ࡈ࠶⚛♽᦭ᯏࠥ࡞ൻ೷ࠍၮ⋚ߣߒߚ࿾⃿᷷ᥦൻࠟࠬߩ࿕ቯൻᛛⴚߩ㐿⊒⎇ⓥઍ⴫⠪ጊญᄢቇᄢቇ㒮ℂᎿቇ⎇ⓥ⑼ ಎᢎ᝼ ጟᧄᶈ᣿౒ห⎇ⓥ⠪ጊญᄢቇ Ꮏቇㇱ ᛛⴚ⡯ຬ ᫪↰↱♿㧝㧚ߪߓ߼ߦ࿾⃿᷷ᥦൻኻ╷ߪ༛✕ߩ⺖㗴ߢ޽ࠆߎߣߪ๟⍮ߩ੐ታߢ޽ࠆ߽ߩߩ‫ੱߦ․ޔ‬ὑ⿠Ḯߩ᷷ቶലᨐࠟࠬߩਛߢᦨ߽ᓇ㗀ߩᄢ߈޿ߣߐࠇࠆੑ㉄ൻ὇⚛㧔%1㧕ߩ೥ᷫᣇᴺߦߪ‫ޡ‬ಾࠅᧅߪሽ࿷ߒߥ޿‫ޕࠆ޽ߢ⁁⃻߇ߩޢ‬ߎߩࠃ߁ߥ⃻⁁ߦ߅޿ߡ‫ޔ‬ㄭᐕ‫ޔ‬ᄢ᳇ਛߩ %1 ೥ᷫᚻᴺߣߒߡ‫ޔ‬ੑ㉄ൻ὇⚛࿁෼࡮㓒
㔌㧔%%5%CTDQPFKQZKFG%CRVWTGCPF5VQTCIG㧕ᛛⴚ߇਎⇇⊛ߦᵈ⋡ߐࠇߡ޿ࠆ=?‫ޕ‬
ߎߩ %%5 ᛛⴚߪ‫ޔ‬Ἣജ⊒㔚ᚲ╬ߩᄢⷙᮨߥ %1 ឃ಴Ḯߦ߅޿ߡ⊒↢ߔࠆ %1 ࠍಽ㔌࡮࿁෼ߒ‫ޔ‬ャㅍߒߚᓟ‫ޔ‬࿾ਛ޽ࠆ޿ߪᶏᵗߥߤ⾂⇐ߔࠆᛛⴚߢ޽ࠆ=?‫ࠚ࠙࡞ࡁޔߦߢߔޕ‬࡯‫ߡ޿߅ߦߤߥ࠳࠽ࠞޔ‬ታ⸽ታ㛎߇ㅴ߼ࠄࠇߡ߅ࠅ‫ޔ‬࿖ౝߢߪ‫ޔ‬㐳ጟ㧔ᣂẟ㧕ߦ߅޿ߡታ⸽ታ㛎߇ⴕࠊࠇ‫ޔ‬࿾⾰᭴ㅧ߇ⶄ㔀ߥᣣᧄߦ߅޿ߡ߽࿾ਛ⾂⇐߇น⢻ߢ޽ࠆߎߣ߇␜ߐࠇߡ޿ࠆ=?‫ޕ‬ߣߎࠈ߇‫ޔ‬%%5 ᛛⴚߦ߅޿ߡ %1 ߩಽ㔌࡮࿁෼߇ࠦࠬ࠻ో૕ߩ㧣㧜㧑ࠍභ߼ࠆߣ߽⸒ࠊࠇߡ߅ࠅ‫ޔ‬ታ↪ൻߩߚ߼ߦߪ‫ޔ‬㕟ᣂ⊛ߥ %1 ಽ㔌࡮࿁෼ᛛⴚߩ㐿⊒߇ᦨ㊀ⷐ߆ߟ༛✕ߩ⺖㗴ߣߥߞߡ޿ࠆ‫ޕ‬ߎߩࠃ߁ߥ %%5 ᛛⴚߦ㑐ߔࠆ⎇ⓥ࡮㐿⊒ߩਛߢ‫ᦨޔ‬ㄭ‫ࡦࠝࠗޔ‬ᶧ૕߇ㆬᛯ⊛ߦੑ㉄ൻ὇⚛ࠍ㜞ല₸ߢ‛ℂ⊛ߦๆ⌕࡮ๆ෼ߔࠆ‫ࡦࠝࠗޡ‬ᶧ૕ߦࠃࠆ %1 ࿕ቯൻᛛⴚ‫߇ޢ‬ᵈ⋡ߐࠇߡ޿ࠆ‫ߩߎޕ‬ᛛⴚߪ‫ޔ‬Ԙࠗࠝࡦᶧ૕ߦΆ὾ࠟࠬߥߤߦ฽߹ࠇࠆ %1 ࠟࠬࠍㆬᛯ⊛ߦๆ෼ߐߖ‫ޔ‬ԙߘߩๆ෼ᶧ߆ࠄ %1 ࠍౣ↢ߔࠆᚻᴺࠍណߞߡ޿ࠆ‫ࡦࠝࠗޔ߇ࠈߎߣޕ‬ᶧ૕ߪᧄ⾰⊛ߦ㨬ᶧ૕㨭ߢ޽ࠅ‫ޔ‬Ᏹߦṳ಴࡮ᵹ಴ߥߤߦߣ߽ߥ߁ෂ㒾ᕈ߇޽ࠆߎߣ߆ࠄ‫ޔ‬%1 ๆ⬿ࠗࠝࡦᶧ૕ࠍ㓸⚂࡮ಣℂߔࠆߚ߼ߩャㅍ࡮㓒㔌࡮⾂⬿ߦ㔍߇޽ࠅᧄ⾰⊛ߥ‫ޟ‬࿕ቯൻ‫ޠ‬ߦߪ⥋ߞߡ޿ߥ޿‫ߩࠄࠇߎޕ‬໧㗴ߩ⸃᳿ᚻᴺߩ৻ߟߣߒߡ‫ޔ‬㜞ಽሶൻߦࠃࠆ࿕૕ൻࠍ⋡ᜰߒߚࠗࠝࡦᶧ૕㧔㜞ಽሶൻࠗࠝࡦᶧ૕㧕ߩ㐿⊒߇ㅴ߼ࠄࠇ‫৻ޔ‬ቯߩᚑᨐࠍ਄ߍߡ޿ࠆ
߽ߩߩ‫ޟޔ‬㜞ಽሶൻࠗࠝࡦᶧ૕‫ ࠆߌ߅ߦޠ‬%1 ࿕ቯൻߦ㑐ߔࠆႎ๔଀ߪ߶ߣࠎߤ⍮ࠄࠇߡ޿ߥ޿‫ߪࠇߎޕ‬㜞ಽሶൻߦ઻޿ᶧ૕࿕᦭ߩᦼᓙߩṁ⸃ᐲ․ᕈ߇ᄬࠊࠇߚߚ߼‫ޔ‬%1 ṁ⸃ᐲߩૐਅ߇৻࿃ߣ⠨߃ࠄࠇࠆ‫ޕ‬ߘߎߢᧄ⎇ⓥߢߪ‫ߦߢ߹ࠇߎޔ‬㐿⊒ߒߚ᦭ᯏࠥ࡞ൻ೷ࠍ␆ߣߒߡ‫ࡦࠝࠗޡޔ‬ᶧ૕ߦࠃࠆ %1 ࿕ቯൻᛛⴚ‫ࡦࠝࠗࠆ޿ߡࠇߐ⋡⌕ߡߒߣޢ‬ᶧ૕ߩࠥ࡞ൻߦࠃࠆ࿕ቯൻࠍ߼ߑߒ‫ޔ‬᦭ᯏࠥ࡞ൻ೷㧔ൻว‛ P ෸߮ P(KIWTG㧕ࠍวᚑߒߚ‫?=ޕ‬㧙㧙ߐࠄߦ‫ޔ‬᭴▽ߒߚࠗࠝࡦᶧ૕ࠥ࡞ߩᾲ‛ᕈࠍ᣿ࠄ߆ߦߒߚ਄ߢ‫ࡦࠝࠗޔ‬ᶧ૕ࠥ࡞ߩ%1 ๆ෼㊂ࠍ᷹ቯߒ‫ޔ‬%1 ಽ㔌䊶࿁෼᧚ᢱ䈫䈚䈩䈱䉟䉥䊮ᶧ૕䉭䊦䈱‛ᕈ䉕⸃᣿䈚ߚ‫ޕ‬
C6F13C2H4S

