Safety Data Sheet

MartinalÒ OL-104 LE; MartinalÒ OL-107 LE; MartinalÒ OL-111 LE
Japan-JIS Z 7253:2012
Occupational Safety and Health Act
Globally Harmonized System (GHS)
Issue Date: 06/Aug/2019
Print Date: 06/Aug/2019

Revision Number: 1.3.1
Page 1 of 8

1. PRODUCT AND COMPANY IDENTIFICATION
Product Name:

MartinalÒ OL-104 LE; MartinalÒ OL-107 LE; MartinalÒ OL-111 LE

Pure substance/mixture

Substance

Aluminum Hydroxide
CAS Number
Weight-%21645-51-2>99

Recommended Use

Additive : Flame retardantCompany:

MARTINSWERK GmbH
Kölner Strasse 110
50127 Bergheim
Germany
Tel. : +49-2271-90.22.78
Fax. : +49-2271-90.27.17

Internetwww.hubermaterials.com

E-mailhubermaterials@huber.com

Emergency Telephone Number CHEMTREC: +1 800 424 9300 or International +1 703 527 3887
+81 03-3560-7316

2. HAZARD IDENTIFICATION
Japan GHS Classification
Physical Hazards

Not classifiedHealth Hazard

Not classified

Environmental Hazards

Not classified

GHS label elements
Symbols/Pictograms

None

Signal Word

None

Hazard statements

Based on available data, the classification criteria are not met

Precautionary Statements
Prevention

Response

Do not handle until all safety precautions have been read and understood.
Employ good industrial hygiene practice
Do not breathe dust
IF exposed or concerned: Get medical advice/attention

HUBER

Safety Data Sheet
MartinalÒ OL-104 LE; MartinalÒ OL-107 LE; MartinalÒ OL-111 LE

Issue Date: 06/Aug/2019
Print Date: 06/Aug/2019

Revision Number: 1.3.1
Page 2 of 8
Wash with plenty of soap and water

Storage

Store away from incompatible materials.
Keep in a dry place

Disposal

Dispose of contents/container to an approved waste disposal plant
None

Additional Information:

3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance

Pure substance/mixture
Chemical Name

CAS NumberJapanJapan GHS
Classification

TSCA: UnitedStates

Aluminum Hydroxide

21645-51-2(1)-17 (ENCS);
ISHL

Not classifiedAREACH
registration
number01-2119529246-39-0016

Weight-%>99

4. FIRST AID MEASURES
If inhaled:

Remove victim to fresh air and keep at rest in a position comfortable for breathing

IF ON SKIN:

Wash with plenty of soap and waterTake off contaminated clothing and wash before reuse

IF IN EYES:In case of eye contact, remove contact lens and rinse immediately with plenty ofwater, also under the eyelids, for at least 15 minutes
Call a physician if irritation develops and persists

If swallowed:

Rinse mouth thoroughly with water

Self-Protection of the First Aider Ensure that medical personnel are aware of the material(s) involved and takeprecautions to protect themselves
Notes to Physician

Treat symptomatically.

5. FIRE-FIGHTING MEASURES

Suitable ExtinguishingMediaWater spray (fog)Foam
Dry chemical
Carbon dioxide (CO2)

Unsuitable Extinguishing Media Do not use water jetstream
Special hazards arising from the Avoid dust formation

HUBER

Safety Data Sheet
MartinalÒ OL-104 LE; MartinalÒ OL-107 LE; MartinalÒ OL-111 LE

Issue Date: 06/Aug/2019Print Date: 06/Aug/2019

Revision Number: 1.3.1
Page 3 of 8

substance or mixture
Fire-fighting measures

In case of fire and/or explosion do not breathe fumes
Water mist may be used to cool closed containers
Keep unauthorized personnel away

Special Protective Equipment
for Firefighters

Wear self-contained breathing apparatus and protective suit

6. ACCIDENTAL RELEASE MEASURES
Protective Equipment andPrecautions for Firefighters

Avoid dust formation
Ensure adequate ventilation
Use personal protection recommended in Section 8
Avoid contact with eyes and skin. Wear suitable personal protection equipment.
Keep unauthorized personnel away

Environmental Precautions

Keep out of drains, sewers, ditches and waterways
Disposal considerations
See section 13 for more information

Methods and material forcontainment and cleaning up

Large Spill: Do not dry sweep dust. Wet dust with water before sweeping or use avacuum to collect dust
Small Spill: Vacuum or sweep material and place in a disposal container Minimize
use of water during clean-up
Recommended filter type: High efficiency particulate air filter (HEPA filter)

