First International Symposium on
Interdisciplinary Materials Science（ISIMS-2008）
March 13-14, 2008
Tsukuba

Abstract Booklet

Strategic Initiatives forCenter of Interdisciplinary Materials Science
University of Tsukuba

Tsukuba Research Center for Interdisciplinary Materials Science (TIMS) wasestablished in 2003 upon the achievements of Emeritus Professor Hideki Shirakawa, aNobel laureate in chemistry, and has achieved substancial results in research andeducation in materials science and nanotechnology. In this fiscal year, we planned thenext phase of TIMS. At the same time, two groups in Graduate School of Pure andApplied Sciences independently proposed plans of the center of innovative hybrid
molecules (leader: Toshiharu Teranishi) and the center of interdisciplinary opticalscience (leader: Yutaka Moritomo). As these proposals are closely related, the university
decided to support them as a unified program in the framework of Pre Strategic
Initiatives.
The First International Symposium on Interdisciplinary Materials Science（ISIMS-2008） will be held as a part of this program, and will provide a forum to
discuss the latest research progress in the related fields, i.e., innovative hybrid
molecules, interdisciplinary optical science, nano-science, and biomaterial.
Organizer:

Strategic Initiatives for Center of Interdisciplinary Materials Science

Date:

March 13-14, 2008

Venue:

EPOCHAL TSUKUBA (Tsukuba International Congress Center)
Conference Room 101 & 102

Organizing Committee
Youiti Ootuka,

Kikuo Yamabe,

Tatsuya Nabeshima,

Yukio Nagasaki,

Takaki Kanbara,

Hidemi Shigekawa,

Yutaka Moritomo,

Keiichi Tomishige,

Toshiharu Teranishi
Administrative Coordinator
Kiyoshi Akiba,

Emiko Omori

Program
March 13 (Thursday)
9:20

Opening
Youiti Ootuka (TIMS, University of Tsukuba)

Session1.

Interdisciplinary Optical Science
chairman: Yutaka Moritomo

9:30-10:10

Collective atomic motion in solids observed as wave-packet propagation
Tohru Suemoto (Institute of Solid-State Physics, University of Tokyo) ..................... 1

10:10-10:35

Femtosecond microscopic study of dynamics of surface plasmon polariton
Atsushi Kubo (University of Tsukuba; PRESTO-JST)

10:35-10:45.............................2

breakchairman: Muneaki Hase

10:45-11:10

Adiabatic manipulation of Raman process and its application to novel coherent
light source
Masayuki Katsuragawa (University of Electro-Communications; PREST-JST)

11:10-11:35.... 3Coherent dynamics of exciton qubits in strain-compensated quantum dots
Junko

Ishi-Hayase(JST-PREST;

National

InstituteofInformation

andCommunications Technology (NICT); Department of Physics, Sophia University) ... 4

11:35-12:00

Phonon-induced low energy dynamics of graphite
Jae Dong Lee（School of materials science, Japan Advanced Institute of Science andTechnology)

12:00-13:30

Session 2.

...............................................................5

Lunch

Innovative Hybrid Molecules
chairman: Takeshi Akasaka

13:30-14:20

Supramolecular Photo- and Electro-active Nanostructures
Nazario Martin (Departament of Organic Chemistry, University of Complutense) .... 6chairman: Hiroki Oshio

14:20-14:55

Spin-chiral-structural Correlation in Frustrated Molecular Based Magnets

Hiroyuki Nojiri (Institute for Materials Research and CINTS, Tohoku University) ....7

14:55-15:05

breakchairman: Toshiharu Teranishi

15:05-15:40

Main Group Approach to New pi-Electron Materials
Shigehiro Yamaguchi (Department of Chemistry, Graduate School of Science,
Nagoya University; SORST, JST)

15:40-16:00.............................................. 8

Design and Synthesis of Helical Oligooxime-Zinc(II) Complexes for Ion
Recognition
Shigehisa Akine (Tsukuba Research Institute for Interdisciplinary Materials Science,
Graduate School of Pure and Applied Sciences, University of Tsukuba)

16:00- 18:30 Poster session(Conference Room 102)

18:30-(Restaurant ESPOIR )Reception............... 9

March 14 (Friday)
Session 3.

Nano Science/ Nano Technology
chairman: Hidemi Shigekawa

9:00-9:40

Future of Nano Technology
Young Kuk (Department of Physics and Astronomy, Seoul National University.) ... 10

9:40-10:00

Characteristics of Nanoscale Devices
Tomihiro Hashizume (Advanced Research Laboratory, Hitachi, Ltd.; Department of
Physics, Tokyo Institute of Technology; WPI Advanced Institute for Materials
Research, Tohoku University)

10:00-10:10............................................. 11

breakchairman: Young Kuk & Takaki Kanbara

10:10-10:30

Functionalized metal complex with molecular recognition ability controlled byexternal stimuli
Junpei Kuwabara (Tsukuba Research Center for Interdisciplinary Materials Science,
University of Tsukuba)............................................................ 1210:30-10:50

Molecular wire for multi-channel transistor
Yutaka Wakayama (Advanced Electronic Materials Center, National Institute forMaterials Science)

10:50-11:10.

............................................ 13

Atomic Switch and Related Applications
Tsuyoshi Hasegawa (WPI Center for Materials Nanoarchitectonics (MANA),
National Institute for Materials Science )11:10-11:30............................................ 14

Superconductivity of Nanometer-size superconductors visualized by STM
Toyoaki Eguchi (Institute for Solid State Physics, University of Tokyo) ........... 15

11:30-13:00 Lunch
Session 4.