O(CH2)nO

SC2H4C6F13

Compounds 1-n [4]O
C6F13C2H4S
O

O(CH2)nO
Compounds 2-n [5]O
SC2H4C6F13O

(KIWTG%JGOKECNUVTWEVWTGUHQTEQORQWPFUPCPFP㧞㧚ታ㛎᷹ቯวᚑߒߚൻว‛ߥࠄ߮ߦᣂⷙൻว‛ߩ᭴ㅧߩหቯ߅ࠃ߮‛ᕈߪਅ⸥ߩⵝ⟎ࠍ↪޿‫ޔ‬ൻว‛ߩ⚐ᐲߪ㜞ㅦᶧ૕ࠢࡠࡑ࠻ࠣ࡜ࡈࠖ࡯ਗ߮ߦ *0/4 ߆ࠄ᳞߼ߚ‫ޕ‬Ⲣὐ㧧;CPCEQ/GNVKPI2QKPV#RRCTCVWU /2, ⿒ᄖๆ෼ࠬࡍࠢ࠻࡞㧧5JKOCF\W+42TGUVKIG*0/4 ࠬࡍࠢ࠻࡞㧧,'1.,0/':᦭ᯏࠥ࡞ߩᒻᚑߩ⏕⹺ߪ‫▤࡞ࡊࡦࠨޔ‬ౝߦᚲቯ㊂ߩൻว‛ࠍ⒊㊂ߒߚᓟ‫᦭ޔ‬ᯏṁᇦߦടᾲṁ⸃ᓟ‫ޔ‬ቶ᷷߹ߢ⥄ὼ಄ළߒ‫ࠍ▤࡞ࡊࡦࠨޔ‬ୟ┙ߒߚ⁁ᘒߢ‫ߩ࡞ࠥޔ‬ᒻᚑࠍ⋡ⷞߦࠃࠅ⏕⹺ߒߚ‫ޕ‬᭴▽ߒߚࠗࠝࡦᶧ૕ࠥ࡞߅ࠃ߮ࠗࠝࡦᶧ૕ߩ %1 ๆ෼⢻ߪ‫ޔ‬㜞࿶ࠟࠬๆ෼ⵝ⟎㧔⏛᳇ᶋㆆᑼᄤ⒊‫ޔ‬ᣣᧄࡌ࡞␠⵾‫ޔ‬/5$#&㧕ࠍ↪޿ߡ᷹ቯߒߚ‫ޕ‬⹜⮎෸߮วᚑൻว‛ߩหቯวᚑᴺߩ⸥ㅀ߇ߥ޿ൻว‛ߦߟ޿ߡߪ‫ޔ‬๺శ⚐⮎Ꮏᬺ㧔ᩣ㧕‫᧲ޔ‬੩ൻᚑ㧔ᩣ㧕‫ࠞ࠽ޔ‬࡜ࠗ࠹ࠬࠢ㧔ᩣ㧕‫ޔ‬㑐᧲ൻቇ㧔ᩣ㧕‫ޔ‬#NFTKEJ%JGO%Q+PEߩᏒ⽼ຠࠍ♖⵾ߔࠆߎߣߥߊ↪޿ߚ‫ޕ‬ᓧࠄࠇߚൻว‛ߪ‫ޔ‬ౣ⚿᥏ᴺ޽ࠆ޿ߪࠪ࡝ࠞࠥ࡞ࠞ࡜ࡓࠢࡠࡑ࠻ࠣ࡜ࡈࠖ࡯ߦࠃࠅ♖⵾ߒ‫ޔ‬㜞⚐ᐲ㧔એ਄㧕ߩ⹜ᢱࠍ᷹ቯߦ↪޿ߚ‫ޕ‬ൻว‛࠺࡯࠲㧔วᚑਛ㑆૕ߩ࠺࡯࠲߽฽߻㧕 6TKFGECHNWQTQQEV[NUWNHCP[N RJGPQN
%QNQTNGUURQYFGTOR㨪͠+4 -$T ǵEO %1 㧘㧘㧘EO %( 㧘EO 1* *0/4 %&%N Ǭ *VV,*\  *V,*\ 㧙㧙 *DTU1*  *F,*\  *F,*\ RROൻว‛ %QNQTNGUURQYFGTOR㨪͠+4 -$T 㧦EO %1 㧘㧘㧘EO %( 㧘EO %* *0/4 %&%N 㧦G *V,*\  *SWKP,*\ 

