Safety Data Sheet

CompaloxÒ AN/V-801; CompaloxÒ AN/V-802; CompaloxÒ AN/V; CompaloxÒ AN/V-812;
CompaloxÒ AN/V-813; CompaloxÒ AN/V-825; CompaloxÒ AN/V-827; CompaloxÒ AN/V-850;
CompaloxÒ AN/V-800; CompaloxÒ AN/V-005
Japan-JIS Z 7253:2012
Occupational Safety and Health Act
Globally Harmonized System (GHS)
Issue Date: 04/Jun/2019
Print Date: 12/Jun/2019

Revision Number: 1.3
Page 1 of 9

1. PRODUCT AND COMPANY IDENTIFICATION
Product Name:

Chemical Name

CompaloxÒ AN/V-801; CompaloxÒ AN/V-802; CompaloxÒ AN/V; CompaloxÒAN/V-812; CompaloxÒ AN/V-813; CompaloxÒ AN/V-825; CompaloxÒ AN/V-827;
CompaloxÒ AN/V-850; CompaloxÒ AN/V-800; CompaloxÒ AN/V-005
Substance : Al2 O3 Al2O3

Pure substance/mixture

Substance

Aluminum oxide
CAS Number
Weight-%1344-28-1>99

Recommended Use

Abrasive Adsorbent(s) Catalyst Filler Chemical industry (raw material for theproduction of other aluminium compounds), etc.

Uses advised against
Company:None known
MARTINSWERK GmbH
Kölner Strasse 11050127 Bergheim
Germany
Tel. : +49-2271-90.22.78
Fax. : +49-2271-90.27.17

Internetwww.hubermaterials.com

E-mailhubermaterials@huber.com

Emergency Telephone Number CHEMTREC: +1 800 424 9300 or International +1 703 527 3887
+81 03-3560-7316

2. HAZARD IDENTIFICATION
Japan GHS Classification
Physical Hazards

Not classifiedHealth Hazard

Not classified

Environmental Hazards

Not classified

GHS label elements
Symbols/Pictograms
Signal Word

None
None

HUBER

Safety Data Sheet

CompaloxÒ AN/V-801; CompaloxÒ AN/V-802; CompaloxÒ AN/V; CompaloxÒ AN/V-812; CompaloxÒAN/V-813; CompaloxÒ AN/V-825; CompaloxÒ AN/V-827; CompaloxÒ AN/V-850; CompaloxÒ AN/V-800;
CompaloxÒ AN/V-005
Issue Date: 04/Jun/2019
Print Date: 12/Jun/2019

Revision Number: 1.3
Page 2 of 9

Not a hazardous substance or mixture according to the Globally Harmonized
System (GHS)

Hazard statements
Precautionary Statements
Prevention

Do not handle until all safety precautions have been read and understood.
Employ good industrial hygiene practice
Do not breathe dust

Response

IF exposed or concerned: Get medical advice/attention
Wash with plenty of soap and water

Storage

Store away from incompatible materials.
Keep in a dry place

Disposal

Dispose of contents/container to an approved waste disposal plant
None

Additional Information:

3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance

Pure substance/mixture
Chemical Name

CAS NumberJapan

Japan GHSClassification

TSCA: UnitedStates

Aluminum oxide

1344-28-1(1)-23(ENCS)(ISHL)

Not classified

YREACHregistration
number01-2119529248-35-xxxx

Weight-%>9901-2119529248-35-0017

4. FIRST AID MEASURES
If inhaled:

Remove victim to fresh air and keep at rest in a position comfortable for breathing

IF ON SKIN:

Wash with plenty of soap and waterTake off contaminated clothing and wash before reuse

IF IN EYES:In case of eye contact, remove contact lens and rinse immediately with plenty ofwater, also under the eyelids, for at least 15 minutes
Call a physician if irritation develops and persists

If swallowed:

Rinse mouth thoroughly with water

Self-Protection of the First Aider Ensure that medical personnel are aware of the material(s) involved and takeprecautions to protect themselves

HUBER

Safety Data Sheet

CompaloxÒ AN/V-801; CompaloxÒ AN/V-802; CompaloxÒ AN/V; CompaloxÒ AN/V-812; CompaloxÒAN/V-813; CompaloxÒ AN/V-825; CompaloxÒ AN/V-827; CompaloxÒ AN/V-850; CompaloxÒ AN/V-800;
CompaloxÒ AN/V-005
Issue Date: 04/Jun/2019
Print Date: 12/Jun/2019

Revision Number: 1.3
Page 3 of 9

Treat symptomatically.