Other Information

Not applicable

7. HANDLING AND STORAGEHandlingTechnical measures

Advice on safe handling

Provide adequate ventilation as well as local exhaustion at critical locations
Ensure adequate ventilation
Use personal protection equipment
See section 8 for more information
Minimize dust generation and accumulation

Conditions for safe storage, Keep containers tightly closed in a cool, well-ventilated place
including any
incompatibilities
Hygiene Measures
Storage
Packaging compatibilities

Wash hands thoroughly after handling
Keep/store only in original container

8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Limits

Provide adequate ventilation as well as local exhaustion at critical locations

Aluminum Hydroxide
Japan
ACGIH
OSHATWA: 2 mg/m3
TLV/TWA 8-hr: 1 mg/m3 (respirable fraction)
TWA: 15 mg/m3 Total Dust

HUBER

Safety Data Sheet
MartinalÒ OL-104 LE; MartinalÒ OL-107 LE; MartinalÒ OL-111 LE

Issue Date: 06/Aug/2019
Print Date: 06/Aug/2019

Revision Number: 1.3.1
Page 4 of 8
5 mg/m3 Respirable DustEngineering Measures

Ensure adequate ventilation, especially in confined areas

Personal Protective Equipment
Respiratory Protection

In case of inadequate ventilation wear respiratory protection

Hand protection

For operations where prolonged or repeated skin contact may occur, impervious
gloves should be worn

Eye Protection

Wear safety glasses with side shields (or goggles)

Skin and Body Protection

Wear suitable protective clothing.
Chemical resistant apron.

Hygiene Measures

Handle in accordance with good industrial hygiene and safety practice
Wash thoroughly after handling
Avoid contact with eyes and skin
Do not breathe dust

9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance:
Physical State
ColorOdor
Odor Threshold
pH:
Melting point / Freezing point
Initial boiling point and boiling
range
Flash Point:
Evaporation Rate
Flammability (solid, gas)
Upper flammability limit:
Lower flammability limit:
Vapor Pressure
Vapor Density
Relative Density
Water Solubility
Solubility in other solvents

SolidPowder
WhiteOdorless
No information available+/- 9 ( 10% Water )~ 300 °C / 572 °F (1013 hPa)
> 2900 °C / 5252 °F (1013 hPa)
Not applicable. Product/Substance is inorganic. Solid.
Not applicableNot flammable

Decomposition Temperature
Dynamic viscosity
Explosive Properties
Oxidizing Properties

Not applicableNot applicable+/- 2.42 g/cm³ (20 °C)
Insoluble
No information available Not applicable Product/Substance is inorganic Noinformation available
No information available
Not applicable Solid
NoneNone

Other information:

No data available

10. STABILITY AND REACTIVITY

HUBER

Safety Data Sheet
MartinalÒ OL-104 LE; MartinalÒ OL-107 LE; MartinalÒ OL-111 LE

Issue Date: 06/Aug/2019
Print Date: 06/Aug/2019

Revision Number: 1.3.1
Page 5 of 8

Reactivity

Stable under normal conditions

Chemical stability

Stable under normal conditions

Possibility of hazardous
reactionsNone known

Incompatible materials

Strong oxidizing agents

Hazardous decomposition
products

None known

11. TOXICOLOGICAL INFORMATION
General Information

Users are advised to consider national Occupational Exposure Limits or otherequivalent values.

Information on Likely Routes of Exposure
Inhalation

Do not breathe dust

Skin

Avoid prolonged or repeated contact with skinContact with dust can cause mechanical irritation or drying of the skin

Eyes

Avoid contact with eyes
Dust contact with the eyes can lead to mechanical irritation

Ingestion

Ingestion is not a likely route of exposure

Aspiration hazard

Not an expected route of exposure.

Symptoms

Low hazard for usual industrial or commercial handling11.1. Information on toxicological effects
Aluminum Hydroxide
Oral LD50Inhalation LC50IARC> 2000 mg/kg Rat
Rat > 2.3 mg/l (Al2O3) Aerosol Maximum attainable concentration
Not Listed

Reproductive Toxicity

Based on available data, the classification criteria are not met.

Carcinogenicity

Based on available data, the classification criteria are not met.

12. ECOLOGICAL INFORMATION
Ecotoxicity

Based on available data, the classification criteria are not met

Persistence and degradability

No data available

Bioaccumulation

No data available.

