ÊÁÅÁ­Òå
2008-007

JAEA-Data/Code὇⚛㍑ߣ 10 ᐕ㑆ធߒߡ޿ߚ࿶❗ࡌࡦ࠻࠽ࠗ࠻ߩᄌ⾰᜼േ⺞ᩏᣣᧄේሶജ⎇ⓥ㐿⊒ᯏ᭴࿾ጀಣಽ⎇ⓥ㐿⊒ㇱ㐷 ࿾ጀಣಽၮ⋚⎇ⓥ㐿⊒࡙࠾࠶࠻㒻ጊ ᔘብ̪㧘਄㊁ ஜ৻㧗㧘╣ᧄ ᐢ㧗
(2008 ᐕ 1 ᦬ 16 ᣣฃℂ)࿶❗ࡌࡦ࠻࠽ࠗ࠻ਛߢߩ὇⚛㍑ߩ㐳ᦼ⊛ߥ⣣㘩᜼േ߅ࠃ߮ࡌࡦ࠻࠽ࠗ࠻ߩ㐳ᦼஜోᕈࠍ
⹏ଔߔࠆߚ߼㧘⓸⚛㔓࿐᳇ਅߦ߅޿ߡੱᎿᶏ᳓߅ࠃ߮ੱᎿ࿾ਅ᳓ࠍ↪޿㧘50͠߅ࠃ߮ 80͠
ߢߩ 10 ᐕ㑆ߦࠊߚࠆᶐẃ⹜㛎߇ⴕࠊࠇߚ‫⺞ᧄޕ‬ᩏߢߪ㧘ߎߩᶐẃ⹜㛎ᓟߩ࿶❗ࡌࡦ࠻࠽ࠗ࠻ࠍኻ⽎ߣߒ㧘㋕㧙ࡌࡦ࠻࠽ࠗ࠻⋧੕૞↪ߦࠃࠆࡌࡦ࠻࠽ࠗ࠻ߩᄌ⾰᜼േࠍ⺞ᩏߒߚ‫ޕ‬ߘߩ⚿ᨐࠍએਅߦ߹ߣ߼ࠆ‫ޕ‬࡮ੱᎿᶏ᳓߅ࠃ߮ੱᎿ࿾ਅ᳓ߦ߅ߌࠆ⹜㛎ᓟߩ࿶❗ࡌࡦ࠻࠽ࠗ࠻ࠍᲧセߒߚ႐ว㧘ੱᎿᶏ᳓ߦᶐẃߐࠇߡ޿ߚ⹜ᢱߢߪ㧘ੱᎿ࿾ਅ᳓ߩ႐วߦᲧߴߡ㧘὇⚛㍑ߩ⣣㘩ߦ઻޿↢ߓߚ㋕߇ࠃࠅ࿶❗ࡌࡦ࠻࠽ࠗ࠻ౝㇱߦ߹ߢ⒖ⴕߒߡ޿ߚ‫ޕ‬࡮ੱᎿᶏ᳓㧔80͠㧕ߦ߅ߌࠆ⹜㛎ᓟ⹜ᢱߩ TEM ⷰኤߢߪ㧘☼࿯㋶‛ߩ․ᓽߢ޽ࠆጀ⁁᭴ㅧ߇⏕⹺ߐࠇߚ‫ߚ߹ޕ‬㧘ጀ㑆ߪ⚂ 12[Å]ߢ޽ࠅ㧘ㅢᏱߩ 2㧦1 ဳࠬࡔࠢ࠲ࠗ࠻ߩጀ㑆ߣห᭽ߢ޽ߞߚ‫ޕ‬ᓥߞߡ㧘⹜㛎೨ᓟߢࠬࡔࠢ࠲ࠗ࠻ߦᄌൻߪ↢ߓߡ޿ߥ޿ߣផኤߐࠇߚ‫ޕ‬࡮⓸⚛㔓࿐᳇ਅߣᄢ᳇㔓࿐᳇ਅߢⴕࠊࠇߚ⹜㛎⚿ᨐࠍᲧセߔࠆߣ㧘⓸⚛㔓࿐᳇ਅߢߪ㧘὇⚛㍑ߩ⣣㘩ߦ઻޿↢ߓߚ㋕߇࿶❗ࡌࡦ࠻࠽ࠗ࠻ౝㇱߦ⒖ⴕߒߡ޿ࠆߩߦኻߒ㧘ᄢ᳇㔓࿐᳇ਅߢߪ㧘㋕ߪ߶ߣࠎߤ࿶❗ࡌࡦ࠻࠽ࠗ࠻ౝㇱߦ⒖ⴕߒߡ޿ߥ߆ߞߚ‫ޕ‬࡮EPMA ಽᨆߩ⚿ᨐ㧘࿶❗ࡌࡦ࠻࠽ࠗ࠻ਛߦ⒖ⴕߒߚ㋕ߩᦨᄢᷓߐߪ⚂ 0.2mm ߢ޽ߞߚ‫ޕ‬࡮㋕ߩ⒖ⴕ߇⹺߼ࠄࠇߚ࿶❗ࡌࡦ࠻࠽ࠗ࠻ࠍኻ⽎ߦ XRD ಽᨆࠍⴕߞߚ⚿ᨐ㧘࿶❗ࡌࡦ࠻࠽ࠗ࠻ਛߦߪ㋕ߩ⣣㘩↢ᚑ‛ߣផቯߐࠇࠆ߽ߩߪᬌ಴ߐࠇߥ߆ߞߚ‫ߚ߹ޕ‬㧘XRD ಽᨆ⚿ᨐ߆ࠄ㧘ࡌࡦ࠻࠽ࠗ࠻ਛߩ☼࿯㋶‛ߪ 2㧙౎㕙૕᭴ㅧࠍ␜ߒ㧘ߐࠄߦḨᐲ೙ᓮਅߢߩ᷹ቯߢߪ㧘Na ဳࠬࡔࠢ࠲ࠗ࠻ߣห᭽ߥ⤘Ảᕈࠍ␜ߒߚ‫ࠄ߆ߣߎߩࠄࠇߎޕ‬㧘⹜㛎೨ߩ Na ဳࠬࡔࠢ࠲ࠗ࠻ߪ㧘⹜㛎ᓟ߽ᄌൻߒߡ޿ߥ߆ߞߚߣផቯߐࠇߚ‫ޕ‬ߎࠇ߹ߢߦ㧘㋕౒ሽਅߢߩࡌࡦ࠻࠽ࠗ࠻ߩᄌ⾰᜼േࠍᛠីߔࠆߚ߼㧘᷷ᐲ㧘ṁᶧ᧦ઙ߅ࠃ߮⹜㛎ᦼ㑆╬ࠍᄌ߃㧘ࡃ࠶࠴♽ߢߩ⹜㛎ࠍታᣉߒߡ߈ߚ‫⚿ߩࠄࠇߘޕ‬ᨐߢߪ㧘ೋᦼߩ
Na ဳࠬࡔࠢ࠲ࠗ࠻ߩ Fe ဳൻ߿ᓸ㊂ߩ㕖⤘Ảᕈ☼࿯㋶‛߳ߩᄌൻ╬㧘૗ࠄ߆ߩᄌൻ߇⹺߼
ࠄࠇߚ‫ࠄ߇ߥߒ߆ߒޕ‬㧘੹࿁⺞ᩏࠍⴕߞߚ࿶❗♽ߢߩ⹜㛎ᓟ⹜ᢱߢߪ㧘࿶❗ࡌࡦ࠻࠽ࠗ࠻
߳ߩ㋕ߩ⒖ⴕߪ⏕⹺ߐࠇߚ߽ߩߩ㧘ೋᦼߩ Na ဳࠬࡔࠢ࠲ࠗ࠻ߦᄌൻߪ↢ߓߡ޿ߥ޿ߣផ
ቯߐࠇߚ‫ߡߞ߇ߚߒޕ‬㧘ಣಽⅣႺߩࠃ߁ߥ࿶❗♽ߦ߅ߌࠆ㋕㧙ࡌࡦ࠻࠽ࠗ࠻⋧੕૞↪ߦࠃࠆᓇ㗀ࠍ⹏ଔߔࠆ਄ߢߪ㧘ࡃ࠶࠴♽ߢߩ⹜㛎⚿ᨐࠍߘߩ߹߹ㆡ↪ߔࠆߩߢߪߥߊ㧘࿶❗♽ߢ↢ߕࠆ⃻⽎ࠍචಽߦℂ⸃ߒߚ਄ߢ⹏ଔߔࠆߎߣ߇㊀ⷐߢ޽ࠆ‫ޕ‬ᩭΆᢱࠨࠗࠢ࡞Ꮏቇ⎇ⓥᚲ(㚢࿷)㧦‫ޥ‬319-1194 ⨙ၔ⋵㇊⃗㇭᧲ᶏ᧛᧛᧻ 4-33
̪ ᛛⴚ㐿⊒දജຬ ᩭΆᢱࠨࠗࠢ࡞Ꮏቇ⎇ⓥᚲ ⅣႺᛛⴚ▤ℂㇱ ಣಽᛛⴚ⺖(౗ോ)
㧗 ᩭΆᢱࠨࠗࠢ࡞Ꮏቇ⎇ⓥᚲ ⅣႺᛛⴚ▤ℂㇱ ಣಽᛛⴚ⺖(౗ോ)
i
2008-007

JAEA-Data/CodeInvestigation of Alteration Behaviour of Compacted Bentonite Contactedwith Carbon Steel for 10 Years
Tadahiro SUYAMA̪, Kenichi UENO㧗 and Hiroshi SASAMOTO㧗
Geological Isolation Research Unit
Geological Isolation Research and Development Directorate
Japan Atomic Energy Agency
Tokai-mura, Naka-gun, Ibaraki-ken(Received January 16, 2008)
To evaluate long term behavior of corrosion for carbon steel in compacted bentonite,
and to evaluate long term stability of bentonite, corrosion experiments were conductedusing synthetic sea water and synthetic groundwater at 50 and 80͠ for 10 years
under anaerobic atmosphere. In the present study, the samples of compacted bentonite
after experiments were investigated to understand the alteration behavior of bentonite
by iron-bentonite interactions. Results were summarized below.
࡮Iron generated by corrosion of carbon steel was migrated into compacted bentonite
further in the synthetic seawater case than in the synthetic groundwater case.
࡮Result of TEM observation for the sample of synthetic sea water case at 80͠
showed that the original layer structure for clay minerals was maintained and thelayer distance was about 12[Å] which was similar to the layer distance of normal
2:1 smectite. Thus, it was suggested that there was no change in smectite before
and after experiments.
࡮Iron generated by corrosion of carbon steel was migrated into compacted bentonite
in anaerobic condition case but scarcely migrated in aerobic condition case.
࡮Results of EPMA analysis indicated that the maximum migration depth of iron incompacted bentonite was about 0.2 mm for sample in synthetic sea water at 80͠
under anaerobic condition.
࡮Results of XRD analysis for the sample in which iron migration in compacted
bentonite was observed showed that there was no corrosion product in compacted
bentonite and the structure of clay mineral in bentonite was di-octahedral.
Furthermore, the result of XRD analysis under relative humidity controlled
condition suggested that the swelling property of sample after experiment was
similar to that of initial Na-type smectite. Therefore, it was supposed that theinitial Na-type smectite did not change during the experiment.
Batch type experiments with different temperature, solutions and duration have been
conducted to understand the alteration behavior of bentonite by interactions with ironmaterial in our previous studies. According to the results of batch type experiments,
some changes like ion type change from Na to Fe type smectite and production of verysmall amount of non-swelling minerals etc. were identified after experiments. However,no change was identified for the present study using compacted bentonite, although
the iron migration in compacted bentonite was observed. In conclusion, in order toevaluate the iron-bentonte interactions in compacted system like repository conditions,
it would be important not to utilize directly the results by batch type experiments but
understand the phenomena which would be occurred in compacted bentonite.
Keywords : Iron-bentonite Interaction, Compacted Bentonite, Carbon Steel, Low
Oxygen Atmosphere, Alteration Behaviour, Smectite
̪Collaborating Engineer: Waste Management Department, Nuclear Fuel Cycle
Engineering Laboratories (Additional Post)+ Waste Management Department, Nuclear Fuel Cycle Engineering Laboratories(Additional Post)ii
⋡ᰴ
1. ߪߓ߼ߦ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 1
2. ⹜㛎ᣇᴺ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 1
2.1 ὇⚛㍑⹜㛎㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 1

2.2 ⹜㛎ṁᶧ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 2
2.3 ✭ⴣ᧚ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 2
2.4 㔓࿐᳇࡮⹜㛎᷷ᐲ࡮ᶐẃᦼ㑆 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 2
2.5 ᶐẃ⹜㛎ߩᚻ㗅 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 2
3. ⹜㛎⹜ᢱߩಽᨆᣇᴺ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 3
3.1 㓁ࠗࠝࡦ੤឵ኈ㊂ಽᨆ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 3
3.2 ࠬࡔࠢ࠲ࠗ࠻ጀ㑆㓁ࠗࠝࡦಽᨆ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 4
3.3 SEM㧛EDS ಽᨆ߅ࠃ߮ TEM㧛EDS ಽᨆ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 4
3.3.1 SEM㧛EDS ಽᨆ೨ಣℂ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 4
3.3.2 TEM㧛EDS ಽᨆ೨ಣℂ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 4
3.4 EPMA ಽᨆ㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 5
3.5 X ✢࿁᛬ಽᨆ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 5
3.5.1 ਇቯᣇ૏ಽᨆ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 5
3.5.2 ቯᣇ૏ಽᨆ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 5
3.5.3 Ḩᐲ೙ᓮ᧦ઙਅߢߩቯᣇ૏ಽᨆ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 5
3.5.4 ࠛ࠴࡟ࡦࠣ࡝ࠦ࡯࡞ಣℂቯᣇ૏ಽᨆ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 5
4. ⚿ᨐ߅ࠃ߮⠨ኤ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 6
4.1 ⹜ᢱߩᄖⷰ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 6
4.2 ᶐẃṁᶧಽᨆ⚿ᨐ߅ࠃ߮⠨ኤ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 6
4.3 㓁ࠗࠝࡦ੤឵ኈ㊂ಽᨆ⚿ᨐߣࠬࡔࠢ࠲ࠗ࠻ጀ㑆㓁ࠗࠝࡦಽᨆ⚿ᨐ߅ࠃ߮⠨ኤ 㨯㨯㨯 6
4.3.1 㓁ࠗࠝࡦ੤឵ኈ㊂ಽᨆ⚿ᨐ߅ࠃ߮⠨ኤ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 6
4.3.2 ࠬࡔࠢ࠲ࠗ࠻ጀ㑆㓁ࠗࠝࡦಽᨆ⚿ᨐ߅ࠃ߮⠨ኤ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 7
4.4 SEM㧛EDS ಽᨆ߅ࠃ߮ TEM㧛EDS ಽᨆ⚿ᨐ߅ࠃ߮⠨ኤ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 7
4.4.1 SEM㧛EDS ಽᨆ⚿ᨐ߅ࠃ߮⠨ኤ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 7
4.4.2 TEM㧛EDS ಽᨆ⚿ᨐ߅ࠃ߮⠨ኤ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 7
4.5 EPMA ಽᨆ⚿ᨐ߅ࠃ߮⠨ኤ㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 8
4.6 X ✢࿁᛬ಽᨆ⚿ᨐ߅ࠃ߮⠨ኤ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 8
4.6.1 ਇቯᣇ૏ಽᨆ⚿ᨐ߅ࠃ߮⠨ኤ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 8
4.6.2 ቯᣇ૏ಽᨆ⚿ᨐ߅ࠃ߮⠨ኤ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 9
4.6.3 Ḩᐲ೙ᓮ᧦ઙਅߢߩቯᣇ૏ಽᨆ⚿ᨐ߅ࠃ߮⠨ኤ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 9
4.6.4 ࠛ࠴࡟ࡦࠣ࡝ࠦ࡯࡞ಣℂቯᣇ૏ಽᨆ⚿ᨐ߅ࠃ߮⠨ኤ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 9
5. ߅ࠊࠅߦ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 9iii⻢ㄉ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 10ෳ⠨ᢥ₂ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 11iv


Contents
1. Introduction 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 1
2. Experimental methods 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 1
2.1 Carbon steel coupons㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 1
2.2 Tests Solution 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 2
2.3 Bentonite buffer 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 2
2.4 Atmosphere࡮Temperature࡮Saturation period 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 2
2.5 Procedure of saturation experiments 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 2
3. Analytical items 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 3
3.1 Cation exchange capacity analysis㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 3
3.2 Smectite inter-layer cation analysis 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 4
3.3 Scanning electron microscopy/energy dispersive X-ray spectrometer (SEM㧛EDS) analysis and Transmission electron microscopy/energy dispersive X-ray
spectrometer (TEM/EDS) analysis 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 4
3.3.1 SEM㧛EDS analysis㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 4
3.3.2 TEM/EDS analysis 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 4
3.4 Electron probe micro analysis (EPMA) 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 5
3.5 X-ray diffraction (XRD) analysis 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 5
3.5.1 Analysis of random sample 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 5
3.5.2 Analysis of oriented sample 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 5
3.5.3 Analysis of oriented sample under humidity controlled conditions 㨯㨯㨯㨯㨯㨯㨯 5
3.5.4 Analysis of oriented sample by ethylene glycol treatment 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 5
4. Results and discussions 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 6
4.1 Appearance of sample 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 6
4.2 Result and discussion of saturated solution analysis 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 6
4.3 Result and discussion of cation exchange capacity and inter-layer exchangeable
cation analysis 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 6
4.3.1 Result and discussion of cation exchange capacity analysis 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 6
4.3.2 Result and discussion of inter-layer exchangeable cation analysis 㨯㨯㨯㨯㨯㨯㨯㨯 7
4.4 Result and discussion of sample surface analysis 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 7
4.4.1 Scanning electron microscopy/energy dispersive X-ray spectrometer (SEM㧛EDS) analysis 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 7
4.4.2 Transmission electron microscopy/energy dispersive X-ray spectrometer(TEM/EDS) analysis 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 7
4.5 Result and discussion of electron probe micro analysis 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 8
4.6 Result and discussion of X-ray diffraction (XRD) analysis 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 8v


4.6.1 Result and discussion of random sample analysis 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 8
4.6.2 Result and discussion of oriented sample analysis 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 9
4.6.3 Result and discussion of oriented sample analysis under humidity controlled
conditions 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 9
4.6.4 Result and discussion of oriented sample by ethylene glycol treatment
analysis 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 9
5. Conclusions 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 9
Acknowledgement㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 10
References 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 11vi
⴫⋡ᰴ
⴫ 2.1㧦὇⚛㍑⹜㛎ߩൻቇ⚵ᚑ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 12

⴫ 2.2㧦⹜㛎ߦ↪޿ߚṁᶧߩ⚵ᚑ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 12
⴫ 2.4㧦⹜㛎᧦ઙ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 12
⴫ 4.2㧦ᶐẃṁᶧಽᨆ⚿ᨐ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 13
⴫ 4.3.1㧙1㧦㓁ࠗࠝࡦ੤឵ኈ㊂߅ࠃ߮ᶐ಴㓁ࠗࠝࡦಽᨆ⚿ᨐ(ᧂᄌ⾰ㇱ) 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 13
⴫ 4.3.1㧙2㧦࿕⋧ߩൻቇ⚵ᚑ(ᧂᄌ⾰ㇱ) 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 13
⴫ 4.3.2㧦ጀ㑆㓁ࠗࠝࡦಽᨆ⚿ᨐ(ᧂᄌ⾰ㇱ) 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 14࿑⋡ᰴ
࿑ 2.5㧙1㧦✭ⴣ᧚ਛߦ߅ߌࠆ὇⚛㍑ߩᶐẃ⹜㛎ࠞ࡜ࡓߩᮨᑼ࿑ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 15
࿑ 2.5㧙2㧦✭ⴣ᧚ਛߦ߅ߌࠆ὇⚛㍑ߩᶐẃ⹜㛎ᣇᴺߩᮨᑼ࿑ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 15
࿑ 2.5㧙3㧦⹜㛎ో૕ߩࡈࡠ࡯ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 16
࿑ 3.1㧦㓁ࠗࠝࡦ੤឵ኈ㊂ಽᨆⵝ⟎⇛࿑ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 16
࿑ 4.4.1㧙1㧦SW㧙80͠⹜ᢱߩ SEM㧛EDS ಽᨆ⚿ᨐ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 17
࿑ 4.4.1㧙2㧦SW㧙50͠⹜ᢱߩ SEM㧛EDS ಽᨆ⚿ᨐ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 17
࿑ 4.4.1㧙3㧦GW㧙1㧙80͠⹜ᢱߩ SEM㧛EDS ಽᨆ⚿ᨐ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 17
࿑ 4.4.1㧙4㧦GW㧙2㧙80͠⹜ᢱߩ SEM㧛EDS ಽᨆ⚿ᨐ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 18
࿑ 4.4.1㧙5㧦SW㧙80͠ᄢ᳇᧦ઙ⹜ᢱߩ SEM㧛EDS ಽᨆ⚿ᨐ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 18
࿑ 4.4.1㧙6㧦SW㧙80͠ Kunipia㧙F ⹜ᢱߩ SEM㧛EDS ಽᨆ⚿ᨐ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 18
࿑ 4.4.2㧦SW㧙80͠⹜ᢱߩ TEM㧛EDS ಽᨆ⚿ᨐ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 19
࿑ 4.5㧙1㧦EPMA ߦࠃࠆ SW㧙80͠⹜ᢱߩᢿ㕙㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 20
࿑ 4.5㧙2㧦EPMA ߦࠃࠆ SW㧙80͠⹜ᢱߩࡑ࠶ࡇࡦࠣಽᏓ㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 20
࿑ 4.5㧙3㧦EPMA ߦࠃࠆ GW㧙1㧙80͠⹜ᢱߩᢿ㕙 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 21
࿑ 4.5㧙4㧦EPMA ߦࠃࠆ GW㧙1㧙80͠⹜ᢱߩࡑ࠶ࡇࡦࠣಽᏓ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 21
࿑ 4.5㧙5㧦EPMA ߦࠃࠆ SW㧙80͠ᄢ᳇᧦ઙ⹜ᢱߩᢿ㕙㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 22
࿑ 4.5㧙6㧦EPMA ߦࠃࠆ SW㧙80͠ᄢ᳇᧦ઙ⹜ᢱߩࡑ࠶ࡇࡦࠣಽᏓ㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 22
࿑ 4.6.1㧙1㧦SW㧙80͠ᄌ⾰ㇱ⹜ᢱߩਇቯᣇ૏᷹ቯ⚿ᨐ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 23
࿑ 4.6.1㧙2㧦SW㧙80͠ᧂᄌ⾰ㇱ⹜ᢱߩਇቯᣇ૏᷹ቯ⚿ᨐ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 23
࿑ 4.6.1㧙3㧦SW㧙50͠ᄌ⾰ㇱ⹜ᢱߩਇቯᣇ૏᷹ቯ⚿ᨐ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 24
࿑ 4.6.1㧙4㧦SW㧙50͠ᧂᄌ⾰ㇱ⹜ᢱߩਇቯᣇ૏᷹ቯ⚿ᨐ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 24
࿑ 4.6.1㧙5㧦GW㧙1㧙80͠ᄌ⾰ㇱ⹜ᢱߩਇቯᣇ૏᷹ቯ⚿ᨐ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 25
࿑ 4.6.1㧙6㧦GW㧙1㧙80͠ᧂᄌ⾰ㇱ⹜ᢱߩਇቯᣇ૏᷹ቯ⚿ᨐ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 25
࿑ 4.6.1㧙7㧦GW㧙2㧙80͠ᄌ⾰ㇱ⹜ᢱߩਇቯᣇ૏᷹ቯ⚿ᨐ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 26
࿑ 4.6.1㧙8㧦GW㧙2㧙80͠ᧂᄌ⾰ㇱ⹜ᢱߩਇቯᣇ૏᷹ቯ⚿ᨐ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 26vii
࿑ 4.6.1㧙9㧦SW㧙80͠ᄢ᳇᧦ઙᄌ⾰ㇱ⹜ᢱߩਇቯᣇ૏᷹ቯ⚿ᨐ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 27
࿑ 4.6.1㧙10㧦SW㧙80͠ᄢ᳇᧦ઙᧂᄌ⾰ㇱ⹜ᢱߩਇቯᣇ૏᷹ቯ⚿ᨐ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 27
࿑ 4.6.1㧙11㧦SW㧙80͠ Kunipia㧙F ᄌ⾰ㇱ⹜ᢱߩਇቯᣇ૏᷹ቯ⚿ᨐ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 28
࿑ 4.6.1㧙12㧦SW㧙80͠ Kunipia㧙F ᧂᄌ⾰ㇱ⹜ᢱߩਇቯᣇ૏᷹ቯ⚿ᨐ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 28
࿑ 4.6.2㧙1㧦SW㧙80͠⹜ᢱߩቯᣇ૏᷹ቯ⚿ᨐ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 29
࿑ 4.6.2㧙2㧦SW㧙50͠⹜ᢱߩቯᣇ૏᷹ቯ⚿ᨐ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 29
࿑ 4.6.2㧙3㧦GW㧙1㧙80͠⹜ᢱߩቯᣇ૏᷹ቯ⚿ᨐ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 29
࿑ 4.6.2㧙4㧦GW㧙2㧙80͠⹜ᢱߩቯᣇ૏᷹ቯ⚿ᨐ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 30
࿑ 4.6.2㧙5㧦SW㧙80͠ᄢ᳇᧦ઙ⹜ᢱߩቯᣇ૏᷹ቯ⚿ᨐ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 30
࿑ 4.6.2㧙6㧦SW㧙80͠ Kunipia㧙F ⹜ᢱߩቯᣇ૏᷹ቯ⚿ᨐ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 30
࿑ 4.6.3㧙1㧦SW㧙80͠ᄌ⾰ㇱ⹜ᢱߩḨᐲ೙ᓮ᷹ቯ⚿ᨐߣ⋧ኻḨᐲߦኻߔࠆ d(001)ᐩ㕙㑆㓒ߩᄌൻ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 31
࿑ 4.6.3㧙2㧦SW㧙80͠ᧂᄌ⾰ㇱ⹜ᢱߩḨᐲ೙ᓮ᷹ቯ⚿ᨐߣ⋧ኻḨᐲߦኻߔࠆ d(001)ᐩ㕙㑆㓒ߩᄌൻ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 31
࿑ 4.6.3㧙3㧦SW㧙50͠ᄌ⾰ㇱ⹜ᢱߩḨᐲ೙ᓮ᷹ቯ⚿ᨐߣ⋧ኻḨᐲߦኻߔࠆ d(001)ᐩ㕙㑆㓒ߩᄌൻ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 32
࿑ 4.6.3㧙4㧦SW㧙50͠ᧂᄌ⾰ㇱ⹜ᢱߩḨᐲ೙ᓮ᷹ቯ⚿ᨐߣ⋧ኻḨᐲߦኻߔࠆ d(001)ᐩ㕙㑆㓒ߩᄌൻ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 32
࿑ 4.6.3㧙5㧦GW㧙1㧙80͠ᄌ⾰ㇱ⹜ᢱߩḨᐲ೙ᓮ᷹ቯ⚿ᨐߣ⋧ኻḨᐲߦኻߔࠆ d(001)ᐩ㕙㑆㓒ߩᄌൻ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 33
࿑ 4.6.3㧙6㧦GW㧙1㧙80͠ᧂᄌ⾰ㇱ⹜ᢱߩḨᐲ೙ᓮ᷹ቯ⚿ᨐߣ⋧ኻḨᐲߦኻߔࠆ d(001)ᐩ㕙㑆㓒ߩᄌൻ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 33
࿑ 4.6.3㧙7㧦GW㧙2㧙80͠ᄌ⾰ㇱ⹜ᢱߩḨᐲ೙ᓮ᷹ቯ⚿ᨐߣ⋧ኻḨᐲߦኻߔࠆ d(001)ᐩ㕙㑆㓒ߩᄌൻ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 34
࿑ 4.6.3㧙8㧦GW㧙2㧙80͠ᧂᄌ⾰ㇱ⹜ᢱߩḨᐲ೙ᓮ᷹ቯ⚿ᨐߣ⋧ኻḨᐲߦኻߔࠆ d(001)ᐩ㕙㑆㓒ߩᄌൻ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 34
࿑ 4.6.3㧙9㧦SW㧙80͠ᄢ᳇᧦ઙᄌ⾰ㇱ⹜ᢱߩḨᐲ೙ᓮ᷹ቯ⚿ᨐߣ⋧ኻḨᐲߦኻߔࠆ d(001)ᐩ㕙㑆㓒ߩᄌൻ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 35
࿑ 4.6.3㧙10㧦SW㧙80͠ᄢ᳇᧦ઙᧂᄌ⾰ㇱ⹜ᢱߩḨᐲ೙ᓮ᷹ቯ⚿ᨐߣ⋧ኻḨᐲߦኻߔࠆ d(001)ᐩ㕙㑆㓒ߩᄌൻ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 35
࿑ 4.6.3㧙11㧦SW㧙80͠ Kunipia㧙F ᄌ⾰ㇱ⹜ᢱߩḨᐲ೙ᓮ᷹ቯ⚿ᨐߣ⋧ኻḨᐲߦኻߔࠆ d(001)ᐩ㕙㑆㓒ߩᄌൻ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 36
࿑ 4.6.3㧙12㧦SW㧙80͠ Kunipia㧙F ᧂᄌ⾰ㇱ⹜ᢱߩḨᐲ೙ᓮ᷹ቯ⚿ᨐߣ⋧ኻḨᐲߦኻߔࠆ d(001)ᐩ㕙㑆㓒ߩᄌൻ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 36
࿑ 4.6.4㧙1㧦SW㧙80͠⹜ᢱߩ EG ಣℂቯᣇ૏᷹ቯ⚿ᨐ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 37
࿑ 4.6.4㧙2㧦SW㧙50͠⹜ᢱߩ EG ಣℂቯᣇ૏᷹ቯ⚿ᨐ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 37
࿑ 4.6.4㧙3㧦GW㧙1㧙80͠⹜ᢱߩ EG ಣℂቯᣇ૏᷹ቯ⚿ᨐ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 37
࿑ 4.6.4㧙4㧦GW㧙2㧙80͠⹜ᢱߩ EG ಣℂቯᣇ૏᷹ቯ⚿ᨐ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 38
࿑ 4.6.4㧙5㧦SW㧙80͠ᄢ᳇᧦ઙ⹜ᢱߩ EG ಣℂቯᣇ૏᷹ቯ⚿ᨐ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 38

viii




࿑ 4.6.4㧙6㧦SW㧙80͠ Kunipia㧙F ⹜ᢱߩ EG ಣℂቯᣇ૏᷹ቯ⚿ᨐ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 38౮⌀⋡ᰴ౮⌀ 4.1㧦⹜ᢱណขᤨߩ↹௝ 㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯 39ix

