Safety Data Sheet

MartifinÒ OL-104LE; MartifinÒ OL-107; MartifinÒ OL-111; MartifinÒ ON-313
OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03
Canadian Workplace Hazardous Material Information System (WHMIS) 2015
Mexico NOM-018-STPS-2000; NOM-018-STPS-2015
Globally Harmonized System (GHS)
Issue Date: 07/May/2020
Print Date: 07/May/2020

Revision Number: 1.3.2
Page 1 of 11

SECTION 1: Identification of the substance/mixture and of thecompany/undertaking
1.1. Product identifier
Product Name:

MartifinÒ OL-104LE; MartifinÒ OL-107; MartifinÒ OL-111; MartifinÒ ON-313

Pure substance/mixture

Substance

1.2. Relevant identified uses of the substance or mixture and uses advised against
Recommended Use

Additive. :. Flame retardant.

Industrial use

Production substance
Polymer processing
Production of plastics and rubber compounds
Formulation flame retardant preparation
Compounds used in transport industry
Compounds used in electrical application
Compounds used in electronic application
Compounds used in Wire & Cable
Abrasive for glass industry, ceramics and stones
Textile coating
Production of corrosion inhibitors
Fuels
Deacidification agent for paper
pH Regulating agent
Use in coatings, inks, paints and roofing
Use as corrosion inhibitor of gas turbines and boilers
Use in cleaning agents
Use in oil field operations
Use in lubricants
Use in metal working fluids
Use in blowing agents
Use in binders and release agents
Use in textile
Use in functional fluids
Use in agrochemicals
Use in water treatment chemicals
Use in mining chemicals
Recycling plastics
White pigment for paper and board, filler, etc.

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Safety Data Sheet
MartifinÒ OL-104LE; MartifinÒ OL-107; MartifinÒ OL-111; MartifinÒ ON-313

Issue Date: 07/May/2020
Print Date: 07/May/2020

Revision Number: 1.3.2
Page 2 of 11

Professional use

Polymer processing
Use in Adhesives and/or sealants
Use in coatings, inks, paints and roofing
Use in agrochemicals
Use in cleaning agents
Use in oil field operations
Use in lubricants
Use in metal working fluids
Use in binders and release agents
Use in propellants
Use in textile
Use in explosives
Use in water treatment chemicals
Use in functional fluids
For use by laboratories for research
Fuels
De-icing & anti-icing applications
Road and construction applications

Consumer use

Use in coatings, inks, paints and roofing
Use in cleaning agents
Use in lubricants
Use in propellants
Fuels
Use in functional fluids
De-icing & anti-icing applications
Cosmetic additive
Use in water treatment chemicals

1.3. Details of the supplier of the safety data sheet
Company:

MARTINSWERK GmbH
Kölner Strasse 110
50127 Bergheim
Germany
Tel. : +49-2271-90.22.78
Fax. : +49-2271-90.27.17

Internetwww.hubermaterials.com

E-mailhubermaterials@huber.com

1.4. Emergency telephone
numberCHEMTREC: +1 800 424 9300 or International +1 703 527 3887

SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
OSHA Regulatory Status
Physical Hazards

This material is not considered hazardous by the OSHA Hazard Communication
Standard (29 CFR 1910.1200)
Not classified

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Safety Data Sheet
MartifinÒ OL-104LE; MartifinÒ OL-107; MartifinÒ OL-111; MartifinÒ ON-313

Issue Date: 07/May/2020
Print Date: 07/May/2020

Revision Number: 1.3.2
Page 3 of 11

Health Hazards

Not classified

Environmental Hazard

Not classified

2.2. Label elements
Symbols/Pictograms

None

Signal Word

None

Hazard Statements

None

Hazard Statements

None

Precautionary Statements
Prevention

Employ good industrial hygiene practice
Do not handle until all safety precautions have been read and understood
Do not breathe dust
Wear protective gloves/protective clothing/eye protection/face protection

Response

IF IN EYES: Rinse cautiously with water for several minutes. Remove contactlenses, if present and easy to do. Continue rinsing
IF ON SKIN: Wash with plenty of soap and water

Storage

Keep in a dry place
Store away from incompatible materials

Disposal

Dispose of contents/containers in accordance with local regulations

Additional Information:

None.

