Safety Data Sheet
Malaysia CLASS Regulation, 2013
GHS (Globally Harmonized System)
Issue Date: 19/Aug/2021
Print Date: 19/Aug/2021

Revision Number: 1.3.2

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF
THE COMPANY/UNDERTAKING
1.1. Product identifier
Product Name:

Pure substance/mixture
Aluminum Hydroxide
CAS Number
Weight-%MartinalÒ ON-310S; MartinalÒ ON-313S; MartinalÒ ON-320; MartinalÒ, ON-904;
MartinalÒ ON-906; MartinalÒ ON-908; MartinalÒ ON-921; MartinalÒ ON-935
Substance
21645-51-2>99

1.2. Relevant identified uses of the substance or mixture and uses advised against
Recommended Use

Additive : Flame retardant

1.3. Details of the supplier of the safety data sheet
Company:MARTINSWERK GmbHKölner Strasse 110
50127 Bergheim
Germany
Tel. : +49-2271-90.22.78
Fax. : +49-2271-90.27.17

Internetwww.hubermaterials.com

E-mailhubermaterials@huber.com

1.4. Emergency telephone
numberCHEMTREC: +1 800 424 9300 or International +1 703 527 3887

2. HAZARDS IDENTIFICATION
2.1. Classification of the substance or mixture
GHS Classification

This product is not classified as hazardous according to the UN GHS guideline
and labeling is not requiredHazards identification
Physical Hazard

Not classifiedHealth Hazards

Not classified

HUBER

Safety Data Sheet

MartinalÒ ON-310S; MartinalÒ ON-313S; MartinalÒ ON-320; MartinalÒ, ON-904; MartinalÒ ON-906; MartinalÒON-908; MartinalÒ ON-921; MartinalÒ ON-935
Issue Date: 19/Aug/2021
Print Date: 19/Aug/2021

Environmental Hazard

Revision Number: 1.3.2
Page 2 of 9

Not classified

2.2. Label elements
Symbols/Pictograms

None

Signal Word

None

Precautionary Statements
Prevention

Employ good industrial hygiene practice
Wash hands thoroughly after handlingResponse

IF IN EYES: Rinse cautiously with water for several minutes. Remove contactlenses, if present and easy to do. Continue rinsing
IF ON SKIN: Wash with plenty of soap and water

Storage

Keep in a dry place. Store away from incompatible materials.

Disposal

Dispose of contents/containers in accordance with local regulations.

Additional Information:None.

2.3. Other hazards

No information available.

3. COMPOSITION/INFORMATION ON INGREDIENTSPure substance/mixture

Substance

Chemical Name

CAS Number

Aluminum Hydroxide

21645-51-2

TSCA: UnitedStatesA

REACH registration number

Weight-%01-2119529246-39>99

Legend X / Y: Complies ; A: Active ; - / N: Exempt Not Listed

4. FIRST AID MEASURES
4.1. Description of first aid measures
General Advice

When in doubt or if symptoms are observed, get medical advice. Ensure that
medical personnel are aware of the material(s) involved and take precautions toprotect themselves.

Eye Contact

In case of eye contact, remove contact lens and rinse immediately with plenty ofwater, also under the eyelids, for at least 15 minutes.

Skin Contact

Wash with plenty of soap and water.

Ingestion

Rinse mouth thoroughly with water.

HUBER

Safety Data SheetMartinalÒ ON-310S; MartinalÒ ON-313S; MartinalÒ ON-320; MartinalÒ, ON-904; MartinalÒ ON-906; MartinalÒON-908; MartinalÒ ON-921; MartinalÒ ON-935
Issue Date: 19/Aug/2021
Print Date: 19/Aug/2021

Revision Number: 1.3.2
Page 3 of 9Inhalation

If breathing is difficult, remove victim to fresh air and keep at rest in a position
comfortable for breathing.

Aspiration hazard

Not an expected route of exposure.

Notes to Physician

Treat symptomatically.

4.2. Most important symptoms
and effects, both acute anddelayedInhalation of dust may cause irritation of the respiratory system. Eye irritation.

