W +8 ?FV ̖ case ㇱߢߪ‫▚⸘ޔ‬ᑼߩ⸥ㅀࠍᢛℂߔࠆߚ߼ߦਛ㑆ᄌᢙࠍ↪޿ࠆߎߣ߇ߢ߈ࠆ‫ޕ‬ਛ㑆ᄌᢙฬߪ⧷
ሼߢᆎ߹ࠆ⧷ᢙሼ㧔16 ᢥሼએౝ㧕ߢ⴫⸥ߔࠆ‫ޕ‬ᄢᢥሼߣዊᢥሼߪ඙೎ߐࠇࠆ‫ޕ‬ એਅߩ଀ߢߪ A1 ߇ਛ㑆ᄌᢙߢ޽ࠆ‫ޕ‬ ଀
  #=Z*?   =Z*?
  F=Z0R 8 ?FV =Z0R 8 ? =Z7 +8 ? # case ㇱߩᢥᴺߪ߶߷ FORTRAN ߣหߓߢ޽ࠅ‫ޔ‬એਅߩࠃ߁ߥ▚ⴚṶ▚ሶ߇น⢻ߢ޽ࠆ‫ޕ‬Ṷ▚ሶߩఝవ㗅૏෸߮⚿วᕈߪ FORTRAN ߣหߓߢ޽ࠆ‫ޕ‬
▚ⴚṶ▚ሶ
  

㧔ᱜᢙࠍ⴫ߔන㗄Ṷ▚ሶ㧕  

㧔⽶ᢙࠍ⴫ߔන㗄Ṷ▚ሶ㧕

 

㧔๺㧕

  

㧔Ꮕ㧕

  

㧔Ⓧ㧕

  

㧔໡㧕

 



㧔ߴ߈ਸ਼‫⚵ޔ‬ㄟ㑐ᢙߣߒߡ߽ขࠅ਄ߍߚ㧕case ㇱߢߪ‫ޔ‬Ớᐲ╬ߩᄌᢙߪోߡ୚♖ᐲታᢙဳߣ⸃㉼ߔࠆ‫ޕ‬㧤㧚㧟㧚㧢 ੍⚂⺆෸߮⚵ㄟ㑐ᢙ㧔㧝㧕੍⚂⺆ ⸘▚ᑼߩ⒳㘃ߦᔕߓߡ੍߼ᗧ๧߇ਈ߃ࠄࠇߚએਅߩࠃ߁ߥ੍⚂⺆ࠍ↪޿ࠆߎߣ߇ߢ߈ࠆ‫ޕ‬ᄢᢥሼߣዊᢥሼߪ඙೎ߐࠇࠆ‫ ߪ⺆⚂੍ߩࠄࠇߎޕ‬cond ㇱߣ case ㇱߢ౒ㅢߦ૶↪น⢻ߢ޽ࠆ‫ޕ‬d1 ဳ 㧦

Frc, tau, ln10, xNO362

d2 ဳ 㧦Frc, tau, ln10, xNO3, Tf

rx ဳ 㧦

T, ln10, xNO3, CN

ry ဳ 㧦

T, ln10 ฦ੍⚂⺆ߩᗧ๧ߪએਅߩߣ߅ࠅ‫ޕ‬Frc

㧦

TBP ߩ૕Ⓧಽ₸ [ - ]tau㧦ṁᶧ᷷ᐲߩㅒᢙߣᏱ᷷㧔25͠㧕ߣߩᏅ㧔1 / T - 1 / 298㧕

ln10

㧦

log e 10xNO3 㧦

⎣㉄ᩮỚᐲ㧔ᄢ᜝ᒐ "[]" ߢ࿐߹ߥ޿ߎߣ㧕
-3

Tf

㧦

ࡈ࡝࡯TBP Ớᐲ [mol dm ]T㧦ṁᶧ᷷ᐲ [K]CN㧦⎣㉄ᩮỚᐲ㧔xNO3 ߣߪ೎ቯ⟵㧕㧔㧞㧕⚵ㄟ㑐ᢙ੍߼ᗧ๧߇ਈ߃ࠄࠇߚએਅߩࠃ߁ߥ⚵ㄟ㑐ᢙࠍ↪޿ࠆߎߣ߇ߢ߈ࠆ‫⧷ߡోޕ‬ሼዊᢥሼߢ⴫⸥ߔ
ࠆ‫⚵ߩࠄࠇߎޕ‬ㄟ㑐ᢙߪ cond ㇱߣ case ㇱߢ౒ㅢߦ૶↪น⢻ߢ޽ࠆ‫ޕ‬ᒁᢙߪዊ᜝ᒐ"()"ߢ࿐߻‫ޕ‬ᢛᢙဳ෸߮ታᢙဳߦߟ޿ߡߪᰴ▵ෳᾖ‫ޕ‬abs㧦⛘ኻ୯  㧔ᒁᢙߪᢛᢙဳ߹ߚߪታᢙဳ㧕exp㧦ᜰᢙ㑐ᢙ 㧔ᒁᢙߪታᢙဳ㧔ᢛᢙဳߪਇน㧕㧕log㧦⥄ὼኻᢙ 㧔ᒁᢙߪታᢙဳ㧔  ‫  ޖ‬㧕㧕

log10 㧦Ᏹ↪ኻᢙ 㧔ᒁᢙߪታᢙဳ㧔  ‫  ޖ‬㧕㧕**㧦ߴ߈ਸ਼  㧔ᒁᢙߪታᢙဳ㧔  ‫  ޖ‬㧕㧕

sqrt

㧦

ᐔᣇᩮ  㧔ᒁᢙߪታᢙဳ㧔  ‫  ޖ‬㧕㧕

cosh

㧦

෺ᦛ✢㑐ᢙ㧔ᒁᢙߪታᢙဳ㧔  ‫  ޖ‬㧕㧕

sin2h 㧦෺ᦛ✢㑐ᢙ㧔ᒁᢙߪታᢙဳ㧔  ‫  ޖ‬㧕㧕㧦෺ᦛ✢㑐ᢙ㧔ᒁᢙߪታᢙဳ㧔  ‫  ޖ‬㧕㧕tanh ଀ GZR =Z*?

㧤㧚㧟㧚㧣 ቯᢙ ⸘▚ᑼਛߦ 0.5 ‫ޔ‬-1.4e-3 ╬ߩቯᢙࠍ↪޿ࠆߎߣ߇น⢻ߢ޽ࠆ‫ޕ‬ቯᢙߪ‫ޔ‬ᢛᢙဳ(integer)㧛ታᢙဳ(real)ߩ⼂೎߇ߥߐࠇࠆ‫ޕ‬࿑ 8.3 ߦ⼂೎ߩߚ߼ߩ᳿ቯᕈ᦭㒢ࠝ࡯࠻ࡑ࠻ࡦࠍ␜ߔ‫߁޿ߢߎߎޕ‬ᢛᢙဳߣߪ‫ޔ‬ᢥሼ '0' 㨪 '9' ߩਗ߮ߢ޽ࠅ‫ޔ‬ᱜ⽶ࠍ␜ߔ╓ภ߇ᢥሼ೉ߩవ㗡ߦߟߊߎߣ߇޽ࠅ‫ޔ‬ዊᢙὐ෸߮ᜰᢙࠍ␜ߔ "E"‫"ޔ‬e" ࠍᜬߚߥ޿‫ޕ‬એਅߦታᢙဳ෸߮ᢛᢙဳߩቯᢙߩ⴫⸥଀ࠍ␜ߔ‫ޕ‬63 ⸵นߐࠇࠆᢛᢙဳߩ଀   ⸵นߐࠇࠆታᢙဳߩ଀ '' '     GG  ߹ߚ‫ޔ‬ቯᢙߪዊ᜝ᒐ "( ଀)"ߢ࿐߻ߎߣ߇ߢ߈ࠆ‫ޕ‬ ೨▵ߢ␜ߒߚ⚵ㄟ㑐ᢙߪ‫ߩߘޔ‬ᒁᢙߦᢛᢙဳࠍ⸵ߐߥ޿߽ߩ߇ᄙ޿ߚ߼ᵈᗧ߇ᔅⷐߢ޽ࠆ‫ޕ‬ ⸵นߐࠇࠆ଀  =Z7 8+ ?

 ⸵นߐࠇߥ޿଀ =Z7 8+ ?

㧔ᢛᢙਸ਼ߪ⸵นߒߥ޿‫ޕ‬㧕64㧤㧚㧠 ૏⟎࠺࡯࠲㧤㧚㧠㧚㧝 ૏⟎࠺࡯࠲ߩᦠᑼ
૏⟎࠺࡯࠲ㇱߢߪ‫ޔ‬ᮨᡆߒࠃ߁ߣߔࠆࡊ࡜ࡦ࠻ߩ⸳⸘࡮ㆇォߩᖱႎ㧔᛽಴ེߩኸᴺ‫ޔ‬ធ⛯‫ࡄޔ‬࡞ࠬ᧦ઙ‫࠼࡯ࠖࡈޔ‬ᵹ㊂‫ޔ‬Ớᐲ╬㧕ࠍ౉ജߔࠆ‫ޕ‬૏⟎࠺࡯࠲ߦ㑐ߔࠆᦠᑼߪ‫ޔ‬න⚐ߢ޽ࠅ‫ޔ‬ฦࡈࠖ࡯࡞࠼㧔৻ߟ৻ߟߩ౉ജ୯㧕ߪ㧝୘એ਄ߩⓨ⊕㧔ඨⷺ㧕ߢ඙ಾࠄࠇࠆ‫ޕ‬ ᧄ౉ജࡑ࠾ࡘࠕ࡞ਛߢ㧝ⴕߦ⴫⸥ߔࠆ࠺࡯࠲ߣߒߡ␜ߐࠇߚⶄᢙ୘ߩࡈࠖ࡯࡞࠼ߪ‫ࡈߩߡోޔ‬ࠖ࡯࡞࠼߇ḩߚߐࠇࠆ߹ߢ౉ജࡈࠔࠗ࡞ߩⶄᢙⴕߦࠊߚߞߡត⚝ߐࠇࠆ‫ޕ‬ᓥߞߡ‫౉ޔ‬ജࡈࠔࠗ࡞
ਛߢߪ‫ޔ‬㧝ⴕ߇㐳ߊߥࠅߔ߉ࠆ႐วߦߪ‫ޔ‬ㆡᒰߦᡷⴕࠍ౉ࠇⶄᢙⴕߣߔࠆߎߣ߇น⢻ߢ޽ࠆ‫ޕ‬ ଀㧝ߢߪ‫ޔ‬t = 0 ߢߩࡈࠖ࡯࠼ᶧߩỚᐲࠍ 14 ൻቇ⒳ߦߟ޿ߡ⸳ቯߒߚ߽ߩߢ޽ࠆ‫ޕ‬15 ୘ోߡߩ౉ജ୯ࠍหߓⴕߦਗߴࠆߣⴕ߇㐳ߊߥࠆߎߣ߆ࠄ‫ޔ‬ㅜਛߢᡷⴕࠍ౉ࠇߡⶄᢙⴕߦಽഀߒߡ޿ࠆ
㧔ߪᵈ㉼ⴕࠍ␜ߔ߽ߩ㧕‫ޕ‬଀㧝  %QPEGPVTCVKQPVCDNG  VKOG*72W2W7*#0*;&*01  OKP/I.I.I.I.///  G  <T6E0R0R0R*0  I.I.I.I.I./ ߹ߚ‫౉ޔ‬ജࡑ࠾ࡘࠕ࡞ߢᡷⴕߐࠇࠆߎߣߣߐࠇߡ޿ࠆㇱಽߢߪ‫ޔ‬ᚲቯ୘ᢙߩ࠺࡯࠲ࠍ⺒ߺㄟࠎߛᓟߦ࠺࡯࠲߇ᱷߞߡ޿ߚߣߒߡ߽‫ޔ‬ᱷࠅߩ࠺࡯࠲ߪ⺒ߺㄟ߹ࠇߥ޿‫଀ޕ‬㧞ߢߪ‫ޔ‬8 ൻቇ⒳⸘▚ߩ౉ജߦ߅޿ߡ 9 ൻቇ⒳ಽ⸳ቯߒߡ޿ࠆ߇‫ߺ⺒ޔ‬ㄟߺߪ 1.0e-5 ߹ߢߢ⚳ੌߒ‫ߩߘޔ‬ᓟߩ 10.0 ߪ⺒ߺㄟ߹ࠇߥ޿㧔ࠛ࡜࡯಴ജߪ಴ߥ޿㧕‫ޕ‬଀㧞  %QPEGPVTCVKQPVCDNG  VKOG*72W2W7*#0*;&*01VJ  OKP/I.I.I.I.///  G  ߹ߚ‫ޔ‬n ୘ߩหߓᢙ୯ߩ౉ജߢߪ‫ޔ‬n ࠍᱜᢛᢙߣߒߡ‫ޔ‬P ࠍᢙ୯ߩ೨ߦ⟎ߊ⴫⃻߇น⢻ߢ޽ࠆ‫ޕ‬଀߃߫‫ޔ‬0.0 ࠍ 8 ୘ਗߴࠆ႐วߢߪ‫ޔ‬ᰴߩ଀ 3 ෸߮଀ 4 ߇ߤߜࠄ߽น⢻ߢ޽ࠆ‫ޕ‬65଀㧟  ଀㧠   FORTRAN ߩ free format ߣ⇣ߥࠆὐߪ‫౉ޔ‬ജ࠺࡯࠲ߩ࠲ࠗ࠻࡞㧔8.4.2.1 ▵ (1)㧕ࠍ㒰޿ߡ‫ޔ‬ᢥሼ೉߽ⓨ⊕ߢ඙ಾࠄࠇࠆ߽ߩߣߐࠇࠆ‫ߢ╬)‘(ࡦ࡚ࠪ࡯࠹࡯ࠜࠢ࡞ࠣࡦࠪޕ‬࿐߻ᔅⷐߪߥ޿‫ޕ‬ ᜰᢙㇱߟ߈ߩᶋേዊᢙὐᢙࠍ౉ജࡈࠔࠗ࡞ߢ౉ജߔࠆ႐วߪ‫ޔ‬ᜰᢙㇱࠍ␜ߔᢥሼߣߒߡ E ߹ߚ
ߪ e ࠍ↪޿ࠆ㧔FORTRAN ߩࠃ߁ߦ D ߪ૶↪ߒߥ޿㧕‫ޕ‬㧤㧚㧠㧚㧞 ౉ജ࠺࡯࠲
㧤㧚㧠㧚㧞㧚㧝 ✚ว࠺࡯࠲㧔㧝㧕Title
Title 㧦⸘▚ߩ࠲ࠗ࠻࡞㧔LINLEN એౝߩᢥሼ೉㧕⥄↱ߦ⸥ㅀߢ߈ࠆ‫ޕ‬LINLEN=1000‫ోޕ‬૕߇৻ⴕߦ⚊߹ߞߡ޿ߥߌࠇ߫ߥࠄߥ޿‫ޕ‬
㧔㧞㧕nMemSiz,nMemQuadSiz,

nMemVarSiz,

nMemSymSizࡊࡠࠣ࡜ࡓߩേ૞ߦᔅⷐߥࡔࡕ࡝ࠍ⏕଻ߔࠆ⸳ቯࠍⴕ߁‫ޕ‬nMemSiz㧦ࠗࡦ࠲ࡊ࡝࠲એᄖߩㇱಽߩߚ߼ߦࡊࡠࠣ࡜ࡓታⴕᤨߦ⏕଻ߔࠆࡔࡕ࡝ߩࠨࠗ
࠭㧔ᱜᢛᢙ㧕

[bytes]nMemQuadSiz 㧦ਛ㑆⸒⺆㧔྾ߟ⚵㧕ߩ㗔ၞߩߚ߼ߦࡊࡠࠣ࡜ࡓታⴕᤨߦ⏕଻ߔࠆࡔࡕ࡝ߩࠨ
ࠗ࠭㧔ᱜᢛᢙ㧕 [bytes]
nMemVarSiz㧦ਛ㑆⸒⺆ߢ૶߁ᄌᢙߩߚ߼ߦࡊࡠࠣ࡜ࡓታⴕᤨߦ⏕଻ߔࠆࡔࡕ࡝ߩࠨࠗ࠭
㧔ᱜᢛᢙ㧕

nMemSymSiz[bytes]㧦⸥ภ⴫ߩߚ߼ߦࡊࡠࠣ࡜ࡓታⴕᤨߦ⏕଻ߔࠆࡔࡕ࡝ߩࠨࠗ࠭㧔ᱜᢛᢙ㧕 [bytes]

㧔㧟㧕fSpefSpe 㧦⸘▚ኻ⽎ߩൻቇ⒳ߩㆬᛯ㧔㐳ߐ 29 ߩᢥሼ೉㧕
NFIX㧔⚵ㄟߺൻቇ⒳ߩᢙ‫ޔ‬NFIX=29㧕୘ߩൻቇ⒳ߩ߁ߜ‫ߩߤޔ‬ൻቇ⒳ࠍ⸘▚ኻ⽎ߣߔࠆ߆ࠍ
'1' ෶ߪ '0' ߆ࠄᚑࠆ 29 ᢥሼߩᢥሼ೉ߢᜰቯߔࠆ‫ޕ‬ኻ⽎ൻቇ⒳ࠍ⴫ߔ૏⟎ߦ '1' ࠍᜰቯߒ‫ޔ‬ኻ⽎ߣߒߥ޿ൻቇ⒳ߪ '0' ࠍᜰቯߔࠆ‫ޕ‬NFIX ୘ోߡߦߟ޿ߡᜰቯߒߥߌࠇ߫ߥࠄߥ޿‫ޕ‬fSpe ਛߦ⃻ࠇࠆ'1'ߩ୘ᢙࠍ nNFIX ߣߔࠆ‫ޕ‬ฦൻቇ⒳ߣ fSpe ਛߩ૏⟎ߩ㑐ଥߪ‫ޔ‬એਅߩߣ߅ࠅ‫ޕ‬66

Ꮐ┵߆ࠄߩ૏⟎ 1

2

ㆬᛯൻቇ⒳

H

11

3

9

10

U(VI) Pu(IV) Pu(III) U(IV) HAN HYD

HNO2 Zr

Tc

12

18

19

20
Cs

13

4

5

14

15

6

7

16

17

8

Np(IV) Np(V) Np(VI) HN3iBAL nBAL iBAC

nBAC I

21

22

24

25

26

28

Ru

Pu(VI) V(IV)

V(V)

DBP

MBP H3PO4 FP

23

27

29
H2O2

଀㧝 H, U(VI), Pu(IV), Pu(III), U(IV), HAN, HYD, HNO2, HN3 ࠍ⸘▚ኻ⽎ߣߔࠆ႐ว(nNFIX = 9)    H5RG   ଀㧞

଀ 1 ߩൻቇ⒳ߦട߃ߡ DBP, MBP, H3PO4 ࠍ⸘▚ኻ⽎ߣߔࠆ႐ว (nNFIX = 12)    H5RG   

PARC ߢߪ‫ߩߢߎߎޔ‬ൻቇ⒳ㆬᛯߦᔕߓߡ‫ޔ‬5 ┨㨪6 ┨ߦ␜ߒߚൻቇ෻ᔕㅦᐲ߿ಽ㈩Ყߩ⸘▚ᑼ㧔એਅ‫⚵ޟޔ‬ㄟߺᑼ‫ޕ߁޿ߣ╬ޠ‬㧕ߩਛ߆ࠄᔅⷐߥ߽ߩࠍ⥄േ⊛ߦㆬᛯߔࠆ‫ޔ߫߃଀ޕ‬Np
ߦଥࠆ⸘▚ࠍᔅⷐߣߒߥ޿႐วߪ‫ޔ‬fSpe ߢᜰቯߔࠆߎߣߦࠃࠅ Np ߦ㑐ଥߔࠆ෻ᔕᑼࠍ⋭⇛ߔࠆߎߣ߇ߢ߈‫ᤨ▚⸘ޔ‬㑆ߩ⍴❗ࠍ࿑ࠆߎߣ߇ߢ߈ࠆ‫ࠆߔߣ⊛⋡߇ࠩ࡯࡙ޕ‬ൻቇ෻ᔕㅦᐲᑼ߇ㆡ
ಾߦㆬᛯߐࠇࠆࠃ߁ fSpe ࠍ⸳ቯߔࠆᔅⷐ߇޽ࠆ‫ޔ߫߃଀ޕ‬੝⎣㉄ߩࡅ࠼࡜ࠫࡦߦࠃࠆಽ⸃෻ᔕ
㧔㧡┨ෳᾖ㧕ࠍ⠨ᘦߒࠃ߁ߣߔࠆ႐วߪ‫ޔ‬ዋߥߊߣ߽ࡅ࠼࡜ࠫࡦ‫ޔ‬੝⎣㉄‫ޔ‬᳓⚛ࠗࠝࡦ‫ࠫࠕޔ‬ൻ᳓⚛߇ fSpe ߢㆬᛯߐࠇߡ޿ߥߌࠇ߫ߥࠄߥ޿‫ޕ‬㧔㧠㧕nDelnDel 㧦೥㒰ߔࠆ⚵ㄟߺᑼߩ୘ᢙ㧔ᱜᢛᢙ㧕⚵ㄟߺᑼߪ‫౉ࠩ࡯࡙ޔ‬ജߦࠃߞߡ೥㒰߇น⢻ߢ޽ࠆ‫ޕ‬೥㒰ߔࠆ߽ߩߩ୘ᢙࠍ౉ജߔࠆ‫ޕ‬
㧔㧡㧕iFrmTyp,iFrmNum’s

਄⸥ nDel ߇ 1 એ਄ߩߣ߈ߩߺ‫ޔ‬એਅࠍ➅ࠅ㄰ߒ‫ޔ‬nDel ⴕߩ࠹࡯ࡉ࡞ߣߔࠆ‫ޕ‬iFrmTyp㧦೥㒰ߔࠆ⚵ㄟߺᑼߩဳ㧔d1, d2, rx, ry㧕‫ޕ‬d1 ဳߩಽ㈩Ყ⸘▚ᑼࠍ೥㒰ߔࠆߣ߈0d2 ဳߩಽ㈩Ყ⸘▚ᑼࠍ೥㒰ߔࠆߣ߈1rx ဳߩᑼ㧔᳓⋧ߢߩ෻ᔕㅦᐲᑼ㧕ࠍ೥㒰ߔࠆߣ߈2ry ဳߩᑼ㧔᦭ᯏ⋧ߢߩ෻ᔕㅦᐲᑼ㧕ࠍ೥㒰ߔࠆߣ߈

367

iFrmNum㧦೥㒰ߔࠆታ㛎ᑼߩ⇟ภ‫ޕ‬iFrmTyp = 0 or 1 ߩߣ߈

ൻቇ⒳ ID㧔4 ┨ෳᾖ㧕ࠍᜰቯ㧔1㨪29 ߩ޿ߕࠇ߆ߩᱜᢛᢙ㧕= 2 ߩߣ߈

෻ᔕㅦᐲᑼ ID㧔5 ┨ෳᾖ㧕㧔1㨪26 ߩ޿ߕࠇ߆ߩᱜᢛᢙ㧕= 3 ߩߣ߈

ಽ㈩Ყ⸘▚ᑼ ID㧔6 ┨ෳᾖ㧕㧔1㨪5 ߩ޿ߕࠇ߆ߩᱜᢛᢙ㧕଀ ᳓⋧ߢߩൻቇ෻ᔕㅦᐲߩ⸘▚ᑼ 3 ෸߮ 6 ߩ೥㒰   P&GN    K(TO6[R  K(TO0WO 
 K(TO6[R  K(TO0WO 
㧔㧢㧕nwspe, ncomp,ns

nwspe 㧦࡙࡯ࠩ౉ജߦࠃࠅᣂߒߊㅊടቯ⟵ߔࠆൻቇ⒳ᢙ㧔ᱜᢛᢙ㧕
ncomp 㧦ࠦࡦࡐ࡯ࡀࡦ࠻ߩ୘ᢙ㧔ᱜᢛᢙ㧕㧔ࠦࡦࡐ࡯ࡀࡦ࠻ߣߪࡄ࡞ࠬࠞ࡜ࡓ‫ߩࠄࠇߘޔߪߢߎߎޕࠢࡦ࠲ޔ࡜࠻࠮ࠨࠠࡒޔ‬ว⸘୘ᢙࠍᜰቯߔࠆ‫ࡓ࡜ࠞࠬ࡞ࡄޔ߫߃଀ޕ‬㧡ၮ‫࡜࠻࠮ࠨࠠࡒޔ‬㧞ၮ‫ࠢࡦ࠲ޔ‬㧠ၮࠍㅪ⚿ߒߚࡊ࡜ࡦ࠻ߢߪ‫ޔ‬ncomp = 5+2+4 = 11 ߣߥࠆ‫ޕ‬㧕
㧦1 ߟߩࡔ࠶ࠪࡘ㧔଀߃߫ࡒࠠࠨ࠮࠻࡜ߢߪ 1 Ბߦ⋧ᒰ‫ޕ‬㧕߳ߩฦ⋧޽ߚࠅᵹ౉ᢙߩᦨ

nsᄢ୯ߎߎߢ޿߁ᵹ౉ᢙߣߪࡈࠖ࡯࠼ᢙ㧗ઁࠦࡦࡐ࡯ࡀࡦ࠻߆ࠄߩᵹ౉ᢙߢ޽ࠆ‫ޕ‬ਅ࿑ߩ଀ߢߪ‫ޔ‬6 Ბ⋡ߩᵹ౉ᢙߪ᳓⋧ 2 ෸߮᦭ᯏ⋧ 0 ߢว⸘ 2 ߢ޽ࠆߚ߼‫ޔ‬ns҈2 ߢ޽ࠆࠃ߁
ߥᱜᢛᢙ ns ߩ⸳ቯ߇ᔅⷐߢ޽ࠆ‫ޕ‬㧕

Ბ⇟ภ

1

2

3

4

5

6

̪ (3)ߢㆬᛯߒߚൻቇ⒳ߣ࡙࡯ࠩ౉ജߦࠃࠅㅊടቯ⟵ߔࠆൻቇ⒳ߩว⸘ᢙ nspe ࠍᰴᑼߢቯ⟵ߔࠆ‫ޕ‬nspe = nNFIX + nwspeએਅߪ‫ޔ‬ᣂⷙൻቇ⒳ߣ㑐ㅪߔࠆ෻ᔕᑼࠍ(6)㨪(11)ߦ߅޿ߡ⸳ቯߒߚ଀ߢ޽ࠆ㧔"/*" "*/"ߢ࿐߹ࠇߚㇱಽߪࠦࡔࡦ࠻㧕‫ޕ‬68଀   PYURG  PEQOR  PU    %JGO(TO  #DDTGX0CO  9GKIJV  H01  H%0  8CNGPEG   0'9%*'/ +++  0'9
  0'9%*'/ +8 0'9   PY(TO 
 DGIKP   P%QPF  K(TO6[R    &GUETKRVKQPQHEJOKECNTGCEVKQPU   2W +8

0'9%*'/ +++  2W +++ 0'9%*'/ +8   '.5'  M GZR      6   F=Z2W +8 ?FVM =Z2W +8 ? =Z*? %0 =Z0'9%*'/ +++ ? 
  GPF㧔㧣㧕ChemFrm,

AbbrevNam,

Weight,fXNO3,

fCN,

Valence

nwspe ߇ 1 એ਄ߩߣ߈ߩߺ‫ޔ‬એਅࠍ➅ࠅ㄰ߒ‫ޔ‬nwspe ⴕߩ࠹࡯ࡉ࡞ߣߔࠆ‫ޕ‬
ChemFrm 㧦ㅊടቯ⟵ߔࠆൻቇ⒳ߩൻቇᑼ㧔16 ᢥሼએౝߩᢥሼ೉㧕AbbrevNam 㧦ChemFrm ߩ⋭⇛ฬ⒓㧔಴ജᤨߦ⴫␜ߐࠇࠆ㧕㧔4 ᢥሼએౝߩᢥሼ೉㧕
Weight㧦ㅊടቯ⟵ߔࠆൻቇ⒳ߩන૏ᄌ឵ଥᢙ
Ớᐲන૏ߩᄌ឵ߦ↪޿ࠆ‫ޕ‬g dm-3 ߆ࠄ mol dm-3 ߳ߩන૏ᄌ឵ߢߪ Weight ߢ㒰ߒ‫ޔ‬
mol dm-3 ߆ࠄ g dm-3 ߳ᄌ឵ߔࠆߣ߈ߦߪ Weight ࠍਸ਼ߕࠆ‫౉ޕ‬಴ജࡈࠔࠗ࡞ߢߩන
૏ࠍ g dm-3 ߢߪߥߊ mol dm-3 ߣߔࠆ႐วߪ 1.0 ߣߔࠆ‫ޕ‬

fXNO3

fCN

Valence㧦ㅊടቯ⟵ߔࠆൻቇ⒳߇⎣㉄ᩮỚᐲ xNO3 ߩ▚಴ߦነਈߔࠆߣߔࠆ߆ุ߆ߩ⸳ቯ ነਈߒߥ޿ߣߔࠆ႐ว

0 ነਈߔࠆߣߔࠆ႐ว

1㧦ㅊടቯ⟵ߔࠆൻቇ⒳߇⎣㉄ᩮỚᐲ CN ߩ▚಴ߦነਈߔࠆߣߔࠆ߆ุ߆ߩ⸳ቯ ነਈߒߥ޿ߣߔࠆ႐ว

0 ነਈߔࠆߣߔࠆ႐ว

1㧦ㅊടቯ⟵ߔࠆൻቇ⒳ߩ㔚⩄ᢙ㧔ᱜᢛᢙ㧕
fXNO3 = 1 ෶ߪ fCN = 1 ߣߒߚ႐ว‫ޔ‬xNO3 ෶ߪ CN ߦነਈߔࠆ⎣㉄ᩮỚᐲߩ▚಴ߦ↪޿ࠆ‫ޕ‬fXNO3, fCN ෸߮ Valence ߪ‫߇ࠩ࡯࡙ޔ‬ㅊടቯ⟵ߒߚൻቇ⒳߇‫߫߃଀ޔ‬㓁ࠗࠝࡦ Mn+ߢ޽ࠆߣ߈ߦ‫ޔ‬ಽ㈩Ყ⸘▚ᑼߦ⃻ࠇࠆ⎣㉄ᩮỚᐲ xNO3‫ޔ‬CN ߦኻߒߡỚᐲ߇ n[Mn+]ߩ⎣㉄ᩮࠍട߃ࠆᔅ
ⷐ߇޽ࠆ߆ߤ߁߆ࠍ⸳ቯߔࠆ߽ߩߢ޽ࠆ‫ޕ‬xNO3 ߣ CN ߪ‫ޔ‬ቯ⟵߇⇣ߥߞߡ޿ࠆ‫ޕ‬69ߚߛߒ‫ޔ‬fXNO3 = 1 ߩ႐ว‫㉄⎣ޔ‬ᩮỚᐲߩ▚಴߳ߩነਈߪ‫⚵ޔ‬ㄟߺಽ㈩Ყ⸘▚ᑼ㧔࠲ࠗࡊ d1 ,d2㧕ߦ⃻ࠇࠆ xNO3 ߦኻߒߡ⠨ᘦߐࠇࠆ৻ᣇߢ‫⚵ޔ‬ㄟߺ෻ᔕㅦᐲᑼ㧔࠲ࠗࡊ rx , ry㧕ߦ⃻ࠇࠆ xNO3
ߦኻߒߡ⠨ᘦߐࠇߥ޿‫ ߪࠇߎޕ‬fCN = 1 ߩ႐วߢ߽ห᭽ߢ޽ࠆ‫ޕ‬㧔⚵ㄟߺᑼߦଥࠆࡊࡠࠣ࡜ࡓ
ߩ᭴ㅧ਄ߩℂ↱ߦࠃࠆ‫ޕ‬㧕⚵ㄟߺ෻ᔕㅦᐲᑼߩ xNO3 , CN ߦኻߒߡ‫ޔ‬ㅊടቯ⟵ߒߚൻቇ⒳ߩỚᐲ [Mn+]ߩᓇ㗀߇෸߱ࠃ߁
ߦߔࠆߚ߼ߦߪ‫ޔ‬೨⸥ 8.4.2.1 ▵(5)ߦ߅޿ߡߘߩ⚵ㄟߺ෻ᔕㅦᐲᑼࠍ೥㒰ߔࠆ⸳ቯࠍߒߚ਄ߢ‫ޔ‬ᡷ߼ߡ⋡⊛ߣߔࠆ෻ᔕㅦᐲᑼࠍ 8.4.2.1 ▵(10)ߦ߅޿ߡࠗࡦ࠲ࡊ࡝࠲౉ജߔࠆᔅⷐ߇޽ࠆ‫ޕ‬㧔㧤㧕nwFrmnwFrm

㧦ㅊടቯ⟵ߔࠆ෻ᔕㅦᐲᑼߣಽ㈩Ყ⸘▚ᑼߩว⸘୘ᢙ㧔ᱜᢛᢙ㧕㧔㧥㧕begin3"begin3" 㧦ᢥሼ೉㧔੍⚂⺆㧕
nwFrm ߇ 1 એ਄ߩ႐วߦ‫ޔ‬DGIKP ߥࠆᢥሼ೉ࠍ౉ജࡈࠔࠗ࡞ߦ౉ࠇࠆ‫౉ޔߪࠇߎޕ‬ജⴕ 1ⴕࠍභ᦭ߔࠆ‫ޕ‬㧔㧝㧜㧕ㅊടቯ⟵ߔࠆ⸘▚ᑼߩ౉ജnwFrm ߇ 1 એ਄ߩߣ߈‫ޔ‬એਅࠍ➅ࠅ㄰ߒ‫ޔ‬nwFrm ୘ಽߩᑼࠍ⸥ㅀߔࠆ‫ޕ‬㧔㧝㧜㧚㧝㧕nCond,nCond

iFrmTyp㧦ㅊടቯ⟵ߔࠆ⸘▚ᑼߦ⃻ࠇࠆ᧦ઙᑼߩ୘ᢙ‫ޕ‬iFrmTyp 㧦ታ㛎ᑼߩ⒳㘃㧔d1,d2,rx,ry㧕‫ޕ‬d1 ဳߩ႐ว

0d2 ဳߩ႐ว

1rx ဳߩ႐ว

2ry ဳߩ႐ว

3㧔㧝㧜㧚㧞㧕ൻቇ෻ᔕᑼ㧔rx ဳ߹ߚߪ ry ဳߩߣ߈㧕౉ജᦠᑼߪ 8.3.3 ▵ࠍෳᾖߩߎߣ‫ޕ‬㧔㧝㧜㧚㧟㧕cond ㇱ᧦ઙᑼ㧔C1, C2, C3, ...㧕ࠍᔅⷐ୘ᢙ㧔nCond ୘㧕౉ജߔࠆ‫౉ޕ‬ജᦠᑼߪ 8.3.4 ▵ࠍෳᾖߩߎ
ߣ‫ޕ‬㧔㧝㧜㧚㧠㧕case ㇱ⸘▚ᑼ㧔case ࡉࡠ࠶ࠢ 1, 2, 3, ...㧕ࠍᔅⷐ୘ᢙ㧔nCond ୘㧕౉ജߔࠆ‫౉ޕ‬ജᦠᑼߪ 8.3.5 ▵ࠍෳᾖߩߎߣ‫ޕ‬70㧔㧝㧝㧕end3"end3" 㧦ᢥሼ೉㧔੍⚂⺆㧕
nwFrm ߇ 1 એ਄ߩ႐วߦ‫ޔ‬GPF"ߣ޿߁ᢥሼ೉ࠍ౉ജߔࠆ‫౉ޔߪࠇߎޕ‬ജⴕ 1 ⴕࠍභ᦭ߔࠆ‫ޕ‬㧔㧝㧞㧕ItMax,

eps,

DtMin,

nDtMax,

DtFac

ItMax

㧦࠾ࡘ࡯࠻ࡦᴺߩᦨᄢ➅ࠅ㄰ߒ࿁ᢙ㧔ᱜᢛᢙ㧕eps㧦෼᧤್ቯߦ↪޿ࠆ⋧ኻ⺋Ꮕ

DtMin

㧦࠲ࠗࡓࠬ࠹࠶ࡊ᏷ߩᦨዊ୯

[min]

nDtMax 㧦ᦨᄢ࠲ࠗࡓࠬ࠹࠶ࡊ᏷ߩ࠹࡯ࡉ࡞㧔ਅ⸥(13)㧕ߩ㐳ߐ㧔ᱜᢛᢙ㧕
DtFac㧦⸘▚ߩᚑุߦᔕߓߡ࠲ࠗࡓࠬ࠹࠶ࡊ᏷ࠍᄌേߐߖࠆߚ߼ߩଥᢙ
࠲ࠗࡓࠬ࠹࠶ࡊ᏷ߦਸ਼ߓࠆ‫ߪ޿ࠆ޽ޔ‬㒰ߔࠆߎߣߢࠬ࠹࠶ࡊ᏷ࠍᄌൻߐߖࠆ‫ޕ‬㧔㧝㧟㧕TIME,