Bio Materials
chairman: Yukio Nagasaki

13:00-13:40

Quantification of copy number variation by multiplex ligation-dependent
sequence amplification (MLSA) and photodiode-based pyrosequencer
Guohua Zhou (Medical School, Nanjing University) .............................................. 16

13:40-14:00

Density Controlled PEG/Biomacromolecule Co-Immobilized Gold Surface as anIntelligent Sensor Platform
Keitaro Yoshimoto (Center for Tsukuba Advanced Research Alliance (TARA),
Graduate School of Pure and Applied Sciences, and Tsukuba Research Center forInterdisciplinary Materials Science (TIMS), University of Tsukuba) ....................... 18

14:00-14:10

breakchairman: Guohua Zhou ＆14:10-14:30

Keitaro Yoshimoto

Effective Protein Recognition on the Glycosylated Self- Assembled Monolayer
Yukari Sato (National Institute of Advanced Industrial Science and Technology(AIST))

14:30-14:50............................................ 19

Novel Biocompatible Surface with Concentrated Polymer Brushes
Chiaki Yoshikawa (International Center for Materials Nanoarchitectonics, National
Institute for Materials Science)

14:50-15:10............................................ 20

Dynamic control of cellular microenvironment based on caged compounds
Jun Nakanishi (WPI Center for Materials Nanoarchitectonics (MANA), National

Institute for Materials Science; PREST-JST)

15:10-15:30......................................... 21

Formation of elaborately-patterned co-culture system by photo-control of celladhesion
Kimio Sumaru (Research Center of Advanced Bionics, National Institute ofAdvanced Industrial Science and Technology (AIST))

15:30

Closing
Toshiharu Teranishi(University of Tsukuba)............................ 22

List of Poster Presentations
P-1

Activation of Alkynes by Indium Salts and Its Application to Catalytic CarbonCarbon Bond Formation
Katsukiyo Miura, Kiyomi Yamamoto, Sayaka Toyohara, Junji Ichikawa and Akira
Hosomi
Department of Chemistry, Graduate School of Pure and Applied Sciences,
University of Tsukuba

P-2

Synthesis of Fluorine-Containing Five-Membered Heterocyclic Compounds via
Nucleophilic 5-endo-trig Cyclizations of Metalloenolates and Metalloenamines
Masahiro Ikeda1, Kotaro Sakoda2, and Junji Ichikawa1
1 Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba,
Ibaraki 305-8573, Japan
2 Graduate School of Science, University of Tokyo,

P-3

Synthetic Study on 13-Oxyingenol
Takayuki Ohyoshi, Toshihiro Haruna, Yuki Asuma, Kenta Aoki, Satomi Ohmura,
Ichiro Hayakawa and Hideo Kigoshi
Department of Chemistry, Graduate School of Pure and Applied Sciences, andCenter for Tsukuba Advanced Research Alliance, University of Tsukuba,

P-4

Synthesis of Ustalic Acid
Hidekazu, WATANABE; Ichiro, HAYAKAWA; Hideo, KIGOSHI.
Department of Chemistry, Graduate School of Pure and Applied Sciences, andCenter for Tsukuba Advanced Research Alliance, University of Tsukuba,

P-5

Total Synthesis of Haterumalide NA
Mitsuru UEDA, Yuta SUZUKI, Kensaku YOSHIZATO, Yoichi IKEDA, Masashi
YAMAURA, Ichiro HAYAKAWA, Hideo KIGOSHI ,Department of Chemistry, Graduate School of Pure and Applied Sciences, andCenter for Tsukuba Advanced Reserch Alliance, University of Tsukuba,

P-6

Synthesis of Glaziovianin A
Akiyuki Ikedo, Ichiro Hayakawa, Hideo Kigoshi
Department of Chemistry, Graduate School of Pure and Applied Sciences, andCenter for Tsukuba Advanced Research Alliance, University of Tsukuba,

P-7

Synthesis of Cyclic Zinc(II) Dipyrrin Trimer by Heteroleptic Coordination
Satoko Ueda1, Chusaku Ikeda1, Tatsuya Nabeshima1,2.
1 Graduate School of Pure and Applied Sciences, University of Tsukuba,
2 Tsukuba Research Institute for Interdisciplinary Materials Science, University ofTsukuba,

P-8

Ion pair recognition by multidentate pyridine ligand bearing urea moieties
Hiroshi Tamai1 and Tatsuya Nabeshima1,2
1 Department of Chemistry, University of Tsukuba
2 Tsukuba Research Center for Interdisciplinary Materials Science (TIMS),
University of Tsukuba

P-9

Recognition of Aromatic Guests by Molecular Metalloclefts Bearing TerpyridinePt(II) Moieties
Nozomi Kimura1, Mayumi Hasegawa1, Shigehisa Akine1, 2 and Tatsuya

Nabeshima1, 2
1 Graduate School of Pure and Applied Sciences, University of Tsukuba,
2 Tsukuba Research Institute for Interdisciplinary Materials Science, University ofTsukuba,
P-10

Self-assembled Cyclic Boron-Dipyrrin Oligomers as a Supramolecular Host
Chusaku Ikeda1 and Tatsuya Nabeshima1, 2
1 Graduate School of Pure and Applied Sciences, University of Tsukuba
2 Tsukuba Research Center for Interdisciplinary Materials Science (TIMS),
University of Tsukuba

