Flow direction

http://www.htsj.or.jp/heat-page.html

0㩷

0

2mm

2mm

๟࿐ⓨ᳇ᵹㅦ2.6cm/s ߩਛߦ⟎߆ࠇߚΆᢱᶧṢἫἻߩ⋥ធ౮⌀㧔ᵹࠇߪᏀ߆ࠄฝ㧘౮⌀ߪ㧘ᶧṢ⋥ᓘ߇ 2.3mm ߩ⍍㑆ࠍᝒ߃ߚ߽ߩ㧚Άᢱ㧦n-ࡁ࠽࠺ࠞࡦ,๟࿐㉄⚛Ớᐲ 35%㧕

⋥ធἫἻߣหᤨߦ᠟ᓇߒߚἫἻ
ౝㇱߩߔߔ↢ᚑ᭴ㅧ㧔532nm ࡟࡯ࠩశࠍ⢛᥊శߣߒߡ᠟ᓇ,  ု✢ߣߒߡ 125μm ߩ⍹⧷ࡈࠔࠗࡃ
࡯ࠍ૶↪㧕ᓸዊ㊀ജ႐䉕೑↪䈚䈢ዊ䈘䈭䉴䊥䉾䊒ㅦᐲ䈱䈅䉎ΆᢱᶧṢ๟䉍䈱ἫἻ䈫䈜䈜↢ᚑ᭴ㅧ䈱ⷰኤ
Soot formation in a droplet combustion exposed to a low external flow velocity under microgravity⮮↰ ୃ㧔ർᶏ㆏ᄢቇ㧕 Osamu FUJITA (Hokkaido University)
ofujita@eng.hokudai.ac.jp ྃ㔵Ά὾ߩᶧṢ☸ሶߪ⋥ᓘ߇ᢙච μ㨙ߣዊߐߊ㧘ΆᢱᶧṢߪ๟࿐ᵹࠇߣ߶߷ㅪേߒߡ⒖േߔࠆ߇㧘ታ㓙ߦߪ☸ሶߣ๟࿐ᵹߩ㑆ߦࠊߕ߆ߥࠬ࡝࠶ࡊㅦᐲ߇ሽ࿷ߒߡ޿ࠆ㧚৻ᣇ㧘න৻ᶧṢࠍ↪޿ታ㛎⊛ߦᶧṢΆ὾ߦኻߔࠆࠬ࡝࠶ࡊ
ㅦᐲߩᓇ㗀ࠍ⺞ߴࠃ߁ߣߒߡ߽㧘ᶧṢ๟ࠅߦᒝ޿⥄ὼኻᵹ߇⊒↢ߒ㧘છᗧߩࠬ࡝࠶ࡊㅦᐲࠍਈ߃ࠆߎߣ⥄૕ਇน⢻ߢ޽ࠆ㧚ߘߎߢ㧘ᓸዊ㊀ജ႐ࠍ೑↪ߔࠆߎߣߢ⥄ὼኻᵹߩᓇ㗀ࠍឃ㒰ߒ㧘ᭂ߼ߡዊߐߥࠬ࡝࠶ࡊᵹㅦ㧔2.6cm/s㧕ߩਛߢᶧṢΆ὾ࠍⷰኤߒߚ㧚ᓸዊ㊀ജ႐ߩἫἻߪㅢᏱ⃿ᒻߦߥࠆ߇㧘ࠊߕ߆ߥࠬ࡝࠶ࡊㅦᐲࠍਈ߃ࠆߣ㧘ἫἻߪᵹࠇߩਅᵹᣇะ߳િ߮ߚᒻ⁁ߣߥࠆ㧚ߐࠄߦ㧘⢛᥊శ᠟ᓇߦࠃࠅἫἻౝㇱߩߔߔࠍนⷞൻߒߚߣߎࠈ㧘౮⌀ߩࠃ߁ߦᶧṢㄭறߦߔߔỚᐲߩ㜞޿Ზ⁁ߩ㗔ၞ߇⃻ࠇ㧘ߎࠇ߇ਅᵹ߳િ߮ߡ޿ࠆ᭽ሶ߇⷗಴ߐࠇߚ㧚ߎࠇߪ㧘㕒ᱛ㔓࿐᳇ਅߩᶧṢἫἻߦ⃻ࠇࠆ Soot Shell ߩਅᵹ஥߇㧘ࠬ࡝࠶ࡊㅦᐲߩᓇ㗀ߢ⎕ࠇߚ᭴ㅧߢ޽ࠆߣ⠨߃ࠄࠇࠆ㧚߹ߚ㧘ߎߩ Shellߩᄖ஥ߦᐢߊಽᏓߔࠆߔߔߩᓇ߇ਅᵹߦㅴ߻߶ߤ㧘Shell ㄭறߦ㓸߹ߞߡߊࠆ᭽ሶ߇ࠊ߆ࠆ߇㧘ߎࠇߪἫἻߣ Shellߩ㑆ߩ᷷ᐲ൨㈩ߦࠃࠆᾲᵒേലᨐߢߔߔ߇ Shell ᣇะߦャㅍߐࠇߚ⚿ᨐߣ⸃㉼ߒߡ޿ࠆ㧚 ᧄ౮⌀ߪ㧘ᒰᤨർᄢᄢቇ㒮↢ߩ੗਄㗅ᤘำ㧔⃻ਃ⪉㊀Ꮏ㧕ߣදജߒขᓧߒߚ߽ߩߢߔ㧚ߎߎߦ⻢ᗧࠍ⴫ߒ߹ߔ㧚વᾲ 2009 ᐕ 4 ᦬

J. HTSJ, Vol. 48, No. 203

Vol.48

2009

No.203April

વ  ᾲ⋡ ᰴ‫․ޛ‬㓸㧦᳓⚛ߩ‛ᕈ߅ࠃ߮᧚ᢱ‫ޜ‬᳓⚛ߩ⇣ᕈ૕ߣᾲ‛ᕈ············································㜞↰଻ਯ㧘ㄼ↰⋥਽㧔਻Ꮊᄢቇ㧕 ··············1
HYDROGENIUS ࡊࡠࠫࠚࠢ࠻ߦ߅ߌࠆ᳓⚛⣀ൻ⎇ⓥ㧦᳓⚛⣀ൻߪ⣀ᕈ⎕უ߆ᑧᕈ⎕უ߆······················································································᧻ጟਃ㇢㧔਻Ꮊᄢቇ㧕 ··············7
᳓⚛ߩ⾂⬿ャㅍߣ᳓⚛⾂⬿᧚ᢱ································⑺⪲ᖝ↵㧔↥ᬺᛛⴚ✚ว⎇ⓥᚲ㧕 ············ 20᳓⚛ߪෂߥ޿߆················································ ਃ⍹ᵗਯ㧔㧔⽷㧕ᣣᧄ⥄േゞ⎇ⓥᚲ㧕 ············ 26⢻േ⊛ߥ὇⚛ᓴⅣࠛࡀ࡞ࠡ࡯ࠪࠬ࠹ࡓߩน⢻ᕈᬌ⸛ ·············ട⮮ਯ⾆㧔᧲੩Ꮏᬺᄢቇ㧕 ············ 34㜞࿶࡮㜞᷷᧦ઙਅߩ᳓⚛ߩᾲ‛ᕈ⸘᷹································⮮੗਍ᄦ㧔↥✚⎇㧕㜞↰଻ਯ㧔਻Ꮊᄢቇ㧕ᣂ㉿ኡ⧷㧔↥✚⎇㧕 ············ 40‫࠻ࠢࠚࠫࡠࡊޛ‬㧽‫ޜ‬ᄢቇࠠࡖࡦࡄࠬߩ᳓⚛ࠬ࠹࡯࡚ࠪࡦ ··········᧖᧛ਂ৻㧘ጟ↰િᑝ㧘દ⮮ⴧᐔ㧔਻Ꮊᄢቇ㧕 ············ 48
᡼ᾲᕈ㍑᧼‫࠷ࡀ࡯ࡎࡌ࡯ࠦޟ‬տ‫ߩޠ‬㐿⊒····································㜞ᯅ๺㓶㧔␹ᚭ⵾㍑㧕 ············ 54
߈ߊ 8 ภ៞タዷ㐿ဳ࡜ࠫࠛ࡯࠲ߩ゠㆏਄ㆇ↪ߣ 1 ᐕ⋡ߩേ૞․ᕈ
····························Ꮉፒᤐᄦ, ⍫ㇱ㜞ብ, ጟᧄ◊, ㊄᫪ᐽ㇢㧔ቝቮ⥶ⓨ⎇ⓥ㐿⊒ᯏ᭴㧕 ································ ⍹Ꮉඳ┨, ㊁᧛ᱞ⑲㧔ਃ⪉㔚ᯏ㧕ᢪ⮮ᐽਯ㧔ਃ⪉㔚ᯏࠛࡦࠫ࠾ࠕ࡝ࡦࠣ㧕 ············ 58‫․ޛ‬೎ነⓂ‫ޜ‬⠴ᾲశࡈࠔࠗࡃ·······································································᧛਄ᵏ㧔ାᎺᄢቇ㧕 ············ 63‫ޛ‬Ꮞ㗡ࠣ࡜ࡆࠕ㧦heat-page‫ޜ‬ᓸዊ㊀ജ႐ࠍ೑↪ߒߚዊߐߥࠬ࡝࠶ࡊㅦᐲߩ޽ࠆΆᢱᶧṢ๟ࠅߩἫἻߣߔߔ↢ᚑ᭴ㅧߩⷰኤ
···················································································⮮↰ ୃ㧔ർᶏ㆏ᄢቇ㧕 ······ ⴫⚕ⵣ‫ⴕޛ‬੐ࠞ࡟ࡦ࠳࡯‫ ·········································································································· ޜ‬67‫߅ޛ‬⍮ࠄߖ‫ޜ‬╙ 14 ࿁࿖㓙વᾲળ⼏㧦IHTC-14 ⺰ᢥ൐㓸ߩ߅⍮ࠄߖ㧔ળ๔㧕 ············································· 68╙ 46 ࿁ᣣᧄવᾲࠪࡦࡐࠫ࠙ࡓ㐿௅⋥೨ߩߏ᩺ౝ ··································································· 69੐ോዪ߆ࠄߩㅪ⛊············································································································ 89✬㓸಴ㇱળࡁ࡯࠻········································································································· 94

Vol. 48㧘No. 203㧘April 2009
CONTENTS
㧨Special Issue㧪
Hydrogen Isomers and Its Thermophysical Properties
Yasuyuki TAKATA, Naoya SAKODA (Kyushu University) ·························································· 1
Research of Hydrogen Embrittlement in HYDROGENIUS Project
Saburo MATSUOKA (Kyushu University) ···················································································· 7
Hydrogen Storage and Transportation: Hydrogen Storage Materials
Etsuo AKIBA (AIST) ··················································································································· 20
Safety Research on Hydrogen Fueled Vehicle
Hiroyuki MITSUISHI (Japan Automobile Research Institute) ······················································ 26
Feasibility Study of Active Carbon Recycle Energy System
Yukitaka KATO (Tokyo Institute of Technology) ········································································· 34
Measurements of Thermophysical Properties of Hydrogen at High Pressure and High Temperature
Motoo FUJII(AIST) Yasuyuki TAKATA(Kyushu University), Kan-ei SINZATO (AIST) ············ 40

㧨Project Q㧪
Hydrogen Refueling Station in University Campus
Joichi SUGIMURA, Nobuhiro OKADA, Kohei ITO (Kyushu University) ···································· 48
Development of “KOBEHONRTSU” Heat Releasing Steel Sheet
Kazuo Takahashi (Kobe Steel Ltd.) ······························································································ 54
The First Annual Characteristics Test of Deployable Radiator (DPR) of Kiku-Ϊ on Geo Stationary Orbit
Haruo KAWASAKI, Takahiro YABE, Atsushi OKAMOTO, Yasurou KANAMORI(JAXA),
Hiroaki ISHIKAWA, Takehide NOMURA(MELCO), Yasuyuki SAITO (MEE) ·························· 58

㧨Contribution㧪Heat-resistant Glass Optical Fiber
Yasushi MURAKAMI (Shinshu University) ·················································································· 63

㧨Opening-page Gravure: heat-page㧪
Soot formation in a droplet combustion exposed to a low external flow velocity under microgravity
Osamu FUJITA (Hokkaido University) ······································································ Opening Page

㧨Calendar㧪·························································································································································· 67
㧨Announcements㧪 ············································································································································ 68

․㓸㧦᳓⚛ߩ‛ᕈ߅ࠃ߮᧚ᢱ

᳓⚛ߩ⇣ᕈ૕ߣᾲ‛ᕈ
Hydrogen Isomers and Its Thermophysical Properties㜞↰଻ਯ㧘ㄼ↰⋥਽㧔਻Ꮊᄢቇ㧕
Yasuyuki TAKATA and Naoya SAKODA (Kyushu University)e-mail: takata@mech.kyushu-u.ac.jp, sakoda@mech.kyushu-u.ac.jp
ᕈ୯߇ឝタߐࠇߡ޿ࠆ߇㧘ᓟㅀߔࠆࠃ߁ߦ㧘ታ᷹࠺࡯࠲ߪਲߒߊ㧘ૐ࿶㧘ૐ᷷ၞߩ࠺࡯࠲߆ࠄߩᄖ
ᝌ୯߇૶ࠊࠇߡ޿ࠆ㧚2007 ᐕߦ㧘Leachman[6]㧘GERG[7]ߩ⁁ᘒᣇ⒟ᑼ
߇㐿⊒ߐࠇߡ޿ࠆ߇㧘㜞᷷㧘㜞࿶ၞߩታ᷹࠺࡯࠲
ߪ߿ߪࠅሽ࿷ߖߕ㧘⁁ᘒᣇ⒟ᑼߩ▸࿐ࠍ᜛ᒛߒߡ
૶↪ߒߡ޿ࠆߩ߇⃻⁁ߢ޽ࠆ㧚FCV ߩ᳓⚛ኈེߩ㜞࿶ൻߦ઻ߞߡ㧘100MPa ߹ߢߩታ᷹࠺࡯࠲ࠍᢛ
஻ߒ㧘㜞࿶ၞ߹ߢ♖ᐲ߇଻㓚ߐࠇߚ⁁ᘒᣇ⒟ᑼߩ
㐿⊒߇ᦸ߹ࠇߡ޿ࠆ㧚ߎߩࠃ߁ߥ⁁ᴫߢ㧘᳓⚛ߩᾲ‛ᕈߦߟ޿ߡߩ⍮⷗ࠍᢛℂߒߡ߅ߊߎߣߪ㕖Ᏹ
ߦ㊀ⷐߢ޽ࠆ㧚ᧄⓂߢߪ㧘᳓⚛ߩ⇣ᕈ૕㧘ᾲജቇᕈ⾰߅ࠃ߮ャㅍᕈ⾰ߩ⃻⁁ࠍ⚫੺ߔࠆ㧚ߪߓ߼ߦ
᳓⚛ߪࠢ࡝࡯ࡦߥੑᰴࠛࡀ࡞ࠡ࡯ߣߒߡ዁᧪߇
ᦼᓙߐࠇߡ޿ࠆ‛⾰ߢ޽ࠅ㧘ㄭᐕ㧘㐿⊒߿᥉෸߇ᵴ⊒ߣߥߞߚ࿕૕㜞ಽሶᒻΆᢱ㔚ᳰ(PEFC)ߩΆ
ᢱߣߒߡ૶↪ߐࠇ㧘⣉శࠍᶎ߮ߡ޿ࠆ㧚PEFC ࠍ៞タߒߚΆᢱ㔚ᳰゞ(FCV)ߩ᳓⚛ኈེߦߪ㧘⃻࿷
35MPa ߩ㜞࿶᳓⚛߇లႯߐࠇߡ޿ࠆ߇㧘৻࿁ߩలႯߢࠟ࠰࡝ࡦゞਗߺߩ⿛ⴕ〒㔌ࠍᓧࠆߚ߼ߦ㧘৻
ㇱ 70MPa ߢߩలႯ߽ᆎ߹ߞߡ޿ࠆ㧚ߣߎࠈ߇㧘ߎߩࠃ߁ߥ⿥㜞࿶ၞߩ᳓⚛ߩᾲ‛ᕈ୯ߩታ᷹୯ߪ㕖Ᏹߦਇ⿷ߒߡ޿ࠆߩ߇ታᖱߢ޽ࠆ㧚᳓⚛ߪ⓸⚛߿㉄⚛ߣหߓ 2 ේሶಽሶߢ޽ࠆ߇㧘ߘߩᝄࠆ⥰޿ߪߘࠇ⒟න⚐ߢߪߥ޿㧚ᚒ‫߇ޘ‬ㅢᏱ᳓⚛ߣ๭ࠎߢ޿ࠆ‛⾰ߪ㧘ࠝ࡞࠰᳓⚛
(ortho-hydrogen, o-H2) ߣ ࡄ ࡜ ᳓ ⚛ (para-hydrogen,p-H2)ߣ޿߁ 2 ߟߩ⇣ᕈ૕(isomer)ߩᷙว‛ߢ޽ࠅ㧘ߎࠇࠍᚒ‫࡞ࡑ࡯ࡁߪޘ‬᳓⚛(normal hydrogen, n-H2)ߣ๭ࠎߢ޿ࠆ㧚ߎߩ⇣ᕈ૕߇ Bonhoeffer ߣ Harteckߦࠃࠅ⊒⷗ߐࠇߚߩߪ 1929 ᐕߩߎߣߢ޽ࠅ㧘੹ᐕߪߘߩ⊒⷗߆ࠄ 80 ᐕ߇⚻ㆊߒߚߎߣߦߥࠆ㧚ታ↪
⊛ߦߪࡁ࡯ࡑ࡞᳓⚛ߣࡄ࡜᳓⚛ߩᾲ‛ᕈ߇㊀ⷐߥߩߢ޽ࠆ߇㧘Ყᾲ߿ᾲવዉ₸ߥߤ޿ߊߟ߆ߩᾲ‛ᕈߪਔ⠪ߢ⇣ߥࠆ୯ࠍᜬߟ㧚1935 ᐕߩ Farkas ߩ⪺ᦠ[1]ߦߪ㧘ࡄ࡜᳓⚛߿㊀᳓⚛ࠍ฽߻᳓⚛ߩ‛ᕈ߇⹦ߒߊ߹ߣ߼ࠄࠇߡ߅ࠅ㧘᳓⚛ߦ㑐ߔࠆᦨೋߩ‛ᕈ୯㓸ߣ⸒ߞߡ߽ࠃ޿ߢ޽ࠈ߁㧚1948 ᐕߦ Woolley ࠄ[2]߇߆ߥࠅᐢ▸࿐ߩ᷷ᐲ㧘࿶ജ㗔ၞߦㆡ↪ߢ߈ࠆ⁁ᘒᣇ⒟ᑼࠍ㐿⊒ߒߡ޿ࠆ㧚ߎߩ⁁ᘒᣇ⒟ᑼߪ⃻࿷ߢ߽৻ㇱ૶ࠊࠇߡ߅ࠅ㧘⪺⠪ߩ৻ੱ߇ᚲዻߔࠆࠣ࡞࡯ࡊߢ㐿⊒ߒߡ޿ࠆᵹ૕
ߩᾲ‛ᕈ୯ࡊࡠࠣ࡜ࡓ࡮ࡄ࠶ࠤ࡯ࠫ PROPATH ߦ߽⚵ߺㄟ߹ࠇߡ޿ࠆ㧚ߘߩᓟ㧘ࡠࠤ࠶࠻Άᢱߣߒߡߩ᳓⚛ߩ‛ᕈ୯ߩᔅⷐᕈ߆ࠄ㧘1970 ᐕઍߦ McCarty ࠄߦࠃߞߡ⹦⚦ߥ᳓⚛ߩ‛ᕈ୯࠺࡯࠲㓸߇⛯‫[➏✬ߣޘ‬3,4,5]ߐࠇ
ߚ㧚McCarty ߩ࠺࡯࠲㓸ߦߪ㧘㜞࿶㧘㜞᷷ၞߩ‛વᾲ 2009 ᐕ 4 ᦬᳓⚛ߩ⇣ᕈ૕ ࠝ࡞࠰㧘ࡄ࡜㧘ࡁ࡯ࡑ࡞㧘ᐔⴧ᳓⚛᳓⚛ߪ 2 ේሶಽሶߢ޽ࠆ߇㧘ᩭࠬࡇࡦߩะ߈ߩ
㆑޿ߦࠃࠅ㧘ࠝ࡞࠰ߣࡄ࡜ߩ 2 ߟߩ⇣ᕈ૕߇ሽ࿷
ߔࠆ㧚ㅢᏱߩ᳓⚛ࠟࠬ㧘ߔߥࠊߜࡁ࡯ࡑ࡞᳓⚛ߪ㧘
ࠝ࡞࠰ 75㧑㧘ࡄ࡜ 25㧑ߩᷙว‛ߢ޽ࠆ㧚ࠝ࡞࠰ߣࡄ࡜ߩ᭴ᚑᲧߪ᷷ᐲߦଐሽߒ㧘᳓⚛ਛߩࡄ࡜ᚑಽ
ߩ㊂ߪ㧘ᰴᑼߢਈ߃ࠄࠇࠆ[1]㧚
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⎪
⎪⎪
(2 j + 1)e − j ( j +1) B / kT ⎬∑[p-H 2 ] j = even⎪β==[o-H 2 ] ∑ 3(2 j + 1)e − j ( j +1) B / kT ⎪⎪⎭j = oddp-H 2 ᚑಽ =(1)ߎߎߢ㧘B/k=84.837 ߢ޽ࠆ㧚ᑼ(1)ࠍ᷷ᐲߦኻߒߡ
ࡊࡠ࠶࠻ߒߚߩ߇࿑ 1 ߢ޽ࠆ㧚ᑼ(1)ߪ㧘ߘߩ᷷ᐲߦኻߔࠆࠝ࡞࠰࡮ࡄ࡜ߩᐔⴧ⁁ᘒߩ᭴ᚑᲧࠍਈ߃ࠆ 㧚 ߎ ߩ ⚵ ᚑ ߩ ᳓ ⚛ ࠍ ᐔ ⴧ ᳓ ⚛ (equilibriumhydrogen, e-H2)ߣ๭߱㧚࿑ 1 ߆ࠄ㧘ૐ᷷ߦߥࠆߦߟ
ࠇߡࡄ࡜᳓⚛ߩᲧ₸߇Ⴧടߒ㧘ᶧ૕᳓⚛ߪ߶ߣࠎߤࡄ࡜᳓⚛ߢ᭴ᚑߐࠇࠆߎߣ߇ࠊ߆ࠆ㧚-1-

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․㓸㧦᳓⚛ߩ‛ᕈ߅ࠃ߮᧚ᢱ
ߩ㑐ଥ߇޽ࠆߩߢ㧘ኈེౝߦᱷሽߔࠆᶧ૕᳓⚛ߩ⾰㊂ഀวߪᰴᑼߢ⸘▚ߢ߈ࠆ㧚Fraction of p-H2

1

o-H2 75%

0.5

0.25

⎛ m ⎞ ⎛ Δh ⎞ ⎡⎤1ln ⎜ ⎟ = ⎜ conv ⎟ ⋅ ⎢− x0 ⎥   (4)⎜⎟⎝ m0 ⎠ ⎝ Δhevap ⎠ ⎣1/ x0 + ct⎦

Equilibrium Hydrogen: e-H 2

0.75

Normal Hydrogen: n-H 2

0 1
10

ᑼ(4)ߢ㧘లႯᤨߩೋᦼߩࠝ࡞࠰᳓⚛ߩഀวࠍ 0.1
㨪0.75 ߹ߢᄌൻߐߖߡ㧘ᢿᾲኈེౝߩᱷሽߔࠆᶧ
૕᳓⚛ߩഀวࠍ᳞߼ߡߺࠆߣ࿑ 2 ߩࠃ߁ߦߥࠆ㧚ᶧ૕᳓⚛ߩೋᦼ⚵ᚑ߇ࡁ࡯ࡑ࡞᳓⚛(x0=0.75)ߩ႐
วߪ㧘ᄌ឵ᾲߦࠃࠆ⥄Ꮖ⫳⊒ߢᶧ૕ߩഀว߇⚂42%߹ߢᷫዋߒߡߒ߹߁ߎߣ߇ࠊ߆ࠆ㧚ߎߩࠃ߁ߦ㧘ࠝ࡞࠰࡮ࡄ࡜ᄌ឵ߦߟ޿ߡߪ㧘㐳ᦼߦᷰࠆ᷹ⷰ߇ᔅⷐߥߩߢ㧘ෳ⠨ߦߥࠆᢥ₂߇ዋߥ޿㧚߹ߚ㧘᳓⚛ਛߩࠝ࡞࠰࡮ࡄ࡜᭴ᚑᲧࠍ᷹ቯ
ߔࠆߦߪ㧘NMR ߿࡜ࡑࡦಽశࠍ↪޿ࠆᣇᴺ߇޽
ࠆ߇㧘৻⇟◲ଢߥߩߪ㧘ࡄ࡜᳓⚛ߣࡁ࡯ࡑ࡞᳓⚛
ߩᾲવዉ₸ߩ㆑޿ࠍ೑↪ߒߚ᷹ቯᴺߢ޽ࠅ㧘ᶧൻ᳓⚛ࡊ࡜ࡦ࠻ߥߤߢណ↪ߐࠇߡ޿ࠆ[9]㧚

p-H2 25%

102
Temperature (K)103

Figure 1: Equilibrium composition of para- andortho-hydrogen as a function of temperatureࠝ࡞࠰࡮ࡄ࡜ᄌ឵
ࠝ࡞࠰ߣࡄ࡜ߩ㑆ߩᄌ឵ߦߪ 2 ߟߩ․╩ߔߴ߈ᕈ⾰߇޽ࠆ㧚৻ߟߪ㧘ᄌ឵ㅦᐲ߇ᭂ߼ߡㆃ޿ߣ޿
߁ߎߣߢ޽ࠆ㧚ࡁ࡯ࡑ࡞᳓⚛ࠍ಄ළߒߡᶧൻߒߡ
߽ᶧൻ᳓⚛ߩࠝ࡞࠰࡮ࡄ࡜᭴ᚑᲧߪࡁ࡯ࡑ࡞᳓⚛
ߩ߹߹ߢ޽ࠆ㧚ᤨ㑆߇⚻ߟߦߟࠇߡ㧘ᓢ‫࡞ࠝߦޘ‬࠰߆ࠄࡄ࡜߳ߩᄌ឵߇ㅴ߻߇㧘ඨಽߩࠝ࡞࠰᳓⚛
߇ࡄ࡜᳓⚛ߦᄌ឵ߔࠆߩߦ 1 ᐕએ਄߆߆ࠆߣ⸒ࠊ
ࠇߡ޿ࠆ㧚ߒߚ߇ߞߡ㧘ᶧൻࡊ࡜ࡦ࠻ߥߤߢߪ⏛ᕈ⸅ᇦࠍ↪޿ߡ㧘ᄌ឵ࠍടㅦߐߖߡࡄ࡜᳓⚛ࠍ⵾ㅧߔࠆ㧚
߽߁ 1 ߟߩ․ᓽߪ㧘ࠝ࡞࠰߆ࠄࡄ࡜ߦᄌ឵ߔࠆ
㓙ߦᾲߩ⊒↢ࠍ઻߁ߣ޿߁ߎߣߢ޽ࠆ㧚⊒ᾲ㊂ߪ᷷ᐲߦଐሽߒ㧘300K ઃㄭߢߪ㧘ࡁ࡯ࡑ࡞᳓⚛න૏⾰㊂޽ߚࠅߩᄌ឵ᾲߪ 27kJ/kg ⒟ᐲߣዊߐ޿߇㧘ᮡḰᴣὐ(20.4K)ߦ߅ߌࠆᄌ឵ᾲߪ 523kJ/kg ߢ޽ࠅ㧘ߎߩ୯ߪ⫳⊒ẜᾲ 448.3kJ/kg ࠃࠅ߽ᄢ߈޿㧚ᶧൻߐࠇߚࡁ࡯ࡑ࡞᳓⚛ߩਛߩࠝ࡞࠰᳓⚛߇ࡄ࡜᳓⚛ߦᄌ឵ߔࠆ㓙ߩ⊒ᾲߦࠃࠅ㧘⥄Ꮖ⫳⊒߇↢ߓࠆ㧚Larsen[8]ߪࠝ࡞࠰࡮ࡄ࡜ᄌ឵ߩ㓙ߩࠝ࡞࠰᳓
⚛ߩỚᐲࠍᰴᑼߢਈ߃ߡ޿ࠆ㧚⎫dx / dt = −cx 2⎬    
x = 1/[(1/ x0 ) + ct ]⎭Mass fraction ofremaining liquid, m/m0 (-)