DtMaxએਅࠍ➅ࠅ㄰ߒ‫ޔ‬nDtMax ⴕߩ࠹࡯ࡉ࡞ߣߔࠆ‫ဳ✢ߪ࡞ࡉ࡯࠹ߩߎޕ‬ౝᝌߒߡ૶ࠊࠇࠆ‫ޕ‬TIME㧦ᤨೞ [min]

DtMax

㧦ᤨೞ TIME ߦ߅޿ߡ⸵ߐࠇࠆᦨᄢ࠲ࠗࡓࠬ࠹࠶ࡊ᏷ [min]଀ ౉ജ㧔nDtMax = 4 ߩ႐ว㧕ߣ✢ᒻౝᝌߦࠃࠆ⸃㉼   6+/'  &V/CZ                                             

DtMax
0.1
0.01
0

10.0

30.0

50.0 Time㧔㧝㧠㧕iTran
iTran 㧦ㆊᷰ⸘▚෸߮ቯᏱ⸘▚ߩ➅㄰ߒ࿁ᢙ㧔ᱜᢛᢙ㧕ㆊᷰ⸘▚ߩߺߩߣ߈

1ㆊᷰ⸘▚ߩᓟ‫ޔ‬ቯᏱ⸘▚ߔࠆߣ߈2

ㆊᷰ ĺ ቯᏱ ĺ ㆊᷰ ߩߣ߈

3

ㆊᷰ ĺ ቯᏱ ĺ ㆊᷰ ĺ ቯᏱ ߩߣ߈

471㧔㧝㧡㧕fPrintX, fPrintR,

fPrintTએਅߩ 3 ⒳㘃ߩ಴ജࡈࠔࠗ࡞ߦߟ޿ߡ‫ޔ‬iTran ߢᜰቯߐࠇߚㆊᷰ⸘▚‫ޔ‬ቯᏱ⸘▚ߩ৻ㅪߩᵹࠇ
ߩਛߢ‫ߢߎߤޔ‬಴ജߐߖࠆ߆ࠍᜰቯߔࠆ‫ޕ‬Ԙ ਥⷐ಴ജ㧔X㧕㧦 ᄌᢙฬ‫ޔ‬න૏╬ߩ⺑᣿ߣߣ߽ߦ‫ޔ‬ᄙ⒳㘃ߩ㊂㧔Ớᐲ‫ࡃࠬࡑޔ‬࡜ࡦࠬ╬㧕ࠍ৻ߟߩࡈࠔࠗ࡞㧔ࡈࠔࠗ࡞ฬ㧦*.out 㧕ߦ಴ജߔࠆ‫ޕ‬ԙ ࡝ࠬ࠲࡯࠻಴ജ㧔R㧕㧦 ࡙࡯ࠩ߇ᜰቯߔࠆᤨೞߢߩỚᐲ╬ߩ㊂ࠍ಴ജߔࠆ‫ޕ‬ฦᤨೞߏߣߦ nRFile ୘ߩ಴ജࡈࠔࠗ࡞㧔ࡈࠔࠗ࡞ฬ㧦*.rst㧕߇↢ᚑߐࠇࠆ㧔ࡈࠔࠗ࡞ฬߪ⥄േ↢ᚑߐࠇࠆ㧕‫૶ߢ▚⸘࠻࡯࠲ࠬ࡝ޕ‬↪ߢ߈ࠆ‫ޕ‬Ԛ ⚻ᤨ಴ജ㧔T㧕㧦 ࡙࡯ࠩ߇ᜰቯߔࠆ․ቯߩࠦࡦࡐ࡯ࡀࡦ࠻‫ޔࡘࠪ࠶ࡔޔ‬ൻቇ⒳ߩỚᐲߩ⚻ᤨᄌൻࠍ಴ജߔࠆ㧔8.4.2.1 ▵(23)㨪(24)ෳᾖ㧕‫ޕ‬

fPrintX㧦ਥⷐ಴ജߩ಴ജ႐ᚲࠍ⴫ߔࡈ࡜ࠣ㧔ᢥሼ೉㧕

fPrintR㧦࡝ࠬ࠲࡯࠻಴ജߩ಴ജ႐ᚲࠍ⴫ߔࡈ࡜ࠣ㧔ᢥሼ೉㧕

fPrintT㧦⚻ᤨ಴ജߩ಴ജ႐ᚲࠍ⴫ߔࡈ࡜ࠣ㧔ᢥሼ೉㧕

fPrintX , fPrintR , fPrintT ߪ‫ޔ‬ฦ‫ޔޘ‬ᢙሼ '0' ෸߮ '1' ߆ࠄᚑࠆᢥሼ೉ߢ‫ޔ‬iTran એ਄ߩ㐳ߐࠍᜬߚߥߌࠇ߫ߥࠄߥ޿㧔૛ಽߩᢥሼߪήⷞߐࠇࠆ㧕‫ޕ‬0 ߪ⹥ᒰߔࠆ⸘▚ߦߟ޿ߡ⸘▚⚿ᨐࠍ಴ജߒߥ޿ߎߣࠍ‫ޔ‬1 ߪ⚿ᨐࠍ಴ജߔࠆߎߣࠍ␜ߔ‫ޕ‬଀ iTran = 3 ߩ႐วߣߘߩ⸃㉼   H2TKPV:    H2TKPV4  H2TKPV6 
ㆊᷰ⸘▚  ψቯᏱ⸘▚  ψ

ㆊᷰ⸘▚

಴ജߔࠆ

಴ജߒߥ޿

࡝ࠬ࠲࡯࠻಴ജ㧦಴ജߔࠆ

಴ജߔࠆ

಴ജߒߥ޿

⚻ᤨ಴ജ

಴ജߒߥ޿

಴ജߔࠆ

ਥⷐ಴ജ

㧔㧝㧢㧕Time1,㧦಴ജߒߥ޿
㧦಴ജߔࠆ
Dt1,

EndTim1

Time1

㧦1 ࿁⋡ߩㆊᷰ⸘▚ߩ㐿ᆎᤨೞ

[min]

Dt1

㧦1 ࿁⋡ߩㆊᷰ⸘▚ߩೋᦼ࠲ࠗࡓࠬ࠹࠶ࡊ᏷

[min]

EndTim1 㧦1 ࿁⋡ߩㆊᷰ⸘▚ߩ⚳ੌᤨೞ

[min]

72

㧔㧝㧣㧕Time2,

Dt2,

EndTim2

iTran ߇ 3 એ਄ߩߣ߈ߩߺ౉ജߔࠆ‫ޕ‬Time2

㧦2 ࿁⋡ߩㆊᷰ⸘▚ߩ㐿ᆎᤨೞ

[min]

Dt2

㧦2 ࿁⋡ߩㆊᷰ⸘▚ߩೋᦼ࠲ࠗࡓࠬ࠹࠶ࡊ᏷

[min]

EndTim2 㧦2 ࿁⋡ߩㆊᷰ⸘▚ߩ⚳ੌᤨೞ[min]㧔㧝㧤㧕iSoltFr
iSoltFr㧦ṁᶧਛߩൻቇ⒳Ớᐲߩ⴫⃻ߦߟ޿ߡ‫ޔ‬૕Ⓧࡕ࡞Ớᐲ㧔න૏૕Ⓧṁᶧਛߩṁ⾰ߩ‛
⾰㊂㧕[mol dm-3]߆ࠄ solute-free Ớᐲ㧔න૏૕Ⓧṁᇦਛߩṁ⾰ߩ‛⾰㊂‫ޔ‬ਛᕈၮḰỚᐲߣ߽޿߁‫ޕ‬㧕[mol dm-3]߳ߩᄌ឵ࠍⴕ߁߆ߤ߁߆ߩ⸳ቯ㧔ᱜᢛᢙ㧕ᄌ឵ࠍⴕࠊߥ޿ߣ߈

0ᄌ឵ࠍⴕ߁ߣ߈

1

Richardson ߦࠃࠆಽ㈩Ყࡕ࠺࡞㧔U(VI), Pu(IV)╬㧕ߪ‫▚⸘᧪ᧄޔ‬ᑼ߇ solute-free Ớᐲߢ⴫⃻ߐࠇߡ޿ࠆߎߣ߆ࠄ‫ޔ‬૕Ⓧࡕ࡞Ớᐲ߆ࠄ solute-free Ớᐲ⴫⃻ߦᄌ឵ߒߚ਄ߢಽ㈩⸘▚ࠍታⴕߔࠆߩ߇ᦸ߹ߒ޿ߣߐࠇߡ޿ࠆ‫ޔߪߢ⁁⃻ޕ‬Richardson ࡕ࠺࡞ߦട߃ߡ‫ޔ‬ᄙߊߩൻቇ⒳ߩಽ㈩Ყ
 ᑼࠍㅊടߒߡ޿ࠆ߇‫ߩࠄࠇߎޔ‬ㅊടᑼߪ Richardson ߩࠃ߁ߥ solute-free Ớᐲߩ⴫⃻ߦߥߞߡ߅ࠄߕ‫ޔ‬ᓥߞߡ solute-free ߣ૕Ⓧࡕ࡞Ớᐲ߇౒ሽߒߚ⁁ᘒߦߥߞߡ޿ࠆ‫ޕ‬㧔㧝㧥㧕iRstFlg
iRstFlg㧦ታⴕߒࠃ߁ߣߔࠆ⸘▚߇‫ߩ߆߁ߤ߆▚⸘࠻࡯࠲ࠬ࡝ޔ‬ᜰቯ㧔ᱜᢛᢙ㧕 ࡝ࠬ࠲࡯࠻⸘▚ߢߪߥ޿ߣ߈

0 ࡝ࠬ࠲࡯࠻⸘▚ߢ޽ࠆߣ߈

1

㧔㧞㧜㧕CRFILE
CRFILE 㧦࡝ࠬ࠲࡯࠻⸘▚ߩታⴕߦᔅⷐߥࠦࡦࡐ࡯ࡀࡦ࠻ౝߩỚᐲ୯╬ࠍ฽߻ࡈࠔࠗ࡞ฬ ਄⸥(19)ߦ߅޿ߡ iRstFlg = 1㧔࡝ࠬ࠲࡯࠻⸘▚ࠍታⴕߔࠆ㧕ߩߣ߈ߩߺ౉ജߔࠆ‫ޕ‬ᢥሼᢙߪ FILLEN એౝߣߔࠆ㧔FILLEN = 128㧕‫ޕ‬଀   K4UV(NI   %4(+.'          

VGUV6TUV਄⸥ߩ଀ߩ႐ว‫ޔ‬એ೨ߦ⸘▚ߒߡᓧߚ test01T1050.rst ߥࠆࡈࠔࠗ࡞ߦ޽ࠆỚᐲ࠺࡯࠲ࠍ⺒ߺㄟߺ‫ࠍࠇߘޔ‬ೋᦼỚᐲߣߒߡㆊᷰ⸘▚ࠍታⴕߔࠆ㧔2 ┨ෳᾖ㧕‫ޕ‬
CRFILE ߣߒߡ*.rst ࡈࠔࠗ࡞ࠍᜰቯߔࠆߎߣ߇ᄙ޿ߣᕁࠊࠇࠆ߇‫*ޔ‬.rst ߩਛりࠍ⷗ࠇ߫ಽ߆
ࠆߣ߅ࠅ‫࠻ࡦࡀ࡯ࡐࡦࠦޔ‬ᢙ‫ࡘࠪ࠶ࡔޔ‬ᢙ‫ޔ‬ൻቇ⒳ߩ⒳㘃ߪએ೨ߩ⸘▚ߣห৻ߢߥߌࠇ߫⺒ߺ

73ㄟ߻ߎߣ߇ߢ߈ߥ޿‫ޕ‬㧔㧞㧝㧕nRFilenRFile 㧦ᤨ♽೉಴ജߩ࿁ᢙ㧔ᱜᢛᢙ߹ߚߪ⽶ᢛᢙ㧕಴ജ㧔X, R, T㧕߳ߩ಴ജᤨೞߩ୘ᢙࠍ౉ജߔࠆ㧔nRFile ߪ 0 એ਄ߩᱜᢛᢙ㧕‫ ߢߎߎޕ‬nRFile߇⽶ᢛᢙߣߒߚ႐วߪ‫ޔ‬಴ജᤨೞߪ‫ᦨޔ‬ೋߩᤨೞ‫ᤨߩ⚳ᦨޔ‬ೞ෸߮಴ജᤨೞ㑆㓒ߩ 3 ߟߩ㊂ࠍ౉ജߔࠆߎߣߦࠃߞߡᜰቯߐࠇࠆ߽ߩߣߺߥߐࠇࠆ㧔ਅ⸥(22)ෳᾖ㧕‫ޕ‬㧔㧞㧞㧕RTIME
nRFile ߇ 0 એᄖߩߣ߈ߩߺએਅࠍ౉ജߔࠆ‫ޕ‬㧔㧞㧞㧚㧝㧕nRFile ߇ᱜᢛᢙߩ႐ว
಴ജᤨೞ[min]ࠍ nRFile ୘ਗߴࠆ‫ޕ‬㧔㧞㧞㧚㧞㧕nRFile ߇⽶ᢛᢙߩ႐ว
ᦨೋߩᤨೞ[min]‫ᤨߩ⚳ᦨޔ‬ೞ[min]‫ޔ‬಴ജᤨೞ㑆㓒[min]ߩ 3 ߟߩ㊂ࠍߎߩ㗅ߦ౉ജߔࠆ‫ޕ‬଀   P4(KNG   









   VKOG 
㧔㧞㧟㧕nTrnLbl
nTrnLbl 㧦⚻ᤨ಴ജࡈࠔࠗ࡞㧔*.trn ࡈࠔࠗ࡞㧕ߦ಴ജߐߖࠆ࠺࡯࠲ߩ⒳㘃ᢙ㧔ᱜᢛᢙ‫ޔ‬ਅ⸥(24)ෳᾖ㧕㧔㧞㧠㧕TRNLBL
nTrnLbl ߇ 1 એ਄ߩߣ߈‫ޔ‬એਅߩᦠᑼߩᢥሼ೉ ZTiijjjkk ࠍ nTrnLbl ୘ਗߴࠆ‫ߩߎޕ‬ᢥሼ೉ߪ‫ᤨ⚻ޔ‬಴ജࡈࠔࠗ࡞ߦ಴ജߐߖߚ޿࠺࡯࠲㧔ࡊࡠ࠮ࠬౝߢߩ૏⟎ߣൻቇ⒳ࠍᜰቯߔࠆ㧕ࠍ⴫ߒߡ߅ࠅ 9 ᢥሼ㧔Z㧔1 ᢥሼ㧕, T㧔1 ᢥሼ㧕, ii㧔2 ᢥሼ㧕, jjj㧔3 ᢥሼ㧕, kk㧔2 ᢥሼ㧕ࠍㅪធߒߚ
߽ߩ㧕߆ࠄߥࠆ‫ޕ‬
ZTiijjjkk
Z 㧦᳓⋧ߩ႐ว

:᦭ᯏ⋧ߩ႐ว

;

T 㧦ࡄ࡞ࠬࠞ࡜ࡓߩ႐ว

2ࡒࠠࠨ࠮࠻࡜ߩࡒࠠࠨߩ႐ว

/

ࡒࠠࠨ࠮࠻࡜ߩ࠮࠻࡜ߩ႐ว

5

74



᳓⋧࠲ࡦࠢߩ႐ว

#᦭ᯏ⋧࠲ࡦࠢߩ႐ว

1

ii 㧦ࠦࡦࡐ࡯ࡀࡦ࠻ ID

㧔2 ᩴߩᱜᢛᢙ㧕 㧔଀㧦, , , …㧕

jjj 㧦ࡔ࠶ࠪࡘ⇟ภ

㧔3 ᩴߩᱜᢛᢙ㧕 㧔଀㧦, , , …㧕

kk㧦ൻቇ⒳ߩㅢߒ⇟ภ

㧔2 ᩴߩᱜᢛᢙ㧕 㧔଀㧦, , …㧕ߎߎߢ⸒߁ൻቇ⒳ߩㅢߒ⇟ภߣߪ‫ޔ‬8.4.2.1 ▵(3) ߦ߅޿ߡ '1' ߦࠃߞߡᜰቯߒߚ nNFIX ୘ߩ
ൻቇ⒳ࠍൻቇ⒳ ID ߩ㗅ᐨߢਗߴߡ⇟ภࠍઃߒߚ߽ߩߢ޽ࠆ‫ޕ‬ൻቇ⒳ ID ߢߪߥ޿ߎߣߦᵈᗧ‫ޕ‬
8.4.2.1 ▵(3)ߩ଀ 2 ߩࠃ߁ߦ fSpe ࠍ⸳ቯߒߚ႐ว‫ޔ‬ฦൻቇ⒳ߣㅢߒ⇟ภߩኻᔕߪએਅߩࠃ߁ߦߥࠆ‫ ߚ߹ޕ‬8.4.2.1 ▵(6)㨪(7)ߦ߅޿ߡᣂߚߥൻቇ⒳ࠍㅊടߒߚ႐วߪ‫ޔ‬fSpe ߢᜰቯߒߚൻቇ
⒳ߩᓟߦ⛯ߌߡㅢߒ⇟ภ㧔nNFIX+1, nNFIX+2, ...㧕߇ઃߐࠇࠆ‫ޕ‬ㅢߒ⇟ภ 1

2

ൻቇ⒳U(VI) Pu(IV) Pu(III) U(IV) HAN HYD HNO2 HN3 DBP MBP H3PO4

H

3

4

5

6

7

8

9

10

11

12

଀ 㧔ࡄ࡞ࠬࠞ࡜ࡓ㧔ID = 30㧕ߩ╙ 5 ࡔ࠶ࠪࡘߩൻቇ⒳㧔ㅢߒ⇟ภ 01㨪04㧕ߩ᦭ᯏ⋧Ớᐲߩ⚻ᤨᄌൻ಴ജࠍ಴ജߔࠆ႐ว㧕   P6TP.DN    640.$.U ;2;2;2;2
㧔㧞㧡㧕Delta
Delta 㧦Ṷ▚ߩ቟ቯൻߩߚ߼ߦዉ౉ߒߚࡄ࡜ࡔ࡯࠲㧔3.1.1 ▵ෳᾖ㧕
ൻቇ⒳ߩỚᐲ߇‫ޔ‬0 ߆ࠄߩߎߩ᏷ߩ඙㑆ߢᒝ೙⊛ߦ┙ߜ਄ߍࠄࠇࠆ‫ޕ‬㧔㧞㧢㧕ck, dr,en ࡒࠠࠨ࠮࠻࡜㧔ࡒࠠࠨㇱ㧕ߢߩੑ⋧㑆ߩ⇇㕙Ⓧ⸘▚ߦ↪޿ࠆࡄ࡜ࡔ࡯࠲㧔3.2.4 ▵ෳᾖ㧕‫ޕ‬ck㧦ᑼో૕ߦដ߆ࠆࡈࠔࠢ࠲㧔ήᰴర㧕
 3.2.4 ▵ߦ߅ߌࠆ K ߦ⋧ᒰߔࠆ߽ߩ‫ޕ‬ᑼ(3.61)㨪(3.63)ࠍߘߩ߹߹↪޿ࠆߩߢ޽ࠇ߫ 100ߣߔࠆ‫ޕ‬dr㧦ᡬᜈ⠢ߩ⋥ᓘ[cm]

en㧦ᡬᜈ⠢ߩ࿁ォㅦᐲ[min-1]㧔㧞㧣㧕Frc,

PhiS

Frc 㧦᦭ᯏ⋧ਛߩ TBP ߩ૕Ⓧಽ₸[-]଀߃߫ 30 vol%ߢ޽ࠇ߫‫ޔ‬0.3 ߣߔࠆ‫ޕ‬
PhiS 㧦ࡒࠠࠨ࠮࠻࡜ߩ࠮࠻࡜ㇱߦ߅ߌࠆ᳓⋧ߩࡎ࡯࡞࠼ࠕ࠶ࡊ

75

[-]

㧔㧞㧤㧕NPREAC, INPEQ,NPDISTࡀࡊ࠷࠾࠙ࡓߩൻቇ෻ᔕ‫ޔ‬ಽ㈩ߦ㑐ߔࠆ⸳ቯࠍⴕ߁‫ޕ‬
NPREAC 㧦Np(V)ߩ࠙࡜࠽ࠬߦࠃࠆㆶర෻ᔕᑼ(5.26)ߦߟ޿ߡ෻ᔕㅦᐲᑼࠍㆬᛯߔࠆ‫ޕ‬

INPEQ

REACT ࡕ࠺࡞㧔ᑼ(5.27)㧕ߩ႐ว

0

Advanced-MIXSET ࡕ࠺࡞㧔ᑼ(5.28)㧕ߩ႐ว

1

㧦Np ߩਇဋൻ෻ᔕ㧔ᑼ(5.39), (5.41)㧕ߩ⠨ᘦߦߟ޿ߡㆬᛯ
⠨ᘦߔࠆ႐ว

1⠨ᘦߒߥ޿႐ว

1 એᄖߩ୯

NPDIST 㧦Np(IV)෸߮ Np(VI)ߩಽ㈩Ყߩ⸘▚ᑼߩㆬᛯ
ࡈ࡝࡯TBP ߩ 3 ਸ਼ߦᲧ଀ߔࠆᑼ㧔ᑼ(6.9),(6.12)㧕ߩ႐ว0

ࡈ࡝࡯TBP ߩ 2 ਸ਼ߦᲧ଀ߔࠆᑼ㧔ᑼ(6.10),(6.13)㧕ߩ႐ว

1

㧤㧚㧠㧚㧞㧚㧞 ࡈࠖ࡯࠼࠺࡯࠲
㧤㧚㧠㧚㧞㧚㧞㧚㧝 ࡈࠖ࡯࠼✚᜝࠺࡯࠲㧔㧝㧕nfa, nfo
nfa 㧦᳓⋧ࡈࠖ࡯࠼ߩ୘ᢙ㧔ᱜᢛᢙ㧕㧔8.4.2.2.2 ▵ߦ߅޿ߡ nfa ୘ಽߩ⸳ቯࠍⴕ߁㧕nfo 㧦᦭ᯏ⋧ࡈࠖ࡯࠼ߩ୘ᢙ㧔ᱜᢛᢙ㧕㧔8.4.2.2.3 ▵ߦ߅޿ߡ nfo ୘ಽߩ⸳ቯࠍⴕ߁㧕㧔㧞㧕TfdTfd 㧦ࡈࠖ࡯࠼ᶧ᷷ᐲ [͠]㧤㧚㧠㧚㧞㧚㧞㧚㧞 ᳓⋧ࡈࠖ࡯࠼࠹࡯ࡉ࡞ એਅߩ㧔㧝㧕㨪㧔㧡㧕ࠍ nfa ࿁➅ࠅ㄰ߔ‫ޕ‬
㧔㧝㧕nXfTabnXfTab 㧦એਅߦ␜ߔ᳓⋧Ớᐲࡈࠖ࡯࠼࠹࡯ࡉ࡞ߩ㐳ߐ㧔ᱜᢛᢙ㧕
㧔㧞㧕TIME,

X1,

X2, ...

 એਅࠍ➅ࠅ㄰ߒ‫ޔ‬nXfTab ⴕߩ࠹࡯ࡉ࡞ߣߔࠆ‫ޕ‬
TIME

㧦ᤨೞ

[min]

X1, X2, ... 㧦ฦൻቇ⒳ߩ᳓⋧ࡈࠖ࡯࠼ਛỚᐲ㧔nspe ୘ߩਗ߮㧕 [g dm-3]߹ߚߪ[mol dm-3]
  ߎߎߢ౉ജߔࠆൻቇ⒳ߩ߁ߜᦨೋߩ nNFIX ୘ߪਥⷐᚑಽ㧔8.4.2.1 ▵(3)㧕ߢ޽ࠅ‫ޔ‬ᱷࠅߩ
nspe-nNFIX ୘㧔nwspe ୘㧕ߪ࡙࡯ࠩ߇ㅊടߒߚᚑಽߢ޽ࠆ‫ޕ‬ਥⷐᚑಽߪൻቇ⒳ ID ߩ㗅⇟ߢਗߴࠆ‫ޕ‬Ớᐲන૏ߪ‫ޔ‬એਅߩㅢࠅ‫ޕ‬76

Ԙ ᳓⚛ࠗࠝࡦ‫ޔ‬HAN‫ޔࡦࠫ࡜࠼ࡅޔ‬੝⎣㉄‫ࠫࠕޔ‬ൻ᳓⚛‫ޔ‬
iso-, n-ࡉ࠴࡞ࠕ࡞࠺ࡅ࠼‫ޔ‬iso-, n-㈼㉄‫ޔ‬DBP‫ޔ‬MBP‫ޔ㉄ࡦ࡝ޔ‬㧦[mol dm-3]

FP‫ޔ‬ㆊ㉄ൻ᳓⚛
ԙ ࠙࡜ࡦ‫ޔࡓ࠙࠴ࡀࠢ࠹ޔࡓ࠙࠾ࠦ࡞ࠫޔࡓ࠙࠾࠻࡞ࡊޔ‬ࡀࡊ࠷࠾࠙ࡓ‫ࡓ࠙ࠫ࠽ࡃޔࡓ࠙࠾࠹࡞ޔࡓ࠙ࠪ࠮ޔ⚛࡛࠙ޔ‬㧦[g dm-3]

଀ ౉ജ㧔nXfTab =5, nspe = 9 ߩ႐ว㧕ߣ✢ᒻౝᝌߦࠃࠆ⸃㉼  #37'175(''& # 
   P:H6CD   VKOG*72W2W7*#0*;&*01*0  Gĸ ╙ 1 ⴕ
  Gĸ ╙ 2 ⴕ
  G  G  Gĸ ╙ nXfTab ⴕ䊐䉞䊷䊄ᶧਛ䈱
U(VI)䈱Ớᐲ[g dm-3]
250.0
200.0

50.0
0

100.0

300.0

500.0

5000.0Time

㧔㧟㧕nFfTabnFfTab㧦એਅߦ␜ߔ᳓⋧ᵹ㊂ࡈࠖ࡯࠼࠹࡯ࡉ࡞ߩ㐳ߐ㧔ᱜᢛᢙ㧕

㧔㧠㧕TIME,FFએਅࠍ➅ࠅ㄰ߒ‫ޔ‬nFfTab ⴕߩ࠹࡯ࡉ࡞ߣߔࠆ‫✢ޕ‬ᒻౝᝌߩ⠨߃ᣇߪ‫ޔ‬Ớᐲ࠹࡯ࡉ࡞ߣห᭽‫ޕ‬
TIME 㧦ᤨೞFF[min]㧦ࡈࠖ࡯࠼ᵹ㊂

㧔㧡㧕IFDSTA.cmp,[dm3 h-1]

IFDSTA.msh

IFDSTA.cmp 㧦ࡈࠖ࡯࠼వߩࠦࡦࡐ࡯ࡀࡦ࠻ ID
IFDSTA.msh 㧦ࡈࠖ࡯࠼వߩࡔ࠶ࠪࡘ⇟ภࡔ࠶ࠪࡘߩ਄ᵹ┵ߦᵈ౉ߐࠇࠆߣߒߡࡔ࠶ࠪࡘౝߩᵹ㊂ࠍ⸘▚ߔࠆ‫ޕ‬77㧤㧚㧠㧚㧞㧚㧞㧚㧟 ᦭ᯏ⋧ࡈࠖ࡯࠼࠹࡯ࡉ࡞ એਅߩ㧔㧝㧕㨪㧔㧡㧕ࠍ nfo ࿁➅ࠅ㄰ߔ‫ޕ‬
㧔㧝㧕nXfTabnXfTab 㧦એਅߦ␜ߔ᦭ᯏ⋧Ớᐲࡈࠖ࡯࠼࠹࡯ࡉ࡞ߩ㐳ߐ㧔ᱜᢛᢙ㧕
㧔㧞㧕TIME,

X1,

X2, ...

 એਅࠍ➅ࠅ㄰ߒ‫ޔ‬nXfTab ⴕߩ࠹࡯ࡉ࡞ߣߔࠆ‫ᦠޕ‬ᑼߪ᳓⋧ߣห᭽ߢ޽ࠆ‫✢ޕ‬ᒻౝᝌߩ⠨߃ᣇߪ‫ޔ‬Ớᐲ࠹࡯ࡉ࡞ߣห᭽‫ޕ‬
㧦ᤨೞ

TIME

[min]

X1, X2, .. 㧦ฦൻቇ⒳ߩ᦭ᯏ⋧ࡈࠖ࡯࠼ਛỚᐲ㧔nspe ୘ߩਗ߮㧕 [g dm-3] ߹ߚߪ [mol dm-3]
㧔㧟㧕nFfTab㧦એਅߦ␜ߔ᦭ᯏ⋧ᵹ㊂ࡈࠖ࡯࠼࠹࡯ࡉ࡞ߩ㐳ߐ㧔ᱜᢛᢙ㧕

nFfTab

㧔㧠㧕TIME,FFએਅࠍ➅ࠅ㄰ߒ nFfTab ⴕߩ࠹࡯ࡉ࡞ߣߔࠆ‫✢ޕ‬ᒻౝᝌߩ⠨߃ᣇߪ‫ޔ‬Ớᐲ࠹࡯ࡉ࡞ߣห᭽‫ޕ‬
TIME 㧦ᤨೞFF[min][dm3 h-1]㧦ࡈࠖ࡯࠼ᵹ㊂

㧔㧡㧕IFDSTO.cmp,

IFDSTO.msh

IFDSTO.cmp 㧦ࡈࠖ࡯࠼వߩࠦࡦࡐ࡯ࡀࡦ࠻ ID
IFDSTO.msh 㧦ࡈࠖ࡯࠼వߩࡔ࠶ࠪࡘ⇟ภࡔ࠶ࠪࡘߩ਄ᵹ┵ߦᵈ౉ߐࠇࠆߣߒߡࡔ࠶ࠪࡘౝߩᵹ㊂ࠍ⸘▚ߔࠆ‫ޕ‬㧤㧚㧠㧚㧞㧚㧟 ࠦࡦࡐ࡯ࡀࡦ࠻࠺࡯࠲
ฦࠦࡦࡐ࡯ࡀࡦ࠻㧔ncomp ୘㧕ߦߟ޿ߡ‫ޔ‬એਅߩ౉ജ୯ࠍ೉⸥ߔࠆ‫⸥ߡ޿ߟߦࡓ࡜ࠞࠬ࡞ࡄޕ‬ㅀߔࠆ႐วߦߪ 8.4.2.3.1 ෸߮ 8.4.2.3.2 ▵‫ߩ࡜࠻࠮ࠨࠠࡒޔ‬႐ว 8.4.2.3.1 ෸߮ 8.4.2.3.3 ▵‫ޔ‬᳓⋧࠲ࡦࠢߩ႐ว 8.4.2.3.1 ෸߮ 8.4.2.3.4‫᦭ޔ‬ᯏ⋧࠲ࡦࠢߩ႐ว 8.4.2.3.1 ෸߮ 8.4.2.3.5 ▵ߦ␜ߒߚ㗄⋡ࠍ౉ജߔࠆ‫ޕ‬㧤㧚㧠㧚㧞㧚㧟㧚㧝 ౒ㅢ࠺࡯࠲ߩ౉ജ㧔㧝㧕ID,ID

iType,

MSH,

idisp

㧦ࠦࡦࡐ࡯ࡀࡦ࠻ ID

78

TRNLBL ࠍᜰቯߔࠆ႐วߪ‫ޔ‬1㨪99 ߹ߢߩᱜᢛᢙ‫ޕ‬ㅪ⇟ߢ޽ࠆᔅⷐߪߥ޿‫ޕ‬iType 㧦ࠦࡦࡐ࡯ࡀࡦ࠻ߩ⒳㘃ࠍㆬᛯ㧔ᱜᢛᢙ㧕ࡄ࡞ࠬࠞ࡜ࡓ

0ࡒࠠࠨ࠮࠻࡜

1

᳓⋧࠲ࡦࠢ

2

᦭ᯏ⋧࠲ࡦࠢ

3

MSH 㧦ࠦࡦࡐ࡯ࡀࡦ࠻ࠍ඙ಾࠆࡔ࠶ࠪࡘᢙ
ࡄ࡞ࠬࠞ࡜ࡓߢߪ਄ਅಽ⋧࠲ࡦࠢࠍ฽߻ࡔ࠶ࠪࡘᢙࠍ‫ߪߢ࡜࠻࠮ࠨࠠࡒߚ߹ޔ‬Ბᢙࠍ⴫ߔ‫ޕ‬TRNLBL ࠍᜰቯߔࠆ႐วߪ‫ޔ‬1㨪999 ߹ߢߩᱜᢛᢙ‫ޕ‬᳓⋧෶ߪ᦭ᯏ⋧࠲ࡦࠢߩ႐วߦߪ౉ജߒߥ޿‫ޕ‬㧦ಽᢔ⋧ߩㆬᛯ ࠲ࡦࠢߩ႐วߦߪ౉ജߒߥ޿‫ޕ‬

idisp᳓⋧ಽᢔ㧔᦭ᯏ⋧ㅪ⛯㧕

0᦭ᯏ⋧ಽᢔ㧔᳓⋧ㅪ⛯㧕

1

㧔㧞㧕ICDSTA.cmp,

ICDSTA.mshࡄ࡞ࠬࠞ࡜ࡓ‫࡜࠻࠮ࠨࠠࡒޔ‬෶ߪ᳓⋧࠲ࡦࠢߩ႐วߦ౉ജߔࠆ‫᦭ޕ‬ᯏ⋧࠲ࡦࠢߢߪ౉ജߒߥ޿‫ޕ‬ICDSTA.cmp 㧦ࠦࡦࡐ࡯ࡀࡦ࠻ߩ᳓⋧ߩ಴ญ߇ធ⛯ߐࠇߡ޿ࠆవߩࠦࡦࡐ࡯ࡀࡦ࠻ ID
ߤߩࠦࡦࡐ࡯ࡀࡦ࠻ߦ߽ធ⛯ߐࠇߥ޿႐ว㧔♽ᄖߦᵹ಴ߔࠆ႐ว㧕ߪ 0‫ޕ‬
ICDSTA.msh 㧦ࠦࡦࡐ࡯ࡀࡦ࠻ߩ᳓⋧ߩ಴ญ߇ធ⛯ߐࠇߡ޿ࠆవߩࠦࡦࡐ࡯ࡀࡦ࠻ߩࡔ࠶ࠪࡘ⇟ภICDSTA.cmp ߇ 0 ߩ႐วߪ‫ޔ‬છᗧߩᢛᢙ୯‫ޕ‬㧔㧟㧕ICDSTO.cmp,

ICDSTO.mshࡄ࡞ࠬࠞ࡜ࡓ‫࡜࠻࠮ࠨࠠࡒޔ‬෶ߪ᳓⋧࠲ࡦࠢߩ႐วߦ౉ജߔࠆ‫ޕ‬᳓⋧࠲ࡦࠢߢߪ౉ജߒߥ޿‫ޕ‬ICDSTO.cmp 㧦ࠦࡦࡐ࡯ࡀࡦ࠻ߩ᦭ᯏ⋧ߩ಴ญ߇ធ⛯ߐࠇߡ޿ࠆవߩࠦࡦࡐ࡯ࡀࡦ࠻ ID
ߤߩࠦࡦࡐ࡯ࡀࡦ࠻ߦ߽ធ⛯ߐࠇߥ޿႐วߪ 0‫ޕ‬
ICDSTO.msh 㧦ࠦࡦࡐ࡯ࡀࡦ࠻ߩ᦭ᯏ⋧ߩ಴ญ߇ធ⛯ߐࠇߡ޿ࠆవߩࠦࡦࡐ࡯ࡀࡦ࠻ߩࡔ࠶ࠪࡘ⇟ภICDSTO.cmp ߇ 0 ߩ႐วߪ‫ޔ‬છᗧߩᢛᢙ୯‫ޕ‬
㧔㧠㧕T
T 㧦ࠦࡦࡐ࡯ࡀࡦ࠻ߩㆇォ᷷ᐲ [͠] ෻ᔕㅦᐲ߿ಽ㈩Ყ⸘▚ߦ↪޿ࠄࠇࠆ‫ޕ‬
㧔㧡㧕rxh, rxu6,

rxpu4

᳓⋧ߩ‛ᕈ୯ផ▚ߦᔅⷐߥ౉ജࠍ⸥ㅀߔࠆ‫࡜࠻࠮ࠨࠠࡒޔࡓ࡜ࠞࠬ࡞ࡄޕ‬෶ߪ᳓⋧࠲ࡦࠢߩ႐วߦ౉ജߔࠆ‫᦭ޕ‬ᯏ⋧࠲ࡦࠢߢߪ౉ജߒߥ޿‫ޕ‬rxh㧦᳓⋧ߩઍ⴫⎣㉄Ớᐲ[mol dm-3]

79㧦᳓⋧ߩઍ⴫ U(VI)Ớᐲ[g dm-3]

rxpu4 㧦᳓⋧ߩઍ⴫ Pu(IV)Ớᐲ[g dm-3]rxu6

㧔㧢㧕ryh, ryu6,

rypu4

᦭ᯏ⋧ߩ‛ᕈ୯ផ▚ߦᔅⷐߥ౉ജࠍ⸥ㅀߔࠆ‫࡜࠻࠮ࠨࠠࡒޔࡓ࡜ࠞࠬ࡞ࡄޕ‬෶ߪ᦭ᯏ⋧࠲ࡦࠢߩ႐วߦ౉ജߔࠆ‫ޕ‬᳓⋧࠲ࡦࠢߢߪ౉ജߒߥ޿‫ޕ‬ryh㧦᦭ᯏ⋧ߩઍ⴫⎣㉄Ớᐲ[mol dm-3]

ryu6

㧦᦭ᯏ⋧ߩઍ⴫ U(VI)Ớᐲ[g dm-3]

rypu4 㧦᦭ᯏ⋧ߩઍ⴫ Pu(IV)Ớᐲ[g dm-3]㧤㧚㧠㧚㧞㧚㧟㧚㧞 ࡄ࡞ࠬࠞ࡜ࡓߦ㑐ߔࠆ౉ജ㧔㧝㧕ara, alp,

amp,

freq,

h,

d0

ara 㧦ࡄ࡞ࠬࠞ࡜ࡓߩᢿ㕙Ⓧ[cm2]

alp 㧦⋡⋁᧼ free area ಽ₸㧔0 㨪 1.0 ߩ㑆ߩዊᢙ㧕[-]amp 㧦ࡄ࡞ࠬᝄ᏷ࠍ 2 ୚ߒߚ୯㧔ਔᝄ᏷㧕[cm]

freq 㧦ࡄ࡞ࠬᝄേᢙ

[min-1]㧦ࡊ࡟࡯࠻㑆㓒

[cm]

d0 㧦ࡊ࡟࡯࠻ߩⓣ⋥ᓘ

[cm]

h

㧔㧞㧕phi1, phi2
phi1 㧦ਅㇱಽ⋧࠲ࡦࠢߦ߅ߌࠆ᳓⋧ߩࡎ࡯࡞࠼ࠕ࠶ࡊ㧔0 㨪 1.0 ߩ㑆ߩዊᢙ㧕[ - ]phi2 㧦਄ㇱಽ⋧࠲ࡦࠢߦ߅ߌࠆ᳓⋧ߩࡎ࡯࡞࠼ࠕ࠶ࡊ㧔0 㨪 1.0 ߩ㑆ߩዊᢙ㧕[ - ]㧔㧟㧕sa1,sa2

sa1 㧦ਅㇱಽ⋧࠲ࡦࠢߦ߅ߌࠆන૏૕Ⓧᒰߚࠅߩ⇇㕙Ⓧ[cm-1]

sa2 㧦਄ㇱಽ⋧࠲ࡦࠢߦ߅ߌࠆන૏૕Ⓧᒰߚࠅߩ⇇㕙Ⓧ[cm-1]

㧔㧠㧕BETAB1,BETAB2, ...㧔nspe ୘ߩ୯ߩਗ߮㧕

BETAB1, BETAB2, ... 㧦ฦൻቇ⒳ߩਅㇱಽ⋧࠲ࡦࠢߦ߅ߌࠆ᦭ᯏ⋧ၮḰߩ✚᜝‛⾰⒖േଥᢙ
㧔㧡㧕BETAT1,[cm s-1]

BETAT2, ...㧔nspe ୘ߩ୯ߩਗ߮㧕

BETAT1, BETAT2, ...

