X üñÜ@ðp¢½nCubh^½E«à®öÌÌ\¢]¿ÃìC½ÈwZpU»@\såwERATO kì×EvWFNg¨¿_×EVXe_§600_8815 ssºæ°¾c¬93âcCgv|

àc@lPxõÈw¤Z^[O[v[_[ÁCy³ösT[`p[N 3 Ùå²¤õ

5198 ºÉ§²pS²p¬õs 1_1_1§679_L@¨Æà®CI©ç©ÈWIÉ\z³êé½E«à®öÌiPCPsjÆÄÎêéVµ¢zÞ¿ðp¢ÄCnt©çÌGs^LV¬·ÉæèunCubh^½E«à®öÌvðn»µCúËõðp¢½ X üñÜÀ±Éæè\¢Öðè·é±ÆÉ¬÷µ½B»Åé PCPs Ì X üñÜ@©çÌtB[hobNÉæéVKÞ¿ÝvíªÉÂ¢Äà¾·éB

1. Cg_NVVjÉª´µ½àÌÅèC±êçðRg[·é±ÆC·Èí¿C×EÌå«³C×E\ÊÌ»wICü½E«Þ¿ÆÍC»ÌàÉ³Ì÷¬È×EðàÂÞ¿Ì±ÆÅèCgßÈÆ±ëÅÍCELÈÇÉgíêÄð©ÝÉ§ä·é±ÆªÅ«êÎC³çÈé@\ÌüãªúÒÅ«éB¢é«Y©çCHÆIÉàG}ÆµÄL­p¢çêÄ¢{gsbNXÅÐî·éu½E«à®öÌviPorous

é[ICgÜÅCäXÌ¶É[­©©íÁÄ¢éB»

Coordination Polymers, PCPsCàµ­Í Metal­OrganicÌÅàå«ÈÁ¥ÆµÄC×E\¢Ì½ßÉ©½Ú©çÍ

Frameworks, MOFs ÆµÄmçêÄ¢éjÍCà®CIzàÂ©È¢ÙÇÌå«È\ÊÏðLµÄ¢éB½Æ¦ÆC»êðA·éL@ªqiË´zÊqÆ¢¤jÉæÎC1 cm3 Ì§ûÌÌ\ÊÏÍ 6 cm2 ÅÁÄ\¬³êé»«ÌÅÌÅéªC±Ì§ûÌÉC1 nm ¨«É 1 nm~1 nm Ì 1 ³ÌEð­è²¢ÉzÊâ½àÌðl¦ÄÝéÆC»Ì\ÊÏÍ1000 m2 iejXIÉÏêÈi\¢ªgÝèCntÅ\¬vfÔfÈÇÌÝìpªÍ½ç«C©ÈWªé1)BÜ½à®CIÌ

R[g 4 ÊªjÉàyÔiFig. 1jBÜ½C×EÌTCYª§Ì\¢ÆC»êçðA·éË´zÊqÌ`ó¨æÑTªqTCYiimTCYjöxÉÈÁÄ­éÆC×EÇÊ

CYðKØÉIð·é±ÆÉæÁÄC»Ìi¨æÑ×E©çÌªqÔÍªdÈè

¢C×EàóÔÉÍCPê\Êæèà[¢|eVêª`¬³êéB»Ìæ¤ÈêÉ
QXgªqÍ­­ø«ÜêC§À³ê½óÔÉÅ«é¾¯ÀèÉlÜë¤Æ·é½ßCÊíÅÍµÄìçÈ¢ÁÙIÈW\¢ð`¬·é±ÆªmçêÄ¢éB½E«Þ¿Ì@\ÍC±ÌñÂÌÁ¥iå«È\ÊÏC[¢|eFig. 1

Schematic illustration of pore surface area and surface
potential.

Fig. 2 Schematic illustration of (a) versatilities of framework topo­
logies and pore sizes and (b) versatility of pore surface fun­ctionalities of PCPs.

úËõ Sept. 2009 Vol.22 No.5  249(C) 2009 The Japanese Society for Synchrotron Radiation Research\¢ð©ÝÉÝvÉ\z·é±ÆªÅ«éB³çÉÍCË´zÊqÉlXÈu·îð±ü·é±ÆÉæÁÄ×E\ÊÌóÔðÏ»³¹é±ÆàÂ\ÅéiFig. 2jB±Ìæ¤P ¬Ì½â·³CòQ \¢Ýv«Ì³Cò
R\É PCPs Íò¢Ïê«Ì³CÆ¢Á½bgð¯Éõ¦Ä¨èC
1990Näã¼È~C½E«Þ¿ÆµÄÌ¤ªòôIÉsíêC»ÝÅÍ«YC[ICgÉ®æO½E«Þ¿ÆµÄF¯³êéÉ¢½ÁÄ¢éB

2. nCubh^½E«à®öÌ\¢Ýv«C\¢Ïê«Ì³Æ¢¤ PCPs Ìå«ÈÁ¥ðp·é±ÆÅC«Yâ[ICgð½í·é@\Fig. 3

Schematic illustration of crystal hybridization for multi­
functional PCPs.

ªñ³êÄ¢éB»ÌÅàC×EÌTCYC×E\ÊÌ»wCüðÅåÀÉp·é±ÆÅCñ_»YfÌIð

»xÅ·é¬ðsÁ½B{gsbNXÅÍC2) CAZ`ÌIðIZk3) CË´zÊqÉäXª¬·é±ÆÉ¬÷µ½egSit[[IåÊz±ü³ê½A~hîyÑà®NX^[ÌzÊsOaTCNÌnÉÂ¢ÄñµCÁÉúËõ X üñÜ@ðp¢Ägðpµ½G}½4)ÈÇC½E«Þ¿É¨¯éXÌ¾ç©Éµ½\¢ÌÖÖWÉÂ¢Äq×éBu[NX[ª±ÌNÌÔÉN±èCPCPs ÉÖ·é¤ÍNÔ2000ñð´¦é_¶ª­\³êéêåÌæÖ

3. egSit[[NÆ­WµÄ¢éBà®CIÆË´zÊqÌgÝí¹Í³ÀÉ¶Ý·énCubh PCPs Ìî{\¢ÆµÄÍCà®CIÆ½ßC±êÜÅñ³êÄ¢é¤ÍCPCPs ÌVµ¢\2 íÞÌzÊqÉæè\z³êéegSit[¢ÆCz[Nðp¢½BFig. 4 É¦·æ¤ÉC2 ÂÌà®CICª£CG}CÈÇêÂÌ@\ðÇ·éàÌéB»êç@\ðL·éàÌðHêx©çÈéöÌ_C}[ª 2 ÂÌJ{_ÊðàÂËÅ·é±ÆÉæèCYÆIÈÚIÆµÄp·é±Æ´zÊq 1 ÉæÁÄA³êC2 ³Ì³ûiqðgã°ªÙÆñÇÅªÂ\ÉÈé½ßÅéBêûÅC½E«Þ¿ÉÍCzÜCª£ÜÈÇÌ]^ÌpÌ¼ÉàCàóÔðpéB³çÉöÌ_C}[ÌãºÉfÜLA~nzÊqiË´zÊq 2jª·é±ÆÅ 2 ³³ûiqªA

