1/7

Safety Data Sheet
1. Identification of the Substance/Preparation and of the Company
Product Name

Fine-cool(Concentrate Solution)

Recommended Use and Water-soluble cutting and grinding fluids
Manufacturer

Kyowa Oil Lubricants Co. Ltd.

Address

1-30-5Phone

tel 045(591)2311 fax 045(591)2318

Email Address

info@kyouwa-oil.com

Date of creation

February. 2.2017,Hayabuchi, Tsuzuki-cu,Yokohama- City,kanagawa, Japan

Revised date
Sales company

HEIWA TECHNICA CO., LTD.

2. Hazard Identification
GHS Classification:
Physical Hazards

Not applicable to the GHS Classification

Health Hazards

Skin Corrosion/Irritation

Category 2

Serious Eye Damage/Eye Irritation

Category 1

STOT/Systemic Toxicity - Single Exposure
Category 2（liver）
Category 3（Respiratory irritation）
Those not mentioned above can not be classified or not subject to classification
Label Elements
Pictograms/Symbols

Signal WordDanger

Hazard Statements

Skin irritancy
Causes serious eye damage
May cause respiratory irritation
May cause damage to the liver

Precautionary Statements[Prevention]

Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Do not breathe mist/vapors/spray.
Do not eat, drink or smoke when using this product.
Wear protective gloves/protective clothing/eye protection/face protection.
Wash hands thoroughly after handling.
Fine-cool (2017.2.2) HEIWA TECHNICA CO., LTD2/7
Contaminated work clothing should not be allowed out of the workplace.
Use only outdoors or in well-ventilated areas[Response]

Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
If eye irritation persists, get medical attention
Wash with plenty of soap and water.
If swallowed, rinse mouth.
Do not induce vomiting.
If skin irritation or rash occurs: Get medical advice/attention.
If exposed or concerned: Get medical advice/attention.
Get medical advice/attention if you feel unwell.
Take off contaminated clothing and wash it before reuse.
If inhaled, remove victim to fresh air and keep at rest in a position
comfortable for breathing.

[Storage]

Store locked up.
Avoid direct sunlight, keep away from fire, heat source and store
in a well-ventilated place.
Keep containers tightly closed.

[Disposal]

Dispose of contents/container in accordance with regulations.

3. Composition/Information on Ingredients
Homogeneous / Mixture:

MixturePurpose:

Grinding fluid

Chemical name

Water and additives

Chemical or Structural Formula

Not specifiable

Components and Contents:(CAS No)

Rust inhibitor

7.0%-Triethanolamine

20%(102-71-6)

Antifoam

0.1%-Discoloration inhibitor 0.5%

(95-14-7)

Water(7732-18-5)

72.4%

4. First-Aid Measures
Inhalation

Remove victim to fresh air and let him rinse mouth thoroughly with water.
Wrapping a blanket and the like around him to keep warm for a rest, call adoctor/physician immediately.

Skin Contact

Rinse skin with soap and water.

Eye Contact

Immediately rinse eyes with clean water for at least 15 minutes. Remove
contact lenses if present. Continue rinsing. If eye irritation persists,
Fine-cool (2017.2.2) HEIWA TECHNICA CO., LTD3/7
get medical attention.
Ingestion

Call a doctor/physician immediately. Do not induce vomiting.
If affected, the mouth should be rinsed out thoroughly with water.

Expected Acute andIf swallowed, may suffer from diarrhea and vomiting.

Delayed Symptoms, andMay cause inflammation if in eyes.

Most Important Symptoms/ May cause inflammation if on skin.
Effects

May feel unwell if mist is inhaled.

5. Fire-Fighting Measures
Suitable Extinguishing Media

Foggy reinforcing agent, foam, powder, or carbon dioxide

Unsuitable Extinguishing Media

Jet water

Specific Hazards

A fire may cause irritating, corrosive, and/or toxic gas.

