BORONIC ACID COMPOUNDS
Suzuki coupling reaction, for synthesis of biaryl compounds from aryl boronic acids and aryl
halides using transition metals as catalysts, is one of the most actively researched organic
synthesis reaction in recent years.

The reaction in aqueous/organic biphase system using palladium compounds with phosphine
ligand as catalysts and carbonates such as sodium carbonate as bases is common method1).
NaOH2), Et3N3) and K3PO44) are also applicable to the reaction except for carbonates. The
reaction is accelerated by 1 equivalent of TBAB（Tetrabutylammonium Bromide） which is aphase transfer catalyst, and progresses even if only in the aqueous phase5). Recently, organic
synthesis using microwave have been actively investigated. Studies have shown that transition
metals are unnecessary and that phase catalysts such as TBAB are sufficient for Suzuki
coupling reactions to progress if microwave is used6).
Wako provides a wide variety of chemicals used for Suzuki coupling reaction including Boronic
acids, Boronic acid esters and Palladium catalysts.
Please contact us if you require different package size.

Reaction Examples

Ⅱ

References
1）Miyaura, N.; Suzuki, A.: Chem. Rev., 95, 2457（ 1995）.
2）Watanabe, T.; Miyaura, N.; Suzuki, A.: Synlett, 207（ 1992）.
3）Muller, W.; Lowe, D. A. Neijt, H. Urwyler, S.: Helv. Chim. Acta, 75, 855（ 1992）.
4）Coleman, R. S.; Grant, E. B.: Tetrahedron Lett., 34, 222（ 1993）.
5）Badone, D.; Baroni, M.; Cardamone, R.; Ielmini, A. Guzzi, U.: J. Org. Chem., 62, 7170（ 1997）.
6）Leadbeater, N. E.; Marco, M.: J.Org. Chem., 68, 5660（ 2003）.
7）Yuzuru Masuda et al.: J. Org. Chem, 62, 6458（ 1997）.

1

BORONIC ACIDS
Tetrahydroxydiboron

Methylboronic Acid

Ethylboronic Acid

（2-Methylpropyl）boronic Acid

［CAS No.13675-18-8］［13061-96-6］［4433-63-0］［84110-40-7］

326-63411
322-63413

1g
5g

320-64151
326-64153

1g
5g

327-84941
323-84943

1g
5g

329-72171
327-72172

5g
25g

n-Butylboronic Acid

1-Pentylboronic Acid（E）-1-Pentenylboronic Acidn -Hexylboronic Acid

［4426-47-5］［4737-50-2］［59239-44-0］［16343-08-1］

327-52331
323-52333

1g
5g

322-84871
328-84873

1g
5g

320-72961
326-72963

1g
5g

326-72201
322-72203

1g
5g

2-Furanboronic Acid

5-Formyl-2-furanboronic Acid

2-Thiopheneboronic Acid

3-Thiopheneboronic Acid

［13331-23-2］［27329-70-0］［6165-68-0］［6165-69-1］

320-73441
326-73443

1g
5g

5-Bromo-2-thiopheneboronic Acid

［162607-17-2］
321-69561
327-69563

1g

5-Chloro-2-thiopheneboronic Acid

［162607-18-3］
1g
5g

5-Acetyl-2-thiopheneboronic Acid

325-64101
321-64103

5g
25g

2,5-Thiophenediboronic Acid

4-Pyridineboronic Acid

328-84091
326-84092

1g
5g

2-Chloro-4-pyridineboronic Acid

326-77201

1g
5g

2-Formyl-3-thiopheneboronic Acid

326-64131
322-64133

1-BOC-pyrrole-2-boronic Acid

1g

327-87001
323-87003

322-64091
328-64093

1g
5g

3-Formyl-2-thiopheneboronic Acid

［17303-83-2］
1g
5g

320-65251
326-65253

1g
5g

3-Pyridineboronic Acid

［1692-25-7］［135884-31-0］5g
25g［1692-15-5］
329-59851
325-59853

321-63461
327-63463［4347-31-3］
1g
5g［26076-46-0］［206551-43-1］
325-84361
323-84362

324-67351

1g
5g

322-59841
328-59843

1g
5g

2-Fluoro-3-pyridineboronic Acid

2-Methoxy-5-pyridineboronic Acid

［174669-73-9］［163105-89-3］

324-83351
320-83353

1g
5g

326-57301

1g

2

2,6-Dimethoxy-3pyridineboronic Acid

［221006-70-8］
329-76191
325-76193

041-23371

10g

327-67341
323-67343

o-Bromophenylboronic Acid

［244205-40-1］［4612-26-4］［98-80-6］1g
5g

p-Phenylenediboronic Acid

1g
5g

326-70501
324-70502

5g
25g

m-Bromophenylboronic Acid

p-Bromophenylboronic Acido-Chlorophenylboronic Acid

m-Chlorophenylboronic Acid

［89598-96-9］［5467-74-3］［3900-89-8］［63503-60-6］

328-69571
324-69573

1g
5g

322-70461
328-70463

1g
5g

321-63341
327-63343

1g
5g

327-64161
323-64163

1g
5g

p-Chlorophenylboronic Acid

3-Chloro-4-methylphenylboronic Acid

2,3-Dichlorophenylboronic Acid

2,4-Dichlorophenylboronic Acid

［1679-18-1］［175883-63-3］［151169-74-3］［68716-47-2］

320-63311
328-63312

5g
25g

320-84931

1g

326-70481
324-70482

5g
25g

325-64081
321-64083

1g
5g

2,5-Dichlorophenylboronic Acid

2,6-Dichlorophenylboronic Acid

3,4-Dichlorophenylboronic Acid

3,5-Dichlorophenylboronic Acid

［135145-90-3］［73852-17-2］［151169-75-4］［67492-50-6］

324-69551
320-69553

1g
5g

3-Chloro-4-methoxyphenylboronic Acid

［175883-60-0］
321-88121
327-88123

1g
5g

5-Chloro-2-methoxyphenylboronic Acid

320-83331
328-83332

1g
5g

4-Chloro-3-fluorophenylboronic Acid

320-67331

328-70201
326-70202

5g
25g

3-Chloro-4-ethoxyphenylboronic Acid

［279261-81-3］5g
25g［137504-86-0］［144432-85-9］
323-70511
329-70513

328-77021
324-77023［89694-48-4］
1g
5g

3-Chloro-4-fluorophenylboronic Acid

3

Dihydroxyphenylborane

325-84861
321-84863

2-Chloro-4trifluoromethylphenylboronic Acid

321-76151

5g
25g

2-Chloro-4-fluorophenylboronic Acid

［313545-72-1］
1g
5g［254993-59-4］
1g

328-70181
326-70182

329-84881

1g

2-Chloro-5（trifluoromethyl）phenylboronic Acid

［182344-18-9］
1g

329-84901

1g

Boronic
Acids
Biphenyl4-Chloro-3（trifluoromethyl）phenylboronic Acido-Fluorophenylboronic Acid

