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Safranine,JUNSEI CHEMICAL CO., LTD.,31371jis_J_E1-1,04/06/2014
date of issue : 04/06/2014

Safety Data Sheets

1. Identification
Product name :Safranine
Name of supplier :JUNSEI CHEMICAL CO., LTD.
Address :1-6, Ohmano-Cho, Koshigaya, Saitama 343-0844, Japan
Division :Quality Assurance Department
Phone :+81-48-986-6161
FAX :+81-48-989-2787
E-mail :shiyaku-t@junsei.co.jp
Product code(SDS NO) :31371jis_J_E1-1

2. Hazards identification
GHS classification and label elements of the product
GHS classification(Note) GHS classification without description : Not applicable/Out of classification/Not
classifiable

3. Composition/information on ingredients
Substance/Preparation :SubstanceCommon name, synonyms :Basic Red 2; [CI-50240]
Ingredient name:Safraninecontent(%):Chemical formula:C20H19ClN4
Chemicals No, Japan:5-1948
CAS No.:477-73-6
MW:350.85
ECNO:207-518-8

4. First-aid measures
IF INHALED
Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Call a POISON CENTER or doctor/physician if you feel unwell.
IF ON SKIN（or hair）
Take off immediately all contaminated clothing. Rinse skin with water/shower.
If skin irritation or rash occurs: Get medical advice/attention.
IF IN EYES :Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing.
If eye irritation persists: Get medical advice/attention.
IF SWALLOWED
Rinse mouth.
Call a POISON CENTER or doctor/physician if you feel unwell.

5. Fire-fighting measures
Suitable extinguishing media
Use appropriate extinguishing media suitable for surrounding facilities.

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Safranine,JUNSEI CHEMICAL CO., LTD.,31371jis_J_E1-1,04/06/2014
Specific hazards arising from the chemical
Containers may explode when heated.
Fire may produce irritating, corrosive and/or toxic gases.
Special protective equipment and precautions for fire-fighters
Wear fire/flame resistant/retardant clothing.
Wear cold insulating gloves/face shield/eye protection.
Firefighters should wear self-contained breathing apparatus with full face peace operated
positive pressure mode.

6. Accidental release measures
Personnel precautions, protective equipment and emergency procedures
Ventilate area after material pick up is complete.
Wear proper protective equipment.
Environmental precautionsAvoid release to the rivers, lakes, ocean, groundwater.
Methods and materials for neutralization, containment and cleaning up
Sweep up, place in a bag and hold for waste disposal.
Preventive measures for secondary accident
Collect spillage.

7. Handling and storage
Precautions for safe handling
Preventive measures(Protective measures against fire & explosion)
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Exhaust/ventilator
Exhaust/ventilator should be available.
Safety treatments
Avoid contact with skin.
Avoid contact with eyes.
Avoid breathing dust, vapor, mist, or gas.
Safety Measures/Incompatibility
Wear protective gloves, protective clothing or face protection.
Use personal protective equipment as required.
When using do not eat, drink or smoke.
Conditions for safe storage, including any incompatibilities
Recommendation for storage
Keep container tightly closed.
Keep cool . Protect from sunlight.
Store in well-ventilated place.

8. Exposure controls/personal protection
Appropriate engineering controls
Do not use in areas without adequate ventilation.
Eye wash station should be available.
Washing facilities should be available.
Protective equipmentRespiratory protection
Wear positive pressure self-contained breathing apparatus (SCBA).
Hand protection
Wear protective gloves.

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Safranine,JUNSEI CHEMICAL CO., LTD.,31371jis_J_E1-1,04/06/2014
Eye protection
Wear eye/face protection.

9. Physical and Chemical Properties
Physical properties
Appearance :crystalline powder
Color :red brown - dark brownodour data N.A.
pH data N.A.
Phase change temperature
Initial Boiling Point/Boiling point data N.A.
Melting point/Freezing point data N.A.
Decomposition temperature data N.A.
Flash point data N.A.
Auto-ignition temperature data N.A.
Explosiont data N.A.
Vapor pressure data N.A.
Vapor density data N.A.
Specific gravity/Density data N.A.
Solubility
Solubility in water :slightly soluble
Solubility in solvent :slightly soluble in ethanol.
n-Octanol /water partition coefficient data N.A.

10. Stability and Reactivity
Stability
Stable under normal storage/handling conditions.
Conditions to avoid
Contact with incompatible materials.
Open flames. Heat.
Incompatible materials
Strong oxidizing agents
Hazardous decomposition products
Carbon oxides, Nitrogen oxides, Chloride.

11. Toxicological Information
Symptoms related to the physical, chemical and toxicological characteristics
No Acute toxicity data available
No Irritant properties data available
No Allergenic and sensitizing effects data available
No Mutagenic effects data available
No Teratogenic effects data available
No Carcinogenic effects data available
No Toxicity for reproduction data available
No Delayed/chronic effects from short/long-term exposure data available
No Aspiration hazard data available

12. Ecological Information
Ecotoxicity
No Aquatic toxicity data available

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Safranine,JUNSEI CHEMICAL CO., LTD.,31371jis_J_E1-1,04/06/2014
No Persistence and degradability data available
No Bioaccumulative potential data available

13. Disposal Considerations
Disposal methods
Dispose of contents/container in accordance with local/national regulation.

14. Transport Information
UN No, UN CLASS
Not applicable to UN NO.

15. Regulatory Information
The product is not applicable to GHS classifications.
US major regulations
TSCA
Safranine
Other regulatory information
Ensure this material in compliance with federal requirements and ensure conformity to local
regulations.

16. Other information
Reference Book
Globally Harmonized System of classification and labelling of chemicals, (4th ed., 2011), UN
Recommendations on the TRANSPORT OF DANGEROUS GOODS 18th edit., 2013 UN
Classification, labelling and packaging of substances and mixtures (table3-1 ECNO6182012)2012 EMERGENCY RESPONSE GUIDEBOOK(US DOT)
2014 TLVs and BEIs. (ACGIH)
http://monographs.iarc.fr/ENG/Classification/index.php
Supplier's data/information
Chemical Risk Information Platform (CHRIP)(NITE) http://www.safe.nite.go.jp/japan/db.html
GHS Classification Guidance for Enterprises 2013 Revised Edition （August, 2013,METI)
Other information
This information contained in this data sheet represents the best information currently
available to us. However, no warranty is made with respect to its completeness and weassume no liability resulting from its use. It are advised to make their own tests todeterminate the safety and suitability of each such product or combination for their own
purposes.
The data given here is based on current knowledge and experience. The purpose of this
Safety Data Sheet is to describe the products in terms of their safety requirements. The
data does not signify any warranty with regard to the products' properties.
The GHS classification data given here is based on current EU official data