·é±ÆÅ¶ÌàÈÇÉàp·é±Æª{¿IÉÍÂ\³êC3 ³ÌWOW^t[[Nðgã°Åé5)B»Ì½ßÉÍC¢­Â©ÌÛèð·éKvé7)Bt[[NÌ\Ê\¢ÉÚ·éÆC6 ÊÌ¤ªéªCÁÉ PCPs Ì»TCY§äC¶ÌK«ÈÇ¿ 2 ÊÍ 2 ÂÌË´zÊq 1 ðÓÆµÄàÂ³ûiqªCcèÌ 4 ÊÍË´zÊq 1 ÆË´zÊq 2 ©çÈéªdvÉÈÁÄ­éB»Ìæ¤ÈÚIÌàÆÉCäXÍnCubh^½E«·ûiqª¶ÝµÄ¨èC±Ì\¢ðegSit[à®öÌinCubh PCPsjÆ¢¤Vµ¢TOðñÄ[NÆÄñÅ¢éB»ÌÁ¥ÆµÄCà®CICËµ½6jB·Èí¿Cê±Ì»ÌÉ¡íÌ½E«à®

´zÊq 1CË´zÊq 2 Æ¢¤ 3 ÂÌp[^ðÏ»öÌÌ\¢ð·é±ÆÅC»Ì\¢É¶½@\Ì³¹é±ÆÅCiqTCYðÏ»Â\Åðàs¤iFig. 3jB½Æ¦ÎCåÊzâG}\ðL·é\¢ÌüèÉª£\ðL·é\¢ð·é±ÆÅIðIåÊzéÆ¢¤_ÅèClXÈíÞÌË´zÊqðp¢é±ÆÅ»Ì×E@\ð½ÊÉÏ¦é±ÆªÅ«éBCªqIð IG}\ð L·énC ubh{¤ÅÍ±ÌegSit[[NÌ»ðRPCPs Ìn»ªÂ\ÆÈéB±êçÌTOÍC±êÜÅHAÆµÄiRA»jC»Ì»\ÊãÉà®CIàµêxÅsÁÄ¢é@\ð»xÅs¤±Æ©

­ÍË´zÊqðÏ»³¹½ÊÌegSit[çuPê»HêvÆ¢¤¼OðÂ¯Ä¢éBµ©µÈª[NðGs^LV¬·³¹½i±±ÅÍVF»çCê±Ì»ÉlXÈ\¢ð·é±ÆÍeÕÅÍÈÆÄÔjBGs^LV¬·³¹éÉ¢B»±ÅäXÍ PCPs ªntÉ¨¯é©ÈW»ÉævfÍRA»ÆVF»Ìiq·Ì·ÅÁÄgÝãªéÆ¢¤«¿ÉÚµCtÉ¨¯éGs^ª 0 Éß¯êÎß¢ÙÇGs^LVxª­ÈéÆ½èÅàdvÈ
èC±Ì·LV»¬·ðp¢Ä¬Å«éÌÅÍÈ¢©Æl¦l¦çêéB±ÌegSit[[NÌDê½_½BPCPs Ì»\ÊÌ¤àF³Éµ¢ÅC\¢ÌÍCJ{_ÊðL·éË´zÊq 1 É¨¢ÄCxg|W[Æ»ÌtHW[É»\Ê\¢ÌÖW[Âüèð»wCüµÄàªqÌ·³C·Èí¿iqÉ·ªÏíçÈ¢_ÅÚµCà®CIâË´zÊqÌá¤¡Ì\¢ðP

250  úËõ Sept. 2009 Vol.22 No.5

èClXÈ×E\ÊðL·énCu

gsbNX ¡ X üñÜ@ðp¢½nCubh^½E«à®öÌÌ\¢]¿Fig. 4

Schematic illustration of tetragonal frameworks.

Fig. 5

Framework components for epitaxial growth.

bh PCPs ð¬Â\ÅFig. 6

Two distinct crystal surfaces of tetragonal frameworks; (a)the (001) surface and (b) the (100) surface.

Fig. 7(a) Optical microscopic view of a hybridized crystal andmicroscopic infrared spectra of (b) colorless part and (c)greenish part of a hybridized crystal, (d) the powder crystalsof [Zn2(ndc)2(dabco)]n, and (e) [Cu2(ndc)2(dabco)]n.