m-Fluorophenylboronic Acid

p-Fluorophenylboronic Acid

［176976-42-4］［1993-03-9］［768-35-4］［1765-93-1］

326-84911

500mg

320-57201
326-57203

1g
5g

326-72181
324-72182

5g
25g

325-39431
323-39432

5g
25g

2,3-Difluorophenylboronic Acid

2,4-Difluorophenylboronic Acid

2,5-Difluorophenylboronic Acid

2,6-Difluorophenylboronic Acid

［121219-16-7］［144025-03-6］［193353-34-3］［162101-25-9］

322-81071
328-81073

1g
5g

327-57071
325-57072

5g
25g

329-80361
327-80362

5g
25g

329-70471
325-70473

1g
5g

3,4-Difluorophenylboronic Acid

3,5-Difluorophenylboronic Acid

2-Fluoro-4-methylphenylboronic Acid

（4-Fluoro-2-methylphenyl）boronic Acid

［168267-41-2］［156545-07-2］［170981-26-7］［139911-29-8］

329-75971
327-75972

5g
25g

4-Fluoro-3-methylphenylboronic Acid

［139911-27-6］
325-80341
323-80342

5g
25g

5-Fluoro-2-methylphenylboronic Acid

［163517-62-2］5g
25g

5-Fluoro-2-hydroxyphenylboronic Acid

321-84961
327-84963

1g
5g

2-Fluoro-5-formylphenylboronic Acid

324-84951

327-83341
323-83343

1g
5g

4-Fluoro-3（trifluoromethyl）phenylboronic Acid

［182344-23-6］1g
5g［352534-79-3］［259209-20-6］
321-84101
327-84103

322-77041
320-77042

328-83371
324-83373

5-Fluoro-2-methoxyphenylboronic Acid

328-79461
326-79462

1g
5g

3-Cyano-4-fluorophenylboronic Acid

［214210-21-6］1g
5g［179897-94-0］
1g

328-69071
324-69073

328-76161

1g

3-Fluoro-4-methoxyphenylboronic Acid

［149507-26-6］
5g
25g

322-72161
328-72163

1g
5g

4-Ethoxy-3-fluorophenylboronic Acid

2,3,4-Trifluorophenylboronic Acid

2,4,5-Trifluorophenylboronic Acid

3,4,5-Trifluorophenylboronic Acid

［279263-10-4］［226396-32-3］［247564-72-3］［143418-49-9］

326-84891
322-84893

1g
5g

324-82251
320-82253

1g
5g

329-72791
325-72793

1g
5g

328-63471
324-63473

1g
5g

4

o-Hydroxyphenylboronic Acid

1g
5g

1g
5g

325-69081
321-69083

m-Aminophenylboronic Acid

［30418-59-8］
1g
5g

329-52151
325-52153

1g
5g

m-Aminophenylboronic Acid
Hydrochloride

m-Nitrophenylboronic Acid

p-Nitrophenylboronic Acid

3-Methoxycarbonyl-5nitrophenylboronic Acid

［85006-23-1］［13331-27-6］［24067-17-2］［117342-20-8］

321-69061
327-69063

1g
5g

324-59801
320-59803

1g
5g

321-59811
327-59813

1g
5g

326-85011

1g

4-Methoxycarbonyl-2nitrophenylboronic Acido-Methoxyphenylboronic Acid

m-Methoxyphenylboronic Acid

p-Methoxyphenylboronic Acid

［85107-55-7］［5720-06-9］［10365-98-7］［5720-07-0］

329-85001

1g

327-63321
325-63322

5g
25g

324-41471
320-41473

1g
5g

321-69201
329-69202

5g
25g

m-Ethoxyphenylboronic Acidp-Ethoxyphenylboronic Acid

p-Isopropoxyphenylboronic Acid

p-Propoxyphenylboronic Acid

［90555-66-1］［22237-13-4］［153624-46-5］［186497-67-6］

320-84791
326-84793

1g
5g

p-Butoxyphenylboronic Acid

［105365-51-3］
324-88091
320-880935g25go-（Trifluoromethoxy）phenylboronic Acid

324-73461
320-73463

1g
5g

2,4-Dimethoxyphenylboronic Acid

327-70531
323-70533

327-72971
323-72973

1g
5gm-（Trifluoromethoxy）phenylboronic
Acid［179113-90-7］
1g
5g

321-73471
327-73473

1g
5g

2,5-Dimethoxyphenylboronic Acid

328-80331
326-80332

324-88111
322-88112

5g
25g

p（Trifluoromethoxy）phenylboronic
Acid［139301-27-2］
1g
5g［107099-99-0］［133730-34-4］［208399-66-0］
326-84391
322-84393

322-82171
320-82172［175676-65-0］
1g
5g

4-Methoxy-2methylphenylboronic Acid5

323-72191
329-72193（p-Hydroxyphenyl）boronic Acid

［71597-85-8］［87199-18-6］［89466-08-0］
323-72951
329-72953

m-Hydroxyphenylboronic Acid

321-83361
327-83363

1g
5g

2,6-Dimethoxyphenylboronic Acid

［23112-96-1］
5g
25g

325-70191
323-70192

5g
25g

Boronic
Acids
Biphenyl
3,4-Dimethoxyphenylboronic Acid

［121124-97-8］［122775-35-3］
320-70521
328-70522

3-Formyl-4methoxyphenylboronic Acid

5g
25g

321-72991
329-72992

3,5-Dimethyl-4methoxyphenylboronic Acid

［301699-39-8］
5g
25g

322-85471
328-85473

3,4,5-Trimethoxyphenylboronic Acid

［182163-96-8］
1g
5g

327-73451

1g

o（Methylthio）phenylboronic Acid

m-（Methylthio）phenylboronic Acidp（Methylthio）phenylboronic Acido-Methylphenylboronic Acid

［168618-42-6］［128312-11-8］［98546-51-1］［16419-60-6］

320-84431
326-84433

1g
5g

322-69091
328-69093

1g
5g

321-41481
327-41483

1g
5g

328-41491
324-41493

1g
5g

m-Methylphenylboronic Acid

p-Methylphenylboronic Acid

2,3-Dimethylphenylboronic Acid

2,4-Dimethylphenylboronic Acid

［17933-03-8］［5720-05-8］［183158-34-1］［55499-44-0］

321-41501
327-41503

1g
5g

323-63301
321-63302

5g
25g

323-70491
321-70492

5g
25g

321-77011
327-77013

1g
5g

2,5-Dimethylphenylboronic Acid

2,6-Dimethylphenylboronic Acid

3,4-Dimethylbenzeneboronic Acid

3,5-Dimethylphenylboronic Acid

［85199-06-0］［100379-00-8］［55499-43-9］［172975-69-8］

325-77031
321-77033

1g
5g

o-Ethylphenylboronic Acid

1g
5gp-（Bromomethyl）phenylboronic Acidp-Ethylphenylboronic Acid

328-73481
326-73482

1g5go-（Hydroxymethyl）phenylboronicAcid328-84971
324-84973

325-53731
321-53733

1g
5g

p-Vinylphenylboronic Acid

［2156-04-9］5g
25g［87199-14-2］［68162-47-0］
320-84811
326-84813

1g
5g［63139-21-9］［90002-36-1］
327-88081
323-88083

325-72151
321-72153

329-84401
325-84403

p-Propylphenylboronic Acid

323-73431
329-73433

5g
25g

m-（Bromomethyl）phenylboronic Acid

［51323-43-4］
1g
5g［134150-01-9］
1g
5g

322-80351
320-80352

323-84801
329-84803

1g
5g

o-Isopropylphenylboronic Acid

［89787-12-2］
1g
5g

322-84991
328-84993

100mg
500mg

6

m-Isopropylphenylboronic Acid

100mg
500mg

1g
5g

326-54501
322-54503

p-Pentylphenylboronic Acid

［121219-12-3］
1g
5g

324-84831
320-84833

100mg
500mg

p-t-Butylphenylboronic Acido-Trifluoromethylphenylboronic Acidm-（Trifluoromethyl）phenylboronicAcidp-（Trifluoromethyl）phenylboronic
Acid［123324-71-0］［1423-27-4］［1423-26-3］［128796-39-4］