1
0.8

0.2

0.6

0.3
0.4
0.5
0.6

0.4

Initial o-H 2 concentration
x0=0.75

100

101
102
103
Storage time, t (h)104Figure 2: Mass fraction of remaining liquid in
adiabatic container᳓⚛ߩᾲജቇᕈ⾰
 286 ߣ⁁ᘒᣇ⒟ᑼ ᳓ ⚛ ߩ ⥃ ⇇ ὐ ߪ 㧘 ⥃ ⇇ ᷷ ᐲ 33K㧘 ⥃ ⇇ ࿶ ജ
1.3MPa ߣ㕖Ᏹߦૐ᷷㧘ૐ࿶ߢ PVT ߩ⁁ᘒᦛ㕙ߪ
࿑ 3 ߩࠃ߁ߦߥߞߡ޿ࠆ㧚PVT ߩ㑐ଥߪ㧘ࡁ࡯ࡑ࡞᳓⚛ߣࡄ࡜᳓⚛ߢ߶ߣࠎߤᄌࠊࠄߥ޿㧚࿑ 3 ߆ࠄ᣿ࠄ߆ߥࠃ߁ߦ㧘᳓⚛ߩኒᐲߪ㕖Ᏹߦዊߐߊ㧘଀ ߃ ߫ 60ºC ߢ 100MPa ߹ ߢ ࿶ ❗ ߒ ߡ ߽
22.9mol/dm3(= 46.2kg/m3)⒟ᐲߦߒ߆ߥࠄߥ޿㧚ℂᗐ᳇૕ߦㄭ޿ߣ⠨߃ࠄࠇࠆ᳓⚛ߛ߇㧘ℂᗐ᳇૕ߩ⁁ᘒᣇ⒟ᑼ㧧P = ρRT ߢኒᐲࠍ⸘▚ߔࠆߣ㧘(2)ߎߎߢ㧘c=12.6510-3hr-1 ߢ޽ࠅ㧘x0 ߪೋᦼ⁁ᘒߩࠝ࡞࠰᳓⚛ߩỚᐲߢ޽ࠆ㧚ᶧ૕᳓⚛ߩ⾰㊂ࠍ
m(kg)㧘⫳⊒ẜᾲߣᄌ឵ᾲࠍߘࠇߙࠇ㧘Δhevap㧘Δhconv
ߣߔࠆߣ㧘ኈེ߇ᢿᾲ⁁ᘒߢ๟࿐߆ࠄߩଚ౉ᾲߪ
ߥ޿ߣߔࠆߣ

−Δhconv m(dx / dt ) = −Δhevap (dm / dt )   (3)વᾲ 2009 ᐕ 4 ᦬

0.1

-2-

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․㓸㧦᳓⚛ߩ‛ᕈ߅ࠃ߮᧚ᢱ

20

Pressure (MPa)

line

40

)
(K
re
tu
ra

25

pe

K

m
Te

K
40

10 MPa

Solid
phase
K

20 MPa60

20

Tc

30 MPa80

Melting

K

K

50

K

60

K
100

80

K

20
0K

150

K
300

50 MPa

800
600
400
200

100

250
K

400
K

600
K

100 MPa

80 MPa

500
K

700
K

800 K

36.1mol/dm3 ߢ޽ߞߡ㧘58%߽⇣ߥࠆߎߣ߆ࠄ㧘ℂᗐ᳇૕ߢߩઍ↪ߪ࿎㔍ߢ㧘߿ߪࠅᱜ⏕ߥ‛ᕈ୯߇ᔅⷐਇนᰳߢ޽ࠆ㧚

0

10

20

30

5 MPa

40
3

50

0

Density (mol/dm )Figure 3: PVT surface of hydrogen calculated from theequation of state of normal hydrogen by Leachman [6]Pressure (MPa)

100

10

1

0.1
0

100

200

Verschoyle (1926), normal
Scott (1929), normal
Wiebe (1938), normal
Goodwin (1963), para
Weber (1975), para
Critical point
Younglove (1982)

300

400

500

Temperature (K)Bartlett (1927), normal
Bartlett (1930), normal
Michels (1941), normal
Roder (1963), para
Machado (1988), normal

600

700

800

Bartlett (1928), normal
Townend (1931), normal
Michels (1959), normal
Presnall (1969), normal
Jaeschke, Ruhrgas(1990), normalᕈ⾰ߩታ᷹୯ᖱႎࠍ߹ߣ߼ߡ޿ࠆ㧚࿑ 4 ߦ PVT ߩታ᷹୯ಽᏓࠍ␜ߔ㧚423K ߹ߢߪ van der Waals ⎇ⓥᚲߩ Michels ࠄ[12,13]߇᷹ቯ୯ࠍႎ๔ߒߡ޿ࠆ
߇㧘ߘࠇએ਄ߩ᷷ᐲߢߪ߶ߣࠎߤ᷹ቯ߇ⴕࠊࠇߡ
޿ߥ޿ߩ߇⃻⁁ߢ޽ࠆ㧚Younglove[14]ߪ 1982 ᐕߦࡄ࡜᳓⚛ߦኻߒ㧘᷷ᐲ▸࿐ 14K(ਃ㊀ὐ᷷ᐲ)߆ࠄ 400K㧘࿶ജ▸࿐
121MPa ߹ߢߩ㗔ၞߢㆡ↪น⢻ߥ㧘ᑼ(5)ߢ⴫ࠊߐ
ࠇࠆ Modified Benedict-Webb-Rubin (MBWR)ဳߩ
⁁ᘒᣇ⒟ᑼࠍ૞ᚑߒߚ㧚ߎߩ⁁ᘒᣇ⒟ᑼߪ㧘25 ᐕએ਄ߩ㐳߈ߦࠊߚࠅᐢߊ૶↪ߐࠇߡ޿ࠆ㧚 2007 ᐕߦߪ࠼ࠗ࠷ߩࠟࠬળ␠ࠍਛᔃߣߔࠆࠣ
࡞࡯ࡊߢ޽ࠆ GERG[7]߇ࡁ࡯ࡑ࡞᳓⚛ߦኻߒ㧘ᑼ(6)߆ࠄᑼ(8)ߦ␜ߔࠃ߁ߥ Helmholtz ⥄↱ࠛࡀ࡞ࠡ࡯ߩᒻߢ⸥ㅀߐࠇࠆ⁁ᘒᣇ⒟ᑼࠍ㧘᷷ᐲ▸࿐ 14K
߆ࠄ 700K㧘࿶ജ 300MPa ߹ߢߩ㗔ၞߦኻߒߡ૞ᚑ
ߒߚ㧚߹ߚ㧘NIST-ࠕࠗ࠳ࡎᄢቇߩࠣ࡞࡯ࡊߩ
Leachman[6]ߪ㧘ࠝ࡞࠰᳓⚛㧘ࡄ࡜᳓⚛㧘ࡁ࡯ࡑ࡞᳓⚛ߩ 3 ߟߩ᳓⚛ߦኻߒߡ㧘14K ߆ࠄ 1000K㧘
2000MPa ߹ߢ ߩ ᐢ ▸ ࿐ ߦ ࠊ ߚ ࠆ ⁁ ᘒ ᣇ ⒟ ᑼ ࠍ
GERG ߣห᭽ߥ Helmholtz 㑐ᢙဳߢ૞ᚑߒߚ(ᑼ(9)߆ࠄᑼ(11))㧚ታ᷹୯ߩౣ⃻ᕈ߆ࠄ್ᢿߔࠆߣ㧘⃻⁁ߢߪ Leachman ߩ⁁ᘒᣇ⒟ᑼࠍ↪޿ࠆߎߣ߇ᦸ
߹ߒ޿㧚ߒ߆ߒߎࠇࠄߩ⁁ᘒᣇ⒟ᑼߪᣢሽߩታ᷹
୯ࠍ↪޿ߡ૞ᚑߐࠇߡ߅ࠅ㧘ታ᷹୯ߦኻߔࠆౣ⃻ᕈߪ Younglove ߩ⁁ᘒᣇ⒟ᑼߣᲧセߒߡะ਄ߒߡ
޿ࠆ߇㧘㜞᷷㧘㜞࿶ၞߪᄖᝌߩ⁁ᘒߢ㧘ߥ߅ᣂߚߥ㜞♖ᐲߩታ᷹୯ߩႎ๔߇ಾᦸߐࠇߡ޿ࠆ㧚Younglove ߩ⁁ᘒᣇ⒟ᑼ
P = ρRT + ρ 2 ( N 1T + N 2T 1 / 2 + N 3 + N 4 / T + N 5 / T 2 )+ ρ 3 ( N 6T + N 7 + N 8 / T + N 9 / T 2 )+ ρ 4 ( N 10T + N 11 + N12 / T ) + ρ 5 ( N13 )Figure 4: Distribution of PVT for hydrogen+ ρ 6 ( N 14 / T + N15 / T 2 ) + ρ 7 ( N16 / T )+ ρ 8 ( N 17 / T + N18 / T 2 ) + ρ 9 ( N 19 / T 2 )+ ρ 3 ( N 20 / T 2 + N 21 / T 3 ) exp(γρ 2 ) ᾲജቇᕈ⾰ߦ߅޿ߡᦨ߽ၮᧄ⊛ߥ‛ᕈߢ޽ࠅ㧘⁁ᘒᣇ⒟ᑼ૞ᚑߩၮ␆࠺࡯࠲ߣߥࠆ PVT ߪ 1963
ᐕߩ Goodwin ࠄ[10]ߦࠃࠆ᷷ᐲ▸࿐ 15K ߆ࠄ 100K㧘࿶ജ▸࿐ 35MPa ߹ߢߩᶧ⋧ၞࠍ฽߻ᐢ▸࿐ߩ᷹ቯߦࠃࠅ᣿ࠄ߆ߦߥߞߡ߈ߚߣ⸒߃ࠆ㧚ߘࠇએ㒠㧘1970 ᐕઍࠍਛᔃߦ NBS(⃻ NIST)ߣ NASA ߦࠃߞߡ㧘ᶧ⋧ၞࠍਛᔃߦᄙߊߩ PVT ᷹ቯ߇ⴕࠊࠇߚ㧚
1980 ᐕઍߦ౉ࠆߣ㧘૕♽⊛ߥ᷹ቯߪోߊⴕࠊࠇߥ
ߊߥߞߚ߇㧘ㄭᐕౣ߮᳓⚛‛ᕈߦᵈ⋡߇㓸߹ߞߡ޿ࠆ㧚2007 ᐕߦߪ Jacobsen ࠄ[11]߇ㆊ෰ߩᾲജቇ

વᾲ 2009 ᐕ 4 ᦬(5)+ ρ 5 ( N 22 / T 2 + N 23 / T 4 ) exp(γρ 2 )+ ρ 7 ( N 24 / T 2 + N 25 / T 3 ) exp(γρ 2 )+ ρ 9 ( N 26 / T 2 + N 27 / T 4 ) exp(γρ 2 )+ ρ 11 ( N 28 / T 2 + N 29 / T 3 ) exp(γρ 2 )+ ρ 13 ( N 30 / T 2 + N 31 / T 3 + N 32 / T 4 ) exp(γρ 2 )Ni, γ 㧦‛⾰࿕᦭ߩቯᢙGERG ߩ⁁ᘒᣇ⒟ᑼ
a( ρ , T ) / RT = α 0 (δ ,τ ) + α r (δ ,τ )

-3-

(6)

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․㓸㧦᳓⚛ߩ‛ᕈ߅ࠃ߮᧚ᢱ
ࠆ㧚ࠝ࡞࠰᳓⚛ߣࡄ࡜᳓⚛ߢ‛ᕈ୯߇⇣ߥࠆ⺃ዉ⁁
ᘒ㊂ߩ଀ߣߒߡ㧘࿑ 6 ߦ Leachman ߩ⁁ᘒᣇ⒟ᑼ
߆ࠄ⸘▚ߒߚ㖸ㅦߩ⁁ᘒᦛ㕙ࠍ␜ߔ㧚࿑ 6 ߪࡄ࡜᳓⚛ߩ⁁ᘒᦛ㕙ߢ޽ࠆ߇㧘50MPa ߣ 100MPa ߩ╬࿶✢ߦߩߺࠝ࡞࠰᳓⚛ߣࡁ࡯ࡑ࡞᳓⚛ߩ╬࿶✢߽␜ߒߡ޿ࠆ㧚㖸ㅦࠍ⁁ᘒᣇ⒟ᑼ߆ࠄዉ಴ߔࠆ႐ว
ߦߪ㧘Ყᾲห᭽ߦℂᗐ᳇૕ߩቯ࿶Ყᾲࠍᔅⷐߣߔ
ࠆߚ߼㧘150K ઃㄭߢࡁ࡯ࡑ࡞᳓⚛ߣࡄ࡜᳓⚛ߩ‛ᕈ୯߇⇣ߥࠅᵈᗧ߇ᔅⷐߢ޽ࠆ㧚(7)− ∑ mk ln[cosh(θ kτ )] + ln(δ )]k =2 , 4

5

14

(8)

α (δ ,τ ) = ∑ niδ d τ t + ∑ niδ d τ t exp( −δ p )
r

i

i

i =1

i

i

i

i =6

Ideal gas isobaric heat capacity (J/(mol·K))a㧦Helmholtz ⥄↱ࠛࡀ࡞ࠡ࡯
α㧦ήᰴరൻߐࠇߚ Helmholtz ⥄↱ࠛࡀ࡞ࠡ࡯਄ઃ߈ 0
㧦ℂᗐ᳇૕㗄਄ઃ߈ r㧦೾૛㗄㧦ᣥࠟࠬቯᢙ(= 8.314510)
R*R
㧦⃻࿷ߩࠟࠬቯᢙ( = 8.314472)
δ = ρ / ρc, τ = Tc / T
ρc
㧦⥃⇇ኒᐲ
Tc
㧦⥃⇇᷷ᐲ
cI, cII, c0, mk, θk, ni, di, ti, pi㧦‛⾰࿕᦭ߩଥᢙ

Leachman ߩ⁁ᘒᣇ⒟ᑼ
a( ρ , T ) / RT = α 0 (δ ,τ ) + α r (δ ,τ )(9)2

exp(u k / T )
C P0
⎛u ⎞
= n0 + ∑ v k ⎜ k ⎟2kR⎝ T ⎠ [exp(u k / T ) − 1]
7

(10)

9

α r (δ ,τ ) = ∑ niδ d τ t + ∑ niδ d τ t exp( −δ p )
i

i

i =1

i

i

i

i =8

(11)

14

+ ∑ niδ d τ t exp[ −ϕ i (δ − Di ) − β i (τ − γ i )]
i

i

i =10

C P0 㧦ℂᗐ᳇૕ߩቯ࿶Ყᾲ
n0, vk, uk, ni, di, ti, pi, ϕi, Di, βi, γi㧦‛⾰࿕᦭ߩଥᢙ

α 0 ߪᾲജቇ㑐ଥᑼࠃࠅ C P0 ߆ࠄዉ಴⺃ዉ⁁ᘒ㊂
 Ყᾲ߿㖸ㅦ㧘ࠛࡦ࠲࡞ࡇ࡯㧘ࠛࡦ࠻ࡠࡇ࡯㧘ࠫࡘ࡯࡞㨯࠻ࡓ࠰ࡦଥᢙߣ޿ߞߚ⺃ዉ⁁ᘒ㊂ߪ㧘⁁ᘒᣇ⒟ᑼ߆ࠄᾲജቇ㑐ଥᑼࠍ↪޿ߡ⸘▚ߔࠆߎߣ߇
ߢ߈ࠆ㧚᳓⚛ߩ⺃ዉ⁁ᘒ㊂ߦ㑐ߔࠆታ᷹୯ߪ߶ߣ
ࠎߤߥߊ㧘ታ᷹୯ߩႎ๔߇ᓙߚࠇࠆߣߎࠈߢ޽ࠆ
߇㧘‛ᕈ୯ߩ૶↪ߦ㓙ߒߡߪ㧘PVT ߣߪ⇣ߥࠅ㧘ࠝ࡞࠰᳓⚛ߣࡄ࡜᳓⚛ߩ㆑޿ࠍ⹺⼂ߒ㧘ਔ⠪ߩ‛ᕈ୯ࠍ૶޿ಽߌࠆߎߣ߇㊀ⷐߢ޽ࠆ㧚 ࿑ 5 ߪ Leachman ߩ⁁ᘒᣇ⒟ᑼ߆ࠄ⸘▚ߒߚࠝ࡞࠰᳓⚛㧘ࡄ࡜᳓⚛㧘ࡁ࡯ࡑ࡞᳓⚛ߩℂᗐ᳇૕⁁ᘒߦ߅ߌࠆቯ࿶Ყᾲߢ޽ࠆ㧚400K ߢߪࡁ࡯ࡑ࡞᳓
⚛ߣࡄ࡜᳓⚛ߢߪ 0.5%ߒ߆㆑ࠊߕ㧘ߘࠇએ਄ߩ᷷
ᐲߢߪߐࠄߦᏅߪዊߐߊ㧘෼᧤ߔࠆࠃ߁ߥ᜼േߦߥ ߞ ߡ ޿ ࠆ ߇ 㧘 150K ߢ ߪ ࡁ ࡯ ࡑ ࡞ ᳓ ⚛ ߪ
25J/mol·K ߥߩߦኻߒ㧘ࡄ࡜᳓⚛ߪ 33J/mol·K ߢ޽ࠆߩߢ㧘ࡄ࡜᳓⚛ߩᣇ߇ 32%߽ᄢ߈޿㧚ࠝ࡞࠰᳓⚛ߣࡄ࡜᳓⚛ߩᲧᾲߪ㧘⛔⸘ജቇߢℂ⺰⊛ߦ⸘▚ߔࠆߎߣ߇น⢻ߢ޽ࠅ㧘⪺ฬߥ⛔⸘ജቇߩ࠹ࠠࠬ
࠻[15]ߢṶ⠌໧㗴ߦ߽ขࠅ਄ߍࠄࠇߡ޿ࠆ㧚ߎߩࠃ߁ߥࠝ࡞࠰᳓⚛ߣࡄ࡜᳓⚛ߩ‛ᕈߦ߅ߌࠆ㆑޿
ߪ㧘Ყᾲࠍߪߓ߼ߣߔࠆᾲ㊂⊛ᕈ⾰ߦᄢ߈ߊ⃻ࠇ

p-H2
30

n-H2
o-H2

25

20
0

200

400

600

Temperature (K)Figure 5: Ideal gas isobaric heat capacity

800

of ortho-, para-, and normal hydrogen2500

p-H2 , 100o-H2, 100 MPa
MPa

2000
1500

p-H2, Saturated liquidp-H2 , 50

MPan-H2, 100 MPa

p-H2, 2 MPa

1000
500
0

p-H 2,
1 MPa

p-H2,
0.5 MPa

Speed-of-sound (m/s)

3000

p-H2,
0.1 MPaવᾲ 2009 ᐕ 4 ᦬

35

ph
ase

R * II[c + c Iτ + c0 ln(τ ) + ∑ mk ln[sinh(θ kτ )]k =1, 3RSolid

α 0 (δ ,τ ) =o-H2, 50 MPa

n-H2, 50 MPa,
p-H 2

p-H 2,
5 MPa

Pa
10 M

p-H2, 3 MPa
p-H2, 1.5 MPa

p-H2, Saturated vapor

50

100

Temperature (K)500

Figure 6: Speed-of-sound of ortho-, para-, and normalhydrogenャㅍᕈ⾰☼ᕈଥᢙ߿ᾲવዉ₸ߣ޿ߞߚャㅍᕈ⾰߽᳓⚛ࠛࡀ࡞ࠡ࡯ߩ೑↪ߦ߅޿ߡᔅⷐਇนᰳߢ޽ࠆ㧚᳓⚛
ߩャㅍᕈ⾰ߩታ᷹୯ߪ Leachman ࠄ[16]ߦࠃߞߡ
߹ߣ߼ࠄࠇߡ޿ࠆ㧚࿑ 7㧘8 ߦ☼ᕈଥᢙߣᾲવዉ₸-4-

J. HTSJ, Vol. 48, No. 203

․㓸㧦᳓⚛ߩ‛ᕈ߅ࠃ߮᧚ᢱ
ߩታ᷹୯ಽᏓࠍ␜ߔ㧚☼ᕈଥᢙ߿ᾲવዉ₸ߦ߅޿ߡ߽㧘400K એ਄ߩ᷷ᐲ㗔ၞߦ߅޿ߡታ᷹୯߇ਇ⿷
ߒߡ߅ࠅ㧘ᾲജቇᕈ⾰ห᭽ߦታ᷹୯ߩႎ๔߇ಾᦸ
ߐࠇߡ޿ࠆ⃻⁁ߦ޽ࠆ㧚ᾲવዉ₸ߦߟ޿ߡߪ㧘Roder[18]߇ 1984 ᐕߦ 78K
߆ࠄ 310K㧘70MPa ߹ߢߩ㗔ၞߢ㧘ࡁ࡯ࡑ࡞᳓⚛
ߣࡄ࡜᳓⚛ߩ᷹ቯࠍⴕ޿㧘ᑼ(14)߆ࠄᑼ(16)ߦ␜ߔ
ᑼࠍ૞ᚑߒߚ㧚(14)
λ = λ0 (T ) + λexcess ( ρ , T ) + Δλcritical ( ρ , T )(15)
λexcess ( ρ , T ) = αρ + δ [exp( βργ ) − 1]2(16)Δλcritical ( ρ , T ) = A exp(− x )Pressure (MPa)

100

λ
㧦ᾲવዉ₸
λ0
㧦Ꮧ⭯᳇૕ߩᾲવዉ₸λexcess 㧦೾૛㗄Δλcritical 㧦⥃⇇ὐㄭறࠍ⴫ߔߚ߼ߩ㗄δ, A㧦᷷ᐲߩ㑐ᢙ
X
㧦ኒᐲߩ㑐ᢙ
α, β, γ 㧦ቯᢙ101ߒ߆ߒ㧘☼ᕈଥᢙ㧘ᾲવዉ₸ߣ߽ߦ㧘Ᏹ᷷એ਄ߩ᷷ᐲ㗔ၞߢߪ㧘⋧㑐ߔߴ߈ታ᷹୯߇ሽ࿷ߒߥ޿
ߚ߼ߦ㧘ಽሶ㑆ജ߅ࠃ߮ㆇേ⺰ߦၮߠ޿ߚ
Chapman-Enskog ߩℂ⺰ᑼ߇‛ᕈ୯⸘▚ߦ↪޿ࠄࠇࠆ㧚Chapman-Enskog ߩℂ⺰ᑼߩ♖ᐲߪ 10%߆ࠄ
15%⒟ᐲߢ޽ࠆߣផቯߐࠇࠆ㧚 ߹ߚ㧘ᾲવዉ₸ߩ႐วߦߪࠝ࡞࠰᳓⚛ߣࡄ࡜᳓⚛ߢ‛ᕈ߇⇣ߥࠆߚ߼ᵈᗧ߇ᔅⷐߢ޽ࠆ㧚࿑ 9 ߪᏗ⭯᳇૕ߦ߅ߌࠆࡁ࡯ࡑ࡞᳓⚛ߣࡄ࡜᳓⚛ߩᾲવዉ ₸ ߢ ޽ ࠆ 㧚 150K ߢ ࡁ ࡯ ࡑ ࡞ ᳓ ⚛ ߪ
1.0mW/(cm·K) ߢ ޽ ࠆ ߩ ߦ ኻ ߒ 㧘 ࡄ ࡜ ᳓ ⚛ ߪ
1.3mW/(cm·K)ߢ޽ࠆߚ߼㧘ߎߜࠄ߽ 30%ߩ㆑޿߇
޽ࠆ㧚

0.1
0

100

200

Boyd (1930), normal
van Itterbeek (1938), normal
Michels (1953), nomal
Diller (1965), para
Kestin (1968), normal
Chuang (1976), normal
Critical point

300

400

500

Temperature (K)600Adzumi (1937), normal
van Itterbeek (1940), normal
Barua (1964), normal
Diller (1965), normal
Gracki (1969), normal
Assael (1986), normal
Younglove (1982)

700

800

Keesom (1938), normal
Johnston (1940), normal
Kestin (1964), normal
Menabde (1965), normal
Guevara (1969), normal
Nabizadeh (1999), normal

Figure 7: Distribution of viscosity for hydrogen

10

Thermal conductivity (mW/(cm·K))

Pressure (MPa)

100

1

0.1
0

100

200

Ubbink (1948), normal
Hamrin (1966), normal
Saxena (1970), normal
Roder (1984), para
Mustafa (1987), normal

300

400

500

Temperature (K)Lenoir (1951), normal
Roder (1970), para
Assael (1981), normal
Roder (1984), normal
Critical point

600

700

800

Keyes (1954), normal
Roder (1970), normal
Clifford (1981), normal
Hemminger (1987), normal
Younglove (1982)

