HAU - 1 / 4SAFETY DATA SHEET
2020-8-8
May be used to comply with
OSHA's Hazard Communication Standard,
29 CFR 1910. 1200.
Standard must be consulted for specific requirements.

U.S. Department of Labor
Occupational Safety and Health Administration(Non-Mandatory Form)OMB No.1218-0072

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§ 1 - IDENTITY INFORMATION
Product Name (as used on label and list) : HOLBEIN ACRYLIC COLORS HEAVY BODY
Manufacturer : HOLBEIN Works, Ltd.
Address : 2-2-5, Ueshio, Chuo-ku, Osaka-shi,OSAKA 542-0064 JAPAN
Telephone Number for information : 81-6-6191-7722
Emergency Telephone Number : 81-72-985-1221
Preparer : ALAKI, Yutaka──────────────────────────────────────────§ 2 - HAZARD IDENTIFICATIONThis product is water-based and not classified as dangerous for supply or conveyance.
The ingredients are water-reducible and falls well within the acceptable safety limits.
The information of individuals are shown on Table 1 of appendix.
Classification :Danger :Eye Effects :Non-regulated
Nonflammable
Category 2B／Causes eye irritation. Physically stimulates in theeyes, and may cause keratitis.
Ecological consideration : →§12
GHS label elements : Void──────────────────────────────────────────

§ 3 - COMPOSITION / INGREDIENTS
Substance/Mixture ：Mixture (* and ** are main ingredients)

Components (Specific Chemical Identity, Common Name (s))
CAS
Colorant *(Pigment)
Binder **(Acrylic-Metacrylic Copolymer Emulsion)
25852-37-3
Dispersant(Sodium Polycarboxylate)25549-84-2
Moisturizer(Propylene Glycol)
57-55-6
Thickener(Polyacrylate)9003-01-4
pH Agent(Dimethylaminoethanol)
108-01-0
Preservative/Fungicide(Thiabendazole)148-79-8
Preservative/Antiseptic(Benzisothiazoline)
2634-33-5──────────────────────────────────────────§ 4 - FIRST AID MEASURES
Eyes :

In case of eye contact, rinse with plenty of water and if necessary consult an eyespecialist.
Ingestion : In case of swallowing, drink plenty of water. Induce vomiting. If you feelunwell, seek medical advice.
Skin Contact : Upon skin contact, wash with plenty of water, soap or other non-irritatingcleansing agents.
Inhalation : Upon inhalation of aerosol/vapor, take the person to fresh air. If there isdifficulty in breathing, medical advice is required.
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§ 5 - FIRE AND EXPLOSION HAZARD DATA
Flammability : Not combustible
Flash Point, Ignition Point : Not below 100 ﾟ C
Combustion Products : Formation of carbon dioxide and oxide of metal according to pigment.
Extinguishing Method : Regular
Extinguishing Media : Water (Foam, Dry powder and Carbon dioxide, if necessary)
Precaution for Firefighters : Do not inhale combustion gases.
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§ 6 - ACCIDENTAL RELEASE MEASURES
Accidental Release Measures :Environmental Precautions :Wipe off.
Prevent spills from entering storm sewers or drains and contact withsoil.
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§ 7 - HANDLING AND STORAGE
Precautions for Storing ： Keep from freezing.
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§ 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
Avoid invasion to the eyes or body. Avoid prolonged or repeated contact with skin.
Wash mouth or hands well after use. Avoid inhaling aerosols.
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§ 9 - PHYSICAL / CHEMICAL CHARACTERISTICS
Appearance and Odor : Colored Paste with faint acrylic odor
Specific Gravity (H2O = 1) : 1.1～1.5
Boiling Point : Approx. 100℃
Vapor Density (Air = 1) : －Vapor Pressure (Butyl Acetate = 1) : Same as water
pH : 7.5～8.5
Solubility in Water : Can be diluted. Not so, after dried.
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§ 10 - HAZARD INFORMATION AND STABILITY
Physical Dangers :Stability :Reactivity :Byproducts :Nonflammable
Stable under normal state
None
Carbon dioxide, oxide of metal according to pigment and water incase of fire.
No thermal decomposition when stored and handled correctly.
Incompatibility (Materials to Avoid) : None──────────────────────────────────────────§ 11 - TOXICOLOGICAL INFORMATION
Primary Routes of Entry :Oral Toxicity :Dermal, eye contact, inhalation, swallowing
The products may flocculate by gastric acid.
Toxicity of this media itself is not confirmed.

