58.0

Page 1/10

Safety Data Sheetacc. to OSHA HCS
Printing date 01/03/2024*Revision date 01/03/2024

1 Identification· Product identifier· Trade name: SM-102· Synonym 8-[(2-hydroxyethyl)[6-oxo-6-(undecyloxy)hexyl]amino]-octanoic acid, 1-octylnonyl ester· Article number: 33474· Application of the substance / the mixtureThis product is for research use - Not for human or veterinary diagnostic or therapeutic use.
· Details of the supplier of the safety data sheet· Manufacturer/Supplier:
Cayman Chemical Co.
1180 E. Ellsworth Rd.
Ann Arbor, MI 48108
USA· Information department: Product safety department· Emergency telephone number:
During normal opening times: +1 (734) 971-3335
US/CANADA: 800-424-9300
Outside US/CANADA: 703-741-5970*2 Hazard(s) identification· Classification of the substance or mixture~
dGHS02 Flame

Flammable Liquids 2~
dH225 Highly flammable liquid and vapor.

GHS07

Acute Toxicity - Oral 4 H302 Harmful if swallowed.
Skin Irritation 2
H315 Causes skin irritation.
Eye Irritation 2A
H319 Causes serious eye irritation.
· Label elements· GHS label elements
The product is classified and labeled according to the Globally Harmonized System (GHS).
(Contd. on page 2)
US58.0

Page 2/10

Safety Data Sheetacc. to OSHA HCS
Printing date 01/03/2024

Revision date 01/03/2024

Trade name: SM-102(Contd. from page 1)· Hazard pictograms~dd~
GHS02 GHS07· Signal word Danger· Hazard-determining components of labeling:
SM-102· Hazard statements
H225 Highly flammable liquid and vapor.
H302 Harmful if swallowed.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
· Precautionary statements
P210
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P233
Keep container tightly closed.
P240
Ground/bond container and receiving equipment.
P241
Use explosion-proof electrical/ventilating/lighting/equipment.
P242
Use only non-sparking tools.
P243
Take precautionary measures against static discharge.
P264
Wash thoroughly after handling.
P270
Do not eat, drink or smoke when using this product.
P280
Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312
If swallowed: Call a poison center/doctor if you feel unwell.
P330
Rinse mouth.
P321
Specific treatment (see on this label).
P303+P361+P353 If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin withwater/shower.
P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P332+P313
If skin irritation occurs: Get medical advice/attention.
P362+P364
Take off contaminated clothing and wash it before reuse.
P337+P313
If eye irritation persists: Get medical advice/attention.
P370+P378
In case of fire: Use CO2, powder or water spray to extinguish.
P403+P235
Store in a well-ventilated place. Keep cool.
P501
Dispose of contents/container in accordance with local/regional/national/international
regulations.
· Classification system:· NFPA ratings (scale 0 - 4)

20

Health = 2
Fire = 0
Reactivity = 00· HMIS-ratings (scale 0 - 4)
HEALTH

2FIRE0

REACTIVITY 0

Health = 2
Fire = 0
Reactivity = 0· Other hazards· Results of PBT and vPvB assessment· PBT: Not applicable.
(Contd. on page 3)
US58.0

Page 3/10

Safety Data Sheetacc. to OSHA HCS
Printing date 01/03/2024

Revision date 01/03/2024

Trade name: SM-102(Contd. from page 2)· vPvB: Not applicable.
*

3 Composition/information on ingredients· Chemical characterization: Mixtures· Description: Mixture of the substances listed below with nonhazardous additions.
· Dangerous components:
CAS: 64-17-5ethanol
RTECS: KQ6300000
CAS: 2089251-47-6 SM-102

*

90.0%
10.0%

4 First-aid measures· Description of first aid measures· General information:
Immediately remove any clothing soiled by the product.
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least
48 hours after the accident.
· After inhalation: In case of unconsciousness place patient stably in side position for transportation.
· After skin contact: Immediately wash with water and soap and rinse thoroughly.
· After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
· After swallowing: Immediately call a doctor.
· Information for doctor:· Most important symptoms and effects, both acute and delayed
No further relevant information available.
· Indication of any immediate medical attention and special treatment needed
No further relevant information available.

*

5 Fire-fighting measures· Extinguishing media· Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
· Special hazards arising from the substance or mixture No further relevant information available.
· Advice for firefighters· Protective equipment: No special measures required.

*

6 Accidental release measures· Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
· Environmental precautions:
Dilute with plenty of water.
Do not allow to enter sewers/ surface or ground water.
· Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to section 13.
Ensure adequate ventilation.
(Contd. on page 4)
US

58.0

Page 4/10

Safety Data Sheetacc. to OSHA HCS
Printing date 01/03/2024

Revision date 01/03/2024

Trade name: SM-102(Contd. from page 3)*· Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
· Protective Action Criteria for Chemicals· PAC-1:
64-17-5 ethanol

1,800 ppm

· PAC-2:
64-17-5 ethanol

3300* ppm

· PAC-3:
64-17-5 ethanol

15000* ppm

7 Handling and storage· Handling:· Precautions for safe handlingNo special precautions are necessary if used correctly.
Avoid breathing dust/fume/gas/mist/vapours/spray.
Avoid prolonged or repeated exposure.
Keep away from sources of ignition.
Take precautionary measures against static discharge.re.
· Information about protection against explosions and fires:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
· Conditions for safe storage, including any incompatibilities· Storage: Store in accordance with information listed on the product insert.
· Requirements to be met by storerooms and receptacles: Store in a cool location.
· Information about storage in one common storage facility: Not required.
· Further information about storage conditions:
Keep receptacle tightly sealed.
Store in cool, dry conditions in well sealed receptacles.
· Specific end use(s) No further relevant information available.

