VAPROX® HC
Sterilant
Safety Data Sheetaccording to Regulation (EC) No. 453/2010
Date of issue: 3/23/2017

Version: 1.0

SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1.

Product identifier

Product form

: Mixture

Trade name

: VAPROX® HC Sterilant

Product code

: PB007, PB028

SDS NoA124

1.2.

Relevant identified uses of the substance or mixture and uses advised against

1.2.1.

Relevant identified uses

Industrial/Professional use spec

: Product for industrial use only

Use of the substance/mixture: For use with STERIS V-Pro® Sterilizers

1.2.2.

Uses advised against

No additional information available
1.3.

Details of the supplier of the safety data sheet

Manufacturer:
STERIS Corporation
P. O. Box 147, St. Louis, MO 63166, US
Telephone Number for Information: 1-800-548-4873 (Customer Service-Healthcare Products)
US Emergency Telephone No.1-314-535-1395 (STERIS); 1-800-424-9300 (CHEMTREC)
Supplier:
STERIS Limited
Chancery House, 190 Waterside Road, Hamilton Industrial Park,
Leicester, LE5 1QZ, UK
Product/Technical Information Phone No: +44 (0) 116 276 8636
Email: asksteris_msds@steris.com
1.4.

Emergency telephone number

Emergency number: +44 (0) 1895 622 639

SECTION 2: Hazards identification
2.1.

Classification of the substance or mixture

Classification according to Regulation (EC) No. 1272/2008 [CLP]Show CLP information + DPD classification in section 2.1
Ox. Liq. 2

H272

Acute Tox. 4 (Oral)

H302

Acute Tox. 4 (Inhalation:dust,mist) H332
Skin Corr. 1B

H314

STOT SE 3

H335

Full text of H-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available

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VAPROX® HC
Sterilant
Safety Data Sheetaccording to Regulation (EC) No. 453/2010

2.2.

Label elements

Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP):

Signal word (CLP): Danger

Hazard statements (CLP): H272 - May intensify fire; oxidiser
H302 - Harmful if swallowed
H332 - Harmful if inhaled
H314 - Causes severe skin burns and eye damage
H335 - May cause respiratory irritation

Precautionary statements (CLP): P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smokingP261- Avoid breathing mist and/or vapours
P301+P330+P331 - IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
P303+P361+P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinseskin with water/shower

GHS03

GHS05

GHS07

P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing
P370 + P378 – In case of fire: Use water for extinction
2.3.

Other hazards

Risk of decomposition by heat or by contact with incompatible materials.

SECTION 3: Composition/information on ingredients
3.1.

Substance

Not applicable
3.2.

MixtureName

Product identifier%

Classification according toRegulation (EC) No.
1272/2008 [CLP]Hydrogen peroxide(CAS No) 7722-84-1(EC no) 231-765-0(EC index no) 008-003-00-9

59

Ox. Liq. 1, H271
Acute Tox. 4 (Oral), H302
Acute Tox. 4 (Inhalation), H332
Skin Corr. 1A, H314
STOT SE 3, H335
Aquatic Chronic 3, H412

Full text H-phrases: see section 16

SECTION 4: First aid measures
4.1.

Description of first aid measures

First-aid measures general: Never give anything by mouth to an unconscious person. In all cases of doubt, or when
symptoms persist, seek medical attention

First-aid measures after inhalation: Remove to fresh air and keep at rest in a position comfortable for breathing. If not breathing, give
artificial respiration. Immediately get medical attention

First-aid measures after skin contact: Remove contaminated clothing immediately. Immediately flush skin with plenty of water for atleast 15 minutes. If skin irritation occurs: Get medical advice/attention. Wash contaminatedclothing before reuseFirst-aid measures after eye contact: In case of contact with eyes flush immediately with plenty of flowing water for 10 to 15 minutes
holding eyelids apart. Immediately get medical attention. Remove contact lenses, if present andeasy to do. Continue rinsing.

.First-aid measures after ingestion: If victim completely conscious/alert, give water or milk. Rinse mouth. Do NOT induce vomiting.
Obtain emergency medical attention. Call a POISON CENTER/doctor/physician if you feelunwell.

4.2.

