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Printing date 28.01.2021

Version number 13.0

Revision: 28.01.2021

SECTION 1: Identification of the substance/mixture and of the company/
undertaking· 1.1 Product identifier· Trade name: KEIM SOLDALIT· 1.2 Relevant identified uses of the substance or mixture and uses advised against· Application of the substance / the mixture Sol-silicate paint for use on exterior walls.
· Uses advised against All other uses are not recommended.
· 1.3 Details of the supplier of the safety data sheet· Manufacturer/Supplier:
KEIM MINERAL PAINTS LTD
Santok Building / Deer Park Way, Donnington Wood GB-Telford, Shropshire TF2 7NA
Tel +44 1952 231 250 / Fax +44 1952 231 251
www.keim.com / sales@keimpaints.co.uk· Further information obtainable from:David Pratt
Telefon: +44 1952 231250
E-Mail: sales@keimpaints.co.uk· 1.4 Emergency telephone number:
GBK GmbH Global Regulatory Compliance
Emergency number: +49(0)6132/84463*

SECTION 2: Hazards identification· 2.1 Classification of the substance or mixture· Classification according to Regulation (EC) No 1272/2008
The product is not classified, according to the CLP regulation.
· 2.2 Label elements· Labelling according to Regulation (EC) No 1272/2008 Void
· Hazard pictograms Void
· Signal word Void
· Hazard statements Void
· Additional information:
EUH210 Safety data sheet available on request.
EUH211 Warning! Hazardous respirable droplets may be formed when sprayed. Do not breathe
spray or mist.
· 2.3 Other hazards Alkaline product. Avoid contact with skin and eyes.
· Results of PBT and vPvB assessment· PBT: Not applicable· vPvB: Not applicable*

SECTION 3: Composition/information on ingredients· 3.2 Mixtures· Description:
Sol-Silicate-based paint for outdoor use, with light resistant, inorganic pigments and mineral fillers.
(Contd. on page 2)
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Printing date 28.01.2021

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Trade name: KEIM SOLDALIT(Contd. of page 1)· Dangerous components:
CAS: 13463-67-7
EINECS: 236-675-5
Index number: 022-006-00-2
Reg.nr.: 01-2119486799-10xxxx
CAS: 12001-26-2
EC number: 601-648-2
CAS: 1312-76-1
EINECS: 215-199-1
Reg.nr.: 01-2119456888-17xxxx

titanium dioxide [in powder form containing 1 % or more 10-25%
of particles with aerodynamic diameter ≤ 10 μm]
Carc. 2, H351

Mica
2.5-10%substance with a Community workplace exposure limit
Silicic acid, potassium salt
≤2.5%
Skin Irrit. 2, H315; Eye Irrit. 2, H319
Specific concentration limits:
Skin Irrit. 2; H315: C ≥ 40 %Eye Irrit. 2; H319: C ≥ 40 %· Additional information: For the wording of the listed hazard phrases refer to section 16.

SECTION 4: First aid measures· 4.1 Description of first aid measures· General information:
No special measures required.
When seeing the doctor we suggest to present this safety data sheet.
· After inhalation: Supply fresh air; consult doctor in case of complaints.
· After skin contact:
Immediately wash with water and soap and rinse thoroughly.
Do not use solvents or thinners.
If skin irritation continues, consult a doctor.
· After eye contact:
Rinse opened eye for several minutes under running water. Then consult a doctor.
· After swallowing:
Rinse mouth and throat well with water.
Do not induce vomiting; call for medical help immediately.
· 4.2 Most important symptoms and effects, both acute and delayed
No further relevant information available.
· 4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.

SECTION 5: Firefighting measures· 5.1 Extinguishing media· Suitable extinguishing agents:
Product itself does not burn. Co-ordinate fire-fighting measures to the fire surroundings.
· 5.2 Special hazards arising from the substance or mixture
No further relevant information available.
· 5.3 Advice for firefighters· Specila protective equipment: Wear self-contained respiratory protective device.
(Contd. on page 3)
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Printing date 28.01.2021

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Revision: 28.01.2021

Trade name: KEIM SOLDALIT(Contd. of page 2)· Additional information
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
In case of fire do not breathe smoke, fumes and vapours.
Cool endangered receptacles with water spray.