*8 Exposure controls/personal protection· Additional information about design of technical systems: No further data; see section 7.
· Control parameters· Components with limit values that require monitoring at the workplace:
The following constituent is the only constituent of the product which has a PEL, TLV or otherrecommended exposure limit.
At this time, the remaining constituent has no known exposure limits.
64-17-5 ethanol
PEL Long-term value: 1900 mg/m³, 1000 ppm
REL Long-term value: 1900 mg/m³, 1000 ppm
TLV Short-term value: 1000 ppm
A3· Additional information: The lists that were valid during the creation were used as basis.
(Contd. on page 5)
US58.0

Page 5/10

Safety Data Sheetacc. to OSHA HCS
Printing date 01/03/2024

Revision date 01/03/2024

Trade name: SM-102(Contd. from page 4)· Exposure controls· Personal protective equipment:· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
· Breathing equipment: Not required.
· Protection of hands:

S_Protective gloves

The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ thepreparation/ the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and thedegradation· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks ofquality and varies from manufacturer to manufacturer. As the product is a preparation of severalsubstances, the resistance of the glove material can not be calculated in advance and has therefore to
be checked prior to the application.
· Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has
to be observed.
· Eye protection:R_*

Tightly sealed goggles

9 Physical and chemical properties· Information on basic physical and chemical properties· General Information· Appearance:
Form:
LiquidColor:
According to product specification· Odor:Characteristic· Structural Formula
C44H87NO5· Molecular Weight710.2 g/mol· Odor threshold:Not determined.
· Formulation
A solution in ethanol· pH-value:

Not determined.

· Change in condition
Melting point/Melting range:
Boiling point/Boiling range:

Undetermined.
78 °C (172.4 °F)· Flash point:

13 °C (55.4 °F)(Contd. on page 6)US58.0

Page 6/10

Safety Data Sheetacc. to OSHA HCS
Printing date 01/03/2024

Revision date 01/03/2024

Trade name: SM-102(Contd. from page 5)· Flammability (solid, gaseous):

Highly flammable.

· Auto igniting:

425 °C (797 °F)· Decomposition temperature:

Not determined.

· Ignition temperature:

Product is not selfigniting.

· Danger of explosion:

Product is not explosive. However, formation of explosive air/vapor mixtures are possible.

· Explosion limits:
Lower:
Upper:

3.3 Vol %19 Vol %· Vapor pressure at 20 °C (68 °F):
· Vapor pressure at 50 °C (122 °F):

59 hPa (44.3 mm Hg)
280 hPa (210 mm Hg)· Density at 20 °C (68 °F):

1.47988 g/cm³ (12.3496 lbs/gal)· Bulk density:· Relative density· Vapor density· Evaporation rate

1,480 kg/m³
Not determined.
Not determined.
Not determined.

· Solubility in / Miscibility with
Water:

Fully miscible.

· Partition coefficient (n-octanol/water): Not determined.
· Viscosity:
Dynamic at 20 °C (68 °F):
Kinematic:
SOLUBILITY· Solvent content:
Organic solvents:
VOC content:
Solids content:· Other information

0.56 mPas
Not determined.
Chloroform: 100 mg/ml; Ethanol: 100 mg/ml
90.0 %
90.00 %
1,331.9 g/l / 11.12 lb/gal
10.0 %
No further relevant information available.

10 Stability and reactivity· Reactivity No further relevant information available.
· Chemical stability· Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.
· Possibility of hazardous reactions No dangerous reactions known.
· Conditions to avoid No further relevant information available.
· Incompatible materials: No further relevant information available.
· Hazardous decomposition products: No dangerous decomposition products known.
US(Contd. on page 7)58.0

Page 7/10

Safety Data Sheetacc. to OSHA HCS
Printing date 01/03/2024

Revision date 01/03/2024

Trade name: SM-102(Contd. from page 6)*

11 Toxicological information· Information on toxicological effects· Acute toxicity:· LD/LC50 values that are relevant for classification:
ATE (Acute Toxicity Estimate)
Oral
LD50
5,000 mg/kg
64-17-5 ethanol
Oral
LD50

10,470 mg/kg (rat)OECD Test Guideline 401
Inhalative LC50/4 h 117–125 mg/l (rat)OECD 403 (rat)· Primary irritant effect:· on the skin: Irritant to skin and mucous membranes.
· on the eye: Irritating effect.
· Sensitization: No sensitizing effects known.
· Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for
preparations:HarmfulIrritant· Carcinogenic categories· IARC (International Agency for Research on Cancer)
64-17-5 ethanol

1· NTP (National Toxicology Program)
None of the ingredients is listed.
· OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.

