RINSYUNDOU Co.,Ltd
SUNMAX Building4-47 Nakagawara,
Gifu City, GIFU-Pref.
Postal Code 502-0013
Telephone 058-294-7333

MATERIAL SAFETY DATA SHEETPerformance Pigments & Colors

1.

IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING

Product Name:
CAS-No.:Recommended use:
Product Code:

GSLA LMM-14 Black Laser Marking
MixtureIndustrial Use Only
1320589

Date of Preparation: 03/01/2013

2. HAZARDS IDENTIFICATION
Emergency Overview
Warning
May cause respiratory tract, eye and skin irritation. May cause allergic skin or respiratory reaction. Contains crystalline silica whichcauses silicosis and lung cancer. Cancer hazard from inhalation (Nickel compounds).

Health:Flammability:

HMIS
2*

NFPA 704
211

Color:
Black
Physical Liquidstate:
Odor:
Characteristic

Physical Hazard: 0 0 PPE: B

Potential Health Effects
Eye contact:

Contact with eyes may cause irritation.

Skin contact:

Prolonged skin contact may cause skin irritation. May cause allergic skin reaction.

Inhalation:

May cause irritation of respiratory tract. May be harmful by inhalation. May cause allergic
respiratory reaction.

Ingestion:

May irritate digestive tract.

Chronic toxicity:

Chronic inhalation exposure can cause lung damage. Long term inhalation causes lungdamage (silicosis and cancer). Respirable crystalline silica has been classified as a GroupI (sufficient evidence in humans for carcinogenicity) carcinogenic by IARC and is listed by
NTP as a substance which may reasonably be anticipated to be a carcinogen. Inhalation ofnickel and nickel compounds is associated with nasal and lung damage and cancer.

3. COMPOSITION/INFORMATION ON INGREDIENTS
Components
Molybdenum compound

CAS Number

Weight %20 - 30%

Quartz silica

14808-60-7

5 - 10%

Nickel iron chromite, black, spinel

71631-15-7

1 - 5%

Mica

12001-26-2

1 - 5%

Silica, amorphous, fumed, cryst.-free

112945-52-5

1 - 5%The specific chemical identities are being withheld as a trade secret (29CFR1910.1200).

Product name: GSLA LMM-14 Black Laser Marking

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4. FIRST AID MEASURES
Eye contact:

Rinse immediately with plenty of water, also under the eyelids. Get medical attention if
irritation develops.

Skin contact:

Wash off immediately with soap and plenty of water. Remove and wash contaminatedclothing before re-use. If symptoms persist, call a physician.

Inhalation:

Move to fresh air. If breathing is difficult, give oxygen. If symptoms persist, call a physician.

Ingestion:

Drink plenty of water. Do not induce vomiting. Consult a physician if necessary.

Notes to physician:Treat symptomatically

5. FIRE-FIGHTING MEASURES
Flash point (°C): >93( >200°F) Method: PMCC
Suitable extinguishing media:

Use dry chemical, CO2, water spray or "alcohol" foam.

Hazardous decomposition products Carbon oxides. Heavy metal compounds.
under fire conditions:
Special protective equipment for

As in any fire, wear self-contained breathing apparatus (pressure-demand, NIOSH

firefighters:

approved or equivalent) and full protective gear

6. ACCIDENTAL RELEASE MEASURES
Personal precautions:

Environmental precautions:

Methods for cleaning up:

Remove all non-essential people from the affected area. Ensure adequate ventilation. In caseof insufficient ventilation, wear suitable respiratory equipment. Avoid contact with skin, eyesand clothing. Wear personal protective equipment.
Prevent further leakage or spillage if safe to do so. Prevent product from entering drains. Do
not flush into surface water or sanitary sewer system. Do not allow material to contaminate
ground water system.
Wear personal protective equipment. Absorb spill with inert material (e.g. dry sand or earth),then place in a chemical waste container. Clean contaminated surface thoroughly. Dispose ofpromptly.

7. HANDLING AND STORAGE
Handling:
Handle in accordance with good industrial hygiene and safety practice. Use only in area provided with appropriate exhaust
ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Avoid contact with skin, eyes and clothing. Wear
personal protective equipment. Do not eat, drink, or smoke in areas of use or storage. Do not take internally. Wash thoroughly afterhandling.
Storage:
Keep in a dry, cool and well-ventilated place

8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure limits
Minimize exposure in accordance with good hygiene practice.
Components

OSHA
3ACGIH
3Quartz silica

0.1 mg/m TWA (respirable dust)

0.025 mg/m TWA respirable fractionMica

20 mppcf TWA

3 mg/m3 TWA respirable fraction

Engineering measures:

Provide appropriate exhaust ventilation wherever dust, mist, vapors, or fumes can be generated.
Ensure that eyewash stations and safety showers are proximal to the work-station location.

Eye protection:

Safety glasses with side-shields.

Product name: GSLA LMM-14 Black Laser Marking

2/5Skin and body protection:

Lightweight protective clothing. Keep working clothes separately. Remove and wash ontaminatedclothing before re-use.

Hand protection:

Impervious gloves. Follow the recommendations given by the manufacturer of protective gloves.

Respiratory protection:In case of insufficient ventilation, wear suitable respiratory equipment. NIOSH-approved respirators
should be worn where engineering controls and work practices do not reduce exposure to or below
the PEL. Seek professional advice prior to respirator selection and use.