éiFig. 5jB{gsbNXÅÍÙíà®ðL·énCubh PCPs ÌnÉÂ¢ÄÐîÝé½ßCË´zÊqÍRA»Æ¯¶ ndc, dabco ð·éBL·éªºCIÉæÁÄgÝãªéegSit[4. tGs^LV¬·Éæé¬[NÅémCu2 (ndc)2 (dabco)]n ðVF»ÆµÄ ¬ · ³ ¹ é ± Æ ð  Ý ½ B  ¬ Í º C I  C ndc CRA»ÆÈéegSit[[NÆµÄCCICË´zÊq 1 ÆµÄit^WJ{_dabco ÌªqðgG/^m[Ì 1 Î 1 Ìn}ÉnðµCRA»ÅémZn2 (ndc)2 (dabco)]n ð»Ìt

i ndc jC Ë ´ z Ê q 2 Æ µ Ä W A U r V N  I N ^ ÖüêC120xÅ½³¹½B»ÌÊCÎFÌ¼ûÌidabcoj©çÈéCmZn2(ndc)2(dabco)]n ðp¢½B¬Ì»ð¾½B»Ì»ð^ñÅØfµõw°÷¾ÅÏ

ÍãL 3 ÂÌªqðW`zA~hiDMFjÅ@µ½Æ±ëC200}CN[gÌ³F§¾Ì»Ì

120xÅ½³¹é±ÆÉæèC200}CN[gÌüèÉ20}CN[gÙÇÌÎFÌÊª¶ÝµÄ³F§¾¼ûÌ»ÆµÄ¾½8)B»\¢ÍegSi¢½iFig. 7jB³F§¾ÊCÎFÊð»ê¼ê°÷

CóÔQ P4/mmm ÅèCndc ÆCI©çÈéIR ª õ É æ è ª è µ ½ Æ ± ë C ³ F § ¾  Ê Í m Zn2³ûiqª»ÌPÊEÌ¸_É¨¢Ä dabco ðîµÄA(ndc)2(dabco)]n ÉCÎFÊÍmCu2(ndc)2(dabco)]n É³êegSit[[N\¢ðLµÄ¢éBP

A®³êés[NªÏª³ê½±Æ©çCRA»Å» X üñÜªèÌÊCFig. 6 É¦·æ¤É¼ûÌÌ 2mZn2(ndc)2(dabco)]n Ì 6 Ê·×ÄÌ»\ÊãÉ VFÊÍ 2 ÂÌ ndc ðÓÆµCIª¸_ðµßé³û»ÅiqÌÊÅé{001}Êª»êÄ¨èCcèÌ 4 ÊÍ 1 ÂÌ ndc Æ 1 ÂÌ dabco ðÓÆµCIª¸_ðµßé·ûiqÌÊÅéémCu2 (ndc)2 (dabco)]n ª¬·µÄ¢é±Æªm F ³ ê C n C u  b h PCP  » Å

