ᖺᗘ
ᖺḟሗ࿌࠶࠸ࡕࢩࣥࢡࣟࢺࣟࣥගࢭࣥࢱ࣮

ᡤ㛗ᣵᣜ࠶࠸ࡕࢩࣥࢡࣟࢺࣟࣥගࢭࣥࢱ࣮㸦௨ୗࠊAichiSR㸧ࡢ㐠⏝㛤ጞ࠿ࡽ 9 ᖺ┠࡜࡞ࡿ 2021 ᖺᗘࡢάືࢆ
ࡲ࡜ࡵࡓᖺሗࡀ࡛ࡁࡲࡋࡓࠋ๓ᖺᗘ࡟⥆ࡁࠊ᪂ᆺࢥࣟࢼឤᰁࡢཝࡋ࠸≧ἣࡢ୰࡛ࡢ㐠Ⴀ࡜࡞ࡾࡲࡋࡓࡀࠊ
ⓙᵝࡢࡈ༠ຊࡢඖࠊ᮶ሙேᩘไ㝈ࡢ௚ࠊ࡛ࡁࡿ㝈ࡾࡢឤᰁᑐ⟇ࢆࡍࡿࡇ࡜࡛ AichiSR ࢆ⏝࠸ࡓᐇ㦂ࢆ⥅⥆ࡍࡿࡇ࡜ࡀ࡛ࡁࡲࡋࡓࠋ᪋タ඲య࡛ࡣࡇࢀࡲ࡛ 11 ᮏࡢࣅ࣮࣒ࣛ࢖ࣥࡀタ⨨ࡉࢀ࡚࠾ࡾࡲࡋࡓࡀࠊ2021ᖺ࡟ࡣ᪂ࡓ࡟ BL11S3 ࡜ࡋ࡚ 2 ᮏ┠ࡢ௻ᴗᑓ⏝ࣅ࣮࣒ࣛ࢖ࣥࡢタ⨨ࡀ㐍ࡳࠊ2021 ᖺ 11 ᭶ࡼࡾヨ㦂㐠⏝ࡀጞࡲࡾࡲࡋࡓࠋࡇࢀ࡛ AichiSR ๰タᙜึ࡟┠ᶆ࡜ࡋࡓ 12 ᮏࡢࣅ࣮࣒ࣛ࢖ࣥࢆ㐩ᡂࡍࡿࡇ࡜ࡀ࡛ࡁࡲ
ࡋࡓࠋࡇࢀࡽࡢෆࡢ⛉Ꮫᢏ⾡஺ὶ㈈ᅋᡤ᭷ࡢ 8 ᮏ࡜ඹ࡟ࠊឡ▱┴ᡤ᭷㸯ᮏ࡜ྡྂᒇ኱Ꮫᡤ᭷ 1 ᮏࢆຍ࠼ࡓィ 10 ᮏࡀඹ⏝ࣅ࣮࣒ࣛ࢖ࣥ࡜࡞ࡗ࡚࠸ࡲࡍࠋࡇࢀࡽඹ⏝ࣅ࣮࣒ࣛ࢖ࣥࠊ௻ᴗᑓ⏝ࣅ࣮࣒ࣛ࢖ࣥࢆຍ
࠼ࡓ AichiSR ඲యࡢ㐠⏝ᐇ⦼࡟ࡘ࠸࡚ࡣ➨ 1 ❶࡟ࡲ࡜ࡵ࡚࠶ࡾࡲࡍࠋ⥲฼⏝᫬㛫ࡣᖺ㛫 8,637 ᫬㛫࡜࡞ࡾࠊࡇࢀࡲ࡛࡛᭱኱࡜࡞ࡾࡲࡋࡓࠋ୰࡛ࡶ ᐃ௦⾜࡟ࡘ࠸࡚ࡣࠊឤᰁ⑕ࡢᣑ኱ึᮇ࡟฼⏝ࡀ኱ࡁࡃᣑ
኱ࡋࡓᚋࡶࠊࡑࡢ฼౽ᛶࢆㄆ㆑ࡉࢀࡓࡇ࡜ࡶ࠶ࡗ࡚ࠊ඲యࡢ฼⏝᫬㛫ࡢ 1 ๭࡯࡝ࡢ࡛ࣞ࣋ࣝᐃ╔ࡋ࡚ࡁࡲࡋࡓࠋࡲࡓࠊ⥲฼⏝᫬㛫ࡢ༙ศ௨ୖࢆ⏘ᴗ⏺ࡢ฼⏝ࡀ༨ࡵࠊ࢔࢝ࢹ࣑࢔ࡀ⣙ 3 ศࡢ 1 ࡢ฼⏝࡜࡞ࡗ࡚࠸ࡲࡍࠋࡇࢀࡽࡢ฼⏝࡟ࡼࡿ◊✲ᡂᯝࡢ஦౛ࡣ➨ 2 ❶࡟♧ࡋ࡚࠶ࡾࡲࡍࡀࠊࡑࡢከࡃࡀ࢔࢝ࢹ࣑࢔࡟ࡼ
ࡿࡶࡢࠊ↓ൾ฼⏝࡞࡝බ⾲ྍ⬟࡞ࡶࡢ࠿ࡽᢳฟࡋࡓࡶࡢ࡛ࡍࠋࡑࡢ௚࡟ࡶ௻ᴗࢆ୰ᚰ࡟ᡂᯝ㠀බ㛤ࡢㄢ㢟࡟ࡼࡿᡂᯝࡀ࠶ࡾࠊࡑࢀࡽࡣᆅᇦࢆ୰ᚰ࡜ࡋࡓ௻ᴗࡢ◊✲㛤Ⓨ࡟ά࠿ࡉࢀ࡚࠸ࡿ࡜ᛮࢃࢀࡲࡍࠋࡇࢀ
ࡽࡢ◊✲㛤Ⓨࡢᡭẁ࡜ࡋ࡚ࡢග※ࠊࣅ࣮࣒ࣛ࢖ࣥ࡟ࡘ࠸࡚ࡣࡑࡢᶵჾ᭦᪂ࠊᨵၿ࡟ࡼࡿ㧗ᶵ⬟໬ࡢヨࡳ
ࢆ AichiSR ࡛㐍ࡵ࡚࠾ࡾࠊ➨ 3 ❶ࠊ➨ 4 ❶࡟ࡇࢀࡽ࡟ࡘ࠸࡚ࡶ㏙࡭࡚࠸ࡲࡍࠋࡑࡢ௚ࠊ฼⏝ಁ㐍࣭ᣑ኱ࡢࡓࡵࡢᵝࠎ࡞άື࡜ࡑࡢᡂᯝࡶᚋ༙࡟ࡲ࡜ࡵ࡚࠶ࡾࡲࡍࠋ
 AichiSR ࡣ㐠⏝㛤ጞ࠿ࡽ 9 ᖺ┠࡜࡞ࡾࠊ㧗ᶵ⬟໬࡜⪁ᮙ໬ᑐ⟇ࡀㄢ㢟࡜࡞ࡗ࡚࠾ࡾࡲࡍࠋ2021 ᖺᗘ࡛ࡣࠊ๓ᖺᗘ࠿ࡽᑟධࢆ㐍ࡵ࡚᮶ࡓ BL11S2 ࡢᖹ⾜ග࣑࣮ࣛࡢヨ㦂฼⏝ࡀጞࡲࡾࡲࡋࡓࠋX ⥺ CTࠊ᭦࡟ࡣ 3 ḟඖ XAFS ࢆ┠ᣦࡋࡲࡍࠋࡇࢀࡣ AichiSR ࡀࡇࢀ࠿ࡽ┠ᣦࡍ㧗ᶵ⬟໬ࡢ୰ࡢ࢖࣓࣮ࢪࣥࢢ㸦ྍྍど໬㸧ࡢ᪉ྥ࡟ἢࡗࡓࡶࡢ࡛ࡍࠋ௚࡟ࡶ BL5S2 ࡟࠾ࡅࡿ᳨ฟჾᨭᣢᵓ㐀ࡢᨵⰋࠊBL8S3 ࡬ࡢ኱ᆺ᧜ീ
᳨ฟჾࡢᑟධࠊBL6N1 ࡢ㥑ື⣔ࡢ⮬ື໬ࡢヨࡳࡶ࠶ࡾࠊࡇࢀࡽࡣࡶ࠺୍ࡘࡢ᪉ྥᛶࠊ㧗㧗㏿໬࣭ຠ⋡໬࡟ྥࡅࡓࡶࡢ࡜ゝ࠺ࡇ࡜ࡀ࡛ࡁࡲࡍࠋ2021 ᖺᗘࡢ➨ 5 ᮇࠊ➨ 6 ᮇࡢເ㞟࡛ࡣ◳ X ⥺ࣅ࣮࣒ࣛ࢖ࣥࢆ୰ᚰ
࡟⏦ㄳᩘࡀເ㞟ᯟࢆ 50%௨ୖ㉺࠼ࡿ஦ែ࡜࡞ࡾࠊ࠿࡞ࡾࡢ࣮ࣘࢨ࣮ࡢࡈせᮃ࡟ᛂ࠼ࡽࢀ࡞࠸஦ែࡀ㉳ࡁࡲࡋࡓࠋ௚᪋タࡢ฼⏝೵Ṇ࡜ᖺᗘᮎࡢ⦾ᛁᮇࡀ㔜࡞ࡗࡓࡇ࡜࡛ࡣ࠶ࡿࡶࡢࡢࠊィ ࡢ㧗㏿໬ࠊຠ⋡໬ࡸ௚᪋タ࡜ࡢ㐃ᦠ࡞࡝ࡢ᳨ウࢆ㐍ࡵࡲࡍࠋࡑࡢ୍᪉࡛ࠊ⪁ᮙ໬࡟క࠸ᨾ㞀ࡍࡿᶵჾࡀฟጞࡵ࡚࠸ࡲࡍࠋ୰
࡛ࡶග※ࡢ࣐࢖ࢡࣟἼᅇ㊰ࡢ୍㒊ࡢࣁࣥࢲ᥋ྜ㒊࡛₃ỈࡀⓎ⏕ࡋࠊࡑࡢ㒊ศࡢྲྀࡾእࡋࠊᕤሙ࡛ᨵಟࠊ෌タ⨨ࡢࡓࡵ࡟ 1 㐌㛫᪋タ඲యࡢ㐠⏝ࢆṆࡵࡿ஦ែࡶⓎ⏕ࡋࡲࡋࡓࠋ௚ࡢ᪋タࡢ≧ἣࡶ㚷ࡳࠊࡇࡢ㒊ศࢆ᪂つ࡟〇㐀ࡋࠊྠᵝ࡞ᨾ㞀࡟ᑐᛂࡍࡿࡇ࡜࡟ࡋ࡚࠸ࡲࡍࠋࡇࡢ௚ࠊ᪤࡟㐍ࡵ࡚࠸ࡿ⪏⏝ᖺᩘࡢ㐣ࡂࡓᶵჾࡢ᭦᪂ࢆィ⏬ⓗ࡟⥆ࡅ࡚࠸ࡁࡲࡍࠋ
 AichiSR ࡛ࡣࠊࡇࡇ࡟ࡲ࡜ࡵࡓ 2021 ᖺᗘ࠾ࡼࡧࡇࢀࡲ࡛ࡢά
ືࢆ᣺ࡾ㏉ࡾࠊḟࡢ 10 ᖺࡢ◊✲㛤Ⓨࡢືྥࢆぢᤣ࠼࡚ᑗ᮶ィ⏬
ࢆ᳨ウࡋ࡚⾜ࡁࡓ࠸࡜⪃࠼࡚࠸ࡲࡍࠋ௒ᚋ࡜ࡶࡈຓゝࠊࡈ༠ຊࢆ
㡬ࡁࡲࡍࡼ࠺࠾㢪࠸࠸ࡓࡋࡲࡍࠋබ┈㈈ᅋἲே ⛉Ꮫᢏ⾡஺ὶ㈈ᅋ
࠶࠸ࡕࢩࣥࢡࣟࢺࣟࣥගࢭࣥࢱ࣮
ᡤ㛗  ᅧᯞ ⚽ୡ

┠ḟ
ᡤ㛗ᣵᣜ
1. ඲యࡢᴫせ ....................................................................................................................................... 1
1.1 ᴫせ .......................................................................................................................................... 2
1.2 ᪋タࡢ㐠㌿≧ἣ ........................................................................................................................ 3(1) ග※ຍ㏿ჾ ........................................................................................................................... 3(2) ࣅ࣮࣒ࣛ࢖ࣥ ....................................................................................................................... 3
1.3 ฼⏝ࡢ≧ἣ ............................................................................................................................... 4
1.4 ᖺ㛫ࡢάືᴫせ ........................................................................................................................ 6
2. 2021 ᖺᗘᡂᯝ஦౛........................................................................................................................... 7
3. ◊✲㛤Ⓨࡢ≧ἣ .............................................................................................................................. 25
3.1 ◊✲㛤Ⓨ ................................................................................................................................. 26(1) ග※ຍ㏿ჾ ......................................................................................................................... 26(2) ࣅ࣮࣒ࣛ࢖ࣥ ..................................................................................................................... 28
3.2 እ㒊Ⓨ⾲ ................................................................................................................................. 33(1) ㄽᩥ .................................................................................................................................... 33(2) እ㒊Ⓨ⾲............................................................................................................................. 45
3.3 ⛉◊㈝➼እ㒊㈨㔠ࡢ⋓ᚓ≧ἣ ................................................................................................ 48
4. ᪋タ㐠Ⴀࡢグ㘓 .............................................................................................................................. 49
4.1 ග※ࡢ≧ἣ ............................................................................................................................. 50
4.2 ࣅ࣮࣒ࣛ࢖ࣥࡢ≧ἣ .............................................................................................................. 51(1) ㈈ᅋࣅ࣮࣒ࣛ࢖ࣥ .............................................................................................................. 51(2) ឡ▱┴ࣅ࣮࣒ࣛ࢖ࣥ .......................................................................................................... 57(3) ྡྂᒇ኱Ꮫࣅ࣮࣒ࣛ࢖ࣥ ................................................................................................... 58(4) ௻ᴗᑓ⏝ࣅ࣮࣒ࣛ࢖ࣥ ....................................................................................................... 59
4.3 ฼⏝ಁ㐍 ................................................................................................................................. 62(1) ฼⏝ไᗘࡢᴫせ.................................................................................................................. 62(2) ⏘ᴗ฼⏝ࢥ࣮ࢹ࢕ࢿ࣮ࢱ࣮ࡢάື .................................................................................... 63(3) ฼⏝⪅࠿ࡽࡢせᮃ࡬ࡢᑐᛂ ............................................................................................... 64(4) ᨺᑕ⥺ᴗົᚑ஦⪅ᩍ⫱カ⦎ ............................................................................................... 65(5) ぢᏛ⪅ᩘ............................................................................................................................. 66
5. ◊✲఍࣭ࢭ࣑ࢼ࣮ .......................................................................................................................... 67
5.1 ㅮ⩦఍࣭◊✲఍ ........................................................................................................................ 68
5.2 ࢩࣥࢡࣟࢺࣟࣥග฼⏝⪅◊✲఍࠙ᐇᆅ◊ಟࠚ ......................................................................... 695.3 ࢭ࣑ࢼ࣮ ................................................................................................................................... 69
5.4 ➨ 10 ᅇ࠶࠸ࡕࢩࣥࢡࣟࢺࣟࣥගࢭࣥࢱ࣮஦ᴗᡂᯝⓎ⾲఍ .................................................... 70
5.5 ྡྂᒇ኱Ꮫࢩࣥࢡࣟࢺࣟࣥග◊✲ࢭࣥࢱ࣮ࢩ࣏ࣥࢪ࣒࢘....................................................... 71
6. ᡂᯝሗ࿌᭩ ..................................................................................................................................... 73
6.1 බඹ➼฼⏝ᡂᯝሗ࿌᭩ ........................................................................................................... 74
6.2 ᡂᯝබ㛤↓ൾ฼⏝஦ᴗᡂᯝሗ࿌᭩......................................................................................... 87
7. ጤဨ఍............................................................................................................................................. 89
7.1 ࠶࠸ࡕࢩࣥࢡࣟࢺࣟࣥගࢭࣥࢱ࣮㐠Ⴀጤဨ఍ ...................................................................... 90
7.2 ࠶࠸ࡕࢩࣥࢡࣟࢺࣟࣥගࢭࣥࢱ࣮ᡂᯝබ㛤↓ൾ฼⏝஦ᴗㄢ㢟ᑂᰝጤဨ఍........................... 90
7.3 ࡑࡢ௚ጤဨ఍ ......................................................................................................................... 90
8. Ᏻ඲⟶⌮ ......................................................................................................................................... 91
8.1 ᨺᑕ⥺⟶⌮ ............................................................................................................................. 92(1) ⟶⌮యไ............................................................................................................................. 92(2) ᚑ஦⪅Ⓩ㘓 ......................................................................................................................... 92(3) ⫋ဨ⏝ᨺᑕ⥺ᴗົᚑ஦⪅ᩍ⫱カ⦎ㅮ⩦఍.......................................................................... 92
8.2 ࡑࡢ௚ .................................................................................................................................... 92
9. ᪋タ⟶⌮ ......................................................................................................................................... 93
9.1 㟁Ẽ .......................................................................................................................................... 94
9.2 Ỉ㐨........................................................................................................................................... 94
10. 㐠Ⴀ .............................................................................................................................................. 95
10.1 㐣ཤ 5 ᖺ㛫ࡢண⟬࣭฼⏝ᩱ཰ධࡢ᥎⛣.................................................................................. 96
10.2 㐠Ⴀ⤌⧊ ................................................................................................................................. 96(1) බ┈㈈ᅋἲே⛉Ꮫᢏ⾡஺ὶ㈈ᅋ ⤌⧊ᅗ.......................................................................... 96(2) ࢫࢱࢵࣇྡ⡙ ..................................................................................................................... 97
10.3 ጤဨྡ⡙ ................................................................................................................................. 98(1) ࠶࠸ࡕࢩࣥࢡࣟࢺࣟࣥගࢭࣥࢱ࣮㐠Ⴀጤဨ఍ .................................................................. 98(2) ࠶࠸ࡕࢩࣥࢡࣟࢺࣟࣥගࢭࣥࢱ࣮ᡂᯝබ㛤↓ൾ฼⏝஦ᴗㄢ㢟ᑂᰝጤဨ఍ ...................... 99
10.4 ᨭ᥼ᩍဨ㸦◊✲⪅㸧ྡ⡙ ........................................................................................................ 99௜㘓 ................................................................................................................................................. 101
ࣅ࣮࣒ࣛ࢖ࣥ㓄⨨ᅗ........................................................................................................................ 102
ඹ⏝ࣅ࣮࣒ࣛ࢖ࣥ ........................................................................................................................... 102
ග※ࡢᛶ⬟ ...................................................................................................................................... 102
࢔ࢡࢭࢫ .......................................................................................................................................... 103

㸬඲యࡢᴫせ1

඲యࡢᴫせ

 ᴫせ࣭࣮ࣘࢨ࣮ཷධ᪥

AichiSR ࡣࠊ௜ຍ౯್ࡢ㧗࠸ࣔࣀ࡙ࡃࡾࢆᨭ᥼ࡍࡿ
ࡓࡵឡ▱┴ࡀᩚഛࡋ࡚࠸ࡿࠊ
ࠕ▱ࡢᣐⅬ࠶࠸ࡕࠖ࡟タ⨨౛ᖺ୪ࡳࡢᖺ㛫 160 ᪥࡜ࡋࠊ᪋タࡢᏳᐃⓗ࡞㐠㌿࡟ࡉࢀࠊ2013 ᖺ 3 ᭶ࡼࡾࠊ⏘ᴗ⏺ࠊ኱Ꮫࠊឡ▱┴ࡢᨭ᥼ᚲせ࡞࣐ࢩࣥࢫࢱࢹ࢕ࡣࠊᖺ㛫 53 ᪥ࢆ☜ಖ࣭࣓ࣥࢸࢼࣥࢫࡢࡓࡵࡢ㛗ᮇఇᴗᮇ㛫ࢆཷࡅ࡞ࡀࡽࠊබ┈㈈ᅋἲே⛉Ꮫᢏ⾡஺ὶ㈈ᅋࡀ㐠Ⴀ

4 ᭶࠿ࡽ 5 ᭶๓༙ࡋ࡚࠸ࡿࠋ2021 ᖺᗘᮎ࡛㐠Ⴀ㛤ጞ࠿ࡽ 9 ᖺࡀ⤒㐣ࡋ࣭ග※⣔ࡢᏳᐃ㐠㌿ࡢࡓࡵࡢಖᏲ࣭ㄪᩚᮇ㛫ࡓࠋ

10 ᭶ᚋ༙㹼11 ᭶๓༙࡟ 1 㐌㛫⛬ᗘ㛤ᡤᙜึ 6 ᮏࡔࡗࡓ㈈ᅋᡤ᭷ࣅ࣮࣒ࣛ࢖ࣥࡣࠊ2015ᖺᗘཬࡧ 2016 ᖺᗘ࡟ྛ 1 ᮏࢆ㏣ຍࡋࠊ2021 ᖺᗘᮎ⌧ᅾ࡛ 8 ᮏ࡜࡞ࡗ࡚࠸ࡿࠋࡲࡓࠊ௚ᶵ㛵ᡤ᭷ࡢࣅ࣮࣒ࣛ

࠙฼⏝༊ศࠚ

࢖ࣥࡶᚎࠎ࡟ᩚഛࡉࢀࠊ2021 ᖺᗘࡣ 4 ᖺࡪࡾ࡟᪂つࣅx ୍⯡฼⏝

࣮࣒ࣛ࢖ࣥ㸦௻ᴗᑓ⏝㸧1 ᮏࢆタ⨨࣭✌ാࡋࡓࠋࡑࡢ⤖㏻ᖖ฼⏝ཬࡧ ᐃ௦⾜࡟࠾࠸࡚ࠊ୺࡟௻ᴗࡀ฼⏝ࡍ

ᯝࠊ2021 ᖺᗘᮎ⌧ᅾ࡛ࠊྡྂᒇ኱Ꮫᡤ᭷ 1 ᮏࠊឡ▱┴ࡿ༊ศࠋᡂᯝࢆ㠀බ㛤࡜ࡍࡿࡇ࡜ࡀྍ⬟ᡤ᭷ 1 ᮏࠊ௻ᴗᑓ⏝㸦ᰴᘧ఍♫ࢹࣥࢯ࣮ᡤ᭷㸧2 ᮏࢆ

x ୰ᑠ௻ᴗ฼⏝ྵࡴィ 12 ᮏࡀ✌ാࡋ࡚࠸ࡿࠋ

㏻ᖖ฼⏝ཬࡧ ᐃ௦⾜࡟࠾࠸࡚ࠊ୰ᑠ௻ᴗࡀ฼⏝ࡍ

2021 ᖺᗘࡶࠊ2020 ᖺᗘ࡟ᘬࡁ⥆࠸࡚᪂ᆺࢥࣟࢼ࢘

ࡿ༊ศࠋᡂᯝࢆ㠀බ㛤࡜ࡍࡿࡇ࡜ࡀྍ⬟࢖ࣝࢫឤᰁ⑕ࡢᙳ㡪ࡣ࠶ࡗࡓࡀࠊ୍᫬ⓗ࡟฼⏝⪅ࡢ᮶x බඹ➼฼⏝ᡤࢆไ㝈ࡋࡓ 2020 ᖺᗘ࡜␗࡞ࡾࠊឤᰁᑐ⟇࡟ྲྀࡾ⤌㏻ᖖ฼⏝ཬࡧ ᐃ௦⾜࡟࠾࠸࡚ࠊ኱Ꮫࠊබタヨ㦂◊✲

ࡳࡘࡘࠊ㏻ᡤ฼⏝ࢆไ㝈ࡍࡿࡇ࡜࡞ࡃ㐠Ⴀࢆ⥆ࡅࡓࠋᶵ㛵➼ࡢබඹⓗ࡞ᅋయࡀ฼⏝ࡍࡿ༊ศࠋᡂᯝබ㛤ࡀᖺ㛫ࢆ㏻ࡌ࡚㐠㌿࡟ᨭ㞀ࢆ᮶ࡍࡼ࠺࡞኱ࡁ࡞ࢺࣛࣈࣝ

๓ᥦࡶ࡯࡜ࢇ࡝࡞ࡃࠊ௻ᴗᑓ⏝ࣅ࣮࣒ࣛ࢖ࣥࡢ᪂タࡸࠊx ࢺࣛ࢖࢔ࣝ฼⏝ᐃ௦⾜ࡢ฼⏝ࡀᘬ⥆ࡁ㧗࠸Ỉ‽࡛࠶ࡗࡓࡇ࡜࡞࡝࡟ࡼ

බඹ➼฼⏝ࢆ㝖ࡃ㏻ᖖ฼⏝࡟࠾࠸࡚ࠊࣅ࣮࣒ࣛ࢖ࣥ

ࡾࠊ඲ࣅ࣮࣒ࣛ࢖ࣥ㸦12 ᮏ㸧ࡢ฼⏝᫬㛫ᩘࡣ㐣ཤ᭱ከࢆヨ⾜ⓗ࡟฼⏝ࡍࡿ༊ศࠋ฼⏝ᩱࡣ༙㢠

࠿ࡘ㈈ᅋࡢ฼⏝ᩱ཰ධࡣ㐣ཤ 2 ␒┠ࡢከࡉ࡜࡞ࡗࡓࠋ
࠙ࣅ࣮࣒ࣛ࢖ࣥタ⨨ࡢ᥎⛣ࠚ
ᖺᗘ

BL ᮏᩘ

2013

6ᮏ

2015

8ᮏ

2016

10 ᮏ

2017
2021

࠙฼⏝᪉ἲࠚ
x ㏻ᖖ฼⏝㸸஦ 㡯࣮ࣘࢨ࣮ࡀ AichiSR ࡟᮶ᡤࡋ࡚ ᐃࡍࡿ᪉ἲ

2012 ᖺᗘ 3 ᭶࡟ࢫࢱ࣮ࢺ
x

BL1N2ࠊBL2S1㸦ྡྂᒇ኱Ꮫ㸧

ᐃ௦⾜

౪⏝㛤ጞ

࣮ࣘࢨ࣮࠿ࡽ㡸࠿ࡗࡓヨᩱࢆ AichiSR ࢫࢱࢵࣇࡀ௦

BL11S2 ౪⏝㛤ጞࠊBL2S3㸦௻ࢃࡾ࡟ ᐃࡍࡿ᪉ἲ

ᴗᑓ⏝㸧タ⨨

ͤ㏻ᖖ฼⏝ࡢ⏦㎸᪉ἲ

11 ᮏ

BL8S2㸦ឡ▱┴㸧౪⏝㛤ጞx ᐃᮇ฼⏝⏦㎸

12 ᮏ

BL11S3㸦௻ᴗᑓ⏝㸧タ⨨ᖺ 6 ᅇࠊྛᮇ๓᭶ࡢึࡵ࡟⏦ࡋ㎸ࡴ᪉ἲ࠙㐠㌿ィ⏬ࠚx 㝶᫬฼⏝⏦㎸࣭᭶᭙᪥㸸ග※ㄪᩚ࣭࣐ࢩࣥࢫࢱࢹ࢕

ᐃᮇ฼⏝⏦㎸⤊஢ᚋ࡟✵ࡁࡢ࠶ࡿࣅ࣮࣒ࣛ࢖ࣥ࡟⏦ ͤ᭶᭙᪥ࡀ⚃᪥ࡢሙྜࡣࠊ⩣Ⴀᴗ᪥࡟ᐇ᪋

ࡋ㎸ࡴ᪉ἲ࣭ⅆ᭙᪥㹼㔠᭙᪥㸸࣮ࣘࢨ࣮฼⏝᪥x 㛗ᮇ฼⏝⏦㎸࣭࣮ࣘࢨ࣮ࢱ࢖࣒㸸➨ 1 ࢩࣇࢺ 10:00㹼14:00

๓ᮇ㸦➨ 1㹼3 ᮇ㸧ࠊᚋᮇ㸦➨ 4㹼6 ᮇ㸧ࡢ 2 ᅇ࡟ศࡅ࡚⏦ࡋ㎸ࡴ᪉ἲ

➨ 2 ࢩࣇࢺ 14:30㹼18:30

2

 ᪋タࡢ㐠㌿≧ἣ࠙ឡ▱┴ࣅ࣮࣒ࣛ࢖ࣥࠚ  ග※ຍ㏿ჾ

BL8S2㸸 ఩┦ CTᐃࢩࢫࢸ࣒ࡢ฼⏝㛤ጞග※ຍ㏿ჾࡣࠊ50MeV ࡢ┤⥺ຍ㏿ჾࠊ1.2GeV ࣈ࣮ࢫࢱ࣮ࢩࣥࢡࣟࢺࣟࣥࠊ
1.2GeV 㟁Ꮚ⵳✚ࣜࣥࢢ࡛ᵓᡂ

࠙ྡྂᒇ኱Ꮫࣅ࣮࣒ࣛ࢖ࣥࠚ

ࡉࢀ࡚࠸ࡿࠋࣅ࣮࣒ࣛ࢖ࣥ࡟ࢩࣥࢡࣟࢺࣟࣥගࡢ౪⤥BL2S1㸸 ஧ḟඖࣆࢡࢭ᳨ࣝฟჾࡢᑟධ࡟ྥࡅࡓ᳨ドࢆ㛤ጞࡋࡓᙜึ࠿ࡽࠊ⵳✚㟁ὶ 300mA ࡢࢺࢵࣉ࢔ࢵࣉ㐠㌿ࢆ⾜ࡗ࡚࠸ࡿࠋࢺࢵࣉ࢔ࢵࣉ㐠㌿୰ࡢ㟁ὶ್ࡢ࠙௻ᴗᑓ⏝ࣅ࣮࣒ࣛ࢖ࣥࠚ

ኚ໬ࡣ300mA ࡟ᑐࡋ࡚⣙0.1%࡛࠶ࡿࠋග※ຍ㏿ჾࡣࠊ

BL2S3㸸 ࣅ࣮࣒ࣛ࢖ࣥᶵჾ⮬ື┘どࢩࢫࢸ࣒ࡢᵓ⠏㏻ᖖ᭶᭙᪥ࡣ࣐ࢩࣥࢫࢱࢹ࢕࡛ࠊⅆ᭙᪥࠿ࡽ㔠᭙᪥ࡀ

ͤBL11S3 ࡣ 2021 ᖺᗘ 12 ᭶࡟タ⨨฼⏝᪥࡜࡞ࡗ࡚࠾ࡾࠊ฼⏝᪥࡟ࡣࠊᮅ 8 ᫬㐣ࡂ࠿ࡽධᑕࢆ⾜࠸ࠊኤ᪉ 19 ᫬㡭ࡲ࡛ࢩࣥࢡࣟࢺࣟࣥගࡢᥦ౪ࢆ
⾜ࡗ࡚࠸ࡿࠋ
ᮏᖺᗘࡢග※ຍ㏿ჾࡢ⥲㐠㌿᫬㛫ࡣ1,979
᫬㛫࡛࠶ࡗࡓࠋ๓ᖺᗘ࡜ẚ㍑ࡍࡿ࡜⣙ 3.0㸣ቑຍࡋࡓࠋ
ࡇࡢ࠺ࡕ࣮ࣘࢨ࣮ࡢ฼⏝᫬㛫ࡣ 1,235 ᫬㛫ࠊග※ຍ㏿ჾࡢ㧗ᗘ໬ࡸᏳᐃ໬ࡢࡓࡵࡢ࣐ࢩࣥࢫࢱࢹ࢕᫬㛫ࡣ
389 㛫࡛࠶ࡗࡓ㸦4.1 ཧ↷㸧ࠋ  ࣅ࣮࣒ࣛ࢖ࣥ
8 ᮏࡢ㈈ᅋࣅ࣮࣒ࣛ࢖ࣥ㸦BL1N2ࠊBL 5S1ࠊBL 5S2ࠊ
BL 6N1ࠊBL 7UࠊBL 8S1ࠊBL 8S3ࠊBL 11S2㸧ࠊឡ▱┴ࣅ࣮࣒ࣛ࢖ࣥ㸦BL8S2㸧ࠊྡྂᒇ኱Ꮫࣅ࣮࣒ࣛ࢖ࣥ
㸦BL2S1㸧ࠊࡑࡋ࡚ࠊ௻ᴗᑓ⏝ࣅ࣮࣒ࣛ࢖ࣥ㸦BL2S3ࠊ
BL 11S3㸧ࡢィ 12 ᮏࡢࣅ࣮࣒ࣛ࢖࡛ࣥከᵝ࡞ ᐃࡀ⾜ࢃࢀࡓࠋ฼⏝⪅ࡢ฼౽ᛶࢆ㧗ࡵࡿࡓࡵ 2021 ᖺᗘ࡟ᐇ᪋ࡋࡓ୺࡞ᨵၿࡣḟࡢ࡜࠾ࡾ࡛࠶ࡿࠋ
㸦4.2 ཧ↷㸧
࠙㈈ᅋࣅ࣮࣒ࣛ࢖ࣥࠚ
BL1N2㸸Excel VBA ࢆ⏝࠸ࡓ⡆᫆ XAFS ࢫ࣌ࢡࢺࣝ
⾲♧ࣉࣟࢢ࣒ࣛࡢ㛤Ⓨ
BL5S1㸸 SDD 㐲㝸⛣ືࢩࢫࢸ࣒ࡢᑟධ
BL5S2㸸 㧗㏿໬ࢧࣥࣉࣝࢳ࢙ࣥࢪ࣮ࣕࡢ฼⏝㛤ጞཬ
ࡧ PDF ゎᯒࢯࣇࢺࡢᑟධ
BL6N1㸸┿✵ࢳ࢙ࣥࣂ࣮࡬ࡢ SDD ᑟධ࡜኱Ẽᅽࢳ࢙ࣥࣂ࣮࣐ࢽࣆ࣮ࣗࣞࢱࡢ⮬ື໬
BL7U㸸 ࢚ࣥࢻࢫࢸ࣮ࢩࣙࣥほ ⿦⨨ࡢ᭦᪂
BL8S1㸸 3 㐃ศග⤖ᬗࡢᑟධ
BL8S3㸸 ฼⏝ྍ⬟࡞࣓࢝ࣛ㛗ࡢᣑ኱ཬࡧ᪂つ᳨ฟჾࡢᑟධ
BL11S2㸸ᗈࡀࡗࡓࢩࣥࢡࣟࢺࣟࣥගࢆ฼⏝ࡋࡓ 2 ḟ
ඖཬࡧ 3 ḟඖ XAFSᐃ3 ฼⏝ࡢ≧ἣ2021 ᖺᗘ࡟࠾ࡅࡿ඲ࣅ࣮࣒ࣛ࢖ࣥ 12 ᮏࡢ฼⏝ᐇ⦼

2019 ᖺᗘ௨๓࡜ẚ㍑ࡍࡿ࡜㧗࠸Ỉ‽࡟␃ࡲࡗࡓ
㸦ᅗ1㸧
ࠋ

ࡣ 8,637.0 ᫬㛫࡜㛤ᡤ௨᮶᭱ࡶከ࠿ࡗࡓࠋࡲࡓࠊ ᐃ௦฼⏝ᩱ཰ධࡣ 1 ൨ 9,500 ୓෇࡜㐣ཤ 2 ␒┠࡟ከࡃ࡞ࡗ⾜ࡢ฼⏝᫬㛫ࡣ 833 ᫬㛫࡜ࠊ᪂ᆺࢥࣟࢼ࢘࢖ࣝࢫឤᰁ

ࡓ㸦ᅗ 2㸧
ࠋ⑕ࡢᙳ㡪࡛ᛴቑࡋࡓ 2020 ᖺᗘࡼࡾᑡ࡞ࡃ࡞ࡗࡓࡀࠊ

ᅗ 1 ᖺᗘู ฼⏝᫬㛫ᩘࡢ᥎⛣㸦඲ BL㸸12 ᮏ㸧


䠄ⓒ୓෇䠅









70.4







135.9
154.6
173.3
189.7
101.0
176.6
኱௻ᴗ ୰ᑠ௻ᴗ ⏘Ꮫඹྠ ኱Ꮫ බඹ➼


197.1

ᅗ 2 ᖺᗘู ฼⏝ᩱ཰ධࡢ᥎⛣㸦㈈ᅋ BL㸸8 ᮏ㸧

4


195.0

䠄ⓒ୓෇䠅

ࢆఙࡤࡋ࡚࠾ࡾࠊᵝࠎ࡞ᆅᇦ࠿ࡽࡢ฼⏝ࡀぢࡽࢀࡿࡼ฼⏝᫬㛫࡟༨ࡵࡿ฼⏝⪅ࡢᵓᡂࡣࠊ⏘ᴗ฼⏝ࡀ඲య࠺࡟࡞ࡗ࡚ࡁ࡚࠸ࡿ㸦ᅗ 4㸧ࠋ

ࡢ 59.2%㸦኱௻ᴗ 47.2%ࠊ୰ᑠ௻ᴗ 4.5%ࠊ⏘Ꮫඹྠ
7.5%㸧࡛ࠊ༙ᩘ௨ୖࢆ༨ࡵ࡚࠸ࡿ㸦ᅗ 3㸧ࠋ๓ᖺᗘ࡜ẚ฼⏝᫬㛫࡟༨ࡵࡿᴗ✀ูࡢ฼⏝≧ἣࡣࠊ㛤ᡤ௨᮶ẖ࡭࡚ࠊࡑࢀࡒࢀࡢ༊ศࡢ๭ྜ࡟኱ࡁ࡞ኚືࡣ࡞࠿ࡗࡓࠋ

ᖺᗘ᭱ࡶከ࠸๭ྜࢆ༨ࡵ࡚࠸ࡿ
ࠕ㍺㏦⏝ᶵჾࠖ
ࡀ 38.0㸣฼⏝᫬㛫࡟༨ࡵࡿᆅᇦู฼⏝⪅ࡢᵓᡂࡣࠊࡇࢀࡲ࡛

࡜๓ᖺᗘࡼࡾࡶࡉࡽ࡟ῶᑡࡋࡓࠋࡑࡢ୍᪉࡛ࠊࡇࡇᩘ

ྠᵝࠊឡ▱┴ෆࡢ฼⏝ࡀ඲యࡢ༙ᩘ௨ୖࢆ༨ࡵࡿࡀࠊ

ᖺࡣࠕ㟁Ẽᶵჾ࣭㟁Ꮚ㒊ရࠖࠕ໬Ꮫࠖࠕㄪᰝ࣭ศᯒࢧ࣮ࣅ

ࡑࡢ๭ྜࡣ๓ᖺᗘࡼࡾ 4.0 ࣏࢖ࣥࢺῶᑡࡋࡓࠋࡲࡓࠊ

ࢫࠖࡢ฼⏝ࡀఙࡧ࡚࠾ࡾࠊࡑࢀࡒࢀ 10%๓ᚋࢆ༨ࡵ࡚

ឡ▱┴ࢆྵࡵࡓ୰㒊ᆅᇦࡢ฼⏝ࡶࠊ๓ᖺᗘࡼࡾ 4.6 ࣏࠸ࡿࠋࡑࡢ௚ࠊ๭ྜࡣᑠࡉ࠸ࡀࠊ
ࠕ㔠ᒓ࣭㕲㗰ࠖࡸࠕ㣗࢖ࣥࢺῶᑡࡋࡓࠋ୍᪉ࠊ㏆␥࠿ࡽࡢ฼⏝⪅ࡣ๓ᖺᗘࡼ

ရ࣭࣊ࣝࢫࢣ࢔ࠖ࡞࡝ࠊᖜᗈ࠸⏘ᴗศ㔝࡟ά⏝ࡉࢀ࡚࠸ࡾ 3.4 ࣏࢖ࣥࢺቑࠊ㛵ᮾ࠿ࡽࡣ 0.6 ࣏࢖ࣥࢺቑ࡜๭ྜ

ࡿ㸦ᅗ 5㸧
ࠋᖺᗘ

ᖺᗘ


᫬㛫

⏘Ꮫඹྠ
7.5%


᫬㛫

୰ᑠ௻ᴗ


⏘Ꮫඹྠ


୰ᑠ௻ᴗ
4.5%

ᅗ 3 ⥲฼⏝᫬㛫࡟༨ࡵࡿ฼⏝⪅ࡢᵓᡂ㸦඲ BL㸸12 ᮏ㸧ࡑࡢ௚㸦ᾏእࢆྵࡴ㸧ᖺᗘ

ᖺᗘ
ࡑࡢ௚



᫬㛫


᫬㛫

୰㒊
ឡ▱┴㝖ࡃ


୰㒊
㸦ឡ▱┴ࢆ㝖ࡃ㸧ᅗ 4 ⥲฼⏝᫬㛫࡟༨ࡵࡿᆅᇦู฼⏝⪅ࡢᵓᡂ㸦඲ BL㸸12 ᮏ㸧

5ᖺᗘ
ᶵᲔ 1.2%ᖺᗘ

ࡑࡢ௚ 6.5%

⧄⥔ 1.3%⧄⥔ ᶵᲔ ࢦ࣒〇ရ࣭ᶞ⬡ 1.7%

ࡑࡢ௚ ࢦ࣒〇ရ࣭ᶞ⬡ 㣗ရ࣭࣊ࣝࢫࢣ࢔2.8%

㣗ရ࣭࣊ࣝࢫࢣ࢔

㔠ᒓ࣭㕲㗰 3.9%㔠ᒓ࣭㕲㗰 ࢞ࣛࢫ࣭❔ᴗ࣭
ᅵ▼ 3.9%࢞ࣛࢫ࣭❔ᴗ࣭ᅵ▼ 


᫬㛫


᫬㛫

ᅗ 5 ⏘ᴗ฼⏝᫬㛫࡟༨ࡵࡿศ㔝ู฼⏝⪅ࡢᵓᡂ㸦඲ BL㸸12 ᮏ㸧 ᖺ㛫ࡢάືᴫせ2021 ᖺᗘࡢάື࡜ࡋ࡚ࠕ࣮ࣘࢨ࣮ࡢ฼౽ᛶྥୖ࡟ྥ

᥇ᢥࡋࠊሗ࿌఍ࡣࠊ2022 ᖺ 4 ᭶ 26 ᪥ ⅆ ࡟ࠊ఍ሙ࡛ࡅࡓྲྀ⤌ࠖࠊࠕ฼⏝ಁ㐍࡟㛵ࡍࡿྲྀ⤌ࠖࠊࠕᬑཬၨⓎ࡟㛵ࡢཧຍ࡜࢜ࣥࣛ࢖ࣥ࡟ࡼࡿཧຍࢆే⏝ࡋ࡚㛤ദࡋࠊ
186

ࡍࡿྲྀ⤌ࠖࡢ 3 ࡘࡢྲྀ⤌ࢆ⾜ࡗࡓࠋྡࡢཧຍࡀ࠶ࡗࡓࠋࡲࡓࠊ⏘ᴗ฼⏝ࢥ࣮ࢹ࢕ࢿ࣮ࢱ࣮

࣮ࣘࢨ࣮ࡢ฼౽ᛶྥୖ࡟ྥࡅࡓྲྀ⤌࡛ࡣࠊᐃᮇⓗ࡟ࡀ୰ᚰ࡜࡞ࡗ࡚ࠊ฼⏝┦ㄯࠊᢏ⾡ᣦᑟࢆ⥅⥆ⓗ࡟⾜ࡗ฼⏝⪅࢔ࣥࢣ࣮ࢺࢆᐇ᪋ࡋࠊࣅ࣮࣒ࣛ࢖ࣥᢏ⾡⪅ࡀ୰ࡓ௚ࠊㅮ⩦఍ࡸᐇᆅ◊ಟࢆ㛤ദࡋࡓ㸦4.3(2) ཧ↷㸧ࠋᚰ࡟࡞ࡗ࡚ࠊ࣮ࣘࢨ࣮࠿ࡽࡢせᮃ࡟ᑐᛂࡋࡓᨵၿάື

ᬑཬၨⓎ࡟㛵ࡍࡿྲྀ⤌࡛ࡣࠊ᪂ᆺࢥࣟࢼ࢘࢖ࣝࢫឤࡢ᳨ウࢆ⾜ࡗࡓࠋࡑࡢ⤖ᯝࠊ2021 ᖺᗘࡣࠊタഛᶵჾཬᰁ⑕ࡢᙳ㡪࡟ࡼࡾࠊᶵ఍ࡣከࡃ࡞࠿ࡗࡓࡶࡢࡢࠊࢭ࣑ࡧ᪋タ࡟ࡘ࠸࡚ 37 㡯┠ࡢᨵၿࢆᐇ᪋ࡋࡓ㸦4.3(3) ཧࢼ࣮➼ࡢ㛤ദ࣭㛵ಀᏛ఍➼࡬ࡢཧຍࡸࠊᒎ♧఍࡬ࡢฟ↷㸧ࠋࡲࡓࠊ᪂ᆺࢥࣟࢼ࢘࢖ࣝࢫឤᰁ⑕ࡢᗈࡀࡾࢆዎᶵᒎཬࡧぢᏛ⪅ࡢཷධࢀࢆ㏻ࡌ࡚ࠊࢩࣥࢡࣟࢺࣟࣥගࡢ

࡟ࢽ࣮ࢬࡀ㧗ࡲࡗࡓ ᐃ௦⾜ࢆࠊ⥅⥆ࡋ࡚ᐇ᪋ࡋࡓࠋ

ά⏝౛ࢆ࢔ࣆ࣮ࣝࡋࡓ㸦4.3(2) ཧ↷㸧ࠋ฼⏝ಁ㐍࡟㛵ࡍࡿྲྀ⤌࡛ࡣࠊᡂᯝබ㛤↓ൾ฼⏝஦ᴗࢆᐇ᪋ࡋࡓ㸦6.2 ཧ↷㸧ࠋ2021 ᖺᗘࡣࠊ16 ௳ࡢㄢ㢟ࢆ6㸬
ᖺᗘᡂᯝ
ᯝ஦౛

7㨱ἲゅࢶ࢖ࢫࢺ 2 ᒙࢢࣛࣇ࢙ࣥ࡟࠾ࡅࡿࣇࣛࢵࢺࣂࣥࢻࡢほᐹ
ྡྂᒇ኱Ꮫ
஌ᯇ⯟
1. ࡣࡌࡵ࡟

ࡾከゅⓗ࡞◊✲ࡢࡓࡵ࡟ࡣࠊ኱㠃✚ࡢヨᩱࢆస〇ࡍ 2 ᒙࡢࢢࣛࣇ࢙ࣥࢆࠊࢃࡎ࠿࡟ᅇ㌿ࡉࡏ࡚✚ᒙࡋࡿᚲせࡀ࠶ࡿࠋࡑࢀ࡟ᑐࡋ࡚ᡃࠎࡣࠊSiC ⇕ศゎἲࡓࡶࡢࢆࠊࢶ࢖ࢫࢺ 2 ᒙࢢࣛࣇ࢙ࣥ㸦TBG㸧࡜࿧ࡪ࡟ࡼࡾࠊ࣑࣓࣮ࣜࢺࣝࢫࢣ࣮ࣝࡢ༢୍᪉఩ࢢࣛࣇ࢙

㸦ᅗ 1(a)㸧ࠋ2007 ᖺ㡭࠿ࡽࠊTBG ࡟࠾࠸࡚ࠊࢶ࢖ࣥࢆస〇ࡍࡿᢏ⾡ࢆ☜❧ࡋ࡚࠸ࡿࠋ
ᮏ◊✲ࡢ┠ⓗࡣࠊࢫࢺゅ࡟ᛂࡌ࡚࢚ࢿࣝࢠ࣮ࣂࣥࢻᵓ㐀ࡀኚࢃࡿࡇ࡜

SiC ⇕ศゎἲ࡟ࡼࡗ࡚ᚓࡓࢢࣛࣇ࢙ࣥࢆ⏝࠸࡚኱㠃ࡀሗ࿌ࡉࢀࡓ[1]ࠋゝ࠸᥮࠼ࡿ࡜ࠊ༢⊂࡛ࡶᵝࠎ࡞⯆✚ TBG ヨᩱࢆస〇ࡋࠊࡑࡢヲ⣽࡞㟁Ꮚ≧ែࢆ࿡῝࠸ᛶ㉁ࢆᣢࡘࢢࣛࣇ࢙ࣥࡢ㟁Ꮚ≧ែࢆኚㄪࡉࡏ

ARPES

ᐃ࡟ࡼࡗ࡚᫂ࡽ࠿࡟ࡍࡿࡇ࡜࡛࠶ࡿࠋ

ࡿ᪉ἲ࡜ࡋ࡚ࠊࢶ࢖ࢫࢺゅࡀὀ┠ࡉࢀࡣࡌࡵࡓࠋ୰
࡛ࡶ 2018 ᖺ࡟ࠊ㨱ἲゅ࡜࿧ࡤࢀࡿ 1.1°ࡢࢶ࢖ࢫࢺ

2. ᐇ㦂᪉ἲ

ゅࢆᣢࡘ TBG㸦magic-angle TBG, MATBG㸧࡛ࡣࠊ 2 ᯛࡢ 4H-SiC(0001)༢⤖ᬗᇶᯈࢆ኱Ẽᅽ Ar ୰㉸ఏᑟࡀⓎ⌧ࡍࡿࡇ࡜ࡀሗ࿌ࡉࢀࠊ෌ࡧ◊✲ࡀάᛶ

1700Υ࡛ຍ⇕ࡍࡿࡇ࡜࡟ࡼࡾࠊ኱㠃✚༢୍᪉఩ࢢࣛ

໬ࡋࡓ[2]ࠋMATBG ࡛ࡣࠊᅇ㌿ࡋࡓࢢࣛࣇ࢙ࣥࡢࣂ

ࣇ࢙ࣥࢆస〇ࡋࡓࠋࡑࡢ࠺ࡕ 1 ᯛࡢࢢࣛࣇ࢙ࣥࢆᘬࣥࢻࡀᖸ΅ࡍࡿࡇ࡜࡟ࡼࡾࠊࣇ࢙࣑࢚ࣝࢿࣝࢠ࣮௜

ࡁ๤ࡀࡋࠊࡶ࠺ 1 ᯛࡢࢢࣛࣇ࢙ࣥୖ࡟㈞ࡾ௜ࡅࡿࡇ

㏆࡟ᅗ 1(b)ࡢࡼ࠺࡞ࣇࣛࢵࢺ࡞ࣂࣥࢻࡀฟ⌧ࡋࠊࡑ

࡜࡛ࠊTBG ヨᩱࢆస〇ࡋࡓࠋࢢࣛࣇ࢙ࣥ㌿෗࡟ࡘ࠸ࢀ࡟ࡼࡾ≧ែᐦᗘࡀᴟࡵ࡚኱ࡁࡃ࡞ࡿࡇ࡜ࡀࠊ㉸ఏ࡚ࡣࠊඹྠ◊✲⪅࡛࠶ࡿ⡿ᅜ࣐ࢧࢳ࣮ࣗࢭࢵࢶᕤ⛉ᑟࡢ㉳※࡜ࡉࢀ࡚࠸ࡿࠋ

኱Ꮫࡢ Jeehwan Kim ෸ᩍᤵࡀ㛤Ⓨࡋࡓᡭἲࢆ⏝࠸ ࡇࡢࣇࣛࢵࢺࣂࣥࢻ࡟ࡘ࠸࡚ࠊゅᗘศゎග㟁Ꮚศࡓ[5]ࠋᚓࡽࢀࡓヨᩱ࡟ᑐࡋ࡚ࠊཎᏊ㛫ຊ㢧ᚤ㙾ほᐹග ᐃ㸦ARPES㸧࡟ࡼࡿ┤᥋ほᐹࡢ⤖ᯝࡀ 2021 ᖺ࠾ࡼࡧ࣐ࣛࣥศග ᐃࢆ⾜࠸ࠊTBG ࡀᙧᡂࡉࢀ࡚࠸

࡟ሗ࿌ࡉࢀࡓ[3,4]ࠋࡑࢀࡒࢀࠊ㨱ἲゅ࡟㏆࠸ 1.34°࠾ࡿࡇ࡜ࢆ☜࠿ࡵࡓࠋࡑࡢᚋࠊ࠶࠸ࡕࢩࣥࢡࣟࢺࣟࣥ

ࡼࡧ 0.96°ࡢ TBG ࢆᶵᲔⓗ๤㞳ἲ࡟ࡼࡾస〇ࡋࠊヲගࢭࣥࢱ࣮BL7U ࣅ࣮࣒ࣛ࢖ࣥ࡟࡚ࠊARPES⣽࡞㟁Ꮚ≧ែࡀㄪ࡭ࡽࢀ࡚࠸ࡿࠋ୍᪉࡛ࠊࡇࢀࡽࡢ

ࢆ⾜ࡗࡓࠋᮏ✏࡛ࡣࠊࢶ࢖ࢫࢺゅ 2.9°ࠊ1.1°㸦㨱ἲሗ࿌ࢆྵࡵࠊ㉸ఏᑟ ᐃࡢ⤖ᯝࢆሗ࿌ࡋࡓ◊✲࡛ࡶࠊゅ㸧ࡢヨᩱࡢ ᐃ⤖ᯝࢆሗ࿌ࡍࡿ[6]ࠋ

ᐃࢢࣛࣇ࢓࢖ࢺ⤖ᬗ࠿ࡽࡢᶵᲔⓗ๤㞳࡟ࡼࡾస〇ࡋࡓ
3. ᐇ㦂⤖ᯝ

ヨᩱࡢ኱ࡁࡉࡣࠊ኱ࡁࡃ࡚ࡶᩘ༑ μm ࡛࠶ࡗࡓࠋࡼ

3-1 2.9°ࢶ࢖ࢫࢺ 2 ᒙࢢࣛࣇ࢙ࣥࡢ㟁Ꮚ≧ែ ᅗ 2 ࡟ࠊࢶ࢖ࢫࢺゅ 2.9°ࡢ TBG ヨᩱ࡟ᑐࡋ࡚⾜ࡗࡓ ARPESᐃࡢ⤖ᯝࢆ♧ࡍࠋᅗ 2 (a) ࡣࠊky =1.70 ύ-1ࠊࡍ࡞ࢃࡕࢢࣛࣇ࢙ࣥࡢࣈࣜࣝ࢔ࣥࢰ࣮
ࣥ࡟࠾ࡅࡿ K Ⅼ௜㏆࡛ᚓࡽࢀࡓ ARPES ീ࡛࠶ࡿࠋ
ᅗ࠿ࡽࠊkx = 0.0 ύ-1 ࢆ୰ᚰ࡜ࡍࡿᙉᗘࡢᙅ࠸ࣂࣥ
ࢻ࡜ࠊkx = 0.09 ύ-1 ࢆ୰ᚰ࡜ࡍࡿᙉᗘࡢᙉ࠸ࣂࣥࢻ
ᅗ 1(a) TBG ࡢᶍᘧᅗࠋࡇࡇ࡛ࡣࠊࢶ࢖ࢫࢺゅࡀᏑᅾࡍࡿࡇ࡜ࡀࢃ࠿ࡿࠋ୧⪅ࡣ࠸ࡎࢀࡶࠊࢢࣛࣇ

3.0°ࡢࡶࡢࢆ♧ࡋ࡚࠸ࡿࠋᅇ㌿ゅ࡟ࡼࡗ࡚ࣔ࢔ࣞ

࢙ࣥ≉᭷ࡢ⥺ᙧࣂࣥࢻศᩓ࡟ࡼࡗ࡚≉ᚩ࡙ࡅࡽࢀࡿ

࿘ᮇࡀኚ໬ࡍࡿࠋ(b) MATBG ࡢ࢚ࢿࣝࢠ࣮ࣂࣥ

[7]ࠋග㟁Ꮚࡢ⬺ฟ῝ࡉࢆ⪃៖ࡍࡿ࡜ࠊᙉᗘࡢᙅ࠸ࣂ

ࢻᵓ㐀ࠋࣇ࢙࣑࢚ࣝࢿࣝࢠ࣮㸦EF㸧௜㏆࡟ࣇࣛࢵࣥࢻࡀୗᒙࠊᙉ࠸ࣂࣥࢻࡀୖᒙࡢࢢࣛࣇ࢙ࣥ࡟⏤᮶ࢺࣂࣥࢻ࡜࿧ࡤࢀࡿᖹᆠ࡞ࣂࣥࢻࡀぢࡽࢀࡿࠋࡍࡿ࡜⪃࠼ࡽࢀࡿࠋࡲࡓࠊࡑࢀࡒࢀࡢ≉ᚩࡣࠊ⥺ᙧ

8ࣂࣥࢻࡢ஺Ⅼ࡛࠶ࡿࢹ࢕ࣛࢵࢡⅬࡢ࢚ࢿࣝࢠ࣮EDࡣࠊ2 ᒙࡢࢢࣛࣇ࢙ࣥ㛫ࡢᒙ㛫┦஫స⏝ࡀᙉ࠸ࡇ࡜

ࡀ␗࡞ࡿࡇ࡜࡛࠶ࡿࠋࢹ࢕ࣛࢵࢡ࢚ࢿࣝࢠ࣮ED ࡣࠊࢆ♧ࡋ࡚࠸ࡿࠋࡲࡓࠊࡇࢀࡽࡢࣂࣥࢻࢆ 3 ḟඖⓗ࡟ୗᒙࢢࣛࣇ࢙࡛ࣥࡣ⣙ 0.27 eVࠊୖᒙࢢࣛࣇ࢙࡛ࣥ

ᥥ࠸ࡓࡶࡢࢆ(c)࡟ࠊ㏫✵㛫ࡢ K Ⅼ௜㏆࡟࠾ࡅࡿࣔ࢔

ࡣ 0.20 eV ࡛࠶ࡗࡓࠋED ࡀ㈇࡛࠶ࡿࡇ࡜ࡣࠊࢢࣛ

ࣞࣈࣜࣝ࢔ࣥࢰ࣮ࣥ㸦mBZ㸧ࢆ(d)࡟♧ࡋ࡚࠸ࡿࠋ(d)ࣇ࢙ࣥࡀ㟁Ꮚࢻ࣮ࣉࡉࢀ࡚࠸ࡿࡇ࡜ࢆព࿡ࡍࡿࠋ

࡟࠾࠸࡚ࠊୗᒙ࠾ࡼࡧୖᒙࢢࣛࣇ࢙ࣥࡢ K ⅬࢆࠊKL

SiC ୖ࡟ᙧᡂࡉࢀࡓࢢࣛࣇ࢙࡛ࣥࡣࠊභ᪉ᬗ SiC ࡢ࠾ࡼࡧ KU ࡜⾲ࡋ࡚࠸ࡿࠋᒙ㛫┦஫స⏝ࡀᙉ࠸ࡇ࡜

⮬Ⓨศᴟ࡜⏺㠃ᒙࡢຠᯝ࡟ࡼࡾࠊࢢࣛࣇ࢙ࣥࡣ㟁Ꮚ࠿ࡽ TBG ࡣࣔ࢔ࣞᵓ㐀ࢆᣢࡕࠊࡑࡢ㟁Ꮚ≧ែࡣࣔࢻ࣮ࣉࡉࢀࡿࡇ࡜ࡀ▱ࡽࢀ࡚࠸ࡿ [8]ࠋୖᒙ࡜ୗᒙ

࢔ࣞ࿘ᮇࢆ཯ᫎࡋࡓ mBZ ࢆᙧᡂࡍࡿࠋᅗ(e)࡟ࡣࠊ

࡛㟁Ꮚࢻ࣮ࣉ㔞ࡀ␗࡞ࡿࡢࡣࠊᇶᯈ࠿ࡽࡢ㊥㞳ࡀ㐲EEF = 0.2 eV ࡟࠾ࡅࡿ kx-ky ീࠊࡘࡲࡾ➼࢚ࢿࣝ࠸ࡇ࡜࡟ࡼࡾࠊࡑࡢຠᯝࡀࡼࡾᙅࡃ࡞ࡿࡇ࡜࡟ࡼࡿ

ࢠ࣮㠃ࢆ♧ࡋ࡚࠸ࡿࠋKL ࠾ࡼࡧ KU ࡀほᐹࡉࢀࡿࠋ

࡜⪃࠼ࡽࢀࡿࠋࡲࡓࠊ୧⪅ࡢࢹ࢕ࣛࢵࢡⅬࡀ⣙ 0.09(f)࠾ࡼࡧ(g)࡟ࡣࡑࢀࡒࢀࠊKL ࡟ᑐᛂࡍࡿ kx = 0ύ-1

ύ-1 㞳ࢀ࡚࠸ࡿ࡜࠸࠺஦ᐇࡣࠊࢢࣛࣇ࢙ࣥࡀ஫࠸࡟

࠾ࡼࡧ KU ࡟ᑐᛂࡍࡿ kx = 0.09 ύ-1 ࡟࠾ࡅࡿ E-ky

⣙ 2.9°ᅇ㌿ࡋࡓ≧ែ࡛✚ᒙࡋ࡚࠸ࡿࡇ࡜ࢆ♧ࡋ࡚࠸ീࢆ♧ࡋ࡚࠸ࡿࠋ(g)࡟࠾࠸࡚ࡶࠊᙉ࠸ᒙ㛫┦஫స⏝ࡿࠋࡇࡢᅇ㌿ゅ࡜ ED ࢆ⪃៖ࡋ࡚ࠊࢶ࢖ࢫࢺ 2 ᒙࢢࢆ♧ࡍࢠࣕࢵࣉࡀࠊ㯮▮༳ࡢ఩⨨࡟ほᐹࡉࢀࡿࠋᅗ

ࣛࣇ࢙ࣥࡢࣂࣥࢻᵓ㐀ࢆࢱ࢖ࢺࣂ࢖ࣥࢹ࢕ࣥࢢἲ࡟(h)࡟ࡣࠊస〇ࡋࡓ 55 mm2 ࡢヨᩱࡢྛᡤ࡟࠾࠸࡚

ࡼࡾィ⟬ࡋࡓ⤖ᯝࢆᐇ㦂⤖ᯝ࡟㔜ࡡࡓࡶࡢࢆࠊᅗ

ᐃࡋࡓ E-kx ീࢆ♧ࡋ࡚࠸ࡿࠋᅗࡢ୰ኸ࡟ࡣࠊヨᩱ

2(b)࡟♧ࡋ࡚࠸ࡿࠋࡇࡢィ⟬࡛ࡣࠊᒙ㛫┦஫స⏝ࢆ࣍ࣝࢲ࡛ᅛᐃࡋࡓヨᩱ࡜ࠊ ᐃ఩⨨ࢆ♧ࡋ࡚࠸ࡿࠋ

⪃៖ࡋ࡚࠸࡞࠸ࠋᐇ㦂⤖ᯝࡣᐃᛶⓗ࡟ࡣࡼࡃ෌⌧ࡉᅗ୰ࠊ㟷Ⅼ࡛♧ࡍ఩⨨࡛ ᐃࡋࡓ⤖ᯝࡀ(a)࡛࠶ࡿࠋ

ࢀ࡚࠸ࡿࠋࡓࡔࡋࠊ(a)࡟࠾࠸࡚㯮▮༳࡛♧ࡍ࢚ࢿࣝࡲࡓࠊ㉥Ⅼ࡛♧ࡍ఩⨨࡛ࡣࠊࢠࣕࢵࣉࢆᣢࡘ TBG ࡢࢠ࣮࡛ࡣࠊ㟷࡜㉥ࡢ 2 ࡘࡢࣂࣥࢻࡀ஺ᕪࡍࡿⅬ࡛ࠊࣂࣥࢻᵓ㐀ࡀほᐹࡉࢀࡓࠋ୍᪉ࠊ㯮Ⅼ࡛♧ࡍ఩⨨࡛ᙉᗘࡢᙅ࠸㡿ᇦࠊࡘࡲࡾࢠࣕࢵࣉࡀᏑᅾࡍࡿࠋࡇࢀ

ࡣࠊୗᒙࢢࣛࣇ࢙ࣥࡢࣂࣥࢻࡢࡳࡀほᐹࡉࢀࡓࠋࡇ

ᅗ 2 2.9° TBG ࡢ ARPESᐃ⤖ᯝࠋ(a) K Ⅼ௜㏆ࡢ ARPES ീࠋ(b) (a)࡟ࠊ2.9° TBG ࡢࣂࣥࢻᵓ㐀ࢆ᭩ࡁຍ࠼ࡓࡶࡢࠋ㟷࡜㉥ࡢࣂࣥࢻࡣࠊࡑࢀࡒࢀୗ࠾ࡼࡧୖࡢࢢࣛࣇ࢙ࣥᒙ࡟⏤᮶ࡍࡿࠋ(c) TBG ࡢࣂࣥࢻᵓ㐀ࡢ㏫✵㛫࡟࠾ࡅࡿᶍᘧᅗࠋ(d) ࣔ࢔ࣞࣈࣜࣝ࢔ࣥࢰ࣮ࣥ㸦mBZ㸧
ࠋ(e) EEF = 0.2 eV ࡟࠾ࡅࡿ kx-ky
ീࠋ(f) kx = 0 ύ-1 ࡟࠾ࡅࡿ E-ky ീࠋ(g) kx = 0.09 ύ-1 ࡟࠾ࡅࡿ E-ky ീࠋ(h) ᇶᯈୖࡢ」ᩘ⟠ᡤ࡛ࡢ ARPES
ീࠋ



9

ࢀࡽࡢ⤖ᯝࡣࠊ㉥ⅬࡀᏑᅾࡍࡿᑡ࡞ࡃ࡜ࡶ 35

ᅗ 2 ࡜ẚ㍑ࡋ࡚᫂░࡟ศ㞳ࡉࢀ࡚࠸࡞࠸ࠋࡇࢀࡣࠊ

mm2 ࡢ⠊ᅖ࡛ࠊ2.9°ࡢ TBG ࡀᙧᡂࡉࢀࡓࡇ࡜ࢆ♧ࢶ࢖ࢫࢺゅࡀᑠࡉ࠸ࡇ࡜ࢆ♧၀ࡋ࡚࠸ࡿࠋᒙ㛫┦஫ࡋ࡚࠸ࡿࠋࡘࡲࡾࠊ࣑࣓࣮ࣜࢺࣝࢫࢣ࣮ࣝࡢ TBG ヨస⏝ࡢ࡞࠸ 1.1°ࡢ TBG ࢆ᝿ᐃࡋ࡚ィ⟬ࡋࡓࣂࣥࢻ

ᩱࢆᚓࡿࡇ࡜ࡀ࡛ࡁࡓࠋ

ᵓ㐀ࢆᐇ㦂ീ࡟㔜ࡡࡓࡶࡢࢆࠊ(e)࡟♧ࡍࠋ㟷࠾ࡼࡧ㉥ࡢ▮༳࡛♧ࡍ 2 ᮏࡢࣂࣥࢻࡀࠊᐃᛶⓗ࡟ࡣ෌⌧ࡉ

3-2 㨱ἲゅࢶ࢖ࢫࢺ 2 ᒙࢢࣛࣇ࢙ࣥࡢ㟁Ꮚ≧ែࢀ࡚࠸ࡿࠋࡲࡓࠊࡇࡢ ARPES ീ࡟࠾ࡅࡿ kx = 0.016

 ⥆࠸࡚ࠊ㉸ఏᑟࡀሗ࿌ࡉࢀࡓ㨱ἲゅ 1.1° TBG ࡢ

ύ-1 ௜㏆ࡢᙉᗘࣉࣟࣇ࢓࢖ࣝࢆ(c)࡟♧ࡍࠋ(c)ࡢᙉᗘ

ᐃࡢ⤖ᯝࢆᅗ 3 ࡟♧ࡍࠋ(a)࡟ࡣࠊヨᩱࡢࣉࣟࣇ࢓࢖ࣝ࡟ࡣࠊ◚⥺࡛♧ࡍ࢚ࢿࣝࢠ࣮ 0.22 ࠾ගᏛ㢧ᚤ㙾ീࢆࠊࢥࣥࢺࣛࢫࢺࢆᙉㄪࡋ࡚♧ࡋ࡚࠸ࡼࡧ 0.51 eV ࡟ࣆ࣮ࢡࡀぢࡽࢀࡿࠋຍ࠼࡚⯆࿡῝ࡿࠋ࢚ࢵࢪ௜㏆ࡢࢥࣥࢺࣛࢫࢺࡢⷧ࠸㡿ᇦ࡛ࡣࠊ࢚

࠸ࡇ࡜࡟ࠊ0.37 eV ࡟ࡶࠊᙅ࠸࡞ࡀࡽࡶᙉᗘᴟ኱ࡀ

ࣆࢱ࢟ࢩࣕࣝ༢ᒙࢢࣛࣇ࢙ࣥ㸦EMLG㸧ࡢࡳࡀᏑᅾ

ぢࡽࢀࡿࠋᅗ(f)ࡣࠊᒙ㛫┦஫స⏝ࢆ⪃៖ࡋ࡚ࠊࢶ࢖

ࡍࡿࠋ୰ኸ௜㏆ࡢࢥࣥࢺࣛࢫࢺࡀࢃࡎ࠿࡟⃰࠸㡿ᇦ

ࢫࢺゅ 1.08°ࡢ TBG ࡟ᑐࡋ࡚ィ⟬ࡋࡓࢫ࣌ࢡࢺࣝ

࡟ࢢࣛࣇ࢙ࣥࡀ㌿෗ࡉࢀ࡚࠾ࡾࠊ2 ᒙࡢࢢࣛࣇ࢙ࣥ

㛵ᩘࢆ♧ࡋ࡚࠸ࡿࠋᐃᛶⓗ࡟ࡣࠊᐇ㦂ⓗ࡟᳨ฟࡉࢀ

ࡀᏑᅾࡍࡿࠋᇶᯈࡢ࢚ࢵࢪ࡜ࠊ㌿෗ࡋࡓࢢࣛࣇ࢙ࣥ

ࡓ㟷࠾ࡼࡧ㉥ࡢ▮༳࡛♧ࡍࣂࣥࢻࡣ෌⌧ࡉࢀ࡚࠸ࡿࠋ

ࡢ࢚ࢵࢪࡢゅᗘࡣࠊ0.6㹼1.0°⛬ᗘ࡛࠶ࡗࡓࠋᅗ(b)ࡣࠊ

ࡲࡓࠊ0.37 eV ࡟࠾࠸࡚ࠊᖹᆠ࡞ࣂࣥࢻࠊ࠸ࢃࡺࡿ

ࡇࡢヨᩱ୰ኸ௜㏆࡛ᚓࡽࢀࡓ ARPES ീ࡛࠶ࡿࠋ▮ࣇࣛࢵࢺࣂࣥࢻࡀ᫂░࡟ほᐹࡉࢀࡿࠋᅗ(d)ࡣࠊ(f)࡟

༳࡛♧ࡍࡼ࠺࡟ࠊ」ᩘࡢࣂࣥࢻࡀぢࡽࢀࡿࡶࡢࡢࠊ

࠾ࡅࡿ kx = 0.016 ύ-1 ௜㏆ࡢᙉᗘࣉࣟࣇ࢓࢖࡛ࣝ࠶

ARPES

ᅗ 3 㨱ἲゅ 1.1° TBG ࡢ ARPESᐃ⤖ᯝࠋ(a) ヨᩱࡢගᏛ㢧ᚤ㙾ീࠋ(b) K Ⅼ௜㏆ࡢ ARPES ീࠋ(c),(d)(b)࠾ࡼࡧ(f)࡟࠾ࡅࡿ kx = 0.016 ύ-1 ௜㏆࡛ࡢᙉᗘࣉࣟࣇ࢓࢖ࣝࠋ(e) MATBG ࡟࠾ࡅࡿᒙ㛫┦஫స⏝ࡢ࡞࠸ࣂࣥࢻᵓ㐀ࢆ(b)࡟㔜ࡡࡓࡶࡢࠋ(f) ᒙ㛫┦஫స⏝ࢆ⪃៖ࡋ࡚ィ⟬ࡋࡓ 1.08° TBG ࡢࢫ࣌ࢡࢺࣝ㛵ᩘࠋ

10ࡿࠋ0.37 eV ࡟࠾࠸࡚ࠊࣇࣛࢵࢺࣂࣥࢻ࡟ࡼࡾᴟࡵ

99, 256802 (2007).