    


1. ߪߓ߼ߦ
㜞࡟ࡌ࡞᡼኿ᕈᑄ᫈‛ߩ࿾ጀಣಽࠪࠬ࠹ࡓߦ߅޿ߡߪ㧘ੱᎿࡃ࡝ࠕ᧚ߩ᭴ᚑⷐ⚛ߣߒߡࠝ࡯ࡃ࡯ࡄ࠶ࠢ㧔὇⚛㍑㧧㋕㧕ߣ✭ⴣ᧚㧔ࡌࡦ࠻࠽ࠗ࠻㧧ࠬࡔࠢ࠲ࠗ࠻ࠍਥᚑಽߣߔࠆ☼࿯㧕߇↪޿ࠄࠇࠆ 1)‫ޕ‬᡼኿ᕈᑄ᫈‛ߩಣಽᓟ㧘✭ⴣ᧚߇࿾ਅ᳓ߢ㘻๺ߒ㧘὇⚛㍑ࠝ࡯ࡃ࡯ࡄ
࠶ࠢ߇⣣㘩ߒߚ႐ว㧘ࠝ࡯ࡃ࡯ࡄ࠶ࠢ⣣㘩↢ᚑ‛ߣ✭ⴣ᧚ߣߩ⋧੕૞↪ߦࠃߞߡ✭ⴣ᧚ߩᕈ⾰߇ᄌൻߔࠆน⢻ᕈ߇޽ࠆ‫ޕ‬㋕ߣࡌࡦ࠻࠽ࠗ࠻ߩ⋧੕૞↪ߦ઻߁ࡌࡦ࠻࠽ࠗ࠻ߩᄌൻߦ
㑐ߒߡߪ㧘ߎࠇ߹ߢߦᄙᢙߩ⹜㛎߇ⴕࠊࠇߡ߅ࠅ㧘ⅣႺ᧦ઙ㧔᷷ᐲ㧘ᦼ㑆㧘ṁᶧ᧦ઙߥߤ㧕ߦࠃࠅᄌ⾰᜼േ߇⇣ߥࠆߎߣ߇ࠊ߆ߞߡ޿ࠆ 2)‫ߚ߹ޕ‬ᣢᓔߩ⎇ⓥߦࠃࠅ㧘ಣಽⅣႺߦ㘃ૃߒߚ᧦ઙߢߩᄌ⾰᜼േߣߒߡߪ㧘ࠬࡔࠢ࠲ࠗ࠻ߩጀ㑆ࠗࠝࡦߩࠗࠝࡦ੤឵ߦࠃࠆ Fe ဳൻ߇ਥⷐߥ⃻⽎ߢ޽ࠆߣᗐቯߐࠇߡ޿ࠆ 3)‫߃߹〯ࠍࠄࠇߎޕ‬㧘㋕౒ሽਅߢߩ✭ⴣ᧚ߩ㐳ᦼ⊛ߥᄌ⾰᜼േࠍᛠីߔࠆߚ߼㧘ߎࠇ߹ߢߦടㅦ⹜㛎ߣߒߡ㧘Fe ဳൻࠬࡔࠢ࠲ࠗ࠻ࠍ಴⊒‛⾰ߣߒ㧘㜞᷷ߢߩࡃ࠶࠴⹜㛎ࠍታᣉߒߡ߈ߚ‫⚿ߩߘޕ‬ᨐ㧘250͠ߢ 6 ࡩ᦬㑆㕒⟎ߒߚ⹜ᢱߢߪᓸ㊂ߩ㕖⤘Ảᕈ☼࿯㋶‛߇↢ᚑߒߚ߇ᄢㇱಽߪࠬࡔࠢ࠲ࠗ࠻ጀ㑆ߩ㓁ࠗࠝࡦ੤឵ߦ⇐߹ࠅ㧘ᄢ߈ߥࠬࡔࠢ࠲ࠗ࠻᭴ㅧߩᄌൻ߿⤘Ảᕈ⢻╬ߩ․ᕈߩᄌൻߪ⿠߈ߡ޿ߥ޿ 4)‫ ޕ‬150͠ߢߩ⹜ᢱ
ߢߪ 1 ଔߩ㓁ࠗࠝࡦ߇ጀ㑆ߦሽ࿷ߔࠆ⤘Ảㆊ⒟ߣ߽ 2 ଔߩ㓁ࠗࠝࡦ߇ጀ㑆ߦሽ࿷ߔࠆ⤘Ả
ㆊ⒟ߣ߽ᄙዋ⇣ߥߞߚ⤘Ảㆊ⒟ࠍ␜ߒߚ߇ࠬࡔࠢ࠲ࠗ࠻ߩ᭴ㅧߩᄌൻ߿⤘Ảᕈ⢻╬ߩ․ᕈ
ߩᄌൻߪ⿠߈ߡ޿ߥ޿ 5)‫ޕ‬ߎࠇ߹ߢߦታᣉߒߡ߈ߚ਄⸥ߩ⹜㛎ߪࡃ࠶࠴♽ߢ޽ࠅ㧘㋕ߣࡌࡦ࠻࠽ࠗ࠻ߩ⋧੕૞↪ߦࠃࠅߤߩࠃ߁ߥ⃻⽎߇↢ߓᓧࠆ߆㧘ߘߩ⊒↢ߩⷐ࿃߿⊒↢ߒߚ႐วߩ㐳ᦼ⊛ߥ᜼േࠍቯᕈ
⊛ߦᛠីߔࠆߎߣࠍ⋡⊛ߣߒߡ޿ߚ‫߼ߚߩߘޕ‬㧘ಣಽⅣႺߦᲧߴࠆߣ㜞᷷ߥ᧦ઙ߿࿕ᶧᲧ
ߩዊߐ޿᧦ઙߢߩ⹜㛎࠺࡯࠲ߢ޽ࠅ㧘ᗐቯߐࠇࠆಣಽⅣႺߣߪ⇣ߥࠆ᧦ઙߩ࠺࡯࠲߽฽߹
ࠇࠆߎߣ߆ࠄ㧘ߎࠇࠄߩ࠺࡯࠲ࠍߘߩ߹߹ಣಽⅣႺߢߩᄌ⾰⃻⽎ߣߒߡ⠨ᘦߒߡ⦟޿߆ߤ
߁߆⏕⹺ߔࠆߎߣ߇ᔅⷐߢ޽ࠆ‫ࠅࠃޕ‬ಣಽⅣႺߦ㘃ૃߒߚ᧦ઙߢߩቯ㊂⊛ߥ࠺࡯࠲ࠍᓧࠆ
ߦߪ㧘࿶❗♽ߢߩ὇⚛㍑౒ሽਅߦ߅ߌࠆࡌࡦ࠻࠽ࠗ࠻ߩᄌ⾰᜼േߦ㑐ߔࠆ࠺࡯࠲߇㊀ⷐߢ޽ࠆ‫ޕ‬੹࿁㧘࿶❗ࡌࡦ࠻࠽ࠗ࠻ਛߢߩ὇⚛㍑ߩ㐳ᦼ⊛ߥ⣣㘩᜼േࠍᛠីߒ૬ߖߡࡌࡦ࠻࠽ࠗ࠻
ߩ㐳ᦼஜోᕈࠍ⺞ߴࠆߚ߼㧘10 ᐕ㑆㧘⓸⚛㔓࿐᳇ਅߢᶐẃߐࠇߚ὇⚛㍑⹜㛎 ߩขࠅ಴ߒ
߇ⴕࠊࠇߚ 6)‫⺞ᧄޕ‬ᩏߢߪ㧘ߎߩᶐẃ⹜㛎ᓟߩ࿶❗ࡌࡦ࠻࠽ࠗ࠻ࠍኻ⽎ߦ‛ℂ⊛߅ࠃ߮ൻቇ
⊛․ᕈߩᄌൻߩ᦭ήߦߟ޿ߡ⹦⚦ߥ⺞ᩏࠍታᣉߒߚߩߢ㧘ߘߩ⚿ᨐࠍႎ๔ߔࠆ‫ޕ‬
2. ⹜㛎ᣇᴺ⹜㛎ᣇᴺߪ὇⚛㍑⣣㘩ᶐẃ⹜㛎 6)ߢ⹦⚦ߦ⸥ㅀߐࠇߡ߅ࠅ㧘ߎߩ▵ߦ߅޿ߡߪ⹜㛎ᣇᴺߩ᭎⇛ࠍ⸥ㅀߔࠆ‫ޕ‬
2.1 ὇⚛㍑⹜㛎 ὇⚛㍑⹜㛎 ߣߒߡ㧘SM400B ࠍ↪޿ߚ‫ߩߘޕ‬ൻቇ⚵ᚑࠍ⴫ 2.1 ߦ␜ߔ‫⹜ޕ‬㛎 ߩᒻ⁁

1

 


ߪ 30302mm ߩᐔ᧼ဳߣߒߚ‫ޕ‬ ⹜㛎 ߩ⴫㕙ߪࠛࡔ࡝࡯#800 ߩḨᑼ⎇⏴ߦࠃࠅ઀਄ߍ㧘ࠕ࠮࠻ࡦߢ⣕⢽ᓟ㧘⫳⇐᳓ߢᵞᵺߒ㧘ੇ῎ߐߖߚ‫ޕ‬
2.2 ⹜㛎ṁᶧ⹜㛎ṁᶧߣߒߡ㧘એਅߩ 3 ⒳㘃ߩ᳓ṁᶧࠍ↪޿ߚ‫ߩࠇߙࠇߘޕ‬ṁᶧ⚵ᚑࠍ⴫ 2.2 ߦ␜ߔ‫ޕ‬࡮ੱᎿᶏ᳓(SW㧘pH=7.9㨪8.4)
࡮ੱᎿ࿾ਅ᳓㧙1(GW㧙1㧘㜞὇㉄Ⴎ᳓ṁᶧ㧘0.1M㧙NaHCO3㧘pH=8.7)
࡮ੱᎿ࿾ਅ᳓㧙2(GW㧙2㧘ૐ὇㉄Ⴎ㧙ૐႮൻ‛᳓ṁᶧ㧘2.5mM㧙NaHCO3+2.5mM㧙NaCl㧘
pH=9.1㨪9.2)
2.3 ✭ⴣ᧚ ✭ⴣ᧚ߣߒߡએਅߦ␜ߔࠃ߁ߦ╙ 1 ᰴขࠅ߹ߣ߼ 7)ߦ߅ߌࠆ✭ⴣ᧚઀᭽ࠍᗐቯߒߚ߽ߩ
ࠍ↪޿ߚ‫ ╙ޕ‬1 ᰴขࠅ߹ߣ߼✭ⴣ᧚઀᭽ߦ߅޿ߡߪੇ῎ኒᐲ 1.8[Mg/m3]㧘100%ࠢ࠾ࠥ࡞V1 ߣߒߚ‫ޕ‬߹ߚ㧘Ყセߣߒߡੇ῎ኒᐲ 1.8[Mg/m3]㧘100%ࠢ࠾ࡇࠕ F ߦߟ޿ߡ߽⹜㛎ࠍⴕߞߚ‫ޕ‬
2.4 㔓࿐᳇࡮⹜㛎᷷ᐲ࡮ᶐẃᦼ㑆 ᶐẃ⹜㛎ߪ᳇⋧ㇱ㉄⚛Ớᐲ 1ppm એਅߦ೙ᓮߒߚ⓸⚛㔓࿐᳇ߩࠣࡠ࡯ࡉࡏ࠶ࠢࠬઃዻߩ
ᕡ᷷ᮏਛߢⴕߞߚ‫⹜ޕ‬㛎᷷ᐲߪ 80͠߅ࠃ߮ 50͠ߣߒߚ‫ߚ߹ޕ‬㧘㔓࿐᳇ߦࠃࠆ㆑޿ࠍ⏕⹺ߔࠆߚ߼㧘ᄢ᳇㔓࿐᳇ߢߩ⹜㛎߽ⴕߞߚ‫ޕ‬ᶐẃᦼ㑆ߪ 10 ᐕߣߒߚ‫ޕ‬ એ਄ߩ⹜㛎᧦ઙࠍ⴫ 2.4 ߦ߹ߣ߼ߚ‫ޕ‬
2.5 ᶐẃ⹜㛎ߩᚻ㗅Ԙ⹜㛎೨ߦ⹜㛎 ߩ㊀㊂ߩ᷹ቯࠍⴕ߁‫ߩߘޕ‬ᓟ㧘࿑ 2.5㧙㧝ߦ␜ߔࠃ߁ߦ࠴࠲ࡦࠞ࡜ࡓౝߦ
✭ⴣ᧚ߣ⹜㛎

ࠍ౉ࠇߡ㧘࿶ኒߒߚᓟߦࠞ࡜ࡓߩ⬄ࠍࡏ࡞࠻ߢ✦߼ߟߌߚ‫ޕ‬ԙ⹜㛎ࠞ࡜ࡓࠍ㔓࿐᳇೙ᓮࠣࡠ࡯ࡉࡏ࠶ࠢࠬߦ៝౉ߒߡ㧘⌀ⓨᒁ߈ߣ⓸⚛⟎឵ࠍ 3 ࿁એ਄➅ࠅ㄰ߒߚ‫⌀ߦᦝޕ‬ⓨਛߦ⚂ 24 ᤨ㑆଻ᜬߒߚᓟ㧘ౣ߮⓸⚛⟎឵ߔࠆ‫⹜ޕ‬㛎ṁᶧߪหߓࠣ
ࡠ࡯ࡉࡏ࠶ࠢࠬਛߢࡏ࠶ࠢࠬౝߩࠟࠬࠍ 24 ᤨ㑆એ਄ㅢ᳇ߒߡ⣕᳇ߒߚ‫ޕ‬
Ԛ࿑ 2.5㧙2 ߦ␜ߔࠃ߁ߦ࠴࠲ࡦࠞ࡜ࡓߣ⹜㛎ṁᶧࠍ࠹ࡈࡠࡦ⵾ߩኈེߦ౉ࠇߡ㧘ߎߩኈེࠍࠣࡠ࡯ࡉࡏ࠶ࠢࠬਛߩᕡ᷷ᮏౝߦᚲቯᦼ㑆(੹࿁ߪ 10 ᐕ㑆)㕒⟎ߒߚ‫ޕ‬ԛᶐẃᦼ㑆ᓟ㧘࠴࠲ࡦࠞ࡜ࡓࠍ⸃૕ߒߡ⹜㛎Ԝಽഀߒߚࡌࡦ࠻࠽ࠗ࠻ߩ⹜㛎ߣࡌࡦ࠻࠽ࠗ࠻ࠍಽഀߒߚ‫ޕ‬ធ⸅㕙ㄭறࠍ೥ࠅขߞߚ‫ޕ‬ԝࡌࡦ࠻࠽ࠗ࠻⹜ᢱߦኻߒߡએਅ(╙ 3 ▵)ߦ␜ߔಽᨆ㗄⋡ࠍታᣉߒߚ‫ޕ‬ߎࠇࠄߩࡈࠜࡠ࡯࿑ࠍ࿑ 2.5㧙3 ߦ␜ߔ‫ޕ‬

2

 


3. ⹜㛎⹜ᢱߩಽᨆᣇᴺ
ᶐẃᦼ㑆㧔10 ᐕ㑆㧕㕒⟎ᓟ㧘࠴࠲ࡦࠞ࡜ࡓࠍ⸃૕ߒ㧘὇⚛㍑⹜㛎 ធ⸅㕙ㄭறㇱߩࡌࡦ࠻࠽ࠗ࠻࿕⋧ಽᨆߦࠃࠅ㧘ࡌࡦ࠻࠽ࠗ࠻ߩᄌൻߩ᦭ήࠍᛠីߒ㧘ᄌൻ߇⹺߼ࠄࠇߚ႐ว㧘ᣂߚߦ↢ߓߚ࿕⋧㧔⣣㘩↢ᚑ‛߅ࠃ߮ᄌ⾰↢ᚑ‛㧕ࠍหቯߒߚ‫ޕ‬
3.1 㓁ࠗࠝࡦ੤឵ኈ㊂ಽᨆ㓁ࠗࠝࡦ੤឵ኈ㊂(CEC)ߩ᷹ቯߦߪ㧘ᣣᧄࡌࡦ࠻࠽ࠗ࠻ᎿᬺળᮡḰ⹜㛎ᣇᴺ JBAS㧙106㧙778)ߦᓥߞߚ‫ޕ‬એਅߦᚻ㗅ࠍ␜ߔ‫⇛ߩ⟎ⵝޕ‬࿑ࠍ࿑ 3.1 ߦ␜ߔ‫ޕ‬Ԙ⹜ᢱߣᷙߗวࠊߖࠆᶏ⍾ߩߏߺ߿Ⴎ⚛ࠗࠝࡦࠍ㒰෰ߔࠆߚ߼㧘⣕ࠗࠝࡦ᳓ߢ 5㨪6 ࿁⒟ᐲ
ᵞᵺߒߚ‫ޕ‬6N ߩႮ㉄ࠍട߃ߡ⚂ 1 ᤨ㑆ᾚᴣߒߚ‫ޕ‬಄ළᓟ㧘ࡉࡠ࠽࡯ࡠ࡯࠻ߢࠈㆊߒ㧘Ⴎ⚛ࠗࠝࡦ߇ᬌ಴ߐࠇߥߊߥࠆ߹ߢ⣕ࠗࠝࡦ᳓ߢᵞᵺߒߚ‫ޕ‬㈶㉄㌁ṁᶧߦࠃࠅႮ⚛ࠗࠝࡦ߇ᬌ಴ߐࠇߥߊߥߞߚߩࠍ⏕⹺ᓟ㧘⚂ 60͠ߩᕡ᷷ᮏߢ⚂ 8 ᤨ㑆એ਄ੇ῎ߐߖߚ‫ޕ‬ԙ਄⸥Ԙߩᠲ૞ࠍⴕߞߚᶏ⍾ߣ⹜ᢱࠍᷙวߒߚ(ᶏ⍾ߪ⹜ᢱߦኻߒߡ 10 ୚⒟ᐲߩ㊂)‫ޕ‬Ԛᶐ಴▤ B ߩᦨਅㇱߦዋ㊂ߩ⍹⧷࠙࡯࡞ࠍᐔࠄߦ⹣߼ߚ‫ߩߘޕ‬਄ߦ੃ൻࠈ⚕ࠍ 3㨪5mm ⒟ᐲߩෘߐߦ⹣߼ߚ‫ߦᦝޕ‬㧘ԙߢᷙวߒߚᶏ⍾ߣ⹜ᢱࠍ⹣߼ߚ‫ޕ‬ԛ⹜ᢱߩ౉ߞߚᶐ಴▤ B ߦ 1N ㈶㉄ࠕࡦࡕ࠾࠙ࡓṁᶧࠍዋߒߕߟ౉ࠇ㧘⹜ᢱਛߦቢోߦᶐ
ㅘߒߚࠄᶐ಴▤ B ࠍⵝ⟎ߦ࠮࠶࠻ߒ㧘ᵞᵺᶧኈེ A ߦ౉ߞߚ 100ml ߩ 1N ㈶㉄ࠕࡦࡕ࠾࠙ࡓṁᶧࠍ 4㨪24 ᤨ㑆ߢᶐ಴߇⚳ੌߔࠆࠃ߁ߦ㧘ᵞᵺᶧኈེ A ߩࠦ࠶ࠢࠍ⺞▵ߒߡᵹਅߐߖߚ‫ޕ‬
Ԝᵞᵺᶧኈེ A ࠍలಽߦ᳓ᵞߒߚᓟ㧘50ml ߩ 80㧑ࠛ࠴࡞ࠕ࡞ࠦ࡯࡞ࠍട߃ᵹਅߐߖߡ⹜
ᢱࠍᵞᵺߒߚ‫ޕ‬
ԝᵞᵺᶧኈེ A ߣฃེ C ࠍలಽߦ᳓ᵞߒߚᓟ㧘ᵞᵺᶧኈེ A ߦ 100ml ߩ 10㧑Ⴎൻࠞ࡝࠙
ࡓṁᶧࠍട߃ߡᵹਅߐߖߚᓟ㧘⹜ᢱਛߩࠕࡦࡕ࠾࠙ࡓࠗࠝࡦࠍࠞ࡝࠙ࡓࠗࠝࡦߣ੤឵ߐ
ߖߚ‫ޕ‬Ԟฃེ C ߩࠕࡦࡕ࠾࠙ࡓࠗࠝࡦࠍ฽߻ᵹ಴ᶧࠍ⫳⇐ⵝ⟎ߦ⒖ߒߚ‫࡞࡯࠳࡞ࠤޕ‬ᴺߦᓥߞߡ㧘ࠕࡦࡕ࠾ࠕࠍ⫳⇐ߒߚ‫ޕ‬ᵹ಴ᶧߪ৻ቯ㊂ߩ 0.1N ⎫㉄ߦฃߌㆊ೾ߩ⎫㉄ࠍ 0.1N ᳓㉄ൻ࠽࠻࡝࠙ࡓṁᶧߢṢቯߒߚ‫ޕ‬หᤨߦ㧘ⓨ⹜㛎ࠍⴕߞߚ‫ޕ‬ᰴᑼߦࠃࠅ⸘▚ߒ㧘ዋᢙ╙৻૏߹ߢࠍੇ῎⹜ᢱ 100g ᒰߚࠅߩࡒ࡝ᒰ㊂ᢙ(meq/100g)ߢ⴫␜ߒߚ‫ޕ‬( A  B) u f u 100

CEC( meq / 100g )Su

100  M100

ߎߎߢ㧘A㧦ⓨ⹜㛎ߦⷐߒߚ 0.1N NaOH ߩኈ㊂(ml)㧘B㧦ታ㓙ߦⷐߒߚ 0.1N NaOH ߩኈ㊂(ml)㧘f㧦0.1N NaOH ߩࡈࠔࠢ࠲࡯㧘S㧦⹜ᢱណข㊂(g)㧘M㧦⹜ᢱߩ᳓ಽ(%)
1 ⹜ᢱᒰߚࠅߩ᷹ቯ➅ࠅ㄰ߒ࿁ᢙࠍ 2 ߣߒߚ‫ޕ‬

3

 


3.2 ࠬࡔࠢ࠲ࠗ࠻ጀ㑆㓁ࠗࠝࡦಽᨆ
⹜㛎ᓟࡌࡦ࠻࠽ࠗ࠻⹜ᢱߩࠬࡔࠢ࠲ࠗ࠻ጀ㑆ߦሽ࿷ߔࠆ㓁ࠗࠝࡦߩ⒳㘃߿㊂ࠍᛠីߔࠆ
ߚ߼㧘ࠬࡔࠢ࠲ࠗ࠻ጀ㑆㓁ࠗࠝࡦߩಽᨆࠍⴕߞߚ‫ޕ‬ ⹜㛎ߣಽഀߒߚ࿕⋧⹜ᢱ㧔ࡌࡦ࠻࠽ࠗ࠻㧕ࠍ↪޿ߡ㧘એਅߩᚻ㗅ߦࠃࠅࠬࡔࠢ࠲ࠗ࠻

