(1／7)

SAFETY DATA SHEETMSDS: 66139-0115E41EEN
Date Prepared: 2010/07/01
Date Revised: 2014/02/03
Product Name:PYRONOC GREASE WS 0

1. Identification of the substance/mixture and of the company/undertaking
Product Name:
Identification of thesupplier:Address:
Charge section:

PYRONOC GREASE WS 0
JX Nippon Oil & Energy Corporation
6-3,Otemachi 2-Chome,Chiyoda-ku,Tokyo, 100-8162 Japan
Lubricants Quality Assurance Group（TEL:+81 3-6275-5158）

2. Hazards identification
hazard category
Acute toxicity（oral）
Acute toxicity（dermal）
Skin corrosion/irritationSerious eye damage/eye irritation
Skin sensitizer
Specific target organ systemic toxicity
following single exposure
Specific target organ systemic toxicity
following repeated exposure
Aspiration hazard

Category
No Classification
No Classification
No Classification
No Classification
Category 1
Category 2
No Classification
No Classification

LABEL ELEMENTS
Precautionary
pictograms:

Signal word:
Hazard Statement:

Warning
May cause allergic skin reaction
May cause damage to organs (or state all organs affected(bloodsystems))

Precautionary Statements:
Prevention Do not handle until all safety precautions have been read andunderstood.
Wear protective gloves/protective clothing/eye protection/faceprotection.
Contaminated work clothing should not be allowed out of theworkplace.
Do not breathe dust/fume/gas/mist/vapours/spray.
Wash hands thoroughly after handling.
Do not eat, drink or smoke when using this product.
Response IF SWALLOWED: Immediately call a POISON CENTER ordoctor/physician.
IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
IF ON SKIN: Wash with plenty of soap and water.
IF exposed or if you feel unwell: Call a POISON CENTER or
doctor/physician.

(2／7)SAFETY DATA SHEETMSDS: 66139-0115E41EEN
Date Prepared: 2010/07/01
Date Revised: 2014/02/03
Product Name:PYRONOC GREASE WS 0

Wash contaminated clothing before reuse.
If skin irritation or a rash occurs: Get medical
advice/attention.
Storage The product must be stored in a cool, well-ventilated location
where it will not be exposed to direct sunlight.
Store locked up.
Disposal Dispose of contents/container in accordance withlocal/regional/national/international regulations.

3. Composition/information on ingredients
Substance/Mixture:
Ingredients and Concentration

MixtureIngredient NameBase Oil(s)Thickener
Additives

Concentrationwt.%
80-90
1-10
<204. First-aid measures
Inhalation:

Skin Contact:

Eye Contact:

Ingestion:

IF INHALED: Remove victim to fresh air and keep at rest in aposition comfortable for breathing.
Cover the body with blankets to keep warm and quiet. If you feelunwell, seek medical advice.
Immediately flush skin with large amounts of water.
Wash contaminated clothing before reuse.
If skin irritation occurs : Get medical advice/attention.
Rinse with clean water carefully for several minutes. Remove
contact lenses if present and if removal is easy, then continue
rinsing. Rinse for 15 minutes at a minimum and seek medical
attention.
Do not induce vomiting. Drink [one glass] [two glasses] of water.
Call a physician [or poison controlcenter] immediately.

5. Fire-fighting measures
Suitable Extinguishing Media:
Extinguishing Media to Avoid:Specific hazards arising from thechemical:
Fire Fighting:

Mist of loaded liquid, dry chemicals, carbon dioxide, fire foam,
and dry sand are effective.
Use of straight steam of water can cause a risk of spreadingfire.
In some cases of fire, may release irritant gases.
When burnt, may generate carbon monoxide and other toxic gases.
Spray water to the surrounding facilities for cooling.

(3／7)SAFETY DATA SHEETMSDS: 66139-0115E41EEN
Date Prepared: 2010/07/01
Date Revised: 2014/02/03
Product Name:PYRONOC GREASE WS 0

Special protective equipment andprecautions for fire fighters:

Keep unauthorized persons off the site of occurrence of fire andthe surroundings.
Even after extinction, cool containers thoroughly with plenty ofwater.
Wear fire/flame resistant/retardant clothing.
Fight fire from windward direction while wearing protectiveequipment. If contact with skin is expected, wear impervious
protective equipment and gloves.
Use air-breathing apparatus and protective clothing whenevernecessary.