*O  *V,*\  *V,*\  *F,*\  *F,*\ RROൻว‛ %QNQTNGUURQYFGTOR㨪͠
+4 -$T 㧦㧘EO %1 㧘㧘㧘㧘EO %( 㧘EO %* *0/4 %&%N 㧦G *O  *O  *O  *O  *F,*\  *F,*\ RRO㧟㧚⎇ⓥ⚿ᨐ᦭ᯏࠥ࡞ൻ೷ߩวᚑൻว‛ P ෸߮ P ࠍਅ⸥ߩวᚑࠬࠠ࡯ࡓߦᓥ޿วᚑߒߚ‫ޕ‬Ꮢ⽼ߩ㧠гࡔ࡞ࠞࡊ࠻ࡈࠚࡁ࡯࡞ߩ࠴ࠝ࡯࡞ၮߦ 6TKFGECHNWQTQQEV[NKQFKFG ࠍ૞↪ߐߖ‫࡞ࠠ࡞ࠕޔ‬ൻߒߚᓟ‫╬  ߣࠇߎޔ‬㊂ߩ ȁࠫࡉࡠࡕࠕ࡞ࠞࡦࠍ෻ᔕߐߖࠆ
ߎߣߢൻว‛ P ࠍᓧࠆߎߣ߇ߢ߈ߚ‫ޕ‬ߐࠄߦ‫ޔ‬ൻว‛ P ࠍㆊ㉄ൻ᳓⚛᳓ߢ㉄ൻߔࠆߎߣߢ‫ޔ‬ൻว‛ P ࠍᓧࠆߎߣ߇ߢ߈ߚ‫ޕ‬HS

C6F13C2H4S

OH

C6F13C2H4I
K2CO3, acetone, reflux

O(CH2)nO

C6F13C2H4S

OH

SC2H4C6F13

Compounds 1-nO
C6F13C2H4S
O

O(CH2)nO
Compounds 2-nBr(CH2)nBr, K2CO3
3-pentanone, reflux

30% H2O2AcOH

O
SC2H4C6F13O

5EJGOG5[PVJGVKEUEJGOGQHEQORQWPFUPCPFP㧙㧙᦭ᯏࠥ࡞ൻ೷ߦࠃࠆࠗࠝࡦᶧ૕ߩࠥ࡞ൻߣࠗࠝࡦᶧ૕ࠥ࡞ߩ‛ᕈ೨㗄ߢᓧࠄࠇߚൻว‛ P ߅ࠃ߮ P ߩฦ⒳᦭ᯏṁᇦߦ߅ߌࠆ᦭ᯏࠥ࡞ᒻᚑ⢻ࠍᬌ⸛ߒߚ‫ޕ‬ൻว‛ P ߅ࠃ߮ P ߆ࠄᒻᚑߒߚ᦭ᯏࠥ࡞ߪ‫(ޔ‬KIWTG ߦ␜ߔࠃ߁ߦടᾲ࡮಄ළߦࠃࠅ࠱࡞࡮ࠥ࡞߳ߣนㅒ⊛ߦᄌൻߔࠆᾲนㅒࠥ࡞㧔‛ℂࠥ࡞㧕ߢ޽ߞߚ‫ޕ‬ടᾲ಄ළ

C 



D (KIWTG2JQVQITCRJUQHVJGTOQTGXGTUKDNG RJ[UKECN IGN C IGNUVCVGCPF
D UQNUVCVG
ฦ⒳᦭ᯏṁᇦࠍቶ᷷ߦ߅޿ߡࠥ࡞ൻߔࠆߚ߼ߦᔅⷐߥൻว‛ P ߅ࠃ߮ൻว‛ P ߩᦨዊᷝട㊂㧔ᦨૐࠥ࡞ൻỚᐲ㧕ࠍ 6CDNG ߦ߹ߣ߼ߚ‫ޕ‬୯߇ዊߐ޿߶ߤ‫ޔ‬ዋ㊂ߩᷝട㊂ߢࠥ࡞ൻߔࠆߚ߼‫᦭ޔ‬ᯏࠥ࡞ൻ೷ߣߒߡఝࠇߚᕈ⾰ࠍ߽ߟߎߣࠍ␜ߒߡ޿ࠆ‫ޕ‬᦭ᯏࠥ࡞ൻ೷ߩ⎫㤛ቭ⢻ၮߩ㉄ൻᐲ߿ಽሶਛᄩߩࡔ࠴࡟ࡦ㎮㐳ߣ᦭ᯏṁᇦߩ㆑޿ߦࠃࠅ‫ᦨޔ‬ૐࠥ࡞ൻỚᐲߪᄌൻߔࠆ߽ߩߩ‫࡞࡯ࠦ࡞ࠕޔ‬ᕈߩࡊࡠ࠻ࡦᕈ᦭ᯏṁᇦߛߌߢߥߊ‫ߩߤߥ࠻࡯ࡀࡏ࡯ࠞࡦ࡟ࡇࡠࡊ߿࡞࡝࠻࠾࠻࠮ࠕޔ‬㕖ࡊࡠ࠻ࡦᕈߩᭂᕈṁᇦ߽ࠥ࡞ൻߔࠆߎߣ߇ಽ߆ߞߚ‫ޕ‬
6CDNGൻว‛ P㧔P㧕෸߮ P㧔P㧕ߩฦ⒳᦭ᯏṁᇦߦ߅ߌࠆᦨૐࠥ࡞ൻỚᐲ㧔㊀㊂㧑㧕ൻว‛ Pൻว‛ Pṁ ᇦP