SECTION 6: Accidental release measures· 6.1 Personal precautions, protective equipment and emergency procedures
Ensure adequate ventilation
Avoid contact with skin and eyes.
Particular danger of slipping on leaked/spilled product.
Respect the protection rules (see section 7 a. 8).
· 6.2 Environmental precautions:
Do not allow product to reach soil, sewage system or any water course.
Follow local governmental rules and regulations.
Dilute with plenty of water.
· 6.3 Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Ensure adequate ventilation.
Dispose of the material collected according to regulations.
Clear contaminated areas thoroughly.
Flush rests with sufficient amount of water.
· 6.4 Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.

SECTION 7: Handling and storage· 7.1 Precautions for safe handling
Keep receptacles tightly sealed.
Avoid contact with skin and eyes.
Do not inhale aerosols.
Ensure good ventilation/exhaustion at the workplace.
See item 8 (8.2) for information about suitable protective equipment and technical precautions.
Respect the protection rules.
· Information about fire - and explosion protection:
The product is not flammable.
No special measures required.
· 7.2 Conditions for safe storage, including any incompatibilities· Storage:· Requirements to be met by storerooms and receptacles:
Keep in the original containers in a cool and dry place.
Store only in unopened original receptacles.
· Information about storage in one common storage facility: Do not store together with acids.
(Contd. on page 4)
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Trade name: KEIM SOLDALIT(Contd. of page 3)· Further information about storage conditions:Store in a cool place.
Protect from frost.
Protect from heat and direct sunlight.
· Storage class: 12· 7.3 Specific end use(s) No further relevant information available.
*

SECTION 8: Exposure controls/personal protection· 8.1 Control parameters· Ingredients with limit values that require monitoring at the workplace:
13463-67-7 titanium dioxide [in powder form containing 1 % or more of particles withaerodynamic diameter ≤ 10 μm]
WEL Long-term value: 10* 4** mg/m³*total inhalable **respirable
12001-26-2 Mica
WEL Long-term value: 10* 0.8** mg/m³*total inhalable **respirable· Additional information: The lists valid during the making were used as basis.
· 8.2 Exposure controls· Personal protective equipment:· General protective and hygienic measures:
Avoid contact with the eyes and skin.
Do not inhale aerosols.
Wash hands before breaks and at the end of work.
Immediately remove all soiled and contaminated clothing.
· Respiratory protection:
Use suitable respiratory protective device only when aerosol or mist is formed.
Filter: P2· Protection of hands: Protective gloves· Material of gloves
suitable material e.g.:
Nitrile impregnated cotton-gloves
Recommended thickness of the material:  0.5 mm
Nitrile rubber, NBR
Recommended thickness of the material:  0.4 mm
Butyl rubber, BR
Recommended thickness of the material:  0.7 mm
The selection of the suitable gloves does not only depend on the material, but also on further marksof quality and varies from manufacturer to manufacturer. As the product is a preparation of several
substances, the resistance of the glove material can not be calculated in advance and has therefore
to be checked prior to the application.
(Contd. on page 5)
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Trade name: KEIM SOLDALIT(Contd. of page 4)· Penetration time of glove material
Value for the permeation: level  6 (480 min)The determined penetration times according to EN 16523-1:2015 are not performed under practicalconditions. Therefore a maximum wearing time, which corresponds to 50% of the penetration time,is recommended.
The exact break trough time has to be found out by the manufacturer of the protective gloves andhas to be observed.
· Eye protection: Tightly sealed goggles· Body protection:
Protective work clothing
After contact with skin wash thoroughly with water and apply lotion.
· Limitation and supervision of exposure into the environment
See Section 12 and 6.2
No further relevant information available.

SECTION 9: Physical and chemical properties· 9.1 Information on basic physical and chemical properties· General Information· Appearance:
Form:
Pasty
Colour:Different, according to colouring.
· Odour:Weak, characteristic· Odour threshold:Not determined· pH-value at 20 °C:~11*· Change in condition
Melting point/freezing point:
Not determined
Initial boiling point and boiling range: >100 °C· Flash point:

Not applicable· Flammability (solid, gas):

Not applicable· Ignition temperature:

Not determined· Decomposition temperature:

Not determined· Auto-ignition temperature:

Product is not selfigniting.