Mobility in soil

No data available

HUBER

Safety Data SheetMartinalÒ OL-104 LE; MartinalÒ OL-107 LE; MartinalÒ OL-111 LE

Issue Date: 06/Aug/2019
Print Date: 06/Aug/2019
Hazardous to the ozone layer

Revision Number: 1.3.1
Page 6 of 8
No data available

13. DISPOSAL CONSIDERATIONS
Disposal

Dispose of in accordance with federal, state and local regulations

Contaminated packaging

Empty containers should be taken to an approved waste handling site for recycling
or disposal

14. TRANSPORT INFORMATION
Mode of Transportation (Road, Water, Air, Rail)Not regulated
Not regulated
Not regulated
Not regulated
Not regulated

TDG -CanadaDOTIATA
IMDG/IMO
ICAO

None

14.1. UN number

14.2. UN proper shipping name None
14.3. Transport hazard class(es) None
14.4. Packing group

None

14.5. Environmental hazards

No

14.6. Special precautions foruser

Not applicable

14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC CodeNot applicable

15. REGULATORY INFORMATION
Global Inventories
Pure substance/mixture
Chemical Name

AluminumHydroxide

CAS
NumberSubstance

EC No

REACH Australia
registrati (AICS)
onnumber21645-51- 244-492-7 01-211952
Y29246-39-0016

Canada(DSL)China(IECSC)

Japan

S. Korea(KECL)

MexicoYY(1)-17(ENCS);
ISHL

KE-00980

YLegend
X / Y: Complies ; A: Active ; - / N: Exempt / Not Listed

KECL - Korean Existing and Evaluated Chemical Substances

NewPhilippine Taiwan
Zealand s (PICCS)YYY

TSCA:UnitedStatesAHUBER

Safety Data Sheet
MartinalÒ OL-104 LE; MartinalÒ OL-107 LE; MartinalÒ OL-111 LE

Issue Date: 06/Aug/2019
Print Date: 06/Aug/2019

Revision Number: 1.3.1
Page 7 of 8

IECSC - China Inventory of Existing Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
AICS - Australian Inventory of Chemical Substances
TSCA (Toxic Substances Control Act)DSL (Domestic Substance List)
NDSL (Non-Domestic Substances List)
Japan - ISHL Notifiable Substances
ENCS - Japan Existing and New Chemical Substances

16. OTHER INFORMATION
Prepared byHuber Engineered Materials Global Regulatory Affairs
email: regulatory.affairs@huber.com

Reason for RevisionThis SDS complies with the requirements of JIS Z 7250:2010 and JIS Z 7252:2009 (Japan)

Bibliography

NITE GHS Classified list
Japan Society for occupational health (2015) recommendation of allowable concentrations,etc.
ACGIH TLV: American Conference of Governmental Industrial Hygienists - Threshold Limit
ValueAbbreviations and acronyms

International Agency for Research on Cancer (IARC)
International Air Transport Association (IATA)
International Maritime Dangerous Goods (IMDG)International Uniform Chemical Information Database (IUCLID)
Workplace Hazardous Materials Information System (WHMIS) status and classification
EPA SARA Title III Section 312 (40 CFR 370) Hazard Classification
DOT (Department of Transportation)
OSHA (Occupational Safety and Health Administration of the US Department of Labor)
TWA - Time-Weighted Average
The Classification, Labeling and Packaging of Substances and Mixtures (CLP) Regulation (EC1272/2008)
PPE - Personal Protection Equipment
NIOSH - National Institute for Occupational Safety and Health
TDG (Transport of Dangerous Goods) Canada
CERCLA (Comprehensive Environmental Response, Compensation, and Liability Act)
Reportable Quantity (RQ) (RQ/% in mixture)
STEL - Short Term Exposure Limit
TLV® - Threshold Limit Value
Derived No Effect Level (DNEL)
SVHC: Substances of Very High Concern for Authorization:
Land transport (ADR/RID)
Biochemical oxygen demand (BOD)
Chemical oxygen demand (COD)
ICAO (air)(IMDG) International Maritime Dangerous Goods
Positive Pressure Self-Contained Breathing Apparatus (SCBA)
Predicted No Effect Concentration (PNEC)
Globally Harmonized System (GHS)

Disclaimer

The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only
as a guidance for safe handling, use, processing, storage, transportation, disposal andrelease and is not to be considered a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material usedin combination with any other materials or in any process, unless specified in the text
End of Safety Data SheetHUBER

Safety Data Sheet
MartinalÒ OL-104 LE; MartinalÒ OL-107 LE; MartinalÒ OL-111 LE

Issue Date: 06/Aug/2019
Print Date: 06/Aug/2019

Revision Number: 1.3.1
Page 8 of 8