ጀ㑆㓁ࠗࠝࡦಽᨆ↪ߩṁᶧ⹜ᢱࠍḰ஻ߒߚ‫ޕ‬Ԙ㆙ᔃಽ㔌▤ߦ⹜ᢱߣ 80%ߩࠛ࠲ࡁ࡯࡞ࠍ౉ࠇߡ㧘㆙ᔃಽ㔌㧔࿁ォᢙ㧩12,000[rpm] 60 ಽ㑆㧕ࠍⴕߞߚ‫ߩߎޕ‬ᠲ૞ࠍ 3 ࿁⒟ᐲ➅ࠅ㄰ߔߎߣߢਇ⚐‛ࠍ㒰෰ߒߚ‫ޕ‬ԙ㔓࿐᳇೙ᓮࠣࡠ࡯ࡉࡏ࠶ࠢࠬౝߢ⥄ὼੇ῎ߐߖߚ‫ߡߒߘޕ‬㧘ੇ῎ߒߚ⹜ᢱࠍ੃㋬ߦࠃࠅ☳⎈ߒߚࡌࡦ࠻࠽ࠗ࠻⹜ᢱ 0.5g ࠍ♖⒊ߒߡ㆙ᔃಽ㔌▤ߦ౉ࠇ㧘㆙ᔃಽ㔌㧔࿁ォᢙ㧩
12,000[rpm] 60 ಽ㑆㧕ࠍⴕߞߚ‫ޕ‬Ԛ㆙ᔃಽ㔌ᓟߩ⹜ᢱߦ 1N ߩ㈶㉄ࠕࡦࡕ࠾࠙ࡓ(CH3COONH4)ࠍട߃ߡࡂࡦ࠼ࠪࠚࠗࠢߦ
ࠃࠅ⦟ߊᡬᜈߔࠆߎߣߢ㧘ࠬࡔࠢ࠲ࠗ࠻ጀ㑆㓁ࠗࠝࡦߣ⟎឵ߐߖߚ‫ޕ‬ౣᐲ㧘㆙ᔃಽ㔌㧔࿁ォᢙ㧩12,000[rpm] 90 ಽ㑆㧕ࠍⴕߞߚ‫ޕ‬ԛ㆙ᔃಽ㔌ᓟߩ਄Ẵߺᶧࠍࠈㆊ㧔0.45Pm ߩࡔࡦࡉ࡟ࡦࡈࠖ࡞࠲ߦࠃࠆỹㆊߦ⛯޿ߡಽ↹ಽ
ሶ㊂ 10,000 ߢߩ㒢ᄖỹㆊ㧕ߒߚ‫ޕ‬㋕ߩᴉᲚࠍ㒐ߋߚ߼㧘ỹㆊᓟߩṁᶧߦႮ㉄ࠍട߃㧘㉄ᕈ㧔pH=3㨪4㧕ߦߒ㧘ṁᶧಽᨆ↪
ߩ⹜ᢱߦଏߒߚ‫ޕ‬ṁᶧಽᨆర⚛ߪ Ca㧘Na㧘K㧘Mg ߅ࠃ߮ Fe ߣߒߚ‫ޕ‬
3.3 SEM㧛EDS ಽᨆ߅ࠃ߮ TEM㧛EDS ಽᨆ⹜㛎ធ⸅㕙ㄭறㇱߩࡌࡦ࠻࠽ࠗ࠻⹜ᢱߩ⴫㕙⁁ᘒ߿⴫㕙ߦಽᏓߔࠆర⚛ߩ⁁ᘒࠍᲧセࠍߔࠆߚ߼㧘SEM㧛EDS ಽᨆࠍታᣉߒߚ‫ߚ߹ޕ‬㧘ࡌࡦ࠻࠽ࠗ࠻⹜ᢱߦኻߒ㧘ࠃࠅᓸ⚦ߥࠬࠤ࡯࡞ߢ㧘ࠬࡔࠢ࠲ࠗ࠻ጀ㑆ߦሽ࿷ߔࠆర⚛ߩ⒳㘃߿ಽᏓ⁁ᘒߦ㑐ߔࠆᖱႎࠍᓧࠆߚ߼㧘TEM㧛EDS ಽᨆߦߟ޿ߡ߽ⴕߞߚ‫ޕ‬એਅߦฦ‫ߩޘ‬ಽᨆߦଏߔࠆߚ߼ߩ೨ಣℂᣇᴺߦߟ޿ߡ߹ߣ߼ࠆ‫ޕ‬3.3.1 SEM㧛EDS ಽᨆ೨ಣℂ⹜㛎ធ⸅㕙ㄭறㇱߩࡌࡦ࠻࠽ࠗ࠻⹜ᢱࠍਔ㕙࠹࡯ࡊߩ㕙߇⾍ࠅઃߌߡ޽ࠆ⹜ᢱࡎ࡞

࠳࡯ߦขࠅઃߌߚ‫⹜ߩߎޕ‬ᢱࡎ࡞࠳࡯ࠍ㔓࿐᳇೙ᓮࠣࡠ࡯ࡉࡏ࠶ࠢࠬ߆ࠄขࠅ಴ߒ㧘SEM
㧛EDS ಽᨆࠍታᣉߒߚ‫⹜࠻ࠗ࠽࠻ࡦࡌޕ‬ᢱߪ㕖ዉ㔚ᕈߢ޽ࠆߚ߼㧘೨ಣℂߣߒߡ㊄⫳⌕ࠍⴕߞߚ‫ޕ‬
3.3.2 TEM㧛EDS ಽᨆ೨ಣℂ⹜㛎ធ⸅㕙ㄭறㇱߩࡌࡦ࠻࠽ࠗ࠻⹜ᢱࠍᄙ㊂ߩ⫳⇐᳓ߢṁ⸃ߐߖߚ‫ߩߎޕ‬ṁᶧࠍࠛࡐࠠࠪ᮸⢽ߩਛߦ൮ၒߒߚ‫ޕ‬㔓࿐᳇೙ᓮࠣࡠ࡯ࡉࡏ࠶ࠢࠬ߆ࠄขࠅ಴ߒ㧘60͠ߩᕡ᷷ᮏߢ৻ᤤᄛੇ῎ߐߖߚ‫ࠪࠠࡐࠛߩߎޕ‬᮸⢽ࠍ⭯ߦߒߡ TEM㧛EDS ಽᨆࠍⴕߞߚ‫ޕ‬

4

 


3.4 EPMA ಽᨆ ⹜㛎 ធ⸅㕙߆ࠄࡌࡦ࠻࠽ࠗ࠻ਛ߳ߩ㋕ߩ᜛ᢔࡊࡠࡈࠔࠗ࡞ࠍ⏕⹺ߔࠆߚ߼ߦ EPMA ߦࠃࠆ㕙ಽᨆࠍⴕߞߚ‫ޕ‬ฦ‫ߩޘ‬ಽᨆߦଏߔࠆߚ߼ߩ೨ಣℂߣߒߡ㧘⹜㛎ߩᒻ⁁ࠍ፣ߐߧࠃ

߁ߦ㔚᳇Ἱ(700͠㧘20 ಽ㑆)ߦߡ὾߈࿕߼ߚ‫ߩߎޕ‬ᓟ㧘ࠛࡐࠠࠪ᮸⢽ߦߡ⹜ᢱࠍᶐẃߒ㧘ಽᨆᢿ㕙ࠍಾᢿ㧘⎇⏴ߒߡ EPMA ߩ⹜ᢱߣߒߚ‫ޕ‬
3.5 X ✢࿁᛬ಽᨆછᗧᦼ㑆㕒⟎ᓟߦ⣣㘩↢ᚑ‛߿ᣂߚߥ⚿᥏ᕈ㋶‛ߩ↢ᚑ߇⹺߼ࠄࠇࠆ߆㧘߹ߚ⹜㛎ᓟߩࡌࡦ࠻࠽ࠗ࠻߇⹜㛎೨ߣห᭽ߦ☼࿯㋶‛ߣߒߡߩ․ᕈߢ޽ࠆጀ⁁᭴ㅧࠍ᦭ߒߡ޿ࠆ߆ߤ߁
߆ࠍ⏕⹺ߔࠆߚ߼㧘ቯᣇ૏ಽᨆ߅ࠃ߮ਇቯᣇ૏ಽᨆࠍⴕߞߚ‫ߚ߹ޕ‬㧘Ḩᐲ೙ᓮ᧦ઙਅߦ߅
޿ߡ⹜㛎ᓟࡌࡦ࠻࠽ࠗ࠻ߩቯᣇ૏ಽᨆࠍⴕ޿㧘Ḩᐲᄌൻߦ઻߁⹜㛎ᓟࡌࡦ࠻࠽ࠗ࠻ߩᐩ㕙㑆㓒ߩᐢ߇ࠅߩᄌൻ߆ࠄጀ㑆㓁ࠗࠝࡦࠍ․ቯߒߚ‫ޕ‬એਅߦ㧘ฦಽᨆߦ߅ߌࠆ⹜ᢱߩ೨ಣℂ
ᣇᴺ╬ߦߟ޿ߡ߹ߣ߼ࠆ‫ޕ‬
3.5.1 ਇቯᣇ૏ಽᨆ⹜㛎 ធ⸅㕙ㄭறㇱ߅ࠃ߮㆙㓒ㇱߩࡌࡦ࠻࠽ࠗ࠻⹜ᢱࠍ㧘☳ᧃ X ✢࿁᛬↪⹜ᢱ᧼ߦలႯ
ߒ㧘ߘߩᓟ㔓࿐᳇೙ᓮ࠮࡞ࠍ૶↪ߒ㧘⹜ᢱࠍᄢ᳇ߣធ⸅ߐߖߥ޿⁁ᘒߢ X ✢࿁᛬ಽᨆࠍⴕ
ߞߚ‫ޕ‬
3.5.2 ቯᣇ૏ಽᨆ
⹜㛎ធ⸅㕙ㄭறㇱ߅ࠃ߮㆙㓒ㇱߩࡌࡦ࠻࠽ࠗ࠻⹜ᢱߦ⫳⇐᳓ࠍട߃㧘ࠃߊᡬᜈߒߚᓟ

ߩ⹜ᢱߩ Ộㇱಽࠍή෻኿⹜ᢱ᧼ߩ਄ߦ⭯ߊᑧ߫ߒ㧘৻ᤤᄛ⥄ὼੇ῎ߐߖߚ‫ߩߘޕ‬ᓟ㧘㔓࿐᳇೙ᓮ࠮࡞ࠍ૶↪ߒ㧘⹜ᢱࠍᄢ᳇ߣធ⸅ߐߖߥ޿⁁ᘒߢ X ✢࿁᛬ಽᨆࠍⴕߞߚ‫ޕ‬㋕ߩᓇ㗀߇ㆊ೾ߥ႐วߦߪ㧘㔓࿐᳇೙ᓮࠣࡠ࡯ࡉࡏ࠶ࠢࠬౝߦ߅޿ߡ⿥㖸ᵄᵞᵺಣℂࠍⴕߞߚᓟ
ߦ X ✢࿁᛬ಽᨆࠍⴕߞߚ‫ޕ‬
3.5.3 Ḩᐲ೙ᓮ᧦ઙਅߢߩቯᣇ૏ಽᨆ
⹜㛎ធ⸅㕙ㄭறㇱ߅ࠃ߮㆙㓒ㇱߩࡌࡦ࠻࠽ࠗ࠻⹜ᢱߦ⫳⇐᳓ࠍട߃㧘ࠃߊᡬᜈߒߚᓟ

ߩ⹜ᢱߩ Ộㇱಽࠍή෻኿⹜ᢱ᧼ߩ਄ߦ⭯ߊᑧ߫ߒ㧘৻ᤤᄛ⥄ὼੇ῎ߐߖߚ‫ߩߘޕ‬ᓟ㧘⓸⚛ࠟࠬࠍᏱᤨᵈ౉ߢ߈ࠆḨᐲ೙ᓮ࠮࡞ࠍ૶↪ߒ㧘Ḩᐲ 0 %㨪100 %ߦᄌൻߐߖ㧘Ḩᐲࠍ 10 %ᄌൻߐߖࠆᐲߦ X ✢࿁᛬ಽᨆࠍⴕߞߚ‫ޕ‬㋕ߩᓇ㗀߇ㆊ೾ߥ႐วߦߪ㧘㔓࿐᳇೙ᓮࠣࡠ࡯ࡉ
ࡏ࠶ࠢࠬౝߦ߅޿ߡ⿥㖸ᵄᵞᵺಣℂࠍⴕߞߚᓟߦ X ✢࿁᛬ಽᨆࠍⴕߞߚ‫ޕ‬
3.5.4 ࠛ࠴࡟ࡦࠣ࡝ࠦ࡯࡞ಣℂቯᣇ૏ಽᨆ
⹜㛎ធ⸅㕙ㄭறㇱ߅ࠃ߮㆙㓒ㇱߩࡌࡦ࠻࠽ࠗ࠻⹜ᢱߦ⫳⇐᳓ࠍട߃㧘ࠃߊᡬᜈߒߚᓟ

ߩ⹜ᢱߩ Ộㇱಽࠍή෻኿⹜ᢱ᧼ߩ਄ߦ⭯ߊᑧ߫ߒ㧘20%ࠛ࠴࡟ࡦࠣ࡝ࠦ࡯࡞ṁᶧࠍ 1㧘2

5

 


Ṣട߃ߡ෻኿⹜ᢱ᧼ߩ਄ߩ⹜ᢱߦ㚔ᨴ߹ߖߡ৻ᤤᄛ⥄ὼੇ῎ߐߖߚ‫ߩߘޕ‬ᓟ㧘㔓࿐᳇೙ᓮ࠮࡞ࠍ૶↪ߒ㧘⹜ᢱࠍᄢ᳇ߣធ⸅ߐߖߥ޿⁁ᘒߢ X ✢࿁᛬ಽᨆࠍⴕߞߚ‫ޕ‬㋕ߩᓇ㗀߇ㆊ೾ߥ႐วߦߪ㧘㔓࿐᳇೙ᓮࠣࡠ࡯ࡉࡏ࠶ࠢࠬౝߦ߅޿ߡ⿥㖸ᵄᵞᵺಣℂࠍⴕߞߚᓟߦ X ✢࿁᛬ಽᨆࠍⴕߞߚ‫ޕ‬
4. ⚿ᨐ߅ࠃ߮⠨ኤߎࠇએ㒠ߩ⴫⸥ߣߒߡ㧘SW㧙80͠⹜ᢱ㧘SW㧙50͠⹜ᢱ㧘GW㧙1㧙80͠⹜ᢱ㧘GW㧙2
㧙80͠⹜ᢱ㧘SW㧙80͠ᄢ᳇᧦ઙ⹜ᢱ߅ࠃ߮ SW㧙80͠ Kunipia㧙F ⹜ᢱߪߘࠇߙࠇੱᎿᶏ
᳓ࠍ૶↪ߒߚ 80͠⹜㛎㧘ੱᎿᶏ᳓ࠍ૶↪ߒߚ 50͠⹜㛎㧘ੱᎿ࿾ਅ᳓㧙1 ࠍ૶↪ߒߚ 80͠⹜㛎㧘ੱᎿ࿾ਅ᳓㧙2 ࠍ૶↪ߒߚ 80͠⹜㛎㧘ੱᎿᶏ᳓ࠍ૶↪ߒߚ 80͠ߩᄢ᳇᧦ઙ⹜㛎߅ࠃ߮ੱᎿᶏ᳓ࠍ૶↪ߒߚ 80͠ߩ Kunipia㧙F ࡌࡦ࠻࠽ࠗ࠻⹜㛎ࠍ␜ߔߎߣߣߔࠆ‫ޕ‬
4.1 ⹜ᢱߩᄖⷰ
⹜ᢱណขᤨߩ↹௝ࠍ౮⌀ 4.1 ߦ␜ߔ‫ޕ‬౮⌀ਛߩ(A)߇࠴࠲ࡦࠞ࡜ࡓߢ޽ࠆ‫ޕ‬౮⌀ਛߩ(B)߇࠴࠲ࡦࠞ࡜ࡓߩ

஥⬄ࠍขࠅᄖߒߚ⁁ᘒߢ޽ࠆ‫ޕ‬౮⌀ਛߩ(C)߇࠴࠲ࡦࠞ࡜ࡓࠍขࠅᄖߒ

ߚ⁁ᘒߢ޽ࠆ‫ޕ‬਄ㇱߩ⊕޿౞╴ᒻߩ߽ߩߪ࠮࡜ࡒ࠶ࠢࡈࠖ࡞࠲ߢ޽ࠆ‫ޕ‬౮⌀ਛߩ(D)ߪ☼࿯ㇱಽࠍੑߟߦഀߞߡ὇⚛㍑ࠍขࠅ㒰޿ߚ⁁ᘒߢ޽ࠆ‫ޕ‬౮⌀ਛߩ(D)ߩ὇⚛㍑ߣធ⸅ߒߡ޿ߚ
⴫㕙ߪᥧ㕍⦡ࠍߒߡ޿ࠆߩߦኻߒߡ὇⚛㍑ߣធ⸅ߒߡ޿ߥ޿ࡌࡦ࠻࠽ࠗ࠻ㇱಽߪ᷆㕍⦡ࠍ๒ߒߡ޿ߚ‫ޕ‬
4.2 ᶐẃṁᶧಽᨆ⚿ᨐ߅ࠃ߮⠨ኤᶐẃṁᶧಽᨆ⚿ᨐࠍ⴫ 4.2 ߦ␜ߔ‫ੱޕ‬Ꮏᶏ᳓♽(SW㧙50͠⹜ᢱ߅ࠃ߮ SW㧙80͠ᄢ᳇᧦ઙ⹜ᢱ)⹜㛎ߦ߅ߌࠆᶐẃṁᶧߩỚᐲߪ߶ߣࠎߤᄌൻߒߡ޿ߥ߆ߞߚ‫ੱޕ‬Ꮏ࿾ਅ᳓♽(GW㧙1
㧙80͠⹜ᢱ߅ࠃ߮ GW㧙2㧙80͠⹜ᢱ)⹜㛎ߦ߅ߌࠆᶐẃṁᶧߩỚᐲߪฦర⚛ߣ߽ߦჇടߒ
ߡ޿ࠆ߇㧘㓙┙ߞߚჇട㊂ߢߪߥ߆ߞߚ‫⹜ߩࠇߕ޿ޕ‬ᢱߦ߅޿ߡ߽὇⚛㍑ṁ⸃ߦࠃࠆ㋕߇ṁሽߒߡ߅ࠅ㧘GW㧙1㧙80͠⹜ᢱߢߪ⚂ 75㧑߇ੑଔ㋕ߢ޽ߞߚ‫ޕ‬ ᶐẃṁᶧߩ pH ߪ⓸⚛㔓࿐᳇ਅߢߩ⹜㛎ߢߪೋᦼ pH ࠃࠅ㜞ߊߥࠆ௑ะ(SW㧙50 ⹜ᢱ㧘
GW㧙1㧙80͠⹜ᢱ߅ࠃ߮ GW㧙2㧙80͠⹜ᢱ)ߦ޽ࠅ㧘ᄢ᳇㔓࿐᳇ਅߢߩ⹜㛎ߢߪૐߊߥࠆ௑ะ(SW㧙80͠ᄢ᳇᧦ઙ⹜ᢱ)ߦ޽ߞߚ‫ߚ߹ޕ‬㧘㉄ൻㆶర㔚૏ߪㆶర೷ࠍᷝടߒߡ޿ߥ޿ߦ
߽߆߆ࠊࠄߕૐ޿୯ߢ޽ࠆߣ⸒߃㧘⹜㛎ᦼ㑆ਛߪㆶర㔓࿐᳇߇଻ߚࠇߚߣ⸒߃ࠆ‫ޕ‬
4.3 㓁ࠗࠝࡦ੤឵ኈ㊂ಽᨆ⚿ᨐߣࠬࡔࠢ࠲ࠗ࠻ጀ㑆㓁ࠗࠝࡦಽᨆ⚿ᨐ߅ࠃ߮⠨ኤ
4.3.1 㓁ࠗࠝࡦ੤឵ኈ㊂ಽᨆ⚿ᨐ߅ࠃ߮⠨ኤ ฦ⹜ᢱߩᧂᄌ⾰ㇱߩ㓁ࠗࠝࡦ੤឵ኈ㊂߅ࠃ߮ᶐ಴㓁ࠗࠝࡦಽᨆ⚿ᨐࠍ⴫ 4.3.1㧙1 ߦ␜ߔ‫ޕ‬߹ߚ㧘࿕⋧ߩൻቇ⚵ᚑࠍ⴫ 4.3.1㧙2 ߦ␜ߔ‫ ߩࠄࠇߎޕ‬2 ߟߩ⴫ߦ߅޿ߡᲧセߩߚ߼ߦࠢ࠾
ࠥ࡞ V1 ߣࠢ࠾ࡇࠕ F ߩ୯ 9)߽วࠊߖߡ␜ߒߡ޿ࠆ‫ޕ‬㓁ࠗࠝࡦ੤឵ኈ㊂ߦ߅޿ߡ㧘ࠢ࠾ࠥ࡞

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V1 ߪ 52.4[meq/100g]ߢ޽ࠆߩߦኻߒߡోߡߩ⹜ᢱߦ߅޿ߡ⧯ᐓ㜞޿୯ߣߥߞߚ‫ߚ߹ޕ‬㧘ࠢ࠾ ࡇ ࠕ F ߪ 116.5[meq/100g] ߢ ޽ ࠆ ߩ ߦ ኻ ߒ ߡ SW 㧙 80 ͠ Kunipia 㧙 F ⹜ ᢱ ߪ
111.2[meq/100g]ߣ⧯ᐓૐ޿୯ߣߥߞߚ‫ޕ‬ᶐ಴㓁ࠗࠝࡦಽᨆ⚿ᨐ߆ࠄ㧘Na ߦߟ޿ߡߪ GW
㧙1㧙80͠⹜ᢱએᄖߪᷫዋߒߡ޿ߚ‫ޕ‬K ߦߟ޿ߡߪోߡߩ⹜ᢱߦ߅޿ߡჇടߒߡ޿ߚ‫ޕ‬ᶏ᳓♽ߩ⹜ᢱߦ߅޿ߡߪ Mg ߇Ⴧടߒߡ߅ࠅ Ca ߇ᷫዋߒߡ޿ߚ‫߇࠻ࠗ࠲ࠢࡔࠬߪࠇߎޕ‬ṁ⸃ߒߡ Mg ߇Ⴧടߒߡጀ㑆ਛߩ Ca ߣ⟎឵ߒߚߣ⠨߃ࠄࠇࠆ‫ߚ߹ޕ‬㧘࿾ਅ᳓♽ߩ⹜ᢱߦ߅޿ߡߪ
Mg ߇ᷫዋߒߡ߅ࠅ Ca ߇Ⴧടߒߡ޿ߚ‫ߪࠇߎޕ‬㧘ࡌࡦ࠻࠽ࠗ࠻ਛߩᣇ⸃⍹߇ṁ⸃ߒߡ Ca߇Ⴧടߒߡጀ㑆ਛߩ Mg ߣ⟎឵ߒߡṁᶧਛߦ᡼಴ߐࠇߚߣ⠨߃ࠄࠇࠆ‫ޕ‬ ⴫ 4.3.1㧙2 ߆ࠄ㧘㋕㉄ൻ‛(Fe2O3)ߪోߡߩ⹜ᢱߦ߅޿ߡࠢ࠾ࠥ࡞ V1 ߅ࠃ߮ࠢ࠾ࡇࠕ F
ߦኻߒߡ⧯ᐓჇടߒߡ޿ߚ‫ߪࠇߎޕ‬὇⚛㍑߆ࠄṁ಴ߒߚ㋕߇ᓇ㗀ߒߡ޿ࠆ߽ߩߣ⠨߃ࠄࠇࠆ‫ߪઁߩߘޕ‬ᄙዋߩჇᷫ߇޽ࠆ߽ߩߩᄢ߈ߥ㆑޿ߪή߆ߞߚ‫ޕ‬
4.3.2 ࠬࡔࠢ࠲ࠗ࠻ጀ㑆㓁ࠗࠝࡦಽᨆ⚿ᨐ߅ࠃ߮⠨ኤ ᧂᄌ⾰ㇱಽߩࠬࡔࠢ࠲ࠗ࠻ጀ㑆㓁ࠗࠝࡦಽᨆ⚿ᨐࠍ⴫ 4.3.2 ߦ␜ߔ‫ ⴫ޕ‬4.3.1㧙1 ߩ CEC
ߩ᷹ቯߦ઻߁ᶐ಴㓁ࠗࠝࡦಽᨆߣᲧセߔࠆߣ㧘ᩴ㆑޿ߦᄢ߈ߊߥߞߚ‫ߪࠇߎޕ‬㧘ࠛ࠲ࡁ࡯࡞ߦࠃࠆนṁᕈႮߩ㒰෰߇ቢోߢߪߥ߆ߞߚߚ߼㧘ጀ㑆㓁ࠗࠝࡦߣߒߡሽ࿷ߔࠆએᄖߩర
⚛ߦߟ޿ߡ߽ಽᨆ୯ߦട▚ߐࠇߡߒ߹ߞߚߣ⠨߃ࠄࠇࠆ‫ޕ‬
4.4 SEM㧛EDS ಽᨆ߅ࠃ߮ TEM㧛EDS ಽᨆ⚿ᨐ߅ࠃ߮⠨ኤ
4.4.1 SEM㧛EDS ಽᨆ⚿ᨐ߅ࠃ߮⠨ኤ SW㧙80͠⹜ᢱ㧘SW㧙50͠⹜ᢱ㧘GW㧙1㧙80͠⹜ᢱ㧘GW㧙2㧙80͠⹜ᢱ㧘SW㧙80͠ᄢ᳇᧦ઙ⹜ᢱ߅ࠃ߮ SW㧙80͠ Kunipia㧙F ⹜ᢱߩ SEM㧛EDS ߩಽᨆ⚿ᨐࠍ࿑ 4.4.1㧙1
㨪࿑ 4.4.1㧙6 ߦ␜ߔ‫ޕ‬SEM ↹௝߆ࠄߪߤߩ⹜ᢱߣ߽߶ߣࠎߤ㆑޿߇⷗ࠄࠇߕ㧘↢ᚑ‛߽⏕⹺ߢ߈ߥ߆ߞߚ‫ޕ‬EDS ಽᨆߢߪ SW㧙80͠⹜ᢱ㧘SW㧙50͠⹜ᢱ㧘GW㧙2㧙80͠⹜ᢱ߅ࠃ
߮ SW㧙80͠ᄢ᳇᧦ઙ⹜ᢱߦ߅޿ߡ㋕߇ᄙߊᬌ಴ߐࠇߚ‫ߚ߹ޕ‬㧘GW㧙1㧙80͠⹜ᢱએᄖߢ
ߪ Ca ߽ᬌ಴ߐࠇߚ‫ੱޕ‬Ꮏᶏ᳓♽ߩ⹜ᢱ(SW㧙80͠⹜ᢱ㧘SW㧙50͠⹜ᢱ㧘SW㧙80͠ᄢ᳇᧦ઙ⹜ᢱ߅ࠃ߮ SW㧙80͠ Kunipia㧙F ⹜ᢱ)ߦ߅޿ߡߪੱᎿᶏ᳓ߩᚑಽߢ޽ࠆ Ca ߇ᶐㅘߒߚߣ⠨߃ࠄࠇࠆ߇㧘GW㧙2㧙80͠⹜ᢱߩᶐẃᶧߢ޽ࠆੱᎿ࿾ਅ᳓ߦߪ Ca ߇౉ߞߡ޿ߥ
޿ߎߣࠍ⠨ᘦߔࠆߣ㧘ࡌࡦ࠻࠽ࠗ࠻⴫㕙ߢߩ Ca ߪࡌࡦ࠻࠽ࠗ࠻ߦ฽߹ࠇࠆᣇ⸃⍹߇ṁ⸃ߒߚߎߣߦࠃࠆ߽ߩߛߣ⠨߃ࠄࠇࠆ‫ޕ‬
4.4.2 TEM㧛EDS ಽᨆ⚿ᨐ߅ࠃ߮⠨ኤ SW㧙80͠⹜ᢱߩ TEM㧛EDS ߩಽᨆ⚿ᨐࠍ࿑ 4.4.2 ߦ␜ߔ‫ޕ‬
TEM ↹௝߆ࠄጀ⁁᭴ㅧ߇⏕⹺ߢ߈ߚ‫ޕ‬ጀ㑆ߪ⚂ 12[Å]ߢ޽ࠅ㧘ㅢᏱߩ 2㧦1 ဳࠬࡔࠢ࠲ࠗ࠻ߩጀ㑆ߣหߓ㑆㓒ߢ޽ߞߚ‫ޕ‬
EDS ಽᨆߢߪ㧘ࠬࡔࠢ࠲ࠗ࠻ߩਥⷐ᭴ᚑర⚛ߢ޽ࠆ Si㧘Al ߅ࠃ߮ Mg ߩઁߦ Fe ߣ Ca ߇ᬌ಴ߐࠇߚ‫ޕ‬Fe ߪ὇⚛㍑߇ṁ⸃ߒߚ߽ߩ㧘Ca ߪੱᎿᶏ᳓ߩᚑಽߢ޽ࠆ Ca ߇ᶐㅘߒߚ߆⧯