࡚ᙉᗘࡢᙉ࠸ࣆ࣮ࢡࡀᏑᅾࡍࡿࠋᚑࡗ࡚ࠊᐇ㦂࡛ᚓ[2] Y. Cao, et al., Nature 556, 43 (2018).

ࡽࢀࡓ0.37 eV ࡢࣆ࣮ࢡࡣࠊィ⟬࡜ẚ㍑ࡋ࡚ᙉᗘࡣ

[3] S. Lisi, et al., Nature Phys. 17, 189 (2021).

ᙅ࠸ࡶࡢࡢࠊࣇࣛࢵࢺࣂࣥࢻ࡟ࡼࡿࡶࡢ࡛࠶ࡿ࡜⪃[4] M. I. B. Utama, et al., Nature Phys. 17, 184࠼ࡽࢀࡿࠋࡍ࡞ࢃࡕࠊ኱㠃✚㨱ἲゅࢶ࢖ࢫࢺ 2 ᒙࢢ

(2021).

ࣛࣇ࢙ࣥ࡟࠾ࡅࡿࣇࣛࢵࢺࣂࣥࢻࡢ┤᥋ほᐹ࡟ᡂຌ[5] J. Kim, et al., Science 342, 833 (2013).

ࡋࡓࠋ[6] K. Sato, et al., Commun. Mater. 2, 117 (2021).

 ࡇࡢᐇ㦂⤖ᯝࡢ≉ᚩࡣࠊࣇࣛࢵࢺࣂࣥࢻࡀ 0.37[7] M. Kusunoki, et al., J. Phys. Soc. Jpn. 84,eV ௜㏆࡟Ꮡᅾࡍࡿࡇ࡜࡛࠶ࡿࠋࡇࢀࡣࠊ๓⠇࡛㏙࡭

121014 (2015).

ࡓᇶᯈࡢຠᯝ࡟ࡼࡾࠊTBG ࡀ㟁Ꮚࢻ࣮ࣉࡉࢀ࡚࠸ࡿ

[8] J. Ristein, et al., Phys. Rev. Lett. 108, 246104

ࡇ࡜ࢆព࿡ࡋ࡚࠸ࡿࠋࠕࡣࡌࡵ࡟࡛ࠖ㏙࡭ࡓࠊࣇࣛ

(2012).

ࢵࢺࣂࣥࢻࡢほᐹ࡟ᡂຌࡋࡓ᪤ሗ࡛ࡣࠊࣇ࢙࣑࢚ࣝ
ࢿࣝࢠ࣮࡟ࣇࣛࢵࢺࣂࣥࢻࡀほᐹࡉࢀ࡚࠸ࡿࠋ௒ᅇ
ࡢ⤖ᯝ࡟࠾࠸࡚ࠊTBG ࡀ㟁Ꮚࢻ࣮ࣉࡉࢀ࡚࠸ࡿࡇ࡜
࡟ࡼࡾࠊࣇࣛࢵࢺࣂࣥࢻ࡟ᑐࡋ࡚㧗࢚ࢿࣝࢠ࣮ഃࡢ
ほᐹࡶྍ⬟࡟࡞ࡗࡓࠋࡇࢀࡣࠊᇶᯈຠᯝࡀ TBG ࡢ㟁Ꮚ≧ែࢆኚㄪࡍࡿᡭἲ࡜ࡋ࡚ࡶ㠀ᖖ࡟㔜せ࡛࠶ࡿࡇ࡜ࢆ♧၀ࡋ࡚࠸ࡿࠋ
4. ࡲ࡜ࡵ
 ㏆ᖺࠊ2 ḟඖ≀㉁࡟࠾ࡅࡿࢶ࢖ࢫࢺࣟࢽࢡࢫࡢ◊✲ࡀ┒ࢇ࡟⾜ࢃࢀ࡚࠸ࡿࠋࡇࢀࡣࠊࢢࣛࣇ࢙ࣥࢆྵ
ࡴ 2 ḟඖ≀㉁ࢆ✚ᒙࡍࡿ㝿࡟ࠊࢶ࢖ࢫࢺゅࢆ᪂ࡓ࡞⮬⏤ᗘ࡜ࡋ࡚฼⏝ࡍࡿᢏ⾡࡛࠶ࡿࠋ኱㠃✚ࡢࢶ࢖ࢫࢺ 2 ᒙࢢࣛࣇ࢙ࣥヨᩱࡢస〇᪉ἲࡀ☜❧ࡉࢀࠊࡑࡢ
㟁Ꮚ≧ែࡀ᫂ࡽ࠿࡟࡞ࡗࡓࡇ࡜࡟ࡼࡾࠊࢶ࢖ࢫࢺࣟ
ࢽࢡࢫࡢᐇ⌧࡟୍Ṍ㏆࡙࠸ࡓ࡜ゝ࠼ࡿࠋㅰ㎡ ᮏ◊✲ࡣࠊ◊✲ᐇ᪋ᙜ᫬ྡྂᒇ኱Ꮫ኱Ꮫ㝔⏕ࡢబ⸨ிᶞẶ㸦⌧࣮࣒ࣟᰴᘧ఍♫㸧ࠊᯘ┤㍤Ặࠊྡྂᒇ኱Ꮫࢩࣥࢡࣟࢺࣟࣥග◊✲ࢭࣥࢱ࣮ఀ⸨Ꮥᐶ෸ᩍᤵࠊ
࣮࣒ࣟᰴᘧ఍♫┾◁⣖அ༤ኈࠊ㧗ᮧㄔ༤ኈࠊ᳃ᮏ‶༤ኈࠊ๓ᕝᣅ⁠༤ኈࠊ⡿ᅜ࣐ࢧࢳ࣮ࣗࢭࢵࢶᕤ⛉኱Ꮫ Doyoon Lee ẶࠊKuan Qiao ẶࠊJeehwan Kim෸ᩍᤵࠊ㛵すᏛ㝔኱Ꮫ୰ᕝཎᆂ♸Ặࠊⱝᯘඞἲᩍᤵࠊ
᪥ẚ㔝ᾈᶞᩍᤵ࡜ࡢඹྠ◊✲࡜ࡋ࡚ᐇ᪋ࡉࢀࡓࠋཧ⪃ᩥ⊩[1] J. M. B. Lopes dos Santos, et al., Phys. Rev. Lett.



11ࢩࣥࢡࣟࢺࣟࣥග࡟ࡼࡿ⇕ฎ⌮ᮌᮦࡢ⣽⬊ቨ୰ࢭ࣮ࣝࣟࢫࡢຊᏛᣲືゎᯒ᳃ᯘ⥲ྜ◊✲ᡤᑠᓥ⍛㔛ዉ
1. ࡣࡌࡵ࡟

⬊ቨࡢຊᏛᣲື ᡃࡀᅜ࡟ࡣᑎ♫௖㛶ࢆࡣࡌࡵ࡜ࡍࡿఏ⤫ᒙⓗ࡞⤌⧊ᵓ㐀ࢆྲྀࡾ㝖࠸ࡓࠊⷧ∦ヨ㦂యⓗ࡞ᮌ㐀ᘓ⠏⩌ࡀᏑᅾࡋ࡚࠸ࡿࠋࡇࢀࡽࡢ

ࢆᑐ㇟࡜ࡋࡓ X ⥺ ᐃࡀ⾜ࢃࢀ࡚࠸ࡓ[2]ࠋ

ከࡃࡣᘓ❧ᙜ᫬ࡢᵝᏊࢆ⌧௦࡟ఏ࠼࡚࠾ࡾࠊ

ࡋ࠿ࡋ࡞ࡀࡽᮌᮦࡢຊᏛᣲືࢆㄞࡳゎ࠸࡚ୡ⏺࡟㄂ࡿᩥ໬ⓗ㈈⏘࡛࠶ࡿࠋࡇࡢࡼ࠺࡞

࠸ࡃࡓࡵ࡟ࡣࠊࡍ࡭࡚ࡢ㝵ᒙᵓ㐀㸦ᖺ㍯ᵓ㛗ᮇ㛫࡟ரࡿᵓ㐀ⓗ฼⏝࡟ࡼࡾࠊ㒊ᮦ࡛࠶㐀㸧ࢆ᭷ࡋࡓ≧ែ࡛ࡢෆ㒊ࡢຊᏛᣲືࢆᢕ

ࡿᮌᮦࡢᮦ㉁ࡣኚ໬㸦ྂᮦ໬㸧ࡍࡿࡇ࡜ࡀศ

ᥱࡍࡿᚲせࡀ࠶ࡿࠋࡇࡢࡼ࠺࡞ㄢ㢟࡟ᑐࡋ࠿ࡗ࡚࠸ࡿࠋࡇࢀ࡟క࠺ຊᏛⓗ࡞ᛶ⬟ࡢኚ࡚ࠊᙉຊ࡞ග※ࢆᣢࡘࢩࣥࢡࣟࢺࣟࣥග࡟

໬ࡣࠊᵓ㐀≀ࡢᏳ඲ᛶࡢほⅬ࠿ࡽ኱ࡁ࡞㛵ࡼࡿ X ⥺ᅇᢡ࡛ࡣศཌ࠸ヨ㦂య࡛ࡶ ᐃࡀᚰ஦࡛ࡣ࠶ࡿࡀࠊࡇࢀ࡟㛵ࡍࡿ࣓࢝ࢽࢬ࣒

ྍ⬟࡜࡞ࡿࠋ

ࡣᮍࡔ࡟୙᫂࡞Ⅼࡀከ࠸ࠋࡇࢀ࡟ࡘ࠸࡚ࠊᮌ ᮏ✏࡛ࡣࠊ␲ఝྂᮦ໬ฎ⌮࡜ࡋ࡚⇕ฎ⌮ᮦ࡟⇕ฎ⌮ࢆ᪋ࡍ࡜ࠊྂᮦ໬࡜ఝࡓᮦ㉁ࡢ

ࢆ᪋ࡋࡓ」ᩘᖺ㍯ࢆ᭷ࡍࡿᮌᮦࢆᑐ㇟࡟ࠊ

ኚ໬ࢆ♧ࡍࡓࡵࠊྂᮦ໬ࡢ࣓࢝ࢽࢬ࣒ࡢゎ

ᘬᙇ㈇Ⲵస⏝ୗ࡛ࢩࣥࢡࣟࢺࣟࣥග࡟ࡼࡿ

᫂ࢆ┠ⓗ࡜ࡋࡓ⇕ฎ⌮ᮌᮦࡢᮦ㉁࠾ࡼࡧຊ

XRD

Ꮫ◊✲ࡣᩘከ࠸[1]ࠋ

࡞ᣲືࢆ ᐃࡋࡓ஦౛ࢆ⤂௓ࡍࡿ[3]ࠋ

 ࡇࡇ࡛ࠊᮌᮦࡣ」㞧࡞㝵ᒙᵓ㐀ࢆ᭷ࡋ࡚

2. ᐇ㦂᪉ἲ

࠸ࡿࠋࡍ࡞ࢃࡕࠊᮌᮦࡣ୍ᖺࡢ㛫࡛ᡂ㛗㏿ᗘ

2-1 ᮦᩱ

ࡢ␗࡞ࡿ⣽⬊㸦᪩ᮦ࡜ᬌᮦ㸧࠿ࡽᡂࡿᖺ㍯ᵓ ౪ヨᮦࡣ࢔࣐࢝ࢶ㸦Pinus densiflora㸧࡛ࠊ㐀ࡀ࠶ࡾࠊࡇࢀࡽࡢ⣽⬊ࡣࠊ⾲ᒙ࡟ⷧࡃᙧᡂ

ヨ㦂∦ࡢᙧ≧ࡣᮌᮦࡢ⧄⥔᪉ྥࢆ㛗㍈࡜ࡍࡉࢀࡓ 1 ḟቨ㸦P ᒙ㸧࡜ࠊ⫧኱⏕㛗࡟ࡼࡗࡿࢲࣥ࣋ࣝᆺ࡛ࠊᑍἲࡣ㛗ࡉ㸦⧄⥔᪉ྥ㸧60࡚ᙧᡂࡋࡓ 2 ḟቨ࠿ࡽᡂࡿࠋࡉࡽ࡟ 2 ḟቨmmࠊᖜ㸦༙ᚄ᪉ྥࡲࡓࡣ᥋⥺᪉ྥ㸧10 mmࠊ

ࡣእᒙ࠿ࡽ S1 ᒙࠊS2 ᒙࠊS3 ᒙࡢ 3 ᒙ࡛ᡂཌࡉ㸦᥋⥺᪉ྥࡲࡓࡣ༙ᚄ᪉ྥ㸧5 mm ࡛ࠊࡾ❧ࡗ࡚࠸ࡿࠋࡲࡓࠊࡑࢀࡒࢀࡢᒙࡣࢭࣝࣟ

୰ኸ㒊ࡢ᩿㠃ᑍἲࡀ 5 mm x 5 mm ࡜࡞ࡿ࣮ࢫࠊ࣑࣊ࢭ࣮ࣝࣟࢫࠊࣜࢢࢽࣥࡢ 3 ࡘࡢࡼ࠺࡟ࢸ࣮ࣃ࣮ࢆ᪋ࡋࡓࠋ⇕ฎ⌮ࡣࠊྂᮦ໬

୺ᡂศ࠿ࡽᡂࡿࠋࡇࡢࡼ࠺࡞࣑ࢡࣟ࠿ࡽ࣐

࡜ྠᵝ࡟⣽⬊ቨෆࡢ࣐ࢺࣜࢡࢫ࡜ࢭ࣮ࣝࣟ

ࢡࣟ࡟⮳ࡿᵓ㐀ࡢ⤌ࡳྜࢃࡏ࡟ࡼࡾࠊᮌᮦ

ࢫࡢ⤖ྜせ⣲࡛࠶ࡿ࣑࣊ࢭ࣮ࣝࣟࢫࡀῶᑡ

ࡢຊᏛᛶ⬟ࡣⓎ⌧ࡋ࡚࠸ࡿࠋᮌᮦࡢ⤒ᖺኚ

ࡍࡿ 150 ºC ࡜ࠊ࣑࣊ࢭ࣮ࣝࣟࢫ࡟ຍ࠼⣽⬊໬࡟క࠺ຊᏛⓗ࡞ኚ໬ࡢ࣓࢝ࢽࢬ࣒ࢆゎ᫂ቨෆࡢ၏୍ࡢ㙐せ⣲࡛࠶ࡿࢭ࣮ࣝࣟࢫࡶศ

ࡍࡿࡓࡵ࡟ࡣࠊࡑࢀࡒࢀࡢ⤌⧊ᵓ㐀ࢆᶓ᩿ゎࡍࡿ 180 ºC ࡜ࡢ 2 ✀㢮ࢆタᐃࡋࡓࠋฎ⌮ࡋࠊᮌᮦࡢᕧどⓗ࡞ᣲື࡜ᚤどⓗ࡞ᣲືࡢ᫬㛫ࡣ㔜㔞ῶᑡ⋡㸦௨㝆ࠊML ࡜⛠ࡍ㸧ࢆᇶ୧⪅ࢆ⤖ࡧࡘࡅ⌮ゎࡋ࡚࠸ࡃᚲせࡀ࠶ࡿࠋ‽࡟ྛ 3 ẁ㝵࡛࠶ࡿࠋTable 1 ࡟ฎ⌮᮲௳ᚑ᮶ࡢᮌᮦࡢᚤどⓗ࡞ᣲືࠊࡍ࡞ࢃࡕ⣽ᐃࢆ⾜࠺ࡇ࡜࡛ࠊᮌᮦෆ㒊ࡢᚤどⓗࢆࡲ࡜ࡵࡓࠋ

12ᐃ࡟ࡣࠊᮌᮦࡢ᭷ࡍࡿ㝵ࡿࠋd004 ࡣ Bragg ࡢἲ๎࡟ᇶ࡙ࡁゎᯒࡋࡓࠋ

Table 1 Thermal modification condition.
Temperature

Mass
loss

n

Modification௨ୖࡢࡼ࠺࡟ࡋ࡚ồࡵࡓࢭ࣮ࣝࣟࢫⲴ㔜࡜ࠊtimeࢭ࣮ࣝࣟࢫࡦࡎࡳ'd/d0 ࠿ࡽࠊࢭ࣮ࣝࣟࢫࡢ

(Hour)

Ⲵ㔜㸫ࡦࡎࡳ㛵ಀࢆゎᯒࡋࡓࠋ

(ºC)

(%)

0

0

4

0

3

3

58

4

4

154

ࢡ࡜⛠ࡍ㸧࡞ຊᏛᣲືࢆ☜ㄆࡍࡿࡓࡵࠊヨ㦂

6

4

259

∦୰ኸ࡟ࡦࡎࡳࢤ࣮ࢪࢆ㈞௜ࡋࡓࠋ㈇Ⲵ෬

3

3

3

ල࡟ྲྀࡾ௜ࡅࡓ࣮ࣟࢻࢭࣝ࠿ࡽࡢⲴ㔜࡜ࡦ

4

3

6

ࡎࡳࢤ࣮ࢪࡢ್ࡣࢹ࣮ࢱ࣮ࣟ࢞ࢆ௓ࡋ࡚グ

18

3

90

㘓ࡋࡓࠋᮌᮦࣂࣝࢡࡢⲴ㔜㸫ࡦࡎࡳ㛵ಀࡣ

150

180

ࡉࡽ࡟ࠊヨ㦂∦ࡢᕧどⓗ㸦௨㝆ࠊᮌᮦࣂࣝ

n: number of specimen

2-2 XRD
XRDࡇࢀࡽࡢࢹ࣮ࢱ࠿ࡽゎᯒࡋࡓࠋ
3. ⤖ᯝ࡜⪃ᐹᐃ࡜ᘬᙇヨ㦂 ᘬᙇⲴ㔜ୗ࡛ࡢ XRDᐃࡣ࠶࠸ࡕࢩࣥࢡࣟࢺࣟࣥගࢭ

ᐃ࡟ࡼࡾᚓࡽࢀ

ࡓࠊS2 ᒙෆࢭ࣮ࣝࣟࢫ࠾ࡼࡧࡑࡢ᫬ࡢᮌᮦ

ࣥࢱ࣮BL8S1 ࡛⾜ࡗࡓࠋ ᐃࡋࡓ Bragg ゅࣂࣝࢡࡢⲴ㔜㸫ࡦࡎࡳ᭤⥺ࢆ Fig. 1 ࡟♧ࡍࠋࡣࢭ࣮ࣝࣟࢫ㸦004㸧㠃㸦⣙ d004=2.59 Å[4]㸧

ࡇࡇ࡛ࡣ౛࡜ࡋ࡚ 150Υ⇕ฎ⌮ࢆ᪋ࡋࡓሙ

࡟ᑐᛂࡍࡿ 26.5r㹼35r࡛࠶ࡿࠋᮏ✏࡛ࡣྜࡢ඾ᆺⓗ࡞Ⲵ㔜㸫ࡦࡎࡳ᭤⥺ࢆ♧ࡋࡓࠋ⧄⥔᪉ྥ࡜࡯ࡰᖹ⾜࡟㓄ྥࡋ࡚࠸ࡿ S2 ᒙෆࡢࢭ࣮ࣝࣟࢫࡢᣲືࢆㄪ࡭ࡿࡓࡵ࡟㏱㐣ἲࢆ⏝࠸ࡓࠋᘬᙇ㈇Ⲵస⏝ୗ࡛ XRD⾜࠺ࡓࡵ࡟ࠊXRD

1400

ᐃࢆ

ᐃ⿦⨨ࡢࢫࢸ࣮ࢪࡢ୰

1000
Load (N)ኸ࡟⮬సࡢ㈇Ⲵ἞ලࢆタ⨨ࡋࡓࠋࡇࡢ෬ල
࡟ヨ㦂∦ࢆྲྀࡾ௜ࡅࠊヨ㦂∦ࡢᮦ㍈᪉ྥ㸦ࡍ

800
600
400

ᘬᙇ㈇Ⲵࢆ୚࠼ࡓࠋヨ㦂∦ࡀ◚ቯ࡟⮳ࡿࡲ

200

࡛ࠊ4㹼10 ᅇࡢẁ㝵ⓗ࡞ᘬᙇ㈇Ⲵࢆ୚࠼࡞

0Unmodified
ML 3%
ML 4%
ML 6%

࡞ࢃࡕࠊᮌᮦࡢᕧどⓗ࡞⧄⥔᪉ྥ㸧࡜ᖹ⾜࡟ࡀࡽࠊ㒔ᗘ XRD(a) 150䢛C Bulk wood

1200

0

2000

ᐃ㸦1 ᅇ࡟ࡘࡁ 330 ⛊㸧
1400

ࢆ⾜ࡗࡓࠋS2 ᒙෆࡢࢭ࣮ࣝࣟࢫ࡟స⏝ࡍࡿ8000(b) 150䢛C㻌Cellulose

1200

Ⲵ㔜࡟ࡘ࠸࡚ࠊࢭ࣮ࣝࣟࢫࡣᮦ㍈࡟ᑐࡋ࡚

4000
6000
Strain (㽢10-6)

1000
Load (N)ⱝᖸഴᩳࡋ࡚࠸ࡿࡓࡵᮌᮦࣂࣝࢡ࡟࠿࠿ࡗ
ࡓᘬᙇⲴ㔜ࡢ᪉ྥ࡜୍⮴ࡋ࡞࠸ࠋࡑࡇ࡛ࠊࢭ

800
600

࣮ࣝࣟࢫ࡟స⏝ࡍࡿᘬᙇⲴ㔜ࢆࠊᮦ㍈ࢆᇶ

400‽࡜ࡍࡿࢭ࣮ࣝࣟࢫࡢ㓄ྥゅ࡬ࡢศຊ࡜ࡋ

200

࡚ồࡵࡓࠋḟ࡟ࠊࢭ࣮ࣝࣟࢫࡢᘬᙇࡦࡎࡳࡣ

0ࢭ࣮ࣝࣟࢫ㸦004㸧㠃ࡢ㠃㛫㝸 d004 ࡢኚ໬⋡Unmodified
ML 3%
ML 4%
ML 6%
0

2000

4000
6000
Strain (㽢10-6)

8000

Fig. 1 Ⲵ㔜㸫ࡦࡎࡳ᭤⥺㸦[3]ࢆᨵኚ㸧'd/d0㸦d0㸸↓㈇Ⲵ᫬ࡢ㠃㛫㝸 d004㸹'd㸸d0㸦a㸧ᮌᮦࣂࣝࢡ 㸦b㸧ࢭ࣮ࣝࣟࢫ

࡜㈇Ⲵ᫬ࡢ㠃㛫㝸 d004 ࡢᕪ␗㸧࡛ᐃ⩏࡛ࡁ

13

Ratio of maximum loadࡣࡌࡵ࡟↓ฎ⌮ࡢሙྜ㸦●ࣉࣟࢵࢺ㸧࡟ࡘ࠸࡚ࠊᮌᮦࣂࣝࢡࡢᣲືࡣ⥺ᙧᣲືࢆ♧ࡋࡓࡢ࡟ᑐࡋࠊࢭ࣮ࣝࣟࢫࡣᴫࡡ⥺ᙧᣲືࢆ♧ࡋࡓࡶࡢࡢࠊᮌᮦࣂࣝࢡࡢᣲື࡜ࡣᚲࡎࡋ
ࡶ୍⮴ࡏࡎࠊࢭ࣮ࣝࣟࢫࡢࡦࡎࡳࡢ᪉ࡀᑠ
ࡉ࠸ࡇ࡜ࡀࢃ࠿ࡿࠋ150Υࡢ⇕ฎ⌮ࢆ᪋ࡋࡓ

1.0
0.8
0.6
0.4
0.2
0.0

ሙྜࠊࡍ࡭࡚ࡢ᮲௳࡛ᮌᮦࣂࣝࢡ࡜ࢭࣝࣟ

UnML3% ML4% ML6% ML3% ML4% ML18%
modified

150 䢛C࣮ࢫඹ࡟᭱኱Ⲵ㔜ࡢῶᑡࡀㄆࡵࡽࢀࡓࠋ୍

180 䢛C

Fig. 2 ᭱኱Ⲵ㔜ẚ㸦[3]ࢆᨵኚ㸧᪉ࠊ᭱኱ࡦࡎࡳ࡛ࡣᮌᮦࣂࣝࢡ࡜ࢭ࣮ࣝࣟ
ࢫࡢഴྥࡀ␗࡞ࡾࠊࢭ࣮ࣝࣟࢫ࡛ࡣ⇕ฎ⌮࡟ࡼࡾ᭱኱ࡦࡎࡳࡀቑຍࡋࠊML ࡟ࡼࡿ㐪࣮ࣝࣟࢫࡢᘬᙇᣲື㸦Ⲵ㔜ࡢቑຍ࡟క࠸ࡦ

࠸ࡣㄆࡵࡽࢀ࡞࠿ࡗࡓࠋ

ࡎࡳࡀቑຍࡍࡿ㸧ࡀṆࡲࡗࡓᚋ㸦᭱኱ࡦࡎࡳ ࡇࡇ࡛ࠊ⇕ฎ⌮ࡀᮌᮦࣂࣝࢡ࡜ࢭ࣮ࣝࣟ

ᚋ㸧ࡶᮌᮦࣂࣝࢡࡢⲴ㔜ࡣࡉࡽ࡟ୖ᪼ࢆ⥆ࢫࡢຊᏛᛶ⬟࡟ཬࡰࡍᙳ㡪ࢆㄪ࡭ࡿࡓࡵ࡟ࠊ

ࡅࠊ◚᩿ࡍࡿࡲ࡛⪏࠼ࡓࡇ࡜ࡀ⪃࠼ࡽࢀࡿࠋ

᭱኱Ⲵ㔜࡜᭱኱ࡦࡎࡳ࡟ࡘ࠸࡚ࠊᮌᮦࣂࣝ

ḟ࡟ࠊ᭱኱ࡦࡎࡳẚࢆ⇕ฎ⌮᮲௳ࡈ࡜࡟

ࢡ࡟ᑐࡍࡿࢭ࣮ࣝࣟࢫࡢẚ⋡ࢆㄪ࡭ࡓࠋ௨

Fig. 3 ࡟♧ࡍࠋࢢࣛࣇࡼࡾ↓ฎ⌮ࡢሙྜࢭ㝆ࠊ᭱኱Ⲵ㔜ẚࠊ᭱኱ࡦࡎࡳẚ࡜⛠ࡍࠋࡣࡌ࣮ࣝࣟࢫࡢ᭱኱ࡦࡎࡳࡣᮌᮦࣂࣝࢡࡢࡑࢀ

ࡵ࡟ࠊ᭱኱Ⲵ㔜ẚࢆ⇕ฎ⌮᮲௳ࡈ࡜࡟ Fig.2

ࡢ࠾ࡼࡑ 0.5 ಸ࡛࠶ࡿࠋ150 ºC ⇕ฎ⌮࡛ࡣ࡟♧ࡍࠋ↓ฎ⌮ࡢሙྜࡣࠊ࡯ࡰ㸯࡟㏆࠸್ࢆ↓ฎ⌮࡜ẚ㍑ࡋ࡚ࠊML ࡟ẚ౛ࡋ࡚᭱኱ࡦ

♧ࡋࠊᮌᮦࣂࣝࢡࡢ◚᩿ࡢ┤๓ࡲ࡛ࢭࣝࣟ

ࡎࡳẚࡀቑຍࡍࡿഴྥ࡜࡞ࡗࡓࠋ≉࡟ ML࣮ࢫࡣᘬᙇᣲືࢆ♧ࡋ࡚࠸ࡓࡇ࡜ࡀࢃ࠿ࡿࠋ

6%࡛ࡣ࠾ࡼࡑ 0.9 ಸ࡜࡞ࡾࠊࢭ࣮ࣝࣟࢫࡣ

࡞࠾ࠊS2 ᒙࢭ࣮ࣝࣟࢫ࡟స⏝ࡍࡿⲴ㔜ࡣࠊᮌᮦࣂࣝࢡ࡜ྠ⛬ᗘࡲ࡛ఙ㛗ࡋ࡚࠸ࡿࡇ࡜

ࢭ࣮ࣝࣟࢫࡢ㓄ྥ᪉ྥ㸦MFAҸ9.0°㸧࡬ࡢࡀࢃ࠿ࡿࠋḟ࡟ࠊ180 ºC ⇕ฎ⌮ᮦ࡛ࡣࠊMLศຊ࡜ࡋ࡚ホ౯ࡋ࡚࠸ࡿࡓࡵࠊᮌᮦࣂࣝࢡ

3%࠾ࡼࡧ 4%ࡢ᭱኱ࡦࡎࡳẚࡣࠊ150ºC ⇕࡜ࢭ࣮ࣝࣟࢫ࡟స⏝ࡋࡓⲴ㔜ࡢẚࡣ⣙ฎ⌮ࡢྠࡌ ML ࡜ྠ⛬ᗘ࡛࠶ࡿࡀࠊ
ML 18%

0.988 ࡛࠶ࡿࠋ⇕ฎ⌮ࡢ ML 3%࠾ࡼࡧ 4%࡛ࡣపୗࡋࠊ᭱኱ࡦࡎࡳẚࡣ࠾ࡼࡑ 0.4 ಸ࡛ࡣࠊ୧ᗘ࡜ࡶ↓ฎ⌮࡜ྠᵝ࡟᭱኱Ⲵ㔜ࢀࡽࡢ᮲௳ୗ࡟࠾ࡅࡿ⇕ฎ⌮ࡀᮌᮦࣂࣝࢡ
࡜ࢭ࣮ࣝࣟࢫࡢ᭱኱Ⲵ㔜࡟ཬࡰࡍᙳ㡪ࡣ࡯࡜ࢇ࡝ྠ⛬ᗘ࡛࠶ࡗࡓ࡜⪃࠼ࡽࢀࡿࠋ୍᪉ࠊ
150 ºC ⇕ฎ⌮ ML 6%࠾ࡼࡧ 180 ºC ⇕ฎ⌮
ML 18%ࡢ᭱኱Ⲵ㔜ẚࡣ↓ฎ⌮࡟ᑐࡋ࡚᫂

Ratio of maximum strainẚࡣ 1 ࡟㏆࠸್ࢆ♧ࡋࡓࠋࡋࡓࡀࡗ࡚ࠊࡇ

1.4
1.2
1.0
0.8
0.6
0.4
0.2
0.0 Un-ࡽ࠿࡟పୗࡋࠊࡑࢀࡒࢀ 0.87ࠊ0.17 ࡛࠶ࡗ

modifiedࡓࠋ≉࡟ࠊ180 ºC ⇕ฎ⌮ ML 18%ࡢ᭱኱Ⲵ㔜ẚࡢపୗࡀ㢧ⴭ࡛࠶ࡿࠋ⌧㇟࡜ࡋ࡚ࡣࠊࢭ

ML3% ML4% ML6% ML3% ML4%ML18%

150 䢛C180 䢛C

Fig. 3 ᭱኱ࡦࡎࡳẚ㸦[3]ࢆᨵኚ㸧14࡜࡞ࡗࡓࠋࡍ࡞ࢃࡕࠊ⇕ฎ⌮ࡀ᭱኱ࡦࡎࡳẚㅰ㎡࡟ཬࡰࡍᙳ㡪ࡣᗘ࡛␗࡞ࡿࡇ࡜ࡀ᫂ࡽ࠿

ᮏ◊✲ࡢᐇ㦂ࡣ࠶࠸ࡕࢩࣥࢡࣟࢺࣟࣥග

࡟࡞ࡗࡓࠋࡇࡢࡇ࡜࠿ࡽࠊࢭ࣮ࣝࣟࢫ⮬㌟ࡀ

ࢭࣥࢱ࣮ࡢ BL8S1 ࡛ᐇ᪋ࡋࡓࠋࡈ༠ຊ࠸ࡓ

ศゎࡍࡿ 180 ºC ⇕ฎ⌮ࡔࡅ࡛࡞ࡃࠊࢭࣝࣟ

ࡔ࠸ࡓ㛵ಀ⪅ࡢⓙᵝ࡟ࡣㅰពࢆ⾲ࡍࡿࠋ࣮ࢫ࡜⣽⬊ቨࡢ࣐ࢺࣜࢡࢫࡢ⤖ྜせ⣲࡛࠶ࡿ࣑࣊ࢭ࣮ࣝࣟࢫࡢ⇕ศゎ࡟ࡼࡗ࡚ࡶࠊ⣽ཧ⪃ᩥ⊩⬊ቨ୰ࡢࢭ࣮ࣝࣟࢫࡢᣲືࡣኚ໬ࡍࡿࡇ࡜

[1] ౛ ࠼ ࡤ K. Endo et al., “Effects ofࡀ♧ࡉࢀࡓࠋ

heating

4. ࡲ࡜ࡵ

properties␲ఝྂᮦ໬ฎ⌮࡜ࡋ࡚⇕ฎ⌮㸦150Υ࠾ࡼ

sprucehumidityofthephysicalhydrothermallytreatedwood”,

on

Wood

Sci.

Technol.

ࡧ 180Υ㸧ࢆ᪋ࡋࡓᮌᮦࢆᑐ㇟࡟ࠊᘬᙇ㈇Ⲵ

50:1161–1179 (2016).

స⏝ୗ࡛ XRD

ᐃࢆ⾜࠸ࠊ⣽⬊ቨ S2 ᒙෆ[2] ౛ ࠼ ࡤ N. Sobue et al., “On theࡢࢭ࣮ࣝࣟࢫࡢᣲື࡜ᮌᮦࣂࣝࢡࡢᣲືࢆ

measurement of strain distribution inẚ㍑ࡋࡓࠋࡑࡢ⤖ᯝࠊ୧ ᗘ᮲௳࡟࠾࠸࡚⇕wood under the axial tension force by X-ฎ⌮࡟ࡼࡿ㔜㔞ῶᑡ⋡ࡀ኱ࡁ࠸ሙྜ࡟ࡣࠊ

rayᮌᮦࣂࣝࢡࡼࡾࡶඛ࡟ෆ㒊ࡢࢭ࣮ࣝࣟࢫࡣ

(1971).

ᘬᙇᣲືࢆ♧ࡉ࡞ࡃ࡞ࡿሙྜࡀ࠶ࡿࡇ࡜ࡀ

[3] Kojima, E et al., “Effects of thermalࢃ࠿ࡗࡓࠋࡲࡓࠊ150Υࡢ⇕ฎ⌮࡛ࡣ᭱኱ࡦ

modification on the mechanical propertiesࡎࡳẚࡣቑຍഴྥࢆࠊ180Υࡢ⇕ฎ⌮࡛ࡣῶ

of the wood cell wall of soft wood: behaviorᑡഴྥࢆ♧ࡋࡓࠋࡇࡢ㐪࠸ࡣ୺࡟ࢭ࣮ࣝࣟ

of S2 cellulose microfibrils under tensileࢫ࡜࣐ࢺࣜࢡࢫࡢ⤖ྜせ⣲࡛࠶ࡿ࣑࣊ࢭࣝ

loading”, J. Mater. Sci. 55: 5038–5047

࣮ࣟࢫࡀศゎࡉࢀࡓ࠿ࠊ࠶ࡿ࠸ࡣࢭ࣮ࣝࣟ

(2020).

ࢫ⮬㌟ࡀศゎࡉࢀࡓ࠿ࡢ㐪࠸࡟ࡼࡿ࡜᥎ᐹ

[4]ࡉࢀࡓࠋ≉࡟࣑࣊ࢭ࣮ࣝࣟࢫࡢῶᑡࡣᮌᮦ

distribution of cellulose crystallites inࡢྂᮦ໬ࡢ୰࡛㢧ⴭ࡞ኚ໬ࡢ୍ࡘ࡛࠶ࡿࠋ

woody plants. Part I.: Pole-figures andᘓ⠏ゎయᮦ࡞࡝࠿ࡽ౪ヨᮦࢆᚓࡿࡇ࡜࡛ࠊ

orientation⇕ฎ⌮ᮌᮦ࡜ྂᮦࢆẚ㍑ࡋࠊྂᮦ໬ࡢຊᏛ

crystallites in opposite wood of Pinusⓗ࣓࢝ࢽࢬ࣒ࡢゎ᫂࡟ࡘ࡞ࡆࡓ࠸ࠋ

densiflora”, Wood Res. Bull. Wood Res.

diffraction”,

F.

TanakaZairyoetal.,functions

20:1188-1193“Orientationofcellulose

Inst. Kyoto Univ. 66:17–22 (1980).




15

ࣜࢳ࣒࢘࢖࢜ࣥ㟁ụṇᴟᮦᩱ Li(Ni1/3Co1/3Mn1/3)O2 ࡢຎ໬ゎᯒa(බ㈈)⛉Ꮫᢏ⾡஺ὶ㈈ᅋ

࠶࠸ࡕࢩࣥࢡࣟࢺࣟࣥගࢭࣥࢱ࣮ࠊb ࣉࣛ࢖࣒࢔࣮ࢫ EV ࢚ࢼࢪ࣮ᰴᘧ఍♫ࠊc ❧࿨㤋኱Ꮫ㹑㹐ࢭࣥࢱ࣮Ọぢဴኵ aࠊ㔝ᮏ㇏࿴ a, †ࠊᮡᒣ㝧ᰤ aࠊ❧ᮌ⩧἞ a, †ࠊᆏᮏᗮ bࠊኴ⏣ಇ᫂ aࠊcࡇࡢグ஦ࡣྑグㄽᩥࢆ୍㒊ಟṇࡋࡓෆᐜ࡛࠶ࡿ(OHFWURFKHPLVWU\    㸬 ࡣࡌࡵ࡟

ࢀࡽ࡟ࡘ࠸࡚⪏ஂ࡟క࠺໬Ꮫ≧ែኚ໬ࠊ⤖ᬗᵓ㐀 ࢚ࢿࣝࢠ࣮㈨※ࡢᯤῬࠊᆅ⌫ ᬮ໬ࡀ㔜せ࡞ㄢ

ኚ໬ࢆ㌾X⥺྾཰ศග(XAS)ࠊX⥺⢊ᮎᅇᢡ(XRD)㢟࡟࡞ࡗ࡚ࡁࡓ᫖௒ࠊ஧ḟ㟁ụ࡬ࡢ㟂せࡣࡲࡍࡲ࡟ࡼࡗ࡚ㄪ࡭ࡓ⤖ᯝ࡟ࡘ࠸࡚ሗ࿌ࡍࡿࠋࡑࡋ࡚ࠊ

ࡍ㧗ࡲࡾࡘࡘ࠶ࡿࠋ஧ḟ㟁ụࡣṇᴟ࡟ LiCoO2 ࢆࡇࢀࡲ࡛ࡢຎ໬ゎᯒሗ࿌࡜ࡢẚ㍑᳨ウࢆ⾜࠺ࠋ⏝࠸ࡓࣜࢳ࣒࢘࢖࢜ࣥ㟁ụ (LIB) ࡀ㛤Ⓨࡉࢀ࡚㣕㌍ⓗ࡞㐍Ṍࢆ㐙ࡆࠊࡑࢀ࡟కࡗ࡚LIBࡢ㧗ᛶ⬟㸬 ヨᩱࡢస〇࡜ホ౯ἲ໬࡟ྥࡅࡓ◊✲ࡀ⏘ᐁᏛࢆၥࢃࡎ┒ࢇ࡟࡞ࡗࡓࠋ

⪏ஂヨ㦂⏝㟁ụヨᩱࡢస〇㧗 ౯ ࡛ ᭷ ẘ ࡞ Co ࢆ Ni ࡸ Mn ࡟ ⨨ ࡁ ᥮ ࠼ ࡓ ṇᴟά≀㉁NCM⢊ᮎ࡟ᑟ㟁ຓ๣࢔ࢭࢳࣞࣥࣈ

Li(Ni1/3Co1/3Mn1/3)O2ࡀᐇ⏝໬ࡉࢀࡓࡀ1ࠊࡇࢀࡽࣛࢵࢡ㸦௨ୗAB㸧ࠊ⤖╔๣PVDF(PolyVinylidene

Liࠊ Mn࠶ࡿ࠸ࡣNiࡢ⤌ᡂࢆኚ࠼ࡓࡾࠊ௚ࡢඖ⣲DiFluoride)ࢆΰྜࡋࡓ࣮࣌ࢫࢺࢆ࢔࣑ࣝࢽ࣒࢘

ࢆᑟධࡍࡿࡇ࡜࡛ࠊࡉࡽ࡟㧗࠸࢚ࢿࣝࢠ࣮ᐦᗘࢆ

⟩࡟ሬᕸࡋ࡚஝⇱ࡉࡏࡓࡶࡢࢆṇᴟᯈ࡜ࡋ࡚⏝࠸ᣢࡘ㟁ụᮦᩱࡢ㛤Ⓨࡀඖ⣲ᡓ␎ⓗ࡟㐍ࡵࡽࢀ࡚࠸

ࡓࠋ㈇ᴟᯈࡣⅣ⣲⢊ᮎ࡜⤖╔๣ࢆΰྜࡋࡓ࣮࣌ࢫ

ࡿࠋࢺࢆ㖡ᯈୖ࡟ሬᕸࡋࡓࡶࡢ࡛࠶ࡾࠊࢭࣃ࣮ࣞࢱ࡜ ஧ḟ㟁ụࡢ㧗ᛶ⬟໬࡜ࡣࠊ࢚ࢿࣝࢠ࣮ᐦᗘࡀ㧗ࡋ ࡚ PP(Polypropyrene)/PE(Polyethylene)/PP ࡢ࠸ࡇ࡜ࡣࡶࡕࢁࢇ࡛࠶ࡿࡀࠊࢧ࢖ࢡࣝ≉ᛶࡀⰋ࠸

3ᒙᵓ㐀ᚤከᏍᛶ᭷ᶵⷧ⭷ࢆ⏝࠸ࠊࡇࢀࡽࢆ㟁ụࡇ࡜ࠊᏳ඲࡛ࡋ࠿ࡶࠊᗮ౯࡛࠶ࡿࡇ࡜ࡶᐇ⏝㟁ụࢣ࣮ࢫ࡟ᤄධࡋࡓࠋࡇࢀ࡟㟁ゎᾮ࡜ࡋ࡚LiPF6/࢚࡜ࡋ࡚㔜せ࡟࡞ࡿࠋ㛗ᑑ࿨࡛฼⏝ฟ᮶ࡿ㟁ụ㛤Ⓨࢳ࣮ࣞࣥ࢝࣎ࢿ࣮ࢺ(EC)/࢚ࢳ࣓ࣝࢳ࣮ࣝ࢝࣎ࢿ

ࡢࡓࡵ࡟ࠊ᪂ᮦᩱࡢ㛤Ⓨ࡜୪⾜ࡋ࡚ࠊ㟁ụࡢຎ໬࣮ࢺ(EMC)/ࢪ࣓ࢳ࣮ࣝ࢝࣎ࢿ࣮ࢺ(DMC)ΰྜ⁐ゎᯒࡢ◊✲ࡶᩘከࡃࡉࢀ࡚࠸ࡿࠋࡋ࠿ࡋࠊ㟁ụᮦᾮࢆὀධࡋ࡚ᐦᑒࡋヨ㦂⏝㟁ụ࡜ࡋࡓࠋ⪏ஂヨ㦂ᩱࡣ」㞧࡞⣔࡛࠶ࡾࠊྠࡌṇᴟᮦᩱ࡛ࡶࡑࡢ⢏ᚄ⏝࡟ 2 ✀㢮ࡢ㟁ụࢆ⏝ពࡋࡓࠋ ࢧ࢖ࢡࣝ⪏ஂရࡸᑟ㟁ຓ๣ࠊ㟁ゎᾮࡢ✀㢮ࠊ඘ᨺ㟁㐣⛬࡟࠾ࡅࡿ

ࡣࠊ85 °Cࠊ඘ᨺ㟁࣮ࣞࢺ2C/2Cࠊ࢝ࢵࢺ࢜ࣇ㟁ᅽ࢝ࢵࢺ࢜ࣇ㟁ᅽ㸦඘㟁⋡㸧ࠊ඘ᨺ㟁࣮ࣞࢺࠊ ᗘ

3.0–4.1V/ࢭ࡛ࣝ250ࠊ500࠾ࡼࡧ1000ࢧ࢖ࢡࣝ඘

࡞࡝ᵝࠎ࡞せᅉ࡟ࡼࡗ࡚ຎ໬ࡢ௙᪉ࡶ␗࡞ࡗ࡚࠸

ᨺ㟁ࢆ⾜ࡗࡓࡶࡢ࡛࠶ࡿࠋಖᏑ⪏ஂရࡣࠊ3.7ࠊ4.0

ࡿ2ࠋゎᯒࡢᡭἲࡶᵝࠎ࡛࠶ࡾࠊࡑࡢ⤖ᯝ࡜ࡋ࡚ࠊ

࠾ࡼࡧ4.1V/ࢭࣝ࡟඘㟁ᚋ70 °Cࠊ150᪥㛫ಖᏑࡋ࠸ࢁ࠸ࢁ࡞ຎ໬≧ែࡀሗ࿌ࡉࢀ࡚࠸ࡿࠋ௦⾲ⓗ࡞ࡓࡶࡢ࡛࠶ࡾࠊࡇࢀࡽࡢ඘㟁≧ែ(State of Chargeࠊࡶࡢ࡜ࡋ࡚ࡣࠊຎ໬࡜࡜ࡶ࡟㟁ᴟ⾲㠃ࡢᵓ㐀ࡀኚ

SOC)ࡣࡑࢀࡒࢀ60ࠊ 90ࠊ 100%࡟ᑐᛂࡋ࡚࠸ࡿࠋ

໬ࡋࡓࡾ3,4ࠊ๪⏕ᡂ≀ࡀሁ✚ࡍࡿࡇ࡜࡟ࡼࡿࡶࡢ

⪏ஂヨ㦂ᚋࡢ㟁ụࢭࣝࢆศゎࡋࠊࣜࢳ࣒࢘ࢆ㈇ᴟ

5,6ࠊ㓟⣲㞳⬺ࡀ㉳ࡇࡾࠊNiࡀLiᒙ࡟୙ྍ㏫ⓗ࡟ධ࡜ࡍࡿࣁ࣮ࣇࢭࣝࢆస〇ᚋSOC 0%ရ㸦ᨺ㟁≧ែ㸧ࠊࡾ㎸ࢇ࡛ࡋࡲ࠺7,8ࠊ࡞࡝ࡀᣲࡆࡽࢀࡿࠋ

࠾ࡼࡧSOC 100%ရ㸦඘㟁ရ㸧࡟ㄪᩚࡋࡓࠋࡇࢀ ࡇࡇ ࡛ࡣ ࠊ᭱ࡶ ୍⯡ⓗ ࡜ᛮ ࢃࢀ ࡿṇᴟ ᮦᩱࡽࢆࢢ࣮ࣟࣈ࣎ࢵࢡࢫ୰࡛ศゎࡋ࡚ṇᴟ㒊ศࢆྲྀLi(Ni1/3Co1/3Mn1/3)O2㸦௨ୗNCM࡜࿧ࡪ㸧ࢆ⏝࠸ࡾฟࡋࠊEMC࡬ࡢᾐₕ10ศࢆ2ᅇ⧞ࡾ㏉ࡋ࡚௜╔ࡓ⣔ࢆᑐ㇟࡟ࡋ࡚ࠊ࡛ࡁࡿࡔࡅ࣐࢖ࣝࢻ࡞᮲௳ࡢ

ࡋࡓ㟁ゎᾮࢆ㝖ཤࡋࡓࠋࡶ࡜࡛ࢧ࢖ࢡࣝ⪏ஂရࠊಖᏑ⪏ஂရࢆస〇ࡋࠊࡇ͊ ⌧࠶࠸ࡕ⏘ᴗ⛉Ꮫᢏ⾡⥲ྜࢭࣥࢱ࣮




16

ホ౯ᐇ㦂᥇⏝ࡋࡓࠋヨᩱࡣࠊࢢ࣮ࣟࣈ࣎ࢵࢡࢫෆ࡛ṇᴟヨ ṇᴟࡢᐜ㔞ຎ໬ ᐃᩱࢆษࡾฟࡋࡓࡶࡢࢆ኱Ẽ㠀ᭀ㟢ࡢࡲࡲ ᐃࢳ࢙ ึᮇရ㸦㟁ụࢆస〇ᚋࠊࢥࣥࢹ࢕ࢩࣙࢽࣥࢢ࡜

ࣥࣂ࣮࡟ᑟධࡋࡓࠋ ᐃ࡟ࡣ⾲㠃ᩄឤ࡞඲㟁Ꮚ཰ࡋ࡚ᩘࢧ࢖ࢡࣝࡢ඘ᨺ㟁ࢆᐇ᪋ࠊ௨ᚋ0 cycle࡜ࡶ㔞(TEY)ἲࢆ⏝࠸ࠊࣂࣝࢡᩄឤ࡞㒊ศ⺯ග཰㔞࿧ࡪ㸧ࠊ࠾ࡼࡧࠊ⪏ஂရ࡟ࡘ࠸࡚ࠊᐜ㔞ຎ໬⋡ࢆ

(PFY)ἲࡶే⏝ࡋࡓࠋㄪᰝࡋࡓࠋᐇ㦂࡟ࡣࠊึᮇရࡲࡓࡣ⪏ஂရࡢṇᴟࢆస⏝ᴟࠊ㔠ᒓࣜࢳ࣒࢘ࢆᑐᴟࠊཧ↷ᴟ࡜ࡋࠊ㸬 ⤖ᯝ࡜⪃ᐹ

LiPF6/EC/EMC/DMCࢆ㟁ゎᾮ࡜ࡋࡓࣅ࣮࣮࢝ࢭ

ᐜ㔞ຎ໬ࣝࢆస〇ࡋࡓࠋ࿘ᅖ

ᗘ25 °Cࠊ඘ᨺ㟁࣮ࣞࢺ

 Figure 1(a)࡟ࢧ࢖ࢡࣝ⪏ஂရࠊ(b)࡟ಖᏑ⪏ஂရ

0.2C/0.2Cࠊ࢝ࢵࢺ࢜ࣇ㟁ᅽࢆ3.0–4.3V/ࢭࣝ࡜ࡋࡢ඘ᨺ㟁᭤⥺ࢆ♧ࡋࡓࠋࡲࡓࠊTable 1࡟ᐜ㔞࡜ࡑ

࡚3ࢧ࢖ࢡࣝᐇ᪋ࡋࠊࡑࢀࡒࢀࡢ඘ᨺ㟁᭤⥺ࢆࡢຎ໬⋡ࢆ♧ࡍࠋࢧ࢖ࢡࣝ⪏ஂရ࡟࠾࠸࡚ࡣࠊࢧ

ᐃࡋࡓࠋࡑࡋ࡚ࠊ3ࢧ࢖ࢡࣝ┠ࡢᐜ㔞್ࡼࡾᐜ㔞ຎ࢖ࢡࣝᩘࡢቑຍ࡜ඹ࡟ᐜ㔞ຎ໬ࡀ㐍⾜ࡋࠊࡑࡢኚ

໬⋡ࢆồࡵࡓࠋ

໬ࡢᗘྜ࠸ࡣᑐᩘⓗ࡛࠶ࡿࡇ࡜ࡀ☜ㄆࡉࢀࡓࠋࡇ ஧ḟ⢏Ꮚࡢ㹑㹃㹋ほᐹࢀ࡟ᑐࡋ࡚ࠊಖᏑ⪏ஂရࡢሙྜࠊኚ໬ࡢᗘྜ࠸ࡣ 㟁ụຎ໬࡟࠾ࡅࡿ஧ḟ⢏Ꮚࡢ≧ែࢆほᐹࡍࡿᣦᩘⓗ࡛ࠊಖᏑ᫬ࡢ㟁ᅽࡀ4.0V/ࢭࣝ࠿ࡽࢃࡎ࠿

ࡓࡵ࡟ࠊึᮇရࠊ4.1V/ࢭࣝ඘㟁ᚋ࡟150᪥㛫ಖᏑ

0.1V/ࢭࣝቑຍࡍࡿ࡜ຎ໬⋡ࡣ2ಸ࡟ୖ᪼ࡍࡿࠋ࢝

ࡋࡓ⪏ஂရࠊ࠾ࡼࡧࠊ1000ࢧ࢖ࢡࣝ㏻㟁⪏ஂရࡢࢵࢺ࢜ࣇ㟁ᅽࡀ4.0V/ࢭࣝࢆ㉸࠼ࡿ࡜ᛴ⃭࡟ቑຍᨺ㟁᫬ࡢヨᩱ࡟ࡘ࠸࡚ࠊ
㉮ᰝᆺ㟁Ꮚ㢧ᚤ㙾⿦⨨㸦᪥ࡋ࡚࠾ࡾࠊ4.1V/ࢭࣝࡲ࡛ୖࡆ࡚ಖᏑࡍࡿࡇ࡜ࡀຎ

❧ࣁ࢖ࢸࢡSU8030㸧ࢆ⏝࠸ࠊຍ㏿㟁ᅽ3.0 kV࡟࡚໬ࡢ኱ࡁ࡞せᅉ࡛࠶ࡿࡇ࡜ࢆ♧ࡋ࡚࠸ࡿࠋ

ṇᴟษ᩿㠃ࡢSEMほᐹࢆ⾜ࡗࡓࠋ 㹖㹐㹂 ᐃ
 XRDࡣࠊ࠶࠸ࡕࢩࣥࢡࣟࢺࣟࣥගࢭࣥࢱ࣮
Potential (V vs. Li/Li+)

BL5S2࡟࡚⾜ࡗࡓࠋᐇ㦂ࡣࠊᖖ ኱Ẽୗ࡛ࠊධᑕ
࢚ࢿࣝࢠ࣮18 keVࠊ ᐃ⠊ᅖࢆ3㹼95°࡟ࡋࡓࠋヨᩱࡣࡍ࡭࡚ᨺ㟁≧ែ(SOC 0%)ࡢࡶࡢ࡛࠶ࡾࠊṇᴟ࠿ࡽ࠿ࡁྲྀࡗࡓ⢊ᮎࢆෆᚄ0.2mmࡢࣜࣥࢹ࣐ࣥࣥ࢞ࣛࢫ〇࢟ࣕࣆࣛࣜ࢕࡟඘ሸࡋᑒṆࡋࡓࡶࡢࢆ
⏝ ࠸ࡓ ࠋᚓ ࡽࢀࡓ ⤖ᯝ࡟ ᑐࡋ ࡚ࠊ ᒙ≧ᒾ ሷᆺ
hexagonalᵓ㐀ࢆ௬ᐃࡋ࡚࣮ࣜࢺ࣋ࣝࢺゎᯒࢆᐇ
᪋ࡋࠊa㍈ࠊc㍈ࡢ㛗ࡉࠊ࠾ࡼࡧࡑࡢẚࢆồࡵࡓࠋ࡞࠾ࠊ඘㟁≧ែ࡛ࡢ ᐃࡶヨࡳࡓࡀࠊゎᯒ࡟⪏࠼࠺ࡿ‶㊊࡞ࢹ࣮ࢱࡣᚓࡽࢀ࡞࠿ࡗࡓࠋ
 ㌾㹖⥺㹖㸿㹑

ᐃ MnࠊCoࠊNi L➃XASࠊ࠾ࡼࡧCࠊOࠊF K➃XAS
ࢫ࣌ࢡࢺࣝࡢ ᐃࡣࠊ࠶࠸ࡕࢩࣥࢡࣟࢺࣟࣥගࢭ
ࣥࢱ࣮BL1N2㌾X⥺ศගࣅ࣮࣒ࣛ࢖ࣥ࡟࡚⾜ࡗࡓࠋ ᐃᑐ㇟ඖ⣲ࡢ྾཰➃ࡀ㏆ࡃࠊࣂࢵࢡࢢࣛࣥࢻホ౯ࡢ᭕᫕ࡉࢆ㑊ࡅࡿࡓࡵࠊ1ࢫ࣌ࢡࢺࣝ୰࡟
㞄ࡾྜ࠺ඖ⣲ࡢࢫ࣌ࢡࢺࣝࢆ」ᩘྵࡴ ᐃ᪉ἲࢆ



17



ᙧែኚ໬
 Figure 2࡟NCM஧ḟ⢏Ꮚ᩿㠃ࡢSEMほᐹ⤖ᯝࢆ♧ࡍࠋࡍ࡭࡚ࡢ෗┿࡟ほ ࡉࢀࡿ⦪➽ࡣ◊☻യ࡟ࡼࡿࡶࡢ࡛࠶ࡿࠋึᮇရࡣ஧ḟ⢏Ꮚࡀ⦓ᐦ࡟㞟ྜࡋ࡚࠾ࡾࠊ⢏⏺ࢆㄆ㆑ࡋ㞴࠸㒊఩ࡀ㝶ᡤ࡟ぢࡽ
ࢀࡿࠋ4.1V/ࢭࣝ඘㟁ಖᏑ⪏ஂရࡢ≧ែࡣึᮇရ࡟
㏆࠸ࡀࠊ⢏⏺࡟㛫㝽ࡀ⏕ࡌጞࡵ࡚࠸ࡿ㒊఩ࡀᏑᅾࡋࡓࠋ୍᪉ࠊ1000ࢧ࢖ࢡࣝ⪏ஂᚋࡢヨᩱ࡛ࡣ஧ḟ⢏Ꮚ㛫࡟0.1μmᙅࡢࢡࣛࢵࢡࡀ඲㠃࡟Ⓨ⏕ࡋ࡚࠸ࡓࠋࢧ࢖ࢡࣝ⪏ஂရ࡛ࡣ඘ᨺ㟁ࡀ⧞ࡾ㏉ࡉࢀࡿࠋ
NCMࡣ඘㟁࡟కࡗ࡚a㍈ࡣ཰⦰ࡋࠊc㍈ࡣఙ㛗ࡋࠊᨺ㟁᫬࡟ࡣྍ㏫ⓗ࡟ࡶ࡜࡟ᡠࡿࡇ࡜ࡀ▱ࡽࢀ࡚࠸㟁ᗘࡀ㧗࠸࡯࡝a㍈ࡀࢃࡎ࠿࡟▷ࡃ࡞ࡾࠊc㍈ࡀ㛗ࡃ࡞ࡿഴྥࡀᚓࡽࢀࡓࠋຎ໬࡟ࡼࡗ࡚ṇᴟ⾲㠃ࡀࡿ8ࠋࡋ࠿ࡋࠊ඘ᨺ㟁ࡀ⧞ࡾ㏉ࡉࢀࡿ࡜ࡸࡀ࡚⢏⏺

ࢫࣆࢿࣝᵓ㐀࡟┦ኚ໬ࡍࡿ࡜࠸࠺ሗ࿌ࡀ࠶ࡿࡀ3,4ࠊ࡟ṍࡀ⏕ࡌࠊࢡࣛࢵࢡⓎ⏕࡟⮳ࡗࡓ࡜ᛮࢃࢀࠊࡇ

ࢫࣆࢿࣝ┦LiNi2O4 ࡢᅇᢡࣃࢱ࣮ࣥࡣNCM࡜࡯ࢀࡀᐜ㔞ຎ໬࡟኱ࡁࡃຠ࠸࡚࠸ࡿ࡜⪃࠼ࡽࢀࡿࠋ

ࡰ୍⮴ࡋ࡚࠸ࡿࡓࡵ࡟ࠊࡑࢀࢆぢศࡿࡇ࡜ࡣ࡛ࡁ
࡞࠿ࡗࡓࠋ⤖ᬗᵓ㐀ኚ໬ NCMࡣᒙ≧ᒾሷᆺ࡛hexagonalᵓ㐀ࢆࡋ࡚࠾
Intensity (a.u.)ࡾࠊୖ㏙ࡢࡼ࠺࡟඘ᨺ㟁࡟ࡼࡗ࡚a㍈࡜c㍈ࡢ㛗ࡉࡀྍ㏫ⓗ࡟ኚ໬ࡍࡿࠋࡇࡇ࡛ᚓࡽࢀࡓ⤖ᯝࡣᨺ㟁᫬ࡢࡶࡢࡔࡅ࡛࠶ࡿࡀࠊ1000 cycle⪏ஂရࡢXRD
ࣃࢱ࣮ࣥ࡜࣮ࣜࢺ࣋ࣝࢺゎᯒ࡟ࡼࡿࢩ࣑࣮ࣗࣞࢩ
ࣙࣥࡢ⤖ᯝࢆFig. 3࡟♧ࡋࡓࠋRwp್ࡣึᮇရ࡛
5.8%ࠊຎ໬ࡀ㐍ࡴ࡟ࡘࢀ࡚኱ࡁࡃ࡞ࡾ1000 cycle⪏ஂရ࡛7.2%ࡲ࡛࡟࡞ࡾࠊຎ໬࡟ࡼࡗ࡚ᵓ㐀ࡢ஘ࢀࡀቑ࠼࡚࠸ࡃࡇ࡜ࢆ཯ᫎࡋ࡚࠸ࡿࠋゎᯒࡢ⤖ᯝᚓࡽࢀࡓa㍈㛗ࠊc㍈㛗ࠊ࠾ࡼࡧc㍈㛗/a㍈㛗ࢆᐜ㔞ຎ໬⋡࡟ᑐࡋ࡚ࣉࣟࢵࢺࡋࡓࡶࡢࢆFig. 4࡟♧ࡋࡓࠋࢧ࢖ࢡࣝᩘࡀቑຍࡍࡿ࡯࡝ࠊࡲࡓಖᏑ᫬ࡢ඘


18ึᮇရࠊSOC 0%ࡣ853 eV࡟୺ࣆ࣮ࢡࢆᣢࡕࠊ
Ni2+࡛࠶ࡿࡇ࡜ࢆ♧ࡍࠋࡇࢀ࡟ᑐࡋ࡚SOC 100%
࡛ࡣ855 eV࡟୺ࣆ࣮ࢡࡀ⛣ࡿࠋࡇࡢኚ໬ࡣ඘㟁࡟
ࡼࡗ࡚NiࡀNi2+࠿ࡽNi3+ࠊNi4+࡬࡜㓟໬ࡉࢀ㟁Ⲵ⿵ൾࢆᢸࡗ࡚࠸ࡿࡇ࡜ࢆព࿡ࡍࡿࠋKubobuchiࡽࡣ⌮ㄽィ⟬࡜TEYࢫ࣌ࢡࢺࣝࡢẚ㍑࠿ࡽࠊ4.3V/ࢭࣝ༳ຍ᫬ࡢNi౯ᩘࡣ⣙3.4࡟┦ᙜࡍࡿ࡜ሗ࿌ࡋ࡚
࠸ࡿ10ࠋࢧ࢖ࢡࣝᩘࡢቑຍ࡜࡜ࡶ࡟ࠊ඘㟁᫬࡟኱ࡁ࡞ࢫ࣌ࢡࢺࣝኚ໬ࡣほ ࡉࢀ࡞࠸ࡀࠊᨺ㟁᫬࡟㧗࢚ࢿࣝࢠ࣮ഃࡢ⫪ࡀቑ࠼࡚࠸ࡃഴྥࡀ࠶ࡾࠊຎ໬
ࡀ㐍ࡴ࡟ࡘࢀ࡚ࠊᨺ㟁ࡋ࡚ࡶNi2+ࡲ࡛᏶඲࡟ᡠࡽ
࡞ࡃ࡞ࡿࡇ࡜ࢆ♧ࡋ࡚࠸ࡿࠋ
୍᪉ࠊಖᏑຎ໬࡛ࡣࠊ
ಖᏑ㛤ጞ᫬ࡢ㟁఩ࡀ4.0V/ࢭࣝࢆ㉸࠼ࡿ࡜ࠊ඘㟁࡟
ࡼࡗ࡚Ni4+ࡲ࡛⾜ࡁษࢀࡎࠊࢧ࢖ࢡࣝຎ໬ࡢሙྜ
࡜㢧ⴭ࡞㐪࠸ࢆ♧ࡋ࡚࠸ࡿࠋࡇࢀࡽNi L3ࢫ࣌ࢡࢺࣝࢆࠊึᮇရ㸦0ࢧ࢖ࢡࣝ㸧ࠊLiNiO2ࠊNiO2ࡢࢫ 㑄⛣㔠ᒓ㹊➃㹖㸿㹑࣌ࢡࢺࣝࡢ㔜ࡡྜࢃࡏ࡜ࡋ࡚⥺ᙧ⤖ྜゎᯒࢆ⾜ࡗ Figure 5(a)࡟ࠊึᮇ࠾ࡼࡧࢧ࢖ࢡࣝ⪏ஂရࠊ(b)ࡓࠋࡇࡇ࡛ࠊLiNiO2ࠊNiO2ࡢᶆ‽ࢫ࣌ࢡࢺࣝࡣศ

