日本環境化学会

第 22 回

環境化学討論会

講演要旨集
22nd Symposium on Environmental Chemistry
Program and Abstracts
Faculty of Agriculture, Tokyo University of Agriculture and Technology, Fuchu, Tokyo.
July 31st, 2013 – Aug.2nd, 2013
Organized by Japan Society for Environmental Chemistry
Supported by Faculty of Agriculture, Tokyo University of Agriculture and Technology
Cooperated with SETAC Japan

主催

日本環境化学会

後援

東京農工大学農学部

協力

SETAC Japan日本環境化学会

第 22 回

環境化学討論会

講演要旨集
22nd Symposium on Environmental Chemistry
Program and Abstracts
Faculty of Agriculture, Tokyo University of Agriculture and Technology, Fuchu, Tokyo.
July 31st, 2013 – Aug.2nd, 2013
Organized by Japan Society for Environmental Chemistry
Supported by Faculty of Agriculture, Tokyo University of Agriculture and Technology
Cooperated with SETAC Japan

主 催：日本環境化学会
後 援：東京農工大学農学部
協 力：SETAC Japan㻣 ᭶ 㻟㻝 ᪥䠄Ỉ䠅㻌 㻝 ᪥┠㻌 㻝㻭 ఍ሙ䠄➨ 㻝 䝤䝻䝑䜽䠅㻌 䝉䝑䝅䝵䞁 㻞㻌 㻌 㻌 㻌 㻝㻟㻦㻞㻜ࠥ㻝㻠㻦㻟㻡㻌㻌㻌䝬䞊䜹䞊≀㉁㻌
ㅮ₇␒ྕ㻌㻝㻙㻝㻭㻙㻞㻙㻝㻌㻝㻙㻝㻭㻙㻞㻙㻞㻌₇㻌 㢟㻌Ⓨ⾲⪅䠄ᡤᒓ䠅㻌ἙᕝỈ୰་⸆ရ㢮䛾Ꮡᅾ≧ἣ䜢ᣦᶆ䛸䛧䛯ㅖእᅜ㒔䕿୰⏣㻌 ඾⚽ 㻝㻘㻌 ⰼᮏ㻌 ᚁஓ 㻝㻘㻌 ⏣୰㻌 ᏹ᫂ 㻝㻌 䠄㻝 ி㒔኱㝔䞉ᕷἙᕝὶᇦ䛾デ᩿ᡭἲ䛾᳨ウ㻌㻾㻯㻱㻽㻹䠅㻌ᆅୗỈ䜈䛾ୗỈ₃ฟホ౯ἲ䛾᳨ウ㻌 㻙Ỉ⁐ᛶ㞴ศゎ≀㉁䜢ᣦᶆ䛻䛧䛶㻙㻌䕿Ώ㎶㻌 ⿱ኴ 㻝㻘㻌 ᢡᘧ⏣㻌 ᓫோ 㻝㻘㻌 ୰⏣㻌 ᬕᙪ 㻝㻘㻌 ⣽㔝㻌 㧗ၨ 㻞㻘㻌 ฼㒊㻌 ៅ 㻝㻘㻌 ᑠ㔝㻌 ᫀᙪ 㻝㻘㻌 ᚨỌ㻌 ㈗኱㻝㻘㻌 ᔱ⏣㻌 ⣧ 㻝㻌 䠄㻝 ⇃ᮏ኱㝔䞉⮬↛㻘㻌㻞 ⇃ᮏ኱㝔䞉ඛᑟ䠅㻌䕿㧗⏣㻌 ⚽㔜㻝㻘㻌 ᑠụ㻌 㐩ஓ㻝㻘㻌㻭㼓㼥㼑㼙㼍㼚㻌㻿㼕㼍㼣㻝㻘㻌㻻㼒㼛㼟㼡㻙㻭㼚㼕㼙㻌㻶㼛㼔㼚㻞㻘㻌㻝㻙㻝㻭㻙㻞㻙㻟㻌㻿㻹㻭㻾㼀㻌㼃㻭㼀㻱㻾㻿䠖ୗỈ䝬䞊䜹䞊䜢⏝䛔䛯䜰䝣䝸䜹䛾㻿㼍㼎㼕㻌㻱㼐㼣㼍㼞㼐㻞㻘㻌㼃㼍㼟㼛㼚㼓㼍㻌㻻㼘㼕㼢㼑㼞㻟㻘㻌㻺㼑㼣㼙㼍㼚㻌㻮㼞㼑㼚㼠㻠㻘㻌㼃㼑㼑㼞㼠㼟㻌㻿㼠㼑㼢㼑㼚㻠㻌Ỉ⎔ቃởᰁ䛾ホ౯㻌䠄㻝 ᮾி㎰ᕤ኱㻘㻌㻞 䜺䞊䝘኱㻘㻌㻟 䝘䜲䝻䝡኱㻘㻌㻠 ༡䜰䝣䝸䜹ඹ࿴ᅜ⛉Ꮫ⏘ᴗ◊✲఍㆟䠅㻌䕿⇃⏣㻌 ⱥᓠ 㻝㻘㻌 㟷ᮌ㻌 ┿㔛 㻝㻘㻌 ዟ⏣㻌 ▱᫂ 㻞㻘㻌 ୰ᓥ㻌 ඾அ 㻟㻘㻌 㧗⏣㻌㻝㻙㻝㻭㻙㻞㻙㻠㻌䜰䝆䜰኱㒔ᕷ䛾኱Ẽ䜶䜰䝻䝌䝹୰ேⅭ㉳※Ỉ⣲໬䝺⚽㔜㻠㻘㻌 ␊ᒣ㻌 ྐ㑻㻠㻘㻌 ෆ⏣㻌 ᫀ⏨㻡㻘㻌 㟷ᮌ㻌 ඖ⚽㻝㻘㻌 ⸨ཎ㻌 ⚑ከኵ㻝㻌䝆䞁㓟⃰ᗘ䞉⤌ᡂ䛾ẚ㍑㻌