Hygiene measures:

Wash hands before breaks and at the end of workday

9. PHYSICAL AND CHEMICAL PROPERTIES
Color:
Odor:
Boiling point/range (°C):
Melting point/range (°C):
Vapor density:
Evaporation Rate (Water = 1)
VOC contentBlack
Characteristic
No data available
No data available>1.00<1.00
70%Physical state:
Molecular weight:
pH:
Specific gravity (Water =1):
Vapor pressure :Water solubility:

LiquidNo data available
No data available
No data available
No data available
Insoluble

10. STABILITY AND REACTIVITY
Stability:

Stable at normal conditions

Polymerization

None under normal processing

Hazardous decomposition products: Thermal decomposition can lead to release of irritating gases and vapors. Carbon oxides.
Heavy metal compounds.
Materials to avoid:
Nitric acid.
Conditions to avoid
None known.

11. TOXICOLOGICAL INFORMATION
Acute toxicity:
Information given is based on data on the components and the toxicology of similar
products
Chronic Toxicity:
Contains crystalline silica which causes silicosis and lung cancer.
Carcinogenic Effects:
Respirable crystalline silica has been classified as a Group I (sufficient evidence in humansfor carcinogenicity) carcinogenic by IARC and is listed by NTP as a substance which may reasonably be anticipated to be a
carcinogen. Crystalline silica is also a known cause of silicosis, a non-cancerous lung disease caused by excessive exposure tocrystalline silica. IARC made the overall evaluation that "Nickel compounds are carcinogenic to humans (Group 1)" on the basis of
the combined results of epidemiological studies, carcinogenicity studies in experimental animals, and several types of other relevant
data.
Components
NIOSH - Pocket Guide - Target Organs
Quartz silica
eyes respiratory systemMica
respiratory system
Nickellungs skin nasal cavities
Chromiumeyes respiratory system skinComponent information, if any, is listed below
Molybdenum compound

Product name: GSLA LMM-14 Black Laser Marking

3/5LD50s and LC50s: Oral LD50 (Rat) = 2689 mg/kg
Dermal LD50 (Rat) = 2 g/kg
Inhalation LC50 (Rat) = 5840 mg/m3
Quartz silica
LD50s and LC50s: Oral LD50 (Rat) = 500 mg/kg
OSHA - SelectPresentCarcinogens:
Known Human Carcinogen Listed
NTP:
IARC - Group 1: Present
Nickel iron chromite,
Known Human Carcinogenblack, spinel
ListedOSHA - SelectCarcinogens:
NTP:
IARC - Group 1:
Silica, amorphous, fumed, cryst.-free
LD50s and LC50s:
Oral LD50 (Rat) = 3160 mg/kg

12. ECOLOGICAL INFORMATION
Aquatic toxicity:
Persistence anddegradability:

No data is available on the product itself. Information given is based on data on the components and theecotoxicology of similar products.
Not determined

13. DISPOSAL CONSIDERATIONS
Waste from residues /unused products:

Waste must be disposed of in accordance with federal, state and local environmental control regulations.
Where possible recycling is preferred to disposal or incineration.

DOT (U.S.)

Not Regulated

14. TRANSPORT INFORMATION

Proper shipping name:

TDG (Canada)
Proper Shipping Name
IMDG
Proper Shipping Name
IATA
Proper shipping name

Not Regulated

Not Regulated
Not Regulated

15. REGULATORY INFORMATION
U.S. Regulations:
TSCA:

Not subject to TSCA 12(b) Export Notification

Product name: GSLA LMM-14 Black Laser Marking

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SARA 313:
Components
Nickel compounds (1 - 5%)
Chromium (III) compounds (1 - 5%)
Molybdenum compound (20 - 30%)

U.S. - CERCLA/SARA - Section 313 - Emission Reporting
0.1 % de minimis concentration
1.0 % de minimis concentration
1.0 % de minimis concentration

State Regulations
This product or its ingredients have been evaluated for New Jersey, Pennsylvania, and California Prop 65 supplier notificationrequirements. Substances that are subject to notification requirements, if any, are listed below.
Components
Nickel compounds
Chromium (III) compounds
Molybdenum compound
Components
Nickel compounds
Chromium (III) compounds
Quartz silica
Components
Nickel compounds
Quartz silica

PARTK:
Listed (PARTK)
Listed (PARTK)
Listed (PARTK)NJRTK:
1341
0432
1660
State Regulation - CA Prop65
Carcinogen
Carcinogen

Canadian WHMIS
WHMIS hazard class:

D2A Very toxic materials

Canadian Ingredient Disclosure List (IDL):
Components
Nickel compounds
Chromium (III) compounds
Quartz silica
Mica
Molybdenum compound

Canada - WHMIS Ingredient Disclosure:
0.1
0.1
111

International Inventories
TSCA 8(b):Canadian DSL/NDSL list
EC-No.
Philippines (PICCS):
Japan (ENCS):
Korea (KECL):
China (IECS):
Australia (AICS):New Zealand (NZloC):

Listed or exempt.
All ingredient(s) are listed on the DSL or NDSL
Listed or exempt.
One or more ingredient(s) are not on the PICCS list.
Listed or exempt.
Listed.
Listed.
Listed.
Listed.

16. OTHER INFORMATIONFor Industrial Use Only
Prepared by: Ferro Technical Center
Disclaimer: The information and recommendations contained in this Material Safety Data Sheet have been compiled from sources
believed to be reliable and to represent the most reasonable current opinion on the subject when the MSDS was prepared. Nowarranty, guaranty or representation is made as to the correctness or sufficiency of the information. The user of this product must
decide what safety measures are necessary to safely use this product, either alone or in combination with other products, anddetermine its environmental regulatory compliance obligations under any applicable federal or state laws.

End of Safety Data Sheet
Product name: GSLA LMM-14 Black Laser Marking

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