SAFETY DATA SHEETper OSHA HazCom 2012
Revised Date: May 5, 2017

1. IDENTIFICATION OF THE SUBSTANCE AND OF THE COMPANY
Product name:

IRA 931

Product Number:09310

Product use:

For laboratory research purposes

Restrictions on use:

Not for drug or household use

Safety Sheet Supplier:

Oakley, Inc.
4000 Luxottica Place
Mason, OH 45040
USATelephone:(614) 492-5610

Emergency Phone:(614) 674-4846

E-mail address:

info.exciton@luxotticaretail.com
2. HAZARDS IDENTIFICATIONClassification of the substance or mixture
Acute toxicity, Oral (Category 4),
H302
Acute toxicity, Inhalation (Category 4), H332
Acute toxicity, Dermal (Category 4),
H312
Carcinogenicity (Category 1B),
H350
Label elements
Pictogram

Signal word

DangerHazard statement(s)
H302
H312
H332
H350

Harmful if swallowed
Harmful in contact with skinHarmful if inhaled
May cause cancer

Precautionary statement(s)P201
Obtain special instructions before use.
P202
Do not handle until all safety precautions have been read and understood.
P261
Avoid breathing dust.
P264
Wash skin thoroughly after handlingP270
Do not eat, drink or smoke when using this product.
P271
Use only outdoors or in a well-ventilated area
P280
Wear protective gloves/ protective clothing.
P281
Use personal protective equipment as required.
P301 + P312
IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel unwell.
P302 + P352
IF ON SKIN: Wash with plenty of soap and water.
P304 + P340
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
P308 + P313
IF exposed or concerned: Get medical advice/attention.
P312
Call a POISON CENTER or doctor/ physician if you feel unwell.
P330
Rinse mouthOakley, Inc. – IRA 931

P361
P363
P405
P501

per OSHA HazCom 2012, 2 of 6

Remove/Take off immediately all contaminated clothing
Wash contaminated clothing before reuse.
Store locked up.
Dispose of contents/ container to an approved waste disposal plant

Hazards not otherwise classified or not covered by GHS
None
3. COMPOSITION/INFORMATION ON INGREDIENTS
Synonyms:
Formula:Molecular Weight:
CAS-No.:EC-No.:

Metal complex dye
Trade SecretTrade SecretTrade Secret
None

Hazardous components:

IRA931
4. FIRST AID MEASURES

If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration.
In case of skin contact
Wash off with soap and plenty of water.
In case of eye contact
Flush eyes with water as a precaution.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water.
Most important symptoms and effects, both acute and delayed
No further relevant information available
Indication of any immediate medical attention and special treatment needed
No further relevant information available
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special hazards arising from the substance or mixture
Carbon oxides, nickel/nickel oxides, nitrogen oxides (NOx), sulfur oxides
Special protective equipment for fire-fighters
Wear self contained breathing apparatus for fire fighting if necessary.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions
Avoid dust formation. Avoid breathing dust.
Environmental precautions
Do not let product enter drains.
Methods and materials for containment and cleaning up
Sweep up and shovel. Keep in suitable, closed containers for disposal.

Oakley, Inc. – IRA 931

per OSHA HazCom 2012, 3 of 6

7. HANDLING AND STORAGE
Precautions for safe handling
Provide appropriate exhaust ventilation at places where dust is formed. Normal measures for preventive fireprotection.
Conditions for safe storage
Keep container tightly closed in a dry and well-ventilated place. Store in cool place.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Control Parameters
Components with workplace control parameters
Component

Value

Control Parameters

Basis

ABS419 (due to Nickel)

PEL; TWA (8 hour)

20 mg/m

ABS419 (due to Nickel)

REL; TWA (10 hour)

0.3 mg/m

ABS419 (due to soluble Nickel)

TLV

2 mg/m3

USA. ACGIH TLVs® and BEIs® guideABS419 (due to soluble Nickel)

TLV

4 mg/m3

USA. ACGIH TLVs® and BEIs® guide3USA. OSHA - Table Z-1 Limits for Air
Contaminants

3USA. NIOSH pocket Guide to Chemical
Hazards, Appendix A

Hygiene measures and engineering controls
Avoid dispersal of dust in the air (ie, clearing dusty surfaces with compressed air). Emergency eye wash fountains
and safety showers should be available in the immediate vicinity of any potential exposure. Provide adequate
ventilation and/or containment in accordance with good laboratory practices.
Personal protective equipment
Respiratory protection
Where protection from nuisance levels of dusts are desired, use type P95 (US) or type P1 (EU EN 143) dust masks incombination with engineering controls. For higher level protection use type OV/AG/P99 (US) or type ABEK-P2 (EUEN 143) respirator cartridges. Use respirators and components tested and approved under appropriate government
standards such as NIOSH (US) or CEN (EU).
Hand protection
Handle with impermeable gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without
touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves
after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.
Eye / face protection
Use equipment for eye protection tested and approved under appropriate government standards such as
NIOSH (US) or EN 166(EU).
Body protection
Choose body protection in relation to its type, to the concentration and amount of dangerous substances,and to the specific work-place., The type of protective equipment must be selected according to theconcentration and amount of the dangerous substance at the specific workplace.
9. PHYSICAL AND CHEMICAL PROPERTIESa) Appearanceb) Odorc) Odor Threshold