䠄㻝 ᮾி⸆⛉኱䞉⏕࿨㻘㻌㻞 ៞ᛂ⩏ሿ኱㻘㻌㻟 ᮾி኱㻘㻌㻠 ᮾி㎰ᕤ኱㻘㻌㻡ᅜ⎔◊䠅㻌䕿ఀ⸨㻌 ಙ㟹 㻝㻘㻌 ᆏୖ㻌 ఙ⏕ 㻞㻘㻌 㫽ᮧ㻌 ᨻᇶ 㻟㻘㻌 Ώ㑔㻌 ┾⣖Ꮚ 㻠㻌 䠄㻝㻝㻙㻝㻭㻙㻞㻙㻡㻌⍇⍈†ሁ✚≀୰䛾䝨䝸䝺䞁ྵ᭷᩿∦䛾≉ᚩ㻌⏘⥲◊䞉ィ ᶆ‽㻘㻌㻞 Ⲉᇛ኱䞉㎰㻘㻌㻟 ⏘⥲◊䞉⎔ቃ⟶⌮㻘㻌㻠 㤳㒔኱ᮾி䠅㻌㻣 ᭶ 㻟㻝 ᪥䠄Ỉ䠅㻌 㻝 ᪥┠㻌 㻝㻮 ఍ሙ䠄➨ 㻝 䝤䝻䝑䜽䠅㻌 䝉䝑䝅䝵䞁 㻞㻌 㻌 㻌 㻌 㻝㻟㻦㻞㻜ࠥ㻝㻠㻦㻟㻡㻌㻌㻌㔜㔠ᒓ䞉ᚤ㔞ඖ⣲㻌 䠄⏕యᙳ㡪䠅㻌䕿㜿ⲡ㻌 ဴ㑻㻝㻘㻌 ᖹᕝ㻌 ࿘స㻞㻘㻌 Ώ㑓㻌 Ἠ㻟㻘㻌 ụᮏ㻌 ᚨᏕ㻠㻘㻌 Ᏹ㧗㻌 ┿⾜ 㻡㻘㻌 㔠㻌 ᜠⱥ 㻢㻘㻌㻼㼑㼠㼞㼛㼢㻌㻱㼢㼓㼑㼚㼥㻣㻘㻌㻮㼍㼠㼛㼑㼢㻌㼂㼍㼘㼑㼞㼕㼥㻤㻘㻌 ⏣㎶㻌 ಙ௓ 㻝㻘㻌㻝㻙㻝㻮㻙㻞㻙㻝㻌䝞䜲䜹䝹䜰䝄䝷䝅䛾ᚤ㔞ඖ⣲⵳✚䛸䛭䛾ᛂ⟅㑇ఏᏊᒾ⏣㻌 ஂே 㻝㻌 䠄㻝 ឡ፾኱䞉ἢ⎔◊䝉㻘㻌㻞 ⚟ᒸ┴ಖ⎔◊㻘㻌㻟 ᮾி㎰ᕤ䛾᥈⣴㻌኱㻘㻌㻠 䝃䞊䝰䝣䜱䝑䝅䝱䞊䝃䜲䜶䞁䝔䜱䝣䜱䝑䜽㻘㻌㻡 ឡ፾┴ཎᏊຊ䝉㻘㻌㻢㻷㼥㼡㼚㼓㻌㻴㼑㼑㻌㼁㼚㼕㼢㻌㻘㻌㻣㻱㼍㼟㼠㼑㼞㼚㻙㻿㼕㼎㼑㼞㼕㼍㼚㻌㻿㼏㼕㻌㻼㼞㼛㼐㻌㻲㼕㼟㼔㻌㻯㼠㼞㻘㻌㻤㻮㼍㼕㼗㼍㼘㻌㻵㼚㼟㼠㻌㻺㼍㼠㻌㻹㼍㼚㼍㼓㼑㻌㻿㻮㻌㻾㻭㻿䠅㻌㻝㻙㻝㻮㻙㻞㻙㻞㻌㻝㻙㻝㻮㻙㻞㻙㻟㻌㻝㻙㻝㻮㻙㻞㻙㻠㻌㻝㻙㻝㻮㻙㻞㻙㻡㻌䜺䞊䝘䛾㔠㖔ᒣ࿘㎶䠄䜸䝤䜰䝅⮬἞༊䠅䛻䛚䛡䜛䝠⣲ởᰁ䛸㝣⏕့ங㢮䜈䛾ẘᛶᙳ㡪ホ౯㻌Ỉ㖟䛚䜘䜃䝉䝺䞁໬ྜ≀䛾ῐỈ⏘⏕≀䛻ᑐ䛩䜛ẘᛶ䕿኱㇂㻌 ㇦ 㻝㻌 䠄㻝 ໭ᾏ㐨኱䞉⋇་䠅㻌䕿すᮧ㻌 ᙬ 㻝㻘㻌 ༡㻌 ᭷⣖㻘㻌 ୰ᓥ㻌 ᖖ᠇ 㻝㻘㻌 㧗᲍㻌 ၨ࿴ 㻝㻘㻌 ኱ᮌ㻌 ❶ 㻝㻌䠄㻝 㮵ඣᓥ኱㝔䞉⌮ᕤ䠅㻌䝉䝺䞁⵳✚ᛶ᳜≀䛻䛚䛡䜛᭷ᶵ䝉䝺䞁໬ྜ≀䛾⵳✚䕿Ⲷཎ㻌 ཭㔛⤮㻝㻘㻌 ᚫᮏ㻌 ┿⣖㻝㻘㻌 㜿༡㻌 ᘺᑑ⨾㻝㻘㻌 ᑠ᳚㻌 ᗣග㻝㻌 䠄㻝ཬ䜃௦ㅰᶵᵓ䛾ゎᯒ㻌᫛࿴⸆⛉኱䠅㻌䝉䝺䞁⵳✚ᛶ᳜≀䛻䛚䛡䜛↓ᶵ䝔䝹䝹௦ㅰᶵᵓ䛾ゎ䕿ྜྷ⏣㻌 ⨾㞷 㻝㻘㻌 㜿༡㻌 ᘺᑑ⨾ 㻝㻘㻌 㛗㇂ᕝ㻌 ᪩႐ 㻝㻘㻌 ᚫᮏ㻌 ┿⣖ 㻝㻘㻌᫂㻌ᑠ᳚㻌 ᗣග 㻝㻌 䠄㻝 ᫛࿴⸆⛉኱䠅㻌㻶㼡㼘㼥㻌㻟㻝㻌㻔㼃㼑㼐㻕㻌㻝㼟㼠㻌㼐㼍㼥㻦㻌 㻌 㻾㼛㼛㼙㻌㻝㻯㻌 㻌 㻿㼑㼟㼟㼕㼛㼚㻙㻞㻌 㻌 㻌 㻝㻟㻦㻞㻜ࠥ㻝㻠㻦㻠㻜㻌 㻌 㻌 㻌 㻌㻌㻌