Notes to Physician

5. FIRE-FIGHTING MEASURESWater spray (fog)Foam
Dry chemical
Carbon dioxide (CO2)Suitable ExtinguishingMedia

Unsuitable Extinguishing Media Do not use water jetstream
Special hazards arising from the Avoid dust formation
substance or mixture
Fire-fighting measures

In case of fire and/or explosion do not breathe fumes
Water mist may be used to cool closed containers
Keep unauthorized personnel away

Special Protective Equipment
for Firefighters

Wear self-contained breathing apparatus and protective suit

6. ACCIDENTAL RELEASE MEASURES
Protective Equipment andPrecautions for Firefighters

Avoid dust formation
Ensure adequate ventilationUse personal protection recommended in Section 8
Avoid contact with eyes and skin. Wear suitable personal protection equipment.
Keep unauthorized personnel away

Environmental Precautions

Keep out of drains, sewers, ditches and waterways
Disposal considerations
See section 13 for more information

Methods and material forcontainment and cleaning up

Large Spill: Do not dry sweep dust. Wet dust with water before sweeping or use avacuum to collect dust
Small Spill: Vacuum or sweep material and place in a disposal container Minimize
use of water during clean-up
Recommended filter type: High efficiency particulate air filter (HEPA filter)

Other Information

Not applicable

7. HANDLING AND STORAGE
Handling
Technical measures

Provide adequate ventilation as well as local exhaustion at critical locations
Ensure adequate ventilation
Use personal protection equipment
See section 8 for more information

HUBER

Safety Data Sheet

CompaloxÒ AN/V-801; CompaloxÒ AN/V-802; CompaloxÒ AN/V; CompaloxÒ AN/V-812; CompaloxÒAN/V-813; CompaloxÒ AN/V-825; CompaloxÒ AN/V-827; CompaloxÒ AN/V-850; CompaloxÒ AN/V-800;
CompaloxÒ AN/V-005
Issue Date: 04/Jun/2019
Print Date: 12/Jun/2019

Revision Number: 1.3
Page 4 of 9Advice on safe handling

Minimize dust generation and accumulation

Conditions for safe storage, Keep containers tightly closed in a cool, well-ventilated place
including any
incompatibilities
Wash hands thoroughly after handling

Hygiene Measures
Storage
Packaging compatibilities

Keep/store only in original container

8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Provide adequate ventilation as well as local exhaustion at critical locations

Exposure Limits
Aluminum oxide

TWA: 0.5 mg/m3 (respirable dust)
2 mg/m3 (total dust)
TWA: 10 mg/m3
TWA: 15 mg/m3 total dustTWA: 5 mg/m3 respirable fraction(vacated) TWA: 10 mg/m3 total dust
(vacated) TWA: 5 mg/m3 respirable fraction

JapanACGIHOSHAEngineering Measures

Ensure adequate ventilation, especially in confined areas

Personal Protective Equipment
Respiratory Protection

In case of inadequate ventilation wear respiratory protection

Hand protection

For operations where prolonged or repeated skin contact may occur, impervious
gloves should be worn

Eye Protection

Wear safety glasses with side shields (or goggles)

Skin and Body Protection

Wear suitable protective clothing.
Chemical resistant apron.

Hygiene Measures

Handle in accordance with good industrial hygiene and safety practice
Wash thoroughly after handling
Avoid contact with eyes and skin
Do not breathe dust

9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance:
Physical State
ColorOdor
Odor Threshold
pH:
Melting point / Freezing point
Flash Point:
Evaporation Rate
Flammability (solid, gas)

Solid
GranulesWhiteOdorless
No information available
Not available
2045 °C / 3713 °F
Not applicable. Product/Substance is inorganic. Solid.
Not applicable Melting Point : > 300°C
No information available

HUBER

Safety Data SheetCompaloxÒ AN/V-801; CompaloxÒ AN/V-802; CompaloxÒ AN/V; CompaloxÒ AN/V-812; CompaloxÒAN/V-813; CompaloxÒ AN/V-825; CompaloxÒ AN/V-827; CompaloxÒ AN/V-850; CompaloxÒ AN/V-800;
CompaloxÒ AN/V-005
Issue Date: 04/Jun/2019
Print Date: 12/Jun/2019
Upper flammability limit:
Lower flammability limit:
Vapor Pressure
Vapor Density

Revision Number: 1.3
Page 5 of 9

Dynamic viscosity
Explosive Properties
Oxidizing Properties

1 hPa (2158 °C)
Not applicable
Melting Point : > 300°C
4 g/cm3 (20°C)
Insoluble
No information available Not applicable : Product/Substance is inorganic No
information available
Not applicable SolidNoneNone

Other information:

No data available

Relative Density
Water Solubility
Solubility in other solvents

10. STABILITY AND REACTIVITY
Reactivity

Stable under normal conditions

Chemical stability

Stable under normal conditions

Possibility of hazardous
reactionsNone known

Incompatible materials

Strong oxidizing agents

Hazardous decomposition
products

None known

11. TOXICOLOGICAL INFORMATION
General Information

Users are advised to consider national Occupational Exposure Limits or otherequivalent values.