Form: crystals
Color: black
No data available
No data available

Oakley, Inc. – IRA 931

per OSHA HazCom 2012, 4 of 6d) pHe) Melting pointf) Initial boiling point and boiling rangeg) Flash pointh) Evaporation ratei) Flammabilityj) Upper/lower flammability or explosive limitsk) Vapor pressurel) Vapor densitym) Relative densityn) Solubilityo) Partition coefficient: n-octanol/waterp) Auto-ignition temperatureq) Decomposition temperaturer) Viscosity

No data available>325-326 °C
No data available
No data available
No data available
No data available
No data available
No data available
No data available
No data available
No data available
No data available
No data available
No data available
No data available

10. STABILITY AND REACTIVITYa)b)c)d)e)f)Reactivity
Chemical stability
Possibility of hazardous reactions
Conditions to avoid (e.g. static discharge)
Incompatible materials
Hazardous decomposition products

No data available
Stable under recommended storage conditions
No data available
No data available
Strong oxidizing agentsSee Section 5.

11. TOXICOLOGICAL INFORMATION
Acute toxicity
no data available
Skin corrosion/irritation
no data available
Serious eye damage/eye irritation
no data available
Respiratory or skin sensitization
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
This product is or contains a component that has been reported to be probably carcinogenic based on its IARC, OSHA,ACGIH, NTP, or EPA classification.
Carcinogenic to humans.
IARC: Group 1: Carcinogenic to humans, nickel compounds (ABS419).
NTP:

Known to be Human Carcinogen, nickel compounds (ABS419).

OSHA: No component of this product present at levels greater than or equal to 0.1% is identified as acarcinogen or potential carcinogen by OSHA.
Reproductive toxicity
No data available

Oakley, Inc. – IRA 931

Routes of Exposure:per OSHA HazCom 2012, 5 of 6

Inhalation, Eye contact, Ingestion, Skin contact.

Specific target organ toxicity - single exposure
Inhalation – May cause respiratory irritation.
Specific target organ toxicity - repeated exposure
No data available
Aspiration hazard
No data available
Signs and Symptoms of Exposure
May cause respiratory irritation. May cause skin irritation. To the best of our knowledge, the chemical, physical, andtoxicological properties have not been thoroughly investigated.
Additional Information
RTECS: Not available
12. ECOLOGICAL INFORMATION
Toxicity
No data available
Persistence and degradability
No data available
Bioaccumulative potential
No data available
Mobility in soil
No data available
PBT and vPvB assessment
No data available
Other adverse effects
No data available
13. DISPOSAL CONSIDERATIONS
Product
Offer surplus and non-recyclable solutions to a licensed disposal company.
Contaminated packaging
Dispose of as unused product.
14. TRANSPORT INFORMATION
DOT (US)Not dangerous goods
IMDG
Not dangerous goods
IATA
Not dangerous goods

Oakley, Inc. – IRA 931

per OSHA HazCom 2012, 6 of 6

15. REGULATORY INFORMATIONSARA 302 Components
SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313 Components
The following components are subject to reporting levels established by SARA Title III, Section 313:
Nickel compound
SARA 311/312 Hazards
Acute Health Hazard, Chronic Health Hazard
Pennsylvania Right To Know Components
No components are subject to the Pennsylvania Right to Know Act.
Massachusetts Right To Know Components
Nickel compound
New Jersey Right To Know Components
Nickel compound
California Prop. 65 Components
Nickel compound
16. OTHER INFORMATION
H302
H312
H332
H350
HMIS Rating
Health hazard:
Chronic Health Hazard:
Flammability:
Physical Hazard:
NFPA Rating
Health hazard:
Fire Hazard:
Reactivity Hazard:

Harmful if swallowed
Harmful in contact with skinHarmful if inhaled
May cause cancer.

200200Further information
Copyright 2017 Oakley, Inc. License granted to make unlimited paper copies for internal use only.
The above information is believed to be correct but does not purport to be all inclusive and shall be used
only as a guide. The information in this document is based on the present state of our knowledge and isapplicable to the product with regard to appropriate safety precautions. It does not represent any guaranteeof the properties of the product. Oakley, Inc. shall not be held liable for any damage resulting fromhandling or from contact with the above product.
Revised Date: May 5, 2017