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ߒߊߪࡌࡦ࠻࠽ࠗ࠻ߩ㓐઻㋶‛ߩᣇ⸃⍹߇ṁ⸃ߒߚ߽ߩߣ⠨߃ࠄࠇࠆ‫ ߩߎޕ‬EDS ಽᨆ߆ࠄߢߪ Fe ߣ Ca ߇ጀ㑆ߦ૏⟎ߒߡ޿ࠆ߆ࠍ್ᢿߢ߈ߥ߆ߞߚ‫ޕ‬
4.5 EPMA ಽᨆ⚿ᨐ߅ࠃ߮⠨ኤ SW㧙80͠⹜ᢱߩಽᨆᢿ㕙ࠍ࿑ 4.5㧙1㧘ࡑ࠶ࡇࡦࠣ࿑ࠍ 4.5㧙2 ߦ␜ߔ‫ޕ‬GW㧙1㧙80͠⹜ᢱߩಽᨆᢿ㕙ࠍ࿑ 4.5㧙3㧘ࡑ࠶ࡇࡦࠣ࿑ࠍ 4.5㧙4 ߦ␜ߔ‫ߚ߹ޕ‬㧘 SW㧙80͠ᄢ᳇᧦ઙ⹜ᢱ
ߩಽᨆᢿ㕙ࠍ࿑ 4.5㧙5㧘ࡑ࠶ࡇࡦࠣ࿑ࠍ 4.5㧙6 ߦ␜ߔ‫ޕ‬࿑ 4.5㧙1㧘࿑ 4.5㧙3 ߅ࠃ߮࿑ 4.5
㧙5 ߩ⊕✢ߢ࿐ࠎߛㇱಽ߇ࡑ࠶ࡇࡦࠣߒߚ▸࿐ߢ޽ࠆ‫ޕ‬࿑ߩ㤥޿ㇱಽ߇὇⚛㍑ߣធ⸅ߒߡ޿
ߚ႐ᚲߢ޽ࠆ‫ޕ‬SW㧙80͠⹜ᢱ(࿑ 4.5㧙2)ߦ߅޿ߡ㧘㋕ߪ὇⚛㍑ធ⸅ㇱߢ৻⇟ሽ࿷㊂߇ᄙߊᲧセ⊛ࡌࡦ࠻࠽ࠗ࠻ౝㇱ(0.2mm ⒟ᐲ)߹ߢᶐㅘߒߡ޿ࠆ‫ޕ‬Ca ߪሽ࿷㊂߇Ყセ⊛ዋߥ߆ߞߚ‫ߚ߹ޕ‬㧘Naߪࡌࡦ࠻࠽ࠗ࠻ౝㇱߢ৻᭽ߦሽ࿷ߒߡ޿ߚ‫ޕ‬
GW㧙1㧙80͠⹜ᢱ(࿑ 4.5㧙4)ߦ߅޿ߡ㧘㋕ߪ὇⚛㍑ធ⸅ㇱߩߺߢࡌࡦ࠻࠽ࠗ࠻ౝㇱ߹ߢᶐㅘߒߡ޿ߥ߆ߞߚ‫ޕ‬ㅒߦ Ca ߪ὇⚛㍑ធ⸅ㇱߢߪ߶ߣࠎߤሽ࿷ߒߡ߅ࠄߕ㧘ࡌࡦ࠻࠽ࠗ࠻
ౝㇱߦᄙߊሽ࿷ߒߡ޿ߚ‫ޕ‬Na ߪࡌࡦ࠻࠽ࠗ࠻ౝㇱߢ৻᭽ߦሽ࿷ߒߡ޿ࠆ߇㧘὇⚛㍑ធ⸅ㇱߩᣇ߇ࡌࡦ࠻࠽ࠗ࠻ౝㇱࠃࠅሽ࿷㊂߇ᄙ߆ߞߚ‫ޕ‬SW㧙80͠ᄢ᳇᧦ઙ⹜ᢱ(࿑ 4.5㧙6)ߦ߅޿ߡ㧘㋕ߪ὇⚛㍑ធ⸅ㇱߩߺߢࡌࡦ࠻࠽ࠗ࠻ౝㇱ߹ߢ㋕߇ᶐㅘߒߡ޿ߥ߆ߞߚ‫ޕ‬Ca ߪ SW㧙80͠⹜ᢱ߅ࠃ߮ GW㧙1㧙80͠⹜ᢱߩ⚿ᨐߣߪ⇣ߥࠅ㧘ሽ࿷ߔࠆ႐ᚲ߇ὐ‫߇ࠆ޿ߡߒߣޘ‬ሽ࿷㊂߇ᄙ߆ߞߚ‫ޕ‬Na ߪࡌࡦ࠻࠽ࠗ࠻ౝㇱߢ৻᭽ߦሽ࿷ߒߡ޿ࠆ߇㧘GW㧙1㧙80͠⹜ᢱߩ⚿ᨐࠃࠅሽ࿷㊂߇ዋߥ߆ߞߚ‫ޕ‬ ߎࠇࠄߩ⚿ᨐ߆ࠄ㧘὇⚛㍑ߣߩធ⸅ㇱ߆ࠄ㋕ߪ⚂ 0.2mm ⒟ᐲߒ߆ࡌࡦ࠻࠽ࠗ࠻ਛߦᶐㅘ
ߒߡ޿ߥ޿ߎߣ߇⏕⹺ߢ߈ߚ‫ޕ‬SW㧙80͠ᄢ᳇᧦ઙ⹜ᢱߦ߅޿ߡߪ Ca ߩሽ࿷㊂߇ᄙߊ㧘ࡌࡦ࠻࠽ࠗ࠻ਛߦ฽߹ࠇࠆᣇ⸃⍹ߩṁ⸃ߦࠃࠆ߽ߩߣ⠨߃ࠄࠇࠆ‫ޕ‬Na ߪోߡߩ⹜ᢱߦ߅޿ߡ
ᄙᢙ㊂ሽ࿷ߒߡ߅ࠅ㧘ࡌࡦ࠻࠽ࠗ࠻ߩਥⷐߥ᭴ᚑᚑಽߢ޽ࠆߎߣ߇⏕⹺ߢ߈ߚ‫ޕ‬ SW㧙80͠⹜ᢱ߅ࠃ߮ GW㧙1㧙80͠⹜ᢱࠍ὇⚛㍑ធ⸅㕙߆ࠄ㒰‫ߦޘ‬೥ࠅ(㊀ߐ 0.05㨪
0.2[g])ㅙᰴ᛽಴ߒߚ⚿ᨐ 10)ߦ߅޿ߡ㧘὇⚛㍑ធ⸅㕙߆ࠄߩ㋕ߩᶐㅘෘߐ߇ SW㧙80͠⹜ᢱߢߪ⚂ 0.5mm ߅ࠃ߮ GW㧙1㧙80͠⹜ᢱߢߪ⚂ 3.5mm ߣႎ๔ߒߡ޿ࠆ‫ޕ‬EMPA ಽᨆߩ⚿ᨐࠃࠅߪ㋕ߩᶐㅘෘߐ߇ᄙ޿⹜ᢱ߽޽ࠅ㧘10 ᐕ㑆ߢᦨᄢ 3.5mm ߢ޽ࠆ‫ޕ‬
4.6 X ✢࿁᛬ಽᨆ⚿ᨐ߅ࠃ߮⠨ኤ
4.6.1 ਇቯᣇ૏ಽᨆ⚿ᨐ߅ࠃ߮⠨ኤ ਇቯᣇ૏ಽᨆ⚿ᨐࠍ࿑ 4.6.1㧙1㨪࿑ 4.6.1㧙12 ߦ␜ߔ‫ ࡞ࠥ࠾ࠢޕ‬V1 ࠍ૶↪ߒߚ࿑ 4.6.1
㧙1㨪࿑ 4.6.1㧙10(SW㧙80͠⹜ᢱ㧘SW㧙50͠⹜ᢱ㧘GW㧙1㧙80͠⹜ᢱ㧘GW㧙2㧙80͠⹜ᢱ߅ࠃ߮ SW㧙80͠ᄢ᳇᧦ઙ⹜ᢱ)ߦߟ޿ߡߩ 2ǰ=58㨪64qߩ࿑ਛߢ 2 ߟߩࡇ࡯ࠢ߇⏕⹺ߢ߈ߚ‫ޕ‬60qઃㄭߩࡇ࡯ࠢߪ⍹⧷ߩ߽ߩߢ޽ࠅ㧘62qઃㄭߩࡇ࡯ࠢߪࠬࡔࠢ࠲ࠗ࠻ߩ d(060)ߩ߽ߩߢ޽ࠆ‫ޕ‬ㅢᏱ㧘d(060)㕙ࡇ࡯ࠢ૏⟎ߪ 2㧙౎㕙૕ߩࠬࡔࠢ࠲ࠗ࠻ߢ 1.49㨪1.50[Å]ߦ㧘

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3㧙౎㕙૕ߩࠬࡔࠢ࠲ࠗ࠻ߢ 1.52㨪1.54[Å]ߦ૏⟎ߔࠆߣߐࠇߡ޿ࠆ 11)‫ࠄ߆ߣߎߩߎޕ‬㧘޿ߕࠇߩ⹜ᢱߦ߅޿ߡ߽ 2㧙౎㕙૕᭴ㅧߢ޽ࠅ⹜㛎೨ߩࠬࡔࠢ࠲ࠗ࠻ߣᄌൻߒߡ޿ߥ޿ߣ⸒
߃ࠆ‫ߚ߹ޕ‬㧘ߤߩ⹜ᢱߦ߅޿ߡ߽ᣂߚߥ⣣㘩↢ᚑ‛ߩࡇ࡯ࠢߪᬌ಴ߐࠇߥ߆ߞߚ‫ޕ‬
4.6.2 ቯᣇ૏ಽᨆ⚿ᨐ߅ࠃ߮⠨ኤ ቯᣇ૏ಽᨆ⚿ᨐࠍ࿑ 4.6.2㧙1㨪࿑ 4.6.2㧙6 ߦ␜ߔ‫⹜ߩߡోޕ‬ᢱߦߟ޿ߡߩ d(001)ࡇ࡯ࠢ
ߪᄌ⾰ㇱ߅ࠃ߮ᧂᄌ⾰ㇱߣ߽ߦᐩ㕙㑆㓒߇⚂ 12.5[Å]ߦ૏⟎ߒߡ߅ࠅ㧘ࡕࡦࡕ࡝ࡠ࠽ࠗ࠻ߩ
ᐩ㕙㑆㓒ߪ᥉ㅢߩ㘑ੇ⁁ᘒ(Ḩᐲ 60㧑೨ᓟ)ߢߪጀ㑆㓁ࠗࠝࡦ߇ Na ߩ႐ว 13[Å]㧘ጀ㑆㓁ࠗࠝࡦ߇ Ca ߿ Mg ߩ႐ว 15[Å]ߣߥࠆ 12)ߎߣ߆ࠄ㧘੹࿁ߩ⹜㛎ᓟ⹜ᢱߪᄌ⾰ߒߡ޿ߥ޿ߣ⠨߃ࠄࠇࠆ‫ޕ‬4.6.3 Ḩᐲ೙ᓮ᧦ઙਅߢߩቯᣇ૏ಽᨆ⚿ᨐ߅ࠃ߮⠨ኤ Ḩᐲ೙ᓮ᧦ઙਅߢߩቯᣇ૏ಽᨆ⚿ᨐࠍ࿑ 4.6.3㧙1㨪࿑ 4.6.3㧙12 ߦ␜ߔ‫ޕ‬࿑ 4.6.3㧙1 ߩ
SW㧙80͠ᄌ⾰ㇱ⹜ᢱߢߩḨᐲ೙ᓮ᷹ቯ⚿ᨐߪ Ca ဳߦㄭ޿⤘Ảᕈࠍ␜ߒߡ޿ߚ‫ޕ‬࿑߆ࠄ߽⏕⹺ߢ߈ࠆࠃ߁ߦࡇ࡯ࠢߪ᣿⍎ߢߪߥ޿ߚ߼㧘ጀ㑆ߩਥⷐߥ㓁ࠗࠝࡦ߇ 2 ଔߩ㓁ࠗࠝࡦߢ޽ࠆߣߪᢿ⸒ߢ߈ߥ޿⚿ᨐߢ޽ߞߚ‫ޕ‬࿑ 4.6.3㧙2㨪࿑ 4.6.3㧙12 ߩ⹜ᢱߢߩḨᐲ೙ᓮ᷹ቯ⚿ᨐߪ Na ဳߦㄭ޿⤘Ảᕈࠍ␜ߒߡ޿ߚ‫ߒ߆ߒޕ‬㧘޿ߕࠇߩ⹜ᢱߦ߅޿ߡ߽⤘Ảᕈ⢻ߪ⛽ᜬߒߡ޿ࠆߎߣ߇⏕⹺ߢ߈ߚ‫⹜ߩߤࠎߣ߶ޕ‬ᢱߪጀ㑆ߩਥⷐߥ㓁ࠗࠝࡦߣߒߡ 1 ଔߩ㓁ࠗࠝࡦ߇ሽ࿷ߒߡ޿ࠆ߽ߩߣ⠨߃ࠄࠇࠆ‫ޕ‬
4.6.4 ࠛ࠴࡟ࡦࠣ࡝ࠦ࡯࡞ಣℂቯᣇ૏ಽᨆ⚿ᨐ߅ࠃ߮⠨ኤ ࠛ࠴࡟ࡦࠣ࡝ࠦ࡯࡞ಣℂቯᣇ૏ಽᨆ⚿ᨐࠍ࿑ 4.6.4㧙1㨪࿑ 4.6.4㧙6 ߦ␜ߔ‫ޕ‬ቯᣇ૏ಽᨆ
⚿ᨐ(࿑ 4.6.2㧙1㨪࿑ 4.6.2㧙6)ߣᲧセߒߡ㧘ోߡߩ⹜ᢱߦ߅޿ߡ㧘d(001)ࡇ࡯ࠢ૏⟎߇⚂ 12.5
[Å]߆ࠄ⚂ 17.0[Å]ߦᐩ㕙㑆㓒߇᜛߇ߞߚ‫ޕ‬ ࠬࡔࠢ࠲ࠗ࠻ߣࠢࡠ࡜ࠗ࠻ߩᷙว☼࿯㋶‛ߩ႐ว㧘ࠢࡠ࡜ࠗ࠻ߩᷙวഀว߇ᄙߊߥࠆߦ
ߒߚ߇ߞߡ㧘ࠛ࠴࡟ࡦࠣ࡝ࠦ࡯࡞ಣℂࠍⴕߞߚࠬࡔࠢ࠲ࠗ࠻ߩᐩ㕙㑆㓒ߪ⁜ߊߥࠆ௑ะߦ
ߥࠆߎߣ߇⏕⹺ߐࠇߡ޿ࠆ 13)‫ޕ‬੹࿁ߩ⹜ᢱߦߟ޿ߡߪ㧘ࠛ࠴࡟ࡦࠣ࡝ࠦ࡯࡞ಣℂࠍⴕߞߚ⚿ᨐ㧘ోߡߩ⹜ᢱߦ߅޿ߡࠢ
ࡠ࡜ࠗ࠻߇ᷙวߒߡ޿ߥ޿ࠬࡔࠢ࠲ࠗ࠻ߩᐩ㕙㑆㓒(㧩16.5[Å])ߣ߶ߣࠎߤหߓߢ޽ࠅ㧘ࠢࡠ࡜ࠗ࠻ߩࠃ߁ߥ㕖⤘Ả☼࿯㋶‛߇ᷙวߒߡ޿ߥ޿ࠬࡔࠢ࠲ࠗ࠻ߢ޽ࠆߣ⠨߃ࠄࠇࠆ‫ޕ‬
5. ߅ࠊࠅߦ
࿶❗ࡌࡦ࠻࠽ࠗ࠻ਛߢߩ὇⚛㍑ߩ㐳ᦼ⊛ߥ⣣㘩᜼േࠍ⹏ଔߔࠆߚ߼㧘⓸⚛㔓࿐᳇ਅߦ߅
޿ߡੱᎿᶏ᳓߅ࠃ߮ੱᎿ࿾ਅ᳓ࠍ↪޿㧘50͠߅ࠃ߮ 80͠ߢߩ 10 ᐕ㑆ߦࠊߚࠆᶐẃ⹜㛎߇ⴕࠊࠇߚ‫⺞ᧄޕ‬ᩏߢߪ㧘ߎߩᶐẃ⹜㛎ᓟߩ࿶❗ࡌࡦ࠻࠽ࠗ࠻ࠍኻ⽎ߣߒ㧘ߎࠇ߹ߢߩࡃ࠶
࠴♽⹜㛎ߢ⹺߼ࠄࠇߚࠃ߁ߥࠬࡔࠢ࠲ࠗ࠻ߩ Fe ဳൻ߿㕖⤘Ảᕈ☼࿯㋶‛߳ߩᄌൻ╬ߩ㋕㧙

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ࡌࡦ࠻࠽ࠗ࠻⋧੕૞↪ߦࠃࠆࡌࡦ࠻࠽ࠗ࠻ߩᄌ⾰᜼േࠍ⺞ᩏߒߚ‫⹜ޕ‬㛎ߩ⚿ᨐࠍએਅߦ߹
ߣ߼ࠆ‫ޕ‬
࡮ੱᎿᶏ᳓߅ࠃ߮ੱᎿ࿾ਅ᳓ߦ߅ߌࠆ⹜㛎ᓟߩ࿶❗ࡌࡦ࠻࠽ࠗ࠻ࠍᲧセߒߚ႐ว㧘ੱᎿᶏ᳓ߦᶐẃߐࠇߡ޿ߚ⹜ᢱߢߪ㧘ੱᎿ࿾ਅ᳓ߩ႐วߦᲧߴߡ㧘὇⚛㍑ߩ⣣㘩ߦ઻޿↢ߓߚ㋕ࠗࠝࡦ߇ࠃࠅ࿶❗ࡌࡦ࠻࠽ࠗ࠻ౝㇱߦ߹ߢ⒖ⴕߒߡ޿ߚ‫ޕ‬࡮ੱᎿᶏ᳓㧔80͠㧕ߦ߅ߌࠆ⹜㛎ᓟ⹜ᢱߩ TEM ⷰኤߢߪ㧘☼࿯㋶‛ߩ․ᓽߢ޽ࠆጀ⁁᭴ㅧ߇⏕⹺ߐࠇߚ‫ߚ߹ޕ‬㧘ጀ㑆ߪ⚂ 12[Å]ߢ޽ࠅ㧘ㅢᏱߩ 2㧦1 ဳࠬࡔࠢ࠲ࠗ࠻ߩጀ㑆ߣห᭽ߢ޽ߞߚ‫ޕ‬ᓥߞߡ㧘⹜㛎೨ᓟߢࠬࡔࠢ࠲ࠗ࠻ߪᄌ⾰ߒߡ޿ߥ޿ߣផኤߐࠇߚ‫ޕ‬࡮⓸⚛㔓࿐᳇ਅߣᄢ᳇㔓࿐᳇ਅߢⴕࠊࠇߚ⹜㛎⚿ᨐࠍᲧセߔࠆߣ㧘⓸⚛㔓࿐᳇ਅߢߪ㧘὇⚛㍑ߩ⣣㘩ߦ઻޿↢ߓߚ㋕ࠗࠝࡦ߇࿶❗ࡌࡦ࠻࠽ࠗ࠻ౝㇱߦ⒖ⴕߒߡ޿ࠆߩߦኻߒ㧘ᄢ᳇㔓࿐᳇ਅߢߪ㧘㋕ࠗࠝࡦߪ߶ߣࠎߤ࿶❗ࡌࡦ࠻࠽ࠗ࠻ౝㇱߦ⒖ⴕߒߡ޿ߥ߆ߞߚ‫ޕ‬࡮ᶐẃṁᶧߩ pH ߪ⓸⚛㔓࿐᳇ਅߢߩ⹜㛎ߢߪೋᦼ pH ࠃࠅ㜞ߊߥࠆ௑ะߦ޽ࠅ㧘ᄢ᳇㔓࿐᳇ਅߢߩ⹜㛎ߢߪૐߊߥࠆ௑ะߦ޽ߞߚ‫ޕ‬࡮EPMA ಽᨆߩ⚿ᨐ㧘࿶❗ࡌࡦ࠻࠽ࠗ࠻ਛߦ⒖ⴕߒߚ㋕ߩᦨᄢᷓߐߪ⚂ 0.2mm ߢ޽ߞߚ‫ޕ‬࡮㋕ߩ⒖ⴕ߇⹺߼ࠄࠇߚ࿶❗ࡌࡦ࠻࠽ࠗ࠻ࠍኻ⽎ߦ XRD ಽᨆࠍⴕߞߚ⚿ᨐ㧘࿶❗ࡌࡦ࠻࠽ࠗ࠻ਛߦߪ㋕ߩ⣣㘩↢ᚑ‛ߣផቯߐࠇࠆ߽ߩߪᬌ಴ߐࠇߥ߆ߞߚ‫ߚ߹ޕ‬㧘XRD ಽᨆ⚿ᨐ߆ࠄ㧘ࡌࡦ࠻࠽ࠗ࠻ਛߩ☼࿯㋶‛ߪ 2㧙౎㕙૕᭴ㅧࠍ␜ߒ㧘ߐࠄߦḨᐲ೙ᓮਅߢߩ
᷹ቯߢߪ㧘Na ဳࠬࡔࠢ࠲ࠗ࠻ߣห᭽ߥ⤘Ảᕈࠍ␜ߒߚ‫ࠄ߆ߣߎߩࠄࠇߎޕ‬㧘⹜㛎೨ߩNa ဳࠬࡔࠢ࠲ࠗ࠻ߪ㧘⹜㛎ᓟ߽ᄌൻߒߡ޿ߥ߆ߞߚߣផቯߐࠇߚ‫ޕ‬ߎࠇ߹ߢߦ㧘㋕౒ሽਅߢߩࡌࡦ࠻࠽ࠗ࠻ߩᄌ⾰᜼േࠍᛠីߔࠆߚ߼㧘᷷ᐲ㧘ṁᶧ᧦ઙ߅ࠃ߮⹜㛎ᦼ㑆╬ࠍᄌ߃㧘ࡃ࠶࠴♽ߢߩ⹜㛎ࠍታᣉߒߡ߈ߚ‫⚿ߩࠄࠇߘޕ‬ᨐߢߪ㧘ೋᦼߩ Naဳࠬࡔࠢ࠲ࠗ࠻ߩ Fe ဳൻ߿ᓸ㊂ߩ㕖⤘Ảᕈ☼࿯㋶‛߳ߩᄌൻ╬㧘૗ࠄ߆ߩᄌൻ߇⹺߼ࠄࠇ
ߚ‫ࠄ߇ߥߒ߆ߒޕ‬㧘੹࿁⺞ᩏࠍⴕߞߚ࿶❗♽ߢߩ⹜㛎ᓟ⹜ᢱߢߪ㧘࿶❗ࡌࡦ࠻࠽ࠗ࠻߳ߩ
㋕ߩ⒖ⴕߪ⏕⹺ߐࠇߚ߽ߩߩ㧘ೋᦼߩ Na ဳࠬࡔࠢ࠲ࠗ࠻ߦᄌൻߪ↢ߓߡ޿ߥ޿ߣផቯߐࠇ
ߚ‫ߡߞ߇ߚߒޕ‬㧘ಣಽⅣႺߩࠃ߁ߥ࿶❗♽ߦ߅ߌࠆ㋕㧙ࡌࡦ࠻࠽ࠗ࠻⋧੕૞↪ߦࠃࠆᓇ㗀ࠍ⹏ଔߔࠆ਄ߢߪ㧘ࡃ࠶࠴♽ߢߩ⹜㛎⚿ᨐࠍߘߩ߹߹ㆡ↪ߔࠆߩߢߪߥߊ㧘࿶❗♽ߢ↢ߕࠆ⃻⽎ࠍචಽߦℂ⸃ߒߚ਄ߢ⹏ଔߔࠆߎߣ߇㊀ⷐߢ޽ࠆ‫ޕ‬⻢ㄉ 10 ᐕ㑆㧘὇⚛㍑ߣធߒߡ޿ߚࡌࡦ࠻࠽ࠗ࠻ߩᄌ⾰᜼േ⺞ᩏࠍታᣉߔࠆߦ޽ߚߞߡ㧘࿾ጀಣಽ⎇ⓥ㐿⊒ㇱ㐷࠾ࠕࡈࠖ࡯࡞࠼⎇ⓥࠣ࡞࡯ࡊߩ⼱ญ⋥᮸᳁㧘Ꮉፒቇ᳁߅ࠃ߮࿾ጀಣಽ⎇ⓥ㐿⊒ㇱ㐷 TRU ࠣ࡞࡯ࡊᧄ↰᣿᳁ߦߪ㧘ࡌࡦ࠻࠽ࠗ࠻⹜ᢱࠍឭଏߒߡ㗂޿ߚ‫ߚ߹ޕ‬㧘⹜ᢱណขᤨߦߪᓮදജ߅ࠃ߮ᓮഥ⸒ࠍߒߡ㗂޿ߚ‫ޕ‬ᢥㇱ⑼ቇ⋭⑼ቇᛛⴚ࡮ቇⴚ᡽╷ዪේሶജ቟
ో⺖ߩᩊ↰㓷ඳ᳁ߦߪಽᨆࠍⴕ߁ߦ޽ߚߞߡᓮഥ⸒ࠍ㗂޿ߚ‫ޕ‬ⅣႺᛛⴚ▤ℂㇱಣಽᛛⴚ⺖ߩਭ଻↰ḩ᳁ߦߪ TEM㧛EDS ಽᨆߦ߅޿ߡᓮදജߒߡ㗂޿ߚ‫ߚ߹ޕ‬㧘ห⺖ߩᄢౝ␭ม᳁ߦ
ߪ EPMA ಽᨆߦ߅޿ߡᓮදജߒߡ㗂޿ߚ‫ޕ‬ౣಣℂᛛⴚ㐿⊒࠮ࡦ࠲࡯ᛛⴚ㐿⊒ㇱߩ㑐సᏆ᳁