é m Cu2 ( ndc )2(dabco)]n/[Zn2(ndc)2(dabco)]n Ì¬É¬÷µ½B

é{100}Êª»êÄ¢é±Æªí©Á½B±ÌRA»Ì\ÊãÉÊÌ»iVF»jð¬·

5. úËõ X üñÜªèÉæéRA»Æ
VF»Ì\¢ÖðÍ³¹é½ßC³çÈé½ðsÁ½BÜ¸CVF»ÆµÄÊÌà®CIðL·énCubh PCPs Ì¬ð

nCubh PCP »Ì\¢ÖðÍðs¤É½

úËõ Sept. 2009 Vol.22 No.5  251

èCRA»CVF»»ê¼êÌ»wIp[^ð¾é½ßÉC»ê¼êP»yÑ² X üñÜªèÉæ è \ ¢ ð Í ð s Á ½ Bi ó Ô Q P4/ mmm C R A  »mZn2(ndc)2(dabco)]nFa10.921(1)Cc9.611(1) ÅCVF »m Cu2 (ndc )2 (dabco)]n F a10.8190(3)C c
9.6348(6) ÅjB»ê¼êÍñíÉÊÁ½PÊiq·ðLµÄ¢éªCÁÉ a ²ûüÌ·³ªñ0.1 Å öáÁÄ¢éBÜ½VF»ÌÁ«ãC}CN[gTCYÌP»Ì¬Íñ³êÄ¢È¢½ßC² X üñÜªè©ç[gxgðÍ@ðp¢Ä\¢èðsÁ½B¡ ñ  ¬ µ ½ n C u  b h PCP  » Í 200 } C N [gTCYÌ¬³ÈàÌÅèCÀ±ºÅpÂ\ÈX üñÜuðp¢½\¢ðÍÍeÕÅÍÈ¢B»±ÅCSPring­8 Ìr[C BL13XU ðp¢ÄRA»ÆVF»Ì\¢ÖððÍµ½B1 Óª200~NÌoN»©çÌ X üñÜÍÁiVµ¢±ÆÍÈ¢ÆvíêéÇÒà¢éÆv¤ÌÅC¿ª\ÊâÌêÉÍoNÌ X üñÜªèÉÍÈ¢ªèÌÁê«ðL·B¤

Fig. 8(a) Schematic illustration of four­circle diractometer atBL13XU, SPring­8. (b) The conguration of the crystal
mounted on a substrate.

Fig. 9(a) The u_2u scan of the hybrid crystal at the initial position
along the a axis. (b) The q scan around the [100] direction.
Oset: the reciprocal lattice space.

ÌÚIÍCweEÊÉ¨¢ÄVF»ªRA»ÉÎµÄGs^LV¬·µÄ¢é©Ç¤©ð²×é±ÆÅéB»Ì½ßÉÍC¿Ì¤ÊÉÄ¸É\ÊÉ¾¯ÆË·éKvªé±ÆC³çÉC»Ì\ÊÉÎ·éüËX üCñÜ X üÌpxð¸§É§ä·éKvªÁ½B¡ñÌñÍ½Ü½Üc¡30~NÌå«³ÌüËr[Åpª«è½ªCKvÉ¶Ä 2 ³Wõõwn
ðp¢C~NTCYÌüËr[àÊÉp¢Ä¢éBüË X üÌGlM[Í12.4 keV ðp¢½Bõw°÷¾ðp¢ÄnCubh PCP »ðTdÉKXîÂÌãÉÅèµC4 ²ñÜvðp¢ÄªèðsÁ½iFig. 8jBÜ¸C»ªÇÌæ¤ÈzüÅîÂÉÅè³ê½Ì©ðmF·é½ßC¿\Êð½ÊÉ½sÈpxÊu©ç u_2u XLðsÁ½Æ±ëCih00)Ê©çÌñÜÌÝªÏª³ê½ÌÅC±ÌnCubh PCP »Í a ²ãü«É¬·µÄ¢é±Æª¾ç©ÉÈÁ½BÉC110u
bO_ßTÅ a ²üèÉ¿ðñ]³¹ÈªçXLðs Á ½B 180Ô u Å 2 Â Ì s [ N ð L ^ µ½ ± Æ © çiFig. 9 jCVF»ª½»âzü»ÌÂ\«ÍrÅ«½BVF»ªAt@XÅéÂ\«à»_ÅÍcéªCãq·éæ¤ÉRA»ÆÍª£³ê½ñÜ
s[NªÏª³ê½±Æ©çCVF»ÍP»Æl¦½BVF»ÍRA»ðev[gÆµÄGs^LV¬·µCP»ÆµÄ¬·µÄ¢é±Æ\zµ½
iFig. 10jBVF»ÅémCu2 (ndc)2(dabco)]n Í±êÜÅoN¬É¨¢ÄÍ²»ÆµÄµ©¬³êÄ¢È©Á½ªC±±ÅÍP»ÆµÄ¬·µÄ¢éÂ\«ª¢B»ÌRÆµÄCÊÁ½iðÂRA»ðîÂÆµÄp¢½½ßÅéÆl¦çêéBÁ½Bi00l)Ê©çÌñÜÌÝªÏª³êéæ¤C¿ðÉCÊÌ»ðãLÆ¯lÌðÅîÂÉÅèµC