English session㻌㻼㻼㻯㻼㼟㻌㼑㼠㼏㻌㻳㻯㻙㻹㻿㻌㻰㼑㼠㼑㼞㼙㼕㼚㼍㼠㼕㼛㼚㻌㼍㼚㼐㻌㻾㼕㼟㼗㼟㻌㻱㼢㼍㼘㼡㼍㼠㼕㼛㼚㻌㼛㼒㻌㻝㻙㻝㻯㻙㻞㻙㻝㻌 㻼㼔㼍㼞㼙㼍㼏㼑㼡㼠㼕㼏㼍㼘㼟㻌㼍㼚㼐㻌㻼㼑㼞㼟㼛㼚㼍㼘㻌㻯㼍㼞㼑㻌㻼㼞㼛㼐㼡㼏㼠㼟㻌㻔㻼㻼㻯㻼㼟㻕㻘㻌㼍㼚㼐㻌㻼㼔㼑㼚㼛㼘㼕㼏㻌㻯㼛㼙㼜㼛㼡㼚㼐㼟㻌㼕㼚㻌㻾㼕㼢㼑㼞㼟㻌㼒㼞㼛㼙㻌㻵㼚㼐㼕㼍㻌 㻌㻻㼏㼏㼡㼞㼞㼑㼚㼏㼑㻌㼍㼚㼐㻌㻹㼍㼟㼟㻌㻲㼘㼛㼣㼟㻌㼛㼒㻌㻲㼘㼡㼛㼞㼛㼠㼑㼘㼛㼙㼑㼞㻌㻭㼘㼏㼛㼔㼛㼘㼟㻌㻝㻙㻝㻯㻙㻞㻙㻞㻌 㼕㼚㻌㻹㼡㼚㼕㼏㼕㼜㼍㼘㻌㻿㼑㼣㼍㼓㼑㻌㼀㼞㼑㼍㼠㼙㼑㼚㼠㻌㻼㼘㼍㼚㼠㼟㻦㻌㻯㼛㼙㼜㼍㼞㼕㼟㼛㼚㻌㼠㼛㻌㻼㼑㼞㼒㼘㼡㼛㼞㼕㼚㼍㼠㼑㼐㻌㻯㼍㼞㼎㼛㼤㼥㼘㼕㼏㻌㻭㼏㼕㼐㼟㻌32䕿㻾㼍㼙㼍㼟㼣㼍㼙㼥㻌㻮㼍㼎㼡㻾㼍㼖㼑㼚㼐㼞㼍㼚㻝㻘㻌㻿㼔㼍㼚㼙㼡㼓㼍㼙㻌㻳㼛㼢㼕㼚㼐㼍㼞㼍㼖㻌㻝㻘㻌㻿㼑㼘㼢㼍㼞㼍㼖㻌㻷㼞㼕㼟㼔㼚㼍㼗㼡㼙㼍㼞㻌㻝㻘㻌㻿㼍㼙㼜㼍㼠㼔㻌㻿㼞㼕㼙㼡㼞㼍㼘㼕㻌㻝㻌 䠄㻝㻮㼔㼍㼞㼍㼠㼔㼕㼐㼍㼟㼍㼚㻌㼁㼚㼕㼢䠅㻌䕿㻴㼁㻌㻶㼕㼍㼚㼥㼕㼚㼓㻝㻘㻌㻼㻱㻺㻳㻌 㻌 㻴㼡㼕㻌㻝㻌 䠄㻝㻯㼛㼘㼘㻌㼁㼞㼎㼍㼚㻌㻒㻌㻱㼚㼢㼕㼞㼛㼚㻌㻿㼏㼕㻘㻌㻼㼑㼗㼕㼚㼓㻌㼁㼚㼕㼢䠅㻌䕿㼂㼘㼍㼐㼕㼙㼕㼞㻌㻼㻚㻌㻮㼑㼟㼗㼛㼟㼗㼕㻝㻘㻞㻘㻌㻿㼔㼡㼟㼡㼗㼑㻌 㻌 㼀㼍㼗㼑㼙㼕㼚㼑㻟㻘㻌㼀㼍㼗㼑㼟㼔㼕㻌 㻌㻺㼍㼗㼍㼚㼛㻠㻘㻌㻸㼍㼠㼕㼚㼗㼍㻌㻿㼘㼍㼢㼗㼛㼢㼕㼏㻌 㻌 㻮㼑㼟㼗㼛㼟㼗㼕㻡㻘㻌㻹㼍㼕㼖㼍㻙㻸㼕㼟㼍㻌 㻌 㻹㼍㼠㼠㼕㼚㼑㼚㻢㻘㻌㻝㻙㻝㻯㻙㻞㻙㻟㻌㻼㼛㼘㼘㼡㼠㼕㼛㼚㻌㼃㼕㼠㼔㼛㼡㼠㻌㻮㼛㼡㼚㼐㼍㼞㼕㼑㼟㻦㻌㻾㼕㼢㼑㼞㻌㻰㼍㼚㼡㼎㼑㻘㻌㻿㼑㼞㼎㼕㼍㻘㻌㻱㼡㼞㼛㼜㼑㻌㻳㼛㼞㼐㼍㼚㼍㻌 㻌 㻳㼛㼖㼓㼕㼏㻙㻯㼢㼕㼖㼛㼢㼕㼏㻞㻘㻌㻹㼕㼞㼛㼟㼘㼍㼢㻌㻹㻚㻌㼂㼞㼢㼕㼏㻝㻘㻞㻌 䠄㻝㻲㼍㼏㼡㼘㻌㻯㼔㼑㼙㻘㻌㼁㼚㼕㼢㻌㻮㼑㼘㼓㼞㼍㼐㼑㻘㻌㻿㼑㼞㼎㼕㼍㻘㻌㻞㻵㼚㼟㼠㻌㻯㼔㼑㼙㻘㻌㼀㼑㼏㼔㼚㼛㼘㻌㻒㻌㻹㼑㼠㼍㼘㼘㻘㻌㼁㼚㼕㼢㻌㻮㼑㼘㼓㼞㼍㼐㼑㻘㻌㻿㼑㼞㼎㼕㼍㻘㻌㻟㻴㼥㼛㼓㼛㻌㻼㼞㼑㼒㻌㻵㼚㼟㼠㻌㻱㼚㼢㼕㼞㼛㼚㻌㻿㼏㼕㻘㻌㻠㻯㼠㼞㻌㻭㼐㼢㻌㻿㼏㼕㻌㻒㻌㻵㼚㼚㼛㼢㼍㼠㼕㼛㼚㻘㻌㻻㼟㼍㼗㼍㻌㼁㼚㼕㼢㻘㻌㻡㻵㼚㼟㼠㻌㻺㼡㼏㼘㻌㻿㼏㼕㻌 䇾㼂㼕㼚㼏㼍䇿㻘㻌㼁㼚㼕㼢㻌㻮㼑㼘㼓㼞㼍㼐㼑㻘㻌㻿㼑㼞㼎㼕㼍㻘㻌㻢㼂㼀㼀㻌㻮㼕㼛㼜㼞㼛㼏㼑㼟㼟㼕㼚㼓㻘㻌㻱㼟㼜㼛㼛㻘㻌㻲㼕㼚㼘㼍㼚㼐䠅㻌㻝㻙㻝㻯㻙㻞㻙㻠㻌㻵㼚㼠㼑㼞㼍㼏㼠㼕㼢㼑㻌㻵㼚㼠㼑㼞㼚㼍㼠㼕㼛㼚㼍㼘㻌㻼㼑㼘㼘㼑㼠㻌㼃㼍㼠㼏㼔㻦㻌㻵㼚㼠㼑㼓㼞㼍㼠㼕㼚㼓㻌㻼㻻㻼㼟㻌㼙㼛㼚㼕㼠㼛㼞㼕㼚㼓㻌㼍㼚㼐㻌㻾㼕㼟㼗㻌㻯㼛㼙㼙㼡㼚㼕㼏㼍㼠㼕㼛㼚㻌䕿㼅㼑㼛㻌㻮㼑㼑㻌㻳㼑㼛㼗㻝㻘㻌㼀㼍㼗㼍㼐㼍㻌㻴㼕㼐㼑㼟㼔㼕㼓㼑㻝㻘㻌㼀㼍㼥㼘㼛㼞㻌㻴㼑㼕㼐㼕㻘㻌㻵㼠㼛㻌㻹㼍㼗㼕㻘㻌㻴㼛㼟㼛㼐㼍㻌㻶㼡㼚㼗㼕㻘㻌㻿㼙㼕㼠㼔㻌㼃㼍㼘㼘㼥㻌 