322-64111
328-64113

1g
5g

328-76281
324-76283

1g
5g

328-41511
324-41513

1g
5g

325-41521
321-41523

1g
5g

2,4-Bis（trifluoromethyl）phenylboronic
Acid

3,5-Bis（trifluoromethyl）phenylboronic
Acidm-Cyanophenylboronic Acid

p-Cyanophenylboronic Acid

［153254-09-2］［73852-19-4］［150255-96-2］［126747-14-6］

327-84821
323-84823

1g
5g

m-Formylphenylboronic Acid

［87199-16-4］
327-57211
323-57213
325-57212

1g
5g

p-Formylphenylboronic Acid324-57221
320-57223

1g
5g（p-Benzoylphenyl）boronic Acid

320-68311

326-20931
324-20932

5g
25g

p-（Aminocarbonyl）phenylboronic Acid

320-76121
326-76123

320-57061
326-57063

1g
5g

m-Acetylphenylboronic Acid

［204841-19-0］［123088-59-5］1g
5g［268218-94-6］［149104-90-5］
323-64141
329-64143

320-63291
326-63293［87199-17-5］
1g
5g
25g

p-Acetylphenylboronic Acid7

321-77991
327-77993

4-n-Butylbenzeneboronic Acid

［145240-28-4］［16152-51-5］［216019-28-2］
325-84981
321-84983

p-Isopropylphenylboronic Acid

1g
5g

324-70541
322-70542

5g
25g

m-Carboxyphenylboronic Acid

［25487-66-5］
1g

323-57051
329-57053

1g
5gp-Carboxyphenylboronic Acid

4-Carboxy-3-fluorophenylboronic Acid

3-Carboxy-5-nitrophenylboronic Acid

4-Carboxy-2-nitrophenylboronic Acid

［14047-29-1］［120153-08-4］［101084-81-5］［85107-54-6］

320-41451
326-41453

1g
5g

323-84921

1g

321-84841

1g

328-84851

1g

Boronic
Acids
Biphenylo-（Methoxycarbonyl）phenylboronic
Acid［99769-19-4］［374538-03-1］
329-76211
325-76213

m-（Methoxycarbonyl）phenylboronic
Acid

1g
5g

326-57281
322-57283

p（Methoxycarbonyl）phenylboronic
Acid［99768-12-4］
1g
5g

323-57291
329-57293

o-Ethoxycarbonylphenylboronic
Acid［380430-53-5］
1g
5g

326-73421
322-73423

1g
5g

m-Ethoxycarbonylphenylboronic Acidp-Ethoxycarbonylphenylboronic Acidm-（Isopropoxycarbonyl）phenylboronic
Acidp-（Isopropoxycarbonyl）phenylboronic
Acid［4334-87-6］［4334-88-7］［342002-80-6］［342002-82-8］

329-57151
325-57153

1g
5g

326-57161
322-57163

1g
5g

325-74091
321-74093

1g
5g

322-72781
328-72783

1g
5g

o-Acetamidophenylboronic Acidm-Acetamidophenylboronic Acidp-Acetamidophenylboronic Acid

N-（4-Boronophenyl）succinamic Acid

［169760-16-1］［78887-39-5］［101251-09-6］［480424-95-1］

329-56931
325-56933

1g
5g

322-52141
328-52143

1g
5g

326-56941
322-56943

1g
5g

2-（Pivaloylamino）phenylboronic Acid

3-（BOC-amino）phenylboronic Acid

4（BOC-amino）phenylboronic Acid

［146140-95-6］［380430-68-2］［380430-49-9］

321-57111
327-57113

1g
5g

3-N-（Methanesulfonamide）phenylboronic Acid

1g
5g

3,4-（Methylenedioxy）phenylboronic
Acid

4-N（Methanesulfonamide）phenylboronic Acid

329-57271
325-57273

1g
5g

1-Methyl-5-indoleboronic Acid

323-77211

320-52321

1go［（Dimethylamino）sulfonyl］
phenylboronic Acid

327-68321

1g（1,4-Benzodioxan-6-yl）boronic Acid

323-56951
329-56953

2-N（Methanesulfonamide）phenylboronic Acid

325-57251
321-57253

1g
5gp-（Trimethylsilyl）phenylboronic Acid

328-85331
324-85333

1g
5g

2-Benzofuranboronic Acid

［98437-24-2］［164014-95-3］
1g

1g
5g

［17865-11-1］［178432-25-2］
1g
5g［192182-55-1］［94839-07-3］
322-57381
328-57383

1g
5g［380430-57-9］［148355-75-3］
322-57261
328-57263

323-52311
329-52313

328-59821
324-59823

1g
5g

322-84371
328-84373

1g
5g

8

Boronic Acids
Benzo［b］thiophene-2-boronic Acid

1g
5g

1-Naphthaleneboronic Acid

1g
5g

3-Biphenylboronic Acid

［5122-95-2］［13922-41-3］
326-63391
322-63393

328-74101
324-74103

1g
5g

4'-Methyl-4-biphenylboronic Acid

328-82151
324-82153

2-Fluoro-4-biphenylylboronicAcid327-88101
323-88103［192182-56-2］
1g
5g

329-63381

1g

4-Biphenylboronic Acid

328-59441
326-59442

5g
25g

4'-Ethyl-4-biphenylboronic Acid

［153035-62-2］
1g
5g

321-24401

1g

o-Benzyloxyphenylboronic Acid

m-Benzyloxyphenylboronic Acid

p-Benzyloxyphenylboronic Acid

4-Benzyloxy-3-fluorophenylboronic
Acid［190661-29-1］［156682-54-1］［146631-00-7］［133057-83-7］

329-77171
325-77173

1g
5g

326-77181
322-77183

1g
5g

p-Benzyloxycarbonylphenylboronic
Acid

4-Phenoxathiinboronic Acid

［184000-11-1］［100124-07-0］

327-84441
323-84443

91g

327-77111
323-77113

4-Isoquinolineboronic Acid

［5122-94-1］
1g
5g［178305-99-2］
328-24391

8-Quinolineboronic Acid

［86-58-8］［191162-39-7］［98437-23-1］
329-64121
325-64123

3-Quinolineboronic Acid

1g
5g

323-67321

1g

329-84381
325-84383

1g
5g

323-84421
329-84423

1g
5g

BORONIC ACIDS ESTERS
2-（Hydroxymethyl）phenylboronic Acid
Cyclic Monoester［25015-63-8］［5735-41-1］
326-72941
322-72943

1g
5g

2-Butyl-N,N,N',N'-tetramethyl-1,3,2dioxaborolane-（4R,5R）-dicarboxamide［161344-85-0］
321-52351
327-52353

4,4,5,5-Tetramethyl-1,3,2-dioxaborolane

325-59831
323-59832［61676-62-8］5g
25g

2-Butyl-N,N,N',N'-tetramethyl-1,3,2dioxaborolane-（4S,5S）-dicarboxamide［161344-84-9］1g
5g