Figure 8: Distribution of thermal conductivity forhydrogen

1

n-H2

0.5

0

100

Ubbink (1948), normal
Roder (1970), normal
Roder (1984)

200

Johnston (1946), normal
Roder (1970), para

Figure 9: Thermal conductivity of dilute para- andnormal hydrogen߹ߣ߼ ㄭᐕ㧘ࡊ࡜ࠣࠗࡦ࡮ࡂࠗࡉ࡝࠶࠼ゞ(PHEV)ߩᛛ
ⴚ㐿⊒߇⋡ⷡ߹ߒߊ㧘FCV ߪਇⷐߦߥࠅ㧘᳓⚛ߩ㧦☼ᕈଥᢙ㧦Ꮧ⭯᳇૕ߩ☼ᕈଥᢙ㧦೾૛㗄㧦ኒᐲߩ㑐ᢙ

વᾲ 2009 ᐕ 4 ᦬

p-H2

Temperature (K)Diller[17]ߪ 1965 ᐕߦ 14K ߆ࠄ 100K㧘35MPa ߩ㗔ၞߦ߅޿ߡࡄ࡜᳓⚛ߩ☼ᕈଥᢙࠍ᷹ቯߒ㧘ᑼ(12)㧘(13)ߢ⴫ߐࠇࠆ☼ᕈଥᢙߩᑼࠍ૞ᚑߒߚ㧚(12)
η = η 0 (T ) + η E ( ρ , T )(13)η E ( ρ , T ) = A exp( B / T )
η
η0
ηΕ
A, B

1.5

-5-

J. HTSJ, Vol. 48, No. 203

․㓸㧦᳓⚛ߩ‛ᕈ߅ࠃ߮᧚ᢱ
ᤨઍߪ᧪ߥ޿ߩߢߪߥ޿߆ߣ޿߁⷗ᣇ߇৻ㇱߦ޽ࠆ㧚╩⠪ߪ㧘PHEV ߪⴝਛࠍ⿛ࠅ࿁ࠆゞߣߒߡ᥉෸ߒ㧘㐳〒㔌઀᭽ߩゞߪ߿ߪࠅ FCV ߦߥࠅ㧘߿ߪࠅ᳓⚛ߩᤨઍ߇ߊࠆߩߢߪߥ޿߆ߣᦼᓙߒߡ޿ࠆ㧚
ᧄⓂߢߪ㧘᳓⚛ߩ⇣ᕈ૕㧘ࠝ࡞࠰ߣࡄ࡜߅ࠃ߮ߘ
ࠇࠄߩᾲ‛ᕈ୯ߩ⃻⁁ߦߟ޿ߡ⚫੺ߒ㧘㜞࿶ၞߩ᳓⚛ߩᾲ‛ᕈ୯ߩታ᷹࠺࡯࠲ߩਇ⿷ࠍᜰ៰ߒߚ㧚᳓⚛ߩ‛ᕈ୯ߪ᳓⚛ߩᤨઍߩၮ⋚ߣߥࠆ㊀ⷐߥᖱႎߢ޽ࠅ㧘ߘߩᗧ๧ߢ߽ᐢ▸࿐ߩ‛ᕈ୯ࠍᢛ஻ߒ
ߡ߅ߊߎߣߪᭂ߼ߡ㊀ⷐߢ޽ࠆߣ⠨߃ߡ޿ࠆ㧚
 㩷
ෳ⠨ᢥ₂
[1] Farkas, A., Orthohydrogen, Parahydrogen andHeavy Hydrogen, Cambridge University Press,
1935[2] Woolley, H.W., et al., Compilation of Thermal
Properties of Hydrogen in Its Various Isotopic andOrtho-Para Modifications, NBS Research Paper
RP1932, Vol.41, 1948
[3] McCarty, R.D. and Weber, L.A., Thermophysical
Properties of Parahydrogen from Freezing LiquidLine to 5000 R for Pressures to 10,000 Psia, NBS
Technical Note 617, 1972
[4] McCarty, R.D., Hydrogen Technological SurveyThermophysical Properties, NASA SP-3089, 1975
[5] McCarty, R.D., et al., Selected Properties ofHydrogen (Engineering Design Data), NBS
Monograph 168, 1981
[6] Leachman, J., Fundamental Equations of State for
Parahydrogen, Normal Hydrogen, and Orthohydrogen, Master's Thesis, University of Idaho,
2007[7] Kunz, O., et. al., The GERG-2004 Wide-Range
Equation of State for Natural Gases and Other
Mixtures, GERG Technical Monograph 15, 2007
[8] Larsen, A.H., et al., The Rate of Evaporation of
Liquid Hydrogen Due to the Ortho-Para Hydrogen
Conversion, The Review of Scientific Instruments,

વᾲ 2009 ᐕ 4 ᦬-6-Vol.19, No.4, pp.266-269, 1948[9] ᄤၳᵗ৻㧘ઁ 4 ฬ㧘ࠝ࡞࠰࡮ࡄ࡜᳓⚛ಽᨆ⸘ߩ⹜૞㧘ࡗ࠽ࠦ࠾ࡘ࡯ࠬ㧘Vol.14, No.4, pp.1-5,
1985[10] Goodwin, R.D., et al., Pressure-DensityTemperature Relations of Fluid Para Hydrogen
From 15 to 100 ºK at Pressures to 350
Atmospheres, Journal of Research of the National
Bureau of Standards-A. Physical and Chemistry
Vol.67A, No.2, pp.173-192, 1963[11] Jacobsen, R.T., et. al., Current Status ofThermodynamic
Properties
ofHydrogen,International Journal of Thermophysics, Vol.28,
No.3, pp.758-772, 2007[12] Michels, A. and Goudeket, M., Compressibilities
of Hydrogen Between 0ºC and 150ºC up to 3000
Atmospheres, Physica, Vol.8, pp.347-352, 1941
[13] Michels, A., et al., Compressilibity Isotherms ofHydrogen and Deuterium at Temperatures
Between -175ºC and +150ºC (at Densities up to
960 Amagat), Physica, Vol.25, pp.25-42, 1959
[14] Younglove, B. A., Thermophysical Properties of
Fluids. I. Argon, Ethylene, Parahydrogen, Nitrogen,Nitrogen Trifluoride, and Oxygen, Journal of
Physical and Chemical Reference Data, Vol.11,
Supplement No.1, 1982[15] ਭ ଻ ੫ ੖ ✬ 㧘 ᾲ ቇ ࡮ ⛔ ⸘ ജ ቇ 㧘 ⵷ ⪇ ᚱ 㧘
pp.319-321, 1961[16] Leachman, J.W., Current Status of Transport
Properties of Hydrogen, International Journal of
Thermophysics, Vol.28, No.3, pp.773-795, 2007[17] Diller, D. E., Measurements of the Viscosity of
Parahydrogen, Journal of Chemical Physics, Vol.42,
No.6, pp.2089-2100, 1965[18] Roder, H. M., Thermal Conductivity of Hydrogen
for Temperatures Between 78 and 310 K withPressures to 70 MPa, International Journal of
Thermophysics, Vol.5, No.4, pp.323-350, 1984

J. HTSJ, Vol. 48, No. 203

․㓸㧦᳓⚛ߩ‛ᕈ߅ࠃ߮᧚ᢱ

HYDROGENIUS ࡊࡠࠫࠚࠢ࠻ߦ߅ߌࠆ᳓⚛⣀ൻ⎇ⓥ㧦᳓⚛⣀ൻߪ⣀ᕈ⎕უ߆ᑧᕈ⎕უ߆Research of Hydrogen Embrittlement in HYDROGENIUS Project᧻ጟਃ㇢㧔਻Ꮊᄢቇ㧕
Saburo MATSUOKA (Kyushu University)e-mail: smatuoka@mech.kyushu-u.ac.jp⪺ᦠ[2]߿⸃⺑[2-5]ߪᄙߊ޽ࠆ㧚ߎࠇࠄߩਛߦߪᄙ
ߊߩ᳓⚛⣀ൻࡕ࠺࡞߇⚫੺ߐࠇߡ޿ࠆ߇㧘ᦨㄭߢߪ㧘᳓⚛⣀ൻࡔࠞ࠾࠭ࡓߪਥߣߒߡᩰሶ⣀ൻ⺑ߣዪᚲᄌᒻഥ㐳⺑ߢ⺑᣿ߐࠇߡ޿ࠆ[4, 6-8]㧚ᩰሶ⣀ൻ⺑ߪ㧘᳓⚛ߩଚ౉ߦࠃࠅේሶ㑆⚿วജ߇ૐਅߒ㧘⣀ᕈ⎕უ߇⿠߈߿ߔߊߥࠆߣ⠨߃ࠆ⺑ߢ޽ࠆ[4,6]㧚ዪㇱᄌᒻഥ㐳⺑ߪ㧘᳓⚛߇႟ᕈᄌᒻࠍኈᤃߦ
ߒ㧘ዪᚲ⊛ߥᄌᒻ߇↢ߓࠆߚ߼㧘⚿ᨐߣߒߡࡑࠢ
ࡠ⊛ߦߪዊߐ޿ᄌᒻߢ⎕უߔࠆߣ⠨߃ࠆ⺑ߢ޽ࠆ
[4, 7, 8] 㧚ߒ߆ߒ㧘ߤߜࠄߩ⺑߇ᱜߒ޿߆ߦߟ޿ߡ
ߪ㧘⃻࿷ߢ߽᳿⌕߇ߟ޿ߡ޿ߥ޿㧚ߎߩࠃ߁ߥේ
࿃ߩ৻┵ߪ㧘᳓⚛߇ర⚛ߩਛߢᦨ߽シߊ㧘ዊߐ޿ߚ߼㧘޿߹߹ߢ᧚ᢱਛߩ᳓⚛㊂߇᷹ቯߢ߈ߥ߆ߞ
ߚߎߣ㧘᧚ᢱਛߩ᳓⚛ߩሽ࿷૏⟎߇ⷰኤߢ߈ߥ߆
ߞߚߎߣߦࠃࠆ㧚ᦨㄭ㧘᣹᷷⣕㔌ಽᨆߩㅴᱠߦࠃ
ࠅ᧚ᢱਛߩ᳓⚛㊂߇᷹ቯߢ߈ࠆࠃ߁ߦߥߞߚ㧚࿑ 1 ߪ㧘᧚ᢱਛߩଚ౉᳓⚛㊂ߦߟ޿ߡ㧘ᣂࠛࡀ࡞ࠡ࡯࡮↥ᬺᛛⴚ✚ว㐿⊒ᯏ᭴ NEDO ߩႎ๔ᦠ[9]ߦ⸥タߐࠇߡ޿ࠆᢙ୯࠺࡯࠲ࠍࠫ࡯ࡌ࡞࠷ೣߦߒ
ߚ߇ߞߡ࿑␜ߒߚ߽ߩߢ޽ࠆ[10]㧚ߎߩႎ๔ᦠߦ
ߪ㧘35MPa ߩ࿶ജࠍਛᔃߣߒߚ㜞࿶᳓⚛ࠟࠬਛߦ߅޿ߡ㧘ࠝ࡯ࠬ࠹࠽ࠗ࠻♽ࠬ࠹ࡦ࡟ࠬ㍑ SUS304㧘
SUS304L㧘SUS316㧘SUS316L㧘SUS316LN㧘SUS310S㧘
SUS630㧘ࠕ࡞ࡒ࠾࠙ࡓว㊄ 6061-T6㧘㌃ว㊄ C771㧘
ૐว㊄㍑ SCM440 ߩᒁᒛ․ᕈ㧘∋ഭ․ᕈ㧘᳓⚛ଚ౉․ᕈࠍ⺞ߴߚ⚿ᨐ߇⸥タߐࠇߡ޿ࠆ㧚࿑ 1(a)ߦ
ߪૐว㊄㍑ SCM440㧘࿑ 1(b)ߦߪࠝ࡯ࠬ࠹࠽ࠗ࠻
♽ࠬ࠹ࡦ࡟ࠬ㍑ SUS304L㧘SUS316㧘SUS316L ߩ⚿ᨐࠍ␜ߔ㧚ᢥ₂[9]ߦ⸥タߐࠇߡ޿ࠆ᳓⚛ࠟࠬᦑ㔺᧦ઙߣߒߡߪ㧘࿶ജ߇ 11.3㨪45 MPa㧘᷷ᐲ߇ 358
ߣ 473 K㧘ᤨ㑆߇ 240 ߣ 1000 h ߢ޽ࠆ㧚⹜㛎 ߪ⋥ᓘ 4 mm ߩਣ᫔ߢ޽ࠆ߇㧘⋥ᓘ 2 ߣ 3 mm ߩਣ᫔߽৻ㇱ૶↪ߒߡ޿ࠆ㧚ᾲᐔⴧ⁁ᘒߦ޽ࠆߣ߈ߩ࿕ṁ᳓⚛㊂ CH ߪ㧘ᰴᑼߩࠫ࡯ࡌ࡞࠷ೣߢ⴫ߐࠇࠆ㧚ߪߓ߼ߦ
࿾⃿ⅣႺ໧㗴ࠍ⸃᳿ߔࠆ᦭ജߥᚻᲑߩ৻ߟߣߒ
ߡ㧘Άᢱ㔚ᳰ⥄േゞ FCV ߥߤߩ᳓⚛ࠛࡀ࡞ࠡ࡯ࠪ
ࠬ࠹ࡓ㧘᳓⚛ࠬ࠹࡯࡚ࠪࡦߥߤߩ᳓⚛ࠛࡀ࡞ࠡ࡯
ࠗࡦࡈ࡜ߩ⎇ⓥ㐿⊒߇ㅴ߼ࠄࠇߡ޿ࠆ㧚ᣣᧄߢߪ㧘
2002 ᐕ߆ࠄ JHFC ࡊࡠࠫࠚࠢ࠻㧔᳓⚛࡮Άᢱ㔚ᳰታ⸽ࡊࡠࠫࠚࠢ࠻㧕߇ⴕࠊࠇߡ޿ࠆ[1]㧚35 MPa᳓⚛࠲ࡦࠢࠍ៞タߒߚ FCV ࠍ౏㆏ߢ⿛ࠄߖ㧘35
MPa ᳓⚛ࠬ࠹࡯࡚ࠪࡦߢ FCV ߦ᳓⚛ࠍଏ⛎ߒ㧘ߎࠇࠄߩታ↪ൻߦะߌߚᕈ⢻⹏ଔ߿⺖㗴᛽಴ࠍⴕߞߡ޿ࠆ㧚2008 ᐕ߆ࠄߪ 70 MPa FCV ߣ 70 MPa
᳓⚛ࠬ࠹࡯࡚ࠪࡦߦࠃࠆ 70 MPa ታ⸽⹜㛎߇㐿ᆎߐࠇߚ㧚ห᭽ߥ 70 MPa ታ⸽⹜㛎ߪ᰷☨ߢ߽ⴕࠊࠇߡ޿ࠆ㧚JHFC ࡊࡠࠫࠚࠢ࠻ߣߪ೎ߦ㧘↥ᬺᛛⴚ✚ว⎇ⓥᚲߦ߅޿ߡ㧘‫ޟ‬᳓⚛࡮Άᢱ㔚ᳰ⎇ⓥߪၮ␆ߦ┙ߜᚯࠆߴ߈‫ߡߒߣޠ‬㧘ਃߟߩขࠅ⚵ߺ߇㐿ᆎߐࠇߚ㧚2005 ᐕߦ㧘࿕૕㜞ಽሶဳΆᢱ㔚ᳰߩᛮᧄ⊛ߥૐࠦࠬ࠻ൻߣ⠴ਭᕈ࡮ା㗬ᕈߩะ਄ࠍ⋡⊛ߦ㧘࿕૕㜞ಽሶဳΆᢱ㔚ᳰవ┵ၮ⋚⎇ⓥ࠮ࡦ࠲࡯㧔FC-Cubic㧕߇⸳┙ߐࠇߚ㧚2006 ᐕߦ㧘‫ޟ‬᳓⚛⣀
ൻ‫ߩޠ‬ၮᧄࡔࠞ࠾࠭ࡓ⸃᣿ߣ૶↪᧚ᢱߩታ↪⊛ߥ቟ోᜰ㊎ߩ⏕┙ࠍ⋡⊛ߦ㧘᳓⚛᧚ᢱవ┵⑼ቇ⎇ⓥ
࠮ࡦ࠲࡯㧔HYDROGENIUS㧕߇⸳┙ߐࠇߚ㧚2007ᐕߦߪ㧘᳓⚛⾂⬿᧚ᢱߩ㕟ᣂ⊛ߥᕈ⢻ะ਄ࠍ⋡⊛ߦ㧘᳓⚛⾂⬿᧚ᢱవ┵ၮ⋚⎇ⓥ੐ᬺ߇㐿ᆎߐࠇߚ㧚ᧄ⸃⺑ߢߪ㧘᳓⚛⣀ൻߩၮᧄࡔࠞ࠾࠭ࡓߩ⸃᣿
ࠍᔨ㗡ߦ⟎޿ߡ㧘HYDROGENIUS ߩᚑᨐߩ৻┵ࠍଚ౉᳓⚛㊂㧘ᒁᒛᒝᐲ㧘∋ഭ߈ⵚㅴዷߦಽߌߡ⚫
੺ߔࠆ㧚㧚ଚ౉᳓⚛㊂᳓⚛ࠛࡀ࡞ࠡ࡯ࠪࠬ࠹ࡓ࡮ࠗࡦࡈ࡜ߦ૶↪ߐࠇࠆ᭴ㅧ᧚ᢱߪ᳓⚛ߦᦑߐࠇࠆߚ߼㧘᳓⚛⣀ൻ߇㊀ⷐߥ⺖㗴ߣߥߞߡ޿ࠆ㧚᳓⚛⣀ൻ޽ࠆ޿ߪㆃࠇ⎕უߪฎߊ߆ࠄ⎇ⓥߐࠇߡ޿ࠆ߇㧘޿߹ߛߦ⸃᳿ߐ
ࠇߡ޿ߥ޿㧚᳓⚛⣀ൻ޽ࠆ޿ߪㆃࠇ⎕უߦ㑐ߔࠆ

વᾲ 2009 ᐕ 4 ᦬-7-

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․㓸㧦᳓⚛ߩ‛ᕈ߅ࠃ߮᧚ᢱ

CH = P P0 exp[− ( ΔHs R) + ( ΔS R)]

ᢔଥᢙ߇ૐ޿ࠝ࡯ࠬ࠹࠽ࠗ࠻♽ࠬ࠹ࡦ࡟ࠬ㍑ߪᾲᐔⴧ⁁ᘒߦ޽ࠆ߆ߤ߁߆ߪਇ᣿ߢ޽ࠆ߇㧘ᾲᐔⴧ⁁ᘒߦ㆐ߒߡ޿ߥ޿ߣ⠨߃ࠆߣ㧘࿑ 1(b)ࠃࠅߐࠄ
ߦᄙߊߩ᳓⚛߇ଚ౉ߔࠆ㧚 HYDROGENIUS ߢߪ㧘ᦨ㜞᳓⚛࿶ജ߇ 100MPaߢᦨ㜞᷷ᐲ߇ 300 ͠ߣ 120 ͠ߩ 2 บߩ㜞࿶᳓⚛ࠟࠬᦑ㔺ኈེ㧘྾㊀ᭂ⾰㊂ಽᨆᣇᑼ㧔TDS㧕ߣࠟࠬࠢࡠࡑ࠻ࠣ࡜ࡈࠖ࡯ᣇᑼ㧔TDA㧕ߩ 2 บߩ᣹᷷⣕㔌ಽᨆⵝ⟎ࠍᢛ஻ߒ㧘㜞࿶᳓⚛ࠟࠬਛߢଚ౉ߔࠆ
᳓⚛㊂ࠍ᷹ቯߒߡ޿ࠆ㧚࿑ 2 ߪᣂߚߦ㐿⊒ߒߚ᧚ᢱਛߩ᳓⚛᷹ቯᴺߩ⚿ᨐߢ޽ࠆ[11]㧚᧼ෘ h ࠍᄌ߃ߚ⋥ᓘ 7mm ߩ౞⋚ࠍ㜞࿶᳓⚛ࠟࠬߦᦑ㔺ߒ㧘᳓⚛㊂ࠍ᷹ቯߔࠆ㧚࿑ 2 ߦߪ㧘❑ゲߦ᳓⚛㊂CH㧘ᮮゲߦ᧼ෘߩㅒᢙ 1/h ࠍߣࠅ㧘SUS316L ߦߟ޿ߡ␜ߒߡ޿ࠆ㧚1/h ߇ዊߐ޿㧘ߔߥࠊߜ h ߇ෘ޿ߣ߈ߦߪ㧘᧚ᢱౝㇱ߹ߢ᳓⚛߇ଚ౉ߒߥ޿ߩߢ㧘CH ߪዊߐ޿㧚1/h ߇ᄢ߈ߊߥࠅ㧘᧚ᢱ⴫㕙߆ࠄౝㇱ߹ߢ᳓⚛߇߶߷ဋ৻ߦଚ౉ߔࠆߣ㧘CH ߪ㘻๺ߔࠆ㧚࿑ 2 ߩ൨㈩ㇱಽ߆ࠄ᳓⚛᜛ᢔଥᢙ㧘㘻๺୯߆ࠄ᳓⚛࿕ṁᐲ߇᳞߹ࠆ㧚⃻࿷ߪ㧘ࠝ࡯ࠬ࠹࠽ࠗ࠻
♽ࠬ࠹ࡦ࡟ࠬ㍑㧘ૐว㊄㍑㧘὇⚛㍑ߩ࿕ṁ᳓⚛㊂ߣ᳓⚛᜛ᢔㅦᐲߩ᳓⚛ࠟࠬ࿶ജߣ᷷ᐲߦኻߔࠆଐ
ሽᕈ㧔ࠕ࡟࠾࠙ࠬࡊࡠ࠶࠻㧘࿑ 1 ෳᾖ㧕ࠍ♽⛔⊛ߦ㓸Ⓧߒߡ޿ࠆ㧚ߔߥࠊߜ㧘࿕ṁ᳓⚛㊂ߣ᳓⚛᜛ᢔㅦᐲߩ࠺࡯࠲ࡌ࡯ࠬࠍ᭴▽ߒߡ޿ࠆ㧚

(1)

ߎߎߢ㧘
P ߪ᳓⚛ࠟࠬ࿶ജ㧘P0 ߪ 0.1 MPa㧔1 ᳇࿶㧕㧘ǍHs ߪṁ⸃ᾲ㧘ǍS ߪṁ⸃ߩࠛࡦ࠻ࡠࡇ࡯ߢ޽ࠆ㧚
ᑼ(1)ߩࠃ߁ߥ㑐ଥ㧔ࠕ࡟࠾࠙ࠬࡊࡠ࠶࠻㧕ࠍ⺞ߴࠆ႐ว㧘ᄙߊߩ⎇ⓥߢߪ㧘лPexp(-1000/T)ࠍ૶↪
ߔࠆ㧚ߘߎߢ㧘࿑ 1 ߢߪᮮゲߦлPexp(-1000/T)ࠍ
ណ↪ߒߚ㧚ૐว㊄㍑ SCM440 ߣࠝ࡯ࠬ࠹࠽ࠗ࠻♽ࠬ࠹ࡦ࡟ࠬ㍑ SUS304L㧘SUS316㧘SUS316L ߦ߅ߌࠆ CH ߣлPexp(-1000/T)ߩ㑐ଥߪߤߜࠄ߽⋥✢ߣߥߞߡ޿ࠆ㧚лPexp(-1000/T)ߩหߓ୯ߦኻߒߡ
ߪ㧘ଚ౉ߔࠆ᳓⚛㊂ߪ㧘ૐว㊄㍑ࠃࠅࠝ࡯ࠬ࠹࠽
ࠗ࠻♽ࠬ࠹ࡦ࡟ࠬ㍑ߩ߶߁߇ 1 ᩴએ਄ᄙ޿㧚л
Pexp(-1000/T)ߩࡄ࡜ࡔ࡯࠲ߩណ↪ߪᾲᐔⴧ⁁ᘒࠍ೨ឭߣߒߡ޿ࠆ㧚਄ㅀߩᦑ㔺᷷ᐲߣᦑ㔺ᤨ㑆㧘⹜㛎 ⋥ᓘ߆ࠄ್ᢿߒߡ㧘ࠝ࡯ࠬ࠹࠽ࠗ࠻♽ࠬ࠹ࡦ
࡟ࠬ㍑ߣᲧߴߡ᳓⚛᜛ᢔଥᢙ߇ 3㨪4 ᩴᄢ߈޿SCM440 ㍑ߪ㧘ᾲᐔⴧ⁁ᘒߦ޽ࠆ㧚৻ᣇ㧘᳓⚛᜛Hydrogen contents, CH/ppm

1.0
0.8

Tempered-martensitic steels
SCM4400.6
0.4
0.2
CH=0.539(лPexp(-1000/T))+0.100

0
0

0.2

0.4
0.6
лPexp(-1000/T)

0.8

㧔㨍㧕ૐว㊄㍑ SCM440

Hydrogen contents, CH/ppm

60
Austenitic stainless steels
SUS304L
SUS31640
SUS316L
50

30

࿑ 2 ଚ౉᳓⚛㊂ߣ⹜ᢱ᧼ෘߩ㑐ଥ

20㧚ᒁᒛᒝᐲ
 0#5# ࠺࡯࠲ࡌ࡯ࠬ
NASA ߩ Safety Standard of Hydrogen andHydrogen Systems[12]ߦߪ㧘69MPa ᳓⚛ࠟࠬਛߢ᳞
߼ߚ⒳‫᧚ߩޘ‬ᢱߩᒁᒛ․ᕈ߇ੑߟߩ⴫㧔Table A5.8
ߣ A5.9㧕ߦ߹ߣ߼ࠄࠇߡ޿ࠆ㧚Table A5.8 ߦ߅޿

10CH=50.3(лPexp(-1000/T))+3.33

0
0

0.2

0.4
0.6
лPexp(-1000/T)