Specific Fire-Fighting Measures

Shut off the fire source.
Use powder or carbon dioxide extinguishers at the beginning of fire.
It is effective to intercept the air from a big fire with foam
extinguishers. Use of water may cause spreading of fire.
Cool the surrounding facilities with water spray.
Evacuate non essential

personnel around the fire.

Special Protective Actions for

Wearing protective glasses, protective clothing, and if necessary,

Fire-Fighting

respiratory protective equipment, start to fight fire on the windwardside.

6. Accidental Release Measures
Personal Precautions, Protective

Immediately isolate the spill area wide enough in all directions.

Equipment and Emergency Procedures

If skin or eye contact is possible, wear protective equipment. If mistis produced, wear respiratory protective equipment to avoidinhalation.

Environmental Precautions

Take up as much as possible to avoid soil contamination and waterpollution. Avoid release to the environment

Collection/Neutralization

Eliminate the source of ignition of the surrounding.

and Methods/Materials

In the case of a large amount: Dike ahead of liquid spill areafor Containment

to minimize migration and then sweep into an empty
container for disposal in a safe place. After disposal, wash
away with plenty of water. In doing so, take care to preventthe high concentration of wastes from entering public
watercourses such as rivers.
In the case of a small amount: Take up into an empty
container by absorbing the spill with earth and sand or rags,and furthermore sop up with rags thoroughly.

Prevention of Secondary

Remove all the ignition sources immediately. (Do not smoke
Fine-cool (2017.2.2) HEIWA TECHNICA CO., LTD4/7
Hazards

Nearby and keep away from sparks and flames.)
Report to the related organs for help.

7. Handling and Storage
Handling

Before repairing machinery with remnant oils on, remove themTechnical Measuresthoroughly in a safe place. Take precautionary measures
Against static discharge and wear electro conductive clothing
and shoes.As vapors released from petroleum products areheavier than air,they are liable to stagnate.
Due to it, attention should be paid to ventilation and fire.
Handle at room temperatures, paying attention to moisture andTo impurities not to mix with.
If skin or eye contact is possible, wear protective equipment. If
mist is produced, wear respiratory protective equipment toavoid inhalation.
Use a pump and the like to take out of container.
Do not suck through a tube.
Do not weld, heat, hole, and cut off the container. Residues may
ignite involving explosion.

Local Exhaust Ventilation/

8. Exposure Controls/Personal Protection’.

Full Ventilation SystemAvoiding Contact

Refer to ‘’10. Stability and Reactivity’.

Precautions for Safe Handling

Obtain special instructions before use.
Do not handle until all safety precautions have been read andunderstood.
As this product contains ethanolamine, do not use antirust
Agents containing nitrite together.
Be cautious not to use any naked fire.
Wash hands thoroughly after handling.
Use only outdoors or in a well-ventilated area.
Do not eat, drink or smoke when using this product.
Do not press an empty container. It may explode under pressure.
Do not drink.
Keep out of reach of children.

Storage:Technical Measures

Avoid heat, sparks, flames, and static electricity.
Keep container tightly closed.

Incompatible Materials

Refer to ’10. Stability and Reactivity’.

Conditions for Safe Storage

Store in a well-ventilated area.
Fine-cool (2017.2.2) HEIWA TECHNICA CO., LTD5/7
Store avoiding exposure to direct sunlight.
Store away from oxidizer.
Store locked up.
Materials for Containers/Packaging
When replacing the container, use metal or glass container.
Somekinds of resin-treated container may melt.

Use airtight, anti-breakage type containers.
8. Exposure Controls/Personal Protection
Engineering Controls

When mist and vapors are produced, seal off sources or provide
exhaust ventilation. Facilities for rinsing eyes and washinga body are required near the workplace.

Permissible Concentration

Not specified

Standards for Allowable Density of Hazardous Substances in Labor Operation Air
Not established
Personal Protective Equipment
Respiratory ProtectionWear appropriate respiratory protection.

Hand Protection

If necessary, wear oil-resistant protective gloves.