Most important symptoms and effects, both acute and delayed

Symptoms/injuries
3/23/2017: Hydrogen peroxide at these concentrations is a strong oxidant. Causes severe skin burns andeye damage
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VAPROX® HC
Sterilant
Safety Data Sheetaccording to Regulation (EC) No. 453/2010

Symptoms/injuries after inhalation: Harmful if inhaled. Possible inflammation of the respiratory tract or pulmonary edema.

Symptoms/injuries after eye contact: Eye contact with concentrated solutions may cause severe eye damage followed by loss of sight

Symptoms/injuries after ingestion: Swallowing a small quantity of this material will result in serious health hazard. Severe irritationor burns to the mouth, throat, esophagus, and stomach

4.3.

Indication of any immediate medical attention and special treatment needed

No additional information available.

SECTION 5: Firefighting measures
5.1.

Extinguishing media

Suitable extinguishing media: Water or water fog

Unsuitable extinguishing media: Do not use foam, dry powder or carbon dioxide.

5.2.

Special hazards arising from the substance or mixture

Hazardous decomposition products in case of
fire
5.3.

: Hydrogen peroxide at these concentrations is a strong oxidant. On decomposition releases
oxygen which may intensify fire. Containers may swell and burst during a fire due to internalpressure caused by heat

Advice for firefighters

Precautionary measures fire

: On heating, there is a risk of bursting due to internal pressure build-up. Cool down the containers
exposed to heat with a water spray

Firefighting instructions: Exercise caution when fighting any chemical fire. Use water spray or fog for cooling exposedcontainers. Prevent fire-fighting water from entering environment

Protective equipment for firefighters: Use self-contained breathing apparatus. Do not enter fire area without proper protective
equipment, including respiratory protection

Other information: Oxygen evolution decomposition may burst sealed containers and accelerate the burning rates
of other combustible materials. Damp material in contact with paper, wood, cloth, etc. may cause
spontaneous combustion of the organic material

SECTION 6: Accidental release measures
6.1.

Personal precautions, protective equipment and emergency procedures

General measures
6.1.1.

: Ensure adequate ventilation. Do not breathe fumes, vapors. Avoid contact with skin, eyes andclothes. Contain spill if safe to do so.

For non-emergency personnel

Protective equipment: Wear protective gloves and eye/face protection. For further information refer to section 8:
Exposure-controls/personal protection

Emergency procedures: Contain spill if safe to do so. Evacuate unnecessary personnel

6.1.2.

For emergency responders

Protective equipment: Equip cleanup crew with proper protection

Emergency procedures: Ventilate area

6.2.

Environmental precautions

Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. Avoid release to the environment
6.3.

Methods and material for containment and cleaning up

Methods for cleaning up: Spills should be contained and may be cautiously neutralized with sodium metabisulfite or
sodium sulfite (1.0 lb of either to 100 ml peroxide), or absorbed on appropriate materials andplaced in a container for disposal. Do not use sawdust or cellulose materials as an absorbent.
Flush spill site with large quantities of water (20 parts water to 1 part hydrogen peroxide) to asanitary sewer.

Other information: Combustible materials exposed to hydrogen peroxide should be immediately submerged in orrinsed with large amounts of water to ensure that all hydrogen peroxide is removed. Residualhydrogen peroxide that is allowed to dry (upon evaporation hydrogen peroxide can concentrate)on organic materials such as paper, fabrics, cotton, leather, wood or other combustibles cancause the material to ignite and result in fire

6.4.

Reference to other sections

See Heading 8. Exposure controls and personal protection

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VAPROX® HC
Sterilant
Safety Data Sheetaccording to Regulation (EC) No. 453/2010

SECTION 7: Handling and storage
7.1.

Precautions for safe handling

Precautions for safe handling: Read and observe all labeled use instructions.

Hygiene measures: Take care for general good hygiene and housekeeping. Wash hands thoroughly after handling.
Contaminated clothing should be washed thoroughly in order to eliminate a delayed potential fire
hazard. Do not eat, drink or smoke when using this product7.2.

Conditions for safe storage, including any incompatibilities

Technical measures: Provide adequate ventilation. A washing facility/water for eye and skin cleaning purposes should
be present. Floors should be impervious, resistant to liquids and easy to clean

Storage conditions: Store in a cool, well ventilated place.