䠄㻝㼀㼛㼗㼥㼛㻌㼁㼚㼕㼢㻌㻭㼓㼞㼕㻌㻒㻌㼀㼑㼏㼔㼚㼛㼘㻘㻌㻞㼀㼍㼚㼓㼍㼞㼛㼍㻌㻮㼘㼡㼑㻌㻲㼛㼡㼚㼐䠅㻌㻣 ᭶ 㻟㻝 ᪥䠄Ỉ䠅㻌 㻝 ᪥┠㻌 㻞㻰 ఍ሙ䠄➨ 㻞 䝤䝻䝑䜽䠅㻌 䝉䝑䝅䝵䞁 㻞㻌 㻌 㻌 㻌 㻝㻟㻦㻞㻜ࠥ㻝㻠㻦㻞㻜㻌㻌㻌㻼㻯㻮㼟䞉㻼㻻㻼㼟㻌 䠄ศᯒἲ 㻞䠅㻌㻝㻙㻞㻰㻙㻞㻙㻝㻌㻝㻙㻞㻰㻙㻞㻙㻞㻌㻝㻙㻞㻰㻙㻞㻙㻟㻌᭷ᶵ㢦ᩱ୰ 㻼㻯㻮 ศᯒ䜈䛾⤯⦕Ἔ୰䛾 㻼㻯㻮 ⡆᫆ᐃ㔞ἲ䛾㐺⏝㻌ప⃰ᗘ 㻼㻯㻮 ྵ᭷ᗫᲠ≀䛻㛵䛩䜛 ᐃ᪉ἲ䠄➨ 㻝 ∧䠅䛾ศᯒ౛㻌ప⃰ᗘ 㻼㻯㻮 ᗫᲠ≀䛾㎿㏿ฎ⌮䜢ᐇ⌧䛩䜛䝣䝻䞊ᘧ䜲䝮䝜䝉䞁䝃䜢⏝䛔䛯┤᥋ᕼ㔘 ᐃἲ㻌㻝㻙㻞㻰㻙㻞㻙㻠㻌 㻳㻯㻛㻹㻿㻔㻺㻵㻯㻵㻕䛻䜘䜛᭷ᶵ㢦ᩱ୰ 㻼㻯㻮 䛾⡆᫆ᐃ㔞ἲ㻌䕿㧗ᶫ㻌 ▱ྐ 㻝㻌 䠄㻝 ୕ᾆᕤᴗ䠅㻌䕿㧗ᶫ㻌 ▱ྐ 㻝㻌 䠄㻝 ୕ᾆᕤᴗ䠅㻌䕿❧▼㻌 ඾⏕ 㻝㻘㻌 ኱ᓥ㻌 㔜ಙ 㻝㻘㻌 㧗ᮌ㻌 㝧Ꮚ 㻝㻌 䠄㻝 ி㒔㟁Ꮚᕤᴗ䠅㻌䕿బ⸨㻌 ᬛ⾜㻝㻘㻌 ໭ཎ㻌 ♸㍜㻝㻘㻌 ⥙⏣㻌 ┿୍㑻㻝㻘㻌 ᑠᯘ㻌 ཌ㻝㻘㻌 ᳃㻌 ṇ༤ 㻝㻘㻌 బ⸨㻌 ಙಇ 㻝㻘㻌 㕥ᮌ㻌 ⁠ 㻝㻘㻌 ᯇ㻌 ᏹ 㻝㻌 䠄㻝 ᮾ໭⥳໬⎔ቃಖ඲䠅㻣 ᭶ 㻟㻝 ᪥䠄Ỉ䠅㻌 㻝 ᪥┠㻌 㻞䠡఍ሙ䠄➨ 㻞 䝤䝻䝑䜽䠅㻌 䝉䝑䝅䝵䞁 㻞㻌 㻌 㻌 㻌 㻝㻟㻦㻞㻜ࠥ㻝㻠㻦㻟㻡㻌㻌㻌⮯⣲⣔㞴⇞๣㻌 䠄ศᯒἲ䛭䛾௚䠅㻌㻝㻙㻞㻱㻙㻞㻙㻝㻌㻝㻙㻞㻱㻙㻞㻙㻞㻌⮯⣲⣔㞴⇞๣䛾≀ᛶ᥎⟬䛸ṧ␃ᛶ䛚䜘䜃㛗㊥㞳⛣ື䕿಴ᣢ㻌 ⚽ᩄ 㻝㻘㻌 ⁪ୖ㻌 ⱥᏕ 㻝㻘㻌㻿㼏㼔㼑㼞㼕㼚㼓㼑㼞㻌㻹㼍㼞㼠㼕㼚㻞㻘㻌 㓇஭㻌 ఙ୍ 㻟㻌ᛶ䛾ホ౯㻌䠄㻝 ᅜ⎔◊㻘㻌㻞 䝇䜲䝇㐃㑥ᕤ⛉኱㻘㻌㻟 ி㒔኱䠅㻌䝫䝸䝇䝏䝺䞁䝣䜷䞊䝮ᗫᲠ≀䛻ྵ᭷䛥䜜䜛㞴⇞๣䝦䜻䝃䝤䝻䝰䝅䜽䝻䝗䝕䜹䞁䛾⇞↝ศゎᣲື䛻䛴䛔䛶㻌㻝㻙㻞㻱㻙㻞㻙㻟㻌㉸㡢Ἴ↷ᑕ䛻䜘䜛⮯⣲⣔㞴⇞๣ 㻴㻮㻯㻰 䛾ศゎ㻌㻝㻙㻞㻱㻙㻞㻙㻠㻌㻸㻯㻙㼀㻻㻲㻹㻿 䛻䜘䜛 㻴㻮㻯㻰 䛸䛭䛾㛵㐃໬ྜ≀䛾ྠᐃ㻌㻝㻙㻞㻱㻙㻞㻙㻡㻌㻸㻯㻛㻹㻿㻛㻹㻿 䛻䜘䜛⮯⣲⣔㞴⇞๣䛾ศᯒἲ䛸ㄪᰝ㻌䕿⁪ୖ㻌 ⱥᏕ 㻝㻘㻌 Ώ㒊㻌 ┿ᩥ㻘㻌 Ლཎ㻌 ኟᏊ㻌 䠄㻝 ᅜ⎔◊䞉㈨※ᚠ⎔䠅㻌䕿Ḉ஭㻌 ᫂ᙪ 㻝㻘㻌 Ἑ㔝㻌 ᑗ኱ 㻝㻘㻌 ྔ㻌 ጾ 㻝㻌 䠄㻝 ⚟஭኱㝔䞉ᕤ䠅㻌䕿┿ྡᇉ㻌 ⪽ 㻝㻘㻌 ࿋㻌 ṇ᰿ 㻞㻘㻌 ┈Ọ㻌 ⱱᶞ 㻞㻘㻌 బ⸨㻌 ಙṊ 㻟㻌 䠄㻝 Ṋⶶ㔝኱㻘㻌㻞 ᶓ὾ᅜ኱㻘㻌㻟 ᪥ᮏ䜴䜷䞊䝍䞊䝈䠅㻌䕿኱ୖ㻌 ᱁ 㻝㻘㻌 㕥ᮌ㻌 ⱱ 㻝㻌 䠄㻝 ୰㒊኱㝔䞉ᛂ⏝⏕≀䠅㻌㻣 ᭶ 㻟㻝 ᪥䠄Ỉ䠅㻌 㻝 ᪥┠㻌 㻝㻭 ఍ሙ䠄➨ 㻝 䝤䝻䝑䜽䠅㻌 䝉䝑䝅䝵䞁 㻟㻌 㻌 㻌 㻌 㻝㻠㻦㻠㻡ࠥ㻝㻢㻦㻝㻡㻌㻌㻌ί໬䞉ฎ⌮ᢏ⾡㻌ㅮ₇␒ྕ㻌㻝㻙㻝㻭㻙㻟㻙㻝㻌₇㻌 㢟㻌Ⓨ⾲⪅䠄ᡤᒓ䠅㻌