࡟ಖᏑ⪏ஂရࡢࡑࢀࡒࢀSOC 0%㸦ᨺ㟁ရ㸧ࠊ100%ゎ⬟ࡀᝏࡃ࡚ࡇࡢࡲࡲ࡛ࡣゎᯒ࡛ࡁ࡞࠸ࡓࡵࠊࣆ

ရ㸦඘㟁ရ㸧ࡢTEY࣮ࣔࢻ࡛ ᐃࡋࡓNi L3➃XAS

࣮ࢡ఩⨨ࢆྜࢃࡏ࡚࢞࢘ࢫ㛵ᩘ࡛ࣇ࢕ࢵࢸ࢕ࣥࢢ

ࢫ࣌ࢡࢺࣝࢆ♧ࡋࡓࠋᶆ‽ࢫ࣌ࢡࢺࣝ࡜ࡋ࡚ࠊNi2+

ࡋࡓࢫ࣌ࢡࢺࣝࢆ⏝࠸ࡓࠋࡇࢀ࠿ࡽྛヨᩱࡢNiᖹࡣNiO࡜ึᮇရ㸦0ࢧ࢖ࢡࣝ㸧ࠊNi3+ࠊNi4+࡟ࡘ࠸ᆒ౯ᩘࢆồࡵࠊᐜ㔞ຎ໬⋡࡟ᑐࡋ࡚ࣉࣟࢵࢺࡋࡓ

࡚ࡣࡑࢀࡒࢀLiNiO2ࠊNiO2ࡢEELSࢫ࣌ࢡࢺࣝ9

ࡶࡢࡀFig. 6࡛࠶ࡿࠋᨺ㟁᫬ࡢഴྥࡣࠊࢧ࢖ࢡࣝຎ

ࢆేࡏ࡚㍕ࡏࡓࠋ

໬ࠊಖᏑຎ໬ࢆၥࢃࡎᐜ㔞ຎ໬⋡ࡢቑຍ࡜ඹ࡟ᖹ

Normalized unit (a.u.)໬Ꮫ≧ែኚ໬




19

ᆒ౯ᩘࡢቑຍࡀぢࡽࢀࡿࠋ඘㟁᫬࡛ࡣࠊࢧ࢖ࢡࣝ

Co4+࡬ኚ໬ࡍࡿ࡟ࡘࢀ࡚୺ࣆ࣮ࢡࡀ㧗࢚ࢿࣝࢠ࣮

ຎ໬࡛ࡣṤ࡝౯ᩘࡢኚ໬ࡀ࡞ࡃࠊಖᏑຎ໬࡛Ni౯

ഃ࡟ࢩࣇࢺࡋࠊྠ᫬࡟ప࢚ࢿࣝࢠ࣮ഃ࡟⫪ࡀ⌧ࢀᩘࡢῶᑡࡀࡳࡽࢀࡿࠋゎᯒ࡛ᚓࡽࢀࡓ඘㟁᫬ࡢᖹ࡚ࡃࡿࡇ࡜ࢆሗ࿌ࡋ࡚࠸ࡿࠋᙼࡽࡢ⤖ᯝࢆᶆ‽ࢫ

ᆒ౯ᩘࡣ3.39࡛࠶ࡗࡓࠋ࡞࠾ࠊࣂࣝࢡ≧ែࢆ཯ᫎ࣌ࢡࢺࣝ࡜ࡋ࡚ేࡏ࡚㍕ࡏࡓࠋ௒ᅇᚓࡽࢀࡓ⤖ᯝ

ࡋࡓPFYἲ࡟ࡼࡿࢫ࣌ࢡࢺࣝࡣࠊ⮬ᕫ྾཰ຠᯝࡢ

࡛ࡣࠊ඘㟁࡟ࡼࡗ࡚୺ࣆ࣮ࢡࡀ0.3 eVࡔࡅ㧗࢚ࢿࡓࡵᐃ㔞ⓗ࡞ゎᯒࡣ㞴ࡋ࠸ࡶࡢࡢࠊ඘㟁᫬ࡢᖹᆒࣝࢠ࣮࡟ࢩࣇࢺࡍࡿࡇ࡜ࡀほᐹࡉࢀࡓࠋ

౯ᩘࡣTEYἲ࡟ẚ࡭㧗࠸ഴྥࢆ♧ࡋ࡚࠸ࡓࠋ

Mizokawaࡽ࡟ࡼࡿCo3+࠿ࡽCo3.75+࡬ࡢࢩࣇࢺ㔞࠿ࡽᮏᐇ㦂࡛ࡢ඘㟁᫬ࡢCoࡢ౯ᩘࢆぢ✚ࡶࡿ࡜ࠊ⣙3.3࡟࡞ࡗࡓࠋࡓࡔࠊ㓟໬࡟ࡼࡗ࡚⌧ࢀࡿప࢚ࢿ
ࣝࢠ࣮ഃࡢࢧࢸࣛ࢖ࢺࡣ㢧ⴭ࡟ࡣ⌧ࢀࡎࠊࡇࢀࡣ
௒ᅇࡢヨᩱࡀ⢊ᮎヨᩱ࡛࠶ࡾࠊ೫ග≉ᛶࡀᖹᆒ໬
ࡉࢀࡓࡇ࡜ࡀཎᅉ࡜⪃࠼ࡓࠋCoࡀ㟁Ⲵ⿵ൾ࡟ᐤ୚
ࡋ࡚࠸ࡿ࡜࠸࠺ሗ࿌ࡣࠊKobayashi13ࡸYoonࡽ14࡟ࡼࡗ࡚ࡶ࡞ࡉࢀ࡚࠸ࡿࠋ
ࡋ࠿ࡋࠊࢧ࢖ࢡࣝຎ໬ࠊ
ಖᏑຎ໬࡟ࡼࡗ࡚ࠊࢃࡎ࠿࡟ࢧࢸࣛ࢖ࢺࡢቑຍࡀ
ࡳࡽࢀࡿࡶࡢࡢࠊ㢧ⴭ࡞ኚ໬ࡣほ ࡉࢀࡎCoࡣຎ
໬࡟ࡣ㛵ಀ࡞࠸࡜࠸࠼ࡿࠋ

 Co࡟㛵ࡋ࡚ࡣࠊTsaiࡽࡀin situ Co K➃XASࡢ ࡞࠾ࠊMn L3➃XASࢫ࣌ࢡࢺࣝࡢᅗࡣ㍕ࡏ࡚࠸ᐃゎᯒࢆ⾜ࡗ࡚࠾ࡾࠊ3.0V/ࢭࣝ࠿ࡽ4.5V/ࢭࣝ࡞࠸ࡀࠊ඘ᨺ㟁࡟ࡼࡗ࡚ࣆ࣮ࢡ఩⨨ࡸᙧ≧࡟ኚ໬ࡲ࡛ࡢ඘㟁࡟ࡼࡗ࡚K➃࢚ࢿࣝࢠ࣮ࡢࢩࣇࢺࡀほࡣㄆࡵࡽࢀࡎࠊMnࡣ㟁Ⲵ⿵ൾ࡟ࡣ㛵୚ࡋ࡚࠸࡞

ࡉࢀ࡞࠿ࡗࡓࡇ࡜࠿ࡽࠊCoࡣ඘ᨺ㟁࡟ᐤ୚ࡋ࡚

࠸࡜࠸࠺ࡇࢀࡲ࡛ࡢሗ࿌࡜୍⮴ࡋ࡚࠸ࡿࠋࡲࡓࠊ

࠸࡞࠸࡜࠸࠺⤖ᯝࢆሗ࿌ࡋ࡚࠸ࡿ11ࠋFigure 7࡟⪏ஂヨ㦂࡟ࡼࡗ࡚ࢫ࣌ࢡࢺࣝኚ໬ࡣぢࡽࢀ࡞࠿ࡗ

Co L3➃XASࢫ࣌ࢡࢺࣝࢆ♧ࡋࡓࠋMizokawaࡽ12ࡓࡇ࡜࠿ࡽࠊMn࡟㛵ࡋ࡚ࡣࠊࢧ࢖ࢡࣝຎ໬ࠊಖᏑ

ࡣࠊLiCoO2࠿ࡽ໬Ꮫⓗ࡟Liࢆᘬࡁᢤ࠸࡚࠸ࡗࡓ༢

ຎ໬ࡣ㉳ࡇࡗ࡚࠸࡞࠸࡜⪃࠼ࡽࢀࡿࠋ

Normalized unit (a.u.)⤖ᬗヨᩱࡢCo L➃ࢫ࣌ࢡࢺࣝࢆ ᐃࡋࠊCo3㸩࠿ࡽ




20

ࢺࣝ࡟࠾࠸࡚ࣆ࣮ࢡA࡟ᑐࡍࡿࣆ࣮ࢡBࡢቑຍศ Figure 8(a)ࠊ(b)࡟ಖᏑ⪏ஂရࠊࢧ࢖ࢡࣝ⪏ஂရࡢኚ໬ࢆㄪ࡭ࡿࡇ࡜࡛ࠊᐜ㔞ຎ໬࡟ࡼࡿࢫࣆࢿࣝ

ࡢTEYἲࠊPFYἲ࡟ࡼࡗ࡚ᚓࡽࢀࡓᨺ㟁᫬ࡢO K

ᵓ㐀ࡢ⏕ᡂᗘྜ࠸ࢆồࡵࡓࠋ⤖ᯝࢆFig. 11(a)࡟♧➃XASࣉ࢚ࣜࢵࢪ㡿ᇦࡢࢫ࣌ࢡࢺࣝࢆ♧ࡋࡓࠋࡇࡋࡓࡀࠊࢧ࢖ࢡࣝຎ໬࡟㛵ࡋ࡚ࡣึᮇရ࠿ࡽ࠶ࡲ

ࡢ㡿ᇦ࡟⌧ࢀࡿࡢࡣNi2+ࠊCo3+ࠊMn4+࢖࢜ࣥࡀO

ࡾኚ໬ࡀ࡞࠸ࡢ࡟ᑐࡋ࡚ࠊಖᏑຎ໬࡛ࡣ⣙2ಸࡢ࡜ඹ᭷⤖ྜࡍࡿࡇ࡜࡟ࡼࡗ࡚⏕ࡌࡿO 2pࣂࣥࢻࢫࣆࢿࣝ┦ࡢ⏕ᡂࡀぢࡽࢀࠊಖᏑ㛤ጞ᫬ࡢ㟁఩࡟ࡢ✵Ꮝ≧ែ࡬ࡢ㑄⛣࡟ᑐᛂࡋ࡚࠸ࡿࠋࣂࣝࢡࢆࣉ

ࡼࡗ࡚ቑຍࡍࡿഴྥࢆ♧ࡋ࡚࠸ࡿࠋ

࣮ࣟࣈࡍࡿPFYࢫ࣌ࢡࢺ࡛ࣝࡣಖᏑຎ໬ࠊࢧ࢖ࢡ

 Figure 9࡟ࡣಖᏑ⪏ஂရ࡜ࢧ࢖ࢡࣝ⪏ஂရ࡜ࡢࣝຎ໬࡝ࡕࡽࡶ኱ࡁ࡞ኚ໬ࢆ♧ࡉࡎࠊࡑࡢᙧ≧ࡣᨺ㟁᫬ࡢC K➃XASࡢTEYࢫ࣌ࢡࢺࣝࢆ♧ࡋࡓࠋึᮇရ㸦0ࢧ࢖ࢡࣝ㸧ࠊࡉࡽ࡟ࡣᮍฎ⌮ရ15࡜ࡶṤᮏ㟁ụᮦᩱࡢⅣ⣲ᡂศࡣᑟ㟁ຓ๣࡛࠶ࡿAB࡜⤖࡝୍⮴ࡋ࡚࠸ࡿࠋࣆ࣮ࢡAࡣNi2+(eg)-Oࠊ࠾ࡼࡧ╔ ๣ ࡛ ࠶ ࡿ PVDF ࡀ ୺ ࡜ ⪃ ࠼ ࡽ ࢀ ࠊ ࣆ ࣮ ࢡ A1

Co3+(eg)-O ΰ ᡂ ㌶ 㐨 ࡬ ࡢ 㑄 ⛣ ࠊ ࣆ ࣮ ࢡ B ࡣ(285.6 eV)ࠊA3 (293 eV)ࡣABࡢȧ*㑄⛣ࠊȪ*㑄⛣Mn4+(t2g)-Oΰᡂ㌶㐨࡬ࡢ㑄⛣࡟ᖐᒓࡉࢀࡿ15ࠋࡇ࡟ࠊࣆ࣮ࢡA2 (292 eV)ࠊA4 (294.7 eV)ࡣPVDFࡢ

ࢀ࡟ᑐࡋ࡚ࠊ⾲㠃ᩄឤ࡞TEYࢫ࣌ࢡࢺ࡛ࣝࡣࠊࣆ

C-F⤖ྜ࡟⏤᮶ࡍࡿȧ*ࠊȪ*㑄⛣࡟ᖐᒓ࡛ࡁࡿ17ࠋ

࣮ࢡBࡀึᮇရ࡛ࡍ࡛࡟㢧ⴭ࡟ቑ኱ࡋ࡚࠸ࡿࠋࡇ

ྜ๣㟁ᴟࢆస〇ࡍࡿࡇ࡜࡟ࡼࡗ࡚᪂ࡓ࡟⏕ࡌࡓࣆࢀࡣ඘ᨺ㟁ฎ⌮࡟ࡼࡗ࡚ṇᴟ⾲㠃࡟ఱࡽ࠿ࡢ≧ែ

࣮ࢡB2(288.5 eV)ࠊB3 (290.4 eV)ࡣࡑࢀࡒࢀ࢝ࣝ

ኚ໬ࡀ㉳ࡁ࡚࠸ࡿࡇ࡜ࢆព࿡ࡍࡿࠋࡇࡢࣆ࣮ࢡB࣎ࣥ㓟໬ྜ≀18࡜Ⅳ㓟ሷ19࡟ࡼࡿࡶࡢ࡜ᖐᒓ࡛ࡁ

࡟㛵ࡋ࡚ࡣࠊShikanoࡽࡀ⌮ㄽィ⟬ࡶేࡏ࡚⾜࠸ࠊࡿࠋࡇࢀࡽࡢࣆ࣮ࢡࡣึᮇရ࡛ࡶ᪤࡟⌧ࢀ࡚࠸ࡿ❧᪉ᬗࢫࣆࢿࣝᵓ㐀ෆࡢNi-O㌶㐨࡬ࡢ㑄⛣࡟ᖐࡀࠊຎ໬࡟ࡼࡗ࡚ḟ➨࡟ቑ኱ࡋ࡚࠸ࡃࠋಖᏑຎ໬

ᒓࡋ࡚࠸ࡿ16ࠋࡍ࡞ࢃࡕࠊTEYࢫ࣌ࢡࢺࣝ࡟࠾ࡅ

ࡢヨᩱ࡛ࡣࠊ
ࡇࢀࡽࡢࣆ࣮ࢡࡀࡼࡾᙉࡃほ ࡉࢀࠊࡿࣆ࣮ࢡBࡢቑຍศࡣ⾲㠃࡟⏕ᡂࡋࡓ❧᪉ᬗࢫࣆ

286.4 eV࡟ࡶ᪂ࡓ࡟࢝ࣝ࣎ࢽࣝ໬ྜ≀18࡟ᖐᒓࡉࢿࣝᵓ㐀࡟ࡼࡿࡇ࡜ࢆ♧ࡋ࡚࠸ࡿࠋFigure 8࡟♧ࢀࡿࣆ࣮ࢡB1ࡀ⫪ᵓ㐀࡜ࡋ࡚⌧ࢀࡿࠋࡇࡢࡼ࠺࡟ࠊ

ࡋࡓࢫ࣌ࢡࢺࣝࡣ࢚ࢵࢪࢪࣕࣥࣉ࡛つ᱁ࡋࡓࡶࡢ

㟁ゎᾮࡢศゎ⏕ᡂ≀ࡀḟ➨࡟ṇᴟ⾲㠃࡟ሁ✚ࡋ࡚࡛࠶ࡿࡀࠊ㓟⣲ྵ᭷௜╔≀ࡢከᐻ࡟ࡼࡗ࡚ࣉ࢚ࣜ

࠸ࡃᵝᏊࡀࡳ࠼ࡿࡀࠊࣆ࣮ࢡA1࡟ᑐࡍࡿࣆ࣮ࢡ

ࢵࢪࣆ࣮ࢡᙉᗘࡀኚ໬ࡍࡿࠋࡑࡇ࡛ࠊTEYࢫ࣌ࢡ

B2ࡢᙉᗘẚࡀຎ໬࡟ࡼࡗ࡚࡝ࡢࡼ࠺࡟ኚ໬ࡍࡿ

Normalized unit (a.u.) 㹍ࠊ㹁ࠊ㹄 㹉➃㹖㸿㹑




21

࠿ࢆㄪ࡭ࡓࡢࡀFig. 11(b)࡛࠶ࡿࠋಖᏑຎ໬ࡢ᪉ࡀ
⣙2ಸ኱ࡁࡃࠊຎ໬࡜ඹ࡟ቑ࠼࡚࠸ࡃഴྥࢆ♧ࡋ
Normalized unit (a.u.)࡚࠸ࡿࠋ Figure 10࡟F K➃XASࡢTEYࢫ࣌ࢡࢺࣝࡢ౛
ࢆ㍕ࡏࡓࡀࠊࡇࢀࡽࡣࡍ࡭࡚PVDF࡜LiFࡢ㔜ࡡྜࢃࡏ࡛‶㊊࡟෌⌧ࡉࢀࡿࡇ࡜ࡀศ࠿ࡗࡓࠋPVDF
ࡣ㟁ụ⤌ࡳ❧࡚᫬࠿ࡽᏑᅾࡋࠊ⪏ஂヨ㦂࡟ࡼࡗ࡚ࡶࡑࡢ㔞ࡣኚࢃࡽ࡞࠸ࡀࠊLiFࡣ㟁ゎᾮࡢศゎ࡟ࡼࡗ࡚⏕ࡌࡓࡶࡢ࡜⪃࠼ࡽࢀࡿࠋࡑࡇ࡛ࠊPVDF
ࢆᇶ‽࡟ࡋࡓLiFࡢᏑᅾ㔞ࢆồࡵࡓࠋᐜ㔞ຎ໬ᗘ࡟ࡓ࠸ࡋ࡚ᨺ㟁᫬ࡢヨᩱࡢ್ࢆࣉࣟࢵࢺࡋࡓࡶࡢ
ࡀFig. 11(c)࡛࠶ࡿࠋ኱ࡁ࡞໬Ꮫኚ໬࡟ࡼࡗ࡚ࡤࡽ
ࡘࡁࡢ኱ࡁ࠸0ࢧ࢖ࢡࣝࡢヨᩱࢆ㝖ࡅࡤᐜ㔞ຎ໬

Normalized unit (a.u.)࡜࡜ࡶ࡟LiF㔞ࡀቑ኱ࡍࡿഴྥࢆ♧ࡋ࡚࠾ࡾࠊࢧ
࢖ࢡࣝຎ໬ࠊಖᏑຎ໬࡝ࡕࡽ࡟࠾࠸࡚ࡶLiFࡢ⾲㠃࡬ࡢሁ✚ቑຍࡀ㟁ụຎ໬࡜ᐦ᥋࡞㛵ಀ࡟࠶ࡿࡇ
࡜ࢆ♧၀ࡋ࡚࠸ࡿࠋ
ຎ໬ᣲືࡢ⪃ᐹ 㟁ụᮦᩱࢆ໬Ꮫኚ໬ࡢ❧ሙ࠿ࡽぢࡿ࡜ࠊᮍฎ⌮ရ࠿ࡽ᭱ึ࡟඘ᨺ㟁ࡍࡿࡇ࡜࡟ࡼࡗ࡚㸦ࡇࡇ࡛ࡣ0ࢧ࢖ࢡࣝ࡟ᑐᛂ㸧኱ࡁ࡞ኚ໬ࡀᘬࡁ㉳ࡇࡉࢀࡿࠋ
ࡑࡋ࡚ࠊ඘ᨺ㟁ࡢ⧞ࡾ㏉ࡋࠊ඘㟁≧ែ࡛ࡢ㛗ᮇಖᏑ࡟ࡼࡗ࡚ḟ➨࡟ᵓ㐀ኚ໬ࡀ㉳ࡇࡾࠊᐜ㔞ࡀపୗࡋ࡚࠸ࡃࠋୖ㏙ࡋࡓࡼ࠺࡟ࠊᐜ㔞ຎ໬ࡢᶵᵓࡣ」㞧࡛࠶ࡾࠊ㟁ụࡢ⤌ᡂ࡞࡝ෆⓗ᮲௳࡜࢝ࢵࢺ࢜ࣇ
㟁ᅽࡸ඘ᨺ㟁࣮ࣞࢺࠊ ᗘ࡞࡝ᵝࠎ࡞እⓗ᮲௳࡟ࡼࡗ࡚␗࡞ࡗ࡚ࡃࡿࠋIkedaࡽࡣࠊ㛗ᮇ㧗 ಖᏑရࡢ㉮ᰝ㏱㐣ᆺ㟁Ꮚ㢧ᚤ㙾ほ ࡟ࡼࡗ࡚ࠊᒙ≧ᒾሷᆺᵓ㐀ࢆࡋࡓNCMά≀㉁ࡢ⾲㠃࡟ᩘnmࡢཌࡉࡢ❧᪉ᬗࢫࣆࢿࣝᵓ㐀ࡀ⏕ᡂࡍࡿࡇ࡜ࢆሗ࿌ࡋ࡚࠾
ࡾࠊࡑࢀ࡟ࡼࡗ࡚⏺㠃᢬ᢠࡀቑ኱ࡍࡿࡇ࡜ࡀຎ໬
ࡢཎᅉ࡛࠶ࡿ࡜ࡋ࡚࠸ࡿ4ࠋ୍᪉ࠊLinࡽࡣࠊึᮇ
ᩘ༑ࢧ࢖ࢡࣝ඘ᨺ㟁ࢆࡋࡓヨᩱ࡛ࡢ㟁Ꮚ㢧ᚤ㙾ほᐹ࠿ࡽࠊྠᵝ࡟2nmཌࡉࡢ❧᪉ᬗࢫࣆࢿࣝᵓ㐀ࡢ⏕ᡂࢆほ ࡋ࡚࠸ࡿ3ࠋࡇࡢࡇ࡜ࡣࠊึᮇ඘ᨺ㟁ẁ㝵࡟࠾࠸࡚ࡶࡍ࡛࡟⾲㠃࡟኱ࡁ࡞ᵓ㐀ኚ໬ࢆ⏕ࡌຎ໬ᶵᵓࡢゎ᫂ࢆ┠ᣦࡋࡓࡶࡢ࡛࠶ࡾࠊ࢝ࢵࢺ࢜

࡚࠸ࡿࡇ࡜ࢆ♧၀ࡋ࡚࠸ࡿࠋ

ࣇ㟁ᅽࢆ3.0–4.1V/ࢭࣝ࡟ࡋࡓࡇ࡜࠿ࡽࠊ඘ᨺ㟁ࢆ ᮏᐇ㦂࡛ࡣࠊ࡛ࡁࡿࡔࡅ࣐࢖ࣝࢻ࡞⎔ቃୗ࡛ࡢ22ᢸ࠺ࡢࡣNi࢖࢜ࣥ࡜୍㒊ࡢCo࢖࢜ࣥࡔࡅ࡛࠶ࡗ

K➃XASࡢ⤖ᯝ࠿ࡽࠊ⾲㠃ࢫࣆࢿࣝ┦ࠊṇᴟ⾲㠃ࡓࠋࡓࡔࡋࠊᖖ ࡛ࡢຎ໬ࡣ࠶ࡲࡾ࡟ࡶ㛗᫬㛫ࢆሁ✚ᒙࡀࢧ࢖ࢡࣝ⪏ஂရࡼࡾ2ಸ௨ୖ࠶ࡿࠋࡇࢀ

せࡍࡿࡇ࡜࠿ࡽࠊಖᣢ ᗘࢆ85 °C㸦ࢧ࢖ࢡࣝຎ໬㸧ࠊࡽࡢṇᴟ⾲㠃ࡢ┦ኚ໬ࡸሁ✚ᒙࡢቑຍࡀ୺࡞࢖࢜

70 °C㸦ಖᏑຎ໬㸧࡟ࡋࡓࠋࡇࡢࡇ࡜ࡣࠊ㟁ゎᾮࡢࣥఏᑟ㜼ᐖࡢせᅉ࡟࡞ࡗ࡚࠸ࡿ࡜⪃࠼ࡽࢀࡿࠋ

ศゎࠊሁ✚ࡀࡼࡾ㉳ࡇࡾ᫆࠸⎔ቃୗ࡛ࡢຎ໬⌧㇟࡛࠶ࡿࡇ࡜ࡣྰࡵ࡞࠸ࠋ௒ᅇࡢᐜ㔞ホ౯࡟࠾࠸࡚㸬 ⤖ㄽ

ࡣ⪏ஂヨ㦂ᚋࡢ㟁ụࢆศゎࡋࠊLiࢆ㈇ᴟ࡜ࡍࡿࣁ

 NCMࢆṇᴟ࡜ࡋࡓ௦⾲ⓗ࡞ࣜࢳ࣒࢘㟁ụ࡟ࡘ࣮ࣇࢭࣝࢆస〇ࡋ࡚SOCㄪᩚࢆᐇ᪋ࡋ࡚࠸ࡿࡢ

࠸࡚ࠊࢧ࢖ࢡࣝຎ໬࡜㛗ᮇ඘㟁ಖᏑຎ໬ࡢ᣺ࡿ⯙࡛ࠊ㈇ᴟ࠿ࡽࡢLi౪⤥ࡀไ⣙ࡉࢀࡿࡇ࡜ࡣ࡞࠸ࠋ࠸ࢆXASࠊXRDࠊSEMࢆ⏝࠸࡚ㄪ࡭ࡓࠋࡑࡢ⤖ᯝࠊࡑࡢࡼ࠺࡞᮲௳ୗࠊFig. 6࡟♧ࡋࡓຎ໬ࡢ㐍⾜࡜࢝ࢵࢺ࢜ࣇ㟁ᅽ3. 0~4. 1V/ࢭ࡛ࣝ඘ᨺ㟁ࢆᢸ࠺ࡢNiᖹᆒ౯ᩘ࡜ࡢ㛵ಀ࠿ࡽࡶศ࠿ࡿ࡜࠾ࡾࠊᨺ㟁᫬

ࡣNi࡜୍㒊ࡢCoࡔࡅ࡛࠶ࡾࠊNiࡔࡅ࡟ຎ໬࡟ࡼࡿ

ࡢNiᖹᆒ౯ᩘࡣࠊಖᏑຎ໬ࡶࢧ࢖ࢡࣝຎ໬ࡶྠࡌ

໬Ꮫኚ໬ࡀぢࡽࢀࡓࠋࢧ࢖ࢡࣝຎ໬࡜ಖᏑຎ໬࡟

ഴྥࢆ♧ࡋࠊᐜ㔞ຎ໬⋡࡜࡯ࡰẚ౛㛵ಀ࡟࠶ࡿࠋ

࠾࠸࡚ࠊᨺ㟁≧ែ࡟㛵ࡋ࡚ࡣࠊ࡝ࡕࡽࡶᐜ㔞ຎ໬

ࡇࢀࡣࠊFig. 4࡟♧ࡋࡓXRDゎᯒ࡟ࡼࡿc㍈㛗/a㍈⋡࡟᥮⟬ࡋࡓ࡜ࡁࠊNiᖹᆒ౯ᩘࠊ᱁Ꮚᐃᩘẚc/a࡜㛗ẚ࡜ᐜ㔞ຎ໬⋡࡟ᑐࡍࡿഴྥ࡜ࡶ୍⮴ࡋ࡚࠸ࡿࠋ

ṇࡢẚ౛㛵ಀ࡟࠶ࡾࠊᐜ㔞ຎ໬࡜ඹ࡟ᨺ㟁᫬࡟඘ࡇࡢࡇ࡜ࡣຎ໬ࡀ㐍ࡴ࡟ࡘࢀ࡚ࠊࡋࡔ࠸࡟᏶඲࡞

㟁≧ែࡀࡼࡾከࡃṧࡿࡇ࡜ࢆ♧ࡋ࡚࠸ࡓࠋࡇࡢせᨺ㟁≧ែ࡟ࡲ࡛ᡠࡾ࡟ࡃࡃ࡞ࡿࡇ࡜ࢆព࿡ࡍࡿࠋ

ᅉ࡜ࡋ࡚ࠊNCM⢏Ꮚ㛫ࡢ࣐࢖ࢡࣟࢡࣛࢵࢡࡀ኱ࡁ

᥮ゝࡍࢀࡤࠊṇᴟഃ࡛࡞ࢇࡽ࠿ࡢLi࢖࢜ࣥఏᑟ㜼ࡃ࡞ࡾࠊ⢏Ꮚ⾲㠃࡟ࢫࣆࢿࣝ┦ࡀ⏕ᡂࡋࠊ㟁ゎᾮᐖࡀ⏕ࡌ࡚࠸ࡿ࡜⪃࠼ࡽࢀࡿࠋIkedaࡽࡶ㛗ᮇ㧗ศゎ⏕ᡂ≀ࡀḟ➨࡟ሁ✚ࡋ࡚࠸ࡁࠊࣜࢳ࣒࢘ఏᑟ

ಖᏑຎ໬ࡢᐇ㦂࡛ྠᵝࡢ⤖ᯝࢆᚓ࡚࠸ࡿ4ࠋ௒ᅇࠊࣃࢫࢆ㜼ᐖࡋ࡚࠸ࡃࡇ࡜ࡀ᫂ࡽ࠿࡟࡞ࡗࡓࠋ
≉࡟ࠊᡃࠎࡣ඘㟁ಖᏑຎ໬࡜ࢧ࢖ࢡࣝຎ໬ࡢ2✀㢮ࡢຎࢧ࢖ࢡࣝຎ໬࡛ࡣ࣐࢖ࢡࣟࢡࣛࢵࢡࡢ⏕ᡂࡀ㢧ⴭ໬ᐇ㦂ࢆ⾜࠸ࠊ୧⪅࡜ࡶ㢮ఝࡋࡓຎ໬ࡢ᣺ࡿ⯙࠸࡛࠶ࡿࡢ࡟ᑐࡋ࡚ࠊಖᏑຎ໬࡛ࡣṇᴟ⾲㠃ࢆ♧ࡋࡓࡀࠊSEMീࡸOࠊ C K➃XASࡢ⤖ᯝࡣ୧ࡢࢫࣆࢿࣝ┦⏕ᡂࡀ㢧ⴭ࡟ࡳࡽࢀࡓࠋ

⪅࡛ຎ໬ࡢせᅉࡀ␗࡞ࡗ࡚࠸ࡿࡇ࡜ࢆ♧၀ࡋ࡚࠸
ࡿࠋ

ཧ⪃ᩥ⊩

 ࢧ࢖ࢡࣝ⪏ஂရ࡛ࡣ඘ᨺ㟁ࡀ⧞ࡾ㏉ࡉࢀࡿࡇ࡜

1. T. Ohzuku and Y. Makimura, Chem. Lett., 30,࡟࡞ࡿࠋṇᴟࡢNCMࡣ඘㟁࡟కࡗ࡚a㍈ࡣ཰⦰ࡋࠊ

642 (2001).

c㍈ࡣఙ㛗ࡋࠊᨺ㟁᫬࡟ࡣྍ㏫ⓗ࡟ࡶ࡜࡟ᡠࡿࠋࡋ

2. (ᅜ)⛉Ꮫᢏ⾡᣺⯆ᶵᵓపⅣ⣲♫఍ᡓ␎ࢭࣥࢱ࣮,࠿ࡋࠊ඘ᨺ㟁ࡀ⧞ࡾ㏉ࡉࢀࡿ࡜ࡸࡀ࡚⢏⏺࡟ṍࡀㄪᰝሗ࿌᭩ࠕࣜࢳ࣒࢘࢖࢜ࣥ㟁ụࡢຎ໬ᣲືㄪᰝࠖ

⏕ࡌࠊࢡࣛࢵࢡࡀⓎ⏕ࡍࡿࠋFigure 2ࡢSEMീ࡟

(2020).

♧ࡋࡓࡼ࠺࡟1000ࢧ࢖ࢡࣝᚋࡢNCM஧ḟ⢏Ꮚ࡟

3. F. Lin, M. Markus, D. Nordlund, T.-S. Weng,㢧ⴭ࡞ࢡࣛࢵࢡࡢⓎ⏕ࡀぢࡽࢀࡿࠋࡑࡢ⤖ᯝࠊLi

M. D. Asta, H. L. Xin, and M. M. Doeff, Nat.

࢖࢜ࣥఏᑟࣃࢫࡀᑍ᩿ࡉࢀࠊᏙ❧ࡋࡓNCM⢏Ꮚࡀ

Commun., 5, 3529 (2014).

Ⓨ⏕ࡍࡿࡇ࡜ࡀ୺࡞せᅉ࡜࡞ࡗ࡚ࠊᨺ㟁᫬࡟㈇ᴟ

4. Y. Ikeda, Y. Tao, R. Kido, M. Masuda, T.

࠿ࡽṇᴟ࡟Li࢖࢜ࣥࡀᡠࡾ࡟ࡃࡃ࡞ࡗࡓ࡜⪃࠼ࡽYamafuku, S. Mori, T. Sasaki, and T. Inamasu,

ࢀࡿࠋGS Yuasa Technical report, 13, page 1 (2016).

 ࡇࢀ࡟ᑐࡋ࡚ࠊಖᏑ⪏ஂရ࡛ࡣ඘ᨺ㟁ࡣ⾜ࢃࢀ

5. S. Hashigami, K. Yoshimi, Y. Kato, H.

࡞࠸ࡢ࡛஧ḟ⢏Ꮚࡢ⭾ᙇ཰⦰ࡀ࡞ࡃ࣐࢖ࢡࣟࢡࣛ

Yoshida, T. Inagaki, M. Tatematsu, H. Deguchi,ࢵࢡࡣṤ࡝⏕ࡌ࡚࠸࡞࠿ࡗࡓࠋ࡜ࡇࢁࡀࠊOࠊ C

M. Hashinokuchi, T. Doi, and M. Inaba,




23

Electrochemistry, 87, 357 (2019).

13. H. Kobayashi, J. Power Sources, 146, 640

6. T. Liu, A. Garsuch, F. Chesneau, and B. L.

(2005).

Lucht, J. Power Sources, 269, 920 (2014).

14. W.-S. Yoon, M. Balasubramanian, K. Y.

7. Z. H. Lu and J. R. Dahn, J. Electrochem. Soc.,

Chung, X.-Q. Yang, J. McBreen, C. P. Grey, and149, A815 (2002).

D. A. Fischer, J. Am. Chem. Soc., 127, 17479

8. N. Yabuuchi, K. Yoshii, S.-T. Myung, I. Nakai,(2005).

and S. Komaba, J. Am. Chem. Soc., 133, 4404

15. M. G. Kim, H. J. Shin, J.-H. Kim, S.-H. Park,(2011).

and Y.-K. Sun, J. Electrochem. Soc., 152, A1320

9. Y. Koyama, T. Mizoguchi, H. Ikeno, and I.

(2005).

Tanaka, J. Phys. Chem. B, 109, 10749 (2005).

16. M. Shikano, H. Kobayashi, S. Koike, H.

10. K. Kubobuchi, M. Mogi, M. Matsumoto, T.

Sakebe, Y. Saito, H. Hori, H. Kageyama, and K.

Baba, C. Yogi, C. Sato, T. Yamamoto, T.

Tatsumi, J. Power Sources, 196, 6881 (2011).

Mizoguchi, and H. Imai, J. Appl. Phys., 120,

17. T. Ohta, K. Seki, T. Yokoyama, I. Morisada,

142125 (2016).

and K. Edamatsu, Phys. Scr., 41, 150 (1990).

11. Y. W. Tsai, B. J. Hwang, G. Ceder, H. S.

18. O. Dhez, H. Ade, and S. G. Urquhart, J.

Sheu, D. G. Liu, and J. F. Lee, Chem. Mater., 17,Electron Spectrosc. Relat. Phenom., 128, 85

3191 (2005).

(2003).

12. T. Mizokawa, Y. Wakisaka, T. Sudayama, C.

19. J. A. Brandes, S. Wirick, and C. Jacobsen, J.

Iwai, K. Miyoshi, J. Takeuchi, H. Wadati, D. G.

Synchrotron Radiat., 17, 676 (2010).

Hawthorn, T. Z. Regier, and G. A. Sawatzky,
Phys. Rev. Lett., 111, 056404 (2013).






24

㸬◊✲㛤Ⓨࡢ≧ἣ

25



◊✲㛤Ⓨࡢ≧ἣ ◊✲㛤Ⓨ  ග※ຍ㏿ჾࢀ࡚࠾ࡾࠊᦆኻࣅ࣮࣒࡟ࡼࡗ࡚⏕ࡌࡓᨺᑕ⥺ࢆᤊ࠼ձࣅ࣮࣒ᦆኻ࡟ࡼࡿᨺᑕ⥺ ᐃ⣔ࡢ㛤Ⓨ࡚࠸ࡿ࡜⪃࠼ࡽࢀࡿࠋᨺᑕ⥺ศᕸࡢ ᐃ࡟ࡼࡗ࡚ࣅ
࣮࣒ᦆኻࡢ✵㛫ⓗ࡞᝟ሗࢆྲྀᚓ࡛ࡁࢀࡤࠊධᑕຠ⋡⵳✚ࣅ࣮࣒ࡢᦆኻ࡟ࡼࡿᨺᑕ⥺ࢆຍ㏿ჾ඲య࡟ࢃ

ࡢࡉࡽ࡞ࡿᨵၿࡀᮇᚅ࡛ࡁࡿࠋ୍᪉ࠊຍ㏿ჾᐊෆ࡛ࡓࡗ࡚ィ ࡋࠊࡑࡢศᕸࢆྍど໬࡛ࡁࢀࡤࠊࡼࡾᏳ

ࡢᖖ᫬㐠⏝࡟ࡣࣀ࢖ࢬᑐ⟇࡞࡝ࡢㄢ㢟ࡀ࠶ࡾࠊᘬࡁ

඲࡞ᨺᑕ⥺㐽ⶸࡣࡶ࡜ࡼࡾࠊຍ㏿ჾ㐠㌿ࡢຠ⋡໬࡟⥆ࡁᐇ⏝໬࡟ྥࡅࡓ㛤Ⓨࢆ⾜࠺[1]ࠋ

ࡘ࡞ࡀࡿࠋከⅬィ ࡟ࡼࡿᨺᑕ⥺ศᕸࡢ ᐃࢩࢫࢸ࣒ࢆᵓ⠏ࡍࡿࡓࡵ࡟ࠊ༙ᑟయ᳨ฟჾࢆ⏝࠸ࡓᑠᆺ࠿
ࡘᏳ౯࡞ࣅ࣮࣒ࣟࢫ ᐃჾࡢ㛤Ⓨࢆ⾜ࡗࡓࠋ᳨ฟჾࡣⲴ㟁⢏Ꮚᨺᑕ⥺࡟ࡼࡿࣇ࢛ࢺࢲ࢖࣮࢜ࢻ
ࡢࢳ࣮ࣕࢪ࢔ࢵࣉࢆฟຊࡍࡿ Bergoz ♫ࡢࣅ࣮࣒ࣟ
ࢫࣔࢽࢱࢆ౑⏝ࡍࡿࠋ᳨ฟჾࡢಙྕィᩘࡣࠊࣃࣝࢫ
࢝࢘ࣥࢺᶵ⬟ࢆࡶࡕ↓⥺࡛ィᩘ್ࢆฟຊ࡛ࡁࡿ࣐࢖
ࢡࣟࢥࣥࣆ࣮ࣗࢱ ESP32 ࢆ⏝࠸ࡿࠋᅗ 1 ࡟ᵓᡂࡋࡓィ ࣔࢪ࣮ࣗࣝࡢ෗┿ࢆ♧ࡍࠋ㟁※࡟ࡣ㟁ᅽࡢᏳ

ᅗ 2 㐠㌿㛤ጞ᫬ࡢᨺᑕ⥺㔞ኚ໬ ᐃᐃࡋࡓࣔࣂ࢖ࣝࣂࢵࢸ࣮ࣜࢆ౑⏝ࡍࡿࠋղග※ຍ㏿ჾ┿✵⣔ࡢᨵⰋ
AichiSR ࡛ࡣࣈ࣮ࢫࢱ࣮ࢩࣥࢡࣟࢺࣟࣥࡸ⵳✚ࣜࣥࢢࡢධᑕ࠾ࡼࡧฟᑕࢭࣉࢱ࣒┿✵ᵴ࡟✚ᒙ㗰ᯈࡀタ⨨ࡉࢀ࡚࠾ࡾࠊࡇࢀࡽ㗰ᯈ࠿ࡽࡢ࢞ࢫᨺฟࡀග※ຍ㏿ჾࡢ┿✵ᝏ໬ࡢ୺ᅉ࡜ࡋ࡚⪃࠼ࡽࢀ࡚࠸ࡿࠋ
ࢭࣉࢱ࣒㒊࡟࠾ࡅࡿ┿✵ᝏ໬ࡣ 2015 ᖺ㡭࠿ࡽⓎ⏕ࡋ࡚࠾ࡾࠊ2018 ᖺ࠿ࡽ࢖࣏࢜ࣥࣥࣉࡢ஺᥮ࢆ୺
࡟┿✵⣔ࡢᨵⰋࢆ⾜ࡗ࡚࠸ࡿࠋ2019 ᖺ 4 ᭶࠾ࡼࡧ10 ᭶ࡢ࣓ࣥࢸࢼࣥࢫᮇ㛫࡟ࠊ⵳✚ࣜࣥࢢ࠾ࡼࡧࣈ
࣮ࢫࢱ࣮ࡢࢭࣉࢱ࣒㒊࡟ 10-5 ~ 10-7 Pa ࡢ㡿ᇦ࡛ືసᅗ 1 ࣅ࣮࣒ࣟࢫ ᐃჾࡍࡿ᪂ࡋ࠸ࢤࢵࢱ࣮ᮦࢆ౑⏝ࡋࡓ NEG ࣏ࣥࣉࢆቑタࡋࠊ᤼Ẽ⬟ຊࡢቑᙉ࡜࢖࣏࢜ࣥࣥࣉຎ໬ࡢపῶࢆࡇࡢィ ჾࢆࣅ࣮࣒㌶㐨ࡢ㧗ࡉ࡛⵳✚ࣜࣥࢢධᑕ

ᅗࡗࡓࠋࢭࣉࢱ࣒࡟ᅛᐃࡋࠊ㐠㌿㛤ጞ᫬ࡢࣅ࣮࣒ධᑕ࡟୪⾜2020 ᖺ 10 ᭶࡟ࡣࠊࣈ࣮ࢫࢱ࣮ධᑕࢭࣉࢱ࣒࿘㎶ࡋ࡚ヨ㦂ⓗ࡞ᨺᑕ⥺ィᩘᐇ㦂ࢆ⾜ࡗࡓࠋᅗ 2 ࡣධᑕࡢ 20 L/s ࢖࣏࢜ࣥࣥࣉ 2 ྎࢆࠊࡼࡾ㧗࠸᤼Ẽ⬟ຊࢆ࠿ࡽ⵳✚࣮ࣔࢻ࡬⛣⾜ࡍࡿࡲ࡛ࡢ࢝࢘ࣥࢱィᩘ್ࡢ

ࡶࡘ 55 L/s ࢖࣏࢜ࣥࣥࣉ࡬஺᥮ࡋࠊࡉࡽ࡟ NEG ࣏ኚ໬ࢆ⤒᫬࡛⾲ࡋࠊᑐᛂࡍࡿࣅ࣮࣒㟁ὶ್ࢆ♧ࡍࠋࣥࣉࢆቑタࡋࡓࠋࡲࡓࠊ2021 ᖺ 4 ᭶࡟ࡣࠊ⵳✚ࣜධᑕ࡜⵳✚᫬ࡢィᩘ್࡟᭷ព࡞ᕪ␗ࢆ☜ㄆࡋࡓࠋࣥࢢ࠾ࡼࡧࣈ࣮ࢫࢱ࣮ධᑕࢭࣉࢱ࣒㒊ࡢ 500 L/s⌧ᅾ AichiSR ࡟࠾ࡅࡿ⵳✚ࣜࣥࢢ࡬ࡢධᑕຠ⋡ࡣ

Diode ᆺ࢖࣏࢜ࣥࣥࣉࢆ 300L/s StarCell ᆺ࢖࣏࢜ࣥ

50%࡯࡝࡛ࠊධᑕࣅ࣮࣒ࡢ༙ศࡣ⵳✚࡛ࡁࡎ࡟ኻࢃ

ࣥࣉ࡬஺᥮ࡍࡿ࡜࡜ࡶ࡟㸪NEG ࣏ࣥࣉࢆ㧗ᛶ⬟ရ

26࡟஺᥮ࡋࡓࠋᅗ 3 ࡟᭦᪂ࡋࡓࢭࣉࢱ࣒㒊࢖࣏࢜ࣥࣥ

[1] ⏣㒊ᆂᝅ࡯࠿ࠊ”࠶࠸ࡕ SR ග※ຍ㏿ჾ࿘㎶ࡢᨺࣉࡢ୍౛ࢆ♧ࡍࠋᑕ⥺ศᕸ ᐃࢩࢫࢸ࣒ࡢ㛤Ⓨ”ࠊ➨ 18 ᅇ᪥ᮏຍ㏿ჾࡲࡓࠊග※ຍ㏿ჾ࡛ࡣ࢖࣏࢜ࣥࣥࣉ⏝ࢥࣥࢺ࣮ࣟ

Ꮫ఍ᖺ఍(2021)ࣉࣟࢩ࣮ࢹ࢕ࣥࢢ

ࣛ࡜ࡋ࡚ Agilent 〇 Dual ࢆ౑⏝ࡋ࡚ࡁࡓࡀࠊ㏆ᖺ

[2] 㧗ᔱᆂྐ࡯࠿ࠊ”࠶࠸ࡕ SR ග※ຍ㏿ჾࡢ⌧≧”ࠊᨾ㞀ࡀከⓎࡋ࡚࠸ࡿࠋྠᆺ␒ရࡢ〇㐀ࡣ⌧ᅾࡍ࡛࡟➨ 18 ᅇ᪥ᮏຍ㏿ჾᏛ఍ᖺ఍(2021)᪋タሗሗ࿌⤊ᜥࡋ࡚࠸ࡿࡓࡵࠊGamma Vacuum 〇 SPC ࡬ࡢኚ᭦ࢆ㐍ࡵ࡚࠾ࡾࠊ2021 ᖺ 4 ᭶࡟ࣈ࣮ࢫࢱ࣮ཬࡧ㧗࢚ࢿࣝࢠ࣮㍺㏦㊰ࡢ࢖࣏࢜ࣥࣥࣉࢆไᚚࡍࡿィ 11ྎࡢࢥࣥࢺ࣮ࣟࣛࢆ஺᥮ࡋࡓࠋ࢖࣏࢜ࣥࣥࣉ⏝ࢥࣥࢺ࣮ࣟࣛࡢ᭦᪂సᴗࡣ⥅⥆ࡋࠊ඲ᩘ஺᥮ࢆ⾜࠺ணᐃ࡛࠶ࡿ[2]ࠋ

ᅗ 3 (ୖ)࢖࣏࢜ࣥࣥࣉࡢ᭦᪂๓ࠊ(ୗ)᭦᪂ᚋ

27

  ࣅ࣮࣒ࣛ࢖ࣥձ ⤯⦕యヨᩱࡢ㟁Ꮚ཰㔞 ᐃ࡟࠾ࡅࡿග㟁Ꮚࡢᣲື%/8㸦┿✵⣸እศග㸧ࢫ࣌ࢡࢺࣝࢆ♧ࡍࠋ(a), (b)ࡣࡑࢀࡒࢀᖏ㟁ᑐ⟇ࢆ᪋ࡋ࡚࠸࡞࠸ヨᩱࠊIn ᯈୖ࡟ⷧࡃሬᕸࡋࡓヨᩱ࡛࠶ࡿࠋ(a)࡛ࡣࣆ࣮ࢡࡽࡋࡁᵓ㐀ࡣほ ࡉࢀࡎࠊࡲࡓᙉᗘࡶ኱

ෆẆ྾཰ศගἲࡣ≀㉁࡟㹖⥺ࢆ↷ᑕࡋࡓ࡜ࡁ࡟⏕ࡁࡃῶᙅࡋ࡚࠸ࡿࠋ(b)࡛ࡣヨᩱ୰࡟ྵࡲࢀࡿྛඖ⣲ࡌࡿ྾཰ࢆほ ࡍࡿࡶࡢ࡛࠶ࡾࠊࡑࡢ྾཰➃ࡢ࢚ࢿ࡟ࡼࡿࣆ࣮ࢡࡀほ ࡉࢀ࡚࠸ࡿࡀࠊࡍ࡭࡚ᩘ eV ⛬ᗘࣝࢠ࣮ࡣඖ⣲࡟ᅛ᭷ࡢ್ࢆᣢࡕࠊ໬Ꮫ≧ែࢆ཯ᫎࡋ

ప࠸㐠ື࢚ࢿࣝࢠ࣮࡟ほ ࡉࢀ࡚࠸ࡿࠋ࡞࠾ࠊC 1s ࡣࡓࢫ࣌ࢡࢺࣝࢆ୚࠼ࡿࡇ࡜࠿ࡽඖ⣲ศᯒ࣭໬Ꮫ≧ែ୙⣧≀࡟ࡼࡿࡶࡢ࡛࠶ࡿࠋᖏ㟁࡟ࡼࡿ࢚ࢿࣝࢠ࣮ࢩ

ศᯒࡢࢶ࣮ࣝ࡜ࡋ࡚ᗈࡃ⏝࠸ࡽࢀ࡚࠸ࡿࠋAichiSR ࡟ࣇࢺࡀ↷ᑕග㔞࡟౫Ꮡࡍࡿࡶࡢ࡛࠶ࡿ࠿࡝࠺࠿ㄪ࡭

࠾࠸࡚ࡶ୺せ࡞ᐇ㦂ᡭἲࡢ㸯ࡘ࡜࡞ࡗ࡚࠸ࡿࠋィࡿࡓࡵ࡟ࠊ࢔ࣥࢪ࣮ࣗࣞࢱࡢࢠࣕࢵࣉ್ࢆㄪᩚࡍࡿ

ἲ࡜ࡋ࡚ࡣࠊ㏱㐣ἲࠊ㟁Ꮚ཰㔞ἲࠊ⺯ග཰㔞ἲ࡞࡝ࡇ࡜࡟ࡼࡾධᑕ X ⥺ࡢග㔞ࢆኚ໬ࡉࡏ࡞ࡀࡽ XPS ࢆࡀ࠶ࡿࡀࠊ㌾㹖⥺㡿ᇦ࡟࠾࠸࡚ࡣධᑕ㹖⥺ࡢ㏱㐣⬟ࡀᴟࡵ࡚ప࠸ࡇ࡜࠿ࡽ㏱㐣ἲࡣ⏝࠸ࡽࢀ࡞࠸ࠋࡲࡓࠊ
⺯ග཰㔞ἲࡣ⮬ᕫ྾཰ຠᯝ࡟ࡼࡾࢫ࣌ࢡࢺࣝࡀṍࡳᐃࡋࡓࡶࡢࡀᅗ  ࡛࠶ࡿࠋࢫ࣌ࢡࢺࣝࡣ Ek < 165 eVࡢ኱ࡁ࡞ࣆ࣮ࢡ࡜ࡑࢀ࡟⥆ࡃ〈ࡀ B KLL-Auger ࡟ࡼࡿࡶࡢ࡛࠶ࡾࠊ㧗 Ek ഃࡢᑠࡉ࡞ࣆ࣮ࢡࡣ౯㟁Ꮚᖏ࡛࠶ࡸࡍࡃࠊࡲࡓࠊ㌾X⥺㡿ᇦ࡛ࡢ୺せ࡞ ᐃᑐ㇟࡛࠶ࡿ

ࡿࠋEk= 95 eV࡟ぢࡽࢀࡿࣆ࣮ࢡࡣࠊࣅ࣮࣒ࣛ࢖ࣥศග

㍍ඖ⣲࡛ࡣ⺯ග཰㔞ࡀ኱ኚᑠࡉ࠸ࡓࡵᇶᮏⓗ࡟ࡣ㟁ჾࡢ㧗ḟᅇᢡ࡟ࡼࡿග࡟ࡼࡿࡶࡢ࡛࠶ࡾࠊ࢔ࣥࢪࣗ

Ꮚ཰㔞࡟ࡼࡿ ᐃ࡜࡞ࡿࠋ

࣮ࣞࢱࡢࢠࣕࢵࣉ್࡟ࡼࡾ㧗ḟගẚࡀኚࢃࡿࡓࡵぢ㟁Ꮚ཰㔞ἲࡣࠊX ⥺ࢆ↷ᑕࡋࡓ࡜ࡁ࡟ᨺฟࡉࢀࡿග࠼ࡓࡾぢ࠼࡞࠿ࡗࡓࡾࡍࡿࠋhν = 195 eV (a)ࠊ198 eV (b)㟁Ꮚࡸ࣮࢜ࢪ࢙㟁Ꮚࢆほ ࡍࡿࡶࡢ࡛࠶ࡿࡀࠊ⤯⦕ඹ࡟ග㔞ࡀቑ࠼ࡿ࡟ᚑ࠸ప㐠ື࢚ࢿࣝࢠ࣮ഃ࡬ࢩࣇ

యヨᩱࡢሙྜ࡟ࡣ㟁Ꮚᨺฟ࡟ࡼࡾ⾲㠃࡟⏕ࡌࡓ㟁Ⲵࢺࡋ࡚࠸ࡿᵝᏊࡀࢃ࠿ࡿࡀࠊ(a) ࡟ẚ࡭ (b) ࡢ᪉ࡀࢩࣇ

ࢆ୰࿴ࡍࡿࡇ࡜ࡀ࡛ࡁࡎᖏ㟁ࢆ⏕ࡌࡿࠋࡇࢀ࡟ࡼࡾ

ࢺ㔞ࡀ኱ࡁࡃ࡞ࡗ࡚࠸ࡿࠋhν = 198 eV ࡣ྾཰ࢫ࣌ࢡࢺ

ᨺฟࡉࢀࡿ㟁Ꮚࡣ㐠ື࢚ࢿࣝࢠ࣮ (Ek) ࡢ୍㒊ࡶࡋࡃࡣࣝ࡟࠾࠸࡚ࣆ࣮ࢡࡀほ ࡉࢀࡿ࢚ࢿࣝࢠ࣮࡛࠶ࡿ(ᅗ࡯࡜ࢇ࡝ࢆኻ࠸ࠊ㟁Ꮚࡢ཰㔞ࡣῶᑡࡋ࡚ࡋࡲ࠺ࡇ࡜

(b))ࠋ

࠿ࡽṇᖖ࡞ࢫ࣌ࢡࢺࣝࢆᚓࡿࡇ࡜ࡀᅔ㞴࡛࠶ࡿࠋ࡛
ࡣࠊᐇ㝿࡟ࡣ࡝ࡢ⛬ᗘ࢚ࢿࣝࢠ࣮ࢆኻࡗ࡚࠸ࡿࡢ࠿ࠊ
࡝ࡢ⛬ᗘࡢᖏ㟁࡛࠶ࢀࡤࠗṇࡋ࠸࠘࡜࠸࠼ࡿࢫ࣌ࢡ
ࢺࣝࡀᚓࡽࢀࡿࡢ࠿᳨ドࡍࡿࡇ࡜ࡣ኱ኚ᭷⏝࡛࠶ࡿࠋࡇࢀࡣᨺฟࡉࢀࡓ㟁Ꮚࡢ Ek ศᕸࠊࡘࡲࡾග㟁Ꮚࢫ࣌ᖏ㟁㔞ࡀ㟁Ꮚᨺฟ㔞ࠊࡘࡲࡾ྾཰ᙉᗘ࡟౫Ꮡࡋࠊ
࢚ࢿࣝࢠ࣮ࢩࣇࢺ㔞ࡀᖏ㟁㔞ࢆ཯ᫎࡍࡿࡶࡢ࡛࠶ࢀ
ࡤࠊ྾཰➃㏆ഐ࡟࠾࠸࡚ࢩࣇࢺ㔞ࢆほ ࡍࢀࡤ㟁Ꮚ཰㔞࡟┦ᙜࡍࡿࢫ࣌ࢡࢺࣝࢆᚓࡿࡇ࡜ࡀ࡛ࡁࡿ࡜⪃࠼ࡿࡇ࡜ࡀ࡛ࡁࡿࠋࡑࡇ࡛ࠊB K ྾཰➃㏆ഐ࡟࠾࠸࡚

ࢡࢺࣝࢆィ ࡍࡿࡇ࡜࡛ྍ⬟࡛࠶ࡿࠋࡑࡢࡓࡵᮏ◊hν ࢆኚ໬ࡉࡏ࡞ࡀࡽ XPS ࢆ ᐃࡋࡓࠋᅗ  ࡣ XPS ࢫ✲࡛ࡣࠊ௦⾲ⓗ࡞⤯⦕యࡢ୍ࡘ࡛࠶ࡿභ᪉ᬗ❅໬࣍࣌ࢡࢺࣝࡢ hν ౫Ꮡᛶ࡛࠶ࡾࠊᙉᗘࡣ᭱኱ࣆ࣮ࢡᙉᗘ

࢘⣲ (h-BN) ⢊ᮎヨᩱ࡟ࡘ࠸࡚ࠊ྾཰➃㏆ഐࡢ X⥺࢚ࢿࣝࢠ࣮ (hν) ࡟࠾࠸࡚ග㟁Ꮚศග (XPS)ᅗ 4 ࡟ບ㉳ග࢚ࢿࣝࢠ࣮ hν = 500 eV࡛ ᐃࡋࡓ XPS

࡛つ᱁໬ࡋ࡚࠸ࡿࠋప hν ഃ࡛୺࡟ほ ࡉࢀ࡚࠸ࡿࡢ

ᐃࢆ⾜ࡗࡓࠋ

ࡣ౯㟁Ꮚᖏ࡛࠶ࡾࠊhν = 191.2 eV࠿ࡽ B 1s ෆẆ㟁Ꮚࡢບᐃࡣ AichiSR ࡢ㌾ X ⥺࢔ࣥࢪ࣮ࣗࣞࢱࣅ࣮࣒ࣛ࢖ࣥ

㉳࡟కࡗ࡚ KLL-Auger ࡀⓎ⌧ࡋ࡚࠸ࡿࠋᖏ㟁ࡋ࡚࠸࡞

BL7U࡛⾜ࡗࡓࠋBL7U࡛ࡣ྾཰ศග࡜ග㟁Ꮚศගࢆྠ

࠸ヨᩱ࡛࠶ࢀࡤࠊග㟁Ꮚ (౯㟁Ꮚ) ࡢ Ek ࡣ hν ࡟కࡗ୍࡚┿✵ᵴෆ࡛ィ ྍ⬟࡛࠶ࡾࠊࣅ࣮࣒ࣛ࢖ࣥศගჾቑ኱ࡋࠊAuger 㟁Ꮚ࡛ࡣ hν ࡟࠿࠿ࢃࡽࡎ୍ᐃࡢ್ࢆᣢ

࠾ࡼࡧࡑࢀࡒࢀࡢィ ᶵჾࢆ㐃ືࡉࡏࠊ྾཰ศගࡢ

ࡘࠋhν ࡟౫Ꮡࡋ࡚᫂☜࡟࢚ࢿࣝࢠ࣮ࢩࣇࢺࡀ⏕ࡌ࡚ྛ ᐃ hν ࡛ XPS ࢫ࣌ࢡࢺࣝࢆ⮬ືⓗ࡟ྲྀᚓࡍࡿࡇ࡜

࠸ࡿᵝᏊࡀࢃ࠿ࡿࠋࡇࢀࢆࢃ࠿ࡾࡸࡍ࠸ࡼ࠺࡟ᙉᗘ

ࡀྍ⬟࡛࠶ࡿࠋ

ࢆ⃰ῐ࡛⾲⌧ࡋࡓࡢࡀᅗ (a) ࡛࠶ࡿࠋᶓ㍈ࡣ hνࠊ⦪㍈28ࡣ Ek ࡛࠶ࡿࠋẚ㍑ࡋࡸࡍ࠸ࡼ࠺࡟⦪㍈ࡣୖࡀᑠࡉࡃࠊ

⠊ᅖෆ࡛ග㔞ࢆ୍ᐃ࡟ಖࡘᚲせࡀ࠶ࡿࠋࡲࡓࠊ୍㐃ୗഃࡀ౯㟁ᏊᖏഃࠊୖഃࡀෆẆ‽఩ഃ࡜࡞ࡿࡼ࠺࡟

ࡢࢹ࣮ࢱࢆྲྀᚓࡍࡿࡢ࡟㸯ࡘࡢ྾཰➃ᙜࡓࡾ⣙ 3 ᫬㛫సᅗࡋ࡚࠸ࡿࡇ࡜࡟ὀពࡉࢀࡓ࠸ࠋ(b) ࡟ᖏ㟁㔞ࡀ༑ࢆせࡋ࡚࠸ࡿࠋᮏ◊✲ࡢ⤖ᯝࡣ⤯⦕య࡟㐺⏝࡛ࡁࡿศ࡟ᑠࡉࡃ࡞ࡿࡼ࠺࡟ㄪ〇ࡋࡓヨᩱ࡟ࡼࡗ࡚ ᐃࡋ᪂ࡓ࡞㟁Ꮚ཰㔞 ᐃἲࡢ㛤Ⓨ࡟㐨ࢆᣅࡃࡶࡢ࡛࠶ࡿ

ࡓ඲㟁Ꮚ཰㔞 (TEY) ࢫ࣌ࢡࢺࣝࠊ(c) ࡟ hν = 225 eV ࡟࠾࡜⪃࠼࡚࠸ࡿࡀࠊୖグၥ㢟ⅬࢆゎỴࡋࠊ୍⯡ⓗ࡟㐺ࡅࡿ XPS ࢫ࣌ࢡࢺࣝࢆ♧ࡋࡓࠋ(a) ࡢ Ek< 150 eV ࡟ぢࡽ⏝࡛ࡁࡿᡭἲ࡜࡞ࡾ࠺ࡿ࠿◊✲ࢆ㐍ࡵ࡚࠸ࡃࠋ

ࢀࡿ⃰࠸㒊ศࡀ KLL-Auger࡛࠶ࡾࠊhν ࡜࡜ࡶ࡟ Ekࡀቑ኱ࡋ࡚࠸ࡿࡢࡀග㟁Ꮚ࡟ࡼࡿࣆ࣮ࢡ࡛࠶ࡾࠊKLL-

h-BN
XPS
hν = 500 eVAuger ࡼࡾࡶ㧗 Ek ࡟ぢࡽࢀ࡚࠸ࡿࡢࡣ౯㟁Ꮚᖏࠊప Ek
࡟ⷧࡃほ ࡉࢀ࡚࠸ࡿࡢࡣὸ࠸ෆẆ‽఩࡜㧗ḟග࡟(a) ᖏ㟁ᑐ⟇ࢆ᪋ࡋ࡚࠸࡞࠸ヨᩱࡼࡿෆẆ‽఩࡛࠶ࡿࠋ୍ぢࡋ࡚ࢃ࠿ࡿࡼ࠺࡟ࠊXPS ࡢࡒࢀ XPS ࡢ࢚ࢿࣝࢠ࣮ࢩࣇࢺࠊTEYࠊ඲⺯ග཰㔞
100(TFY) ࢫ࣌ࢡࢺ࡛ࣝ࠶ࡿࠋࡇࡕࡽࡶࡼࡃ෌⌧ࡋ࡚࠸ࡿࠋN KLL

࡟ࡘ࠸࡚⾜ࡗࡓ⤖ᯝࡀᅗ  ࡛࠶ࡾࠊ㉥ࠊ㟷ࠊ⥳ࡀࡑࢀ(b) Inࢩ࣮ࢺୖ࡟ⷧࡃሬᕸࡋࡓヨᩱ

B 1s

N 1s

ࡲ࡛኱ኚࡼࡃ෌⌧ࡋ࡚࠸ࡿࠋྠᵝࡢ ᐃࢆ N K྾཰➃

C 1s࢚ࢿࣝࢠ࣮ࢩࣇࢺ㔞ࡣࠊTEYࢫ࣌ࢡࢺࣝࢆ⣽࠿࠸ᵓ㐀

200
300
Electron Kinetic Energy (eV)

400

500

ࡇࡢࡼ࠺࡟ࠊ྾཰➃࡟࠾ࡅࡿ⤯⦕యヨᩱࡢᖏ㟁㔞ᅗ㸲 භ᪉ᬗ❅໬࣍࢘⣲ࡢග㟁Ꮚࢫ࣌ࢡࢺࣝࠋ(a) ᖏ

ࡣXPS࡟ࡼࡾほ ࡛ࡁࡿࡇ࡜ࡀ᫂ࡽ࠿࡟࡞ࡾࠊࡑࡢEk

㟁ᑐ⟇ࢆ᪋ࡋ࡚࠸࡞࠸⢊ᮎヨᩱ㸪(b) In ࢩ࣮ࢺୖ࡟ⷧ

ࢩࣇࢺ㔞ࡣ྾཰ᙉᗘࢆ཯ᫎࡍࡿࡇ࡜ࡀศ࠿ࡗࡓࠋࡓ

ࡃሬᕸࡋࡓ⢊ᮎヨᩱࠋᖏ㟁ᑐ⟇ࢆ᪋ࡋ࡚࠸࡞࠸ヨᩱࡔࡋࠊ௒ᅇࡢᐇ㦂࡛ࡣධᑕගᙉᗘࡢ hν ࡟ࡼࡿኚືࢆ

࡛ࡣヨᩱ⾲㠃ᖏ㟁ࡢࡓࡵࣆ࣮ࢡࢆ☜ㄆࡍࡿࡇ࡜ࡀ࡛

ไᚚࡋ࡚࠸࡞࠸ࠋࢩࣇࢺ㔞ࡣධᑕගᙉᗘ࡟౫Ꮡࡍࡿ

ࡁ࡞࠸ࠋࡇ࡜࠿ࡽࠊᐃ㔞໬ࡢࡓࡵ࡟ࡣ ᐃධᑕග࢚ࢿࣝࢠ࣮
(a) hν = 195 eV(b) hν = 198 eV

×1011
photons/sec.

8.8
7.6

8.8

6.4
6.7

5.0

4.7

3.6
2.4

2.7

1.5

1.3

0.88
0.58

0.62

0.35

0.37

0.27

0.28

0.20

0.20

60

100

140

180

60

Kinetic Energy (eV)

100

140

0.19
180

Kinetic Energy (eV)ᅗ㸳 X ⥺࢚ࢿࣝࢠ࣮195, 198 eV ࡛ ᐃࡋࡓග㟁Ꮚࢫ࣌ࢡࢺࣝࡢ↷ᑕග㔞౫Ꮡᛶࠋග㔞ࡀቑ࠼ࡿ࡜ప㐠ື࢚ࢿࣝࢠ࣮࡬ࢩࣇࢺࡋࠊࢩࣇࢺᖜࡣ X⥺࢚ࢿࣝࢠ࣮࡛␗࡞ࡿࠋ

29

(c) EDC

225(a) Intensity Map

50

B KLL

100

220

205

200

190

195

200

205

210

215

220

225

Photon Energy (eV)

Excitation Photon Energy (eV)Photoelectron Intensity (arb. units)

185

210

(b) Total Electron Yield

200

Photon Energy= 225 eV215

Valence150ᅗ㸵 X ⥺࢚ࢿࣝࢠ࣮ࠊ㟁Ꮚࡢ࢚ࢿࣝࢠ࣮࡟ᑐࡍࡿ
ᙉᗘศᕸࠋᙉᗘࡣ⃰ῐ࡛⾲ࡋࠊ⃰࠸᪉ࡀᙉ࠸ࠋ(b)࡟඲㟁Ꮚ཰㔞ࢫ࣌ࢡࢺࣝࠊ(c)࡟ X ⥺࢚ࢿࣝࢠ࣮
225eV ࡛ ᐃࡋࡓග㟁Ꮚࢫ࣌ࢡࢺࣝࢆ♧ࡋࡓࠋ

Energy Shift

195
Electron Yield

Fluorescence Yield

190

G1
S1/S2=75/75
I0: Mesh/PD/Mesh
TEY:Keithley8625
TFY:MCP –2.3kV
Eshift:A1#8,Epass100,10x1

380

185

400

420

440

460

480

Photon Energy (eV)

40
80
120
160
Electron Kinetic Energy (eV)ᅗ㸶 N K ྾཰➃࡟࠾ࡅࡿ࢚ࢿࣝࢠ࣮ࢩࣇࢺࡢ X ⥺ᅗ㸴 B K ྾཰➃㏆ഐ࡛ ᐃࡋࡓග㟁Ꮚࢫ࣌ࢡࢺࣝ

࢚ࢿࣝࢠ࣮౫Ꮡᛶ(a)ࠋẚ㍑ࡢࡓࡵࠊ(b)඲㟁Ꮚ཰㔞ࡢ X⥺࢚ࢿࣝࢠ࣮౫Ꮡᛶࠋ㐠ື࢚ࢿࣝࢠ୍࣮ᐃ࡛࠶

ࢫ࣌ࢡࢺࣝࠊ(c)඲⺯ග཰㔞ࢫ࣌ࢡࢺࣝࢆ♧ࡋࡓࠋࡿ Auger 㟁Ꮚࡢ࢚ࢿࣝࢠ࣮ࡀ X ⥺࢚ࢿࣝࢠ࣮࡜࡜ࡶ
࡟ኚືࡋ࡚࠸ࡿࠋ

30

ղ ,QVLWX; ⥺ࢺ࣏ࢢࣛࣇ࢕ ᐃࢩࢫࢸ࣒ࡢ㛤Ⓨ

D

%/6㸦; ⥺ࢺ࣏ࢢࣛࣇ࢕࣭; ⥺ &7㸸ឡ▱┴㸧
1. ࡣࡌࡵ࡟
BL8S2 ࡛ࡣࠊ༢Ⰽ X ⥺ࢆ⏝࠸ࡓ X ⥺ࢺ࣏ࢢࣛࣇ࢕ ᐃ࡟ࡼࡾࠊ༢⤖ᬗヨᩱࡢ⤖ᬗḞ㝗ほᐹࢆ⾜࠺ࡇ࡜ࡀ࡛ࡁࡿࠋලయⓗ࡟ࡣࠊ஧⤖ᬗศගჾࡢ Si ⤖ᬗࡢ θ ゅᗘࢆኚ࠼ࡿࡇ࡜࡛ⓑⰍ㹖⥺࠿ࡽᢳฟࡋࡓ༢Ⰽ
X ⥺㸦࢚ࢿࣝࢠ࣮㸸⣙ 6㹼26keV㸪Ἴ㛗㸸⣙ 2.07㹼
0.48 ύ㸧ࢆࠊ༢⤖ᬗヨᩱ࡟↷ᑕࡋ࡚ᅇᢡࡉࢀࡓ㹖⥺ࢆࢺ࣏ࢢࣛࣇ࢕ീ࡜ࡋ࡚ 2 ḟඖ᳨ฟჾ࡛ྲྀᚓࡍࡿࡇ
࡜࡟ࡼࡾࠊ⤖ᬗḞ㝗ࡢほᐹࢆ⾜࠺ࠋ BL8S2 ࡛ࡣ≉࡟ࠊṍࡳࡀ࠶ࡿ༢⤖ᬗヨᩱࡸ⤖ᬗᛶࡀⰋዲ࡛࡞࠸༢
⤖ᬗヨᩱ࡛࠶ࡗ࡚ࡶ୍ᗘࡢ ᐃ࡛඲㠃ࡀほᐹ࡛ࡁࡿE  F ࡼ࠺࡟ࠊ༢Ⰽ㹖⥺ࡢἼ㛗㸦࢚ࢿࣝࢠ࣮㸧ࢆ㐃⥆ⓗ࡟ᤲᘬࡉࡏࡿࡇ࡜࡛ X ⥺ࢺ࣏ࢢࣛࣇ࢕ീࢆྲྀᚓࡍࡿᐇ
㦂ࢆࡼࡃ⾜ࡗ࡚࠸ࡿࠋ
ᡃࠎࡣࠊ㧗 ࢔ࢽ࣮ࣝ୰ࡢ⤖ᬗ࡞࡝ࡢin-situ㸦ࡑࡢሙ㸧࡛ࡢ㹖⥺ࢺ࣏ࢢࣛࣇ࢕ ᐃࡢせᮃ࡟ᛂ࠼ࡿࡓ
ࡵࠊsCMOS X⥺࣓࢝ࣛࢆ⏝࠸࡚ࠊ⤖ᬗḞ㝗ࡢኚ໬ࢆ⛊༢఩࡛ほ ࡍࡿࡇ࡜ࡀྍ⬟࡞in-situ X⥺ࢺ࣏ࢢᅗ  in-situ X ⥺ࢺ࣏ࢢࣛࣇ࢕ ᐃࢆ⏝࠸ࡓ㧗ࣛࣇ࢕ ᐃࢩࢫࢸ࣒ࢆ㛤Ⓨࡋࡓࠋᐇ㦂ࠋ(a)㧗 㟁Ẽ⅔࡜㹖⥺ᅇᢡィᯫྎࢆ⤌ࡳྜࢃࡏࡓ㹖⥺ࢺ࣏ࢢࣛࣇ࢕ ᐃ⿦⨨ࡢᴫ␎

2. in-situ X⥺ࢺ࣏ࢢࣛࣇ࢕ ᐃࢩࢫࢸ࣒ࡢ㛤Ⓨ

ᅗࠊ(b)㏱㐣㓄⨨㹖⥺ࢺ࣏ࢢࣛࣇ࢕ ᐃᐇ㦂ᴫ㛤Ⓨࡋࡓin-situ X⥺ࢺ࣏ࢢࣛࣇ࢕ ᐃࢩࢫࢸ࣒࡟

␎ᅗࠊ(c)཯ᑕ㓄⨨㹖⥺ࢺ࣏ࢢࣛࣇ࢕ ᐃᐇ㦂ࡼࡾࠊX⥺࢚ࢿࣝࢠ࣮㸦Ἴ㛗㸧ࡢࢫ࢟ࣕࣥ⠊ᅖࠊ㟢ᴫ␎ᅗ㸦Fumihiro Fujie, et al., Appl. Phys. Lett.