6. Accidental release measures
Personal precautions, protective
Wear protective equipment when working.
equipment and emergency procedures:
Remove nearby potential ignition sources immediately.
When mist is generated, use respiratory equipment to prevent
inhalation of mist.
Do not touch or walk through spillage.
Pay attention to the site of spillage, which is slippery.
Environmental precautions:
Prevent spreading of oil spill with earth and sand, sandbags, orother proper materials and use care not to allow the oil spill toflow to street drains, sewer systems, and rivers.
At sea, install oil spill containment booms to prevent spreadingof spills and absorb with absorption mat or other propermaterials.
Methods and materials for
In case of spillage in small quantity, collect spillage bycontainment and cleaning up:
absorbing with earth, sand, sawdust, waste, or other propermaterials.
In case of spillage in large quantity, enclose with embankment toprevent spreading of spillage and collect spillage in empty
containers to the extent possible.
Prevention of second accident:
In case of spillage, immediately inform the organizations
concerned of the spillage to prevent possible accidents andspreading of spillage.
Remove nearby potential ignition sources immediately and makefire-extinguishing agents available. Remove spillage completely,and ventilate and clean the site and the surroundings.

7. Handling and storage
Handling
Technical Measures:

Keep away from any possible contact with sparks, open flames, andhigh-temperature materials, and do not allow release of vapor
without justification.
Use pumps or other proper equipment for taking out fromcontainers. Do not siphon with your mouth using a tube. Do notdrink.
When mist is generated, use respiratory equipment to prevent
inhalation of mist.

(4／7)SAFETY DATA SHEETMSDS: 66139-0115E41EEN
Date Prepared: 2010/07/01
Date Revised: 2014/02/03
Product Name:PYRONOC GREASE WS 0

Ventilation
requirements:
Precautions:
Precautions for safe
handling:

In case of vapor/mist dispersion, install a closed system, local
ventilation system, and/or other proper equipment for the sourcesof vapor/mist generation.
Avoid rough handling of containers such as falling, dropping,exposing to shock, and dragging.
Maintain adequate ventilation when handling indoors.
Wash hands and face thoroughly after handling.
Be careful with fire.
Avoid falling, dropping, exposing to shock, or dragging ofcontainers.
Wear protective gloves when opening containers to eliminate arisk of hand injury.

Storage
Storage Conditions:

Safety adequate
container materials:

Store in a well ventilated, cool, dry, dark place, protectingfrom direct sunlight and keeping away from any potential ignition
sources and high-temperature materials.
Store tightly stopped after use to prevent possible contamination
with dust and moisture.
Preferably store locked up in a proper storage area.
Use spill-proof containers that are free of damage/corrosion.

8. Exposure controls/personal protection
Appropriate engineering controls:

In case of mist generation, enclose the source of mist
generation, or install a ventilation system.
Install eye cleaning and body cleaning equipment near thehandling site.

Control parameters
Ingredient Name
Base Oil(s)Thickner

Personal Protective Equipment
Respiratory Protection:
Hand protection:
Eye/face protection:
Skin Protection:

Japan Society for
ACGIH
Occupational
Occupational
TLV-STEL
TLV-TWA
Exposure Limits
None established None established None establishedppm,ppm,ppm,3mg/m3(Mineral Oil None established 5mg/m3(Mineral OilMist)
mg/m3Mist)
None established None established None establishedppm,ppm,ppm,
None established None established None established
mg/m3
mg/m3
mg/m3

Not needed under normal conditions, but wear a gas mask (againstorganic gases) whenever required.
In case of prolonged or repeated exposure, wear oil-resistanthand protection.
In case of exposure to splashes, wear ordinary type goggles.
In case of handling over a prolonged period of time or in case ofexposure to oil, wear oil-resistant, long-sleeved work clothing.

(5／7)SAFETY DATA SHEETMSDS: 66139-0115E41EEN
Date Prepared: 2010/07/01
Date Revised: 2014/02/03
Product Name:PYRONOC GREASE WS 0Hygiene Measures:

Take off contaminated clothing and wash thoroughly before reuse.
Wash hands thoroughly after handling.

9. Physical and chemical properties
ProductForm:
Semi solid
Color:
Light yellow
Odor:
Slight odor
Melting point/freezing
Dropping Point≧250(℃)
point:
Initial boiling point
Initial boiling point - End point No dataand boiling range:
Upper/lower flammability Explosion Limit (1-7％)
or explosive limits:
Solubility:
water：Insoluble.
Partition coefficient:
No data.
n-octanol/water:
Decomposition
No data.
temperature:

10. Stability and reactivity
Chemical stability:
Possibility of hazardous
reactions:
Conditions to avoid:
Incompatible materials:
Hazardous decomposition
products:

Stable when stored or preserved in a dark place at room temperature.
Keep away from any possible contact with strong oxidizing agents.
Contact with incompatible hazard substances
Prolonged heating, open flames, and ignition sources
Use care to keep away from any possible contact with halogens, strong
acids, alkalis, and acidifying substances.
When burnt, may release carbon monoxide and other gases.