4-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan2-yl）-1H-pyrazole

328-52361
324-52363

2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2dioxaborolane

327-41461
325-41462［69190-62-1］
5g
25g

trans-4,4,5,5-Tetramethyl-2-（1-octenyl）1,3,2-dioxaborolane［83947-55-1］
1g
5g

1-Methyl-4-（4,4,5,5-tetramethyl-1,3,2dioxaborolan-2-yl）-1H-pyrazole

322-60211
328-60213

2-Butyl-4,4,5,5-tetramethyl-1,3,2dioxaborolane

324-56981
320-56983

1g
5g

2-Cyclopropyl-4,4,5,5-tetramethyl-1,3,2dioxaborolane［126689-01-8］
1g
5g

1-BOC-4-（4,4,5,5-tetramethyl-1,3,2dioxaborolan-2-yl）pyrazole

322-76181

1g

1-Benzyl-4-（4,4,5,5-tetramethyl-1,3,2dioxaborolan-2-yl）-1H-pyrazole［269410-08-4］
324-60151
320-60153

1g
5g

3,5-Dimethyl-4-（4,4,5,5-tetramethyl-1,3,2dioxaborolan-2-yl）-1H-pyrazole

322-57141
328-57143

1g
5g

326-57421
322-57423

1g
5g

321-60161
327-60163

1g
5g

2-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan2-yl）thiophene

3-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan2-yl）thiophene［248924-59-6］［193978-23-3］［214360-70-0］

326-59981
322-59983

1g
5g

323-63421
329-63423

1g
5g

4-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan2-yl）pyridine

2-Chloro-5-（4,4,5,5-tetramethyl-1,3,2dioxaborolan-2-yl）pyridine［329214-79-1］［181219-01-2］［444120-94-9］

1g
5g

2-Methoxy-5-（4,4,5,5-tetramethyl-1,3,2dioxaborolan-2-yl）pyridine

1g5g

3-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan2-yl）furan

3-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan2-yl）pyridine

328-60171
324-60173

323-77191
329-77193

325-60181
321-60183

1g
5g

2-Amino-5-（4,4,5,5-tetramethyl-1,3,2dioxaborolan-2-yl）pyridine

324-76141
320-76143

320-63431
326-63433

1g
5g

1g
5g

2-Hydroxy-5-（4,4,5,5-tetramethyl-1,3,2dioxaborolan-2-yl）pyridine

1-［5-（4,4,5,5-Tetramethyl-1,3,2dioxaborolan-2-yl）pyridin-2-yl］piperazine［445264-61-9］
327-57331

1g

322-77161
328-77163

1g
5g

327-77231

1g

321-76271
327-76273

1g
5g

10

4-［5-（4,4,5,5-Tetramethyl-1,3,2dioxaborolan-2-yl）pyridin-2-yl］morpholine

1-Methyl-4-［4-（4,4,5,5-tetramethyl-1,3,2dioxaborolan-2-yl）pyridin-2-yl］piperazine

1-［4-（4,4,5,5-Tetramethyl-1,3,2dioxaborolan-2-yl）pyridin-2-yl］piperazine

2-Amino-5-（4,4,5,5-tetramethyl-1,3,2dioxaborolan-2-yl）pyrimidine［485799-04-0］
324-76261
320-76263

1g
5g

2,6-Dimethoxy-5-（4,4,5,5-tetramethyl1,3,2-dioxaborolan-2-yl）pyrimidine

322-76201
328-76203

1g
5g

1g

324-77241

1g

321-77251

1g（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2yl）benzene

4-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan2-yl）chlorobenzene

2（3,4-Dichlorophenyl）-4,4,5,5tetramethyl-1,3,2-dioxaborolane［24388-23-6］［195062-61-4］［401797-02-2］

327-59911
325-59912

5g
25g

325-59951
323-59952

5g
25g

325-63361
323-63362

5g
25g

4-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan2-yl）fluorobenzene

2-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan2-yl）-1,5-difluorobenzene

2-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan2-yl）aniline

3-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan2-yl）aniline［214360-58-4］［288101-48-4］［191171-55-8］［210907-84-9］

329-59971
325-59973

1g
5g

322-59961
320-59962

5g
25g

320-59881
326-59883

1g
5g

327-59891
323-59893

1g
5g

4-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan2-yl）aniline

N,N-Dimethyl［4-（4,4,5,5-tetramethyl-1,3,2dioxaborolan-2-yl）phenyl］amine

2-Methoxy-4-（4,4,5,5-tetramethyl-1,3,2dioxaborolan-2-yl）aniline

2-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan2-yl）nitrobenzene［214360-73-3］［171364-78-6］［461699-81-0］［190788-59-1］

320-59901
326-59903

1g
5g

3-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan2-yl）nitrobenzene

1g5g

4-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan2-yl）phenol

1g5g

4-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan2-yl）nitrobenzene

327-60021
323-60023

1g
5g

2-Methoxy-4-（4,4,5,5-tetramethyl-1,3,2dioxaborolan-2-yl）phenol

323-57311
329-57313

329-82201
325-82203

1g
5g

2-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan2-yl）phenol［269409-97-4］
1g
5g［269410-22-2］［269409-70-3］
327-57451
323-57453

325-82161
321-82163［171364-83-3］［68716-48-3］
320-60011
326-60013

11

320-76241

324-60031
320-60033

323-60001
329-60003

1g
5g

3-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan2-yl）phenol［214360-76-6］
1g
5g

2,6-Dimethyl-4-（4,4,5,5-tetramethyl-1,3,2dioxaborolan-2-yl）phenol

321-60041
327-60043

1g
5g

2-（3-Benzyloxyphenyl）-4,4,5,5-tetramethyl1,3,2-dioxaborolane［269410-25-5］
1g
5g

328-57121
324-57123

1g
5g

321-82141
327-82143

1g
5g

Boronic Acids Esters
2-（4-Benzyloxyphenyl）-4,4,5,5-tetramethyl1,3,2-dioxaborolane［754226-40-9］
327-76131
323-76133

3-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan2-yl）toluene［195062-57-8］［253342-48-2］
1g
5g

327-82241
323-82243

4-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan2-yl）toluene

1g
5g

325-60201
321-60203

2-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan2-yl）benzonitrile［214360-48-2］
1g
5g

320-82231
326-82233

1g
5g

3-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan2-yl）benzonitrile

4-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan2-yl）benzonitrile

4-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan2-yl）benzaldehyde

3-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan2-yl）benzoic Acid

［214360-46-0］［171364-82-2］［128376-64-7］［269409-73-6］

321-59931
327-59933

1g
5g

328-59941
324-59943

1g
5g

320-86131
326-86133

1g
5g

324-59921
320-59923

1g
5g

4-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan2-yl）benzoic Acid

Methyl 2-（4,4,5,5-Tetramethyl-1,3,2dioxaborolan-2-yl）benzoate

Methyl 3（4,4,5,5-Tetramethyl-1,3,2dioxaborolan-2-yl）benzoate

Methyl 4-（4,4,5,5-Tetramethyl-1,3,2dioxaborolan-2-yl）benzoate［180516-87-4］［653589-95-8］［480425-35-2］［171364-80-0］

320-57441
326-57443

1g
5g

323-82221
329-82223

1g
5g

322-57401
328-57403

1g
5g

329-57411
325-57413

1g
5g

Ethyl 2-（4,4,5,5-Tetramethyl-1,3,2dioxaborolan-2-yl）benzoate

Ethyl 3（4,4,5,5-Tetramethyl-1,3,2dioxaborolan-2-yl）benzoate

Ethyl 4-（4,4,5,5-Tetramethyl-1,3,2dioxaborolan-2-yl）benzoate

2-（2-Methoxyphenyl）-4,4,5,5-tetramethyl1,3,2-dioxaborolane［269409-99-6］［269410-00-6］［195062-62-5］［190788-60-4］