P-11

Synthesis and Complexation of Podand with a Catechol Moiety for Responsible
Metallohost
Shiho Kijima1, Yuki Imamura1,2 and Tatsuya Nabeshima1,2
1Graduate School of Pure and Applied Sciences, University of Tsukuba,
2Tsukuba Research Institute for Interdisciplinary Materials Science, University ofTsukuba,

P-12

One-pot Synthesis of Hetero and Homo Multi-metal Complexes of Macrocyclic
Trisaloph Ligand
Ryoko Ebata1 and Tatsuya Nabeshima1,2
1Graduate School of pure and applied Sciences, University of Tsukuba
2Tsukuba Research Center for Interdisciplinary Materials Science (TIMS),
University of Tsukuba,

P-13

Synthesis of Macrocyclic Hexaoxime Ligand Using Two Different Metal Ions
Shuichi Sunaga,1 Shigehisa Akine,1,2 and Tatsuya Nabeshima1,2
1 Graduate School of Pure and Applied Sciences, University of Tsukuba
2 Tsukuba Research Center for Interdisciplinary Materials Science (TIMS),
University of Tsukuba

P-14

Synthesis and luminescent properties of zinc(II)-lanthanide(III) complexes of oximechelate ligands
Utsuno Fumihiko,1 Morita Yoko,1 Akine Shigehisa1,2 and Nabeshima Tatsuya1,2
1Graduate School of Pure and Applied Sciences, University of Tsukuba,
2Tsukuba Research Center for Interdisciplinary Materials Science (TIMS),
University of Tsukuba

P-15

Synthesis, Ion Recognition Ability and Luminescence Properties of Novel Iridium
Complexes with Azacrown Ethers
Masaki Sairenji,1 Chusaku Ikeda,1 and Tatsuya Nabeshima1,2
1 Graduate School of Pure Applied Sciences, University of Tsukuba
2 Tsukuba Research Center for Interdisciplinary Materials Science (TIMS),
University of Tsukuba

P-16

Synthesis of Novel Macrocyclic Oligo-oxime Ligands by Ring-closing Olefin
Metathesis of Helical Metal Complexes
Toshio Tadokoro1, Shigehisa Akine1,2 and Tatsuya Nabeshima1,2
1 Graduate School of Pure and Applied Sciences, University of Tsukuba
2 Tsukuba Research Center for Interdisciplinary Materials Science (TIMS),
University of Tsukuba

P-17

Synthesis and Guest Recognition Ability of Macrocyclic Oligo-Dipyrrin BF2ComplexNaoya Sakamoto,1 Chusaku Ikeda1 and Tatsuya Nabeshima1,2
1Graduate School of Pure and Applied Sciences, University of Tsukuba,
2 Tsukuba Research Center for Interdisciplinary Materials Science (TIMS),
University of Tsukuba,
P-18

Platinum-Directed Formation of Terpyridine-Type Cyclic Trinuclear Self-Assembly
Robert Trokowski, Shigehisa Akine and Tatsuya Nabeshima
Graduate School of Pure and Applied Sciences, University of Tsukuba
Tsukuba Research Institute for Interdisciplinary Materials Science (TIMS),
University of Tsukuba,

P-19

Helical Complexes of Flexible Ligand Based on Two N2O2 Chelate Moieties
Connected with Polyether Linker
Yoko Morita,1 Shigehisa Akine1,2 and Tatsuya Nabeshima1,2
1 Graduate School of Pure and Applied Sciences, University of Tsukuba
2 Tsukuba Research Center for Interdisciplinary Materials Science (TIMS),
University of Tsukuba

P-20

Synthesis and Function of Novel Terpyridine Podand Bearing Several Recognition
Sites
Takuro Makiguchi,1 Shigehisa Akine,1, 2 Tatsuya Nabeshima1, 2
1Graduate School of Pure and Applied Sciences, University of Tsukuba,
2Tsukuba Research Center for Interdisciplinary Materials Science (TIMS),
University of Tsukuba

P-21

Synthesis of Novel Terpyridine Ligand Bearing Naphthalene-diimide Moieties at 6,6’’-Positions
Toshihiko Shimada1, Chusaku Ikeda1 and Tatsuya Nabeshima1, 2
1 Graduate School of Pure and Applied Sciences, University of Tsukuba,
2 Tsukuba Research Institute for Interdisciplinary Materials Science, University ofTsukuba,P-22

Synthesis and Complexation of Tripodand Having Terminal Catechol Moieties
Yuki Imamura and Tatsuya Nabeshima
Graduate School of Pure and Applied Sciences, University of Tsukuba
Tsukuba Research Center for Interdisciplinary Materials Science (TIMS),
University of Tsukuba

P-23

Electron transfer from cytochrome c to blue copper proteins
Kiyofumi Irie,1 Shin-ichi J. Takayama,1 Hulin Tai,1 Shin-ichi Mikami,1 Shin
Kawano,1
Shigenori Nagatomo,1 Takumi Kawahara,2 Noriaki Funasaki,2 Teruhiro Takabe,3
Shun Hirota,4,5 and Yasuhiko Yamamoto1
1Univ. of Tsukuba; 2Kyoto Pharm. Univ.; 3Meijo Univ.; 4NIST; 5PRESTO.;

P-24

Role of heme 17-propionic acid in the regulation of redox potential of Pseudomonas

aeruginosa cytochrome c551

Shin-ichi Mikami1, Kiyofumi Irie1, Shin-ichi J. Takayama1, Hulin Tai1, Masato
Kage1, Shin
Kawano1, Shigenori Nagatomo1, and Yasuhiko Yamamoto1
1 Tsukuba Research Institute for Interdisciplinary Materials Science, University ofTsukuba,
P-25