ග᫬㛫ࠊ࢖ࣥࢱ࣮ࣂࣝ᫬㛫ࢆࣃ࣓࣮ࣛࢱ࡜ࡋ࡚㹖⥺

113, 012101 (2018)࠿ࡽᢤ⢋㸧ࠋࢺ࣏ࢢࣛࣇ࢕ ᐃࢆ㐃⥆ⓗ࡟in-situ࡛⾜࠼ࡿࡼ࠺࡟
࡞ࡗࡓࠋࡋ࡚⾲♧ࡉࢀࡿࠋ⾲♧ᚋࠊ࢖࣓࣮ࢪࢹ࣮ࢱࡢ⏬ീࣇ

X⥺ࢺ࣏ࢢࣛࣇ࢕ ᐃ๓ࡢ᮲௳ㄪᩚࡣࠊࣛ࢖ࣈ࢖

࢓࢖ࣝಖᏑ࡜X⥺࢚ࢿࣝࢠ࣮㸦Ἴ㛗㸧ࡢ ᐃ㛤ጞ఩࣓࣮ࢪ ᐃᶵ⬟ࢆ⏝࠸࡚⾜࠺ࠋࣛ࢖ࣈ࢖࣓࣮ࢪ ᐃ⨨࡬ࡢ⛣ືࢆ୪ิ࡛⾜࠺ࠋࡇࡢ୍㐃ࡢࣉࣟࢭࢫࢆ⧞

ᶵ⬟ࢆ⏝࠸࡚ࠊࢺ࣏ࢢࣛࣇ࢕ീࢆ㐃⥆⾲♧ࡉࡏࡘࡘࠊ ࡾ㏉ࡋ㐃⥆ⓗ࡟⾜࠺ࡇ࡜࡟ࡼࡾࠊin-situ X⥺ࢺ࣏ࢢᮏ ᐃ๓ࡢヨᩱ఩⨨ㄪᩚࠊX⥺࢚ࢿࣝࢠ࣮㸦Ἴ㛗㸧ࣛࣇ࢕ ᐃࢆᐇ⌧ࡋ࡚࠸ࡿࠋ

ㄪᩚࢆ⾜࠺ࠋ᮲௳ㄪᩚࢆ⤊࠼ࡓᚋ࡟ࠊぢฟࡋࡓ᮲௳
ࢆࡶ࡜࡟ ᐃ᮲௳ࢆධຊࡋࠊࢺ࣏ࢢࣛࣇ࢕ ᐃࡢᣦ

3. 4H-SiC༢⤖ᬗࡢ㧗 in-situ X⥺ࢺ࣏ࢢࣛࣇ࢕

♧ࢆฟࡍ࡜ ᐃࡀ㛤ጞࡉࢀࡿࠋධᑕX⥺ࡢ࢚ࢿࣝࢠᐃ [1]࣮㸦Ἴ㛗㸧ࢆ㐃⥆ⓗ࡟ᤲᘬࡋ࡞ࡀࡽࠊX⥺࣓࢝ࣛ࡟㛤Ⓨࡋࡓin-situ X⥺ࢺ࣏ࢢࣛࣇ࢕ ᐃࢩࢫࢸ࣒ࢆ

X⥺ࢺ࣏ࢢࣛࣇ࢕ᅇᢡගࢆ㟢ගࡋ࡚ࢺ࣏ࢢࣛࣇ࢕ീ

⏝࠸࡚ࠊ⸨ᴿࡽ㸦ྡྂᒇ኱㸧࡟ࡼࡗ࡚ࠊ㏱㐣㓄⨨࠾ࢆྲྀᚓࡋࠊྲྀᚓࡉࢀࡓࢹ࣮ࢱࡣ⏬㠃ୖ࡟࢖࣓࣮ࢪ࡜

ࡼࡧ཯ᑕ㓄⨨࡛ࡢ4H-SiC༢⤖ᬗෆࡢ✚ᒙḞ㝗ࡢ㧗

31

ᅗ  (a)ࡣ࢔ࢽ࣮ࣝ๓ࠊ(b)~(g)ࡣ࢔ࢽ࣮ࣝ୰ࠊ(h)ࡣ࢔ࢽ࣮ࣝᚋࡢࠊ(-1100)཯ᑕࡢࢺ࣏ࢢࣛࣇ࢕ീࠋ
㸦Fumihiro Fujie, et al., Appl. Phys. Lett. 113, 012101 (2018)࠿ࡽᢤ⢋㸧ࠋ࡛ࡢᣲືࡢほᐹࡀ⾜ࢃࢀࡓࠋᅗࡣ ᐃ࡟⏝࠸ࡽࢀࡓᐇ㦂⿦⨨ࡢᴫせ࡛࠶ࡿࠋ4H-SiC༢⤖ᬗࡢ᪼᫬࡟ࠊ⤖ᬗෆࡢ✚ᒙḞ㝗ࡀࠊ1370 ~ 1550 Kࡢ⠊ᅖ࡟࠾࠸࡚ᣑ኱ࡋࠊ1550 K௨ୖ࡟࡞ࡿ࡜⦰ᑠࡍࡿࡇ
࡜ࡀ☜ㄆࡉࢀࡓ㸦ᅗ㸧ࠋࡲࡓࠊ㝆 ୰࡟࠾࠸࡚ࡣࠊ
1370 ~ 1550 Kࡢ⠊ᅖ࡟࠾࠸࡚ࡶ✚ᒙḞ㝗ࡀᣑ኱ࡍࡿࡇ࡜ࡣ࡞࠿ࡗࡓࠋࡇࢀࡽࡢ⤖ᯝ࠿ࡽࠊ4H-SiC༢⤖ᬗෆࡢ⤖ᬗ࢚ࢵࢪ㏆ഐࡢ✚ᒙḞ㝗ࢆࠊ᪼ ࡟ࡼࡗ࡚᤼ฟ࡛ࡁࡿྍ⬟ᛶࡀ♧၀ࡉࢀࡓࠋ
ཧ⪃ᩥ⊩[1] Fumihiro Fujie, et al., Appl. Phys. Lett. 113,012101 (2018).
32 እ㒊Ⓨ⾲

Binding and Degradation, A. Nakamura, N.

  ㄽᩥ㸦 ᖺ  ᭶㹼 ᖺ  ᭶ 

Kobayashi, N. Koga, R. Iino, ACS Catal. 11, 14, 8550–
8564 (2021).

ձᰝㄞ௜ࡁㄽᩥ
BL1N2

BL2S1

Effects of aluminum substitution in nickel-richovel Device and Strategy for Growing Large, HighQuality

layered LiNixAl1−xO2 (x = 0.92, 0.95) positive electrodeProtein

Crystals

Conditions,byN.

Controllingmaterials for Li-ion batteries on high-rate cycle

Crystallization

Tanigawa,

S.

performance, H. Kaneda, Y. Furuichi, A. Ikezawa, H.

Takahashi, B. Yan, M. Kamo, N. Furubayashi, K.
Kubota, K. Inaka, H. Tanaka, Crystals 11(11), 1311

Arai, J. Mater. Chem. A, 9, 21981-21994 (2021).

(2021). DOI:10.3390/cryst11111311
BL1N2
BL2S1

Atomic Structures and Chemical States of Active andInactive Dopant Sites in Si-Doped GaN, J. Tang andStructural basis of the protochromic green/red

Y. Yamashita, ACS Appl. Electron. Mater. 3, 10,

photocycle of the chromatic acclimation sensor RcaE,
T. Nagae, M. Unno, T. Koizumi, Y. Miyanoiri, T.

4618–4622 (2021).

Fujisawa, K. Masui, T. Kamo, K. Wada, T. Eki, Y. Ito,
BL1N2

Y. Hirose, M. Mishima, Biochemistry, 118 (20)ࣜࢳ࣒࢘࢖࢜ࣥ㟁ụṇᴟᮦᩱ Li(Ni1/3Co1/3Mn1/3)O2

e2024583118 (2021).

ࡢຎ໬ゎᯒ, Ọぢ ဴኵ, 㔝ᮏ ㇏࿴, ᮡᒣ 㝧ᰤ, ❧ᮌ ⩧BL2S1

἞, ᆏᮏ ᗮ, ኴ⏣ ಇ᫂, Electrochemistry, 89(4) pp

Structural Insights into the Regulation of Actin363-369 (2021).

Capping Protein by Twinfilin C-terminal Tail,

DOI:10.5796/electrochemistry.21-00031

S. Takeda, R. Koike, I. Fujiwara, A. Narita, M.
Miyata, M. Ota, Y. Maéda, Journal of Molecular

BL1N2

Biology, Volume 433, Issue 9, 30 April 2021, 166891.

Local atomic structure analysis around Mg atom
doped in GaN by X-ray absorption spectroscopy and

BL2S1

spectrum simulations, N. Isomura, Y. Kimoto, J.

Elasticity of nanocrystalline kyanite at high pressure

Synchrotron Radiation, Vol. 28(4) 1114-1118 (2021).

and temperature from ultrasonic and synchrotron Xray techniques, N.A. Gaida, S. Gréaux, Y. Kono, H.

BL1N2, BL6N1, BL11S2
Mechanism of gold and palladium adsorption on

Ohfuji, H. Kuwahara, N. Nishiyama, O. Beermann,

thermoacidophilic red alga Galdieria sulphuraria, E.

T. Sasaki, K. Niwa, M. Hasegawa, Journal of theAmerican Ceramic Society (2021).

Adams, K. Maeda, T. Kato, C. Tokoro, Algal Research,

DOI:10.1111/jace.17464

Vol. 60, 102549 (2021).

BL2S1

BL2S1
Positive Charge Introduction on the Surface of

3D Supramolecular Chiral Crystal Structures ofThermostabilized PET Hydrolase Facilitates PET

Radical Anion Salts of (−)-NDI-Δ and Possible

33

Magnetic Phase Diagrams, Asato Mizuno, Yoshiaki

BL5S1

Shuku, Rie Suizu, Masahisa Tsuchiizub and Kunio

Carbonated nanohydroxyapatite from bone waste

Awaga, Cryst Eng Comm, 23, 5053–5059 (2021).

and its potential as a super adsorbent for removal of

DOI:10.1039/d1ce00628b

toxic ions, Y. Sekine, T. Nankawa, T. Yamada, D.
Matsumura, Y. Nemoto, M. Takeguchi, T. Sugita, I.

BL2S1

Shimoyama, N. Kozai, S. Morooka, Journal of

Crystal and Electronic Structure of U7Te12-Type

Environmental Chemical Engineering, Volume 9,

Tungsten Nitride Synthesized under High Pressure,

Issue 2, April 2021, 105114.

C-C. Chang, T. Sasaki, N.A. Gaida, K. Niwa, M.
BL5S1

Hasegawa, Inorg. Chem. 60, 17, 13278–13283 (2021).

Ferromagnetism and giant magnetoresistance in
BL2S1

zinc-blende

FeAs

Nitriding synthesis and structural change ofsemiconductor structures, L.D. Anh, T. Hayakawa, Y.

phosphorus nitrides at high pressures, K. Niwa, Y.

Nakagawa, H. Shinya, T. Fukushima, M. Kobayashi,

Iijima, M. Ukita, R. Toda, K. Toyoura, T. Sasaki, K.

H. Katayama-Yoshida, Y. Iwasa, M. Tanaka, Nature

Matsunaga, N.A. Gaida, M. Hasegawa, Raman

Communications volume 12, Article number: 4201

Spectroscopy, Vol. 52(5), 1064-1072 (2021).

(2021).

BL2S1

BL5S1

Crystal and Electronic Structures of MoSi2-Type

Kinetic Control of the Li0.9Mn1.6Ni0.4O4 Spinel

CrGe2 Synthesized under High Pressure, Takuya

Structure

Sasaki, Kota Kanie, Tatsuya Yokoi, Ken Niwa, Nico

Performance, F.A. Vásquez, N.C. Rosero-Navarro, A.

Alexander Gaida, Katsuyuki Matsunaga, andMiura, R. Jalem, Y. Goto, M. Nagao, Y. Tateyama, K.

Masashi Hasegawa, Inorg. Chem., 60(3) 1767–1772

Tadanaga, J.A. Calderón, ACS Appl. Mater.

(2021).

Interfaces 13, 12, 14056–14067 (2021).

BL2S1, BL5S2

BL5S1

Structural phase transition and giant negative

Oxidative decomposition of ammonium ion withthermal expansion in pyrophosphate Zn2–xMgxP2O7,

ozone in the presence of cobalt and chloride ions for

Y. Kadowaki, R. Kasugai, Y. Yokoyama, N.

the treatment of radioactive liquid waste, H. Aihara,

Katayama, Y. Okamoto, K. Takenaka, Appl. Phys.

S. Watanabe, A. Shibata, L. Mahardiani, R. Otomo,

Lett., Vol 119(17) 201906 (2021).

Y. Kamiya, Progress in Nuclear Energy, Volume 139,withmonolayers

Enhanced

embeddedinElectrochemical

September 2021, 103872.
BL5S1
Fluorine solubility and superconducting properties of

BL5S1

Sm(O,F)BiS2 single crystals, K. Kinamia, Y. Hanada,

Electron transfer in LiMn1.5Ni0.5O4 during charging

M. Nagao, A. Miura, S. Hirai, Y. Maruyama, S.

studied with soft X-ray spectrometry, R. Okamoto, M.

Watauchi, I. Tanaka, Journal of Alloys andTerauchi, Microscopy, Volume 70, Issue 5, OctoberCompounds, Vol. 883, 25 November 2021, 160812.

2021, Pages 450–460.

34

BL5S1Lanthanoid Elements (Eu, Gd, Tb, and Dy) in Their

Synthesis of nanometer-sized gallium oxide using

Complex Oxides, H. Asakura, S. Hosokawa, K.

graphene oxide template as a photocatalyst for

Teramura, T. Tanaka, Inorg. Chem. 60, 13, 9359–

carbon dioxide reduction, K. Sonoda, M. Yamamoto,

9367 (2021).

T. Tanabe, T. Yoshid, Applied Surface Science,
BL5S1

Volume 542, 15 March 2021, 148680.

Removal mechanisms of arsenite by coprecipitation
BL5S1

with ferrihydrite, Y. Takaya, M. Kadokura, T. Kato,

Flexible Photocatalytic Electrode Using Graphene,

C. Tokoro, Journal of Environmental Chemical

Non-noble Metal, and Organic Semiconductors forEngineering, Volume 9, Issue 5, October 2021,

Hydrogen Evolution Reaction, K. Kondo, Y.

105819.

Watanabe, J. Kuno, Y. Ishii, S. Kawasaki, M. Kato,
G. Kalita, Y. Hattori, O. Mashkov, M. Sytnyk, W.

BL5S1

Heiss, Energy Technology, Vol. 9 (8) 2100123 (2021).

Separation of cathode particles and aluminum
current foil in Lithium-Ion battery by high-voltage

BL5S1

pulsed discharge Part I: Experimental investigation

Effects of particle size of raw materials on phase

C. Tokoro, S. Lim, K. Teruya, M. Kondo, K.

formation and optical properties of Ce3+-doped

Mochidzuki, T. Namihira, Y. Kikuchi, Waste

Y3Al5O12 phosphors, S. Akiyama, R. Moriyama, J.

Management, Volume 125, 15 April 2021, Pages 58-

Tanaka, Y. Sato, M. Kakihana, H. Kato, Optical

66.

Materials, Volume 121, November 2021, 111549.
BL5S1
BL5S1

Understanding the active sites of boron nitride forHigh-capacity Li-excess lithium nickel manganese

CWPO:

oxide as a Co-free positive electrode material, M.

approach, A. Quintanilla, G. Vega, J. Carbajo, J.A.

Tabuchi, R. Kataoka, K. Yazawa, Materials Research

Casas, Y. Lei, K. Fujisawa, H. Liu, R. Cruz-Silva, M.

Bulletin, Volume 137, May 2021, 111178.

Terronesbcd, P. Miranzo, M.I. Osendi, M. Belmonte,Anexperimental

andcomputational

J.F. Sanz, Chemical Engineering Journal, Volume406, 15 February 2021, 126846.

BL5S1
Cationic

poly-L-aminoacid-enhanced

selectivehydrogen production based on formate decomposition

BL5S1, BL5S2

with

by

A novel Eu2+-activated calcium zirconium silicate

polyvinylpyrrolidone, Yusuke Minami and Yutaka

phosphor: Ca3ZrSi2O9:Eu2+, Y. Sato, R. Miyake, A.

Amao, New J. Chem., 45, 9324-9333 (2021). DOI:

Tanigaki, S. Akiyama, K. Tomita, M. Kakihana,

10.1039/D1NJ01181B

Journal of Luminescence, Volume 231, March 2021,

platinumnanoparticles

dispersed

117752.
BL5S1
Local Structure and L1- and L3-Edge X-ray

BL5S1, BL5S2

Absorption Near Edge Structures of Middle

Effect35

ofchemicaloxidationofspinel-type

LiNi0.5Mn1.3Ti0.2O4 by soaking in HNO3, HCl and

BL5S1, BL11S2

H2SO4, K. Fujimoto, Y. Kitajima, A. Aimi, Journal of

Structure–Property

Solid State Chemistry, Volume 302, October 2021,

Nanoparticles

122366.

Dehydrogenation of Methylcyclohexane, K. Murata,

Relationships

Supported

on

of

Al2O3

Pt–Sn
for

the

N. Kurimoto, Y. Yamamoto, A. Oda, J. Ohyama, A.
BL5S1, BL6N1

Satsuma, ACS Appl. Nano Mater. 4, 5, 4532–4541

Electrochemically synthesized liquid-sulfur/sulfide(2021).

composite materials for high-rate magnesium
battery cathodes, K. Shimokawa, T. Furuhashi, T.

BL5S1, BL11S2

Kawaguchi, W.Y. Park, T. Wada, H. Matsumoto, H.

High Durability of a 14-Membered Hexaaza

Kato, T. Ichitsubo, J. Mater. Chem. A, 9, 16585-16593

Macrocyclic Fe Complex for an Acidic Oxygen(2021).

Reduction Reaction Revealed by In Situ XAS
Analysis, J. Ohyama, M. Moriya, R. Takahama, K.

BL5S1, BL11S2

Kamoi, S. Kawashima, R. Kojima, T. Hayakawa, Y.

Electrochemical quartz crystal microbalance studies

Nabae, JACS Au 1, 10, 1798–1804 (2021).

on specific adsorption of nanoparticle stabilizers on
platinum surface, J. Kugai, S. Tanaka, S. Seino, T.

BL5S2

Nakagawa, T.A. Yamamoto, H. Yamada, Journal ofPressure-Tunable Crystal Structure and Magnetic

Electroanalytical Chemistry, Vol. 897, 15 September

Transition Temperature of the Nowotny Chimney-

2021, 115596.

Ladder CrGeγ Phase, T. Sasaki, K. Noda, N.A. Gaida,
K. Niwa, M. Hasegawa, Inorg. Chem. 60, 19, 14525–

BL5S1, BL11S2

14529 (2021).

Low temperature activation of inert hexagonal boron
nitride for metal deposition and single atom catalysis,

BL5S2

Y. Lei, S. Pakhira, K. Fujisawa, H. Liu, C. Guerrero-

Giant negative thermal expansion of polycrystalline

Bermea, T. Zhang, A. Dasgupta, L.M. Martinez, S.R.

Ti2O3 induced by microstructural effects, Y.

Singamaneni, K. Wang, J. Shallenberger, A.L. Elías,

Kadowaki, R. Kasugai, Y. Yokoyama, N. Katayama,

R. Cruz-Silva, M. Endo, J.L. Mendoza-Cortes, M.

Y. Okamoto, and K. Takenaka, Appl. Phys. Lett., Vol

Terrones, Materials Today, Volume 51, December

119(17) 171901 (2021).

2021, Pages 108-116.
BL5S2
BL5S1, BL11S2

Slow dynamics of disordered zigzag chain molecules

Structural Transformation of Pt–Ni Nanowires asin layered LiVS2 under electron irradiation, N.

Oxygen Reduction Electrocatalysts to Branched

Katayama, K. Kojima, T. Yamaguchi, S. Hattori, S.

Nanostructures during Potential Cycles, M. Kato, Y.

Tamura, K. Ohara, S. Kobayashi, K. Sugimoto, Y.

Iguchi, T. Li, Y. Kato, Y. Zhuang, K. Higashi, T.

Ohta, K. Saitoh, H. Sawa, npj Quantum Materials

Uruga, T. Saida, K. Miyabayashi, I. Yagi, ACS Catal.

volume 6, Article number: 16 (2021).

12, 1, 259–264 (2022).

36

BL5S2
Tailoring the Lithium-ion Conductivity of Li2OHBr

BL5S2

by Substitution of Bromine with Other Halogens,

Structural adsorption mechanism of chloroform in

M.K. Sugumar, T. Yamamoto, M. Motoyama, Y.

narrow micropores of pitch-based activated carbon

Iriyama,fibres, Y. Yoshikawa, K. Teshima, R. Futamura, H.

Chem.

Lett.

50,

448–451(2021).

Tanaka, T. Iiyama, K. Kaneko, Carbon, Vol. 171, pp.

DOI:10.1246/cl.200778

681-688 (2021).
BL5S2
Phase relations and thermoelasticity of magnesium

BL5S2

silicide at high pressure and temperature, N. A.

High-Density Frenkel Defects as Origin of N-Type

Gaida, K. Niwa, T. Sasaki, M. Hasegawa, J. Chem.

Thermoelectric Performance and Low Thermal

Phys. 154, 144701 (2021). DOI:10.1063/5.0044648

Conductivity in Mg3Sb2-Based Materials, T. Kanno,
H. Tamaki, M. Yoshiya, H. Uchiyama, S. Maki, M.

BL5S2

Takata, Y. Miyazaki, Advanced Functional Materials,

Novel synthesis of single-crystalline TbCu7-type Sm–

Vol. 31(13) 2008469 (2021).

Fe powder by low-temperature reduction-diffusion
process using molten salt, S. Okada, K. Takagi,

BL5S2

Journal of Rare Earths, 40 1126-1133 (2022).

Low-Resistance Mechanism of Nanoflake Crystalline

DOI: 10.1016/j.jre.2021.05.017

Aromatic Dicarboxylates with Selective Defects for
Safe and Fast Charging Negative Electrodes, N.

BL5S2

Ogihara, M. Hasegawa, H. Kumagai, H. Nozaki,

Phase Evolution of Trirutile Li0.5FeF3 for Lithium-Ion

ACS Nano 15, 2, 2719–2729 (2021).

Batteries, Y. Zheng, S. Tawa, J. Hwang, Y. Orikasa,
K. Matsumoto, R. Hagiwara, Chem. Mater. 33, 3,

BL5S2

868–880 (2021).

Synthesis and ion transport properties of RE3GaO6(RE = rare earth) oxide ion conductors, S. Tajima, J.

BL5S2

Lee, A. Suzumura, N. Ohba, Journal of the European

Structural and transport properties of Ni- and Ti-

Ceramic Society Volume 41, Issue 8, July 2021, Pages

doped lithium manganese spinels, S. Abe, M. Takagi,

4516-4527.

S. Iwasaki, F. Munakata, Journal of Solid State
Chemistry, Volume 294, February 2021, 121863.

BL5S2
Synthesis

andIon-Transport

Properties

of

BL5S2

EuKGe2O6-, Ca3Fe2Ge3O12-, and BaCu2Ge2O7-Type

Investigation of the Difference in Charge/Discharge

Oxide-Ion Conductors, S. Tajima, N. Ohba, A.

Resistance for Cathode Materials after Cycle Test

Suzumura, S. Kajita, Inorg. Chem. 60, 22, 17019–

Combined with STEM-EELS and XAFS Analysis, Y.

17032 (2021).

Shimonishi, D. Mori, Y. Maeda, S. Taminato, N.
Imanishi, S. Yoshida, J. Electrochem. Soc. 168

BL5S2040533 (2021).

Thermal Behavior of Li1+x[Li1/3Ti5/3]O4 and a Proof of37

Concept for Sustainable Batteries, K. Mukai, T.

BL5S2, BL8S3

Uyama, T. Nonaka, ACS Appl. Mater. Interfaces 13,

Spontaneously formed nanostructures in double

36, 42791–42802 (2021).

perovskite rare-earth tantalates for thermal barrier
coatings, T. Ogawa, T. Matsudaira, D. Yokoe, E.

BL5S2, BL8S1

Kawai, N. Kawashima, C.A.J. Fisher, Y. Habu, T.

Room Temperature Operation and High Cycle

Kato, S. Kitaoka, Acta Materialia, Volume 216, 1

Stability of an All-Solid-State Lithium Battery

September 2021, 117152.

Fabricated by Cold Pressing Using Soft Li2OHBr
Solid Electrolyte, K. Yoshikawa, T. Yamamoto, M. K.

BL5S2, BL11S2

Sugumar, M. Motoyama, Y. Iriyama, Energy Fuels

Promoting35, 15, 12581–12587 (2021).

Magnesium

Reversible

CathodeRechargeable

Reactions

Batteries

in

Using

Metastable Cubic MgMn2O4 Spinel Nanoparticles, H.
BL5S2, BL8S1

Kobayashi, K. Samukawa, M. Nakayama, T. Mandai,

Theoretical and Experimental Studies of KLi6TaO6I. Honma, ACS Appl. Nano Mater. 4, 8, 8328–8333

as a Li-Ion Solid Electrolyte, N. Suzuki, J. Lee, Y.

(2021).

Masuoka, S. Ohta, T. Kobayashi, R. Asahi, Inorg.
BL5S2, BL11S2

Chem. 60, 14, 10371–10379 (2021).

Quantitative Evaluation of the Activity of Low-Spin
BL5S2, BL8S1

Tetravalent Nickel Ion Sites for the Oxygen

Highly oxidation-resistant graphene-based porous

Evolution Reaction, Y. Ren, T. Horiguchi, T.

carbon as a metal catalyst support, S. Wang, Y.

Uchiyama, Y. Orikasa, T. Watanabe, K. Yamamoto,

Yoshikawa, Z. Wang, H. Tanaka, K. Kaneko, Carbon

T. Takami, T. Matsunaga, Y. Nishiki, S. Mitsushima,

Trends, Volume 3, April 2021, 100029.

Y. Uchimoto, ACS Appl. Energy Mater. 4, 10, 10731–
10738 (2021).

BL5S2, BL8S1
The subtracting pore effect method for an accurate

BL5S2, BL11S2

and reliable surface area determination of porous

The Effect of Cation Mixing in LiNiO2 toward thecarbons, S. Wang, F.V-Burgos, A. Furuse, Y.

Oxygen Evolution Reaction, Y. Ren, R. Yamaguchi, T.

Yoshikawa, H. Tanaka, K. Kaneko, Carbon, Volume

Uchiyama, Y. Orikasa, T. Watanabe, K. Yamamoto,175, 30 April 2021, Pages 77-86.

T. Matsunaga, Y. Nishiki, S. Mitsushima, Y.
Uchimoto, ChemElectronChem, Vol. 8(1) 70-76

BL5S2, BL8S1(2021).

Anisotropic Nd-Fe ultrafine particles with stable andmetastable phases prepared by induction thermal

BL5S2, BL11S2

plasma, Y. Hirayama, M. Shigeta, Z. Liu, N. Yodoshi,

Effect of Al substitution on structure and cathodeA. Hosokawa, K. Takagi, J. Alloys and Compounds,

performance of MgMn2O4 spinel for magnesium

Volume 873, 25 August 2021, 159724.

rechargeable battery, R. Yokozaki, H. Kobayashi, T.
Mandai, I. Honma, J. Alloys and Compounds, Vol.
872(15) 159723 (2021).

38

Interphase in Lithium–Sulfur Batteries, C. Kensy, D.
BL5S2, BL11S2

Leistenschneider, S. Wang, H. Tanaka, S. Dörfler, K.

Phase Transition Behavior of MgMn2O4 Spinel Oxide

Kaneko, S. Kaskel, Batteries & Supercaps, Volume4,

Cathode during Magnesium Ion Insertion, Feilure

Issue4, April 2021, Pages 612-622.

Tuerxun,

Saeko

Otani,

KentaroYamamoto,

Toshiyuki Matsunaga, Hiroaki Imai, Toshihiko

BL6N1

Mandai, Toshiki Watanabe, Tomoki Uchiyama,

Distribution and chemical species of phosphorus

Kiyoshi Kanamura, and Yoshiharu Uchimoto, Chem.

across density fractions in Andisols of contrasting

Mater. 33, 3, 1006–1012 (2021).

mineralogy, A. Takamoto, Y. Hashimoto, M. Asano,
K. Noguchi, R. Wagai, Geoderma, Volume 395, 1
August 2021, 115080.

BL5S2, BL11S2
CaMn7O12 Quadruple Perovskite Oxides Proceed by
Two-Active-Site Reaction Mechanism for the Oxygen

BL6N1

Evolution Reaction, Y. Ren, K. Kashihara, T.

Microscale

Uchiyama, Y. Orikasa, T. Watanabe, K. Yamamoto,Speciation of Phosphorus in Soils Amended with

T. Takami, T. Matsunaga, Y. Nishiki, S. Mitsushima,

Mineral Fertilizer and Cattle Manure Compost, N.

Y. Uchimoto, Chemistry Europe, Volume8, Issue23,

Yamaguchi, T. Ohkura, A. Hikono, Y. Hashimoto, A.

Pages 4605-4611 (2021).

Suda, T. Yamamoto, K. Ando, M. Kasuya, P.

Heterogeneous

Distribution

andNorthrup, S-L. Wang, D. Hesterberg, Minerals 11(2),121 (2021). DOI:10.3390/min11020121

BL6N1
Eutectic salt mixture-assisted sodium-vapor-induced
synthesis of Pt–Ca nanoparticles, and their

BL6N1

microstructural and electrocatalytic properties, H.

Preparation

Itahara, N. Takahashi, S. Kosaka, Y. Takatani, M.

Nanoparticle Powders Submitting Reactive Oxygen

Inaba, Y. Kamitaka, Chem. Commun., 57, 4279-4282

Species (ROS) under Dark Conditions, T.M.P.

(2021).

Nguyen, P. Lemaitre, M. Kato, K. Hirota, K.

of

AnataseTitanium

DioxideTsukagoshi, H. Yamada, A. Terabe, H. Mizutani, S.
BL6N1

Kanehira, Materials Sciences and Applications, 12,

Design, Identification, and Evolution of a Surface

89 (2021). DOI:10.4236/msa.2021.122006

Ruthenium(II/III) Single Site for CO Activation, L.
Kang, B. Wang, A. Thetford, K. Wu, M. Danaie, Q.

BL6N1

He, E.K. Gibson, L-D. Sun, H. Asakura, C.R.A.

Fe(III) loaded chitosan-biochar composite fibers for

Catlow,Chemie,the removal of phosphate from water, K. N.

Volume133, Issue3, January 18, 2021, Pages 1232-

Palansooriya, S. Kim, A. D. Igalavithana, Y.

1239.

Hashimoto, Y.-E. Choi, R. Mukhopadhyay, B. Sarkar,

F.R.

Wang,

Angewandte

Y.S. Ok, Journal of Hazardous Materials, Volume415, 5 August 2021, 125464.

BL6N1
The Role of Carbon Electrodes Pore Size Distribution
on the Formation of the Cathode–Electrolyte

39

BL6N1
Speciation of phosphorus accumulated in fertilized

BL6N1

cropland of Aichi prefecture in Japan with different

X-ray Absorption Near-Edge Spectroscopy Analysis

soil properties by sequential chemical extraction andof Indomethacin in Crystalline Forms and in

P K-edge XANES, K. Ando, N. Yamaguchi, Y.

Amorphous Solid Dispersions, H. Suzuki, M. Iwata,

Nakamura, M. Kasuya, K. Taki, Soil Science and

M. Ito, S. Noguchi, Mol. Pharmaceutics, 18(9) 3475–

Plant Nutrition, Volume 67, Issue 2, Pages 150-161

3483 (2021).

(2021).
BL6N1
BL6N1

Preparationofsilver-decorated

Soluplus®

Structural characterization by X-ray analytical

nanoparticles and antibacterial activity towards S.

techniques of calcium aluminate cement modified

epidermidis biofilms as characterized by STEM-CL

with sodium polyphosphate containing cesium

spectroscopy, C. Takahashi, T. Yamada, S. Yagi, T.

chloride, Y. Takahatake, S. Watanabe, K. Irisawa, H.

Murai, S. Muto, Materials Science and Engineering:

Shiwaku, M. Watanabe, J. Nuclear Materials,

C, Volume 121, February 2021, 111718.

Volume 556, 1 December 2021, 153170.
BL6N1
BL6N1

A practical method for determining film thickness

Investigation of Physical Properties of Disodiumusing X-ray absorption spectroscopy in total electron

Etidronateofyield mode, N. Isomura, K. Oh-ishi, N. Takahashi

Phosphorus K-Edge X-Ray Absorption Near-Edgeand S. Kosaka, J. Synchrotron Rad. 28, 1820-1824

Structure Spectroscopy, N. Ito, T. Hashizuka, M. Ito,

(2021). DOI:10.1107/S1600577521009401

TetrahydrateandApplication

H. Suzuki, S. Noguchi, Pharmaceutical Research, Vol.
38, pp. 2147–2155 (2021).

BL7U
Functional nitrogen science based on plasma

BL6N1

processing: quantum devices, photocatalysts andHigh Rate Capability from a Graphite Anodeactivation of plant defense and immune systems, T.

through Surface Modification with Lithium Iodide for

Kaneko, H. Kato, H. Yamada, M. Yamamoto, T.

All-Solid-State Batteries, S. Yang, K. Yamamoto, X.

Yoshida, P. Attri, K. Koga, T. Murakami, K. Kuchitsu,

Mei, A. Sakuda, T. Uchiyama, T. Watanabe, T.

S. Ando, Y. Nishikawa, K. Tomita, R. Ono, T. Ito, A.M.

Takami, A. Hayashi, M. Tatsumisago, Y. Uchimoto,Ito, K. Eriguchi, T. Nozaki, T. Tsutsumi, K. Ishikawa,

ACS Appl. Energy Mater. 5, 1, 667–673 (2022)..

Jpn. J. Appl. Phys. Volume 61, Number SA, SA0805(2022).

BL6N1
Preparation of titania with double band structure

BL7U

derived from a quantum size effect: Drastic increase

Humin: No longer inactive natural organic matter,in the photocatalytic activity, S. Somekawa, H.

D.M. Pham, T. Kasai, M. Yamaura, A. Katayama,

Watanabe, Y. Ono, Y. Oaki, H. Imai, Materials

Chemosphere, Volume 269, April 2021, 128697.

Letters, Volume 304, 1 December 2021, 130609.

40

BL7U

BL8S1

Electronic Structures of Transition-Metal Pernitrides

Robust Polarization Stability in a Self-Assembled

Studied Using X-ray Absorption and Photoelectron

Ultrathin Organic Ferroelectric Nano Lamellae, P.

Spectroscopy, K. Soda, D. Kato, M. Komabuchi, T.

Viswanath, K.K.H. De Silva, Y. Morikuni, M.

Terabe, S. Takayama, T. Ibaragi, M. Kato, K. Niwa,

Yoshimura, Advanced Electronic Materials (2021).

M. Hasegawa, S. Takakura, M. Nakatake, J. Phys.

DOI:10.1002/aelm.202001085

Soc. Jpn. 90, 201, 044710 (2021).
BL8S1
BL7U

XRD investigation of mechanical properties ofObservation of a flat band and bandgap incellulose microfibrils in S1 and S3 layers of thermally

millimeter-scale twisted bilayer graphene, K. Sato, N.

modified wood under tensile loading, E. Kojima, M.

Hayashi, T. Ito, N. Masago, M. Takamura, M.

Yamasaki, K. Imaeda, C-G. Lee, T. Sugimoto, Y.

Morimoto, T. Maekawa, D. Lee, K. Qiao, J. Kim, K.

Sasaki, Wood Science and Technology volume 55,

Nakagahara, K. Wakabayashi, H. Hibino, W.

pages955–969 (2021).

Norimatsu, Communications Materials volume 2,
BL8S1

Article number: 117 (2021) .

Exchange-Coupled

SmCo5/Fe

BL7U

MagnetbySingle germanene phase formed by segregation

Metallurgy Process, K. Park, Y. Hirayama, W.

through Al(111) thin films on Ge(111), J. Yuhara, H.

Yamaguchi,M.

Muto, M. Araidai, M. Kobayashi, A. Ohta, S.

Transactionson

Miyazaki, S. Takakura, M. Nakatake, G.L. Lay, 2D

DOI:10.1109/TMAG.2021.3080688

Prepared

Low

Kobashi,

Nanocomposite
OxygenK.

Magnetics,

PowderTakagi,

IEEE

58(2)

(2022).

Materials, Volume 8, Number 4, 045039 (2021).
BL8S1
BL7U

Anisotropic

Epitaxial growth of massively parallel germanium

induction thermal plasma, K. Park, Y. Hirayama, M.

nanoribbons by segregation through Ag(110) thin

Shigeta, Z. Liu, M. Kobashi, K. Takagi, Journal offilms on Ge(110), J. Yuhara, H. Shimazu, M.

Alloys and Compounds, Volume 882, 15, 160633

Kobayashi, A. Ohta, S. Miyazaki, S. Takakura, M.

(2021).

Sm-Co

nanopowder

preparedbyNakatake, G.L. Lay, Applied Surface Science,
Volume 550, 1 June 2021, 149236.

BL8S1
Preparationofflake-shaped

Fe-based

BL7U

nanocrystalline

soft

magnetic

particles

In-plane strain-free stanene on a Pd2Sn(111) surface

subjected to plastic deformation, Satoshi Motozuka,

alloy, J. Yuhara, T. Ogikubo, M. Araidai, S.Takakura,

Hisashi Sato, Hidenori Kuwata, Mitsuo Bito, Yasuo

M. Nakatake, G.L. Lay, Phys. Rev. Materials 5,

Okazaki, Philosophical Magazine Letters, 101, 399

053403 (2021).

(2021). DOI:10.1080/09500839.2021.1953713

41

alloy

BL8S1BL8S2Fabrication of L10-FeNi films with island structures

Immobilization of partial dislocations boundingby nitrogen insertion and topotactic extraction for

double Shockley stacking faults in 4H-SiC observed

improved coercivity, T. Nishio, H. Kura, K. Ito, K.

by in situ synchrotron X-ray topography, F. Fujie, S.

Takanashi, H. Yanagihara, APL Materials 9, 091108

Harada, H. Suo, B Raghothamachar, M. Dudley, K.

(2021). DOI:10.1063/5.0062692

Hanada, H. Koizumi, T. Kato, M. Tagawa, T. Ujihara,
Materialia, Volume 20, December 2021, 101246.

BL8S2
Mixed alkali-ion transport and storage in atomic-

BL8S2

disordered honeycomb layered NaKNi2TeO6, T.

Synchrotron X-ray topographic image contrast

Masese, Y. Miyazaki, J. Rizell, G.M. Kanyolo, C-Y.

variation of screw-type basal plane dislocations

Chen, H. Ubukata, K. Kubota, K. Sau, T. Ikeshoji, Z-

located at different depths below the crystal surface

D. Huang, K. Yoshii, T. Takahashi, M. Ito, H. Senoh,in 4H-SiC, F. Fujie, H. Peng, T. Ailihumaer, B.

J. Hwang, A. Alshehabi, K. Matsumoto, T.

Raghothamachar, M. Dudley, S. Harada, M. Tagawa,Matsunaga, K. Fujii, M. Yashima, M. Shikano, C.

T. Ujihara, Acta Materialia, Vol. 208(15) 116746

Tassel, H. Kageyama, Y. Uchimoto, R. Hagiwara, T.

(2021).

Saito, Nature Communications volume 12, Article
BL8S2

number: 4660 (2021).

X-ray radiolysis-induced-photochemical reaction atinterface between liquid and substrate, S. Saegusa, N.

BL8S2
Synthesised

Akamatsu, I. Sakurai, I. Okada, Y. Utsumi, A.

Nanoparticles, K. Elphick ,A. Yamaguchi, A. Otsuki,

Yamaguchi, 2021 International Conference on

N.L. Hayagan, A. Hirohata, Materials 14(3), 613

Electronics(2021). DOI:10.3390/ma14030613

DOI:10.23919/ICEP51988.2021.9451970

BL8S2

BL8S2

Design of automatic detection algorithm for

Detection and classification of dislocations in GaN by

dislocation contrasts in birefringence images of SiC

optical microscope using birefringence, A. Tanaka, S.

wafers, A. Kawata, K. Murayama, S. Sumitani, S.

Harada, K. Hanada, Y. Honda, T. Ujihara, H. Amano,

Harada, Jpn. J. Appl. Phys., 60, SBBD06 (2021).

Proceedings Vol. 11706, Light-Emitting Devices,

Non-Destructive

Imagingon

Packaging(ICEP),

63(2021).

Materials, and Applications XXV; 117060Y, 2021.
BL8S2

DOI:10.1117/12.2577164

Evaluation of Porosity in Gas-Atomized Powder by
Synchrotron X-ray CT and Investigation of the Effect

BL8S3

of Gas Species, N. Yodoshi, T. Endo, N. Masahashi,

Cold Crystallization and the Molecular Structure ofMaterials

Imidazolium-Based Ionic Liquid Crystals with a p-

Transactions,62(10),

1549(2021).

DOI:10.2320/matertrans.MT-Y2021001

Nitroazobenzene Moiety, K. Ishino, H. Shingai, Y.
Hikita, I. Yoshikawa, H. Houjou, K. Iwase, ACS

42

Omega 6, 48, 32869–32878 (2021).

Volume 227, 16 June 2021, 123868.

BL8S3

BL8S3

ᅜෆᨺᑕග᪋タᶓ᩿㹖⥺ᑠゅᩓ஘ࣛ࢘ࣥࢻࣟࣅࣥᐇ

Al-1%Mn ྜ㔠ࡢ⇕㛫ຍᕤ࡛ᙧᡂࡍࡿᯒฟ≀࡜ࡑࡢ㦂, ᮡᒣಙஅ, ᒣඖ༤Ꮚ, ຍ⸨⿱࿴, ኱ᆏᜨ୍, బ⸨┾ศᩓ≧ែ, ⏣୰ ᏹᶞ, బࠎᮌ ຾ᐶ, ❧ᒣ ┿ྖ, ㍍㔠ᒓ,┤, ᮡᮏὈఙ, SPring-8/SACLA ฼⏝◊✲ᡂᯝ㞟/9 ᕳ

71 ᕳ 12 ྕ p. 549-554 (2021).

4 ྕ, p. 211-218 (2021).
BL8S3
In Situ Small-Angle X-ray Scattering Studies on the

BL8S3
Antithrombogenicpoly(2-methoxyethyl

Growthacrylate)

MechanismofAnisotropic

Platinumwith

Nanoparticles, W. Yoshimune, A. Kuwaki, T. Kusano,poly(methyl methacrylate), N. Kurokawa, F. Endo, K.

T. Matsunaga, H. Nakamura, ACS Omega 6, 16,

Bito, T. Maeda, A. Hotta, Polymer Volume 228, 16

10866–10874 (2021).

elastomer

via

triblockcopolymerization

July 2021, 123876.
BL8S3
BL8S3

Transparent

Formation of Highly Active Ziegler–Natta Catalysts

refractive index-adjustable polymer blend, T. Hirai,

Clarified

Characterization

K. Yagi, K. Nakai, K. Okamoto, T. Matsunaga, H.

Approach, A. Piovano, T. Wada, A. Amodio, G.

Okamoto, Composites Part B: Engineering, 225(15),

Takasao, T. Ikeda, D. Zhu, M. Terano, P.

109258 (2021).

Chammingkwan, E. Groppo, T. Taniike, ACS Catal.

11, 22, 13782–13796 (2021).

BL11S2byaMultifaceted

thermoplastic

compositefrom aChromium Oxides as Structural Modulators of
BL8S3

Rhodium Dispersion on Ceria to Generate Active

Insights into the Formation Pathway of Templated

Sites for NO Reduction, S. Ikemoto, S. Muratsugu, T.

Ordered Nanostructured Carbonaceous Particles

Koitaya, M. Tada, ACS Catal. 12, 1, 431–441 (2022).

under Hydrothermal Conditions, Shiori Kubo,
BL11S2

Langmuir, 37, 36, 10866–10874 (2021).

Three-way catalytic properties and microstructures
BL8S3

of metallic glass driven composite catalysts, M.

Tunable and ordered porous carbons with folding-like

Hattori, N. Katsuragawa, S. Yamaura, M. Ozawa,

nanoscale framework via interdigitation and twisting,

Catalysis Today, Volume 375(1), 273 (2021).

S. Kubo, Mater. Adv., 2, 4029-4040 (2021).
BL11S2
BL8S3

Quadruple perovskite oxides CaMn7O12 proceed byImportance of interfacial mixed layer to determine

twoactive-site reaction mechanism for oxygenthe middle block Tg in lamellar structures of uncross-evolution reaction, Yadan Ren, Kodai Kashihara,

linked and cross-linked hard-b-soft-b-hard triblock

Tomoki Uchiyama, Yuki Orikasa, Toshiki Watanabe,

copolymers, I. Kawarazaki, M. Hayashi, Polymer,

Kentaro Yamamoto, Tsuyoshi Takami, Toshiyuki

43Shigenori

Applications of Smart Material of Li2O-(Nb/Ta)2O5-

Mitsushima, Yoshiharu Uchimoto, Chem. Electro.

TiO2 Solid Solution Having a Unique Periodical

Chem., 8(23), 4605 (2021).

Structure, H. Nakano, Materials Science Forum, vol.

DOI:10.1002/celc.202101228

1016, 1009–1013 (2021).

Matsunaga,

Yoshinori

Nishiki,

DOI:10.4028/www.scientific.net/MSF.1016.1009
BL11S2
Influence of Nd3+ modifying on 80TeO2–xZnO–

BL11S2(20−x)Na2O ternary glass system, J.de Clermont-

Heterogeneously Ni–Pd nanoparticle-catalyzed base-Gallerande, D. Taniguchi, M. Colas, P. Thomas, T.

free formal C–S bond metathesis of thiols, K.

Hayakawa, APL Materials 9, 111111 (2021).

Mitamura, T. Yatabe, K. Yamamoto, T. Yabe, K.

DOI:10.1063/5.0061880

Suzuki, K. Yamaguchi, Chem. Commun., 57, 37493752 (2021). DOI: 10.1039/D1CC00995H

BL11S2
Soluble porous carbon cage-encapsulated highly

BL11S2

active metal nanoparticle catalysts, H. Liu, L. Chen,

Crystal melting and vitrification behaviors of a three-

C-C. Hou, Y-S. Wei, Q. Xu, J. Mater. Chem. A, 9,

dimensional nitrile-based metal–organic framework,

13670-13677 (2021).

C. Das, S. Horike, Faraday Discuss., 225, 403-413(2021). DOI: 10.1039/D0FD00003E

BL11S2Ultrahigh-Pressure

Preparation

and

BL11S2

Catalytic

Activity of MOF-Derived Cu Nanoparticles, I.

⺯ග XAFS ࡟ࡼࡿ℩ᡞᰁ௜ࡢᡂศศᯒ, ኴ⏣බ඾, ࡪ

Yamane, K. Sato, R. Otomo, T. Yanase, A. Miura, T.

ࢇࡏࡁ, 8, 387 (2021).

Nagahama, Y. Kamiya, T. Shimada, Nanomaterials
11(4), 1040 (2021). DOI:10.3390/nano11041040
⥲ㄽ࣭ゎㄝ

BL11S2
Reductive solvothermal synthesis of MgMn2O4 spinel
nanoparticles for Mg-ion battery cathodes, R.

࣮࣍ࣝຠᯝ࡟ࡼࡿ㟁Ẽⓗ≉ᛶホ౯㸫➨㸰ᅇ㸫ࠊ➉⏣Yokozaki, H. Kobayashi, I. Honma, Ceramics⨾࿴ࠊCrystal Letters, 76, 3-9 (2021).

International, 47(7), Part B, 10236 (2021).
ࢥࣟࢼ⚝࡟࠾ࡅࡿඹ⏝᪋タࡢ㐠Ⴀࠊ➉⏣⨾࿴ࠊ
BL11S2Crystal Letters, 76, 56-58 (2021).

Relationship between photoluminescence intensity,
Mn ion oxidation, and crystal structure of newphosphors

Li-M-Ti-O:Mn4+࣮࣍ࣝຠᯝ࡟ࡼࡿ㟁Ẽⓗ≉ᛶホ౯㸫➨㸱ᅇ㸫ࠊ➉⏣(M = Nb or Ta), H.

⨾࿴ࠊCrystal Letters, 77, 3-9 (2021).

Nakano, S. Ando, Materials Research Bulletin,
Volume 143, November 111445 (2021).

࣮࣍ࣝຠᯝ࡟ࡼࡿ㟁Ẽⓗ≉ᛶホ౯㸫➨㸲ᅇ㸫ࠊ➉⏣⨾࿴ࠊCrystal Letters, 78, 3-7 (2021).

BL11S244

X-ray Absorption Fine Structure 2021(XAFS2021
࠶࠸ࡕࢩࣥࢡࣟࢺࣟࣥගࢭࣥࢱ࣮㹼᪂ᫍࡢㄌ⏕㹼ࠊ

virtual), July 11 - 13, 2021, Sydney, Australia➉⏣⨾࿴ࠊ ⛉Ꮫᢏ⾡஺ὶࢽ࣮ࣗࢫ 26(3), 4-5 (2021).
Extracting local symmetry of liquid metals from࠶࠸ࡕࢩࣥࢡࣟࢺࣟࣥගࢭࣥࢱ࣮㹼᪂ᫍࡢᡂ㛗㹼ࠊ

extended x-ray absorption fine structure using deep➉⏣⨾࿴ࠊ ⛉Ꮫᢏ⾡஺ὶࢽ࣮ࣗࢫࠊ27(1), 6-8

neural networks, F. Iesari, H. Setoyama, T. Okajima,(2021),.

25th Congress of the International Union of
Cystography, August 14-22, 2021, Prague, Czech࠶࠸ࡕࢩࣥࢡࣟࢺࣟࣥගࢭࣥࢱ࣮㹼᪂ᫍࡢฟ఍࠸㹼ࠊ Republic + on-line➉⏣⨾࿴ࠊ⛉Ꮫᢏ⾡஺ὶࢽ࣮ࣗࢫࠊ27(2), 12-15
Reverse Monte Carlo of EXAFS data for materials(2021).

characterization (invited), F. Iesari, T. Okajima, A. Di
ࡑࡢ௚Cicco, Materials Research Meeting 2021, December

Crystallization of amorphous indium-based oxide

13-17, 2021, Yokohama, Japanfilms, J. Jia, S. Iwasaki, S. Yamamoto, S. Nakamura,
E. Magome, T. Okajima, Y. Shigesato, ACS Applied
Materials and Interfaces, 13, 31825-31834 (2021).
ճ Ꮫ఍࣭ࢩ࣏ࣥࢪ࣒࢘ㅮ₇

DOI:10.1021/acsami.1c05706

ᅛయ㟁ゎ㉁ LixLa(1-x)/3NbO3 ࣂࣝࢡ༢⤖ᬗࡢゅᗘศゎࡑࡢ௚ග㟁Ꮚศග, ᒣඖ෽ࠊ௰Ṋᫀྐࠊ㧗಴ᑗ୍ࠊᒣ⏣┿Extracting Local Symmetry of Mono-Atomic Systems୍㑻ࠊ⏣୰Ύᑦࠊ⸨ཎ㟹ᖾࠊ᳃ศ༤⣖ࠊධᒣᜤᑑࠊ

from Extended X-ray Absorption Fine Structureఀ⸨Ꮥᐶࠊ ᪥ᮏ≀⌮Ꮫ఍ 2021 ᖺ⛅Ꮨ኱఍, ࢜ࣥࣛUsing Deep Neural Networks, F. Iesari, H. Setoyama,࢖ࣥ㛤ദ, 2021 ᖺ 9 ᭶ 20-23 ᪥T.

Okajima,Symmetry,13(6),

1070(2021).

DOI:10.3390/sym13061070

࣮࢝࣎ࣥᒙ⿕そࡋࡓ❅໬࣍࢘⣲ࢼࣀࢳ࣮ࣗࣈ࡟࠾ࡅ
ࡿ໬Ꮫ⤖ྜ≧ែࡢゎᯒ, ຍ⸨㞞Ύࠊ஭ୖὈ㍤ࠊ
Chiew Yi Ling, ᮎỌ࿴▱ࠊ௰Ṋᫀྐࠊ㧗಴ᑗ୍ࠊΏ
㎶⩏ኵࠊᑠᯘ៞⿱ࠊ➨ 69 ᅇᛂ⏝≀⌮Ꮫ఍᫓ᏘᏛ⾡ እ㒊Ⓨ⾲㸦 ᖺ  ᭶㹼 ᖺ  ᭶ ㅮ₇఍ࠊ㟷ᒣᏛ㝔኱Ꮫ┦ᶍཎ࢟ࣕࣥࣃࢫ㸤࢜ࣥࣛ࢖ձᅜ㝿఍㆟ࣥࠊ2022 ᖺ 3 ᭶ 22-26 ᪥Analysis of liquid metals EXAFS data using deepⷧ⭷ࣇ࢛ࢺ࢝ࢯ࣮ࢻ⏝ࢢࣛࣇ࢙ࣥ⭷ᇶ┙ࡢຍ⇕Ὑίneural networks, F. Iesari, H. Setoyama, T. Okajima,ຠᯝࡢホ౯ࠊᚋ⸨ၨኴࠊ㒌☨ࠊᒣཱྀᑦⓏࠊ௰Ṋᫀྐࠊ

International Conference on X-ray Absorption Fine

㧗಴ᑗ୍ࠊᒣᮏᑗ༤ࠊ㧗ᔱᆂྐࠊ➨ 35 ᅇ᪥ᮏᨺᑕ

Structure 2021(XAFS2021 virtual), July 11 - 13, 2021,ගᏛ఍ᖺ఍ࠊ࢜ࣥࣛ࢖ࣥ㛤ദࠊ2022 ᖺ 1 ᭶ 7-9 ᪥

Sydney, Australia༙ᑟయࣇ࢛ࢺ࢝ࢯ࣮ࢻศᯒ⏝┿✵㍺㏦⿦⨨ࡢ㛤ⓎࠊFull-potential multiple scattering calculations inሷཎ្௓ࠊ㒌☨ࠊ௰Ṋᫀྐࠊ㧗಴ᑗ୍ࠊ┿㔝⠜ᚿࠊ

EXAFS regime, Y. Tamura, K. Yoshikawa, F. Iesari,㧗ᔱᆂྐࠊ ࢜ࣥࣛ࢖ࣥ㛤ദࠊ᪥ᮏ≀⌮Ꮫ఍➨ 77

T. Okajima, K. Hatada, International Conference on45ᅇᖺḟ኱఍ࠊ2022 ᖺ 03 ᭶ 15-19 ᪥

neural networks, Iesari Fabio㸪℩㈝ⱘᐶஅ㸪ᒸᓥᩄᾈ, ➨ 24 ᅇ XAFS ウㄽ఍, 2021 ᖺ 9 ᭶ 1 ᪥㹼3 ᪥, ࢜

TPP[FePc(CN)2]2 ࡢゅᗘศゎග㟁Ꮚศගࠊಖ⛉ᣅᾏࠊ ࣥࣛ࢖ࣥ㛤ദ௰Ṋᫀྐࠊ㧗಴ᑗ୍ࠊฟ⏣┿୍㑻ࠊ⏣୰Ύᑦࠊ
Thierry Ouisseࠊఀ⸨Ꮥᐶࠊ ࢜ࣥࣛ࢖ࣥ㛤ദࠊ᪥ᗈᇦ X ⥺྾཰ᚤ⣽ᵓ㐀ࡢࢫࣃ࣮ࢫࣔࢹࣜࣥࢢ࡟ࡼࡿ

ᮏ≀⌮Ꮫ఍➨ 77 ᅇᖺḟ኱఍ࠊ2022 ᖺ 3 ᭶ 15-19 ᪥࢖ࢵࢺ࣒ࣜ࢘㓟Ỉ⣲໬≀ⷧ⭷ࡢ㏆᥋ᵓ㐀ࡢỴᐃ, ⇃ῧ༤அ, ஬༑ᔒᗣᙪ, Iesari Fabio, ΎỈுኴ, ᑠᯇ㐟▮,

Hex-Au(001)ᇶᯈୖࢢࣛࣇ࢙ࣥࡢࢫࣆࣥศゎゅᗘศ୍ᮡኴ㑻, ᯇᮧ኱ᶞ, 㰻⸨ᐶஅ, ᒾ‶୍ຌ, ᒸᓥᩄᾈ,ゎග㟁ᏊศගࠊᯇỌ࿴ஓࠊᯘ┤㍤ࠊ௰Ṋᫀྐࠊฟ⏣ጒᑿ୚ᚿᮌ, ᒸ⏣┿ே, ㉥஭୍㑻, ᪥ᮏ≀⌮Ꮫ఍ 2021┿୍㑻ࠊ⏣୰Ύᑦࠊ⏣୰ៅ୍㑻ࠊ஌ᯇ⯟ࠊಖ⏣ㅍࠊ⛅Ꮨ኱఍, 2021 ᖺ 9 ᭶ 20 ᪥㹼23 ᪥, ࢜ࣥࣛ࢖ࣥ㛤ദὸᒸ⚽ேࠊᑎ⃝▱₻ࠊఀ⸨Ꮥᐶࠊ࢜ࣥࣛ࢖ࣥ㛤ദࠊ᪥ᮏ≀⌮Ꮫ఍➨ 77 ᅇᖺḟ኱఍ࠊ2022 ᖺ 3 ᭶ 15-19

࢖ࢵࢺ࣒ࣜ࢘㓟Ỉ⣲໬≀ⷧ⭷࡛ィ ࡉࢀࡓᗈᇦ X ⥺᪥྾཰ᚤ⣽ᵓ㐀ࡢࢫࣃ࣮ࢫࣔࢹࣜࣥࢢ , ⇃ῧ༤அ, ஬༑ᔒᗣᙪ, Fabio Iesari, ΎỈுኴ, ᑠᯇ㐟▮, ୍ᮡኴ㑻,཯ᙉ☢ᛶ i-MAX ┦໬ྜ≀(Mo2/3Dy1/3)2ALC ࡢ 3 ḟᯇᮧ኱ᶞ, 㰻⸨ᐶஅ, ᒾ‶୍ຌ, ᒸᓥᩄᾈ, ጒᑿ୚ᚿᮌ,ඖゅᗘศゎග㟁Ꮚศගࠊᮡᮏ༟ྐࠊྂ⏣㈏ᚿࠊ

ᒸ⏣┿ே, ㉥஭୍㑻, ➨㸴ᅇィ ࢖ࣥࣇ࢛࣐ࢸ࢕ࢡࢫ

Damir Pinekࠊ௰Ṋᫀྐࠊฟ⏣┿୍㑻ࠊ⏣୰Ύᑦࠊ◊✲఍, 2021 ᖺ 11 ᭶ 26 ᪥, ࢜ࣥࣛ࢖ࣥ㛤ദ

Thierry Quisseࠊఀ⸨Ꮥᐶࠊ ࢜ࣥࣛ࢖ࣥ㛤ദࠊ᪥ᮏ≀⌮Ꮫ఍➨ 77 ᅇᖺḟ኱఍ࠊ2022 ᖺ 3 ᭶ 15-19 ᪥✵Ẽ᭚㟢ࡉࢀࡓ Li5La3Ta2O12 ࡟࠾࠸࡚⺯ග཰㔞ἲ࡛ィ ࡉࢀࡓ ㌾ X ⥺྾཰➃㏆ഐᵓ㐀ࡢ࣋࢖ࢬศග,◳ X ⥺ XAFSࣅ࣮࣒ࣛ࢖ࣥ࡟࠾ࡅࡿᨭ᥼ෆᐜ࡟ࡘ࠸

⏣ᮧ♸ᶞ, ⸨ᮌῄៅ, ᑠᕝᏱᐂ, ᒣୖ㑈, ᒣᓮ኱㞞, ᒾ࡚㸪㡲⏣⪔ᖹ㸪ຍ⸨ᘯὈ㸪⚟Ọṇ๎㸪⏣ῲ㞞ኵ㸪Ώ‶୍ຌ, ⇃ῧ༤அ, ᒸᓥᩄᾈ, ㉥஭୍㑻, ➨ 32 ᅇග≀㎶⩏ኵ㸪ᅧᯞ⚽ୡ㸪➨ 1 ᅇᮾᾏᅜ❧኱Ꮫᶵᵓᢏ⾡Ⓨᛶ◊✲఍, 2021 ᖺ 12 ᭶ 10 ᪥㹼11 ᪥, ࢜ࣥࣛ࢖ࣥ㛤⾲఍㸪P1㸪࢜ࣥࣛ࢖ࣥ㛤ദ㸪2022 ᖺ 3 ᭶ 7 ᪥ദ஧㓟໬Ⅳ⣲㑏ඖ཯ᛂሙ࡟࠾ࡅࡿ㖟ᢸᣢ㓟໬࣒࢞ࣜ࢘

✵Ẽ᭚㟢ࡉࢀࡓ Li5La3Ta2O12 ࡟࠾࠸࡚඲㟁Ꮚ཰㔞ගゐ፹ࡢ≧ែศᯒ㸪ᒣᮏ᐀᫛㸪໭ᔱ஀ᶞ㸪㝜ᆅᏹ㸪ἲ࡛ィ ࡉࢀࡓ ㌾ X ⥺྾཰➃㏆ഐᵓ㐀ࡢ࣋࢖ࢬศ

㡲⏣⪔ᖹ㸪ሯ⏣༓ᜨ㸪ᰘ⏣ెᏕ㸪⚄ᒸṊᩥ㸪Ọぢဴග, ⸨ᮌῄៅ, ⏣ᮧ♸ᶞ, ᑠᕝᏱᐂ, ᒣୖ㑈, ᒣᓮ኱㞞,ኵ㸪⏣㎶ဴᮁ㸪ྜྷ⏣᭸Ꮚ㸪➨ 57 ᅇ X ⥺ศᯒウㄽ఍㸪 ᒾ‶୍ຌ, ⇃ῧ༤அ, ᒸᓥᩄᾈ, ㉥஭୍㑻, ➨ 32 ᅇග
O2-3㸪࢜ࣥࣛ࢖ࣥ㛤ദ㸪2021 ᖺ 11 ᭶ 6 ᪥≀ᛶ◊✲఍, 2021 ᖺ 12 ᭶ 10 ᪥㹼11 ᪥, ࢜ࣥࣛ࢖ࣥ㛤ദ

XAFS ࡢ㟁Ꮚ཰㔞ἲ࡜㌿᥮㟁Ꮚ཰㔞ἲ࡟࠾ࡅࡿศᯒ
῝ࡉ࡟ࡘ࠸࡚ࠊ㝜ᆅᏹࠊ2021 ᖺᗘᐇ⏝⾲㠃ศᯒㅮ

L1 ṇ๎໬࡟ࡼࡿከ㔜ᩓ஘ຠᯝࢆ⪃៖ࡋࡓ Cu2O ࡢ

₇ ఍ 㸦 Symposium on Practical Surface Analysis

ᗈᇦ X ⥺྾཰ᚤ⣽ᵓ㐀ゎᯒ, ⇃ῧ༤அ, ஬༑ᔒᗣᙪ,2021 (PSA-21)㸧ࠊ2021 ᖺ 11 ᭶ 18 ᪥㹼19 ᪥ࠊ࢜ࣥFabio Iesari, ᒾ‶୍ຌ, ℩ᡞᒣᐶஅ, ᒸᓥᩄᾈ, ጒᑿ୚ࣛ࢖ࣥ఍㆟ࠊཱྀ㢌Ⓨ⾲ᚿᮌ, ᒸ⏣┿ே, ㉥஭୍㑻, ➨ 32 ᅇග≀ᛶ◊✲఍,

http://www.sasj.jp/PSA/PSA21/program.html

2021 ᖺ 12 ᭶ 10 ᪥㹼11 ᪥, ࢜ࣥࣛ࢖ࣥ㛤ദ

Analysis of mono-atomic EXAFS data using deep

ᗈᇦ X ⥺྾཰ᚤ⣽ᵓ㐀ࡢࢫࣃ࣮ࢫࣔࢹࣜࣥࢢࢆ䔏46࠸ࡓ࢖ࢵࢺ࣒ࣜ࢘㓟㰛⣲໬≀ⷧ⭷ࡢ㏆㊥㞳ᵓ㐀ゎᯒ,㉥஭୍㑻, ᒸ⏣┿ே, ᛂ⏝≀⌮Ꮫ఍᫓ᏘᏛ⾡ㅮ₇఍,⇃ῧ༤அ, ஬⌨ᔒᗣᙪ, Iesari Fabio, Ύ㰛ுኴ, ⯶ᯇ㐟2022 ᖺ 3 ᭶ 22 ᪥㹼26 ᪥, 㟷ᒣᏛ㝔኱┦ᶍཎ࢟ࣕࣥ

䟉, ᷧᮡኴ㑻, ᯇᮧ⤎ᶞ, 㰻⸨ᐶஅ, ᒾ‶ᷧຌ, ᒸᓥᩄࣃࢫ㸩࢜ࣥࣛ࢖ࣥ㛤ദᾈ, ጒᑿ୚ᚿ㜏, ᒸ䔗┿ạ, 嵋஭ᷧ㑻, ➨ 35 ᅇ᪥ᮏᨺᑕගᏛ఍ᖺ఍࣭ᨺᑕග⛉Ꮫྜྠࢩ࣏ࣥࢪ࣒࢘, 2022

EXAFS ࡢࢫࣃ࣮ࢫࣔࢹࣜࣥࢢ, ㉥஭୍㑻, ⇃ῧ༤அ,ᖺ 1 ᭶ 7 ᪥㹼9 ᪥, ᮾி኱Ꮫᮏ㒓࢟ࣕࣥࣃࢫ㸩࢜ࣥࣛ஬༑ᔒᗣᙪ, Fabio Iesari, ᒾ‶୍ຌ,ᒸᓥᩄᾈ, ጒᑿ୚࢖ࣥ㛤ദᚿᮌ, ᒸ⏣ ┿ே, ᪥ᮏ໬Ꮫ఍➨ 102 ᫓Ꮨ኱఍ (2022 ᖺ
3 ᭶ 23 ᪥㹼26 ᪥ࠊ࢜ࣥࣛ࢖ࣥ㛤ദ), ࢩ࣏ࣥࢪ࣒࢘

CRESTࠕ᝟ሗィ ࠖ(㸯)ࠕ࣋࢖ࢬ⤫ィࢫ࣌ࢡࢺࣝศ

ࠕ໬Ꮫ⪅ࡢࡓࡵࡢᨺᑕගࡇ࡜ࡣࡌࡵ㸫XAFS ࡢᇶ♏

ゎࠖ(ᣍᚅㅮ₇), 嵋஭ᷧ㑻, ᒸᓥᩄᾈ, 㰛∾ோᷧᮁ, 犲࡜ඛ➃ᛂ⏝ࠖ2022 ᖺ 3 ᭶ 25 ᪥奦஽, ᒣᓮ⿱୍, 2021 ᖺᗘ࣭➨ 5 ᅇඖ⣲ᡓ␎ࢩ࣏ࣥ
ࢪ࣒࢘, 2022 ᖺ 2 ᭶ 4 ᪥, ࢜ࣥࣛ࢖ࣥ㛤ദճࣉࣞࢫ࣮ࣜࣜࢫ➼

EXAFS ࡢ Bayesian sparse modeling (ᣍᚅㅮ₇), 嵋஭ᷧ㑻, ⇃ῧ༤அ, ஬༑ᔒᗣᙪ, Fabio Iesari, ΎỈுኴ,

2021 ᖺ 6 ᭶ 3 ᪥ ୰᪥᪂⪺ᑠᯇ㐟▮, ୍ᮡኴ㑻, ᯇᮧ኱ᶞ, 㰻⸨ᐶஅ, ᒾ‶୍ຌ,ࠕࡇࡢேࠖ࠶࠸ࡕࢩࣥࢡࣟࢺࣟࣥගࢭࣥࢱ࣮ᡤ㛗ᑵᒸᓥᩄᾈ, ጒᑿ୚ᚿᮌ, ᒸ⏣┿ே, SPRUC X ⥺ࢫ࣌ࢡ௵࢖ࣥࢱࣅ࣮ࣗ, ᅧᯞ⚽ୡࢺࣝࢫࢥࣆ࣮฼⏝◊✲఍, 2022 ᖺ 3 ᭶ 11 ᪥, ࢜ࣥࣛ࢖ࣥ㛤ദ

2021 ᖺ 9 ᭶ 7 ᪥࠶࠸ࡕࢩࣥࢡࣟࢺࣟࣥගࢭࣥࢱ࣮HP࣋࢖ࢬศගἲࢆ⏝࠸ࡓ Li5La3Ta2O12 ࡢ㌾ X⥺྾཰➃ࠕୗグㄽᩥࡀ 2021 ᖺ 7㺃8 ᭶ Electrochemistry ㄅࢲ㏆ഐᵓ㐀ࡢ௬᝿ィ ゎᯒ, ᑠᕝᏱᐂ, ᒣୖ㑈, ᒾ‶୍࣮࢘ࣥࣟࢻᩘ 3 ఩࡜࡞ࡾ㟁Ẽ໬Ꮫ఍ࡼࡾ Certificate

ຌ, ⇃ῧ༤அ, ᒸᓥᩄᾈ, ㉥஭୍㑻, ᪥ᮏ≀⌮Ꮫ఍➨ 77

ࢆ 㡬 ࡁ ࡲࡋ ࡓ ࠖ ࣜࢳ ࣒࢘ ࢖ ࢜ ࣥ㟁 ụ ṇ ᴟᮦ ᩱᅇᖺḟ኱఍, 2022 ᖺ 3 ᭶ 15 ᪥㹼19 ᪥, ࢜ࣥࣛ࢖ࣥ㛤

Li(Ni1/3Co1/3Mn1/3)O2 ࡢຎ໬ゎᯒ, Ọぢ ဴኵ, 㔝ᮏ ㇏ദ࿴, ᮡᒣ 㝧ᰤ, ❧ᮌ ⩧἞, ᆏᮏ ᗮ, ኴ⏣ ಇ᫂,
Electrochemistry, 89(4) pp 363-369 (2021).