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ߦߪ EPMA ಽᨆߩ೨ಣℂߦ߅޿ߡᓮදജߒߡ㗂޿ߚ‫ߡߒ⸥ߦߎߎޕ‬ᗵ⻢ߩᗧࠍ⴫ߒ߹ߔ‫ޕ‬ෳ⠨ᢥ₂1) ᩭΆᢱࠨࠗࠢ࡞㐿⊒ᯏ᭴㧦̌ࠊ߇࿖ߦ߅ߌࠆ㜞࡟ࡌ࡞᡼኿ᕈᑄ᫈‛࿾ጀಣಽߩᛛⴚ⊛ା㗬ᕈ㧙࿾ጀಣಽ㐿⊒╙ 2 ᰴขࠅ߹ߣ߼㧙ಽౠ 3 ࿾ጀಣಽࠪࠬ࠹ࡓߩ቟ో⹏ଔ̍㧘ᩭΆᢱࠨࠗ
ࠢ࡞㐿⊒ᯏ᭴ ᛛⴚ⾗ᢱ㧘JNC TN1400 99-23 (1999).
2) ᩊ↰㓷ඳ㧘╣ᧄᐢ㧘␹ᓼᢘ㧘ᴤ੗ਃ๺㧦̌✭ⴣ᧚ߩ㐳ᦼ቟ቯᕈ⹏ଔᛛⴚߩ⃻⁁̍㧘ᩭΆᢱࠨࠗࠢ࡞㐿⊒ᯏ᭴ ᛛⴚ⾗ᢱ㧘JMC TN8400 2004-010 (2004).
3) G. Kamei, C. Oda, S. Mitsui, M. Shibata and T. Shinozaki : “Fe(II)-Na Ion Exchange
at Interlayers of Smectite : Adsorption-Desorption Experiments and a Natural
Analogue”, Engineering Geology,vol.54, pp.15-20 (1999).
4) 㒻ጊᔘብ㧘ᩊ↰㓷ඳ㧘╣ᧄᐢ㧦̌㋕ဳൻࡌࡦ࠻࠽ࠗ࠻᳓ᾲ⹜㛎㧙ૐ㉄⚛㔓࿐᳇ߢߩ㜞᷷᧦ઙਅߦ߅ߌࠆ㋕ဳൻࡌࡦ࠻࠽ࠗ࠻ߩᄌൻߩหቯ̍㧘ᣣᧄේሶജ⎇ⓥ㐿⊒ᯏ᭴ ᛛⴚ⾗ᢱ㧘
JAEA-Research 2006-064 (2006).
5) 㒻ጊᔘብ㧘ᩊ↰㓷ඳ㧘਄㊁ஜ৻㧘╣ᧄᐢ㧦̌㋕ဳൻࡌࡦ࠻࠽ࠗ࠻᳓ᾲ⹜㛎(II)㧙ૐ㉄⚛㔓࿐᳇㧘150͠ߦ߅ߌࠆ㋕ဳൻࡌࡦ࠻࠽ࠗ࠻ߩᄌൻߩหቯ̍㧘ᣣᧄේሶജ⎇ⓥ㐿⊒ᯏ᭴ ᛛⴚ⾗ᢱ㧘JAEA-Research 2007-018 (2007).
6) ⼱ญ⋥᮸㧘Ꮉፒቇ㧘ౝ⮮቞ᱜ㧦̌✭ⴣ᧚ਛߦ߅ߌࠆ὇⚛㍑ߩ⣣㘩᜼േߩታ㛎⊛ᬌ⸛-Σ㧙10 ᐕ㑆ߩᶐẃ⹜㛎⚿ᨐߦၮߠߊ⣣㘩ㅴዷ᜼േߩᬌ⸛㧙̍㧘ᣣᧄේሶജ⎇ⓥ㐿⊒ᯏ᭴㧘
JAEA-Research 2008-011 (2008).
7) േജἹ࡮ᩭΆᢱ㐿⊒੐ᬺ࿅㧦̌㜞࡟ࡌ࡞᡼኿ᕈᑄ᫈‛࿾ጀಣಽ⎇ⓥ㐿⊒ߩᛛⴚႎ๔ᦠ㧙ᐔ
ᚑ 3 ᐕᐲ㧙̍㧘േജἹ࡮ᩭΆᢱ㐿⊒੐ᬺ࿅ ᛛⴚ⾗ᢱ PNC TN1410 92-081 (1992).
8) ᣣᧄࡌࡦ࠻࠽ࠗ࠻ᎿᬺળᮡḰ⹜㛎ᣇᴺ㧦̌ࡌࡦ࠻࠽ࠗ࠻(☳ᧃ)ߩ㓁ࠗࠝࡦ੤឵ኈ㊂(CEC)
᷹ቯᣇᴺ㧘JBAS㧙106㧙77(1977).
9) ⍹Ꮉඳਭ㧘㑆㊁ᱜ㧘દ⮮㓷๺㧘ጟᧄ⌀↱⟤㧘ᩊ↰㓷ඳ㧘૒‫ᧁޘ‬ᐽ㓶㧘სේᔀ㧘㋈ᧁ໪ਃ㧘ᷰㄝ㓉㧦̌ࡌࡦ࠻࠽ࠗ࠻ߩ㋶‛⚵ᚑಽᨆ̍㧘േജἹ࡮ᩭΆᢱ㐿⊒੐ᬺ࿅ ᛛⴚ⾗ᢱ㧘PNC
TN8430 93-003 (1993).
10) T. Ishidera, K. Ueno and T. Suyama : “Investigation of Montmorillonite Altaration
and Form of Iron Corrosion Products in Compacted Bentonite in Contact with Carbon
Steel for Ten Years”, Clays in Natural&Engineered Barriers for Radioactive Waste
Confinement, September 17-20, LILLE 3rd International Meeting abstracts, p.269(2007).
11) ਅ↰ฝ㧦̌☼࿯㋶‛⎇ⓥᴺ̍㧘ഃㅧ␠ (1985).
12) ೨㊁᣽ᒄ㧦̌☼࿯ߩ⑼ቇ̍㧘ᣣೀᎿᬺᣂ⡞␠ (1993).
13) ᷰㄝ㓉㧦
̌Chlorite/Saponite ᷙวጀ㋶‛ߩ X ✢࿁᛬✢ࡊࡠࡈࠔࠗ࡞̍
㧘਻ᄢℂ⎇ႎ(࿾⾰)㧘
12 Ꮞ 3 ภ㧘pp.303-309 (1977).

11

 

⴫ 㪉㪅㪈㩷 ὇⚛㍑⹜㛎䈱ൻቇ⚵ᚑ㩷

᧚ᢱ㩷

㪚㩷

㪤㫅

㪪㫀㩷

㪪㩷

㪧㩷

㪪㪤㪋㪇㪇㪙㩿㪡㪠㪪㩷㪞㪊㪉㪇㪉㪀

㪇㪅㪈㪊

㪇㪅㪍㪐

㪇㪅㪈㪐

㪇㪅㪇㪇㪎

㪇㪅㪇㪈㪈㩷⴫ 㪉㪅㪉㩷 ⹜㛎䈮↪䈇䈢ṁᶧ䈱⚵ᚑ㩷 㪲㫄㫆㫃㪆㪣㪴
ᚑಽ㩷
㪥㪸㪂㩷
㪢㪂㩷
㪚㪸㪉㪂㩷
㪤㪾㪉㪂㩷
㪚㫃㪄㩷
㪪㪦㪋㪉㪄㩷
㪟㪚㪦㪊㪄㩷
㪝㪄㩷㪙㫉㪄㩷㪙㪦㪊㪊㪄㩷
㪪㫉㪉㪂㩷
㫇㪟㩷

ੱᎿᶏ᳓
㪋㪅㪏㬍㪈㪇㪄㪈㩷㪈㪅㪇㬍㪈㪇㪄㪉
㪈㪅㪇㬍㪈㪇㪄㪉
㪌㪅㪌㬍㪈㪇㪄㪉
㪌㪅㪍㬍㪈㪇㪄㪈㩷㪉㪅㪐㬍㪈㪇㪄㪉㩷㪉㪅㪋㬍㪈㪇㪄㪊㩷㪎㪅㪋㬍㪈㪇㪄㪌㩷㪏㪅㪍㬍㪈㪇㪄㪋㩷㪋㪅㪋㬍㪈㪇㪄㪋㩷㪎㪅㪇㬍㪈㪇㪄㪋㩷㪎㪅㪐䌾㪏㪅㪋㩷

ੱᎿ࿾ਅ᳓䋭㪈㩷
㪍㪅㪍㬍㪈㪇㪄㪈㩷䋭㩷䋭㩷䋭㩷㪌㪅㪍㬍㪈㪇㪄㪈㩷䋭㩷㪈㪅㪇㬍㪈㪇㪄㪈㩷
䋭㩷
䋭㩷
䋭㩷
䋭㩷
㪏㪅㪊䌾㪏㪅㪎㩷

ੱᎿ࿾ਅ᳓䋭㪉㩷
㪌㪅㪇㬍㪈㪇㪄㪊㩷䋭㩷䋭㩷䋭㩷㪉㪅㪌㬍㪈㪇㪄㪊㩷䋭㩷㪉㪅㪌㬍㪈㪇㪄㪊㩷
䋭㩷
䋭㩷
䋭㩷
䋭㩷
㪐㪅㪈䌾㪐㪅㪉㩷

㩷⴫ 㪉㪅㪋㩷 ⹜㛎᧦ઙ㩷
㪥㫆㪅㩷

⹜㛎ṁᶧ㩷

᷷ᐲ㩿㷄㪀

㔓࿐᳇

✭ⴣ᧚㩷
㪁㪁㪁

⹜㛎 㩷

㪈㩷
ੱᎿᶏ᳓㩷
㪏㪇㩷
⓸⚛㩷 㪟㩷㪊 ઀᭽㪪㪤㪋㪇㪇㪙㩷
㪁㪁㪁
㪉㩷
ੱᎿᶏ᳓㩷
㪌㪇㩷
⓸⚛㩷 㪟㩷㪊 ઀᭽㪪㪤㪋㪇㪇㪙㩷㪊㩷 ੱᎿ࿾ਅ᳓㪄㪈㪁㩷㪏㪇㩷⓸⚛㩷 㪟㩷㪊 ઀᭽㪁㪁㪁㪪㪤㪋㪇㪇㪙㩷㪁㪁㪁㪁㪁㪋㩷 ੱᎿ࿾ਅ᳓㪄㪉 㩷㪏㪇㩷⓸⚛㩷 㪟㩷㪊 ઀᭽㪪㪤㪋㪇㪇㪙㩷
㪌㩷
ੱᎿᶏ᳓㩷
㪏㪇㩷
ᄢ᳇㩷 㪟㩷㪊 ઀᭽㪁㪁㪁㪪㪤㪋㪇㪇㪙㩷
㪍㩷
ੱᎿᶏ᳓㩷
㪏㪇㩷
⓸⚛㩷
㪢㫌㫅㫀㫇㫀㪸㪄㪝㪪㪤㪋㪇㪇㪙㩷
㪁ੱᎿᶏ᳓㪄㪈䋺㪲㪟㪚㪦㪊㪄㪴㪔㪈㪅㪇㬍㪈㪇㪄㪈㩿㪤㪀䋬㪲㪥㪸㪂㪴㪔㪍㪅㪍㬍㪈㪇㪄㪈㩿㪤㪀㩷㪁㪁ੱᎿᶏ᳓㪄㪉䋺㪲㪚㫃㪄㪴㪔㪉㪅㪌㬍㪈㪇㪄㪊㩿㪤㪀䋬㪲㪟㪚㪦㪊㪄㪴㪔㪉㪅㪌㬍㪈㪇㪄㪊㩿㪤㪀䋬㪲㪥㪸㪂㪴㪔㪌㪅㪇㬍㪈㪇㪄㪊㩿㪤㪀㩷㪁㪁㪁㪟㩷㪊 ઀᭽䋺╙ 㪈 ᰴข䉍䉁䈫䉄✭ⴣ᧚઀᭽䉕ᗐቯ䋺ੇ῎ኒᐲ 㪈㪅㪏㪲㪤㪾㪆㫄㪊㪴䋬㪈㪇㪇㩼䉪䊆䉭䊦 㪭㪈

12

 

⴫ 㪋㪅㪉㩷 ᶐẃṁᶧಽᨆ⚿ᨐ㩷 㪲㫄㫆㫃㪆㪣㪴㩷
㩷㩷
㪥㪸㩷
㪢㩷
㪚㪸㩷
㪤㪾㩷
㪝㪼㩷
㩿㪝㪼㪉㪂㪀㩷
㪘㫃㩷
㪪㫀㩷
㪚㫃㪄㩷

㪪㪮䋭㪏㪇㷄㩷
䋭㩷
䋭㩷
䋭㩷
䋭㩷

㪪㪮䋭㪌㪇㷄
㪋㪅㪎㪋㬍㪈㪇㪄㪈㪈㪅㪋㪇㬍㪈㪇㪄㪉㪈㪅㪇㪉㬍㪈㪇㪄㪉㪌㪅㪉㪉㬍㪈㪇㪄㪉䋭㩷㪏㪅㪐㪌㬍㪈㪇㪄㪎㪁

䋭㩷
䋭㩷
䋭㩷

㪓㪈㪅㪏㪌㬍㪈㪇㪄㪌㪋㪅㪏㪈㬍㪈㪇㪄㪋㪌㪅㪏㪋㬍㪈㪇㪄㪈㪞㪮䋭㪈䋭㪏㪇㷄
㪎㪅㪇㪌㬍㪈㪇㪄㪈㩷㪈㪅㪎㪊㬍㪈㪇㪄㪊㩷㪉㪅㪇㪇㬍㪈㪇㪄㪌㩷㪏㪅㪉㪊㬍㪈㪇㪄㪍㩷㪈㪅㪋㪊㬍㪈㪇㪄㪌㪁㩷㩿㪈㪅㪇㪎㬍㪈㪇㪄㪌㪀㪁㩷㪓㪈㪅㪏㪌㬍㪈㪇㪄㪌㩷㪊㪅㪌㪉㬍㪈㪇㪄㪊㩷㪍㪅㪏㪏㬍㪈㪇㪄㪈㩷㪪㪦㪋㪉㪄㩷

䋭㩷㪉㪅㪍㪉㬍㪈㪇㪄㪉㪋㪅㪇㪍㬍㪈㪇㪄㪊㩷㪊㪅㪉㪌㬍㪈㪇㪄㪊㩷㪉㪅㪋㪊㬍㪈㪇㪄㪉㩷㫇㪟㩷㪍㪅㪏㩿䊔䊮䊃䊅䉟䊃⴫㕙㪀㩷㪏㪅㪍㪎㩷㪈㪇㪅㪇㪏㩷

㪐㪅㪌㪇㩷

㪎㪅㪊㪇㩷

䋭㩷

㪈㪇㪏㩷

㪄㪈㪈㪇㩷

㪄㪉㪍㪎㩷

㪈㪌㪈㩷

㪜㪿㩷㩿㫄㪭㪀㩷

㪞㪮䋭㪉䋭㪏㪇㷄㩷 㪪㪮䋭㪏㪇㷄ᄢ᳇㩷㪈㪅㪎㪐㬍㪈㪇㪄㪉㩷㪋㪅㪎㪇㬍㪈㪇㪄㪈㩷㪐㪅㪉㪈㬍㪈㪇㪄㪌㩷㪈㪅㪊㪏㬍㪈㪇㪄㪊㩷㪄㪌㪈㪅㪎㪌㬍㪈㪇 㩷㪈㪅㪉㪈㬍㪈㪇㪄㪉㩷㪋㪅㪈㪈㬍㪈㪇㪄㪍㩷㪋㪅㪋㪋㬍㪈㪇㪄㪉㩷㪎㪅㪈㪍㬍㪈㪇㪄㪎㪁㩷䋭㩷㩿㪈㪅㪎㪐㬍㪈㪇㪄㪎㪀㩷㪁㩷㪄㪌㪓㪈㪅㪏㪌㬍㪈㪇 㩷㪊㪅㪌㪌㬍㪈㪇㪄㪉㩷㪉㪅㪈㪋㬍㪈㪇㪄㪊㩷㪓㪈㪅㪉㪌㬍㪈㪇㪄㪌㩷㪄㪊㪉㪅㪎㪊㬍㪈㪇 㩷㪌㪅㪈㪍㬍㪈㪇㪄㪈㩷㪁ᶐẃṁᶧ䈱 㫇㪟 䉕 㪊䌾㪋 䈮⺞ᢛᓟ᷹ቯ⴫ 㪋㪅㪊㪅㪈䋭㪈㩷 㓁䉟䉥䊮੤឵ኈ㊂䈍䉋䈶ᶐ಴㓁䉟䉥䊮ಽᨆ⚿ᨐ㩿ᧂᄌ⾰ㇱ㪀㪲㫄㪼㫈㪆㪈㪇㪇㪾㪴㩷㩷㩷㪪㪮㪄㪏㪇㷄㩷
㪪㪮㪄㪌㪇㷄㩷
㪞㪮㪄㪈㪄㪏㪇㷄㩷㪞㪮㪄㪉㪄㪏㪇㷄㩷㪪㪮㪄㪏㪇㷄㩷 㪘㫀㫉㩷㪪㪮㪄㪏㪇㷄㩷 㪢㫌㫅㫀㫇㫀㪸㪄㪝㩷㪢㫌㫅㫀㪾㪼㫃㩷㪭㪈㪐㪀㩷㪢㫌㫅㫀㫇㫀㪸䋭㪝㪐㪀㩷

㪥㪸㩷
㪋㪏㪅㪍㩷
㪋㪈㪅㪈㩷
㪍㪋㪅㪌㩷
㪋㪋㪅㪎㩷
㪊㪋㪅㪌㩷
㪏㪏㪅㪍㩷
㪌㪉㪅㪋㩷
㪈㪈㪋㪅㪐㩷

㪢㩷
㪋㪅㪌㩷
㪊㪅㪐㩷
㪉㪅㪇㩷
㪈㪅㪌㩷
㪊㪅㪎㩷
㪋㪅㪎㩷
㪈㪅㪊㩷
㪈㪅㪈㩷

㪤㪾㩷
㪈㪇㪅㪋㩷
㪉㪊㪅㪐㩷
㪉㪅㪊㩷
㪉㪅㪍㩷
㪉㪎㪅㪌㩷
㪈㪍㪅㪋㩷
㪍㪅㪍㩷
㪉㪅㪍㩷

㪚㪸㩷
㪉㪇㪅㪍㩷
㪊㪈㪅㪈㩷
㪌㪊㪅㪏㩷
㪋㪊㪅㪈㩷
㪈㪌㪅㪎㩷
㪈㪇㪅㪌㩷
㪋㪈㪅㪐㩷
㪉㪇㪅㪍㩷

㪫㫆㫋㪸㫃㩷㪏㪋㪅㪈㩷㪈㪇㪇㩷㪈㪉㪉㪅㪍㩷㪐㪈㪅㪐㩷㪏㪈㪅㪋㩷㪈㪉㪇㪅㪉㩷
㪈㪇㪋㪅㪋㩷
㪈㪊㪐㪅㪉㩷

㪚㪜㪚㩷㪌㪏㪅㪍㩷 㩷㪌㪌㪅㪍㩷 㩷㪍㪈㪅㪐㩷 㩷㪌㪏㪅㪍㩷 㩷㪌㪍㪅㪊㩷 㩷㪈㪈㪈㪅㪉㩷 㩷㪌㪉㪅㪋㩷 㩷㪈㪈㪍㪅㪌㩷 㩷⴫ 㪋㪅㪊㪅㪈䋭㪉㩷 ࿕⋧䈱ൻቇ⚵ᚑ㩿ᧂᄌ⾰ㇱ㪀㪲㩼㪴㩷㩷㪪㫀㪦㪉㩷㪘㫃㪉㪦㪊㩷
㪝㪼㪉㪦㪊㩷
㪫㫀㪦㪉㩷
䌍䌧㪦㩷
㪚㪸㪦㩷
㪥㪸㪉㪦㩷
㪢㪉㪦㩷
㪠㪾㪄㫃㫆㫊㫊㩷
㪲䋦㪴㩷㪫㫆㫋㪸㫃㩷
㪚㫃㩷㪪㪦㪊㩷㪪㪮㪄㪏㪇㷄㩷 㪪㪮㪄㪌㪇㷄 㪞㪮㪄㪈㪄㪏㪇㷄㩷 㪞㪮㪄㪉㪄㪏㪇㷄㪪㪮㪄㪏㪇㷄 㪪㪮㪄㪏㪇㷄ᄢ᳇㩷㪢㫌㫅㫀㫇㫀㪸㪄㪝㪢㫌㫅㫀㪾㪼㫃㩷㪭㪈㪐㪀㩷 㪢㫌㫅㫀㫇㫀㪸䋭㪝㪐㪀㩷㪍㪐㪅㪍㩷 㩷㪈㪋㪅㪏㩷 㩷㪉㪅㪍㪌㩷 㩷㪇㪅㪈㪏㩷 㩷㪉㪅㪉㪋㩷 㩷㪈㪅㪋㪉㩷 㩷㪈㪅㪏㪇㩷 㩷㪇㪅㪋㪏㩷 㩷㪍㪐㪅㪉㩷 㩷㪈㪋㪅㪈㩷 㩷㪉㪅㪋㪈㩷 㩷㪇㪅㪈㪏㩷 㩷㪉㪅㪈㪇㩷 㩷㪉㪅㪉㪐㩷 㩷㪈㪅㪊㪌㩷 㩷㪇㪅㪌㪈㩷 㩷㪍㪐㪅㪉㩷 㩷㪈㪋㪅㪉㩷 㩷㪈㪅㪐㪏㩷 㩷㪇㪅㪈㪎㩷 㩷㪉㪅㪇㪐㩷 㩷㪉㪅㪎㪌㩷 㩷㪉㪅㪍㪉㩷 㩷㪇㪅㪊㪊㩷 㩷㪍㪐㪅㪏㩷 㩷㪈㪋㪅㪍㩷 㩷㪉㪅㪈㪋㩷 㩷㪇㪅㪈㪏㩷 㩷㪉㪅㪇㪈㩷 㩷㪉㪅㪎㪊㩷 㩷㪈㪅㪏㪏㩷 㩷㪇㪅㪊㪌㩷 㩷㪍㪐㪅㪎㩷 㩷㪈㪋㪅㪉㩷 㩷㪉㪅㪋㪋㩷 㩷㪇㪅㪈㪎㩷 㩷㪉㪅㪍㪈㩷 㩷㪈㪅㪍㪊㩷 㩷㪈㪅㪉㪊㩷 㩷㪇㪅㪌㪋㩷 㩷㪍㪈㪅㪊㩷 㩷㪉㪊㪅㪋㩷 㩷㪉㪅㪌㪌㩷 㩷㪇㪅㪈㪌㩷 㩷㪉㪅㪏㪎㩷 㩷㪇㪅㪋㪇㩷 㩷㪉㪅㪇㪊㩷 㩷㪇㪅㪉㪊㩷 㩷㪎㪇㪅㪎㩷 㩷
㪈㪊㪅㪏㩷
㪈㪅㪋㪐㩷
㪇㪅㪉㪇㩷
㪉㪅㪉㪍㩷
㪉㪅㪊㪇㩷
㪉㪅㪌㪍㩷
㪇㪅㪊㪊㩷

㪍㪈㪅㪊㩷 㩷㪉㪈㪅㪐㩷 㩷
㪈㪅㪎㪏㩷
㪇㪅㪈㪋㩷
㪊㪅㪉㪋㩷
㪇㪅㪌㪈㩷
㪊㪅㪋㪉㩷
㪇㪅㪈㪇㩷

㪍㪅㪏㪊㩷 㩷㪎㪅㪏㪉㩷 㩷㪍㪅㪍㪌㩷 㩷㪍㪅㪊㪉㩷 㩷㪎㪅㪋㪋㩷 㩷㪎㪅㪇㪎㩷 㩷㪄㩷㪄㩷㪈㪇㪇㪅㪇㩷 㩷㪇㪅㪊㪉㩷 㩷㪈㪅㪇㪋㩷 㩷㪈㪇㪇㪅㪇㩷
㪇㪅㪉㪏㩷 㩷㪇㪅㪐㪇㩷 㩷㪈㪇㪇㪅㪇㩷 㩷㪇㪅㪊㪉㩷 㩷㪇㪅㪏㪍㩷 㩷㪈㪇㪇㪅㪇㩷 㩷㪇㪅㪇㪇㩷 㩷㪇㪅㪏㪌㩷 㩷㪈㪇㪇㪅㪇㩷
㪇㪅㪈㪌㩷 㩷㪇㪅㪏㪐㩷 㩷㪈㪇㪇㪅㪇㩷
㪇㪅㪉㪎㩷 㩷㪇㪅㪈㪇㩷 㩷㪐㪈㪅㪊㪏㩷
㪓㪇㪅㪇㪇㪈㩷
㪄㩷㪐㪉㪅㪊㪐㩷
㪇㪅㪊㪊㩷
㪄㩷

13

 

⴫ 㪋㪅㪊㪅㪉㩷 ጀ㑆㓁䉟䉥䊮ಽᨆ⚿ᨐ㩿ᧂᄌ⾰ㇱ㪀㪲㫄㪼㫈㪆㪈㪇㪇㪾㪴㩷㩷㩷㪪㪮䋭㪏㪇㷄㩷
㪪㪮䋭㪌㪇㷄㩷
㪞㪮䋭㪈䋭㪏㪇㷄㩷㪞㪮䋭㪉䋭㪏㪇㷄㩷㪪㪮䋭㪏㪇㷄ᄢ᳇㩷㪪㪮䋭㪏㪇㷄㩷 㪢㫌㫅㫀㫇㫀㪸䋭㪝㩷㪥㪸㩷㪊㪐㪍㪅㪋㩷
㪊㪋㪇㪅㪈㩷
㪊㪏㪐㪅㪎㩷
㪊㪈㪋㪅㪇㩷
㪉㪏㪉㪅㪎㩷
㪎㪏㪈㪅㪉㩷

㪢㩷㪉㪊㪅㪎㩷 㩷㪈㪐㪅㪐㩷 㩷㪌㪅㪍㩷 㩷
㪏㪅㪉㩷 㩷
㪉㪈㪅㪌㩷 㩷㪉㪈㪅㪇㩷 㩷

14

 

㪤㪾㩷
㪊㪍㪅㪏㩷 㩷㪍㪍㪅㪉㩷 㩷㪐㪅㪇㩷 㩷
㪈㪎㪅㪎㩷 㩷㪏㪌㪅㪍㩷 㩷㪉㪎㪅㪊㩷 㩷㪚㪸㩷㪌㪎㪅㪐㩷 㩷㪐㪋㪅㪊㩷 㩷㪐㪊㪅㪊㩷 㩷㪐㪎㪅㪍㩷 㩷㪍㪇㪅㪐㩷 㩷㪈㪍㪅㪍㩷 㩷㪝㪼㩿㪝㪼㪉㪂㪀㩷㪐㪅㪇㩿㪐㪅㪇㪀㩷㪈㪏㪅㪍㩿㪈㪏㪅㪈㪀㩷㪈㪅㪏㩿㪈㪅㪊㪀㩷㪈㪅㪈㩿㪈㪅㪈㪀㩷㪐㪅㪇㩿㪏㪅㪍㪀㩷 㩷㪇㪅㪌㪉䋨㪇㪅㪌㪇䋩㩷