㧦ฦൻቇ⒳ߩਅㇱಽ⋧࠲ࡦࠢߦ߅ߌࠆ᦭ᯏ⋧ၮḰߩ✚᜝‛⾰⒖േଥᢙ

[cm s-1]

㧔㧢㧕X1, X2, ...㧔nspe ୘ߩ୯ߩਗ߮㧕એਅࠍ➅ࠅ㄰ߒ‫ޔ‬MSH ⴕߩ࠹࡯ࡉ࡞ߣߔࠆ‫ޕ‬80

X1, X2, ... 㧦ฦൻቇ⒳ߩ᳓⋧ೋᦼỚᐲ[g dm-3] ෶ߪ [mol dm-3]

ൻቇ⒳ߩਗߴࠆ㗅ᐨߪ‫ޔ‬
8.4.2.2.2 ▵ߣห᭽ߢ޽ࠆ‫ޕ‬
8.4.2.1 ▵(19)ߦ߅޿ߡ iRstFlg = 1 ߩ႐วߪ‫ޔ‬(20)ߢᜰቯߐࠇࠆ CRFILE ߆ࠄೋᦼỚᐲ߇⺒ߺㄟ߹ࠇࠆߩߢ౉ജߒߥ޿‫ޕ‬
㧔㧣㧕Y1, Y2, ...㧔nspe ୘ߩ୯ߩਗ߮㧕એਅࠍ➅ࠅ㄰ߒ‫ޔ‬MSH ⴕߩ࠹࡯ࡉ࡞ߣߔࠆ‫ޕ‬Y1,

Y2, ... 㧦ฦൻቇ⒳ߩ᦭ᯏ⋧ೋᦼỚᐲ[g dm-3] ෶ߪ [mol dm-3]

ൻቇ⒳ߩਗߴࠆ㗅ᐨߪ‫ޔ‬
8.4.2.2.2 ▵ߣห᭽ߢ޽ࠆ‫ޕ‬
8.4.2.1 ▵(19)ߦ߅޿ߡ iRstFlg = 1 ߩ႐วߪ‫ޔ‬(20) ߢᜰቯߐࠇࠆ CRFILE ߆ࠄೋᦼỚᐲ߇⺒ߺㄟ߹ࠇࠆߩߢ౉ജߒߥ޿‫ޕ‬㧔㧤㧕VB, VT
VB 㧦ਅㇱಽ⋧࠲ࡦࠢߩኈⓍ[dm3]

VT 㧦਄ㇱಽ⋧࠲ࡦࠢߩኈⓍ[dm3]

㧔㧥㧕DZ1,

DZ2, ...㧔MSH-2 ୘ߩ୯ߩਗ߮㧕

DZ1, DZ2, ... 㧦਄ਅಽ⋧࠲ࡦࠢࠍ㒰޿ߚㇱಽ㧔ࠪࡖࡈ࠻ㇱ㧕ࠍ㋦⋥ᣇะߦࡔ࠶ࠪࡘಽഀ
ߒߚߣ߈ߩฦࡔ࠶ࠪࡘߩ᏷㧔㜞ߐ㧕

[cm]㧤㧚㧠㧚㧞㧚㧟㧚㧟 ࡒࠠࠨ࠮࠻࡜ߦ㑐ߔࠆ౉ജ
㧔㧝㧕XM1,

XM2, ...㧔nspe ୘ߩ୯ߩਗ߮㧕એਅࠍ➅ࠅ㄰ߒ‫ޔ‬MSH ⴕߩ࠹࡯ࡉ࡞ߣߔࠆ‫ޕ‬
XM1, XM2, ... 㧦ࡒࠠࠨㇱߩฦൻቇ⒳ߩ᳓⋧ೋᦼỚᐲ[g dm-3] ෶ߪ [mol dm-3]

ൻቇ⒳ߩਗߴࠆ㗅ᐨߪ‫ޔ‬
8.4.2.2.2 ▵ߣห᭽ߢ޽ࠆ‫ޕ‬
8.4.2.1 ▵(19)ߦ߅޿ߡ iRstFlg = 1 ߩ႐วߪ‫ޔ‬(20) ߢᜰቯߐࠇࠆ CRFILE ߆ࠄೋᦼỚᐲ߇⺒ߺㄟ߹ࠇࠆߩߢ౉ജߒߥ޿‫ޕ‬
㧔㧞㧕XS1, XS2, ...㧔nspe ୘ߩ୯ߩਗ߮㧕એਅࠍ➅ࠅ㄰ߒ‫ޔ‬MSH ⴕߩ࠹࡯ࡉ࡞ߣߔࠆ‫ޕ‬XS1,

XS2, ... 㧦࠮࠻࡜ㇱߩฦൻቇ⒳ߩ᳓⋧ೋᦼỚᐲ[g dm-3] ෶ߪ [mol dm-3]

ൻቇ⒳ߩਗߴࠆ㗅ᐨߪ‫ޔ‬
8.4.2.2.2 ▵ߣห᭽ߢ޽ࠆ‫ޕ‬
8.4.2.1 ▵(19)ߦ߅޿ߡ iRstFlg = 1 ߩ႐วߪ‫ޔ‬(20) ߢᜰቯߐࠇࠆ CRFILE ߆ࠄೋᦼỚᐲ߇⺒ߺㄟ߹ࠇࠆߩߢ౉ജߒߥ޿‫ޕ‬
㧔㧟㧕YM1,

YM2, ...㧔nspe ୘ߩ୯ߩਗ߮㧕એਅࠍ➅ࠅ㄰ߒ‫ޔ‬MSH ⴕߩ࠹࡯ࡉ࡞ߣߔࠆ‫ޕ‬81

YM1, YM2, ... 㧦ࡒࠠࠨㇱߩฦൻቇ⒳ߩ᳓⋧ೋᦼỚᐲ[g dm-3] ෶ߪ [mol dm-3]

ൻቇ⒳ߩਗߴࠆ㗅ᐨߪ‫ޔ‬
8.4.2.2.2 ▵ߣห᭽ߢ޽ࠆ‫ޕ‬
8.4.2.1 ▵(19)ߦ߅޿ߡ iRstFlg = 1 ߩ႐วߪ‫ޔ‬(20) ߢᜰቯߐࠇࠆ CRFILE ߆ࠄೋᦼỚᐲ߇⺒ߺㄟ߹ࠇࠆߩߢ౉ജߒߥ޿‫ޕ‬
㧔㧠㧕YS1, YS2, ...㧔nspe ୘ߩ୯ߩਗ߮㧕એਅࠍ➅ࠅ㄰ߒ‫ޔ‬MSH ⴕߩ࠹࡯ࡉ࡞ߣߔࠆ‫ޕ‬YS1,

YS2, ... 㧦࠮࠻࡜ㇱߩฦൻቇ⒳ߩ᳓⋧ೋᦼỚᐲ[g dm-3] ෶ߪ [mol dm-3]

ൻቇ⒳ߩਗߴࠆ㗅ᐨߪ‫ޔ‬
8.4.2.2.2 ▵ߣห᭽ߢ޽ࠆ‫ޕ‬
8.4.2.1 ▵(19)ߦ߅޿ߡ iRstFlg = 1 ߩ႐วߪ‫ޔ‬(20) ߢᜰቯߐࠇࠆ CRFILE ߆ࠄೋᦼỚᐲ߇⺒ߺㄟ߹ࠇࠆߩߢ౉ജߒߥ޿‫ޕ‬
㧔㧡㧕V11,
V11,

V12, ... 㧦ฦᲑߩࡒࠠࠨㇱߩኈⓍ

㧔㧢㧕V21,
V21,

[dm3]

V22, ...㧔MSH ୘ߩ୯ߩਗ߮㧕

V22, ... 㧦ฦᲑߩ࠮࠻࡜ㇱߩኈⓍ

㧔㧣㧕FR1,
FR1,

V12, ...㧔MSH ୘ߩ୯ߩਗ߮㧕[dm3]

FR2, ...㧔MSH ୘ߩ୯ߩਗ߮㧕

FR2, ...㧦ฦᲑߩ࡝ࠨࠗࠢ࡞ᵹ㊂[dm3 h-1]㧔㧤㧕phi1
phi1㧦ࡒࠠࠨㇱߩ᳓⋧ߩࡎ࡯࡞࠼ࠕ࠶ࡊ㧔0 㨪 1.0 ߩ㑆ߩዊᢙ㧕[ - ]㧤㧚㧠㧚㧞㧚㧟㧚㧠 ᳓⋧࠲ࡦࠢߦ㑐ߔࠆ౉ജ
㧔㧝㧕X1, X2, ...㧔nspe ୘ߩ୯ߩਗ߮㧕
X1, X2, ... 㧦ฦൻቇ⒳ߩ᳓⋧ೋᦼỚᐲ[g dm-3] ෶ߪ [mol dm-3]

ൻቇ⒳ߩਗߴࠆ㗅ᐨߪ‫ޔ‬
8.4.2.2.2 ▵ߣห᭽ߢ޽ࠆ‫ޕ‬
8.4.2.1 ▵(19)ߦ߅޿ߡ iRstFlg = 1 ߩ႐วߪ‫ޔ‬(20) ߢᜰቯߐࠇࠆ CRFILE ߆ࠄೋᦼỚᐲ߇⺒ߺㄟ߹ࠇࠆߩߢ౉ജߒߥ޿‫ޕ‬㧔㧞㧕V1V1 㧦᳓⋧࠲ࡦࠢߩኈⓍ[dm3]

㧤㧚㧠㧚㧞㧚㧟㧚㧡 ᦭ᯏ⋧࠲ࡦࠢߦ㑐ߔࠆ౉ജ82

㧔㧝㧕Y1, Y2, ... 㧔nspe ୘ߩ୯ߩਗ߮㧕
Y1, Y2, ... 㧦ฦൻቇ⒳ߩ᦭ᯏ⋧ೋᦼỚᐲ[g dm-3] ෶ߪ [mol dm-3]

ൻቇ⒳ߩਗߴࠆ㗅ᐨߪ‫ޔ‬
8.4.2.2.2 ▵ߣห᭽ߢ޽ࠆ‫ޕ‬
8.4.2.1 ▵(19)ߦ߅޿ߡ iRstFlg = 1 ߩ႐วߪ‫ޔ‬(20) ߢᜰቯߐࠇࠆ CRFILE ߆ࠄೋᦼỚᐲ߇⺒ߺㄟ߹ࠇࠆߩߢ౉ജߒߥ޿‫ޕ‬㧔㧞㧕V1V1 㧦᦭ᯏ⋧࠲ࡦࠢߩኈⓍ

[dm3]

83

⴫㧤㧚㧝 ࠗࡦ࠲ࡊ࡝࠲౉ജߢߩฦൻቇ⒳ߩ⴫⸥ᴺ

ࠗࡦ࠲ࡊ࡝࠲
౉ജߢߩ⴫⸥ᴺ

PARC ߦ߅ߌࠆ⸃㉼㧔ඨⷺ⧷ᢙሼߢ⴫⸥㧕*
7 8+ 
2W +8 2W +++ 
7 +8 
*#0
*;&
*01
<T
6E
0R +8 0R 8 
0R 8+ *0
K%*%*1
P%*%*1
K%*%11*
P%*%11*+%U
4W +++ 
8 +8 
8 8 
&$2
/$2
21
(2
*1
*1
01

H+
᳓⚛ࠗࠝࡦ
2+
UO2
࠙࡜ࡦ 6 ଔPu4+ࡊ࡞࠻࠾࠙ࡓ 4 ଔ
3+Puࡊ࡞࠻࠾࠙ࡓ 3 ଔ
U4+
࠙࡜ࡦ 4 ଔ+NH3OH
ࡅ࠼ࡠࠠࠪ࡞ࠕࡒࡦ
N2H5+
ࡅ࠼࡜ࠫࡦ
HNO2
੝⎣㉄
Zr
ࠫ࡞ࠦ࠾࠙ࡓ
Tc
࠹ࠢࡀ࠴࠙ࡓ
Np4+
ࡀࡊ࠷࠾࠙ࡓ 4 ଔ+
NpO2ࡀࡊ࠷࠾࠙ࡓ 5 ଔ
NpO22+
ࡀࡊ࠷࠾࠙ࡓ 6 ଔ
HN3
ࠕࠫൻ᳓⚛
iso-C3H7CHO
iso-ࡉ࠴࡞ࠕ࡞࠺ࡅ࠼
n-C3H7CHO
n-ࡉ࠴࡞ࠕ࡞࠺ࡅ࠼
iso-C3H7COOH iso-㈼㉄n-C3H7COOH
n-㈼㉄
I
࡛࠙⚛
Cs
࠮ࠪ࠙ࡓ
3+
Ru
࡞࠹࠾࠙ࡓ 3 ଔ
V4+ࡃ࠽ࠫ࠙ࡓ 4 ଔ
5+Vࡃ࠽ࠫ࠙ࡓ 5 ଔ
DBP࡝ࡦ㉄ࠫࡉ࠴࡞
MBP
࡝ࡦ㉄ࡕࡁࡉ࠴࡞
H3PO4
࡝ࡦ㉄
FP
ᩭಽⵚ↢ᚑ‛㧔ᵈ 1㧕
H2O2
ㆊ㉄ൻ᳓⚛
H2O
᳓㧔ᵈ 2㧕
NO3⎣㉄ࠗࠝࡦ㧔ᵈ 2㧕

xNO3 ߳ߩ
ነਈ

CN ߳ߩ
ነਈ

᦭㧦٤
ή㧦

᦭㧦٤
ή㧦

٤
٤
٤
٤
٤





٤
٤
٤















㧙
㧙

٤
٤
٤
٤
٤
٤
٤



٤
٤
٤















㧙
㧙

㧔ᵈ 1㧕ᣢߦ⚵ߺㄟ߹ࠇߡ޿ࠆࡕ࠺࡞ߢߪ‫ޔ‬FP㧔ᩭಽⵚ↢ᚑ‛㧕ࠍ߭ߣߟߩర⚛ߣห╬ߦᛒ޿‫ޔ‬ಽ㈩Ყࠍቯ⟵ߒߡ޿ࠆ㧔6 ┨ෳᾖ㧕‫ޕ‬㧔ᵈ 2㧕H2O ෸߮ NO3- ߪ‫౉࠲࡝ࡊ࠲ࡦࠗޔ‬ജߪฃߌઃߌࠆ߇‫ߚߒ┙⁛ޔ‬ൻቇ⒳ߣߒߡߩỚᐲ⸘▚ߪⴕࠊߥ޿‫ޕ‬84㧔a㧕౉ജࡈࠔࠗ࡞ߩ᭴ㅧ

ࠠ࡯ࡢ࡯࠼࠺࡯࠲

㧚

૏⟎࠺࡯࠲

⚳┵
㧔ࡇ࡝ࠝ࠼ “ . ”㧕૏⟎࠺࡯࠲ࠠ࡯ࡢ࡯࠼࠺࡯࠲

㧔b㧕ࠠ࡯ࡢ࡯࠼࠺࡯࠲ߩ᭴ㅧ

begin1end1ᢥ;㧔c㧕ᢥߩ᭴ㅧ

ᄌᢙฬ=

㧔RX0101╬ߩᄌᢙฬ㧕ቯᢙ
㧔0.1 ╬ߩቯᢙ㧕㧔d㧕૏⟎࠺࡯࠲ߩ᭴ㅧ

begin2ᵹ㊂‫ޔ‬Ớᐲ‫ޔ‬૕Ⓧ╬ߩ⸳ቯ୯࿑㧤㧚㧝 PARC ౉ജ࠺࡯࠲ߩ᭴ᢥࠣ࡜ࡈ

85

end2

4

other

5

other

‘/’
‘/’

0

1

‘/’
‘*’

2

other

ߘߩઁߩᢥሼ

err

ࠛ࡜࡯

…

…

⁁ᘒ

…

ฃℂ⁁ᘒ

3

‘*’

other
ᡷⴕ

other …

‘*’

error

ᡷⴕ

error

ߎߩ᦭㒢ࠝ࡯࠻ࡑ࠻ࡦߪ‫̌ޔ‬//̍߇౉ജߐࠇࠆߣ⁁ᘒ4
ߦㆫ⒖ߒฃℂߔࠆ㧔ࠛ࡜࡯ߦߥࠄߥ޿㧕‫ޕ‬߹ߚ‫“ޔ‬/* 㧔ᢥሼ೉㧕 */”߇౉ജߐࠇࠆߣ‫⁁ޔ‬ᘒ5ߦㆫ
⒖ߒฃℂߔࠆ‫”ޕ‬/*”෸߮”*/”ߩ㑆ߦᡷⴕ߇౉ࠆߣࠛ࡜࡯ߣ
ߥࠆ‫ޕ‬࿑㧤㧚㧞 ౉ജࡈࠔࠗ࡞ਛߩࠦࡔࡦ࠻ࠍ⹺⼂ߔࠆ᳿ቯᕈ᦭㒢ࠝ࡯࠻ࡑ࠻ࡦ

D

integer
2
E
D

8

P

1

S
E

4

D

5

real
D

D

P
D

3

E

7
D

6
real
D

D …
S …
P …
E …
1

‘0’, ‘1’, ‘2’ , .... ‘9’ ߩᢥሼ (digit)
ᱜ⽶ࠍ␜ߔ’+’, ‘-’ߩᢥሼ (sign)ዊᢙὐ (point)ᜰᢙㇱࠍ⴫ߔ’E’, ‘e’ߩᢥሼ㧔’D’ߪਇน㧕…

⁁ᘒਛߩᢙሼߪ⁁ᘒ⇟ภ

…

ฃℂ⁁ᘒ

ฃℂ⁁ᘒ2ߦ⥋ߞߚ႐วߪᢛᢙဳߣߒߡฃℂߔࠆ‫ޕ‬
ฃℂ⁁ᘒ4߹ߚߪ6ߦ⥋ߞߚ႐วߪታᢙဳߣߒߡฃℂߔࠆ‫ޕ‬ᦨᓟ߹ߢฃℂ⁁ᘒߦ೔㆐ߢ߈ߥ߆ߞߚ႐วߪࠛ࡜࡯ߣߥࠆ‫ޕ‬࿑㧤㧚㧟 ᢛᢙဳߣታᢙဳࠍ⼂೎ߔࠆ᳿ቯᕈ᦭㒢ࠝ࡯࠻ࡑ࠻ࡦ

㧥 ಴ജࡈࠔࠗ࡞ߩᦠᑼ
ᧄ┨ߢߪ‫ޔ‬PARC ࠍታⴕߒߚ㓙ߦ↢ᚑߔࠆࡈࠔࠗ࡞ߦߟ޿ߡ⺑᣿ߔࠆ‫ࠠ࠹ߪ࡞ࠗࠔࡈߩߡోޕ‬ࠬ࠻ᒻᑼߢ޽ࠆ‫ޕ‬㧥㧚㧝 ਥⷐ಴ജ㧔".out" ࡈࠔࠗ࡞㧕
PARC ࠍታⴕߔࠆߣ‫࡞ࠗࠔࡈޔ‬ฬߩ᜛ᒛሶ߇ ".out" ߢ޽ࠆਥⷐ಴ജࡈࠔࠗ࡞㧔࠹ࠠࠬ࠻ࡈࠔࠗ
࡞㧕߇৻ߟ↢ᚑߐࠇࠆ‫ޕ‬એਅߩౝኈ߇㗅ߦ಴ജߐࠇࠆ‫ߢ " "ޕ‬࿐߹ࠇߚㇱಽߪ‫ޔ‬ᢥሼ೉ࠍ␜ߔ‫ޕ‬㧥㧚㧝㧚㧝 ౉ജ࠺࡯࠲ߩࠛࠦ࡯ࡃ࠶ࠢ
౉ജ࠺࡯࠲ߩోⴕࠍ಴ജߔࠆ‫ޕ‬㧥㧚㧝㧚㧞 ࡄ࡞ࠬࠞ࡜ࡓߦ㑐ߔࠆ಴ജ ฦࡄ࡞ࠬࠞ࡜ࡓߦߟ޿ߡએਅߩࠃ߁ߦ‫ࠩ࡯࡙ޔ‬ᜰቯߩ࠲ࠗࡒࡦࠣ㧔8.4.2.1 ▵(15)ෳᾖ㧕ߢ಴ജߔࠆ‫ޕ‬ ̪Ớᐲ߇ PRINTMIN㧔PRINTMIN = 10-100㧕ࠃࠅዊߐ޿႐วߪ 0 ߣߒߡ⴫␜ߔࠆ‫ޕ‬
㧔㧝㧕Title
Title

㧦⸘▚࠲ࠗ࠻࡞

㧔㧞㧕Time,dt, nStep,

Iter

Time 㧦ᤨೞdt㧦࠲ࠗࡓࠬ࠹࠶ࡊࠨࠗ࠭

nStep 㧦⸘▚ࠬ࠹࠶ࡊᢙ
Iter㧦ࠗ࠲࡟࡯࡚ࠪࡦ࿁ᢙ

㧔㧟㧕 ID,
ID

TYPE,

idisp

㧦ࠦࡦࡐ࡯ࡀࡦ࠻ ID

TYPE 㧦ࠦࡦࡐ࡯ࡀࡦ࠻࠲ࠗࡊ
idisp㧦ಽᢔ⋧ࠍ␜ߔࡈ࡜ࠣ㧔0㧦᳓⋧ಽᢔ‫ޔ‬1㧦᦭ᯏ⋧ಽᢔ㧕㧔㧠㧕rhoa, rhoorhoa 㧦᳓⋧ኒᐲ

㧔3.4.1 ▵ෳᾖ㧕rhoo 㧦᦭ᯏ⋧ኒᐲ

㧔3.4.1 ▵ෳᾖ㧕88㧔㧡㧕mua,muomua 㧦᳓⋧☼ᕈ₸

㧔3.4.2 ▵ෳᾖ㧕

muo 㧦᦭ᯏ⋧☼ᕈ₸

㧔3.4.2 ▵ෳᾖ㧕㧔㧢㧕sigsig 㧦⇇㕙ᒛജ

㧔3.4.3 ▵ෳᾖ㧕㧔㧣㧕2WNUGF%QNWOP%QPEGPVTCVKQPU #SWGQWU 
㧔㧤㧕OGUJX ൻቇ⒳ฬ

01 Ớᐲන૏

:016H%QP/5C
 OQNN  OQNN   Ớᐲන૏ߩ⴫⸥ߪ‫ޔ‬ൻቇ⒳ߦࠃߞߡ OQNN ෶ߪ IN ߩ޿ߕࠇ߆߇ㆬᛯߐࠇࠆ‫ޕ‬㧔㧥㧕j+1, Xn,

xno3, Tf,

ConFcaฦࡔ࠶ࠪࡘ㧔ࡔ࠶ࠪࡘᢙ nmsh㧕ߦߟ޿ߡએਅࠍ಴ജߔࠆ‫ޕ‬
j+1㧦ࡔ࠶ࠪࡘ⇟ภ㧔1 㨪 nmsh ߹ߢߩᢛᢙ㧕Xn㧦ฦൻቇ⒳ߩ᳓⋧Ớᐲ㧔ൻቇ⒳ᢙ nspe㧕

xno3 㧦⎣㉄ᩮỚᐲ㧦ࡈ࡝࡯TBP Ớᐲ

Tf

ConFca㧦૕Ⓧࡕ࡞Ớᐲ߆ࠄ Solute-free Ớᐲ߳ߩᄌ឵ଥᢙ
㧔㧝㧜㧕2WNUGF%QNWOP%QPEGPVTCVKQPU 1TICPKE 
㧔㧝㧝㧕OGUJY ൻቇ⒳ฬ  01 Ớᐲන૏  OQNN  OQNN   Ớᐲන૏ߩ⴫⸥ߪ‫ޔ‬ൻቇ⒳ߦࠃߞߡ OQNN ෶ߪ IN ߩ޿ߕࠇ߆߇ㆬᛯߐࠇࠆ‫ޕ‬㧔㧝㧞㧕j+1,

Xnฦࡔ࠶ࠪࡘ㧔ࡔ࠶ࠪࡘᢙ nmsh㧕ߦߟ޿ߡએਅࠍ಴ജߔࠆ‫ޕ‬
j+1 㧦ࡔ࠶ࠪࡘ⇟ภ㧔1㨪nmsh ߹ߢߩᢛᢙ㧕Xn 㧦ฦൻቇ⒳ߩ᦭ᯏ⋧Ớᐲ㧔ൻቇ⒳ᢙ nspe㧕㧔㧝㧟㧕&KUVTKDWVKQP%QGHHKEKGPVU 2WNUGF%QNWOP 
㧔㧝㧠㧕OGUJ 

D ൻቇ⒳ฬ

01  89㧔㧝㧡㧕j+1,

Dis ฦࡔ࠶ࠪࡘ㧔ࡔ࠶ࠪࡘᢙ nmsh㧕ߦߟ޿ߡએਅࠍ಴ജߔࠆ‫ޕ‬
j+1 㧦ࡔ࠶ࠪࡘ⇟ภ㧔1㨪nmsh ߹ߢߩᢛᢙ㧕Dis 㧦ฦൻቇ⒳ߩಽ㈩Ყ [-]㧔㧝㧢㧕/CUU6TCPUHGT%QGHHKEKGPVU 2WNUGF%QNWOP 
㧔㧝㧣㧕OGUJBT ൻቇ⒳ฬ

01 EOU 㧔㧝㧤㧕j+1,

Beta’sฦࡔ࠶ࠪࡘ㧔ࡔ࠶ࠪࡘᢙ nmsh㧕ߦߟ޿ߡએਅࠍ಴ജߔࠆ‫ޕ‬
j+1 㧦ࡔ࠶ࠪࡘ⇟ภ㧔1㨪nmsh ߹ߢߩᢛᢙ㧕
Beta 㧦ฦൻቇ⒳ߩ✚᜝‛⾰⒖േଥᢙ㧔3.1.5 ▵ߦ߅ߌࠆǪ‫ޔ‬ൻቇ⒳ᢙ nspe㧕㧔㧝㧥㧕1VJGTU 2WNUGF%QNWOP 
㧔㧞㧜㧕OGUJ&+85#2JK#2JK1'#'1(#(1  0101 O      OU  OU  NJ  NJ 㧔㧞㧝㧕j+1, hd+1,

SA,

Phi,

1-Phi,

EA,

EO,

FA,

FO

ฦࡔ࠶ࠪࡘ㧔ࡔ࠶ࠪࡘᢙ nmsh㧕ߦߟ޿ߡએਅࠍ಴ജߔࠆ‫ޕ‬
j+1㧦ࡔ࠶ࠪࡘ⇟ภ㧔1㨪nmsh ߹ߢߩᢛᢙ㧕

hd+1 㧦࠺ࠖࡧ࡚ࠖࠫࡦ⇟ภ㧔ᢛᢙ㧕
SA

㧦න૏૕Ⓧᒰߚࠅߩ⇇㕙Ⓧ

㧔3.1.5 ▵ෳᾖ㧕Phi㧦᳓⋧ࡎ࡯࡞࠼ࠕ࠶ࡊ

㧔3.1.6 ▵ෳᾖ㧕

1-Phi 㧦᦭ᯏ⋧ࡎ࡯࡞࠼ࠕ࠶ࡊ

㧔3.1.6 ▵ෳᾖ㧕

EA㧦᳓⋧ߩㅒᷙวଥᢙ

㧔3.1.4 ▵ෳᾖ㧕EO㧦᦭ᯏ⋧ߩㅒᷙวଥᢙ

㧔3.1.4 ▵ෳᾖ㧕FA

㧦᳓⋧ߩᵹ㊂FO㧦᦭ᯏ⋧ߩᵹ㊂㧔㧞㧞㧕8CNWGUHQT/CUU$CNCPEG 2WNUGF%QNWOP 
㧔㧞㧟㧕+VGO ൻቇ⒳ฬ 1WVIQ      㧔න૏㧕Ớᐲන૏ߩ⴫⸥ߪ‫ޔ‬ൻቇ⒳ߦࠃߞߡ OQNN ෶ߪ IN ߩ޿ߕࠇ߆߇ㆬᛯߐࠇࠆ‫ޕ‬90㧔㧞㧠㧕6QVCN(F MssFlwFd's  

MssFlwFd 㧦ㅪ⚿ߐࠇߚࠪࠬ࠹ࡓ㧔ోࠦࡦࡐ࡯ࡀࡦ࠻㧕߳ߩන૏ᤨ㑆ᒰߚࠅࡈࠖ࡯࠼㊂㧔᳓⋧㧗᦭ᯏ⋧㧕ߩ๺‫ޕ‬㧔ൻቇ⒳ᢙ nspe㧕㧔㧞㧡㧕5WO+P

MSSFLWSRC   

MSSFLWSRC㧦ࠦࡦࡐ࡯ࡀࡦ࠻߳ߩන૏ᤨ㑆ᒰߚࠅࡈࠖ࡯࠼㊂㧔᳓⋧㧗᦭ᯏ⋧㧕ߩ๺㧔ઁࠦࡦࡐ࡯ࡀࡦ࠻߆ࠄߩᵹ౉㧗ࠪࠬ࠹ࡓᄖㇱ߆ࠄߩࡈࠖ࡯࠼㧕‫ޕ‬㧔ൻቇ⒳ᢙ nspe㧕㧔㧞㧢㧕1WV#MSSOUTAOUTGOMSSOUTA 㧦ߘߩࠦࡦࡐ࡯ࡀࡦ࠻߆ࠄ಴ߡⴕߊ᳓⋧ᵹ㊂㧔ൻቇ⒳ᢙ nspe㧕
OUTGO

㧦ઁߩࠦࡦࡐ࡯ࡀࡦ࠻ߦᵹ౉ߖߕ‫ࠄ߆ࡓ࠹ࠬࠪޔ‬ᵹ಴ߔࠆ႐ว 176‫ޔ‬ઁߩࠦࡦࡐ࡯ࡀࡦ࠻ߦᵹ౉ߔࠆߣ߈   㧔㧞㧣㧕1WV1MSSOUTOOUTGOMSSOUTO 㧦ߘߩࠦࡦࡐ࡯ࡀࡦ࠻߆ࠄ಴ߡⴕߊ᦭ᯏ⋧ᵹ㊂㧔ൻቇ⒳ᢙ nspe㧕
OUTGO

㧦ઁߩࠦࡦࡐ࡯ࡀࡦ࠻ߦᵹ౉ߖߕ‫ࠄ߆ࡓ࠹ࠬࠪޔ‬ᵹ಴ߔࠆ႐ว176‫ޔ‬ઁߩࠦࡦࡐ࡯ࡀࡦ࠻ߦᵹ౉ߔࠆߣ߈   㧔㧞㧤㧕+VGO ൻቇ⒳ฬ 1WVIQ      㧔㧞㧥㧕1WV4CV# MSSRATIOAOUTGOMSSRATIOA 㧦MSSOUTA ߣ MssFlwFd ߩᲧ㧔= MSSOUTA / MssFlwFd㧕㧔ൻቇ⒳ᢙ nspe㧕
OUTGO

