ᐇ㦂ሗ࿌᭩ᵝᘧ䠄୍⯡฼⏝ㄢ㢟䞉ᡂᯝබ㛤฼⏝䠅㻌䠄 䈜ᮏሗ࿌᭩䛿ⱥㄒ䛷グ㏙䛧䛶䛟䛰䛥䛔䚹䛯䛰䛧䚸⏘ᴗ฼⏝ㄢ㢟䛸䛧䛶᥇ᢥ䛥䜜䛶䛔䜛᪉䛿᪥ᮏㄒ䛷グ㏙䛧䛶䛔䛯䛰䛔䛶䜒⤖ᵓ䛷䛩䚹 䠅㻌Experimental Report㻌ᢎㄆ᪥ Date of Approval㻌 2015/6/17
ᢎㄆ⪅ Approver㻌 K aoru Shibata
ᥦฟ᪥ Date of Report㻌 2015/6/16

ㄢ㢟␒ྕ㻌 Project No.㻌⿦⨨㈐௵⪅ Name of Instrument scientist㻌

2015A0077

ᰘ⏣㻌 ⸅㻌

ᐇ㦂ㄢ㢟ྡ㻌 Title of experiment㻌⿦⨨ྡ Name of Instrument/䠄BL No.䠅㻌

୰ᛶᏊ‽ᙎᛶᩓ஘ἲ䛻䜘䜛ᯫᶫ䝣䜵䝜䞊䝹ᶞ⬡୰䛻㻌

DNA/BL02㻌ᣊ᮰䛥䜜䛯䝯䝍䝜䞊䝹ศᏊᣑᩓᣲື䛾ゎᯒ㻌ᐇ᪋᪥ Date of Experiment㻌ᐇ㦂㈐௵⪅ྡ㻌 Name of principal investigator㻌