4.3. Indication of any immediate Treatment should be symptomatic and supportive.
medical attention and special
treatment needed

5. FIRE-FIGHTING MEASURES
5.1. Extinguishing media
Suitable ExtinguishingMedia
Water spray (fog). Foam. Dry chemical. Carbon dioxide (CO2).
Unsuitable Extinguishing Media
None known.
5.2. Special hazards arising from the substance or mixture
None known.
5.3. Advice for firefighters
Special protective
equipment for firefighters
Wear a self-contained breathing apparatus and chemical protective clothing.
Fire-fighting measures
In case of fire and/or explosion do not breathe fumes.

6. ACCIDENTAL RELEASE MEASURES
6.1. Personal precautions,protective equipment andemergency procedures
For non-emergency personnel

Ensure adequate ventilation. Use personal protection recommended in Section 8.
Avoid dust formation. Keep unauthorized personnel away.
Keep unauthorized personnel away.

HUBER

Safety Data Sheet

MartinalÒ ON-310S; MartinalÒ ON-313S; MartinalÒ ON-320; MartinalÒ, ON-904; MartinalÒ ON-906; MartinalÒON-908; MartinalÒ ON-921; MartinalÒ ON-935
Issue Date: 19/Aug/2021
Print Date: 19/Aug/2021
For emergency responders

Revision Number: 1.3.2Page 4 of 9
Keep unauthorized personnel away. Use personal protection recommended inSection 8.

6.2. Environmental precautions Avoid runoff to waterways and sewers.
6.3. Methods and material forcontainment and cleaning up

Methods for Containment : Prevent further leakage or spillage if safe to do soMethods for Clean-up : Sweep up and shovel into suitable containers for disposal

6.4. Reference to other sections Section 8: Exposure controls and personal protection. See Section 13 foradditional waste treatment information.

7. HANDLING AND STORAGE
7.1. Precautions for safehandling

Minimize dust generation and accumulation. Provide local exhaust ventilation.
Handle in accordance with good industrial hygiene and safety practice.

7.2. Conditions for safe storage, Store away from incompatible materials. Keep container tightly closed and dry.
including any incompatibilities
7.3. Specific end use(s)No information available.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1. Control parameters
Occupational exposure limits
Aluminum Hydroxide
NIOSH
ACGIH
OSHA

TWA: 5 mg/m3 (respirable dust); 10 mg/m3 TWA (total dust)
TLV/TWA 8-hr: 1 mg/m3 (respirable fraction)
TWA: 15 mg/m3 Total Dust
5 mg/m3 Respirable Dust

Biological Limit Values:

None

Recommended monitoringprocedures

Refer also to national guidance documents for information on currently
recommended monitoring procedures

8.2. Exposure controls
Engineering Measures

Do not handle until all safety precautions have been read and understood
Ensure adequate ventilation, especially in confined areas
Provide a good standard of controlled ventilation (10 to 15 air changes per hour)
Use exhaust ventilation to keep airborne concentrations below exposure limits
In case of insufficient ventilation, wear suitable respiratory equipment

Personal protective equipment
Eye/Face Protection

Wear safety glasses with side shields (or goggles)

Skin and Body Protection

Wear suitable protective clothing.

HUBER

Safety Data Sheet

MartinalÒ ON-310S; MartinalÒ ON-313S; MartinalÒ ON-320; MartinalÒ, ON-904; MartinalÒ ON-906; MartinalÒON-908; MartinalÒ ON-921; MartinalÒ ON-935
Issue Date: 19/Aug/2021
Print Date: 19/Aug/2021

Revision Number: 1.3.2
Page 5 of 9Hand Protection

Wear suitable gloves.

Respiratory Protection

In case of inadequate ventilation wear respiratory protection.

Thermal hazards

None known.

Hygiene Measures

Follow general hygiene considerations recognized as common good workplace
practices. The worker should wash daily at the end of each work shift, and prior toeating, drinking, smoking, etc.

Environmental Exposure
Controls

Dispose of in accordance with local regulations.