㧦ઁߩࠦࡦࡐ࡯ࡀࡦ࠻ߦᵹ౉ߖߕ‫ࠄ߆ࡓ࠹ࠬࠪޔ‬ᵹ಴ߔࠆ႐ว 176‫ޔ‬ઁߩࠦࡦࡐ࡯ࡀࡦ࠻ߦᵹ౉ߔࠆߣ߈   㧔㧟㧜㧕1WV4CV1 MSSRATIOOOUTGOMSSRATIOO 㧦MSSOUTO ߣ MssFlwFd ߩᲧ㧔= MSSOUTO / MssFlwFd㧕㧔ൻቇ⒳ᢙ nspe㧕
OUTGO

㧦ઁߩࠦࡦࡐ࡯ࡀࡦ࠻ߦᵹ౉ߖߕ‫ࠄ߆ࡓ࠹ࠬࠪޔ‬ᵹ಴ߔࠆ႐ว 176‫ޔ‬ઁߩࠦࡦࡐ࡯ࡀࡦ࠻ߦᵹ౉ߔࠆߣ߈   㧔㧟㧝㧕+VGO ൻቇ⒳ฬ
 

㧔න૏㧕

 Ớᐲන૏ߩ⴫⸥ߪ‫ޔ‬ൻቇ⒳ߦࠃߞߡ OQNN ෶ߪ IN ߩ޿ߕࠇ߆߇ㆬᛯߐࠇࠆ‫ޕ‬㧔㧟㧞㧕/CUU+PX MSSINVMSSINV 㧦ࡑࠬࠗࡦࡌࡦ࠻࡝

91㧥㧚㧝㧚㧟 ࡒࠠࠨ࠮࠻࡜ߦ㑐ߔࠆ಴ജฦࡒࠠࠨ࠮࠻࡜ߦߟ޿ߡએਅߩࠃ߁ߦ‫ࠩ࡯࡙ޔ‬ᜰቯߩ࠲ࠗࡒࡦࠣ㧔8.4.2.1 ▵(15)ෳᾖ㧕ߢ಴ജߔࠆ‫ޕ‬ ̪Ớᐲ߇ PRINTMIN㧔PRINTMIN = 10-100㧕ࠃࠅዊߐ޿႐วߪ 0 ߣߒߡ⴫␜ߔࠆ‫ޕ‬
㧔㧝㧕Title
Title

㧦⸘▚࠲ࠗ࠻࡞

㧔㧞㧕Time,dt, nStep,

Iter

Time 㧦ᤨೞ㧦࠲ࠗࡓࠬ࠹࠶ࡊࠨࠗ࠭

dt

nStep 㧦⸘▚ࠬ࠹࠶ࡊᢙ
Iter㧦ࠗ࠲࡟࡯࡚ࠪࡦ࿁ᢙ㧔㧟㧕ID, TYPE,
ID

idisp

㧦ࠦࡦࡐ࡯ࡀࡦ࠻ ID

TYPE 㧦ࠦࡦࡐ࡯ࡀࡦ࠻࠲ࠗࡊ
idisp㧦ಽᢔ⋧ࠍ␜ߔࡈ࡜ࠣ㧔0㧦᳓⋧ಽᢔ‫ޔ‬1㧦᦭ᯏ⋧ಽᢔ㧕㧔㧠㧕rhoa, rhoorhoa 㧦᳓⋧ኒᐲ

㧔3.4.1 ▵ෳᾖ㧕rhoo 㧦᦭ᯏ⋧ኒᐲ

㧔3.4.1 ▵ෳᾖ㧕㧔㧡㧕mua,muo

mua 㧦᳓⋧☼ᕈ₸

㧔3.4.2 ▵ෳᾖ㧕

muo 㧦᦭ᯏ⋧☼ᕈ₸

㧔3.4.2 ▵ෳᾖ㧕㧔㧢㧕sig, PhiSsig 㧦⇇㕙ᒛജ

㧔3.4.3 ▵ෳᾖ㧕

PhiS 㧦ฦࡒࠠࠨ࠮࠻࡜ߩ࠮࠻࡜ㇱߩ᳓⋧ࡎ࡯࡞࠼ࠕ࠶ࡊ
㧔㧣㧕/KZGT%QPEGPVTCVKQPU #SWGQWU 
㧔㧤㧕OGUJX ൻቇ⒳ฬ

:016H%QP/5C 01 Ớᐲන૏㧔ᵈ 㧕  OQNN  OQNN   Ớᐲන૏ߩ⴫⸥ߪ‫ޔ‬ൻቇ⒳ߦࠃߞߡ OQNN ෶ߪ IN ߩ޿ߕࠇ߆߇ㆬᛯߐࠇࠆ‫ޕ‬92

㧔㧥㧕j+1, Xn,

xno3, Tf,

ConFcaฦᲑ㧔Ბᢙ nmsh㧕ߦߟ޿ߡએਅࠍ಴ജߔࠆ‫ޕ‬j+1㧦Ბ⇟ภ㧔1㨪nmsh ߹ߢߩᢛᢙ㧕Xn㧦ࡒࠠࠨㇱߢߩฦൻቇ⒳ߩ᳓⋧Ớᐲ㧔ൻቇ⒳ᢙ nspe㧕

xno3 㧦⎣㉄ᩮỚᐲTf㧦ࡈ࡝࡯TBP Ớᐲ

ConFca㧦૕Ⓧࡕ࡞Ớᐲ߆ࠄ Solute-free Ớᐲ߳ߩᄌ឵ଥᢙ
㧔㧝㧜㧕5GVVNGT%QPEGPVTCVKQPU #SWGQWU 
㧔㧝㧝㧕OGUJ  01

X ൻቇ⒳ฬ :01Ớᐲන૏ OQNN 

Ớᐲන૏ߩ⴫⸥ߪ‫ޔ‬ൻቇ⒳ߦࠃߞߡ OQNN ෶ߪ IN ߩ޿ߕࠇ߆߇ㆬᛯߐࠇࠆ‫ޕ‬㧔㧝㧞㧕j+1,

Xn, xno3

ฦᲑ㧔Ბᢙ nmsh㧕ߦߟ޿ߡએਅࠍ಴ജߔࠆ‫ޕ‬
j+1 㧦Ბ⇟ภXn 㧦࠮࠻࡜ㇱߢߩฦൻቇ⒳ߩ᳓⋧Ớᐲ㧔ൻቇ⒳ᢙ nspe㧕
xno3㧦⎣㉄ᩮỚᐲ㧔㧝㧟㧕/KZGT%QPEGPVTCVKQPU 1TICPKE 
㧔㧝㧠㧕OGUJY ൻቇ⒳ฬ  01 Ớᐲන૏Ớᐲන૏ߩ⴫⸥ߪ‫ޔ‬ൻቇ⒳ߦࠃߞߡ OQNN ෶ߪ IN ߩ޿ߕࠇ߆߇ㆬᛯߐࠇࠆ‫ޕ‬㧔㧝㧡㧕j+1,XnฦᲑ㧔Ბᢙ nmsh㧕ߦߟ޿ߡએਅࠍ಴ജߔࠆ‫ޕ‬
j+1 㧦Ბ⇟ภXn 㧦ࡒࠠࠨㇱߢߩฦൻቇ⒳ߩ᦭ᯏ⋧Ớᐲ㧔ൻቇ⒳ᢙ nspe㧕㧔㧝㧢㧕5GVVNGT%QPEGPVTCVKQP 1TICPKE 
㧔㧝㧣㧕OGUJY ൻቇ⒳ฬ  01 Ớᐲන૏Ớᐲන૏ߩ⴫⸥ߪ‫ޔ‬ൻቇ⒳ߦࠃߞߡ OQNN ෶ߪ IN ߩ޿ߕࠇ߆߇ㆬᛯߐࠇࠆ‫ޕ‬93㧔㧝㧤㧕j+1,

XnฦᲑ㧔Ბᢙ nmsh㧕ߦߟ޿ߡએਅࠍ಴ജߔࠆ‫ޕ‬
j+1 㧦Ბ⇟ภXn 㧦࠮࠻࡜ㇱߢߩฦൻቇ⒳ߩ᦭ᯏ⋧Ớᐲ㧔ൻቇ⒳ᢙ nspe㧕㧔㧝㧥㧕&KUVTKDWVKQP%QGHHKEKGPVU /KZGT 
㧔㧞㧜㧕OGUJ 

D ൻቇ⒳ฬ

01  㧔㧞㧝㧕j+1,DisฦᲑ㧔Ბᢙ nmsh㧕ߦߟ޿ߡએਅࠍ಴ജߔࠆ‫ޕ‬
j+1 㧦Ბ⇟ภDis 㧦ฦൻቇ⒳ߩಽ㈩Ყ
㧔㧞㧞㧕/CUU6TCPUHGT%QGHHKEKGPVU /KZGT 
㧔㧞㧟㧕OGUJBT ൻቇ⒳ฬ  01 EOU 㧔㧞㧠㧕j+1,

Beta’sฦᲑ㧔Ბᢙ nmsh㧕ߦߟ޿ߡએਅࠍ಴ജߔࠆ‫ޕ‬j+1㧦Ბ⇟ภ㧔1㨪nmsh ߹ߢߩᢛᢙ㧕Beta㧦ࡒࠠࠨㇱߢߩฦൻቇ⒳ߩ✚᜝‛⾰⒖േଥᢙ㧔3.1.5 ▵ߦ߅ߌࠆǪ‫ޔ‬ൻቇ⒳ᢙ nspe㧕㧔㧞㧡㧕1VJGTU /KZGT 
㧔㧞㧢㧕OGUJ&+85#2JK#2JK1(#(1 0101 O      NJ  NJ 㧔㧞㧣㧕j+1, hd+1,

SA,

Phi, 1-Phi,

FA, FOฦᲑ㧔Ბᢙ nmsh㧕ߦߟ޿ߡએਅࠍ಴ജߔࠆ‫ޕ‬j+1㧦Ბ⇟ภ㧔1㨪nmsh ߹ߢߩᢛᢙ㧕

hd+1 㧦࠺ࠖࡧ࡚ࠖࠫࡦ⇟ภ㧔ᢛᢙ㧕
SA

㧦න૏૕Ⓧᒰߚࠅߩ⇇㕙Ⓧ

㧔3.2.4 ▵ෳᾖ㧕Phi㧦᳓⋧ࡎ࡯࡞࠼ࠕ࠶ࡊ

㧔3.2.4 ▵ෳᾖ㧕

1-Phi 㧦᦭ᯏ⋧ߩࡎ࡯࡞࠼ࠕ࠶ࡊ

㧔3.2.4 ▵ෳᾖ㧕FA

㧦᳓⋧ߩᵹ㊂94

FO㧦᦭ᯏ⋧ߩᵹ㊂㧔㧞㧤㧕8CNWGUHQT/CUU$CNCPEG /KZGT5GVVNGT 
㧔㧞㧥㧕+VGO ൻቇ⒳ฬ

1WVIQ㧔න૏㧕Ớᐲන૏ߩ⴫⸥ߪ‫ޔ‬ൻቇ⒳ߦࠃߞߡ OQNN ෶ߪ IN ߩ޿ߕࠇ߆߇ㆬᛯߐࠇࠆ‫ޕ‬㧔㧟㧜㧕6QVCN(F MssFlwFd  

MssFlwFd 㧦ㅪ⚿ߐࠇߚࠪࠬ࠹ࡓ㧔ోࠦࡦࡐ࡯ࡀࡦ࠻㧕߳ߩන૏ᤨ㑆ᒰߚࠅࡈࠖ࡯࠼㊂㧔᳓⋧㧗᦭ᯏ⋧㧕ߩ๺‫ޕ‬㧔ൻቇ⒳ᢙ nspe㧕㧔㧟㧝㧕5WO+P

MSSFLWSRC   

MSSFLWSRC㧦ߘߩࠦࡦࡐ࡯ࡀࡦ࠻߳ߩන૏ᤨ㑆ᒰߚࠅࡈࠖ࡯࠼㊂㧔᳓⋧㧗᦭ᯏ⋧㧕ߩ๺㧔ઁࠦࡦࡐ࡯ࡀࡦ࠻߆ࠄߩᵹ౉㧗ࠪࠬ࠹ࡓᄖㇱ߆ࠄߩࡈࠖ࡯࠼㧕‫ޕ‬㧔ൻቇ⒳ᢙ nspe㧕㧔㧟㧞㧕1WV#MSSOUTAOUTGOMSSOUTA 㧦ߘߩࠦࡦࡐ࡯ࡀࡦ࠻߆ࠄ಴ߡⴕߊ᳓⋧ᵹ㊂㧔ൻቇ⒳ᢙ nspe㧕
OUTGO

㧦ઁߩࠦࡦࡐ࡯ࡀࡦ࠻ߦᵹ౉ߖߕ‫ࠄ߆ࡓ࠹ࠬࠪޔ‬ᵹ಴ߔࠆ႐ว 176‫ޔ‬ઁߩࠦࡦࡐ࡯ࡀࡦ࠻ߦᵹ౉ߔࠆߣ߈   㧔㧟㧟㧕1WV1MSSOUTO’s

OUTGOMSSOUTO 㧦ߘߩࠦࡦࡐ࡯ࡀࡦ࠻߆ࠄ಴ߡⴕߊ᦭ᯏ⋧ᵹ㊂㧔ൻቇ⒳ᢙ nspe㧕
OUTGO

㧦ઁߩࠦࡦࡐ࡯ࡀࡦ࠻ߦᵹ౉ߖߕ‫ࠄ߆ࡓ࠹ࠬࠪޔ‬ᵹ಴ߔࠆ႐ว 176‫ޔ‬ઁߩࠦࡦࡐ࡯ࡀࡦ࠻ߦᵹ౉ߔࠆߣ߈   㧔㧟㧠㧕+VGO ൻቇ⒳ฬ 1WVIQ  
㧔㧟㧡㧕1WV4CV# MSSRATIOAOUTGOMSSRATIOA 㧦MSSOUTA ߣ MssFlwFd ߩᲧ㧔= MSSOUTA / MssFlwFd㧕㧔ൻቇ⒳ᢙ nspe㧕
OUTGO

㧦ઁߩࠦࡦࡐ࡯ࡀࡦ࠻ߦᵹ౉ߖߕ‫ࠄ߆ࡓ࠹ࠬࠪޔ‬ᵹ಴ߔࠆ႐ว 176‫ޔ‬ઁߩࠦࡦࡐ࡯ࡀࡦ࠻ߦᵹ౉ߔࠆߣ߈   㧔㧟㧢㧕1WV4CV1 MSSRATIOOOUTGOMSSRATIOO 㧦MSSOUTO ߣ MssFlwFd ߩᲧ㧔= MSSOUTO / MssFlwFd㧕㧔ൻቇ⒳ᢙ nspe㧕
OUTGO

㧦ઁߩࠦࡦࡐ࡯ࡀࡦ࠻ߦᵹ౉ߖߕ‫ࠄ߆ࡓ࠹ࠬࠪޔ‬ᵹ಴ߔࠆ႐ว 176‫ޔ‬

95ઁߩࠦࡦࡐ࡯ࡀࡦ࠻ߦᵹ౉ߔࠆߣ߈   㧔㧟㧣㧕+VGO ൻቇ⒳ฬ
 

㧔න૏㧕

Ớᐲන૏ߩ⴫⸥ߪ‫ޔ‬ൻቇ⒳ߦࠃߞߡ OQNN ෶ߪ IN ߩ޿ߕࠇ߆߇ㆬᛯߐࠇࠆ‫ޕ‬㧔㧟㧤㧕/CUU+PX MSSINVMSSINV 㧦ࡑࠬࠗࡦࡌࡦ࠻࡝

㧥㧚㧝㧚㧠 ᳓⋧࠲ࡦࠢߦ㑐ߔࠆ಴ജฦ᳓⋧࠲ࡦࠢߦߟ޿ߡએਅߩࠃ߁ߦ‫ࠩ࡯࡙ޔ‬ᜰቯߩ࠲ࠗࡒࡦࠣ㧔8.4.2.1 ▵(15)ෳᾖ㧕ߢ಴ജߔࠆ‫ޕ‬ ̪Ớᐲ߇ PRINTMIN㧔PRINTMIN = 10-100㧕ࠃࠅዊߐ޿႐วߪ 0 ߣߒߡ⴫␜ߔࠆ‫ޕ‬
㧔㧝㧕Title
Title

㧦⸘▚࠲ࠗ࠻࡞

㧔㧞㧕Time,dt, nStep,

Iter

Time 㧦ᤨೞ㧦࠲ࠗࡓࠬ࠹࠶ࡊࠨࠗ࠭

dt

nStep 㧦⸘▚ࠬ࠹࠶ࡊᢙ
Iter㧦ࠗ࠲࡟࡯࡚ࠪࡦ࿁ᢙ㧔㧟㧕ID, TYPE
ID㧦ࠦࡦࡐ࡯ࡀࡦ࠻ ID

TYPE 㧦ࠦࡦࡐ࡯ࡀࡦ࠻࠲ࠗࡊ
㧔㧠㧕rhoa
rhoa

㧦᳓⋧ኒᐲ

㧔3.4.1 ▵ෳᾖ㧕㧔㧡㧕muamua㧦᳓⋧☼ᕈ₸

㧔3.4.2 ▵ෳᾖ㧕㧔㧢㧕#SWGQWU6CPM%QPEGPVTCVKQP"㧔㧣㧕OGUJX ൻቇ⒳ฬ

 01 Ớᐲන૏

:01 OQNN 

Ớᐲන૏ߩ⴫⸥ߪ‫ޔ‬ൻቇ⒳ߦࠃߞߡ OQNN ෶ߪ IN ߩ޿ߕࠇ߆߇ㆬᛯߐࠇࠆ‫ޕ‬96

㧔㧤㧕j+1, Xn,

xno3

j+1 㧦ࡔ࠶ࠪࡘ⇟ภ 㧔= 1㧕
Xn 㧦ฦൻቇ⒳ߩ᳓⋧Ớᐲ㧔ൻቇ⒳ᢙ nspe㧕
xno3㧦⎣㉄ᩮỚᐲ㧔㧥㧕1VJGTU #SWGQWU6CPM 
㧔㧝㧜㧕OGUJ&+8(#  0101  NJ 㧔㧝㧝㧕j+1, hd+1,
j+1

FA㧦ࡔ࠶ࠪࡘ⇟ภ 㧔= 1㧕

hd+1 㧦࠺ࠖࡧ࡚ࠖࠫࡦ⇟ภ㧔ᢛᢙ㧕
FA

㧦᳓⋧ߩᵹ㊂㧔㧝㧞㧕8CNWGUHQT/CUU$CNCPEG #SWGQWU6CPM 
㧔㧝㧟㧕+VGO ൻቇ⒳ฬ 1WVIQ
 

㧔න૏㧕

Ớᐲන૏ߩ⴫⸥ߪ‫ޔ‬ൻቇ⒳ߦࠃߞߡ OQNN ෶ߪ IN ߩ޿ߕࠇ߆߇ㆬᛯߐࠇࠆ‫ޕ‬㧔㧝㧠㧕6QVCN(F MssFlwFd's  

MssFlwFd 㧦ㅪ⚿ߐࠇߚࠪࠬ࠹ࡓ㧔ోࠦࡦࡐ࡯ࡀࡦ࠻㧕߳ߩන૏ᤨ㑆ᒰߚࠅࡈࠖ࡯࠼㊂㧔᳓⋧㧗᦭ᯏ⋧㧕ߩ๺㧔ൻቇ⒳ᢙ nspe㧕㧔㧝㧡㧕5WO+P

MSSFLWSRC   

MSSFLWSRC㧦ߘߩࠦࡦࡐ࡯ࡀࡦ࠻߳ߩන૏ᤨ㑆ᒰߚࠅࡈࠖ࡯࠼㊂㧔᳓⋧㧗᦭ᯏ⋧㧕ߩ๺㧔ઁࠦࡦࡐ࡯ࡀࡦ࠻߆ࠄߩᵹ౉㧗ࠪࠬ࠹ࡓᄖㇱ߆ࠄߩࡈࠖ࡯࠼㧕‫ޕ‬㧔ൻቇ⒳ᢙ nspe㧕㧔㧝㧢㧕1WV#MSSOUTAOUTGOMSSOUTA 㧦ߘߩࠦࡦࡐ࡯ࡀࡦ࠻߆ࠄ಴ߡⴕߊ᳓⋧ᵹ㊂‫ޕ‬㧔ൻቇ⒳ᢙ nspe㧕
OUTGO

㧦ઁߩࠦࡦࡐ࡯ࡀࡦ࠻ߦᵹ౉ߖߕ‫ࠄ߆ࡓ࠹ࠬࠪޔ‬ᵹ಴ߔࠆ႐ว 176‫ޔ‬ઁߩࠦࡦࡐ࡯ࡀࡦ࠻ߦᵹ౉ߔࠆߣ߈   㧔㧝㧣㧕1WV1MSSOUTOOUTGOMSSOUTO 㧦ߘߩࠦࡦࡐ࡯ࡀࡦ࠻߆ࠄ಴ߡⴕߊ᦭ᯏ⋧ᵹ㊂‫ޕ‬㧔ൻቇ⒳ᢙ nspe㧕

97

OUTGO㧦ઁߩࠦࡦࡐ࡯ࡀࡦ࠻ߦᵹ౉ߖߕ‫ࠄ߆ࡓ࠹ࠬࠪޔ‬ᵹ಴ߔࠆ႐ว 176‫ޔ‬ઁߩࠦࡦࡐ࡯ࡀࡦ࠻ߦᵹ౉ߔࠆߣ߈   㧔㧝㧤㧕+VGO ൻቇ⒳ฬ 1WVIQ  
㧔㧝㧥㧕1WV4CV# MSSRATIOA'sOUTGOMSSRATIOA 㧦MSSOUTA ߣ MssFlwFd ߩᲧ㧔= MSSOUTA / MssFlwFd㧕㧔ൻቇ⒳ᢙ nspe㧕㧦ઁߩࠦࡦࡐ࡯ࡀࡦ࠻ߦᵹ౉ߖߕ‫ࠄ߆ࡓ࠹ࠬࠪޔ‬ᵹ಴ߔࠆ႐ว 176‫ޔ‬

OUTGO

ઁߩࠦࡦࡐ࡯ࡀࡦ࠻ߦᵹ౉ߔࠆߣ߈   㧔㧞㧜㧕1WV4CV1 MSSRATIOOOUTGOMSSRATIOO 㧦MSSOUTO ߣ MssFlwFd ߩᲧ㧔= MSSOUTO / MssFlwFd㧕㧔ൻቇ⒳ᢙ nspe㧕
OUTGO

㧦ઁߩࠦࡦࡐ࡯ࡀࡦ࠻ߦᵹ౉ߖߕ‫ࠄ߆ࡓ࠹ࠬࠪޔ‬ᵹ಴ߔࠆ႐ว 176‫ޔ‬ઁߩࠦࡦࡐ࡯ࡀࡦ࠻ߦᵹ౉ߔࠆߣ߈   㧔㧞㧝㧕+VGO ൻቇ⒳ฬ
 

㧔න૏㧕

Ớᐲන૏ߩ⴫⸥ߪ‫ޔ‬ൻቇ⒳ߦࠃߞߡ OQNN ෶ߪ IN ߩ޿ߕࠇ߆߇ㆬᛯߐࠇࠆ‫ޕ‬㧔㧞㧞㧕/CUU+PX MSSINVMSSINV 㧦ࡑࠬࠗࡦࡌࡦ࠻࡝

㧥㧚㧝㧚㧡 ᦭ᯏ⋧࠲ࡦࠢߦ㑐ߔࠆ಴ജฦ᦭ᯏ⋧࠲ࡦࠢߦߟ޿ߡએਅߩࠃ߁ߦ‫ࠩ࡯࡙ޔ‬ᜰቯߩ࠲ࠗࡒࡦࠣ㧔8.4.2.1 ▵(15)ෳᾖ㧕ߢ಴ജߔࠆ‫ޕ‬ ̪Ớᐲ߇ PRINTMIN㧔PRINTMIN = 10-100㧕ࠃࠅዊߐ޿႐วߪ 0 ߣߒߡ⴫␜ߔࠆ‫ޕ‬
㧔㧝㧕Title
Title

㧦⸘▚࠲ࠗ࠻࡞

㧔㧞㧕Time,dt, nStep,

Iter

Time 㧦ᤨೞdt㧦࠲ࠗࡓࠬ࠹࠶ࡊࠨࠗ࠭

nStep 㧦⸘▚ࠬ࠹࠶ࡊᢙ
Iter㧦ࠗ࠲࡟࡯࡚ࠪࡦ࿁ᢙ

98

㧔㧟㧕ID, TYPE㧦ࠦࡦࡐ࡯ࡀࡦ࠻ ID

ID

TYPE 㧦ࠦࡦࡐ࡯ࡀࡦ࠻࠲ࠗࡊ
㧔㧠㧕rhoo㧦᦭ᯏ⋧ኒᐲ

rhoo

㧔3.4.1 ▵ෳᾖ㧕㧔㧡㧕muomuo 㧦᦭ᯏ⋧☼ᕈ₸

㧔3.4.2 ▵ෳᾖ㧕㧔㧢㧕1TICPKE6CPM%QPEGPVTCVKQPU
㧔㧣㧕OGUJY ൻቇ⒳ฬ

01 Ớᐲන૏ Ớᐲන૏ߩ⴫⸥ߪ‫ޔ‬ൻቇ⒳ߦࠃߞߡ OQNN ෶ߪ IN ߩ޿ߕࠇ߆߇ㆬᛯߐࠇࠆ‫ޕ‬㧔㧤㧕j+1, Xn
j+1 㧦ࡔ࠶ࠪࡘ⇟ภ 㧔= 1㧕
Xn 㧦ฦൻቇ⒳ߩ᦭ᯏ⋧Ớᐲ㧔ൻቇ⒳ᢙ nspe㧕㧔㧥㧕1VJGTU 1TICPKE6CPM 
㧔㧝㧜㧕OGUJ&+8(10101 NJ 㧔㧝㧝㧕j+1,hd+1,FO
j+1㧦ࡔ࠶ࠪࡘ⇟ภ㧔= 1㧕

hd+1 㧦࠺ࠖࡧ࡚ࠖࠫࡦ⇟ภ㧔ᢛᢙ㧕FO㧦᦭ᯏ⋧ߩᵹ㊂㧔㧝㧞㧕8CNWGUHQT/CUU$CNCPEG 1TICPKE6CPM 
㧔㧝㧟㧕+VGO ൻቇ⒳ฬ 1WVIQ㧔න૏㧕Ớᐲන૏ߩ⴫⸥ߪ‫ޔ‬ൻቇ⒳ߦࠃߞߡ OQNN ෶ߪ IN ߩ޿ߕࠇ߆߇ㆬᛯߐࠇࠆ‫ޕ‬㧔㧝㧠㧕6QVCN(F MssFlwFd's  

MssFlwFd 㧦ㅪ⚿ߐࠇߚࠪࠬ࠹ࡓ㧔ోࠦࡦࡐ࡯ࡀࡦ࠻㧕߳ߩන૏ᤨ㑆ᒰߚࠅࡈࠖ࡯࠼㊂99㧔᳓⋧㧗᦭ᯏ⋧㧕ߩ๺‫ޕ‬㧔ൻቇ⒳ᢙ nspe㧕㧔㧝㧡㧕5WO+P

MSSFLWSRC   

MSSFLWSRC㧦ߘߩࠦࡦࡐ࡯ࡀࡦ࠻߳ߩන૏ᤨ㑆ᒰߚࠅࡈࠖ࡯࠼㊂㧔᳓⋧㧗᦭ᯏ⋧㧕ߩ๺㧔ઁࠦࡦࡐ࡯ࡀࡦ࠻߆ࠄߩᵹ౉㧗ࠪࠬ࠹ࡓᄖㇱ߆ࠄߩࡈࠖ࡯࠼㧕‫ޕ‬㧔ൻቇ⒳ᢙ nspe㧕㧔㧝㧢㧕1WV#MSSOUTAOUTGOMSSOUTA 㧦ߘߩࠦࡦࡐ࡯ࡀࡦ࠻߆ࠄ಴ߡⴕߊ᳓⋧ᵹ㊂‫ޕ‬㧔ൻቇ⒳ᢙ nspe㧕
OUTGO

㧦ઁߩࠦࡦࡐ࡯ࡀࡦ࠻ߦᵹ౉ߖߕ‫ࠄ߆ࡓ࠹ࠬࠪޔ‬ᵹ಴ߔࠆ႐ว 176‫ޔ‬ઁߩࠦࡦࡐ࡯ࡀࡦ࠻ߦᵹ౉ߔࠆߣ߈   㧔㧝㧣㧕1WV1MSSOUTOOUTGOMSSOUTO 㧦ߘߩࠦࡦࡐ࡯ࡀࡦ࠻߆ࠄ಴ߡⴕߊ᦭ᯏ⋧ᵹ㊂‫ޕ‬㧔ൻቇ⒳ᢙ nspe㧕
OUTGO

㧦ઁߩࠦࡦࡐ࡯ࡀࡦ࠻ߦᵹ౉ߖߕ‫ࠄ߆ࡓ࠹ࠬࠪޔ‬ᵹ಴ߔࠆ႐ว 176‫ޔ‬ઁߩࠦࡦࡐ࡯ࡀࡦ࠻ߦᵹ౉ߔࠆߣ߈   㧔㧝㧤㧕+VGO ൻቇ⒳ฬ 1WVIQ  

㧔㧝㧥㧕1WV4CV# MSSRATIOA'sOUTGOMSSRATIOA 㧦MSSOUTA ߣ MssFlwFd ߩᲧ㧔= MSSOUTA / MssFlwFd㧕㧔ൻቇ⒳ᢙ nspe㧕
OUTGO

㧦ઁߩࠦࡦࡐ࡯ࡀࡦ࠻ߦᵹ౉ߖߕ‫ࠄ߆ࡓ࠹ࠬࠪޔ‬ᵹ಴ߔࠆ႐ว 176‫ޔ‬ઁߩࠦࡦࡐ࡯ࡀࡦ࠻ߦᵹ౉ߔࠆߣ߈   㧔㧞㧜㧕1WV4CV1 MSSRATIOOOUTGOMSSRATIOO 㧦MSSOUTO ߣ MssFlwFd ߩᲧ㧔= MSSOUTO / MssFlwFd㧕㧔ൻቇ⒳ᢙ nspe㧕
OUTGO

㧦ઁߩࠦࡦࡐ࡯ࡀࡦ࠻ߦᵹ౉ߖߕ‫ࠄ߆ࡓ࠹ࠬࠪޔ‬ᵹ಴ߔࠆ႐ว 176‫ޔ‬ઁߩࠦࡦࡐ࡯ࡀࡦ࠻ߦᵹ౉ߔࠆߣ߈   㧔㧞㧝㧕+VGO ൻቇ⒳ฬ㧔න૏㧕Ớᐲන૏ߩ⴫⸥ߪ‫ޔ‬ൻቇ⒳ߦࠃߞߡ OQNN ෶ߪ IN ߩ޿ߕࠇ߆߇ㆬᛯߐࠇࠆ‫ޕ‬㧔㧞㧞㧕/CUU+PX MSSINVMSSINV 㧦ࡑࠬࠗࡦࡌࡦ࠻࡝

100㧥㧚㧞 ࡝ࠬ࠲࡯࠻಴ജ㧔".rst"ࡈࠔࠗ࡞㧕
PARC ࠍታⴕߔࠆߣ‫࡞ࠗࠔࡈޔ‬ฬߩ᜛ᒛሶ߇ .rst ߢ޽ࠆ࡝ࠬ࠲࡯࠻಴ജࡈࠔࠗ࡞㧔࠹ࠠࠬ࠻ࡈ
ࠔࠗ࡞㧕߇࡙࡯ࠩᜰቯߩ࠲ࠗࡒࡦࠣߢ‫ޔ‬ᜰቯߩ୘ᢙ߇↢ᚑߐࠇࠆ‫ޕ‬એਅߩౝኈ߇㗅ߦ಴ജߐࠇࠆ‫ޕ‬" "ߢ࿐߹ࠇߚㇱಽߪ‫ޔ‬ᢥሼ೉ࠍ␜ߔ‫ޕ‬㧥㧚㧞㧚㧝 ౒ㅢ࠺࡯࠲OGUJ, ൻቇ⒳ฬ, :016H(NY4CV