Control of the electrochemical properties of ruthenium complexes containingsecondary thioamide-based pincer ligands
Takuya Teratani1,2, Ken Okamoto1,2, Take-aki Koizumi2, Takaki Kanbara1, andTakakazu Yamamoto2
1Tsukuba Research Center for Interdisciplinary Materials Science, University ofTsukuba2Chemical Resources Laboratory, Tokyo Institute of Technology
P-26

Modulation of Luminescence of Pincer Platinum Complexes Coordinated Secondary
Thioamide Units by Base and Anion
Ken Okamoto1,2, Takakazu Yamamoto1, and Takaki Kanbara2
1Chemical Resources Laboratory, Tokyo Institute of Technology,
2Tsukuba Research Center for Interdisciplinary Materials Science, University ofTsukuba,P-27

Positional Control of Encapsulated Metal Atoms Inside a Fullerene Cage by
Exohedral Chemical Functionalization
Michio Yamada,1 Chika Someya,1 Takatsugu Wakahara,1 Takahiro Tsuchiya,1Takeshi Akasaka,1 Yutaka Maeda,2 Kenji Yoza,3 Naomi Mizorogi,4 and Shigeru
Nagase4

1 Center for Tsukuba Advanced Research Alliance, University of Tsukuba,
2Department of Chemistry, Tokyo Gakugei University, Koganei,
3Bruker AXS K. K.,
4Department of Theoretical Molecular Science,Institute for Molecular Science,

P-28

Chemical Derivatization of La@C82 and La2@C80 with Phenylchlorodiazirine
Haruka Enoki1, Midori O. Ishitsuka1, Takahiro Tsuchiya1, Takeshi Akasaka1,
Zdenek Slanina1, Michael T. H. Liu2, Naomi Mizorogi3, Shigeru Nagase3
1 Center for Tsukuba Advanced Research Alliance, University of Tsukuba,
2 Department of Chemistry, University of Prince Edward Island,
3 Institute for Molecular Science,

P-29

Photophysical Properties of N@C60
Hidefumi Nikawa1, Yoichiro Matsunaga1, Takeshi Akasaka1, Tatsuhisa Kato2,
Yasuyuki Araki3, Osamu Ito3, Masafumi Ata4, and Klaus-Peter Dinse5

1Center for Tsukuba Advanced Research Alliance, University of Tsukuba,
2Department of Chemistry, Josai University,
3Institute of Multidisciplinary Research for Advanced Materials, Tohoku
University,
4 National Institute of Advanced Industrial Science and Technology (AIST),
5Physical Chemistry III, Darmstadt University of Technology,

P-30

Structure determination and chemical functionalization of metal-carbide
endohedral metallofullerene Sc2C2@C82(C2v)
Koji Nakajima1, Yuko Yamazaki1, Takatsugu Wakahara1, Takahiro Tsuchiya1,
Yutaka Maeda2, Takeshi Akasaka1*, Markus Waelchli3, Kenji Yoza4, Naomi
Mizorogi5, and Shigeru Nagase5
1Center for Tsukuba Advanced Research Alliance, University of Tsukuba,
2Department of Chemistry, Tokyo Gakugei University,
3Bruker Biospin K. K.
4Bruker AXS K. K,
5Department of Theoretical and Computational Molecular Science, Institute for
Molecular Science,

P-31

Structure and Electronic Property of Sc@C82

Makoto Hachiya1, Yuko Iiduka1, Takatsugu Wakahara1, Takahiro Tsuchiya1,
Yutaka Maeda2, Takeshi Akasaka1, Naomi Mizorogi3, Shigeru Nagase3
1Center for Tsukuba Advanced Research Alliance, University of Tsukuba,
2Department of Chemistry, Tokyo Gakugei University,
3Department of Theoretical and Computational Molecular Science, Institute for
Molecular Science,
P-32

Synthesis and Properties of Endohedral Metallofullerene Ligand
Yuya Yokosawa, Takahiro Tsuchiya, Takeshi Akasaka

Center for Tsukuba Advanced Research Alliance, University of Tsukuba
P-33

13C NMR Spectroscopic Study on C2 Cluster Encapsulated in Fullerene Cage
Yuko Yamazaki,1 Koji Nakajima,1 Takatsugu Wakahara,1 Tsuchiya Takahiro,1
Yutaka Maeda,2 Takeshi Akasaka,1,* Markus Waelchli,3 Naomi Mizorogi,4Shigeru Nagase,4,*
1Center for Tsukuba Advanced Research Alliance, University of Tsukuba,
2Department of Chemistry, Tokyo Gakugei University,
3Bruker BioSpin, K. K.,
4Department of Theoretical and Computational Molecular Science, Institute for
Molecular Science

P-34

Reaction of La@C82 with Cyclopentadiene Derivatives
Satoru Sato,1 Yutaka Maeda,2 Koji Inada,2 Michio Yamada,1 Takahiro Tsuchiya,1Midori O. Ishitsuka,1 Tadashi Hasegawa,2 Takeshi Akasaka,1 Tatsuhisa Kato,3Naomi Mizorogi, 4 and Shigeru Nagase4

1Center for Tsukuba Advanced Research Alliance, University of Tsukuba,
2Department of Chemistry, Tokyo Gakugei University,
3Department of Chemistry, Josai University,
4Department of Theoretical and Computational Molecular Science, Institute for
Molecular Science,