*12 Ecological information· Toxicity· Aquatic toxicity: No further relevant information available.
· Persistence and degradability No further relevant information available.
· Behavior in environmental systems:· Bioaccumulative potential No further relevant information available.
· Mobility in soil No further relevant information available.
· Additional ecological information:· General notes:
Water hazard class 1 (Self-assessment): slightly hazardous for water
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage
system.
· Results of PBT and vPvB assessment· PBT: Not applicable.
· vPvB: Not applicable.
· Other adverse effects No further relevant information available.
US(Contd. on page 8)58.0

Page 8/10

Safety Data Sheetacc. to OSHA HCS
Printing date 01/03/2024

Revision date 01/03/2024

Trade name: SM-102(Contd. from page 7)*

13 Disposal considerations· Waste treatment methods· Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage
system.
· Uncleaned packagings:· Recommendation: Disposal must be made according to official regulations.
· Recommended cleansing agent: Water, if necessary with cleansing agents.

*14 Transport information· UN-Number· DOT, IMDG, IATA
· UN proper shipping name· DOT· IMDG· IATA

UN1170Ethanol solutions
ETHANOL SOLUTION (ETHYL ALCOHOLSOLUTION)
Ethanol solution· Transport hazard class(es)· DOTxgc̀
d· Class· Label

3 Flammable liquids
3· IMDG, IATA

xgc̀d· Class· Label

3 Flammable liquids
3· Packing group· DOT, IMDG, IATA

II

· Environmental hazards:

Not applicable.

· Special precautions for user
Warning: Flammable liquids· Hazard identification number (Kemler code): 33· EMS Number:
F-E,S-D· Stowage CategoryA· Transport in bulk according to Annex II of
MARPOL73/78 and the IBC CodeNot applicable.
(Contd. on page 9)US58.0

Page 9/10

Safety Data Sheetacc. to OSHA HCS
Printing date 01/03/2024

Revision date 01/03/2024

Trade name: SM-102(Contd. from page 8)· Transport/Additional information:· DOT· Quantity limitations· IMDG· Limited quantities (LQ)
· Excepted quantities (EQ)

· IATA· Remarks:· UN "Model Regulation":*On passenger aircraft/rail: 5 L
On cargo aircraft only: 60 L
1L
Code: E2Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 500 ml
When sold in quantities of less than or equal to 1 mL,or 1 g, with an Excepted Quantity Code ofE1, E2, E4, or E5, this item meets the De Minimis
Quantities exemption, per IATA 2.6.10.
Therefore packaging does not have to be labeled asDangerous Goods/Excepted Quantity.
UN 1170 ETHANOL SOLUTION (ETHYL ALCOHOLSOLUTION), 3, II

15 Regulatory information· Safety, health and environmental regulations/legislation specific for the substance or mixture
No further relevant information available.
· Sara· Section 355 (extremely hazardous substances):
None of the ingredients is listed.
· Section 313 (Specific toxic chemical listings):
None of the ingredients is listed.
· TSCA (Toxic Substances Control Act):
64-17-5 ethanol

ACTIVE· Hazardous Air Pollutants
None of the ingredients is listed.
· Proposition 65· Chemicals known to cause cancer:
None of the ingredients is listed.
· Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
· Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
· Chemicals known to cause developmental toxicity:
64-17-5 ethanol· Carcinogenic categories· EPA (Environmental Protection Agency)
None of the ingredients is listed.
(Contd. on page 10)
US

58.0

Page 10/10

Safety Data Sheetacc. to OSHA HCS
Printing date 01/03/2024

Revision date 01/03/2024

Trade name: SM-102(Contd. from page 9)· TLV (Threshold Limit Value)64-17-5 ethanol

A3· NIOSH-Ca (National Institute for Occupational Safety and Health)None of the ingredients is listed.
· Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

16 Other information
All chemicals may pose unknown hazards and should be used with caution. This SDS applies only tothe material as packaged. If this product is combined with other materials, deteriorates, or becomes
contaminated, it may pose hazards not mentioned in this SDS. Cayman Chemical Company assumes
no responsibility for incidental or consequential damages, including lost profits, arising from the use of
these data. It shall be the user's responsibility to develop proper methods of handling and personal
protection based on the actual conditions of use. While this SDS is based on technical data judged tobe reliable, Cayman Chemical Company assumes no responsibility for the completeness or accuracy ofthe information contained herein.
· Department issuing SDS: Environment protection department.
· Contact: · Date of preparation / last revision 01/03/2024· Abbreviations and acronyms:
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
Flammable Liquids 2: Flammable liquids – Category 2
Acute Toxicity - Oral 4: Acute toxicity – Category 4
Skin Irritation 2: Skin corrosion/irritation – Category 2
Eye Irritation 2A: Serious eye damage/eye irritation – Category 2A· * Data compared to the previous version altered.
US