Safety Data Sheet

According to Regulation (EC) No 1907/2006, Annex II,Amended by COMMISSION REGULATION (EU) 2015/830,
According to REGULATION (EC) No 1272/2008
PolyFlex™ TPU90
Version 1.0
Issue date: 18-07-2020
Revision date: 18-07-2020

SDS Record Number: CSSS-TCO-010-133600

Section 1 Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier:Identification on the label/Trade name:

PolyFlex™ TPU90

Additional identification:

Not available

Identification of the product:

See section 3

Index Number:

Not available

REACH registration No.:

Not available

1.2 Relevant identified uses of the substance or mixture and uses advised against:
1.2.1 Identified uses:
3D Printing Filament.
1.2.2 Uses advised against:
Not available.

1.3 Details of the supplier of the safety data sheet:
Supplier(Only representative):-Supplier(Manufacturer):

JF Polymers (Suzhou) Co., Ltd.

Address:

Building 6&7&11, No.2, Hai Cheng Road, Chang Shu Economic &Technological Development Zone, 215513, People’s Republic of China

Contact person(E-mail):

Zhenggang Cai (zhenggang.cai@polymaker.com)

Telephone:+86-512-52058005

Fax:-1.4 Emergency telephone Number:+86-512-52058005
Available outside office hours?

YESNOX

Section 2 Hazards Identification
2.1 Classification of the substance or mixture:
2.1.1 Classification:
According to REGULATION (EC) No 1272/2008, based on available data, the classification criteria are not met:
REGULATION (EC) No 1272/2008
Hazard classes/Hazard categories

Hazard codes

Not classified

N/A

2.2 label elements:
Hazard Pictograms:

No hazard pictogram is used.

Signal Word(S):No signal word is used.

Hazard Statement:

Not applicable.

Precautionary statement:

Not applicable.

2.3 Other hazards:
Product name: PolyFlex™ TPU90
Version #: 1.0
Issue date: 18-07-2020.

Revision date: 18-07-2020.

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Not available.

Section 3 Composition/information on ingredients
Substance/Mixture:

Substance

Ingredient(s): This product does not contain hazardous ingredients above cut-off value according to Regulation (EC)1272/2008.

Section 4 First aid measures
4.1 Description of first aid measures:
In all cases of doubt, or when symptoms persist, seek medical attention.
4.1.1 In case of inhalation:
Remove to fresh air. Get medical attention for any breathing difficulty.
4.1.2 In case of skin contact:
May irritate damaged skin. Wash off with soap and plenty of water.
4.1.3 In case of eyes contact:
Immediately flush eyes with plenty of water, lifting upper and lower eyelids occasionally. Get medical attention if irritation
persists.
4.1.4 In case of ingestion:
If large amounts were swallowed, give water to drink and get medical advice.

4.2 Most important symptoms and effects, both acute and delayed:
The product is not classified as harmful to human health effect.

4.3 Indication of any immediate medical attention and special treatment needed:
If skin irritation or rash occurs, get medical advice/attention.

Section 5 Firefighting measures
5.1 Extinguishing media:
Suitable extinguishing media:

Use extinguishing measures that are appropriate to local circumstances and thesurrounding environment.

Unsuitable extinguishing media:

5.2 Special hazards arising from thesubstance or mixture
5.3 Advice for firefighters:

Not available.
No specific fire or explosion hazard.
Wear self contained breathing apparatus for fire fighting if necessary.

Section 6 Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures:
6.1.1 For non-emergency personnel:

Avoid dust formation.

6.1.2 For emergency responders:

Wear an appropriate NIOSH/MSHA approved respirator if dust is generated.

6.2 Environmental Precautions:

Do not let large amount of product enter drains.

6.3 Methods and material for Containment
and Cleaning up:
6.4 Reference to other sections:for disposal.

Sweep up and shovel. Keep in suitable, closed and properly labelled containers
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for information on disposal.

Section 7 Handling and storage
Product name: PolyFlex™ TPU90
Version #: 1.0
Issue date: 18-07-2020.