· Explosive properties:

Product does not present an explosion hazard.

· Explosion limits:
Lower:
Upper:· Oxidising properties:

Not applicableNot applicableNot applicable· Vapour pressure at 20 °C:~23 hPa· Density at 20 °C:

1.5-1.7* g/cm³(Contd. on page 6)
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Trade name: KEIM SOLDALIT(Contd. of page 5)· Relative density· Vapour density· Evaporation rate

Not determined
Not applicable.
Not applicable.

· Solubility in / Miscibility withwater:

Fully miscible· Partition coefficient: n-octanol/water:

Not applicable· Viscosity:
Dynamic at 20 °C:
Kinematic:

1.100-1.550* mPas
Not determined· 9.2 Other information* The values are for freshly produced material and maychange with the time.

SECTION 10: Stability and reactivity· 10.1 Reactivity No further relevant information available.
· 10.2 Chemical stability Stable under normal conditions of storage and use.
· Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.
· 10.3 Possibility of hazardous reactions No dangerous reactions known.
· 10.4 Conditions to avoid No further relevant information available.
· 10.5 Incompatible materials: Acids· 10.6 Hazardous decomposition products:
No hazardous decomposition products if stored and handled as prescribed.
*

SECTION 11: Toxicological information· 11.1 Information on toxicological effects· Acute toxicity Based on available data, the classification criteria are not met.
· LD/LC50 values relevant for classification:
13463-67-7 titanium dioxide [in powder form containing 1 % or more of particles withaerodynamic diameter ≤ 10 μm]
Inhalative ATE mix (4h) >5 mg/l (inhalation)
ATE mix>2,000 mg/kg (dermal)>2,000 mg/kg (orally)
NOAEL
3,500 mg/kg /Oral (rat) (90d)1312-76-1 Silicic acid, potassium salt
Oral
LD50
>5,000 mg/kg (rat) (OECD 401)
DermalLD50>5,000 mg/kg (rat) (OECD 402)
Inhalative LC50/4 h>5 mg/l (rat)(Contd. on page 7)
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Trade name: KEIM SOLDALIT(Contd. of page 6)· Primary irritant effect:· Skin corrosion/irritation Frequent persistent contact with the skin may cause skin irritation.
· Serious eye damage/irritation In case of longer exposure, irritating effect is possible.
· during inhalation: Irritant effect possible.
· during swallowing: Irritant effect possible· Respiratory or skin sensitisation Based on available data, the classification criteria are not met.
· Other information (about experimental toxicology):
Experimental analysis are not available.
The product was not tested. The statements on toxicology have been derived from the properties of
the individual components.
· Subacute to chronic toxicity:· Repeated dose toxicity
13463-67-7 titanium dioxide [in powder form containing 1 % or more of particles withaerodynamic diameter ≤ 10 μm]
Inhalative NOAEC 10 mg/m³ (rat) (90d)· CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) Not applicable· Germ cell mutagenicity Based on available data, the classification criteria are not met.
· Carcinogenicity Based on available data, the classification criteria are not met.
· Reproductive toxicity Based on available data, the classification criteria are not met.
· STOT-single exposure Based on available data, the classification criteria are not met.
· STOT-repeated exposure Based on available data, the classification criteria are not met.
· Aspiration hazard Based on available data, the classification criteria are not met.
*