㧔㧝㧕nspe,

㧦ൻቇ⒳ᢙ

nspe

㧔㧞㧕ncomp,

Time,

dt,

EndTimncomp

㧦ࠦࡦࡐ࡯ࡀࡦ࠻ᢙ

Time

㧦ᤨೞ

dt

㧦࠲ࠗࡓࠬ࠹࠶ࡊࠨࠗ࠭

EndTim 㧦⸘▚⚳ੌᤨೞ㧥㧚㧞㧚㧞 ࡄ࡞ࠬࠞ࡜ࡓߩỚᐲߦ㑐ߔࠆ಴ജ ฦࠦࡦࡐ࡯ࡀࡦ࠻ߦߟ޿ߡỚᐲ࠺࡯࠲ࠍ಴ജߔࠆ‫ޕ‬̪Ớᐲ߇ PRINTMIN㧔⃻࿷ 10-100 ߣߒߡ޿ࠆ‫ޕ‬㧕ࠃࠅዊߐ޿႐วߪ 0 ߣߒߡ⴫␜ߔࠆ‫ޕ‬
㧔㧝㧕ID, nmsh,ID㧦ࠦࡦࡐ࡯ࡀࡦ࠻ ID

nmsh 㧦ࡔ࠶ࠪࡘᢙ
㧔㧞㧕j+1,Xn,

xno3, Tf,FA ฦࡔ࠶ࠪࡘ㧔ࡔ࠶ࠪࡘᢙ nmsh㧕ߦߟ޿ߡએਅࠍ಴ജߔࠆ‫ޕ‬
j+1㧦ࡔ࠶ࠪࡘ⇟ภXn㧦ฦൻቇ⒳ߩ᳓⋧Ớᐲ㧔ൻቇ⒳ᢙ nspe㧕

xno3 㧦⎣㉄ᩮỚᐲTf㧦ࡈ࡝࡯TBP Ớᐲ

FA

㧦᳓⋧ᵹ㊂

㧔㧟㧕ID, nmsh,ID㧦ࠦࡦࡐ࡯ࡀࡦ࠻ ID

nmsh 㧦ࡔ࠶ࠪࡘᢙ

101㧔㧠㧕j+1, Xn,

G , G ,FOฦࡔ࠶ࠪࡘ㧔ࡔ࠶ࠪࡘᢙ nmsh㧕ߦߟ޿ߡએਅࠍ಴ജߔࠆ‫ޕ‬
j+1㧦ࡔ࠶ࠪࡘ⇟ภXn’s㧦ฦൻቇ⒳ߩ᦭ᯏ⋧Ớᐲ㧔ൻቇ⒳ᢙ nspe㧕

FO㧦᦭ᯏ⋧ᵹ㊂㧥㧚㧞㧚㧟 ࡒࠠࠨ࠮࠻࡜ߩỚᐲߦ㑐ߔࠆ಴ജ ฦࠦࡦࡐ࡯ࡀࡦ࠻ߦߟ޿ߡỚᐲ࠺࡯࠲ࠍ಴ജߔࠆ‫ޕ‬̪Ớᐲ߇ PRINTMIN㧔⃻࿷ 10-100 ߣߒߡ޿ࠆ‫ޕ‬㧕ࠃࠅዊߐ޿႐วߪ 0 ߣߒߡ⴫␜ߔࠆ‫ޕ‬
㧔㧝㧕ID, nmsh,ID㧦ࠦࡦࡐ࡯ࡀࡦ࠻ ID

nmsh 㧦Ბᢙ㧔㧞㧕j+1,Xn,

xno3, Tf,FA ฦᲑ㧔Ბᢙ nmsh㧕ߦߟ޿ߡએਅࠍ಴ജߔࠆ‫ޕ‬
j+1㧦ࠬ࠹࡯ࠫ⇟ภXn㧦ࡒࠠࠨㇱߢߩฦൻቇ⒳ߩ᳓⋧Ớᐲ㧔ൻቇ⒳ᢙ nspe㧕

xno3 㧦⎣㉄ᩮỚᐲTf㧦ࡈ࡝࡯TBP Ớᐲ

FA

㧦᳓⋧ᵹ㊂

㧔㧟㧕ID, nmsh,ID㧦ࠦࡦࡐ࡯ࡀࡦ࠻ ID

nmsh 㧦Ბᢙ㧔㧠㧕j+1, Xn,

xno3, 0.0,

0.0 ฦᲑ㧔Ბᢙ nmsh㧕ߦߟ޿ߡએਅࠍ಴ജߔࠆ‫ޕ‬
j+1㧦ࠬ࠹࡯ࠫ⇟ภXn㧦࠮࠻࡜ߢߩฦൻቇ⒳ߩ᳓⋧Ớᐲ㧔ൻቇ⒳ᢙ nspe㧕

xno3 㧦⎣㉄ᩮỚᐲ㧔㧡㧕ID, nmsh,ID㧦ࠦࡦࡐ࡯ࡀࡦ࠻ ID

nmsh 㧦Ბᢙ102

㧔㧢㧕j+1, Xn,

0.0,

0.0,

FO

 ฦᲑ㧔Ბᢙ nmsh㧕ߦߟ޿ߡએਅࠍ಴ജߔࠆ‫ޕ‬
j+1㧦ࠬ࠹࡯ࠫ⇟ภXn㧦ࡒࠠࠨߢߩฦൻቇ⒳ߩ᦭ᯏ⋧Ớᐲ㧔ൻቇ⒳ᢙ nspe㧕

FO㧦᦭ᯏ⋧ᵹ㊂㧔㧣㧕ID, nmsh,ID㧦ࠦࡦࡐ࡯ࡀࡦ࠻ ID

nmsh 㧦Ბᢙ㧔㧤㧕j+1, Xn,

0.0,

0.0,

0.0

 ฦᲑ㧔Ბᢙ nmsh㧕ߦߟ޿ߡએਅࠍ಴ജߔࠆ‫ޕ‬
j+1㧦ࠬ࠹࡯ࠫ⇟ภXn㧦࠮࠻࡜ㇱߢߩฦൻቇ⒳ߩ᦭ᯏ⋧Ớᐲ㧔ൻቇ⒳ᢙ nspe㧕㧥㧚㧞㧚㧠 ᳓⋧࠲ࡦࠢߩỚᐲߦ㑐ߔࠆ಴ജ ฦࠦࡦࡐ࡯ࡀࡦ࠻ߦߟ޿ߡỚᐲ࠺࡯࠲ࠍ಴ജߔࠆ‫ޕ‬̪Ớᐲ߇ PRINTMIN㧔⃻࿷ 10-100 ߣߒߡ޿ࠆ‫ޕ‬㧕ࠃࠅዊߐ޿႐วߪ 0 ߣߒߡ⴫␜ߔࠆ‫ޕ‬
㧔㧝㧕ID, nmsh,ID㧦ࠦࡦࡐ࡯ࡀࡦ࠻ ID

nmsh 㧦ࡔ࠶ࠪࡘᢙ
㧔㧞㧕j+1,Xn,(=1)

xno3, 0.0,

FA

j+1

㧦ࡔ࠶ࠪࡘ⇟ภXn㧦ฦൻቇ⒳ߩ᳓⋧Ớᐲ㧔ൻቇ⒳ᢙ nspe㧕

(=1)

xno3 㧦⎣㉄ᩮỚᐲ
FA

㧦᳓⋧ᵹ㊂



㧥㧚㧞㧚㧡 ᦭ᯏ⋧࠲ࡦࠢߩỚᐲߦ㑐ߔࠆ಴ജ ฦࠦࡦࡐ࡯ࡀࡦ࠻ߦߟ޿ߡỚᐲ࠺࡯࠲ࠍ಴ജߔࠆ‫ޕ‬̪Ớᐲ߇ PRINTMIN㧔⃻࿷ 10-100 ߣߒߡ޿ࠆ‫ޕ‬㧕ࠃࠅዊߐ޿႐วߪ 0 ߣߒߡ⴫␜ߔࠆ‫ޕ‬
㧔㧝㧕ID, nmsh,ID㧦ࠦࡦࡐ࡯ࡀࡦ࠻ ID

nmsh 㧦ࡔ࠶ࠪࡘᢙ

(=1)

103

㧔㧞㧕j+1, Xn,

0.0,

0.0,

FO

j+1

㧦ࡔ࠶ࠪࡘ⇟ภXn㧦᦭ᯏ⋧Ớᐲ‫ޕ‬nspe ୘FO㧦᦭ᯏ⋧ᵹ㊂(=1)

㧥㧚㧞㧚㧢 ࡄ࡞ࠬࠞ࡜ࡓߩಽ㈩Ყߦ㑐ߔࠆ಴ജ ฦࠦࡦࡐ࡯ࡀࡦ࠻ߦߟ޿ߡಽ㈩Ყ࠺࡯࠲ࠍ಴ജߔࠆ㧔㧝㧕ID, nmsh,ID㧦ࠦࡦࡐ࡯ࡀࡦ࠻ ID

nmsh 㧦ࡔ࠶ࠪࡘᢙ
㧔㧞㧕j+1, Dis ฦࡔ࠶ࠪࡘ㧔ࡔ࠶ࠪࡘᢙ nmsh㧕ߦߟ޿ߡએਅࠍ಴ജߔࠆ‫ޕ‬
j+1 㧦ࡔ࠶ࠪࡘ⇟ภDis 㧦ฦൻቇ⒳ߩಽ㈩Ყ㧔ൻቇ⒳ᢙ nspe㧕㧥㧚㧞㧚㧣 ࡒࠠࠨ࠮࠻࡜ߩಽ㈩Ყߦ㑐ߔࠆ಴ജ ฦࠦࡦࡐ࡯ࡀࡦ࠻ߦߟ޿ߡಽ㈩Ყ࠺࡯࠲ࠍ಴ജߔࠆ㧔㧝㧕ID, nmsh,
ID



㧦ࠦࡦࡐ࡯ࡀࡦ࠻ ID

nmsh 㧦Ბᢙ㧔㧞㧕j+1, Dis’sฦᲑ㧔Ბᢙ nmsh㧕ߦߟ޿ߡએਅࠍ಴ജߔࠆ‫ޕ‬
j+1 㧦ࠬ࠹࡯ࠫ⇟ภDis 㧦ಽ㈩Ყ‫ޕ‬nspe ୘㧥㧚㧟 ⚻ᤨ಴ജ㧔".trn"ࡈࠔࠗ࡞㧕
PARC ࠍታⴕߔࠆߣ‫࡞ࠗࠔࡈޔ‬ฬߩ᜛ᒛሶ߇ .trn ߢ޽ࠆ⚻ᤨ಴ജࡈࠔࠗ࡞㧔࠹ࠠࠬ࠻ࡈࠔࠗ࡞㧕߇↢ᚑߐࠇࠆ‫ޕ‬એਅߩౝኈ߇㗅ߦ಴ജߐࠇࠆ‫ߢ" "ޕ‬࿐߹ࠇߚㇱಽߪ‫ޔ‬ᢥሼ೉ࠍ␜ߔ‫ޕ‬̪Ớᐲ߇ PRINTMIN㧔⃻࿷ 10-100 ߣߒߡ޿ࠆ‫ޕ‬㧕ࠃࠅዊߐ޿႐วߪ 0 ߣߒߡ⴫␜ߔࠆ‫ޕ‬104㧔㧝㧕6KOG,

TrnLbl㧦ㆊᷰ࠺࡯࠲ߩ࡜ࡌ࡞㧔8.4.2.1 ▵(23)㨪(24)ෳᾖ㧕‫ޕ‬nTrnLbl㧔౉ജ࠺࡯࠲㧕୘

TrnLbl㧔㧞㧕Time,Xn’s એਅࠍ nRFile㧔8.4.2.1 ▵(21)ෳᾖ㧕࿁➅ࠅ㄰ߔ
Time 㧦ᤨೞXn[min]㧦ᜰቯߒߚൻቇ⒳ߩỚᐲ㧔nTrnLbl ୘㧕㧥㧚㧠 ෼᧤⁁ᘒ಴ജ㧔".cnv"ࡈࠔࠗ࡞㧕
Newton ᴺߦࠃࠆ⸘▚ߩ➅㄰ߒ࿁ᢙ߇ᦨᄢᢙ ItMax ߦ㆐ߒߡ߽෼᧤ߒߥ߆ߞߚ႐วߦ‫ޔ‬ฦࠦࡦࡐ࡯ࡀࡦ࠻Ფ‫ޔ‬ฦൻቇ⒳ᲤߩỚᐲߩ෼᧤⁁ᴫࠍ಴ജߔࠆ‫ޕ‬
㧔㧝㧕Time,dt, nStep,

ItMax

Time 㧦ᤨೞdt[min]㧦࠲ࠗࡓࠬ࠹࠶ࡊ᏷ [min]nStep 㧦⸘▚ࠬ࠹࠶ࡊᢙ
ItMax 㧦ᦨᄢࠗ࠲࡟࡯࡚ࠪࡦ࿁ᢙ
㧔㧞㧕%OR+&, 6[RG, ൻቇ⒳ฬ㧔㧟㧕ID, ࠦࡦࡐ࡯ࡀࡦ࠻࠲ࠗࡊ, ⋧ኻ⺋Ꮕ ోࠦࡦࡐ࡯ࡀࡦ࠻ߩࠦࡦࡐ࡯ࡀࡦ࠻࠲ࠗࡊߩᢙߛߌ➅ࠅ㄰ߔID

㧦ࠦࡦࡐ࡯ࡀࡦ࠻ ID

ࠦࡦࡐ࡯ࡀࡦ࠻࠲ࠗࡊ㧦ࡄ࡞ࠬࠞ࡜ࡓ᳓⋧‫᦭ޔ‬ᯏ⋧⋧ኻ⺋Ꮕ

PA, POࡒࠠࠨ࠮࠻࡜ࡒࠠࠨㇱ᳓⋧‫᦭ޔ‬ᯏ⋧MA, MO  ห   ࠮࠻࡜ㇱ᳓⋧‫᦭ޔ‬ᯏ⋧SA, SO᳓⋧࠲ࡦࠢAA᦭ᯏ⋧࠲ࡦࠢ

OO

㧦ฦࡔ࠶ࠪࡘߩỚᐲᄌൻ㊂㧔➅㄰ߒ⸘▚೨ᓟߢߩᄌൻ㊂㧕ߩੑਸ਼๺ߩᐔᣇᩮ‫ޕ‬105

㧝㧜 㧼㧭㧾㧯ߦࠃࠆ⸘▚ታⴕ଀ᧄ┨ߢߪ‫ޔ‬PARC ࠍ↪޿ߚ PUREX ࡊࡠ࠮ࠬߩ⸘▚଀ࠍ␜ߔ‫ޕ‬࿑ 10.1 ߪࡊ࡞࠻࠾࠙ࡓ♖⵾Ꮏ⒟ߩࡈࡠ࡯ࠪ࡯࠻ߩ଀ߢ޽ࠅ‫౏ޔ‬㐿ᢥ₂ 62-63) ࠍෳ⠨ߦ૞ᚑߒߚ‫ޕ‬࿑ 10.2 ߦ౉ജࡈࠔࠗ࡞ example1.inpߩ଀ࠍ␜ߔ‫ޕ‬࿑ 10.3 ߪ‫ޔ‬PARC ታⴕᓟߩࡈࠜ࡞࠳ౝߩࡈࠔࠗ࡞↢ᚑߩ᭽ሶࠍ␜ߒߡ޿ࠆ‫ߩߎޕ‬ታⴕ଀ߪ‫ޔ‬DELL
␠⵾ PC‫ޔ‬Optiplex GX520㧔CPU㧦Pentium 4 (3.2 GHz)‫ޔ‬ਥ⸥ᙘ㧦2 GBytes㧕ߢታⴕߒߚ߽ߩߢ޽ࠆ‫ޕ‬ㆊᷰ⸘▚ߣቯᏱ⸘▚ߪ 3㨪4 ಽ⒟ᐲߢ⚳ੌߒ‫࠳࡞ࠜࡈޔ‬ౝߦߪ 1 ୘ߩ example1.out ࡈࠔࠗ࡞‫ޔ‬14
୘ߩ example1T1***.rst ࡈࠔࠗ࡞㧔ㆊᷰ⸘▚⚿ᨐ㧕෸߮ 1 ୘ߩ example1S2.rst ࡈࠔࠗ࡞㧔ቯᏱ⸘▚⚿ᨐ㧕߇↢ᚑߐࠇߚ߶߆‫࡯࡜ࠛޔ‬಴ജ‫ޔ‬ᮡḰ಴ജ‫↢߇࡞ࠗࠔࡈࠢ࡯ࡢޔ‬ᚑߐࠇߚ‫ޕ‬ ࿑ 10.4 ߪ‫ޔ‬ቯᏱ⸘▚ߩ⚿ᨐ㧔example1S2.rst㧕ࠍࡊࡠ࠶࠻ߒߚ߽ߩߢ޽ࠆ‫ޕ‬ᮮゲߪ᛽಴ེߩࡔ
࠶ࠪࡘ⇟ภ㧔Ბ⇟ภ㧕‫❑ޔ‬ゲߪฦൻቇ⒳ߩỚᐲࠍ⴫ߒߡ޿ࠆ‫ޕ‬

106

107

න૏
U
: g/dm-3
Pu: g/dm-3
HNO3, : mol/dm-3

A :᳓⋧
O :᦭ᯏ⋧㧔 30 vol%TBP-DD㧕

U(VI) :9.52
Pu(IV) :4.78
HNO3 :3.1
437 dm3/h

A1

HNO3 :1.0
61 dm3/hA2

83 dm3/hO2

HNO3 :12.0
46 dm3/h

A4

HNO3 :1.0
36 dm3/h

A5

᳓⋧಴ญ

3AႡ

1.06 dm3/hO3⎣㉄㩕㩎㩨㩥㩁㩆㩣㨻㩚㩧:0.51 mol/dm-3⎣㉄㩕㩎㩨㩡㩆㩨㩧:0.22 mol/dm-3
HNO3 :0.2
47 dm3/hA6࿑㧝㧜㧚㧝 PUREXࡊࡠ࠮ࠬߩ⸘▚଀146 dm3/h

O1

2AႡ

2BႡ

᳓⋧಴ญ

HNO3 :0.35
132 dm3/h

A3

Uṁᇦ಴ญ
146 dm3/hPu⵾ຠ಴ญ
47 dm3/h

21.3 dm3/h

O4

3BႡਅㇱ

3BႡ਄ㇱ

Uṁᇦ಴ญ
105 dm3/hKPRWVGZCORNGKPR
+0276&#6#5*''6HQT2#4%A.%1&'



JGCFGTDNQEMDGIKP
GPFDGIKP
 6KVNG 
#PGZCORNGQH274':2NCPV P/GO5K\  P/GO3WCF5K\  P/GO8CT5K\  P/GO5[O5K\ 
EJGOKECNU

*72W2W7*#0*;&*01<T6E0R0R0R
*0K$#.P$#.K$#%P$#%+%U4W2W88&$2/$2*21(2*1 H5RG EJGOKECNU
 P&GN 
 K(TO6[R  +(TO0WO  PYURG  PEQOR  PU 
 %JGO(TO  #DDTGX0CO  9GKIJV  H:01  H%0  8CNGPEG  PY(TO 

DGIKP
 P%QPF  K(TO6[R  &GUETKRVKQPQHEJOKECNTGCEVKQPU GPF
 +V/CZ  GRU G &V/KP G P&V/CZ  &V(CE 
6CD&V/CZ 6KOG&V/CZ 


 K6TCP 
 H2TKPV:  H2TKPV4  H2TKPV6 
 6KOG  &V  'PF6KO 
 K5QNV(T 
 K4UV(NI 
 %4(+.'  VGUV6TUV  P4(KNG 
 46+/'5 


 P6TP.DN 
 640.$.U 
 &GNVC G2CTCOGVGTUHQT/KZGT5GVVNGTU EM  FT  GP 
 (TE  2JK5 
࿑㧝㧜㧚㧞 PARC ౉ജࡈࠔࠗ࡞ߩ଀㧔㧝㧛㧤㧕


108


2CTCOGVGTUHQT0GRVWPKWO 024'#%  +02'3  02&+56 
(GGFFCVC  PHC  PHQ 
 6HF 
#37'175(''&
 #  #  P:H6CD 
%QPEGPVTCVKQPVCDNG %JGOKECNU VKOG*72W2W7*#0*;&*01OKP/I.I.I.I.///G<T6E0R0R0R*0
I.I.I.I.I./


G

 P(H6CD (NQYTCVGVCDNG
OKP=FOJ?


 +(&56#EOR  +(&56#OUJ 
 #  #  P:H6CD 
%QPEGPVTCVKQPVCDNGVKOG*
OKP/
 
 
 P(H6CD (NQYTCVGVCDNG
OKP=FOJ?


 +(&56#EOR  +(&56#OUJ 

 #  #  P:H6CD 
%QPEGPVTCVKQPVCDNGVKOG*
OKP/
 
 
 P(H6CD (NQYTCVGVCDNG
OKP=FOJ?


࿑㧝㧜㧚㧞 PARC ౉ജࡈࠔࠗ࡞ߩ଀㧔㧞㧛㧤㧕

109




 +(&56#EOR  +(&56#OUJ 

 #  #  P:H6CD 
%QPEGPVTCVKQPVCDNGVKOG*
OKP/
 
 
 P(H6CD (NQYTCVGVCDNG
OKP=FOJ?


 +(&56#EOR  +(&56#OUJ 

 #  #  P:H6CD 
%QPEGPVTCVKQPVCDNGVKOG*72W2W7*#0*;&*01*0

 P(H6CD (NQYTCVGVCDNG
OKP=FOJ?


 +(&56#EOR  +(&56#OUJ 

 #  #  P:H6CD 
%QPEGPVTCVKQPVCDNGVKOG*72W2W7*#0*;&*01*0

 P(H6CD 
(NQYTCVGVCDNG
OKP=FOJ?


 +(&56#EOR  +(&56#OUJ 
14)#0+%(''&
 1  1  P:H6CD 
%QPEGPVTCVKQPVCDNGVKOGOKP  ࿑㧝㧜㧚㧞 PARC ౉ജࡈࠔࠗ࡞ߩ଀㧔㧟㧛㧤㧕110 P(H6CD (NQYTCVGVCDNG
OKP=FOJ?


 +(&561EOR  +(&561OUJ 

 1  1  P:H6CD 
%QPEGPVTCVKQPVCDNGVKOGOKP  
 P(H6CD (NQYTCVGVCDNG
OKP=FOJ?


 +(&561EOR  +(&561OUJ 

 1  1  P:H6CD 
%QPEGPVTCVKQPVCDNGVKOGOKP  
 P(H6CD (NQYTCVGVCDNG
OKP=FOJ?


 +(&561EOR  +(&561OUJ 

 1  1  P:H6CD 
%QPEGPVTCVKQPVCDNGVKOGOKP  
 P(H6CD (NQYTCVGVCDNG
OKP=FOJ?


 +(&561EOR  +(&561OUJ 
࿑㧝㧜㧚㧞 PARC ౉ജࡈࠔࠗ࡞ߩ଀㧔㧠㧛㧤㧕111

%QORQPGPV&CVC  %QORQPGPV2WNUGF%QNWOP 
 +&  K6[RG  /5*  KFKUR 
 +%&56#EOR  +%&56#OUJ 
 +%&561EOR  +%&561OUJ 
 6 
 TZJ  TZW  TZRW 
 T[J  T[W  T[RW 

2WNUGF%QNWOP&CVC CTC  CNR  COR  HTGS  J  F 
 RJK  RJK 
 UC G UC G $'6#$  
 $'6#6  

#SWGQWUKPKVKCNEQPEGPVTCVKQP OGUJ G 
G 
G 
G 
G 
G 
G 
G 
G 
G 
G 
G 
G 
G 
G 
G 
G 
G 
G 
G 

1TICPKEKPKVKCNEQPEGPVTCVKQP OGUJ G 
G 

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 8$=FO?  86=FO? 
 &<=EO?  OGUJ

 %QORQPGPV2WNUGF%QNWOP 
 +&  K6[RG  /5*  KFKUR 
 +%&56#EOR  +%&56#OUJ 
 +%&561EOR  +%&561OUJ 
 6 
࿑㧝㧜㧚㧞 PARC ౉ജࡈࠔࠗ࡞ߩ଀㧔㧡㧛㧤㧕


112







 TZJ  TZW  TZRW 
 T[J  T[W  T[RW 

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࿑㧝㧜㧚㧞 PARC ౉ജࡈࠔࠗ࡞ߩ଀㧔㧢㧛㧤㧕


113









1TICPKEKPKVKCNEQPEGPVTCVKQP OGUJ G 
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#VQO5VTEV
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 RJK  RJK 
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 $'6#6  

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 T[J  T[W  T[RW ࿑㧝㧜㧚㧞 PARC ౉ജࡈࠔࠗ࡞ߩ଀㧔㧣㧛㧤㧕


114











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 $'6#6  

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GPF

࿑㧝㧜㧚㧞 PARC ౉ജࡈࠔࠗ࡞ߩ଀㧔㧤㧛㧤㧕

115





࿑㧝㧜㧚㧟 PARC ታⴕᓟߩࡈࠜ࡞࠳ౝ᭴ᚑ㧔଀㧕ਅㇱ㪈㪅㪜㪂㪇㪊

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HNO3 [mol/L] U(VI) [g/L]
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Pu(IV) [g/L]aqorg

Pu(III) [g/L]aqorg

HAN [mol/L] HYD [mol/L] HNO2 [mol/L]
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࿑㧝㧜㧚㧠㧙㧝 㧞㧭Ⴁߩ⸘▚⚿ᨐਅㇱ㪈㪅㪜㪂㪇㪊

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࿑㧝㧜㧚㧠㧙㧞 㧞㧮Ⴁߩ⸘▚⚿ᨐ

117

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118

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࿑㧝㧜㧚㧠㧙㧡 㧟㧮Ⴁ਄ㇱߩ⸘▚⚿ᨐ

119

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⻢  ㄉ ᧄ⎇ⓥߩታᣉ߅ࠃ߮ႎ๔ᦠߩ૞ᚑߦ޽ߚࠅ‫ޔ‬቟ో⎇ⓥ࠮ࡦ࠲࡯ ౝጊ ァ⮥᳁‫ޔ‬ේሶജၮ␆Ꮏቇ
⎇ⓥㇱ㐷 ᓟ⮮ ታ᳁߆ࠄᄙߊߩഥ⸒‫ޔ‬ᖱႎࠍ㗂߈߹ߒߚ‫ߩ࠼࡯ࠦޔߚ߹ޕ‬ᢛ஻૞ᬺߢߪ‫ޔ‬ᄢፒ ᶈ᳁‫ ᧛᧻ޔ‬ᱜ๺᳁ࠍߪߓ߼‫ޔ‬ᱧઍߩᄙߊߩᣇ‫ߩޘ‬දജࠍ㗂߈߹ߒߚ‫ޕ‬ᔃࠃࠅᗵ⻢޿ߚߒ߹ߔ‫ޕ‬

ෳ⠨ᢥ₂
1)

T.Asakura, S.Hotoku, Y.Ban, M.Matsumura, Y.Morita : "Technetium Separation for Future
Reprocessing", J. Nucl. Radiochem. Sci., 6, p.271 (2005).

2)

G.L.Richardson, J.L.Swanson㧦"Plutonium Partitioning in the Purex Process with HydrazineStabilized Hyroxylamine Nitrate", HEDL-TME-75-31 (1975).

3)

ㄞ㊁ཅብ㧦"ࠦࡦࡄࠗ࡜", ᤘᤩၴ (1996). ઁ

4)ਭ଻↰శ৻‫ޔ‬દℂᱜᄦ㧦"ࠕ࡞ࠧ࡝࠭ࡓߩ⥄േᓸಽߣᔕ↪ ⃻ઍ㕖✢ᒻ⑼ቇࠪ࡝࡯࠭㧟", ࠦࡠ࠽␠ (1998).

5)

B.W.Kernighan, D.M.Ritchie㧔⪺㧕‫ޔ‬⍹↰᥍ਭ㧔⸶㧕㧦"ࡊࡠࠣ࡜ࡒࡦࠣ⸒⺆ C ╙ 2
಴

6)

", ౒┙

(1989). ઁ

A.Kumar, S.Hartland㧦"Prediction of Drop Size in Pulsed Perforated-Plate Extraction Columns",
Chem. Eng. Commun., 44, p.163 (1986).

7)

A.Kumar, S.Hartland㧦"Prediction of Continuous-Phase Axial Mixing Coefficients in Pulsed
Perforated-Plate Extraction Columns", Ind. Eng. Chem. Res. Process., 28, p.1507 (1989).

8)

A.Kumar, S.Hartland㧦"Prediction of Dispersed Phase Holdup in Pulsed Perforated-Plate Extraction
Columns", Chem. Eng. Process., 23, p.41 (1988).

9)

M.Maeda, et al.㧦"Simulation Code of Extraction Contactor for Analyzing Transient Behavior",
Solvent Extraction in the Process Industries (Proc. of ISEC '93), Vol.3, Elsevier Applied Science,p.1517 (1993).

10) ⮮ᩮᐘ㓶‫ޔ‬೨↰ల㧦"ࡄ࡞ࠬࠞ࡜ࡓᎿ⒟⸃ᨆࠦ࡯࠼ SAFE", ╙ 8 ࿁ේሶജߦ߅ߌࠆ࠰ࡈ࠻࠙
ࠚࠕ㐿⊒⎇ⓥળႎ๔㓸, JAERI-M 93-033, p.164 (1993).
11) ᮭ↰ᶈਃ‫↰᧻ޔ‬ᾖᄦ㧦"ࡄ࡞ࠬࠞ࡜ࡓߦ߅ߌࠆ Purex ࡊࡠ࠮ࠬ⸘▚ࠦ࡯࠼ PULCO", PNC-TN
841-82-19 (1982).
12) G.Petrich㧦" Computer-Simulation of the PUREX Process ", Nukleare Entsorgung Band 2, Verlag
Chemie, p.317 (1983).
13) ᮭ↰ᶈਃ‫ޔ‬ጟ⚔৻㇢‫┨↰⑔ޔ‬ੑ㧦"Purex ࡊࡠ࠮ࠬ⸘▚ࠦ࡯࠼ Revised MIXSET", PNC-TN841-79-26 (1979).
14) ౝ⮮ᄢᔒ‫ޔ‬㗇⮮ବᐘ‫ޔ‬㤗Ꮉ๺⵨‫ޔ‬ᨰᧁᩕ੺㧦"᛽಴⸘▚ࠦ࡯࠼㧔MIXSET-X㧕", JNC-TN8400 99-005(1999).
15) 㙚⋓ൎ৻㧦"EXTRA-M㧦ౣಣℂࡇࡘ࡟࠶ࠢࠬᎿ⒟㧔ࡒࠠࠨ࡯࠮࠻࡜㧕⸃ᨆ↪ㆊᷰ⸘▚ࠦ࡯࠼ࠪࠬ࠹ࡓ", JAERI 1331 (1994).

12016) ൻቇᎿቇදળ✬㧦"ᡷ⸓੖ ൻቇᎿቇଢⷩ", ਣༀ, p.565 (1988).

17) Hanford Atomic Products Operation㧦"Purex Technical Manual", HW-31000, Chapter 4-B (1955).
18) J.D.Moore, R.L.Walser, J.J.Fritch㧦"Purex Technical Manual", RHO-MA-116 (1980).
19) Άᢱࠨࠗࠢ࡞቟ోᎿቇㇱ㧦"ౣಣℂࡊࡠ࠮ࠬ࡮ൻቇࡂࡦ࠼ࡉ࠶ࠢ", JAERI-Review 2001-038(2001).
20) P.Biddle, H.A.C.McKay, J.H.Miles㧦" The Role of Nitrous Acid in the Reduction of Plutonium(IV) by
Uranium(IV) in TBP Systems ", Solvent Extraction Chemistry of Metals, Macmillan, London (1965).
21) G.S.Barney, "A Kinetic Study of the Reaction of Plutonium(IV) with Hydroxylamine", J. Inorg. Nucl.
Chem., 38, p.1677 (1976).
22) A.L.Slade, "Oxidation of Uranium(IV) by Oxygen and Nitrous Acid", DP-554 (1961).
23) H.A.C.McKay, R.J.W. Streeton, A.G.Wain㧦"Mixer-settler Runs to Study Uranium(IV) as a Reductant
in Uranium/Plutonium Separation", AERE-R 4381 (1963).
24) J.Halpern, J.G.Smith㧦"Kinetics of the Oxidation of Uranium(IV) by Molecular Oxygen in Aqueous
Perchloric Acid Solution", Can. J. Chem., 34, p.1419 (1956).
25) J.R.Perrot, G.Stedman, N.Uysal㧦" Kinetic and Product Study of the Reaction between Nitrous Acidand Hydrazine", J. Chem. Soc. Dalton Trans., p.2058 (1976).
26) G.S.Barney㧦"The Reaction of Hydroxylamine with Nitrous Acid", ARH-SA-97 (1971).
27) J.Garraway, P.D.Wilson, "The Technetium-Catalysed Oxidation of Hydrazine by Nitric Acid", J.
Less-Common Metals, 97, p.191 (1984).
28) P.D.Wilson, J.Garraway, "The Impact of Technetium on Reprocessing Chemistry", Proc. of Int. Meet.
on Fuel Reprocessing and Waste Management, Jackson, Vol.1, p.467 (1984).
29) B.Guillaume, J.P.Moulin, Ch.Maurice㧦"Chemical Properties of Neptunium Applied to Neptunium
Management in Extraction Cycles of Purex Process", I. Chem. E. Symposium Series 88 (Proc. ofExtraction '84, Dounreay), p.267 (1984).
30) D.Goulise㧦"Oxydation du Neptunium(V) par les Solutions Aqueuses d'Acide Nitrique en Presenced'Acide Nitreux", J. Inorg. Nucl. Chem., 33, p.831 (1971).
31) J.P.Moulin㧦"Cinetiques des Reactions d'Oxydo-Reduction du Neptunium en Solution Nitrique Oxidation du Neptunium(IV) en Neptunium(V), Oxydation du Neptunium(V) en Neptunium(VI) parl'Acide Nitrique, Catalysees par l'Acide Nitreux", CEA-R-4912 (1978).
32) L.Salomon, E.L.Menchero, J.L.Manterola, G.Leynen㧦"Etude sur la Recuperation du Neptunium dansle Cycle du Combustible et sur sa Purification", ETR-233 (1968).
33) 㙚⋓ൎ৻㧦"REACT-Mod: U-Pu-Np-Tc-⎣㉄᳓ṁᶧ♽ൻቇ෻ᔕߩㆊᷰ⸘▚ࡕ࠺࡞",JAERI-Data/Code 96-030 (1996).
34) 㙚⋓ൎ৻㧦"ࠕࠢ࠴࠾࠼ర⚛ߩ⎣㉄᳓ṁᶧ♽ൻቇ෻ᔕᢙ୯ࡕ࠺࡞㧦REACT", JAERI-M 90-018(1990).
35) I.V.Shilin, T.A.Rumyantseva㧦"Kinetics of the Reactions of Neptunium(V) - Uranium(IV) in Nitrate
Solutions", Soviet Radiochem., 20, p.460 (1978).
36) ⑳ା.

12137) N.K.Shastri, E.S.Amis㧦"Kinetics of the Reduction of Neptunium(V) with Uranium(IV) in Aqueous
Perchlorate and Chloride Media", J. Inorg. Nucl. Chem., 27, p.2413 (1965).
38) V.S.Koltunov, M.F.Tikhonov㧦" Kinetics of the Reduction of Actinides by Hydroxylamine - I.
Reduction of Neptunium(VI) in Nitric Acid Solution", Soviet Radiochem., 19, p.502 (1977).
39) V.S.Koltunov, M.F.Tikhonov㧦" Kinetics of Reduction of Neptunium by Hydrazine - II. Reductionof Np(VI) to Np(V) in Nitric Acid", Soviet Radiochem., 15, p.190 (1973).
40) V.S.Koltunov, V.I.Marchhenko, G.I.Zhuravleva, M.F.Tikhonov, M.P.Shapovalov㧦" Kinetics of theReactions of Oxidation of Np(IV) by Pu(IV), Fe(III), and V(V) Ions and the Reduction of Np(V) by
Hydrazine", Soviet Radiochem., 18, p.59 (1976).
41) R.B.Fulton and T.W.Newton㧦"The Kinetics of the Oxidation pf Plutonium(III) by Neptunium(VI)",
J. Phys. Chem., 74, p.1661 (1970).
42) V.S.Koltunov, et al.㧦"New Investigations in the Field of the Kinetics and Mechanism of Reactions of
Neptunium and Plutonium", Soviet Radiochem., 24, p.504 (1982).
43) H.Escure㧦"Contribution a l'Etude de la Dismutation du Neptunium Pentavalent en Solution Acide",
CEA-R-4574 (1974).
44) L.M.Frolova, G.A.Timofeev, A.G.Rykov㧦" Kinetics of the Reaction of Neptunium(IV)-Neptunium(VI) in Tributyul Phosphate", Soviet Radiochem., 14, p.127 (1972).
45) A.G.Rykov, G.N.Yakovlev㧦"Investigations of the Oxidation-Reduction Reactions of the Actinide
Elements II. Kinetics of the Reaction between Neptunium(IV) and Neptunium(VI) in Nitrate
Solutions", Soviet Radiochem., 8, p.26 (1966).
46) G.Uchiyama, S.Hotoku, S.Fujine, M.Maeda㧦"Reduction of Neptunium(VI) by Butyraldehyde Isomers
in Nitric Acid Solution", Nucl. Technol., 122, p.222 (1998).
47) G.Uchiyama, S.Fujine, S.Hotoku and M.Maeda㧦"New Separation Process for Neptunium, Plutonium,
and Uranium Using Butyraldehydes as Reductants in Reprocessing", Nucl. Technol., 102, p.341(1993).
48) T.W.Newton㧦"The Kinetics of the Oxidation-Reduction Reactions of Uranium, Neptunium,
Plutonium, and Americium in Aqueous Solutions", TID-26506 (1975).
49) L.Stieglitz and R.Becker㧦"Chemical and Radiolytic Solvent Degradation in the Purex Process",
Nukleare Entsorgung, Band 2 (Proc. of the Seminar "Reprocessing of Breeder Fuel"), Verlag Chemie,
p.333 (1983).
50) G.L.Richardson, "The Effect of High Solvent Radiation Exposures on TBP Processing of SpentLMFBR Fuels", HEDL-TME 73-51 (1973).
51) ቲᓼᔋ‫ᧁޔ‬ේᱞᒄ‫ޔ‬ౝጊァ⬿‫⮮ޔ‬ᩮᐘ㓶‫ޔ‬೨↰ల㧦"੝⎣㉄ߩౣಣℂṁᶧਛߢߩಽ㈩ᐔⴧ",JAERI-M 93-095 (1993).
52) K.Alcock, F.C.Bedford, W.H.Hardwick, H.A.C.McKay㧦"Tri-n-butyl Phosphate as an Extracting
Solvent for Inorganic Nitrates - I Zirconium Nitrate", J. Inorg. Nucl. Chem., 4, p.100 (1957).
53) Hanford Atomic Products Operation㧦"Purex Technical Manual", HW-31000, Chapter 4-C (1955).
54) Z.Kolarik and P.Dressler㧦"Extraction and Coextraction of Tc(VII), Zr(IV), Np(IV,VI), Pa(V) and122

Nb(V) with Tributyl Phosphate from Nitric Acid Solutions", Solv. Extra. and Ion Exch., 7, p.625(1989).
55) G.Petrich㧦"The 1981 Purex Distribution Data Index" , KfK-3080 (1981).
56) A.D.Kelmers and D.N.Browning䋺"Hydrazoic Acid Distribution between TBP-Dodecane and Nitric
Acid Solutions", Inorg. Nucl. Chem. Letters, 13, p.505 (1977).
57) G.Uchiyama, S.Hotoku, S.Fujine and M.Maeda㧦"Distribution of n- and iso-Butyraldehydes Between
Tri-n-Butyl Phosphate / n-Dodecane and Nitric Acid", Solv. Ext. and Ion Exch., 15, p.863 (1997).
58) A.Kumar, A.C.Deb, S.K.Mukerjee, V.N.Vaidya, D.D.Sood䋺"Distribution of Pu(VI) from Nitric Acid
to Tri-n-butyl Phosphate Saturated with Uranium(VI)", J. Radioanal. Nucl. Chem., 240, p.375 (1999).
59) C.J.Hardy and D.Scargill㧦"Studies on Mono- and Di-n-Butylphosphoric Acids - II The Solubility
and Distribution of Mono- and Di-n-butylphosphoric Acids in Aqueous-Organic Solvent Systems", J.
Inorg. Nucl. Chem., 11, p.128 (1959).
60) ㇺୖା᮸㧦"ࠝ࡯࠻ࡑ࠻ࡦߣᒻᑼ⸒⺆", ᤘᤩၴ (1995). ઁ61) ᶆᤘੑ㧦"FORTRAN 77 ౉㐷 ᡷ⸓", ၭ㘑㙚 (1990). ઁ62) M.Benedict, T.H.Pigford, H.W.Levi㧔⪺㧕‫ޔ‬ᷡἑ㊂ᐔ㧔⸶㧕㧦"Άᢱౣಣℂߣ᡼኿ᕈᑄ᫈‛▤ℂߩൻቇᎿቇ", ᣣೀᎿᬺᣂ⡞␠ (1983).
63) K.J.Schneider, et al.㧦"Technology, Safety, and Costs of Decommissioning a Reference Nuclear Fuel
Reprocessing Plant", NUREG-0278 (1977).