On pigments, to be noted.as :Colors named with Cadmium :Cobalt Blue, Cerulean Blue :Eye irritation ：Skin irritation ：Inhalation Toxicity ：Contains Cadmium ingredient, influences to fetus, induce
kidney or lungs damage.
Contains soluble Cobalt, induce anemia and heart or lungs
damage.

Irritant, but damage the organization
Irritant by repeated or prolonged contact, and may cause
inflammation.
Although some of raw materials are pointed to may stimulate eyes
and respiratory organs with their vapor or mists under highly
concentrated state, the toxic act of acrylic colors is not confirmed.

HAU - 3 / 4Carcinogenicity, Sensitization, Mutagenicity, Teratogenicity, Reproductive Toxicity :No data available on products.
──────────────────────────────────────────§ 12 - ECOLOGICAL INFORMATIONFish Toxicity :It is pointed that acrylic polymer emulsion may obstruct the breathingof fishes, in case of pouring the excess colors to river or pond.
Persistence and Degradability : Not confirmed as a product. Involves colorant-contamination.
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§ 13 - DISPOSAL CONSIDERATIONS
Disposal Considerations :Dispose in accordance with national and/or local regulations.
Avoid entry into the sewage system (danger of clogging).
──────────────────────────────────────────§ 14 - TRANSPORT INFORMATION
Precautions for Transport : None, especially
UN Proper Shipping Name : Not applicable
UN Number : Not applicable
UN Hazard Class : Not applicable
Packing Group : Not applicable──────────────────────────────────────────

§ 15 - REGULATORY INFORMATION
Danger Class :Fire Service Law :Industrial Safety and Health Law :Pollutant Release and Transfer Register :N/A (Not flammable liquid)
N/A
N/A
N/A

Conforms to ACMI under ASTM D 4236.
ACMI : The Art & Creative Materials Institute, Inc.
ASTM : ASTM International (Former “American Society for Testing and Materials”)──────────────────────────────────────────

§ 16 - OTHER INFORMATION
Notice： All information contained herein is for references and guidance for normal use, and not for all conceivableconditions of handling and use. The responsibility for irregular use belongs to user individuals. Allinformation are under our knowledge of today, and not secure the perfection. All information may change
according to circumstances.

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Appendix
Table 1Ref NoName

Information of Acrylic Colors

Hazardous Classification
ingredient
AU 100 Amethyst
APAU 006 Anthraquinone RedAP
AU 084 Aqua BlueAP
AU 118 Azo Brown
AP
AU 058 Bamboo GreenAP
AU 048 Bismuth Yellow
AP
AU 027 Brilliant Pink
AP
AU 111 Burnt Sienna
AP
AU 112 Burnt Umber
AP
AU 061 Cadmium GreenCd
CL
AU 062 Cadmium Green Deep Cd
AP
AU 060 Cadmium Green Light Cd
CL
AU 024 Cadmium Orange
Cd
AP

Ref NoName

Hazardous Classification
ingredient
AU 022 Cadmium RedCdAP
AU 023 Cadmium Red LightCd
AP
AU 021 Cadmium Red Purple
CdAPAU 046 Cadmium YellowCdAP
AU 045 Cadmium Yellow Deep Cd
AP
AU 047 Cadmium Yellow Light Cd
CLAU 078 Cerulean BlueCoAP
AU 079 Cobalt BlueCoAP
AU 076 Cobalt Blue Hue
AP
AU 066 Cobalt GreenCoAP
AU 099 Cobalt Violet
Co
AP
AU 086 Compose Blue No.1
AP
AU 087 Compose Blue No.2
AP