✵Ẽ᭚㟢๓ࡢ Li5La3Ta2O12 ࡢ㌾ X⥺྾཰➃㏆ഐᵓ㐀ࡢ࣋࢖ࢬศගࠊᒣୖ㑈, ᑠᕝᏱᐂ, ᒾ‶୍ຌ, ⇃ῧ༤2021 ᖺ 12 ᭶ 19 ᪥அ, ᒸᓥᩄᾈ, ㉥஭୍㑻, ᪥ᮏ≀⌮Ꮫ఍➨ 77 ᅇᖺḟ኱ᆏ⏣࣭᪩ᕝ࣓ࢲࣝཷ㈹ ➨ 18 ᅇグᛕࣞࢡࢳ࣮ࣕྡྂ

఍, 2022 ᖺ 3 ᭶ 15 ᪥㹼19 ᪥, ࢜ࣥࣛ࢖ࣥ㛤ദᒇᕷ⛉Ꮫ㤋, ࠕࢫ࣮࣌ࢫኳᩥᏛ X ⥺ほ ࡢṌࡳ࡜Ꮫࢇࡔࡇ࡜ࠖ, ᅧᯞ ⚽ୡ, https://www.phys.nagoya-

XANES ࢫ࣌ࢡࢺࣝࡢ࣋࢖ࢬⓗࢫ࣌ࢡࢺࣝศゎ, ᯽

u.ac.jp/SakataHayakawa18/index.html

ᮧ࿘ᖹ, ∦ୖ⯗, ᒾ‶୍ຌ, ⇃ῧ༤அ, Ọ⏣㈼஧, ᒸᓥᩄᾈ, ㉥஭୍㑻, ᒸ⏣┿ே, ᪥ᮏ≀⌮Ꮫ఍➨ 77 ᅇᖺḟ኱఍, 2022 ᖺ 3 ᭶ 15 ᪥㹼19 ᪥, ࢜ࣥࣛ࢖ࣥ㛤ദX ⥺྾཰ᚤ⣽ᵓ㐀㸦EXAFS) ࢹ࣮ࢱ࡟ᑐࡍࡿࢫࣃ࣮
ࢫࣔࢹࣜࣥࢢ࡟ࡼࡿ≀⌮᝟ሗᢳฟ, ஬༑ᔒᗣᙪ, ⇃ῧ༤அ, Iesari Fabio, ᒾ‶୍ຌ, ᒸᓥᩄᾈ, ጒᑿ୚ᚿᮌ,47

 ⛉◊㈝➼እ㒊㈨㔠ࡢ⋓ᚓ≧ἣ  ⛉◊㈝
஺௜Ỵᐃ㢠㸦㓄ศ㢠㸧
┤᥋⤒㈝
㛫᥋⤒㈝
ྜィ

◊✲✀┠

◊✲ㄢ㢟

◊✲⪅

ᇶ┙◊✲
㸦B㸧

㧗㟁ᅽ༳ຍ࡟క࠺㧗ศᏊࡢ㝵ᒙᵓ㐀ኚ໬㏣㊧࡜⤯⦕◚ቯᶵᵓࡢゎ᫂ᒣඖ ༤Ꮚ
(◊✲ศᢸ⪅)

250 ༓෇
ͤ1

75 ༓෇
ͤ1

325 ༓෇
ͤ1

ᇶ┙◊✲
㸦B㸧

㧗㟁ᅽ༳ຍ࡟క࠺㧗ศᏊࡢ㝵ᒙᵓ㐀ኚ໬㏣㊧࡜⤯⦕◚ቯᶵᵓࡢゎ᫂⏣௦ Ꮥ஧
(◊✲௦⾲⪅)

3,250 ༓෇ͤ2975 ༓෇
ͤ2

4,225 ༓෇
ͤ2

ᇶ┙◊✲
㸦C㸧

AI ไᚚ࡛స〇ࡉࢀࡓࢩࣝࢡࢼࣀࣇ࢓࢖ࣂ࣮
㸱D ᵓ㐀య࡟ࡼࡿ iPS⣽⬊ᇵ㣴⏣௦ Ꮥ஧
(◊✲ศᢸ⪅)

100 ༓෇
ͤ1

30 ༓෇
ͤ1

130 ༓෇
ͤ1◊✲௦⾲⪅㸸⚟஭኱Ꮫ࣭ᒣୗ ⩏⿱ᩍᤵ

ᇶ┙◊✲
㸦C㸧
㸦୍⯡㸧

ࢲ࢖ࣖࣔࣥࢻ⤖ᬗ୰ࡢ㑄⛣㔠ᒓ୙⣧≀࡜㌿఩ࡢ࢖ࣥࢱࣛࢡࢩࣙࣥ

◊✲ศᢸ⪅㸸
ྡྂᒇ኱Ꮫ࣭
⏣ῲ㞞ኵᩍᤵ
ᒣ᲍኱Ꮫ࣭᭷ඖᆂ௓෸ᩍᤵ

ⱝᡭ◊✲

ᇶ┙◊✲
㸦A㸧
㸦୍⯡㸧

┬࢚ࢿࣝࢠ࣮♫఍࡟ྥࡅࡓ㏆㉥እගࢆ྾཰ࡍ
ࡿ༢ศᩓࡢ❅໬ࢳࢱࣥࢼࣀ⢏Ꮚࡢ㛤Ⓨࢼࣀ㟁Ꮚࣉ࣮ࣟࣈᐇ࣭
㏫✵㛫㉮ᰝ࡟ࡼࡿ⤫ྜࢹ࣮ࢱ㥑ືᆺᮦᩱ≀ᛶゎᯒⰼ⏣ ㈼ᚿ
(◊✲௦⾲⪅)

340 ༓෇
ͤ2

102 ༓෇
ͤ2442 ༓෇
ͤ2ሯ⏣ ༓ᜨ
(◊✲௦⾲⪅)

400 ༓෇

120 ༓෇

520 ༓෇ᒸᓥ ᩄᾈ
(◊✲ศᢸ⪅)

2,000 ༓෇
ͤ1600 ༓෇
ͤ12,600 ༓෇ͤ1ഛ⪃◊✲௦⾲⪅㸸
ྡྂᒇ኱Ꮫ࣭Ṋ⸨ ಇ௓ᩍᤵ

ͤ1 ◊✲௦⾲⪅࠿ࡽࡢ㓄ศ㢠
ͤ2 ◊✲ศᢸ⪅࡬ࡢ㓄ศ㢠ࢆ㝖ࡃ  ࡑࡢ௚㸦ጤク஦ᴗ㸧
஦ᴗྡ

◊✲ㄢ㢟

◊✲⪅

ጤクዎ⣙㢠

ഛ⪃

ᡓ␎ⓗ๰㐀◊✲᥎㐍஦ᴗ㸦&5(67㸧ࢹ࣮ࢱ✌ື⛉Ꮫ࡟ࡼࡿ㧗ḟඖ㹖⥺྾཰ィ ࡢ㠉᪂ᒸᓥ ᩄᾈ
୺ࡓࡿඹྠ◊✲⪅

 ෇ጤクඖ㸸ᅜ❧◊✲㛤Ⓨἲே⛉Ꮫᢏ⾡᥎㐍ᶵᵓ

48

㸬᪋タ㐠Ⴀࡢグ㘓

49 ᪋タ㐠Ⴀࡢグ㘓ග※ࡢ≧ἣࡲࡓࠊ10 ᭶ࡢ࣓ࣥࢸࢼࣥࢫ୰ㄪᩚ㐠㌿᫬࡟ࡣࠊ 2021 ᖺ ᗘ ࡟ ࠾ ࡅ ࡿ ຍ ㏿ ჾ ࡢ ⥲ 㐠 ㌿ ᫬ 㛫 ࡣ
1,979 ᫬㛫࡛࠶ࡾࠊᨺᑕග࣮ࣘࢨ࣮ࡢ฼⏝᫬㛫ࡣ㉸ఏᑟ೫ྥ㟁☢▼㟁※㟁ὶࢆ┘どࡍࡿ 225 A ࡢ

1,235 ᫬㛫࡛࠶ࡗࡓࠋィ⏬ࡉࢀࡓ࣮ࣘࢨ࣮฼⏝㐠DC ࣈ࣮࣮ࣞ࢝࡟ᨾ㞀ࡀぢࡘ࠿ࡗࡓࠋྠᆺ␒ရࡢ

㌿᫬㛫࡟ᑐࡋ࡚ග※ࡀ㐠㌿࡛ࡁ࡞࠿ࡗࡓ᫬㛫ࡣ

ὶ㏻ࡀṆࡲࡗ࡚࠸ࡓࡓࡵࠊᛴࡁࡻࣈࣛࢣࢵࢺࢆ

⣙ 39 ᫬㛫࡛࠶ࡾࠊ✌ാ⋡ࡣ⣙ 97.0%࡛࠶ࡗࡓࠋ

௓ࡋ࡚ྠᐃ᱁ࣈ࣮࣮ࣞ࢝࡟஺᥮ࡋࡓࠋ࣓ࣥࢸࢼ

ᅗ 1 ࡟ࠊ2021 ᖺᗘ࡟࠾ࡅࡿᙜึィ⏬ࡉࢀࡓ࣮ࣘ

ࣥࢫᮇ㛫୰࡛࠶ࡗࡓࡓࡵࠊ࣮ࣘࢨ࣮㐠㌿࡬ࡢᙳࢨ࣮฼⏝㐠㌿᫬㛫࡟ᑐࡍࡿග※ຍ㏿ჾࡢ㐠㌿᫬㡪ࡣ࡞࠿ࡗࡓࠋ

㛫ࡢ๭ྜ㸦✌ാ⋡㸧ࢆ 1 ᪥ẖ࡟♧ࡍࠋAichiSR ࡛

 2018 ᖺᗘࡼࡾ㐍ࡵ࡚࠸ࡿࠊග※ຍ㏿ჾࡢ┿✵ࡣࠊẖᖺ 4 ᭶࡟ 1 ࣨ᭶࡯࡝ࡢຍ㏿ჾ࣓ࣥࢸࢼࣥࢫ

⥔ᣢ࠾ࡼࡧྥୖࢆ┠ⓗ࡜ࡋࡓ࢖࣏࢜ࣥࣥࣉ⣔ࡢᮇ㛫ࡀ࠶ࡾࠊ5 ᭶ࡢ㐃ఇ᫂ࡅ࠿ࡽ࣮ࣘࢨ࣮฼⏝ࡀ᭦ ᪂ స ᴗ ࢆ ࠊ 2021 ᖺ ᗘ ࡶ ⥅ ⥆ ࡋ ࡚ ⾜ ࡗ ࡓ ࠋ⾜ࢃࢀ࡚࠸ࡿࠋࡑࡢ࡯࠿ࠊ10 ᭶ୗ᪪࡟࣓ࣥࢸࢼ

AichiSR ࡣ 2022 ᖺ࡛ࣇ࢓࣮ࢫࢺࣛ࢖ࢺ࠿ࡽ 10 ᖺࣥࢫᮇ㛫࡜ࡋ࡚ 1 㐌㛫ࠊᖺᮎᖺጞ࡟ࡣఇ᪥࠾ࡼࡧ

┠ࢆ㏄࠼ࡿࡀࠊ㛗ᮇࢩࣕࢵࢺࢲ࢘ࣥࢆ࡜ࡶ࡞࠺ㄪᩚ㐠㌿ࡢࡓࡵ 2 㐌㛫࡯࡝࣮ࣘࢨ࣮฼⏝㐠㌿ࢆఇ኱ࡁ࡞ࢺࣛࣈࣝࡣ⌧ᅾࡲ࡛Ⓨ⏕ࡋ࡚࠸࡞࠸ࠋ୍

Ṇࡋ࡚࠸ࡿࠋ

᪉ࠊࢧ࣮࣮࢟ࣗࣞࢱ₃Ỉ࡜࠸ࡗࡓ⪁ᮙ໬࡟ࡼࡿ

 2021 ᖺ 7 ᭶ 5 ᪥࡟ࠊ500 MHz ࢡࣛ࢖ࢫࢺࣟࣥ

ᨾ㞀ࡀ┠❧ࡕࡣࡌࡵ࡚࠾ࡾࠊࡲࡓᢡࡋࡶ༙ᑟయ

࠿ࡽ⵳✚ࣜࣥࢢ࡬ࡢ RF ఏ㏦㊰㏵୰࡟࠶ࡿ RF ࢧ㒊ရࡢୡ⏺ⓗ࡞౪⤥୙㊊ࡀග※ຍ㏿ჾࡢಖᏲィ࣮࣮࢟ࣗࣞࢱ࡛෭༷Ỉࡀ₃Ỉࡍࡿ㔜ᨾ㞀ࡀⓎ⏕⏬ࡸ᭦᪂సᴗ࡬ᙳ㡪ࢆ୚࠼ࡘࡘ࠶ࡿࠋࡇࢀࡽㅖ

ࡋࠊ㐌ᮎࡲ࡛㐠㌿೵Ṇࢆవ൤࡞ࡃࡉࢀࡓࠋࢧ࣮

ၥ㢟࡟ᰂ㌾࡟ᑐᛂࡋ࡞ࡀࡽࠊ௒ᚋࡶᏳᐃࡋࡓࣘ

࣮࢟ࣗࣞࢱࢆྲྀࡾእࡋࠊ࣓࣮࣮࢝࡟࡚ศゎㄪᰝ࣮ࢨ࣮฼⏝㐠㌿ࡢ⥅⥆ࢆ┠ᣦࡍࠋࢆ⾜ࡗࡓ࡜ࡇࢁࠊࢧ࣮࣮࢟ࣗࣞࢱෆ㒊ࢆ෭༷ࡍࡿ㖡ࣈࣟࢵࢡ࡟ᇙࡵ㎸ࡲࢀࡓ෭༷Ỉ㊰ࡢࣁࣥࢲ᥋ྜ㒊࡟ࣆ࣮ࣥ࣍ࣝࡀⓎ⏕ࡋࠊࡇࡇ࠿ࡽ₃Ỉࡋ࡚࠸ࡓࡇ࡜ࡀࢃ࠿ࡗࡓࠋࡇࡢࡓࡵࠊ✰ᇙࡵ⿵ಟࢆ⾜࠸ࠊࡑࡢᚋ⌧ᅾࡲ࡛ṇᖖ࡟✌ാࡋ࡚࠸ࡿࠋ
2022 ᖺᗘ࡟ࠊ෌Ⓨ㜵Ṇ࡜ணഛࡢಖ᭷ࢆ┠ⓗ࡜ࡋ࡚ࠊ෭༷Ỉ㊰ࡢᕤἲࢆぢ┤ࡋࡓᨵⰋᆺࡢ RF ࢧ࣮࣮࢟ࣗࣞࢱࢆ᪂㐀ࡍࡿࠋᅗ 1 2021 ᖺᗘࡢ✌ാ⋡50 ࣅ࣮࣒ࣛ࢖ࣥࡢ≧ἣ㧗ࡲࡾ࠿ࡽࠊࣇ࣮ࣜࢯࣇࢺ࢙࢘࢔ࡢ⚗Ṇࡸࠊᕷ㈈ᅋࣅ࣮࣒ࣛ࢖ࣥ

%/1㸦㌾ ; ⥺ ;$)6࣭ග㟁Ꮚศගϩ㸧㈍ࡢࢯࣇࢺ࢙࢘࢔࡛ࡶᑂᰝࡀᚲせ࡜࡞ࡾࠊձࢹ࣮ࢱࢆᣢࡕᖐࡗࡓᚋࡢ㎿㏿࡞ࢹ࣮ࢱゎᯒࡢ㞀

㐠㌿≧ἣ

ᐃ

ᐃ

ᐖ࡜࡞ࡿ஦౛ࡀぢࡽࢀࡿࠋࡑࡢࡓࡵࠊBL1N2 ࡢ࡛౑ࢃࢀࠊ඲㟁Ꮚ཰㔞ἲ࡜㒊ศ⺯ග཰㔞ἲࡢྠᐃࢹ࣮ࢱᑓ⏝ࡢࠊExcel VBA ࢆ⏝࠸ࡓ⡆᫆

2021 ᖺᗘࡣࠊ඲࡚ࡢ฼⏝࡟࠾࠸࡚ XAFS᫬ᐃࠊ XAFS ࢫ࣌ࢡࢺࣝ⾲♧ࣉࣟࢢ࣒ࣛࢆ㛤Ⓨࡋࡓࠋࡇᐃ࠾ࡼࡧ㒊ศ⺯ග཰㔞ἲࡢࡓࡵࡢ XRF

୪ࡧ࡟ࠊ࢚ࢿࣝࢠ࣮⿵ṇ್ࢆࡢࣉࣟࢢ࣒ࣛࡣ Excel ୖ࡛౑⏝࡛ࡁࠊGUI ࢆഛᐃࡍࡿࡓࡵࡢ㔠ࡢෆẆ‽఩ࡢ XPS ࡀ⾜ࢃࢀࡓࠋ2021 ᖺᗘࡼࡾ࢜

࠼ࠊࢫ࣌ࢡࢺࣝࡢࣀ࣮࣐ࣛ࢖ࢬࠊ⾲♧⠊ᅖᣦᐃࠊ࣮ࢪ࢙㟁Ꮚ཰㔞ἲࡶ౪⏝ࢆ㛤ጞࡋࡓࡀࠊ࢔ࣥࢪ

」ᩘࢫ࣌ࢡࢺࣝ⾲♧➼ࡀྍ⬟࡛࠶ࡿ㸦ᅗ 3㸧ࠋ௻࣮ࣗࣞࢱග※࡛ࡣ࡞࠸ࡓࡵග㔞ࡀᑡ࡞ࡃᴗᡤᒓࡢ࣮ࣘࢨ࣮࡟ࡶᏳᚰࡋ࡚౑⏝࡛ࡁࡿࣉࣟ

ᐃ᫬ࢢ࣒ࣛ࡜࡞ࡗ࡚࠸ࡿࠋࡲࡓࠊᑓ⏝ࢯࣇࢺ࢙࢘࢔

㛫ࡀ㛗኱࡞ࡓࡵࠊ฼⏝ࡣ 2 ௳ࡋ࠿࡞࠿ࡗࡓࠋ

ࡢ⩦⇍ࡶ୙せ࡛࠶ࡿࠋ⌧ᅾࡣ BL1N2 ࢆ฼⏝ࡋࡓከࡃࡢ฼⏝࡛」ᩘඖ⣲ࡀศᯒࡉࢀࡓࠋศᯒᑐ

࣮ࣘࢨ࣮࡟ࠊ↓ൾ࡛㓄ᕸࡋ࡚࠸ࡿࠋ

㇟ඖ⣲ࡣࠊ㓟⣲ࠊⅣ⣲ࠊ࢔࣑ࣝࢽ࣒࢘ࠊ❅⣲ࡢ㡰࡟ከࡃࠊࡇࡢ 4 ඖ⣲࡛༙ᩘࢆ㉸࠼ࡓࠋ㓟⣲࣭Ⅳ⣲ࡀከ࠸ࡢࡣࠊ࡝ࡢᮦᩱ⣔࡛ࡶศᯒࡉࢀࡿ࠿ࡽ
࡛࠶ࡿࠋศᯒࡉࢀࡿヨᩱࡣࠊ᭷ᶵ໬Ꮫᮦᩱ࡜㟁ụᮦᩱࡀྠ⋡㤳఩࡛ 21%ࠊ㔠ᒓᮦᩱ 13%ࡢ㡰࡟ከ࠿ࡗࡓ㸦ᅗ 2㸧ࠋᅗ 3 ⡆᫆ XAFS ࢫ࣌ࢡࢺࣝ⾲♧ࣉࣟࢢ࣒ࣛ
ᅗ 2 BL1N2 ࡟࠾ࡅࡿ 2021 ᖺᗘࡢ฼⏝ඖ⣲ෆヂ%/6㸦◳ ; ⥺ ;$)6Ϩ㸧ղ ᨵၿ≧ἣձ 㐠㌿≧ἣ([FHO 9%$ ࢆ⏝࠸ࡓ⡆᫆ ;$)6 ࢫ࣌ࢡࢺࣝ⾲♧

BL5S1 ࡣᖺ㛫㏻ࡋ࡚኱ࡁ࡞ࢺࣛࣈࣝ࡞ࡃ㐠⏝ࣉࣟࢢ࣒ࣛࡢ㛤Ⓨࡍࡿࡇ࡜ࡀ࡛ࡁࡓࠋᅗ 4 ࡟ 2021 ᖺᗘࡢ ᐃᡭἲᐃࡋࡓ XAFS ࢫ࣌ࢡࢺࣝࢆ⾲♧ࡍࡿ㝿࡟ࡣࠊཬࡧᐃඖ⣲ࡢ๭ྜࢆ♧ࡍࠋᐃᡭἲẖ࡟ぢࡿ◳ X ⥺ XAFS ࡛ࡣࣇ࣮ࣜࢯࣇࢺ࢙࢘࢔ࡢ Athenaࠊ ࡜㏱㐣ἲ 4 ๭ᙅࠊ⺯ගἲࡀ 6 ๭ᙅ฼⏝ࡉࢀ࡚࠾㌾ X ⥺ XAFS ࡛ࡣᕷ㈍ࡢࢢࣛࣇ⾲♧ࢯࣇࢺ࢙࢘ࡾࠊ㌿᥮㟁Ꮚ཰㔞ἲࡣࢃࡎ࠿࡛࠶ࡗࡓࠋ

࢔ࡶࡋࡃࡣ Athena ࡀ୺࡟౑⏝ࡉࢀ࡚࠸ࡿࠋࡋ࠿

⣲࡜ࡋ࡚ࡣࠊ㟁Ꮚᮦᩱࡸ㕲㗰ᮦᩱ࡛ࡼࡃ⏝࠸ࡽࡋࠊ㏆ᖺࡢ௻ᴗ࡟࠾ࡅࡿࢭ࢟ࣗࣜࢸ࢕࣮ព㆑ࡢ

ࢀࡿ TiࠊVࠊMnࠊFeࠊCoࠊNiࠊCu ࡢ 3d 㑄⛣㔠51ᐃඖᒓࠊゐ፹࡟ࡼࡃ⏝࠸ࡽࢀࡿ Ptࠊ⎔ቃศᯒࡢᑐ㇟
࡜࡞ࡾࡸࡍ࠸ As ࡀከ࠸⤖ᯝ࡜࡞ࡗࡓࠋࡲࡓ ᐃෆᐜ࡜ࡋ࡚ࡣࠊ༢⣧࡞㏱㐣ἲࡸ⺯ගἲࡔࡅ࡛࡞
ࡃࠊ࢞ࢫࡸᗘࠊ㟁Ẽ໬Ꮫⓗ࡞཯ᛂࢆࡉࡏ࡞ࡀ

ࡽࡢ In-situᐃࡸ࣐࢖ࢡࣟ࢟ࣕࣆ࣮ࣛࣜࢆ⏝࠸ࡓᚤᑠ㒊 ᐃࠊ2 ḟඖ࣐ࢵࣆࣥࢢ࡞࡝ࡶከࡃ฼⏝ࡉࢀࡓࠋ
ᅗ 4 XafsM2 ୖࡢ⺯ග X ⥺ࢫ࣌ࢡࢺࣝ

%/6㸦⢊ᮎ ; ⥺ᅇᢡ㸧%/ձ 㐠㌿≧ἣ
BL5S2 ࡣᖺ㛫㏻ࡋ࡚኱ࡁ࡞ࢺࣛࣈࣝ࡞ࡃ㐠⏝Bᅗ 2 BL5S1 ࡟࠾࠸࡚ 2021 ᖺᗘ࡟฼⏝ࡉࢀࡓࡍࡿࡇ࡜ࡀ࡛ࡁࡓࠋ฼⏝≧ἣ࡟㛵ࡋ࡚ࡣࠊ♫఍(ᕥ) ᐃᡭἲ๭ྜࠊ(ྑ) ᐃඖ⣲๭ྜ᝟ໃ࡟ࡼࡿ⛣ືไ㝈ࡢᙳ㡪ࡶ࠶ࡾࠊᐃ௦⾜ࡢ๭ྜࡀ౛ᖺࡼࡾከࡃࠊ⣙ 4 ศࡢ 1 ࢆ༨ࡵࠊ඲ BLղ ᨵၿ≧ἣ

ࡢ୰୍࡛␒ከ࠸⤖ᯝ࡜࡞ࡗࡓ㸦ᅗ 7(ᕥ)㸧ࠋヨᩱ

6'' 㐲㝸⛣ືࢩࢫࢸ࣒ࡢᑟධ

ࡀᶆ‽໬ࡉࢀ࡚࠸ࡿࡇ࡜ࡸ⮬ື໬ࡀ㐍ࢇ࡛࠸ࡿ

BL5S1 ࡛ࡣ⺯ගἲ࡛౑⏝ࡍࡿ SDD ࢆ⮬ືࢫࢸࡇ࡜ࡶࡑࡢせᅉ࡜ᛮࢃࢀࡿࠋ

࣮ࢪୖ࡟タ⨨ࡋࠊᐃᡭἲ࡛ࡣᐊ

ᐃࢯࣇࢺ࢙࢘࢔࡛࠶ࡿ

ᐃࡀ༙ศ௨ୖࢆ༨ࡵࠊḟ

XafsM2 ୖ࡛㐲㝸ไᚚࡍࡿࡇ࡜ࡀྍ⬟࡜࡞ࡗࡓࠋ

࠸࡛㧗

ᐃࠊప

ᐃࡢ㡰࡛࠶ࡗࡓ㸦ᅗ

ᚑ᮶ࡣ SDD ࡢ࢝࢘ࣥࢺㄪᩚࢆ⾜࠺ࡓࡵ࡟ࠊࣁࢵ

7(ྑ)㸧ࠋࡑࡢ௚ࠊ࢞ࢫ in situ

ࢳࡢධ㏥ᐊࢆ⧞ࡾ㏉ࡍࡇ࡜࡛ SDD ࡜ヨᩱ㛫ࡢ㊥࡜࠸ࡗࡓ≉Ṧ࡞㞳ㄪᩚࢆ⾜ࡗ࡚࠸ࡓࡀࠊ㐲㝸ไᚚࢩࢫࢸ࣒ࡢᑟ

ࡿࠋ

ᐃࡸ PDF ゎᯒᐃᡭἲࡶᖺࠎቑຍࡢഴྥ࡟࠶

ධ࡟ࡼࡗ࡚ XafsM2 ୖ࡛ࣜ࢔ࣝࢱ࢖࣒࡛ࡢ࢝࢘ࣥ
ࢺㄪᩚࡀྍ⬟࡜࡞ࡾࠊ኱ᖜ࡞ㄪᩚ᫬㛫ࡢ▷⦰ࢆ㐩ᡂࡋࡓ㸦ᅗ 5,6㸧ࠋᅗ 5 BL5S2 ࡟࠾࠾࠸࡚ 2021 ᖺᗘ࡟฼⏝ࡉࢀࡓ(ᕥ)฼⏝≧ἣ๭ྜࠊ(ྑ) ᐃᡭἲ๭ྜヨᩱղ ᨵၿ≧ἣ

SDD
㸦ヨᩱ᪉ྥ࡟๓ᚋ࡟⛣ື㸧฼⏝ຠ⋡ࡢྥୖSR ග

BL5S2 ࡛ࡣ᫖ᖺᗘᑟධࡋࡓ㧗㏿໬ࢧࣥࣉࣝࢳ

ᅗ 3 SDD ࢆ㐲㝸࡛⛣ືࡉࡏ࡚࠸ࡿᵝᏊ㸦ࣛ࢖࢙ࣥࢪ࣮ࣕࡢ฼⏝ࢆ㛤ጞࡋࡓࠋ఩⨨ㄪᩚࣉࣟࢢ

ࣈ࣓࢝ࣛീ㸧࣒ࣛࡶᨵⰋࡍࡿࡇ࡜࡛ࠊ

52

ᐃ௨እ࡟せࡍࡿ᫬㛫ࠊ

PDF ゎᯒ࡛㧗࠸✵㛫ศゎ⬟࡛▷⠊ᅖᵓ㐀ࢆṇヨᩱ஺᥮ࡸ఩⨨ㄪᩚࡢ᫬㛫ࢆᚑ᮶ࡢ༙ศ⛬ᗘࡲ☜࡟⌮ゎࡍࡿࡓࡵ࡟ࡣࠊᗈゅᗘ㡿ᇦࡲ࡛࡛▷⦰ࡍࡿࡇ࡜ࡀ࡛ࡁࡓ㸦ᅗ 8,9,10㸧ࠋᐃࡍࡿࡇ࡜ࡀᮃࡲࡋ࠸ࠋ୍᫬ 2ȟᅇᢡィࡢ୙ㄪ࡟ࡼࡾࠊ
ࡑࡢ⠊ᅖࡣ㝈ࡽࢀ࡚࠸ࡓࡀࠊ2ȟᅇᢡィࡢ᭦᪂ࢆ⾜࠸ࠊ⌧ᅾ 132r(Q ್㸸18.5)ࡲ࡛ࡢ ᐃࡀྍ⬟࡜࡞ࡗ࡚࠸ࡿࠋ
ࡑࡢ௚ࠊ㧗ཬࡧప࢞ࢫࡢ྿௜࡟ᚲせ࡞❅⣲࢞ࢫࢆ⏕ᡂࡍࡿࠕ❅⣲࢞ࢫⓎ⏕⿦⨨ࠖࢆ 1 ྎ㏣ຍࡋࡓࠋ❅⣲࢞ࢫ⏕ᡂ㔞ࡢ㛵ಀ࠿ࡽࠊᚑ᮶ 3 ᫬㛫⛬ᗘ࠿࠿ࡗ࡚࠸ࡓ㧗

ᐃ࡜ప

ᐃࡢษࡾ᭰

࠼ࡀࠊ⿦⨨ࢆ㏣ຍࡋࡓࡇ࡜࡛ 1 ᫬㛫௨ෆ࡟▷⦰ࡉࢧࣥࣉࣝࢳ࢙ࣥࢪ࣮ࣕ

ࢀࠊྠ᪥࡟㧗

ᐃࠊపᐃࢆ⾜࠺ࡇ࡜ࡀྍ

⬟࡜࡞ࡗࡓࠋ

ᅗ 6 㧗㏿໬ࢧࣥࣉࣝࢳ࢙ࣥࢪ࣮ࣕ

%/1㸦㌾ ; ⥺ ;$)6࣭ග㟁ᏊศගϨ㸧ձ 㐠㌿≧ἣ
2021 ᖺᗘ࡟࠾ࡅࡿ BL6N1 ࡛ࡢศᯒ᪉ἲཬࡧ
ᐃヨᩱศ㢮ࡢ฼⏝᫬㛫๭ྜࢆᅗ 11 ࡟♧ࡍࠋศᯒ᪉ἲ࡛ࡣ᫖ᖺᗘ࡜ྠᵝ࡟ XAFS ࡀ 9 ๭㏆ࡃࢆ༨ࡵࡓࡀࠊ௒ᖺᗘࡣ┿✵ࢳ࢙ࣥࣂ࣮ࢆ౑⏝ࡋࡓ
XAFS ࡀ᫖ᖺᗘࡢ 9%࠿ࡽ 21%࡟ࠊ ᐃヨᩱศ㢮ᅗ 7 㧗㏿໬ࡋࡓࢧࣥࣉࣝࢳ࢙ࣥࢪ࣮ࣕ

࡛ࡣ㟁ụᮦᩱࡀ᫖ᖺᗘࡢ 7㸣࠿ࡽ 32㸣࡟ࠊࡑࢀࡒ
ࢀ኱ᖜ࡟ቑຍࡋࡓࠋ2021 ᖺᗘ࡟┿✵ࢳ࢙ࣥࣂ࣮
࡟ࢩࣜࢥࣥࢻࣜࣇࢺ᳨ฟჾࡀᑟධࡉࢀࠊ௨๓ࡼ
ࡾ㟁ụᮦᩱ࣮ࣘࢨ࣮࡞࡝࠿ࡽせᮃࡢ࠶ࡗࡓ┿✵୰࡛ࡢ㒊ศ⺯ග཰㔞 XAFS ࡀྍ⬟࡜࡞ࡗࡓࡇ࡜
ࡀࠊࡇࡢ୍ᅉ࡜⪃࠼ࡽࢀࡿࠋ

ᐃඖ⣲ࡢ๭ྜࡣࠊ

S K (34%), P K (28%), Si K (15%), Ag L3(7%), Cl
K(4%), K K (2%), ࡑࡢ௚ࡢඖ⣲(9%)࡛࠶ࡗࡓࠋ

ᅗ 8 㧗㏿໬ࡋࡓࢧࣥࣉࣝࢳ࢙ࣥࢪ࣮ࣕ
ᐃ࡟㛵ࡋ࡚ BL5S2 ࡛᭱㏆ከࡃ฼⏝ࡉࢀࡿᐃࡢ୍ࡘ࡟ PDF ゎᯒࡀ࠶ࡿࠋࡇࡢ ᐃἲࡣ㠀ᬗ㉁⣔࡛ࡣ▷㊥㞳ᵓ㐀ࡢゎᯒࠊ⤖ᬗ㉁⣔࡛ࡣᒁᡤᵓ㐀ࡢ஘ࢀゎᯒ࡟ᛂ⏝ࡉࢀࡿ᪉ἲ࡛࠶ࡿࠋゎᯒ

ᅗ 9 BL6N1 ࡟࠾࠸࡚ 2021 ᖺᗘ࡟฼⏝ࡉࢀࡓ࡟࡞ࡌࡳࡢ↓࠸࣮ࣘࢨ࣮࡟ࡶ฼⏝ࡋࡸࡍ࠸ࡼ࠺(ᕥ)ศᯒ᪉ἲ๭ྜࠊ(ྑ) ᐃヨᩱศ㢮๭ྜ

௒ᖺᗘ PDF ゎᯒࢯࣇࢺࢆ㉎ධࡋࡓࠋ53ղ ᨵၿ≧ἣ%/8㸦┿✵⣸እศග㸧┿✵ࢳ࢙ࣥࣂ࣮࡬ࡢ 6'' ᑟධ࡜኱Ẽᅽࢳ࢙ࣥࣂձ 㐠㌿≧ἣ
BL7U ࡣ࢚ࣥࢻࢫࢸ࣮ࢩࣙࣥほ ⿦⨨ࡢ᭦᪂ࢆ࣮࣐ࢽࣆ࣮ࣗࣞࢱࡢ⮬ື໬
2021 ᖺᗘ࡟ᐇ᪋ࡋࡓ୺࡞ᨵၿⅬࡣḟࡢ 2 Ⅼ࡛࠶⾜ࡗࡓࡓࡵࠊ2021 ᖺ 10 ᭶ୗ᪪࠿ࡽࡢ࣮ࣘࢨ࣮฼

ࡿࠋ୍ࡘ┠ࡣࠊ┿✵ࢳ࢙ࣥࣂ࣮࡟ 1 ⣲Ꮚࢩࣜࢥࣥ

⏝㛤ጞ࡜࡞ࡗࡓࠋ ᐃᡭἲ࡜ࡋ࡚ࡣ㌾ X ⥺྾཰ศࢻࣜࣇࢺ᳨ฟჾ㸦ࢸࢡࣀ AP 〇 XSDD50-01Be㸧ග㸦XAS㸧࡜ග㟁Ꮚศග㸦PES㸧ࡀ⾜ࢃࢀ࡚࠾ࢆᑟධࡋࠊࡇࢀࡲ࡛┿✵ࢳ࢙ࣥࣂ࣮࡛ࡣᮍᑐᛂ࡛

ࡾࠊ4 ศࡢ 1 ࡣࡇࢀࡽࢆే⏝ࡋࡓᐇ㦂࡜࡞ࡗ࡚࠸

࠶ࡗࡓ㒊ศ⺯ග཰㔞ἲ XAFSᐃ࡟ᑐᛂࡋࡓࠋࡇࡿࠋPES ࡛ࡣෆẆග㟁Ꮚศග࡜౯㟁Ꮚᖏゅᗘศࢀ࡟ࡼࡾྠࢳ࢙ࣥࣂ࣮࡛ࠊ඲㟁Ꮚ཰㔞ࠊ㒊ศ⺯ගゎග㟁Ꮚศගࡀ࡯࡜ࢇ࡝࡛࠶ࡾࠊഹ࠿࡛࠶ࡿࡀ

཰㔞ἲཬࡧ࣮࢜ࢪ࢙㟁Ꮚ཰㔞ἲࡢ୕ࡘࡢ᪉ᘧ࡟ࡼග 㟁Ꮚ ᅇᢡ ࡸ௙ ஦㛵 ᩘࡢࡿ XAFS13㸧ࠋᐃࡀྍ⬟࡜࡞ࡗࡓࠋᐃ ࡶ⾜ ࢃࢀ ࡓ 㸦 ᅗᐃඖ⣲࡜ࡋ࡚ࡣࠊC, O, N, Si ࡞࡝ࡢ㍍ඖ⣲ࡀ஧ࡘ┠ࡣࠊࡇࢀࡲ࡛ᡭືᘧ࡛࠶ࡗࡓ኱Ẽᅽࢳ࢙ࣥࣂ࣮ࡢヨᩱ࣐ࢽࣆ࣮ࣗࣞࢱ࡜ SDD ࢫࢸ࣮ࢪࢆ

୰ᚰ࡜࡞ࡗ࡚࠸ࡿࠋ

⮬ື໬ࡋࠊヨᩱ࡜ SDD ࡢ఩⨨ࢆ PC ࠿ࡽㄪᩚྍ⬟ᩱࡸ㟁ụ⣔ᮦᩱࡀከ࠸ࠋBL7U ࡛ࡣᏛ⾡฼⏝ࡀ㸵࡜ࡋࡓࠋࢧࣥࣉࣝࣉ࣮ࣞࢺࡣୗ㒊ᑟධཱྀ࠿ࡽࢺࣛ

๭ࢆ༨ࡵ࡚࠾ࡾࠊࢢࣛࣇ࢙ࣥࡸ㛵㐃≀㉁ࡶከࡃ

ࣥࢫࣇ࢓࣮ࣟࢵࢻ࡛ᘬࡁୖࡆࠊ࣐ࢽࣆ࣮ࣗࣞࢱ࡟

ᐃࡉࢀࡓࠋ㏆ᖺࠊẸ㛫௻ᴗࡢ฼⏝࡛ࡶゅᗘศ᥋⥆ࡋࠊヨᩱ㟁ὶィᐃᑐ㇟࡜ࡋ࡚ࡣⅣ⣲⣔ᮦゎග㟁Ꮚศගࢆ฼⏝ࡋࡓᇶ♏ⓗ◊✲ࡶ࠾ࡇ࡞ࢃ

⏝ࡢ㟁Ẽⓗ᥋⥆ࡶࡇࡢ᫬⾜ࢀࡿࡼ࠺࡟࡞ࡗ࡚ࡁࡓ㸦ᅗ 14㸧ࠋࢃࢀࡿࠋࡇࡢᶵᵓ࡟ࡼࡾࠊࡇࢀࡲ࡛ᮍᑐᛂ࡛࠶ࡗ
ࡓ኱Ẽᅽ⏝ࢺࣛࣥࢫࣇ࢓࣮࣋ࢵࢭࣝ฼⏝᫬ࡢ㌿᥮㟁Ꮚ཰㔞 XAFS

XAS
50%ᐃࡀྍ⬟࡜࡞ࡗࡓ㸦ᅗ 12㸧ࠋ

PES
76%

ᅗ 11 ඲฼⏝ࢩࣇࢺᩘ࡟ᑐࡍࡿ

ᐃᡭἲࡢ๭ྜࠋ

4 ศࡢ 1 ࡀ XAS ࡜ XPS ࡢే⏝࡜࡞ࡗ࡚࠸ࡿࠋ
Lii
3%
̖ᩓ
̖ᩓ‫‒࠘܇‬ᩓ‫࠘܇‬ήᩓ‫܇‬Ўή‒
ήᩓ
ᩓ‫܇‬Ў
‫܇‬Ў
Ўή
40
4
0%

B
3%

C
18
8%

↌↝˂Ψእ‒
↌↝
↝˂Ψ
˂Ψ
Ψእ
40
4
0%
Tii
T
2%

ᅗ 10 ⮬ື໬ࡋࡓヨᩱ࣐ࢽࣆ࣮ࣗࣞࢱ

Ag
Ag
2% A
All
2%

Si
6%

O
12
2%

N
4%

Ge
G
2%

ᅗ 12 BL7U ࡟࠾࠸࡚ 2021 ᖺᗘ࡟฼⏝ࡉࢀࡓᐃᑐ㇟ඖ⣲ࡢ๭ྜࠋ౯㟁Ꮚᖏࡢ
ゅᗘศゎග㟁Ꮚศග࡛࠶ࡿࠋ

54ᐃࡣ࡯࡜ࢇ࡝ղ ᨵၿ≧ἣ%/6㸦ⷧ⭷ ; ⥺ᅇᢡ㸧࢚ࣥࢻࢫࢸ࣮ࢩࣙࣥほ ⿦⨨ࡢ᭦᪂ձ 㐠㌿≧ἣ

BL7U ࡛ࡣࠊග㟁Ꮚศග࣭྾཰ศග ᐃ⿦⨨

BL8S1 ࡣᖺ㛫㏻ࡋ࡚኱ࡁ࡞ࢺࣛࣈࣝ࡞ࡃ౪⏝ྍࡀタ⨨ࡉࢀ࡚࠸ࡿࡀࠊ⤒ᖺຎ໬࡟ࡼࡿືస୙Ⰻ

⬟࡛࠶ࡗࡓࠋᅗ 16 ࡣ 2021 ᖺᗘࡢ฼⏝࡟࠾ࡅࡿࡢゎᾘ࡜ࡼࡾ㧗ᗘ࡞ ᐃࢆྍ⬟࡟ࡍࡿࡓࡵほ౑⏝࢚ࢿࣝࢠ࣮ཬࡧ౑⏝᳨ฟჾࡢ๭ྜࢆ♧ࡋࡓ⿦⨨ࡢ᭦᪂ࢆ⾜ࡗࡓࠋ᪂ࡋ࠸⿦⨨࡛ࡣヨᩱ఩⨨ࡶ ࡢ ࡛ ࠶ ࡿ ࠋ ฼ ⏝ ࢚ ࢿ ࣝ ࢠ ࣮ ࡣ 9.15keV ࡜ࢆไᚚࡍࡿ࣐ࢽࣆ࣮ࣗࣞࢱࢆࡇࢀࡲ࡛ 4 ㍈ไᚚ

14.37keV ࡢ฼⏝ࡀ඲యࡢ 96%ࢆ༨ࡵ࡚࠾ࡾࠊṧ࡛࠶ࡗࡓࡶࡢࢆ 6 ㍈㸦ୖୗ࣭๓ᚋ࣭ᕥྑ࣭ᴟ

ࡾࡣ 22.7keV ࡛࠶ࡿࠋヨᩱྵ᭷ඖ⣲࡟㉳ᅉࡍࡿゅ࣭௮ゅ࣭㠃ෆゅ㸧໬ࡋࠊᐃ㓄⨨ࡢ⮬⏤ᗘࡀ⺯ග X ⥺ࢆపῶࡍࡿ┠ⓗ࡛࢚ࢿࣝࢠ࣮ࡀ㑅ࡤࢀࡿ኱ࡁࡃྥୖࡋࡓ㸦ᅗ 15㸧ࠋࡇࢀ࡟ࡼࡾࠊ౛࠼ࡤ

ࢣ࣮ࢫࡀከ࠸ࡀࠊ22.7keV ࡟ࡘ࠸࡚ࡣ㏱㐣㓄⨨࡛ࡇࢀࡲ࡛ධᑕග࢚ࢿࣝࢠ࣮ࢆ㧗ࡃࡋ࡞࠸࡜ ᐃࡢ࡛ࡁ࡞࠿ࡗࡓࢢࣛࣇ࢓࢖ࢺࡢ K Ⅼ௜㏆ࡢゅᗘศᢥࡉࢀ࡚࠸ࡿࠋ᳨ฟჾࡣ๓ᖺᗘ࡟ᘬࡁ⥆ࡁࢩࣥゎග㟁Ꮚศගࡀศゎ⬟ࡢ㧗࠸ప࢚ࢿࣝࢠ࣮ഃ࡛

ࢳ࣮ࣞࢩࣙࣥ࢝࢘ࣥࢱࡼࡾࡶ PILATUS-100K ᳨ࡶほ ྍ⬟࡟࡞ࡾࠊࡲࡓࠊヨᩱࢆྲྀࡾฟࡍࡇ࡜

ฟჾࡀከࡃ฼⏝ࡉࢀ࡚࠸ࡿࠋ

࡞ࡃ᪉఩ࢆኚ᭦࡛ࡁࡿࡼ࠺࡟࡞ࡗࡓࠋධᑕゅᅛᐃ 2ȟ࡟ຍ࠼ࠊIn-Plane ᅇᢡࠊṧ␃ᛂຊࠊᐃࡸ㧗 Q-range ࡲ࡛ࡢᐃࢆ┠ⓗ࡜ࡋ࡚㑅ᐃᡭἲ࡛ࡣȟ/2ȟࠊ཯ᑕ⋡ࠊᴟⅬᅗࡶ฼⏝ࡉࢀࡓࠋࡲࡓࠊୖグᡭἲ࡟࣐ࢵࣆࣥࢢࠊຍ⇕ᐇ㦂ࢆ⤌ࡳྜࢃࡏࡓ฼⏝ࡶ࠶ࡗࡓࠋᅗ 14 BL8S1 ࡟࠾࠸࡚ 2021 ᖺᗘ࡟฼⏝ࡉࢀࡓ(ᕥ)౑⏝࢚ࢿࣝࢠ࣮ࠊ(ྑ)౑⏝᳨ฟჾղ ᨵၿ≧ἣ 㐃ศග⤖ᬗࡢᑟධ
BL8S1 ࡛ࡣࠊ⤖ᬗࢆษࡾ᭰࠼ࡿࡇ࡜࡛࢚ࢿࣝ
ࢠ࣮ࡢኚ᭦ࢆ⾜ࡗ࡚࠸ࡿࠋ3 㐃ศග⤖ᬗ㸦ᅗ 17㸧
ࡀ BL8S1 ࡟ᑟධࡉࢀࡓࡇ࡜࡟ࡼࡾࠊศගჾࢳࣕࣥ ࣂ࣮ ࢆ㛤 ᨺࡍ ࡿࡇ ࡜࡞ ࡃ ୕ ࡘࡢ ࢚ࢿ ࣝࢠ ࣮
㸦9.15keVࠊ14.4keVࠊ22.7keV㸧ࡢษࡾ᭰࠼ࡀ
ྍ⬟࡜࡞ࡗࡓࠋࡇࢀ࡟ࡼࡾࠊ࢚ࢿࣝࢠ࣮ษࡾ᭰
࠼࡟క࠺ㄪᩚ᫬㛫ࡀ▷⦰ࡉࢀࠊ౪⏝ྍ⬟࡞ࢩࣇᅗ 13 (ୖ)ヨᩱ࣐ࢽࣆ࣮ࣗࣞࢱࡢヨᩱࢫࢸ࣮ࢪࠊ ࢺࡀቑຍࡋࡓࠋྛ࢚ࢿࣝࢠ࣮࡛ ᐃࡋࡓ CeO2 ⢊(ୗ)᭦᪂ࡋࡓ࢚ࣥࢻࢫࢸ࣮ࢩࣙࣥほ⿦⨨ࡢ඲ᬒࠋ ᮎࡢᅇᢡࣉࣟࣇ࢓࢖ࣝࢆᅗ 18 ࡟♧ࡍࠋヨᩱࢫࢸ࣮ࢪࡣ㸰ẁ࠶ࡾࠊୖẁ㸲㍈ࠊୗẁ㸴㍈㥑ື55ᅗ 17 BL8S3 ࡟࠾࠸࡚ 2021 ᖺᗘ࡟฼⏝ࡉࢀࡓ(ᕥ) ᐃᡭἲ๭ྜࠊ(ᕥ)ྛ࣓࢝ࣛ㛗ࡢ฼⏝⋡ղ ᨵၿ≧ἣ

ᅗ 15 3 㐃ศග⤖ᬗ฼⏝ྍ⬟࡞࣓࢝ࣛ㛗ࡢᣑ኱ཬࡧ᪂つ᳨ฟჾࡢᑟධ2020 ᖺᗘ࡟ࠊヨᩱኚ᭦࡟࠿࠿ࡿ᫬㛫ࢆ๐ῶࡋࠊ
ከࡃࡢᐃࢆྍ⬟࡟ࡍࡿࡓࡵ࡟ࠊከ㐃ࢧࣥࣉࣝࢳ࢙ࣥࢪ࣮ࣕࢆᑟධࡋࡓࡀࠊZ ࢫࢸ࣮ࢪࡢ⛣ື࡟᫬㛫ࡀ࠿࠿ࡗ࡚࠾ࡾࠊPILATUS ࢆ฼⏝ࡋࡓᐇ㦂࡟ࡣ㐺ᛂ࡛ࡁ࡚࠸࡞࠿ࡗࡓࠋࡑࡇ࡛ࠊ⛣ື㏿ᗘ
ࡀ㏿࠸ Z ࢫࢸ࣮ࢪࢆᑟධࡋࠊᐇ㦂ࣁࢵࢳࡢ㛤㛢ᅇᩘࢆῶࡽࡋࠊࡉࡽ࡞ࡿࢫ࣒࣮ࢬ࡞

ᅗ 16 CeO2 ⢊ᮎᅇᢡࣉࣟࣇ࢓࢖ࣝ

ᐃࢆྍ⬟࡟

ࡋࡓࠋ
BL8S3 ࡛ࡣࠊ150 nm ௨ୗࡢᵓ㐀ゎᯒࡀྍ⬟࡛%/6㸦ᗈゅ࣭ᑠゅ ; ⥺ᩓ஘㸧࠶ࡗࡓࡀࠊᮦᩱࡢᶵ⬟ࡢⓎ⌧ࢆ⌮ゎࡍࡿࡓࡵ࡟ࠊձ 㐠㌿≧ἣ

ࡉࡽ࡞ࡿ኱ࡁ࡞㡿ᇦ࡛ࡢ㝵ᒙᵓ㐀ࡢゎᯒࡀࠊࣘ

2021 ᖺᗘࡢ BL8S3 ࡢ฼⏝≧ἣࡣࠊ2020 ᖺᗘ࣮ࢨ࣮࠿ࡽࡢせᮃ࡜ࡋ࡚࠶ࡗࡓࠋࡑࡢࡓࡵࠊᐇ

ᐃ௦⾜ࡢẚ⋡ࡀ㧗࠿ࡗࡓࠋࡲࡓࠊ

㦂ࣁࢵࢳࢆ᭱኱㝈฼⏝ࡋࠊ᭱኱࣓࢝ࣛ㛗ࢆ 6.5 m

᪂つ࣮ࣘࢨ࣮ࡶቑຍࡋࡓࠋᅗ 19 ࡟ࠊ ᐃᡭἲཬࡲ࡛ᣑ኱ࡍࡿࡇ࡜࡟ࡼࡾࠊ250 nm ௨ୗࡢᵓ㐀ゎࡧྛ࣓࢝ࣛ㛗ࡢ฼⏝⋡ࢆ♧ࡍࠋ2021 ᖺᗘࡣࠊᩳ

ᯒࢆྍ⬟࡟ࡋࡓࠋࡲࡓࠊ኱㠃✚ࡢ PILATUS 2M

ධᑕᑠゅ X ⥺ᩓ஘࣭ᗈゅ X ⥺ᅇᢡἲࡢ฼⏝ࡀ 9ࢆᑟධࡋࡓࠋ኱㠃✚ PILSTUS ࡢᑟධࡣࠊ㧗 q 㡿ࢩࣇࢺ⛬ᗘ࡜๓ᖺᗘࡼࡾࡉࡽ࡟ῶᑡࡋࡓࠋྛ࢝

ᇦ࡟࠾ࡅࡿ SN ࡢྥୖ࠾ࡼࡧ㓄ྥᵓ㐀ࡢホ౯ࢆྍ࣓ࣛ㛗࡟࠾ࡅࡿ฼⏝⋡࡛ࡣࠊ࣓࢝ࣛ㛗 4 m ࡢᑠゅ⬟࡟ࡍࡿࠋ2022 ᖺᗘ࠿ࡽࠊ࣓࢝ࣛ㛗 6.5 m ࠾ࡼX ⥺ᩓ஘ἲࡢ฼⏝ࡀ୍␒ከࡃࠊḟ࡟࣓࢝ࣛ㛗 0.2

ࡧ PILATUS 2M ࡢ㐠⏝ࢆ㛤ጞࡍࡿ㸦ᅗ 20,21㸧ࠋ࡜ྠᵝ࡟ࠊm ࡀࡼࡃ฼⏝ࡉࢀ࡚࠸ࡓࠋྛ✀ᮦᩱ࡟࠾࠸࡚ࡣࠊ
㧗ศᏊࡢ࣮ࣘࢨ࣮ࡀ୍␒ከࡃࠊ㔠ᒓᮦᩱࡢ࣮ࣘ
ࢨ࣮ࡀቑຍࡋ࡚࠸ࡓࠋࡲࡓࠊSAXS࣭WAXD ྠ᫬ᐃࢆ⾜࠺ᐇ㦂ࡢ࣮ࣘࢨ࣮ࡶቑຍࡋࡓࠋ

ᅗ 18 ᑟධࡋࡓ 6.5㹫࣓࢝ࣛ㛗

56

⬟࡟࡞ࡗࡓࠋᅗ 23 ࡢࡼ࠺࡟ 2 ḟඖ᳨ฟჾࢆ⤌ࡳྜࢃࡏࡿࡇ࡜࡟ࡼࡾࠊ2 ḟඖ࠾ࡼࡧ㸱ḟඖ XAFSᐃࡀྍ⬟࡛࠶ࡿࠋᅗ 24 ࡣࠊCu2OࠊCuOࠊBNࡢΰྜ࣌ࣞࢵࢺࡢ 2 ḟඖ XAFSᐃ⤖ᯝ࡛࠶ࡿࠋ

ࢧࣥࣉࣝྛⅬ࡛ࡢ XAFS ࢫ࣌ࢡࢺࣝࢆ▷᫬㛫࡛ศᯒࡍࡿࡇ࡜ࡀ࡛ࡁࡿࠋ

ᅗ 19 PILATUS 2M ᳨ฟჾ%/6㸦◳ ; ⥺ ;$)6ϩ㸧ձ 㐠㌿≧ἣ
BL11S2 ࡣᖺ㛫ࢆ㏻ࡋ࡚኱ࡁ࡞ࢺࣛࣈࣝ࡞ࡃ㐠⏝ࡍࡿࡇ࡜ࡀ࡛ࡁࡓࠋᅗ 22 ࡣࠊ2021 ᖺᗘ࡟
BL11S2 ࡛ ᐃࡉࢀࡓඖ⣲ࡢ๭ྜ࡛࠶ࡿࠋCu ࢆጞࡵ࡜ࡋࡓ 3d 㑄⛣㔠ᒓࡢᅗ 21 2 ḟඖ࠾ࡼࡧ 3 ḟඖ XAFSᐃ᫬ࡢᵓᡂᅗ 22 ΰྜ࣌ࣞࢵࢺࡢ 2 ḟඖ XAFSᐃ⤖ᯝᐃࡀከ࠿ࡗࡓࠋ ᐃ

ᡭἲࡣ㏱㐣ἲ࡜⺯ග཰㔞ἲࡢ ex-situᐃࡀከ࠿ࡗࡓࡀࠊࣅ࣮࣒ࣛ࢖ࣥࡢ࢞ࢫタഛࢆ⏝࠸ࡓ insituᐃࡸࠊࢡࣛ࢖࢜ࢫࢱࢵࢺࢆ⏝࠸࡚ヨᩱࢆ෭༷ࡋ࡞ࡀࡽࡢ ᐃ➼ࡶᐇ᪋ࡉࢀࡓࠋ

ឡ▱┴ࣅ࣮࣒ࣛ࢖ࣥ

%/6㸦; ⥺ࢺ࣏ࢢࣛࣇ࢕࣭; ⥺ &7㸸ឡ▱┴㸧ᅗ 20 BL11S2 ࡟࠾࠸࡚ 2021 ᖺᗘ࡟ձ 㐠㌿≧ἣ

ᐃࡉࢀࡓ

BL8S2 ࡛ࡣࠊX ⥺ࢺ࣏ࢢࣛࣇ࢕ࠊLIGA㸦X ⥺ඖ⣲ࡢ๭ྜࣜࢯࢢࣛࣇ࢕㸧ࠊ2 ḟඖࣟࢵ࢟ࣥࢢ࣮࢝ࣈᐃղ ᨵၿ≧ἣ

㸦2D-RC㸧ࠊX ⥺↷ᑕᐇ㦂ࠊX ⥺ CT

ᗈࡀࡗࡓࢩࣥࢡࣟࢺࣟࣥගࢆ฼⏝ࡋࡓ  ḟඖཬඖ XAFS㸦2D-XAFS㸧ࠊCT-XAFS ࡞࡝ࠊᵝࠎ࡞ࡧ  ḟඖ ;$)6

ᐃࠊ2 ḟ

✀㢮ࡢᐇ㦂ࡀྍ⬟࡛࠶ࡿࠋ2017㹼2018 ᖺᗘࡣ Xᐃᚋ⨨࣑࣮ࣛ࡜ࡋ࡚ࠊᚑ᮶ࡢ࣋ࣥࢻࢩࣜࣥࢻࣜ

⥺ࢺ࣏ࢢࣛࣇ࢕㸦2D-RC ࢆྵࡴ㸧ࡢ฼⏝ࡀ༙ศ࣑࣮࢝ࣝࣛ࡟ຍ࠼࡚ࠊࣉ࣮࣑࣮ࣞࣥࣛࢆ㏣ຍࡋ

௨ୖࢆ༨ࡵ࡚࠸ࡓࡀࠊ2019㹼2020 ᖺᗘࡣ X ⥺ࡓࠋࡇࢀ࡟ࡼࡾࠊ㞟ගࡋࡓࢩࣥࢡࣟࢺࣟࣥගࡔ

CT ᐇ㦂ࡢ฼⏝ࡀቑຍࡋ඲฼⏝ࢩࣇࢺࡢ༙ᩘ௨ୖ

ࡅ࡛࡞ࡃࠊᗈࡀࡗࡓࢩࣥࢡࣟࢺࣟࣥගࡶ฼⏝ྍࢆ༨ࡵࡓࠋ2021 ᖺᗘࡣࠊX ⥺ CT ᐇ㦂ࡢ฼⏝ࡀ

57඲฼⏝ࢩࣇࢺࡢ༙ᩘ௨ୖࢆ༨ࡵࠊX ⥺ࢺ࣏ࢢࣛࣇ

ࡑࡢ཯㠃ࠊX ⥺ࡢᖹ⾜ᛶࡀపୗࡋ఩┦ീࡢࢥࣥࢺ

࢕ᐇ㦂ࡢ฼⏝ࡀ 4 ศࡢ 1 ㏆ࡃ⾜ࢃࢀࠊࡑࡢ௚ࠊ

ࣛࢫࢺ࡜✵㛫ศゎ⬟ࡀపୗࡍࡿࠋ

LIGAࠊX ⥺↷ᑕᐇ㦂ࠊ2 ḟඖ XAFS ࡢ฼⏝ࡀ⾜Ғ૮&7଎ఈεητϞࢃࢀࡓ㸦ᅗ 25㸧ࠋ௻ᴗࠊ኱Ꮫࠊ◊✲ᡤࠊබタ᪋࣏‫̯ݫ‬તΩϟϧタࠊᙜ㈈ᅋ࠿ࡽ฼⏝ࡉࢀࡓ㸦ᅗ 26㸧ࠋ

ϧΤΦ݃ধ
ヨᩱ఩⨨

ᅗ 23 BL8S2 ࡟࠾࠸࡚ 2021 ᖺᗘ࡟฼⏝ࡉࢀࡓϔϧρή݃ধ

ᐇ㦂ᡭἲෆヂ

ᅗ 25 ఩┦ CT



ᐃࢩࢫࢸ࣒

ྡྂᒇ኱Ꮫࣅ࣮࣒ࣛ࢖ࣥ

%/6㸦༢⤖ᬗ ; ⥺ᅇᢡ㸸ྡྂᒇ኱Ꮫ㸧ձ 㐠㌿≧ἣ
BL2S1 ࡣ⪁ᮙ໬ࡋࡓᶵჾࡢᨾ㞀ࡀ┦ḟ࠸࡛Ⓨᅗ 24 BL8S2 ࡟࠾ࡅࡿ 2017㹼2021 ᖺᗘࡢ฼⏝⏕ࡋࠊ2021 ᖺᗘࡢ㐠⏝࡟ᙳ㡪ࡀⓎ⏕ࡋࡓࠋࡲࡓࠊ

⪅ෆヂ஧ࡘࡢศග⤖ᬗࢆ⿦ሸྍ⬟࡞ศගჾࡢᑟධ࡟ྥղ ᨵၿ≧ἣ

ࡅࡓࣅ࣮࣒ࣛ࢖ࣥࢫࢱࢹ࢕ࢆᐇ᪋ࡋࡓࡓࡵࠊࣘ఩┦ &7࣮ࢨ࣮࡟ᥦ౪ࡋࡓࢩࣇࢺᩘࡀ๓ᖺᗘࡼࡾῶᑡࡋ

ᐃࢩࢫࢸ࣒

ࡓ㸦ᅗ 28㸧ࠋBL2S1 ࡛ࡣࢲ࢖࢔ࣔࣥࢻ࢔ࣥࣆࣝ

BL8S2 ࡛ࡣࠊ⏕యᮦᩱࠊ᳜≀ヨᩱࠊ㍍ඖ⣲ᮦᩱ࡞࡝ࠊ྾཰ࢥࣥࢺࣛࢫࢺ X ⥺ CTࢭࣝࢆ⏝࠸ࡓ㧗ᅽ ᐃࡀ 4 ๭⛬ᗘ฼⏝ࡉࢀ࡚࠸ࡿࠋᐃ࡛ࡣほᐹᅔ㞴࡞ヨᩱࡢ㠀◚ቯ 3 ḟඖᚤ⣽ᵓ㐀ほᐹࢆྍ⬟࡟ࡲࡓ㧗࢚ࢿࣝࢠ࣮ࡢ X ⥺ࡢ฼⏝ࡀ 6 ๭࡟㐩ࡋ࡚࠸ࡍࡿࡓࡵ࡟ࠊ఩┦ࢥࣥࢺࣛࢫࢺ X ⥺ CT㸦఩┦ࡿ㸦ᅗ 29㸧ࠋ ᐃ࣮ࣔࢻኚ᭦ࡸ X ⥺ࡢ࢚ࢿࣝࢠ

CT㸧 ᐃࢩࢫࢸ࣒ࡢᵓ⠏ࢆ⾜ࡗࡓ㸦ᅗ 27㸧ࠋ࣮ኚ᭦࡟క࠺ࣅ࣮࣒ࣛ࢖ࣥ㐠⏝ᡭ㡰ࡢ㧗㏿໬ࡸࠊᐃࡣࠊX ⥺ᖹ⾜໬ࡢࡓࡵ࡟ࣈࣛࢵࢢ

ࢧࣥࣉࣝᦆയࡢᑡ࡞࠸㧗࢚ࢿࣝࢠ࣮X ⥺⤖ᬗ࡛ X ⥺ࢆᅇᢡࡉࡏࠊヨᩱࡢ X ⥺㏱㐣ീ࠿ࡽ㸦16.53keV㸧ࡢရ㉁ᨵၿࢆᐇ᪋ࡋࠊᥦ౪ࢩࣇࢺ

X ⥺఩┦ീࢆྲྀࡾฟࡍࡓࡵ࡟࢚ࣛ࢘⤖ᬗ࡛ X ⥺ࢆᩘࡢῶᑡࢆ⿵ࡗࡓࠋୖグࡢᑐᛂ࡟ࡼࡾࠊࣅ࣮࣒

ᅇᢡࡉࡏࡿࡀࠊ2 ᗘࡢ X ⥺ᅇᢡ࡟ࡼࡾ X ⥺ᙉᗘࡀࣛ࢖ࣥ฼⏝⪅ࡢ◊✲ᡂᯝࡢ㔞ࡣ⥔ᣢࡋ࡚࠸ࡿ࡜

኱ᖜ࡟పୗࡍࡿࡓࡵ

ぢ㎸ࡲࢀࡿࠋ

఩┦ CTᐃ࡟᫬㛫ࡀ࠿࠿ࡿ࡜࠸࠺

㞴Ⅼࡀ࠶ࡿࠋX ⥺ᙉᗘపୗࢆᢚไࡋ࡚ ᐃ᫬㛫ࢆ▷⦰ࡍࡿࡓࡵ࡟ࠊࣈࣛࢵࢢ⤖ᬗ୙౑⏝ࡢ఩┦ CTᐃࡢᩚഛࢆ⾜࠸ᐃ᫬㛫▷⦰ࡀྍ⬟࡜࡞ࡗࡓࠋ

58

ᅗ 26 㐣ཤ 2 ᖺ࡟࠾ࡅࡿᥦ౪ࢩࣇࢺᩘࡢ᥎⛣ᅗ 27 BL2S1 ࡟࠾࠸࡚ 2021 ᖺᗘ࡟฼⏝ࡉࢀࡓ(ᕥ) ᐃ᪉ἲࡢศᕸࠊ(ྑ)X ⥺࢚ࢿࣝࢠ࣮ࡢศᕸղ ᨵၿ≧ἣ
஧ḟඖࣆࢡࢭ᳨ࣝฟჾࡢᑟධ࡟ྥࡅ࡚
ࣅ࣮࣒ࣛ࢖ࣥࡀṇᘧ࡟✌ാࡋࡓ 2015 ᖺᗘ࠿ࡽࠊ
኱㠃✚ࡢ஧ḟඖ CCD ᳨ฟჾ࡛◳ X ⥺ᅇᢡ ᐃࢆᥦ౪ࡋ࡚ࡁࡓࠋ⣙ 10 ᖺ㛫ࡢ㐠⏝࡟క࠸ࠊ㧗࢚ࢿᅗ 28 (ୖ)BL2S1 ࠿ࡽᦙฟࡋࡓ Q315r ᳨ฟჾࣝࢠ࣮ࡢ X ⥺ࢆ᭱ᑠࡢࣀ࢖ࢬ࡛㧗㏿ ᐃ࡛ࡁࡿ㧗(ADSC)ࠊ(ୗ)BL2S1 ᳨࡛ドࡋࡓࣆࢡࢭ᳨ࣝฟჾឤ ᗘࡢ ᳨ฟ ჾ࡬ ษࡾ ᭰࠼ ࡿ᪉ 㔪ࢆ Ỵᐃ ࡋࡓ ࠋ