P

P

P

'VJCPQN





1EVCPQN



#EGVQPKVTKNG



J$WV[TQNCEVQPG )$. 

2TQR[NGPGECTDQPCVG 2% 㧙㧙ߐࠄ ߦ‫ޔ‬ቶ᷷ߦ ߅޿ߡࠗࠝ ࡦᶧ૕㧔 0/GVJ[N0RTQR[NR[TTQNKFKPKWO DKU VTKHNWQTQOGVJCPGUWNHQP[N COKFG26(5#(KIWTG ෳᾖ㧕ࠍࠥ࡞ൻߔࠆߚ߼ߦᔅⷐߥൻว‛ P ߅ࠃ߮ P ߩỚᐲ㧔ᦨૐࠥ࡞ൻỚᐲ㧕ࠍ 6CDNG ߦ߹ߣ߼ߚ‫ޕ‬
F3C

CF3S N SO O O O N(KIWTG %JGOKECN UVTWEVWTG HQT 0/GVJ[N0RTQR[NR[TTQNKFKPKWO DKU VTKHNWQTQOGVJCPGUWNHQP[N COKFG 26(5# 
6CDNG ൻว‛ P ෸߮ P ߩࠗࠝࡦᶧ૕㧔26(5#㧕ߦ߅ߌࠆᦨૐࠥ࡞ൻỚᐲ㧔㊀㊂㧑㧕ൻว‛ Pൻว‛ Pࠗࠝࡦᶧ૕PPP P