½x©t¯È¨µ½BÂÜèCnCubh PCP »ª½ÊÉ½sÈpxÊu©ç u_2u XLðsîÂÉÎµÄ c ²ãü«É¬·µÄ¢éÊðÉ²×½B¿\Êð

252  úËõ Sept. 2009 Vol.22 No.5

gsbNX ¡ X üñÜ@ðp¢½nCubh^½E«à®öÌÌ\¢]¿Fig. 12Fig. 10Chart to assign the shell crystal conguration on the core
crystal.

Two miller domains of the shell crystals.

101ÌñÜª90xüúÅÏª³ê½Bµ©µÈªçC»Ìs[NÍgvbgÖÆªôµÄ¢½B±Ìgvbgs[NÌpxÊuð¸§»µ½Æ±ëCgvbgs[NÌ¼¤Ì 2 ÂÌs[NÌ 2u ÍC2u8.1864_8.1997ÌÍÍÅ
8.1136_8.1170ÅèCSÌs[NÍC2uÁ½Bgvbgs[NÌ¼¤Ìs[NÍiqÌZ¢VF»©çÌñÜCÜ½SÌs[NÍiqÌ·¢RA»©çÌñ^Å éÆ_µ½BSÌs[NÆ¼¤Ìs[NÌpx·iDqjÍCVF»ªRA»ÉÎµÄX¢Ä¬·µÄ¢épxÅéÆl¦çêéB·Èí¿Ci001)ÊÉ¨¢ÄVF»ÆRA»ªñ]µÄ¢é±ÆðÓ¡·éB101ubO_É¨¢ÄÍ Dq11.5}0.1Å
ÄÍ Dq11.7}0.6Å

èC011ubO_É¨¢éÌÅCVF»ÍRA»ÉÎµÄ11.6X¢Ä¬·µÄ¢éÆà¾Å«éB¯lÌpx·ðÁ½ñÜªSÌs[NÉÎµÄ¼¤É 2 ÂÏª³êÄ¢é±Æ©çC¶E¼ûÉñ11.6ñ]µ½»hCª¬·µÄ¢é±Æª¦´³ê½iFig. 12jB±Ìpx·ÍêÊIÈ³ûiqÉ¨¯éCiqûüÆ
26 ûüÌpx·iDq11.3jÉñíÉæ¢êvð¦·iFig. 13jB³ûiqÅé(001)ÊÉ¨¢ÄÍCRA»ia10.921(1) ÅjÆVF»ia10.8190(3) ÅjÌiq·Ìá¢ª°ÉÈé½ßCVF»ªRA»ãFig. 11(a) The u_2u scan of the hybrid crystal at the initial position
along the c axis. Oset: the reciprocal lattice space. (b) Theq scan around the [001] direction.

ÉGs^LV¬··é½ßÉÍ·³ðí¹éKvªéB»±ÅVF»ÍRA»ÉÎµÄñ11.6ñ]µCVF»Ìi 26~ 26j\¢ðRA»Ìi5~5j\¢ÉêvµÄ¬··é±ÆÅiq·Ìá¢ðÉaµÄ¢éÆ l@µ½ B±Ìæ¤ Èñ]Gs^ LV¬ ·Í±±Åà¯lÉ101ubO_ßTÅCc ²üèÉ¿ð(001)ÊÅÏª³êCi100)ÊÌêÅÍÏª³êÈ©Áñ]³¹ÈªçXLðsÁ½Æ±ëCa ²ãü«ÆÍ