Hazards not otherwise classified Not classified.
(HNOC)SECTION 3: Composition/information on ingredients
Pure substance/mixture
Chemical Name

Aluminum Hydroxide

Substance

CAS Number TSCA: United Canada (DSL)
States21645-51-2

AY

MexicoY

REACH
registration
number
01-211952924
6-39-0016

OSHA
Regulatory
Status

WHMIS

Weight-%Not classified

--

>99

LegendX / Y: Complies ; A: Active ; - / N: Exempt / Not Listed

SECTION 4: First aid measures

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Safety Data Sheet
MartifinÒ OL-104LE; MartifinÒ OL-107; MartifinÒ OL-111; MartifinÒ ON-313

Issue Date: 07/May/2020
Print Date: 07/May/2020

Revision Number: 1.3.2
Page 4 of 11

4.1. Description of first aid measures
General Advice

When in doubt or if symptoms are observed, get medical advice. Ensure that
medical personnel are aware of the material(s) involved and take precautions toprotect themselves.

Eye Contact

In case of eye contact, remove contact lens and rinse immediately with plenty ofwater, also under the eyelids, for at least 15 minutes.

Skin Contact

Wash with plenty of soap and water.

Ingestion

Rinse mouth thoroughly with water.

Inhalation

If breathing is difficult, remove victim to fresh air and keep at rest in a position
comfortable for breathing.

Aspiration hazard

Not an expected route of exposure.

4.2. Most important symptoms
and effects, both acute anddelayedDust contact with the eyes can lead to mechanical irritation. Contact with dust cancause mechanical irritation or drying of the skin.

4.3. Indication of any immediate Treatment should be symptomatic and supportive.
medical attention and special
treatment needed

SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable ExtinguishingMedia
Water spray (fog). Foam. Dry chemical. Carbon dioxide (CO2).
Unsuitable Extinguishing Media
None known.
5.2. Special hazards arising from the substance or mixture
None known.
5.3. Advice for firefighters
Special protective
equipment for firefighters
Wear a self-contained breathing apparatus and chemical protective clothing.
Fire-fighting measures
In case of fire and/or explosion do not breathe fumes.

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Safety Data Sheet
MartifinÒ OL-104LE; MartifinÒ OL-107; MartifinÒ OL-111; MartifinÒ ON-313

Issue Date: 07/May/2020
Print Date: 07/May/2020

Revision Number: 1.3.2
Page 5 of 11

SECTION 6: Accidental release measures
Ensure adequate ventilation. Use personal protection recommended in Section 8.
Avoid dust formation. Keep unauthorized personnel away.

6.1. Personal precautions,protective equipment andemergency procedures
For non-emergency personnel

Keep unauthorized personnel away.

For emergency responders

Keep unauthorized personnel away. Use personal protection recommended in
Section 8.

6.2. Environmental precautions Avoid runoff to waterways and sewers.
6.3. Methods and material forcontainment and cleaning up

Methods for Containment : Prevent further leakage or spillage if safe to do so
Methods for Clean-up : Sweep up and shovel into suitable containers for disposal

6.4. Reference to other sections Section 8: Exposure controls and personal protection. See Section 13 foradditional waste treatment information.

SECTION 7: Handling and storage
7.1. Precautions for safe
handling

Minimize dust generation and accumulation. Provide local exhaust ventilation.
Handle in accordance with good industrial hygiene and safety practice.

7.2. Conditions for safe storage, Store away from incompatible materials. Keep container tightly closed and dry.
including any incompatibilities
7.3. Specific end use(s)No information available.

SECTION 8: Exposure controls/personal protection
8.1. Control parameters
Occupational exposure limits
Aluminum Hydroxide
TWA: 15 mg/m3 Total Dust
5 mg/m3 Respirable Dust
ACGIH
TLV/TWA 8-hr: 1 mg/m3 (respirable fraction)
NIOSH
TWA: 5 mg/m3 (respirable dust); 10 mg/m3 TWA (total dust)
Canada - BC TWA
TWA: 1 mg/m3 (respirable)
Canada - Manitoba - OEL - TWA
TWA: 1 mg/m3 (respirable)
Canada - Newfoundland & Labrador - TWA: 1 mg/m3 (respirable)
OEL - TWA
Canada - Nova Scotia - OEL - TWA
TWA: 1 mg/m3 (respirable)
Canada - Prince Edward Island - OEL - TWA: 1 mg/m3 (respirable)
TWA
OSHA

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Safety Data Sheet
MartifinÒ OL-104LE; MartifinÒ OL-107; MartifinÒ OL-111; MartifinÒ ON-313

Issue Date: 07/May/2020
Print Date: 07/May/2020
MexicoRevision Number: 1.3.2
Page 6 of 11
No se ha establecido

Biological Limit Values:None

8.2. Exposure controls
Engineering Measures

Provide a good standard of controlled ventilation (5 to 10 air changes per hour).
Use exhaust ventilation to keep airborne concentrations below exposure limits. In
case of insufficient ventilation, wear suitable respiratory equipment.

Personal protective equipment
Eye/Face Protection

Wear safety glasses with side shields (or goggles).