0/GVJ[N0RTQR[NR[TTQNKFKPKWODKU VTKHNWQTQOGVJCPGUWNHQP[N COKFGࠗࠝࡦᶧ૕ߪ⺃㔚₸߇㕖Ᏹߦ㜞ߊ‫ޔ‬ᚲ⻐‫⦟ޡ‬ṁᇦ‫ޔߕࠄࠊ߆߆߽ߦࠆ޽ߢޢ‬ൻว‛P ߅ࠃ߮ P ߪࠥ࡞ൻߔࠆߎߣ߇ಽ߆ߞߚ‫ޔߦࠄߐޕ‬ൻว‛ P ߦ߅޿ߡߪ‫ޔ‬ਛᄩߩࡔ࠴࡟ࡦ㎮㐳ߩિ㐳ߦ઻޿‫ᦨޔ‬ૐࠥ࡞ൻ⢻߇ૐਅߔࠆߎߣ߆ࠄ‫࡞ࠥޔ‬ൻ⢻߇ะ਄ߒߚ‫ޕ‬৻ᣇ‫ޔ‬ൻว‛ P ߢߪ‫ᦨޔ‬ૐࠥ࡞ൻỚᐲߪಽሶਛᄩߩࡔ࠴࡟ࡦ㎮㐳ߩᓇ㗀ࠍߐ߶ߤฃߌࠆߎߣߥߊ‫ޯޔ‬YV⒟ᐲߩᦨૐࠥ࡞ൻỚᐲߢ޽ࠆߎߣ߇ಽ߆ߞߚ‫ޕ‬ࠗࠝࡦᶧ૕ࠍૐಽሶ㊂ൻว‛ߢࠥ࡞ൻߔࠆ⹜ߺߪ‫ޔ‬᳓⚛⚿วᕈߩቭ⢻ၮࠍ฽߻ൻว‛ߦࠃࠅ㆐ᚑߐࠇߡ޿ࠆ߽ߩߩ=?‫ޔ‬᳓⚛⚿วᕈߩቭ⢻ၮࠍ฽߹ߥ޿‫ޟ‬㕖᳓⚛⚿วᕈ‫ޠ‬ߩૐಽሶ㊂ൻว‛ߦࠃࠆࠗࠝࡦᶧ૕ߩࠥ࡞ൻߪ‫ߦઁޔ‬㘃଀߇ߥߊ‫ޔ‬㕖Ᏹߦ⥝๧ᷓ޿‫ޕ‬ߐ ࠄ ߦ ‫ ޔ‬1EVCPQN ‫ ޔ‬J$WV[TQNCEVQPG )$. ‫ ޔ‬2TQR[NGPG ECTDQPCVG 2% ‫ޔ‬0/GVJ[N0RTQR[NR[TTQNKFKPKWODKU VTKHNWQTQOGVJCPGUWNHQP[N COKFG 26(5#ࠍṁᇦߣߒߚ႐วߩ࠱࡞гࠥ࡞ォ⒖᷷ᐲࠍൻว‛  ߩỚᐲߦኻߒߡࡊࡠ࠶࠻ߒߚ
㧔(KIWTG㧕‫ޕ‬޿ߕࠇߩ᦭ᯏࠥ࡞ߦ߅޿ߡ߽‫ޔ‬ൻว‛  ߩỚᐲ਄᣹ߦ઻޿࠱࡞гࠥ࡞ォ⒖᷷ᐲߪ✭߿߆ߦ਄᣹ߔࠆ‫ޕ‬1EVCPQN‫ޔ‬2%‫)ޔ‬$. ࠍṁᇦߣߒߚ᦭ᯏࠥ࡞ߩ႐วߦߪ‫ޔ‬YVએ਄ߩỚᐲߦ߅޿ߡ‫࡞࠱ޔ‬гࠥ࡞ォ⒖᷷ᐲߪ߶߷৻ቯߣߥࠅ‫͠ޔ͠ ࠇߙࠇߘޔ‬⒟ᐲߩ࠱࡞
гࠥ࡞ォ⒖᷷ᐲߦ⇐߹ࠆߎߣ߇ಽ߆ߞߚ‫ޕ‬㧙㧙৻ᣇ‫ޔ‬26(5# ࠍṁᇦߣߒߚࠥ࡞ߩ႐ว‫ޔ‬YVએ਄ߩỚᐲߦ߅޿ߡ߽࠱࡞гࠥ࡞ォ⒖᷷ᐲߪ਄᣹ࠍ⛯ߌ‫ޔ‬YV⒟ᐲߩỚᐲߩ႐ว‫࡞࠱ޔ‬гࠥ࡞ォ⒖᷷ᐲߪ ͠⒟ᐲߣߥࠆߎߣ
߇ಽ߆ߞߚ‫ޕ‬೨ㅀߩࠃ߁ߦ‫ࡦࠝࠗޔ‬ᶧ૕ߪ‫⦟ޡ‬ṁᇦ‫ߡߒߣޢ‬⍮ࠄࠇߡ߅ࠅ‫࡞ࠥޔ‬ൻߔࠆߎߣ߇ᭂ߼ߡ࿎㔍ߢ޽ࠆߦ߽߆߆ࠊࠄߕ‫ޔ‬ዋ㊂ߩᷝട㊂ߢࠥ࡞ൻߔࠆ਄ߦ‫ߩઁޔ‬ṁᇦ♽ࠃࠅ߽࠱࡞гࠥ࡞ォ⒖᷷ᐲ߇㜞޿ߎߣߪᭂ߼ߡ⥝๧ᷓ޿⚿ᨐߣ⸒߃ࠆ‫ޕ‬
T/͠