0.8

㧔㨎㧕ࠝ࡯ࠬ࠹࠽ࠗ࠻♽ࠬ࠹ࡦ࡟ࠬ㍑
࿑ 1 ଚ౉᳓⚛㊂ߣࠫ࡯ࡌ࡞ࡄ࡜ࡔ࡯࠲࡯ߩ㑐ଥ

વᾲ 2009 ᐕ 4 ᦬-8-

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․㓸㧦᳓⚛ߩ‛ᕈ߅ࠃ߮᧚ᢱ
ࠟࠬਛߩ⛉ࠅߩᲧǾH/ǾHe ߦߟ޿ߡ㧘࿑ 3 ߩᒁᒛᒝᐲߩ႐วߣหߓࠃ߁ߦߒߡ߹ߣ߼ߡ޿ࠆ㧚એᓟ㧘ǾH/ǾHe ࠍ⋧ኻ⛉ࠅߣ๭߱㧚ᢥ₂[13-15]ߦ⸥タߐࠇߡ޿ࠆᒁᒛ⹜㛎᧦ઙߣߒߡߪ㧘᳓⚛ߣࡋ࡝࠙ࡓ
ߩࠟࠬ࿶ജߣ᷷ᐲߪߘࠇߙࠇ 69 MPa ߣ 22͠ߢ޽ࠆ㧚߭ߕߺㅦᐲߪ㧘ᐔṖ⹜㛎 ߩ႐วߦߪ㧘ᒢᕈᄌᒻၞߢ 0.002/minute㧔3.3×10-5 s-1㧕㧘႟ᕈᄌᒻၞ
-4 -1
ߢ 0.04/minute㧔6.7×10 s 㧕ߢ޽ࠆ㧚
࿑ 3 ߦ␜ߔࠃ߁ߦ㧘ᐔṖ⹜㛎 ߩ႐ว㧘ࡋ࡝࠙ࡓࠟࠬਛߩᒁᒛᒝᐲ߇ 1200 MPa ߹ߢߪ㧘⋧ኻᒁᒛᒝᐲǻB,H/ǻB,He ߪ᳓⚛ߣ᧚ᢱߩᓇ㗀ࠍฃߌߥ޿㧚ߔߥࠊߜ㧘ǻB,H/ǻB.He = 1 ߢ޽ࠆ㧚ࡋ࡝࠙ࡓࠟࠬ
ਛߩᒁᒛᒝᐲ߇ 1200 MPa ࠍ⿧߃ࠆߣ㧘⋧ኻᒁᒛᒝᐲߪ᳓⚛ߩᓇ㗀ࠍฃߌ㧘ૐਅߔࠆ㧚৻ᣇ㧘࿑ 4ߦ␜ߔࠃ߁ߦ㧘⛉ࠅߦ෸߷ߔ᳓⚛ߩᓇ㗀ߪᒁᒛᒝᐲߩ႐วߣ⇣ߥࠆ㧚ࠝ࡯ࠬ࠹࠽ࠗ࠻♽ࠬ࠹ࡦ࡟ࠬ
㍑㧘ࠕ࡞ࡒ࠾࠙ࡓว㊄㧘㌃ว㊄ߩ⋧ኻ⛉ࠅǾH/Ǿ
He ߪ᳓⚛ߩᓇ㗀ࠍฃߌߕ㧘ǾH/ǾHe =1 ߢ޽ࠆ㧚৻ᣇ㧘὇⚛㍑㧘ૐว㊄㍑㧘࠴࠲ࡦว㊄㧘࠾࠶ࠤ࡞ว
㊄ߩ⋧ኻ⛉ࠅߪ᳓⚛ߩᓇ㗀ࠍฃߌ㧘ǾH/ǾHe < 1 ߣߥࠆ㧚ߘߒߡ㧘⋧ኻ⛉ࠅߪ㧘ࡋ࡝࠙ࡓࠟࠬਛߩᒁ
ᒛᒝᐲ߇Ⴧടߔࠆߦߒߚ߇ߞߡૐਅߔࠆ㧚࿑ 3 ߢ⋧ኻᒁᒛᒝᐲ㧘࿑ 4 ߢ⋧ኻ⛉ࠅ߇౒ߦૐਅߒߥ޿
ࠝ࡯ࠬ࠹࠽ࠗ࠻♽ࠬ࠹ࡦ࡟ࠬ㍑㧘ࠕ࡞ࡒ࠾࠙ࡓว
㊄㧘
㌃ว㊄ߪ㧘NASA ߩ Table A5.8 ߢߪ㧘”Negligibly
embrittled”ࠣ࡞࡯ࡊߦዻߔࠆ㧚਄ㅀߩ NASA ߩ㜞࿶᳓⚛ࠟࠬਛᒁᒛ⹜㛎ߪ
69MPa㧘22͠ߢⴕࠊࠇߡ޿ࠆ[13-15]㧚᳓⚛ࠟࠬਛߦ߅ߌࠆ⹜㛎 ⵝ⌕߆ࠄ⹜㛎㐿ᆎ߹ߢߩ଻ᜬᤨ㑆ߪ߶߷࠯ࡠߢ޽ࠆ㧚଻ᜬᤨ㑆ࠍ߶߷࠯ࡠߦߒߚߎ
ߣߦߟ޿ߡߪ㧘ࠝ࡯ࠬ࠹࠽ࠗ࠻♽ࠬ࠹ࡦ࡟ࠬ㍑
SUS310㧘὇⚛㍑ A-302 Gr. C㧘࠴࠲ࡦว㊄ Ti-6Al-4V
ߩ὾㊰᧚ߣᤨല᧚ࠍ↪޿ߡ㧘଻ᜬᤨ㑆ࠍ߶߷ 0㧘1㧘
8㧘24 h ߣߒߚᒁᒛ⹜㛎ࠍⴕ޿㧘଻ᜬᤨ㑆ߪᒁᒛᒝᐲߣ⛉ࠅߦᓇ㗀ࠍ෸߷ߐߥ߆ߞߚߣߒߡ޿ࠆ
[13-15]㧚ߒ߆ߒ㧘22 ͠ߢ଻ᜬᤨ㑆߇࠯ࡠߢ޽ࠆߣ
߈ߦߪ㧘⹜㛎 ⴫㕙ߣౝㇱߩ᳓⚛㊂߇⇣ߥࠆ㧚․ߦ㧘᳓⚛᜛ᢔㅦᐲ߇ㆃ޿ࠝ࡯ࠬ࠹࠽ࠗ࠻♽ࠬ࠹ࡦ
࡟ࠬ㍑ߢߪ㧘22 ͠ߩ߽ߣߢ 24 ᤨ㑆ߢ߽᳓⚛ߪ⹜㛎 ⴫㕙߆ࠄᢙǴm ߹ߢߒ߆ଚ౉ߒߡ޿ߥ޿㧚ߎߩࠃ߁ߦ⹜㛎 ਛߩ᳓⚛ಽᏓ߇ဋ৻ߢߥ޿߽ߣߢ
ߪ㧘ᒁᒛ․ᕈߦ෸߷ߔ᳓⚛ߩᓇ㗀߇ࡃ࡞ࠢ․ᕈߣ
ߒߡ⹏ଔߢ߈ࠆ߆ߤ߁߆ߪਇ᣿ߢ޽ࠆ㧚ߘߎߢ㧘
HYDROGENIUSU ߢߪ㧘⹜㛎 ਛߩ᳓⚛ಽᏓ߇߶ߡߪ㧘᳓⚛ࠟࠬਛߣࡋ࡝࠙ࡓࠟࠬਛߩಾᰳ߈⹜㛎ߩᒁᒛᒝᐲߣᐔṖ⹜㛎 ߩ⛉ࠅࠍ್ᢿၮḰߣߒ㧘᧚ᢱ߇ᭂ┵ߦ⣀ൻߔࠆ”Extremely embrittled”㧘⣀ൻߔࠆ”Severely embrittled”㧘ዋߒ⣀ൻߔࠆ”Slightly
embrittled”㧘⣀ൻߒߥ޿”Negligibly embrittled”ߩಽ㘃ࠍⴕߞߡ޿ࠆ㧚”Negligibly embrittled”ࠣ࡞࡯ࡊߦߪ㧘᳓⚛ࠟࠬਛߢಾᰳ߈⹜㛎 ߩᒁᒛᒝᐲߣᐔ
Ṗ⹜㛎 ߩ⛉ࠅ߇ߤߜࠄ߽ૐਅߒߥ޿᧚ᢱࠍಽ㘃ߒߡ޿ࠆ㧚
࿑ 3 ߣ 4 ߪ㧘ᢥ₂[13-15]ߦタߞߡ޿ࠆᢙ୯࠺࡯
࠲ࠍ↪޿ߡ૞࿑ߒߚ߽ߩ[10]ߢ޽ࠆ㧚ᢥ₂[13-15]
ߪ NASA ߩ Tables A5.8 ߣ A5.9 ߩ߽ߣߦߥߞߚᢥ
₂ߢ޽ࠆ㧚࿑ 3 ߦߪ㧘ᐔṖ⹜㛎 ߢᓧࠄࠇߚᒁᒛ
ᒝᐲࠍ␜ߔ㧚❑ゲߦߪࡋ࡝࠙ࡓࠟࠬਛߩᒁᒛᒝᐲ
ߦኻߔࠆ᳓⚛ࠟࠬਛߩᒁᒛᒝᐲߩᲧǻB,H/ǻB.He㧘ᮮゲߦߪࡋ࡝࠙ࡓࠟࠬਛߩᒁᒛᒝᐲǻB.He ࠍណ↪
ߒߡ޿ࠆ㧚એᓟ㧘ǻB,H/ǻB,He ࠍ⋧ኻᒁᒛᒝᐲߣ๭
߱㧚࿑ 4 ߪ㧘ࡋ࡝࠙ࡓࠟࠬਛߩ⛉ࠅߦኻߔࠆ᳓⚛

࿑ 3 ⋧ኻᒁᒛᒝᐲߣࡋ࡝࠙ࡓਛ߹ߚߪᄢ᳇ਛᒁ
ᒛᒝᐲߩ㑐ଥ

࿑ 4 ⋧ኻ⛉ࠅߣࡋ࡝࠙ࡓਛ߹ߚߪᄢ᳇ਛᒁᒛᒝᐲߩ㑐ଥ

વᾲ 2009 ᐕ 4 ᦬-9-J. HTSJ, Vol. 48, No. 203

․㓸㧦᳓⚛ߩ‛ᕈ߅ࠃ߮᧚ᢱ
mm㧘ෘߐ 35 mm ߩ౞╴㧕߆ࠄಾࠅ಴ߒߚ㧚᳓⚛
㊂᷹ቯ↪ਣ᫔ߪ㧘40 ͠ߦ଻ᜬߒߚ 20 mass%࠴ࠝࠪࠕࡦ㉄ࠕࡦࡕ࠾࠙ࡓ᳓ṁᶧ㧔NH4SCN ᳓ṁᶧ㧕ߦᶐẃߒ㧘᳓⚛ࠍ࠴ࡖ࡯ࠫߒߚ㧚ᶐẃᤨ㑆ߪ 6㧘
12, 24, 48 h ߢ޽ࠆ㧚
࿑ 5 ߦ␜ߔࠃ߁ߦ㧘ਣ᫔ࠍ࠴ࠝࠪࠕࡦ㉄ࠕࡦࡕ࠾࠙ࡓ᳓ṁᶧߦ 48 ᤨ㑆ᶐẃߒߚߣ߈ߦᓧࠄࠇߚ
᳓⚛᡼಴᷷ᐲࡊࡠࡈࠔࠗ࡞ࠍ␜ߔ㧚᳓⚛᡼಴ߪ㧘᷷ᐲ߇᷹ቯ㐿ᆎߩቶ᷷㧔298 K (25͠㧕)߆ࠄ਄᣹ߔ
ࠆߣߣ߽ߦᄙߊߥࠅ㧘߶߷ 350 K (77͠)ߢࡇ࡯ࠢ
ࠍㄫ߃ߚߩߜ㧘߶߷ 450 K (177͠)ߢ⚳ੌߒߡ޿ࠆ㧚
Takai ߣ Watanuki[16]ߦࠃࠆߣ㧘ߎߩ᷷ᐲ▸࿐ߢ᡼಴ߐࠇࠆ᳓⚛ߪ᜛ᢔᕈ᳓⚛ߢ޽ࠅ㧘᳓⚛⣀ൻࠍᒁ߈⿠ߎߔ㧚࿑ 5 ߩࡊࡠࡈࠔࠗ࡞ߩਅ஥ߩ㕙Ⓧࠍ࠴
ࠝࠪࠕࡦ㉄ࠕࡦࡕ࠾࠙ࡓ᳓ṁᶧᶐẃߢ㍑ਛߦଚ౉ߒߚ᜛ᢔᕈ᳓⚛㊂ߣߒߚ㧚࿑ 6 ߦ㧘ଚ౉ߒߚ᜛ᢔᕈ᳓⚛㊂ CH ߣ࠴ࠝࠪࠕ
ࡦ㉄ࠕࡦࡕ࠾࠙ࡓ᳓ṁᶧᶐẃᤨ㑆 t ߩ㑐ଥࠍ␜ߔ[10]㧚ଚ౉᳓⚛㊂ߪ㧘ᄙዋ߫ࠄߟ޿ߡ޿ࠆ߇㧘12ᤨ㑆ᶐẃߢ߶߷㘻๺ߒߡ޿ࠆࠃ߁ߦ⷗߃ࠆ㧚ଚ౉᳓⚛㊂߇㘻๺ߔࠆߎߣߪ㧘⋥ᓘ 5 mm ߩਣ᫔ࠍ 12ᤨ㑆એ਄ᶐẃߔࠆߣ㧘᳓⚛㊂ߪਣ᫔⴫㕙ߣਛᔃߢหߓߦߥࠅ㧘߶߷ဋ৻ಽᏓߦߥࠆߎߣࠍᗧ๧ߒߡ
޿ࠆ㧚ߘߎߢ㧘⋥ᓘ 5 mm ߩ 14A ภਣ᫔ᒁᒛ⹜㛎ߪ 48 ᤨ㑆ᶐẃߒߚߩߜ㧘ᄢ᳇ਛߢᒁᒛ⹜㛎ߒߚ㧚ᒁᒛ⹜㛎 ਛߩ᳓⚛㊂ࠍᄌ߃ࠆߚ߼㧘48 ᤨ㑆ᶐⓍߒߚ⹜㛎 ࠍᄢ᳇ਛߦ 1 ᤨ㑆߆ࠄ 300 ᤨ㑆᡼⟎ߒߚ㧚ᒁᒛ⹜㛎ᓟߩߔߴߡߩ⹜㛎 ߦᱷ⇐ߒߡ޿ߚ᳓⚛㊂ CH,R ߪ TDA ߢ᷹ቯߒߚ㧚࿑ 7 ߦߪ㧘SCM435 ㍑ߩ⋧ኻᒁᒛᒝᐲǻB,H/ǻBߣ⋧ኻ⛉ࠅǾH/Ǿࠍᱷ⇐᳓⚛㊂ CH,R ߦኻߒߡ␜ߔ
[10]㧚CH,R ߪ 0.14㨪0.93 ppm ߩ㑆ߢᄌൻߒߡ޿ࠆ
߇㧘ǻB,H/ǻB = 1.0 ߢ৻ቯߢ޽ࠆ㧚ߒߚ߇ߞߡ㧘ᒁᒛᒝᐲ߇ 930 MPa ߢ޽ࠆ SCM435 ㍑ߦ߅޿ߡߪ㧘
0.14㨪0.93 ppm ߩ᜛ᢔᕈ᳓⚛㊂ߪᒁᒛᒝᐲߦᓇ㗀ࠍਈ߃ߥ޿㧚৻ᣇ㧘⋧ኻ⛉ࠅߪ㧘ᦨዊߩ CH,R = 0.14
ppm ߢ߽ǾH/Ǿ = 1 ߣߥࠄߕ㧘ߐࠄߦ CH,R ߇Ⴧ߃ࠆߦߒߚ߇ߞߡ⋥✢⊛ߦૐਅߒߡ޿ࠆ㧚ߒߚ߇ߞߡ㧘ᒁᒛᒝᐲ 930 MPa ߩ SCM435 ㍑ߩ⛉ࠅߪ㧘0.14
㨪0.93 ppm ߩ᜛ᢔᕈ᳓⚛㊂ߦࠃߞߡૐਅߔࠆ㧚 ࿑ 8 ߦ㧘SCM435 ㍑ߩᧂ࠴ࡖ࡯ࠫ᧚ߣ᳓⚛࠴ࡖ࡯ࠫ᧚ߩᒁᒛ⎕უ⎕㕙ߩ SEM ௝ࠍ␜ߔ[10]㧚ᧂ࠴ࡖ࡯ࠫ᧚ߣ᳓⚛࠴ࡖ࡯ࠫ᧚ߪߣ߽ߦࠞ࠶ࡊࠕࡦ࠼
ࠦ࡯ࡦ⎕უߒߡ޿ࠆ㧚ߔߥࠊߜ㧘⎕უߒߚ⹜㛎

Hydrogen release rate / ppm/min߷ဋ৻ߥࠆ᧦ઙߩ߽ߣߢ㧘⹜㛎 ߦ੍߼᳓⚛ࠍ࠴ࡖ࡯ࠫߔࠆᣇᴺ㧔㜞࿶᳓⚛ࠟࠬᦑ㔺㧘ᶐẃ᳓⚛࠴ࡖ࡯ࠫ㧘㔚⸃᳓⚛࠴ࡖ࡯ࠫ㧕ࠍណ↪ߒߚ㧚․ߦ㧘ࠝ࡯ࠬ࠹࠽ࠗ࠻♽ࠬ࠹ࡦ࡟ࠬ㍑ߢߪ㧘᳓⚛᜛ᢔଥᢙࠍᄢ߈ߊߔࠆߚ߼㧘᳓⚛ࠟࠬᦑ㔺᷷ᐲࠍ 300͠ઃㄭߦ⸳ቯߒߡ޿ࠆ㧚ߘߒߡ㧘᳓⚛࠴ࡖ࡯ࠫᓟ㧘ቶ᷷ᄢ᳇ਛߢᒁᒛ⹜㛎ࠍⴕߞߡ޿ࠆ㧚ᒁᒛ⹜㛎ߣᐔⴕߒ㧘ଚ౉᳓⚛㊂ࠍ᳓⚛㊂᷹ቯ↪⹜㛎 ࠍ૞ᚑ
ߒߡ TDS ߹ߚߪ TDA ࠍ↪޿ߡ᷹ቯߒߡ޿ࠆ㧚߹ߚ㧘ᒁᒛ⎕უߒߚߔߴߡߩ⹜㛎 ߩ᳓⚛㊂߽᷹ቯߒߡ޿ࠆ㧚 ᳓⚛ࠬ࠹࡯࡚ࠪࡦ⫾࿶ེ↪ૐว㊄㍑ 5%/ ࿑ 5 ߦ᳓⚛ࠬ࠹࡯࡚ࠪࡦ⫾࿶ེߢ૶↪ߐࠇߡ޿
ࠆૐว㊄㍑ SCM435㧔ᒁᒛᒝᐲǻB = 927 MPa㧘὾߈ᚯߒࡑ࡞࠹ࡦࠨࠗ࠻⚵❱㧕ߩଚ౉᳓⚛㊂ࠍ TDA
ߢ᷹ቯߒߚ⚿ᨐࠍ␜ߔ[10]㧚᳓⚛㊂᷹ቯ↪ਣ᫔㧔⋥
ᓘ 5mm㧘㐳ߐ 50mm㧕ߪ㧘ታ㓙ߩ⫾࿶ེ㧔ᄖᓘ 315
0.02

0.01

0

100 200 300 400 500 600 700 800

Temperature / K࿑ 5 SCM435 ㍑ߩ᳓⚛᡼಴᷷ᐲࡊࡠࡈࠔࠗ࡞

Hydrogen content, CH / ppm

1
0.8
0.6
0.4
0.2

0

10

20

30

40

Charging time, t / h5060

࿑ 6 SCM435 ㍑ߩଚ౉᳓⚛㊂ߣ᳓⚛࠴ࡖ࡯ࠫᤨ㑆ߩ㑐ଥ

વᾲ 2009 ᐕ 4 ᦬- 10 -J. HTSJ, Vol. 48, No. 203

․㓸㧦᳓⚛ߩ‛ᕈ߅ࠃ߮᧚ᢱ

1.2
1.0

(a)

(b)

σB,H/σB=1

σB,H/σB

0.8
th = 1 h
V = 1 mm/min

0.6
0.4
0.2
0.0

500 μm

0.2

0.4

0.6

0.8

㧔㨍㧕ᧂ࠴ࡖ࡯ࠫ᧚  㧔㨎㧕᳓⚛࠴ࡖ࡯ࠫ᧚   CH,R = 0 ppm
CH,R = 0.73 ppm

1.0

Residual hydrogen content, CH,R / ppm

࿑ 8 SCM435 ㍑ߩᒁᒛ⎕㕙㧚ࠢࡠࠬࡋ࠶࠼ㅦᐲ V = 1mm/min㧚㧔㨍㧕⋧ኻᒁᒛᒝᐲ
1.2(a)th = 1 h
V = 1 mm/min

1.0

500 μm

(a)

φH/φ

0.8
0.6
0.4
0.2
0

1 μm

0.2

0.4

0.6

0.8

1 μm

㧔㨍㧕ᧂ࠴ࡖ࡯ࠫ᧚  㧔㨎㧕᳓⚛࠴ࡖ࡯ࠫ᧚
CH,R = 0.73 ppm
   CH,R = 0 ppm

1

Residual hydrogen content, CH,R / ppm

࿑ 9 SCM435 ㍑ߩᒁᒛ⎕㕙ု⋥ᔕജ⎕უၞߩ࠺ࠖࡦࡊ࡞㧚ࠢࡠࠬࡋ࠶࠼ㅦᐲ V = 1mm/min㧚㧔㨎㧕⋧ኻ⛉ࠅ࿑ 7 SCM435 ㍑ߩ⋧ኻᒝᐲ߹ߚߪ⋧ኻ⛉ࠅߣᱷ⇐᜛ᢔᕈ᳓⚛ߩ㑐ଥ

H

Dimpleߩਛᄩㇱߦߪ⹜㛎 ゲߦኻߒߡో૕⊛ߦ߶߷
90ࠑࠍߥߔ㕙߆ࠄߥࠆု⋥ᔕജ⎕უၞ߇ᒻᚑߐࠇ㧘๟ㄝㇱߦߪ⹜㛎 ゲߦኻߒߡ߶߷ 45ࠑߩߖࠎᢿ
ᔕജ⎕უၞ߇ᒻᚑߐࠇߡ޿ࠆ㧚࿑ 8 ߢᦨ߽․ᓽ⊛ߥߎߣߪ㧘᳓⚛࠴ࡖ࡯ࠫ᧚ߣᧂ࠴ࡖ࡯ࠫ᧚ߩု⋥ᔕജ⎕უၞߪ߶߷หߓᐢߐߢ޽ࠆ߇㧘᳓⚛࠴ࡖ࡯ࠫ᧚ߩߖࠎᢿᔕജ⎕უၞߩ߶߁߇ᧂ࠴ࡖ࡯ࠫ᧚ࠃ
ࠅᐢ޿ߎߣߢ޽ࠆ㧚࿑ 9 ߦ㧘ᧂ࠴ࡖ࡯ࠫ᧚ߣ᳓⚛
࠴ࡖ࡯ࠫ᧚ߩု⋥ᔕജ⎕უၞߦᒻᚑߐࠇߡ޿ߚ࠺
ࠖࡦࡊ࡞ࠍ␜ߔ㧚ᧂ࠴ࡖ࡯ࠫ᧚ߣ᳓⚛࠴ࡖ࡯ࠫ᧚㧘ု⋥ᔕജ⎕უၞߣߖࠎᢿᔕജ⎕უၞߦ㑐ଥߥߊ㧘⎕㕙ߪ⋥ᓘ⚂ 1Ǵm ߩዊߐߥ࠺ࠖࡦࡊ࡞ߢⷒࠊࠇ
ߡ޿ߚ㧚
࿑ 10 ߦ㧘࿑ 7(b)ߩ⛉ࠅߣ࿑ 8 ߣ 9 ߩ SEM ௝ࠍ߽ߣߦ૞ᚑߒߚᒁᒛ⎕უߒߚᧂ࠴ࡖ࡯ࠫ᧚ߣ᳓

વᾲ 2009 ᐕ 4 ᦬- 11 -

H
H

䇯䇯䇯䇯䇯䇯䇯䇯䇯䇯䇯䇯䇯䇯

Shear stressfracture

Normal stressfracture

H
H

DimpleShear stressfractureH䇯䇯䇯䇯䇯䇯䇯䇯䇯䇯䇯䇯䇯䇯䇯

Shear stressfracture

H
H

Normal stressfracture
H

H

Shear stressfracture㧔㨍㧕ᧂ࠴ࡖ࡯ࠫ᧚  㧔㨎㧕᳓⚛࠴ࡖ࡯ࠫ᧚
࿑ 10 SCM435 ㍑ߩᒁᒛ⎕㕙❑ᢿ㕙ߩᮨᑼ࿑㧚⚛࠴ࡖ࡯ࠫ᧚ߩ❑ഀࠅᢿ㕙ߩᮨᑼ࿑ࠍߘࠇߙࠇ␜
ߔ㧚ᧂ࠴ࡖ࡯ࠫ᧚ߣ᳓⚛࠴ࡖ࡯ࠫ᧚ߪߣ߽ߦࠞ࠶
ࡊࠕࡦ࠼ࠦ࡯ࡦ⎕უߒ㧘ု⋥ᔕജ⎕უၞߣߖࠎᢿ
ᔕജ⎕უၞߦߪߣ߽ߦዊߐߥ࠺ࠖࡦࡊ࡞߇ᒻᚑߐ
ࠇࠆ㧚ߒ߆ߒ㧘ု⋥ᔕജ⎕უၞߪᧂ࠴ࡖ࡯ࠫ᧚ߣ
᳓⚛࠴ࡖ࡯ࠫ᧚ߢหߓᐢߐߢ޽ࠆ߇㧘ߖࠎᢿᔕജ

J. HTSJ, Vol. 48, No. 203

વᾲ 2009 ᐕ 4 ᦬- 12 -

1.4
1.2
1.0
0.8
0.6
0.4
0.2
0

5

10

15

Prestrain (%)