123ઃ㍳ ࠛ࡜࡯ࠦ࡯࠼⴫
ฦࠨࡉ࡞࡯࠴ࡦ㑐ᢙߩࠛ࡜࡯ࠦ࡯࠼‫ߩ࠼࡯ࠦ࡯࡜ࠛޔ‬ᄌᢙฬ‫ߩ࡯࡜ࠛޔ‬ౝኈࠍਅ⸥ߩฦᰣߦ␜
ߔ‫ޔߦᤨ↢⊒࡯࡜ࠛޕ‬᜛ᒛሶ߇ ".err" ߢ޽ࠆ࠹ࠠࠬ࠻ࡈࠔࠗ࡞ߦ಴ജߐࠇࠆ‫ޕ‬
㧔㧝㧕SlvFlw (system.c)
100000SLVFLW0᳓⋧ࡈࠖ࡯࠼ߩធ⛯వ߇᦭ᯏ⋧࠲ࡦࠢߢ޽ࠆ‫ޕ‬

100001SLVFLW1

ࡔ࠶ࠪࡘࠞ࠙ࡦ࠲ icount ߩ୯߇ోࡔ࠶ࠪࡘᢙ n ࠍ⿧߃ߚ‫ޕ‬

100002SLVFLW2

ࠦࡦࡐ࡯ࡀࡦ࠻ߩ᳓⋧಴ญߩធ⛯వ߇᦭ᯏ⋧࠲ࡦࠢߢ޽ࠆ‫ޕ‬

100003SLVFLW3

᦭ᯏ⋧ࡈࠖ࡯࠼ߩធ⛯వ߇᳓⋧࠲ࡦࠢߢ޽ࠆ‫ޕ‬

100004SLVFLW4ࡔ࠶ࠪࡘࠞ࠙ࡦ࠲ icount ߩ୯߇ోࡔ࠶ࠪࡘᢙ n ࠍ⿧߃ߚ‫ޕ‬

100005SLVFLW5ࠦࡦࡐ࡯ࡀࡦ࠻ߩ᦭ᯏ⋧಴ญߩធ⛯వ߇᳓⋧࠲ࡦࠢߢ޽ࠆ‫ޕ‬

㧔㧞㧕Systm (system.c)
101000SYSTM0৻ߟߩࡔ࠶ࠪࡘߦ౉ࠆ᳓⋧ᵹ౉ᢙߩࠞ࠙ࡦ࠲ icount ߩ୯߇‫ޔ‬ᵹ౉ᢙߩᦨ
ᄢ୯ ns ࠍ⿧߃ߚ‫ޕ‬

101001

SYSTM1৻ߟߩࡔ࠶ࠪࡘߦ౉ࠆ᳓⋧ᵹ౉ᢙߩࠞ࠙ࡦ࠲ icount ߩ୯߇‫ޔ‬ᵹ౉ᢙߩᦨ
ᄢ୯ ns ࠍ⿧߃ߚ‫ޕ‬

101002

SYSTM2৻ߟߩࡔ࠶ࠪࡘߦ౉ࠆ᦭ᯏ⋧ᵹ౉ᢙߩࠞ࠙ࡦ࠲ icount ߩ୯߇‫ޔ‬ᵹ౉ᢙߩᦨᄢ୯ ns ࠍ⿧߃ߚ‫ޕ‬

101003

SYSTM3৻ߟߩࡔ࠶ࠪࡘߦ౉ࠆ᦭ᯏ⋧ᵹ౉ᢙߩࠞ࠙ࡦ࠲ icount ߩ୯߇‫ޔ‬ᵹ౉ᢙߩᦨᄢ୯ ns ࠍ⿧߃ߚ‫ޕ‬

101004

SYSTM4nMemSiz ߢ⏕଻ߒߚࡔࡕ࡝߇ਇ⿷ߒߡ޿ࠆ‫ޕ‬

101005

SYSTM5nMemSiz ߢ⏕଻ߒߚࡔࡕ࡝߇ਇ⿷ߒߡ޿ࠆ‫ޕ‬

㧔㧟㧕ChgNmr (chgnmr.c)
102000CHGNMR0᳓⋧ࡈࠖ࡯࠼ߩᵈ౉వߩࠦࡦࡐ࡯ࡀࡦ࠻ ID ߦ৻⥌ߔࠆࠦࡦࡐ࡯ࡀࡦ࠻
ID ߇⷗ߟ߆ࠄߥ޿‫ޕ‬

102001CHGNMR1᦭ᯏ⋧ࡈࠖ࡯࠼ߩᵈ౉వߩࠦࡦࡐ࡯ࡀࡦ࠻ ID ߦ৻⥌ߔࠆࠦࡦࡐ࡯ࡀࡦ
࠻ ID ߇⷗ߟ߆ࠄߥ޿‫ޕ‬

102002CHGNMR2ࠦࡦࡐ࡯ࡀࡦ࠻ߩ᳓⋧಴ญߩᵈ౉వߩࠦࡦࡐ࡯ࡀࡦ࠻ ID ߦ৻⥌ߔࠆࠦࡦࡐ࡯ࡀࡦ࠻ ID ߇⷗ߟ߆ࠄߥ޿‫ޕ‬

102003

CHGNMR3ࠦࡦࡐ࡯ࡀࡦ࠻ߩ᦭ᯏ⋧಴ญߩᵈ౉వߩࠦࡦࡐ࡯ࡀࡦ࠻ ID ߦ৻⥌ߔࠆࠦࡦࡐ࡯ࡀࡦ࠻ ID ߇⷗ߟ߆ࠄߥ޿‫ޕ‬㧔㧠㧕prodm2m (matrixop.c)
103000PRODM2M0ⴕ೉߹ߚߪㇱಽⴕ೉ߩࠨࠗ࠭߇ਇᴺߢ޽ࠆ‫ޕ‬124

㧔㧡㧕prod2mm (matrixop.c)
104000ⴕ೉߹ߚߪㇱಽⴕ೉ߩࠨࠗ࠭߇ਇᴺߢ޽ࠆ‫ޕ‬

PROD2MM0㧔㧢㧕DecomB (solverb.c)
105000DECOMB0ࡉࡠ࠶ࠢਃ㊀ኻⷺߩ߁ߜਛᄩߩࡉࡠ࠶ࠢߩㅒⴕ೉ࠍ᳞߼ࠆߣ߈ߦࠛ࡜
࡯߇⊒↢ߒߚ‫ޕ‬105002DECOMB2ࡉࡠ࠶ࠢਃ㊀ኻⷺߩ߁ߜਛᄩߩࡉࡠ࠶ࠢߩㅒⴕ೉ߣฝ஥ߩࡉࡠ࠶ࠢߩ
Ⓧࠍ૞ࠆߣ߈ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬105003

DECOMB3

ࡉࡠ࠶ࠢਃ㊀ኻⷺߩ߁ߜਛᄩߩࡉࡠ࠶ࠢߩㅒⴕ೉ߣฝ஥ߩࡉࡠ࠶ࠢߩ
Ⓧࠍฝ஥ߩࡉࡠ࠶ࠢ㈩೉ߦࠦࡇ࡯ߔࠆߣ߈ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬105005DECOMB5

ࡉࡠ࠶ࠢਃ㊀ኻⷺߩ߁ߜᏀ஥ߩࡉࡠ࠶ࠢߣฝ஥ߩࡉࡠ࠶ࠢߩⓍࠍ૞ࠆߣ߈ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬105006DECOMB6

ࡉࡠ࠶ࠢਃ㊀ኻⷺߩ߁ߜᏀ஥ߩࡉࡠ࠶ࠢߣฝ஥ߩࡉࡠ࠶ࠢߩⓍࠍਛᄩߩࡉࡠ࠶ࠢ߆ࠄᒁߊߣ߈ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬105007DECOMB7

ࡉࡠ࠶ࠢਃ㊀ኻⷺߩ߁ߜਛᄩߩࡉࡠ࠶ࠢߩㅒⴕ೉ࠍ᳞߼ࠆߣ߈ߦࠛ࡜
࡯߇⊒↢ߒߚ‫ޕ‬

㧔㧣㧕SolveB (solverb.c)
106000SOLVEB0

LU ಽ⸃ᓟߩࡉࡠ࠶ࠢਃ㊀ኻⷺߩ߁ߜਛᄩߩࡉࡠ࠶ࠢߩㅒⴕ೉ߣᣇ⒟ᑼߩฝㄝߩቯᢙࡌࠢ࠻࡞ߩⓍࠍ૞ࠆߣ߈ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬106001SOLVEB1

ࡢ࡯ࠢ㈩೉߆ࠄᣇ⒟ᑼߩฝㄝߩࡌࠢ࠻࡞ߩ㈩೉߳୯ࠍࠦࡇ࡯ߔࠆߣ߈
ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬106003SOLVEB3

LU ಽ⸃ᓟߩࡉࡠ࠶ࠢਃ㊀ኻⷺߩᏀ஥ߩࡉࡠ࠶ࠢߣᣇ⒟ᑼߩฝㄝߩࡌ
ࠢ࠻࡞ߩⓍࠍ૞ࠆߣ߈ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬106004SOLVEB4

ᣇ⒟ᑼߩฝㄝߩࡌࠢ࠻࡞߆ࠄࡢ࡯ࠢ㈩೉㧔ࡌࠢ࠻࡞㧕ࠍᒁߊߣ߈ߦࠛ
࡜࡯߇⊒↢ߒߚ‫ޕ‬106005SOLVEB5

LU ಽ⸃ᓟߩࡉࡠ࠶ࠢਃ㊀ኻⷺߩ߁ߜ⌀ࠎਛߩࡉࡠ࠶ࠢߩㅒⴕ೉ߣᣇ⒟ᑼߩฝㄝߩࡌࠢ࠻࡞ߩⓍࠍ૞ࠆߣ߈ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬106006SOLVEB6

ࡢ࡯ࠢࡌࠢ࠻࡞߆ࠄᣇ⒟ᑼߩฝㄝߩࡌࠢ࠻࡞ߦ୯ࠍࠦࡇ࡯ߔࠆߣ߈ߦ
ࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬106007SOLVEB7

LU ಽ⸃ᓟߩࡉࡠ࠶ࠢਃ㊀ኻⷺߩ߁ߜฝ஥ߩࡉࡠ࠶ࠢߣᣇ⒟ᑼߩฝㄝ
ߩࡌࠢ࠻࡞ߩⓍࠍ૞ࠆߣ߈ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬106008SOLVEB8

ᣇ⒟ᑼߩฝㄝߩࡌࠢ࠻࡞߆ࠄ‫ޔ‬LU ಽ⸃ᓟߩࡉࡠ࠶ࠢਃ㊀ኻⷺߩฝ஥ߩ
ࡉࡠ࠶ࠢߣᣇ⒟ᑼߩฝㄝߩࡌࠢ࠻࡞ߩⓍࠍᒁߊߣ߈ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬106009SOLVEB9

Capacitance matrix ᴺߩ E ⴕ೉ߩㇱಽⴕ೉ߩ࠯ࡠࠢ࡝ࠕߩ㓙ߦࠛ࡜࡯߇

125

⊒↢ߒߚ‫ޕ‬
106010SOLVEB10

LU ಽ ⸃ ᓟ ߩ ࡉ ࡠ ࠶ ࠢ ਃ ㊀ ኻ ⷺ ߩ ਛ ᄩ ߩ ࡉ ࡠ ࠶ ࠢ ߩ ㅒ ⴕ ೉ ࠍ ‫ޔ‬Capacitance matrix ᴺߩ E ⴕ೉ߩㇱಽⴕ೉ߦࠦࡇ࡯ߔࠆ㓙ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

106011SOLVEB11

LU ಽ⸃ᓟߩࡉࡠ࠶ࠢਃ㊀ኻⷺߩᏀ஥ߩࡉࡠ࠶ࠢߣ‫ޔ‬Capacitance matrix
ᴺߩ E ⴕ೉ߩㇱಽⴕ೉ߩⓍࠍ⸘▚ߔࠆߣ߈ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

106012SOLVEB12

LU ಽ⸃ᓟߩࡉࡠ࠶ࠢਃ㊀ኻⷺߩਛᄩߩࡉࡠ࠶ࠢߩㅒⴕ೉ߣࡢ࡯ࠢ㈩೉ߩⓍࠍ૞ࠆߣ߈ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

106013SOLVEB13

Capacitance matrix ᴺߩ E ⴕ೉ߩㇱಽⴕ೉ߩ╓ภࠍᄌ߃ࠆߣ߈ߦࠛ࡜࡯
߇⊒↢ߒߚ‫ޕ‬

106014SOLVEB14

LU ಽ⸃ᓟߩਃ㊀ኻⷺߩฝ஥ߩࡉࡠ࠶ࠢߣ‫ޔ‬Capacitance matrix ᴺߩ E ⴕ೉ߩㇱಽⴕ೉㧔forward substitution ߩᓟߩ㧕ߣߩⓍࠍ૞ࠆߣ߈ߦࠛ࡜࡯
߇⊒↢ߒߚ‫ޕ‬

106015SOLVEB15

Capacitance matrix ᴺߩ E ⴕ೉ߩㇱಽⴕ೉㧔forward substitution ߩᓟߩ㧕
ߣࡢ࡯ࠢ㈩೉ߩᏅࠍ૞ࠆߣ߈ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

106016SOLVEB16

ᣇ⒟ᑼߩฝㄝߩࡌࠢ࠻࡞ߦࡉࡠ࠶ࠢਃ㊀ኻⷺⴕ೉ߩㅒⴕ೉ࠍដߌߚ߽ߩߦ‫ ߦࠄߐޔ‬Capacitance matrix ᴺߩ R ⴕ೉ࠍដߌߚ߽ߩߩ଻ሽ↪ߩࡢ࡯ࠢ㈩೉ߩ࠯ࡠࠢ࡝ࠕߩ㓙ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

106017SOLVEB17

ᣇ⒟ᑼߩฝㄝߩࡌࠢ࠻࡞ߦࡉࡠ࠶ࠢਃ㊀ኻⷺⴕ೉ߩㅒⴕ೉ࠍដߌߚ߽
ߩߦ‫ޔ‬Capacitance matrix ᴺߩ R ⴕ೉ࠍដߌࠆߣ߈ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬㧔ㇱಽࡌࠢ࠻࡞ߣㇱಽⴕ೉ߩⓍ㧕

106018SOLVEB18

ᣇ⒟ᑼߩฝㄝߩࡌࠢ࠻࡞ߦࡉࡠ࠶ࠢਃ㊀ኻⷺⴕ೉ߩㅒⴕ೉ࠍដߌߚ߽
ߩߣ‫ޔ‬Capacitance matrix ᴺߩ R ⴕ೉ߩⓍ㧔ㇱಽࡌࠢ࠻࡞ߣㇱಽⴕ೉ߩⓍ㧕ࠍࡢ࡯ࠢ㈩೉ߦട߃ࠆߣ߈ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

106019SOLVEB19

ࡉࡠ࠶ࠢਃ㊀ኻⷺⴕ೉ߩㅒⴕ೉ߣ Capacitance matrix ᴺߩ E ⴕ೉ߩⓍߦ
หᴺߩ R ⴕ೉ࠍដߌߚ߽ߩࠍ⫾߃ࠆࡢ࡯ࠢ㈩೉ߩ࠯ࡠࠢ࡝ࠕߩ㓙ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬106021SOLVEV21ࡉࡠ࠶ࠢਃ㊀ኻⷺⴕ೉ߩㅒⴕ೉ߣ Capacitance matrix ᴺߩ E ⴕ೉ߩⓍߦ‫ޔ‬หᴺߩ R ⴕ೉ࠍដߌࠆߣ߈ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬㧔ㇱಽⴕ೉ߣㇱಽ
ⴕ೉ߩⓍ㧕

106022SOLVEB22

Capacitance matrix ߩ LU ಽ⸃ߩߣ߈ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬106023SOLVEB23

ᣇ⒟ᑼߩฝㄝߩࡌࠢ࠻࡞ߦࡉࡠ࠶ࠢਃ㊀ኻⷺⴕ೉ߩㅒⴕ೉ࠍដߌ‫ߐޔ‬ࠄߦ Capacitance matrix ᴺߩ R ⴕ೉ࠍដߌߚ߽ߩߦ Capacitance matrix ߩㅒⴕ೉ࠍដߌࠆߣ߈ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬106024SOLVEB24

Capacitance matrix ᴺߩ E ⴕ೉ߦࡉࡠ࠶ࠢਃ㊀ኻⷺⴕ೉ߩㅒⴕ೉ࠍដߌ
ߚ߽ߩࠍ‫ޔ‬Capacitance matrix ᴺߩ y ࡌࠢ࠻࡞ߦដߌࠆߣ߈ߦࠛ࡜࡯߇
⊒↢ߒߚ‫ޕ‬㧔ㇱಽⴕ೉ߣㇱಽࡌࠢ࠻࡞ߩⓍ㧕

126

106025

SOLVEB25

ᣇ⒟ᑼߩฝㄝߩࡌࠢ࠻࡞ߦࡉࡠ࠶ࠢਃ㊀ኻⷺⴕ೉ߩㅒⴕ೉ࠍដߌߚ߽
ߩ߆ࠄ‫ޔ‬Capacitance matrix ᴺߩ E ⴕ೉ߦࡉࡠ࠶ࠢਃ㊀ኻⷺⴕ೉ߩㅒⴕ
೉ࠍដߌߚ߽ߩߣ Capacitance matrix ᴺߩ y ࡌࠢ࠻࡞ߩⓍࠍᒁߊߣ߈ߦ
ࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬㧔ㇱಽࡌࠢ࠻࡞ߩᏅ㧕

㧔㧤㧕MakPhi (makephi.c)
108000

MAKPHI0ࡄ࡞ࠬࠞ࡜ࡓߢߩಽᢔ⋧ߣㅪ⛯⋧ߩࡎ࡯࡞࠼ࠕ࠶ࡊࠍ⸘▚ߔࠆ㓙ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

㧔㧥㧕PhiP (makephi.c)
109000PHIP0ಽᢔ⋧ߩᜰ␜ሶ idisp ߦ⇣Ᏹߥ୯߇౉ߞߡ޿ࠆ‫ޕ‬

㧔㧝㧜㧕MakeE (mekee.c)
110000

MAKEE0ࡄ࡞ࠬࠞ࡜ࡓߩㅒᷙวଥᢙߩ⸘▚ߩ㓙ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬㧔㧝㧝㧕DispCo (makee.c)
111000DISPCO0ಽᢔ⋧ߩᜰ␜ሶ idisp ߦ⇣Ᏹߥ୯߇౉ߞߡ޿ࠆ‫ޕ‬

㧔㧝㧞㧕MakeSa (makesa.c)
112000

MAKESA0ࡄ࡞ࠬࠞ࡜ࡓߢߩੑ⋧ߩ⇇㕙Ⓧࠍ⸘▚ߔࠆߣ߈ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

112001

MAKESA1

ࡒࠠࠨ࠮࠻࡜ߢߩੑ⋧ߩ⇇㕙Ⓧࠍ⸘▚ߔࠆߣ߈ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬㧔㧝㧟㧕SaP (makesa.c)
113000SAP0ಽᢔ⋧ߩᜰ␜ሶ idisp ߦ⇣Ᏹߥ୯߇౉ߞߡ޿ࠆ‫ޕ‬㧔㧝㧠㧕SaM (makesa.c)
114000SAM0ಽᢔ⋧ߩᜰ␜ሶ idisp ߦ⇣Ᏹߥ୯߇౉ߞߡ޿ࠆ‫ޕ‬

㧔㧝㧡㧕MakeCC (makecc.c)
115000

MAKECC0ࡄ࡞ࠬࠞ࡜ࡓߩ‛⾰⒖േ㗄ߣൻቇ෻ᔕ㗄એᄖߩଥᢙࠍ᳞߼ࠆ㓙ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

115001

MAKECC1

ࡒࠠࠨ࠮࠻࡜ߩ‛⾰⒖േ㗄ߣൻቇ෻ᔕ㗄એᄖߩଥᢙࠍ᳞߼ࠆ㓙ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

115002

MAKECC2⇣Ᏹߥࠦࡦࡐ࡯ࡀࡦ࠻ဳ߇⃻ࠇߚ‫ޕ‬㧔㧝㧢㧕CcP (makecc.c)
116000CCP0࡞࡯ࡊᄌᢙߩ୯߇ࡔ࠶ࠪࡘᢙߢ᳿߹ࠆ▸࿐ߩᄖߦ಴ߚ‫ޕ‬127

116001

CCP1

ࡔ࠶ࠪࡘߩဳࠍ␜ߔᄌᢙ icase ߇⇣Ᏹߥ୯ߢ޽ࠆ‫ޕ‬㧔㧝㧣㧕CcM (makecc.c)
117000CCM0࡞࡯ࡊᄌᢙߩ୯߇ࡔ࠶ࠪࡘᢙߢ᳿߹ࠆ▸࿐ߩᄖߦ಴ߚ‫ޕ‬

117001CCM1ࡔ࠶ࠪࡘߩဳࠍ␜ߔᄌᢙ icase ߇⇣Ᏹߥ୯ߢ޽ࠆ‫ޕ‬

㧔㧝㧤㧕ReactZ (reactz.c)
121000

REACTZ0᳓⋧ߩൻቇ෻ᔕ㗄↪ߩ㈩೉ߩ࠯ࡠࠢ࡝ࠕߩ㓙ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

121001

REACTZ1

᦭ᯏ⋧ߩൻቇ෻ᔕ㗄↪ߩ㈩೉ߩ࠯ࡠࠢ࡝ࠕߩ㓙ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

121002

REACTZ2

᳓⋧ߩൻቇ෻ᔕ㗄ߩᓸಽଥᢙ↪ߩ㈩೉ߩ࠯ࡠࠢ࡝ࠕߩ㓙ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

121003

REACTZ3

᦭ᯏ⋧ߩൻቇ෻ᔕ㗄ߩᓸಽଥᢙ↪ߩ㈩೉ߩ࠯ࡠࠢ࡝ࠕߩ㓙ߦࠛ࡜࡯߇
⊒↢ߒߚ‫ޕ‬121004

REACTZ4

᳓⋧ߩൻቇ෻ᔕ㗄ߣᓸಽଥᢙࠍ᳞߼ࠆ㓙ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬㧔⚵ㄟᑼ㧕

121005

REACTZ5

᦭ᯏ⋧ߩൻቇ෻ᔕ㗄ߣᓸಽଥᢙࠍ᳞߼ࠆ㓙ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬㧔⚵ㄟᑼ㧕

121006

REACTZ6

᳓⋧ߩൻቇ෻ᔕ㗄↪ߩ㈩೉ߩ࠯ࡠࠢ࡝ࠕߩ㓙ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

121007

REACTZ7

᳓⋧ߩൻቇ෻ᔕ㗄ߩᓸಽଥᢙ↪ߩ㈩೉ߩ࠯ࡠࠢ࡝ࠕߩ㓙ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

121008

REACTZ8

᳓⋧ߩൻቇ෻ᔕ㗄ߣᓸಽଥᢙࠍ᳞߼ࠆ㓙ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬㧔⚵ㄟᑼ㧕

121009REACTZ9᳓⋧ߩൻቇ෻ᔕ㗄ߩᓸಽଥᢙ↪ߩ㈩೉ߩ࠯ࡠࠢ࡝ࠕߩ㓙ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

121010

REACTZ10᦭ᯏ⋧ߩൻቇ෻ᔕ㗄ߩᓸಽଥᢙ↪ߩ㈩೉ߩ࠯ࡠࠢ࡝ࠕߩ㓙ߦࠛ࡜࡯߇
⊒↢ߒߚ‫ޕ‬121011

REACTZ11᦭ᯏ⋧ߩൻቇ෻ᔕ㗄ߣᓸಽଥᢙࠍ᳞߼ࠆ㓙ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬㧔⚵ㄟᑼ㧕

121012

REACTZ12᳓⋧ߣ᦭ᯏ⋧ߩ⚵ߺวࠊߖߩဳ iChem ߦ⇣Ᏹߥ୯߇౉ߞߡ޿ࠆ‫ޕ‬

121013

REACTZ13

ࠗࡦ࠲ࡊ࡝࠲ߦࠃࠆ᳓⋧ߩൻቇ෻ᔕ㗄ߣᓸಽଥᢙߩ⸘▚ߢࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

121014

REACTZ14

ࠗࡦ࠲ࡊ࡝࠲ߦࠃࠆ᦭ᯏ⋧ߩൻቇ෻ᔕ㗄ߣᓸಽଥᢙߩ⸘▚ߢࠛ࡜࡯߇
⊒↢ߒߚ‫ޕ‬121015

REACTZ15

ࠗࡦ࠲ࡊ࡝࠲ߦࠃࠆ᳓⋧ߩൻቇ෻ᔕ㗄ߣᓸಽଥᢙߩ⸘▚ߢࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

121016

REACTZ16

ࠗࡦ࠲ࡊ࡝࠲ߦࠃࠆ᦭ᯏ⋧ߩൻቇ෻ᔕ㗄ߣᓸಽଥᢙߩ⸘▚ߢࠛ࡜࡯߇
⊒↢ߒߚ‫ޕ‬128

㧔㧝㧥㧕MassTr (masstr.c)
124000ಽ㈩Ყߣߘߩᓸಽଥᢙߩ⸘▚ߢࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬MASSTR0㧔㧞㧜㧕MssTr2 (msstr.c)
125000MSSTR20

ಽ㈩Ყߣߘߩᓸಽଥᢙߩ⸘▚ߢࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬㧔㧞㧝㧕Distri (masstr.c)
126000

DISTRI0ࡈ࡝࡯TBP ߩ 0 ਸ਼ߦኻᔕߔࠆ⷗߆ߌߩᐔⴧቯᢙߩ㈩೉ߩ࠯ࡠࠢ࡝ࠕߢࠛ
࡜࡯߇⊒↢ߒߚ‫ޕ‬

126001

DISTRI1

ࡈ࡝࡯TBP ߩ 1 ਸ਼ߦኻᔕߔࠆ⷗߆ߌߩᐔⴧቯᢙߩ㈩೉ߩ࠯ࡠࠢ࡝ࠕߢࠛ
࡜࡯߇⊒↢ߒߚ‫ޕ‬

126002

DISTRI2

ࡈ࡝࡯TBP ߩ 2 ਸ਼ߦኻᔕߔࠆ⷗߆ߌߩᐔⴧቯᢙߩ㈩೉ߩ࠯ࡠࠢ࡝ࠕߢࠛ
࡜࡯߇⊒↢ߒߚ‫ޕ‬

126003

DISTRI3

ࡈ࡝࡯TBP ߩ 3 ਸ਼ߦኻᔕߔࠆ⷗߆ߌߩᐔⴧቯᢙߩ㈩೉ߩ࠯ࡠࠢ࡝ࠕߢࠛ
࡜࡯߇⊒↢ߒߚ‫ޕ‬

126004

DISTRI4

ࡈ࡝࡯TBP ߩ 0 ਸ਼ߦኻᔕߔࠆ⷗߆ߌߩᐔⴧቯᢙߩ⎣㉄ᩮߦࠃࠆ 1 㓏ᓸಽଥᢙ↪ߩ㈩೉ߩ࠯ࡠࠢ࡝ࠕߢࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

126005

DISTRI5

ࡈ࡝࡯TBP ߩ 1 ਸ਼ߦኻᔕߔࠆ⷗߆ߌߩᐔⴧቯᢙߩ⎣㉄ᩮߦࠃࠆ 1 㓏ᓸಽଥᢙ↪ߩ㈩೉ߩ࠯ࡠࠢ࡝ࠕߢࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

126006

DISTRI6

ࡈ࡝࡯TBP ߩ 2 ਸ਼ߦኻᔕߔࠆ⷗߆ߌߩᐔⴧቯᢙߩ⎣㉄ᩮߦࠃࠆ 1 㓏ᓸಽଥᢙ↪ߩ㈩೉ߩ࠯ࡠࠢ࡝ࠕߢࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

126007

DISTRI7

ࡈ࡝࡯TBP ߩ 3 ਸ਼ߦኻᔕߔࠆ⷗߆ߌߩᐔⴧቯᢙߩ⎣㉄ᩮߦࠃࠆ 1 㓏ᓸಽଥᢙ↪ߩ㈩೉ߩ࠯ࡠࠢ࡝ࠕߢࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

126008

DISTRI8

ࡈ࡝࡯TBP ߩ 0 ਸ਼ߦኻᔕߔࠆ⷗߆ߌߩᐔⴧቯᢙߩ⎣㉄ᩮߦࠃࠆ 2 㓏ᓸಽଥᢙ↪ߩ㈩೉ߩ࠯ࡠࠢ࡝ࠕߢࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

126009

DISTRI9

ࡈ࡝࡯TBP ߩ 1 ਸ਼ߦኻᔕߔࠆ⷗߆ߌߩᐔⴧቯᢙߩ⎣㉄ᩮߦࠃࠆ 2 㓏ᓸಽଥᢙ↪ߩ㈩೉ߩ࠯ࡠࠢ࡝ࠕߢࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

126010

DISTRI10

ࡈ࡝࡯TBP ߩ 2 ਸ਼ߦኻᔕߔࠆ⷗߆ߌߩᐔⴧቯᢙߩ⎣㉄ᩮߦࠃࠆ 2 㓏ᓸಽଥᢙ↪ߩ㈩೉ߩ࠯ࡠࠢ࡝ࠕߢࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

126011

DISTRI11

ࡈ࡝࡯TBP ߩ 3 ਸ਼ߦኻᔕߔࠆ⷗߆ߌߩᐔⴧቯᢙߩ⎣㉄ᩮߦࠃࠆ 2 㓏ᓸಽଥᢙ↪ߩ㈩೉ߩ࠯ࡠࠢ࡝ࠕߢࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

126012

DISTRI12

ࡈ࡝࡯TBP ߩ 0 ਸ਼ߦኻᔕߔࠆ⷗߆ߌߩᐔⴧቯᢙߩฦൻቇ⒳ߦࠃࠆ 1 㓏ᓸಽଥᢙ↪ߩ㈩೉ߩ࠯ࡠࠢ࡝ࠕߢࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

126013

DISTRI13

ࡈ࡝࡯TBP ߩ 1 ਸ਼ߦኻᔕߔࠆ⷗߆ߌߩᐔⴧቯᢙߩฦൻቇ⒳ߦࠃࠆ 1 㓏ᓸಽଥᢙ↪ߩ㈩೉ߩ࠯ࡠࠢ࡝ࠕߢࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

126014

DISTRI14

ࡈ࡝࡯TBP ߩ 2 ਸ਼ߦኻᔕߔࠆ⷗߆ߌߩᐔⴧቯᢙߩฦൻቇ⒳ߦࠃࠆ 1 㓏ᓸ

129ಽଥᢙ↪ߩ㈩೉ߩ࠯ࡠࠢ࡝ࠕߢࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬
126015

DISTRI15

ࡈ࡝࡯TBP ߩ 3 ਸ਼ߦኻᔕߔࠆ⷗߆ߌߩᐔⴧቯᢙߩฦൻቇ⒳ߦࠃࠆ 1 㓏ᓸಽଥᢙ↪ߩ㈩೉ߩ࠯ࡠࠢ࡝ࠕߢࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

126016

DISTRI16

ࡈ࡝࡯TBP ߩỚᐲࠍ᳞߼ࠆߚ߼ߩ 2 ᰴᣇ⒟ᑼߢ‫࡯࡝ࡈޔ‬TBP ߩ 2 ਸ਼ߩଥᢙߦߥߞߡ޿ࠆ㊂ߩ‫ޔ‬ฦൻቇ⒳ߦࠃࠆ 1 㓏ᓸಽଥᢙ↪ߩ㈩೉ߩ࠯ࡠࠢ࡝
ࠕߢࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

126017

DISTRI17

ࡈ࡝࡯TBP ߩỚᐲࠍ᳞߼ࠆߚ߼ߩ 2 ᰴᣇ⒟ᑼߢ‫࡯࡝ࡈޔ‬TBP ߩ 1 ਸ਼ߩଥᢙߦߥߞߡ޿ࠆ㊂ߩ‫ޔ‬ฦൻቇ⒳ߦࠃࠆ 1 㓏ᓸಽଥᢙ↪ߩ㈩೉ߩ࠯ࡠࠢ࡝
ࠕߢࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

126018

DISTRI18

ಽ㈩Ყߩฦൻቇ⒳ߦࠃࠆ 1 㓏ᓸಽଥᢙ↪ߩ㈩೉ߩ࠯ࡠࠢ࡝ࠕߢࠛ࡜࡯߇
⊒↢ߒߚ‫ޕ‬126019

DISTRI19

ࡈ࡝࡯TBP ߩ 0 ਸ਼ߦኻᔕߔࠆ⷗߆ߌߩᐔⴧቯᢙߩ‫ޔ‬ฦൻቇ⒳ߦࠃࠆ 2 㓏ᓸಽଥᢙ↪ߩ㈩೉ߩ࠯ࡠࠢ࡝ࠕߢࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

126020

DISTRI20

ࡈ࡝࡯TBP ߩ 1 ਸ਼ߦኻᔕߔࠆ⷗߆ߌߩᐔⴧቯᢙߩ‫ޔ‬ฦൻቇ⒳ߦࠃࠆ 2 㓏ᓸಽଥᢙ↪ߩ㈩೉ߩ࠯ࡠࠢ࡝ࠕߢࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

126021

DISTRI21

ࡈ࡝࡯TBP ߩ 2 ਸ਼ߦኻᔕߔࠆ⷗߆ߌߩᐔⴧቯᢙߩ‫ޔ‬ฦൻቇ⒳ߦࠃࠆ 2 㓏ᓸಽଥᢙ↪ߩ㈩೉ߩ࠯ࡠࠢ࡝ࠕߢࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

126022

DISTRI22

ࡈ࡝࡯TBP ߩ 3 ਸ਼ߦኻᔕߔࠆ⷗߆ߌߩᐔⴧቯᢙߩ‫ޔ‬ฦൻቇ⒳ߦࠃࠆ 2 㓏ᓸಽଥᢙ↪ߩ㈩೉ߩ࠯ࡠࠢ࡝ࠕߢࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

126023

DISTRI23

ࡈ࡝࡯TBP ߩỚᐲࠍ᳞߼ࠆߚ߼ߩ 2 ᰴᣇ⒟ᑼߢ‫࡯࡝ࡈޔ‬TBP ߩ 2 ਸ਼ߩଥᢙߦߥߞߡ޿ࠆ㊂ߩ‫ޔ‬ฦൻቇ⒳ߦࠃࠆ 2 㓏ᓸಽଥᢙ↪ߩ㈩೉ߩ࠯ࡠࠢ࡝
ࠕߢࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