(DECTRIS)DECTRIS ࡜ RIGAKU ࡢ ᳨ ฟ ჾ ࡢ ᳨ ド ࡸ ࠊ
PILATUS 1M ࡢ ✌ ാ ࡟ ྥ ࡅ ࡚ ࠊ ྂ ࠸ ADSC
Q315r ᳨ฟჾࢆࣅ࣮࣒ࣛ࢖ࣥ࠿ࡽᦙฟࡋࡓ㸦ᅗ௻ᴗᑓ⏝ࣅ࣮࣒ࣛ࢖ࣥ

30㸧ࠋ⌧ᅾࡣ ADSC Q270 ࢆ㐠⏝ࡋࠊPILATUS%/6㸦ࢹࣥࢯ࣮㸧

1M ࢆ✌ാࡉࡏࡿࡓࡵ࡟ࢯࣇࢺ࢙࢘࢔ࢆ᭦᪂ࡋ࡚ձ 㐠㌿≧ἣ

࠸ࡿ࡜ࡇࢁ࡛࠶ࡿࠋ

BL2S3 ࡣ XAFSࠊXRDࠊX ⥺ CT ࢆษࡾ᭰࠼
࡚฼⏝ࡋ࡚࠸ࡿࠋᅗ 31 ࡟ 2021 ᖺᗘࡢࡑࢀࡽࡢ
฼⏝๭ྜࢆ♧ࡍࠋ࡞࠾ࠊࡑࢀࡒࢀ

ᐃ௨እ࡟⿦⨨ᩚഛࡸᢏ⾡㛤Ⓨ฼⏝ࡶྵࢇ࡛࠸ࡿࠋ⿦⨨ẖ࡟ぢࡿ࡜ X ⥺ CT ࡛ 5 ๭⛬ᗘ฼⏝ࡋ࡚࠾ࡾࠊḟ࡟
XRD ࡛ 3 ๭⛬ᗘ฼⏝ࡋ࡚࠸ࡓࠋ ᐃඖ⣲࡜ࡋ࡚
ࡣࠊXAFS ࡛ࡣࠊFeࠊNiࠊCu ࡞࡝ࡢ 3d 㑄⛣㔠ᒓࡀከ࠿ࡗࡓࠋࡲࡓ

59ᐃෆᐜ࡜ࡋ࡚ࡣࠊ㏱㐣ἲࡢᐃࡀ୺య࡛࠶ࡗࡓࡀࠊ㛤Ⓨࡋࡓ XAFS ࢖࣓࣮ ࢪࣥ ࢢࢆ ฼⏝ ࡋࡓᐃ ࡛ࡶ ከࡃ ฼⏝ ࡋࡓ ࠋ

XRD ࡛ࡣࠊ᫖ᖺᗘ࡟ᘬࡁ⥆ࡁᏳᐃⓗ࡞฼⏝ࢆ┠ᣦࡋࡓᩚഛ฼⏝ࡀ୺య࡛࠶ࡗࡓࠋX ⥺ CT ࡛ࡣࠊᐇᮦᩱࡢෆ㒊ᵓ㐀࢖࣓࣮ࢪࣥࢢ࡟ຍ࠼ࠊ㧗ศゎ⬟໬ࢆ┠ᣦࡋࡓᢏ⾡㛤Ⓨ࡛ࡢ฼⏝ࡀቑ࠼ࡓࠋ

ᅗ 30 ⮬ື཰㞟ࢹ࣮ࢱ୍ぴᅗ 29 BL2S3 ࡟࠾ࡅࡿ 2021 ᖺᗘࡢྛ⿦⨨฼⏝๭ྜᅗ 31 ཰㞟㛫㝸 タᐃ⏬㠃ղ ᨵၿ≧ἣ
ࣅ࣮࣒ࣛ࢖ࣥᶵჾ⮬ື┘どࢩࢫࢸ࣒ࡢᵓ⠏%/6㸦ࢹࣥࢯ࣮㸧ࣅ࣮࣒ࣛ࢖ࣥ⟶⌮࡛ࡣ౑⏝ࡢ๓ᚋࠊ⟶⌮㡯┠ձ 㐠㌿≧ἣ

࡟ᑐࡋ࡚᪥ᖖⅬ᳨ࢆᐇ᪋ࡋ࡚࠸ࡿࠋ
௒ᅇࠊࣅ࣮࣒ࣛ࢖ࣥ⟶⌮㡯┠ࡢ୍㒊࡛࠶ࡿ┿

BL11S3 ࡣ 2021 ᖺᗘࠊග※ࡢ㛗ᮇ೵Ṇᮇ㛫ࢆ✵ᗘ⥔ᣢ➼࡟㛵ࢃࡿ㔜せ࡞ᶵჾࢆ⮬ື┘ど࡛ࡁ฼⏝ࡋ࡚ᕤ஦ࢆ㐍ࡵࠊ࠾ࡼࡑ 1 ᖺ࠿ࡅ࡚ 2022 ᖺࡿࢩࢫࢸ࣒ࢆᵓ⠏ࡋࡓ㸦ᅗ 32㸧ࠋ

4 ᭶࡟ィ⏬㏻ࡾ❧ࡕୖࡆᕤ஦඲࡚ࢆ᏶஢ࡋ࡚࠸ࡿࠋ

ᮏࢩࢫࢸ࣒ࡣ୺࡟┿✵ᗘࠊIP 㟁ὶࠊ෭༷Ỉὶ

2021 ᖺ 4 ᭶࡟ᐇ㦂ࣁࢵࢳཬࡧࢣ࣮ࣈࣝࣛࢲ࣮ࡢ㔞࣭ ᗘࠊ࣏ࣥࣉ࣭TMP 㟁ຊࠊBe ❆㓟⣲⃰ᗘ࣭ᘓタࠊ8 ᭶࡟ࣅ࣮࣒ࣛ࢖ࣥᶵჾࡢタ⨨ࠊ11 ᭶࡟ὶ㔞ࠊ࢚࢔ᅽຊࢆ⟶⌮⪅ࡀ௵ព࡟タᐃࡋࡓ㛫㝸CT ⿦⨨ࡢタ⨨࡜࢖ࣥࢱ࣮ࣟࢵࢡࡢᵓ⠏ࠊ₃ὤࢳ

࡛㸦ᅗ 33㸧࡛ࢹ࣮ࢱྲྀᚓࡀྍ⬟࡜࡞ࡾࠊ⟶⌮つ࢙ࢵࢡࢆ᏶஢ࡋࠊ12 ᭶ᮎࡼࡾࢲ࢖ࣞࢡࢺගࡢ฼

᱁ࢆእࢀࡿ࡜㏻▱ࡍࡿᶵ⬟ࡶ௜ຍࡋࡓࠋ

⏝ࢆ㛤ጞࡋࡓࠋࡲࡓࠊ2022 ᖺ 4 ᭶࡟ࡣࠊṧࡉࢀ࡚࠸ࡓ M0ࠊM1 ࣑࣮ࣛࡢ࢖ࣥࢫࢺ࣮ࣝᕤ஦ࢆ᏶

ࡇࢀ࡟ࡼࡾࠊ᪥ᖖⅬ᳨ࡢ⡆⣲໬࡟ຍ࠼ࠊタഛ஢ࡋࠊ඲࡚ࡢᕤ஦ࢆ᏶஢ࡋࡓࠋ

≧ែࡢࢺࣞࣥࢻࢆᤊ࠼ண㜵ಖ඲࡟⧅ࡀࡿ⎔ቃࡶᅗ 34ࠊ35 ࡟ BL11S3 ᐇ㦂ࣁࢵࢳࡢእほ෗┿࡜ഛࢃࡗࡓࠋࣁ ࢵࢳ ෆࡢ ᐇ㦂 ⿦⨨ ࡢ෗ ┿ࢆ ࡑࢀ ࡒࢀ ♧ࡍ ࠋ
BL11S3 ࡣ X ⥺ CT ᑓ⏝ࡢࣅ࣮࣒ࣛ࢖ࣥ࡜ࡋ࡚ᵓ
ᡂࡉࢀ࡚࠾ࡾࠊࣁࢵࢳෆ⿦⨨ᯫྎୖ࡟ࡣࠊCT ⏝ࡢᅇ㌿ヨᩱࢫࢸ࣮ࢪࠊ᳨ฟჾࢫࢸ࣮ࢪ➼ࡀഛ࠼ࡽࢀ࡚࠸ࡿࠋ࣑ࣛࣀࢢࣛࣇ࢕

ᐃ࡟ࡶᑐᛂࡋ࡚

࠾ࡾࠊヨᩱࢫࢸ࣮ࢪ࡟ഴᩳᶵᵓࡀഛ࠼ࡽࢀ࡚࠸
ࡿࠋࣅ࣮࣒ࣛ࢖ࣥࡢගᏛ⣲Ꮚ࡜ࡋ࡚ࡣࠊࣇࣛࢵ

60

ࢡࢫྥୖࢆ≺ࡗࡓᖹ⾜໬࣑࣮ࣛ㸦M0㸧ࡸࠊ㧗࢚ࢿࣝࢠ࣮࢝ࢵࢺࢆ┠ⓗ࡜ࡋࡓ M1 ࣑࣮ࣛࢆタ⨨ࡋ࡚࠾ࡾࠊࡇࢀࡽࡢ౑࠸ศࡅ࡟ࡼࡾከᵝ࡞ᮦ㉁ࡢ
CTᐃ࡟ᑐᛂࡋࡓࣅ࣮࣒ࣛ࢖ࣥ࡜࡞ࡗ࡚࠸ࡿࠋ

2022 ᖺᗘࡣ࣑࣮ࣛࡢㄪᩚࢆ᏶஢ࡉࡏࠊࣇࣝࢫ
࣌ࢵࢡ࡛ࡢ✌ാࢆ┠ᣦࡋᩚഛࢆ㐍ࡵࡿࠋᅗ 32 BL11S3 ᐇ㦂ࣁࢵࢳእほᅗ 33 ᐇ㦂⿦⨨61฼⏝ಁ㐍฼⏝ไᗘࡢᴫせ➨5ᮇ

 ᖺ 6 ᅇࡢᐃᮇ฼⏝ເ㞟ࠊᖺ 2 ᅇࡢ㛗ᮇ฼⏝ເ㞟
࡟ຍ࠼ࠊ

฼⏝ᮇ㛫

ᐃ௦⾜࠾ࡼࡧᡂᯝබ㛤↓ൾ฼⏝஦ᴗ

2021 ᖺ 12 ᭶ 1 ᪥(Ỉ)
㹼2022 ᖺ 1 ᭶ 28 ᪥(㔠)ࢆᐇ᪋ࡋࡓࠋヲ⣽ࢆ௨ୗ࡟♧ࡍࠋ⏦㎸ᮇ㛫

2021 ᖺ 11 ᭶ 1 ᪥(᭶) 8 ᫬ 45 ศ
㹼2021 ᖺ 11 ᭶ 4 ᪥(ᮌ) ṇ༗࠙ᐃᮇ฼⏝ࠚᖺ  ᅇເ㞟

ͤ2021 ᖺ 11 ᭶ 12 ᪥(㔠)ࡼࡾࠊ㝶᫬฼⏝࡟ษࡾ

➨1ᮇ
฼⏝ᮇ㛫
⏦㎸ᮇ㛫

᭰࠼࡚ເ㞟ࢆ෌㛤
2021 ᖺ 5 ᭶ 11 ᪥(ⅆ)
㹼2021 ᖺ 5 ᭶ 28 ᪥(㔠)➨6ᮇ

2021 ᖺ 4 ᭶ 1 ᪥(ᮌ) 8 ᫬ 45 ศ฼⏝ᮇ㛫

㹼2021 ᖺ 4 ᭶ 5 ᪥(᭶) ṇ༗

2022 ᖺ 2 ᭶ 1 ᪥(ⅆ)
㹼2022 ᖺ 3 ᭶ 31 ᪥(ᮌ)

ͤ2021 ᖺ 4 ᭶ 14 ᪥(Ỉ)ࡼࡾࠊ㝶᫬฼⏝࡟ษࡾ᭰⏦㎸ᮇ㛫࠼࡚ເ㞟ࢆ෌㛤

2022 ᖺ 1 ᭶ 6 ᪥(ᮌ) 10 ᫬
㹼2022 ᖺ 1 ᭶ 7 ᪥(㔠) 17 ᫬

ͤ2022 ᖺ 1 ᭶ 18 ᪥(ⅆ)ࡼࡾࠊ㝶᫬฼⏝࡟ษࡾ᭰
➨2ᮇ
฼⏝ᮇ㛫
⏦㎸ᮇ㛫

࠼࡚ເ㞟ࢆ෌㛤
2021 ᖺ 6 ᭶ 1 ᪥(ⅆ)
㹼2021 ᖺ 7 ᭶ 30 ᪥(㔠)࠙㛗ᮇ฼⏝ࠚᖺ  ᅇເ㞟

2021 ᖺ 5 ᭶ 6 ᪥(ᮌ) 8 ᫬ 45 ศ๓ᮇ㹼2021 ᖺ 5 ᭶ 10 ᪥(᭶) ṇ༗฼⏝ᮇ㛫

2021 ᖺ 5 ᭶ 11 ᪥(ⅆ)
㹼2021 ᖺ 9 ᭶ 30 ᪥(ᮌ)

ͤ2021 ᖺ 5 ᭶ 14 ᪥(㔠)ࡼࡾࠊ㝶᫬฼⏝࡟ษࡾ᭰࠼࡚ເ㞟ࢆ෌㛤⏦㎸ᮇ㛫2021 ᖺ 4 ᭶ 1 ᪥(ᮌ) 8 ᫬ 45 ศ
㹼2021 ᖺ 4 ᭶ 5 ᪥(᭶) ṇ༗

➨3ᮇ
฼⏝ᮇ㛫
⏦㎸ᮇ㛫

2021 ᖺ 8 ᭶ 18 ᪥(Ỉ)ᚋᮇ

㹼2021 ᖺ 9 ᭶ 30 ᪥(ᮌ)฼⏝ᮇ㛫

2021 ᖺ 7 ᭶ 1 ᪥(ᮌ) 8 ᫬ 45 ศ

2021 ᖺ 10 ᭶ 1 ᪥(㔠)
㹼2022 ᖺ 3 ᭶ 31 ᪥(ᮌ)

㹼2021 ᖺ 7 ᭶ 5 ᪥(᭶) ṇ༗⏦㎸ᮇ㛫ͤ2021 ᖺ 7 ᭶ 16 ᪥(㔠)ࡼࡾࠊ㝶᫬฼⏝࡟ษࡾ᭰

2021 ᖺ 9 ᭶ 1 ᪥(Ỉ) 8 ᫬ 45 ศ
㹼2021 ᖺ 9 ᭶ 3 ᪥(㔠) ṇ༗࠼࡚ເ㞟ࢆ෌㛤࠙ᐃᮇ฼⏝ເ㞟ᮇ㛫࡟‽ࡌ࡚ཷ௜

➨4ᮇ
฼⏝ᮇ㛫
⏦㎸ᮇ㛫

ᐃ௦⾜ࠚ

2021 ᖺ 10 ᭶ 1 ᪥(㔠)
㹼2021 ᖺ 11 ᭶ 30 ᪥(ⅆ)࠙ ᖺᗘ ࠶࠸ࡕࢩࣥࢡࣟࢺࣟࣥගࢭࣥࢱ࣮

2021 ᖺ 9 ᭶ 1 ᪥(Ỉ) 8 ᫬ 45 ศᡂᯝබ㛤↓ൾ฼⏝஦ᴗࠚ

㹼2021 ᖺ 9 ᭶ 3 ᪥(㔠) ṇ༗฼⏝ᮇ㛫

2021 ᖺ 6 ᭶ 1 ᪥(ⅆ)
㹼2021 ᖺ 11 ᭶ 30 ᪥(ⅆ)

ͤ2021 ᖺ 9 ᭶ 10 ᪥(㔠)ࡼࡾࠊ㝶᫬฼⏝࡟ษࡾ᭰࠼࡚ເ㞟ࢆ෌㛤⏦㎸ᮇ㛫2021 ᖺ 3 ᭶ 22 ᪥(᭶)
㹼2021 ᖺ 4 ᭶ 27 ᪥(ⅆ)

62⏘ᴗ฼⏝ࢥ࣮ࢹ࢕ࢿ࣮ࢱࡢάື
࠙ᬑཬၨⓎ࡟㛵ࡍࡿྲྀ⤌ࠚ

1 ᖺ㛫ࢆ㏻ࡋ࡚ࠊ฼⏝┦ㄯࡢᑐᛂࡸ◊✲఍ࡢ㛤ࠐࢭ࣑ࢼ࣮➼ࡢ㛤ദ࣭㛵ಀᏛ఍➼࡬ࡢཧຍ➼ദ࡞࡝ࢆ⾜ࡗࡓࠋ᪂ᆺࢥࣟࢼ࢘࢖ࣝࢫឤᰁ⑕ࡢ
ᙳ㡪࡟ࡼࡾࠊAichiSR ࡛ࡢ఍㆟ࡣ࢜ࣥࣛ࢖ࣥࠊࢭ

᪂ᆺࢥࣟࢼ࢘࢖ࣝࢫឤᰁ⑕ࡢᙳ㡪࡟ࡼࡾࠊ࣑ࢼ࣮࡞࡝ࡢ࢖࣋ࣥࢺࡶ࢜ࣥࣛ࢖ࣥే⏝㛤ദࡀᶵ఍ࡣከࡃ࡞࠿ࡗࡓࡀࠊྍ⬟࡞⠊ᅖ࡛άືࢆ

୍⯡໬ࡋࡘࡘ࠶ࡿࠋ

⾜ࡗࡓࠋ࣭2021 ᖺᗘ➨ 1 ᅇ AichiSR ࢩࣥࢡࣟࢺࣟࣥග

࠙฼⏝ಁ㐍࡟㛵ࡍࡿྲྀ⤌ࠚ⏘ᴗ฼⏝ࢭ࣑ࢼ࣮㸦࢜ࣥࣛ࢖ࣥే⏝㸧(2/28)‫ۑ‬฼⏝┦ㄯࠊᢏ⾡ᣦᑟཬࡧಶูゼၥࡢᐇ᪋ࢆ㛤ദ⏘ᴗ฼⏝ࢥ࣮ࢹ࢕ࢿ࣮ࢱࡸ࢔ࢻࣂ࢖ࢨ࣮࡟
‫ۑ‬ᒎ♧఍࡬ࡢฟᒎཬࡧぢᏛ⪅ࡢཷධࢀࡼࡿ฼⏝┦ㄯࠊ௻ᴗ➼࡬ࡢά⏝᪉ἲࡢᥦ᱌➼
ࢆᐇ᪋ࠋ

㸦ᒎ♧఍㸧

࣭฼⏝┦ㄯ➼㸦㟁ヰ┦ㄯࠊ࣓࣮ࣝ➼ྵࡴ㸧࣭࣓ࢵࢭࢼࢦࣖ 2021㸦࢜ࣥࣛ࢖ࣥే⏝㸧(11/1㹼13)
࣭➨ 35 ᅇ᪥ᮏᨺᑕගᏛ఍ᖺ఍࣭ᨺᑕග⛉Ꮫྜ‫ ۑ‬฼⏝⪅◊✲఍➼ࡢ㛤ദྠࢩ࣏ࣥࢪ࣒࢘㸦࢜ࣥࣛ࢖ࣥࡢࡳ㸧(1/7㹼9)ᮍ฼⏝௻ᴗ➼࡟ᑐࡋࠊධ㛛ㅮ⩦఍ࡸ XAFS

(ぢᏛ⪅) 126 ྡ 㹙2020 ᖺᗘ 147 ྡ㹛➼ࡢ ᐃᡭἲࡈ࡜࡟ィ య㦂ࢆᐇ᪋ࠋ࣭X ⥺ᅇᢡࠊX ⥺ᩓ஘ධ㛛ㅮ⩦఍㸦11/15㸧ࠊᐃᐇ⩦(11/16) 㸦┴୺ദࠊAichiSR ඹദ㸧࣭EXAFS ゎᯒㅮ⩦఍㸦9/3㸧
ゎᯒࢯࣇࢺࢆ⏝࠸ࡓ EXAFS ࡢゎᯒ᪉ἲࡢ⤂௓ 㸦ྡ኱୺ദࠊAichiSR࣭┴ඹദ㸧࣭ᐇᆅ◊ಟX ⥺ⷧ⭷࣭⾲㠃ᅇᢡᩓ஘(11/25, 2/25㸧ࠊ㌾ X ⥺ XAFS(7/28)ࠊ
◳ X ⥺ XAFS(7/26, 9/1, 9/14, 10/21)⢊ᮎ X ⥺ᅇᢡ(12/7, 12/14, 3/3)ࠊ
ᗈゅ࣭ᑠゅᩓ஘(3/17)
㸦┴୺ദࠊAichiSR ඹദ㸧‫ࠕࡅྥ࣮ࢨ࣮ࣘۑ‬ᨺᑕ⥺ᴗົᚑ஦⪅ᩍ⫱カ⦎ࠖㅮ⩦఍ࡢᐇ᪋᪂つᩍ⫱(3 ᫬㛫)ࠊ෌ᩍ⫱(1.5 ᫬㛫)ࡢㅮ⩦఍ࢆẖ᭶ᐃᮇⓗ࡟↓ᩱ࡛ᐇ᪋ࠋ
࣭㛤ദᅇᩘ㸸24 ᅇ࣭ཷㅮ⪅㸸397 ྡ[2020 ᖺᗘ 24 ᅇ 326 ྡ]63฼⏝⪅࠿ࡽࡢせᮃ࡬ࡢᑐᛂ
ᖺ㛫ࢆ㏻ࡌ࡚ᢏ⾡ⓗ࡞せᮃࢆᢎࡗ࡚࠾ࡾࠊලయⓗ࡟ᑐᛂࡋࡓ 37 ௳࡟ࡘ࠸࡚௨ୗ࡟ヲ⣽ࢆ♧ࡍࠋBL ྡᨵၿෆᐜ㸦2021㸧
1

BL1N2

BL5S1

BL5S2

2
3
4
1
2
3
4
5
6
1
2
3
4
5
6
1
2

BL6N1

3
4
5

BL7U

BL8S1

BL8S3

1
2
3
4
5
1
2
3
1
2
3
4
5

BL11S21
2
3

࣮࢜ࢪ࢙㟁Ꮚ཰㔞ἲ XAFS ᐃࢩࢫࢸ࣒ࡢ㛤Ⓨ࡟ࡼࡿࠊ᪂ ᐃᡭἲࡢᐇ⿦
ᑓ⏝ࢢࣛࣇ⾲♧ࢯࣇࢺ࢙࢘࢔ࡢ㛤Ⓨ࡟ࡼࡿࠊ࣮ࣘࢨ࣮ࡢ XAFS ゎᯒࡢᐜ᫆໬࡜฼౽
ᛶྥୖࢧࣥࣉࣝ఩⨨☜ㄆ⏝ࢩࢫࢸ࣒ࡢ㛤Ⓨ࡟ࡼࡿࠊ ᐃ఩⨨ࡢྍど໬࡜⢭ᗘྥୖჾල࣭ヨᩱ⛣㏦⏝ࢶ࣮ࣝ࣡ࢦࣥࡢᩚഛ࡟ࡼࡿࠊBL࣭‽ഛᐊ㛫ࡢ㐃ᦠᛶࡢྥୖ
ᐃ⏝ࢯࣇࢺ XafsM2 ࡢᨵⰋཧ↷ヨᩱࡢ㏣ຍ㸦FeࠊNiࠊCu ⣔ヨᩱ㸧㧗ḟග㝖ཤ࣑࣮ࣛᑟධ࡟ࡼࡿప࢚ࢿࣝࢠ࣮㡿ᇦ ᐃࡢ㧗ᗘ໬
7chSDD ࡢヨᩱ㛫㊥㞳ࡢ㐲㝸᧯సࢩࢫࢸ࣒ᑟධ࡟ࡼࡿ㊥㞳ㄪᩚࡢ⡆᫆໬ᶵჾ㏻ಙ⤒㊰ࡢᨵⰋ࡟ࡼࡿࣁࢵࢳෆࡢసᴗᛶྥୖ
DXM ⏝ࢳ࣮ࣛࡢቑタ࡟ࡼࡿ෭༷Ỉὶ㔞ࡢᏳᐃ໬
ヨᩱᦙ㏦ࠊヨᩱ఩⨨ㄪᩚࡢྛࣉࣟࢢ࣒ࣛぢ┤ࡋ࡟ࡼࡿ ᐃຠ⋡ࡢྥୖ
PDF ゎᯒࢯࣇࢺ㉎ධ࡟ࡼࡿゎᯒຠ⋡ࡢྥୖ᳨ฟჾࢧ࣮ࣂ࣮ᨵၿ࡟ࡼࡿ ᐃࡢᏳᐃ໬
Huber ᅇᢡィᨵၿ࡟ࡼࡿ ᐃࡢᏳᐃ໬
ヨᩱࢫࢸ࣮ࢪࡢ㸯㍈㏣ຍ࡟ࡼࡿ ᐃຠ⋡ࡢྥୖ
ヨᩱᅇ㌿ࢫࢸ࣮ࢪ㧗㏿໬࡟ࡼࡿ ᐃຠ⋡ࡢྥୖ┿✵ ᐃࢳ࢙ࣥࣂ࣮࡬ࡢ༙ᑟయ᳨ฟჾᑟධ࡟ࡼࡿ┿✵ୗ࡛ࡢ㒊ศ⺯ග཰㔞 XAFS ࡬ࡢᑐᛂヨᩱ఩⨨ㄪᩚᶵᵓࡢ࣮ࣔࢱ࣮㥑ື໬࡟ࡼࡿ኱Ẽᅽ XAFS ᐃࡢ㐲㝸ไᚚ໬ཬࡧ ᐃຠ⋡୪ࡧ࡟⢭ᗘࡢྥୖ
ヨᩱᑟධᶵᵓࡢᨵⰋ࡟ࡼࡿ኱Ẽᅽ XAFS ᐃ᫬ࡢヨᩱ஺᥮ᚅࡕ᫬㛫ࡢ▷⦰໬㸦30 ศ
Ѝ15 ศ㸧᪂つ㟁ὶྲྀฟᶵᵓࡢᑟධ࡟ࡼࡿ኱Ẽᅽୗ࡛ࡢ኱Ẽ㠀ᭀ㟢㌿᥮㟁Ꮚ཰㔞 XAFS ࡬ࡢᑐᛂ㜵᣺ࢲࣥࣃᑟධ࡟ࡼࡿග㔞ࣔࢽࢱ⏝࣓ࢵࢩࣗ࡜ᖖタᶆ‽ヨᩱࡢヨᩱ㟁ὶィ ᫬࡟ΰධࡍࡿ᣺ືࣀ࢖ࢬࡢపῶ
6 ㍈ᅇ㌿ヨᩱࢫࢸ࣮ࢪᑟධ࡟ࡼࡿ ᐃ㓄⨨ࡢᣑ኱ヨᩱ෭༷ࢡࣛ࢖࢜ࢫࢱࢵࢺ᭦᪂࡟ࡼࡿ෭༷㏿ᗘࡢᨵၿヨᩱ࣐ࢽࣆ࣮ࣗࢱ᭦᪂࡟ࡼࡿヨᩱ఩⨨ࡢᏳᐃ໬࣭ప᣺ື໬
ヨᩱࢫࢸ࣮ࢪ 2 ẁ໬࡟ࡼࡿ ᐃຠ⋡ࡢᨵၿࣅ࣮࣒ࣛ࢖ࣥගᏛ࢔ࣛ࢖࣓ࣥࢺ෌ㄪᩚ࡟ࡼࡿࣅ࣮࣒ࢫ࣏ࢵࢺࢧ࢖ࢬࡢᨵၿ
ᅇᢡゅୖ㝈ࢆ 138r࠿ࡽ 160r࡬ᣑᙇ
ヨᩱほᐹ࣓࢝ࣛࡢ᣺ືᑐ⟇ゎᯒࢧ࣏࣮ࢺࡢࡓࡵࡢ⤖ᬗ┦ࢹ࣮ࢱ࣮࣋ࢫࡢ᭦᪂PILATUS ࢆ฼⏝ࡋࡓ㐃⥆ ᐃࢆྍ⬟࡟ࡍࡿࡓࡵࠊ᪂つ Z ࢫࢸ࣮ࢪࢆᑟධ
㧗㹯㡿ᇦࡢᗈゅ X ⥺ᅇᢡ ᐃࢆྍ⬟ࡍࡿࡓࡵࠊ᪂つࡢ┿✵❆ࢆసᡂᏳᐃࡋࡓ ᐃࢆྍ⬟࡟ࡍࡿࡓࡵࠊHUB ࡢ࢔ࢵࣉࢹ࣮ࢺ࡟ࡼࡾࢹ࣮ࢱ㌿㏦ࢆ㧗㏿໬࣓࢝ࣛ㛗ኚ᭦࡟࠿࠿ࡿ᫬㛫ࢆ▷⦰ࡋࠊ࣐ࢩࣥࢱ࢖࣒ෆ࡛ࡢ㝵ᒙᵓ㐀ホ౯ࢆྍ⬟࡟ࡍࡿࡓࡵࠊ᪂つ┿✵࣏ࣥࣉࢆ┿✵ࣛ࢖ࣥ࡬㏣ຍ
ࣂࢵࢡࢢࣛࣥࢻࡢపῶࡋࡓ ᐃࢆྍ⬟࡟ࡍࡿࡓࡵࠊࣇ࢛ࢺࢲ࢖࣮࢜ࢻධࡾࣅ࣮࣒ࢫ
ࢺࢵࣃ࣮ࢆᨵ㐀ࣉ࣮࣑࣮ࣞࣥࣛᑟධ࡟ࡼࡿ㸰ḟඖ XAFS ࠾ࡼࡧ CT XAFS ࡬ࡢᑐᛂ෭༷ຍ⇕ࢫࢸ࣮ࢪ Linkam ᑟධ࡟ࡼࡿ ㄪᡭẁࡢከᵝ໬㌿᥮㟁Ꮚ཰㔞 ᐃࢭࣝࡢᨵⰋ࡟ࡼࡿ ᐃࡢຠ⋡໬64ᨺᑕ⥺ᴗົᚑ஦⪅ᩍ⫱カ⦎ㅮ⩦ෆᐜ㸸᪂つᩍ⫱ࡣձ㹼ճࠊ෌ᩍ⫱ࡣճࡢࡳᨺᑕ⥺㞀ᐖ㜵Ṇἲ࡛ࡣࠊᨺᑕ⥺ྲྀᢅ஦ᴗ⪅࡟ձᑐࡋࠊᨺᑕ⥺ᴗົᚑ஦⪅࡬ࡢ᪂つᩍ⫱࡜ᖺ㸯ᅇᨺᑕ⥺㞀ᐖࡢ㜵Ṇ࡟㛵ࡍࡿἲ௧ཬࡧᨺᑕ⥺㞀ᐖண㜵つ⛬㸦60 ศ㸧ࡢ෌ᩍ⫱ࢆ⩏ົ௜ࡅ࡚࠸ࡿࠋ⛉Ꮫᢏ⾡஺ὶ㈈ᅋ
࡛ࡣࠊ2012 ᖺ 10 ᭶࠿ࡽࠊAichiSR ฼⏝⪅ࢆᑐ㇟ղᨺᑕ⥺ࡢேయ࡟୚࠼ࡿᙳ㡪㸦30 ศ㸧࡟ࠊྠἲ࡟ᑐᛂࡋࡓᨺᑕ⥺ᴗົᚑ஦⪅ᩍ⫱カ⦎ճᨺᑕ⥺ྠ఩ඖ⣲➼ཪࡣᨺᑕ⥺Ⓨ⏕⿦⨨ࡢᏳ඲ྲྀᢅ࠸㸦᪂つ࣭90 ศ㸧ㅮ⩦఍ࢆᐃᮇⓗ࡟㛤ദࡋ࡚࠸ࡿࠋ

ࡲࡓࡣ

2021 ᖺᗘࡢᨺᑕ⥺ᴗົᚑ஦⪅ᩍ⫱カ⦎ㅮ⩦఍ࡢ㛤ദ᪥࠾ࡼࡧཷㅮேᩘࡢ୍ぴࡣୗ⾲ࡢ࡜࠾ࡾࠋ

ᨺᑕ⥺ྠ఩ඖ⣲➼ཪࡣᨺᑕ⥺Ⓨ⏕⿦⨨ࡢᏳ඲ྲྀᢅ࠸࣭ἲ௧࣭ᨺᑕ⥺ࡢேయ࡟୚࠼ࡿᙳ
㡪㸦෌ᩍ⫱࣭90 ศ㸧఍ሙ㸸࠶࠸ࡕࢩࣥࢡࣟࢺࣟࣥගࢭࣥࢱ࣮
2 㝵఍㆟ᐊ㸦࢜ࣥࣛ࢖ࣥే⏝㸧㸦༢఩㸸ྡ㸧

ᐇ᪋᪥
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24



2021 ᖺ

4 ᭶ 14 ᪥
4 ᭶ 28 ᪥
5 ᭶ 12 ᪥
5 ᭶ 26 ᪥
6᭶ 9᪥
6 ᭶ 23 ᪥7᭶ 7᪥
7 ᭶ 21 ᪥8᭶ 4᪥
8 ᭶ 18 ᪥9᭶ 8᪥
9 ᭶ 22 ᪥
10 ᭶ 13 ᪥
10 ᭶ 27 ᪥
11 ᭶ 10 ᪥
11 ᭶ 25 ᪥
12 ᭶ 8 ᪥
12 ᭶ 22 ᪥
2022 ᖺ
1 ᭶ 12 ᪥1 ᭶ 26 ᪥2᭶ 9᪥
2 ᭶ 22 ᪥3᭶ 9᪥
3 ᭶ 23 ᪥
ྜィ

᪂つᩍ⫱
࢜ࣥࣛ࢖ࣥ
ᑐ㠃
2
14
8
6
6
2
3
7
4
4
4
8
3
2
2
10
2
6
0
6
4
11
0
6
1
13
0
7
0
10
0
4
0
6
0
5
0
3
0
2
0
3
0
4
0
4
0
7
39
150



65

෌ᩍ⫱
ᑐ㠃
4
2
3
3
2
4
1
2
0
2
1
0
1
1
0
1
1
0
1
0
1
1
2
1
34

࢜ࣥࣛ࢖ࣥ

3
10
16
8
9
8
12
6
6
8
6
9
6
2
3
2
4
7
3
3
6
9
15
13
174

ྜィ
23
26
27
21
19
24
18
20
14
16
22
15
21
10
13
7
11
12
7
5
10
14
21
21
397



ぢᏛ⪅ᩘ
2021 ᖺᗘࡢ AichiSR ぢᏛ⪅ᩘࡣୗ⾲ࡢ࡜࠾ࡾࠋ
㸦༢఩㸸ྡ㸧
ᡤᒓෆヂேᩘ2021 ᖺ

2022 ᖺ

ྜィ

୍⯡

௻ᴗ

኱Ꮫ

⾜ᨻ

㺚㺻㺖㺹
㛵ಀ

ࡑࡢ௚

4᭶

2

2

0

0

0

0

0

5᭶

10

1

1

1

7

0

0

6᭶

19

0

19

0

0

0

0

7᭶

8

0

5

0

3

0

0

8᭶

22

8

1

3

8

2

0

9᭶

10

0

7

3

0

0

0

10 ᭶

13

0

6

2

5

0

0

11 ᭶

14

0

4

0

10

0

0

12 ᭶

4

0

2

0

2

0

0

1᭶

5

0

1

1

3

0

0

2᭶

6

0

3

3

0

0

0

3᭶

13

0

0

10

3

0

0

126

11

49

23

41

2

0

66

㸬◊✲఍࣭ࢭ࣑ࢼ࣮

67



◊✲఍࣭ࢭ࣑ࢼ࣮
᪂ᆺࢥࣟࢼ࢘࢖ࣝࢫឤᰁ⑕ࡢᙳ㡪࡟ࡼࡾᶵ఍ࡣከࡃ࡞࠿ࡗࡓࡀࠊྍ⬟࡞⠊ᅖ࡛άືࢆ⾜ࡗࡓࠋ2021 ᖺᗘ࡟㛤ദࡉࢀࡓ◊✲఍࣭ࢭ࣑ࢼ࣮ࡣ௨ୗࡢ࡜࠾ࡾࠋ
 ㅮ⩦఍࣭◊✲఍ࢱ ࢖ ࢺ ࣝࢩࣥࢡࣟࢺࣟࣥග฼⏝⪅◊✲఍ ࢩࣥࢡࣟࢺࣟࣥගィᐇ

2021 ᖺ 11 ᭶ 15 ᪥(᭶) 13:30㹼16:00㸸ㅮ⩏

᪋

᪥

ධ㛛ㅮ⩦఍

2021 ᖺ 11 ᭶ 16 ᪥(ⅆ) 10:00㹼17:00㸸ᐇᆅ◊ಟ఍ሙ࢜ࣥࣛ࢖ࣥ㛤ദෆᐜ

11 ᭶ 15 ᪥(᭶)
xX ⥺ᅇᢡධ㛛࠙X ⥺ᅇᢡࡢᇶ♏࡜⢊ᮎ X ⥺ᵓ㐀ゎᯒࠚㅮᖌ㸸㇏⏣ᕤᴗ኱Ꮫࢫ࣐࣮ࢺ࢚ࢿࣝࢠ࣮ᢏ⾡◊✲ࢭࣥࢱ࣮ᩍᤵ ➉ෆ ᜏ༤x

X ⥺ᩓ஘ධ㛛࠙ᑠゅ X ⥺ᩓ஘ᐃ࡟ࡼࡿᵓ㐀ゎᯒࠚㅮᖌ㸸㇏⏣ᕤᴗ኱Ꮫ ྡ㄃ᩍᤵ ⏣௦ Ꮥ஧x

AichiSR ᅇᢡ࣭ᩓ஘ࣅ࣮࣒ࣛ࢖ࣥࡢ᭱᪂᝟ሗ

11 ᭶ 16 ᪥(ⅆ)
xࣅ࣮࣒ࣛ࢖ࣥࡢぢᏛ࡜⤂௓xᐃ࣭ゎᯒཧຍ⪅ࡢᣢ㎸ヨᩱཪࡣࢹࣔヨᩱࢆ⏝࠸࡚ࠊX ⥺ᅇᢡཪࡣ X ⥺ᑠゅᩓ஘ᐃࢆᐇ᪋ᐃࡋࡓࢹ࣮ࢱࢆ⏝࠸࡚ゎᯒࢆ⾜࠸ࠊࢹ࣮ࢱࡢぢ᪉➼ࡢㄝ᫂
ཧ

ຍ

⪅

145 ྡ

ࢱ ࢖ ࢺ ࣝ2021 ᖺᗘ EXAFS ゎᯒㅮ⩦఍ᐇ᪥

2021 ᖺ 9 ᭶ 13 ᪥(᭶) 10:00 㹼 17:30

఍ሙ࢜ࣥࣛ࢖ࣥ㛤ദෆᐜ

࠙EXAFS ධ㛛ࠚ᪋x

EXAFS ࡢཎ⌮࠿ࡽゎᯒ᪉ἲࡢ⪃࠼᪉ㅮᖌ㸸ྡྂᒇ኱Ꮫࢩࣥࢡࣟࢺࣟࣥග◊✲ࢭࣥࢱ࣮ ᩍᤵ ⏣ῲ㞞ኵ࠙ゎᯒࢯࣇࢺ Athena ࡜ Artemis ࢆ⏝࠸ࡓ EXAFS ࡢゎᯒ᪉ἲࡢ⤂௓ࠚ

ཧ

ຍ

⪅

x

Athena ࢆ⏝࠸ࡓ EXAFS ゎᯒࡢ๓‽ഛ㸦ࣂࢵࢡࢢࣛ࢘ࣥࢻࡢỴᐃ➼㸧ࡢ᪉ἲx

Artemis ࢆ⏝࠸ࡓ EXAFS ࢫ࣌ࢡࢺࣝࡢゎᯒ᪉ἲ

34 ྡ



68

ࢩࣥࢡࣟࢺࣟࣥග฼⏝⪅◊✲఍࠙ᐇᆅ◊ಟࠚ࠶࠸ࡕ⏘ᴗ⛉Ꮫᢏ⾡⥲ྜࢭࣥࢱ࣮࡜ඹദ࡛ࠊᐇ⩦ᙧᘧࡢᐇᆅ◊ಟࢆ㛤ദࡋࡓࠋ
ᐇ᪋᪥

ෆ ᐜ

➨㸯ᅇ

7 ᭶ 26 ᪥ ◳ X ⥺ XAFS㸦㏱㐣ἲ௨እ㸧
㸦BL5S1㸧2ྡ

➨㸰ᅇ

7 ᭶ 28 ᪥ ㌾ X ⥺ XAFS㸦BL6N1㸧

4ྡ

➨㸱ᅇ

9 ᭶ 01 ᪥ ◳ X ⥺ XAFS㸦㏱㐣ἲ㸧
㸦BL5S1㸧2ྡ

➨㸲ᅇ

9 ᭶ 14 ᪥ ◳ X ⥺ XAFS㸦㏱㐣ἲ㸧
㸦BL11S2㸧

1ྡ➨㸳ᅇ

10 ᭶ 21 ᪥ ◳ X ⥺ XAFS㸦㏱㐣ἲ㸧
㸦BL5S1㸧1ྡ➨㸴ᅇ

11 ᭶ 25 ᪥ X ⥺ⷧ⭷࣭⾲㠃ᅇᯒᩓ஘㸦BL8S1㸧

1ྡ

➨㸵ᅇ

12 ᭶ 07 ᪥ ⢊ᮎ X ⥺ᅇᯒ㸦BL5S2㸧

3ྡ

➨㸶ᅇ

12 ᭶ 14 ᪥ ⢊ᮎ X ⥺ᅇᯒ㸦BL5S2㸧

1ྡ

➨㸷ᅇ

2 ᭶ 25 ᪥ X ⥺ⷧ⭷࣭⾲㠃ᅇᯒᩓ஘㸦BL8S1㸧

1ྡ

➨ 10 ᅇ

3 ᭶ 03 ᪥ ⢊ᮎ X ⥺ᅇᯒ㸦BL5S2㸧

1ྡ

➨ 11 ᅇ

3 ᭶ 17 ᪥ ᗈゅ࣭ᑠゅᩓ஘㸦BL8S3㸧

2ྡ

ཧຍ⪅ྜィ
୺

19 ྡ

ദ ࠶࠸ࡕ⏘ᴗ⛉Ꮫᢏ⾡⥲ྜࢭࣥࢱ࣮ࠊ࠶࠸ࡕࢩࣥࢡࣟࢺࣟࣥගࢭࣥࢱ࣮

ࢭ࣑ࢼ࣮ࢱ ࢖ ࢺ ࣝ2021 ᖺᗘ➨ 1 ᅇ AichiSR ࢩࣥࢡࣟࢺࣟࣥග⏘ᴗ฼⏝ࢭ࣑ࢼ࣮ᐇ᪥2022 ᖺ 2 ᭶ 28 ᪥(᭶)ሙ࢘࢖ࣥࢡ࠶࠸ࡕࠊ࢜ࣥࣛ࢖ࣥే⏝

఍

᪋

࠙ㅮ₇ࠚ

ෆ

ཧຍ⪅ᩘ

ᐜ

x

XAFS ฼⏝ࡢᖜࢆᗈࡆࡿ 2D/3D XAFSxSPring-8 ࡟࠾ࡅࡿ X ⥺࢖࣓࣮ࢪࣥࢢᢏ⾡x◳ X ⥺ග㟁Ꮚศගἲ(HAXPES)x㟁Ꮚᮦᩱ⏝⇕◳໬ᛶᶞ⬡ᮦᩱ㸭㔠ᒓ⏺㠃ࡢゎᯒxSPring-8 ฼⏝ࡢ฼⏝᪉ἲ ➼ᐃᢏ⾡ࡢ AichiSR ࡛ࡢᒎ㛤ᐃᢏ⾡ࡢ≉ᚩ࡜ά⏝஦౛ࡢ⤂௓ཧ ຍ ⪅ ᩘ145 ྡ㸦࢜ࣥࣛ࢖ࣥྵࡴ㸧୺(බ㈈)⛉Ꮫᢏ⾡஺ὶ㈈ᅋࠊ(බ㈈)㧗㍤ᗘග⛉Ꮫ◊✲ࢭࣥࢱ࣮

ദ



69

➨  ᅇ࠶࠸ࡕࢩࣥࢡࣟࢺࣟࣥගࢭࣥࢱ࣮஦ᴗᡂᯝⓎ⾲఍
2021 ᖺᗘᡂᯝබ㛤↓ൾ฼⏝஦ᴗ࡜ࡋ࡚᥇ᢥࡋࡓ 16 ㄢ㢟ࡢᡂᯝⓎ⾲఍ࢆ㛤ദࡋࡓࠋᙜึࡢ㛤ദணᐃࡣ
2022 ᖺ 3 ᭶࡛࠶ࡗࡓࡀࠊ᪂ᆺࢥࣟࢼ࢘࢖ࣝࢫឤᰁ⑕ࡢ♫఍ⓗ≧ἣࢆ㚷ࡳࠊ2022 ᖺ 4 ᭶࡟㛤ദࡋࡓࠋࢱ ࢖ ࢺ ࣝ➨ 10 ᅇ࠶࠸ࡕࢩࣥࢡࣟࢺࣟࣥගࢭࣥࢱ࣮஦ᴗᡂᯝⓎ⾲఍ᐇ᪥

2022 ᖺ 4 ᭶ 26 ᪥( 火 ) 10:30㹼16:40

఍ሙ࠶࠸ࡕ⏘ᴗ⛉Ꮫᢏ⾡⥲ྜࢭࣥࢱ࣮ ㅮ⩦఍ᐊࠊ࢜ࣥࣛ࢖ࣥే⏝ෆᐜ࠙༗๓ࡢ㒊ࠚ10:30㹼11:55㸦10:30㹼10:40 ᣵᣜ➼㸧᪋ࠕ༢ศᏊ᳨ฟࢆྍ⬟࡜ࡍࡿከᒙࢢࣛࣇ࢙ࣥࣂ࢖࢜ࢭࣥࢧ࣮ࡢ㛤Ⓨࠖᮾὒ኱Ꮫ  ᰿ᓊ Ⰻኴࠕ⤯⦕ᛶ᭷ᶵᮦᩱࡢ NEXAFSᐃࢆྍ⬟࡟ࡍࡿ㔠ᒓ⵨╔᮲௳ࡢ᳨ウࠖ㹈㹑㹐ᰴᘧ఍♫  ㇏⏣ ⏤⾰ࠕX ⥺ᅇᢡ࡟ࡼࡿ㉸㧗⢭⣽ࢫࢡ࣮ࣜࣥ༳ๅ⏝ࡢࢫࢸࣥࣞࢫ࣓ࢵࢩࣗࡢ◊✲㛤Ⓨࠖ              ࢔ࢧࢲ࣓ࢵࢩࣗᰴᘧ఍♫  㟷ᮌ ┿⌮ࠕ඲ᅛయ㟁ụࡢ XAFS ゎᯒࠖ           ᰴᘧ఍♫᪥⏘࢔࣮ࢡ  ఀ⸨ Ꮥ᠇
ࠕSiO2/Si ࡢ GI-PDF㸦grazing-incidence pair distribution functions㸧࡟ࡼࡿᒁᡤᵓ㐀ゎᯒࠖ                       ᰴᘧ఍♫᪥⏘࢔࣮ࢡ  Ᏽ ဴᪿ࠙༗ᚋࡢ㒊ࠚ13:30㹼16:40
ࠕ෭㛫㘫㐀ࡢ₶⁥⿕⭷ᙧᡂࣉࣟࢭࢫ࡟࠾ࡅࡿ࢙࢘ࢵࢺࣈࣛࢫࢺ࡟ࡼࡿ⣲ᮦ๓ฎ⌮ࡢຠᯝ᳨ドࠖ                        ࣐ࢥ࣮ᰴᘧ఍♫  ᶲ ࿴ᑑࠕX ⥺※ࢆ┦⿵฼⏝ࡋࡓ㟁Ꮚศගᐃ࡟ࡼࡿ㧗ศᏊᮦᩱࡢ⾲㠃໬Ꮫᵓ㐀࡟㛵ࡍࡿ῝ࡉ౫Ꮡᛶホ౯ࠖ                     ᰴᘧ఍♫࣓ࢽࢥࣥ  ఀ⸨ ᜨ฼
ࠕ㌾ X ⥺ XAFS ࢫ࣌ࢡࢺࣝ࠿ࡽࡢ≀ᛶணࠖ   ᰴᘧ఍♫ࢹࣥࢯ࣮  ᳃ཱྀ ୐℩ࠕX ⥺࢖࣓࣮ࢪࣥࢢ࡟ࡼࡿཱྀ⭍ෆᔂቯ㘄㸦OD 㘄㸧ࡢᑟỈ㐣⛬ཬࡧᔂቯᣲືほᐹࠖ                 ᰴᘧ఍♫ࢲ࢖ࢭࣝ  㧗ᑿ ┤ᶞࠕ㌾ X ⥺ XAFS ୪ࡧ࡟ග㟁Ꮚศගἲ࡟ࡼࡿ ALPS ỿẊ⣔ᗫᲠ≀ࡢࣜࣥ㓟ሷᅛ໬యᵓᡂඖ⣲ࡢ㟁Ꮚ≧ែゎᯒࠖ            ᮾிᕤᴗ኱Ꮫ  ୰℩ ṇᙪࠕ⺯ග XAFSᐃ࡟࠾ࡅࡿ᫬㛫✵㛫ศゎ⬟ࡢྥୖᡭἲࡢ㛤Ⓨࠖᰴᘧ఍♫ SOKEN  㧗஭ ᬛ᫂ࠕ⤖ᬗᵓ㐀ゎᯒ࡟ࡼࡿࣉࣟࢫࢱࢢࣛࢪࣥ D2 ྜᡂ㓝⣲㜼ᐖ๣ࡢࢫࢡ࣮ࣜࢽࣥࢢࠖ               ᰴᘧ఍♫୸࿴ᰤ㣴㣗ရ  ఀ୰ ᾈ἞ࠕ⢊ᮎ෬㔠ἲ࡟ࡼࡾస〇ࡋࡓ FeAl ᇶ ODS ↝⤖యࡢࢩࣥࢡࣟࢺࣟࣥග XRD ゎᯒࠖ              ㇏⮧⇕ฎ⌮ᕤᴗᰴᘧ఍♫  ᶫ஭ ගᘺࠕ⢊య Materials Genome ࣉࣟࢭࢫ࡟ࡼࡿ඲ᅛయ㟁ụ⏝ᅛయ㟁ゎ㉁ࡢ᥈⣴ࠖᮾி⌮⛉኱Ꮫ  ⸨ᮏ ᠇ḟ㑻࠙࠶࠸ࡕ⏘ᴗ⛉Ꮫᢏ⾡⥲ྜࢭࣥࢱ࣮ᡂᯝⓎ⾲ࠚࠕ⢊ᮎ⢏Ꮚᚄࡀ XAFS ࢫ࣌ࢡࢺࣝࡢᐃ㔞ᛶ࡟ཬࡰࡍᙳ㡪ࠖ࠶࠸ࡕ⏘ᴗ⛉Ꮫᢏ⾡⥲ྜࢭࣥࢱ࣮  㔝ᮏ ㇏࿴ࠖࠕ࠶࠸ࡕ㹑㹐࡟࠾ࡅࡿ㹁㹒ᢏ⾡ࡢ㛤Ⓨ㸦▱ࡢᣐⅬ㔜Ⅼ◊✲ࣉࣟࢪ࢙ࢡࢺϪᮇᡂᯝ㸧          ࠶࠸ࡕ⏘ᴗ⛉Ꮫᢏ⾡⥲ྜࢭࣥࢱ࣮  ᮡᒣ ಙஅ

70

ཧ

ຍ

⪅

186 ྡ㸦࢜ࣥࣛ࢖ࣥྵࡴ㸧୺ദឡ▱┴ࠊ(බ㈈)⛉Ꮫᢏ⾡஺ὶ㈈ᅋ

༠㈶ྡྂᒇ኱Ꮫࢩࣥࢡࣟࢺࣟࣥග◊✲ࢭࣥࢱ࣮ྡྂᒇ኱Ꮫࢩࣥࢡࣟࢺࣟࣥග◊✲ࢭࣥࢱ࣮ࢩ࣏ࣥࢪ࣒࢘ࢱ ࢖ ࢺ ࣝ➨ 10 ᅇྡྂᒇ኱Ꮫࢩࣥࢡࣟࢺࣟࣥග◊✲ࢭࣥࢱ࣮ࢩ࣏ࣥࢪ࣒࢘

ᐇ᪥2022 ᖺ 1 ᭶ 17 ᪥(᭶) 13:00㹼18:00

఍ሙ࢜ࣥࣛ࢖ࣥ㛤ദෆᐜ

BL2S1㸸ྡ኱ࣅ࣮࣒ࣛ࢖ࣥ࡟࠾ࡅࡿ㧗ᅽࢱࣥࣃࢡ㉁⤖ᬗᵓ㐀ゎᯒ᪋ỌỤ ᓠᖾ  ྡྂᒇ኱Ꮫࢩࣥࢡࣟࢺࣟࣥග◊✲ࢭࣥࢱ࣮
BL5S2㸸㉸㧗ᅽୗ࡟࠾ࡅࡿ᪂≀㉁ྜᡂ࡜ᨺᑕග X ⥺ᵓ㐀ゎᯒబࠎᮌ ᣅஓ,୹⩚ ೺,㛗㇂ᕝ ṇ  ྡྂᒇ኱Ꮫ኱Ꮫ㝔ᕤᏛ◊✲⛉BL8S1㸸㧗ศᏊቃ⏺⭷ࡢ₶⁥࣓࢝ࢽࢬ࣒ゎ᫂࡟ྥࡅࡓࢩࣥࢡࣟࢺࣟࣥගィࡢᛂ⏝ఀ⸨ ఙኴ㑻 ྡྂᒇ኱Ꮫ኱Ꮫ㝔ᕤᏛ◊✲⛉, JST ࡉࡁࡀࡅ◊✲ဨ
BL8S2㸸BL8S2 ࡟ᵓ⠏ࡋࡓ X ⥺ᬯど㔝ἲ࡟ᇶ࡙ࡃᒅᢡࢥࣥࢺࣛࢫࢺ CT ᧜ᙳࢩࢫࢸ࣒࡜
ࢯࣇࢺ࣐ࢸࣜ࢔ࣝ࡬ࡢᛂ⏝◁ཱྀ ᑦ㍤  ྡྂᒇ኱Ꮫ኱Ꮫ㝔་Ꮫ⣔◊✲⛉BL8S3㸸X ⥺ᑠゅᩓ஘࠾ࡼࡧ༢⤖ᬗゎᯒ࡛᥈ࡿ࢔ࢡࢳࣥ⧄⥔ษ᩿ࢱࣥࣃࢡ㉁ࣇࣛࢢ࣑ࣥࡢస⏝ᶵᗎṊ⏣ ಟ୍ 1, ᑠ⏣ ಇ㑻 2, ᮡᮏ Ὀఙ 3
1.ᒸᒣ኱Ꮫ␗ศ㔝ᇶ♏⛉Ꮫ◊✲ᡤ 2. ᮾᾏᏛ㝔኱Ꮫ 3.ྡྂᒇ኱Ꮫ
࠶࠸ࡕࢩࣥࢡࣟࢺࣟࣥගࢭࣥࢱ࣮ ග※ຍ㏿ჾࡢ⌧≧㧘ᔱ ᆂྐ  ྡྂᒇ኱Ꮫࢩࣥࢡࣟࢺࣟࣥග◊✲ࢭࣥࢱ࣮ㅮ₇   ➉⏣ ⨾࿴  ࠶࠸ࡕࢩࣥࢡࣟࢺࣟࣥගࢭࣥࢱ࣮
ཧ

ຍ

⪅

124 ྡ

୺

ദ

ྡྂᒇ኱Ꮫࢩࣥࢡࣟࢺࣟࣥග◊✲ࢭࣥࢱ࣮༠㈶࠶࠸ࡕࢩࣥࢡࣟࢺࣟࣥගࢭࣥࢱ࣮

71



72

㸬ᡂᯝሗ࿌᭩

73ᡂᯝሗ࿌᭩

 බඹ➼฼⏝ᡂᯝሗ࿌᭩
AichiSR ࡛ࡣࠊ኱Ꮫࠊබタヨ㦂◊✲ᶵ㛵➼ࡢබඹⓗ࠙ᥖ㍕࣮࣌ࢪ URLࠚ࡞ᅋయ࡟ࡼࡿ฼⏝ࢆᑐ㇟࡜ࡋࡓࠊබඹ➼฼⏝ࡢไᗘࢆhttps://www.aichisr.jp/publication/report/2021/1.html

タࡅ࡚࠾ࡾࠊ୍⯡฼⏝ࡢ฼⏝ᩱࡢ༙㢠࡛฼⏝࡛ࡁࡿࠋ࠙QR ࢥ࣮ࢻࠚ

ࡓࡔࡋࠊᡂᯝබ㛤ࢆ๓ᥦ࡜ࡋ࡚࠾ࡾࠊᡂᯝሗ࿌᭩ࡢᥦ
ฟࡀ⩏ົ௜ࡅࡽࢀ࡚࠸ࡿࠋ
ࠕ2021 ᖺᗘබඹ➼฼⏝࡛ࠖᡂᯝሗ࿌᭩ࡀᥦฟࡉࢀࡓㄢ㢟ࡣ௨ୗࡢ࡜࠾ࡾ࡛࠶ࡿࠋ
࡞࠾ࠊᡂᯝሗ࿌᭩ࡢෆᐜࡣࠊAichiSR ࣮࣒࣮࣍࣌ࢪ
࡛බ㛤ࡉࢀ࡚࠸ࡿࠋ
%/1 㸦㌾ ; ⥺ ;$)6࣭ග㟁Ꮚศගϩ ᐇ㦂␒ྕͤࡣබ㛤ᘏᮇࡢ⏦ㄳࡀ࠶ࡗࡓࡶࡢᐇ 㦂 ྡᡤᒓ࣭ᐇ᪋㈐௵⪅202101001

GaN ࡢ㠀ᑓ᭷≧ែ㟁Ꮚ≧ែ ᐃ(ᅜ◊)≀㉁࣭ᮦᩱ◊✲ᶵᵓ࣭ᒣୗⰋஅ

202101029Ỉ㟁ゎゐ፹ࡢ㌾ X ⥺྾཰ศගゎᯒ❧࿨㤋኱Ꮫ࣭ᢡ➟᭷ᇶ

202102015࣮ࣞࢨ࣮ຍᕤ㔠ᒓࡢ⾲㠃≧ែほᐹᐑᇛ┴⏘ᴗᢏ⾡⥲ྜࢭࣥࢱ࣮࣭ᩪ⸨㞞ᘯ

202102100 ͤ

X ⥺྾཰ศග࡟ࡼࡿࣜࢳ࣒࢘◲㯤㟁ụ⏝ṇᴟࡢ࢖࢜ࣥఏᑟࣃࢫ
ᙧᡂ࠾ࡼࡧ᪂つ⵳㟁࣓࢝ࢽࢬ࣒ࡢゎ᫂㛵す኱Ꮫ࣭ィ㈼2021D2028

Ỉ㟁ゎゐ፹ࡢ㌾ X ⥺྾཰ศගゎᯒ❧࿨㤋኱Ꮫ࣭ᢡ➟᭷ᇶ

202103004

Mg ࢆࢻ࣮ࣉࡋࡓ GaN ࡢ㠀ᑓ᭷≧ែ㟁Ꮚ≧ែ ᐃ(ᅜ◊)≀㉁࣭ᮦᩱ◊✲ᶵᵓ࣭ᒣୗⰋஅ

202103016

X ⥺྾཰ศග࡟ࡼࡿࣜࢳ࣒࢘◲㯤㟁ụ⏝ṇᴟࡢ࢖࢜ࣥఏᑟࣃࢫ
ᙧᡂ࠾ࡼࡧ᪂つ⵳㟁࣓࢝ࢽࢬ࣒ࡢゎ᫂㛵す኱Ꮫ࣭ィ㈼202103048

⵳㟁ᮦᩱࡢ㓟⣲ࡢ㟁Ꮚ≧ែศᯒᮾ໭኱Ꮫ࣭ᑠᯘᘯ᫂

202103053

Ỉ㟁ゎゐ፹ࡢ㌾ X ⥺྾཰ศගゎᯒ 3❧࿨㤋኱Ꮫ࣭ᢡ➟᭷ᇶ

202103067

ࢳࢱࢽ࢔⣔ྍどගᛂ⟅ගゐ፹࡟ྵ᭷ࡍࡿ❅⣲ᡂศࡢ ᐃ

202104092

ࢪ࢔࣑ࢻ࢔࣑ࣥ⣔྾╔ᮦࡢ྾╔๓ᚋࡢ❅⣲࿘ࡾ࡟╔┠ࡋࡓᵓ㐀ゎᯒ(ᆅ⊂)ᮾி㒔❧⏘ᴗᢏ⾡◊✲ࢭࣥࢱ࣮࣭ᰁᕝ
ṇ୍ᮾி㒔ᕷ኱Ꮫ࣭ᯇᾆ἞᫂

202104093⁐⼥ሷ⵨␃ṧ␃≀ࢆᑐ㇟࡜ࡋࡓࢭ࣒ࣜ࢘ࡢཎᏊ౯ホ౯ᮾி㒔ᕷ኱Ꮫ࣭ᯇᾆ἞᫂

202104100

ࢮ࢜ࣛ࢖ࢺゐ፹ࡢάᛶⅬࡢᒁᡤᵓ㐀ゎᯒྡྂᒇ኱Ꮫ࣭⧊⏣᫭

2021L4003

Ỉ㟁ゎゐ፹ࡢ㌾ X ⥺྾཰ศගゎᯒ 4❧࿨㤋኱Ꮫ࣭ᢡ➟᭷ᇶ

202105001

202105002▼Ⅳ࣭▼Ⅳ⅊㸦ࣇࣛ࢖࢔ࢵࢩ࣭ࣗࢡࣜࣥ࢝⅊㸧࡟ྵࡲࢀࡿ࣍࢘⣲ࡢ໬ᏛᙧែศᯒADAAM ྾╔ᮦ࡟࠾ࡅࡿ XANES ᵓ㐀ẚ㍑㹼ᕼᅵ㢮༢ඖ⣔࡜ඹᏑ⣔㹼ᮾி㒔ᕷ኱Ꮫ࣭ᯇᾆ἞᫂

ᮾி㒔ᕷ኱Ꮫ࣭ᯇᾆ἞᫂

202105007

ࢫࣆࢿࣝᵓ㐀୰ࡢ Mg ࢧ࢖ࢺࡢᒁᡤᵓ㐀ゎᯒྡྂᒇ኱Ꮫ࣭⧊⏣᫭

202105050⁐⼥ሷ⵨␃ṧ␃≀ࡢࢭ࣒ࣜ࢘࿘ࡾ࡟╔┠ࡋࡓᵓ㐀ゎᯒ(ᅜ◊)᪥ᮏཎᏊຊ◊✲㛤Ⓨᶵᵓ࣭㧗␊ᐜᏊ

2021L5003

Ỉ㟁ゎゐ፹ࡢ㌾ X ⥺྾཰ศගゎᯒ 4❧࿨㤋኱Ꮫ࣭ᢡ➟᭷ᇶ

202106035

4H-SiC(0001)୰ࢻ࣮ࣃࣥࢺࡢ㠀ᑓ᭷≧ែ㟁Ꮚ≧ែ ᐃ(ᅜ◊)≀㉁࣭ᮦᩱ◊✲ᶵᵓ࣭ᒣୗⰋஅ

202106041

ࢮ࢜ࣛ࢖ࢺ㦵᱁୰࣊ࢸࣟཎᏊࡢᒁᡤᵓ㐀ゎᯒᮾ໭኱Ꮫ࣭すᇼ㯞⾰Ꮚ

202106045

࢚࣏࢟ࢩࣔࢹࣝᶞ⬡ࡢ XAFS

202106060㓟໬≀㟁ᴟゐ፹ࡢ໬Ꮫ≧ែศᯒ(୍㈈)ࣇ࢓࢖ࣥࢭ࣑ࣛࢵࢡࢫࢭࣥࢱ࣮࣭ྜྷ⏣ᐃせ༓ⴥᕤᴗ኱Ꮫ࣭㧘ᶫఀஂ☻74

202106106

ࣜࣥ㓟㕲ࣜࢳ࣒࢘㓟໬≀ᮦᩱࡢ㓟⣲ࡢ㟁Ꮚ≧ែศᯒᮾ໭኱Ꮫ࣭ᑠᯘᘯ᫂

2021L6003

Ỉ㟁ゎゐ፹ࡢ㌾ X ⥺྾཰ศගゎᯒ 4❧࿨㤋኱Ꮫ࣭ᢡ➟᭷ᇶ%/6 㸦༢⤖ᬗ ; ⥺ᅇᢡ㸸ྡྂᒇ኱Ꮫ ᐇ㦂␒ྕ
2021N1001
2021N1002
2021N2001

2021N2002

2021N2003

2021N2004ᐇ 㦂 ྡᡤᒓ࣭ᐇ᪋㈐௵⪅㧗ᅽୗ࡛ྜᡂࡉࢀࡓᚤᑠヨᩱࡢᖖᅽ࠾ࡼࡧ㧗ᅽࡑࡢሙᅇᢡ ᐃ㸸㉸㧗ᅽୗ࡟࠾ࡅࡿ᪂つ㑄⛣㔠ᒓⅣ໬≀ࡢྜᡂຍᅽ࡟ࡼࡿ⤖ᬗᛶྥୖ࡜㧗࢚ࢿࣝࢠ࣮ᵓ㐀ࡢᤕᤊ㧗ᅽຊୗ࡟࠾ࡅࡿỈ⣲⤖ྜᛶ⤖ᬗࡢᵓ㐀ኚ໬㸫ị VII ┦࡜࢞ࢫࣁ࢖ࢻ࣮ࣞࢺ㸫ࡑࡢ㸲㧗ᅽୗ࡛ྜᡂࡉࢀࡓᚤᑠヨᩱࡢᖖᅽ࠾ࡼࡧ㧗ᅽࡑࡢሙᅇᢡ ᐃ㸸᪂つ Mn-Sn ⣔໬ྜ≀ࡢ㉸㧗ᅽྜᡂࡢヨࡳග࢚ࢿࣝࢠ࣮ኚ᥮ࡢᶵᵓゎ᫂࡟ྥࡅࡓගྜᡂ⺮ⓑ㉁ࡢ⤖ᬗᵓ㐀ゎᯒ
Toward automated and optimized operations of hard x-ray
diffraction experimentsྡྂᒇ኱Ꮫ࣭୹⩚೺ྡྂᒇ኱Ꮫ࣭ỌỤᓠᖾᒱ㜧኱Ꮫ࣭బࠎᮌ㔜㞝ྡྂᒇ኱Ꮫ࣭୹⩚೺ྡྂᒇ኱Ꮫ࣭ᱵྡὈྐ

ྡྂᒇ኱Ꮫ࣭ChavasLeonard

2021N2005⥳ෆ㞀ཎᅉࢱࣥࣃࢡ㉁ࡢ⤖ᬗࡢࢯ࣮࢟ࣥࢢ࡟ࡼࡿᙳ㡪ホ౯Ꮫ⩦㝔኱Ꮫ࣭཭ụྐ᫂

2021N2006ຍᅽ࡟ࡼࡿ⤖ᬗᛶྥୖ࡜㧗࢚ࢿࣝࢠ࣮ᵓ㐀ࡢᤕᤊྡྂᒇ኱Ꮫ࣭ỌỤᓠᖾ

2021N2008ከ๣⪏ᛶ࡟㛵ࢃࡿ⣽⳦ࢱࣥࣃࢡ㉁ࡢ⤖ᬗᏛⓗ◊✲ྡྂᒇᕷ❧኱Ꮫ࣭ຍ⸨᫭୍

2021N2009

Toward automated and optimized operations of hard X-ray
diffraction experimentsྡྂᒇ኱Ꮫ࣭ChavasLeonard

