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0.005mol/L Potassium permanganate solution,
JUNSEI CHEMICAL CO., LTD.,95278jis_J_E2-1,08/11/2018
Date of issue for the 1st edition: 08/11/2018

Safety Data Sheet

1. Identification of the substance/mixture and of the company/undertaking
Product identifier:Product name: 0.005mol/L Potassium permanganate solution
Product code(SDS NO): 95278jis_J_E2-1
Details of the supplier of the safety data sheet
Manufacturer/Supplier: JUNSEI CHEMICAL CO., LTD.
Address: 1-6, Ohmano-Cho, Koshigaya, Saitama 343-0844, Japan
Division: Quality Assurance Department
Telephone number: +81-48-986-6161
FAX: +81-48-989-2787
e-mail address: shiyaku-t@junsei.co.jp

2. Hazards identification
GHS classification and label elements of the product
Classification of the substance or mixture(Note) GHS classification without description: Not applicable/Out of classification/Not classifiable

3. Composition/information on ingredients
Mixture/Substance selection:
MixtureIngredient name:Potassium permanganate
Content(%):ca. 0.08
Chemical formula:KMnO4
Chemicals No, Japan:1-446
CAS No.:7722-64-7
MW:158.03
ECNO:231-760-3
Ingredient name:Water
Content(%):Residual quantity of the ingredient mentioned above.
Chemical formula:H2O
CAS No.:7732-18-5
MW:18.02
ECNO:231-791-2

4. First-aid measures
Descriptions of first-aid measures
IF INHALED
Remove person to fresh air and keep comfortable for breathing.
Call a POISON CENTER or doctor/physician if you feel unwell.
IF ON SKIN (or hair）
Take off immediately all contaminated clothing. Rinse skin with water/shower.
If skin irritation or rash occurs: Get medical advice/attention.
IF IN EYES
Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy

2/60.005mol/L Potassium permanganate solution,
JUNSEI CHEMICAL CO., LTD.,95278jis_J_E2-1,08/11/2018
to do. Continue rinsing.
If eye irritation persists: Get medical advice/attention.
IF SWALLOWED
Rinse mouth.
Call a POISON CENTER or doctor/physician if you feel unwell.

5. Fire-fighting measures
Extinguishing media
Suitable extinguishing media
Use appropriate extinguishing media suitable for surrounding facilities.
The product is non-flammable.
Specific hazards arising from the substance or mixture
Containers may explode when heated.
Fire may produce irritating, corrosive and/or toxic gases.
Advice for firefightersSpecific fire-fighting measures
Evacuate non-essential personnel to safe area.
Special protective equipment and precautions for fire-fighters
Wear fire/flame resistant/retardant clothing.
Wear protective gloves/protective clothing/eye protection/face protection.
Firefighters should wear self-contained breathing apparatus with full face peace operated
positive pressure mode.

6. Accidental release measures
Personnel precautions, protective equipment and emergency procedures
Ventilate area after material pick up is complete.
Wear proper protective equipment.
Environmental precautions
Avoid release to the rivers, lakes, ocean and groundwater.
Methods and materials for containment and cleaning up
Absorb spill with inert material (dry sand, earth, et al), then place in a chemical waste
container.
Preventive measures for secondary accident
Collect spillage.

7. Handling and storage
Precautions for safe handling
Preventive measures(Protective measures against fire and explosion)
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Exhaust/ventilator
Exhaust/ventilator should be available.
Safety treatments
Avoid contact with skin.
Avoid contact with eyes.
Avoid breathing dust, fume, gas, mist or vapor.
Safety Measures/Incompatibility
Wear protective gloves, protective clothing or face protection.
Use personal protective equipment as required.
When using do not eat, drink or smoke.

3/60.005mol/L Potassium permanganate solution,
JUNSEI CHEMICAL CO., LTD.,95278jis_J_E2-1,08/11/2018
Conditions for safe storage, including any incompatibilities
Recommendation for storage
Store in a well-ventilated place. Keep container tightly closed.
Keep cool. Protect from sunlight.

8. Exposure controls/personal protection
Control parameters
Control value(Potassium permanganate)
Japan control value (2004) <= 0.2mg-Mn/m3
Adopted value
No Adopted value data available in JSOH
(Potassium permanganate)
ACGIH(2012) TWA: 0.02mg-Mn/m3(R);
TWA: 0.1mg-Mn/m3(I) (CNS impair)
OSHA-PEL(Potassium permanganate)
STEL: C 5mg-Mn/m3
Exposure controls
Appropriate engineering controls
Do not use in areas without adequate ventilation.
Eye wash station should be available.
Washing facilities should be available.
Individual protection measures
Respiratory protection
Wear respiratory protection.
Hand protection
Wear protective gloves. Recommended material(s): neoprene, nitrile, butyl rubber, viton, PVC,
impermeable or chemical resistant rubber
Consult with your glove and/or personnel equipment manufacturer for selection ofappropriate compatible materials.
Eye protection
Wear safety glasses with side-shields or chemical safety goggle.
Wear eye/face protection.

