th19 International
Mass Spectrometry
Conference

PROGRAMME

Kyoto International Conference Center
Saturday 15th September ‒ Friday 21st September 2012

19th IMSC
Thursday, 20th September
PTh-162
13:30 − 14:40

ThuAnalysis of perfluorinated compounds insediment samples from wastewater
canal of Pancevo industrial area, Serbia

PTh-167
11:10 − 12:20

Urinary oxidative metabolites of di(2ethylhexyl)phthalate can predict thedaily intake of phthalate-tainted foodsin Taiwanese children

Vladimir P Beskoski1, Shuusuke Takemine2, Takeshi Nakano3,Latinka Slavkovic-Beskoski4, Gordana Gojgic-Cvijovic1, Mila Ilic1,Srdjan Miletic1, Miroslav M Vrvic1,5I-Chen Wu1, Chia-Fang Wu2, Jentaie Shiea3, Bai-Hsiun Chen4,Jiunn-Ren Wu5, Ming-Tsang Wu*2,6,71

1

Institute of Chemistry, Technology and Metallurgy, University of Belgrade,
Serbia, 2Hyogo Prefectural Institute of Environmental Science, Kobe, Japan,
3
Center for Advanced Science and Innovation, Osaka University, Japan,
4
Institute of Nuclear Sciences, 5Faculty of Chemistry, University of Belgrade,
SerbiaPTh-163
11:10 − 12:20

Division of Gastroenterology, Department of Internal Medicine, Kaohsiung
Medical University Hospital, Kaohsiung, Taiwan, 2Department of PublicHealth, Kaohsiung Medical University, Kaohsiung, Taiwan, 3Department ofChemistry, National Sun Yat-Sen University, Kaohsiung, Taiwan, 4Departmentof Laboratory Medicine, Kaohsiung Medical University Hospital, Kaohsiung
Medical University, Kaohsiung, Taiwan, 5Department of Pediatrics, Kaohsiung
Medical University Hospital, Kaohsiung Medical University, Kaohsiung,Taiwan, 6Department of Family Medicine, Kaohsiung Medical University
Hospital, Kaohsiung, Taiwan, 7Center of Environmental and OccupationalMedicine, Kaohsiung Municipal Hsiao-Kang Hospital, Kaohsiung, Taiwan

Study of On-site sampling method for
Dioxin in water with high concentrationsof suspended solids.

Takeshi Enomoto1, Miho Okimoto1, Chuanpit Boonyoy2,Areerat Jaksakul2, Ruchaya Boonyatumanond2,
Genta Takahashi5, Kenji Tawara5, Tohru Matsumura3,
Takeshi Nakano4

PTh-168
13:30 − 14:40

1JEOL Ltd.,Tokyo,Japan, 2ERTC,Pathumthani,Thailand, 3IDEA Consultant
Inc.,Shizuoka,Japan, 4Osaka University, Osaka, Japan, 5Hyogo Environmental
Advancement Association,Kobe,Japan

PTh-164
13:30 − 14:40

Toshio Miwa1, Isao Saito1, Atsushi Yamamoto1,Yoshinori Inoue2, Mitsuru Saito2Multi-residue analysis of pesticides inanimal and fishery products, and theirprocessed foods by dual-column GCMS/MS

1

11:10 − 12:20

Jeonnam Provincial Office, National Agricultural Products Quality
Management Service, MIFAFF, Korea

PTh-170

Simultaneous analysis of cationic,
anionic and neutral surfactants fromdifferent matrices using LCMS/MS.
11Studies on Residual Characteristics ofGrowth Regulator 6-BA in Bean Sprout

Wan-Hee Seo, Young-Mo Jeong, Soon-Kil Cho, Bong-Suk Oh

Aichi Prefectural Institute of Public Health, Nagoya, Japan

11:10 − 12:20

Chubu University, Aichi, Japan, 2Nippon Filcon Co., Tokyo, Japan

PTh-169

Eiji Ueno, Haruka Ohno, Minae Watanabe, Harumi Oshima,Eiichi Mikami

PTh-165

LC-MS analysis of neonicotinoid
insecticides in the crops using a novel
selective solid-phase extractant having
dipole type functional group13:30 − 14:40