㱢㪋㪋㫄㫄㩷ⓣ䈱䈅䉎䉼䉺䊮䉦䊋䊷

὇⚛㍑㩷

㪊㪇㫄㫄㩷

䋨㪊㪇㬍㪊㪇㬍㪉㫄㫄䋩㩷䉼䉺䊮䊗䊦䊃㩷

㪉㫄㫄䉶䊤䊚䉾䉪䊐䉞䊦䉺㩷㪈㪋㫄㫄䊁䊐䊨䊮䉴䊕䊷䉰䊷✭ⴣ᧚㩷䉼䉺䊮䉦䊤䊛㩷

䋨㱢㪋㪉㫄㫄㫏㪈㪋㫄㫄䋩㩷࿑ 㪉㪅㪌䋭㪈㩷 ✭ⴣ᧚ਛ䈮䈍䈔䉎὇⚛㍑䈱ᶐẃ⹜㛎䉦䊤䊛䈱ᮨᑼ࿑㪥㪉㩷 㔓࿐᳇䉫䊨䊷䊑䊗䉾䉪䉴㩷㩿㪦㪉㪾㪸㫊㪓㪈㫇㫇㫄㪀㩷㪧㪝㪘⵾ኈེ㩷ᕡ᷷ᮏᶐẃᶧ㩷⹜㛎䉦䊤䊛㩷࿑ 㪉㪅㪌䋭㪉㩷 ✭ⴣ᧚ਛ䈮䈍䈔䉎὇⚛㍑䈱ᶐẃ⹜㛎ᣇᴺ䈱ᮨᑼ࿑

15

 



⹜㛎䉦䊤䊛䈱૞⵾㩷㩿䊔䊮䊃䊅䉟䊃䋫⹜㛎 㪀㸢䉼䉺䊮䉦䊤䊛㩷࿶ኒᓟ䋬䉦䊤䊛䈱⬄䉕䊗䊦䊃䈪✦䉄䈧䈔䉎㔓࿐᳇೙ᓮ䉫䊨䊷䊑䊗䉾䉪䉴䈮៝౉㩿䉼䉺䊮䉦䊤䊛䋫⹜㛎ṁᶧ㪀㸢䊁䊐䊨䊮⵾䈱ኈེ䉫䊨䊷䊑䊗䉾䉪䉴ਛ䈱ᕡ᷷ᮏౝ䈮㕒⟎㩷㪥㪉 㔓࿐᳇㩷䋨㉄⚛Ớᐲ 㪈㫇㫇㫄 એਅ䋩છᗧᦼ㑆㕒⟎㩿㪈㪇 ᐕ㑆㪀䉼䉺䊮䉦䊤䊛䈱⸃૕⹜㛎䊔䊮䊃䊅䉟䊃

㩿὇⚛㍑㪀㩷
㪜㪧㪤㪘 ಽᨆ㩷㪪㪜㪤䋯㪜㪛㪪 ಽᨆ䈍䉋䈶㩷㪫㪜㪤䋯㪜㪛㪪 ಽᨆ㪚㪜㪚 ᷹ቯ㪯 ✢࿁᛬ಽᨆ
䊶ቯᣇ૏ಽᨆ㩷䊶ਇቯᣇ૏ಽᨆ
䊶Ḩᐲ೙ᓮಽᨆ䊶㪜㪞 ಣℂಽᨆጀ㑆䉟䉥䊮᛽಴㩷
䊶㈶㉄䉝䊮䊝䊆䉡䊛ᷝട࿕ᶧಽ㔌䋨㪈䋩㩷
䊶㆙ᔃಽ㔌䋨㪈㪉㪃㪇㪇㪇㫉㫇㫄䋬㪐㪇 ಽ䋩࿕ᶧಽ㔌䋨㪉䋩㩷
䊶㪇㪅㪋㪌P㫄 䊜䊮䊑䊧䊮䊐䉞䊦䉺䊷䊶㪈㪇㪃㪇㪇㪇㪤㪮㪚㪦 㒢ᄖ䉐ㆊ㩷࿑ 㪉㪅㪌䋭㪊㩷 ⹜㛎ో૕䈱䊐䊨䊷

㪘䋺ᵞᵺᶧኈེ㩷㪙 ᶐ಴▤㩷
ᶏ⍾㪂⹜ᢱ
੃ൻ䉐⚕
⍹⧷䉡䊷䊦
㪚 ฃེ

࿑ 㪊㪅㪈㩷 㓁䉟䉥䊮੤឵ኈ㊂ಽᨆⵝ⟎⇛࿑㩷

16

 

䉐ᶧ䈱Ớᐲಽᨆ㩷㩿㪚㪸㪃㪥㪸㪃㪢㪃㪤㪾㪃㪝㪼㪀㩷

㪪㫀

㪦

㪘㫃

㪥㪸

㪝㪼㩷
㪚㪸

㪈㪇P㫄
㪈㪇P㫄

࿑ 㪋㪅㪋㪅㪈䋭㪈㩷 㪪㪮䋭㪏㪇㷄⹜ᢱ䈱 㪪㪜㪤䋯㪜㪛㪪 ಽᨆ⚿ᨐ

㪪㫀
㪦

㪘㫌
㪤㪾

㪝㪼㩷
㪚㪸

㪈㪇P㫄

࿑ 㪋㪅㪋㪅㪈䋭㪉㩷 㪪㪮䋭㪌㪇㷄⹜ᢱ䈱 㪪㪜㪤䋯㪜㪛㪪 ಽᨆ⚿ᨐ

㪪㫀

㪦
㪘㫃
㪥㪸

㪤㪾
㪘㫌

㪝㪼㩷

㪈㪇P㫄

࿑ 㪋㪅㪋㪅㪈䋭㪊㩷 㪞㪮䋭㪈䋭㪏㪇㷄⹜ᢱ䈱 㪪㪜㪤䋯㪜㪛㪪 ಽᨆ⚿ᨐ

17

 



㪪㫀
㪦
㪘㫃
㪘㫌

㪤㪾

㪝㪼㩷

㪥㪸
㪚㪸
㪈㪇P㫄

࿑ 㪋㪅㪋㪅㪈䋭㪋㩷 㪞㪮䋭㪉䋭㪏㪇㷄⹜ᢱ䈱 㪪㪜㪤䋯㪜㪛㪪 ಽᨆ⚿ᨐ

㪪㫀
㪦
㪘㫌
㪤㪾

㪘㫃
㪚㪸

㪝㪼㩷

㪈㪇P㫄

࿑ 㪋㪅㪋㪅㪈䋭㪌㩷 㪪㪮䋭㪏㪇㷄ᄢ᳇᧦ઙ⹜ᢱ䈱 㪪㪜㪤䋯㪜㪛㪪 ಽᨆ⚿ᨐ

㪪㫀

㪦

㪘㫃

㪥㪸

㪤㪾
㪘㫌

㪚㪸

㪝㪼㩷

㪈㪇P㫄

࿑ 㪋㪅㪋㪅㪈䋭㪍㩷 㪪㪮䋭㪏㪇㷄㩷 㪢㫌㫅㫀㫇㫀㪸䋭㪝 ⹜ᢱ䈱 㪪㪜㪤䋯㪜㪛㪪 ಽᨆ⚿ᨐ

18

 

㪈㪇㫅㫄࿑ 㪋㪅㪋㪅㪉㩷 㪪㪮䋭㪏㪇㷄⹜ᢱ䈱䌔㪜㪤䋯㪜㪛㪪 ಽᨆ⚿ᨐ

19

 

㪝㪼㩷

㪈㪇㪇P㫄

- 20 - 
㪈㪇㪇P㫄㩷㪥㪸20㩷࿑ 㪋㪅㪌䋭㪉㩷 㪜㪧㪤㪘 䈮䉋䉎 㪪㪮䋭㪏㪇㷄⹜ᢱ䈱䊙䉾䊏䊮䉫ಽᏓ㪚㪸࿑ 㪋㪅㪌䋭㪈㩷 㪜㪧㪤㪘 䈮䉋䉎 㪪㪮䋭㪏㪇㷄⹜ᢱ䈱ᢿ㕙

㪈㪇㪇P㫄

㪈㪇㪇P㫄

㩷

JAEA-Data/Code 2008-0XX

㪝㪼㩷

㪈㪇㪇P㫄

- 21 - 
㪈㪇㪇P㫄㩷

㪥㪸

21

࿑ 㪋㪅㪌䋭㪋㩷 㪜㪧㪤㪘 䈮䉋䉎 㪞㪮䋭㪈䋭㪏㪇㷄⹜ᢱ䈱䊙䉾䊏䊮䉫ಽᏓ㪚㪸࿑ 㪋㪅㪌䋭㪊㩷 㪜㪧㪤㪘 䈮䉋䉎 㪞㪮䋭㪈䋭㪏㪇㷄⹜ᢱ䈱ᢿ㕙

㪈㪇㪇P㫄

㪈㪇㪇P㫄



JAEA-Data/Code 2008-0XX㪝㪼㩷- 22 - 
㪈㪇㪇P㫄㩷

㪥㪸

22

࿑ 㪋㪅㪌䋭㪍㩷 㪜㪧㪤㪘 䈮䉋䉎 㪪㪮䋭㪏㪇㷄ᄢ᳇᧦ઙ⹜ᢱ䈱䊙䉾䊏䊮䉫ಽᏓ

㪈㪇㪇P㫄

㪚㪸

࿑ 㪋㪅㪌䋭㪌㩷 㪜㪧㪤㪘 䈮䉋䉎 㪪㪮䋭㪏㪇㷄ᄢ᳇᧦ઙ⹜ᢱ䈱ᢿ㕙

㪈㪇㪇P㫄

㪈㪇㪇P㫄


JAEA-Data/Code 2008-0XX
㪈㪌㪇㪇

㪈㪉㪇㪇㪇

㪌㪐㪅㪐㪎㫦㩿㪈㪅㪌㪋㫻㪀㩷
㪈㪇㪇㪇㪇

㪈㪇㪇㪇

㪍㪈㪅㪐㪎㫦㩿㪈㪅㪌㪇㫻㪀㩷ᒝᐲ㩿㪺㫇㫊㪀

ᒝᐲ㩿㪺㫇㫊㪀

㪏㪇㪇㪇

㪍㪇㪇㪇

㪋㪇㪇㪇

㪌㪇㪇

㪉㪇㪇㪇

㪇
㪇㪅㪇㪇

㪊㪇㪅㪇

㪍㪇㪅㪇

㪇
㪌㪏㪅㪇

㪐㪇㪅㪇

㪌㪐㪅㪇

㪍㪇㪅㪇

㪉㱔㩿㪚㫌㪄㪢㪸㪀

㪍㪈㪅㪇

㪍㪉㪅㪇

㪍㪊㪅㪇

㪍㪋㪅㪇

㪉㱔㩿㪚㫌㪄㪢㪸㪀 ࿑ 㪋㪅㪍㪅㪈䋭㪈㩷 㪪㪮䋭㪏㪇㷄ᄌ⾰ㇱ⹜ᢱ䈱ਇቯᣇ૏᷹ቯ⚿ᨐ㩷

㪉㪌㪇㪇

㪉㪌㪇

㪉㪇㪇㪇

㪉㪇㪇

㪈㪌㪇㪇

㪈㪌㪇

ᒝᐲ㩿㪺㫇㫊㪀

ᒝᐲ㩿㪺㫇㫊㪀

㪌㪐㪅㪐㪉㫦㩿㪈㪅㪌㪋㫻㪀㩷

㪈㪇㪇㪇

㪌㪇㪇

㪇
㪇㪅㪇㪇

㪍㪈㪅㪐㪊㫦㩿㪈㪅㪌㪇㫻㪀㩷

㪈㪇㪇

㪌㪇

㪊㪇㪅㪇

㪉㱔㩿㪚㫌㪄㪢㪸㪀

㪍㪇㪅㪇

㪇
㪌㪏㪅㪇

㪐㪇㪅㪇

㪌㪐㪅㪇

㪍㪇㪅㪇

㪍㪈㪅㪇

㪉㱔㩿㪚㫌㪄㪢㪸㪀 ࿑ 㪋㪅㪍㪅㪈䋭㪉㩷 㪪㪮䋭㪏㪇㷄ᧂᄌ⾰ㇱ⹜ᢱ䈱ਇቯᣇ૏᷹ቯ⚿ᨐ㩷

23

 

㪍㪉㪅㪇

㪍㪊㪅㪇

㪍㪋㪅㪇


㪉㪇㪇㪇

㪉㪇㪇

㪌㪐㪅㪐㪏㫦㩿㪈㪅㪌㪋㫻㪀㩷㪈㪌㪇ᒝᐲ㩿㪺㫇㫊㪀

ᒝᐲ㩿㪺㫇㫊㪀

㪈㪌㪇㪇

㪈㪇㪇㪇

㪌㪇㪇

㪇
㪇㪅㪇㪇

㪍㪈㪅㪐㪎㫦㩿㪈㪅㪌㪇㫻㪀㩷

㪈㪇㪇

㪌㪇

㪊㪇㪅㪇

㪍㪇㪅㪇

㪇
㪌㪏㪅㪇

㪐㪇㪅㪇

㪌㪐㪅㪇

㪍㪇㪅㪇

㪍㪈㪅㪇

㪍㪉㪅㪇

㪍㪊㪅㪇

㪍㪋㪅㪇

㪉㱔㩿㪚㫌㪄㪢㪸㪀㪉㱔㩿㪚㫌㪄㪢㪸㪀 ࿑ 㪋㪅㪍㪅㪈䋭㪊㩷 㪪㪮䋭㪌㪇㷄ᄌ⾰ㇱ⹜ᢱ䈱ਇቯᣇ૏᷹ቯ⚿ᨐ㩷

㪋㪇㪇

㪉㪇㪇㪇

㪊㪌㪇
㪈㪌㪇㪇

㪍㪇㪅㪉㪌㫦㩿㪈㪅㪌㪊㫻㪀㩷㪊㪇㪇ᒝᐲ㩿㪺㫇㫊㪀

ᒝᐲ㩿㪺㫇㫊㪀

㪉㪌㪇
㪈㪇㪇㪇

㪉㪇㪇
㪈㪌㪇

㪌㪇㪇

㪍㪉㪅㪈㪏㫦㩿㪈㪅㪋㪐㫻㪀㩷

㪈㪇㪇
㪌㪇

㪇
㪇㪅㪇㪇

㪊㪇㪅㪇

㪉㱔㩿㪚㫌㪄㪢㪸㪀

㪍㪇㪅㪇

㪇
㪌㪏㪅㪇

㪐㪇㪅㪇

㪌㪐㪅㪇

㪍㪇㪅㪇

㪍㪈㪅㪇

㪉㱔㩿㪚㫌㪄㪢㪸㪀 ࿑ 㪋㪅㪍㪅㪈䋭㪋㩷 㪪㪮䋭㪌㪇㷄ᧂᄌ⾰ㇱ⹜ᢱ䈱ਇቯᣇ૏᷹ቯ⚿ᨐ㩷

24

 

㪍㪉㪅㪇

㪍㪊㪅㪇

㪍㪋㪅㪇


㪉㪇㪇㪇

㪉㪇㪇

㪍㪇㪅㪇㪇㫦㩿㪈㪅㪌㪋㫻㪀㩷
㪈㪌㪇㪇

㪈㪌㪇

ᒝᐲ㩿㪺㫇㫊㪀

ᒝᐲ㩿㪺㫇㫊㪀

㪍㪉㪅㪇㪏㫦㩿㪈㪅㪋㪐㫻㪀㩷
㪈㪇㪇㪇

㪌㪇㪇

㪇
㪇㪅㪇㪇

㪈㪇㪇

㪌㪇

㪊㪇㪅㪇

㪉㱔㩿㪚㫌㪄㪢㪸㪀

㪍㪇㪅㪇

㪇
㪌㪏㪅㪇

㪐㪇㪅㪇

㪍㪇㪅㪇

㪉㱔㩿㪚㫌㪄㪢㪸㪀 ࿑ 㪋㪅㪍㪅㪈䋭㪌㩷 㪞㪮䋭㪈䋭㪏㪇㷄ᄌ⾰ㇱ⹜ᢱ䈱ਇቯᣇ૏᷹ቯ⚿ᨐ㩷

㪉㪌㪇㪇

㪍㪉㪅㪇

㪍㪋㪅㪇

㪉㪌㪇

㪍㪇㪅㪇㪊㫦㩿㪈㪅㪌㪋㫻㪀㩷
㪉㪇㪇㪇

㪉㪇㪇

㪈㪌㪇㪇

㪈㪌㪇

ᒝᐲ㩿㪺㫇㫊㪀

ᒝᐲ㩿㪺㫇㫊㪀

㪍㪉㪅㪇㪇㫦㩿㪈㪅㪌㪇㫻㪀㩷

㪈㪇㪇㪇

㪌㪇㪇

㪇
㪇㪅㪇㪇

㪈㪇㪇

㪌㪇

㪊㪇㪅㪇

㪍㪇㪅㪇

㪇
㪌㪏㪅㪇

㪐㪇㪅㪇

㪉㱔㩿㪚㫌㪄㪢㪸㪀

㪌㪐㪅㪇

㪍㪇㪅㪇

㪍㪈㪅㪇

㪍㪉㪅㪇

㪉㱔㩿㪚㫌㪄㪢㪸㪀 ࿑ 㪋㪅㪍㪅㪈䋭㪍㩷 㪞㪮䋭㪈䋭㪏㪇㷄ᧂᄌ⾰ㇱ⹜ᢱ䈱ਇቯᣇ૏᷹ቯ⚿ᨐ㩷

25

 

㪍㪊㪅㪇

㪍㪋㪅㪇


㪈㪋㪇㪇

㪈㪌㪇

㪌㪐㪅㪐㪎㫦㩿㪈㪅㪌㪋㫻㪀㩷

㪈㪉㪇㪇
㪈㪉㪇

㪍㪈㪅㪐㪍㫦㩿㪈㪅㪌㪇㫻㪀㩷ᒝᐲ㩿㪺㫇㫊㪀

ᒝᐲ㩿㪺㫇㫊㪀

㪈㪇㪇㪇

㪏㪇㪇

㪍㪇㪇

㪐㪇

㪍㪇

㪋㪇㪇
㪊㪇
㪉㪇㪇

㪇
㪇㪅㪇㪇

㪊㪇㪅㪇

㪍㪇㪅㪇

㪇
㪌㪏㪅㪇

㪐㪇㪅㪇

㪍㪇㪅㪇

㪍㪉㪅㪇

㪍㪋㪅㪇

㪉㱔㩿㪚㫌㪄㪢㪸㪀㪉㱔㩿㪚㫌㪄㪢㪸㪀 ࿑ 㪋㪅㪍㪅㪈䋭㪎㩷 㪞㪮䋭㪉䋭㪏㪇㷄ᄌ⾰ㇱ⹜ᢱ䈱ਇቯᣇ૏᷹ቯ⚿ᨐ㩷

㪊㪌㪇㪇

㪉㪌㪇

㪌㪐㪅㪐㪊㫦㩿㪈㪅㪌㪋㫻㪀㩷

㪊㪇㪇㪇
㪉㪇㪇

㪍㪈㪅㪐㪊㫦㩿㪈㪅㪌㪇㫻㪀㩷ᒝᐲ㩿㪺㫇㫊㪀

ᒝᐲ㩿㪺㫇㫊㪀

㪉㪌㪇㪇

㪉㪇㪇㪇

㪈㪌㪇㪇

㪈㪌㪇

㪈㪇㪇

㪈㪇㪇㪇
㪌㪇
㪌㪇㪇

㪇
㪇㪅㪇㪇

㪊㪇㪅㪇

㪍㪇㪅㪇

㪇
㪌㪏㪅㪇

㪐㪇㪅㪇

㪉㱔㩿㪚㫌㪄㪢㪸㪀

㪌㪐㪅㪇

㪍㪇㪅㪇

㪍㪈㪅㪇

㪍㪉㪅㪇

㪉㱔㩿㪚㫌㪄㪢㪸㪀 ࿑ 㪋㪅㪍㪅㪈䋭㪏㩷 㪞㪮䋭㪉䋭㪏㪇㷄ᧂᄌ⾰ㇱ⹜ᢱ䈱ਇቯᣇ૏᷹ቯ⚿ᨐ㩷

26

 

㪍㪊㪅㪇

㪍㪋㪅㪇


㪉㪌㪇㪇

㪊㪇㪇

㪉㪌㪇

㪉㪇㪇㪇

㪍㪇㪅㪇㪐㫦㩿㪈㪅㪌㪋㫻㪀㪈㪌㪇㪇ᒝᐲ㩿㪺㫇㫊㪀

ᒝᐲ㩿㪺㫇㫊㪀

㪉㪇㪇

㪈㪇㪇㪇

㪈㪌㪇

㪍㪉㪅㪇㪐㫦㩿㪈㪅㪋㪐㫻㪀㩷
㪈㪇㪇

㪌㪇㪇

㪇
㪇㪅㪇㪇

㪌㪇

㪊㪇㪅㪇

㪍㪇㪅㪇

㪇
㪌㪏㪅㪇

㪐㪇㪅㪇

㪌㪐㪅㪇

㪍㪇㪅㪇

㪍㪈㪅㪇

㪍㪉㪅㪇

㪍㪊㪅㪇

㪍㪋㪅㪇

㪉㱔㩿㪚㫌㪄㪢㪸㪀㪉㱔㩿㪚㫌㪄㪢㪸㪀 ࿑ 㪋㪅㪍㪅㪈䋭㪐㩷 㪪㪮㪄㪏㪇㷄ᄢ᳇᧦ઙᄌ⾰ㇱ⹜ᢱਇቯᣇ૏᷹ቯ⚿ᨐ㩷
㪉㪌㪇㪇

㪊㪇㪇

㪉㪌㪇

㪉㪇㪇㪇

㪌㪐㪅㪐㪌㫦㩿㪈㪅㪌㪋㫻㪀ᒝᐲ㩿㪺㫇㫊㪀

ᒝᐲ㩿㪺㫇㫊㪀

㪉㪇㪇
㪈㪌㪇㪇

㪈㪇㪇㪇

㪍㪈㪅㪐㪈㫦㩿㪈㪅㪌㪇㫻㪀㩷
㪈㪌㪇

㪈㪇㪇
㪌㪇㪇

㪇
㪇㪅㪇㪇

㪌㪇

㪊㪇㪅㪇

㪍㪇㪅㪇

㪇
㪌㪏㪅㪇

㪐㪇㪅㪇

㪉㱔㩿㪚㫌㪄㪢㪸㪀

㪌㪐㪅㪇

㪍㪇㪅㪇

㪍㪈㪅㪇

㪍㪉㪅㪇

㪉㱔㩿㪚㫌㪄㪢㪸㪀 ࿑ 㪋㪅㪍㪅㪈䋭㪈㪇㩷 㪪㪮㪄㪏㪇㷄ᄢ᳇᧦ઙᧂᄌ⾰ㇱ⹜ᢱ䈱ਇቯᣇ૏᷹ቯ⚿ᨐ㩷

27

 

㪍㪊㪅㪇

㪍㪋㪅㪇


㪈㪇㪇

㪉㪇㪇㪇

㪏㪇
㪈㪌㪇㪇

ᒝᐲ㩿㪺㫇㫊㪀

ᒝᐲ㩿㪺㫇㫊㪀

㪍㪈㪅㪐㪐㫦㩿㪈㪅㪌㪇㫻㪀㩷

㪈㪇㪇㪇

㪍㪇

㪋㪇

㪌㪇㪇
㪉㪇

㪇
㪇㪅㪇㪇

㪊㪇㪅㪇

㪍㪇㪅㪇

㪇
㪌㪏㪅㪇

㪐㪇㪅㪇

㪌㪐㪅㪇

㪍㪇㪅㪇

㪍㪈㪅㪇

㪍㪉㪅㪇

㪍㪊㪅㪇

㪍㪋㪅㪇

㪉㱔㩿㪚㫌㪄㪢㪸㪀㪉㱔㩿㪚㫌㪄㪢㪸㪀 ࿑ 㪋㪅㪍㪅㪈䋭㪈㪈㩷 㪪㪮䋭㪏㪇㷄㩷 㪢㫌㫅㫀㫇㫀㪸䋭㪝 ᄌ⾰ㇱ⹜ᢱ䈱ਇቯᣇ૏᷹ቯ⚿ᨐ㩷

㪉㪇㪇

㪉㪌㪇㪇

㪍㪈㪅㪐㪐㫦㩿㪈㪅㪌㪇㫻㪀㩷
㪉㪇㪇㪇

㪈㪌㪇㪇

ᒝᐲ㩿㪺㫇㫊㪀

ᒝᐲ㩿㪺㫇㫊㪀

㪈㪌㪇

㪈㪇㪇㪇

㪈㪇㪇

㪌㪇
㪌㪇㪇

㪇
㪇㪅㪇㪇

㪊㪇㪅㪇

㪍㪇㪅㪇

㪇
㪌㪏㪅㪇

㪐㪇㪅㪇

㪉㱔㩿㪚㫌㪄㪢㪸㪀

㪍㪇㪅㪇

㪍㪉㪅㪇

㪉㱔㩿㪚㫌㪄㪢㪸㪀 ࿑ 㪋㪅㪍㪅㪈䋭㪈㪉㩷 㪪㪮䋭㪏㪇㷄㩷 㪢㫌㫅㫀㫇㫀㪸䋭㪝 ᧂᄌ⾰ㇱ⹜ᢱ䈱ਇቯᣇ૏᷹ቯ⚿ᨐ㩷

28

 