SECTION 12: Ecological information· 12.1 Toxicity· Aquatic toxicity:
13463-67-7 titanium dioxide [in powder form containing 1 % or more of particles withaerodynamic diameter ≤ 10 μm]
NOEC≥100,000 mg/kg (sediment fresh water)
EC50>100 mg/kg (freshwater alga) (OECD 201)
EC 50
>10,000 mg/l (algae) (ISO 10253)
LC 50>10,000 mg/l (marine fish) (OECD 203)
>1,000 mg/l (freshwater fish) (EPA-540/9-85-006)>1,000 mg/l (daphnia) (OECD 202)
1312-76-1 Silicic acid, potassium salt
NOEC
>1 mg/l (fish)>1 mg/l (invertebrates)
EC 50/48h >100 mg/l (daphnia) (OECD 202)
EC 50/72 h >100 mg/l (algae)
LC 50/96 h >100 mg/l (fish) (DIN EN ISO 7346-2)
EC 0>1,000 mg/l (activated sludge) (30min)(Contd. on page 8)
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Trade name: KEIM SOLDALIT(Contd. of page 7)· 12.2 Persistence and degradability No further relevant information available.
· 12.3 Bioaccumulative potential No further relevant information available.
· 12.4 Mobility in soil No further relevant information available.
· Additional ecological information:· AOX-indication:
Due to the substance of content which do not include organic jointed halogens, the product can nottake influence on the AOX-load of the waste water.
· According to the formulation contains the following heavy metals and compounds from theEU guideline NO. 2006/11/EC:
The product contains TiO2, BaSO4.
· General notes:
The statements on ecotoxicology have been derived from the properties of the individualcomponents.
Do not allow product to reach ground water, water course or sewage system.
At present there are no ecotoxicological assessments.
Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water· 12.5 Results of PBT and vPvB assessment· PBT: Not applicable· vPvB: Not applicable· 12.6 Other adverse effects No further relevant information available.

SECTION 13: Disposal considerations· 13.1 Waste treatment methods· Recommendation
Must not be disposed with household garbage. Do not allow product to reach sewage system.
Disposal must be made according to official regulations.
· European waste catalogue
08 01 12 waste paint and varnish other than those mentioned in 08 01 11· Uncleaned packaging:· Recommendation: Disposal must be made according to official regulations.
· Recommended cleansing agents: Water, if necessary with cleansing agents.

SECTION 14: Transport information· 14.1 UN-Number· ADR, IMDG, IATA

Void

· 14.2 UN proper shipping name
· ADR, IMDG, IATA

Void

· 14.3 Transport hazard class(es)· ADR, IMDG, IATA
· Class

Void(Contd. on page 9)
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Trade name: KEIM SOLDALIT(Contd. of page 8)· 14.4 Packing group· ADR, IMDG, IATA

Void

· 14.5 Environmental hazards:· Marine pollutant:No· 14.6 Special precautions for user

Not applicable· 14.7 Transport in bulk according to Annex IIof Marpol and the IBC CodeNot applicable· Transport/Additional information:

No dangerous good in sense of these transport
regulations.

· UN "Model Regulation":

Void

SECTION 15: Regulatory information· 15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture· Labelling according to Regulation (EC) No 1272/2008
For information on labelling please refer to section 2 of this document.
· Directive 2012/18/EU· Named dangerous substances - ANNEX I None of the ingredients is listed.
· DIRECTIVE 2011/65/EU on the restriction of the use of certain hazardous substances inelectrical and electronic equipment – Annex II
None of the ingredients is listed.
· National regulations:· Waterhazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water.
· Other regulations, limitations and prohibitive regulations· Substances of very high concern (SVHC) according to REACH, Article 57 Not applicable· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

SECTION 16: Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee
for any specific product features and shall not establish a legally valid contractual relationship.
· Relevant phrases
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H351 Suspected of causing cancer.
· Department issuing SDS: KEIMFARBEN Germany, Product safety department· Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning theInternational Carriage of Dangerous Goods by Road)(Contd. on page 10)
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Trade name: KEIM SOLDALIT(Contd. of page 9)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
TRGS: Technische Regeln für Gefahrstoffe (Technical Rules for Dangerous Substances, BAuA, Germany)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
SVHC: Substances of Very High Concern
vPvB: very Persistent and very Bioaccumulative
EC10: Effective concentration at 10% mortality rate.
EC50: Half maximal effective concentration.
LC10: Lethal concentration at 10% mortality rate.
NOEC: No observed effect concentration.
REACH: Registration, Evaluation and Authorisation of Chemicals (Regulation (EC) No.1907/2006)
Skin Irrit. 2: Skin corrosion/irritation – Category 2
Eye Irrit. 2: Serious eye damage/eye irritation – Category 2
Carc. 2: Carcinogenicity – Category 2· * Data compared to the previous version altered.
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