Improvement of Determination Method
for Pesticide Residues in Bean Sprout

Soon-Kil Cho, Wan-Hee Seo, Young-Mo Jeong, Ji-Mi Cho
Jeonnam Provincial Office, National Agricultural Products Quality
Management Service, MIFAFF, Korea

1Rashi Kochhar , Shruti Raju , Deepti Bhandarkar ,Bhairavi Saraf1, Shailendra Rane1, Jitendra Kelkar1, Ajit Datar1,Zhaoqi Zhan2

PTh-1711

Screening of five mycotoxins by using
immunoaffinity column and HPLCorbitrapMS in processed foods

Shimadzu Analytical (India) Pvt.Ltd., Mumbai, India, 2Shimadzu Asia PacificPte.Ltd.

11:10 − 12:20

Food safety

Dong Sik Jeong, Seung Lim Baek, Dae Hyun Kim, Jong Ho Lee,
Cheong-Tae Kim

PTh-166
13:30 − 14:40

Detection of Melamine in Human Renal
Uric Acid Stone by Matrix-Assisted Laser
Desorption / Ionization Time-Of-Flight
Mass Spectrometry (MALDI-TOF MS)NONGSHIM Co., LTD., Seoul, South Korea

PTh-172
13:30 − 14:40

Chia-Fang Wu1, Chia-Chu Liu2,3,4,5, Jentaie Shiea6, Yi-Tzu Cho7,Yii-Her Chou2,3, Bai-Hsiun Chen8, Chao-Yi Chien1,Shu-Pin Huang2,3, Wen-Jeng Wu2,3,9, Jung-Tsung Shen9,Mei-Yu Chang9, Chun-Hsiung Huang2,3, Ai-Wen Chang2,Ming-Tsang Wu*1,4,10,11

Simultaneous determination ofmelamine and its analogues in various
processed foods using LTQ-orbitrap
HRMS

JONG HO LEE, DONGSIK JEONG, DAE HYUN KIM,CHEONG-TAE KIM
NONGSHIM Co., Ltd., Seoul, Korea

1Department of Public Health, Kaohsiung Medical University, Kaohsiung,Taiwan, 2Department of Urology, Kaohsiung Medical University Hospital,Kaohsiung Medical University, Kaohsiung, Taiwan, 3Department of Urology,
Faculty of Medicine, College of Medicine, Kaohsiung Medical University,Kaohsiung, Taiwan, 4Graduate Institute of Medicine, Kaohsiung MedicalUniversity, Kaohsiung, Taiwan, 5Pingtung Hospital, Department of Health,Executive Yuan, Pingtung, Taiwan, 6Department of Chemistry, National Sun
Yat-Sen University, Kaohsiung, Taiwan, 7Department of Cosmetic
Applications and Management, Yuh-Ing Junior College of Health Care &Management, Kaohsiung, Taiwan, 8Department of Laboratory Medicine,
Kaohsiung Medical University Hospital, Kaohsiung, Taiwan, 9Department ofUrology, Kaohsiung Municipal Hsiao-Kang Hospital, Kaohsiung, Taiwan,
10Department of Family Medicine, Kaohsiung Medical University Hospital,
Kaohsiung, Taiwan, 11Center of Environmental and Occupational Medicine,
Kaohsiung Municipal Hsiao-Kang Hospital, Kaohsiung, Taiwan

PTh-174
13:30 − 14:40

Determination of DNA adducts
originating from methyleugenol using
isotope-dilution UPLC-ESI-MS/MS

Wolfram Engst1, Kristin Herrmann1, Fabian Schumacher1,
Simone Florian1, Klaus E Appel2, Hansruedi Glatt1
1German Institute of Human Nutrition Potsdam- Rehbrücke, Nuthetal,
Germany, 2Federal Institute for Risk Assessment, Berlin, Germany

114

Poster Session
Thursday, 20th September

Event Hall

Core Time : 11:10 - 12:20 (Odd number), 13:30 - 14:40 (Even number)

Session 40: Environment IIPTh-162
13:30 − 14:40

Analysis of perfluorinated compounds in sediment samples fromwastewater canal of Pancevo industrial area, Serbia

Vladimir P Beskoski1, Shuusuke Takemine2, Takeshi Nakano3, Latinka Slavkovic-Beskoski4,Gordana Gojgic-Cvijovic1, Mila Ilic1, Srdjan Miletic1, Miroslav M Vrvic1,51