Incompatible materials: Strong alkalis. Strong oxidizing agents. Organic materials. Reducing agents. Metal salts. Alkali
metals. Wood. Paper. Copper and its alloys. Metals. Cyanide. Hazardous reactions may occur
on contact with certain chemicals. (Refer to the list of incompatible materials section 10:"Stability-Reactivity")

Prohibitions on mixed storage: Keep away from incompatible materials

Storage area

: Store in dry, cool, well-ventilated area

Special rules on packaging: Correctly labelled

7.3.

Specific end use(s)No additional information available

SECTION 8: Exposure controls/personal protection
8.1.

Control parameters

Hydrogen peroxide (7722-84-1)
United Kingdom
WEL TWA (mg/m³)
United Kingdom
WEL TWA (ppm)
United Kingdom
WEL STEL (mg/m³)
United Kingdom
WEL STEL (ppm)
USA - ACGIH
ACGIH TWA (ppm)
USA - NIOSH
NIOSH IDLH (ppm)

1.4 mg/m³
1 ppm
2.8 mg/m³
2 ppm
1 ppm
75 ppmUSA - NIOSH

NIOSH REL (TWA) (mg/m³)

1.4 mg/m³

USA - NIOSH

NIOSH REL (TWA) (ppm)

1 ppm

USA - OSHA

OSHA PEL (TWA) (mg/m³)

1.4 mg/m³

USA - OSHA

OSHA PEL (TWA) (ppm)

1 ppm

8.2.

Exposure controls

Appropriate engineering controls:

Ensure adequate ventilation. Emergency eye wash fountains and safety showers should beavailable in the immediate vicinity of any potential exposure. Local exhaust ventilation isrecommended to maintain vapor level below the threshold limit value (TLV)

Personal protective equipment:

Personal protective equipment should be selected based upon the conditions under which thisproduct is handled or used. Protective clothing. Gloves. Protective goggles. Avoid all
unnecessary exposure

Hand protection:

Wear protective gloves. Use gloves constructed of chemical resistant materials such as nitrile,
neoprene, rubber, or vinyl if frequent or prolonged contact is expected.

Eye protection:

Wear protective eyewear.

Skin and body protection:

Wear suitable protective clothing. Chemical resistant lab coat and closed toe shoes

Respiratory protection:

None required for routine use. In emergency situations where established limits are exceeded,
it is recommended to use SCBA (Self-Contained Breathing Apparatus).

Other information:

Do not eat, drink or smoke during use

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VAPROX® HC
Sterilant
Safety Data Sheetaccording to Regulation (EC) No. 453/2010

SECTION 9: Physical and chemical properties
9.1.

Information on basic physical and chemical properties

Physical state: Liquid

Appearance: ClearColour: Colourless

Odour: Odourless

Odour threshold: No data availablepH: ≤ 3.5

Relative evaporation rate (butyl acetate=1): >1

Melting point: No data available

Freezing point:

Boiling point-55C: 119C

Flash point: Not flammableAuto-ignition temperature: Not flammable

Decomposition temperature: > 85C

Flammability (solid, gas)

: Non flammable

Vapour pressure: 14.2 mm Hg @ 30C

Relative vapour density at 20 °C: No data available

Relative density: No data available

Density
Solubility: 1.24 g/ml Specific Gravity @ 20C
: Water: completely soluble

Log Pow: -1.57 @ 20C

Viscosity, kinematic: No data available

Viscosity, dynamic: 1.079 cP @ 25C

Explosive properties: Not explosive

Oxidising properties: Oxidizer

Explosive limits: Not explosive

9.2.

Other information

No additional information available

SECTION 10: Stability and reactivity
10.1.

Reactivity

Reactive and oxidizing agent.
10.2.
Chemical stability
Stable under normal conditions of use.
10.3.

Possibility of hazardous reactions

Hazardous polymerization will not occur. Contamination may cause rapid decomposition, oxygen gas release and dangerous pressures
10.4.

Conditions to avoid

Extremely high or low temperatures. Direct sunlight. Protect from all contamination
10.5.

Incompatible materials

Cyanides, hexavalent chromium compounds, nitric acid, potassium permanganate, oxidizers, reducers, combustible materials, flammable vapors,
alkalies, copper, dirt, dust, iron, heavy meatals and their salts and organic materials (especially vinyl monomers)
10.6.