P-35

Novel Aziridination of [60]Fullerene with Sulfilimine: Interconversion between an
Aziridinofullerene and an Azafulleroid
Mitsunori Okada1, Tsukasa Nakahodo2, Tetsuo Fujie3, Toshiaki Yoshimura3,
Hiroyuki Morita3, Midori Ishitsuka1, Takahiro Tsuchiya1, Yutaka Maeda4, Hisashi
Fujihara2, Takeshi Akasaka1, Xingfa Gao5 and Shigeru Nagase5
1Center for Tsukuba Advanced Research Alliance, University of Tsukuba,
2Department of Applied Chemistry, Kinki University,
3Department of Applied Chemistry, Graduate School of Science and Engineering
University of Toyama,
4Department of Chemistry, Tokyo Gakugei University,
5Department of Theoretical Molecular Science, Institute for Molecular Science,

P-36

Redox Active Single-Chain Magnet and Single-Molecule Magnet
Kiyotaka Mitsumoto, Mayumi Ui, Masayuki Nihei, Takuya Shiga, Hiroki Oshio
Graduate School of Pure and Applied Sciences, University of Tsukuba,

P-37

Manganese-Terbium Single-Molecule Magnets
Takuya Shiga,1 Hiroyuki Nojiri,2 and Hiroki Oshio1
1 Graduate School of Pure and Applied Sciences, University of Tsukuba,
2 Institute of Material Research, Tohoku University, Katahira 2-1-1, Aoba-ku,
Sendai 980–8577, Japan

P-38

Dual Spin State Conversion in An Iron(II) Complex

Masayuki Nihei, Nobukazu Takaahshi, Hirotaka Tahira, Hiroki Oshio ….
Graduate School of Pure and Applied Sciences, University of Tsukuba,
P-39

Electrochemical Polymerization of Furan-based Three Rings Monomers in a
Cholesteric Liquid Crystal Electrolyte
Kohsuke Kawabata, Hiroyuki Yoneyama, Akitsu Tsujimoto, Hiromasa Goto*
Graduate School of Pure and Applied Sciences, Institute of Materials Science,
University of Tsukuba,

P-40

Electrochemical Synthesis and Properties of Optically Active Polyanilines
Kohsuke Kawabata, Hiromasa Goto
Graduate School of Pure and Applied Sciences, Institute of Materials Science,
University of Tsukuba,

P-41

Asymmetric Electrochemical Polymerization of Monomers Consist of Thiophene
and Furan Rings
Hiroyuki Yoneyama, Kohsuke Kawabata, Akitsu Tsujimoto, Hiromasa Goto*
Graduate School of Pure and Applied Sciences, Institute of Materials Science,
University of Tsukuba,

P-42

Novel Synthesis of ZnPd Nanoparticles
Ryota Sato, Masafumi Nakaya, Masayuki Kanehara, and Toshiharu Teranishi
Department of Chemistry, Graduate School of Pure and Applied Sciences,
University of Tsukuba,

P-43

Acid-Mediated Precise Size Control of Thiol-Protected Gold Nanoparticles
Junichi Sakurai, Masayuki Kanehara, Toshiharu Teranishi
Graduate School of Pure and Applied Science, University of Tsukuba,

P-44

Synthesis of Porphyrin Derivative-Protected Small Metal Nanoparticles
Hideaki Tenkaji, Masayuki Kanehara, Toshiharu Teranishi
Graduate School of Pure and Applied Sciences, University of Tsukuba,

P-45

Synthesis and Characterization of PdCoPd Sulfide Nanopeanuts
Masaki Saruyama, Masafumi Nakaya, Masayuki Kanehara, Toshiharu Teranishi
Department of Chemistry, Graduate School of Pure and Applied Sciences,
University of Tsukuba,

P-46

Synthesis and Characterization of Anisotropically Phase-Segregated CdCu Sulfide
Nanoacorns
D. Inui, M. Saruyama, M. Nakaya, M. Kanehara and T. Teranishi
Graduate School of Pure and Applied Sciences, University of Tsukuba,

P-47

One-Pot Synthesis of Indium Tin Oxide Nanoparticles for Transparent Conductive
Thin Films
Hayato Koike, Masayuki Kanehara, Toshiharu Teranishi
Graduate School of Pure and Applied Sciences, University of Tsukuba,

P-48

Catalytic performance of supported Ni catalysts in steam reforming of tar derived
from the pyrolysis of wood biomass
Takuya Sakuraia, Tomohisa Miyazawaa, Kimio Kunimoria, Keiichi Tomishigea,*a Graduate school of Pure and Applied Science University of Tsukuba, Ten-noudai
1-1-1, Tsukuba, Ibaraki

P-49

Surface modification of Ni catalysts with trace noble metals for oxidative steam
reforming of methane
Kaori Yoshida, Yuya Mukainakano, Kimio Kunimori, Keiichi Tomishige
Graduate School of Pure and Applied Sciences, University of Tsukuba,

P-50

Hydrogenolysis of glycerol to propanediols catalyzed by heterogeneous catalysts
Akira Shimao, Tomohisa Miyazawa, Shuichi Koso, Kimio Kunimori, Keiichi
Tomishige
Graduate School of Pure and Applied Sciences, University of Tsukuba,