Revision date: 18-07-2020.

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7.1 Precautions for safe handling:
7.1.1 Protective measures:

Provide appropriate exhaust ventilation at places where dust is formed.

7.1.2 Advice on general occupational

Do not eat, drink and smoke in work areas. Wash hands after use. Removehygiene:

7.2 Conditions for safe storage, including
any incompatibilities:
7.3 Specific end use(s):contaminated clothing and protective equipment before entering eating areas.
Keep container closed in a dry place. Avoid dust formation.
Not applicable.

Section 8 Exposure Controls/Personal Protection
8.1 Control parameters:
8.1.1 Occupational exposure limits:

Not available.

8.1.2 Additional exposure limits under the

Not available.

conditions of use:
8.1.3 DNEL/DMEL and PNEC-Values:

Not available.

8.2 Exposure controls:
8.2.1Appropriate engineering controls:

Use process enclosures, local exhaust ventilation or other engineering controls
to keep worker exposure to airborne contaminants below any recommended orstatutory limits. If user operations generate dust, fumes or mist, use ventilation
to keep exposure to airborne contaminants below the exposure limit.

8.2.2 Individual protection measures, such as personal protective equipment:
Eye/face protection:

Safety glasses when eye contact is possible.

Hand protection:

For prolonged or repeated contact use protective gloves.

Body protection:

Skin covering working clothes; wear dust-proof overalls if large quantities of dust
are generated.

Respiratory protection:

Respiratory protection is not required. Where protection from nuisance levels ofdusts are desired, use type P1 (EN 143) dust masks. Use respirators andcomponents tested and approved under appropriate government standards
such as CEN (EU).

Thermal hazards:
8.2.3 Environmental exposure controls:

Wear suitable protective clothing to prevent heat.
Avoid discharge into the environment.
According to local regulations, Federal and official regulations.

Section 9 Physical and chemical properties
9.1 Information on basic physical and chemical properties:
Appearance:

Solid

Colour:Translucent

Odour:

Odorless

Odour threshold:Not available

pH:

Not available

Melting point/range (°C):

Not available

Boiling point/range (°C):

Not available

Flash point (°C):

Not available

Evaporation rate:

Not available

Flammability limit - lower (%):

Not available

Flammability (solid, gas):

Not available

Ignition temperature (°C):

Not available

Upper/lower explosive limits:

Not available

Product name: PolyFlex™ TPU90
Version #: 1.0
Issue date: 18-07-2020.

Revision date: 18-07-2020.

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Vapour pressure (20°C):

Not available

Vapour density:

Not available

Relative Density:

1.18-1.23

Bulk density (kg/m3):

Not available

Water solubility (g/l):

Insoluble in watern-Octanol/Water (log Po/w):

Not available

Auto-ignition temperature:

Not available

Decomposition temperature:

Not available

Viscosity, dynamic (mPa.s):

Not available

Explosive properties:

Not available

Oxidising properties:

Not available

Molecular Formula:

Not available

Molecular Weight:

Not available

9.2. Other information:
Fat solubility(solvent-oil to be specified)

Not available

etc:
Surface tension:

Not available

Dissociation constant in water( pKa):

Not available

Oxidation-reduction Potential:

Not available

Section 10 Stability and reactivity
10.1 Reactivity:
10.2 Chemical stability:

The substance is stable under normal storage and handling conditions.
Stable at room temperature in closed containers under normal storage andhandling conditions.

10.3 Possibility of hazardous reactions:10.4 Conditions to avoid:10.5 Incompatible materials:
10.6 Hazardous decomposition products:

No dangerous reactions known.
Incompatible materials.
Strong oxidizing agents
Carbon oxide.