㕲㈨ᮦ䜢⏝䛔䛯䝕䜱䝹䝗䝸䞁ศゎ䛻䛚䛡䜛ศゎ⏕ᡂ≀䕿ୖ⏣㻌 ♸Ꮚ 㻝㻘㻌 ᴬཎ㻌 㢼ኴ 㻞㻘㻌 Ύ⏣㻌 ὒṇ 㻟㻘㻌 㛗ᓥ㻌 ඃኴ 㻟㻘㻌 㧘ᮌ㻌䛾ྠᐃ㻌࿴ᗈ 㻞㻘㻌 ᮏ⏣㻌 ඞஂ 㻝㻌 䠄㻝 ឡ፾኱䞉㎰㻘㻌㻞 ㎰⎔◊㻘㻌㻟 ᮾ໭኱㝔䞉㎰䠅㻌䕿ᐑ⬥㻌 ࿴༤㻝㻘㻌 ⚟⏣㻌 Ὀᩍ㻝㻘㻟㻘㻌 ຍ⸨㻌 ᰤ୍㻝㻘㻟㻘㻌 㓇஭㻌 ๛㻞㻘㻌 ๓ᕝ㻌㻝㻙㻝㻭㻙㻟㻙㻞㻌㻼㻯㻮 ởᰁኚᅽჾὙί๣䛾᪂つ䝸䝃䜲䜽䝹ᢏ⾡䛾㛤Ⓨோ▱ 㻞㻘㻌 ᮌ⏣㻌 ᩄஅ 㻟㻘㻌 ୰㔝㻌 Ṋ 㻟㻘㻌 ᫂▼㻌 ‶ 㻟㻌 䠄㻝 䝛䜸䝇୰ኸ◊㻘㻌㻞ᮾி㟁ຊ㻘㻌㻟 ኱㜰኱㝔䞉ᕤ䠅㻌㻝㻙㻝㻭㻙㻟㻙㻟㻌㻝㻙㻝㻭㻙㻟㻙㻠㻌䜰䝭䝜໬䝣䝷䞊䝺䞁䝇䞊䝖䜢⏝䛔䛯භ౯䜽䝻䝮䛾྾╔㝖ཤ㻌㓟໬䝏䝍䞁䜢ᢸᣢ䛧䛯▼ⱥ⧄⥔〇䝣䜱䝹䝍䞊䛻䜘䜛኱Ẽ䜶䜰䝻䝌䝹⢏Ꮚ䛾↓ẘ໬㻌䕿୰ᕝ㻌 ㈗⿱ 㻝㻌 䠄㻝 ಙᕞ኱㝔䞉⌮ᕤ䠅㻌䕿ᮏᶫ㻌 ୍┿ 㻝㻘㻌 㛵᰿㻌 Ⴙ᫭ 㻝㻘㻌 ụ⏣㻌 ᅄ㑻 㻞㻘㻌 䝜䝅䝱䜲䝲㻌 䝍䝜䞁䝃㻟㻘㻌 㛵᰿㻌 ჆㤶 㻝㻌 䠄㻝 ᮾᾏ኱㝔䞉⌮㻘㻌㻞 ᮾᾏ኱㝔䞉ᆅ⌫⎔ቃ㻘㻌㻟㻺㼍㼞㼑㼟㼡㼍㼚㻌㼁㼚㼕㼢䠅㻌33㪉㪉㫅㪻㩷 㪪㫐㫄㫇㫆㫊㫀㫌㫄㩷 㫆㫅㩷 㪜㫅㫍㫀㫉㫆㫅㫄㪼㫅㫋㪸㫃㩷 㪚㪿㪼㫄㫀㫊㫋㫉㫐㪃㩷 㪭㫃㪸㪻㫀㫄㫀㫉㩷 㪧㪅㩷 㪙㪼㫊㫂㫆㫊㫂㫀㪃㩷 㪦㫉㪸㫃㩷 㪧㫉㪼㫊㪼㫅㫋㪸㫋㫀㫆㫅㩷 䋨㪫㫆㫂㫐㫆䋻䋩㩷㪈㪄㪈㪚㪄㪉㪄㪊㩷
Pollution Without Boundaries: River Danube, Serbia, Europe
9ODGLPLU 3 %HãNRVNL1,2, Shusuke Takemine3, Takeshi Nakano4 /DWLQND 6ODYNRYLü %HãNRVNL5,Maija-Lisa Mattinen6, *RUGDQD*RMJLü-&YLMRYLü20LURVODY09UYLü1,2
㧔1Faculty of Chemistry, University of Belgrade, Serbia㧘2 Institute of Chemistry, Technologyand Metallurgy, University of Belgrade, Serbia, 3Hyogo Prefectural Institute of Environmental
Sciences, Japan, 4Center for Advanced Science and Innovation, Osaka University, Japan,Institute oI 1XFOHDU 6FLHQFHV ³9LQþD´ 8QLYHUVLW\ RI %HOJUDGH, Serbia, 6VTT Bioprocessing,