323-57171
329-57173

1g
5g

2-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan2-yl）phenyl Acetate

1g
5g

t-Butyl 2-（4,4,5,5-Tetramethyl-1,3,2dioxaborolan-2-yl）phenyl Carbonate

3-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan2-yl）phenyl Acetate325-60061
321-60063

1g
5g

t-Butyl 3-（4,4,5,5-Tetramethyl-1,3,2dioxaborolan-2-yl）phenyl Carbonate329-57031
325-57033

327-57191
323-57193

1g
5g

4-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan2-yl）phenyl Acetate326-82191
322-82193

1g
5g

2-Methoxy-4-（4,4,5,5-tetramethyl-1,3,2dioxaborolan-2-yl）phenyl Acetate［480424-70-2］
1g
5g［480438-74-2］［480424-71-3］
322-57021
328-57023

1g
5g［480424-69-9］［480424-68-8］
328-60051
324-60053

320-57181
326-57183

322-60071
328-60073

1g
5g

t-Butyl 4（4,4,5,5-Tetramethyl-1,3,2dioxaborolan-2-yl）phenyl Carbonate［480438-75-3］
1g
5g

326-57041
322-57043

320-57321
326-57323

1g
5g

4-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan2-yl）biphenyl［144432-80-4］
1g
5g

326-87451
322-87453

1g
5g

12

1-Methyl-4-［4-（4,4,5,5-tetramethyl-1,3,2dioxaborolan-2-yl）phenyl］piperazine

4-［4-（4,4,5,5-Tetramethyl-1,3,2dioxaborolan-2-yl）phenyl］morpholine［747413-21-4］
323-76231
329-76233

N-［2-（4,4,5,5-Tetramethyl-1,3,2dioxaborolan-2-yl）phenyl］formamide［480425-36-3］
1g
5g

320-77221

1g

329-60081
325-60083［480425-37-4］
1g
5g

326-60091
322-60093

1g
5g

N［4-（4,4,5,5-Tetramethyl-1,3,2dioxaborolan-2-yl）phenyl］formamide

2-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl）acetanilide

3-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan2-yl）acetanilide

4-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan2-yl）acetanilide［480424-94-0］［380430-61-5］［480424-93-9］［214360-60-8］

329-60101
325-60103

1g
5g

N-［4-（4,4,5,5-Tetramethyl-1,3,2dioxaborolan-2-yl）phenyl］succinamic Acid

326-59861
322-59863

1g
5g

2,2-Dimethyl-N-［2-（4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl）phenyl］propionamide［480424-98-4］
327-60141
323-60143

1g
5g

t-Butyl N-［4-（4,4,5,5-Tetramethyl-1,3,2dioxaborolane-2-yl）phenyl］carbamate

325-57131
321-57133

1g
5g

N-BOC-N-methyl-4-（4,4,5,5-tetramethyl1,3,2-dioxaborolan-2-yl）-aniline［330793-01-6］
325-57011
321-57013

1g
5g

N［4-（4,4,5,5-Tetramethyl-1,3,2dioxaborolan-2-yl）phenyl］methanesulfonamide

322-52381
328-52383

1g
5g

2-（2-Methylthiophenyl）-4,4,5,5tetramethyl-1,3,2-dioxaborolane

323-59871
329-59873

1g
5g

1g
5g

1-Methyl-5-（4,4,5,5-tetramethyl-1,3,2dioxaborolan-2-yl）-1H-indole

326-82211
322-82213

1g
5g

4-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan2-yl）isoquinoline

1g
5g

327-63441

1g

1g
5g

t-Butyl N-［3-（4,4,5,5-Tetramethyl-1,3,2dioxaborolane-2-yl）phenyl］carbamate［159624-15-4］［330793-09-4］

321-56991
327-56993

1g
5g

328-57001
324-57003

1g
5g

N-［2（4,4,5,5-Tetramethyl-1,3,2dioxaborolan-2-yl）phenyl］methanesulfonamideN-［3-（4,4,5,5-Tetramethyl-1,3,2dioxaborolan-2-yl）phenyl］methanesulfonamide［380430-60-4］［305448-92-4］

326-60111
322-60113

1g
5g

2-（4-Methylsulfonylphenyl）-4,4,5,5tetramethyl-1,3,2-dioxaborolane

329-82181
325-82183

2-Benzyl-4,4,5,5-tetramethyl-1,3,2dioxaborolane

326-52161
322-52163

323-60121
329-60123

1g
5g

5-（4,4,5,5-Tetramethyl-1,3,2-dioxaborolan2-yl）-1H-indole［269410-24-4］
1g
5g

323-59991
329-59993

1g
5g

trans-2（4,4,5,5-Tetramethyl-1,3,2dioxaborolan-2-yl）styrene［83947-56-2］［87100-28-5］
326-76221
322-76223

323-57431
329-57433

t-Butyl N-［2-（4,4,5,5-Tetramethyl-1,3,2dioxaborolane-2-yl）phenyl］carbamate［603143-27-7］
320-60131
326-60133

13

N-［3-（4,4,5,5-Tetramethyl-1,3,2dioxaborolan-2-yl）phenyl］formamide

1g
5g

322-60191
328-60193

1g
5g

Boronic Acids Esters
1-cis-1,2-Bis（4,4,5,5-tetramethyl-1,3,2dioxaborolan-2-yl）pentene［307531-75-5］
322-52261
328-52263

1-cis-1,2-Bis（4,4,5,5-tetramethyl-1,3,2dioxaborolan-2-yl）hexene

325-52251
321-52253

1g
5g

cis-1,2-Bis（4,4,5,5-tetramethyl-1,3,2dioxaborolan-2-yl）stilbene

p-（1,3,2-Dioxaborinan-2-yl）benzaldehyde［151416-94-3］［160068-88-2］

329-52271
325-52273

1g
5g

320-68291
326-68293

cis-1,2-Bis（4,4,5,5-tetramethyl-1,3,2dioxaborolan-2-yl）styrene［307531-74-4］［312693-52-0］1g
5g

1-cis-1,2-Bis（4,4,5,5-tetramethyl-1,3,2dioxaborolan-2-yl）heptene

328-52241
324-52243

1g
5g

3-（5,5-Dimethyl-1,3,2-dioxaborinan-2yl）pyridine

326-52281
322-52283

5,5-Dimethyl-2-phenyl-1,3,2dioxaborinane［5123-13-7］
1g
5g

322-63371
328-63373

1g
5g

321-57091
327-57093

2-（4-Fluorophenyl）-5,5-dimethyl-1,3,2dioxaborinane

Diisopropyl（Bromomethyl）boronate

Triisopropyl Borate

Triphenylboroxin［225916-39-2］［137297-49-5］［5419-55-6］［3262-89-3］

324-57081
320-57083

1g
5g

323-68301
329-68303

1g
5g

1g
5g

320-41532
324-41535

25g
500g

322-26491
320-26492

1g
5g

5g
25g

Tris
（p-chlorophenyl）boroxin［7519-91-7］
326-26531
324-26532

5g
25g

14

DIBORON ESTERS
Bis（pinacolato）diboron

Bis（N,N,N',N'-tetramethyl-D-tartaramide
glycolato）diboron［ 73183-34-3 ］
327-56971
323-56973