㪍㪋㪅㪇


㪎㪇㪇

㪈㪉㪇㪇

㩿㪙㪀㩷

㩿㪘㪀
㪍㪇㪇

㪈㪇㪇㪇

㪎㪅㪇㪎㫦㩿㪈㪉㪅㪋㪋㫻㪀㪌㪇㪇ᒝᐲ㩿㪺㫇㫊㪀

ᒝᐲ㩿㪺㫇㫊㪀

㪏㪇㪇
㪋㪇㪇

㪊㪇㪇

㪍㪇㪇

㪎㪅㪇㪌㫦㩿㪈㪉㪅㪋㪋㫻㪀㩷

㪋㪇㪇

㪉㪇㪇
㪉㪇㪇

㪈㪇㪇

㪇
㪇㪅㪇㪇

㪈㪇㪅㪇

㪉㪇㪅㪇

㪊㪇㪅㪇

㪋㪇㪅㪇

㪌㪇㪅㪇

㪇
㪇㪅㪇㪇

㪍㪇㪅㪇

㪈㪇㪅㪇

㪉㪇㪅㪇

㪊㪇㪅㪇

㪉㱔㩿㪚㫌㪄㪢㪸㪀࿑ 㪋㪅㪍㪅㪉䋭㪈㩷 㪪㪮䋭㪏㪇㷄⹜ᢱ䈱ቯᣇ૏᷹ቯ⚿ᨐ㩷㩿㪘㪀䋺ᄌ⾰ㇱ⹜ᢱ䋬㩿㪙㪀䋺ᧂᄌ⾰ㇱ⹜ᢱ㩷

㪋㪇㪅㪇

㪌㪇㪅㪇

㪍㪇㪅㪇

㪉㱔㩿㪚㫌㪄㪢㪸㪀

㪈㪍㪇㪇

㪈㪇㪇㪇

㩿㪘㪀

㪎㪅㪇㪋㫦㩿㪈㪉㪅㪍㪉㫻㪀㩷

㪈㪋㪇㪇

㩿㪙㪀㩷

㪎㪅㪈㪇㫦㩿㪈㪉㪅㪋㪋㫻㪀

㪏㪇㪇

㪈㪇㪇㪇

㪍㪇㪇

ᒝᐲ㩿㪺㫇㫊㪀

ᒝᐲ㩿㪺㫇㫊㪀

㪈㪉㪇㪇

㪋㪇㪇

㪏㪇㪇
㪍㪇㪇
㪋㪇㪇

㪉㪇㪇

㪉㪇㪇
㪇
㪇㪅㪇㪇

㪈㪇㪅㪇

㪉㪇㪅㪇

㪊㪇㪅㪇

㪋㪇㪅㪇

㪌㪇㪅㪇

㪇
㪇㪅㪇㪇

㪍㪇㪅㪇

㪈㪇㪅㪇

㪉㪇㪅㪇

㪊㪇㪅㪇

㪉㱔㩿㪚㫌㪄㪢㪸㪀࿑ 㪋㪅㪍㪅㪉䋭㪉㩷 㪪㪮䋭㪌㪇㷄⹜ᢱ䈱ቯᣇ૏᷹ቯ⚿ᨐ㩷㩿㪘㪀䋺ᄌ⾰ㇱ⹜ᢱ䋬㩿㪙㪀䋺ᧂᄌ⾰ㇱ⹜ᢱ㩷

㪋㪇㪅㪇

㪌㪇㪅㪇

㪍㪇㪅㪇

㪉㱔㩿㪚㫌㪄㪢㪸㪀

㪈㪌㪇㪇

㪈㪌㪇㪇

㩿㪘㪀

㪎㪅㪇㪊㫦㩿㪈㪉㪅㪍㪉㫻㪀㩷㩿㪙㪀㩷㪍㪅㪐㪌㫦㩿㪈㪉㪅㪍㪉㫻㪀㪈㪇㪇㪇ᒝᐲ㩿㪺㫇㫊㪀

ᒝᐲ㩿㪺㫇㫊㪀

㪈㪇㪇㪇

㪌㪇㪇

㪌㪇㪇

㪇
㪇㪅㪇㪇

㪈㪇㪅㪇

㪉㪇㪅㪇

㪊㪇㪅㪇

㪉㱔㩿㪚㫌㪄㪢㪸㪀

㪋㪇㪅㪇

㪌㪇㪅㪇

㪇
㪇㪅㪇㪇

㪍㪇㪅㪇

㪈㪇㪅㪇

㪉㪇㪅㪇

㪊㪇㪅㪇

㪉㱔㩿㪚㫌㪄㪢㪸㪀࿑ 㪋㪅㪍㪅㪉䋭㪊㩷 㪞㪮䋭㪈䋭㪏㪇㷄⹜ᢱ䈱ቯᣇ૏᷹ቯ⚿ᨐ㩷㩿㪘㪀䋺ᄌ⾰ㇱ⹜ᢱ䋬㩿㪙㪀䋺ᧂᄌ⾰ㇱ⹜ᢱ㩷

29

 

㪋㪇㪅㪇

㪌㪇㪅㪇

㪍㪇㪅㪇


㪌㪇㪇㪇

㪉㪌㪇㪇

㩿㪙㪀㩷

㩿㪘㪀

㪈㪌㪇㪇

㪈㪇㪇㪇

㪊㪇㪇㪇

㪉㪇㪇㪇

㪈㪇㪇㪇

㪌㪇㪇

㪇
㪇㪅㪇㪇

㪎㪅㪇㪎㫦㩿㪈㪉㪅㪋㪋㫻㪀㩷㪋㪇㪇㪇ᒝᐲ㩿㪺㫇㫊㪀

ᒝᐲ㩿㪺㫇㫊㪀

㪉㪇㪇㪇㪎㪅㪇㪋㫦㩿㪈㪉㪅㪍㪉㫻㪀㩷

㪈㪇㪅㪇

㪉㪇㪅㪇

㪊㪇㪅㪇

㪉㱔㩿㪚㫌㪄㪢㪸㪀

㪋㪇㪅㪇

㪌㪇㪅㪇

㪇
㪇㪅㪇㪇

㪍㪇㪅㪇

㪈㪇㪅㪇

㪉㪇㪅㪇

㪊㪇㪅㪇

㪋㪇㪅㪇

㪌㪇㪅㪇

㪍㪇㪅㪇

㪉㱔㩿㪚㫌㪄㪢㪸㪀࿑ 㪋㪅㪍㪅㪉䋭㪋㩷 㪞㪮䋭㪉䋭㪏㪇㷄⹜ᢱ䈱ቯᣇ૏᷹ቯ⚿ᨐ㩷㩿㪘㪀䋺ᄌ⾰ㇱ⹜ᢱ䋬㩿㪙㪀䋺ᧂᄌ⾰ㇱ⹜ᢱ㩷
㪈㪇㪇㪇

㪎㪇㪇

㪎㪅㪇㪌㫦㩿㪈㪉㪅㪋㪋㫻㪀㩷

㩿㪘㪀

㩿㪙㪀㩷

㪎㪅㪈㪊㫦㩿㪈㪉㪅㪋㪋㫻㪀㩷

㪍㪇㪇

㪏㪇㪇

ᒝᐲ㩿㪺㫇㫊㪀

ᒝᐲ㩿㪺㫇㫊㪀

㪌㪇㪇

㪋㪇㪇

㪊㪇㪇

㪍㪇㪇

㪋㪇㪇

㪉㪇㪇

㪉㪇㪇
㪈㪇㪇

㪇
㪇㪅㪇㪇

㪈㪇㪅㪇

㪉㪇㪅㪇

㪊㪇㪅㪇

㪋㪇㪅㪇

㪌㪇㪅㪇

㪇
㪇㪅㪇㪇

㪍㪇㪅㪇

㪈㪇㪅㪇

㪉㪇㪅㪇

㪊㪇㪅㪇

㪋㪇㪅㪇

㪌㪇㪅㪇

㪍㪇㪅㪇

㪉㱔㩿㪚㫌㪄㪢㪸㪀㪉㱔㩿㪚㫌㪄㪢㪸㪀࿑ 㪋㪅㪍㪅㪉䋭㪌㩷 㪪㪮䋭㪏㪇㷄ᄢ᳇᧦ઙ⹜ᢱ䈱ቯᣇ૏᷹ቯ⚿ᨐ㩷㩿㪘㪀䋺ᄌ⾰ㇱ⹜ᢱ䋬㩿㪙㪀䋺ᧂᄌ⾰ㇱ⹜ᢱ㩷
㪎㪇㪇㪇

㪍㪇㪇㪇

㪋㪇㪇㪇

㩿㪘㪀

㪎㪅㪇㪇㫦㩿㪈㪉㪅㪍㪉㫻㪀㩷

㪊㪌㪇㪇
㪊㪇㪇㪇

㪌㪇㪇㪇

㪉㪌㪇㪇

ᒝᐲ㩿㪺㫇㫊㪀

ᒝᐲ㩿㪺㫇㫊㪀

㩿㪙㪀㩷㪍㪅㪐㪎㫦㩿㪈㪉㪅㪍㪉㫻㪀㩷

㪋㪇㪇㪇

㪊㪇㪇㪇

㪉㪇㪇㪇
㪈㪌㪇㪇

㪉㪇㪇㪇

㪈㪇㪇㪇

㪈㪇㪇㪇

㪇
㪇㪅㪇㪇

㪌㪇㪇

㪈㪇㪅㪇

㪉㪇㪅㪇

㪊㪇㪅㪇

㪋㪇㪅㪇

㪌㪇㪅㪇

㪇
㪇㪅㪇㪇

㪍㪇㪅㪇

㪉㱔㩿㪚㫌㪄㪢㪸㪀

㪈㪇㪅㪇

㪉㪇㪅㪇

㪊㪇㪅㪇

㪋㪇㪅㪇

㪉㱔㩿㪚㫌㪄㪢㪸㪀࿑ 㪋㪅㪍㪅㪉䋭㪍㩷 㪪㪮䋭㪏㪇㷄㩷 㪢㫌㫅㫀㫇㫀㪸䋭㪝 ⹜ᢱ䈱ቯᣇ૏᷹ቯ⚿ᨐ㩷㩿㪘㪀䋺ᄌ⾰ㇱ⹜ᢱ䋬㩿㪙㪀䋺ᧂᄌ⾰ㇱ⹜ᢱ㩷

30

 

㪌㪇㪅㪇

㪍㪇㪅㪇

ᒝᐲ㩿㪺㫇㫊㪀

 

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㪈㪇㪅㪇

㪈㪉㪅㪇

㪻㩿㪇㪇㪈㪀ᐩ㕙㑆㓒㩿㷬㪀
㪏
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㪈㪇

㪈㪉

㪈㪋

㪈㪍

㪈㪏

㪉㪇

㪉㪇㪅㪇

㪋㪇㪅㪇

㪚㪸ဳ㩿㪪㪸㫋㫆㩷㪼㫋㩷㪸㫃㪅㪈㪐㪐㪉㪀㪥㪸ဳ㩿㪪㪸㫋㫆㩷㪼㫋㩷㪸㫃㪅㪈㪐㪐㪉㪀ᄌ⾰ㇱ㪪㪮㪄㪏㪇㷄

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㪉㱔㩿㪚㫌㪄㪢㪸㪀

㪍㪅㪇㪇

㪈㪇㪅㪇

㪇㩼
㪈㪇㩼
㪉㪇㩼
㪊㪇㩼
㪋㪇㩼
㪌㪇㩼
㪍㪇㩼
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㪈㪇㪇㩼

㪈㪉㪅㪇

㪏
㪇㪅㪇㪇

㪈㪇

㪈㪉

㪈㪋

㪈㪍

㪈㪏

㪉㪇

㪉㪇㪅㪇

㪋㪇㪅㪇

㪚㪸ဳ㩿㪪㪸㫋㫆㩷㪼㫋㩷㪸㫃㪅㪈㪐㪐㪉㪀㪥㪸ဳ㩿㪪㪸㫋㫆㩷㪼㫋㩷㪸㫃㪅㪈㪐㪐㪉㪀ᧂᄌ⾰ㇱ㪪㪮㪄㪏㪇㷄

㪍㪇㪅㪇

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31

⋧ኻḨᐲ㩿㩼㪀
࿑ 㪋㪅㪍㪅㪊䋭㪉㩷 㪪㪮䋭㪏㪇㷄ᧂᄌ⾰ㇱ⹜ᢱ䈱Ḩᐲ೙ᓮ᷹ቯ⚿ᨐ䈫⋧ኻḨᐲ䈮ኻ䈜䉎 㪻㩿㪇㪇㪈㪀ᐩ㕙㑆㓒䈱ᄌൻ㩷㪉㪅㪇㪇ᒝᐲ㩿㪺㫇㫊㪀

- 31 㪻㩿㪇㪇㪈㪀ᐩ㕙㑆㓒㩿㷬㪀⋧ኻḨᐲ㩿㩼㪀
࿑ 㪋㪅㪍㪅㪊䋭㪈㩷 㪪㪮䋭㪏㪇㷄ᄌ⾰ㇱ⹜ᢱ䈱Ḩᐲ೙ᓮ᷹ቯ⚿ᨐ䈫⋧ኻḨᐲ䈮ኻ䈜䉎 㪻㩿㪇㪇㪈㪀ᐩ㕙㑆㓒䈱ᄌൻ㩷

㪉㪅㪇㪇

㪇㩼
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㪍㪇㩼
㪎㪇㩼
㪏㪇㩼
㪐㪇㩼
㪈㪇㪇㩼


JAEA-Data/Code 2008-0XX 

ᒝᐲ㩿㪺㫇㫊㪀

㪋㪅㪇㪇

㪏㪅㪇㪇

㪉㱔㩿㪚㫌㪄㪢㪸㪀

㪍㪅㪇㪇

㪈㪇㪅㪇

㪈㪉㪅㪇

㪻㩿㪇㪇㪈㪀ᐩ㕙㑆㓒㩿㷬㪀
㪏
㪇㪅㪇㪇

㪈㪇

㪈㪉

㪈㪋

㪈㪍

㪈㪏

㪉㪇

㪉㪇㪅㪇

㪋㪇㪅㪇

㪚㪸ဳ㩿㪪㪸㫋㫆㩷㪼㫋㩷㪸㫃㪅㪈㪐㪐㪉㪀㪥㪸ဳ㩿㪪㪸㫋㫆㩷㪼㫋㩷㪸㫃㪅㪈㪐㪐㪉㪀ᄌ⾰ㇱ㪪㪮㪄㪌㪇㷄

㪍㪇㪅㪇

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㪍㪅㪇㪇

㪈㪇㪅㪇

㪇㩼
㪈㪇㩼
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㪊㪇㩼
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㪌㪇㩼
㪍㪇㩼
㪎㪇㩼
㪏㪇㩼
㪐㪇㩼
㪈㪇㪇㩼

㪈㪉㪅㪇

㪏
㪇㪅㪇㪇

㪈㪇

㪈㪉

㪈㪋

㪈㪍

㪈㪏

㪉㪇

㪉㪇㪅㪇

㪋㪇㪅㪇

㪚㪸ဳ㩿㪪㪸㫋㫆㩷㪼㫋㩷㪸㫃㪅㪈㪐㪐㪉㪀㪥㪸ဳ㩿㪪㪸㫋㫆㩷㪼㫋㩷㪸㫃㪅㪈㪐㪐㪉㪀ᧂᄌ⾰ㇱ㪪㪮㪄㪌㪇㷄

㪍㪇㪅㪇

㪏㪇㪅㪇

㪈㪇㪇

32

⋧ኻḨᐲ㩿㩼㪀
࿑ 㪋㪅㪍㪅㪊䋭㪋㩷 㪪㪮䋭㪌㪇㷄ᧂᄌ⾰ㇱ⹜ᢱ䈱Ḩᐲ೙ᓮ᷹ቯ⚿ᨐ䈫⋧ኻḨᐲ䈮ኻ䈜䉎 㪻㩿㪇㪇㪈㪀ᐩ㕙㑆㓒䈱ᄌൻ㩷㪉㪅㪇㪇ᒝᐲ㩿㪺㫇㫊㪀

- 32 㪻㩿㪇㪇㪈㪀ᐩ㕙㑆㓒㩿㷬㪀⋧ኻḨᐲ㩿㩼㪀
࿑ 㪋㪅㪍㪅㪊䋭㪊㩷 㪪㪮䋭㪌㪇㷄ᄌ⾰ㇱ⹜ᢱ䈱Ḩᐲ೙ᓮ᷹ቯ⚿ᨐ䈫⋧ኻḨᐲ䈮ኻ䈜䉎 㪻㩿㪇㪇㪈㪀ᐩ㕙㑆㓒䈱ᄌൻ㩷

㪉㪅㪇㪇

㪇㩼
㪈㪇㩼
㪉㪇㩼
㪊㪇㩼
㪋㪇㩼
㪌㪇㩼
㪍㪇㩼
㪎㪇㩼
㪏㪇㩼
㪐㪇㩼
㪈㪇㪇㩼

JAEA-Data/Code 2008-0XX

ᒝᐲ㩿㪺㫇㫊㪀

 

㪋㪅㪇㪇

㪏㪅㪇㪇

㪉㱔㩿㪚㫌㪄㪢㪸㪀

㪍㪅㪇㪇

㪈㪇㪅㪇

㪈㪉㪅㪇

㪻㩿㪇㪇㪈㪀ᐩ㕙㑆㓒㩿㷬㪀
㪏
㪇㪅㪇㪇

㪈㪇

㪈㪉

㪈㪋

㪈㪍

㪈㪏

㪉㪇

㪉㪇㪅㪇

㪍㪇㪅㪇

⋧ኻḨᐲ㩿㩼㪀

㪋㪇㪅㪇㪚㪸ဳ㩿㪪㪸㫋㫆㩷㪼㫋㩷㪸㫃㪅㪈㪐㪐㪉㪀㪥㪸ဳ㩿㪪㪸㫋㫆㩷㪼㫋㩷㪸㫃㪅㪈㪐㪐㪉㪀ᄌ⾰ㇱ㪞㪮㪄㪈㪄㪏㪇㷄

㪏㪇㪅㪇

㪈㪇㪇

㪉㪅㪇㪇

㪋㪅㪇㪇

㪏㪅㪇㪇

㪉㱔㩿㪚㫌㪄㪢㪸㪀

㪍㪅㪇㪇

㪈㪇㪅㪇

㪇㩼
㪈㪇㩼
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㪊㪇㩼
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㪈㪇㪇㩼

㪈㪉㪅㪇

㪏
㪇㪅㪇㪇

㪈㪇

㪈㪉

㪈㪋

㪈㪍

㪈㪏

㪉㪇

㪉㪇㪅㪇

㪍㪇㪅㪇

⋧ኻḨᐲ㩿㩼㪀

㪋㪇㪅㪇㪚㪸ဳ㩿㪪㪸㫋㫆㩷㪼㫋㩷㪸㫃㪅㪈㪐㪐㪉㪀㪥㪸ဳ㩿㪪㪸㫋㫆㩷㪼㫋㩷㪸㫃㪅㪈㪐㪐㪉㪀ᧂᄌ⾰ㇱ㪞㪮㪄㪈㪄㪏㪇㷄

㪏㪇㪅㪇

㪈㪇㪇

33


࿑ 㪋㪅㪍㪅㪊䋭㪍㩷 㪞㪮䋭㪈䋭㪏㪇㷄ᧂᄌ⾰ㇱ⹜ᢱ䈱Ḩᐲ೙ᓮ᷹ቯ⚿ᨐ䈫⋧ኻḨᐲ䈮ኻ䈜䉎 㪻㩿㪇㪇㪈㪀ᐩ㕙㑆㓒䈱ᄌൻ㩷ᒝᐲ㩿㪺㫇㫊㪀

- 33 㪻㩿㪇㪇㪈㪀ᐩ㕙㑆㓒㩿㷬㪀࿑ 㪋㪅㪍㪅㪊䋭㪌㩷 㪞㪮䋭㪈䋭㪏㪇㷄ᄌ⾰ㇱ⹜ᢱ䈱Ḩᐲ೙ᓮ᷹ቯ⚿ᨐ䈫⋧ኻḨᐲ䈮ኻ䈜䉎 㪻㩿㪇㪇㪈㪀ᐩ㕙㑆㓒䈱ᄌൻ㩷

㪉㪅㪇㪇

㪇㩼
㪈㪇㩼
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㪊㪇㩼
㪋㪇㩼
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㪍㪇㩼
㪎㪇㩼
㪏㪇㩼
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㪈㪇㪇㩼


JAEA-Data/Code 2008-0XXᒝᐲ㩿㪺㫇㫊㪀

 

㪋㪅㪇㪇

㪏㪅㪇㪇

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㪈㪇㪅㪇

㪈㪉㪅㪇

㪻㩿㪇㪇㪈㪀ᐩ㕙㑆㓒㩿㷬㪀
㪏
㪇㪅㪇㪇

㪈㪇

㪈㪉

㪈㪋

㪈㪍

㪈㪏

㪉㪇

㪉㪇㪅㪇

㪋㪇㪅㪇

㪚㪸ဳ㩿㪪㪸㫋㫆㩷㪼㫋㩷㪸㫃㪅㪈㪐㪐㪉㪀㪥㪸ဳ㩿㪪㪸㫋㫆㩷㪼㫋㩷㪸㫃㪅㪈㪐㪐㪉㪀ᄌ⾰ㇱ㪞㪮㪄㪉㪄㪏㪇㷄

㪍㪇㪅㪇

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㪈㪇㪇

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㪋㪅㪇㪇

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㪉㱔㩿㪚㫌㪄㪢㪸㪀

㪍㪅㪇㪇

㪈㪇㪅㪇

㪇㩼
㪈㪇㩼
㪉㪇㩼
㪊㪇㩼
㪋㪇㩼
㪌㪇㩼
㪍㪇㩼
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㪈㪇㪇㩼

㪈㪉㪅㪇

㪏
㪇㪅㪇㪇

㪈㪇

㪈㪉

㪈㪋

㪈㪍

㪈㪏

㪉㪇

㪉㪇㪅㪇

㪋㪇㪅㪇

㪚㪸ဳ㩿㪪㪸㫋㫆㩷㪼㫋㩷㪸㫃㪅㪈㪐㪐㪉㪀㪥㪸ဳ㩿㪪㪸㫋㫆㩷㪼㫋㩷㪸㫃㪅㪈㪐㪐㪉㪀ᧂᄌ⾰ㇱ㪞㪮㪄㪉㪄㪏㪇㷄

㪍㪇㪅㪇

㪏㪇㪅㪇

㪈㪇㪇

34

⋧ኻḨᐲ㩿㩼㪀
࿑ 㪋㪅㪍㪅㪊䋭㪏㩷 㪞㪮䋭㪉䋭㪏㪇㷄ᧂᄌ⾰ㇱ⹜ᢱ䈱Ḩᐲ೙ᓮ᷹ቯ⚿ᨐ䈫⋧ኻḨᐲ䈮ኻ䈜䉎 㪻㩿㪇㪇㪈㪀ᐩ㕙㑆㓒䈱ᄌൻ㩷ᒝᐲ㩿㪺㫇㫊㪀

- 34 㪻㩿㪇㪇㪈㪀ᐩ㕙㑆㓒㩿㷬㪀⋧ኻḨᐲ㩿㩼㪀
࿑ 㪋㪅㪍㪅㪊䋭㪎㩷 㪞㪮䋭㪉䋭㪏㪇㷄ᄌ⾰ㇱ⹜ᢱ䈱Ḩᐲ೙ᓮ᷹ቯ⚿ᨐ䈫⋧ኻḨᐲ䈮ኻ䈜䉎 㪻㩿㪇㪇㪈㪀ᐩ㕙㑆㓒䈱ᄌൻ㩷

㪉㪅㪇㪇

㪇㩼
㪈㪇㩼
㪉㪇㩼
㪊㪇㩼
㪋㪇㩼
㪌㪇㩼
㪍㪇㩼
㪎㪇㩼
㪏㪇㩼
㪐㪇㩼
㪈㪇㪇㩼


JAEA-Data/Code 2008-0XXᒝᐲ㩿㪺㫇㫊㪀

 

㪋㪅㪇㪇

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㪉㱔㩿㪚㫌㪄㪢㪸㪀

㪍㪅㪇㪇

㪈㪇㪅㪇

㪈㪉㪅㪇

㪻㩿㪇㪇㪈㪀ᐩ㕙㑆㓒㩿㷬㪀
㪏
㪇㪅㪇㪇

㪈㪇

㪈㪉

㪈㪋

㪈㪍

㪈㪏

㪉㪇

㪉㪇㪅㪇

㪋㪇㪅㪇

㪚㪸ဳ㩿㪪㪸㫋㫆㩷㪼㫋㩷㪸㫃㪅㪈㪐㪐㪉㪀㪥㪸ဳ㩿㪪㪸㫋㫆㩷㪼㫋㩷㪸㫃㪅㪈㪐㪐㪉㪀ᄌ⾰ㇱ㪪㪮㪄㪏㪇㷄ᄢ᳇

㪍㪇㪅㪇

㪏㪇㪅㪇

㪈㪇㪇

㪋㪅㪇㪇

㪏㪅㪇㪇

㪉㱔㩿㪚㫌㪄㪢㪸㪀

㪍㪅㪇㪇

㪈㪇㪅㪇

㪇㩼
㪈㪇㩼
㪉㪇㩼
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㪌㪇㩼
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㪈㪇㪇㩼

㪈㪉㪅㪇

㪏
㪇㪅㪇㪇

㪈㪇

㪈㪉

㪈㪋

㪈㪍

㪈㪏

㪉㪇

㪉㪇㪅㪇

㪋㪇㪅㪇

㪚㪸ဳ㩿㪪㪸㫋㫆㩷㪼㫋㩷㪸㫃㪅㪈㪐㪐㪉㪀㪥㪸ဳ㩿㪪㪸㫋㫆㩷㪼㫋㩷㪸㫃㪅㪈㪐㪐㪉㪀ᧂᄌ⾰ㇱ㪪㪮㪄㪏㪇㷄ᄢ᳇

㪍㪇㪅㪇

㪏㪇㪅㪇

㪈㪇㪇

35

⋧ኻḨᐲ㩿㩼㪀
࿑ 㪋㪅㪍㪅㪊䋭㪈㪇㩷 㪪㪮䋭㪏㪇㷄ᄢ᳇᧦ઙᧂᄌ⾰ㇱ⹜ᢱ䈱Ḩᐲ೙ᓮ᷹ቯ⚿ᨐ䈫⋧ኻḨᐲ䈮ኻ䈜䉎 㪻㩿㪇㪇㪈㪀ᐩ㕙㑆㓒䈱ᄌൻ㩷㪉㪅㪇㪇ᒝᐲ㩿㪺㫇㫊㪀

- 35 㪻㩿㪇㪇㪈㪀ᐩ㕙㑆㓒㩿㷬㪀⋧ኻḨᐲ㩿㩼㪀
࿑ 㪋㪅㪍㪅㪊䋭㪐㩷 㪪㪮䋭㪏㪇㷄ᄢ᳇᧦ઙᄌ⾰ㇱ⹜ᢱ䈱Ḩᐲ೙ᓮ᷹ቯ⚿ᨐ䈫⋧ኻḨᐲ䈮ኻ䈜䉎 㪻㩿㪇㪇㪈㪀ᐩ㕙㑆㓒䈱ᄌൻ㩷

㪉㪅㪇㪇

㪇㩼
㪈㪇㩼
㪉㪇㩼
㪊㪇㩼
㪋㪇㩼
㪌㪇㩼
㪍㪇㩼
㪎㪇㩼
㪏㪇㩼
㪐㪇㩼
㪈㪇㪇㩼


JAEA-Data/Code 2008-0XXᒝᐲ㩿㪺㫇㫊㪀

 