5Espoo, Finland㧕Introduction
Rivers in Southeast European country Serbia belong to the basins of the Black, Adriatic and Aegean Seas.
The Black Sea drainage basin covers the area which occupies 92% of the territory of Serbia. The entire basin isdrained only by the Danube River which flows into the Black Sea. The section of the Danube that flows throughSerbia is 588 km long, out of the total of 2,872 km going through several European countries.
The main problems in Southeast Europe today are: the fact that municipal and industrial wastewater is often
discharged into waterways without treatment; that a small number of plants for the treatment of industrial andmunicipal wastewater is built but not all of the existing facilities are in working order; and finally that disposal ofwaste in illegal dumps that are located near waterways is an obvious source of environmental pollution.
In the recent history some transboundary pollutions occurred such as a cyanide spill into the 6RPHú5LYHU inBaia Mare, Romania in January 2000 caused by a gold mining company when about 100,000 m3 of liquidcontaining 50-100 tonnes of cyanide, travelled into the river Danube before reaching the Black Sea [1]. Anotheris an Ajka alumina sludge spill in Western Hungary in October 2010 when about 700,000 m3 of the red mud witha pH of about 12, that contains several toxic trace metals was released accidentally from the reservoir [2].
Because of biogeochemical activity of microorganisms in the zones of sulphide copper ores in the Eastern Serbia,
Danube receives around 31 t of copper and 0.6 t of arsenic per annum from one place alone [3].
In Serbia, until recently there was no data about presence of perfluorinated compounds (PFCs) in theenvironment. We have analyzed PFCs in the sediment from wastewater canal (WWC) draining the industrial
complex of Panþevo, (oil refinery, petrochemical plant, and fertilizer factory). WWC is artificial with no naturalflows, about 2 km long, 70 m wide, water depth around 1±2 m and directly connected to the Danube River.
Materials and Methods
In total, 4 sediment samples from WWC were collected from the canal and for comparative purposes one
from navigation canal flowing parallel to WWC but not receiving any direct discharge of industrial wastewaters.
Sampling sites were: 1 ± navigation canal; 2 ± the confluence of the WWC with the Danube Riverdownstream from the industrial area and effluents; 3 ± downstream from the fertilizer factory outlet (first); 4 ±downstream from the petrochemical plant (second); 5 ± downstream from the oil refinery outlet (third effluent).
Sediment sample was extracted with methanol. MPFAC-MXA as mass-labeled surrogates was spiked into thesample. The sample was extracted with SPE. The elution was concentrated and labeled 13C8PFOA was added as
Title of presentation:

Pollution Without Boundaries: River Danube, Serbia, EuropeSpeaker¶s lists: 9ODGLPLU3%HãNRVNL
Correspondence (address and email): Faculty of Chemistry, University of Belgrade, 11158 Belgrade, Studentski
trg 16, P.O. Box 51, Serbia; vbeskoski@chem.bg.ac.rs238

㪉㪉㫅㪻㩷 㪪㫐㫄㫇㫆㫊㫀㫌㫄㩷 㫆㫅㩷 㪜㫅㫍㫀㫉㫆㫅㫄㪼㫅㫋㪸㫃㩷 㪚㪿㪼㫄㫀㫊㫋㫉㫐㪃㩷 㪭㫃㪸㪻㫀㫄㫀㫉㩷 㪧㪅㩷 㪙㪼㫊㫂㫆㫊㫂㫀㪃㩷 㪦㫉㪸㫃㩷 㪧㫉㪼㫊㪼㫅㫋㪸㫋㫀㫆㫅㩷 䋨㪫㫆㫂㫐㫆䋻䋩㩷syringe spike. The each final solution was analyzed by liquid chromatography (LC)-tandem mass spectrometer(MS/MS) using Xevo TQ (Waters) coupled with ACQUITY UPLC (Waters). For MALDI-TOF-MS analysis,Autoflex II Bruker Daltonics, software flexControl, flexAnalysis and Maldi biotyper were used.
Results and Discussion
Concentrations of PFCs were determined and presented in Table 1 [4].
Table 1. PFCs content in the sediment samples from WWCV (%)
Sample