Bis（N,N,N',N'-tetramethyl-L-tartaramide
glycolato）diboronBis（diisopropyl-D-tartrateglycolato）diboron［ 230299-42-0 ］
323-52291
329-52293

1g
5g

1g
5g

326-52301
322-52303

1g
5g

327-52191
323-52193

1g
5g

Bis
（diisopropyl-L-tartrateglycolato）diboronBis［（-）-pinanediolato］diboronBis［（+）-pinanediolato］diboronBis（neopentylglycolato）diboron［ 230299-10-2 ］［ 230299-17-9 ］［ 230299-05-5 ］［ 201733-56-4 ］

320-52201
326-52203

324-52221
320-52223

1g
5g

1g
5g

321-52231
327-52233

1g
5g

324-63331
320-63333

1g
5g

Bis（hexyleneglycolato）diboron［ 230299-21-5 ］
327-52211
323-52213

1g
5g

PHASE TRANSFER CATALYST
Wako Cat. No.
205-04331
203-04332
207-04335

15

Description
Tetrabutylammonium Bromide

Package Size
[ 1643-19-2 ]

5g
25g
500g

Chemical Subject Index（Boronic Acids）
o-Acetamidophenylboronic Acidm-Acetamidophenylboronic Acidp-Acetamidophenylboronic Acidm-Acetylphenylboronic Acidp-Acetylphenylboronic Acid
5-Acetyl-2-thiopheneboronic Acidp-(Aminocarbonyl)phenylboronic Acid
m-Aminophenylboronic Acid
m-Aminophenylboronic Acid Hydrochloride(1,4-Benzodioxan-6-yl)boronic Acid
2-Benzofuranboronic Acid
Benzo[b]thiophene-2-boronic Acid
(p-Benzoylphenyl)boronic Acid
p-Benzyloxycarbonylphenylboronic Acid
4-Benzyloxy-3-fluorophenylboronic Acido-Benzyloxyphenylboronic Acid
m-Benzyloxyphenylboronic Acid
p-Benzyloxyphenylboronic Acid
3-Biphenylboronic Acid
4-Biphenylboronic Acid
2,4-Bis(trifluoromethyl)phenylboronic Acid
3,5-Bis(trifluoromethyl)phenylboronic Acid
3-(BOC-amino)phenylboronic Acid
4-(BOC-amino)phenylboronic Acid
1-BOC-pyrrole-2-boronic Acid
N-(4-Boronophenyl)succinamic Acidm-(Bromomethyl)phenylboronic Acidp-(Bromomethyl)phenylboronic Acido-Bromophenylboronic Acid
m-Bromophenylboronic Acid
p-Bromophenylboronic Acid
5-Bromo-2-thiopheneboronic Acid
p-Butoxyphenylboronic Acid
4-n-Butylbenzeneboronic Acidn-Butylboronic Acid
p-t-Butylphenylboronic Acid
4-Carboxy-3-fluorophenylboronic Acid
3-Carboxy-5-nitrophenylboronic Acid
4-Carboxy-2-nitrophenylboronic Acid
m-Carboxyphenylboronic Acid
p-Carboxyphenylboronic Acid
3-Chloro-4-ethoxyphenylboronic Acid
2-Chloro-4-fluorophenylboronic Acid
3-Chloro-4-fluorophenylboronic Acid
4-Chloro-3-fluorophenylboronic Acid
3-Chloro-4-methoxyphenylboronic Acid
5-Chloro-2-methoxyphenylboronic Acid
3-Chloro-4-methylphenylboronic Acido-Chlorophenylboronic Acid
m-Chlorophenylboronic Acid
p-Chlorophenylboronic Acid
2-Chloro-4-pyridineboronic Acid
5-Chloro-2-thiopheneboronic Acid
2-Chloro-4-trifluoromethylphenylboronic Acid
2-Chloro-5-(trifluoromethyl)phenylboronic Acid
4-Chloro-3-(trifluoromethyl)phenylboronic Acid
3-Cyano-4-fluorophenylboronic Acid
m-Cyanophenylboronic Acid
p-Cyanophenylboronic Acid
2,3-Dichlorophenylboronic Acid
2,4-Dichlorophenylboronic Acid
2,5-Dichlorophenylboronic Acid
2,6-Dichlorophenylboronic Acid
3,4-Dichlorophenylboronic Acid
3,5-Dichlorophenylboronic Acid
2,3-Difluorophenylboronic Acid
2,4-Difluorophenylboronic Acid
2,5-Difluorophenylboronic Acid
2,6-Difluorophenylboronic Acid
3,4-Difluorophenylboronic Acid
3,5-Difluorophenylboronic Acid
Dihydroxyphenylborane
2,4-Dimethoxyphenylboronic Acid

Page 8-3
8-3
8-3
7-4
7-5
2-5
7-4
5-1
5-2
8-6
8-6
9-1
7-5
9-5
9-4
9-4
9-4
9-4
9-2
9-2
7-3
7-3
8-4
8-4
2-5
8-3
6-5
6-6
3-1
3-2
3-2
2-4
5-5
7-1
2-2
7-2
7-6
7-6
7-6
7-5
7-6
3-5
3-5
3-6
3-6
3-5
3-5
3-3
3-2
3-2
3-3
2-6
2-4
3-6
3-6
4-1
4-4
7-3
7-3
3-3
3-3
3-4
3-4
3-4
3-4
4-2
4-2
4-2
4-2
4-3
4-3
3-1
5-6

2,5-Dimethoxyphenylboronic Acid
2,6-Dimethoxyphenylboronic Acid
3,4-Dimethoxyphenylboronic Acid
2,6-Dimethoxy-3-pyridineboronic Acido-[(Dimethylamino)sulfonyl]phenylboronic Acid
3,4-Dimethylbenzeneboronic Acid
3,5-Dimethyl-4-methoxyphenylboronic Acid
2,3-Dimethylphenylboronic Acid
2,4-Dimethylphenylboronic Acid
2,5-Dimethylphenylboronic Acid
2,6-Dimethylphenylboronic Acid
3,5-Dimethylphenylboronic Acido-Ethoxycarbonylphenylboronic Acidm-Ethoxycarbonylphenylboronic Acidp-Ethoxycarbonylphenylboronic Acid
4-Ethoxy-3-fluorophenylboronic Acidm-Ethoxyphenylboronic Acidp-Ethoxyphenylboronic Acid
4'-Ethyl-4-biphenylboronic Acid
Ethylboronic Acido-Ethylphenylboronic Acidp-Ethylphenylboronic Acid
2-Fluoro-4-biphenylylboronic Acid
2-Fluoro-5-formylphenylboronic Acid
5-Fluoro-2-hydroxyphenylboronic Acid
3-Fluoro-4-methoxyphenylboronic Acid
5-Fluoro-2-methoxyphenylboronic Acid
2-Fluoro-4-methylphenylboronic Acid
(4-Fluoro-2-methylphenyl)boronic Acid
4-Fluoro-3-methylphenylboronic Acid
5-Fluoro-2-methylphenylboronic Acido-Fluorophenylboronic Acid
m-Fluorophenylboronic Acid
p-Fluorophenylboronic Acid
2-Fluoro-3-pyridineboronic Acid
4-Fluoro-3-(trifluoromethyl)phenylboronic Acid
5-Formyl-2-furanboronic Acid
3-Formyl-4-methoxyphenylboronic Acid
m-Formylphenylboronic Acid
p-Formylphenylboronic Acid
2-Formyl-3-thiopheneboronic Acid
3-Formyl-2-thiopheneboronic Acid
2-Furanboronic Acidn-Hexylboronic Acido-(Hydroxymethyl)phenylboronic Acido-Hydroxyphenylboronic Acid
m-Hydroxyphenylboronic Acid
(p-Hydroxyphenyl)boronic Acidm-(Isopropoxycarbonyl)phenylboronic Acidp-(Isopropoxycarbonyl)phenylboronic Acid
p-Isopropoxyphenylboronic Acido-Isopropylphenylboronic Acid
m-Isopropylphenylboronic Acid
p-Isopropylphenylboronic Acid
4-Isoquinolineboronic Acid
2-N-(Methanesulfonamide)-phenylboronic Acid
3-N-(Methanesulfonamide)-phenylboronic Acid
4-N-(Methanesulfonamide)-phenylboronic Acid
3-Methoxycarbonyl-5-nitrophenylboronic Acid
4-Methoxycarbonyl-2-nitrophenylboronic Acido-(Methoxycarbonyl)phenylboronic Acid
m-(Methoxycarbonyl)phenylboronic Acidp-(Methoxycarbonyl)phenylboronic Acid
4-Methoxy-2-methylphenylboronic Acido-Methoxyphenylboronic Acid
m-Methoxyphenylboronic Acid
p-Methoxyphenylboronic Acid
2-Methoxy-5-pyridineboronic Acid
4'-Methyl-4-biphenylboronic Acid
Methylboronic Acid
3,4-(Methylenedioxy)phenylboronic Acid
1-Methyl-5-indoleboronic Acido-Methylphenylboronic Acid
m-Methylphenylboronic Acid