½Bi100)ÊÍ a ²Æ c ²©çÈé·ûiqÅS­ÙÈÁ½gvbgs[Nª90xüúÅÏª³êÍVF»ÌûªZ¢ª c ²Í·¢½ßiRA»Fc½iFig. 11jBegSit[[N»\ÊÉ¨¯éiqÉÂèCa ²

9.611(1) ÅCVF»Fc9.6348(6) ÅjCiqTCYÌá¢ª»êÙÇå«­È¢½ßÅéÆl¦çêéB¢Äl@·éÆCa ²ãü«C·Èí¿·ûiq©çÈé¡ñÏª³ê½ñ]Gs^LV¬·ÍC½E«à®

(100)ÊÌêÉÍC¿È110Æ 1_10ÌñÜª180üúöÌÌÞ¿»wI_©çÝÄàñíÉ»¡[¢BRA

ÅÏª³êC¼û c ²ãü«C·Èí¿»\Êª³ûi»ÆVF»ÌEÊ\¢Í¢¾¾ç©ÉÈÁÄÍ¢È¢q©çÈé(001)ÊÌêÉÍC¿È011, 101, 0_11, _ªCÊàÉ¨¯éñ]ÉæèEÊtßÅ×ETCYª¸­úËõ Sept. 2009 Vol.22 No.5  253

Fig. 14

Schematic illustration of the hybrid crystal directly grownon the substrate.

ðLµÄ¢éàÌª½­¶ÝµC¯lÌÀ±ðs¤±ÆÅVµ¢Þ¿J­ÌWJªúÒ³êéBäXÌnCubh^½E«à®öÌÉ¨¢ÄàC³çÈéWJªÂ\ÉÈéÅFig. 13

Schematic model of the structural relationship between thecore lattice and the shell lattice on the (001) surface. The
red lines indicate the commensurate lattice between the corelattice and the shell lattice; the (5~5) structure of the core
crystal or the ( 26~ 26) structure of the shell.

ë¤BÜ¸CnCubh^½

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E­mail: shuhei.furukawakip.jst.go.jpêåFöÌ»wmªðn
2005N 3 såwHw¤ÈmÛö C ¹ C 2005 N 4  J g  b N å w
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õjC2007N 4 såwHw¤ÈÁC³C2008N 1  ERATO kì×EvWFNgZ×EO[v[_[i»EjC2008N 4 såw¨¿_×EVXe_ÁCy³öi»EjBâcCgàc@l PxõÈw¤Z^[Éå²¤õE­mail: o­sakataspring8.or.jp
êåF\EÊÉÉim\¢ X üðÍCX üñÜmªðn
1989N`1998N HÆåwHÆÞ¿¤iãÉCpZ~bNX¤jÞ¿\¢ðÍåèB1998N`
2000 N Northwestern å w Departmentof Materials Science and Engineering ÌResearch AssociateB2000N 6 ©çCà PxõÈw¤Z^[B»ÝC\òÊ\¢`[[_[Cå²¤õBStructural evaluation of Hybridized Porous
Coordination Framework by Synchrotron X­rayDiraction Analysis
Shuhei FURUKAWA
Osami SKATA

ERATO Kitagawa Integrated Pores Project, Japan Science and TechnologyAgency (JST) Institute for Integrated Cell­Material Sciences, Kyoto University
Kyoto Research Park Bldg #3, Shimogyo­ku, Kyoto 600_8815, Japan
Japan Synchrotron Radiation Research Institute/Spring­8 (JASRI)
Kouto, Sayo, Hyogo 679_5198, Japan

Abstract Hybridized porous coordination polymer (PCP) crystals are fabricated at the single­crystal level by
epitaxial growth in solution. Synchrotron X­ray diraction measurements unveiled the structural relationshipbetween two hybridized crystals, where the strategic choices of molecular building blocks are of signicant tocontrol the growth direction and the lateral rotation at crystal interfaces.

úËõ Sept. 2009 Vol.22 No.5  255