PFOA

PFHxA

PFHxS

PFOSPFDSȈ3)& QJNJ-1 dw)

112-

3949-

588

24--

96-

2180

3-

-

3

97-

5470

423-

90

56290

5

1312-

75-

562

3-1

When the entire factory is in operation, the discharge is about 6,000 m h of wastewater. The total volume ofwater in the canal at the time of sampling was estimated to be around 32,000 m3 and retention time in the canal is6-9 h. A mass load of 1.38 kg PFOS per year discharged in the Danube River has been calculated, which
undoubtedly points to the contribution to global pollution of Danube waters. The origin of PFCs might be theirusage as components in pipes, fittings, wiring insulations and from firefighting foams.
Hydrocarbon degrading microorganisms isolated from WWC were identified based on the 16S rRNA gene
analysis and furthermore analyzed using whole cell MALDI TOF-MS analysis. Isolated microorganisms belong
to the genera Brachybacterium sp., Rhodococcus sp., Planomicrobium sp., Micrococcus sp., Planococcus sp.,
Pseudomonas sp., and Bacillus sp. The results confirmed presence of different groups of microorganisms whereeach spectrum represents a fingerprint of individual microorganism (Figure 1).

x10 4[a.u.]
Intens.
4

3

2

10







2000



3000



4000



5000



6000



7000



8000



9000



10000





m/z

Figure 1. MALDI-TOF-MS spectra of intact bacterial cells isolated from Panþevo WWC
Since polychlorinated compounds [5] and some fluoro carbon compounds [6] are biodegradable it can beassumed that PFCs are also biodegradable. High microbial biodiversity in PFCs polluted samples indicates andsupport this assumption. Our future research will focus on (bio)transformation and (bio)degradation of thesechemicals known as persistent and recalcitrant. This is very important since these pollutants are ubiquitous in theDanube River Basin, having strong influence on the environment and travel disregarding human borders.
References[1] http://archive.rec.org/REC/Publications/CyanideSpill/ENGCyanide.pdf.
[2] http://pubs.acs.org/doi/abs/10.1021/es104000m.
[3] http://www.scientific.net/AMR.71-73.105.
[4] V.P. BeãNRVNLHWDO, Chemosphere 91 (2013) 1408±1415.
[5] I. Twardowska et al. (eds.), Soil and Water Pollution Monitoring, Springer, (2006) 3±23, pp. 505-521.
[6] R.Natarajan, et al., J. Fluorine Chem. 126 (2005) 425±436.

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ᮾி㒔ከᦶᕷⴠྜ 2-6-1826᪥༳ๅ᪥Ⓨ⾜International Session in the 22nd Symposium on Environmental Chemistry, Tokyo 2013, JapanPOLLUTION WITHOUT BOUNDARIES: RIVER
DANUBE, SERBIA, EUROPE
Vladimir P. Beškoski1,2, Shusuke Takemine3, Takeshi Nakano4, Latinka
Slavković Beškoski5, Maija-Lisa Mattinen6, Gordana Gojgić-Cvijović2, Miroslav
M. Vrvić1,2

1Faculty of Chemistry, University of Belgrade, Serbia，
2 Institute of Chemistry, Technology and Metallurgy, University of Belgrade, Serbia,
3Hyogo Prefectural Institute of Environmental Sciences, Japan,
4Center for Advanced Science and Innovation, Osaka University, Japan,
5Institute of Nuclear Sciences “Vinča”, University of Belgrade, Serbia,
6VTT Bioprocessing, Espoo, FinlandTokyo, July 31, 2013

Tokyo University of Agriculture and Technology
2-24-16, Nakamachi, Koganei, Tokyo 184-8588, Japan

TEL/FAX 042-388-7276 Email: yhashim@cc.tuat.ac.jp

July 1, 2013
Dear Dr. Beškoski
I’m glad to inform that your application entitled “Pollution Without Boundaries: River Danube,Serbia, Europe” has been selected as the invited presentation to which financial support foryour travel will be given. As announced earlier on the website, the financial support (up to100,000 JPY) will cover air tickets, registration (10,000 JPY), accommodation (~8,000 JPYper night) and local trip fees. The financial support will cover the cost you required during theday before the conference (July 30) through August 2, depending on your travel schedule.
Please start to plan your travel to the conference in Fuchu-city, Tokyo, Japan. You willpurchase the air tickets by yourself. We will refund the cost for the air ticket on theconference. Please keep the receipt, flight itinerary, and boarding pass and submit them tous when you request the reimbursement. The international session will be held between July
31 and August 2 in Fuchu, Tokyo. Between Fuchu and Narita international Airport, it takes
about 2 hours by local train and bus. The organizing committee will arrange youraccommodation with a reasonable price near the conference place. We will book theaccommodation for you. In any way, we will contact with you via e-mail regarding logistics
and the official abstract.
We are looking forward to seeing you and your talk at the conference. If you have anyquestions and requests, please do not hesitate to contact us via e-mail at
jecint13@cc.tuat.ac.jp.
Best regards,

Yohey Hashimoto, Ph.D.
Organizing committee of the International Session inthe 22nd Symposium on Environmental Chemistry.
E-mail : jecint13@cc.tuat.ac.jp