9. Physical and Chemical Properties
Information on basic physical and chemical properties
Physical properties
Appearance: Liquid
Color: Dark purple
Odor data N.A.
pH data N.A.
Phase change temperature
Initial Boiling Point/Boiling point data N.A.
Melting point/Freezing point data N.A.
Decomposition temperature data N.A.
Flash point data N.A.
Auto-ignition temperature data N.A.
Explosive properties data N.A.
Vapor pressure data N.A.
Vapor density data N.A.
Specific gravity/Density data N.A.

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0.005mol/L Potassium permanganate solution,
JUNSEI CHEMICAL CO., LTD.,95278jis_J_E2-1,08/11/2018
Solubility
Solubility in water: Miscible
n-Octanol /water partition coefficient data N.A.

10. Stability and Reactivity
Chemical stability
Stable under normal storage/handling conditions.
Conditions to avoidHeat.
Hazardous decomposition products
Metal oxides.

11. Toxicological Information
Information on toxicological effects
Acute toxicity
Acute toxicity (Oral)[GHS Cat. Japan, base data](Potassium permanganate) rat LD50=379mg/kg (NITE primary risk assessment, 2008)
Labor standard law, Japan; Toxic
Potassium permanganate
Irritant properties
Skin corrosion/irritation[GHS Cat. Japan, base data](Potassium permanganate) highly corrosive (HSDB,Access on December 2014)
Serious eye damage /irritation[GHS Cat. Japan, base data](Potassium permanganate) highly corrosive (HSDB, Access on December 2014)No Allergenic and sensitizing effects data available
No Mutagenic effects data available
Carcinogenicity(Potassium permanganate)
ACGIH-A4(2012) : Not Classifiable as a Human Carcinogen (Inorganic Mn)
No reproductive toxicity data available
Delayed and immediate effects and also chronic effects from short- and long-term exposure
STOTSTOT-single exposure[cat.3(resp. irrit.)][Japan published data](Potassium permanganate) Respiratory tract irritation (PATTY 6th, 2012)
No Aspiration hazard data available
Additional data
There are no data available on the preparation itself.

12. Ecological Information
Ecotoxicity
Aquatic toxicity
Aquatic acute toxicity component(s) data
[GHS Cat. Japan, base data](Potassium permanganate)
Crustacea (Calanoida) LC50＝0.185mg/L/96hr (0.0765mg-Mn/L) (Preliminary Assessment ofEnvironmental Risks of Chemical Substances(MOE) vol.6, 2008)

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0.005mol/L Potassium permanganate solution,
JUNSEI CHEMICAL CO., LTD.,95278jis_J_E2-1,08/11/2018
Water solubility(Potassium permanganate) 6.4 g/100 ml (20℃) (ICSC, 2003)
No Persistence and degradability data available
Bioaccumulative potential(Potassium permanganate) BCF < 81 (Existing Chemical Safety Inspections Data)
Additional information
There are no data available on the preparation itself.

13. Disposal considerations
Waste treatment methods
Dispose of contents/container in accordance with local/national regulation.

14. Transport Information
UN No, UN CLASS
Not applicable to UN NO.

15. Regulatory Information
Safety, health and environmental regulations/legislation specific for the substance or mixture
US major regulations
TSCA
Potassium permanganate; Water
Other regulatory information
We are not able to check up the regulatory information in regard to the substances in yourcountry or region, therefore, we request this matter would be filled by your responsibility.
Regulatory information with regard to this substance in your country or in your region
should be examined by your own responsibility.
Ensure this material in compliance with federal requirements and ensure conformity to local
regulations.

16. Other information
Reference Book
Globally Harmonized System of classification and labelling of chemicals, (5th ed., 2013), UN
Recommendations on the TRANSPORT OF DANGEROUS GOODS 19th edit., 2015 UN
Classification, labelling and packaging of substances and mixtures (table3-1 ECNO6182012)2016 EMERGENCY RESPONSE GUIDEBOOK (US DOT)
2018 TLVs and BEIs. (ACGIH)
http://monographs.iarc.fr/ENG/Classification/index.php
Supplier's data/information
NITE Chemical Risk Information Platform（NITE-CHRIP）http://www.safe.nite.go.jp/japan/db.html
GHS Classification Guidance for Enterprises 2013 Revised Edition （Aug. 2013, METI)
General Disclaimer
This information contained in this data sheet represents the best information currently
available to us. However, no warranty is made with respect to its completeness and weassume no liability resulting from its use. It are advised to make their own tests todeterminate the safety and suitability of each such product or combination for their own
purposes.
The data given here is based on current knowledge and experience. The purpose of thisSafety Data Sheet is to describe the products in terms of their safety requirements. The
data does not signify any warranty with regard to the products' properties.

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0.005mol/L Potassium permanganate solution,
JUNSEI CHEMICAL CO., LTD.,95278jis_J_E2-1,08/11/2018
The GHS classification data given here is based on current Japan official data (NITE published in2017).