10080

P13 TFSAPC
GBL60

1-Octanol40
20
00246

Concentration / wt%

(KIWTG 2NQVU QH UQNIGN VTCPUKVKQP VGORGTCVWTGU㷄  CICKPUVEQPEGPVTCVKQP YV QHEQORQWPF
ࠗࠝࡦᶧ૕ࠥ࡞ߩੑ㉄ൻ὇⚛ๆ෼⢻೨㗄ߦߡ᭴▽ߒߚࠗࠝࡦᶧ૕ 26(5# ࠥ࡞ߩ %1 ๆ෼⢻ࠍ㜞࿶ࠟࠬๆ෼ⵝ⟎㧔⏛᳇ᶋㆆᑼᄤ⒊‫ޔ‬ᣣᧄࡌ࡞␠⵾‫ޔ‬/5$#&㧕ࠍ↪޿ߡ᷹ቯߒߚ‫⚿ߩࠄࠇߎޕ‬ᨐࠍ (KIWTG ߦ␜ߔ‫ޕ‬%1 ๆ෼㊂ߩᲧセߩߚ߼ߦ‫ޔ‬ห᧦ઙߦ߅ߌࠆࠗࠝࡦᶧ૕ 26(5# ߩ %1 ๆ෼㊂ࠍ૬ߖߡࡊࡠ࠶࠻ߒߚ‫ޕ‬ࠗࠝࡦᶧ૕߅ࠃ߮ߘߩࠥ࡞ߪ޿ߕࠇ߽ %1 ߩ࿶ജ਄᣹ߣߣ߽ߦ %1 ๆ෼㊂߽⋥✢⊛ߦჇടߒߚ‫ࡦࠝࠗޕ‬ᶧ૕ߩࠥ࡞ൻߦ઻߁ %1 ๆ෼㊂ߩᷫዋߪ߶ߣࠎߤ⷗ࠄࠇߥ޿ߚ߼‫ޔ‬%1ߩๆ෼߇ࠗࠝࡦᶧ૕ߩᵹേᕈߦ⿠࿃ߒߚᕈ⾰ߢߪߥߊ‫᦭ޔ‬ᯏൻว‛ߩࠗࠝࡦߟ޿ߦ⿠࿃ߒߚᕈ⾰ߢ޽ࠆߎߣ߇␜ໂߐࠇߚ‫ࡦࠝࠗޔߜࠊߥߔޕ‬ᶧ૕ࠍ࿕ቯ㧔ࠥ࡞㧕ൻߒ‫‛ޔ‬ℂ⊛㧙㧙ߥ቟ቯᕈࠍઃਈߒߡ߽ %1 ๆ෼ߦߪ߶ߣࠎߤᓇ㗀ࠍ෸߷ߔߎߣߥߊ‫ࡦࠝࠗޔ‬ᶧ૕ߩఝࠇߚ‛ᕈࠍ⛽ᜬߔࠆߎߣ߇⏕⹺ߢ߈ߚ‫ޕ‬
26(5#IGN
26(5#$NCPM

2TGUUWTG=/2C)?