Section 11 Toxicological information
11.1 Information on toxicological effects:
Acute toxicity:
LD50(Oral, Rat):

Not available

LC50(Inhalation, Rat):

Not available

LD50(Dermal, Rabbit):

Not available

Skin corrosion/Irritation:

Not classified

Serious eye damage/irritation:

Not classified

Respiratory or skin sensitization:

Not classified

Germ cell mutagenicity:

Not classified

Carcinogenicity:

Not classified

Reproductive toxicity:

Not classified

STOT- single exposure:

Not classified

STOT-repeated exposure:

Not classified

Aspiration hazard:

Not classified

Section 12 Ecological information
Product name: PolyFlex™ TPU90
Version #: 1.0
Issue date: 18-07-2020.

Revision date: 18-07-2020.

SDS EU4/6

12.1Toxicity:
Acute (short-term) toxicity:
LC50(96h, Fish):

Not available

LC50(48h, Crustacea):

Not available

EC50(72h, Algae/aquatic plants):

Not available

Chronic (long-term) toxicity:
NOEC(Fish):

Not available

NOEC(Crustacea):

Not available

EC50(Algae/aquatic plants):

Not available

12.2 Persistence and degradability:

Not available.

12.3 Bioaccumulative potential:

Not available.

12.4 Mobility in soil:

Not available.

12.5 Results of PBT and vPvB assessment:

Not available.

12.6 Other adverse effects:

Not available.

Section 13 Disposal considerations
13.1 Waste treatment methods:

Any disposal practice must be in compliance with all local and national laws andregulations. Do not dump into any sewers, on the ground, or into any body ofwater.

Section 14 Transport information
Land transport

Inland waterways

Sea transport

Air transport(ADR/RID)(ADN)(IMDG)(ICAO/IATA)

UN number

Not regulated

Not regulated

Not regulated

Not regulated

UN Proper shipping nameNot regulated

Not regulated

Not regulated

Not regulated

Transport hazard Class(es)Not regulated

Not regulated

Not regulated

Not regulated

Packing group

Not regulated

Not regulated

Not regulated

Not regulated

Environmental hazards

NoNoNoNo

Special precautions for user

See section 2.2

See section 2.2

See section 2.2

See section 2.2

Not regulated

Not regulated

Not regulated

Not regulated

Transport in bulk according toAnnex II of Marpol and the IBC
CodeSection 15 Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture:
Relevant information regarding authorization:

Not applicable.

Relevant information regarding restriction:

Not applicable.

Other EU regulations:

Employment restrictions concerning young person must be observed.

Other National regulations:Not applicable15.2 Chemical safety assessment

YES

For use only by technically qualified individuals.

Product name: PolyFlex™ TPU90
Version #: 1.0
Issue date: 18-07-2020.

Revision date: 18-07-2020.

NOX

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Section 16 Other information
16.1 Indication of changes:
Version 1.0 Amended by (EU) 2015/830

16.2 Abbreviations and acronyms:
ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
RID: Regulation for rail International transportation of Dangerous goods
ADN: European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways
IMDG: Code international maritime dangerous goods code
ICAO: International Civil Aviation Organization
IATA: International Air Transport Association
LC50: median lethal concentration
EC50: The effective concentration of substance that causes 50% of the maximum response.
NOEC: No Observed Effect Concentration
DNEL: derived no-effect level
PNEC: predicted no-effect concentration

16.3 Key literature references and sources for data
ECHA Registered substances data

16.4 Training instructions:Not applicable.

16.5 Further information:
This information is based upon the present state of our knowledge. This SDS has been compiled and is solely intended for thisproduct.

16.6 Notice to reader:
Employers should use this information only as a supplement to other information gathered by them, and should makeindependent judgment of suitability of this information to ensure proper use and protect the health and safety of employees. This
information is furnished without warranty, and any use of the product not in conformance with this Safety Data Sheet, or in
combination with any other product or process, is the responsibility of the user.
Author: Hangzhou C&K Testing Technic Co.,Ltd

Product name: PolyFlex™ TPU90
Version #: 1.0
Issue date: 18-07-2020.

Website:www.cirs-ck.com

Revision date: 18-07-2020.

Tel:0571-89900715

Email:test@cirs-group.com

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