Skin and Body Protection

Wear suitable protective clothing.

Hand protection

For operations where prolonged or repeated skin contact may occur, impervious
gloves should be worn. Wear suitable gloves tested to EN 374.

Respiratory Protection

In case of inadequate ventilation wear respiratory protection.

Thermal hazards

None known.

Hygiene Measures

Follow general hygiene considerations recognized as common good workplace
practices. The worker should wash daily at the end of each work shift, and prior toeating, drinking, smoking, etc.

Environmental Exposure
Controls

Dispose of in accordance with local regulations.

SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Appearance:
Solid Powder
Physical State
White
Color
Odorless
Odor
No information available
Odor Threshold+/- 9 ( 10% Water )pH:
Not applicable
Melting point / Freezing point
Initial boiling point and boiling Not applicable
range
Not applicable. Product/Substance is inorganic. Solid.
Flash Point:
Not applicable.
Evaporation Rate
Not flammable
Flammability (solid, gas)

HUBER

Safety Data Sheet
MartifinÒ OL-104LE; MartifinÒ OL-107; MartifinÒ OL-111; MartifinÒ ON-313

Issue Date: 07/May/2020
Print Date: 07/May/2020

Revision Number: 1.3.2
Page 7 of 11Upper flammability limit:
Lower flammability limit:
Vapor Pressure
Vapor Density
Relative Density
Water Solubility
Solubility in other solvents
Partition coefficient
Decomposition Temperature
Dynamic viscosity
Explosive Properties
Oxidizing Properties
9.2. Other information

Not applicableNot applicable+/- 2.42 g/cm³ (20 °C)
Insoluble
No information available
Not applicable Product/Substance is inorganic No information available~ 200 °C
Not applicable Solid
None
None
No data available

SECTION 10: Stability and reactivity
10.1. Reactivity

No data available

10.2. Chemical stability

Stable under normal conditions

10.3. Possibility of hazardous
reactionsNone under normal processing

10.4. Conditions to avoid

Incompatible materials Dust formation Decomposes at 200 °C Al2 O3 Water

10.5. Incompatible materials

None known

10.6. Hazardous decomposition None
products

SECTION 11: Toxicological information
General Information

Users are advised to consider national Occupational Exposure Limits or otherequivalent values.

Information on Likely Routes of Exposure
Inhalation

Do not breathe dust

Skin

Avoid prolonged or repeated contact with skinContact with dust can cause mechanical irritation or drying of the skin

Eyes

Avoid contact with eyes
Dust contact with the eyes can lead to mechanical irritation

Ingestion

Ingestion is not a likely route of exposure

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Safety Data Sheet
MartifinÒ OL-104LE; MartifinÒ OL-107; MartifinÒ OL-111; MartifinÒ ON-313

Issue Date: 07/May/2020
Print Date: 07/May/2020

Revision Number: 1.3.2
Page 8 of 11
Not an expected route of exposure.

Aspiration hazard

11.1. Information on toxicological effects
Aluminum Hydroxide
Oral LD50
Inhalation LC50
IARC

> 2000 mg/kg Rat
Rat > 2.3 mg/l (Al2O3) Aerosol Maximum attainable concentration
Not Listed

Reproductive Toxicity

Based on available data, the classification criteria are not met.

Carcinogenicity

Based on available data, the classification criteria are not met.

SECTION 12: Ecological information
12.1. Ecotoxicity

Very low solubility. Not considered to be harmful to aquatic life.

Aluminum Hydroxide
WGK Classification (AwSV)

5220 WGK: nwg

12.2. Persistence anddegradability

The methods for determining biodegradability are not applicable to inorganic
substances.

12.3. Bioaccumulative potential Not likely to bioaccumulate.
Bioconcentration factor(BCF)

No data available.

12.4. Mobility in soil

No information available.

12.5. Results of PBT and vPvB
assessment

This substance does not meet the criteria for classification as PBT or vPvB.

12.6. Other adverse effects

No information available

SECTION 13: Disposal considerations
13.1. Waste treatment methods
Disposal Methods

Disposal should be in accordance with applicable regional, national and local laws
and regulations.