(KIWTG%1#FUQTRVKQPKUQVJGTOHQTKQPKENKSWKFCPFKQPKENKSWKFIGNCV͠
㧠㧚⚳ࠊࠅߦᧄ⎇ⓥߢ㐿⊒ߒߚ᦭ᯏࠥ࡞ൻ೷ߪ‫ޔ‬᳢↪⊛ߥ᦭ᯏṁᇦߩߺߥࠄߕ‫ࡦࠝࠗޔ‬ᶧ૕ࠍࠥ࡞ൻߔࠆߎߣ߇ಽ߆ߞߚ‫ࡦࠝࠗޔߦࠄߐޕ‬ᶧ૕ࠥ࡞ߩ࠱࡞гࠥ࡞ォ⒖᷷ᐲߪ‫ޔ‬᳢↪⊛ߥ᦭ᯏṁᇦ߆ࠄᒻᚑߒߚ᦭ᯏࠥ࡞ߩ࠱࡞гࠥ࡞ォ⒖᷷ᐲࠃࠅ㜞޿௑ะࠍ␜ߒߚ‫ޕ‬ߐࠄߦ‫ࡦࠝࠗޔ‬ᶧ૕ࠥ࡞ߩ %1 ๆ෼⢻ߪ‫ࡦࠝࠗޔ‬ᶧ૕ߣ᦭ᗧߩᏅߪ⷗ࠄࠇߥ޿ߎߣ߆ࠄ‫࡞ࠥޔ‬ൻߦࠃࠆᵹേᕈߩ༚ᄬߪ %1 ๆ෼㊂ߦߪᓇ㗀ࠍ෸߷ߐߥ޿ߎߣ߇ಽ߆ߞߚ‫ޕ‬৻ᣇ‫⎇ᧄޔ‬ⓥߢ㐿⊒ߒߚ᦭ᯏࠥ࡞ൻ೷ߪ‫ޔ‬᳓⚛⚿วᕈቭ⢻ၮࠍ฽߹ߥ޿ߎߣ߆ࠄ‫ޔ‬%1ๆ෼ߦ઻߁ R* ᄌൻ╬ߦࠃࠆࠗࠝࡦᶧ૕ࠥ࡞߳ߩᓇ㗀߽ߥ޿ߣᕁࠊࠇࠆ‫ޕ‬ߒߚ߇ߞߡ‫⎇ᧄޔ‬ⓥߢ㐿⊒ߒߚࠗࠝࡦᶧ૕ࠥ࡞ߪ‫ޔ‬ఝࠇߚ቟ቯᕈࠍ଻ᜬߒߚ㕟ᣂ⊛ߥ
%1 ಽ㔌࡮࿁෼᧚ᢱߣߒߡߩᔕ↪߇ᦼᓙߢ߈ࠆ‫ޕ‬⻢ㄉᧄ⎇ⓥߩㆀⴕߦ߅޿ߡ‫ޔ‬ᄙᄢߥេഥࠍ޿ߚߛ߈߹ߒߚ㧶㧲㧱㧞㧝਎♿⽷࿅ߦᗵ⻢ߩᗧࠍ⴫ߒ߹ߔ‫ޕ‬㧙㧙ෳ⠨ᢥ₂=? $/GV\1&CXKFUQP*FG%QPKPEM/.QQU./G[GT+2%%5RGEKCN4GRQTV
QP%CTDQP&KQZKFG%CRVWTGCPF5VQTCIG%CODTKFIG7PKXGTUKV[2TGUU  =? ⚻ᷣ↥ᬺ⋭↥ᬺᛛⴚⅣႺዪ⾗ᢱ‫ޟ‬%%5‫  ޠ‬=? <:WG6/CVUWQMC,)GQITCRJ[    =? ጟᧄᶈ᣿‫ޔ‬᫪↰↱♿‫․ޔ‬㗿  2%6,2 =? ጟᧄᶈ᣿‫ޔ‬᫪↰↱♿‫․ޔ‬㗿  2%6,2 =? -*CPCDWUC*(WMWK/5W\WMK*5JKTCK.CPIOWKT  =? $#8QUU,'$CTC&.)KP4&0QDNG%JGO/CVGT  ⊒⴫⺰ᢥ=? #[WMQ +WEJK ;WMK /QTKVC 6QOQOK *KTCMCYC -C\WQ -CUCVCPK CPF *KTQCMK1MCOQVQ 5[PVJGUKU CPF 2J[UKECN 2TQRGTVKGU QH 1TICPQIGNU DCUGF QP .QY
/QNGEWNCT9GKIJV)GNCVQTU 2GTHNWQTQCNM[N GVJ[NVJKQDGPG\GPG&GTKXCVKXGU'%5VTCPUCEVKQPU    ࿖㓙ቇળ⊒⴫=? *KTQCMK 1MOCQVQ ;WMK /QTKVC ;W[C ;COCOQVQ #[WMQ +WEJK 5[PVJGUKU CPF2J[UKECN2TQRGTVKGUQH1TICPQIGNUDCUGFQP.QY/QNGEWNCT9GKIJV)GNCVQTU 2GTHNWQTQQEV[N DWVQZ[DGP\GPG &GTKXCVKXGU VJ '%5 /GGVKPI 5CP
(TCPEKUEQ 75#  ᐕ=? ;WMK /QTKVC *KTQUJK 7GOWTC CPF *KTQCMK 1MCOQVQ 5[PVJGUKU CPF VJGTOCNRTQRGTVKGU QH C\QDGPG\GPG FGTKXCVKXGU JCXKPI C EQWOCTKP UMGNGVQP CV VJGVGTOKPCN RQUKVKQP VJ 'WTQRGCP %QPHGTGPEG QP .KSWKF %T[UVCNU -QNOCT(TCPEG  ᐕ=? ;WMK/QTKVC-GKUWMG-WTQUG,WP[C5W\WMKCPF*KTQCMK1MCOQVQ5[PVJGUKUCPF 2J[UKEQEJGOKECN 2TQRGTVKGU QH 5WDUVKVWVGF *%JTQOGPQPG&GTKXCVKXGUTF+PVGTPCVKQPCN.KSWKF%T[UVCN%QPHGTGPEG-TCMQY 2QNCPF  ᐕ=? ;WMK /QTKVC -GKUWMG -WTQUG *KTQCMK 1MOCQVQ 5[PVJGUKU CPF RJ[UKECNRTQRGTVKGU QH C\QDGP\GPG FGTKXCVKXGU JCXKPI C EQWOCTKP UMGNGVQP CV VJGVGTOKPCNRQUKVKQPQHVJGOQNGEWNG2CEKHKEJGO*QPQNWNW 75# ᐕ㧙㧙㑐ㅪߔࠆ⍮⊛⽷↥ᮭ=? ጟᧄᶈ᣿‫ޔ‬᫪↰↱♿‫․ޔ‬㗿  2%6,2 =? ጟᧄᶈ᣿‫ޔ‬᫪↰↱♿‫․ޔ‬㗿 =? ጟᧄᶈ᣿‫ޔ‬᫪↰↱♿‫․ޔ‬㗿 =? ጟᧄᶈ᣿‫ޔ‬᫪↰↱♿‫․ޔ‬㗿 㧙㧙