Information on Likely Routes of Exposure
Inhalation

Do not breathe dustSkin

Avoid prolonged or repeated contact with skinContact with dust can cause mechanical irritation or drying of the skin

Eyes

Avoid contact with eyes
Dust contact with the eyes can lead to mechanical irritation

Ingestion

Ingestion is not a likely route of exposure

Aspiration hazard

Not an expected route of exposure.

Symptoms

Low hazard for usual industrial or commercial handlingHUBER

Safety Data Sheet

CompaloxÒ AN/V-801; CompaloxÒ AN/V-802; CompaloxÒ AN/V; CompaloxÒ AN/V-812; CompaloxÒAN/V-813; CompaloxÒ AN/V-825; CompaloxÒ AN/V-827; CompaloxÒ AN/V-850; CompaloxÒ AN/V-800;
CompaloxÒ AN/V-005
Issue Date: 04/Jun/2019
Print Date: 12/Jun/2019

Revision Number: 1.3
Page 6 of 9

11.1. Information on toxicological effects
Aluminum oxide
Serious eye damage/eyeirritation
Skin Corrosion/Irritation
Mutagenicity
Reproductive Effects

Non-irritant : Rabbit

Non-irritant : Rabbit
in vitro in vivo Based on available data, the classification criteria are not met
No indication of effects on fertility.
No indication of effects on developmental toxicity.
Lungs
Target Organ Effects
Specific target organ toxicity No information available- Single exposure
Specific target organ toxicity Repeated dose toxicity Inhalation 28-d Rat NOAEL (No observed adverse effectlevel) 70 mg(Al)/m3- Repeated exposure
Repeated dose toxicity 1- Year Rat NOAEL (No observed adverse effect level)>=30 mg Al/kg bw

Acute Toxicity

Al2 O3
Repeated dose toxicity Inhalation 28-d Rat NOAEL (No observed adverse effectlevel) 70 mg(Al)/m3 . Target Organs Lungs Respiratory system
Repeated dose toxicity 1- Year Oral Rat NOAEL (No observed adverse effectlevel) >=30 mg Al/kg bw

Serious eye damage/eye
irritation

Non-irritant : Rabbit
Draize Test Guinea pig : No sensitization responses were observed

Respiratory Sensitization

Based on available data, the classification criteria are not met

Skin Corrosion/Irritation

Non-irritant : Rabbit

Mutagenicity

Based on available data, the classification criteria are not met.

Reproductive Effects

Based on available data, the classification criteria are not met.

Reproductive Toxicity

Based on available data, the classification criteria are not met.

Carcinogenicity

This product does not contain any carcinogens or potential carcinogens as listedby OSHA, IARC or NTP.

Target Organ Effects

Lungs.

Specific target organ toxicity Single exposure

No information available.

Specific target organ toxicity Repeated exposure

No information available.

12. ECOLOGICAL INFORMATION
Ecotoxicity

Based on available data, the classification criteria are not met

HUBER

Safety Data Sheet

CompaloxÒ AN/V-801; CompaloxÒ AN/V-802; CompaloxÒ AN/V; CompaloxÒ AN/V-812; CompaloxÒAN/V-813; CompaloxÒ AN/V-825; CompaloxÒ AN/V-827; CompaloxÒ AN/V-850; CompaloxÒ AN/V-800;
CompaloxÒ AN/V-005
Issue Date: 04/Jun/2019
Print Date: 12/Jun/2019

Revision Number: 1.3
Page 7 of 9

Persistence and degradability

No data available

Bioaccumulation

No data available.