Eye Protection

If diffusion is possible, wear eye protection

Skin and Body Protection

If necessary, wear protective clothing and face protection.

Hygienic Precautions

Wash hands thoroughly after handling.
Regularly inspect protective equipment according to theinspection table of protective equipment.
Do not eat, drink or smoke when using this product.

9. Physical and Chemical Properties
Physical State:Appearance

LiquidColor

Pale red transparentOdor

Slightly amine odor

Boiling PointNo data available

Freezing Point

No data available

Decomposition temperature

No data available

Ignition point

No data available

Flash point

No data available

Flammability

No data available

Explosive Range (Explosive Limits) No data available
Vapor Density (air=1)

No data available

Specific Gravity (Density)

1.05g/cm3 (15℃) (Stock solution)
Fine-cool (2017.2.2) HEIWA TECHNICA CO., LTD6/7
1.01g/cm3 (15℃) (Water-diluted 40-fold)Solubility

Dispersible in waterpH

9.1 (Stock solution)
8.9(Water-diluted 40-fold)

10. Stability and Reactivity
Stability

I avoid contact with strong oxidizing agents

Possibility of Hazardous Reactions

when stored and stored in the dark at room
temperature, and is stable.
I avoid contact with strong oxidizing agents
hazardous reactions possible.

Conditions to Avoid

Contact with incompatible materials Incompatible
Materials be careful not to contact halogens, strong
acids, alkalis, and oxidizing substances.

Hazardous decomposition products.

Smoke, carbon monoxide, sulfur dioxide or alkalis
is produced during the combustion.

11. Toxicological Information
Acute Toxicity:
OralNo useful information

DermalNo useful informationInhalation

No useful information

Skin Corrosion/Irritation
Classified into Skin Corrosion/Irritation Category 2 as mixture.
Serious Eye Damage/Eye Irritation
Classified into Serious Eye Damage/Eye Irritation Category 1 as mixture
Respiratory or Skin Sensitization No useful information
Germ Cell Mutagenicity

No useful information

Carcinogenicity

No useful information

Reproductive Toxicity

No useful information

Classified into Specific Target Organ Toxicity/Systemic (Single Exposure)
Category 2,3 as mixture
Classified into Specific Target Organ Toxicity/Systemic (Repeated Exposure)
No useful information
Aspiration Hazard

No information available.
.

12. Ecological Information
Ecotoxicity

No information available
Fine-cool (2017.2.2) HEIWA TECHNICA CO., LTD7/7
Persistence and Degradability

No information available

Bioaccumulative

No information available

PotentialMobility in Soil

No information available

Other Adverse Effects

No information available

Environmental Criteria

No information available

13. Disposal Considerations
Waste Residues

Dispose the waste according to national and local regulations.
Do not dump.

Contaminated Containers

Contaminated or empty container/packaging are to be disposed

And Packing

according to national and local regulations.

14. Transport Information
International Regulation
UN Classification
Special Precautions

Not applicable
Load the containers in a manner that they are certain not toresult in direct sunlight exposure, damage, corrosion, leak,while being transported.
Do not place heavy load on top of the container.

HS code3403.99000

15. Regulatory Information
No Information
16. Other Information
References:

1) Recommendation of Occupational Exposure Limits by Japan Society for Occupational Health2) Thresholds limit values for chemical substances and physical agents and biological exposure
indices by ACGIH
3) National Institute of Technology and Evaluation
4) SDS ofraw materials

1. As evaluations on hazards are not necessary satisfactory, special attention should be paid for use.
2. This SDS, summarizing matters to be attended to, is required for proper use of the product and is intended fornormal use.
3. Referring to this MSDS, properly use and handle this product on the user’s own responsibility.
4. The contents of this MSDS are based on information available as of today and our knowledge.
The information, data, and evaluations herein are not guaranteed, and in addition, may be revised due
to revision of laws or knowledge newly obtained.

Fine-cool (2017.2.2) HEIWA TECHNICA CO., LTD