2025

࿑ 11 SGP ㍑ߩᱷ⇐᳓⚛㊂ߣ੍߭ߕߺߩ㑐ଥ
1.2
Relative reduction of area φH/φ0⎕უၞߪ᳓⚛࠴ࡖ࡯ࠫ᧚ߩ߶߁߇ᐢ޿㧚ߎߩߎߣߪ㧘᳓⚛ߪߖࠎᢿ⎕უၞߩᒻᚑߦᓇ㗀ߔࠆߎߣࠍ
␜ໂߒߡ޿ࠆ㧚ߖࠎᢿᔕജ⎕უၞ߇ᐢߊߥࠆߚ߼
ߦߪ㧘⹜㛎 ߇ߊ߮ࠇࠆㆊ⒟ߦ߅޿ߡ㧘ߖࠎᢿᔕജߦࠃࠆߔߴࠅᄌᒻ߇᳓⚛ߦࠃࠅഥ㐳ߐࠇ㧘ߖࠎᢿᔕജ⎕უ߇⿠ߎࠅ߿ߔߊߥࠆߎߣ߇ᔅⷐߣߥࠆ㧚ߒߚ߇ߞߡ㧘᳓⚛ࠍ೨߽ߞߡ࠴ࡖ࡯ࠫߒߚ
SCM435 ㍑ߩቶ᷷ᄢ᳇ਛᒁᒛ⹜㛎ߦ߅޿ߡ㧘᳓⚛
ߢ⛉ࠅ߇ૐਅߔࠆ⃻⽎ߔߥࠊߜ᳓⚛⣀ൻߪᩰሶᕈ
઒⺑ߢߥߊ㧘ዪᚲᄌᒻഥ㐳⺑ߢ⺑᣿ߢ߈ࠆ㧚឵⸒ߔࠆߣ㧘᳓⚛⣀ൻߪᩰሶ⣀ൻߦࠃࠆ⣀ᕈ⎕უߢߥߊ㧘ዪᚲᄌᒻഥ㐳ߦࠃࠆࡒࠢࡠᑧᕈ⎕უߢ޽ࠆ㧚 ᳓⚛ࡄࠗࡊ࡜ࠗࡦ↪὇⚛㍑ 5)2
࿑ 11 ߆ࠄ࿑ 15 ߦ᳓⚛ࡄࠗࡊ࡜ࠗࡦ୥⵬᧚ᢱߩ㈩ ▤ ↪ ὇ ⚛ ㍑ ㍑ ▤ SGP (0.078C-0.01Si-0.34Mn-0.017P-0.009S mass%㧘ǻB = 416 MPa)ߢᓧࠄࠇߚ
᳓⚛ಽᨆ⚿ᨐߣᒁᒛ⹜㛎⚿ᨐࠍ␜ߔ[17]㧚਄ㅀߩ
SCM435 ㍑ߩ႐วߣห᭽ߦ㧘᳓⚛࠴ࡖ࡯ࠫߪ 40°C
ߦ଻ᜬߒߚ 20 mass% NH4SCN ᳓ṁᶧߦ⹜㛎 ࠍ
48 ᤨ㑆ᶐẃߒߡⴕߞߚ㧚ߚߛߒ㧘SGP ㍑ߢߪ㍑ਛ
ߩ᳓⚛㊂ࠍჇ߿ߔߚ߼㧘⹜㛎 ߦ੍߭ߕߺࠍਈ߃
ߚ㧚᳓⚛㊂ߪ᣹᷷⣕㔌ಽᨆⵝ⟎ TDS ߢ᷹ቯߒߚ㧚࿑ 11 ߪ SGP ㍑ߦ߅ߌࠆᒁᒛ⹜㛎ᓟߩ⹜㛎 ਛߩᱷ⇐᜛ᢔᕈ᳓⚛㊂ߣ੍߭ߕߺߩ㑐ଥߢ޽ࠆ㧚᜛ᢔᕈ᳓⚛㊂ߪ㧘᣹᷷᳓⚛᡼಴ࡊࡠࡈࠔࠗ࡞ߢቶ᷷
߆ࠄ 300͠߹ߢߩ᳓⚛㊂ߣߒߚ㧚ᱷ⇐᳓⚛㊂ߪ੍߭ߕߺ߇ᄢ߈ߊߥࠆ߶ߤᄙߊߥࠆ㧚ߎߩ⃻⽎ߪ㧘੍߭ߕߺߦࠃߞߡჇടߒߚォ૏߇᳓⚛ࠍ࠻࡜࠶ࡊ
ߔࠆߚ߼ߦ⿠ߎࠆ㧚࿑ 12 ߦ⋧ኻ⛉ࠅǾ H/Ǿ 0 ߣᱷ⇐᜛ᢔᕈ᳓⚛㊂
CH,R ߩ㑐ଥࠍ␜ߔ㧚᳓⚛ߪᒁᒛᒝᐲߦߪᓇ㗀ࠍ෸߷ߐߥ޿߇㧘⛉ࠅࠍૐਅߐߖࠆ㧚 SCM435 ㍑ ߣ SGP ㍑ ࠍ Ყ ߴ ࠆ ߣ 㧘 ⚵ ❱ ߪ
SCM435 ㍑ߢ὾߈ᚯߒࡑ࡞࠹ࡦࠨࠗ࠻㧘SGP ㍑ߢ
ࡈࠚ࡜ࠗ࠻࡮ࡄ࡯࡜ࠗ࠻ߢ޽ࠆ㧚ᒁᒛᒝᐲߪ SGP㍑߶߁߇ૐߊ㧘⚂ 1/2 ߢ޽ࠆ㧚SCM435 ㍑ߢߪ㧘὾߈ᚯߒ⁁ᘒߢ᳓⚛࠻࡜࠶ࡊࠨࠗ࠻ߦߥࠆォ૏ߣ὇ൻ‛߇ᄙߊሽ࿷ߔࠆߩߢ㧘὾߈ᚯߒߩ߹߹ߢ᳓
⚛㊂ߪ⚂ 0.9 ppm ߢ޽ࠆ㧔࿑ 6㧕㧚ߎߩ᳓⚛㊂ߢǾH/Ǿߪ⚂ 0.7 ߣߥߞߡ޿ࠆ(࿑ 7(b))㧚৻ᣇ㧘SGP㍑߅޿ߡߪ㧘ᾲ㑆࿶ᑧ㧔὾㊰㧕ߩ߹߹ߢߪォ૏߇ዋߥ޿ߩߢ㧘੍߭ߕߺࠍਈ߃㧘ォ૏ࠍჇ߿ߒ㧘᳓⚛㊂ࠍᄙߊߒߡ޿ࠆ㧚20㧑ߩ੍߭ߕߺߢ᳓⚛㊂ߪ
⚂ 1 ppm ߦߥࠅ㧔࿑ 11㧕㧘ߎߩ᳓⚛㊂ߢǾH/Ǿ0

Residual hydrogen content (ppm)․㓸㧦᳓⚛ߩ‛ᕈ߅ࠃ߮᧚ᢱ

Uncharged

1.0
0.8
0.6
0.4
0.2
0

VirginPS 10%PS 20%
0.2 0.4 0.6 0.8 1 1.2 1.4
Residual hydrogen content CH,R (ppm)࿑ 12 SGP ㍑ߩ⋧ኻ⛉ࠅߣᱷ⇐᳓⚛㊂ߩ㑐ଥ㧔㨍㧕ᧂ࠴ࡖ࡯ࠫ᧚㧚CH,R = 0.01 ppm

㧔㨎㧕᳓⚛࠴ࡖ࡯ࠫ᧚ CH,R = 0.71 ppm㧚
࿑ 13 SGP ㍑ߩᒁᒛ⎕㕙ု⋥ᔕജ⎕უၞߩ࠺ࠖࡦࡊ࡞

J. HTSJ, Vol. 48, No. 203

․㓸㧦᳓⚛ߩ‛ᕈ߅ࠃ߮᧚ᢱ
ࠖࡦࡊ࡞߇ᒻᚑߐࠇߡ޿ߚ߇㧔࿑ 9㧕
㧘SGP ㍑ߢߪ㧘⋥ᓘ⚂ 10 Ǵm ߩᄢ߈ߥ࠺ࠖࡦࡊ࡞߇੺࿷‛ࠍ⿠ὐߣߒߡᒻᚑߐࠇߡ޿ࠆ(࿑ 13)㧚ߐࠄߦ㧘SGP ㍑
ߩ࠺ࠖࡦࡊ࡞⋥ᓘߪᧂ࠴ࡖ࡯ࠫ᧚ࠃࠅ᳓⚛࠴ࡖ࡯ࠫ᧚ߢᄢ߈ߊߥߞߡ޿ࠆ㧚ߎߩේ࿃ࠍ⺞ߴࠆߚ߼㧘ᒁᒛ⎕უ⹜㛎 ߩ❑ᢿ㕙ࠍⷰኤߒߚ㧚࿑ 14 ߦ SGP ㍑ߩᒁᒛ⎕უ⹜㛎 ❑ᢿ㕙ߢⷰኤߐࠇߚࡏࠗ࠼ࠍ␜ߔ㧚ᒁᒛ⩄㊀ゲᣇะߪ਄ਅᣇะ
ߢ޽ࠆ㧚ᧂ࠴ࡖ࡯ࠫ᧚ߢߪ㧘⩄㊀ゲᣇะߦિᒛߒ
ߚㅢᏱߩࡏࠗ࠼߇ᒻᚑߐࠇߡ޿ࠆ㧚৻ᣇ㧘᳓⚛࠴ࡖ࡯ࠫ᧚ߢߪ㧘㛳ߊߴ߈⃻⽎߇ⷰኤߐࠇߚ㧚ࡏࠗ࠼ߪ⩄㊀ゲߦု⋥ߥᣇะߦᚑ㐳ߒߡ޿ߚ㧚࿑ 15 ߦߪࡏࠗ࠼ߩ⊒↢㧘ᚑ㐳㧘ว૕ࠍᮨᑼ⊛ߦ␜ߔ㧚Ꮐᰣߩᧂ࠴ࡖ࡯ࠫ᧚ߢߪ㧘ࡏࠗ࠼ߪ੺࿷‛ࠍ⿠ὐߣߒߡ⊒↢ߔࠆ㧚ᒁᒛ߭ߕߺ߇ᄢ߈ߊߥࠆ
ߦߟࠇߡ㧘ࡏࠗ࠼ߪ⩄㊀ゲᣇะߦᚑ㐳ߔࠆ㧚ᦨ⚳⊛ߦࡏࠗ࠼㑆ߩࡀ࠶ࠠࡦࠣߢࡏࠗ࠼ߪว૕ߔࠆ㧚৻ᣇ㧘᳓⚛࠴ࡖ࡯ࠫ᧚ߩࡏࠗ࠼ߩ⊒↢㧘ᚑ㐳㧘ว૕ࠍ⠨߃ࠆ਄ߢߩࠠ࡯ࡐࠗࡦ࠻ߪ㧘᳓⚛߇ᔕജ㓸ਛㇱ߳㓸ਛߔࠆߎߣ㧘㓸ਛߒߚ᳓⚛߇ዪᚲߔߴࠅ
ࠍഥ㐳ߔࠆߎߣߢ޽ࠆ㧚࿑ 15 ߩฝᰣߦ␜ߔࠃ߁ߦ㧘੺࿷‛๟ㄝߩᔕജ㓸ਛㇱߦ᜛ᢔߒߡ߈ߚ᳓⚛ߪዪᚲߔߴࠅᄌᒻࠍഥ㐳ߒ㧘ࡏࠗ࠼⊒↢ࠍᣧ߼ࠆ㧚ታ㓙㧘ᒁᒛ⎕უ⹜㛎 ❑ᢿ㕙ߢන૏㕙Ⓧᒰߚࠅߩࡏ
ࠗ࠼୘ᢙߣ⌀߭ߕߺߩ㑐ଥࠍ⺞ߴ㧘᳓⚛ߪࡏࠗ࠼⊒↢ࠍᣧ߼ࠆߎߣࠍ⏕⹺ߒߡ޿ࠆ[17]㧚ᰴߦ㧘ࡏࠗ࠼వ┵ߦ㓸ਛߒߚ᳓⚛ߪࡏࠗ࠼వ┵ߢߩዪᚲߔ
ߴࠅᄌᒻࠍഥ㐳ߒ㧘ࡏࠗ࠼ߪ⩄㊀ゲߦု⋥ᣇะߦᚑ㐳ߔࠆ㧚ߐࠄߦ㧘᳓⚛ߪࡏࠗ࠼㑆ߩߖࠎᢿᄌᒻ
㧔ߔߴࠅ㧕ࠍഥ㐳ߒ㧘ว૕ࠍኈᤃߦߔࠆ㧚ߘߩ⚿ᨐ㧘⛉ࠅߪ᳓⚛࠴ࡖ࡯ࠫ᧚ߢᖡൻߔࠆ㧔࿑ 12㧕㧚એ਄ߢㅀߴߚࠃ߁ߦ㧘ૐว㊄㍑ SCM435 ߣ὇⚛
㍑ SGP ߦ߅޿ߡ㧘⛉ࠅ߇ૐਅߔࠆ⃻⽎ߔߥࠊߜ᳓
⚛⣀ൻߪᩰሶ⣀ൻ⺑ߢߥߊ㧘ዪᚲᄌᒻഥ㐳⺑ߢ⺑᣿ߢ߈ࠆ㧚឵⸒ߔࠆߣ㧘᳓⚛⣀ൻߪᩰሶ⣀ൻߦࠃࠆ⣀ᕈ⎕უߢߥߊ㧘ዪᚲᄌᒻഥ㐳ߦࠃࠆࡒࠢࡠᑧ
ᕈ⎕უߢ޽ࠆߣ⚿⺰ߢ߈ࠆ㧚߽߁৻ߟߩ᳓⚛ࡄࠗࡊ࡜ࠗࡦ୥⵬᧚ᢱߢ޽ࠆ㈩▤↪὇⚛㍑㍑▤
STPG370[18]ߣ᳓⚛ࠛࡀ࡞ࠡ࡯ࠪࠬ࠹ࡓ࡮ࠗࡦࡈ
࡜ߢᄙߊ૶↪ߐࠇߡ޿ࠆࠝ࡯ࠬ࠹࠽ࠗ࠻♽ࠬ࠹ࡦ
࡟ࠬ㍑ SUS316L[19]ߦ߅޿ߡ߽㧘ห᭽ߥ⚿⺰߇ᓧࠄࠇߡ޿ࠆ㧚ߒ߆ߒ㧘⛉ࠅࠍૐਅߐߖࠆⷐ࿃ߪ㧘
STPG370 ㍑ߢߪࡄ࡯࡜ࠗ࠻ഀࠇ㧘SUS316L ߢߪࡏࠗ࠼ࠪ࡯࠻ߢ޽ߞߚ㧚㧔㨍㧕ᧂ࠴ࡖ࡯ࠫ᧚㧚CH,R = 0.01 ppm

㧔㨎㧕᳓⚛࠴ࡖ࡯ࠫ᧚ CH,R = 0.71 ppm㧚
࿑ 14 SGP ㍑ߩᒁᒛ⎕㕙❑ᢿ㕙ߩࡏࠗ࠼
Uncharged

Hydrogen charged
H

Inclusion

H

H
HH
H

H

H

H

Inclusion

H
H

HH
HH

H

Loading direction

H
H
HH

H

H

H

Nucleation
H

H

H
HH
H

H
HHH

H

H

H

H

H
HH
H

H
HHH
H

GrowthNecking

H

H

H
HH
H

H
HH
H
HH
HH

H
H

Shearing

H

H
HH
H
H

H

Coalescence࿑ 15 SGP ㍑ߩࡏࠗ࠼ᚑ㐳ߩᮨᑼ࿑ߪ⚂ 0㧚8 ߣߥߞߡ޿ࠆ㧔࿑ 12㧕㧚ߎߩࠃ߁ߥ᳓⚛
ଚ౉․ᕈ߿⋧ኻ⛉ࠅߦട߃㧘ᒁᒛ⎕㕙ߩ࠺ࠖࡦࡊ
࡞ߦ߽ SCM435 ㍑ߣ SGP ㍑ߢ㆑޿߇޽ࠆ㧚
SGP ㍑ߩᧂ࠴ࡖ࡯ࠫ᧚ߣ᳓⚛࠴ࡖ࡯ࠫ᧚ߩᒁᒛ
⎕უ߽ࠞ࠶ࡊࠕࡦ࠼ࠦ࡯ࡦ⎕უߢ޽ߞߚ㧚࿑ 13
ߦ SGP ㍑ߩု⋥ᔕജ⎕უၞߢߩ࠺ࠖࡦࡊ࡞ࠍߒ
߹ߔ㧚SCM435 ㍑ߢߪ㧘⋥ᓘ⚂ 1 Ǵm ߩዊߐߥ࠺

વᾲ 2009 ᐕ 4 ᦬- 13 -J. HTSJ, Vol. 48, No. 203

․㓸㧦᳓⚛ߩ‛ᕈ߅ࠃ߮᧚ᢱ

Stress amplitude, ǻa(MPa)Stress amplitude, ǻa(MPa)㊂ߪ⚂ 1.2 ppm ߢ޽ߞߚ. ᐔṖ⹜㛎 ߢߪ㧔࿑16(a)㧕㧘᳓⚛࠴ࡖ৻ࠫ᧚ߩ∋ഭኼ๮ߪ㧘⹜㛎ㅦᐲߦ㑐ଥߥߊ㧘ᧂ࠴ࡖ৻ࠫ᧚ߩ⚿ᨐߣ߶߷৻⥌ߒ,᳓⚛ߩᓇ㗀ߪ⷗ࠄࠇߡ޿ߥ޿㧚৻ᣇ㧘ಾᰳ߈᧚ߢ
ߪ㧔࿑ 16(b)㧕㧘ᧂ࠴ࡖ৻ࠫ᧚ߣᲧセߒߡ᳓⚛࠴ࡖ࡯ࠫ᧚ߩ∋ഭኼ๮ߪ㧘⹜㛎ㅦᐲ㨒߇ 30Hz ߆ࠄ
0,2Hz ߣㆃߊߥࠆ߶ߤ㧘⍴ߊߥࠅ㧘ᦨᄢ 1 ᩴ⒟800
S45C Smoothed specimen
Uniaxal load, R=-1
Hydrogen. charged

700
;2Hz
;0.2Hz
1.03 0.71 (mass.ppm);0.02Hz
600

0.42

0.91 0.56500Uncharged
;5Hz

400

103
104
105
Number of cycles to failure, Nf㧔㨍㧕ਣ᫔ᐔṖ⹜㛎 500

S45C Notched specimen(Kt=3.7)
Uniaxal load, R=-1
Uncharged
400
;30Hz

0.70
0.92 0.95 (mass.ppm)
0.71 0.23
300

0.99
Hydrogencharged

0.89
;30Hz
200

;2Hz
;0.2Hz;0.02Hz
100 3

10
104
105
Number of cycles to failure, Nf㧔㨎㧕ਣ᫔ಾࠅᰳ߈⹜㛎 㧔Kt = 3.7㧕࿑ 16 550͠὾߈ᚯߒߚ὇⚛㍑ S45C ߩᧂ࠴ࡖ࡯
ࠫ᧚ߣ᳓⚛࠴ࡖ࡯ࠫ᧚ߩ S-N ․ᕈ㧔R = -1㧕

વᾲ 2009 ᐕ 4 ᦬- 14 --310

S45C RT, 30HzHydrogen charged
10-4;R=0.1

Uncharged
10-5
;R=0.1
10-6
0.1(mass ppm)
10-7

10-8

1
5
10
1/2
ǍK㧔MPa࡮m)࿑ 17 550͠὾߈ᚯߒߚ὇⚛㍑ S45C ߩ∋ഭ߈ⵚ
ㅴዷ․ᕈ㧔R = -1㧕㧚ᐲߩૐਅߢ㘻๺ߒߡ޿ࠆ㧚ಾᰳ߈⹜㛎 ߢߪ㧘ᐔṖ⹜㛎 ߦᲧߴߡ߈ⵚ⊒↢ኼ๮߇⍴ߊߥࠆߚ߼,᳓⚛ߦࠃࠆ∋ഭኼ๮ૐਅߪ߈ⵚㅴዷኼ๮ߩᏅߦ㑐ㅪߒߡ޿ࠆߎߣߦߥࠆ㧚࿑ 17 ߪหߓ S45C ㍑὾߈ᚯߒ᧚ߩ R = -1 ߢߩ∋ഭ߈ⵚㅴዷㅦᐲ da/dN ߣᔕജ᜛ᄢଥᢙ▸࿐ ΔK ߩ㑐ଥߢ޽ࠆ[32]㧚ᧂ࠴ࡖ࡯ࠫ᧚ߦᲧߴ㧘᳓⚛࠴ࡖ࡯ࠫ᧚ߩ߈ⵚㅴዷㅦᐲߪടㅦߒߡ޿ࠆ㧚ߒߚ߇ߞߡ㧘᳓⚛ࠛࡀ࡞ࠡ࡯ࠪࠬ࠹ࡓ㨯ࠗࡦࡈ࡜ߩ቟ోᕈࠍ
⏕଻ߔࠆߚ߼ߦߪ㧘߹ߕ᳓⚛ߦࠃࠆ∋ഭ߈ⵚㅴዷ
ടㅦࡔࠞ࠾࠭ࡓ⸃᣿߇ᔅⷐߢ޽ࠆ㧚 ᳓⚛ࡄࠗࡊ࡜ࠗࡦ↪὇⚛㍑ 5)2
࿑ 18 ߦ 10%੍߭ߕߺࠍਈ߃ߚ STPG ㍑ߩ∋ഭ߈ⵚ⹜㛎㧔R = 0㧕ߢᓧࠄࠇߚ߈ⵚవ┵ߩߔߴࠅࠍ
࡟ࡊ࡝ࠞᴺߢⷰኤߒߚ⚿ᨐࠍ␜ߔ[31]㧚᳓⚛࠴ࡖ
৻ࠫߪ 20mass%࠴ࠝࠪࠕࡦ㉄ࠕࡦࡕ࠾࠙ࡓ᳓ṁᶧᶐẃߢⴕߞߚ㧚࿑ 10 ߦ߅޿ߡ㧘᳓⚛࠴ࡖ࡯ࠫ᧚ߩ
ࡏࠗ࠼ߩ⊒↢㧘ᚑ㐳㧘ว૕ࠍ⠨߃ࠆ਄ߢߩࠠ࡯ࡐ
ࠗࡦ࠻ߪ㧘᳓⚛߇ᔕജ㓸ਛㇱ߳㓸ਛߔࠆߎߣ㧘㓸ਛߒߚ᳓⚛߇ዪᚲߔߴࠅᄌᒻࠍഥ㐳ߔࠆߎߣߢ޽
ࠆߢ޽ࠆߣㅀߴߚ㧚࿑ 18 ߦ␜ߔࠃ߁ߦ㧘ᧂ࠴ࡖ࡯ࠫ᧚ߦ߅޿ߡߪ∋ഭ߈ⵚ๟ㄝߩᐢ޿▸࿐ߢߔߴࠅ
߇ⷰኤߐࠇࠆ߇㧘᳓⚛࠴ࡖ࡯ࠫ᧚߅޿ߡߪ⹜㛎๟
ᵄᢙ 0.01Hz ߢߔߴࠅ߇߶ߣࠎߤⷰኤߐࠇߥ޿㧚ߔߥࠊߜ㧘∋ഭ߈ⵚవ┵ߦ߅޿ߡ᳓⚛ࠃࠅߔߴࠅ߇
ዪ࿷ൻߒߡ޿ࠆߎߣ߇ࠊ߆ࠆ㧚࿑ 19 ߦ SGP ߩ∋ഭ⎕㕙ߩࠬ࠻࡜ࠗࠛ࡯࡚ࠪࡦ
ࠍ␜ߔ㧚ᧂ࠴ࡖ࡯ࠫ᧚ߢߪ㧘ౖဳ⊛ߥᑧᕈࠬ࠻࡜
ࠗࠛ࡯࡚ࠪࡦ߇ᒻᚑߐࠇߡ޿ࠆ㧚৻ᣇ㧘᳓⚛࠴ࡖ࡯ࠫ᧚ߢߪ㧘ࠬ࠻࡜ࠗࠛ࡯࡚ࠪࡦߪᐔမߢ㧘Ⴚ⇇߇ਇ㞲᣿ߢ޽ࠆ㧚ߐࠄߦ㧘ࠬ࠻࡜ࠗࠛ࡯࡚ࠪࡦ
da/dN (mm/cycle)㧚∋ഭ߈ⵚㅴዷࡔࠞ࠾࠭ࡓ
 ∋ഭ߈ⵚ⊒↢ߣ∋ഭ߈ⵚㅴዷ ⎕უ੐᡿ߩ 80㧑ߪ∋ഭ⎕უߦ㑐ଥߔࠆߣ⸒ࠊ
ࠇߡ޿ࠆ㧚ߒߚ߇ߞߡ㧘᳓⚛ࠛࡀ࡞ࠡ࡯ࠪࠬ࠹ࡓ࡮
ࠗࡦࡈ࡜ߩ቟ోᕈ࡮ା㗬ᕈࠍ⏕଻ߔࠆߚ߼ߦߪ㧘∋ഭߦ෸߷ߔ᳓⚛ߩᓇ㗀ࠍ᣿ࠄ߆ߦߒߥߌࠇ߫ߥ
ࠄߥ޿㧚ߒ߆ߒߥ߇ࠄ㧘᳓⚛ⅣႺਅߩ∋ഭ⎇ⓥߪ
ዋߥ޿[20-32]㧚
 ࿑ 16 ߪ὇⚛㍑ S45C ߩ 550͠὾߈ᚯߒ᧚ߩᐔṖ⹜㛎 ߣಾᰳ߈⹜㛎 ߢᓧߚ S-N ․ᕈߢ޽ࠆ[32]㧚
ᔕജᲧ R = ǻmax/ǻmin ߪ-1 ߢ޽ࠆ㧚᳓⚛࠴ࡖ৻ࠫߪ㧘40͠ߦ଻ߞߚ 20mass%࠴ࠝࠪࠕࡦ㉄ࠕࡦࡕ࠾࠙ࡓ᳓ṁᶧਛߦ 48 ᤨ㑆ᶐẃߒߡⴕߞߚ㧚㘻๺᳓⚛

J. HTSJ, Vol. 48, No. 203

(da/dN)/ΔK2, SZWT, max/K2max[(m/cycle)/(MPa㨯лm)2]․㓸㧦᳓⚛ߩ‛ᕈ߅ࠃ߮᧚ᢱ
10-8

10-9
Hydrogen charged

10-10
Uncharged

10-11 -4
10 10-3 10-2 10-1 100 101 102
Test frequency f [Hz]㧔㨍㧕ᧂ࠴ࡖ࡯ࠫ᧚
ǻa = 45.5 MPa, R = 0, a = 12.57 mm, CH = 0 ppm

Hydrogen charged
䂦 Replica (ΔK=80-81MPa㨯лm)䂾 Striation (ΔK=45-97MPa㨯лm)
SZWT, max (Kmax=138MPa㨯лm)
Uncharged
䂥 Replica (ΔK=79-80MPa㨯лm)䃂 Striation (ΔK=44-91MPa㨯лm)
SZWT, max (Kmax=137MPa㨯лm)࿑ 20 SGP ߩၮḰൻߐࠇߚ∋ഭ߈ⵚㅴዷㅦᐲߣ
⹜㛎๟ᵄᢙߩ㑐ଥ㧔㨎㧕᳓⚛࠴ࡖ࡯ࠫ᧚
ǻa = 45.5 MPa, R = 0, a = 12.65 mm, CH = 1.1 ppm
࿑ 18 SGP ㍑ߩ∋ഭ߈ⵚ๟ㄝߩߔߴࠅ㧚SZWT [μm]4030Striation
SZW T, max

20
10䃂Uncharged(0ppm, Kmax=137MPa㨯лm)θ䂾Hydrogen charged(1.1ppm, Kmax=138MPa㨯лm)0-10 0 10 20 30 40 50
Inclination angle of fracture surface θ [o]࿑ 21 SGP ㍑ߩࠬ࠻࡟࠶࠴࠱࡯ࡦ᏷ߣ⎕㕙௑ᢳⷺߩ㑐ଥ