Contaminated Packaging

Empty containers should be taken to an approved waste handling site for recycling

HUBER

Safety Data Sheet
MartifinÒ OL-104LE; MartifinÒ OL-107; MartifinÒ OL-111; MartifinÒ ON-313

Issue Date: 07/May/2020
Print Date: 07/May/2020

Revision Number: 1.3.2
Page 9 of 11
or disposal. Do not reuse container.
Waste codes should be assigned by the user based on the application for which
the product was used

Waste codes
Aluminum Hydroxide
European Waste Catalog
WGK Classification (AwSV)

0602995220 WGK: nwg

SECTION 14: Transport information
Mode of Transportation (Road, Water, Air, Rail)Not regulated
Not regulated
Not regulated
Not regulated
Not regulated

TDG -Canada
DOT
IATA
IMDG/IMO
ICAO

None

14.1. UN number

14.2. UN proper shipping name None
14.3. Transport hazard class(es) None
14.4. Packing group

None

14.5. Environmental hazards

No

14.6. Special precautions foruser

Not applicable

14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC CodeNot applicable

SECTION 15: Regulatory information
Global Inventories
Pure substance/mixture
Chemical Name

AluminumHydroxide
LegendCAS
NumberEC No

Substance

REACH Australia
registrati (AICS)
onnumber21645-51- 244-492-7 01-211952
Y2
9246-39-0
016

Canada(DSL)

China(IECSC)Japan

S. Korea(KECL)

MexicoYY(1)-17(ENCS);
ISHL

KE-00980

Y

New
Philippine Taiwan
Zealand s (PICCS)

Y

Y

Y

TSCA:
UnitedStatesA

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Safety Data Sheet
MartifinÒ OL-104LE; MartifinÒ OL-107; MartifinÒ OL-111; MartifinÒ ON-313

Issue Date: 07/May/2020
Print Date: 07/May/2020

Revision Number: 1.3.2
Page 10 of 11

X / Y: Complies ; A: Active ; - / N: Exempt / Not Listed

US Federal Regulations
EPA
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does
not contain any chemicals which are subject to the reporting requirements of the Act and Title 40n of the Code ofFederal Regulations, Part 372.
Aluminum Hydroxide
Not listed
Not listed

CERCLA
SARA 311/312 Hazardous
Categorization
SARAH 302 RQ, lbs

Not listed

CWA (Clean Water Act)Not listed
CAA (Clean Air Act)Not listed
U.S. State Right-to-Know Regulations
Chemical Name

CAS Number

Aluminum Hydroxide

21645-51-2

California
California CPR Massachusetts
Proposition 65
No
No

Minnesota

New Jersey

Pennsylvania

No

No

No

California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65)
This product does not contain any Proposition 65 chemicals
CANADAWHMIS:
This product has been classified in accordance with the hazard criteria of the Hazardous Products Regulations(HPR) and the SDS contains all the information required by the HPR

SECTION 16: Other information
Prepared by

Huber Engineered Materials (HEM) Global Regulatory Affairs
regulatory.affairs@huber.com

Issue Date:
Print Date:

07/May/2020
07/May/2020

Revision Number:

1.3.2

Reason for Version

OSHA (Occupational Safety and Health Administration of the US Department ofLabor).

HUBER

Safety Data Sheet
MartifinÒ OL-104LE; MartifinÒ OL-107; MartifinÒ OL-111; MartifinÒ ON-313

Issue Date: 07/May/2020
Print Date: 07/May/2020

Revision Number: 1.3.2
Page 11 of 11

Training Advice

Do not handle until all safety precautions have been read and understood.

Abbreviations and acronyms

International Agency for Research on Cancer (IARC)
International Air Transport Association (IATA)
International Maritime Dangerous Goods (IMDG)International Uniform Chemical Information Database (IUCLID)
Workplace Hazardous Materials Information System (WHMIS) status and classification
EPA SARA Title III Section 312 (40 CFR 370) Hazard Classification
DOT (Department of Transportation)
OSHA (Occupational Safety and Health Administration of the US Department of Labor)
TWA - Time-Weighted Average
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA)The Classification, Labeling and Packaging of Substances and Mixtures (CLP) Regulation (EC1272/2008)
PPE - Personal Protection Equipment
NIOSH - National Institute for Occupational Safety and Health
TDG (Transport of Dangerous Goods) Canada
CERCLA (Comprehensive Environmental Response, Compensation, and Liability Act)
Reportable Quantity (RQ) (RQ/% in mixture)
STEL - Short Term Exposure Limit
TLV® - Threshold Limit Value
Derived No Effect Level (DNEL)
SVHC: Substances of Very High Concern for Authorization:
Land transport (ADR/RID)
Biochemical oxygen demand (BOD)
Chemical oxygen demand (COD)
ICAO (air)(IMDG) International Maritime Dangerous Goods
Positive Pressure Self-Contained Breathing Apparatus (SCBA)
Predicted No Effect Concentration (PNEC)
Globally Harmonized System (GHS)

Disclaimer

The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only
as a guidance for safe handling, use, processing, storage, transportation, disposal andrelease and is not to be considered a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material usedin combination with any other materials or in any process, unless specified in the text

End of Safety Data Sheet