Mobility in soil

No data available

Hazardous to the ozone layer

No data available

13. DISPOSAL CONSIDERATIONS
Disposal

Dispose of in accordance with federal, state and local regulations

Contaminated packaging

Empty containers should be taken to an approved waste handling site for recycling
or disposal

14. TRANSPORT INFORMATION
Mode of Transportation (Road, Water, Air, Rail)TDG -Canada
DOT
ADR
IATA
IMDG/IMO
ICAO

14.1. UN number

Not regulated
Not regulated
Not regulated
Not regulated
Not regulated
Not regulatedNone

14.2. UN proper shipping name None
14.3. Transport hazard class(es) None
14.4. Packing group

None

14.5. Environmental hazards

No

14.6. Special precautions foruser

Not applicable

14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC CodeNot applicable

15. REGULATORY INFORMATION
Global Inventories
Pure substance/mixture

Substance

HUBER

Safety Data Sheet

CompaloxÒ AN/V-801; CompaloxÒ AN/V-802; CompaloxÒ AN/V; CompaloxÒ AN/V-812; CompaloxÒAN/V-813; CompaloxÒ AN/V-825; CompaloxÒ AN/V-827; CompaloxÒ AN/V-850; CompaloxÒ AN/V-800;
CompaloxÒ AN/V-005
Issue Date: 04/Jun/2019
Print Date: 12/Jun/2019
REACH Australia
registrati (AICS)
onnumberY
Aluminum oxide 1344-28-1 215-691-6 01-211952
9248-35-x
xxx

Chemical Name

CAS
NumberRevision Number: 1.3
Page 8 of 9

EC NoCanada(DSL)

China(IECSC)

Y

Y

Japan

S. Korea(KECL)(1)-23KE-01012(ENCS)(ISHL)

MexicoY

New
Philippine Taiwan
Zealand s (PICCS)

Y

Y

Y

TSCA:UnitedStates
Y01-211952
9248-35-0017

LegendX / Y: Complies - / N: Not Listed Exempt

KECL - Korean Existing and Evaluated Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
AICS - Australian Inventory of Chemical Substances
TSCA (Toxic Substances Control Act)DSL (Domestic Substance List)
NDSL (Non-Domestic Substances List)
Japan - ISHL Notifiable Substances
ENCS - Japan Existing and New Chemical Substances

16. OTHER INFORMATION
Prepared byHuber Engineered Materials Global Regulatory Affairs
email: regulatory.affairs@huber.com

Reason for RevisionThis SDS complies with the requirements of JIS Z 7250:2010 and JIS Z 7252:2009 (Japan)

Bibliography

NITE GHS Classified list
Japan Society for occupational health (2015) recommendation of allowable concentrations,etc.
ACGIH TLV: American Conference of Governmental Industrial Hygienists - Threshold Limit
Value

Abbreviations and acronyms

International Agency for Research on Cancer (IARC)
International Air Transport Association (IATA)
International Maritime Dangerous Goods (IMDG)International Uniform Chemical Information Database (IUCLID)
Workplace Hazardous Materials Information System (WHMIS) status and classification
EPA SARA Title III Section 312 (40 CFR 370) Hazard Classification
DOT (Department of Transportation)
OSHA (Occupational Safety and Health Administration of the US Department of Labor)
TWA - Time-Weighted Average
The Classification, Labeling and Packaging of Substances and Mixtures (CLP) Regulation (EC1272/2008)
PPE - Personal Protection Equipment
NIOSH - National Institute for Occupational Safety and Health
TDG (Transport of Dangerous Goods) Canada
CERCLA (Comprehensive Environmental Response, Compensation, and Liability Act)
Reportable Quantity (RQ) (RQ/% in mixture)
STEL - Short Term Exposure Limit
TLV® - Threshold Limit Value
Derived No Effect Level (DNEL)
SVHC: Substances of Very High Concern for Authorization:
Land transport (ADR/RID)
Biochemical oxygen demand (BOD)
Chemical oxygen demand (COD)HUBER

Safety Data Sheet

CompaloxÒ AN/V-801; CompaloxÒ AN/V-802; CompaloxÒ AN/V; CompaloxÒ AN/V-812; CompaloxÒAN/V-813; CompaloxÒ AN/V-825; CompaloxÒ AN/V-827; CompaloxÒ AN/V-850; CompaloxÒ AN/V-800;
CompaloxÒ AN/V-005
Issue Date: 04/Jun/2019
Print Date: 12/Jun/2019

Revision Number: 1.3
Page 9 of 9
ICAO (air)(IMDG) International Maritime Dangerous Goods
Positive Pressure Self-Contained Breathing Apparatus (SCBA)
Predicted No Effect Concentration (PNEC)
Globally Harmonized System (GHS)

Disclaimer

The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed onlyas a guidance for safe handling, use, processing, storage, transportation, disposal andrelease and is not to be considered a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material usedin combination with any other materials or in any process, unless specified in the text
End of Safety Data Sheet