㪋㪅㪇㪇

㪏㪅㪇㪇

㪉㱔㩿㪚㫌㪄㪢㪸㪀

㪍㪅㪇㪇

㪈㪇㪅㪇

㪈㪉㪅㪇

㪻㩿㪇㪇㪈㪀ᐩ㕙㑆㓒㩿㷬㪀
㪏
㪇㪅㪇㪇

㪈㪇

㪈㪉

㪈㪋

㪈㪍

㪈㪏

㪉㪇

㪉㪇㪅㪇

㪍㪇㪅㪇

⋧ኻḨᐲ㩿㩼㪀

㪋㪇㪅㪇㪚㪸ဳ㩿㪪㪸㫋㫆㩷㪼㫋㩷㪸㫃㪅㪈㪐㪐㪉㪀㪥㪸ဳ㩿㪪㪸㫋㫆㩷㪼㫋㩷㪸㫃㪅㪈㪐㪐㪉㪀ᄌ⾰ㇱ㪪㪮㪄㪏㪇㷄㩷㪢㫌㫅㫀㫇㫀㪸㪄㪝

㪏㪇㪅㪇

㪈㪇㪇

㪋㪅㪇㪇

㪏㪅㪇㪇

㪉㱔㩿㪚㫌㪄㪢㪸㪀

㪍㪅㪇㪇

㪈㪇㪅㪇

㪇㩼
㪈㪇㩼
㪉㪇㩼
㪊㪇㩼
㪋㪇㩼
㪌㪇㩼
㪍㪇㩼
㪎㪇㩼
㪏㪇㩼
㪐㪇㩼
㪈㪇㪇㩼

㪈㪉㪅㪇

㪏
㪇㪅㪇㪇

㪈㪇

㪈㪉

㪈㪋

㪈㪍

㪈㪏

㪉㪇

㪉㪇㪅㪇

㪋㪇㪅㪇

㪍㪇㪅㪇

㪚㪸ဳ㩿㪪㪸㫋㫆㩷㪼㫋㩷㪸㫃㪅㪈㪐㪐㪉㪀㪥㪸ဳ㩿㪪㪸㫋㫆㩷㪼㫋㩷㪸㫃㪅㪈㪐㪐㪉㪀ᧂᄌ⾰ㇱ㩷㪪㪮㪄㪏㪇㷄㩷㪢㫌㫅㫀㫇㫀㪸㪄㪝

㪏㪇㪅㪇

㪈㪇㪇

36

⋧ኻḨᐲ㩿㩼㪀
࿑ 㪋㪅㪍㪅㪊䋭㪈㪉㩷 㪪㪮䋭㪏㪇㷄㩷 㪢㫌㫅㫀㫇㫀㪸䋭㪝 ᧂᄌ⾰ㇱ⹜ᢱ䈱Ḩᐲ೙ᓮ᷹ቯ⚿ᨐ䈫⋧ኻḨᐲ䈮ኻ䈜䉎 㪻㩿㪇㪇㪈㪀ᐩ㕙㑆㓒䈱ᄌൻ㩷㪉㪅㪇㪇ᒝᐲ㩿㪺㫇㫊㪀

- 36 㪻㩿㪇㪇㪈㪀ᐩ㕙㑆㓒㩿㷬㪀࿑ 㪋㪅㪍㪅㪊䋭㪈㪈㩷 㪪㪮䋭㪏㪇㷄㩷 㪢㫌㫅㫀㫇㫀㪸䋭㪝 ᄌ⾰ㇱ⹜ᢱ䈱Ḩᐲ೙ᓮ᷹ቯ⚿ᨐ䈫⋧ኻḨᐲ䈮ኻ䈜䉎 㪻㩿㪇㪇㪈㪀ᐩ㕙㑆㓒䈱ᄌൻ㩷

㪉㪅㪇㪇

㪇㩼
㪈㪇㩼
㪉㪇㩼
㪊㪇㩼
㪋㪇㩼
㪌㪇㩼
㪍㪇㩼
㪎㪇㩼
㪏㪇㩼
㪐㪇㩼
㪈㪇㪇㩼

JAEA-Data/Code 2008-0XX


㪍㪇㪇

㪋㪇㪇㪇

㩿㪘㪀

㪊㪌㪇㪇

㪌㪇㪇

㩿㪙㪀㩷

㪌㪅㪉㪈㫦㩿㪈㪍㪅㪐㪏㫻㪀㪊㪇㪇㪇㪌㪅㪉㪌㫦㩿㪈㪍㪅㪍㪍㫻㪀㩷㪉㪌㪇㪇ᒝᐲ㩿㪺㫇㫊㪀

ᒝᐲ㩿㪺㫇㫊㪀

㪋㪇㪇

㪊㪇㪇

㪉㪇㪇㪇
㪈㪌㪇㪇

㪉㪇㪇
㪈㪇㪇㪇
㪈㪇㪇
㪌㪇㪇
㪇
㪇㪅㪇㪇

㪈㪇㪅㪇

㪉㪇㪅㪇

㪊㪇㪅㪇

㪉㱔㩿㪚㫌㪄㪢㪸㪀

㪋㪇㪅㪇

㪌㪇㪅㪇

㪇
㪇㪅㪇㪇

㪍㪇㪅㪇

㪎㪇㪇

㪍㪇㪇

㩿㪘㪀

㪌㪅㪉㪈㫦㩿㪈㪍㪅㪐㪏㫻㪀㩷

㪍㪇㪇

㪊㪇㪅㪇

㪋㪇㪅㪇

㪌㪇㪅㪇

㪍㪇㪅㪇

㩿㪙㪀㩷

㪌㪅㪈㪐㫦㩿㪈㪎㪅㪇㪇㫻㪀㪌㪇㪇ᒝᐲ㩿㪺㫇㫊㪀

ᒝᐲ㩿㪺㫇㫊㪀

㪉㪇㪅㪇

㪎㪇㪇

㪌㪇㪇

㪋㪇㪇

㪊㪇㪇

㪋㪇㪇

㪊㪇㪇

㪉㪇㪇

㪉㪇㪇

㪈㪇㪇

㪈㪇㪇

㪇
㪇㪅㪇㪇

㪈㪇㪅㪇

㪉㱔㩿㪚㫌㪄㪢㪸㪀࿑ 㪋㪅㪍㪅㪋䋭㪈㩷 㪪㪮䋭㪏㪇㷄⹜ᢱ䈱 㪜㪞 ಣℂቯᣇ૏᷹ቯ⚿ᨐ㩷㩿㪘㪀䋺ᄌ⾰ㇱ⹜ᢱ䋬㩿㪙㪀䋺ᧂᄌ⾰ㇱ⹜ᢱ㩷

㪈㪇㪅㪇

㪉㪇㪅㪇

㪊㪇㪅㪇

㪋㪇㪅㪇

㪌㪇㪅㪇

㪇
㪇㪅㪇㪇

㪍㪇㪅㪇

㪈㪇㪅㪇

㪉㪇㪅㪇

㪊㪇㪅㪇

㪋㪇㪅㪇

㪌㪇㪅㪇

㪍㪇㪅㪇

㪉㱔㩿㪚㫌㪄㪢㪸㪀㪉㱔㩿㪚㫌㪄㪢㪸㪀࿑ 㪋㪅㪍㪅㪋䋭㪉㩷 㪪㪮䋭㪌㪇㷄⹜ᢱ䈱 㪜㪞 ಣℂቯᣇ૏᷹ቯ⚿ᨐ㩷㩿㪘㪀䋺ᄌ⾰ㇱ⹜ᢱ䋬㩿㪙㪀䋺ᧂᄌ⾰ㇱ⹜ᢱ㩷
㪈㪇㪇㪇

㪈㪋㪇㪇

㩿㪘㪀

㪌㪅㪉㪈㫦㩿㪈㪍㪅㪐㪏㫻㪀㩷

㪈㪉㪇㪇

㩿㪙㪀㩷

㪌㪅㪈㪐㫦㩿㪈㪍㪅㪐㪎㪐㫻㪀

㪏㪇㪇

㪍㪇㪇

ᒝᐲ㩿㪺㫇㫊㪀

ᒝᐲ㩿㪺㫇㫊㪀

㪈㪇㪇㪇

㪋㪇㪇

㪏㪇㪇

㪍㪇㪇

㪋㪇㪇

㪉㪇㪇
㪉㪇㪇

㪇
㪇㪅㪇㪇

㪈㪇㪅㪇

㪉㪇㪅㪇

㪊㪇㪅㪇

㪉㱔㩿㪚㫌㪄㪢㪸㪀

㪋㪇㪅㪇

㪌㪇㪅㪇

㪇
㪇㪅㪇㪇

㪍㪇㪅㪇

㪈㪇㪅㪇

㪉㪇㪅㪇

㪊㪇㪅㪇

㪉㱔㩿㪚㫌㪄㪢㪸㪀㪋㪇㪅㪇࿑ 㪋㪅㪍㪅㪋䋭㪊㩷 㪞㪮䋭㪈䋭㪏㪇㷄⹜ᢱ䈱 㪜㪞 ಣℂቯᣇ૏᷹ቯ⚿ᨐ㩷㩿㪘㪀䋺ᄌ⾰ㇱ⹜ᢱ䋬㩿㪙㪀䋺ᧂᄌ⾰ㇱ⹜ᢱ㩷
37

 

㪌㪇㪅㪇

㪍㪇㪅㪇


㪋㪇㪇㪇

㪉㪇㪇㪇

㩿㪘㪀

㪌㪅㪈㪐㫦㩿㪈㪍㪅㪐㪏㫻㪀㩷

㪊㪌㪇㪇

㩿㪙㪀㩷

㪌㪅㪉㪈㫦㩿㪈㪎㪅㪇㪇㫻㪀

㪊㪇㪇㪇

㪈㪌㪇㪇

ᒝᐲ㩿㪺㫇㫊㪀

ᒝᐲ㩿㪺㫇㫊㪀

㪉㪌㪇㪇
㪈㪇㪇㪇

㪉㪇㪇㪇
㪈㪌㪇㪇
㪈㪇㪇㪇

㪌㪇㪇

㪌㪇㪇
㪇
㪇㪅㪇㪇

㪈㪇㪅㪇

㪉㪇㪅㪇

㪊㪇㪅㪇

㪋㪇㪅㪇

㪌㪇㪅㪇

㪇
㪇㪅㪇㪇

㪍㪇㪅㪇

㪈㪇㪅㪇

㪉㪇㪅㪇

㪉㱔㩿㪚㫌㪄㪢㪸㪀

㪊㪇㪅㪇

㪋㪇㪅㪇

㪌㪇㪅㪇

㪍㪇㪅㪇

㪉㱔㩿㪚㫌㪄㪢㪸㪀࿑ 㪋㪅㪍㪅㪋䋭㪋㩷 㪞㪮䋭㪉䋭㪏㪇㷄⹜ᢱ䈱 㪜㪞 ಣℂቯᣇ૏᷹ቯ⚿ᨐ㩷㩿㪘㪀䋺ᄌ⾰ㇱ⹜ᢱ䋬㩿㪙㪀䋺ᧂᄌ⾰ㇱ⹜ᢱ㩷
㪊㪇㪇㪇

㪏㪇㪇

㩿㪘㪀

㪎㪇㪇

㪉㪌㪇㪇

㪌㪅㪉㪈㫦㩿㪈㪎㪅㪇㪇㫻㪀㩷㩿㪙㪀㩷㪌㪅㪉㪋㫦㩿㪈㪎㪅㪇㪇㫻㪀

㪍㪇㪇
㪉㪇㪇㪇

ᒝᐲ㩿㪺㫇㫊㪀

ᒝᐲ㩿㪺㫇㫊㪀

㪌㪇㪇
㪋㪇㪇
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㪈㪇㪇
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㪋㪇㪅㪇

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㪇
㪇㪅㪇㪇

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㪌㪇㪅㪇

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㪉㱔㩿㪚㫌㪄㪢㪸㪀࿑ 㪋㪅㪍㪅㪋䋭㪌㩷 㪪㪮䋭㪏㪇㷄ᄢ᳇᧦ઙ⹜ᢱ䈱 㪜㪞 ಣℂቯᣇ૏᷹ቯ⚿ᨐ㩷㩿㪘㪀䋺ᄌ⾰ㇱ⹜ᢱ䋬㩿㪙㪀䋺ᧂᄌ⾰ㇱ⹜ᢱ㩷

㪈㪇㪇㪇

㪊㪇㪇㪇

㩿㪙㪀㩷

㩿㪘㪀

㪌㪅㪉㪈㫦㩿㪈㪎㪅㪇㪇㫻㪀㩷

㪉㪌㪇㪇

㪏㪇㪇

㪌㪅㪈㪎㫦㩿㪈㪎㪅㪇㪇㫻㪀ᒝᐲ㩿㪺㫇㫊㪀

ᒝᐲ㩿㪺㫇㫊㪀

㪉㪇㪇㪇
㪍㪇㪇

㪋㪇㪇

㪈㪌㪇㪇

㪈㪇㪇㪇
㪉㪇㪇

㪇
㪇㪅㪇㪇

㪌㪇㪇

㪈㪇㪅㪇

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㪊㪇㪅㪇

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㪇
㪇㪅㪇㪇

㪍㪇㪅㪇

㪈㪇㪅㪇

㪉㪇㪅㪇

㪊㪇㪅㪇

㪋㪇㪅㪇

㪉㱔㩿㪚㫌㪄㪢㪸㪀࿑ 㪋㪅㪍㪅㪋䋭㪍㩷 㪪㪮䋭㪏㪇㷄㩷 㪢㫌㫅㫀㫇㫀㪸䋭㪝 ⹜ᢱ䈱 㪜㪞 ಣℂቯᣇ૏᷹ቯ⚿ᨐ㩷㩿㪘㪀䋺ᄌ⾰ㇱ⹜ᢱ䋬㩿㪙㪀䋺ᧂᄌ⾰ㇱ⹜ᢱ㩷㪉㱔㩿㪚㫌㪄㪢㪸㪀

38

 

㪌㪇㪅㪇

㪍㪇㪅㪇



㩿㪘㪀㩷

㩿㪙㪀

㩿㪚㪀㩷

㩿㪛㪀

㩿㪘㪀䋺ข䉍಴䈚ᤨ䈱䉼䉺䊮䉦䊤䊛㩷㩿㪙㪀䋺䉼䉺䊮䉦䊤䊛䈱 ஥⬄䉕ข䉍ᄖ䈚䈢⁁ᘒ㩷㩿㪚㪀䋺䉼䉺䊮䉦䊤䊛䉕ข䉍ᄖ䈚䈢⁁ᘒ䇯਄ㇱ䈱⊕䈇౞╴ᒻ䈱䉅䈱䈲䉶䊤䊚䉾䉪䊐䉞䊦䉺㩷㩿㪛㪀䋺☼࿯ㇱಽ䉕ੑ䈧䈮ഀ䈦䈩὇⚛㍑䉕ข䉍㒰䈇䈢⁁ᘒ㩷౮⌀ 㪋㪅㪈㩷 ⹜ᢱណขᤨ䈱↹௝㩷

39

 



    

࿖㓙න૏♽㧔5+㧕
⴫㧝㧚5+ၮᧄන૏
5+ၮᧄන૏
ၮᧄ㊂ฬ⒓⸥ภ㐳ߐࡔ ࡯ ࠻ ࡞ O
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ᵹࠕ ࡦ ࡍ ࠕ #ᾲജቇ᷷ᐲ ࠤ ࡞ ࡆ ࡦ ‛ ⾰ ㊂ࡕ࡞ OQNశᐲ ࠞ ࡦ ࠺ ࡜ EF⴫㧞㧚ၮᧄන૏ࠍ↪޿ߡ⴫ߐࠇࠆ5+⚵┙න૏ߩ଀
5+ၮᧄන૏
⚵┙㊂ฬ⒓⸥ภ㕙Ⓧᐔ ᣇ ࡔ ࡯ ࠻ ࡞O૕Ⓧ┙ ᴺ ࡔ ࡯ ࠻ ࡞Oㅦ ߐ 㧘 ㅦ ᐲࡔ ࡯ ࠻ ࡞ Ფ ⑽OUടㅦᐲ ࡔ ࡯ ࠻ ࡞ Ფ ⑽ Ფ ⑽ OU
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O
ኒ ᐲ 㧔 ⾰ ㊂ ኒ ᐲ 㧕 ࠠࡠࠣ࡜ࡓᲤ┙ᴺࡔ࡯࠻࡞ MIO
⾰㊂૕Ⓧ㧔Ყ૕Ⓧ㧕 ┙ᴺࡔ࡯࠻࡞Ფࠠࡠࠣ࡜ࡓ OMI㔚ᵹኒᐲ ࠕ ࡦ ࡍ ࠕ Ფ ᐔ ᣇ ࡔ ࡯ ࠻ ࡞ #O⏛ ⇇ ߩ ᒝ ߐࠕ ࡦ ࡍ ࠕ Ფ ࡔ ࡯ ࠻ ࡞#O㧔 ‛ ⾰ ㊂ ߩ 㧕 Ớ ᐲ ࡕ ࡞ Ფ ┙ ᣇ ࡔ ࡯ ࠻ ࡞ OQNOノᐲ ࠞ ࡦ ࠺ ࡜ Ფ ᐔ ᣇ ࡔ ࡯ ࠻ ࡞ EFOዮ᛬₸ 㧔ᢙ‫ߩޓ‬㧕‫ޓ‬㧝⴫㧡㧚5+ធ㗡⺆ਸ਼ᢙ‫ ޓ‬ធ㗡⺆⸥ภ ਸ਼ᢙ‫ ޓ‬ធ㗡⺆࠲ 㨅ࠪ ࡛
 ࠺࠲ 㨆 ࠯
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⴫㧢㧚࿖㓙න૏♽ߣ૬↪ߐࠇࠆ߇࿖㓙න૏♽ߦዻߐߥ޿න૏

⴫㧟㧚࿕᦭ߩฬ⒓ߣߘߩ⁛⥄ߩ⸥ภߢ⴫ߐࠇࠆ5+⚵┙න૏
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ⷺ࡜ ࠫ ࠕ ࡦO࡮O D┙૕ⷺ ࠬ࠹࡜ࠫࠕࡦ C
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0Oࠛࡀ࡞ࠡ࡯ ઀੐ ᾲ㊂ ࠫ ࡘ ࡯ ࡞,
0࡮OO࡮MI࡮UᎿ ₸  ᡼ ኿ ᧤ࡢ
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O࡮MI࡮U㔚 ⩄  㔚 ᳇ ㊂ࠢ ࡯ ࡠ ࡦ%U࡮#㔚૏Ꮕ㧔㔚࿶㧕 ⿠㔚ജ ࡏ
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O࡮MI࡮U࡮#㕒㔚ኈ㊂ࡈ ࠔ ࡜ ࠼(%8O࡮MI࡮U࡮#
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O࡮MI࡮U࡮#ࠦ ࡦ ࠳ ࠢ ࠲ ࡦ ࠬࠫ ࡯ ࡔ ࡦ ࠬ
5#8O࡮MI࡮U࡮#⏛᧤࠙ ࠛ ࡯ ࡃ
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9D#O࡮MI࡮U࡮#࠮ ࡞ ࠪ ࠙ ࠬ ᷷ ᐲ ࠮࡞ࠪ࠙ࠬᐲ F͠శ᧤࡞ ࡯ ࡔ ࡦNOO࡮O࡮EFEF
EF࡮UT Eᾖᐲ࡞ࠢ
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NZO࡮O࡮EFO࡮EFNOO
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O࡮Uࠡ ࡯ ಽ ਈ  ࠞ ࡯ ࡑ✢㊂ᒰ㊂ ๟ㄝ✢㊂ᒰ
㊂ ᣇะᕈ✢㊂ᒰ㊂ ୘ ࠪ ࡯ ࡌ ࡞ ࠻
5X,MIO࡮U
ੱ✢㊂ᒰ㊂⚵❱✢㊂ᒰC ࡜ࠫࠕࡦ෸߮ࠬ࠹࡜ࠫࠕࡦߩ૶↪ߪ‫ޔ‬หߓᰴరߢ޽ߞߡ߽⇣ߥߞߚᕈ⾰ࠍ߽ߞߚ㊂ࠍ඙೎ߔࠆߣ߈ߩ⚵┙න૏ߩ⴫ߒᣇߣߒߡ೑ὐ߇޽ࠆ‫┙⚵ޕ‬න૏ࠍᒻ૞ࠆߣ߈ߩ޿ߊߟ߆ߩ
‫⴫ߪ଀↪ޓ‬㧠ߦ␜ߐࠇߡ޿ࠆ‫ޕ‬D ታ㓙ߦߪ‫⸥ߪߦᤨࠆߔ↪૶ޔ‬ภTCF෸߮UT߇↪޿ࠄࠇࠆ߇‫ޔ‬⠌ᘠߣߒߡ⚵┙න૏ߣߒߡ
ߩ⸥ภ̌㧝̍ߪ᣿␜ߐࠇߥ޿‫ޕ‬E ᷹శቇߢߪ‫ߩࡦࠕࠫ࡜࠹ࠬޔ‬ฬ⒓ߣ⸥ภUTࠍන૏ߩ⴫ߒᣇߩਛߦߘߩ߹߹⛽ᜬߒߡ޿ࠆ‫ޕ‬F ߎߩන૏ߪ‫ࠬ࠙ࠪ࡞࠮࡝ࡒߡߒߣ଀ޔ‬ᐲ㨙͠ߩࠃ߁ߦ5+ធ㗡⺆ࠍ઻ߞߡ↪޿ߡ߽⦟޿‫ޕ‬⴫㧠㧚න૏ߩਛߦ࿕᦭ߩฬ⒓ߣߘߩ⁛⥄ߩ⸥ภࠍ฽߻5+⚵┙න૏ߩ଀
5+⚵┙න૏
ฬ⒓
⸥ภ
5+ၮᧄන૏ߦࠃࠆ⴫ߒᣇ☼ᐲࡄ ࠬ ࠞ ࡞ ⑽2C࡮UO ࡮MI࡮Uജ ߩ ࡕ ࡯ ࡔ ࡦ ࠻ ࠾ࡘ࡯࠻ࡦࡔ࡯࠻࡞0࡮OO ࡮MI࡮U⴫㕙ᒛജ ࠾ࡘ࡯࠻ࡦᲤࡔ࡯࠻࡞
0O
MI࡮U



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ᐲ࡜ ࠫ ࠕ ࡦ Ფ ⑽TCFUO࡮O ࡮U Uⷺടㅦᐲ ࡜ ࠫ ࠕ ࡦ Ფ ᐔ ᣇ ⑽ TCFU O࡮O࡮UUᾲ ᵹ ኒ ᐲ  ᡼ ኿ ᾖ ᐲ ࡢ࠶࠻Ფᐔᣇࡔ࡯࠻࡞
MI࡮U
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

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ᾲ ኈ ㊂  ࠛ ࡦ ࠻ ࡠ ࡇ ࡯ ࠫࡘ࡯࡞Ფࠤ࡞ࡆࡦ
,O ࡮MI࡮U ࡮⾰ ㊂ ᾲ ኈ ㊂ 㧔 Ყ ᾲ ኈ ㊂ 㧕  ࠫࡘ࡯࡞Ფࠠࡠࠣ࡜ࡓ
, MI࡮- O ࡮U ࡮⾰ ㊂ ࠛ ࡦ ࠻ ࡠ ࡇ ࡯ Ფࠤ࡞ࡆࡦ
⚵┙㊂

⾰ ㊂ ࠛ ࡀ ࡞ ࠡ ࡯ࠫࡘ࡯࡞Ფࠠࡠࠣ࡜ࡓ,MI㧔 Ყ ࠛ ࡀ ࡞ ࠡ ࡯ 㧕ࡢ࠶࠻Ფࡔ࡯࠻࡞Ფࠤ
9 O࡮ᾲ
વዉ₸࡞ࡆࡦࠫࡘ࡯࡞Ფ┙ᣇࡔ࡯࠻૕ Ⓧ ࠛ ࡀ ࡞ ࠡ ࡯
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(Oㅘ⏛₸ ࡋࡦ࡝࡯Ფࡔ࡯࠻࡞
*Oࡕ ࡞ ࠛ ࡀ ࡞ ࠡ ࡯ࠫ ࡘ ࡯ ࡞ Ფ ࡕ ࡞,OQNࡕ ࡞ ࠛ ࡦ ࠻ ࡠ ࡇ ࡯  ࠫࡘ࡯࡞Ფࡕ࡞Ფࠤ࡞, OQN࡮ࡕ࡞ᾲኈ㊂ ࡆࡦ
ᾖ ኿ ✢ ㊂ 㧔 㨄 ✢ ෸ ߮ ǫ ✢ 㧕 ࠢ࡯ࡠࡦᲤࠠࡠࠣ࡜ࡓ
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
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O ࡮UT
Ფࠬ࠹࡜ࠫࠕࡦO ࡮U ࡮-O࡮MI࡮U ࡮O ࡮MI࡮UO࡮MI࡮U ࡮#O ࡮U࡮#
O ࡮U࡮#O ࡮MI ࡮U ࡮#O࡮MI࡮U ࡮#O ࡮MI࡮U ࡮OQN


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O ࡮MI࡮U ࡮- ࡮OQNMI ࡮U࡮#
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O ࡮O ࡮MI࡮U O ࡮MI࡮U⴫㧣㧚࿖㓙න૏♽ߣ૬↪ߐࠇߎࠇߦዻߐߥ޿න૏ߢ
5+න૏ߢ⴫ߐࠇࠆᢙ୯߇ታ㛎⊛ߦᓧࠄࠇࠆ߽ߩ
ฬ⒓⸥ภ
5+න૏ߢ޽ࠄࠊߐࠇࠆᢙ୯㔚 ሶ ࡏ ࡞ ࠻ G8 G8  ,⛔৻ේሶ⾰㊂න૏ W W  MIᄤ ᢥ න ૏ WC WC  O⴫㧤㧚࿖㓙න૏♽ߦዻߐߥ޿߇࿖㓙න૏♽ߣ‫ޓޓޓ‬૬↪ߐࠇࠆߘߩઁߩන૏
ฬ⒓⸥ภ
5+න૏ߢ޽ࠄࠊߐࠇࠆᢙ୯
ᶏ㉿㧝ᶏ㉿Oࡁ࠶࠻㧝ࡁ࠶࠻㧝ᶏ㉿Ფᤨ  OUࠕ࡯࡞ C 㧝CFCOOࡋ ࠢ ࠲ ࡯ ࡞ JC 㧝JCJOOࡃ࡯࡞ DCT 㧝DCT/2CM2CJ2C2C
ࠝࡦࠣࠬ࠻ࡠ࡯ࡓ Έ 㧝ΈPOOࡃ࡯ࡦ D 㧝DHOO⴫㧥㧚࿕᦭ߩฬ⒓ࠍ฽߻%)5⚵┙න૏ฬ⒓⸥ภ 5+න૏ߢ޽ࠄࠊߐࠇࠆᢙ୯ࠛ࡞ࠣ GTI GTI ,࠳ࠗࡦ F[P F[P0

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2
2F[P࡮UEO 2C࡮Uࠬ ࠻ ࡯ ࠢ ࠬ 5V 5VEOUOU

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) 6ࠛ ࡞ ࠬ ࠹ ࠶ ࠼ 1G 1G Ǹ #Oࡑ ࠢ ࠬ ࠙ 㨴 ࡞ /Z /Z9Dࠬ࠴࡞ࡉ UD UDEFEOEFOࡎ࠻ RJ RJNZࠟ࡞ )CN )CNEOUOU



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

⸥ภ
5+න૏ߦࠃࠆ୯
OKP OKPUJJOKPUF
FJUq q Ǹ TCF
̉ ̉  q Ǹ TCF
̍ ̍  ̉ Ǹ TCF
N‫ޔ‬. NFOOVV MI0R 0R$$  NP 0R





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ฬ⒓
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

O ࡮O ࡮MI࡮U MI࡮U⴫㧚࿖㓙න૏ߦዻߐߥ޿ߘߩઁߩන૏ߩ଀
ฬ⒓⸥ภ
5+න૏ߢ޽ࠄࠊߐࠇࠆᢙ୯
ࠠࡘ࡝
࡯ %K %K$S࡟ ࡦ ࠻ ࠥ ࡦ 4 4%MI࡜࠼ TCF TCFE)[)[࡟
ࡓ TGO TGOE5X5X
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:WPKV POࠟࡦࡑ ǫ ǫP66ࠫ ࡖ ࡦ ࠬ ࠠ ࡯ ,[ ,[9࡮Ox*\

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HGTOKHO Oࡔ࡯࠻࡞♽ࠞ࡜࠶࠻
OGVTKEECTCVOI MI࠻࡞ 6QTT 6QTT  2C
ᮡ Ḱ ᄢ ᳇ ࿶ CVO CVO2C
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
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