9. PHYSICAL AND CHEMICAL PROPERTIES
9.1. Information on basic physical and chemical properties
Appearance:
Solid Powder
Physical StateWhite
Color
Odorless
Odor
No information available
Odor Threshold+/- 9 ( 10% Water )pH:~ 300 °C / 572 °F (101.3 hPa)Melting point / Freezing point
Initial boiling point and boiling > 2900 °C / 5252 °F (101.3 hPa)range
Not applicable. Product/Substance is inorganic. Solid.
Flash Point:
Not applicable.
Evaporation Rate
Not flammable
Flammability (solid, gas)
Upper flammability limit:
Lower flammability limit:
Not applicable
Vapor Pressure
Not applicable
Vapor Density+/- 2.42 g/cm³ (20 °C)
Relative Density
Insoluble
Water Solubility
No information available
Solubility in other solvents
Not applicable Product/Substance is inorganic
Partition coefficient
Autoignition Temperature
200 °C (392 °F)Decomposition Temperature
Not applicable Solid
Dynamic viscosity
None
Explosive Properties
NoneOxidizing Properties
9.2. Other information
No data available

10. STABILITY AND REACTIVITY

HUBER

Safety Data Sheet

MartinalÒ ON-310S; MartinalÒ ON-313S; MartinalÒ ON-320; MartinalÒ, ON-904; MartinalÒ ON-906; MartinalÒON-908; MartinalÒ ON-921; MartinalÒ ON-935
Issue Date: 19/Aug/2021
Print Date: 19/Aug/2021

Revision Number: 1.3.2
Page 6 of 9

10.1. Reactivity

No data available

10.2. Chemical stability

Stable under normal conditions

10.3. Possibility of hazardous
reactionsNone under normal processing

10.4. Conditions to avoid

Decomposition Temperature < / =0.3% : Al2 O3 Water

10.5. Incompatible materials

None known

10.6. Hazardous decomposition None known
products

11. TOXICOLOGICAL INFORMATION
General Information

Users are advised to consider national Occupational Exposure Limits or otherequivalent values.

Information on Likely Routes of Exposure
Inhalation

Do not breathe dust

Skin

Avoid prolonged or repeated contact with skinContact with dust can cause mechanical irritation or drying of the skinEyes

Avoid contact with eyes
Dust contact with the eyes can lead to mechanical irritation

Ingestion

Ingestion is not a likely route of exposure

Aspiration hazard

Not an expected route of exposure.

11.1. Information on toxicological effects
Aluminum Hydroxide
Oral LD50
Inhalation LC50
IARC

> 2000 mg/kg Rat
Rat > 2.3 mg/l (Al2O3) Aerosol Maximum attainable concentration
Not Listed

Reproductive Toxicity

Based on available data, the classification criteria are not met.

Carcinogenicity

Based on available data, the classification criteria are not met.

12. ECOLOGICAL INFORMATION

HUBER

Safety Data SheetMartinalÒ ON-310S; MartinalÒ ON-313S; MartinalÒ ON-320; MartinalÒ, ON-904; MartinalÒ ON-906; MartinalÒON-908; MartinalÒ ON-921; MartinalÒ ON-935
Issue Date: 19/Aug/2021
Print Date: 19/Aug/2021

Revision Number: 1.3.2
Page 7 of 9

12.1. Ecotoxicity

Very low solubility. Not considered to be harmful to aquatic life.

Aluminum Hydroxide
WGK Classification (AwSV)

5220 WGK: nwg

12.2. Persistence anddegradability

The methods for determining biodegradability are not applicable to inorganic
substances.

12.3. Bioaccumulative potential Not likely to bioaccumulate.
No data available.

Bioconcentration factor(BCF)
12.4. Mobility in soil

No information available.

12.5. Results of PBT and vPvB
assessment

This substance does not meet the criteria for classification as PBT or vPvB.

12.6. Other adverse effects

No information available

13. DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Disposal Methods

Disposal should be in accordance with applicable regional, national and local laws
and regulations.

Contaminated Packaging

Empty containers should be taken to an approved waste handling site for recycling
or disposal. Do not reuse container.