126024

DISTRI24

ࡈ࡝࡯TBP ߩỚᐲࠍ᳞߼ࠆߚ߼ߩ 2 ᰴᣇ⒟ᑼߢ‫࡯࡝ࡈޔ‬TBP ߩ 1 ਸ਼ߩଥᢙߦߥߞߡ޿ࠆ㊂ߩ‫ޔ‬ฦൻቇ⒳ߦࠃࠆ 2 㓏ᓸಽଥᢙ↪ߩ㈩೉ߩ࠯ࡠࠢ࡝
ࠕߢࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

126025

DISTRI25

ಽ㈩Ყߩฦൻቇ⒳ߦࠃࠆ 2 㓏ᓸಽଥᢙ↪ߩ㈩೉ߩ࠯ࡠࠢ࡝ࠕߢࠛ࡜࡯߇
⊒↢ߒߚ‫ޕ‬126026

DISTRI26

⷗߆ߌߩᐔⴧቯᢙߣߘࠇߩ⎣㉄ᩮߦࠃࠆฦ⒳ᓸಽଥᢙࠍ⸘▚ߔࠆ㓙ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

126027

DISTRI27

৻⥸⊛ߥ⴫⃻ߩಽ㈩Ყߣߘࠇߩฦൻቇ⒳ߦࠃࠆᓸಽଥᢙࠍ⸘▚ߔࠆ㓙ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

126028

DISTRI28

ࠗࡦ࠲ࡊ࡝࠲ߢ‫ߩߌ߆⷗ޔ‬ᐔⴧቯᢙߣߘࠇߩ⎣㉄ᩮߦࠃࠆฦ⒳ᓸಽଥᢙ
ࠍ⸘▚ߔࠆ㓙ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

126029

DISTRI29

ࠗࡦ࠲ࡊ࡝࠲ߢ‫ߩ⃻⴫ߥ⊛⥸৻ޔ‬ಽ㈩Ყߣߘࠇߩฦൻቇ⒳ߦࠃࠆᓸಽଥ
ᢙࠍ⸘▚ߔࠆ㓙ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬㧔㧞㧞㧕JacobP (make.c)130127000

JACOBP0࡞࡯ࡊᄌᢙߩ୯߇ 0 એ਄㧔ࡔ࠶ࠪࡘᢙ㧕㧙1 એਅߣ޿߁▸࿐ᄖߦߥߞߚ‫ޕ‬

127001

JACOBP1

ਔ⋧ߩൻቇ෻ᔕ㗄ߣߘߩᓸಽଥᢙࠍ⸘▚ߔࠆߣ߈ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬127002

JACOBP2‛⾰⒖േ㗄ߣߘߩᓸಽଥᢙࠍ⸘▚ߔࠆߣ߈ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

127007

JACOBP7

ਔ⋧ߩൻቇ෻ᔕ㗄ߣߘߩᓸಽଥᢙࠍ⸘▚ߔࠆߣ߈ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬127008

JACOBP8

ಽ⋧࠲ࡦࠢ↪ߦ‛⾰⒖േ㗄ߣߘߩᓸಽଥᢙࠍ⸘▚ߔࠆߣ߈ߦࠛ࡜࡯߇
⊒↢ߒߚ‫ޕ‬127015

JACOBP15

ਔ⋧ߩൻቇ෻ᔕ㗄ߣߘߩᓸಽଥᢙࠍ⸘▚ߔࠆߣ߈ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬127016

JACOBP16ಽ⋧࠲ࡦࠢ↪ߦ‛⾰⒖േ㗄ߣߘߩᓸಽଥᢙࠍ⸘▚ߔࠆߣ߈ߦࠛ࡜࡯߇
⊒↢ߒߚ‫ޕ‬127023

JACOBP23

ࡔ࠶ࠪࡘߩ⒳㘃㧔ౝㇱࡔ࠶ࠪࡘ‫ޔ‬ਅㇱಽ⋧࠲ࡦࠢ‫ޔ‬਄ㇱಽ⋧࠲ࡦࠢ㧕߇⇣Ᏹߢ޽ࠆ‫ޕ‬㧔㧞㧟㧕JacobM (make.c)
128000JACOBM0࡞࡯ࡊᄌᢙߩ୯߇ 0 એ਄㧔ࠬ࠹࡯ࠫᢙ㧕㧙1 એਅߣ޿߁▸࿐ᄖߦߥߞ
ߚ‫ޕ‬

128001

JACOBM1ਔ⋧ߩൻቇ෻ᔕ㗄ߣߘߩᓸಽଥᢙࠍ⸘▚ߔࠆߣ߈ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬128002

JACOBM2‛⾰⒖േ㗄ߣߘߩᓸಽଥᢙࠍ⸘▚ߔࠆߣ߈ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

128003

JACOBM3᳓⋧ߩൻቇ෻ᔕ㗄ߣߘߩᓸಽଥᢙࠍ⸘▚ߔࠆߣ߈ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬128004

JACOBM4᦭ᯏ⋧ߩൻቇ෻ᔕ㗄ߣߘߩᓸಽଥᢙࠍ⸘▚ߔࠆߣ߈ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

128011

JACOBM11ਔ⋧ߩൻቇ෻ᔕ㗄ߣߘߩᓸಽଥᢙࠍ⸘▚ߔࠆߣ߈ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

128012

JACOBM12‛⾰⒖േ㗄ߣߘߩᓸಽଥᢙࠍ⸘▚ߔࠆߣ߈ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

128013

JACOBM13᳓⋧ߩൻቇ෻ᔕ㗄ߣߘߩᓸಽଥᢙࠍ⸘▚ߔࠆߣ߈ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

128014

JACOBM14᦭ᯏ⋧ߩൻቇ෻ᔕ㗄ߣߘߩᓸಽଥᢙࠍ⸘▚ߔࠆߣ߈ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬128021

JACOBM21ਔ⋧ߩൻቇ෻ᔕ㗄ߣߘߩᓸಽଥᢙࠍ⸘▚ߔࠆߣ߈ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬128022

JACOBM22‛⾰⒖േ㗄ߣߘߩᓸಽଥᢙࠍ⸘▚ߔࠆߣ߈ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬128023

JACOBM23᳓⋧ߩൻቇ෻ᔕ㗄ߣߘߩᓸಽଥᢙࠍ⸘▚ߔࠆߣ߈ߦࠛ࡜࡯߇⊒↢ߒ
ߚ‫ޕ‬

131

128024

JACOBM24᦭ᯏ⋧ߩൻቇ෻ᔕ㗄ߣߘߩᓸಽଥᢙࠍ⸘▚ߔࠆߣ߈ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬128031

JACOBM31

ࠬ࠹࡯ࠫߩ⒳㘃㧔ౝㇱࠬ࠹࡯ࠫ‫ޔ‬Ꮐ┵ࠬ࠹࡯ࠫ‫ޔ‬ฝ┵ࠬ࠹࡯ࠫ㧕߇⇣Ᏹߢ޽ࠆ‫ޕ‬㧔㧞㧠㧕JacobA (make.c)
129000JACOBA0᳓⋧ߩൻቇ෻ᔕ㗄ߣߘߩᓸಽଥᢙࠍ⸘▚ߔࠆߣ߈ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬㧔㧞㧡㧕JacobO (make.c)
130000JACOBO0᦭ᯏ⋧ߩൻቇ෻ᔕ㗄ߣߘߩᓸಽଥᢙࠍ⸘▚ߔࠆߣ߈ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬㧔㧞㧢㧕Make (make.c)
131001

MAKE1

ࡗࠦࡆࠕࡦߩࡉࡠ࠶ࠢਃ㊀ኻⷺߩ߁ߜ‫ޔ‬Ꮐ஥ߩࡉࡠ࠶ࠢߩ࠯ࡠࠢ࡝ࠕ
ߢࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

131002

MAKE2ࡗࠦࡆࠕࡦߩࡉࡠ࠶ࠢਃ㊀ኻⷺߩ߁ߜ‫ޔ‬ਛᄩߩࡉࡠ࠶ࠢߩ࠯ࡠࠢ࡝ࠕ
ߢࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

131003

MAKE3ࡗࠦࡆࠕࡦߩࡉࡠ࠶ࠢਃ㊀ኻⷺߩ߁ߜ‫ޔ‬ฝ஥ߩࡉࡠ࠶ࠢߩ࠯ࡠࠢ࡝ࠕ
ߢࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

131004MAKE4Capacitance matrixs ᴺߩ R ⴕ೉ߩ࠯ࡠࠢ࡝ࠕߢࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

131005MAKE5ࡄ࡞ࠬࠞ࡜ࡓߩࡗࠦࡆࠕࡦߩ⸘▚ߢࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

131006

MAKE6ࡒࠠࠨ࠮࠻࡜ߩࡗࠦࡆࠕࡦߩ⸘▚ߢࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

131007

MAKE7

᳓⋧࠲ࡦࠢߩࡗࠦࡆࠕࡦߩ⸘▚ߢࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

131008

MAKE8᦭ᯏ⋧࠲ࡦࠢߩࡗࠦࡆࠕࡦߩ⸘▚ߢࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

131009MAKE9ࠦࡦࡐ࡯ࡀࡦ࠻ߩဳ㧔P‫ޔ‬M‫ޔ‬A‫ޔ‬O㧕߇⇣Ᏹߢ޽ࠆ‫ޕ‬

㧔㧞㧣㧕RdCard (tools.c)
132000RDCARD0ࡃ࠶ࡈࠔߦᡷⴕએᄖߩᢥሼ߇㧔ᦨᄢᢙ㧕㧗1 ୘⃻ࠇߚ‫ޕ‬

132001

RDCARD1ࡃ࠶ࡈࠔਛߩࠦࡔࡦ࠻ࠍขࠅ㒰ߊ㓙‫ߩ࠻ࡦࡔࠦޔ‬ౝㇱߦᡷⴕ⸥ภ߇⃻ࠇߚ‫ޕ‬132002

RDCARD2ࡃ࠶ࡈࠔਛߩࠦࡔࡦ࠻ࠍขࠅ㒰ߊ㓙‫ߩ࠻ࡦࡔࠦޔ‬ౝㇱߦᡷⴕ⸥ภ߇⃻ࠇߚ‫ޕ‬132003

RDCARD3

᦭㒢ࠝ࡯࠻ࡑ࠻ࡦߢ੍ᦼߒߡ޿ߥ߆ߞߚ⁁ᘒ߇⃻ࠇߚ‫ޕ‬

132004

RDCARD4

ࡈࠔࠗ࡞ߩᦨᓟߦ㆐ߒߡ޿ࠆߴ߈ߥߩߦ㆐ߒߡ޿ߥ޿‫ޕ‬

132005

RDCARD5

౉ജࡈࠔࠗ࡞ߣࡢ࡯ࠢࡈࠔࠗ࡞ߩ౉಴ജߢࠛ࡜࡯߇⊒↢ߒߡ޿ߚ‫ޕ‬132㧔㧞㧤㧕MssP (output.c)
133000MSSP0࡞࡯ࡊᄌᢙߩ୯߇ 0 એ਄㧔ࡔ࠶ࠪࡘᢙ㧕㧙1 એਅߣ޿߁▸࿐ᄖߦߥߞߚ‫ޕ‬

㧔㧞㧥㧕MassBalance (output.c)
134000MASSBALANCE0ࡄ࡞ࠬࠞ࡜ࡓߩࡑࠬࡃ࡜ࡦࠬ಴ജ࠺࡯࠲ࠍ૞ࠆߣ߈ߦࠛ࡜࡯
߇⊒↢ߒߚ‫ޕ‬

134001MASSBALANCE1

ࠦࡦࡐ࡯ࡀࡦ࠻ߩဳ㧔P‫ޔ‬M‫ޔ‬A‫ޔ‬O㧕ߦ੍ᦼߒߥ޿߽ߩ߇⃻ࠇߚ‫ޕ‬㧔㧟㧜㧕OutputX (output.c)
135000OUTPUTX0ࠦࡦࡐ࡯ࡀࡦ࠻ߩဳ㧔P‫ޔ‬M‫ޔ‬A‫ޔ‬O㧕ߦ੍ᦼߒߥ޿߽ߩ߇⃻ࠇߚ‫ޕ‬㧔㧟㧝㧕OutputR (output.c)
136000OUTPUTR0ࠦࡦࡐ࡯ࡀࡦ࠻ߩဳ㧔P‫ޔ‬M‫ޔ‬A‫ޔ‬O㧕ߦ੍ᦼߒߥ޿߽ߩ߇⃻ࠇߚ‫ޕ‬136001OUTPUTR1

ࠦࡦࡐ࡯ࡀࡦ࠻ߩဳ㧔P‫ޔ‬M‫ޔ‬A‫ޔ‬O㧕ߦ੍ᦼߒߥ޿߽ߩ߇⃻ࠇߚ‫ޕ‬㧔㧟㧞㧕DivPath (tools.c)
137000DIVPATH0ࡈࠔࠗ࡞ฬߩ߁ߜ᜛ᒛሶߣࡇ࡝ࠝ࠼ࠍ㒰޿ߚᧄ૕߇ሽ࿷ߒߥ޿‫ޕ‬

137001

DIVPATH1ࡈࠔࠗ࡞ฬߩ߁ߜ᜛ᒛሶߣࡇ࡝ࠝ࠼ࠍ㒰޿ߚᧄ૕߇ሽ࿷ߒߥ޿‫ޕ‬

㧔㧟㧟㧕RelErr (output.c)
138000

RELERR0ࠦࡦࡐ࡯ࡀࡦ࠻ߩဳ㧔P‫ޔ‬M‫ޔ‬A‫ޔ‬O㧕ߦ੍ᦼߒߥ޿߽ߩ߇⃻ࠇߚ‫ޕ‬138001

RELERR1ࠦࡦࡐ࡯ࡀࡦ࠻ߩဳ㧔P‫ޔ‬M‫ޔ‬A‫ޔ‬O㧕ߦ੍ᦼߒߥ޿߽ߩ߇⃻ࠇߚ‫ޕ‬

㧔㧟㧠㧕ReadChr (tools.c)
139000

READCHR0ࡃ࠶ࡈࠔߦᢥሼ೉ࠍ⺒ߺㄟ߻ߎߣ߇ߢ߈ߥ޿‫ޕ‬139001READCHR1ࡃ࠶ࡈࠔߦᢥሼ೉ࠍ⺒ߺㄟ߻ߎߣ߇ߢ߈ߥ޿‫ޕ‬139002READCHR2

౉ജ࠺࡯࠲ਛߩ࠺࡯࠲ᢥሼ೉ߩ㐳ߐ߇‫ࠅࠃߩ߽ߚ޿ߡߒᦼ੍ޔ‬㐳޿‫ޕ‬㧔㧟㧡㧕ReadDbl (tools.c)
140000

READDBL0ࡃ࠶ࡈࠔߦᢥሼ೉ࠍ⺒ߺㄟ߻ߎߣ߇ߢ߈ߥ޿‫ޕ‬

140001READDBL1ࡃ࠶ࡈࠔߦᢥሼ೉ࠍ⺒ߺㄟ߻ߎߣ߇ߢ߈ߥ޿‫ޕ‬

140002READDBL2࠺࡯࠲ᢥሼ೉ࠍ୚♖ᐲታᢙဳߦᄌ឵ߔࠆߣ߈ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

㧔㧟㧢㧕ReadInt (tools.c)
141000READINT0ࡃ࠶ࡈࠔߦᢥሼ೉ࠍ⺒ߺㄟ߻ߎߣ߇ߢ߈ߥ޿‫ޕ‬141001READINT1

ࡃ࠶ࡈࠔߦᢥሼ೉ࠍ⺒ߺㄟ߻ߎߣ߇ߢ߈ߥ޿‫ޕ‬133

141002

READINT2

࠺࡯࠲ᢥሼ೉ࠍ long ဳߦᄌ឵ߔࠆߣ߈ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

㧔㧟㧣㧕RdXf (main.c)
144000Ớᐲߩࡈࠖ࡯࠼࠹࡯ࡉ࡞ߩ߁ߜ‫ᤨޔ‬㑆ࠍ⺒ߺㄟ߻ߣ߈ߦࠛ࡜࡯߇⊒↢

RDXF0

ߒߚ‫ޕ‬
144001Ớᐲߩࡈࠖ࡯࠼࠹࡯ࡉ࡞ߩ߁ߜ‫ޔ‬Ớᐲㇱಽࠍ⺒ߺㄟ߻ߣ߈ߦࠛ࡜࡯߇

RDXF1⊒↢ߒߚ‫ޕ‬㧔㧟㧤㧕RdFf (main.c)
145000ᵹ㊂ߩࡈࠖ࡯࠼࠹࡯ࡉ࡞ߩ߁ߜ‫ᤨޔ‬㑆ࠍ⺒ߺㄟ߻ߣ߈ߦࠛ࡜࡯߇⊒↢

RDFF0

ߒߚ‫ޕ‬
145001

ᵹ㊂ߩࡈࠖ࡯࠼࠹࡯ࡉ࡞ߩ߁ߜ‫ޔ‬ᵹ㊂ㇱಽࠍ⺒ߺㄟ߻ߣ߈ߦࠛ࡜࡯߇

RDFF1⊒↢ߒߚ‫ޕ‬㧔㧟㧥㧕RdDBet (main.c)
146000RDDBET0ਅㇱಽ⋧࠲ࡦࠢߩ✚᜝‛⾰⒖േଥᢙࠍ⺒ߺㄟ߻ߣ߈ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

146001RDDBET1ਅㇱಽ⋧࠲ࡦࠢߩ✚᜝‛⾰⒖േଥᢙࠍ⺒ߺㄟ߻ߣ߈ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

146002

RDDBET2਄ㇱಽ⋧࠲ࡦࠢߩ✚᜝‛⾰⒖േଥᢙࠍ⺒ߺㄟ߻ߣ߈ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

146003

RDDBET3਄ㇱಽ⋧࠲ࡦࠢߩ✚᜝‛⾰⒖േଥᢙࠍ⺒ߺㄟ߻ߣ߈ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬㧔㧠㧜㧕RdP (main.c)
147000RDP0࡝ࠬ࠲࡯࠻⸘▚ߩߣ߈ߦ‫ߩࡓ࡜ࠞࠬ࡞ࡄޔ‬ᢛᢙ࠳ࡒ࡯࠺࡯࠲ࠍ⺒ߺㄟ߻㓙ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

147001

RDP1ࡄ࡞ࠬࠞ࡜ࡓߩ᳓⋧Ớᐲ࠺࡯࠲ࠍ⺒ߺㄟ߻ߣ߈ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

147002RDP2ࡄ࡞ࠬࠞ࡜ࡓߩ᳓⋧Ớᐲ࠺࡯࠲ࠍ⺒ߺㄟ߻ߣ߈ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

147003RDP3࡝ࠬ࠲࡯࠻⸘▚ߩߣ߈ߦ‫ߩࡓ࡜ࠞࠬ࡞ࡄޔ‬ᢛᢙ࠳ࡒ࡯࠺࡯࠲ࠍ⺒ߺㄟ߻㓙ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

147004RDP4࡝ࠬ࠲࡯࠻⸘▚ߩߣ߈ߦ‫ߩࡓ࡜ࠞࠬ࡞ࡄޔ‬᳓⋧Ớᐲ࠺࡯࠲ࠍ⺒ߺㄟ߻㓙ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

147005RDP5࡝ࠬ࠲࡯࠻⸘▚ߩߣ߈ߦ‫ߩࡓ࡜ࠞࠬ࡞ࡄޔ‬ᢛᢙ࠳ࡒ࡯࠺࡯࠲ࠍ⺒ߺㄟ߻㓙ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

147006RDP6ࡄ࡞ࠬࠞ࡜ࡓߩ᦭ᯏ⋧Ớᐲ࠺࡯࠲ࠍ⺒ߺㄟ߻ߣ߈ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

147007RDP7ࡄ࡞ࠬࠞ࡜ࡓߩ᦭ᯏ⋧Ớᐲ࠺࡯࠲ࠍ⺒ߺㄟ߻ߣ߈ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬134

147008

RDP8࡝ࠬ࠲࡯࠻⸘▚ߩߣ߈ߦ‫ߩࡓ࡜ࠞࠬ࡞ࡄޔ‬ᢛᢙ࠳ࡒ࡯࠺࡯࠲ࠍ⺒ߺㄟ߻㓙ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

147009RDP9࡝ࠬ࠲࡯࠻⸘▚ߩߣ߈ߦ‫᦭ߩࡓ࡜ࠞࠬ࡞ࡄޔ‬ᯏ⋧Ớᐲ࠺࡯࠲ࠍ⺒ߺㄟ߻㓙ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

147010RDP10ࡄ࡞ࠬࠞ࡜ࡓߩਅㇱಽ⋧࠲ࡦࠢߩ૕Ⓧࠍ⺒ߺㄟ߻ߣ߈ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

147011

RDP11ࡄ࡞ࠬࠞ࡜ࡓߩ਄ㇱಽ⋧࠲ࡦࠢߩ૕Ⓧࠍ⺒ߺㄟ߻ߣ߈ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

147012RDP12ࡄ࡞ࠬࠞ࡜ࡓߩࡔ࠶ࠪࡘ᏷ࠍ⺒ߺㄟ߻ߣ߈ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

147013

RDP13ࡄ࡞ࠬࠞ࡜ࡓߩࡔ࠶ࠪࡘ᏷ࠍ⺒ߺㄟ߻ߣ߈ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

㧔㧠㧝㧕RdM (main.c)
148000RDM0࡝ࠬ࠲࡯࠻⸘▚ߩߣ߈‫ޔ‬᳓⋧ࡒࠠࠨߩᢛᢙ࠳ࡒ࡯࠺࡯࠲ߩ⺒ߺㄟߺߩ㓙ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

148001RDM1ࡒࠠࠨߩ᳓⋧Ớᐲࠍ⺒ߺㄟ߻ߣ߈ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

148002RDM2ࡒࠠࠨߩ᳓⋧Ớᐲࠍ⺒ߺㄟ߻ߣ߈ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

148003RDM3࡝ࠬ࠲࡯࠻⸘▚ߩߣ߈‫ޔ‬᳓⋧ࡒࠠࠨߩᢛᢙ࠳ࡒ࡯࠺࡯࠲ߩ⺒ߺㄟߺߩ㓙ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

148004RDM4࡝ࠬ࠲࡯࠻⸘▚ߩߣ߈‫ߩࠨࠠࡒޔ‬᳓⋧Ớᐲߩ⺒ߺㄟߺߩ㓙ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬148005RDM5࡝ࠬ࠲࡯࠻⸘▚ߩߣ߈‫ޔ‬᳓⋧࠮࠻࡜ߩᢛᢙ࠳ࡒ࡯࠺࡯࠲ߩ⺒ߺㄟߺߩ㓙ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

148006RDM6࠮࠻࡜ߩ᳓⋧Ớᐲࠍ⺒ߺㄟ߻ߣ߈ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

148007RDM7࠮࠻࡜ߩ᳓⋧Ớᐲࠍ⺒ߺㄟ߻ߣ߈ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

148008RDM8࡝ࠬ࠲࡯࠻⸘▚ߩߣ߈‫ޔ‬᳓⋧࠮࠻࡜ߩᢛᢙ࠳ࡒ࡯࠺࡯࠲ߩ⺒ߺㄟߺߩ㓙ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

148009RDM9࡝ࠬ࠲࡯࠻⸘▚ߩߣ߈‫ߩ࡜࠻࠮ޔ‬᳓⋧Ớᐲߩ⺒ߺㄟߺߩ㓙ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

148010RDM10࡝ࠬ࠲࡯࠻⸘▚ߩߣ߈‫᦭ޔ‬ᯏ⋧ࡒࠠࠨߩᢛᢙ࠳ࡒ࡯࠺࡯࠲ߩ⺒ߺㄟߺߩ㓙ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

148011

RDM11ࡒࠠࠨߩ᦭ᯏ⋧Ớᐲࠍ⺒ߺㄟ߻ߣ߈ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

148012RDM12ࡒࠠࠨߩ᦭ᯏ⋧Ớᐲࠍ⺒ߺㄟ߻ߣ߈ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

148013RDM13࡝ࠬ࠲࡯࠻⸘▚ߩߣ߈‫᦭ޔ‬ᯏ⋧ࡒࠠࠨߩᢛᢙ࠳ࡒ࡯࠺࡯࠲ߩ⺒ߺㄟߺߩ㓙ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

148014RDM14࡝ࠬ࠲࡯࠻⸘▚ߩߣ߈‫᦭ߩࠨࠠࡒޔ‬ᯏ⋧Ớᐲߩ⺒ߺㄟߺߩ㓙ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

148015RDM15࡝ࠬ࠲࡯࠻⸘▚ߩߣ߈‫᦭ޔ‬ᯏ⋧࠮࠻࡜ߩᢛᢙ࠳ࡒ࡯࠺࡯࠲ߩ⺒ߺㄟߺߩ㓙135

ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬
148016RDM16࠮࠻࡜ߩ᦭ᯏ⋧Ớᐲࠍ⺒ߺㄟ߻ߣ߈ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

148017RDM17࠮࠻࡜ߩ᦭ᯏ⋧Ớᐲࠍ⺒ߺㄟ߻ߣ߈ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

148018RDM18࡝ࠬ࠲࡯࠻⸘▚ߩߣ߈‫᦭ޔ‬ᯏ⋧࠮࠻࡜ߩᢛᢙ࠳ࡒ࡯࠺࡯࠲ߩ⺒ߺㄟߺߩ㓙ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

148019RDM19࡝ࠬ࠲࡯࠻⸘▚ߩߣ߈‫᦭ߩ࡜࠻࠮ޔ‬ᯏ⋧Ớᐲߩ⺒ߺㄟߺߩ㓙ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

148020RDM20ࡒࠠࠨߩ૕Ⓧߩ⺒ߺㄟߺߩ㓙ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

148021

RDM21ࡒࠠࠨߩ૕Ⓧߩ⺒ߺㄟߺߩ㓙ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

148022

RDM22࠮࠻࡜ߩ૕Ⓧߩ⺒ߺㄟߺߩ㓙ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

148023

RDM23࠮࠻࡜ߩ૕Ⓧߩ⺒ߺㄟߺߩ㓙ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

148024

RDM24

ࡒࠠࠨ࠮࠻࡜ߩ࡝ࠨࠗࠢ࡞ᵹ㊂ߩ⺒ߺㄟߺߩ㓙ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

148025RDM25ࡒࠠࠨ࠮࠻࡜ߩ࡝ࠨࠗࠢ࡞ᵹ㊂ߩ⺒ߺㄟߺߩ㓙ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

㧔㧠㧞㧕RdA (main.c)
149000RDA0࡝ࠬ࠲࡯࠻⸘▚ߩߣ߈‫ޔ‬᳓⋧࠲ࡦࠢߩᢛᢙ࠳ࡒ࡯࠺࡯࠲ߩ⺒ߺㄟߺߩ㓙ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

149001

RDA1᳓⋧࠲ࡦࠢߩ᳓⋧Ớᐲࠍ⺒ߺㄟ߻ߣ߈ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

149002

RDA2᳓⋧࠲ࡦࠢߩ᳓⋧Ớᐲࠍ⺒ߺㄟ߻ߣ߈ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

149003

RDA3࡝ࠬ࠲࡯࠻⸘▚ߩߣ߈‫ޔ‬᳓⋧࠲ࡦࠢߩᢛᢙ࠳ࡒ࡯࠺࡯࠲ߩ⺒ߺㄟߺߩ㓙ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

149004

RDA4᳓⋧࠲ࡦࠢߩ᳓⋧Ớᐲࠍ⺒ߺㄟ߻ߣ߈ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

149005RDA5᳓⋧࠲ࡦࠢߩ૕Ⓧࠍ⺒ߺㄟ߻ߣ߈ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

㧔㧠㧟㧕RdO (main.c)
150000RDO0࡝ࠬ࠲࡯࠻⸘▚ߩߣ߈‫᦭ޔ‬ᯏ⋧࠲ࡦࠢߩᢛᢙ࠳ࡒ࡯࠺࡯࠲ߩ⺒ߺㄟߺߩ㓙ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

150001

RDO1

᦭ᯏ⋧࠲ࡦࠢߩ᦭ᯏ⋧Ớᐲߩ⺒ߺㄟߺߢࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

150002

RDO2

᦭ᯏ⋧࠲ࡦࠢߩ᦭ᯏ⋧Ớᐲߩ⺒ߺㄟߺߢࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

150003

RDO3

࡝ࠬ࠲࡯࠻⸘▚ߩߣ߈‫᦭ޔ‬ᯏ⋧࠲ࡦࠢߩᢛᢙ࠳ࡒ࡯࠺࡯࠲ߩ⺒ߺㄟߺߩ㓙ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

150004RDO4࡝ࠬ࠲࡯࠻⸘▚ߩߣ߈‫᦭ޔ‬ᯏ⋧࠲ࡦࠢߩ᦭ᯏ⋧Ớᐲߩ⺒ߺㄟߺߩ㓙ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

150005RDO5᦭ᯏ⋧࠲ࡦࠢߩ૕Ⓧߩ⺒ߺㄟߺߢࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬㧔㧠㧠㧕invgj (solver.c)
152000INVGJ0ⴕ೉ߩࠝ࡯࠳࡯߇ 0 એਅߢ޽ࠆ‫ޕ‬136

152001

INVGJ1

1 ᰴߩⴕ೉ߩߣ߈ߦ‫ⴕޔ‬೉߇㕖ᱜೣߢ޽ࠆ‫ޕ‬

152002

INVGJ22 ᰴએ਄ߩⴕ೉ߩߣ߈ߦ‫ⴕޔ‬೉߇㕖ᱜೣߢ޽ࠆ‫ޕ‬㧔㧠㧡㧕decomp (solver.c)
153000DECOMP0ⴕ೉ߩࠝ࡯࠳࡯߇ 0 એਅߢ޽ࠆ‫ޕ‬

153001DECOMP1

ⴕ೉߇㕖ᱜೣߢ޽ࠆ‫ޕ‬㧔㧠㧢㧕solve (solver.c)
154000SOLVE0ⴕ೉ߩࠝ࡯࠳࡯߇ 0 એਅߢ޽ࠆ‫ޕ‬㧔㧠㧣㧕prodmm (matrixop.c)
155000PRODMM0ⴕ೉ߩࠝ࡯࠳࡯߇ 0 એਅߩ߽ߩ߇޽ࠆ‫ޕ‬㧔㧠㧤㧕movevv (matrixop.c)
156000MOVEVV0⸘▚ࠝࡊ࡚ࠪࡦߦ੍ᦼߒߥ޿߽ߩ߇⃻ࠇߚ‫ޕ‬

156001MOVEVV1ࡌࠢ࠻࡞ߩࠝ࡯࠳࡯߇ 0 એਅߢ޽ࠆ‫ޕ‬㧔㧠㧥㧕addvv (matrixop.c)
157000ADDVV0⸘▚ࠝࡊ࡚ࠪࡦߦ੍ᦼߒߥ޿߽ߩ߇⃻ࠇߚ‫ޕ‬

157001ADDVV1ࡌࠢ࠻࡞ߩࠝ࡯࠳࡯߇ 0 એਅߢ޽ࠆ‫ޕ‬㧔㧡㧜㧕clearv (matrixop.c)
158000CLEARV0ࡌࠢ࠻࡞ߩࠝ࡯࠳࡯߇ 0 એਅߢ޽ࠆ‫ޕ‬㧔㧡㧝㧕prodmd (matrixop.c)
159000PRODMD0ⴕ೉ߩࠨࠗ࠭ߦ⇣Ᏹߥ߽ߩ߇⃻ࠇߚ‫ޕ‬㧔㧡㧞㧕proddm (matrixop.c)
160000PRODDM0ⴕ೉ߩࠨࠗ࠭ߦ⇣Ᏹߥ߽ߩ߇⃻ࠇߚ‫ޕ‬㧔㧡㧟㧕prodsv (matrixop.c)
161000PRODSV0ࡌࠢ࠻࡞ߩࠝ࡯࠳࡯߇ 0 એਅߢ޽ࠆ‫ޕ‬

㧔㧡㧠㧕ReactX14 (reactz.c)
162000

REACTX14_0

NPREAC ߩ୯ߦ੍ᦼߒߥ޿߽ߩ߇⃻ࠇߚ‫ޕ‬㧔㧡㧡㧕DistriH (msstr.c)137163000

DISTRIH0᳓⚛ࠗࠝࡦ߇⸘▚ߔߴ߈ൻቇ⒳ߦߥߞߡ޿ߥ޿‫ޕ‬㧔㧡㧢㧕DistriU6 (masstr.c)
164000

DISTRIU6_0

࠙࡜ࡦ(VI)߇⸘▚ߔߴ߈ൻቇ⒳ߦߥߞߡ޿ߥ޿‫ޕ‬㧔㧡㧣㧕DistriPu4 (masstr.c)
165000ࡊ࡞࠻࠾࠙ࡓ(IV)߇⸘▚ߔߴ߈ൻቇ⒳ߦߥߞߡ޿ߥ޿‫ޕ‬