2021N2010ຍᅽ࡟ࡼࡿ⤖ᬗᛶྥୖ࡜㧗࢚ࢿࣝࢠ࣮ᵓ㐀ࡢᤕᤊྡྂᒇ኱Ꮫ࣭ỌỤᓠᖾ

2021N2011ࢤࣝ࡟ໟᇙࡉࢀࡓࢱࣥࣃࢡ㉁⤖ᬗࢆ⏝࠸ࡓᵓ㐀ゎᯒྡྂᒇ኱Ꮫ࣭཭ụྐ᫂

2021N3001
2021N3002
2021N3004
2021N3005
2021N4001
2021N4002
2021N4003

2021N4004
2021N4005
2021N4006

2021N5001

2021N5002

㧗ᅽୗ࡛ྜᡂࡉࢀࡓᚤᑠヨᩱࡢᖖᅽ࠾ࡼࡧ㧗ᅽࡑࡢሙᅇᢡ ᐃ㸸
Co-N ⣔ヨᩱࡢ⇕⭾ᙇᣲືࡢㄪᰝ
Lys48 ᆺࣘࣅ࢟ࢳࣥ㙐ኚ␗యࡢ X ⥺⤖ᬗᵓ㐀ゎᯒග࢚ࢿࣝࢠ࣮ኚ᥮ࡢᶵᵓゎ᫂࡟ྥࡅࡓගྜᡂ⺮ⓑ㉁ࡢ⤖ᬗᵓ㐀ゎᯒ⮬ᕫ⤌⧊໬㉸ศᏊࡢᨺᑕග X ⥺ᅇᢡ࡟ࡼࡿᵓ㐀ゎᯒ㧗ᅽୗ࡛ྜᡂࡉࢀࡓᚤᑠヨᩱࡢᖖᅽ࠾ࡼࡧ㧗ᅽࡑࡢሙᅇᢡ ᐃ㸸ᕼ࢞ࢫ໬ྜ≀ࡢ㉸㧗ᅽྜᡂࢤࣝ࡟ໟᇙࡉࢀࡓࢱࣥࣃࢡ㉁⤖ᬗࡢᵓ㐀ゎᯒ㧗ᅽୗ࡛ྜᡂࡉࢀࡓᚤᑠヨᩱࡢᖖᅽ࠾ࡼࡧ㧗ᅽࡑࡢሙᅇᢡ ᐃ㸸
Ta-N ⣔ヨᩱࡢ⇕⭾ᙇᣲືࡢㄪᰝ
㧗ᅽୗ࡛ྜᡂࡉࢀࡓᚤᑠヨᩱࡢᖖᅽ࠾ࡼࡧ㧗ᅽࡑࡢሙᅇᢡ ᐃ㸸㉸㧗ᅽୗ࡟࠾ࡅࡿ㑄⛣㔠ᒓⅣ❅໬≀ࡢྜᡂࡢヨࡳ㔠ᒓ᭷ᶵᵓ㐀య⤖ᬗࡢᵓ㐀ゎᯒྡྂᒇ኱Ꮫ࣭୹⩚೺ྡྂᒇᕷ❧኱Ꮫ࣭ຍ⸨᫭୍
ྡྂᒇ኱Ꮫ࣭ᱵྡὈྐ
ᮾி኱Ꮫ࣭బ⸨᐀ኴ
ྡྂᒇ኱Ꮫ࣭୹⩚೺Ꮫ⩦㝔኱Ꮫ࣭཭ụྐ᫂ྡྂᒇ኱Ꮫ࣭୹⩚೺ྡྂᒇ኱Ꮫ࣭୹⩚೺ྡྂᒇ኱Ꮫ࣭ᙇ୰ᓅ

㧗ᅽຊୗ࡟࠾ࡅࡿỈ⣲⤖ྜᛶ⤖ᬗࡢᵓ㐀ኚ໬㸫ị VII ┦࡜࢞ࢫࣁ࢖ࢻ࣮ࣞࢺ㸫ࡑࡢ㸳ᇶ㉁ྠ୍㒊఩ከẁ㝵㓟໬ᆺࢩࢺࢡ࣒ࣟ P450 㓝⣲RosC ࡢ⤖ᬗᵓ㐀ゎᯒ㧗ᅽୗ࡛ྜᡂࡉࢀࡓᚤᑠヨᩱࡢᖖᅽ࠾ࡼࡧ㧗ᅽࡑࡢሙᅇᢡ ᐃ㸸᪂つ W-Sn ⣔໬ྜ≀ࡢ㉸㧗ᅽྜᡂࡢヨࡳ75ᒱ㜧኱Ꮫ࣭బࠎᮌ㔜㞝ᮾ㑥኱Ꮫ࣭㕥ᮌᾈ඾ྡྂᒇ኱Ꮫ࣭୹⩚೺

2021N5004
2021N5006

2021N5007

2021N6001
2021N6003

ࢤ࡛ࣝಖㆤࡉࢀࡓࢱࣥࣃࢡ㉁⤖ᬗࡢ᳨ドᏛ⩦㝔኱Ꮫ࣭཭ụྐ᫂㧗ᅽୗ࡛ྜᡂࡉࢀࡓᚤᑠヨᩱࡢᖖᅽ࠾ࡼࡧ㧗ᅽࡑࡢሙᅇᢡ ᐃ㸸᪂つ Fe-Si ⣔໬ྜ≀ࡢ㉸㧗ᅽྜᡂࡢヨࡳ㧗ᅽຊୗ࡟࠾ࡅࡿỈ⣲⤖ྜᛶ⤖ᬗࡢᵓ㐀ኚ໬㸫ị VII ┦࡜࢞ࢫࣁ࢖ࢻ࣮ࣞࢺ㸫ࡑࡢ㸴㧗ᅽୗ࡛ྜᡂࡉࢀࡓᚤᑠヨᩱࡢᖖᅽ࠾ࡼࡧ㧗ᅽࡑࡢሙᅇᢡ ᐃ㸸㉸㧗ᅽୗ࡟࠾ࡅࡿ Kr-N2 ⣔໬ྜ≀ࡢྜᡂຍᅽ࡟ࡼࡿ⤖ᬗᛶྥୖ࡜㧗࢚ࢿࣝࢠ࣮ᵓ㐀ࡢᤕᤊ

202102003

202102019202102040
202102047

ᒱ㜧኱Ꮫ࣭బࠎᮌ㔜㞝ྡྂᒇ኱Ꮫ࣭୹⩚೺ྡྂᒇ኱Ꮫ࣭ỌỤᓠᖾ%/6㸦◳ ; ⥺ ;$)6,㸧ᐇ㦂␒ྕྡྂᒇ኱Ꮫ࣭୹⩚೺ͤࡣබ㛤ᘏᮇࡢ⏦ㄳࡀ࠶ࡗࡓࡶࡢᐇ 㦂 ྡᡤᒓ࣭ᐇ᪋㈐௵⪅Co ゐ፹࠿ࡽࡢ༢ᒙ࣮࢝࣎ࣥࢼࣀࢳ࣮ࣗࣈᡂ㛗㐣⛬ࡢࡑࡢሙ
XAFS

ᐃ㓟໬ࢢࣛࣇ࢙ࣥࢆࢸࣥࣉ࣮ࣞࢺ࡜ࡋࡓ㓟໬࣒࢞ࣜ࢘ගゐ፹స〇ࡢヨࡳ
MOF-on-MOF ᆺ Chemiresistor ࡢ✚ᒙⷧ⭷ᵓ㐀ࡢゎ᫂ྡᇛ኱Ꮫ࣭୸ᒣ㝯ᾈྡྂᒇ኱Ꮫ࣭ྜྷ⏣᭸Ꮚி㒔኱Ꮫ࣭኱➉◊୍↝ᡂ㞺ᅖẼࢆኚ࠼࡚↝ᡂࡋࡓ㟷☢㔙ࡢ㔙Ⰽㄪࠊ㕲౯ᩘཬࡧ㔙ᵓ㐀ࡢ㛵ಀㄪᰝ

202102055」ྜ㓟໬≀ゐ፹ࡢ XAFS

202102061

㧗ᅽୗ࡛ྜᡂࡉࢀࡓࣂࢼࢪ࣒࢘❅໬≀ࡢ࣐࢖ࢡࣟ XAFS

202102081 ͤ㖡㖔▼୰ࡢ◉⣲࡜㖡ࡢ໬Ꮫ✀ศᯒᒱ㜧኱Ꮫ࣭຾⏣㛗㈗202102095

ᅛయ㟁ゎ㉁ᮦᩱࡢ X ⥺྾཰ศග(බ㈈)⛉Ꮫᢏ⾡஺ὶ㈈ᅋ࣭ᒸᓥᩄᾈ

202102101

Ⅳ㓟࢝ࣝࢩ࣒࢘ࡢ X ⥺྾཰ศග(බ㈈)⛉Ꮫᢏ⾡஺ὶ㈈ᅋ࣭ᒸᓥᩄᾈ

2021D2001

2021D2007

2021D2026

2021D2045

ᐃⲈᇛ኱Ꮫ࠙ឡ▱┴ᐇᆅ◊ಟࠚ㞳ࡢỴᐃ⇞ᩱ㟁ụ࢝ࢯ࣮ࢻ⏝ࡢ⇕ฎ⌮ᆺ Fe ゐ፹ࡢ XAFS ࡟ࡼࡿᵓ㐀ゎᯒᒁᡤ㹼㛗㊥㞳ᵓ㐀ไᚚ࡟❧⬮ࡋࡓ࢖࢜ࣥ஺᥮྾╔࡟࠾ࡅࡿぶ࿴ᛶࡢ㉳※ゎ᫂
ᒁᡤ㹼㛗㊥㞳ᵓ㐀ไᚚ࡟❧⬮ࡋࡓ࢖࢜ࣥ஺᥮྾╔࡟࠾ࡅࡿぶ࿴ᛶࡢ㉳※ゎ᫂
㔠ᒓᢸᣢゐ፹ࡢ XAFS

202103025

2021 ᖺᗘ XAFS ኟࡢᏛᰯ ᐃᐇ⩦ձ202103056
202103060

ᐃ

Ir ࡞ࡽࡧ࡟ Mn ࢆྵࡴ㓟໬≀࡟࠾ࡅࡿ౯ᩘ࡜㔠ᒓ̿㓟⣲㛫ࡢ㊥202103019

202103034

ྡྂᒇ኱Ꮫ࣭㑦ḟᬛᐃྡྂᒇ኱Ꮫ࣭୹⩚೺໭ぢᕤᴗ኱Ꮫ࣭ᖹ஭ឿே

⇃ᮏ኱Ꮫ࣭኱ᒣ㡰ஓಙᕞ኱Ꮫ࣭⡘ᬛோಙᕞ኱Ꮫ࣭⡘ᬛோᰴᘧ఍♫୕஬࠙ឡ▱┴ᐇᆅ◊ಟࠚྡྂᒇ኱Ꮫ࣭ᑠᕝᬛྐ

࠙㔜Ⅼ㹋㸱ࠚ‵ᘧࣁ࢖ࢫ࣮ࣝࣉࢵࢺࣉࣟࢭࢫ࡟ࡼࡿከඖ⣔㓟໬≀ᶵ⬟ᮦࡢ᥈⣴
Pt ཎᏊゐ፹ࡢᒁᡤᵓ㐀ゎᯒᮾி⌮⛉኱Ꮫ࣭⸨ᮏ᠇ḟ㑻ྡྂᒇ኱Ꮫ࣭⧊⏣᫭ᐃ㔞⢭ᗘྥୖࢆ┠ᣦࡋࡓXAFS ᐃ᫬ࡢLCF ゎᯒᡭἲࡢ㧗ᗘ໬㸦㸯㸧࠶࠸ࡕ⏘ᴗ⛉Ꮫᢏ⾡⥲ྜࢭࣥࢱ࣮࣭㔝ᮏ㇏࿴ࢳࢱࢽ࢔⣔ྍどගᛂ⟅ගゐ፹ࡢ࢚ࢱࣀ࣮ࣝỈ⁐ᾮ୰࡛ࡢගゐ፹(ᆅ⊂)ᮾி㒔❧⏘ᴗᢏ⾡◊✲ࢭࣥࢱ࣮࣭ᰁᕝ

཯ᛂ୰࡟࠾ࡅࡿ CuO ࡢᣲືゎᯒṇ୍202103071

࢞ࢫᭀ㟢᫬࡟࠾ࡅࡿ㓟໬≀༙ᑟయ࢞ࢫࢭࣥࢧࡢ౯ᩘኚ໬

ᮾி⌮⛉኱Ꮫ࣭⸨ᮏ᠇ḟ㑻

202103074

ࢩࣥࢡࣟࢺࣟࣥගࢆ⏝࠸ࡓ㔙⸆ࡢእほኚ໬ࡢㄪᰝ

࠶࠸ࡕ⏘ᴗ⛉Ꮫᢏ⾡⥲ྜࢭࣥࢱ࣮࣭ᮧ஭ᓫ❶202103083

᭷ᐖඖ⣲㝖ཤ࡟⏝࠸ࡿ Fe-Mg ⣔᪂つ࣐ࢸࣜ࢔ࣝࡢ≀ᛶᢕᥱ᪩✄⏣኱Ꮫ࣭ᡤ༓ᬕ

202103066

762021D3023
202104001
2021D5024
202104002
202104003(ᆅ⊂)ᮾி㒔❧⏘ᴗᢏ⾡◊✲ࢭࣥࢱ࣮࣭ᰁᕝ

㓟⣲㟁ᴟᮦᩱ⏝㓟໬࣐ࣥ࢞ࣥࡢゎᯒṇ୍㓟໬≀ࢼࣀ⢏Ꮚࡢ Eu ࿘ࡾࡢᵓ㐀ホ౯஑ᕞᕤᴗ኱Ꮫ࣭ᮏሯᬛ

Zn ྵ᭷࣏࣐࣮ࣜ࡟࠾ࡅࡿ Zn ࡢ໬Ꮫ≧ែホ౯ឡ▱ᕤᴗ኱Ꮫ࣭⚟᳃೺୕㓟໬ࢢࣛࣇ࢙ࣥࢆࢸࣥࣉ࣮ࣞࢺ࡜ࡋࡓ㓟໬࣒࢞ࣜ࢘ගゐ፹స〇ࡢヨࡳྡྂᒇ኱Ꮫ࣭ྜྷ⏣᭸Ꮚ

202104005

࣐ࣥ࢞ࣥᕼᅵ㢮❅໬≀ࡢ໬Ꮫ≧ែㄪᰝ໭ᾏ㐨኱Ꮫ࣭୕ᾆ❶202104007

࢞ࢫᭀ㟢᫬࡟࠾ࡅࡿ㓟໬≀༙ᑟయ࢞ࢫࢭࣥࢧࡢ౯ᩘኚ໬

ᮾி⌮⛉኱Ꮫ࣭⸨ᮏ᠇ḟ㑻

202104017

࠙㔜Ⅼ㹋㸱ࠚ‵ᘧࣁ࢖ࢫ࣮ࣝࣉࢵࢺࣉࣟࢭࢫ࡟ࡼࡿከඖ⣔㓟໬≀ᶵ⬟ᮦࡢ᥈⣴

ᮾி⌮⛉኱Ꮫ࣭⸨ᮏ᠇ḟ㑻

202104023

㖔≀࡟ྵࡲࢀࡿ㕲࡜ࣜࣥࡢ໬Ꮫᙧែ

ᮾி㎰ᕤ኱Ꮫ࣭ᶫᮏὒᖹ

202104025

XAFS ἲ࡟ࡼࡿࢩࣜ࢝⢏Ꮚෆ࡟ྲྀࡾ㎸ࡲࢀࡓ TiO2 ࡢᵓ㐀ゎᯒ(୍㈈)⥲ྜ⛉Ꮫ◊✲ᶵᵓ࣭㜿ஂὠ࿴ᏹ

202104027

᭷ᶵ㉁㈨ᮦࡢ᪋⏝࡟ࡼࡿ‣Ỉᅵተࣄ⣲ᙧែࡢኚ໬

202104054

ࢩࣥࢡࣟࢺࣟࣥගࢆ⏝࠸ࡓ㔙⸆ࡢእほኚ໬ࡢㄪᰝ

࠶࠸ࡕ⏘ᴗ⛉Ꮫᢏ⾡⥲ྜࢭࣥࢱ࣮࣭ᮧ஭ᓫ❶202104055[ᐇᆅ◊ಟ]㔙⸆⾲㠃ⷧ⭷ࡢ๤㞳せᅉࡢㄪᰝ࠶࠸ࡕ⏘ᴗ⛉Ꮫᢏ⾡⥲ྜࢭࣥࢱ࣮࣭ᮧ஭ᓫ❶202104056

Ⅳ㓟࢝ࣝࢩ࣒࢘ࡢ X ⥺྾཰ศග㸦㸰㸧(බ㈈)⛉Ꮫᢏ⾡஺ὶ㈈ᅋ࣭ᒸᓥᩄᾈ

202104130⎔ቃヨᩱࡢࢭࣞࣥࠊࣄ⣲࡜࣐ࣥ࢞ࣥࡢ໬Ꮫ✀ศᯒᒱ㜧኱Ꮫ࣭຾⏣㛗㈗2021D4004

Br ྵ᭷་⸆ရཎ⸆⤖ᬗከᙧࡢ XAFSᮾ㑥኱Ꮫ࣭㕥ᮌᾈ඾

202105005

࢚࣏࢟ࢩሬᩱ࡬ࡢࢭࢩ࣒࢘ཬࡧࣚ࢘⣲ࡢᾐ㏱ᣲື

202105008

202105019

ᐃ༝㔠ᒓࢼࣀ⢏Ꮚ࠶ࡿ࠸ࡣ㓟໬≀ࡢ⾲㠃࡟ᅛᐃࡉࢀࡓ㈗㔠ᒓ༢ཎᏊࢧ࢖ࢺࡢᒁᡤᵓ㐀ゎᯒ࠙㔜Ⅼ㹋㸱ࠚ‵ᘧࣁ࢖ࢫ࣮ࣝࣉࢵࢺࣉࣟࢭࢫ࡟ࡼࡿከඖ⣔㓟໬≀ᶵ⬟ᮦࡢ᥈⣴(ᅜ◊)㎰ᴗ࣭㣗ရ⏘ᴗᢏ⾡⥲ྜ◊✲ᶵᵓ࣭㡲⏣☐ᾏᮾி㒔ᕷ኱Ꮫ࣭ᯇᾆ἞᫂
ྡྂᒇ኱Ꮫ࣭⧊⏣᫭ᮾி⌮⛉኱Ꮫ࣭⸨ᮏ᠇ḟ㑻

202105021

࢞ࢫᭀ㟢᫬࡟࠾ࡅࡿ㓟໬≀༙ᑟయ࢞ࢫࢭࣥࢧࡢ౯ᩘኚ໬

ᮾி⌮⛉኱Ꮫ࣭⸨ᮏ᠇ḟ㑻

202105043

඲ᅛయ㟁ụ⏝ሷ໬≀㟁ᴟ୰ࡢ㕲ࡢ≧ែゎᯒྡྂᒇᕤᴗ኱Ꮫ࣭㇂➃┤ே

202105056

ᒁᡤ㹼㛗㊥㞳ᵓ㐀ไᚚ࡟❧⬮ࡋࡓ࢖࢜ࣥ஺᥮྾╔࡟࠾ࡅࡿぶ࿴ᛶࡢ㉳※ゎ᫂

ಙᕞ኱Ꮫ࣭⡘ᬛோ

202105060

Sr ࡜ Ba ࡢỈ⁐ᾮ୰࠾ࡼࡧỿẊ࣭ᶞ⬡୰࡛ࡢ໬Ꮫᵓ㐀኱㜰኱Ꮫ࣭➟ᯇⰋᓫ

202105162

Ỉ㓟໬ࢽࢵࢣࣝࢼࣀࢩ࣮ࢺ」ྜయࡢᵓ㐀ゎᯒྡྂᒇᕤᴗ኱Ꮫ࣭ᕝᓮ᫴ྖ

2021D5002

XAFS ࡟ࡼࡿ࣮࢝࣎ࣥᢸᣢ Fe 㘒యゐ፹ࡢᵓ㐀ゎᯒ⇃ᮏ኱Ꮫ࣭኱ᒣ㡰ஓ

2021D5032

202106003

ᒁᡤ㹼㛗㊥㞳ᵓ㐀ไᚚ࡟❧⬮ࡋࡓ࢖࢜ࣥ஺᥮྾╔࡟࠾ࡅࡿぶ࿴ᛶࡢ㉳※ゎ᫂
ࣝࢳࣝ TiO2 ⾲㠃ୖ࡛๰ࡾฟࡉࢀࡿ㈗㔠ᒓཎᏊゐ፹ࡢᒁᡤᵓ㐀ゎᯒಙᕞ኱Ꮫ࣭⡘ᬛோྡྂᒇ኱Ꮫ࣭⧊⏣᫭

202106010

㔠ᒓ㓟໬≀ゐ፹୰ࡢάᛶ✀ᵓ㐀ゎᯒྡྂᒇ኱Ꮫ࣭ྜྷ⏣᭸Ꮚ

202106017†἟ヨᩱࡢࢭࣞࣥࠊࣄ⣲࡜࣐ࣥ࢞ࣥࡢ໬Ꮫ✀ศᯒᒱ㜧኱Ꮫ࣭຾⏣㛗㈗202106030

ගゐ፹࡟ࡼࡿභ౯ࢡ࣒ࣟࡢ㑏ඖ཯ᛂ࡜⏕ᡂ≀ࡢㄪᰝ

202106038

Ỉ⏣ᅵተ୰ࣄ⣲ࡢ໬Ꮫᙧែ࡟ᑐࡍࡿ㈨ᮦ᪋⏝ຠᯝࡢᣢ⥆ᛶ

202106042

ᐃ㔞⢭ᗘྥୖࢆ┠ᣦࡋࡓXAFS ᐃ᫬ࡢLCF ゎᯒᡭἲࡢ㧗ᗘ໬

77(ᆅ⊂)ᮾி㒔❧⏘ᴗᢏ⾡◊✲ࢭࣥࢱ࣮࣭ᰗ⏣ࡉࡸ࠿(ᅜ◊)㎰ᴗ࣭㣗ရ⏘ᴗᢏ⾡⥲ྜ◊✲ᶵᵓ࣭ᒣཱྀ⣖Ꮚ࠶࠸ࡕ⏘ᴗ⛉Ꮫᢏ⾡⥲ྜࢭࣥࢱ࣮࣭㔝ᮏ㇏࿴㸦㸰㸧202106043

202106058

Peroxymonosulfate ࢆάᛶ໬ࡋ 1 㔜㡯㓟⣲ࢆ㧗཰⋡࡛⏕ᡂࡍࡿ❅໬Ⅳ⣲ୖ㧗ᢸᣢ㕲༢ཎᏊゐ፹࡟࠾ࡅࡿ㕲ࡢᒁᡤᵓ㐀ゎᯒ▼Ⅳ࣭▼Ⅳ⅊㸦ࣇࣛ࢖࢔ࢵࢩ࣭ࣗࢡࣜࣥ࢝⅊㸧࡟ྵࡲࢀࡿᚤ㔞㔜ඖ⣲ࡢ໬Ꮫᙧែศᯒ

ྡྂᒇ኱Ꮫ࣭⏣ῲ㞞ኵᮾி㒔ᕷ኱Ꮫ࣭ᯇᾆ἞᫂

202106059

㟷Ⰽ࣮ࣞࢨ࡟ࡼࡿ㖡ࢼࣀ⢏Ꮚప ↝⤖యࡢ XAFS ศᯒ኱㜰኱Ꮫ࣭Ᏻ⏣Ύ࿴

202106067

ள㖄㟁ゎᾮࡢᒁᡤᵓ㐀ゎᯒᮾி኱Ꮫ࣭すᮧ┿୍

202106109

᭷ᐖඖ⣲㝖ཤ࡟⏝࠸ࡿ Fe Mn ⣔᪂つ࣐ࢸࣜ࢔ࣝࡢ≀ᛶᢕᥱ᪩✄⏣኱Ꮫ࣭ᡤ༓ᬕ

2021D6027

㓟໬⿕⭷ࡢ≧ែゎᯒ(ᅜ◊)᪥ᮏཎᏊຊ◊✲㛤Ⓨᶵᵓ࣭୰ཎᑗᾏ

2021D6036

ᒁᡤ㹼㛗㊥㞳ᵓ㐀ไᚚ࡟❧⬮ࡋࡓ࢖࢜ࣥ஺᥮྾╔࡟࠾ࡅࡿぶ࿴ᛶࡢ㉳※ゎ᫂

%/6 㸦⢊ᮎ ; ⥺ᅇᢡ㸧ᐇ㦂␒ྕಙᕞ኱Ꮫ࣭⡘ᬛோͤࡣබ㛤ᘏᮇࡢ⏦ㄳࡀ࠶ࡗࡓࡶࡢᐇ 㦂 ྡᡤᒓ࣭ᐇ᪋㈐௵⪅2021L1002▷㊥㞳⛛ᗎࢆᣢࡘ㔞య໬ࢡࣛࢫࢱ࣮ࡢᖹᆒᵓ㐀◊✲Ϫྡྂᒇ኱Ꮫ࣭∦ᒣᑦᖾ

202102021⵳㟁ᅛయᮦᩱࡢ⢊ᮎ X ⥺ᅇᢡ ᐃྡྂᒇ኱Ꮫ࣭▼ᇉ⠊࿴

202102054

㧗ᅽୗ࡛ྜᡂࡉࢀࡓᚤ㔞ヨᩱࡢᨺᑕග⢊ᮎ X ⥺ᅇᢡ ᐃ㸸ࢳ࣒ࢽ࣮࣭ࣛࢲ࣮┦ CrGeȚ࡟࠾ࡅࡿ⤌ᡂࡢྜᡂᅽຊ౫Ꮡᛶ

ྡྂᒇ኱Ꮫ࣭బࠎᮌᣅஓ

202102074ప࢔ࣝ࢝ࣜᛶࢭ࣓ࣥࢺ࡟࠾ࡅࡿΰ࿴ᮦ᭱㐺໬ࡢ᥈⣴Ϩ(㔜Ⅼ M3)ྡྂᒇ኱Ꮫ࣭⏣ῲ㞞ኵ

202102085

ᰂ㌾ᛶࢼࣀ࣏࣮ࣛࢫ㔠ᒓ㘒యࡢ in situ ࢞ࢫ྾╔-ᵓ㐀ゎᯒྡྂᒇ኱Ꮫ࣭᪥ୗᚰᖹ

202102102 ͤ‵ᘧྜᡂࢆ฼⏝ࡋࡓ FeNi ࢼࣀ⢏Ꮚࡢᵓ㐀ホ౯(ᅜ◊)⏘ᴗᢏ⾡⥲ྜ◊✲ᡤ࣭ᯇᮏ❶ᏹ

202102105

඲⮬ືᵓ㐀ゎᯒࡢࡓࡵࡢࢸࢫࢺᐇ㦂㸰㸦㔜Ⅼ㹋㸱㸧኱㜰኱Ꮫ࣭ᑠ㔝ᐶኴ

202102107

ప࢔ࣝ࢝ࣜᛶࢭ࣓ࣥࢺ࡟࠾ࡅࡿΰ࿴ᮦ᭱㐺໬ࡢ᥈⣴ϩ(㔜Ⅼ M3)ྡྂᒇ኱Ꮫ࣭⏣ῲ㞞ኵ

202102108

Ỉ྾╔࡟క࠺㓟໬ࢢࣛࣇ࢙ࣥᒙ㛫㊥㞳ࡢኚ໬ಙᕞ኱Ꮫ࣭኱ሯ㞙ே

2021D2008 ͤࣇࢵ໬㕲ṇᴟᮦᩱࡢᵓ㐀ゎᯒ 2ி㒔኱Ꮫ࣭ᯇᮏ୍ᙪ

2021D2027ᒁᡤ㹼㛗㊥㞳ᵓ㐀ไᚚ࡟❧⬮ࡋࡓ࢖࢜ࣥ஺᥮྾╔࡟࠾ࡅࡿぶ࿴ᛶࡢ㉳※ゎ᫂

ಙᕞ኱Ꮫ࣭⡘ᬛோ

2021L2002▷㊥㞳⛛ᗎࢆᣢࡘ㔞య໬ࢡࣛࢫࢱ࣮ࡢᖹᆒᵓ㐀◊✲Ϫྡྂᒇ኱Ꮫ࣭∦ᒣᑦᖾ

202103024

⵳㟁ᅛయᮦᩱࡢ⢊ᮎ X ⥺ᅇᢡ ᐃྡྂᒇ኱Ꮫ࣭▼ᇉ⠊࿴

202103033

202103052

࠙㔜Ⅼ㹋㸱ࠚ‵ᘧࣁ࢖ࢫ࣮ࣝࣉࢵࢺࣉࣟࢭࢫ࡟ࡼࡿከඖ⣔㓟໬≀ᶵ⬟ᮦࡢ᥈⣴
㧗ᅽୗ࡛ྜᡂࡉࢀࡓᚤ㔞ヨᩱࡢᨺᑕග⢊ᮎ X ⥺ᅇᢡ ᐃ㸸㧗ᅽ┦࢔࣑ࣝࣥ㓟࢝ࣝࢩ࣒࢘ࡢ┦ศ㞳ᮾி⌮⛉኱Ꮫ࣭⸨ᮏ᠇ḟ㑻ྡྂᒇ኱Ꮫ࣭బࠎᮌᣅஓ

202103069

ࣁ࢖ࢻࣟࢡ࣑ࣟࢬ࣒ࢆ♧ࡍከᏍ㉁ศᏊ⤖ᬗࡢᵓ㐀ゎᯒ⟃Ἴ኱Ꮫ࣭ᒣᓊὒ

202103089◲໬㖟ࡢ⢊ᮎ࡟ᑐࡍࡿ X ⥺ᅇᢡࣃࢱ࣮ࣥࡢゎᯒ㇏⏣ᕤᴗ኱Ꮫ࣭➉ෆᜏ༤

202103092

ࢫࣆࢿࣝ㓟໬≀ࡢ᪼ 㐣⛬࡛ࡢᵓ㐀ኚ໬㏣㊧ᮾ໭኱Ꮫ࣭ᑠᯘᘯ᫂

202103093

඲⮬ືᵓ㐀ゎᯒࡢࡓࡵࡢࢸࢫࢺᐇ㦂㸱 㸦㔜Ⅼ㹋㸱㸧኱㜰኱Ꮫ࣭ᑠ㔝ᐶኴ

202103094

ప࢔ࣝ࢝ࣜᛶࢭ࣓ࣥࢺ࡟࠾ࡅࡿΰ࿴ᮦ᭱㐺໬ࡢ᥈⣴㸦㔜Ⅼ M3㸧

ྡྂᒇ኱Ꮫ࣭⏣ῲ㞞ኵ

2021D3011
2021D3031
2021D3036

ᒁᡤ㹼㛗㊥㞳ᵓ㐀ไᚚ࡟❧⬮ࡋࡓ࢖࢜ࣥ஺᥮྾╔࡟࠾ࡅࡿぶ࿴ᛶࡢ㉳※ゎ᫂
Ga2O3 ࠾ࡼࡧࢻ࣮ࣉ Ga2O3 ࡢ⢭ᐦᵓ㐀ゎᯒಙᕞ኱Ꮫ࣭⡘ᬛோᒱ㜧኱Ꮫ࣭኱▮㇏Investigation of Cooperative Metal Sites within Metal-Organic
Framework78(ᅜ◊)⏘ᴗᢏ⾡⥲ྜ◊✲ᡤ࣭ᒣ⏣⌮2021L3002
202104018▷㊥㞳⛛ᗎࢆᣢࡘ㔞య໬ࢡࣛࢫࢱ࣮ࡢᖹᆒᵓ㐀◊✲Ϫ࠙㔜Ⅼ㹋㸱ࠚ‵ᘧࣁ࢖ࢫ࣮ࣝࣉࢵࢺࣉࣟࢭࢫ࡟ࡼࡿከඖ⣔㓟໬≀ᶵ⬟ᮦࡢ᥈⣴

ྡྂᒇ኱Ꮫ࣭∦ᒣᑦᖾᮾி⌮⛉኱Ꮫ࣭⸨ᮏ᠇ḟ㑻

202104061

࠙ࢩࣥࢡࣟࢺࣟࣥගィ ධ㛛ㅮ⩦఍ࠚ ᐃ࣭ゎᯒᐇ⩦ BL5S2

࠶࠸ࡕ⏘ᴗ⛉Ꮫᢏ⾡⥲ྜࢭࣥࢱ࣮࣭㔝ᮏ㇏࿴

202104075

⵳㟁ᅛయᮦᩱࡢ⢊ᮎ X ⥺ᅇᢡ ᐃྡྂᒇ኱Ꮫ࣭▼ᇉ⠊࿴

202104109⇕ࣉࣛࢬ࣐ἲ࡟ࡼࡿ Nd-Fe ྜ㔠ࢼࣀ⢊ᮎࡢྜᡂ(ᅜ◊)⏘ᴗᢏ⾡⥲ྜ◊✲ᡤ࣭ᖹᒣᝆ௓

202104111

㔞య໬≀㉁ࡢᨺᑕග X ⥺ᵓ㐀ゎᯒྡྂᒇ኱Ꮫ࣭∦ᒣᑦᖾ

202104114

඲⮬ືᵓ㐀ゎᯒࡢࡓࡵࡢࢸࢫࢺᐇ㦂㸱 㸦㔜Ⅼ㹋㸱㸧኱㜰኱Ꮫ࣭ᑠ㔝ᐶኴ

202104115
2021D4022
2021D4023

202105018

202105057

㧗ᅽୗ࡛ྜᡂࡉࢀࡓᚤ㔞ヨᩱࡢᨺᑕග⢊ᮎ X ⥺ᅇᢡ ᐃ㸸ࢳ࣒ࢽ࣮࣭ࣛࢲ࣮┦ CrGeȚ࡬ࡢඖ⣲⨨᥮ࣜࢳ࣒࢘㕲㓟໬≀ࡢࢻ࣮ࣆࣥࢢ࡟ࡼࡿ⤖ᬗᵓ㐀ኚ໬㏣㊧ᒁᡤ㹼㛗㊥㞳ᵓ㐀ไᚚ࡟❧⬮ࡋࡓ࢖࢜ࣥ஺᥮྾╔࡟࠾ࡅࡿぶ࿴ᛶࡢ㉳※ゎ᫂
࠙㔜Ⅼ㹋㸱ࠚ‵ᘧࣁ࢖ࢫ࣮ࣝࣉࢵࢺࣉࣟࢭࢫ࡟ࡼࡿከඖ⣔㓟໬≀ᶵ⬟ᮦࡢ᥈⣴
ᒁᡤ㹼㛗㊥㞳ᵓ㐀ไᚚ࡟❧⬮ࡋࡓ࢖࢜ࣥ஺᥮྾╔࡟࠾ࡅࡿぶ࿴ᛶࡢ㉳※ゎ᫂

ྡྂᒇ኱Ꮫ࣭బࠎᮌᣅஓ
ᮾ໭኱Ꮫ࣭ᑠᯘᘯ᫂
ಙᕞ኱Ꮫ࣭⡘ᬛோᮾி⌮⛉኱Ꮫ࣭⸨ᮏ᠇ḟ㑻ಙᕞ኱Ꮫ࣭⡘ᬛோ

202105062

㔠ᒓከ౯࣍ࢫ࣍ࢿ࣮ࢺ MOF ࡢ⤖ᬗᵓ㐀ゎ᫂ᮾி㎰ᕤ኱Ꮫ࣭๓⏣࿴அ

202105089

࢔࣑ࣝࢼ୰࡟ྵࡲࢀࡿ๪ᡂศࡢྠᐃ࠙ᐇᆅ◊ಟࠚ࠶࠸ࡕ⏘ᴗ⛉Ꮫᢏ⾡⥲ྜࢭࣥࢱ࣮࣭ᮡᒣಙஅ

202105094℩ᡞ㏆㑹ࡢᮌ⠇⢓ᅵࡢ⤖ᬗᛶ࡜ྍረᛶヨ㦂࠶࠸ࡕ⏘ᴗ⛉Ꮫᢏ⾡⥲ྜࢭࣥࢱ࣮࣭ᮧ஭ᓫ❶202105108

ప࢔ࣝ࢝ࣜᛶࢭ࣓ࣥࢺ࡟࠾ࡅࡿΰ࿴ᮦ᭱㐺໬ࡢ᥈⣴㸦㔜Ⅼ M3㸧

ྡྂᒇ኱Ꮫ࣭⏣ῲ㞞ኵ

202105110

Sm-Fe-N Ọஂ☢▼⢊ᮎࡢ X ⥺ᅇᢡྡྂᒇ኱Ꮫ࣭Ỉཱྀᑗ㍤

202105132

X ⥺ᅇᢡἲ࡟ࡼࡿከ౯࢝ࢳ࢜ࣥࢻ࣮ࣉ NaI ࡢ⤖ᬗᵓ㐀ゎᯒྡྂᒇᕤᴗ኱Ꮫ࣭ᐑᓮ᛭㞝ዉ

202105150

㧗ᅽୗ࡛ྜᡂࡉࢀࡓᚤ㔞ヨᩱࡢᨺᑕග⢊ᮎ X ⥺ᅇᢡ ᐃ㸸භ᪉
ᬗ Cr5Ge3 ࡢ㧗ᅽྜᡂ࡜⤖ᬗᵓ㐀ྡྂᒇ኱Ꮫ࣭୹⩚೺

202105155

⵳㟁ᅛయᮦᩱࡢ⢊ᮎ X ⥺ᅇᢡ ᐃྡྂᒇ኱Ꮫ࣭▼ᇉ⠊࿴

202105159‵ᘧྜᡂ࡟ࡼࡾస〇ࡋࡓ FeNi ࢼࣀ⢏Ꮚࡢᵓ㐀ホ౯(ᅜ◊)⏘ᴗᢏ⾡⥲ྜ◊✲ᡤ࣭ᯇᮏ❶ᏹ

202105160

Li 㓟⣲㟁ụᨺ㟁⏕ᡂ≀ࡢ X ⥺ᅇᢡ ᐃ኱㜰኱Ꮫ࣭㛗㇂㝧Ꮚ

202105170

㧗 ࡛▷㊥㞳⛛ᗎࡀ⌧ࢀࡿ㔞య໬≀㉁ࡢᨺᑕග X ⥺ᵓ㐀ゎᯒྡྂᒇ኱Ꮫ࣭∦ᒣᑦᖾ

202106026[ᐇᆅ◊ಟ] ࣐࢖࢝ࣃ࢘ࢲ࣮୰ࡢ⤖ᬗᛶࢩࣜ࢝ࡢホ౯࠶࠸ࡕ⏘ᴗ⛉Ꮫᢏ⾡⥲ྜࢭࣥࢱ࣮࣭ᮧ஭ᓫ❶202106066ᅇᢡἲ࡟ࡼࡿ㔞య໬≀㉁ࡢᒁᡤᵓ㐀ゎᯒྡྂᒇ኱Ꮫ࣭∦ᒣᑦᖾ

202106085

Ỉ྾╔࡟క࠺㓟໬ࢢࣛࣇ࢙ࣥᒙ㛫㊥㞳ࡢኚ໬ಙᕞ኱Ꮫ࣭኱ሯ㞙ே

202106099

TeO2-Ag2O-Bi2O3 ࢸࣝࢱ࢖ࢺ࢞ࣛࢫࡢᵓ㐀ࣔࢹࣜࣥࢢ

ྡྂᒇᕤᴗ኱Ꮫ࣭᪩ᕝ▱ඞ

202106137

X ⥺ᅇᢡ ᐃ࡟ࡼࡿ㔜ඖ⣲⨨᥮ࡋࡓ࣍࢖ࢫ࣮ࣛ໬ྜ≀ࡢ⢭ᐦᵓ㐀ゎᯒྡྂᒇᕤᴗ኱Ꮫ࣭ᐑᓮ⚽ಇ

202106144

Li 㓟⣲㟁ụᨺ㟁⏕ᡂ≀ࡢ X ⥺ᅇᢡ ᐃ኱㜰኱Ꮫ࣭㛗㇂㝧Ꮚ

202106147

㧗ᅽୗ࡛ྜᡂࡉࢀࡓᚤ㔞ヨᩱࡢᨺᑕග⢊ᮎ X ⥺ᅇᢡ ᐃྡྂᒇ኱Ꮫ࣭బࠎᮌᣅஓ

202106168

ከᏍᛶ㔠ᒓ㘒యࡢග཯ᛂ࡟࠾ࡅࡿᵓ㐀ኚ໬ࡢゎ᫂ྡྂᒇ኱Ꮫ࣭᪥ୗᚰᖹ

202106179

㖡⣔ගゐ፹⏝ᮦᩱࡢศᯒ

2021D6025

ࣜࣥ㓟㕲ࣜࢳ࣒࢘㓟໬≀ᮦᩱࡢ⤖ᬗᵓ㐀ゎ

2021D6029(ᆅ⊂)ᮾி㒔❧⏘ᴗᢏ⾡◊✲ࢭࣥࢱ࣮࣭ᰁᕝ
ṇ୍ᮾ໭኱Ꮫ࣭ᑠᯘᘯ᫂

ᒁᡤ㹼㛗㊥㞳ᵓ㐀ไᚚ࡟❧⬮ࡋࡓ࢖࢜ࣥ஺᥮྾╔࡟࠾ࡅࡿぶ࿴ᛶࡢ㉳※ゎ᫂

79ಙᕞ኱Ꮫ࣭⡘ᬛோ

2021D6037◲㓟㕲ࢼࢺ࣒ࣜ࢘ࡢ⤖ᬗᵓ㐀ゎᯒᮾி኱Ꮫ࣭すᮧ┿୍%/1 㸦㌾ ; ⥺ ;$)6࣭ග㟁Ꮚศග,㸧ᐇ㦂␒ྕᐇ 㦂 ྡᡤᒓ࣭ᐇ᪋㈐௵⪅202101026◲㯤ྵ᭷ᮦᩱࡢ XAFS ศᯒ㸯

2021L1001

Cl㸪S ࡲࡓࡣ P ྵ᭷་⸆ရཎ⸆⤖ᬗከᙧࡢ XAFS

202102010ᅵተࡢࣜࣥࡢศගศᯒ

ᮾி㎰ᕤ኱Ꮫ࣭ᶫᮏὒᖹ

202102013඲ᅛయ㟁ụ࡟࠾ࡅࡿ㯮㖄㈇ᴟ/ᅛయ㟁ゎ㉁⏺㠃ࡢ㟁Ꮚ≧ែゎᯒி㒔኱Ꮫ࣭ᒣᮏ೺ኴ㑻

202102017◲㯤ྵ᭷ᮦᩱࡢ XAFS ศᯒ 2ྡྂᒇ኱Ꮫ࣭ඵᮌఙஓ

202102018࢞ࢫศᏊ྾╔≉ᛶ࡟㛵ࢃࡿ㖟ࢼࣀ⢏Ꮚࡢ໬Ꮫ≧ែྡྂᒇ኱Ꮫ࣭ྜྷ⏣᭸Ꮚ

202102023

S-K ྾཰➃ XAFS ࡟ࡼࡿ⍇⍈†ᗏ㉁ࡢᏘ⠇ㄪᰝ㛵す་⛉኱Ꮫ࣭➉ᮏ㑥Ꮚ

202102024⭉᳜≀㉁࡜ࡑࡢ㢮⦕໬ྜ≀ࡢ⏕ᡂ࡜ᾘኻ࡟࠾ࡅࡿᵓ㐀ゎ᫂ྡྂᒇ኱Ꮫ࣭∦ᒣ᪂ኴ

202102036

X ⥺྾཰ᚤ⣽ᵓ㐀ἲ࡟ࡼࡿࢼࣀࢩࣜࢥࣥࡢᒁᡤᵓ㐀ゎᯒྡྂᒇᕤᴗ኱Ꮫ࣭ᐑᓮ⚽ಇ

202102039↓ᶵᅛయ⾲㠃ୖ࡟๰ฟࡉࢀࡿཎᏊ≧άᛶⅬࡢ≧ែゎᯒྡྂᒇ኱Ꮫ࣭⧊⏣᫭࢔࣑ࣝࢽ࣒࢘㟁ụᮦᩱࡢ㌾ X ⥺྾཰ศගゎᯒ❧࿨㤋❧࿨㤋኱Ꮫ࣭ᢡ➟᭷ᇶ

202102050

AlSiO/GaN(0001)ᵓ㐀ࡢ໬Ꮫᵓ㐀ศᯒྡྂᒇ኱Ꮫ࣭኱⏣᫭⏕202102088↓ᶵࣜࣥ㓟」ሷ୰࡟ᢸᣢࡉࡏࡓ㖟໬Ꮫ≧ែࡢศᯒᐩኈࢣ࣑࢝ࣝᰴᘧ఍♫࠙ឡ▱┴ᐇᆅ◊ಟࠚ

202103006

᭷ᶵ≀ྵ᭷㔞ࡢ㧗࠸ᅵተ࡟࠾ࡅࡿࣜࣥࡢᙧែศᯒ

202103008◲㯤ྵ᭷ᮦᩱࡢ XAFS ศᯒ 3ྡྂᒇ኱Ꮫ࣭ඵᮌఙஓ

202103013

S-K ྾཰➃ XAFS ࡟ࡼࡿ⍇⍈†ࡢኟᏘ࡟᥇ྲྀࡋࡓᗏ㉁ࡢศᯒ

㛵す་⛉኱Ꮫ࣭➉ᮏ㑥Ꮚ

202102041
2021D2047

202103015

ྡྂᒇ኱Ꮫ࣭ඵᮌఙஓ
ᐃᮾ㑥኱Ꮫ࣭㕥ᮌᾈ඾(ᅜ◊)㎰ᴗ࣭㣗ရ⏘ᴗᢏ⾡⥲ྜ◊✲ᶵᵓ࣭ᒣཱྀ⣖ᏊX ⥺྾཰ศග࡟ࡼࡿࣜࢳ࣒࢘◲㯤㟁ụ⏝ṇᴟࡢ࢖࢜ࣥఏᑟࣃࢫ
ᙧᡂ࠾ࡼࡧ᪂つ⵳㟁࣓࢝ࢽࢬ࣒ࡢゎ᫂㛵す኱Ꮫ࣭ィ㈼202103022

ឡ▱┴ࡢỈ⏣ᅵተ࡟࠾ࡅࡿࣜࣥࡢ໬Ꮫᙧែ

ឡ▱┴㎰ᴗ⥲ྜヨ㦂ሙ࣭Ᏻ⸨⸅

202103054࢔࣑ࣝࢽ࣒࢘㟁ụᮦᩱࡢ㌾ X ⥺྾཰ศගゎᯒ❧࿨㤋኱Ꮫ࣭ᢡ➟᭷ᇶ

202103090

㖔≀࡟ྵࡲࢀࡿࣜࣥࡢ໬Ꮫᙧែ

ᮾி㎰ᕤ኱Ꮫ࣭ᶫᮏὒᖹ

202103104

X ⥺྾཰ᚤ⣽ᵓ㐀ἲ࡟ࡼࡿ࢔ࣝ࢝ࣜࣚ࢘໬≀୰ࡢࣚ࢘⣲ࡢ㓟໬≧ែࡢゎᯒ

2021L3001

Cl㸪S ࡲࡓࡣ P ྵ᭷་⸆ရཎ⸆⤖ᬗከᙧࡢ XAFS

202104004

࢞ࢫศᏊ྾╔≉ᛶ࡟㛵ࢃࡿ㖟ࢼࣀ⢏Ꮚࡢ໬Ꮫ≧ែྡྂᒇ኱Ꮫ࣭ྜྷ⏣᭸Ꮚ

202104014

඲ᅛయ㟁ụ࡟࠾ࡅࡿ㯮㖄㈇ᴟ/ᅛయ㟁ゎ㉁⏺㠃ࡢ㟁Ꮚ≧ែゎᯒ 2ி㒔኱Ꮫ࣭ᒣᮏ೺ኴ㑻

202104024

㖔≀࡟ྵࡲࢀࡿ㕲࡜ࣜࣥࡢ໬Ꮫᙧែ

ᮾி㎰ᕤ኱Ꮫ࣭ᶫᮏὒᖹ

202104028

Li6PS5Cl ࡢ⁐ゎ෌ᯒฟ࡟ࡼࡿ P ࡢ໬Ꮫ≧ែゎᯒ໭ᾏ㐨኱Ꮫ࣭୕ᾆ❶202104040◲㯤ྵ᭷ᮦᩱࡢ XAFS ศᯒ 4ྡྂᒇ኱Ꮫ࣭ඵᮌఙஓ

202104042⭉᳜≀㉁࡜ࡑࡢ㢮⦕ࣔࢹࣝ໬ྜ≀ࡢᵓ㐀ゎ᫂ྡྂᒇ኱Ꮫ࣭∦ᒣ᪂ኴ

202105013⭉᳜≀㉁࡜ࡑࡢ㢮⦕ࣔࢹࣝ໬ྜ≀ࡢᵓ㐀ゎ᫂ྡྂᒇ኱Ꮫ࣭∦ᒣ᪂ኴ

Si-K XAFS
202105040

ᐃྡྂᒇᕤᴗ኱Ꮫ࣭ᐑᓮ⚽ಇᐃ࡟ࡼࡿ᫬ຠ࡟క࠺పⅣ⣲㗰୰ᅛ⁐ Si ࡢ໬Ꮫ≧ែ

ኚ໬ࡢ㏣㊧ᮾ㑥኱Ꮫ࣭㕥ᮌᾈ඾஑ᕞ኱Ꮫ࣭すᇼ㯞⾰Ꮚ

202105048

ࣁࣛ࢖ࢻሷࡢฎ⌮࡟㛵ࡍࡿ᳨ウ(5)(ᅜ◊)᪥ᮏཎᏊຊ◊✲㛤Ⓨᶵᵓ࣭㧗␊ᐜᏊ

202105049⁐⼥ሷ⵨␃ヨ㦂࡟࡚ᚓࡽࢀࡓ≀㉁࡟࠾ࡅࡿ Cl ࡢᙧែ(ᅜ◊)᪥ᮏཎᏊຊ◊✲㛤Ⓨᶵᵓ࣭Ώ㒊๰

202105055

BaO-SiO2 ⤖ᬗ໬࢞ࣛࢫ࡬ࡢ Li2O ῧຍࡀࢿࢵࢺ࣮࣡ࢡᵓ㐀࡟୚࠼ࡿᙳ㡪ࡢゎ᫂

80஑ᕞ኱Ꮫ࣭Ἴከ⫄2021D5027

ࢫࢸࣥࣞࢫ㗰ୖ࡟ᯒฟࡋࡓࢩࣜ࢝ࡢ໬Ꮫ≧ែゎᯒ㸦Si K ྾཰➃
XANES㸧

ྡྂᒇ኱Ꮫ࣭㧘ℊㅬኴᮁ

2021L5002

࢔࣑ࣝࢽ࣒࢘㟁ụᮦᩱࡢ㌾ X ⥺྾཰ศගゎᯒ 3❧࿨㤋኱Ꮫ࣭ᢡ➟᭷ᇶ

2021L5005

Cl㸪S ࡲࡓࡣ I ྵ᭷་⸆ရཎ⸆⤖ᬗከᙧࡢ XAFS

202106011

࢞ࢫศᏊ྾╔≉ᛶ࡟㛵ࢃࡿ㖟ࢼࣀ⢏Ꮚࡢ໬Ꮫ≧ែྡྂᒇ኱Ꮫ࣭ྜྷ⏣᭸Ꮚ

202106021

ឡ▱┴ࡢỈ⏣ᅵተ࡟࠾ࡅࡿࣜࣥࡢ໬Ꮫᙧែ

ឡ▱┴㎰ᴗ⥲ྜヨ㦂ሙ࣭Ᏻ⸨⸅

202106034

TEM ヨᩱ㌾㹖⥺ィ ᑟධ⿦⨨ࡢࢸࢫࢺᐇ㦂㸰㸦㔜Ⅼ㹋㸱㸧ྡྂᒇ኱Ꮫ࣭⏣ῲ㞞ኵ

202106044

ᶞ⬡⾲㠃࡟┤᥋ᅛᐃ໬ࡉࢀࡓ㔠ᒓࢼࣀ⢏Ꮚࡢ໬Ꮫ≧ែࡢゎᯒ኱㜰኱Ꮫ࣭Ύ㔝ᬛྐ

202106046

Ỉ࡜◲໬≀ᅛయ㟁ゎ㉁ࡢ཯ᛂᶵᵓゎᯒி㒔኱Ꮫ࣭ᒣᮏ೺ኴ㑻ᐃᮾ㑥኱Ꮫ࣭㕥ᮌᾈ඾

Peroxymonosulfate ࢆάᛶ໬ࡋ 1 㔜㡯㓟⣲ࢆ㧗཰⋡࡛⏕ᡂࡍࡿ
202106050❅໬Ⅳ⣲ୖ㧗ᢸᣢ㕲༢ཎᏊゐ፹࡟࠾ࡅࡿῧຍ◲㯤ࡢᒁᡤᵓ㐀ゎྡྂᒇ኱Ꮫ࣭⏣ῲ㞞ኵᯒ
202106064

S-K ྾཰➃ XAFS ࡟ࡼࡿ⍇⍈†ࡢὶධἙᕝ࡛᥇ྲྀࡋࡓᗏ㉁ࡢศᯒ㛵す་⛉኱Ꮫ࣭➉ᮏ㑥Ꮚ

202106069

ࣁࣛ࢖ࢻሷࡢฎ⌮࡟㛵ࡍࡿ᳨ウ(6)(ᅜ◊)᪥ᮏཎᏊຊ◊✲㛤Ⓨᶵᵓ࣭㧗␊ᐜᏊ

202106076

㖔≀࡟ྵࡲࢀࡿࣜࣥࡢ໬Ꮫᙧែ

ᮾி㎰ᕤ኱Ꮫ࣭ᶫᮏὒᖹ

2021L6002

࢔࣑ࣝࢽ࣒࢘㟁ụᮦᩱࡢ㌾ X ⥺྾཰ศගゎᯒ 3❧࿨㤋኱Ꮫ࣭ᢡ➟᭷ᇶ

2021L6005

Cl㸪S ࡲࡓࡣ I ྵ᭷་⸆ရཎ⸆⤖ᬗከᙧࡢ XAFSᐃᮾ㑥኱Ꮫ࣭㕥ᮌᾈ඾%/8 㸦┿✵⣸እศග㸧ᐇ㦂␒ྕ
2021L4001

ᐇ 㦂 ྡᡤᒓ࣭ᐇ᪋㈐௵⪅㍈㓄఩ᆺࣇࢱࣟࢩ࢔ࢽࣥศᏊ⣔ఏᑟయ TPP[(FePc)(CN)2]2 ༢⤖
ᬗࡢゅᗘศゎග㟁Ꮚศගྡྂᒇ኱Ꮫ࣭ఀ⸨Ꮥᐶ

2021L4004

஧ḟඖ᱁Ꮚ≀㉁ࡢ๰〇࡜㟁Ꮚᵓ㐀࡟㛵ࡍࡿ◊✲ྡྂᒇ኱Ꮫ࣭ᰆཎ῟ྖ

202104026

࢚ࣆࢱ࢟ࢩࣕࣝࢢࣛࣇ࢙ࣥࡢ⏺㠃ไᚚ࡜㟁Ꮚ≧ែྡྂᒇ኱Ꮫ࣭஌ᯇ⯟202105044
202105068
202105120

࣮࢝࣎ࣥᒙ⿕そࡋࡓ❅໬࣍࢘⣲ࢼࣀࢳ࣮ࣗࣈ࡟࠾ࡅࡿ໬Ꮫ⤖ྜ≧ែࡢゎᯒ࢚ࣆࢱ࢟ࢩࣕࣝࢢࣛࣇ࢙ࣥࡢ⏺㠃ไᚚ࡜㟁Ꮚ≧ែ኱㜰኱Ꮫ࣭ᑠᯘ៞⿱
ྡྂᒇ኱Ꮫ࣭஌ᯇ⯟ⷧ⭷ࣇ࢛ࢺ࢝ࢯ࣮ࢻ⏝࣓ࢵࢩࣗࢢࣛࣇ࢙ࣥᇶᯈࡢຍ⇕Ὑί ᗘ౫Ꮡᛶࡢホ౯

ྡྂᒇ኱Ꮫ࣭㒌☨

202105142

Al/Si(111)ୖ࡟⾲㠃೫ᯒࡋࡓᴟⷧ Si ᒙࡢග㟁Ꮚศගศᯒ

ྡྂᒇ኱Ꮫ࣭኱⏣᫭⏕202105143

Nb ࢻ࣮ࣉ㓟໬ࢳࢱࣥⷧ⭷ࡢග㟁Ꮚᅇᢡィ㟼ᒸ኱Ꮫ࣭ୗᮧ຾

202105165

඲ᅛయ㟁ụ㟁ゎ㉁ࡢ⤌ᡂホ౯ྡྂᒇᕷᕤᴗ◊✲ᡤ࣭ᐑ⏣ᗣྐ

2021L5001㍈㓄఩ᆺࣇࢱࣟࢩ࢔ࢽࣥศᏊ⣔ఏᑟయ TPP[(FePc)(CN)2]2 ༢⤖
ᬗࡢゅᗘศゎග㟁Ꮚศගྡྂᒇ኱Ꮫ࣭ఀ⸨Ꮥᐶ

2021L5004

஧ḟඖ᱁Ꮚ≀㉁ࡢ๰〇࡜㟁Ꮚᵓ㐀࡟㛵ࡍࡿ◊✲ྡྂᒇ኱Ꮫ࣭ᰆཎ῟ྖ

202106015

ᒙ≧ MAX ┦໬ྜ≀ Zr3SnC2 ࡢゅᗘศゎග㟁Ꮚศගྡྂᒇ኱Ꮫ࣭ఀ⸨Ꮥᐶ

202106063

࢚ࣆࢱ࢟ࢩࣕࣝࢢࣛࣇ࢙ࣥࡢ⏺㠃ไᚚ࡜㟁Ꮚ≧ែྡྂᒇ኱Ꮫ࣭஌ᯇ⯟202106091

஧ḟඖ᱁Ꮚ≀㉁ࡢ๰〇࡜㟁Ꮚᵓ㐀࡟㛵ࡍࡿ◊✲ྡྂᒇ኱Ꮫ࣭ᰆཎ῟ྖ

202106116

㧗 ㉸ఏᑟೃ⿵≀㉁࢖ࣜࢪ࣒࢘㓟໬≀ࡢ XAFS

202106180

ࢳࢱࢽ࢔⣔ගゐ፹⏝ᮦᩱࡢศᯒ

202106184⭉᳜≀㉁࡜ࡑࡢ㢮⦕ࣔࢹࣝ໬ྜ≀ࡢᵓ㐀ゎ᫂ᐃᒸᒣ኱Ꮫ࣭ᇼỤ⌮ᜨ(ᆅ⊂)ᮾி㒔❧⏘ᴗᢏ⾡◊✲ࢭࣥࢱ࣮࣭ᰁᕝ
ṇ୍

81ྡྂᒇ኱Ꮫ࣭∦ᒣ᪂ኴ

2021L6001㍈㓄఩ᆺࣇࢱࣟࢩ࢔ࢽࣥศᏊ⣔ఏᑟయ TPP[(FePc)(CN)2]2 ༢⤖
ᬗࡢゅᗘศゎග㟁Ꮚศගྡྂᒇ኱Ꮫ࣭ఀ⸨Ꮥᐶ

%/6 㸦ⷧ⭷ ; ⥺ᅇᢡ㸧ᐇ㦂␒ྕ
202102053
202102068

ᐇ 㦂 ྡᡤᒓ࣭ᐇ᪋㈐௵⪅㧗ศᏊቃ⏺⭷ࡢ X ⥺཯ᑕ⋡ィྡྂᒇ኱Ꮫ࣭ఀ⸨ఙኴ㑻AZ31 ࣐ࢢࢿࢩ࣒࢘ྜ㔠 A6005C ࢔࣑ࣝࢽ࣒࢘ྜ㔠⇿╔᥋ྜయࡢ᥋ྜ⏺㠃࡟࠾ࡅࡿṧ␃ᛂຊホ౯ྡྂᒇᕤᴗ኱Ꮫ࣭ᡂ⏣㯞ᮍ

202102082

X ⥺㺃୰ᛶᏊ཯ᑕ⋡ἲ࡟ࡼࡿࢩࣜ࢝ⷧ⭷ࡢ┦⿵ⓗᵓ㐀ゎᯒ(୍㈈)⥲ྜ⛉Ꮫ◊✲ᶵᵓ࣭㜿ஂὠ࿴ᏹ

2021L2003

஧㓟໬Ⅳ⣲୰࡛ࡢ࢞ࢫศ㞳⏝㧗ศᏊⷧ⭷ࡢᵓ㐀ホ౯஑ᕞ኱Ꮫ࣭㧗ཎ῟

202103023

ឡ▱┴ࡢỈ⏣ᅵተ࡟࠾ࡅࡿࣜࣥࡢ໬Ꮫᙧែ

ឡ▱┴㎰ᴗ⥲ྜヨ㦂ሙ࣭Ᏻ⸨⸅

202103062

㧗ศᏊቃ⏺⭷ࡢ X ⥺཯ᑕ⋡ィྡྂᒇ኱Ꮫ࣭ఀ⸨ఙኴ㑻

202103068⇕㓟໬ࣁࣇࢽ࣒࢘ࡢ⤖ᬗᵓ㐀ホ౯ྡྂᒇ኱Ꮫ࣭኱⏣᫭⏕202103082

࣐ࢢࢿࢩ࣒࢘ྜ㔠/࢔࣑ࣝࢽ࣒࢘ྜ㔠⇿Ⓨᅽ╔ᮦࡢṧ␃ᛂຊ࡟ཬࡰࡍ 㛫ᅽᘏࡢᙳ㡪ㄪᰝྡྂᒇᕤᴗ኱Ꮫ࣭ᡂ⏣㯞ᮍ

202104062

࠙ࢩࣥࢡࣟࢺࣟࣥගィ ධ㛛ㅮ⩦఍ࠚ ᐃ࣭ゎᯒᐇ⩦ BL8S1

࠶࠸ࡕ⏘ᴗ⛉Ꮫᢏ⾡⥲ྜࢭࣥࢱ࣮࣭㔝ᮏ㇏࿴

202104076

⵳㟁ᅛయᮦᩱࡢⷧ⭷ X ⥺ᅇᢡ ᐃྡྂᒇ኱Ꮫ࣭▼ᇉ⠊࿴

202104110

㧗ศᏊቃ⏺⭷ࡢ X ⥺཯ᑕ⋡ィྡྂᒇ኱Ꮫ࣭ఀ⸨ఙኴ㑻

202104116

㔠ᒓᮦᩱࡢ⾲㠃❅໬≀ᒙࡢゎᯒ࠶࠸ࡕ⏘ᴗ⛉Ꮫᢏ⾡⥲ྜࢭࣥࢱ࣮࣭ຍ⸨ṇᶞ

202104121❅໬ࢧࣥࣉࣝࡢ໬ྜ≀ᒙࡢホ౯ ࠙ᐇᆅ◊ಟࠚ࠶࠸ࡕ⏘ᴗ⛉Ꮫᢏ⾡⥲ྜࢭࣥࢱ࣮࣭㔝ᮏ㇏࿴

202104122⇕ࣉࣛࢬ࣐ἲ࡟ࡼࡿ Nd-Fe ྜ㔠ࢼࣀ⢊ᮎࡢྜᡂ(ᅜ◊)⏘ᴗᢏ⾡⥲ྜ◊✲ᡤ࣭ᖹᒣᝆ௓

202104128

࣐ࢢࢿࢩ࣒࢘ྜ㔠/࢔࣑ࣝࢽ࣒࢘ྜ㔠⇿Ⓨᅽ╔ᮦ࡟࠾ࡅࡿṧ␃ᛂຊࡢ ᐃ᪉ྥ౫Ꮡᛶㄪᰝ

ྡྂᒇᕤᴗ኱Ꮫ࣭ᡂ⏣㯞ᮍ

202105115

X ⥺཯ᑕ⋡ἲ࡟ࡼࡿࢩࣜ࢝ࣁ࢖ࣈࣜࢵࢻ⭷ࡢᵓ㐀ゎᯒ(୍㈈)⥲ྜ⛉Ꮫ◊✲ᶵᵓ࣭㜿ஂὠ࿴ᏹ

202105134

ࣂ࢖࣐࢜ࢫࢆ฼⏝ࡋࡓᅛᙧ⇞ᩱࡢ XRD ศᯒ࠶࠸ࡕ⏘ᴗ⛉Ꮫᢏ⾡⥲ྜࢭࣥࢱ࣮࣭㔝ᮏ㇏࿴

202105176

㔠ᒓࢼࣀ⢏Ꮚࡢᵓ㐀ゎᯒ(ᅜ◊)⏘ᴗᢏ⾡⥲ྜ◊✲ᡤ࣭ᖹᒣᝆ௓

202105178

඲ᅛయ㟁ụ㟁ゎ㉁ࡢ⤌ᡂホ౯ྡྂᒇᕷᕤᴗ◊✲ᡤ࣭ᐑ⏣ᗣྐ

202105180

ࢢࣛࣇ࢙ࣥໟ᥋ࢮ࢜ࣛ࢖ࢺ⭷ࡢᵓ㐀ಙᕞ኱Ꮫ࣭኱ሯ㞙ே

202105181

X ⥺ᅇᢡ࡟ࡼࡿ㠀㈗㔠ᒓ⣔ᢸᣢᆺ࢔ࣥࣔࢽ࢔ྜᡂゐ፹ࡢᵓ㐀ゎ᫂(ϩ)ྡྂᒇ኱Ꮫ࣭Ọᒸ຾ಇ

202106024

ࢯࣇࢺ໬Ꮫᡭἲ࡟ࡼࡾస〇ࡋࡓ㓟໬≀㉸ⷧ⭷ࡢᵓ㐀ほᐹᮾி⌮⛉኱Ꮫ࣭⸨ᮏ᠇ḟ㑻

202106152

㧗ศᏊቃ⏺⭷ࡢ X ⥺཯ᑕ⋡ィྡྂᒇ኱Ꮫ࣭ఀ⸨ఙኴ㑻

202106176

202106185
202106191

࣐ࢢࢿࢩ࣒࢘ྜ㔠/࢔࣑ࣝࢽ࣒࢘ྜ㔠⇿Ⓨᅽ╔ᮦ࡟࠾ࡅࡿṧ␃ᛂຊࡢ ᐃ᪉ྥ౫Ꮡᛶㄪᰝ
ⓑⰍ LED ᛂ⏝ࢆ┠ⓗ࡜ࡋࡓ᪂つ㓟໬≀࠾ࡼࡧ㓟❅໬≀⺯ගయࡢ⤖ᬗᵓ㐀ゎᯒ

ྡྂᒇᕤᴗ኱Ꮫ࣭ᡂ⏣㯞ᮍຍィᏛᅬᒸᒣ⌮⛉኱Ꮫ࣭బ⸨Ὀྐ
࠶࠸ࡕ⏘ᴗ⛉Ꮫᢏ⾡⥲ྜࢭࣥࢱ࣮࣭ᮧ஭ᓫ❶[ᐇᆅ◊ಟ]ࢭ࣑ࣛࢵࢡ⾲㠃ࡢ⤖ᬗ≧ែࡢㄪᰝ%/6 㸦; ⥺ࢺ࣏ࢢࣛࣇ࢕࣭; ⥺ &7㸸ឡ▱┴㸧ᐇ㦂␒ྕ
2021a0001
2021a0003

ᐇ 㦂 ྡᡤᒓ࣭ᐇ᪋㈐௵⪅㧗ศゎ⬟ X ⥺ CT ࡟ࡼࡿ࢔ࢺ࣐࢖ࢬ㔠ᒓ⢊ᮎࡢෆ㒊ẼᏍほᐹ࡜ࡑࡢపῶ໬ᢏ⾡㛤Ⓨ࣮࢟ࣛḞ㝗⮬ື᳨ᰝࢩࢫࢸ࣒ᵓ⠏࡟ྥࡅࡓࣃ࣮࣡ࢹࣂ࢖ࢫ༙ᑟ

82ྡྂᒇ኱Ꮫ࣭Ḉ஭㑳ஓྡྂᒇ኱Ꮫ࣭ཎ⏣ಇኴయ⤖ᬗࡢ X ⥺ࢺ࣏ࢢࣛࣇ࢕ἲ࡟ࡼࡿḞ㝗ホ౯
2021a0004

࢔ࣔࣀࢧ࣮࣐࣭ࣝHVPE ᇶᯈ GaN ⤖ᬗࡢḞ㝗ホ౯ྡྂᒇ኱Ꮫ࣭ཎ⏣ಇኴ2021a0010

ゐ፹ෆ⣽Ꮝࡢほᐹྡྂᒇ኱Ꮫ࣭ᒣ⏣༤ྐ2021a0011

BL8S2 ࡟࠾ࡅࡿ CFRTP ࡢ X ⥺ CT

2021a0012

ᨺᑕගࢺ࣏ࢢࣛࣇ࢕࡟ࡼࡿ GaN ⤖ᬗࡢホ౯

2021a0013

࣮࢟ࣛḞ㝗⮬ື᳨ᰝࢩࢫࢸ࣒ᵓ⠏࡟ྥࡅࡓࣃ࣮࣡ࢹࣂ࢖ࢫ༙ᑟ
య⤖ᬗࡢ X ⥺ࢺ࣏ࢢࣛࣇ࢕ἲ࡟ࡼࡿḞ㝗ホ౯ 22021a0014

GaN ᇶᯈࡢ X ⥺ࢺ࣏ほᐹᐇ㦂2021a0016

ᶍᨃ㟁ụෆ㒊ࡢࣜࢳ࣒࢘㔠ᒓࡢほᐹ

2021a0017

2021a0018

2021a0019
2021a0021
2021a0025

ᐃ࡟ࡘ࠸࡚ 7࠶࠸ࡕ⏘ᴗ⛉Ꮫᢏ⾡⥲ྜࢭࣥࢱ࣮࣭ྜྷ⏣㝧Ꮚྡྂᒇ኱Ꮫ࣭ව㏆ᑗ୍ྡྂᒇ኱Ꮫ࣭ཎ⏣ಇኴྡྂᒇ኱Ꮫ࣭⏣୰ᩔஅᰴᘧ఍♫ SOKEN࣭㕥ᮌ೺஢࠙㔜Ⅼࣉࣟࢪ࢙ࢡࢺࠚ

LIGA ࣉࣟࢭࢫࢆ⏝࠸ࡓᑠᝨᫍ᥈ᰝᶵࡣࡸࡪࡉヨᩱศᯒ⏝㖡〇ヨᩱྎࡢసᡂ
AichiSR BL8S2 ࣅ࣮࣒ࣛ࢖ࣥ࡬ࡢ㹖⥺ᬯど㔝 CT ⿦⨨࡟ࡼࡿࢧࣥࣉࣝ᧜ീᐇ㦂 2
AichiSR BL8S2 ࣅ࣮࣒ࣛ࢖ࣥ࡬ࡢ㹖⥺ᬯど㔝 CT ⿦⨨࡟ࡼࡿࢧࣥࣉࣝ᧜ീᐇ㦂㸱X ⥺ CT ࡟ࡼࡿᶞ⬡」ྜᮦᩱෆ㒊ࡢほᐹྡྂᒇ኱Ꮫ࣭Ḉ஭㑳ஓྡྂᒇ኱Ꮫ࣭◁ཱྀᑦ㍤ྡྂᒇ኱Ꮫ࣭◁ཱྀᑦ㍤ྡྂᒇ኱Ꮫ࣭ᯇᮏᫀᶞ