Waste codes

Waste codes should be assigned by the user based on the application for which
the product was used

Aluminum Hydroxide
European Waste Catalog
WGK Classification (AwSV)

0602995220 WGK: nwg

14. TRANSPORT INFORMATION
Mode of Transportation (Road, Water, Air, Rail)TDG -Canada
DOT
IATA

Not regulated
Not regulated
Not regulated

HUBER

Safety Data Sheet

MartinalÒ ON-310S; MartinalÒ ON-313S; MartinalÒ ON-320; MartinalÒ, ON-904; MartinalÒ ON-906; MartinalÒON-908; MartinalÒ ON-921; MartinalÒ ON-935
Issue Date: 19/Aug/2021
Print Date: 19/Aug/2021

Revision Number: 1.3.2
Page 8 of 9
Not regulated
Not regulated

IMDG/IMOICAONone

14.1. UN number

14.2. UN proper shipping name None
14.3. Transport hazard class(es) None
14.4. Packing groupNone

14.5. Environmental hazards

No

14.6. Special precautions foruser

Not applicable

14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC CodeNot applicable

15. REGULATORY INFORMATION
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Global Inventories
Chemical Name
AluminumHydroxideCAS
NumberEC NoREACH
Australia Canada
registration(AIIC)(DSL)
number21645-51- 244-492-7 01-211952924
YY
26-39

China(IECSC)

Japan

S. Korea(KECL)

MexicoY(1)-17(ENCS);
ISHL

KE-00980

Y

New Philippin TaiwanZealandes(PICCS)Y
Y
Y

TSCA:UnitedStatesA

LegendX / Y: Complies ; A: Active ; - / N: Exempt / Not Listed

16. OTHER INFORMATION
Prepared by

Huber Engineered Materials Global Regulatory Affairs
email: regulatory.affairs@huber.com.

GHS Classification

This product is not classified as hazardous according to the UN GHS guideline
and labeling is not required

Physical Hazard

Not classifiedHealth Hazards

Not classified

Environmental Hazard

Not classified

HUBER

Safety Data Sheet

MartinalÒ ON-310S; MartinalÒ ON-313S; MartinalÒ ON-320; MartinalÒ, ON-904; MartinalÒ ON-906; MartinalÒON-908; MartinalÒ ON-921; MartinalÒ ON-935
Issue Date: 19/Aug/2021
Print Date: 19/Aug/2021

Revision Number: 1.3.2
Page 9 of 9Labeling
Symbols/Pictograms

None

Signal Word

None

Training Advice

Do not handle until all safety precautions have been read and understood.

Abbreviations and acronyms

IARC (International Agency for Research on Cancer)
IATA (International Air Transport Association)
IMDG (International Maritime Dangerous Goods)
International Uniform Chemical Information Database (IUCLID)WHMIS (Workplace Hazardous Materials Information System)
EPA SARA Title III Section 312 (40 CFR 370) Hazard Classification
DOT (Department of Transportation)
OSHA (Occupational Safety and Health Administration of the US Department of Labor)
TWA (Time-Weighted Average)
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA)The Classification, Labeling and Packaging of Substances and Mixtures (CLP) Regulation (EC1272/2008)
PPE (Personal Protection Equipment)
NIOSH - National Institute for Occupational Safety and Health
TDG (Transport of Dangerous Goods) Canada
CERCLA (Comprehensive Environmental Response, Compensation, and Liability Act)
RQ (Reportable Quantity) (RQ/% in mixture)
STEL (Short Term Exposure Limit)
TLV® (Threshold Limit Value)
Derived No Effect Level (DNEL)
SVHC: Substances of Very High Concern for Authorization:
Land transport (ADR/RID)
Biochemical oxygen demand (BOD)
Chemical oxygen demand (COD)
ICAO (International Civil Aviation Organization)
IMDG (International Maritime Dangerous Goods)
Positive Pressure Self-Contained Breathing Apparatus (SCBA)
Predicted No Effect Concentration (PNEC)
GHS (Globally Harmonized System)

Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information
and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use,processing, storage, transportation, disposal and release and is not to be considered a warranty or quality
specification. The information relates only to the specific material designated and may not be valid for such material
used in combination with any other materials or in any process, unless specified in the text.
End of Safety Data Sheet