HAU - 4 / 4Ref No

Name

Hazardous Classification
ingredient
AU 068 Compose GreenAP
AU 104 Compose Rose
AP
AU 103 Compose Violet
AP
AU 067 Cyprus GreenCo
AP
AU 091 Dioxazine Violet
APAU 042 Greenish Yellow
AP
AU 136 Grey V-3
AP
AU 137 Grey V-5
APAU 138 Grey V-7
AP
AU 139 Grey V-8
AP
AU 037 Hansa Yellow
AP
AU 039 Hansa Yellow Lemon
AP
AU 038 Hansa Yellow LightAP
AU 054 Hooker's GreenAP
AU 119 Imidazolone Brown
AP
AU 035 Imidazolone Lemon
AP
AU 019 Imidazolone Orange
AP
AU 034 Imidazolone Yellow
AP
AU 075 Indanthrene BlueAP
AU 031 Isoindolinone Yellow
AP
AU 131 Ivory BlackAP
AU 029 Jaune Brillant
AP
AU 133 Lamp BlackAP
AU 056 Light GreenAP
AU 188 Luminous GreenAP
AU 187 Luminous Lemon
AP
AU 183 Luminous OperaAP
AU 185 Luminous Orange
AP
AU 184 Luminous RedAP
AU 182 Luminous RoseAP
AU 181 Luminous Violet
AP
AU 186 Luminous Yellow
AP
AU 077 Manganese Blue Nova AP
AU 032 Marigold
AP
AU 132 Mars BlackAP
AU 107 Mars Violet
AP
AU 092 Mauve
AP
AU 057 Middle GreenAP
AU 009 Naphthol RedAP
AU 008 Naphthol Red DeepAP
AU 010 Naphthol Red LightAP
AU 049 Naples Yellow
AP
AU 041 Nickel Azo Yellow
AP
AU 065 Oxide of Chromium
AP
AU 135 Payne's Grey
APCdCadmium
CoCobalt
AP (Approved Product) :CL (Cautionary Label)

Ref NoNameHazardous Classification
ingredient
AU 170 Pearl BlueAP
AU 164 Pearl CopperAP
AU 162 Pearl GoldAPAU 169 Pearl GreenAP
AU 166 Pearl Pink
AP
AU 167 Pearl Red
AP
AU 163 Pearl SilverAP
AU 165 Pearl Sparkle
AP
AU 161 Pearl WhiteAP
AU 168 Pearl Yellow
AP
AU 005 Perylene Maroon
AP
AU 072 Phthalo BlueAP
AU 073 Phthalo Blue Red Shade AP
AU 051 Phthalo GreenAP
AU 071 Phthalo TurquoiseAP
AU 154 Primary BlackAP
AU 153 Primary CyanAP
AU 151 Primary Magenta
AP
AU 155 Primary WhiteAP
AU 152 Primary Yellow
AP
AU 016 Pyrrole Orange
AP
AU 014 Pyrrole RedAP
AU 015 Pyrrole Red LightAP
AU 013 Pyrrole Rubin
AP
AU 001 Quinacridone Crimson AP
AU 120 Quinacridone GoldAP
AU 096 Quinacridone Magenta AP
AU 002 Quinacridone RedAP
AU 095 Quinacridone Violet
AP
AU 114 Raw Sienna
AP
AU 115 Raw Umber
AP
AU 117 Red Ochre
AP
AU 055 Sap GreenAP
AU 121 Sepia
AP
AU 053 Shadow GreenAP
AU 028 Shell Pink
AP
AU 141 Titanium WhiteAP
AU 081 Ultramarine BlueAP
AU 082 Ultramarine DeepAP
AU 052 Viridian Hue
AP
AU 043 Yellow OchreAP
AU 142 Zinc WhiteAP

Contain no materials in sufficient quantities to be toxic or injurious to humans.
Any known health risks and with information on the safe and proper use of
these materials