2015/4/27-29㻌㤳⸨㻌 㟹ᖾ㻌ᡤᒓ㻌 Affiliation㻌ఫ཭䝧䞊䜽䝷䜲䝖ᰴᘧ఍♫㻌㻌ヨᩱ䚸ᐇ㦂᪉ἲ䚸฼⏝䛾⤖ᯝᚓ䜙䜜䛯୺䛺䝕䞊䝍䚸⪃ᐹ䚸⤖ㄽ➼䜢䚸グ㏙䛧䛶ୗ䛥䛔䚹䠄㐺ᐅ䚸ᅗ⾲ῧ௜䛾䛣䛸䠅㻌
Please report your samples, experimental method and results, discussion and conclusions. Please add figures andtables for better explanation.
㻝㻚㻌 ヨᩱ Name of sample(s) and chemical formula, or compositions including physical form.㻌䛆ヨᩱ䛇㻌䞉䝃䞁䝥䝹 1䠖㔜Ỉ⣲໬䝣䜵䝜䞊䝹ᶞ⬡◳໬≀(d-PR) / 䝯䝍䝜䞊䝹(h-MeOH)ΰྜ≀ (h-MeOH ྵ᭷㔞 8wt%)
䞉䝃䞁䝥䝹 2䠖㔜Ỉ⣲໬䝣䜵䝜䞊䝹ᶞ⬡◳໬≀(d-PR) / 㔜䝯䝍䝜䞊䝹-d4(d-MeOH)ΰྜ≀ (d-MeOH ྵ᭷㔞8wt%)
d-PR 䛿䚸㔜Ỉ⣲໬䝣䜵䝜䞊䝹䛸㔜Ỉ⣲໬䝩䝹䝮䜰䝹䝕䝠䝗㔜Ỉ⁐ᾮ䜢⏝䛔䛶ⶃ㓟Ꮡᅾୗ䛷ྜᡂ䛧䛯㔜Ỉ⣲໬䝜䝪䝷䝑䜽䛸䚸䝦䜻䝃䝯䝏䝺䞁䝔䝖䝷䝭䞁䜢 100/13(wt/wt)䛷䝗䝷䜲䝤䝺䞁䝗䛧䛯ᚋ䚸175䉝䛷 3 ศ㛫ᅽ⦰ᡂᙧ䛩䜛䛣䛸䛷స〇䛧䛯䚹ᚓ䜙䜜䛯ᡂᙧရ䛸 h-MeOH 䛒䜛䛔䛿 d-MeOH 䜢⪏ᅽᐜჾ䛻ᑒධ䛧䚸80䉝䛷 70 ᫬㛫䚸ຍ⇕䞉ຍᅽฎ⌮䛩䜛䛣䛸䛷䚸䝯䝍䝜䞊䝹䜎䛯䛿㔜䝯䝍䝜䞊䝹䜢 8wt%ྵ䜐ᶞ⬡䝃䞁䝥䝹䜢ᚓ䛯䚹㻌㻞㻚㻌 ᐇ㦂᪉ἲཬ䜃⤖ᯝ㻌 䠄ᐇ㦂䛜䛖䜎䛟䛔䛛䛺䛛䛳䛯ሙྜ䚸䛭䛾⌮⏤䜢グ㏙䛧䛶䛟䛰䛥䛔䚹䠅㻌
Experimental method and results. If you failed to conduct experiment as planned, please describe reasons.
䛆ᐇ㦂᪉ἲ䛇㻌
䝃䞁䝥䝹 1 (d-PR/h-MeOH)䛚䜘䜃䝃䞁䝥䝹 2 (d-PR/d-MeOH)䛿 0.2 mm 䝯䝑䝅䝳䜢⏝䛔䛶㐲ᚰ⢊○ᶵ䛻䜘䜚⢊○䛧䛯ᚋ䚸䜰䝹䝭⟩ୖ䛻ཌ䛥 1 mm 䛻䛺䜛䜘䛖䛻ᩜ䛝䚸ྠᚰ෇⟄ᆺ䝉䝹䛻ᑒධᚋ䚸䝦䝸䜴䝮䜺䝇⨨᥮䜢䛚䛣䛺䛳䛯䚹‽ᙎᛶᩓ஘ ᐃ䛿㧗ศゎ⬟䝰䞊䝗(ΔE = 3.5 μeV)䜢⏝䛔䚸ᐊ (T = 296 K)䛷䛚䛣䛺䛳䛯䚹䛆ᐇ㦂⤖ᯝ䛇
Figure 1 䛻䝃䞁䝥䝹 1(d-PR /h-MeOH)䛚䜘䜃䝃䞁䝥䝹 2 (d-PR/ d-MeOH)䛾஧ḟඖ‽ᙎᛶᩓ஘䝥䝻䝣䜯䜲䝹䜢♧䛩䚹䝃䞁䝥䝹 1 䛷䛿㧗 q 㡿ᇦ䛻䛚䛔䛶‽ᙎᛶᩓ஘䛾ᗈ䛜䜚䛜ほ 䛥䜜䛯䛜䚸䝃䞁䝥䝹 2 䛷䛿᫂☜䛺‽ᙎᛶᩓ஘䛾ᗈ䛜䜚䛿ほ 䛥䜜䛺䛛䛳䛯䚹䝃䞁䝥䝹 1 䛸 2 䛾ᕪ䛿䝯䝍䝜䞊䝹䛾 H/D 䝁䞁䝖䝷䝇䝖䛻⏤᮶䛩䜛䛣䛸䛛䜙䚸䝃䞁䝥䝹 1 䛷ほ 䛥䜜䛯‽ᙎᛶᩓ஘䛾ᗈ䛜䜚䛿ᶞ⬡୰䛻ྵ䜎䜜䜛䝯䝍䝜䞊䝹䛾ᣑᩓ䛻⏤᮶䛩䜛䜒䛾䛷䛒䜛䛸᥎ᐃ䛥䜜䜛䚹ᚓ䜙䜜䛯‽ᙎᛶᩓ஘䝥䝻䝣䜯䜲䝹䜢ヲ⣽䛻ศᯒ䛩䜛䛯䜑䚸㐠ືᛶᡂศ䛜䝻䞊䝺䞁䝒㛵ᩘ䛷グ㏙䛷䛝䜛䜒䛾䛸௬ᐃ䛧䚸୍ḟඖ䝥䝻䝣䜯䜲䝹䛾䝣䜱䝑䝔䜱䞁䜾䜢䛚䛣䛺䛳䛯䚹䝃䞁䝥䝹 1 䛾䝣䜱䝑䝔䜱䞁䜾⤖ᯝ䜢㻞㻚㻌 ᐇ㦂᪉ἲཬ䜃⤖ᯝ䠄䛴䛵䛝䠅㻌 Experimental method and results (continued)
0.10