Hazardous decomposition productsContamination may cause rapid decomposition, oxygen gas release and dangerous pressures

SECTION 11: Toxicological information
11.1.

Information on toxicological effects

Acute toxicity: Harmful if swallowed. Harmful if inhaled.

VAPROX® HC Sterilant
ATE (oral)
ATE (dust,mist)
3/23/2017

500,000 mg/kg bodyweight
1,500 mg/l/4h
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VAPROX® HC
Sterilant
Safety Data Sheetaccording to Regulation (EC) No. 453/2010

Hydrogen peroxide (7722-84-1)
LD50 oral rat
LD50 dermal rat
LD50 dermal rabbit
LC50 inhalation rat (mg/l)
ATE (oral)
ATE (dermal)
ATE (gases)
ATE (vapours)
ATE (dust,mist)

801 mg/kg
4060 mg/kg
2000 mg/kg
2 g/m³ (Exposure time: 4 h)
801,000 mg/kg bodyweight
2000,000 mg/kg bodyweight
4500,000 ppmv/4h
2,000 mg/l/4h
2,000 mg/l/4h

Skin corrosion/irritation: Causes severe skin burns and eye damage

Serious eye damage/irritation

pH: <= 3.5: Serious eye damage, category 1, implicit

Respiratory or skin sensitisation

pH: <= 3.5: Not a sensitizer

Germ cell mutagenicity: This product is not recognized as mutagenic by Research Agencies.

Carcinogenicity: IARC, NTP and OSHA do not list this product or its ingredients as carcinogens. ACGIH lists
hydrogen peroxide as a “Confirmed Animal Carcinogen with Unknown Relevance to Humans”
A3.

Reproductive toxicity: Not classified

Specific target organ toxicity (single exposure): Eyes. Respiratory System. Skin.

Specific target organ toxicity (repeatedexposure): Not classified

Aspiration hazard: Not classified

In vivo tests did not show mutagenic effects.

Based on available data, the classification criteria are not met

Based on available data, the classification criteria are not met

Based on available data, the classification criteria are not met
Potential Adverse human health effects andsymptoms: Harmful if swallowed. Harmful to eyes and skin.

SECTION 12: Ecological information
12.1.

Toxicity

Ecology - water
Hydrogen peroxide (7722-84-1)
LC50 fishes 1
EC50 Daphnia 1
EC50 other aquatic organisms 1
LC50 fish 2
EC50 Daphnia 2
12.2.

16.4 mg/l (Exposure time: 96 h - Species: Pimephales promelas)
7.7 mg/l (Exposure time: 24 h - Species: Daphnia magna)
2.5 mg/l (Exposure time: 72 h - Species: Chlorella vulgaris)
18 - 56 mg/l (Exposure time: 96 h - Species: Lepomis macrochirus [Static])
18 - 32 mg/l (Exposure time: 48 h - Species: Daphnia magna [Static])

Persistence and degradability

VAPROX® HC Sterilant
Persistence and degradability

12.3.

: Harmful to aquatic life with long lasting effects

Hydrogen peroxide in the aquatic environment is subject to various reduction or oxidation
processes and decomposes into water and oxygen. Hydrogen peroxide half-life in freshwater
ranged from 8 hours to 20 days, in air from 10-20 hours and in soils from minutes to hours
depending on microbiological activity and metal contaminants.

Bioaccumulative potential

VAPROX® HC Sterilant
Bioaccumulative potential

Not establishedHydrogen peroxide (7722-84-1)
BCF fish 1(no bioaccumulation)

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VAPROX® HC
Sterilant
Safety Data Sheetaccording to Regulation (EC) No. 453/2010

12.4.

Mobility in soil

Will likely be mobile in the environment due to its water solubility.
12.5.

Results of PBT and vPvB assessment

This product is not considered to be persistent, bioaccumulating nor toxic (PBT).
12.6.

Other adverse effects

Decomposes into oxygen and water.
No adverse effects.

SECTION 13: Disposal considerations
13.1.

Waste treatment methods

Waste disposal recommendations: Empty cartridges may be disposed in normal trash. Expired cartridges should be disposed ofaccording to local policies for hazardous materials. For additional guidance, contact the State
Water Board or Regional Office of the EPA.