Page 5-6
5-6
6-1
3-1
8-5
6-4
6-1
6-3
6-3
6-4
6-4
6-4
8-1
8-2
8-2
4-6
5-4
5-4
9-3
2-1
6-5
6-5
9-3
4-5
4-5
4-5
4-5
4-3
4-3
4-4
4-4
4-1
4-1
4-1
2-6
4-4
2-3
6-1
7-4
7-4
2-4
2-4
2-3
2-2
6-6
5-1
5-1
5-1
8-2
8-2
5-4
6-6
7-1
7-1
9-1
8-4
8-5
8-5
5-2
5-3
8-1
8-1
8-1
5-6
5-3
5-3
5-3
2-6
9-3
2-1
8-6
8-6
6-2
6-3

16

Chemical Subject Index (Boronic Acids)
p-Methylphenylboronic Acid
(2-Methylpropyl)boronic Acido-(Methylthio)phenylboronic Acid
m-(Methylthio)phenylboronic Acidp-(Methylthio)phenylboronic Acid
1-Naphthaleneboronic Acid
m-Nitrophenylboronic Acid
p-Nitrophenylboronic Acid(E)-1-Pentenylboronic Acid
1-Pentylboronic Acid
p-Pentylphenylboronic Acid
4-Phenoxathiinboronic Acidp-Phenylenediboronic Acid
2-(Pivaloylamino)phenylboronic Acid
p-Propoxyphenylboronic Acid
p-Propylphenylboronic Acid
3-Pyridineboronic Acid
4-Pyridineboronic Acid

Page 6-3
2-1
6-2
6-2
6-2
9-2
5-2
5-2
2-2
2-2
7-1
9-5
3-1
8-4
5-4
6-6
2-5
2-6

3-Quinolineboronic Acid
8-Quinolineboronic Acid
Tetrahydroxydiboron
2-Thiopheneboronic Acid
3-Thiopheneboronic Acid
2,5-Thiophenediboronic Acido-(Trifluoromethoxy)phenylboronic Acidm-(Trifluoromethoxy)phenylboronic Acidp-(Trifluoromethoxy)phenylboronic Acido-Trifluoromethylphenylboronic Acidm-(Trifluoromethyl)phenylboronic Acidp-(Trifluoromethyl)phenylboronic Acid
2,3,4-Trifluorophenylboronic Acid
2,4,5-Trifluorophenylboronic Acid
3,4,5-Trifluorophenylboronic Acid
3,4,5-Trimethoxyphenylboronic Acidp-(Trimethylsilyl)phenylboronic Acidp-Vinylphenylboronic Acid

Page 9-1
9-1
2-1
2-3
2-3
2-5
5-5
5-5
5-5
7-2
7-2
7-2
4-6
4-6
4-6
6-1
8-5
6-5

Chemical Subject Index (Esters)

17

2-Amino-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyridine
2-Amino-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyrimidine
2-(3-Benzyloxyphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
2-(4-Benzyloxyphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
2-Benzyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
1-Benzyl-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-pyrazoleBis(diisopropyl-D-tartrate glycolato)diboronBis(diisopropyl-L-tartrate glycolato)diboronBis(hexylene glycolato)diboronBis(neopentyl glycolato)diboronBis(pinacolato)diboronBis[(-)-pinanediolato]diboronBis[(+)-pinanediolato]diboron
1-cis-1,2-Bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)heptene
1-cis-1,2-Bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)hexene
1-cis-1,2-Bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pentene
cis-1,2-Bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)stilbene
cis-1,2-Bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)styrene
Bis(N,N,N',N'-tetramethyl-D-tartaramide glycolato)diboron
Bis(N,N,N',N'-tetramethyl-L-tartaramide glycolato)diboron
N-BOC-N-methyl-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-aniline
1-BOC-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyrazole
2-Butyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
2-Butyl-N,N,N',N'-tetramethyl-1,3,2-dioxaborolane-(4R,5R)-dicarboxamide
2-Butyl-N,N,N',N'-tetramethyl-1,3,2-dioxaborolane-(4S,5S)-dicarboxamide
t-Butyl N-[2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolane-2-yl)phenyl]carbamate
t-Butyl N-[3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolane-2-yl)phenyl]carbamate
t-Butyl N-[4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolane-2-yl)phenyl]carbamate
t-Butyl 2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl Carbonate
t-Butyl 3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl Carbonate
t-Butyl 4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl Carbonate
2-Chloro-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyridine
2-Cyclopropyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
2-(3,4-Dichlorophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
Diisopropyl (Bromomethyl)boronate
2,6-Dimethoxy-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyrimidine
3-(5,5-Dimethyl-1,3,2-dioxaborinan-2-yl)pyridine
5,5-Dimethyl-2-phenyl-1,3,2-dioxaborinane
2,6-Dimethyl-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenol
N,N-Dimethyl[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]amine
2,2-Dimethyl-N-[2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-propionamide
3,5-Dimethyl-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-pyrazolep-(1,3,2-Dioxaborinan-2-yl)benzaldehyde

Page 10-6
11-1
11-6
12-1
13-6
10-3
15-1
15-2
15-3
15-2
15-1
15-2
15-2
14-1
14-1
14-1
14-2
14-1
15-1
15-1
13-4
10-3
10-1
10-2
10-2
13-3
13-3
13-4
12-6
12-6
12-6
10-5
10-2
11-2
14-3
11-2
14-2
14-2
11-6
11-4
13-3
10-4
14-2