ࣜࢳ࣒࢘࢖࢜ࣥ㟁ụ඘ᨺ㟁≧ែࡢ㸰ḟඖ XAFS ほᐹ㸱㸦㔜Ⅼ㹇㸰㸧ྡྂᒇ኱Ꮫ࣭Ώ㒊Ꮥ

2021a0026

XAFS-X ⥺ CT ἲ࡟ࡼࡿ་⸆ရ㘄๣ࡢᵓ㐀ゎᯒᮾ㑥኱Ꮫ࣭㔝ཱྀಟ἞2021a0031

GaN ᇶᯈࡢ X ⥺ࢺ࣏ほᐹᐇ㦂ྡྂᒇ኱Ꮫ࣭⏣୰ᩔஅ2021a0032

㧗ศゎ⬟ X ⥺ CT ࡟ࡼࡿ࢔ࢺ࣐࢖ࢬ㔠ᒓ⢊ᮎࡢෆ㒊ẼᏍほᐹ࡜ࡑࡢపῶ໬ᢏ⾡㛤Ⓨྡྂᒇ኱Ꮫ࣭Ḉ஭㑳ஓ2021a0034

CNT ࢩࣜ࢝ከᏍయ᩿⇕ᮦࡢ୕ḟඖᵓ㐀ほᐹྡྂᒇ኱Ꮫ࣭ୖ㔝ᬛỌ

2021a0035

CFRP ᑕฟᡂᙧရࡢෆ㒊ᵓ㐀ࡢほᐹ࠶࠸ࡕ⏘ᴗ⛉Ꮫᢏ⾡⥲ྜࢭࣥࢱ࣮࣭ྜྷ⏣㝧Ꮚ

2021a0036

ཎᏊ᰾஝ᯈ࡟ࡼࡿ X ⥺⏬ീ᧜ᙳ᮲௳ࡢ᳨ウྡྂᒇ኱Ꮫ࣭ཎ⏣ಇኴ2021a0037

AichiSR BL8S2 ࣅ࣮࣒ࣛ࢖ࣥ࡟ᵓ⠏ࡋࡓ㹖⥺ᬯど㔝ἲ࡟ᇶ࡙ࡃ
ᒅᢡࢥࣥࢺࣛࢫࢺ CT ࡟ࡼࡿ㓇⡿ࡢ᧜ᙳྡྂᒇ኱Ꮫ࣭◁ཱྀᑦ㍤

2021a0040

X ⥺ CT ࡟ࡼࡿࢥࣥࢡ࣮ࣜࢺෆ㒊ࡢ⤌⧊ほᐹ㔠ᇛᏛ㝔኱Ꮫ࣭ᮔ┦ಇ2021a0041

Y ⣔⁐ᑕ⭷ࡢෆ㒊✵㝽ほᐹᐑᇛ┴⏘ᴗᢏ⾡⥲ྜࢭࣥࢱ࣮࣭ෆᾏᏹ࿴

2021a0045

2021a0046

ࣜࢳ࣒࢘࢖࢜ࣥ㟁ụ඘ᨺ㟁≧ែࡢ㸰ḟඖ XAFS ほᐹ㸲㸦㔜Ⅼ㹇㸰㸧㠉᪂ⓗࢩࣥࢡࣟࢺࣟࣥගCTᢏ⾡࡟ࡼࡿḟୡ௦ࣔࣀ࡙ࡃࡾ⏘ᴗ๰ᡂ㹙M4㹛

2021a0047

ゐ፹ෆ⣽Ꮝࡢほᐹ2021a0048

ࣃ࢘ࢲ࣮ࣇ࢓ࣥࢹ࣮ࢩࣙࣥᡂᆺయࡢෆ㒊ᵓ㐀ほᐹ㹙M4㹛

2021a0049

2021a0051

2021a0052

ྡྂᒇ኱Ꮫ࣭Ώ㒊Ꮥྡྂᒇ኱Ꮫ࣭◁ཱྀᑦ㍤ྡྂᒇ኱Ꮫ࣭ᒣ⏣༤ྐ㠉᪂ⓗࢩࣥࢡࣟࢺࣟࣥගCTᢏ⾡࡟ࡼࡿḟୡ௦ࣔࣀ࡙ࡃࡾ⏘ᴗ๰ᡂ㹙M4㹛㠉᪂ⓗࢩࣥࢡࣟࢺࣟࣥගCTᢏ⾡࡟ࡼࡿḟୡ௦ࣔࣀ࡙ࡃࡾ⏘ᴗ๰ᡂ㹙M4㹛㠉᪂ⓗࢩࣥࢡࣟࢺࣟࣥගCTᢏ⾡࡟ࡼࡿḟୡ௦ࣔࣀ࡙ࡃࡾ⏘ᴗ๰
ᡂ㹙M4㹛

83

᪥ᮏ࣓ࢼ࣮ࢻ໬⢝ရᰴᘧ఍♫࣭ὸ㔝ᾈᚿ࠙㔜
Ⅼࣉࣟࢪ࢙ࢡࢺࠚ
ྡྂᒇ኱Ꮫ࣭◁ཱྀᑦ㍤ྡྂᒇ኱Ꮫ࣭◁ཱྀᑦ㍤ྡྂᒇ኱Ꮫ࣭◁ཱྀᑦ㍤

2021a0053
2021a0054

ཎᏊ᰾஝ᯈ࡟ࡼࡿ X ⥺⏬ീ᧜ᙳ᮲௳ࡢ᳨ウ II㠉᪂ⓗࢩࣥࢡࣟࢺࣟࣥගCTᢏ⾡࡟ࡼࡿḟୡ௦ࣔࣀ࡙ࡃࡾ⏘ᴗ๰ᡂྡྂᒇ኱Ꮫ࣭ཎ⏣ಇኴྡྂᒇ኱Ꮫ࣭Ḉ஭㑳ஓ2021a0062

࣌ࣥࢹࣝᖸ΅࡟ࡼࡿ༢⤖ᬗホ౯ྡྂᒇ኱Ꮫ࣭໭ཱྀ㞞ᬡ2021a0065

X ⥺ CTྡྂᒇ኱Ꮫ࣭ᯇᮏᫀᶞ

2021a0066

BL8S2 ࡟࠾ࡅࡿ CFRTP ࡢ X ⥺ CT

2021a0068

ゐ፹ෆ⣽Ꮝࡢほᐹྡྂᒇ኱Ꮫ࣭ᒣ⏣༤ྐ2021a0070

㣗ရཎᩱࡢຍᕤ࡟ࡼࡿᵓ㐀ኚ໬࡟㛵ࡍࡿほᐹ࣭ゎᯒᐑᇛ┴⏘ᴗᢏ⾡⥲ྜࢭࣥࢱ࣮࣭⩚⏕ᖾᘯ2021a0074

LIGA ࣉࣟࢭࢫ࡟ࡼࡿ㉸ᚤ⣽ᵓ㐀యస〇ᢏ⾡ࡢ㛤Ⓨྡྂᒇ኱Ꮫ࣭Ḉ஭㑳ஓ2021a0075

ᐃᐃ࡟ࡘ࠸࡚ 9㧗ศゎ⬟ X ⥺ CT ࡟ࡼࡿ࢔ࢺ࣐࢖ࢬ㔠ᒓ⢊ᮎࡢෆ㒊ẼᏍほᐹ࡜ࡑࡢపῶ໬ᢏ⾡㛤Ⓨᐃ࠶࠸ࡕ⏘ᴗ⛉Ꮫᢏ⾡⥲ྜࢭࣥࢱ࣮࣭ྜྷ⏣㝧Ꮚྡྂᒇ኱Ꮫ࣭Ḉ஭㑳ஓ2021a0077

X ⥺ CTྡྂᒇ኱Ꮫ࣭ᯇᮏᫀᶞ

2021a0081

ࢲ࢖ࣖࣔࣥࢻࡢ㌿఩࠾ࡼࡧṍࡳ ᐃྡྂᒇ኱Ꮫ࣭⏣ῲ㞞ኵ2021a0082

LIGA ࣉࣟࢭࢫ࡟ࡼࡿ㉸ᚤ⣽ᵓ㐀యస〇ᢏ⾡ࡢ㛤Ⓨྡྂᒇ኱Ꮫ࣭Ḉ஭㑳ஓ%/6 㸦ᗈゅ࣭ᑠゅ ; ⥺ᩓ஘㸧ᐇ㦂␒ྕ
202102037
202102059

ͤࡣබ㛤ᘏᮇࡢ⏦ㄳࡀ࠶ࡗࡓࡶࡢᐇ 㦂 ྡᡤᒓ࣭ᐇ᪋㈐௵⪅ᑠゅᩓ஘ἲ࡟ࡼࡿศᩓᚤ⢏Ꮚࡢᵓ㐀ゎᯒྡྂᒇᕤᴗ኱Ꮫ࣭ᒣᮏ຾ᏹ

ࣔࣔᯝᐇࡢ㌾໬࡟㛵୚ࡍࡿExpansinࡢᡂ⇍㐣⛬࡟࠾ࡅࡿ⣽⬊ቨᵓ㐀ኚ໬ࡢ┤᥋ほᐹ㏆␥኱Ꮫ࣭▼୸ᜨ

202102104

㧗ศᏊቃ⏺⭷ࡢ X ⥺཯ᑕ⋡ィྡྂᒇ኱Ꮫ࣭ఀ⸨ఙኴ㑻

2021D2041

␯Ỉᛶ┦஫స⏝ࢆ᭷ࡍࡿࢹࣗ࢔ࣝࢿࢵࢺ࣮࣡ࢡࢤࣝࡢᵓ㐀ゎᯒ໭ᾏ㐨኱Ꮫ࣭୰ᓥ♸202103018

Microstructure study of carbon nanotubes nanocomposites
with aromatic polyamidesಙᕞ኱Ꮫ࣭➉ෆ೺ྖ

202103061

ATP ຍỈศゎ㐣⛬࡛ࡢ࣑࢜ࢩࣥࡢᵓ㐀ࢲ࢖ࢼ࣑ࢡࢫ

ྡྂᒇ኱Ꮫ࣭ᮡᮏὈఙ

202103077

⧞ࡾ㏉ࡋఙ㛗ୗ࡟࠾ࡅࡿ⎔ືࢤࣝࡢఙ㛗ㄏ㉳⤖ᬗ໬ほᐹᮾி኱Ꮫ࣭┾ᘪⓡ୍

202103084

ࢪࣝࢥࢽ࣒࢘㓟໬≀ᅛ┦ࡢ⁐ゎᶵᵓࡢゎ᫂ࡢࡓࡵࡢ⾲㠃ศᯒி㒔኱Ꮫ࣭ᑠᯘ኱ᚿ

202103091 ͤࢩࣜ࢝ྵ᭷࣏࣐࣮ࣜࡢ┦ᵓ㐀ㄪᰝྡྂᒇᕤᴗ኱Ꮫ࣭ᯘᖿ኱

202103096

࢔࣑ࣝࢽ࣒࢘ྜ㔠ࡢ X ⥺ᑠゅᩓ஘(බ㈈)⛉Ꮫᢏ⾡஺ὶ㈈ᅋ࣭ᒸᓥᩄᾈ

202103098

SAXS ࡟ࡼࡿ࣏࣐࣮ࣜࡢ࣓ࢯࢫࢣ࣮ࣝᵓ㐀ࡢ ᐃ࡜ゎᯒ㔠ἑ኱Ꮫ࣭℧೺ኴ㑻

202104063

࠙ࢩࣥࢡࣟࢺࣟࣥගィ ධ㛛ㅮ⩦఍ࠚ ᐃ࣭ゎᯒᐇ⩦ BL8S3࠶࠸ࡕ⏘ᴗ⛉Ꮫᢏ⾡⥲ྜࢭࣥࢱ࣮࣭㔝ᮏ㇏࿴

202104097

࢚ࣞࢡࢺࣟࢫࣆࢽࣥࢢἲ࡟ࡼࡗ࡚ᚓࡽࢀࡿࢼࣀࣇ࢓࢖ࣂ࣮⭷ࡢᵓ㐀ゎᯒྡྂᒇ኱Ꮫ࣭㧗ᶫ೔ኴ㑻

202104099⇕ྍረᛶ࢚ࣛࢫࢺ࣐࣮ࡢ࣏࣐࣮ࣜ࢔ࣟ࢖ᵓ㐀ࡢศᯒ⚟஭኱Ꮫ࣭ᒣୗ⩏⿱

202104119

᭷ᶵಟ㣭㔠ᒓ㓟໬≀ࢼࣀ⢏Ꮚࡢ⁐ᾮ୰࡛ࡢศᩓ࣭จ㞟ᣲື㏣㊧ᮾ໭኱Ꮫ࣭すᇼ㯞⾰Ꮚ

202104120⤖ᬗᛶᡂศࢆྵࡴ୕ඖඹ㔜ྜయ࢚ࣛࢫࢺ࣐࣮ࡢ㧗ḟᵓ㐀࡜ຊᏛ≀ᛶ

⁠㈡┴❧኱Ꮫ࣭➉ୗᏹᶞ

202104124

ᗈゅ X ⥺࡟ࡼࡿ⅕㣤⡿࠾ࡼࡧ⡿⢊ࡢ⤖ᬗ໬ᗘࡢ ᐃᐑᇛ኱Ꮫ࣭ᗉᏊ┿ᶞ

202104127

Zn ྵ᭷ࢼࣀ⢏Ꮚศᩓ࣏࣐࣮ࣜࣈࣞࣥࢻࡢᵓ㐀ゎᯒឡ▱ᕤᴗ኱Ꮫ࣭⚟᳃೺୕

202105087

ᑠゅᩓ஘࡟ࡼࡿ RTa3O9 ࡢᵓ㐀ゎᯒ

202105101

ᑠゅᩓ஘ἲ࡟ࡼࡿ⁐፹ศᩓᚤ⢏Ꮚࡢᵓ㐀ゎᯒྡྂᒇᕤᴗ኱Ꮫ࣭ᒣᮏ຾ᏹ

202105135

ࣂ࢖࣐࢜ࢫࢆ฼⏝ࡋࡓᅛᙧ⇞ᩱࡢ X ⥺ᑠゅᩓ஘ ᐃ࠶࠸ࡕ⏘ᴗ⛉Ꮫᢏ⾡⥲ྜࢭࣥࢱ࣮࣭㔝ᮏ㇏࿴(୍㈈)ࣇ࢓࢖ࣥࢭ࣑ࣛࢵࢡࢫࢭࣥࢱ࣮࣭ᯇᖹ
ᜏ᫛

84

202105149

ࣇ࢚ࣝ࢜ࣟࣛࢫࢺ࣐࣮࡜࢖࢜ࣥᾮయ࠿ࡽ࡞ࡿ࢖࢜ࣥࢤࣝࡢᵓ㐀ゎᯒྡྂᒇ኱Ꮫ࣭㧗ᶫ೔ኴ㑻

202105154

㧗ศᏊ₶⁥Ἔࡢᑠゅ X ⥺ᩓ஘ィྡྂᒇ኱Ꮫ࣭ఀ⸨ఙኴ㑻

202105157

ᗈゅ X ⥺࡟ࡼࡿ㇜➽⫗⣽⬊Ỉ⁐ᛶᡂศࡢ⤖ᬗホ౯ᐑᇛ኱Ꮫ࣭㡲⏣⩏ே

202105163

࣐࢞ࣥ⥺↷ᑕ࡟ࡼࡿ࣏ࣜ࢜ࣞࣇ࢕ࣥࡢ⤖ᬗ࣓ࣛࣛᵓ㐀ኚ໬

⁠㈡┴❧኱Ꮫ࣭➉ୗᏹᶞ

202105164⡿ࡢෆ㒊ᵓ㐀ࡀ㣗࿡࡟ཬࡰࡍᙳ㡪ࡢゎ᫂ឡ▱┴㎰ᴗ⥲ྜヨ㦂ሙ࣭㇂ಇ⏨202105167

Al ྜ㔠ࡢ X ⥺ᑠゅᩓ஘㸦㸰㸧(බ㈈)⛉Ꮫᢏ⾡஺ὶ㈈ᅋ࣭ᒸᓥᩄᾈ

202105175

ᮌᮦࡢ≀ᛶண ࣔࢹࣝᵓ⠏࡟ྥࡅࡓ࣑ࢡࣟࣇ࢕ࣈࣜࣝഴゅィி㒔኱Ꮫ࣭ᑠᯘຍ௦Ꮚ

2021D5037

ᑠゅ X ⥺࡟ࡼࡿ㇜➽⫗⣽⬊Ỉ⁐ᛶᡂศࡢ⤖ᬗホ౯ᐑᇛ኱Ꮫ࣭㡲⏣⩏ே

202106126

ࢭ࣮ࣝࣟࢫࢼࣀࣇ࢓࢖ࣂ࣮ࡢจ㞟ᵓ㐀ゎᯒᐑᇛ┴⏘ᴗᢏ⾡⥲ྜࢭࣥࢱ࣮࣭㐲⸨ᓫṇ

202106131

ࣈࣟࢵࢡඹ㔜ྜయࡀᙧᡂࡍࡿ᪂つ࣑ࢡࣟ┦ศ㞳ᵓ㐀㸲ྡྂᒇᕤᴗ኱Ꮫ࣭ᒣᮏ຾ᏹ

202106151⇕ྍረᛶ࢚ࣛࢫࢺ࣐࣮ࡢ࣏࣐࣮ࣜ࢔ࣟ࢖ᵓ㐀ࡢศᯒ⚟஭኱Ꮫ࣭ᒣୗ⩏⿱

202106153

㧗ศᏊ₶⁥Ἔࡢᑠゅ X ⥺ᩓ஘ィྡྂᒇ኱Ꮫ࣭ఀ⸨ఙኴ㑻

202106163

ATP ຍỈศゎ㐣⛬࡛ࡢ࣑࢜ࢩࣥࡢᵓ㐀ࢲ࢖ࢼ࣑ࢡࢫ

ྡྂᒇ኱Ꮫ࣭ᮡᮏὈఙ

202106170

᭷ᶵಟ㣭㔠ᒓ㓟໬≀ࢼࣀ⢏Ꮚࢥ࣏ࣥࢪࢵࢺࡢจ㞟≧ែホ౯ᮾ໭኱Ꮫ࣭すᇼ㯞⾰Ꮚ

202106171

᭷ᶵಟ㣭㔠ᒓ㓟໬≀ࢼࣀ⢏Ꮚࡢ⁐ᾮ୰࡛ࡢศᩓ࣭จ㞟ᣲື㏣㊧ᮾ໭኱Ꮫ࣭すᇼ㯞⾰Ꮚ

202106172

࣋ࢩࢡࣝࡢࢧ࢖ࢬィᮾி኱Ꮫ࣭ෆᒣ⪷୍

202106173

᭷ᶵ㓄఩ᏊඹᏑୗ࡟࠾ࡅࡿࢪࣝࢥࢽ࣒࢘ࢥࣟ࢖ࢻࡢศᯒ

ி㒔኱Ꮫ࣭ᑠᯘ኱ᚿ

202106181

Pt ࢼࣀ⢏Ꮚࡢ⢏Ꮚᚄ࣭⢏Ꮚ㛫㊥㞳ࡢ ᐃᰴᘧ఍♫࢔ࣖ࣎࠙ឡ▱┴ᐇᆅ◊ಟࠚ

202106186

㕲㗰ᮦᩱࡢ X ⥺ᑠゅᩓ஘(බ㈈)⛉Ꮫᢏ⾡஺ὶ㈈ᅋ࣭ᒸᓥᩄᾈ

202106188
202106189

ࢺࣜࣈࣟࢵࢡඹ㔜ྜయ 2 ᵝࣈࣞࣥࢻ࠿ࡽᙧᡂࡉࢀࡿ‽࿘ᮇᛶࠊ࠶
ࡿ࠸ࡣ㏆ఝ⤖ᬗᛶ࣑ࢡࣟ┦ศ㞳ᵓ㐀ࡢ⢭ᐦᵓ㐀ゎᯒ
SAXS ࡟ࡼࡿ࣏࣐࣮ࣜࡢ࣓ࢯࢫࢣ࣮ࣝᵓ㐀ࡢ ᐃ࡜ゎᯒ%/6 㸦◳ ; ⥺ ;$)6,,㸧202102002
202102007
202102022 ͤ

202102049

ᐇ 㦂 ྡ」ྜ㓟໬≀ゐ፹ࡢ XAFSᡤᒓ࣭ᐇ᪋㈐௵⪅ᐃྡྂᒇ኱Ꮫ࣭㑦ḟᬛ᪂つ⺯ගయᮦᩱ࡟࠾ࡅࡿⓎග୰ᚰ࢖࢜ࣥࡢ㓄఩⎔ቃཬࡧ౯ᩘไ
ᚚ࡜Ⓨගᙉᗘྥୖࡢྲྀࡾ⤌ࡳ
᪂ 2 㐃࣑࣮ࣛࡢヨ㦂฼⏝㸦㔜Ⅼ㹋㸱㸧፹ࡢ XAFS ࡟ࡼࡿᵓ㐀ゎᯒ࣮࢜ࣉ࣓ࣥࢱࣝࢧ࢖ࢺࢆࡶࡘ MOF ࡢ XAFS ࢫ࣌ࢡࢺࣝࡢ⵨Ẽᑟධᅽ࠾ࡼࡧ⤖ᬗᙧែ౫Ꮡᛶࡢゎ᫂⎔ቃゐ፹ࡢ XAFS

202102078ࢼࣀ⢏Ꮚゐ፹ࡢ XAFS

202103001

᪂ 2 㐃࣑࣮ࣛࡢヨ㦂฼⏝㸦㔜Ⅼ㹋3㸧ᐃ(ᅜ◊)⌮໬Ꮫ◊✲ᡤ࣭ୖཱྀ㈼ྡྂᒇ኱Ꮫ࣭ᆏᮏ⿱ಇ
ྡྂᒇ኱Ꮫ࣭ᑠ⃝ṇ㑥ᐃྡྂᒇ኱Ꮫ࣭ᑠ⃝ṇ㑥ྡྂᒇ኱Ꮫ࣭⏣ῲ㞞ኵFe ゐ፹࠿ࡽࡢ༢ᒙ࣮࢝࣎ࣥࢼࣀࢳ࣮ࣗࣈᡂ㛗㐣⛬ࡢࡑࡢሙ
XAFS

㇏ᶫᢏ⾡⛉Ꮫ኱Ꮫ࣭୰㔝⿱⨾ྡྂᒇ኱Ꮫ࣭⏣ῲ㞞ኵ❅⣲ศᏊ࠿ࡽࡢ࢔ࣥࣔࢽ࢔ྜᡂ࡟᭷ຠ࡞ᢸᣢ㔠ᒓࢡࣛࢫࢱ࣮ゐ202102060

202103010

㔠ἑ኱Ꮫ࣭℧೺ኴ㑻ͤࡣබ㛤ᘏᮇࡢ⏦ㄳࡀ࠶ࡗࡓࡶࡢ

ᐇ㦂␒ྕ
202102001ྡྂᒇ኱Ꮫ࣭㧗㔝ᩔᚿᐃྡᇛ኱Ꮫ࣭୸ᒣ㝯ᾈ

202103026

2021 ᖺᗘ XAFS ኟࡢᏛᰯ ᐃᐇ⩦ղྡྂᒇ኱Ꮫ࣭ᑠᕝᬛྐ

202103047

⵳㟁ᮦᩱࡢ㟁Ꮚ≧ែศᯒᮾ໭኱Ꮫ࣭ᑠᯘᘯ᫂

202103049

㧗ࣞ࣋ࣝᨺᑕᛶᗫᲠయ୰ࡢ୙⁐ゎṧ´㸦ⓑ㔠᪘ྜ㔠㸧ࡢᵓ㐀ゎᯒᮾி㒔ᕷ኱Ꮫ࣭ᯇᾆ἞᫂

202103050

NTA ࢔࣑ࢻ⣔྾╔ᮦ࡟྾╔ࡉࢀࡓࣃࣛࢪ࣒࢘ඖ⣲ࡢᵓ㐀ゎᯒᮾி㒔ᕷ኱Ꮫ࣭ᯇᾆ἞᫂

85

202103051

ࢼࣀ⢏Ꮚゐ፹ࡢ XAFS

202103072

Cu ⣔ヨᩱࡢ XAFS ࢫ࣌ࢡࢺࣝ ᐃ࠙ᐇᆅ◊ಟࠚ

202104011
202104019
202104021

ᐃྡྂᒇ኱Ꮫ࣭ᑠ⃝ṇ㑥JX 㔠ᒓᰴᘧ఍♫࠙ឡ▱┴ᐇᆅ◊ಟࠚ

ArO2 ࢟ࣕࣜ࢔࢞ࢫࢆ⏝࠸ࡓ࡜ࡁࡢ Co ゐ፹࠿ࡽࡢ༢ᒙ࣮࢝࣎ࣥ
ࢼࣀࢳ࣮ࣗࣈᡂ㛗㐣⛬ࡢࡑࡢሙ XAFSᐃ

᪂ 2 㐃࣑࣮ࣛࡢヨ㦂฼⏝㸦㔜Ⅼ㹋㸱㸧ྡᇛ኱Ꮫ࣭୸ᒣ㝯ᾈྡྂᒇ኱Ꮫ࣭⏣ῲ㞞ኵ᪂つ⺯ගయᮦᩱ࡟࠾ࡅࡿⓎග୰ᚰ࢖࢜ࣥࡢ㓄఩⎔ቃཬࡧ౯ᩘไ
ᚚ࡜Ⓨගᙉᗘྥୖࡢྲྀࡾ⤌ࡳ㇏ᶫᢏ⾡⛉Ꮫ኱Ꮫ࣭୰㔝⿱⨾202104048

㔜ඖ⣲ࢆ⏝࠸ࡓ㟁ụᮦᩱࡢ XAFS ゎᯒ❧࿨㤋኱Ꮫ࣭ᢡ➟᭷ᇶ

202104057

Mn ᅛ⁐ TiO2 ୖ࡟ᢸᣢࡉࢀࡓ RuOx ࡢᒁᡤᵓ㐀ゎᯒྡྂᒇ኱Ꮫ࣭⧊⏣᫭

202104059

MOF-on-MOF ᆺ」ྜከᏍᛶᮦᩱࡢ✚ᒙⷧ⭷ᵓ㐀ࡢゎ᫂ி㒔኱Ꮫ࣭኱➉◊୍

202105003

NTA ࢔࣑ࢻ⣔྾╔ᮦ࡟྾╔ࡉࢀࡓࣃࣛࢪ࣒࢘ඖ⣲ࡢᵓ㐀ゎᯒᮾி㒔ᕷ኱Ꮫ࣭ᯇᾆ἞᫂

202105004

㧗ࣞ࣋ࣝᨺᑕᛶᗫᲠయ୰ࡢ୙⁐ゎṧ´㸦ⓑ㔠᪘ྜ㔠㸧ࡢᵓ㐀ゎᯒᮾி㒔ᕷ኱Ꮫ࣭ᯇᾆ἞᫂

202105006

㓟໬≀ᅛᐃ໬㔠ᒓ㘒యࡢ XAFSྡྂᒇ኱Ꮫ࣭㑦ḟᬛ

202105009

༢ཎᏊゐ፹ࡢᒁᡤᵓ㐀ゎᯒ

202105010

ᐃྡྂᒇ኱Ꮫ࣭⧊⏣᫭

Ir ゐ፹࠿ࡽࡢ༢ᒙ࣮࢝࣎ࣥࢼࣀࢳ࣮ࣗࣈᡂ㛗㐣⛬ࡢࡑࡢሙ
XAFS

ᐃྡᇛ኱Ꮫ࣭୸ᒣ㝯ᾈ

202105016⏕⌮㞀ᐖࢆⓎ⏕ࡋࡓ࢖ࢳࢦࡢⴥࡢ↓ᶵඖ⣲࣐ࢵࣆࣥࢢ

ᐑᇛ኱Ꮫ࣭⳥ᆅ㑳

202105052」ྜᆺ MOF ࡢ྾╔≧ែไᚚୗ࡛ࡢ XAFS ࢫ࣌ࢡࢺࣝィྡྂᒇ኱Ꮫ࣭ᆏᮏ⿱ಇ

202105059

Ce2Pt6X15 ⣔ࡢ X ⥺྾཰ศග(බ㈈)⛉Ꮫᢏ⾡஺ὶ㈈ᅋ࣭ᒸᓥᩄᾈ

202106004㈗㔠ᒓ༢ཎᏊྵ᭷༝㔠ᒓ㓟໬≀⾲㠃ゐ፹ࡢᒁᡤᵓ㐀ゎᯒྡྂᒇ኱Ꮫ࣭⧊⏣᫭

202106006

X ⥺྾཰ศග࡟ࡼࡿ࢔ࣥࣔࢽ࢔ྜᡂゐ፹ࡢάᛶⅬᵓ㐀ゎ᫂(Ϫ)ྡྂᒇ኱Ꮫ࣭Ọᒸ຾ಇ

202106007

࢖ࢿ✀Ꮚࡢ↓ᶵศᯒᐑᇛ኱Ꮫ࣭㫽⩚኱㝧

202106008

ᢸᣢ㔠ᒓࢡࣛࢫࢱ࣮ゐ፹ࡢ XAFS ࡟ࡼࡿᵓ㐀ゎᯒ(ᅜ◊)⌮໬Ꮫ◊✲ᡤ࣭ୖཱྀ㈼202106019

㓟໬≀ᅛᐃ໬㔠ᒓ㘒య࣭㔠ᒓࢼࣀ⢏Ꮚࡢ XAFSྡྂᒇ኱Ꮫ࣭㑦ḟᬛ

202106022

Ni-Au ࢼࣀ⢏Ꮚࡢྜ㔠┦࡟࠾ࡅࡿᒁᡤᵓ㐀ࡢ EXAFS ゎᯒྡྂᒇ኱Ꮫ࣭ᑠᕝᬛྐ

202106023

ࢩࣥࢡࣟࢺࣟࣥගࢆ⏝࠸ࡓ㔙⸆ࡢእほኚ໬ࡢㄪᰝ

࠶࠸ࡕ⏘ᴗ⛉Ꮫᢏ⾡⥲ྜࢭࣥࢱ࣮࣭ᮧ஭ᓫ❶202106065

ࣂࢼࢪ࣒࢘⣔㔞య໬≀㉁ࡢᒁᡤᵓ㐀ゎᯒྡྂᒇ኱Ꮫ࣭∦ᒣᑦᖾ

202106070⎔≧ࢿࢵࢺ࣮࣡ࢡ౵ධᆺⓎග୰ᚰࡢ౯ᩘホ౯ᒣᙧ኱Ꮫ࣭໭ᾆᏲ

202106098㉥እ཯ᑕ⋡ࡢ㧗࠸㯮Ⰽ㢦ᩱࡢᵓ㐀࡜㟁Ꮚ≧ែศᯒྡྂᒇᕤᴗ኱Ꮫ࣭᪩ᕝ▱ඞ

202106103

ᐃ

Li-Ta-Ti-OMn ⺯ගయࡢ MgO ῧຍ࡟ࡼࡿ౯ᩘไᚚ࡜Ⓨග≉ᛶྥୖࡢྲྀࡾ⤌ࡳ

㇏ᶫᢏ⾡⛉Ꮫ኱Ꮫ࣭୰㔝⿱⨾202106107

㓟໬≀⵳㟁ᮦᩱࡢ㟁Ꮚ≧ែศᯒᮾ໭኱Ꮫ࣭ᑠᯘᘯ᫂

202106110◲໬ែ㔠ᒓࡢ⃰ᗘ ᐃ᪩✄⏣኱Ꮫ࣭ᡤ༓ᬕ

2021D6007

NTA ࢔࣑ࢻ྾╔ᮦཬࡧ⁐፹ࡢ Pd 㘒యᵓ㐀ゎᯒ(ᅜ◊)᪥ᮏཎᏊຊ◊✲㛤Ⓨᶵᵓ࣭Ώ㒊๰





86

 ᡂᯝබ㛤↓ൾ฼⏝஦ᴗᡂᯝሗ࿌
AichiSR ࡢ᪂ࡓ࡞฼⏝ࡢᣑ኱࡟⧅ࡆࡿࡇ࡜ࢆ┠ⓗ࡜࠙ᥖ㍕࣮࣌ࢪ URLࠚࡋࡓࠊᡂᯝබ㛤↓ൾ฼⏝஦ᴗ࡟ࡼࡾࠊ2021 ᖺᗘ࡟᥇ᢥ

https://www.aichisr.jp/publication/report/2021/2.html

ࡉࢀࡓㄢ㢟ࡣ௨ୗࡢ࡜࠾ࡾࠋ

࠙QR ࢥ࣮ࢻࠚ

࡞࠾ࠊᡂᯝሗ࿌᭩ࡢෆᐜࡣࠊAichiSR ࣮࣒࣮࣍࣌ࢪ
࡛බ㛤ࡉࢀ࡚࠸ࡿࠋ

ᐇ㦂␒ྕ
2021P0101
2021P0103
2021P0104

2021P0105

2021P0106

2021P0107

ᐇ 㦂 ㄢ 㢟 ྡ෭㛫㘫㐀ࡢ₶⁥⓶⭷ᙧᡂࣉࣟࢭࢫ࡟࠾ࡅࡿ࢙࢘ࢵࢺࣈࣛࢫࢺ࡟ࡼࡿ⣲ᮦ๓ฎ⌮ࡢຠᯝ᳨ド㌾ X ⥺ XAFS ࢫ࣌ࢡࢺࣝ࠿ࡽࡢ≀ᛶண࣮࣎ࣥࢳࣕ࢖ࢼ⏝⤖ᬗ㔙⸆ࡢⓎⰍ࣭Ⓨ⌧ᶵᵓࡢゎ᫂࡜ࡑࡢᏳᐃ໬࡟ྥࡅࡓᛂ⏝ᢏ⾡ࡢ㛤Ⓨ
a-SiO2/Si ࡢ GI-PDF(grazing-incidence Pair distribution functions)࡟ࡼࡿᒁ
ᡤᵓ㐀ゎᯒ
MA-VHP ࡛ in-situ ྜᡂࡋࡓ FeAl ᇶ ODS ↝⤖యࡢࢩࣥࢡࣟࢺࣟࣥග࡟ࡼࡿ XRD ゎᯒX ⥺࢖࣓࣮ࢪࣥࢢ࡟ࡼࡿཱྀ⭍ෆᔂቯ㘄㸦OD 㘄㸧ࡢᑟỈ㐣⛬࠾ࡼࡧᔂቯᣲືほᐹ⤖ᬗᵓ㐀ゎᯒ࡟ࡼࡿࣉࣟࢫࢱࢢࣛࣥࢪࣥ D2 ྜᡂ㓝⣲㜼ᐖ๣ࡢࢫࢡ࣮ࣜࢽࣥࢢ

2021P0109

༢ศᏊ᳨ฟࢆྍ⬟࡜ࡍࡿከᒙࢢࣛࣇ࢙ࣥࣂ࢖࢜ࢭࣥࢧ࣮ࡢ㛤Ⓨ ͤ

2021P0110⢊య Materials Genome ࣉࣟࢭࢫ࡟ࡼࡿ඲ᅛయ㟁ụ⏝ᅛయ㟁ゎ㉁ࡢ᥈⣴ ͤ

2021P0113

2021P0114⤯⦕ᛶ᭷ᶵᮦᩱࡢ NEXAFS

࣐ࢥ࣮ᰴᘧ఍♫ᰴᘧ఍♫ࢹࣥࢯ࣮

2021P0108

2021P0112

ᐇ᪋௻ᴗ➼ᐃࢆྍ⬟࡟ࡍࡿ㔠ᒓ࣭࣮࢝࣎ࣥⷧ⭷⵨╔᮲௳ࡢ☜❧
XAFS ࢆ⏝࠸ࡓ Pt/Nb-SnO2 ࢼࣀ⢏Ꮚࡢᚤ⣽ᵓ㐀ゎᯒ ͤ㌾㹖⥺ XAFS ୪ࡧ࡟ග㟁Ꮚศගἲ࡟ࡼࡿ ALPS ỿẊ⣔ᗫᲠ≀ࡢࣜࣥ㓟ሷᅛ໬యᵓᡂඖ⣲ࡢ㟁Ꮚ≧ែゎ㬆ᾏ〇㝡ᰴᘧ఍♫ᰴᘧ఍♫ ᪥⏘࢔࣮ࢡ㇏⮧⇕ฎ⌮ᕤᴗᰴᘧ఍♫ᰴᘧ఍♫ࢲ࢖ࢭࣝ
ᰴᘧ఍♫୸࿴ᰤ㣴㣗ရᏛᰯἲேᮾὒ኱Ꮫ
ᰴᘧ఍♫୕࿴
ᮾி⌮⛉኱Ꮫ
ᰴᘧ఍♫ࢹࣥࢯ࣮
JSR ᰴᘧ఍♫ᗈᓥ኱Ꮫᰴᘧ఍♫࢟ࣕࢱ࣮ࣛ
ᮾிᕤᴗ኱Ꮫ
᪥❧ GE ࢽ࣮ࣗࢡࣜ࢔࣭࢚ࢼࢪ
࣮ᰴᘧ఍♫

2021P0115

඲ᅛయ㟁ụࡢ XAFS ゎᯒᰴᘧ఍♫ ᪥⏘࢔࣮ࢡ

2021P0117

X ⥺ᅇᢡ࡟ࡼࡿ㉸㧗⢭⣽ࢫࢡ࣮ࣜࣥ༳ๅ⏝ࢫࢸࣥࣞࢫ࣓ࢵࢩࣗࡢ◊✲㛤Ⓨ࢔ࢧࢲ࣓ࢵࢩࣗᰴᘧ఍♫2021P0119

Tender-㹖⥺ࢆ⏝࠸ࡓศග ᐃ࡟ࡼࡿ㧗ศᏊᮦᩱࡢ῝ࡉ౫Ꮡᛶホ౯ἲࡢ☜❧ᰴᘧ఍♫࣓ࢽࢥࣥ

2021P0120

⺯ග XAFSᰴᘧ఍♫ SOKEN

ᐃ࡟࠾ࡅࡿ✵㛫ศゎ⬟ࡢྥୖᡭἲࡢ㛤Ⓨ

87



88

㸬ጤဨ఍

89



ጤဨ఍

AichiSR ࡛ࡣࠊእ㒊ࡢ᭷㆑⪅ࡀࢭࣥࢱ࣮ࡢᩚഛ࣭㐠Ⴀ࡟ࡘ࠸࡚ࡢㄪᰝᑂ㆟ࢆ⾜࠺ࠕ㐠Ⴀጤဨ఍ࠖࢆࡣࡌࡵࠊ
ࡉࡲࡊࡲ࡞ጤဨ఍ࢆ㛤ദࡋ࡚࠸ࡿࠋ
 ࠶࠸ࡕࢩࣥࢡࣟࢺࣟࣥගࢭࣥࢱ࣮㐠Ⴀጤဨ఍

➨1ᅇ

➨2ᅇ

㛤 ദ ᪥

2021 ᖺ 6 ᭶ 7 ᪥(᭶)

㛤ദሙᡤ࢜ࣥࣛ࢖ࣥ㛤ദ㆟2020 ᖺᗘ஦ᴗሗ࿌࡟ࡘ࠸࡚

㢟

㛤 ദ ᪥

2022 ᖺ 3 ᭶ 2 ᪥(Ỉ)

㛤ദሙᡤ࢜ࣥࣛ࢖ࣥ㛤ദ㆟㢟2022 ᖺᗘᖺ㛫㐠Ⴀィ⏬㸦᱌㸧࡟ࡘ࠸࡚タഛ࣭ᶵჾࡢᩚഛ࣭㧗ᗘ໬ィ⏬࡟ࡘ࠸࡚ ࠶࠸ࡕࢩࣥࢡࣟࢺࣟࣥගࢭࣥࢱ࣮ᡂᯝබ㛤↓ൾ฼⏝஦ᴗㄢ㢟ᑂᰝጤဨ఍㛤 ദ ᪥㸸2021 ᖺ 5 ᭶ 13 ᪥㸦ᮌ㸧㛤ദሙᡤ㸸࠶࠸ࡕࢩࣥࢡࣟࢺࣟࣥගࢭࣥࢱ࣮ 2 㝵 ኱఍㆟ᐊ ࡑࡢ௚ጤဨ఍
㸦1㸧ᴗົᏳ඲⟶⌮ጤဨ఍ẖ᭶ 1 ᅇ㛤ദ㸦10 ᭶ࠊ2 ᭶ࢆ㝖ࡃ㸧

㸦2㸧ᨺᑕ⥺Ᏻ඲⟶⌮ጤဨ఍2 ᅇ㸦6 ᭶ࠊ3 ᭶㸧㛤ദ

90㸬Ᏻ඲⟶⌮

91



Ᏻ඲⟶⌮

 ᨺᑕ⥺⟶⌮  ⟶⌮యไ
AichiSR ࡟࠾࠸࡚⿦⨨➼ࡢྲྀᢅ࠸࡟ᚑ஦ࡍࡿ⪅ཬࡧᏳ඲⟶⌮࡟ᚑ஦ࡍࡿ⪅࡟㛵ࡍࡿ⤌⧊ᅗࡣ௨ୗࡢ࡜
࠾ࡾࠋ࠶࠸ࡕࢩࣥࢡࣟࢺࣟࣥගࢭࣥࢱ࣮ᨺᑕ⥺㞀ᐖண㜵つ⛬㸦2020.9㸧ᢤ⢋  ᚑ஦⪅Ⓩ㘓
2021 ᖺᗘ AichiSR ᨺᑕ⥺ᴗົᚑ஦⪅Ⓩ㘓ᩘ 694 ྡ  ⫋ဨ⏝ᨺᑕ⥺ᴗົᚑ஦⪅ᩍ⫱カ⦎ㅮ⩦఍⫋ဨ⏝ࡢㅮ⩦఍ࢆḟࡢ᪥⛬࡛㛤ദࡋࡓࠋ㸦࠸ࡎࢀࡶ෌ᩍ⫱㸧
11 ᭶ 29 ᪥㸦᭶㸧13:30㹼15:00 ཧຍ⪅㸸㸦఍ሙ㸧8 ྡࠊ㸦࢜ࣥࣛ࢖ࣥ㸧13 ྡ
12 ᭶ 20 ᪥㸦᭶㸧13:30㹼15:00 ཧຍ⪅㸸㸦఍ሙ㸧4 ྡࠊ㸦࢜ࣥࣛ࢖ࣥ㸧6 ྡ ࡑࡢ௚
࣮ࣘࢨ࣮ࡀᣢࡕ㎸ࡴヨᩱࡸ໬Ꮫ⸆ရ➼࡟ࡘ࠸࡚ࠊἲ௧ࡸᡤ๎࡟ᇶ࡙ࡁࠊᏳ඲ᑂᰝࢆᐇ᪋ࡋ࡚࠸ࡿࠋࢭ
ࣥࢱ࣮ࡢ㐠Ⴀ࡟ᚲせ࡞㈨᱁࡛ࠊ⫋ဨࡀಖ᭷ࡋ࡚࠸ࡿ୺࡞ࡶࡢࡣ௨ୗࡢ࡜࠾ࡾࠋx ᨺᑕ⥺ྲྀᢅ୺௵⪅x ⋢᥃ࡅ       

x ᭷ᶵ⁐๣సᴗ୺௵⪅x 㧗ᅽ࢞ࢫྲྀᢅ୺௵⪅x ≉ᐃ໬Ꮫ≀㉁ཬࡧᅄ࢔ࣝ࢟ࣝ㖄➼సᴗ୺௵⪅x ༴㝤≀ྲྀᢅ⪅x ᗋୖ⧞సᘧࢡ࣮ࣞࣥ

92㸬᪋タ⟶⌮

93



᪋タ⟶⌮

 㟁Ẽ
AichiSR ࡢ㟁Ẽࡣࠊ2021 ᖺ 4 ᭶࠿ࡽ 12 ᭶ࡲ࡛ᰴᘧ఍♫࣮࣍ࣉࠊ2022 ᖺ 1 ᭶࠿ࡽ 3 ᭶ࡲ࡛୰㒊㟁ຊᰴᘧ఍♫࠿ࡽ▱ࡢᣐⅬࡢཷ㟁タഛࢆ⤒⏤ࡋ࡚౪⤥ࡉࢀࡓࠋ6,600V ࡛ཷ㟁ࡋࡓ㟁Ẽࢆࠊᙜࢭࣥࢱ࣮࡛ 420Vࠊ
210Vࠊ
105V ࡟㝆ᅽࡋ࡚౑⏝ࡋ࡚࠸ࡿࠋ
㸦ୖẁ㸧᭶ู㟁Ẽ౑⏝㔞㸦༢఩㸸kwh㸧㸭㸦ୗẁ㸧᭶ู㟁Ẽ౑⏝ᩱ㔠㸦༢఩㸸෇㸧
2021 ᖺ
4᭶

5᭶

6᭶

7᭶

8᭶

9᭶

292,500

396,350425,660

437,110355,380

408,980

3,715,730

5,240,462

5,675,848

6,282,673

5,163,111

6,062,1172022 ᖺ

2021 ᖺᗘ

10 ᭶

11 ᭶

12 ᭶

1᭶

2᭶

3᭶

ྜィ

357,520

404,930

418,950

437,100

395,130

410,390

4,740,000

5,194,742

6,011,127

6,398,706

8,497,839

8,399,902

9,072,361

75,714,618Ỉ㐨
AichiSR ࡛ࡣࠊ℩ᡞᕷ࠿ࡽ౪⤥ࡉࢀ࡚࠸ࡿୖỈ㐨Ỉࢆࠊ㣧ᩱỈࡸຍ㏿ჾ➼ࡢ෭༷Ỉ࡜ࡋ࡚౑⏝ࡋ࡚࠸ࡿࠋ
㸦ୖẁ㸧Ỉ㐨౑⏝㔞㸦༢఩㸸ੑ 㸭㸦ୗẁ㸧Ỉ㐨౑⏝ᩱ㔠 ༢఩㸸෇ 2021 ᖺ
3㹼5 ᭶

5㹼7 ᭶

7㹼9 ᭶

9㹼11 ᭶

11 ᭶㹼

2022 ᖺ

2021 ᖺᗘ

2022 ᖺ 1 ᭶

1㹼3 ᭶

ྜィ

661

782

835

604

774

660

4,316

190,135

227,403

243,727

172,579

224,939

189,827

1,248,610



94㸬㐠Ⴀ


95 㐠Ⴀ㐣ཤ  ᖺ㛫ࡢண⟬࣭฼⏝ᩱ཰ධࡢ᥎⛣㸦༢఩㸸༓෇㸧

2017 ᖺᗘ

2018 ᖺᗘ

2019 ᖺᗘ

2020 ᖺᗘ

2021 ᖺᗘ

ண⟬㢠

585,793

507,851

519,566

595,614561,849฼⏝ᩱ཰ධ㢠㸦ᐇ⦼㸧

191,370

194,703207,780

215,249

219,696 ͤண⟬㢠ࡣࠊእ㒊㈨㔠ཬࡧጤク㈝ࢆ㝖ࡃࠋ㐠Ⴀ⤌⧊  බ┈㈈ᅋἲே⛉Ꮫᢏ⾡஺ὶ㈈ᅋ ⤌⧊ᅗ




96

  ࢫࢱࢵࣇྡ⡙
㸦2022 ᖺ 3 ᭶ᮎ᫬Ⅼ㸧ᡤ 㛗ᅧᯞ ⚽ୡ

୺௵ᢏ⾡◊✲ဨ௰Ṋ ᫀྐᢏ⾡◊✲ဨ㧗಴ ᑗ୍

SES

ᒣᮏ೺୍㑻

እ᮶ᢏ⾡ဨ

㓇஭ ஂ㈨ᢏ⾡◊✲ဨⰼ⏣ ㈼ᚿᢏ⾡◊✲ဨ⚄㇂ ࿴Ꮥᢏ⾡◊✲ဨᒣඖ ༤ᏊSES⚟Ọ ṇ๎

SESຍ⸨ ᘯὈᢏ⾡◊✲ဨ㡲⏣ ⪔ᖹ

BL7U
๪ᡤ㛗

⃝ ⏣ 

⠜

๪ᡤ㛗

ᒸᓥ ᩄᾈ
BL8S1

୺ᖍ◊✲ဨ

Ώ㎶ ⩏ኵ

⟶⌮ㄢ

BL8S2

ㄢ 㛗

ᒣෆ ༤㞞
BL8S3

୺஦(஦ົᑓ㛛⫋ဨ)ຍ⸨ ⏤⣖

୺஦(஦ົᑓ㛛⫋ဨ)ᯇཎ ᾈ⨾

BL8S3,BL11S2ග※ㄢ୺ᖿ◊✲ဨ㧗ᔱ ᆂྐ

୺௵ᢏ⾡◊✲ဨ▼⏣ Ꮥྖ

◊✲ဨ⸨ᮏ ᑘ㍤◊✲ဨ㒌☨⏘ᴗ฼⏝ࢥ࣮ࢹ࢕ࢿ࣮ࢱ㔝ᓮ ᙲᏊSES㔠ᮌ බᏕ

⏘ᴗ฼⏝ࢥ࣮ࢹ࢕ࢿ࣮ࢱ

Ọぢ ဴኵSES᳃㔛 㑥ᙪ

⏘ᴗ฼⏝ࢥ࣮ࢹ࢕ࢿ࣮ࢱ

ሯ⏣ ༓ᜨSES㕥ᮌ 㐶ኴ

◊✲ဨ

Iesari Fabio

୺஦(஦ົᑓ㛛⫋ဨ)ሯ ⏣ ࣃ࣮ࢺࢼ࣮⫋ဨ୰ୖ ᝋᏊ



BL11S2࣮ࣘࢨ࣮ᨭ᥼ᐊ

ࣅ࣮࣒ࣛ࢖ࣥㄢ
ㄢ 㛗

㕥ᮌࡳ࡝ࡾ

ᢸᙜㄢ㛗ව୺௵ᢏ⾡◊✲ဨྜྷᮧ ೔ᣅಀ 㛗ᜠ⏣ ᗣభ

Ᏻ඲⟶⌮ㄢ๪ᡤ㛗࡯࠿ 16 ྡවົࣅ࣮࣒ࣛ࢖ࣥࢫࢱࢵࣇ

≉ูࣇ࢙࣮ࣟ㸦ྡ㄃ᡤ㛗㸧➉⏣ ⨾࿴

୺௵ᢏ⾡◊✲ဨᮡᒣ 㝧ᰤ

⏘ᴗ฼⏝࢔ࢻࣂ࢖ࢨ࣮⏣௦ Ꮥ஧ᢏ⾡◊✲ဨᮧ℩ ᬕ⣖⏘ᴗ฼⏝࢔ࢻࣂ࢖ࢨ࣮

ኴ⏣ බ඾

୺௵ᢏ⾡◊✲ဨ⚟ ᒸ ಟ⏘ᴗ฼⏝࢔ࢻࣂ࢖ࢨ࣮

ኴ⏣ ಇ᫂

SESᘅ཭ ⛱ᶞ

⏘ᴗ฼⏝࢔ࢻࣂ࢖ࢨ࣮◒⥥ ┿୍

୺௵ᢏ⾡◊✲ဨ୰す ⿱⣖⏘ᴗ฼⏝࢔ࢻࣂ࢖ࢨ࣮

ᮾ 

SES

బஂ㛫㟹༤

ග※࢔ࢻࣂ࢖ࢨ࣮

኱⇃ ᫓ኵ

୺௵ᢏ⾡◊✲ဨ㝜 ᆅ ࢔ࢻࣂ࢖ࢨ࣮ⰼᮌ ༤ᩥ

୺௵ᢏ⾡◊✲ဨᰘ⏣ ెᏕ

BL1N2

BL5S1

BL5S2
ᏹ

BL6 N1
6(6ʻηϕϨϱήΦ΢φγʖϑη


ᖾ



97

༤ ⣧

ጤဨྡ⡙  ࠶࠸ࡕࢩࣥࢡࣟࢺࣟࣥගࢭࣥࢱ࣮㐠Ⴀጤဨ఍Ặ ྡụཱྀ 㐩἞▼ᕝ ⏤ຍ㔛☾ᮧ ඾Ṋఀ⸨ ࡳ࡯ຍ⸨ ᨻ༤ᮌୗ ᆂ௓

ᅜ㡲 ṇὒᡤ ᒓ ➼
࠶࠸ࡕ⏘ᴗ⛉Ꮫᢏ⾡⥲ྜࢭࣥࢱ࣮ ᡤ㛗୍⯡㈈ᅋἲேࣇ࢓࢖ࣥࢭ࣑ࣛࢵࢡࢫࢭࣥࢱ࣮
ᮦᩱᢏ⾡◊✲ᡤ ᶵ⬟ᛶᮦᩱࢢ࣮ࣝࣉ ࢢ࣮ࣝࣉ㛗ᰴᘧ఍♫㇏⏣୰ኸ◊✲ᡤ ࢚࣐࣮ࢪࣥࢢ◊✲㒊㛛 ศᯒ◊✲㡿ᇦ࣮ࣜࢹ࢕ࣥࢢࣜࢧ࣮ࢳ࣮ࣕ
ᰴᘧ఍♫ࢹࣥࢯ࣮ ඛ➃ᢏ⾡◊✲ᡤ㛗ව࣐ࢸࣜ࢔ࣝ◊✲㒊㛗኱Ꮫඹྠ฼⏝ᶵ㛵ἲே⮬↛⛉Ꮫ◊✲ᶵᵓ ศᏊ⛉Ꮫ◊✲ᡤᴟ➃⣸እග◊✲᪋タ ≉௵ᩍᤵ≉௵ᩍᤵࢺࣚࢱ⮬ື㌴ᰴᘧ఍♫㟁ື໬࣭⎔ቃᮦᩱᢏ⾡㒊 ᮦᩱᇶ┙㛤Ⓨᐊ ᐊ㛗ᰴᘧ఍♫ᮾࣞࣜࢧ࣮ࢳࢭࣥࢱ࣮
⾲㠃⛉Ꮫ◊✲㒊 ➨㸰◊✲ᐊ ୺௵◊✲ဨబ᐀ ❶ᘯ

ᅜ❧኱Ꮫἲேᮾᾏᅜ❧኱Ꮫᶵᵓ㸦ྡྂᒇ኱Ꮫ㸧ᶵᵓ㛗⿵బ㸦๪⥲㛗㸧ᮎྜྷ ᩄᘯ⤒῭⏘ᴗ┬୰㒊⤒῭⏘ᴗᒁ ᆅᇦ⤒῭㒊⏘ᴗᢏ⾡ㄢ㛗㕥ᮌ ㈆ᙪ

୸ࢫ㔙⸆ྜ㈨఍♫ ௦⾲♫ဨ➉ෆ ᜏ༤

ᏛᰯἲேࢺࣚࢱᏛᅬ㇏⏣ᕤᴗ኱Ꮫ ᩍᤵ⏣୰ ୕㑻

ᅜ❧኱Ꮫἲே㇏ᶫᢏ⾡⛉Ꮫ኱Ꮫ ๪Ꮫ㛗෠⏣ ⾺Ꮚ

ᅜ❧◊✲㛤Ⓨἲே⏘ᴗᢏ⾡⥲ྜ◊✲ᡤ ୰㒊ࢭࣥࢱ࣮ ᮦᩱ࣭໬Ꮫ㡿ᇦᴟ㝈ᶵ⬟ᮦᩱ◊✲㒊㛛 ࢼࣀ࣏࣮ࣛࢫᮦᩱࢢ࣮ࣝࣉ ୺௵◊✲ဨỌ⏣ ㅬ஧

ᅜ❧኱Ꮫἲேྡྂᒇᕤᴗ኱Ꮫ ⏘Ꮫᐁ㔠㐃ᦠᶵᵓ ๪ᶵᵓ㛗⸨஭ ๎ᙪឡ▱┴⤒῭⏘ᴗᒁ⏘ᴗ㒊⏘ᴗ⛉Ꮫᢏ⾡ㄢ㛗ᐑ㷂 ㄔ୍ᮧୖ  ᾴᅜ❧኱Ꮫἲேᮾᾏᅜ❧኱Ꮫᶵᵓ㸦ྡྂᒇ኱Ꮫ㸧ࢩࣥࢡࣟࢺࣟࣥග◊✲ࢭࣥࢱ࣮ ࢭࣥࢱ࣮㛗ྡྂᒇၟᕤ఍㆟ᡤ ⏘ᴗ᣺⯆㒊 ࣔࣀ࡙ࡃࡾ࣭࢖ࣀ࣮࣋ࢩࣙࣥࣘࢽࢵࢺ㛗






98


  ࠶࠸ࡕࢩࣥࢡࣟࢺࣟࣥගࢭࣥࢱ࣮ᡂᯝබ㛤↓ൾ฼⏝஦ᴗㄢ㢟ᑂᰝጤဨ఍Ặ ྡᡤ ᒓ ➼

ᅧᯞ ⚽ୡ

࠶࠸ࡕࢩࣥࢡࣟࢺࣟࣥගࢭࣥࢱ࣮ ᡤ㛗➉⏣ ⨾࿴

࠶࠸ࡕࢩࣥࢡࣟࢺࣟࣥගࢭࣥࢱ࣮ ≉ูࣇ࢙࣮ࣟᒸᓥ ᩄᾈ

࠶࠸ࡕࢩࣥࢡࣟࢺࣟࣥගࢭࣥࢱ࣮ ๪ᡤ㛗Ώ㎶ ⩏ኵ

࠶࠸ࡕࢩࣥࢡࣟࢺࣟࣥගࢭࣥࢱ࣮ ୺ᖍ◊✲ဨ◒⥥ ┾୍

࠶࠸ࡕࢩࣥࢡࣟࢺࣟࣥගࢭࣥࢱ࣮ ⏘ᴗ฼⏝࢔ࢻࣂ࢖ࢨ࣮⏣ῲ 㞞ኵ

ྡྂᒇ኱Ꮫࢩࣥࢡࣟࢺࣟࣥග◊✲ࢭࣥࢱ࣮ ᩍᤵຍ⸨ ஂஓ

࠶࠸ࡕ⏘ᴗ⛉Ꮫᢏ⾡⥲ྜࢭࣥࢱ࣮ ඹྠ◊✲ᨭ᥼㒊㛗වヨసホ౯ᐊ㛗ᑠஂಖ ᘯᶞᮡᒣ ಙஅ

࠶࠸ࡕ⏘ᴗ⛉Ꮫᢏ⾡⥲ྜࢭࣥࢱ࣮
ィศᯒᐊ㛗වࢩࣥࢡࣟࢺࣟࣥගά⏝᥎㐍ᐊ㛗࠶࠸ࡕ⏘ᴗ⛉Ꮫᢏ⾡⥲ྜࢭࣥࢱ࣮
ඹྠ◊✲ᨭ᥼㒊 ࢩࣥࢡࣟࢺࣟࣥගά⏝᥎㐍ᐊ ୺௵◊✲ဨᨭ᥼⫋ဨ㸦◊✲⪅㸧ྡ⡙኱Ꮫ㐃ྜ࠿ࡽࡢᨭ᥼⫋ဨ࡟㛵ࡍࡿྲྀỴࡵ➨㸱࡟ᇶ࡙ࡃᨭ᥼⫋ဨ㸦◊✲⪅㸧
ᡤᒓ኱Ꮫ

⫋ ྡ

㸦㈈ᅋ࡟࠾ࡅࡿ⫋ྡ㸧

Ặ ྡ

ྡྂᒇ኱Ꮫ

ࢩࣥࢡࣟࢺࣟࣥග◊✲ࢭࣥࢱ࣮ᩍᤵ

㸦୺ᖿ◊✲ဨ㸧㧗ᔱ ᆂྐ

ྡྂᒇ኱Ꮫࢩࣥࢡࣟࢺࣟࣥග◊✲ࢭࣥࢱ࣮ᩍᤵ

㸦୺ᖿ◊✲ဨ㸧⏣ῲ 㞞ኵ

ྡྂᒇ኱Ꮫࢩࣥࢡࣟࢺࣟࣥග◊✲ࢭࣥࢱ࣮ᩍᤵ

㸦୺ᖿ◊✲ဨ㸧ྡྂᒇ኱Ꮫࢩࣥࢡࣟࢺࣟࣥග◊✲ࢭࣥࢱ࣮෸ᩍᤵ

㸦୺௵◊✲ဨ㸧ఀ⸨ Ꮥᐶ

ྡྂᒇ኱Ꮫࢩࣥࢡࣟࢺࣟࣥග◊✲ࢭࣥࢱ࣮෸ᩍᤵ

㸦୺௵◊✲ဨ㸧ᱵྡ Ὀྐ

ྡྂᒇ኱Ꮫࢩࣥࢡࣟࢺࣟࣥග◊✲ࢭࣥࢱ࣮෸ᩍᤵ

㸦୺௵◊✲ဨ㸧᮷ᮏ Ὀఙ

ྡྂᒇ኱Ꮫࢩࣥࢡࣟࢺࣟࣥග◊✲ࢭࣥࢱ࣮≉௵෸ᩍᤵ㸦୺௵◊✲ဨ㸧Ḉ஭ 㑳ஓ

ྡྂᒇ኱Ꮫࢩࣥࢡࣟࢺࣟࣥග◊✲ࢭࣥࢱ࣮ຓᩍ㸦◊✲ဨ㸧ỌỤ ᓠᖾ

ྡྂᒇ኱Ꮫࢩࣥࢡࣟࢺࣟࣥග◊✲ࢭࣥࢱ࣮ຓᩍ㸦◊✲ဨ㸧㒌  ☨

ྡྂᒇ኱Ꮫࢩࣥࢡࣟࢺࣟࣥග◊✲ࢭࣥࢱ࣮≉௵ຓᩍ㸦◊✲ဨ㸧⸨ᮏ ᑘ㍤ྡྂᒇ኱ᏛᕤᏛ◊✲⛉ᩍᤵ

㸦୺ᖿ◊✲ဨ㸧ᐑ㷂 ㄔ୍

ྡྂᒇ኱ᏛᕤᏛ◊✲⛉ຓᩍ㸦◊✲ဨ㸧ᑠᕝ ᬛྐ

ྡྂᒇᕤᴗ኱Ꮫ

ᕤᏛ◊✲⛉ᩍᤵ

㸦୺ᖿ◊✲ဨ㸧஭⏣  㝯ྡྂᒇᕤᴗ኱Ꮫ

ᕤᏛ◊✲⛉෸ᩍᤵ

㸦୺௵◊✲ဨ㸧ᒣᮏ ຾ᏹ

㇏⏣ᕤᴗ኱Ꮫ

ᕤᏛ◊✲⛉ᩍᤵ

㸦୺ᖿ◊✲ဨ㸧➉ෆ ᜏ༤

㇏⏣ᕤᴗ኱Ꮫ

ᕤᏛ◊✲⛉෸ᩍᤵ

㸦୺௵◊✲ဨ㸧ᯇἼ 㞞἞

㇏ᶫᢏ⾡⛉Ꮫ኱Ꮫ

ᛂ⏝໬Ꮫ࣭⏕࿨ᕤᏛ⣔ᩍᤵ㸦୺ᖿ◊✲ဨ㸧Ỉᔱ ⏕ᬛ

㇏ᶫᢏ⾡⛉Ꮫ኱Ꮫ

ᛂ⏝໬Ꮫ࣭⏕࿨ᕤᏛ⣔ຓᡭ㸦◊✲ဨ㸧⸨⃝ 㑳ⱥ

99

Lenard Michel
Gabriel Chavas



100

௜㘓

101

ࣅ࣮࣒ࣛ࢖ࣥ㓄⨨ᅗඹ⏝ࣅ࣮࣒ࣛ࢖ࣥ
ࣅ࣮࣒ࣛ࢖ࣥྡ ᐃ ᡭ ἲ

ձ

BL1N2

㌾ X ⥺ XAFS࣭ග㟁Ꮚศග ϩ㌾㹖⥺ XAFSࠊ㉸㌾㹖⥺ XAFSࠊග㟁Ꮚศග

ղ

BL2S1

༢⤖ᬗ X ⥺ᅇᢡ㸦ྡྂᒇ኱Ꮫ㸧༢⤖ᬗ X ⥺ᅇᢡ

ճ

BL5S1

◳ X ⥺ XAFS Ϩ◳㹖⥺ XAFSࠊ⺯ග X ⥺

մ

BL5S2

⢊ᮎ X ⥺ᅇᢡ⢊ᮎ㹖⥺ᅇᢡ

յ

BL6N1㌾ X ⥺ XAFS࣭ග㟁Ꮚศග Ϩ㌾㹖⥺ XAFSࠊග㟁Ꮚศග

ն

BL7U

┿✵⣸እศග

┿✵⣸እศගࠊ㉸㌾㹖⥺ XAFSࠊග㟁Ꮚศග

շ

BL8S1

ⷧ⭷ X ⥺ᅇᢡX ⥺཯ᑕ⋡ࠊⷧ⭷⾲㠃ᅇᢡ

ո

BL8S2

X ⥺ࢺ࣏ࢢࣛࣇ࢕࣭X ⥺ CT㸦ឡ▱┴㸧 X ⥺ࢺ࣏ࢢࣛࣇ࢕ࠊX ⥺ CT

չ

BL8S3

ᗈゅ࣭ᑠゅ㹖⥺ᩓ஘

ᗈゅ࣭ᑠゅᩓ஘

պ

BL11S2◳ X ⥺ XAFS ϩ◳㹖⥺ XAFSࠊ⺯ග X ⥺ග※ࡢᛶ⬟
┤⥺ຍ㏿ჾ࠙S-bandࠚ㟁Ꮚ࢚ࢿࣝࢠ࣮㸸50MeVࣈ࣮ࢫࢱ࣮ࢩࣥࢡࣟࢺࣟࣥ

㟁Ꮚ࢚ࢿࣝࢠ࣮㸸50MeV-1.2GeVࠊ࿘㛗㸸48m⮬↛࢚࣑ࢵࢱࣥࢫ㸸200nm㺃rad⵳✚ࣜࣥࢢ⵳✚㟁Ꮚ࢚ࢿࣝࢠ࣮㸸1.2GeVࠊ࿘㛗㸸72m⮬↛࢚࣑ࢵࢱࣥࢫ㸸53nm㺃radࠊ⵳✚㟁ὶ㸸300㹫㸿

ᖖఏᑟ೫ྥ㟁☢▼࠙8 ྎࠚ☢ሙᙉᗘ㸸1.4Tࠊ೫ྥゅ㸸39r㉸ఏᑟ೫ྥ㟁☢▼࠙4 ྎࠚ☢ሙᙉᗘ㸸5Tࠊ೫ྥゅ㸸12r

102࢔ࢡࢭࢫ㕲㐨z ࠕྡྂᒇࠖ
㸦ᆅୗ㕲ᮾᒣ⥺㸧Ѝࠕ⸨ࡀୣࠖ
㸦ᮾ㒊ୣ㝠⥺ࣜࢽࣔ㸧Ѝࠕ㝡☢㈨ᩱ㤋༡ࠖͤྡྂᒇ㥐࠿ࡽ⣙ 50 ศz ࠕᒸᓮࠖࠕ᪂㇏⏣ࠖࠕ㧗ⶶᑎࠖ㸦ឡ▱⎔≧㕲㐨㸧Ѝࠕඵⲡࠖ㸦ᮾ㒊ୣ㝠⥺ࣜࢽࣔ㸧Ѝࠕ㝡☢㈨ᩱ㤋༡ࠖ㐨㊰z ᮾྡ㧗㏿㐨㊰࣭ྡྂᒇ IC ࡼࡾᮾ࡬⣙ 7km
z ᮾྡ㧗㏿㐨㊰࣭᪥㐍 JCT Ѝ ྡྂᒇ℩ᡞ㐨㊰࣭㛗ஂᡭ IC ࡼࡾᮾ࡬⣙ 3km
z ᮾᾏ⎔≧⮬ື㌴㐨࣭㇏⏣⸨ᒸ IC Ѝ ⊷ᢞࢢ࣮࣮ࣜࣥࣟࢻ࣭ඵⲡ IC ࡼࡾす࡬⣙ 800m

103ᮏᖺḟሗ࿌࡟グ㍕ࡍࡿ࠶ࡽࡺࡿᙧࡢࢥࣥࢸࣥࢶࡢⴭసᶒࡣࠊᙜ㈈ᅋཬࡧ
ࢥࣥࢸࣥࢶᥦ౪⪅࡟ᖐᒓࡋ࡚࠸ࡲࡍࠋⴭసᶒ⪅ࡢ஦๓ࡢᢎㅙ࡞ࡋ࡟ࠊᮏ
᭩ࡢ࠸࠿࡞ࡿᙧᘧࡢ」〇ࡲࡓࡣ㌿㍕ࡶ⾜࠺ࡇ࡜ࡣ࡛ࡁࡲࡏࢇࠋ

࠶࠸ࡕࢩࣥࢡࣟࢺࣟࣥගࢭࣥࢱ࣮ ᖺᗘ
ᖺ᭶Ⓨ⾜ᖺḟሗ࿌බ┈㈈ᅋἲே⛉Ꮫᢏ⾡஺ὶ㈈ᅋ
࠶࠸ࡕࢩࣥࢡࣟࢺࣟࣥගࢭࣥࢱ࣮
ࠛ ឡ▱┴℩ᡞᕷ༡ᒣཱྀ⏫␒
WHO
ID[
PDLODLFKLVU#DLFKLVUMS