Additional information: Not applicable

Ecology - waste materials: Decomposes into oxygen and water. No adverse effects.

SECTION 14: Transport information
In accordance with ADR/RID/IMDG/IATA/ADN
Keep well ventilated and away from direct sunlight or heat sources.
14.1.
UN number

Applies to PB007:
UN-No.

: 2014

UN-No.(IATA): 2014

UN-No. (IMDG): 2014

UN-No.(ADN): 201414.2.

UN proper shipping name

Proper Shipping Name

: HYDROGEN PEROXIDE, AQUEOUS SOLUTION

Proper Shipping Name (IATA): HYDROGEN PEROXIDE, AQUEOUS SOLUTIONS, 59 %Transport document description: UN 2014 HYDROGEN PEROXIDE, AQUEOUS SOLUTIONS 59% STABILIZED, 5.1 (8), II

14.3.

Transport hazard class(es)Class (UN): 5.1

Classification code (UN)

: OC1Class (IATA): 5.1

Class (IMDG): 5.1

Class (ADN): 5.1

Hazard labels (UN): 5.1, 8

14.4.

Packing group

Packing group (UN)
14.5.

: II

Environmental hazards

Dangerous for the environment: No

Marine pollutant: No

Other information: No supplementary information available

14.6.

Special precautions for user

14.6.1.

Overland transport

Hazard identification number (Kemler No.)

: 58

Classification code (UN): OC1

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VAPROX® HC
Sterilant
Safety Data Sheetaccording to Regulation (EC) No. 453/2010

Orange plates:

Transport category (ADR): 2

Tunnel restriction code

: E

Limited quantities (ADR): 1L

Excepted quantities (ADR): E2

EAC code: 2P

Applies to PB028: US and Canada: Ground Modes: Conforms with 49 CFR 173.4a and TDG 1.17.1
International: Ground Modes: Conforms with ADR/RID/ADG7 3.5
14.6.2.

Transport by sea

PB007: See above information (IMDG)
PB028: IMDG Conforms with IMDG 3.5 Shipping paper must state, “dangerous goods in excepted quantities”
14.6.3.

Air transport

PB007: Forbidden (US, Canada, International)
PB028: Conforms with 49CFR SP A60 (US) Conforms with ICAO SP A75 (International)
14.6.4.

Inland waterway transport

Vaprox HC is not considered a marine pollutant.
14.7.

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC CodeNot applicable

SECTION 15: Regulatory information
15.1.

Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1.

EU-Regulations

No REACH Annex XVII restrictions
Contains no REACH candidate substance
15.1.2.

National regulations

No additional information available
15.2.

Chemical safety assessment

No chemical safety assessment has been carried out

SECTION 16: Other information
Revision Date

: 3/23/2017

Sources of Key data

: REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE
COUNCIL of 16 December 2008 on classification, labelling and packaging of substances andmixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending
Regulation (EC) No 1907/2006

Other information: NoneFull text of H- phrases:
Acute Tox. 4 (Inhalation: mist)
Acute Tox. 4 (Oral)
Aquatic Chronic 3
Ox. Liq. 1
Ox. Liq. 2
Skin Corr. 1A
Skin Corr. 1B
STOT SE 3
H271

Acute toxicity (Inhalation:mist), Category 4
Acute toxicity (Oral), Category 4
Hazardous to the aquatic environment — Chronic Hazard, Category 3
Oxidising Liquids, Category 1
Oxidising Liquids, Category 2
Skin corrosion/irritation, Category 1A
Skin corrosion/irritation, Category 1BSpecific target organ toxicity (single exposure), Category 3
May cause fire or explosion; strong oxidiser

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VAPROX® HC
Sterilant
Safety Data Sheetaccording to Regulation (EC) No. 453/2010

H272
H302
H314
H332
H335
H412

May intensify fire; oxidiser
Harmful if swallowed
Causes severe skin burns and eye damage
Harmful if inhaled
May cause respiratory irritation
Harmful to aquatic life with long lasting effects

SDS EU (REACH Annex II)
The information on this sheet is not a specification and does not guarantee specific properties. The information is intended to provide general knowledge as to health and safety based upon our knowledgeof the handling, storage and use of the product. It is not applicable to unusual or non-standard uses of the product or where instruction or recommendations are not followed.

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