Institute of Chemistry, Technology and Metallurgy, University of Belgrade, Serbia, 2Hyogo Prefectural Institute ofEnvironmental Science, Kobe, Japan, 3Center for Advanced Science and Innovation, Osaka University, Japan, 4Instituteof Nuclear Sciences, 5Faculty of Chemistry, University of Belgrade, Serbia

Keywords:
PFOA, PFOS, Industrial wastewater canal, Sediment, Danube River
Novel aspects:
This is the first report of presence of PFCs compounds in the sediments from Serbia. Compared to other reports, high levels ofPFOA and PFOS were found.
Abstract:
Perfluorinated compounds（PFCs）are chemicals that do not occur naturally, but have been widely used in chemical production
for some time. They are globally distributed, environmentally persistent, bioaccumulative, and potentially harmful.
Perfluorooctansulfonate（PFOS）and perfluorooctanoate（PFOA）are the two PFCs most commonly used and found in theenvironment. Together with perfluorohexane sulfonate（PFHxS）these compounds are widely employed in different industrial
processes such as in protective coatings.
The wastewater canal（WWC）Vojlovica was built in 1962 to collect the wastewater discharges from the industrial complex of thecity of Pancevo in Serbia. Industrial complex consist of a petrochemical factory（HIP Petrohemija）, an oil refinery（NIS Rafinerija,Pancevo）and chemical fertilizers factory（HIP Azotara）. The canal is artificial with no natural flows, about 2 km long, around 70
m wide and directly connected to the Danube River. The water depth is around 12 m. The environment surrounding the canal has
been strongly affected for a long time by the presence of the industrial complex. Additionally heavy destruction during NATObombing events in 1999 resulted in contamination of air, soil, groundwater and the WWC itself.
In total, 4 sediment samples from WWC were collected. Surface sediments layer of 15 cm were taken by a Van Veen Grab
sampler, transported in glass jars and stored in the laboratory at 4 °C. For comparative purposes, the same type of sample werealso taken from the navigation canal flowing parallel to WWC but not receiving any direct discharge of industrial wastewaters.
Sampling sites are listed below：
No 1 - navigation canal；
No 2 - at the confluence of WWC with the Danube River, downstream from the industrial area and effluents；
No 3 - downstream from the fertilizer factory outlet（first effluent）；
No 4 - downstream from the petrochemical plant（second effluent）；
No 5 - downstream from the oil refinery outlet（third effluent）.
Sediment sample was extracted with methanol. MPFAC-MXA as mass-labeled surrogates was spiked into the sample. The sample
was extracted with SPE. The elution was concentrated and labeled 13C8PFOA was added as syringe spike. The each final solution
was analyzed by liquid chromatography（LC）-tandem mass spectrometer（MS/MS）using Xevo TQ（Waters）coupled withACQUITY UPLC（Waters）.
Concentrations of PFCs were determined as follows：
No 1 ： 68, 230 and 230 ng/kg-dry of PFOA, PFHxS and PFOS, respectively.
No 2 ： 80 and 2100 ng/kg-dry of PFOA and PFOS, respectively.
No 3 ： 170 and 5300 ng/kg-dry of PFHxS and PFOS, respectively.
No 4 ： 130, 170, and 5700 ng/kg-dry of PFOA, PFHxA, and PFOS, respectively.
No 5 ： 76, 66 and 420 ng/kg-dry of PFOA, PFHxA, and PFOS, respectively.
Concentrations of PFOS in the samples No 3 and No 4 are 3 -3.2 times higher compared with sea sediment in Tokyo bay 1). PFOA
and PFOS concentrations from WWC were from two to twenty fold higher comparing to sediment samples taken from Roter Mainriver（Germany）which receives treated waste waters of industrial, commercial and domestic origin from municipal wastewater
treatment plant2). Comparing to upstream Danube River bank sediment samples3) PFOS from the WWC samples were from two tosix fold higher.
This is the first study and report of presence of PFCs compounds in the samples from Serbia. Most of the PFCs are released fromfertilizer factory and petrochemical plant outlets, while oil refinery outlet mostly contribute to petroleum pollution. The exact
origin of PFCs cannot be established from one study but one of the reasons for presence of these compounds might be theirusage as components in pipes, fittings and wiring insulations.

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