㧔㨍㧕ᧂ࠴ࡖ࡯ࠫ᧚
ǍK = 87 MPaлm, R = 0, f = 0.1 Hz, CH = 0 ppm

ⵚㅴዷㅦᐲߣ⹜㛎๟ᵄᢙߩ㑐ଥࠍ␜ߔ㧚߈ⵚㅴዷㅦᐲ da/dN ߦߪ࡟ࡊ࡝ࠞᴺߢ᳞߼ߚㅦᐲߣࠬ࠻࡜
ࠗࠛ࡯࡚ࠪࡦ᏷ߩਔᣇ߇฽߹ࠇߡ޿ࠆ㧚ᧂ࠴ࡖ࡯ࠫ᧚ߢߪ㧘ၮḰߐࠇߚ߈ⵚㅴዷㅦᐲߪ⹜㛎๟ᵄᢙߦଐሽߖߕ㧘৻ቯߢ޽ࠆ㧚ᧂ࠴ࡖ࡯ࠫ᧚ߦᲧߴ㧘᳓⚛࠴ࡖ࡯ࠫ᧚ߢߪ߈ⵚㅴዷㅦᐲߪ f ҇ 10-3 Hzߢടㅦߒ㧘⚂ 10 ୚ߢ㘻๺ߒߡ޿ࠆ㧚ߎߩߎߣߪ㧘᳓⚛ߦࠃࠆ∋ഭ߈ⵚㅴዷߩടㅦߦߪ਄㒢୯߇ሽ࿷ߔࠆߎߣࠍᗧ๧ߒߡ޿ࠆ㧚᳓⚛ߦࠃࠆ∋ഭ߈ⵚㅴዷടㅦࡔࠞ࠾࠭ࡓࠍ⺞ߴࠆߚ߼㧘∋ഭ߈ⵚㅴዷ⹜㛎ᓟߦ 1.5 ୚ߩㆊᄢ⩄㊀
ࠍ⽶⩄ߒߡࠬ࠻࡟࠶࠴࠱࡯ࡦࠍᒻᚑߔࠆ⹜㛎ࠍⴕ޿㧘ࠬ࠻࡟࠶࠴࠱࡯ࡦᒻᚑ⹜㛎ᓟߦ⎕㕙ࠍዋߒߕߟ௑ߌߡ߈ⵚవ┵ߩࠬ࠻࡟࠶࠴࠱࡯ࡦࠍⷰኤߒߚ㧚࿑ 21 ߦࠬ࠻࡟࠶࠴࠱࡯ࡦ᏷ SZWT ߣ⎕㕙ߩ௑ߌ㧔㨎㧕᳓⚛࠴ࡖ࡯ࠫ᧚
ǍK =85 MPaлm, R = 0, f = 0.001 Hz, CH = 0.98 ppm

࿑ 19 SGP ㍑ߩࠬ࠻࡜ࠗࠛ࡯࡚ࠪࡦ
᏷ߪᧂ࠴ࡖ࡯ࠫ᧚ߦᲧߴߡ᳓⚛࠴ࡖ࡯ࠫ᧚ߢ⚂10 ୚ᐢ޿㧚࿑ 20 ߦ SGP ㍑ߦ߅ߌࠆၮḰൻߐࠇߚ∋ഭ߈

વᾲ 2009 ᐕ 4 ᦬- 15 -J. HTSJ, Vol. 48, No. 203

․㓸㧦᳓⚛ߩ‛ᕈ߅ࠃ߮᧚ᢱ
㽴
Stress

㽳

㽵
㽶

㽲

0

Time
H

H

H
H

Ԙ

H

H
H

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H
H

ԙ

H

H

H

H

H

Ԛ

H

H

H

H

H

H
H H

SZW F,

H

H

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ԛ

H

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s

H

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SZW F,
H

H

H

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Ԝ

H

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H H
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s

㧔㨍㧕ᧂ࠴ࡖ࡯ࠫ᧚
㧔㨎㧕᳓⚛࠴ࡖ࡯ࠫ᧚
( )࿑ 22 ∋ഭ߈ⵚㅴዷࡕ࠺࡞
ⷺᐲǰߩ㑐ଥࠍ␜ߔ㧚௑ߌⷺᐲ߇ 0qߩߣ߈㧘⎕㕙ࠍ⌀਄߆ࠄⷰኤߒߡ޿ࠆߎߣߦߥࠆ㧚ᧂ࠴ࡖ࡯ࠫ᧚ߩࠬ࠻࡟࠶࠴࠱࡯ࡦ᏷ߪ௑ߌⷺᐲ 25qߢᦨ
ᄢߦߥࠆߩߦኻߒ㧘᳓⚛࠴ࡖ࡯ࠫ᧚ߩࠬ࠻࡟࠶࠴
࠱࡯ࡦ᏷ߪ 0qߢᦨᄢߦߥߞߡ޿ࠆ㧚ߎߩߎߣߪ㧘ᧂ࠴ࡖ࡯ࠫߢߪ߈ⵚవ┵ߪ㐿ญߒߡ޿ࠆߩߦኻߒ㧘᳓⚛࠴ࡖ࡯ࠫ᧚ߩ߈ⵚవ┵ߪ㐿ญߖߕ㧘㍈޿߹߹ߢ޽ࠆߎߣࠍ␜ߒߡ޿ࠆ㧚࿑ 22 ߦ㧘߈ⵚవ┵ߩߔߴࠅ㧘ࠬ࠻࡜ࠗࠛ࡯࡚ࠪ
ࡦ㧘ࠬ࠻࡟࠶࠴࠱࡯ࡦߩⷰኤ⚿ᨐࠍ߽ߣߦ૞ᚑߒ
ߚ∋ഭ߈ⵚㅴዷߩᮨᑼ࿑ࠍ␜ߔ㧚࿑(a)ߩᧂ࠴ࡖ࡯
ࠫ᧚ߢߪ㧘੹߹ߢߦឭ᩺ߐࠇߡ޿ࠆࡕ࠺࡞[33]ߦ
␜ߐࠇߡ޿ࠆࠃ߁ߦ㧘ᔕജ⽶⩄ㆊ⒟ߢ߈ⵚవ┵ߪ㐿ญߒ㧘ᦨᄢᔕജߩߣ߈ߩ SZWF ߇ᒻᚑߐࠇࠆ㧚㒰⩄ㆊ⒟ߦ߅޿ߡߪㅒߔߴࠅ߇⿠ߎࠅ㧘߈ⵚߪ㐽ญߒߡ޿߈㧘ᦨ⚳⊛ߦࠬ࠻࡜ࠗࠛ࡯࡚ࠪࡦ߇ᒻᚑ
ߐࠇࠆ㧚ߘߩ⚿ᨐ㧘ࠬ࠻࡜ࠗࠛ࡯࡚ࠪࡦ᏷ s ߪ
SZWF ࠃࠅ߽ዊߐߊߥࠆ㧚৻ᣇ㧘࿑(b)ߩ᳓⚛࠴ࡖ࡯ࠫ᧚ߢߪ㧘߈ⵚవ┵ߢ㓸ਛߒߚ᳓⚛ߦࠃߞߡߔ
ߴࠅ߇ዪ࿷ൻߔࠆߚ߼㧘⽶⩄ㆊ⒟ߦ߅޿ߡ߽߈ⵚ
వ┵ߪᄢ߈ߊ㐿ญߖߕ㧘߈ⵚߪ⛮⛯⊛ߦ೨ߦㅴዷ

વᾲ 2009 ᐕ 4 ᦬- 16 -

ߔࠆ㧚ᦨᄢᔕജߦ߅޿ߡ߽߈ⵚߪ㐿ญߒߡ޿ߥ޿
ߩߢ㧘㒰⩄ㆊ⒟ߢㅒߔߴࠅ㊂ߪ߶ߣࠎߤ߅ߎࠄߥ
޿㧚ߎߩ⚿ᨐ㧘ࠬ࠻࡜ࠗࠛ࡯࡚ࠪࡦ᏷ s ߪࠬ࠻࡟࠶࠴࠱࡯ࡦ᏷ SZWF ߣ߶߷╬ߒߊߥࠅ㧘᳓⚛ߦࠃߞߡ∋ഭ߈ⵚㅴዷߪ⚂ 10 ୚ടㅦߔࠆ㧔࿑ 20㧕ߣ⠨߃ࠄࠇࠆ㧚ᚒ‫ߪޘ‬㧘ߎߩࠃ߁ߥ᳓⚛ߦࠃࠆ∋ഭ߈ⵚㅴዷ᜼േࠍ᳓⚛ഥ㐳∋ഭ߈ⵚㅴዷ⛮⛯೨ㅴᯏ᭴㧔Hydrogen Enhanced Successive Fatigue Crack
Growth, HESFCG㧕ߣฬઃߌߡ޿ࠆ[31]㧚HESFCGᯏ᭴ߪ㧘ᒁᒛ⎕უߩ႐วߣห᭽ߦ㧘᳓⚛⣀ൻ߇ᩰሶ⣀ൻߦࠃࠆ⣀ᕈ⎕უߢߥߊ㧘ߔߴࠅߩዪ࿷ൻߦ
ࠃࠆࡒࠢࡠᑧᕈ⎕უߢ޽ࠆߎߣࠍ␜ߒߡ޿ࠆ㧚ਛ᧛ࠄ[43]ߪ⒳‫᧚ߩޘ‬ᢱߢࠬ࠻࡜ࠗࠛ࡯࡚ࠪࡦ
᏷ߣࠬ࠻࡟࠶࠴࠱࡯ࡦ᏷ߩ㑐ଥࠍ⺞ߴ㧘᧚ᢱߦࠃࠄߕࠬ࠻࡟࠶࠴࠱࡯ࡦ᏷ߪࠬ࠻࡜ࠗࠛ࡯࡚ࠪࡦ᏷
ߩ⚂ 10 ୚ߦߥࠆߣႎ๔ߒߡ޿ࠆ㧚ߎߩ୯ߪ᳓⚛ߦࠃࠆ∋ഭ߈ⵚㅴዷടㅦߩ਄㒢୯㧔࿑ 20 ߢ da/dN ߪᧂ࠴ࡖ࡯ࠫ᧚ߦᲧߴߡ᳓⚛࠴ࡖ࡯ࠫ᧚ߢ⚂ 10 ୚㧕ߣ৻⥌ߒߡ޿ࠆ㧚ߔߥࠊߜ㧘᳓⚛ߦࠃࠆ∋ഭ߈ⵚㅴዷടㅦߩ਄㒢୯ߪࠬ࠻࡟࠶࠴࠱࡯ࡦ᏷ߣ৻⥌ߔࠆ㧚᳓⚛ߦࠃࠆ∋ഭ߈ⵚㅴዷടㅦߦ਄㒢୯߇ሽ࿷ߔࠆߎߣߪ㧘ᒝᐲ⸳⸘਄ᭂ߼ߡ㊀ⷐߢ޽ࠆ㧚߹ߚ㧘ߎߩߎߣߪ᳓⚛㔓࿐᳇ߦᦑߐࠇࠆᯏ᪾࡮᭴ㅧ‛ߢߩ޿ࠊࠁࠆ᳓⚛⣀ൻߦኻߒߡ቟ోߥ∋ഭᒝᐲ⸳⸘
ᜰ㊎ࠍ⏕┙ߔࠆᩮ᜚ߣߥࠅ߁ࠆ㧚᳓⚛ࠬ࠹࡯࡚ࠪࡦ⫾࿶ེ↪ૐว㊄㍑ SCM435 ߢ߽㧘᳓⚛ߦࠃߞߡ∋ഭ߈ⵚవ┵ߢߔߴࠅ߇ዪ࿷ൻ
ߒ㧘᳓⚛ߦࠃࠆ∋ഭ߈ⵚㅴዷടㅦߦ਄㒢୯߇ሽ࿷ߔࠆ[29]㧚ࠝ࡯ࠬ࠹࠽ࠗ࠻♽ࠬ࠹ࡦ࡟ࠬ㍑ SUS304㧘
SUS316㧘SUS316L ߢ߽㧘᳓⚛ߦࠃߞߡ∋ഭ߈ⵚవ┵ߢߔߴࠅ߇ዪ࿷ൻߒ㧘᳓⚛ߦࠃߞߡ∋ഭ߈ⵚㅴዷㅦᐲߪടㅦߔࠆ[27,30]㧚ࠝ࡯ࠬ࠹࠽ࠗ࠻♽ࠬ
࠹ࡦ࡟ࠬ㍑ߩ᳓⚛ߦࠃࠆ∋ഭ߈ⵚㅴዷടㅦߢߪ㧘߈ⵚవ┵ߢߩടᎿ⺃⿠ࡑ࡞࠹ࡦࠨࠗ࠻ᄌᘒ߇㊀ⷐߥᓎഀࠍᨐߚߔ[27,30]㧚
 ౝㇱ᳓⚛ߣᄖㇱ᳓⚛੹߹ߢㅀߴߚᒁᒛ⹜㛎ߣ∋ഭ⹜㛎ߪ㧘⹜㛎 ࠍ 20
mass % ࠴ࠝࠪࠕࡦ㉄ࠕࡦࡕ࠾࠙ࡓ᳓ṁᶧߦᶐẃߒߚࠅߒߡ㧘᳓⚛ࠍ⹜㛎 ߦ੍߼࠴ࡖ࡯ࠫߒߡⴕߞߚ㧚੍߼࠴ࡖ࡯ࠫߐࠇ㧘․ᕈߦᓇ㗀ࠍਈ߃ࠆ᳓⚛ࠍౝㇱ᳓⚛ߣ๭߱㧚৻ᣇ㧘᳓⚛ࠬ࠹࡯࡚ࠪࡦ⫾࿶ེ߿᳓⚛ࡄࠗࡊ࡜ࠗࡦߪ⋥ធ᳓⚛ࠟࠬߦᦑߐࠇࠆߩߢ㧘᳓⚛ࠟࠬ߆ࠄ᧚ᢱਛߦ᳓⚛߇ଚ౉ߔࠆ㧚ㇱຠ߿ㇱ᧚ߩ૶↪ਛߦ᳓⚛ࠟࠬߩࠃ߁ߥ๟ㄝߩⅣႺ߆ࠄ᧚ᢱਛߦଚ౉ߒ㧘․ᕈߦᓇ㗀ࠍਈ߃ࠆ᳓⚛ࠍᄖㇱ᳓

J. HTSJ, Vol. 48, No. 203

․㓸㧦᳓⚛ߩ‛ᕈ߅ࠃ߮᧚ᢱ

(da/dN)H2/(da/dN)air

102

Oxide layer

Oxide layer

SM490B, In hydrogen, R = 0.1

ӆ

H

H

H 2 H2
H2
H2 H
2

101

ӆ

Bare surface

H

Bare surfaceH㧔㨍㧕ᄖㇱ᳓⚛     㧔㨎㧕ౝㇱ᳓⚛
࿑ 25 ∋ഭ߈ⵚవ┵ߢߩᄖㇱ᳓⚛ߣౝㇱ᳓⚛ߩ᜛ᢔࡕ࠺࡞

ΔK = 24㨪31 MPa࡮m1/2
Symbols are shown in Fig.5

100

10-1

100
Frequency, f [Hz]101

Hz ߢᓧࠄࠇ㧘ᄢ᳇ਛߩ߈ⵚㅴዷㅦᐲߦᲧߴ㧘⚂ 30୚ߢ޽ࠆ㧚࿑ 20 ߦ␜ߔࠃ߁ߦ㧘᳓⚛࠴ࡖ࡯ࠫߔߥ
ࠊߜౝㇱ᳓⚛ߢᓧࠄࠇߚ SGP ߩ⚿ᨐߢߪ㧘਄㒢୯ߪf ҇ 0.01 Hz ߢ㆐ᚑߐࠇ㧘⚂ 10㨪30 ୚ߢ޽ࠆ㧚ߒߚ߇ߞߡ㧘὇⚛㍑ߩ႐ว㧘ౝㇱ᳓⚛ߣᄖㇱ᳓⚛ࠃࠆ∋ഭ߈ⵚㅴዷടㅦߩ਄㒢୯ߪ╬ߒ޿߇㧘਄㒢୯߇㆐ᚑߐࠇࠆ⹜㛎๟ᵄᢙߪᄢ߈ߊ⇣ߥࠅ㧘ᄖㇱ᳓⚛ߩ߶߁
߇ 100 ୚߽ㅦ޿ߣ⸒߃ࠆ㧚࿑ 24 ߪ 0.7 MPa ᳓⚛ࠟࠬਛ㧘f = 0.1Hz ߢᓧࠄࠇߚ SM490B ㍑ߩࠬ࠻࡜ࠗࠛ࡯࡚ࠪࡦߢ޽ࠆ㧚ࠬ࠻࡜ࠗࠛ࡯࡚ࠪࡦߪᐔမߢ㧘ߘߩႺ⇇ߪਇ㞲᣿ߢ޽ࠅ㧘࿑ 19 ߩ SGP ߩ᳓⚛࠴ࡖ࡯ࠫ᧚ߩࠬ࠻࡜ࠗࠛ࡯࡚ࠪ
ࡦߣ߶ߣࠎߤหߓ․ᓽࠍ᦭ߒߡ޿ࠆ㧚⸒޿឵߃ࠆߣ㧘᳓⚛ߦࠃࠆ∋ഭ߈ⵚㅴዷടㅦ߇਄㒢୯ߦ㆐ߒߡ޿
ࠆ႐ว㧘ࠬ࠻࡜ࠗࠛ࡯࡚ࠪࡦߩ․ᓽߪᄖㇱ᳓⚛ߣౝㇱ᳓⚛ߢหߓߢ޽ࠆ㧚࿑ 25 ߦߪ㧘∋ഭ߈ⵚవ┵ߦ߅ߌࠆᄖㇱ᳓⚛ߣౝㇱ᳓⚛ߩ᜛ᢔࡕ࠺࡞ࠍ␜ߔ㧚࿑(a)ߦ␜ߔࠃ߁ߦ㧘᳓⚛ࠟࠬਛߦ߅޿ߡߪ㧘Ᏹߦ߈ⵚవ┵ߩߔߴࠅᏪߩㄭ
றߦ᳓⚛ࠟࠬ߇ሽ࿷ߒ㧘ᰴ‫ࠆߔ↢⺀ߣޘ‬ᣂ↢㕙ࠍㅢߞߡ᳓⚛߇᧚ᢱౝㇱߦଚ౉ߒ㧘᳓⚛ߦࠃࠆߔߴࠅߩ
ᵴᕈൻ(ዪᚲᄌᒻഥ㐳)߇⿠ߎࠆ߽ߩߣ⠨߃ࠄࠇࠆ㧚ߎࠇߦኻߒߡ㧘࿑(b)ߦ␜ߔࠃ߁ߦ㧘᧚ᢱਛߩォ૏߿ᩰሶ㑆ߦ੍߼ሽ࿷ߒߡ޿ࠆౝㇱ᳓⚛ߪᔕജ⺃⿠᜛ᢔߦࠃߞߡ߈ⵚవ┵ߩ႟ᕈၞߦ㓸߹ߞߡߊࠆ㧚10-2
Hz < f < 1 Hz ߦ߅޿ߡߪ㧘᧚ᢱਛߦሽ࿷ߔࠆ᳓⚛ߪ߈ⵚవ┵ߩߔߴࠅᏪߦ೔⌕ߔࠆߩߦᤨ㑆߇߆߆ࠆߚ߼㧘᳓⚛߇߈ⵚవ┵ߩߔߴࠅᏪߦ೔⌕ߔࠆ೨ߦ㧘∋ഭ߈ⵚ߇ㅴዷߒߡߒ߹߁ߣ⠨߃ࠆߎߣ߇ߢ߈ࠆ㧚ߎࠇࠄߪ SM490B ㍑ߣ SGP ㍑ߩ⇣ߥࠆ὇⚛㍑ߢᓧ
ࠄࠇߚ⚿ᨐߢ޽ࠆߩߢ㧘ߐࠄߦ⏕⹺ߩᔅⷐ߇޽ࠆ߇㧘ߎߩࠃ߁ߥ᳓⚛ߩ᜛ᢔࡔࠞ࠾࠭ࡓߩ⋧㆑ߦࠃߞߡ㧘ౝㇱ᳓⚛ߦࠃࠆടㅦߩ਄㒢୯߇ᓧࠄࠇࠆ⹜㛎๟ᵄ
ᢙߪ 10-2 Hz ⒟ᐲߢ޽ࠅ㧘ᄖㇱ᳓⚛ߢߪ 1 Hz ⒟ᐲߢ
޽ࠆߎߣߪ߶߷㑆㆑޿ߩߥ޿ߣ⠨߃ࠆ㧚In hydrogen at room temperature
Frequency [Hz]Pressure [MPa]
0.1

0.4

0.7

0.1
1
5

In air at room temperature+: R = 0.1, f = 5 Hz

Crack growth direction

࿑ 23 SM490B ㍑ߩ᳓⚛ࠟࠬਛߩ∋ഭ߈ⵚㅴዷ
ടㅦߣ⹜㛎๟ᵄᢙߩ㑐ଥ

10μm

࿑ 24 SM490B ㍑ߩ᳓⚛ࠟࠬਛߩࠬ࠻࡜ࠗࠛ࡯ࠪ
࡚ࡦ㧚f = 0.1 Hz , ΔK = 32 MPa࡮m1/2㧚
⚛ߣ๭߱㧚
࿑ 23 ߦ㧘᳓⚛ࠟࠬਛߢᓧߚṁធ᭴ㅧ↪὇⚛㍑
SM49B ߩ∋ഭ߈ⵚㅴዷㅦᐲ(da/dN)H2/(da/dN)air ࠍ⹜㛎๟ᵄᢙ f ߦኻߒߡ␜ߔ[35]㧚(da/dN)H2 ߪ᳓⚛ࠟࠬਛߩ߈ⵚㅴዷㅦᐲ㧘(da/dN)air ߪᄢ᳇ਛߩ߈ⵚㅴዷㅦ
ᐲߢ޽ࠆ㧚᳓⚛ࠟࠬ࿶ജ p = 0.1㧘0.4㧘0.7 MPa㧔⛘ኻ࿶㧕㧘ΔK = 24㨪31MPa࡮m1/2 ߩ⚿ᨐ߇฽߹ࠇߡ޿
ࠆ㧚SM490B ߩ⚵❱ߪࡈࠚ࡜ࠗ࠻࡮ࡄ࡯࡜ࠗ࠻㧘ᒁᒛᒝᐲߪ 530 MPa ߢ޽ࠆ㧚SGP ㍑ߩ⚵❱ߪࡈࠚ࡜ࠗ
࠻࡮ࡄ࡯࡜ࠗ࠻㧘ᒁᒛᒝᐲߪ 416 MPa ߢ޽ࠆ㧚ߒߚ
߇ߞߡ㧘SM490 ߣ SGP ߪห╬ߩ὇⚛㍑ߣ⷗ߥߔߎ
ߣ߇ߢ߈ࠆ㧚
࿑ 23 ߦ␜ߔࠃ߁ߦ㧘᳓⚛ࠟࠬਛߢᓧࠄࠇߚ
SM490B ߩ∋ഭ߈ⵚㅴዷㅦᐲߪ f = 5 Hz ߢߪዋߒૐ
޿߇㧘f = 0.1 ߣ 1 Hz ߢߪ߶߷╬ߒ޿㧚ߔߥࠊߜ㧘ᄖㇱ᳓⚛ߦࠃࠆ∋ഭ߈ⵚㅴዷടㅦߩ਄㒢୯ߪ f ҇ 1

વᾲ 2009 ᐕ 4 ᦬ӆ㧚߅ࠊࠅߦ
᳓⚛ߪ㧘ࡏࠗ࠼ࠍ⩄㊀ゲߦኻߒߡု⋥ᣇะߦᚑ- 17 -J. HTSJ, Vol. 48, No. 203

․㓸㧦᳓⚛ߩ‛ᕈ߅ࠃ߮᧚ᢱ
[2] ᧻ጊ᤯૞㧘ㆃࠇ⎕უ㧘
㧔1989㧕
㧘ᣣೀᎿᬺᣂ⡞[3] M. Nagumo, Materia Japan 33 (1994) 914-921.
[4] F. Terasaki and N. Takano, Materia Japan 33(1994) 922-931.
[5] T. Kushida and T. Kudo, Materia Japan 33 (1994)
932-939.