11. Toxicological information
Product
Acute toxicity (oral):Acute toxicity (dermal):Acute toxicity (inhalation):
Skin corrosion/irritation:
Serious eye damage/irritation:
Respiratory sensitization:

For mixtures, hazard category was identified based on
the classification criteria for mixtures.
For mixtures, hazard category was identified based on
the classification criteria for mixtures.
For mixtures, hazard category was identified based on
the classification criteria for mixtures.
For mixtures, hazard category was identified based on
the classification criteria for mixtures.
For mixtures, hazard category was identified based on
the classification criteria for mixtures.
For mixtures, hazard category was identified based on
the classification criteria for mixtures.

(6／7)SAFETY DATA SHEETMSDS: 66139-0115E41EENDate Prepared: 2010/07/01
Date Revised: 2014/02/03
Product Name:PYRONOC GREASE WS 0

Skin sensitization:
Mutagenicity:
Carcinogenicity:
Reproductive toxicity:
Target organ effect/Single
exposure:
Target organ effect/Multi
exposure:
Respiratory toxic:

For mixtures, hazard category was identified based on
the classification criteria for mixtures.
For mixtures, hazard category was identified based on
the classification criteria for mixtures.
For mixtures, hazard category was identified based on
the classification criteria for mixtures.
For mixtures, hazard category was identified based on
the classification criteria for mixtures.
For mixtures, hazard category was identified based on
the classification criteria for mixtures.
For mixtures, hazard category was identified based on
the classification criteria for mixtures.
For mixtures, hazard category was identified based on
the classification criteria for mixtures.

IngredientBase Oil(s)Acute toxicity (oral):Acute toxicity (dermal):
Serious eye damage/irritation:
Skin sensitization:
Mutagenicity:
Carcinogenicity:

LD50:≧ 5000 mg/kg[rat]LD50:≧ 5000 mg/kg[rat]Practically None [rabbit]
None Buehler method [guinea pig]
Ames Test:Negative
EU:Category 2：R45 need not apply.(NOTE L isApplicable), IARC:3

Acute toxicity (oral):Acute toxicity (dermal):

LD50:＞ 2000 mg/kg[rat]LD50:＞ 2000 mg/kg[rat]Thickner

12. Ecological information
ProductEcotoxicity
Fish acute toxicity:
Algae acute toxicity:
Fish chronic toxicity:
Algae chronic toxicity:

For mixtures, hazard category was identified based on
the classification criteria for mixtures.
For mixtures, hazard category was identified based on
the classification criteria for mixtures.
For mixtures, hazard category was identified based on
the classification criteria for mixtures.
For mixtures, hazard category was identified based on
the classification criteria for mixtures.

IngredientBase Oil(s)Ecotoxicity
Fish acute toxicity:
Daphnia acute toxicity:

13. Disposal considerations

96hLC50:＞ 5000 mg/L[Oncorhynchus mykiss]
48hEC50:＞ 1000 mg/L[Daphnia magna]

(7／7)SAFETY DATA SHEETMSDS: 66139-0115E41EEN
Date Prepared: 2010/07/01
Date Revised: 2014/02/03
Product Name:

Disposal
methods:

PYRONOC GREASE WS 0

Dispose of contents/container in accordance with local/regional/national/international
regulations.
Every customer/user of the product should dispose of industrial waste on its own
responsibility, otherwise it must rely on a company authorized by prefectural governor fortreating industrial waste or a local public body involved in the disposal of industrial
waste for proper disposal.
Before disposal of used container, remove contents completely.

14. Transport information
IMDG
UN classification：
Specific security precaution andcondition of transportation:

Not applicable
Transport containers without causing any significant friction orshaking.

15. Regulatory information
Korea(KECL)：
Australia(AICS)：
Canada(DSL)：
China(IECSC)：
EU(REACH)：
New Zealand(NZIoC)：
USA(TSCA)：
Philippines(PICCS)：
Taiwan：All components are listed or exempted.
In the case where one or more components are not listed or, even iflisted, in the case of importing to the country or area concerned, anapplication or notification is required.
In the case where one or more components are not listed or, even iflisted, in the case of importing to the country or area concerned, anapplication or notification is required.
All components are listed or exempted.
In the case where one or more components are not listed or, even iflisted, in the case of importing to the country or area concerned, anapplication or notification is required.
In the case where one or more components are not listed or, even iflisted, in the case of importing to the country or area concerned, anapplication or notification is required.
All components are listed or exempted.
In the case where one or more components are not listed or, even iflisted, in the case of importing to the country or area concerned, anapplication or notification is required.
All components are listed or exempted.

16. Other information
Disclaimer

We at JX Nippon Oil & Energy Corporation have prepared the copyrighted
Safety Data Sheet to provide reference information on the hazardous
chemical product of interest for our customers/users to ensure secure andsafe handling.
We would like every customer/user of the product to refer to theinformation and understand the necessity of taking appropriate measures
for the actual handling conditions on their own responsibilities for
optimum practical application of the product of interest.
Consequently, the Safety Data Sheet is not intended to guarantee thesafety of the product referenced to herein.