P-51

Infrared chemiluminescence study of CO oxidation reactions on noble metal
surfaces
Osamu Watanabe1, Kenji Nakao1, Shin-ichi Ito1, Keiichi Tomishige1, Kimio
Kunimori1
1 Tsukuba Research Institute for Interdisciplinary Materials Science, University ofTsukuba,P-52

Preferential CO oxidation promoted by the presence of H2 over K-Pt/Al2O3
Yoichi Ishida1,*, Hisanori Tanaka1, Shin-ichi Ito1, Keiichi Tomishige1, Kimio
Kunimori1
1 Tsukuba Research Institute for Interdisciplinary Materials Science, University ofTsukuba,

P-53

Preparation of Helical Carbon Nanofiber-Fabricated Thin Film
Mutsumasa Kyotani1, Satoshi Matsushita2, Takuro Nagai3, Yoshio Matsui3,
Kazuo Akagi1, 2
1 Tsukuba Research Institute for Interdisciplinary Materials Science, University ofTsukuba,
2 Dep. Polymer Chem., University of Kyoto, Katsura, Kyoto 615-8510, Japan
3 NIMS, Namiki, Tsukuba 305-0044, Japan

P-54

Acceleration of the Z to E photoisomerization of penta-2,4-dieniminium byhydrogen out-of-plane motion: Theoretical study on a model system of retinal
protonated Schiff baseMasato Sumita and Kazuya Saito
Department of Chemistry, Graduate School of Pure and Applied Sciences,
University of Tsukuba.

P-55

Calorimetric investigation of correlated disordering in [Hdamel]2[CuII(tdpd)2]⋅
2THF
Yasuhisa Yamamura,1 Hiroyasu Shimoi,1 Masato Sumita,1 Syuma Yasuzuka,1
Keiichi Adachi,2 Akira Fuyuhiro,2 Satoshi Kawata,2 and Kazuya Saito1
1 Department of Chemistry, Graduate School of Pure and Applied Sciences,
University of Tsukuba,
2 Department of Chemistry, Graduate School of Science, Osaka University,

P-56

Calorimetric and dielectric study on hydrogen-bonded organic ferroelectrics
Y. Suzuki, M. Amano, M. Sumita, Y. Yamamura, S. Yasuzuka and K. Saito
Department of Chemistry, Graduate School of Pure and Applied Sciences,
University of Tsukuba,

P-57

Organization and Size-Controlled Synthesis of Gold Nanoparticles within
Stimuli-Responsive Nanogel-Reactors
Takahito Nakamura 1, Motoi Oishi 1, 2, 3, Yukio Nagasaki 1, 2, 3, 4, 5

1 Graduate School of Pure and Applied Sciences, University of Tsukuba,
2 Tsukuba Research Center for Interdisciplinary Materials Science (TIMS),
University of Tsukuba
3 Center for Tsukuba Advanced Research Alliance (TARA), University of Tsukuba
4 Graduate School of Comprehensive Human Sciences, University of Tsukuba
5 International Center for Materials Nanoarchitectonics (MANA), National
Institute of Materials Science
P-58

Preparation and Characterization of Tumor-Specific Imaging Probes Utilizing thepH-sensitive PEGylated Nanogels Containing 19F Compounds.
Shogo SUMITANI1), Motoi OISHI1), 2), 3) and Yukio NAGASAKI1), 2), 3), 4), 5)
1) Graduate School of Pure and Applied Sciences,
2) Tsukuba Research Center for Interdisciplinary Materials Science(TIMS)
3) Center for Tsukuba Advanced Research Alliance (TARA)
4) Graduate School of Comprehensive Human Sciences,
5) Satellite Laboratory of International Center for Materials Nanoarchitechtonics(MANA), NIMS,

P-59

Mechanism analysis of patterned PEG hydrogel surface on cellular adhesivenesschanges
Masahiro Ichino1, Keitaro Yoshimoto1, 2, Yukio Nagasaki1, 2, 3, 4, 5
1Graduate School of Pure and Applied Science, University of Tsukuba
2Center for Tsukuba Advanced Research Alliance (TARA), University of Tsukuba
3Tsukuba Research Center for Interdisciplinary Materials Science (TIMS),
University of Tsukuba
4Master’s School of Medical Sciences, Graduate School of Comprehensive Human
Sciences, University of Tsukuba
5Satellite Laboratory, International Center for Materials Nanoarchilectonics(MANA), National Institute of Materials Science (NIMS)

P-60

Self-Assembled Polyion Complex Nanosphere by PEG-siRNA Block Copolymer–Effect of siRNA Chain Length on Stabilization of NanosphereTaiga Tatsumi1,2,3, Motoi Oishi1,2,3,5, Kazunori Kataoka6,7, and Yukio
Nagasaki1,2,3,4,5
1Graduate School of Pure and Applied Sciences, University of Tsukuba,
2Tsukuba Research Center for Interdisciplinary Materials Science,
3Center for Tsukuba Advanced Research Alliance,
4Master's School of Medical Science, Graduate School of Comprehensive Human
Science, University of Tsukuba,
5Satellite Laboratory, International Center for Materials Nanoarchitectonics,
National Institute of Materials Science,
6Department of Materials Engineering, Graduate School of Engineering, The
University of Tokyo,
7Division of Clinical Biotechnology, Center for Disease Biology and Integrative
Medicine, Graduate School of Medicine, The University of Tokyo