㐳ߐߖߚࠅ㧘∋ഭ߈ⵚㅴዷࠍ⚂ 10 ୚ടㅦߐߖߚࠅ
ߔࠆ㧚ߎߩࠃ߁ߥ᜼േࠍ⺑᣿ߔࠆࠠ࡯ࡐࠗࡦ࠻ߪ
ੑߟ޽ࠅ㧘৻ߟߪ᳓⚛߇ࡏࠗ࠼✼߿߈ⵚవ┵ߦ㓸ਛߔࠆߎߣ㧘߽߁৻ߟߪ㓸ਛߒߚ᳓⚛߇ࡏࠗ࠼✼߿߈ⵚవ┵ߢߩߔߴࠅࠍዪ࿷ൻߔࠆߎߣߢ޽ࠆ㧚ߎߩࠃ߁ߥ⠨߃ߪ㧘ᩰሶ⣀ൻ⺑㧔⣀ᕈ⎕უ㧕ߢߥߊ㧘ዪᚲᄌᒻഥ㐳⺑㧔ᑧᕈ⎕უ㧕ߣ৻⥌ߔࠆ⠨߃ߢ޽ࠆ㧚
HYDROGENIUS ߢߪ㧘ᓧࠄࠇߚၮ␆⎇ⓥᚑᨐࠍ
ታ↪ൻ⎇ⓥߦᵴ߆ߔขࠅ⚵ߺ߽ⴕߞߡ޿ࠆ㧚⴫ 1ߦߘߩขࠅ⚵ߺࠍ߹ߣ߼ߡ޿ࠆ߇㧘ታ⸽⹜㛎ߦ↪
޿ࠄࠇߚ⫾࿶ེ߿ゞタ࠲ࡦࠢߥߤߩஜోᕈ⹏ଔࠍ
JHFC ߿᳃㑆ડᬺߩ⎇ⓥ⠪ߣ৻✜ߦⴕߞߡ޿ࠆ㧚ੑઙߩ⫾࿶ེߦ㑐ߔࠆ⺞ᩏႎ๔ᦠ߇ߔߢߦ౏㐿ߐࠇߡ޿ࠆ[36,37]㧚㔰ࡩ㑐ࠬ࠹࡯࡚ࠪࡦ⫾࿶ེߩ⺞ᩏႎ๔ᦠߪ Web ਄ߦ౏㐿ߐࠇߡ޿ࠆ[36]㧚ߎࠇࠄߩႎ๔ᦠߪ㧘HYDROGENIUS ߢᓧࠄࠇߚᦨᣂߩ⎇ⓥᚑᨐߩᵴ↪ᣇᴺਗ߮ߦ⵾ㅧ㧘㐿⊒㧘ຠ⾰଻⸽ߦᓎ┙ߟᖱႎࠍ฽߼ߡ޿ࠆ㧚[6] A.R.Troiano, Transactions of the ASM 52(1960)
54-81㧚
[7] C.D.Beachem, Metallurgical Transactions 3(1972) 437-451㧚
[8] H. K. Birnbaum and P. Sofronis, Mater. Sci. Eng.
A176(1994) p.191[9] ᳓⚛቟ో೑↪╬ၮ⋚ᛛⴚ㐿⊒ ᳓⚛ߦ㑐ߔࠆ౒ㅢၮ⋚ᛛⴚ㐿⊒ ᳓⚛↪᧚ᢱၮ␆‛ᕈߩ⎇ⓥ(ᐔᚑ 16 ᐕᐲᚑᨐႎ๔ᦠ), ᣂࠛࡀ࡞ࠡ࡯࡮
↥ᬺᛛⴚ✚ว㐿⊒ᯏ᭴㧘ઍ⴫ᆔ⸤వ 㧔⽷㧕㊄ዻ♽᧚ᢱ㐿⊒ᯏ᭴[10] ᧻ጟਃ㇢㧘ᧄ㑆⚩ᶈ㧘↰ਛ⵨਽㧘⑔ፉ⦟ඳ㧘᧛਄ᢘቱ㧘900MPa ⚖ૐว㊄㍑ SCM435 ߩᒁᒛ․ᕈߦ෸߷ߔ᳓⚛ߩᓇ㗀㧘ᣣᧄ㊄ዻቇળ⹹㧘70-12 (2006) 1002-1011

⴫ 1 HYDROGENIUS ߦ߅ߌࠆஜోᕈ⹏ଔ

[11] ፃ ᵗੑ㧘ᬰፒජ዆㧘㊄ፒବᒾ㧘᧻ጟਃ㇢㧘᧛਄ᢘቱ㧘㜞࿶᳓⚛ࠟࠬ㔓࿐᳇ߦᦑ㔺ߒߚࠝ࡯ࠬ࠹࠽ࠗ࠻♽ࠬ࠹ࡦ࡟ࠬ㍑ߩ∋ഭ߈ⵚㅴዷ
᜼േߣ᳓⚛ଚ౉․ᕈ㧘㋕ߣ㍑㧘93-3 (2007)247-256[12] Safety Standard for Hydrogen and Hydrogen
Systems, NASA NSS 1740.16[13] W. T. Candler and R. J. Walter: Hydrogen
Embrittlement Testing, ed. L. Raymontd, ASTM
STP543 (1974) pp.198-220[14] R. J. Walter and W. T. Chandler: Effect ofHigh-Pressure Hydrogen on Metals, The 1968
Materials Engineering Exposition & Congress,
American Society for Metals, 1968
[15] W. T. Chandler and R. J. Walter: Hydrogen-Environment Embrittlement of Metals and its
Control, Proceedings of the Hydrogen Miami
Energy Conference, ed. T. H. Veziroglu, Plemum
Press, New York, 1975, pp.1057-1078)[16] K. Takai and Ryu Watanuki: ISIJ International,
43(2003), pp.520-526Άᢱ㔚ᳰ⥄േゞߩㇱຠ(ࡄࠗࡊ㧘ࡃ࡞ࡉ㧘࡜ࠗ࠽࡯ߥߤ)ߦߪ㧘᳓⚛⣀ൻߦኻߒߡఝࠇߚ․ᕈࠍ␜ߔ
ࠝ࡯ࠬ࠹࠽ࠗ࠻♽ࠬ࠹ࡦ࡟ࠬ㍑ SUS316L ߣࠕ࡞ࡒว㊄ 6061-T6 ߩ૶↪߇⹺߼ࠄࠇߡ޿ࠆ[38]㧚ߒ߆ߒ㧘Άᢱ㔚⥄േゞߥߤߩ᳓⚛ࠛࡀ࡞ࠡ࡯ࠪࠬ࠹ࡓ߿᳓
⚛ࠛࡀ࡞ࠡ࡯ࠗࡦࡈ࡜ߩታ↪ൻߦะߌߡߪ㧘
SUS316L ߪ㜞ࠦࠬ࠻ߢ޽ࠆߚ߼㧘὇⚛㍑ߩࠃ߁ߥૐࠦࠬ࠻᧚ᢱߩ૶↪ߩน⢻ᕈ߇ᦼᓙߐࠇߡ޿ࠆ㧚ᧄ⸃⺑ߢ⚫੺ߒߚ὇⚛㍑ SGP ߿ SM490B ߩ⎇ⓥᚑᨐߪ㧘ߎߩࠃ߁ߥᦼᓙߦኻߒߡ⽸₂ߢ߈ࠆᚑᨐߢ
޽ࠆߣ⠨߃ߡ޿ࠆ㧚[17] ᧻የ ዏ㧘ᧄ㑆⚩ᶈ㧘᧻ጟਃ㇢㧘᧛਄ᢘቱ㧘
0.1 MPa ᳓⚛ࠟࠬࡄࠗࡊ࡜ࠗࡦ↪὇⚛㍑ SGPෳ⠨ᢥ₂
[1] JHFC ࡎ࡯ࡓࡍ࡯ࠫ㧔http://www.jhfc.jp/㧕વᾲ 2009 ᐕ 4 ᦬- 18 -J. HTSJ, Vol. 48, No. 203

․㓸㧦᳓⚛ߩ‛ᕈ߅ࠃ߮᧚ᢱ
(0.078C-0.012Si-0.45Mn, mass%)ߩᒁᒛ․ᕈߦ
෸߷ߔ᳓⚛ߩᓇ㗀㧘ᣣᧄᯏ᪾ቇળ⺰ᢥ㓸 A㧘
74-744 (2008) 1164-1173[18] ⷏ญᑝᔒ㧘⑔ፉ⦟ඳ㧘᧻ጟਃ㇢㧘᧛਄ᢘቱ㧘
1MPa ᳓ ⚛ ࠟ ࠬ ࡄ ࠗ ࡊ ࡜ ࠗ ࡦ ↪ ὇ ⚛ ㍑
STPG370 (0.19C-0.21Si-o.56Mn, mass%)ߩᒁᒛ
․ᕈߦ෸߷ߔ᳓⚛ߩᓇ㗀㧘ᣣᧄᯏ᪾ቇળ⺰ᢥ㓸 A㧘74-743 (2008) 1016-1025[19] ᧻የዏ㧘ጊㄝ⚐৻㇢㧘᧻ጟਃ㇢㧘᧛਄ᢘቱ㧘ࠝ࡯ࠬ࠹࠽ࠗ࠻♽ࠬ࠹ࡦ࡟ࠬ㍑ SUS316L ߩᒁᒛ․ᕈߦ෸߷ߔ᳓⚛ߣ੍߭ߕߺߩᓇ㗀㧘ᣣᧄᯏ ᪾ ቇ ળ ਻ Ꮊ ᡰ ㇱ ⻠ Ṷ ⺰ ᢥ 㓸 㧘 No.098-1
㧔2009㧕 1-2㧚[20] P.Smith et al., Metal Science, 13 (1979-7) 429-435[21] S. Suresh, CF. Zamiski and RO. Ritchie,
Metallurgical Transaction, 12A (1981) 1435-1443[22] ศጟ⚐ᄦ㧘಴᳓ㅢਯഥ㧘ᾢᴛ㆏ᄦ㧘᳓⚛㔓࿐᳇ਛߩ∋ഭ߈ⵚㅴዷ᜼േ㧘᧚ᢱ㧘32-355 (ᤘ๺58) 435-440[23] ⑔ጊ⺈ม㧘ᮮጊᷡᔒ㧘⨹ᧁ㆏㇢㧘SNCM439 ㍑
ߩቶ᷷㜞࿶᳓⚛ⅣႺਅߦ߅ߌࠆ∋ഭ߈ⵚㅴዷ㧘᧚ᢱ㧘34-331 (ᤘ๺ 60 ᐕ) 709-714[24] ⑔ጊ⺈ม㧘ᮮጊᷡᔒ㧘⨹ᧁ㆏㇢㧘SUS304 ㍑ߩ
ቶ᷷㜞࿶᳓⚛ⅣႺਅߦ߅ߌࠆ⎕უߓࠎᕈߣ∋ഭ߈ⵚㅴዷ㧘᧚ᢱ㧘36-404 (ᤘ๺ 62 ᐕ) 506-512[25] ⑔ጊ⺈ม㧘ᮮጊᷡᔒ㧘⨹ᧁ㆏㇢㧘ዊ㐕ᐘ㓶㧘㕍ᧁ ብ㧘ጊ↰⦟㓶㧘Ni ၮว㊄ߩቶ᷷㜞࿶᳓
⚛ⅣႺਅߦ߅ߌࠆ∋ഭ߈ⵚㅴዷ㧘᧚ᢱ㧘38-428(ᐔᚑరᐕ) 539-545[26] ⑔ጊ⺈ม㧘㖧 ೰㧘૗ ᑪብ㧘ᮮᎹᷡᔒ㧘὇
⚛㍑ߩ߈ⵚㅴዷߦ෸߷ߔ㜞࿶᳓⚛ⅣႺߩᓇ㗀㧘᧚ᢱ㧘46-6 (1997) 607-612[27] Kanezaki, T., Narazaki, C., Mine, Y., Matsuoka, S.
and Murakami, Y., Effect of Hydrogen on Fatigue
Crack Growth and Martensitic Transformation of
Stainless Steels, Transactions of the Japan Societyof Mechanical Engineers, Series A, 72-723 (2006)
1717-1724.
[28] Uyama, H., Mine, Y. and Murakami, Y., Effects ofTest Frequency on Fatigue Behaviour in a
Tempered Martensitic Steel with Hydrogen
Charge, Journal of the Society of Materials
Science, Japan, 55-8 (2006) 726-731.

વᾲ 2009 ᐕ 4 ᦬- 19 -[29] Tanaka, H., Homma, N., Matsuoka, S. and
Murakami, Y., Effect of Hydrogen and Frequency
on Low-Cycle Fatigue Behaviour of SCM435
Steel for Storage Cylinder of Hydrogen Station,
Transactions of the Jap an Society of MechanicalEngineers, Series A, 73-726 (2007) 1358-1365[30] Murakami, Y, Kanezaki, T, Mine, Y. andMatsuoka,S.,
HydrogenEmbrittlement
Mechanism in Fatigue of Austenitic StainlessSteels, to be published in Metallurgical andMaterials Transaction, A, 19A (2008) 1327-1339[31] Matsuoka, S., Tsutsumi, N and Murakami, Y.,
Effect of Hydrogen on Fatigue Crack Growth andStretch Zone of 0.08 mass% Low Carbon Steel
Pipe, Transactions of the Jap an Society of
Mechanical Engineers, Series A, 74-748 (2008)
1528-1537[32] E. Takeuchi, M. Hayakawa, N. Nagashima and S.
Matsuoka, CAMP-ISIJ, Vol.21(2008) 1398
[33] Bichler, C. H. and Pippan, R., Direct observationof the formation of striations, Engineering Against
Fatigue, (1999).211-218.
[34] Nakamura, H., Kobayashi, H. and Nakazawa, H.,
Estimation of Stretch Zone Width by J Integraland Application into Elastic-plastic Fracture
Toughness Test (Japanese) , Transactions of theJapan Society of Mechanical Engineers, Series A, .
45 (1979) 336-345.
[35] ศᎹ୶ᄦ㧘ႇ ♿ሶ㧘᧻ጟਃ㇢㧘᧛਄ᢘቱ㧘᳓⚛ࠟࠬਛߦ߅ߌࠆࡈࠚ࡜ࠗ࠻࡮ࡄ࡯࡜ࠗ࠻
㍑[36] 㔰ࡩ㑐᳓⚛ࠬ࠹࡯࡚ࠪࡦ⫾࿶ེ⺞ᩏႎ๔ᦠ㧘↥ᬺᛛⴚ✚ว⎇ⓥᚲ㧘਻Ꮊᄢቇ㧘⍹ᴤ↥ᬺᵴᕈൻ࠮ࡦ࠲࡯㧘㧔ᐔᚑ 20 ᐕ 11 ᦬㧕
[37] ᳓⚛ャㅍ↪ 20MPa ᄢဳ㐳ዤ⫾࿶ེ㧔ᤘ๺ 50
ᐕ⵾ㅧ㧕⺞ᩏႎ๔ᦠ㧘↥ᬺᛛⴚ✚ว⎇ⓥᚲ㧘਻Ꮊᄢቇ㧘ᣂࠛࡀ࡞ࠡ࡯࡮↥ᬺᛛⴚ✚ว㐿⊒ᯏ᭴㧘㧔ᐔᚑ 21 ᐕ 2 ᦬㧕[38] (⽷)ᣣᧄ⥄േゞ⎇ⓥᚲ,JARI S 001(2005)⻢ㄉᧄ⸃⺑ߢ૶↪ߐࠇߡ޿ࠆ HYDROGENIUS ߩᚑᨐߩ৻ㇱߪ NEDO ᛛⴚ㐿⊒ᯏ᭴ߩ᳓⚛᧚ᢱవ┵⑼ቇၮ␆⎇ⓥ੐ᬺߩ৻Ⅳߣߒߡⴕߞߚ߽ߩߢ޽ࠆ㧚

J. HTSJ, Vol. 48, No. 203

․㓸㧦᳓⚛ߩ‛ᕈ߅ࠃ߮᧚ᢱ

᳓⚛ߩ⾂⬿ャㅍߣ᳓⚛⾂⬿᧚ᢱHydrogen Storage and Transportation: Hydrogen Storage Materials⑺⪲ ᖝ↵㧔↥ᬺᛛⴚ✚ว⎇ⓥᚲ㧕
Etsuo AKIBA (AIST)
e-mail: etsuo-akiba@ni.aist.go.jpߪߓ߼ߦ
᳓⚛ߪ᭽‫⾗࡯ࠡ࡞ࡀࠛߥޘ‬Ḯ㧘ߔߥࠊߜ৻ᰴࠛ
ࡀ࡞ࠡ࡯߆ࠄ⵾ㅧߔࠆߎߣ߇ߢ߈ࠆߚ߼㧘ࠛࡀ࡞ࠡ࡯ᇦ૕㧔ੑᰴࠛࡀ࡞ࠡ࡯㧕ߣߒߡᵈ⋡ࠍ㓸߼ߡ޿ࠆ㧚߹ߚ㧘ൻ⍹Άᢱ߆ࠄౣ↢น⢻ࠛࡀ࡞ࠡ࡯ߩ
ᵴ↪߳ߣ৻ᰴࠛࡀ࡞ࠡ࡯߇ᄌൻߒߡ޿ߊਛߢ㧘ࠛࡀ࡞ࠡ࡯ࠍ᦭ലߦ೑↪ߔࠆߚ߼ߦౣ↢น⢻ࠛࡀ࡞ࠡ࡯߆ࠄᄙߊߩ႐ว↢ߺ಴ߐࠇࠆ㔚ജߣ㔚᳇ಽ⸃ⵝ⟎߅ࠃ߮Άᢱ㔚ᳰߩࠃ߁ߥᣢሽߩᛛⴚߢല₸⦟ߊ⋧੕ߦᄌ឵ߢ߈ࠆ᳓⚛ߪ㧘ࠛࡀ࡞ࠡ࡯ࠪࠬ࠹ࡓ
ࠍᚑ┙ߐߖࠆ਄ߢᄢᄌߦ㝯ജ⊛ߢ޽ࠆ㧚ߒ߆ߒߥ߇ࠄ㧘᳓⚛ߪᏱ᷷ߢߪ᳇૕ߢ޽ࠆߚ߼㧘ᣢሽߩᶧ૕ΆᢱߣᲧߴߡ૕Ⓧࠛࡀ࡞ࠡ࡯ല₸ߪᩰᲑߦૐ޿㧚଀߃߫㧘⥄േゞΆᢱߣߒߡᦨ߽ࡐࡇࡘ
࡜࡯ߥࠟ࠰࡝ࡦߣᲧߴࠆߣ㧘ᮡḰ⁁ᘒ㧔ቶ᷷㧘৻᳇࿶㧕ߩ᳓⚛ߪਃජಽߩ৻ߩ૕Ⓧࠛࡀ࡞ࠡ࡯ኒᐲ
ߒ߆᦭ߒߥ޿㧚ߘߩߚ߼㧘ൻ⍹Άᢱߣห╬ߩ૕Ⓧࠛࡀ࡞ࠡ࡯ኒᐲࠍ⏕଻ߔࠆߎߣ߇น⢻ߥ᳓⚛⥄േゞ߳ߩ᳓⚛៞タᛛⴚߩ⏕┙߇᳞߼ࠄࠇߡ޿ࠆ㧚ౕ૕⊛ߥേ߈ߣߒߡߪ㧘2008 ᐕ 7 ᦬ߦΆᢱ㔚ᳰታ↪ൻផㅴද⼏ળ߆ࠄ౏⴫ߐࠇߚ㧘࿖ౝᄖߩਥⷐ
ߥ⥄േゞࡔ࡯ࠞ࡯߿࿖ౝߩࠛࡀ࡞ࠡ࡯ડᬺ߇߹ߣ
߼ߚΆᢱ㔚ᳰ⥄േゞߣ᳓⚛ࠬ࠹࡯࡚ࠪࡦߩ᥉෸߳
ߩࠪ࠽࡝ࠝߢߪ㧘2015 ᐕߦ᳓⚛ࠬ࠹࡯࡚ࠪࡦࠍ߿
߿వⴕߒߡ੐ᬺൻߒ㧘ߘࠇߦㆃࠇߡΆᢱ㔚ᳰ⥄േゞߩᧄᩰ⊛↢↥߇㐿ᆎߐࠇࠆߣߒߡ޿ࠆ[1]㧚߹ߚ㧘
2008 ᐕ 12 ᦬ߦߪ↥ᬺ┹੎ജᙣ⺣ળ㧔COCN㧕߇ࠃࠅ⹦⚦ߥ 2015 ᐕએ㒠ߩࠪ࠽࡝ࠝࠍឭ⸒ߒߡ޿
ࠆ[2]㧚
ߎߎߢߪ㧘ߎߩࠃ߁ߥⅣႺߩ߽ߣ㧘Άᢱ㔚ᳰ⥄േゞߣ᳓⚛ࠬ࠹࡯࡚ࠪࡦߩ੐ᬺൻߩ࠲࡯ࠥ࠶࠻ߣ
ߐࠇࠆ 2015 ᐕ߅ࠃ߮ߘࠇએ㒠ߩᢙᐕ㨪චᐕߩ㑆ߦታ⃻น⢻ᕈ߇㜞޿ߣߐࠇࠆ᳓⚛៞タᛛⴚࠍ⚫੺ߔࠆߣ౒ߦ㧘ᰴ਎ઍߩ᳓⚛៞タᴺߣߒߡᵈ⋡ߐࠇࠆ᳓⚛⾂⬿᧚ᢱߦߟ޿ߡ⚫੺ߔࠆ㧚

વᾲ 2009 ᐕ 4 ᦬- 20 -

᳓⚛⾂⬿ᛛⴚ ᳓⚛ߩ‛ᕈߣャㅍ⾂⬿ߩ⋡ᮡ୯ ᳓⚛ߩ‛ᕈ୯ߩౝ㧘ャㅍ࡮⾂⬿ߦ㑐ଥߩᷓ޿߽
ߩࠍ⴫ 1 ߦ␜ߒߚ㧚᳓⚛ߩ߽ߟΆ὾ᾲߪ 1m3 ᒰߚࠅ⚂ 12MJ ߢ޽ࠅ㧘೨ㅀߩࠃ߁ߦࠟ࠰࡝ࡦߣᲧセߒߡਃජಽߩ৻ߒ߆ߥ޿㧚ߘߩ৻ᣇߢ㧘᳇૕ߩ᳓⚛ߩኒᐲߪ⚂ 0.084 kg/m3 ߢ޽ࠆ߆ࠄ㧘᳓⚛ 1kg ᒰߚࠅ⊒ᾲ㊂ߪ 142 MJ ߦ㆐ߒ㧘ࠟ࠰࡝ࡦߩਃ୚ㄭ
޿㧚᳇૕⁁ߩΆᢱߢ޽ࠆᄤὼࠟࠬ㧘ᶧ૕⁁ߩΆᢱߢ޽ࠆࠟ࠰࡝ࡦߣߩ૕Ⓧ߅ࠃ߮㊀㊂ࠛࡀ࡞ࠡ࡯ኒᐲߣߩᲧセࠍ⴫ 2 ߦ␜ߒߚ㧚⥄േゞߢߪߘߩࠨࠗ
࠭ߦ೙㒢߇޽ࠅ㧘น⢻ߥ㒢ࠅᄙߊߩⓨ㑆ࠍਸ਼ຬߩ
ዬ૑ߣ⽻‛ߩ෼ኈߦ૶߁ᔅⷐ߇޽ࠆߎߣ߆ࠄ㧘㊀㊂ኒᐲࠃࠅ߽᳓⚛ࠍዋߥ޿૕Ⓧߢࠦࡦࡄࠢ࠻ߦ៞タߔࠆߎߣ߇ࠃࠅ৻ጀ㧘㊀ⷐߣߐࠇߡ޿ࠆ㧚⴫ 1 ᳓⚛ߩ‛ᕈ୯
ಽሶ㊂

2.016

ᴣὐ

-252.8͠Ⲣὐ

-259.1͠Ყ㊀㧔ⓨ᳇ࠍ 1 ߣߒߡ㧕

0.0695⥃⇇࿶ജ

12.759 atm⥃⇇᷷ᐲ-259.9͠ᴣὐߦ߅ߌࠆᶧ૕᳓⚛ߩኒᐲ᳇૕᳇૕ߩኒᐲ㧔20͠,1 atm㧕70.8kg/m3
0.083764 kg/m3

ᾲવዉᐲ㧔20͠,1 atm㧕1.897m W/cm㨯K⫳⊒ᾲ

445.59 kJ/kgΆ὾ᾲ㧔HHV㧕

141.86 MJ/kgⓨ᳇ਛߩ᜛ᢔଥᢙ

0.634 cm2/s

⴫ 2 ૕Ⓧ߅ࠃ߮㊀㊂ᒰߚࠅߩΆ὾ᾲ㧔HHV㧕
MJ/m3

MJ/kg

᳓⚛ࠟࠬ

11.9

142

ᄤὼࠟࠬ

39

54.5

ᶧൻ᳓⚛

10,070142ࠟ࠰࡝ࡦ

34,60049

J. HTSJ, Vol. 48, No. 203

․㓸㧦᳓⚛ߩ‛ᕈ߅ࠃ߮᧚ᢱ ⃻࿷㧘Άᢱ㔚ᳰ⥄േゞߩΆ⾌ߪ 1kg㧔⚂ 12m3㧕
ߩ᳓⚛ᒰߚࠅ⚂ 100km ⒟ᐲߢ޽ࠆ[3]㧚ߒߚ߇ߞߡ㧘ࠟ࠰࡝ࡦゞਗߩ⥶⛯〒㔌 500km ࠍታ⃻ߔࠆߚ߼ߦ 5kg㧔⚂ 60 m3㧕ߩ᳓⚛ࠍน⢻ߥ㒢ࠅࠦࡦࡄࠢ࠻㧘シ㊂߆ߟ቟ోߦ቟ଔߦ៞タߔࠆᛛⴚߩታ⃻߇᳓⚛
␠ળታ⃻ߦᔅⷐਇนᰳߣߐࠇࠆ㧚ࠟ࠰࡝ࡦゞߣߩᲧセߢ 100L ߅ࠃ߮ 100kg ߩ૕ᩰ߅ࠃ߮㊀㊂߇⃻ᤨὐߢߩゞタ↪᳓⚛࠲ࡦࠢߩ⋡ᮡ୯ߣߐࠇߡ޿ࠆ㧚ߔߥࠊߜ㧘૕Ⓧ߅ࠃ߮㊀㊂᳓⚛ኒᐲߢ㧘0.05 kg/L
߅ࠃ߮ 5 ⾰㊂㧑߇᳓⚛៞タࠪࠬ࠹ࡓߣߒߡߩ⋡ᮡߣߥࠆ㧚૕Ⓧߣߒߡߪ㧘ᮡḰ⁁ᘒ㧔1 ᳇࿶㧘ቶ᷷㧕ߢ 60m3㧔60 kL㧕ߩ᳓⚛ࠍ౐⊖ಽߩ৻ߦ⋧ᒰߔࠆ
100 L ߦ߹ߢ❗ዊߔࠆߎߣ߇᳞߼ࠄࠇߡ޿ࠆ㧚 ⴫ 3 ߦߪታ㓙ߦ⥄േゞߦ៞タߐࠇ㧘ߘߩน⢻ᕈ߇ታ⸽ߐࠇߚ࿶❗ࠟࠬ㧘ᶧൻ᳓⚛߅ࠃ߮᳓⚛⾂⬿᧚ᢱߩࠛࡀ࡞ࠡ࡯ኒᐲߥߤࠍ␜ߒߚ㧚⴫ 3 ᳓⚛⾂⬿ャㅍᇦ૕ਛߩ᳓⚛ኒᐲ᳓⚛ࠟࠬ
(300K, 1 atm)᳓⚛ࠟࠬ
350 MPaᶧൻ᳓⚛
(20 K)
᳓⚛ๆ⬿ว㊄LaNi5H6

૕Ⓧኒᐲ
(g /L)

㊀㊂ኒᐲ
(⾰㊂%)

0.09

100

24

100

71

100

105

1.4

 ࿶❗ࠟࠬ߅ࠃ߮ᶧൻ᳓⚛ߦࠃࠆ᳓⚛ャㅍ⾂⬿ ⴫ 4 ߦ᳓⚛ߩ࿶❗࿃ሶࠍ␜ߒߚ㧚৻⥸ߦታ࿷᳇૕ߩ࿶ജ㧘᷷ᐲ߅ࠃ߮ኈⓍߦߪᑼߩࠃ߁ߥ㑐ଥ߇޽ࠆ㧚z㧩pV/RT(1)
࿶ജࠍ p㧘⛘ኻ᷷ᐲࠍ T㧘᳇૕ 1 mol ߩ૕Ⓧࠍ V㧘᳇૕Ᏹᢙࠍ R ߢ⴫ߔ㧚ᑼਛߩ z ߪ࿶❗࿃ሶ㧔࿶❗
ଥᢙߣ߽޿߁㧕ߢ޽ࠆ㧚
⴫ 4 ᳓⚛ߩ࿶❗࿃ሶ࿶ജ/MPa0.1013