DISTRIPU4_0

㧔㧡㧤㧕DistriPu3 (masstr.c)
166000

DISTRIPU3_0ࡊ࡞࠻࠾࠙ࡓ(III)߇⸘▚ߔߴ߈ൻቇ⒳ߦߥߞߡ޿ߥ޿‫ޕ‬㧔㧡㧥㧕DistriU4 (masstr.c)
167000

DISTRIU4_0

࠙࡜ࡦ(IV)߇⸘▚ߔߴ߈ൻቇ⒳ߦߥߞߡ޿ߥ޿‫ޕ‬㧔㧢㧜㧕DistriZr (masstr.c)
168000

DISTRIZR0ࠫ࡞ࠦ࠾࠙ࡓ߇⸘▚ߔߴ߈ൻቇ⒳ߦߥߞߡ޿ߥ޿‫ޕ‬㧔㧢㧝㧕DistriNp4 (masstr.c)
169000

DISTRINP4_0ࡀࡊ࠷࠾࠙ࡓ(IV)߇⸘▚ߔߴ߈ൻቇ⒳ߦߥߞߡ޿ߥ޿‫ޕ‬㧔㧢㧞㧕DistriNp5 (masstr.c)170000

DISTRINP5_0ࡀࡊ࠷࠾࠙ࡓ(V)߇⸘▚ߔߴ߈ൻቇ⒳ߦߥߞߡ޿ߥ޿‫ޕ‬㧔㧢㧟㧕DistriNp6 (masstr.c)171000

DISTRINP6_0ࡀࡊ࠷࠾࠙ࡓ(VI)߇⸘▚ߔߴ߈ൻቇ⒳ߦߥߞߡ޿ߥ޿‫ޕ‬㧔㧢㧠㧕DistriHN3 (masstr.c)172000

DISTRIHN3_0

ࠕࠫൻ᳓⚛߇⸘▚ߔߴ߈ൻቇ⒳ߦߥߞߡ޿ߥ޿‫ޕ‬㧔㧢㧡㧕DistriIBAL (masstr.c)
173000

DISTRIIBAL0

iso-ࡉ࠴࡞ࠕ࡞࠺ࡅ࠼߇⸘▚ߔߴ߈ൻቇ⒳ߦߥߞߡ޿ߥ޿‫ޕ‬㧔㧢㧢㧕DistriNBAL (masstr.c)
174000

DISTRINBAL0n-ࡉ࠴࡞ࠕ࡞࠺ࡅ࠼߇⸘▚ߔߴ߈ൻቇ⒳ߦߥߞߡ޿ߥ޿‫ޕ‬㧔㧢㧣㧕DistriIBAC (masstr.c)175000

DISTRIIBAC0

iso-㈼㉄߇⸘▚ߔߴ߈ൻቇ⒳ߦߥߞߡ޿ߥ޿‫ޕ‬138

㧔㧢㧤㧕DistriNBAC (masstr.c)
176000

DISTRINBAC0

n-㈼㉄߇⸘▚ߔߴ߈ൻቇ⒳ߦߥߞߡ޿ߥ޿‫ޕ‬㧔㧢㧥㧕DistriI (masstr.c)
177000

DISTRII0࡛࠙⚛߇⸘▚ߔߴ߈ൻቇ⒳ߦߥߞߡ޿ߥ޿‫ޕ‬㧔㧣㧜㧕DistriCs (masstr.c)
178000

DISTRICS_0

࠮ࠪ࠙ࡓ߇⸘▚ߔߴ߈ൻቇ⒳ߦߥߞߡ޿ߥ޿‫ޕ‬㧔㧣㧝㧕DistriRu3 (masstr.c)
179000

DISTRIRU3_0࡞࠹࠾࠙ࡓ߇⸘▚ߔߴ߈ൻቇ⒳ߦߥߞߡ޿ߥ޿‫ޕ‬㧔㧣㧞㧕DistriPu6 (masstr.c)180000

DISTRIPU6_0ࡊ࡞࠻࠾࠙ࡓ(VI)߇⸘▚ߔߴ߈ൻቇ⒳ߦߥߞߡ޿ߥ޿‫ޕ‬㧔㧣㧟㧕DistriV4 (masstr.c)
181000

DISTRIV4_0ࡃ࠽ࠫ࠙ࡓ(IV)߇⸘▚ߔߴ߈ൻቇ⒳ߦߥߞߡ޿ߥ޿‫ޕ‬㧔㧣㧠㧕DistriV5 (masstr.c)
182000

DISTRIV5_0ࡃ࠽ࠫ࠙ࡓ(V)߇⸘▚ߔߴ߈ൻቇ⒳ߦߥߞߡ޿ߥ޿‫ޕ‬㧔㧣㧡㧕DistriNO2 (masstr.c)
184000

DISTRINO2_0᳓⚛ࠗࠝࡦ߹ߚߪ੝⎣㉄߇⸘▚ߔߴ߈ൻቇ⒳ߦߥߞߡ޿ߥ޿‫ޕ‬㧔㧣㧢㧕DistriTc_0 (masstr.c)
185000

DISTRITC_0_0

࠹ࠢࡀ࠴࠙ࡓ߇⸘▚ߔߴ߈ൻቇ⒳ߦߥߞߡ޿ߥ޿‫ޕ‬㧔㧣㧣㧕DistriTc_U (masstr.c)
186000

DISTRITC_U_0

࠙࡜ࡦ(VI)෶ߪࡊ࡞࠻࠾࠙ࡓ(IV)߇⸘▚ߔߴ߈ൻቇ⒳ߦߥߞߡ޿
ߥ޿‫ޕ‬㧔㧣㧤㧕DistriTc_Pu (masstr.c)
187000

DISTRITC_PU_0

࠙࡜ࡦ(VI)෶ߪࡊ࡞࠻࠾࠙ࡓ(IV)߇⸘▚ߔߴ߈ൻቇ⒳ߦߥߞߡ޿
ߥ޿‫ޕ‬㧔㧣㧥㧕DistriTc_Zr (masstr.c)139

188000

DISTRITC_ZR_0

ࠫ࡞ࠦ࠾࠙ࡓ߇⸘▚ߔߴ߈ൻቇ⒳ߦߥߞߡ޿ߥ޿‫ޕ‬㧔㧤㧜㧕DistriTc (masstr.c)
189000

DISTRITC0࠹ࠢࡀ࠴࠙ࡓ߇⸘▚ߔߴ߈ൻቇ⒳ߦߥߞߡ޿ߥ޿‫ޕ‬

189001

DISTRITC1࠹ࠢࡀ࠴࠙ࡓߩಽ㈩Ყߩ߁ߜ‫ޔ‬DTC,0 ࠍ⸘▚ߔࠆߣ߈ߦࠛ࡜࡯߇
⊒↢ߒߚ‫ޕ‬189002࠹ࠢࡀ࠴࠙ࡓߩಽ㈩Ყߩ߁ߜ‫ޔ‬DTC,U ࠍ⸘▚ߔࠆߣ߈ߦࠛ࡜࡯߇

DISTRITC2⊒↢ߒߚ‫ޕ‬189003࠹ࠢࡀ࠴࠙ࡓߩಽ㈩Ყߩ߁ߜ‫ޔ‬DTC,PU ࠍ⸘▚ߔࠆߣ߈ߦࠛ࡜࡯߇

DISTRITC3⊒↢ߒߚ‫ޕ‬189004࠹ࠢࡀ࠴࠙ࡓߩಽ㈩Ყߩ߁ߜ‫ޔ‬DTC,ZR ࠍ⸘▚ߔࠆߣ߈ߦࠛ࡜࡯߇

DISTRITC4⊒↢ߒߚ‫ޕ‬㧔㧤㧝㧕prod2sm (matrixop.c)
190000PROD2SM0ⴕ೉ߩࠨࠗ࠭ߦ⇣Ᏹߥ߽ߩ߇⃻ࠇߚ‫ޕ‬㧔㧤㧞㧕prodm2s (matrixop.c)
191000PRODM2S0ⴕ೉ߩࠨࠗ࠭ߦ⇣Ᏹߥ߽ߩ߇⃻ࠇߚ‫ޕ‬

㧔㧤㧟㧕RdCard2 (tools.c)
192000RDCARD2_0"begin2" ߇⷗ߟ߆ࠄߥ߆ߞߚ‫ޕ‬

192001

RDCARD2_1

࠲ࠗ࠻࡞ࠞ࡯࠼߇⷗ߟ߆ࠄߥ߆ߞߚ‫ޕ‬

192002

RDCARD2_2

n*x ࠍዷ㐿ߔࠆߣ߈ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

192003

RDCARD2_3"end2" ߹ߚߪ "end2." ߇⷗ߟ߆ࠄߥ޿߹߹౉ജࡈࠔࠗ࡞⚳┵ߦ㆐ߒߚ‫ޕ‬

192004

RDCARD2_4

ࡈࠔࠗ࡞ࠍ⺒ߺ߈ߞߚߩߦ౉ജࡈࠔࠗ࡞⚳┵ߦ㆐ߒߥ޿‫ޕ‬

192005

RDCARD2_5

౉಴ജߦ㓙ߒࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬㧔㧤㧠㧕ExpandNX (tools.c)
193000EXPANDNX0ᦨೋߩ࠻࡯ࠢࡦ߇ STRING ߢߥ޿‫ޕ‬

193001EXPANDNX1

3 ⇟⋡ߩ࠻࡯ࠢࡦ߇ STRING ߢߥ޿‫ޕ‬

193002EXPANDNX2

n*x ߩ n ߇ᢛᢙߢߥ޿‫ޕ‬

193003

EXPANDNX3

n*x ߩ n ߇ 0 એਅߩᢛᢙߢ޽ࠆ‫ޕ‬

193004EXPANDNX4

2 ⇟⋡ߩ࠻࡯ࠢࡦߦ੍ᦼߒߥ޿߽ߩ߇⃻ࠇߚ‫ޕ‬

㧔㧤㧡㧕PickUpConst (tools.c)
194000PICKUPCONST0౉ജⴕߩ⺒ߺㄟߺ߇߁߹ߊ޿߆ߥ޿‫ޕ‬140

194001

PICKUPCONST1ᣂߒ޿౉ജⴕߩ⺒ߺㄟߺ߇߁߹ߊ޿߆ߥ޿‫ޕ‬

194002PICKUPCONST2ࡀ࡯ࡓ࡝ࠬ࠻ᢥߩ࠻࡯ࠢࡦߩ⺒ߺㄟߺߩ㓙ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

194003PICKUPCONST3ࡀ࡯ࡓ࡝ࠬ࠻ᢥߩ⸥ภฬߣᢙ୯ߩ඙ಾࠅᢥሼߣߒߡ੍ᦼߒߥ޿
߽ߩ߇⃻ࠇߚ‫ޕ‬

㧔㧤㧢㧕GetKeyWord(tools.c)
195000GETKEYWORD0ࠠ࡯ࡢ࡯࠼ࠍតߔߚ߼ߩੑಽត⚝ᴺ߇ᄬᢌߒߚ‫ޕ‬

㧔㧤㧣㧕RdExpParam (main.c)
197000RDEXPPARAM0ࡀ࡯ࡓ࡝ࠬ࠻౉ജߩᄌᢙฬ㧔ࠠ࡯ࡢ࡯࠼㧕ߩត⚝ߢࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬197001RDEXPPARAM1ࠠ࡯ࡢ࡯࠼ߩត⚝ߢ⇣Ᏹߥ࠻࡯ࠢࡦ߇㄰ߐࠇߚ‫ޕ‬

197002

RDEXPPARAM2ࡀ࡯ࡓ࡝ࠬ࠻౉ജߩ "=" ߩត⚝ߢࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

197003

RDEXPPARAM3࠻࡯ࠢࡦ߇ "=" ߢߥ߆ߞߚ‫ޕ‬

197004

RDEXPPARAM4ࡀ࡯ࡓ࡝ࠬ࠻౉ജߩᢙ୯ߩត⚝ߢࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

197005RDEXPPARAM5⷗ߟ߆ߞߚ࠻࡯ࠢࡦ߇ᢙ୯ߢߥ߆ߞߚ‫ޕ‬

197006

RDEXPPARAM6ᢙ୯ᢥሼ೉ࠍ୚♖ᐲታᢙߦᄌ឵ߔࠆߣ߈ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

197007

RDEXPPARAM7ᢙ୯ᢥሼ೉ߩᓟߩ࠻࡯ࠢࡦࠍត⚝ߔࠆߣ߈ߦࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

197008RDEXPPARAM8⷗ߟ߆ߞߚ࠻࡯ࠢࡦ߇੍ᦼߒߥ޿߽ߩߢ޽ߞߚ‫ޕ‬㧔㧤㧤㧕InterpretDistri1 (interpret_d1.c)
198000

INTERPRETDISTRI1_0

ࠗࡦ࠲ࡊ࡝࠲ਛ㑆⸒⺆ߩ᧦ઙㇱ㧔Richardson ဳಽ㈩Ყ㧕ߩಣℂߢࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

198001

INTERPRETDISTRI1_1

ࠗࡦ࠲ࡊ࡝࠲ਛ㑆⸒⺆ߩታⴕࡊࡠࠣ࡜ࡓㇱ㧔Richardson ဳ
ಽ㈩Ყ㧕ߩಣℂߢࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬㧔㧤㧥㧕CondDistri1 (interpret_d1.c)
199000

CONDDISTRI1_0

ೋᦼ୯㈩೉ߩ઒ᒁᢙߩ૏⟎ߩਛߦ੍ᦼߒߥ޿߽ߩ߇⃻ࠇߚ‫ޕ‬

199001CONDDISTRI1_1

྾ߟ⚵ߩṶ▚ሶߩਛߦ੍ᦼߒߥ޿߽ߩ߇⃻ࠇߚ‫ޕ‬㧔㧥㧜㧕CaseDistri1 (interpret_d1.c)
200000CASEDISTRI1_0

ೋᦼ୯㈩೉ߩ઒ᒁᢙߩ૏⟎ߩਛߦ੍ᦼߒߥ޿߽ߩ߇⃻ࠇߚ‫ޕ‬

200001

CASEDISTRI1_1

Ṷ▚ሶ B_MULRR_L ߩᒁᢙ߇ 1 એᄖߢ޽ࠆ‫ޕ‬

200002

CASEDISTRI1_2

Ṷ▚ሶ B_MULRR_R ߩᒁᢙ߇ 1 એᄖߢ޽ࠆ‫ޕ‬

200003

CASEDISTRI1_3

Ṷ▚ሶ B_MULRR_B ߩᒁᢙ߇ 1 એᄖߢ޽ࠆ‫ޕ‬

200004

CASEDISTRI1_4

Ṷ▚ሶ B_DIVRR_L ߩᒁᢙ߇ 1 એᄖߢ޽ࠆ‫ޕ‬

200005

CASEDISTRI1_5

Ṷ▚ሶ B_DIVRR_R ߩᒁᢙ߇ 1 એᄖߢ޽ࠆ‫ޕ‬141

200006

CASEDISTRI1_6

Ṷ▚ሶ B_DIVRR_B ߩᒁᢙ߇ 1 એᄖߢ޽ࠆ‫ޕ‬

200007

CASEDISTRI1_7

Ṷ▚ሶ B_ABSR_L ߩᒁᢙ߇ 1 એᄖߢ޽ࠆ‫ޕ‬

200008

CASEDISTRI1_8

Ṷ▚ሶ B_EXPR_L ߩᒁᢙ߇ 1 એᄖߢ޽ࠆ‫ޕ‬

200009

CASEDISTRI1_9

Ṷ▚ሶ B_LOGR_L ߩᒁᢙ߇ 1 એᄖߢ޽ࠆ‫ޕ‬

200010CASEDISTRI1_10

Ṷ▚ሶ B_LOG10R_L ߩᒁᢙ߇ 1 એᄖߢ޽ࠆ‫ޕ‬

200011

CASEDISTRI1_11

Ṷ▚ሶ B_POWRR_L ߩᒁᢙ߇ 1 એᄖߢ޽ࠆ‫ޕ‬

200012

CASEDISTRI1_12

Ṷ▚ሶ B_POWRR_R ߩᒁᢙ߇ 1 એᄖߢ޽ࠆ‫ޕ‬

200013

CASEDISTRI1_13

Ṷ▚ሶ B_POWRR_B ߩᒁᢙ߇ 1 એᄖߢ޽ࠆ‫ޕ‬

200014

CASEDISTRI1_14

Ṷ▚ሶ B_SQRTR_L ߩᒁᢙ߇ 1 એᄖߢ޽ࠆ‫ޕ‬

200015

CASEDISTRI1_15

Ṷ▚ሶ B_COSHR_L ߩᒁᢙ߇ 1 એᄖߢ޽ࠆ‫ޕ‬

200016

CASEDISTRI1_16

Ṷ▚ሶ B_SINHR_L ߩᒁᢙ߇ 1 એᄖߢ޽ࠆ‫ޕ‬

200017

CASEDISTRI1_17

Ṷ▚ሶ B_TANHRR_L ߩᒁᢙ߇ 1 એᄖߢ޽ࠆ‫ޕ‬

200018

CASEDISTRI1_18

Ṷ▚ሶ T_MULRR_L ߩᒁᢙ߇ 3 એᄖߢ޽ࠆ‫ޕ‬

200019

CASEDISTRI1_19

Ṷ▚ሶ T_MULRR_R ߩᒁᢙ߇ 3 એᄖߢ޽ࠆ‫ޕ‬

200020CASEDISTRI1_20

Ṷ▚ሶ T_DIVRR_L ߩᒁᢙ߇ 3 એᄖߢ޽ࠆ‫ޕ‬

200021

CASEDISTRI1_21

Ṷ▚ሶ T_DIVRR_R ߩᒁᢙ߇ 3 એᄖߢ޽ࠆ‫ޕ‬

200022

CASEDISTRI1_22

Ṷ▚ሶ T_EXPR_L ߩᒁᢙ߇ 3 એᄖߢ޽ࠆ‫ޕ‬

200023

CASEDISTRI1_23

Ṷ▚ሶ T_LOGR_L ߩᒁᢙ߇ 3 એᄖߢ޽ࠆ‫ޕ‬

200024

CASEDISTRI1_24

Ṷ▚ሶ T_LOG10R_L ߩᒁᢙ߇ 3 એᄖߢ޽ࠆ‫ޕ‬

200025

CASEDISTRI1_25

Ṷ▚ሶ T_POWRR_L ߩᒁᢙ߇ 3 એᄖߢ޽ࠆ‫ޕ‬

200026

CASEDISTRI1_26

Ṷ▚ሶ T_POWRR_R ߩᒁᢙ߇ 3 એᄖߢ޽ࠆ‫ޕ‬

200027

CASEDISTRI1_27

Ṷ▚ሶ T_SQRTR_L ߩᒁᢙ߇ 3 એᄖߢ޽ࠆ‫ޕ‬

200028

CASEDISTRI1_28

Ṷ▚ሶ T_COSHR_L ߩᒁᢙ߇ 3 એᄖߢ޽ࠆ‫ޕ‬

200029

CASEDISTRI1_29

Ṷ▚ሶ T_SINHR_L ߩᒁᢙ߇ 3 એᄖߢ޽ࠆ‫ޕ‬

200030CASEDISTRI1_30

Ṷ▚ሶ T_TANHR_L ߩᒁᢙ߇ 3 એᄖߢ޽ࠆ‫ޕ‬

200031

CASEDISTRI1_31྾ߟ⚵ౝߩṶ▚ሶߣߒߡ੍ᦼߒߥ޿߽ߩ߇⃻ࠇߚ‫ޕ‬

200032

CASEDISTRI1_32

಴ജ୯㈩೉ߩ઒ᒁᢙߩ૏⟎ߩਛߦ੍ᦼߒߥ޿߽ߩ߇⃻ࠇߚ‫ޕ‬㧔㧥㧝㧕InterpretDistri2 (interpret_d2.c)
201000

INTERPRETDISTRI2_0ࠗࡦ࠲ࡊ࡝࠲ਛ㑆⸒⺆ߩ᧦ઙㇱ㧔৻⥸ဳߩಽ㈩Ყ㧕ߩಣℂߢࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

201001

INTERPRETDISTRI2_1

ࠗࡦ࠲ࡊ࡝࠲ਛ㑆⸒⺆ߩታⴕࡊࡠࠣ࡜ࡓㇱ㧔৻⥸ဳߩಽ㈩Ყ㧕ߩಣℂߢࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬㧔㧥㧞㧕CondDistri2 (interpret_d2.c)
202000

CONDDISTRI2_0

ೋᦼ୯㈩೉ߩ઒ᒁᢙߩ૏⟎ߩਛߦ੍ᦼߒߥ޿߽ߩ߇⃻ࠇߚ‫ޕ‬

202001CONDDISTRI2_1

྾ߟ⚵ౝߩṶ▚ሶߣߒߡ੍ᦼߒߥ޿߽ߩ߇⃻ࠇߚ‫ޕ‬142㧔㧥㧟㧕CaseDistri2 (interpret_d2.c)
203000CASEDISTRI2_0

ೋᦼ୯㈩೉ߩ઒ᒁᢙߩ૏⟎ߩਛߦ੍ᦼߒߥ޿߽ߩ߇⃻ࠇߚ‫ޕ‬

203001

CASEDISTRI2_1

Ṷ▚ሶ B_MULRR_L ߩᒁᢙߩᢙ߇ 1 એᄖߢ޽ࠆ‫ޕ‬

203002

CASEDISTRI2_2

Ṷ▚ሶ B_MULRR_R ߩᒁᢙߩᢙ߇ 1 એᄖߢ޽ࠆ‫ޕ‬

203003

CASEDISTRI2_3

Ṷ▚ሶ B_MULRR_B ߩᒁᢙߩᢙ߇ 1 એᄖߢ޽ࠆ‫ޕ‬

203004

CASEDISTRI2_4

Ṷ▚ሶ B_DIVRR_L ߩᒁᢙߩᢙ߇ 1 એᄖߢ޽ࠆ‫ޕ‬

203005

CASEDISTRI2_5

Ṷ▚ሶ B_DIVRR_R ߩᒁᢙߩᢙ߇ 1 એᄖߢ޽ࠆ‫ޕ‬

203006

CASEDISTRI2_6

Ṷ▚ሶ B_DIVRR_B ߩᒁᢙߩᢙ߇ 1 એᄖߢ޽ࠆ‫ޕ‬

203007

CASEDISTRI2_7

Ṷ▚ሶ B_ABSR_L ߩᒁᢙߩᢙ߇ 1 એᄖߢ޽ࠆ‫ޕ‬

203008

CASEDISTRI2_8

Ṷ▚ሶ B_EXPR_L ߩᒁᢙߩᢙ߇ 1 એᄖߢ޽ࠆ‫ޕ‬

203009

CASEDISTRI2_9

Ṷ▚ሶ B_LOGR_L ߩᒁᢙߩᢙ߇ 1 એᄖߢ޽ࠆ‫ޕ‬

203010CASEDISTRI2_10

Ṷ▚ሶ B_LOG10R_L ߩᒁᢙߩᢙ߇ 1 એᄖߢ޽ࠆ‫ޕ‬

203011

CASEDISTRI2_11

Ṷ▚ሶ B_POWRR_L ߩᒁᢙߩᢙ߇ 1 એᄖߢ޽ࠆ‫ޕ‬

203012

CASEDISTRI2_12

Ṷ▚ሶ B_POWRR_R ߩᒁᢙߩᢙ߇ 1 એᄖߢ޽ࠆ‫ޕ‬

203013

CASEDISTRI2_13

Ṷ▚ሶ B_POWRR_B ߩᒁᢙߩᢙ߇ 1 એᄖߢ޽ࠆ‫ޕ‬

203014

CASEDISTRI2_14

Ṷ▚ሶ B_SQRTR_L ߩᒁᢙߩᢙ߇ 1 એᄖߢ޽ࠆ‫ޕ‬

203015

CASEDISTRI2_15

Ṷ▚ሶ B_COSHR_L ߩᒁᢙߩᢙ߇ 1 એᄖߢ޽ࠆ‫ޕ‬

203016

CASEDISTRI2_16

Ṷ▚ሶ B_SINHR_L ߩᒁᢙߩᢙ߇ 1 એᄖߢ޽ࠆ‫ޕ‬

203017

CASEDISTRI2_17

Ṷ▚ሶ B_TANHR_L ߩᒁᢙߩᢙ߇ 1 એᄖߢ޽ࠆ‫ޕ‬

203018

CASEDISTRI2_18

Ṷ▚ሶ B_TF ߩᒁᢙߩᢙ߇ 0 ߢ޽ࠆ‫ޕ‬

203019

CASEDISTRI2_19

Ṷ▚ሶ B_XNO3 ߩᒁᢙߩᢙ߇ 0 ߢ޽ࠆ‫ޕ‬

203020CASEDISTRI2_20

Ṷ▚ሶ T_MULRR_L ߩᒁᢙߩᢙ߇ 3 એᄖߢ޽ࠆ‫ޕ‬

203021

CASEDISTRI2_21

Ṷ▚ሶ T_MULRR_R ߩᒁᢙߩᢙ߇ 3 એᄖߢ޽ࠆ‫ޕ‬

203022

CASEDISTRI2_22

Ṷ▚ሶ T_DIVRR_L ߩᒁᢙߩᢙ߇ 3 એᄖߢ޽ࠆ‫ޕ‬

203023

CASEDISTRI2_23

Ṷ▚ሶ T_DIVRR_R ߩᒁᢙߩᢙ߇ 3 એᄖߢ޽ࠆ‫ޕ‬

203024

CASEDISTRI2_24

Ṷ▚ሶ T_EXPR_L ߩᒁᢙߩᢙ߇ 3 એᄖߢ޽ࠆ‫ޕ‬

203025

CASEDISTRI2_25

Ṷ▚ሶ T_LOGR_L ߩᒁᢙߩᢙ߇ 3 એᄖߢ޽ࠆ‫ޕ‬

203026

CASEDISTRI2_26

Ṷ▚ሶ T_LOG10R_L ߩᒁᢙߩᢙ߇ 3 એᄖߢ޽ࠆ‫ޕ‬

203027

CASEDISTRI2_27

Ṷ▚ሶ T_POWRR_L ߩᒁᢙߩᢙ߇ 3 એᄖߢ޽ࠆ‫ޕ‬

203028

CASEDISTRI2_28

Ṷ▚ሶ T_POWRR_R ߩᒁᢙߩᢙ߇ 3 એᄖߢ޽ࠆ‫ޕ‬

203029

CASEDISTRI2_29

Ṷ▚ሶ T_SQRTR_L ߩᒁᢙߩᢙ߇ 3 એᄖߢ޽ࠆ‫ޕ‬203030CASEDISTRI2_30

Ṷ▚ሶ T_COSHR_L ߩᒁᢙߩᢙ߇ 3 એᄖߢ޽ࠆ‫ޕ‬203031

CASEDISTRI2_31

Ṷ▚ሶ T_SINHR_L ߩᒁᢙߩᢙ߇ 3 એᄖߢ޽ࠆ‫ޕ‬203032

CASEDISTRI2_32

Ṷ▚ሶ T_TANHR_L ߩᒁᢙߩᢙ߇ 3 એᄖߢ޽ࠆ‫ޕ‬203033

CASEDISTRI2_33

Ṷ▚ሶ T_TF ߩᒁᢙߩᢙ߇ 0 ߢ޽ࠆ‫ޕ‬203034

CASEDISTRI2_34྾ߟ⚵ౝߩṶ▚ሶߣߒߡ੍ᦼߒߥ޿߽ߩ߇⃻ࠇߚ‫ޕ‬143

203035

CASEDISTRI2_35

಴ജ୯㈩೉ߩ઒ᒁᢙߩ૏⟎ߩਛߦ੍ᦼߒߥ޿߽ߩ߇⃻ࠇߚ‫ޕ‬㧔㧥㧠㧕InterpretReactX (interpret_rx.c)
204000

INTERPRETREACTX_0ࠗࡦ࠲ࡊ࡝࠲ਛ㑆⸒⺆ߩ᧦ઙㇱ㧔᳓⋧ߩൻቇ෻ᔕ㧕ߩಣ
ℂߢࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

204001

INTERPRETREACTX_1

ࠗࡦ࠲ࡊ࡝࠲ਛ㑆⸒⺆ߩታⴕࡊࡠࠣ࡜ࡓㇱ㧔᳓⋧ߩൻቇ෻ᔕ㧕ߩಣℂߢࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬㧔㧥㧡㧕CondReactX (interpret_rx.c)
205000CONDREACTX_0

ೋᦼ୯㈩೉ߩ઒ᒁᢙߩ૏⟎ߩਛߦ੍ᦼߒߥ޿߽ߩ߇⃻ࠇߚ‫ޕ‬

205001CONDREACTX_1

྾ߟ⚵ౝߩṶ▚ሶߣߒߡ੍ᦼߒߥ޿߽ߩ߇⃻ࠇߚ‫ޕ‬㧔㧥㧢㧕CaseReactX (interpret_rx.c)
206000CASEREACTX_0

ೋᦼ୯㈩೉ߩ઒ᒁᢙߩ૏⟎ߩਛߦ੍ᦼߒߥ޿߽ߩ߇⃻ࠇߚ‫ޕ‬

206001CASEREACTX_1

྾ߟ⚵ౝߩṶ▚ሶߣߒߡ੍ᦼߒߥ޿߽ߩ߇⃻ࠇߚ‫ޕ‬

206002CASEREACTX_2

Damping factor g ߦ߽ൻቇ෻ᔕㅦᐲᑼߦ߽⃻ࠇߥ޿ൻቇ⒳߇⃻ࠇߚ‫ޕ‬

206003CASEREACTX_3

಴ജ୯㈩೉ߩ઒ᒁᢙߩ૏⟎ߩਛߦ੍ᦼߒߥ޿߽ߩ߇⃻ࠇߚ‫ޕ‬㧔㧥㧣㧕InterpretRactY (interpret_ry.c)
207000

INTERPRETREACTY_0ࠗࡦ࠲ࡊ࡝࠲ਛ㑆⸒⺆ߩ᧦ઙㇱ㧔᦭ᯏ⋧ߩൻቇ෻ᔕ㧕ߩ
ಣℂߢࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬

207001

INTERPRETREACTY_1ࠗࡦ࠲ࡊ࡝࠲ਛ㑆⸒⺆ߩታⴕࡊࡠࠣ࡜ࡓㇱ㧔᦭ᯏ⋧ߩൻቇ෻ᔕ㧕ߩಣℂߢࠛ࡜࡯߇⊒↢ߒߚ‫ޕ‬㧔㧥㧤㧕CondReactY (interpret_ry.c)
208000CONDREACTY_0

ೋᦼ୯㈩೉ߩ઒ᒁᢙߩ૏⟎ߩਛߦ੍ᦼߒߥ޿߽ߩ߇⃻ࠇߚ‫ޕ‬

208001CONDREACTY_1

྾ߟ⚵ౝߩṶ▚ሶߣߒߡ੍ᦼߒߥ޿߽ߩ߇⃻ࠇߚ‫ޕ‬㧔㧥㧥㧕CaseReactY (interpret_ry.c)
209000CASEREACTY_0

ೋᦼ୯㈩೉ߩ઒ᒁᢙߩ૏⟎ߩਛߦ੍ᦼߒߥ޿߽ߩ߇⃻ࠇߚ‫ޕ‬

209001CASEREACTY_1

྾ߟ⚵ౝߩṶ▚ሶߣߒߡ੍ᦼߒߥ޿߽ߩ߇⃻ࠇߚ‫ޕ‬

209002CASEREACTY_2

Damping factor g ߦ߽ൻቇ෻ᔕㅦᐲᑼߦ߽⃻ࠇߥ޿ൻቇ⒳߇⃻ࠇߚ‫ޕ‬

209003CASEREACTY_3

಴ജ୯㈩೉ߩ઒ᒁᢙߩ૏⟎ߩਛߦ੍ᦼߒߥ޿߽ߩ߇⃻ࠇߚ‫ޕ‬㧔㧝㧜㧜㧕DistriDBP (masstr.c)144210000

DISTRIDBP_0

᳓⚛ࠗࠝࡦ߹ߚߪ DBP ߇⸘▚ߔߴ߈ൻቇ⒳ߦߥߞߡߥ޿‫ޕ‬㧔㧝㧜㧝㧕DistriMBP (masstr.c)
211000

DISTRIMBP_0

DBP ߹ߚߪ MBP ߇⸘▚ߔߴ߈ൻቇ⒳ߦߥߞߡ޿ߥ޿‫ޕ‬㧔㧝㧜㧞㧕DistriPO4 (masstr.c)
212000

DISTRIPO4_0

࡝ࡦ㉄߇⸘▚ߔߴ߈ൻቇ⒳ߦߥߞߡ޿ߥ޿‫ޕ‬㧔㧝㧜㧟㧕DistriFP (masstr.c)
213000

DISTRIFP_0

ᩭಽⵚ↢ᚑ‛㧔FP㧕߇⸘▚ߔߴ߈ൻቇ⒳ߦߥߞߡ޿ߥ޿‫ޕ‬㧔㧝㧜㧠㧕DistriH2O2 (masstr.c)
214000

DISTRIH2O2_0

ㆊ㉄ൻ᳓⚛߇⸘▚ߔߴ߈ൻቇ⒳ߦߥߞߡ޿ߥ޿

145

࿖㓙න૏♽㧔5+㧕

⴫㧝㧚5+ၮᧄන૏
5+ၮᧄන૏
ၮᧄ㊂ฬ⒓⸥ภ㐳ߐࡔ ࡯ ࠻ ࡞ O
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5+ၮᧄන૏
⚵┙㊂ฬ⒓⸥ภ㕙Ⓧᐔ ᣇ ࡔ ࡯ ࠻ ࡞O૕Ⓧ┙ ᴺ ࡔ ࡯ ࠻ ࡞Oㅦ ߐ 㧘 ㅦ ᐲࡔ ࡯ ࠻ ࡞ Ფ ⑽OUടㅦᐲࡔ ࡯ ࠻ ࡞ Ფ ⑽ Ფ ⑽
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⾰㊂૕Ⓧ㧔Ყ૕Ⓧ㧕 ┙ᴺࡔ࡯࠻࡞Ფࠠࡠࠣ࡜ࡓ OMI㔚ᵹኒᐲ ࠕࡦࡍࠕᲤᐔᣇࡔ࡯࠻࡞
#O⏛ ⇇ ߩ ᒝ ߐࠕ ࡦ ࡍ ࠕ Ფ ࡔ ࡯ ࠻ ࡞#O㧔 ‛ ⾰ ㊂ ߩ 㧕 Ớ ᐲ ࡕ ࡞ Ფ ┙ ᣇ ࡔ ࡯ ࠻ ࡞ OQNOノᐲ ࠞ ࡦ ࠺ ࡜ Ფ ᐔ ᣇ ࡔ ࡯ ࠻ ࡞ EFOዮ᛬₸ 㧔ᢙ‫ߩޓ‬㧕‫ޓ‬㧝⴫㧡㧚5+ធ㗡⺆ਸ਼ᢙ‫ ޓ‬ធ㗡⺆⸥ภ ਸ਼ᢙ‫ ޓ‬ធ㗡⺆
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⸥ภ
F
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⴫㧢㧚࿖㓙න૏♽ߣ૬↪ߐࠇࠆ߇࿖㓙න૏♽ߦዻߐߥ޿න૏

⴫㧟㧚࿕᦭ߩฬ⒓ߣߘߩ⁛⥄ߩ⸥ภߢ⴫ߐࠇࠆ5+⚵┙න૏
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5X,MIO࡮U
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‫⴫ߪ଀↪ޓ‬㧠ߦ␜ߐࠇߡ޿ࠆ‫ޕ‬D ታ㓙ߦߪ‫⸥ߪߦᤨࠆߔ↪૶ޔ‬ภTCF෸߮UT߇↪޿ࠄࠇࠆ߇‫ޔ‬⠌ᘠߣߒߡ⚵┙න૏ߣߒߡ
ߩ⸥ภ̌㧝̍ߪ᣿␜ߐࠇߥ޿‫ޕ‬E ᷹శቇߢߪ‫ߩࡦࠕࠫ࡜࠹ࠬޔ‬ฬ⒓ߣ⸥ภUTࠍන૏ߩ⴫ߒᣇߩਛߦߘߩ߹߹⛽ᜬߒߡ޿ࠆ‫ޕ‬F ߎߩන૏ߪ‫ࠬ࠙ࠪ࡞࠮࡝ࡒߡߒߣ଀ޔ‬ᐲ㨙͠ߩࠃ߁ߦ5+ធ㗡⺆ࠍ઻ߞߡ↪޿ߡ߽⦟޿‫ޕ‬⴫㧠㧚න૏ߩਛߦ࿕᦭ߩฬ⒓ߣߘߩ⁛⥄ߩ⸥ภࠍ฽߻5+⚵┙න૏ߩ଀
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⸥ภ
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⸥ภ
5+න૏ߦࠃࠆ୯
OKP OKPUJJOKPUF
FJUq q Ǹ TCF
̉ ̉  q Ǹ TCF
̍ ̍  ̉ Ǹ TCF
N‫ޔ‬. NFOOVV MI0R 0R$$  NP 0R

⴫㧣㧚࿖㓙න૏♽ߣ૬↪ߐࠇߎࠇߦዻߐߥ޿න૏ߢ
5+න૏ߢ⴫ߐࠇࠆᢙ୯߇ታ㛎⊛ߦᓧࠄࠇࠆ߽ߩ
ฬ⒓⸥ภ
5+න૏ߢ޽ࠄࠊߐࠇࠆᢙ୯㔚 ሶ ࡏ ࡞ ࠻ G8 G8  ,⛔৻ේሶ⾰㊂න૏ W W  MIᄤ ᢥ න ૏ WC WC  O⴫㧤㧚࿖㓙න૏♽ߦዻߐߥ޿߇࿖㓙න૏♽ߣ‫ޓޓޓ‬૬↪ߐࠇࠆߘߩઁߩන૏
ฬ⒓⸥ภ
5+න૏ߢ޽ࠄࠊߐࠇࠆᢙ୯
ᶏ㉿㧝ᶏ㉿Oࡁ࠶࠻㧝ࡁ࠶࠻㧝ᶏ㉿Ფᤨ  OUࠕ࡯࡞ C 㧝CFCOOࡋ ࠢ ࠲ ࡯ ࡞ JC 㧝JCJOOࡃ࡯࡞ DCT 㧝DCT/2CM2CJ2C2C
ࠝࡦࠣࠬ࠻ࡠ࡯ࡓ Έ 㧝ΈPOOࡃ࡯ࡦ D 㧝DHOO⴫㧥㧚࿕᦭ߩฬ⒓ࠍ฽߻%)5⚵┙න૏ฬ⒓⸥ภ 5+න૏ߢ޽ࠄࠊߐࠇࠆᢙ୯ࠛ࡞ࠣ GTI GTI ,࠳ࠗࡦ F[P F[P0
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⴫㧚࿖㓙න૏ߦዻߐߥ޿ߘߩઁߩන૏ߩ଀
ฬ⒓⸥ภ
5+න૏ߢ޽ࠄࠊߐࠇࠆᢙ୯
ࠠࡘ࡝
࡯ %K %K$S࡟ ࡦ ࠻ ࠥ ࡦ 4 4%MI࡜࠼ TCF TCFE)[)[࡟
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OGVTKEECTCVOI MI࠻࡞ 6QTT 6QTT  2C
ᮡ Ḱ ᄢ ᳇ ࿶ CVO CVO2C
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