P-61

Fluorescence-based labeling of nucleobases by a hydrogen-bond forming lanthanidechelate complex
Hiroshi Atsumi1, Keitaro Yoshimoto1, 2, 5, 7, Shingo Saito3, 5, Moriya Okuma4,
Mizuo Maeda5, and Yukio Nagasaki1, 2, 6, 7, 8,
1Department of Materials Science, Graduate School of Pure and Applied Sciences,
University of Tsukuba 2Center for Tsukuba Advanced Research Alliance (TARA),
University of Tsukuba
3Graduate School of Science and Engineering, Saitama University,

4Enviromental Molecular Biology Laboratory, RIKEN,
5Bioengineering Laboratory, RIKEN, 6Graduate School of Comprehensive Human,
University of Tsukuba
7Tsukuba Research Center for Interdisciplinary Materials Science (TIMS),
University of Tsukuba,
8Satellite Laboratory, International Center for Materials Nanoarchilectonics(MANA), National Institute of Materials Science (NIMS), University of Tsukuba,
P-62

Antigen binding ability of Fab’/mixed-poly(ethylene glycol) (PEG) tethered-chain
gold surface -A PEG interphase maintains the antibody activityMotohiko Nishio1, Takumi Hirase1, Keitaro Yoshimoto1,3,4, Yukio
Nagasaki1,2,3,4,5
1 Graduate School of Pure and Applied Science,
2 Graduate School of Comprehensive Human,
3 Tsukuba Research Center for Interdisciplinary Materials Science (TIMS),
4 Center for Tsukuba Advanced Research Alliance (TARA), University of Tsukuba,
5 Satellite Laboratory, International Center for Materials Nanoarchilectonics(MANA), National Institute of Materials Science (NIMS)

P-63

Application of Rare-Earth Doped Ceramic Nanophosphors for NIR Biophotonics
N. Venkatachalam1, K. Tokuzen2, Y. Okumura2, M. Kamimura3, Y. Saito2, K.
Shimizu2, K. Soga1,2,4 and Y. Nagasaki1,3,4
1Polyscale Technology Research Center(PTRC), Tokyo University of Science
2Department of Materials Science and Technology, Tokyo University of Science
3Graduate School of Pure and Applied Sciences, University of Tsukuba
4Tsukuba Research Center for Interdisciplinary Materials Science (TIMS),
University of Tsukuba

P-64

Chemical reactions in solutions by atmospheric-pressure nonthermal plasmas
Katsuhisa Kitano and Satoshi Hamaguchi
Center for Atomic and Molecular Technologies, Graduate School of Engineering,Osaka University,

P-65

Spin Transport in Ultrathin Graphite Films
Hidenori Goto1, 2, Takashi Sato1, Sho Tanaka1, Akinobu Kanda1, 2, Youiti
Ootuka1,
Shunsuke Odaka3, 4, Hisao Miyazaki2, 3, Kazuhito Tsukagoshi2, 3, 5, andYoshinobu Aoyagi3, 41Institute of Physics and TIMS, University of Tsukuba,
2Japan Science and Technology Agency, CREST JST,
3The Institute of Physical and Chemical Research (RIKEN),
4Interdisciplinary Graduate School of Science and Engineering, Tokyo Institute ofTechnology,
5Advanced Industrial Science and Technology (AIST),

P-66

Conduction-channel analysis of hydrogen molecule junctions by superconducting
point-contact spectroscopy
Yuya Sakaguchi1, Fumiaki Shimogishi2 and Youiti Ootuka1,2
1 Graduate School of Pure and Applied Sciences, University of Tsukuba,
2TIMS, University of Tsukuba

P-67

A micro SQUID using small tunnel junctions
Tooru Yamagishi1 and Youiti Ootuka1, 2
1Graduate School of Pure and applied Sciences, University of Tsukuba,

2TIMS, University of Tsukuba,
P-68

Local electronic states around conduction band edge of an ultra-thin Al2O3 film on
Ni3Al(111)
Yu Niiyama, Taizo Ohgi, Youiti Ootuka
Institute of Physics, Univ. of Tsukuba

P-69

Plasmon-mediated multiple excitations observed in STM-induced light emission
from rubrene/Au(111) thin films
Arifumi Okada, Ken Kanazawa, Kiwamu Hayashi, Naohiro Okawa, Osamu
Takeuchi and Hidemi Shigekawa
Institute of Applied Physics, CREST-JST, University of Tsukuba,

P-70

STM-induced light emission from an organic-LED structure
N. Okawa, A. Okada, K. Kanazawa, K. Hayashi, O. Takeuchi and H. Shigekawa
Inst. of Appl. Phys., University of Tsukuba,

P-71

Two-dimensional Electronic Structures Realized in Self-assembled Monolayers of
Amino Acids on Cu(100) Surface
Ken Kanazawa, Shoji Yoshida, Atsushi Taninaka, Keisuke Nakamura, Osamu
Takeuchi and Hidemi Shigekawa
Institute of Applied Physics, CREST-JST, Univ. of Tsukuba,

P-72

Investigation of Biotin-Streptavidin Interactions by Dynamic Force Spectroscopy
with Precise Force Control
Atsushi Taninaka, Osamu Takeuchi and Hidemi Shigekawa
Inst. of Appl. Phys, CREST-JST, Univ. of Tsukuba, 1-1-1 Tsukuba, 305-8573
JAPAN

P-73

Influence of junction geometry on single molecular conductance investigated by
STM point contact method
Shoji Yoshida. Yoshitaka Okutsu, Osamu Takeuchi, and Hidemi Shigekawa
Institute of Applied Physics, CREST-JST, University of Tsukuba,Ten-noudai 1-1-1,
Tsukuba, 305-8573, Japan