0.10

T = 296 K
d-PR / h-MeOH

0.08

0.08
0.06

!ZmeV!ZmeV

0.06

T = 296 K
d-PR / d-MeOH

0.04
0.02

0.04
0.020.00

0.00

–0.02

–0.02

–0.04

–0.04
0.0

0.5

1.0

1.5

2.0

0.0

0.5

1.0

–1

1.5

2.0

–1


Figure 1. Quasielastic neutron scattering profiles of sample 1 (d-PR/h-MeOH) (left) and sample 2 (d-PR/q/Å

q/Å

d-MeOH) (right) measured at T = 296 K with ΔE = 3.5 μeV.
Figure 2(a)䛻♧䛩䚹䛣䛾⤖ᯝ䛛䜙‽ᙎᛶᩓ஘䝥䝻䝣䜯䜲䝹䛻䛚䛔䛶䝻䞊䝺䞁䝒㛵ᩘ䛷⾲⌧ྍ⬟䛺㐠ືᛶ䜢᭷䛩䜛ᡂศ䛜Ꮡᅾ䛩䜛䛣䛸䜢☜ㄆ䛥䜜䛯䚹䛣䛾㐠ືᛶᡂศ䛜䝯䝍䝜䞊䝹䛻⏤᮶䛩䜛䜒䛾䛸䛧䚸᭦䛻䝯䝍䝜䞊䝹䛾ᣑᩓ䛜 Jump Diffusion 䝰䝕䝹䛷グ㏙ྍ⬟䛸⪃䛘䚸q2 䜢ᶓ㍈䛻䛸䜚䚸䝻䞊䝺䞁䝒㛵ᩘ䛾䝣䜱䝑䝔䜱䞁䜾⤖ᯝ䛛䜙ᚓ䜙䜜䛯್༙༙ᖜ(HWHM)Γ 䛾ኚ໬䜢 Figure 2(b)䛻♧䛧䛯䚹
161–1

T = 296 K, q = 1.7 Åd-PR / h-MeOHobserved
fittedLorentziandelta
background(a)S(q,Z) / a.u.

010

* / PeV

10–1

1014

d-PR / h-MeOH
Jump Diffusion Model

12(b)

10
8
6
4–2

102–3

10–0.04 –0.02

0.00

0.02

0.04

!Z/ meV

0.06

0.08

0.10

0
0.0

0.5

1.0

1.5

2.0

2–2

q /Å

2.5

3.0

3.5

Figure 2. (a) Dynamic structure factor S(q,ω) of sample 1 (d-PR/h-MeOH) at q = 1.7 Å–1. (b) HWHM Γdependence on q2 of sample 1 (d-PR/h-MeOH). Solid line represents a fitting curve estimated from jumpdiffusion model.
Jump Diffusion 䝰䝕䝹䛻䜘䜛䝣䜱䝑䝔䜱䞁䜾䜹䞊䝤䛷䛿㧗 q 㡿ᇦ䛻䛚䛡䜛 Γ 䛾ኚ໬䜢䛖䜎䛟⾲⌧䛷䛝䜛䛜䚸ప q㡿ᇦ䛾್༙ᖜ䛾ኚ໬䜢෌⌧䛩䜛䝟䝷䝯䞊䝍䛿ᚓ䜙䜜䛺䛛䛳䛯䚹䛣䛾⤖ᯝ䛿䚸ᯫᶫ䝣䜵䝜䞊䝹ᶞ⬡㦵᱁୰䛾䝯䝍䝜䞊䝹䛾ᣊ᮰䛥䜜䛯䝎䜲䝘䝭䜽䝇䜢⾲⌧䛩䜛ୖ䛷 Jump Diffusion 䝰䝕䝹䛜㐺ษ䛷䛺䛔䛣䛸䜢♧၀䛩䜛䛜䚸୍᪉䛷ᶞ⬡㦵᱁䛻ྵ䜎䜜䜛ᯫᶫ๣(䝦䜻䝃䝯䝏䝺䞁䝔䝖䝷䝭䞁)⏤᮶䛾䝯䝏䝺䞁(CH2)䛜㐠ືᛶᡂศ䛸䛧䛶ᙳ㡪䛧䛶䛔䜛䛣䛸䜒⪃䛘䜙䜜䜛䚹௒ᚋ䛿䝯䝍䝜䞊䝹㠀ྵ᭷ᶞ⬡䛾ᐇ㦂⤖ᯝ䛾ゎᯒ䜔䝣䜱䝑䝔䜱䞁䜾㛵ᩘ䛾෌᳨ウ䜢䛚䛣䛺䛔䚸ᯫᶫᶞ⬡୰䛻䛚䛡䜛䝯䝍䝜䞊䝹䛾㐠ືᛶ䜢ヲ⣽䛻ゎᯒ䛩䜛ணᐃ䛷䛒䜛䚹㻌