Chemical Subject Index (Esters)
Ethyl 2-(4,4,5,5-TetramEthyl -1,3,2-dioxaborolan-2-yl)benzoate
Ethyl 3-(4,4,5,5-TetramEthyl -1,3,2-dioxaborolan-2-yl)benzoate
Ethyl 4-(4,4,5,5-TetramEthyl -1,3,2-dioxaborolan-2-yl)benzoate
2-(4-Fluorophenyl)-5,5-dimethyl-1,3,2-dioxaborinane
2-(Hydroxymethyl)phenylboronic Acid Cyclic Monoester
2-Hydroxy-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyridine
2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
2-(2-Methoxyphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
2-Methoxy-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)aniline
2-Methoxy-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenol
2-Methoxy-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl Acetate
2-Methoxy-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyridine
2-(4-Methylsulfonylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
Methyl 2-(4,4,5,5-Tetramethyl -1,3,2-dioxaborolan-2-yl)benzoate
Methyl 3-(4,4,5,5-Tetramethyl -1,3,2-dioxaborolan-2-yl)benzoate
Methyl 4-(4,4,5,5-Tetramethyl -1,3,2-dioxaborolan-2-yl)benzoate
1-Methyl-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-indole
1-Methyl-4-[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]piperazine
1-Methyl-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-pyrazole
1-Methyl-4-[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyridin-2-yl]piperazine
2-(2-Methylthiophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
4,4,5,5-Tetramethyl-1,3,2-dioxaborolane
2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)acetanilide
3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)acetanilide
4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)acetanilide
2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)aniline
3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)aniline
4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)aniline
4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)benzaldehyde(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)benzene
3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)benzoic Acid
4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)benzoic Acid
2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)benzonitrile
3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)benzonitrile
4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)benzonitrile
4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)biphenyl
4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)chlorobenzene
2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)-1,5-difluorobenzene
4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)fluorobenzene
3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)furan
5-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-indole
4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)isoquinoline
2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)nitrobenzene
3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)nitrobenzene
4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)nitrobenzene
2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenol
3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenol
4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenol
2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl Acetate
3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl Acetate
4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl Acetate
N-[2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]formamideN-[3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]formamideN-[4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]formamideN-[2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-methanesulfonamideN-[3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-methanesulfonamideN-[4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-methanesulfonamide
4-[4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]morpholine
N-[4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]succinamicAcid
4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-pyrazole
3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)pyridine
4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)pyridine
4-[5-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)pyridin-2-yl]morpholine
1-[4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)pyridin-2-yl]piperazine
1-[5-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)pyridin-2-yl]piperazine
trans-2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)styrene
2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)thiophene
3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)thiophene
3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)toluene
4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)toluenetrans-4,4,5,5-Tetramethyl-2-(1-octenyl)-1,3,2-dioxaborolane
Triisopropyl Borate
Triphenylboroxin
Tris(p-chlorophenyl)boroxin

Page 12-4
12-4
12-4
14-3
10-1
10-6
10-1
12-4
11-4
11-6
12-5
10-6
13-5
12-3
12-3
12-3
13-6
13-1
10-3
11-1
13-5
10-1
13-2
13-2
13-2
11-3
11-3
11-4
12-2
11-2
12-2
12-3
12-1
12-2
12-2
12-6
11-2
11-3
11-3
10-4
13-5
13-6
11-4
11-5
11-5
11-5
11-5
11-6
12-5
12-5
12-5
13-1
13-1
13-2
13-4
13-4
13-5
13-1
13-3
10-3
10-5
10-5
11-1
11-1
10-6
13-6
10-4
10-4
12-1
12-1
10-2
14-3
14-3
14-4

18

PALLADIUM CATALYSTS
Wako Cat. No.

Description

Package Size024-12151

Bis（acetonitrile）
dichloropalladium（Ⅱ）［14592-56-4］

1g

026-10891

Bis（acetylacetonato）palladium（Ⅱ）［14024-61-4］

1g

027-12141

Bis（benzonitrile）
dichloropalladium（Ⅱ）［14220-64-5］

1g

329-42021

Bis（dibenzylideneacetone）palladium（0）［32005-36-0］

1g

321-27821［1,1'-Bis（diphenylphosphino）ferrocene］dichloropalladium（Ⅱ）,［72287-26-4］

1g
5g

327-27823

Dichloromethane Adduct ［PdCl2（dppf）］

329-37751

Bis（ethylenediamine）
palladium（Ⅱ）Chloride［13963-53-6］

500mg

323-40961

Diamminedichloropalladium（Ⅱ）［14323-43-4］

500mg

040-24061

Dichloro（η-cycloocta-1,5-diene）
palladium（Ⅱ）［12107-56-1］

1g

040-22481

trans-Dichlorobis（triphenylphosphine）
palladium（Ⅱ）

046-22483
048-24241
324-56621

Di-μ-chlorobis［（η-allyl）
palladium（Ⅱ）］［13965-03-2］［12012-95-2］®

FibreCat 1001※

320-56623［Palladium（Ⅱ）Acetate-Triphenylphosphine PE fibres］

321-56631

FibreCat®1007※

327-56633［Palladium（Ⅱ）Acetate-Dicyclohexylphenylphosphine PE fibres］

328-56641

FibreCat®1026※

324-56643［Acetonitrile Dichloropalladium（Ⅱ）-Triphenylphosphine PE fibres］

Pd content：2.7 〜 4%
Pd content：3 〜 4%
Pd content：3.5 〜 4.5%

5g
1g
1g
5g
1g
5g
1g
5g
1g

163-07141
169-07143

1g

Palladium（Ⅱ）Acetate［3375-31-3］5g
25g

161-07142

10g

163-13871

Palladium-Alumina（Pd:5%）

160-13881

Palladium-Barium Carbonate（Pd:5%）10g

167-13891

Pallladium-Barium Sulfate（Pd:5%）10g

169-00041

Palladium Black［7440-05-3］

322-37741

Palladium（Ⅱ）Bromide［13444-94-5］

160-13901

Palladium-Calcium Carbonate, Lindlar Catalyst（Pd:5%）10g

Palladium-Carbon

25g［7440-05-3］

100g

167-07541

1g

166-00051
162-00053

1g
5g

163-07543
165-07542

1g

Palladium（Ⅱ）Chloride［7647-10-1］

5g
25g

164-00052
168-20553

Palladium（Ⅱ）-Hydrotalcite（m）（Pd:0.8%）10g

161-20543

Palladium（Ⅱ）-Hydrotalcite（Pd:1.5%）5g160-20471

Palladium-Nanocage

1g

162-15281
168-15283
168-21991
164-21993

Palladium（Ⅱ）Oxide［1314-08-5］

1g
5g
1g

PI Palladium（Pd abt. 3%）5g
1g

160-22811

PMI Palladium

325-37731

Tetraamminepalladium（Ⅱ）Chloride［13815-17-3］

100mg

320-40971

Tetraamminepalladium（Ⅱ）Nitrate Solution（abt.13%）［13601-08-6］

5g

201-14701

Tetrakis（acetonitrile）
palladium（Ⅱ）Bis（tetrafluoroborate）［21797-13-7］

1g

203-14641

Tetrakis（triphenylphosphine）
palladium（0）［14221-01-3］

5g

205-14721

Tris（dibenzylideneacetone）
dipalladium（0）［52409-22-0］

1g

Listed products are intended for laboratory research use only, and not to be used for drug, food or human use. / Please visit our
online catalog to search for other products from Wako; http://labchem-wako.fujifilm.com/ This leaflet may contain products thatcannot be exported to your country due to regulations. / Bulk quote requests for some products are welcomed. Please contact us.

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