P-74

Nanoscale imaging of carrier dynamics in semiconductor heterostructures by
femtosecond time-resolved STM
Yasuhiko Terada, Shoji Yoshida, Hiroyuki Kondo, Atsushi Okubo,
Osamu Takeuchi, and Hidemi Shigekawa
Institute of Applied Physics, CREST-JST, University of Tsukuba,

P-75

Four-Probe Scanning Tunneling Microscope with True Atomic Resolution
K. Ichikawa, S. Ishibashi, A. Taninaka, O. Takeuchi, and H. Shigekawa
Institute of Applied Physics, University of Tsukuba, JST-CREST,

P-76

The effect of infiltration on atomic step flow
Katsuya Kamata1, Ryota Ozaki2, Ryu Hasunuma3, Kikuo Yamabe3
1 College of Engineering Sciences, University of Tsukuba
2 Institute of Applied Physics, University of Tsukuba
3 Tsukuba Research Institute for Interdisciplinary Materials Science, University ofTsukuba

P-77

Dielectric characteristics of SiO2 film formed by radical oxygen
S.Okamoto1) , R. Hasunuma1,2), and K. Yamabe1,2)1)Institute of Applied Physics, University of Tsukuba,
2)Tsukuba Research center for Interdisciplinary Materials Science (TIMS),
P-78

Ultrafast dynamics of coherent optical phonons in Ge2Sb2Te5 films
Yoshinobu Miyamoto 1, Muneaki Hase 1, 2, *, Junji Tominaga3
1 Institute of Applied Physics, University of Tsukuba,
2 PRESTO-JST,
3 Center for Applied Near-field Optics Research, AIST,

P-79

Photoconductance imaging of a quantum point contact under local opticalexcitations
Hironori Ito, Tetsuya Omi and Shintaro Nomura
Institute of Physics, University of Tsukuba,

P-80

Photo voltage response images of a superconductor-normal metal- superconductor
junction
K. Tsumura1, S. Nomura1, T. Akazaki2, H. Takayanagi3, 4

1 Institute of Physics, University of Tsukuba,
2NTT Basic Research Laboratories,
3Research Institute for Science and Technology, Tokyo University of Science,
4International Center for Materials Nanoarchitectonics (MANA), National Institutefor Materials
Science (NIMS),
P-81

A low-temperature field near-field scanning optical microscope for imaging
electronic states in GaAs/AlGaAs heterostructures
T. Omi , H. Ito, K.Tsumura, S. Nomura, Y. Ootuka
Institute of Physics, University of Tsukuba

P-82

Transient band bending in InP/InAs/InP core-multishell nanowires
Ken Gotoa*, Shinichi Tomimotoa, Bipul Pala, Yasuaki Masumotoa, Premila
Mohanb,Junichi Motohisab, and Takashi Fukuib
aInstitute of Physics, University of Tsukuba,bGraduate School of Information Science and Technology, Hokkaido University,

P-83

Narrowing of exciton linewidth of a quantum dot with increasing temperature
Kazuki Bando and Yasuaki Masumoto
Institute of Physics and Center for Tsukuba Advanced Research Alliance (TARA),
University of Tsukuba,

P-84

Spin orientation of excitons, trions and tetraons in charge tunable InP quantum
dots
Tsukasa Suzuki, Keisuke Kawana, Michio Ikezawa, and Yasuaki Masumoto*

Institute of Physics, University of Tsukuba, Tsukuba 305-8571, Japan
P-85

Single NN pair luminescence and single photon generation in nitrogen δ-doped
GaP
Michio Ikezawa1, Yoshiki Sakuma2, Masato Watanabe1, Yasuaki Masumoto1
1Institute of Physics, University of Tsukuba,
2National Institute for Materials Science,

P-86

Femtosecond observation of coherent plasmon-phonon coupled modes in InAs:
application to estimation of carrier mobility

Kenshi Kai 1, Muneaki Hase 1, 2,
1 Institute of Applied Physics, University of Tsukuba,
2 PRESTO-JST,
P-87

Time-resolved spectroscopy of Fe-Co nano particle
Hayato Kamioka1, 3, Yutaka Moritomo1, 3, Wataru Kosaka2, Shin-ichi Ohkoshi2
1 Graduate School of Pure and Applied Sciences, University of Tsukuba
2 Department of Chemistry, School of Science, The University of Tokyo
3 CREST, Japan Science and Technology Corporation,

P-88

Arbitrary optical waveform generation with ultra-high repetition rate using
line-by-line control of spectral phase of broad Raman sidebands
Kanaka Raju Pandiri, Takayuki Suzuki, and Masayuki Katsuragawa
1 Department of Applied Physics and Chemistry, UEC,

P-89

Dynamics of the three-leg spin tube system
Mitsuhiro Arikawa1, Satoshi Nishimoto2
1Institute of Physics, University of Tsukuba
2Max-Planck-Institut f¨ur Physik komplexer Systeme,

P-90

Specific heat measurements of the geometrically frustrated system Cd1-xZnxV2O4
Yoshikazu Mizuguchi and Masashige Onoda
Institute of Physics, University of Tsukuba,

P-91

NMR study of the geometrically frustrated systems LixVO2 and LiyZn1-yV2O4
Kenjiro Takao and Masashige Onoda
Institute of Physics, University of Tsukuba,

P-92

Substitution effects of the multifunctional composite crystal CuxV4O11 system
Ikuo Goto and Masashige Onoda
Institute of Physics, University of Tsukuba,