10

35

70

1

1.065

1.236

1.489

࿶❗࿃ሶ

 ࿶❗࿃ሶߪታ࿷᳇૕ߩℂᗐ᳇૕߆ࠄߩ஍Ꮕࠍ޽
ࠄࠊߔ߽ߩߢ㧘ℂᗐ᳇૕ߢߪ z㧩1 ߢ޽ࠆ㧚᳇૕ߩ࿶ജࠍ㜞߼ࠆߣ㧘ኈེౝߦሽ࿷ߔࠆ᳇૕ಽሶߩ૕
Ⓧ߇භ߼ࠆಽߛߌ㧘ߘࠇએ਄ᵈ౉ߐࠇࠆ᳇૕߇භ
߼ࠆߎߣߩߢ߈ࠆౝኈⓍ߇ᷫዋߔࠆ㧚ߘߩ৻ᣇߢ㧘વᾲ 2009 ᐕ 4 ᦬- 21 -

᳇૕ಽሶ㑆ߦⷫ๺ജ߇௛޿ߡᒁ߈ߟߌ޽߁ߣ㧘᳇૕ߪⷫ๺ജ߇ή޿႐วߦᲧߴߡࠃࠅᄙߊߩ㊂㧘ኈེߦలႯߢ߈ࠆߎߣߦߥࠆ㧚ߎߩࠃ߁ߦ㧘ኈེౝߦలႯߐࠇߚ᳇૕߇ឃ㒰ߔࠆ૕Ⓧߣ᳇૕ಽሶ㑆ߩⷫ๺ജߩࡃ࡜ࡦࠬߢℂᗐ᳇૕߆ࠄߩߕࠇࠍ⺑᣿ߔࠆߎߣ߇ߢ߈ࠆ㧚৻⥸ߦ޽ࠆ࿶ജએ਄ߢߪ㧘࿶❗
₸ߪ᳇૕ߩ࿶ജߦᲧ଀ߔࠆ႐ว߇ᄙ޿㧚 ⃻࿷㧘Άᢱ㔚ᳰ⥄േゞߦߪᄙߊߩ႐ว 35 MPa޽ࠆ޿ߪዋᢙߢ޽ࠆ߇ 70 MPa ߦ࿶❗ߐࠇߚ᳓⚛
߇៞タߐࠇߡ޿ࠆ㧚500km ⿛ⴕࠍᜂ଻ߔࠆߚ߼ߦ
⃻࿷㧘ᔅⷐߢ޽ࠆߣߐࠇࠆ 5 kg ߩ᳓⚛ࠍ᳓⚛⥄േゞߦ៞タߔࠆߚ߼ߦߪ㧘࿶❗࿃ሶࠍ⠨ᘦߦ౉ࠇࠆ
ߣ࠲ࡦࠢౝኈⓍ 212 L㧔࿶ജ 35 MPa㧕޽ࠆ޿ߪ 127
L㧔࿶ജ 70 MPa㧕߇ᔅⷐߣߐࠇࠆ㧚ߎߩࠃ߁ߥ࿶
ജߦ⠴߃߆ߟシ㊂ߥኈེߦߪ㜞ଔߥ὇⚛❫⛽߇↪
޿ࠄࠇߡ߅ࠅ㧘ߘߩଔᩰߣ࡝ࠨࠗࠢ࡞ᕈߦᄢ߈ߥ
⺖㗴߇޽ࠆߣߐࠇࠆ㧚 ᶧൻ᳓⚛ࠍ↪޿ࠆߎߣߢ⴫ 3 ߦ޽ࠆࠃ߁ߦ᳓⚛
ࠟࠬߩ⚂ 800 ಽߩ 1 ߦ߹ߢ૕Ⓧࠍᷫዋߐߖࠆߎߣ
߇น⢻ߢ޽ࠆ㧚ߒ߆ߒ㧘᳓⚛ߩᴣὐߪ㧙253 ͠ߢ޽ࠆߚ߼㧘ߘߎ߹ߢ᷷ᐲࠍਅߍᶧൻߐߖࠆߚ߼ߦ᳓⚛⥄りߩᜬߟΆ὾ᾲߩ 3 ಽߩ 1 ߇ᶖ⾌ߐࠇࠆߣ⸒ࠊࠇߡ޿ࠆ㧚߹ߚ㧘৻ᣤ㧘ᶧൻ᳓⚛߇⵾ㅧߐࠇ
ߚߥࠄ߫㧘੹ᐲߪኈེო߆ࠄߩᾲଚ౉ߦࠃࠆᶧൻ
᳓⚛ߩ᳇ൻ㧔ࡏࠗ࡞ࠝࡈ㧕߇ήⷞߢ߈ߥ޿㧚ౝኈ
㊂ 80 L㧔5kg ߩ᳓⚛⋧ᒰ㧕⒟ᐲߩゞタ࠲ࡦࠢߢߪ㧘ࡏࠗ࡞ࠝࡈߪᢙ㧑㧛ᣣߣゞタ↪ߣߒߡታ↪ൻࠍߚ߼ࠄ߁߶ߤߩ㜞޿ᢙ୯ߢ޽ࠆߣߐࠇߡ޿ࠆ㧚ᄢဳൻߔࠆߎߣߢࡏࠗ࡞ࠝࡈߪૐᷫߔࠆߩߢ㧘ᶧ૕᳓⚛ߪᄢⷙᮨߦ᳓⚛ࠍ⾂⬿ߔࠆ↪ㅜߦㆡߒߡ޿ࠆ㧚㧚᳓⚛⾂⬿᧚ᢱߦࠃࠆ᳓⚛ャㅍ࡮⾂⬿᳓⚛⾂⬿᧚ᢱߣߪ ᳓⚛ࠍᄢ㊂ߦ⫾߃ࠆߎߣ߇ߢ߈ࠆ᳓⚛⾂⬿᧚ᢱߣ⸒ࠊࠇࠆ‛⾰߇޽ࠆ㧚⴫ 3 ߦ޽ࠆࠃ߁ߦ᳓⚛⾂⬿᧚ᢱߩ૕Ⓧ᳓⚛ࠛࡀ࡞ࠡ࡯ኒᐲߪ㧘࿶❗ࠟࠬ߅ࠃ߮ᶧൻ᳓⚛ࠍߒߩߋ㧚ߒ߆ߒ㧘ේℂ਄㧘㊄ዻ޽
ࠆ޿ߪว㊄㧘ήᯏ‛㧘᦭ᯏ‛╬ߦ᳓⚛ࠍ⾂⬿ߔࠆߚ߼㧘⚐☴ߥ᳓⚛ࠍ↪޿ࠆ࿶❗᳓⚛߿ᶧൻ᳓⚛ߩ႐วߦᲧߴ㊀㊂ߩⷰὐ߆ࠄߪ⋧ᒰߦਇ೑ߢ޽ࠆ㧚 ᳓⚛⾂⬿᧚ᢱߩⷐὐߪ㧘᳓⚛߇᭽‫ߥޘ‬ర⚛ߣൻቇ⊛ߦ⚿วߔࠆ੐ࠍ⾂⬿ߦ೑↪ߒߡ޿ࠆߩߢ㧘⚐☴ߥ᳓⚛ߩ႐วࠃࠅ᳓⚛ේሶ㑆ߩ〒㔌߇ࠃࠅㄭߊ
ߥࠆߎߣߦ޽ࠆ㧚ߒ߆ߒ㧘৻ᣤ㧘᧚ᢱߣ᳓⚛߇⚿J. HTSJ, Vol. 48, No. 203

․㓸㧦᳓⚛ߩ‛ᕈ߅ࠃ߮᧚ᢱ
วߔࠆߣ㧘ߘߩ⚿วࠍಾߞߡ᳓⚛ࠍ᡼಴ߐߖࠆߚ
߼ߦߪ૗ࠄ߆ߩࠛࡀ࡞ࠡ࡯߇ᔅⷐߢ޽ࠆ㧚Άᢱ㔚ᳰ⥄േゞߩ႐ว㧘៞タߒߡ޿ࠆΆᢱ㔚ᳰ߆ࠄߩឃ
ᾲߢ᳓⚛ࠍ᡼಴ߐߖࠆߎߣࠍᗐቯߒߡ޿ࠆ㧚 ᳓⚛ๆ⬿ว㊄ߦ᳞߼ࠄࠇࠆ᧦ઙ
 M + H2 = MH2 ߣ޿߁᳓⚛ൻ෻ᔕࠍ⠨߃ࠆ㧚M ߪ᳓⚛⾂⬿᧚ᢱߩ৻ߟߢ޽ࠆ᳓⚛ๆ⬿ว㊄ߢ޽ࠅ㧘MH ߪ᳓⚛ൻߐࠇߚ᳓⚛ๆ⬿ว㊄ߢ޽ࠆ㧚ߎߩ෻ᔕߩᐔⴧᏱᢙ㧔࿕૕ߩᵴ㊂ࠍ 1 ߣ઒ቯߔࠆߣ᳓⚛
ᐔⴧ࿶ജߦߥࠆ㧕ߪࠛࡦ࠲࡞ࡇ࡯ᄌൻ(ΔH°)ߣࠛࡦ
࠻ࡠࡇ࡯ᄌൻ(ΔS°)㧘᳇૕Ᏹᢙ(R)߅ࠃ᷷߮ᐲ(T)ߦ
ࠃߞߡ(2)ᑼߩࠃ߁ߦ⴫ߐࠇࠆ㧚⴫ 5 ઍ⴫⊛ߥ᳓⚛ๆ⬿ว㊄ߩ᳓⚛ๆ⬿㊂  ln PH2 = ΔH°/ RT + C        (3)ゞ਄ߦ࿕ቯߒߚ࠲ࡦࠢߦ᳓⚛ࠬ࠹࡯࡚ࠪࡦ㧔᳓⚛
ࠬ࠲ࡦ࠼㧕ߢ᳓⚛ࠍలႯߒ㧘ゞ਄ߦ៞タߐࠇߚ᳓⚛ߪΆᢱ㔚ᳰߩ૞േ᷷ᐲߢ޽ࠆ⚂ 80͠޽ࠆ޿ߪ
ߘࠇએਅߩ᷷ᐲߢᢙ᳇࿶ߩ᳓⚛᡼಴ᐔⴧ࿶ജߢ᡼
಴ߐߖࠆߚ߼ߦߪ㧘 (3)ᑼߩ㑐ଥࠍ↪޿ࠆߣ᳓⚛
ൻߩࠛࡦ࠲࡞ࡇ࡯ᄌൻߪ -25~-35 kJ/mol H2 ߩ▸࿐ߦ޽ࠆߎߣ߇ᦸ߹ࠇࠆ㧚㧔ߎߎߢߪ㧘᳓⚛ൻߩࠛࡦ࠲࡞ࡇ࡯ᄌൻࠍ↪޿㧘⽶ߩ႐วߦ᳓⚛ൻ߇᡼ᾲ㧘᳓⚛ߩ᡼಴ᤨߦๆᾲߢ޽ࠆߎߣߣߔࠆ㧚㧕 ᳓⚛ๆ⬿ว㊄ߩᱧผߣ⃻⁁ ᳓⚛ๆ⬿ว㊄߹ߚߪᦨㄭߢߪว㊄♽᳓⚛⾂⬿᧚ᢱߣ๭߫ࠇࠆ᧚ᢱߪ᳓⚛⾂⬿᧚ᢱߩਛߢߪᦨ߽ᣧ
ߊ 1967 ᐕߦߘߩ᭎ᔨ߇␜ߐࠇ[4]㧘1970 ᐕߦቶ᷷ߢ᳓⚛ࠍนㅒ⊛ߦๆ⬿᡼಴ߔࠆ LaNi5 ߇ႎ๔ߐࠇ
ߡ[5]㧘⎇ⓥߣ㐿⊒߇৻᜼ߦടㅦߐࠇߚ㧚ઍ⴫⊛ߥว㊄ߩ᳓⚛ๆ⬿㊂ߣ᳓⚛ߩ᡼಴࿶ജ㧔⸃㔌࿶ജ㧕
ࠍ⴫ 5 ߦ␜ߒߚ㧚૕Ⓧ᳓⚛ࠛࡀ࡞ࠡ࡯ኒᐲߦ㑐ߒߡߪ㧘᳓⚛ๆ⬿ว㊄ߩ߶ߣࠎߤ߇ 70㨪100kg/ m3ߩ▸࿐ߦ޽ࠆ㧚᳓⚛ๆ⬿ว㊄߇ᶧ૕᳓⚛ߩ 1㨪1.5
୚ߩ૕Ⓧኒᄌߢ᳓⚛ࠍๆ⬿ߔࠆߎߣߪࠦࡦࡄࠢ࠻
ߥ᳓⚛⾂⬿ታ⃻ߦߪᭂ߼ߡ᦭↪ߢ޽ࠆ㧚᳓⚛ๆ⬿ว㊄߇᳓⚛ࠍๆ⬿᡼಴ߔࠆᯏ᭴ࠍ࿑ 1 ߦ␜ߒߚ㧚ว㊄ࠍᒻᚑߔࠆ㊄ዻᩰሶߩ㓗㑆㧔ᩰሶ㑆૏⟎㧕ߦ᳓⚛߇ଚ౉ߒߡ᳓⚛ൻ‛߇↢ᚑߔࠆ㧚 ߘߩߚ߼㧘ଚ౉ဳ᳓⚛ൻ‛ߣ๭߫ࠇࠆߎߣ߽޽ࠆ㧚৻⥸ߦ㊄ዻේሶߩේሶඨᓘߪ 0.125ޯ0.200nm ⒟વᾲ 2009 ᐕ 4 ᦬᦭ല᳓⚛ๆ⬿㊂

H/M

⾰㊂%

H/M

⾰㊂%

MPa
(K)

LaNi5

1.0

1.4

0.8

1.1

0.37
(313)

Mg2Ni

1.33

3.6

1.1

3.1

1.15
(633)

TiMn1.5

1.0

1.9

0.7

1.3

0.7
(293)

TiMnV

1.5

2.9

1.1

2.1

0.15
(373)

ว㊄

  ln PH2 = ΔH°/ RT - ΔS°/ R      (2)ΔS° ߪ ᳇ ૕ ߩ H2 ߇ ᄬ ߞ ߚ ࠛ ࡦ ࠻ ࡠ ࡇ ࡯ (131J/mol㨯deg-1 at 298K, 1 atm) ߥߩߢ⾂⬿᧚ᢱߦࠃࠄߕቯᢙߣ߅ߌࠆ㧚ᓥߞߡ㧘᳓⚛ᐔⴧ࿶ജߣ᳓⚛
ൻߩࠛࡦ࠲࡞ࡇ࡯ᄌൻߩ㑆ߦߪᰴߩ㑐ଥ߇޽ࠆ㧚

ᐔⴧ᳓
⚛࿶ജ

ᦨᄢ᳓⚛ๆ⬿㊂

᳓⚛ๆ⬿ว㊄ ว㊄ߩ᳓⚛ൻ‛࿑ 1 ᳓⚛ๆ⬿ว㊄ߩ᳓⚛ๆ⬿᡼಴ᯏ᭴㧔᳓⚛ࠍๆ⬿ߔࠆߣ૕Ⓧ߇ 20ޯ30㧑⤘ᒛߔࠆ㧕ᐲߢ޽ࠆ㧚৻ᣇ㧘㊄ዻᩰሶਛߩ᳓⚛ߩේሶඨᓘߪ
0.035ޯ0.040nm ߢ޽ࠅ㧘㊄ዻේሶ㑆߇ᒻᚑߔࠆᩰ
ሶ㑆㓗㑆ߦ᳓⚛߇චಽߦଚ౉น⢻ߢ޽ࠆߎߣ߇ࠊ
߆ࠆ㧚ታ㓙ߪ㧘᳓⚛ൻߔࠆ੐ߦࠃࠆᩰሶో૕ߩ቟
ቯൻߣ᳓⚛߇౉ߞߡ㊄ዻᩰሶ߇⤘ᒛߔࠆߎߣߦࠃ
ࠆਇ቟ቯൻ߇ࡃ࡜ࡦࠬߔࠆߣߎࠈߢ᳓⚛ൻ‛߇↢ᚑߔࠆ㧚᳓⚛ൻߦࠃࠆᩰሶ૕Ⓧߩ⤘ᒛߪ᳓⚛ๆ⬿
ว㊄ߦ߽ࠃࠆ߇ 15ޯ30㧑ߩ▸࿐ߦ޽ࠆ㧚 ว㊄ߣߪੑ⒳㘃એ਄ߩ㊄ዻࠍᷙวߒߚ߽ߩߢ޽
ࠅ㧘࿕ṁ૕㧘౒᥏㧘㊄ዻ㑆ൻว‛߅ࠃ߮ߘࠇࠄߩ
ᷙว‛ߣߒߡሽ࿷ߔࠆ㧚⴫ 5 ߩ LaNi5 ߪ㊄ዻߦࠃࠆൻว‛ߢ޽ࠆ㊄ዻ㑆ൻว‛ߢ㧘⁜޿⚵ᚑ᏷ߢߩߺሽ࿷ߔࠆ㧚 AB2 ဳߩ᳓⚛ๆ⬿ว㊄ߪ࡜࡯ࡌࠬ
⋧ߣ๭߫ࠇࠆ㊄ዻ㑆ൻว‛ߢ㧘⚵ᚑ᏷ࠍ᦭ߔࠆߚ
߼ TiMn1.5 ߩࠃ߁ߦൻቇ㊂⺰⚵ᚑ߆ࠄᄖࠇߚ⚵ᚑߢ߽቟ቯߦሽ࿷ߔࠆ㧚AB2 ဳว㊄ߪ AB5 ဳߩᦨૐ૞േ᷷ᐲ߇-25͠⒟ᐲߢ޽ࠆߩߦᲧセߒߡࠃࠅૐ޿ߩߢ㧘಄ಓᯏ߿ૐ᷷૞േဳߩ᳓⚛⾂⬿࠲ࡦࠢߦ↪޿ࠄࠇࠆ㧚᳓⚛ๆ⬿ว㊄ߣߒߡ⍮ࠄࠇߡ޿ࠆ
᳓⚛ๆ⬿ว㊄ߩᄙߊߪⶄᢙߩ㊄ዻේሶ߇ᦨኒలႯ
ߒߡ޿ࠆ߽ߩߢ޽ࠆ㧚- 22 -J. HTSJ, Vol. 48, No. 203

․㓸㧦᳓⚛ߩ‛ᕈ߅ࠃ߮᧚ᢱ ኿႐ࠄߪ㧘Ti-V-Mn ♽㧘Ti-V-Cr ♽㧘Ti-V-Cr-Mn♽ߥߤߩ࿕ṁ૕ว㊄ਛߢ㧘૕ᔃ┙ᣇ㧔BCC㧕᭴ㅧࠍ߽ߜ㧘ߘߩਛߦ࠽ࡁࠝ࡯࠳࡯ᄌ⺞᭴ㅧࠍ᦭ߔࠆ
߽ߩ߇ᓥ᧪ߩว㊄․ߦ㊄ዻ㑆ൻว‛᳓⚛ๆ⬿ว㊄ߦᲧߴߡ᳓⚛ๆ⬿㊂߇㆝߆ߦᄙ޿ߎߣࠍ⷗಴ߒߚ
[6]㧚⪺⠪ࠄߪߎߩ⒳ߩว㊄ࠍ‫⋧ࠬߴ࡯࡜ޟ‬㑐ㅪߩ᳓⚛ๆ⬿ว㊄‫ߣޠ‬๮ฬߒߡ޿ࠆ[6]㧚ᓥ᧪㧘BCC ᭴
ㅧߩว㊄ߪ᳓⚛ൻ᜼േ߇ታ↪ߦߪะ߆ߥ޿ߣߐࠇ
ߡ޿ߚ߇㧘࡜࡯ࡌࠬ⋧߇಴⃻ߔࠆ㗔ၞߦᭂㄭ޿⚵ᚑߩ BCC ว㊄߇ᓥ᧪ߦߥ޿㜞޿᳓⚛ๆ⬿㊂ࠍቶ᷷ߢ␜ߔߎߣࠍ⊒⷗ߒߚߚ߼ߦߎߩࠃ߁ߦ๮ฬߒ
ߚ㧚
 2004 ᐕ㧘࠻࡛࠲⥄േゞߪ࿶❗᳓⚛㧔35MPa㧕ߣTi ♽࡜࡯ࡌࠬ⋧᳓⚛ๆ⬿ว㊄ࠍ⚵ߺวࠊߖ㧘㜞޿
૕Ⓧኒᐲࠍᜬߟߣหᤨߦ᳓⚛ๆ⬿ว㊄࠲ࡦࠢߩᰳ
ὐߢ޽ߞߚૐ᷷ᆎേᕈ߅ࠃ߮᳓⚛లႯㅦᐲ߇㜞࿶ࡏࡦߴਗߺߩ᳓⚛࠲ࡦࠢ㧔ࡂࠗࡉ࡝࠶࠼࠲ࡦࠢ㧕ࠍ⊒⴫ߒߚ[7]㧚⊒⴫ᤨߦ૶ࠊࠇߡ޿ߚ࡜࡯ࡌࠬ⋧ว㊄ߩ᳓⚛⾂⬿㊂ߪ 1.9 ⾰㊂㧑ߢ޽ߞߚ߇㧘ᦨㄭߢߪ㧘਄ㅀߩ࡜࡯ࡌࠬ⋧㑐ㅪ BCC ᭴ㅧว㊄ߢ 2.5
⾰㊂㧑ߩ᳓⚛⾂⬿㊂ࠍᜬߟ߽ߩࠍ೑↪ߒߡࠪࠬ࠹
ࡓߣߒߡ 2.2 ⾰㊂㧑ߩ᳓⚛⾂⬿㊂߇㆐ᚑߐࠇߡ޿
ࠆ[8]㧚࿑ 2 ߦߪ㧘ࡂࠗࡉ࡝࠶࠼࠲ࡦࠢߩᮨᑼ࿑ࠍ
␜ߒߚ[7]㧚࿑ 2 ࡂࠗࡉ࡝࠶࠼࠲ࡦࠢߩ᭎ⷐ[7]35MPa ߩ࿶ജߦ⠴߃ࠆゞ਄៞タ↪シ㊂ኈེߦߪ㧘㜞ຠ⾰ߩ὇⚛❫⛽߇ᒝᐲㇱ᧚ߣߒߡᔅⷐਇนᰳߢ
޽ࠆ㧚ߘߩߚ߼㧘ଔᩰ߇ᭂ߼ߡ㜞ߊߥࠆߎߣߣ࡝
ࠨࠗࠢ࡞߇࿎㔍ߣߩ㔍ߒ޿⺖㗴߇ߢߡ޿ߚ㧚ߘߩߚ߼㧘࠻࡛࠲⥄േゞߢߪ὇⚛❫⛽ࠍᔅⷐߣߒߥ޿
15ޯ20MPa ߩ࿶ജ㗔ၞߢࡂࠗࡉ࡝࠶࠼࠲ࡦࠢࠍ
᭴ᚑߒߡ⹜㛎ߒߚ㧚᳓⚛ๆ⬿ว㊄ߪ㊄ዻ⵾ߩࠪࠚ
࡞ࠕࡦ࠼࠴ࡘ࡯ࡉ࠲ࠗࡊߩᾲ੤឵ེߩౝㇱߦలႯߐࠇߚ㧚㊄ዻ⵾ߦߒߚߎߣߣ᳓⚛࿶ജࠍૐ࿶ൻߒ
ߚߎߣߦࠃࠆ㊀㊂Ⴧടߪ᭴ㅧ߇◲නߦߥߞߚߎߣ
ߦࠃࠆ㊀㊂シᷫߣࠠࡖࡦ࠮࡞ߐࠇ㧘35MPa ࠲ࠗࡊવᾲ 2009 ᐕ 4 ᦬- 23 -

ߩ߽ߩߣห╬ߩ૕Ⓧ߅ࠃ߮㊀㊂᳓⚛ኒᐲ߇㆐ᚑߐ
ࠇߚ[9]㧚ߎߩࠃ߁ߦ㧘ࡂࠗࡉ࡝࠶࠼࠲ࡦࠢߪ࿶❗
ࠟࠬߣᲧセߒߡ㧘᳓⚛ࠍࠦࡦࡄࠢ࠻ߦ߆ߟࠃࠅૐ
޿࿶ജߢゞ਄ߦ៞タߔࠆߎߣ߇น⢻ߥᛛⴚߢ޽ࠆ㧚⃻ᤨὐߢߪ㧘ᄙߊߩ᳓⚛⾂⬿᧚ᢱߩਛߢ㧘Άᢱ㔚ᳰ⥄േゞߩ᥉෸ೋᦼߦᵴ↪น⢻ߥ᧚ᢱߪࡂࠗࡉ࡝
࠶࠼࠲ࡦࠢߦ↪޿ࠄࠇࠆ᳓⚛ๆ⬿ว㊄ߒ߆ߥ޿ߣ
⠨߃ࠄࠇࠆ㧚
㕖㊄ዻ♽ߩ᳓⚛⾂⬿᧚ᢱ ㊄ዻࠍ᳓⚛⾂⬿᧚ᢱߣߔࠆߣ㧘㊀㊂᳓⚛ኒᐲߦ৻ቯߩ㒢⇇߇޽ࠆߎߣ߆ࠄ㧘ࠃࠅシ㊂ߥర⚛ࠍ↪
޿ߚ᧚ᢱ㐿⊒߇⋓ࠎߢ޽ࠆ㧚ߘߩ৻࿃ߦ☨࿖᡽ᐭ߇⸳ቯߒߚ᳓⚛⾂⬿᧚ᢱߩᢙ୯⋡ᮡ߇᳓⚛⾂⬿᧚ᢱ㧔㊄ዻ♽᧚ᢱ㧕ߢߪ㆐ᚑߢ߈ߥ޿ࠃ߁ߥ୯ߦ⸳
ቯߐࠇߡ޿ߚߎߣ߇޽ࠆ㧚 㕖㊄ዻ♽᧚ᢱߦߟ޿ߡߪ Edwards ࠄߦࠃࠆఝࠇ
ߚ✚⺑߇޽ࠆߩߢߘࠇࠍෳᾖ㗂߈ߚ޿[10]㧚 㕖㊄ዻ♽᧚ᢱߩਛߢ߽㧘৻⥸ߦήᯏ♽᧚ᢱߣ๭߫ࠇߡ޿ࠆ᳓⚛⾂⬿᧚ᢱߪ㧘ర⚛ߣ᳓⚛߇ਥߦ౒᦭⚿วߦࠃߞߡ⚿วߒߚൻว‛ߢ㧘ߘߩนㅒ⊛ߥಽ⸃࡮↢ᚑ෻ᔕࠍ೑↪ߒߡ᳓⚛ࠍๆ⬿᡼಴ߐߖࠆ
᧚ᢱߢ޽ࠆ㧚ήᯏ♽᧚ᢱߪ৻⥸ߦࠕ࡞ࠞ࡝࡮ࠕ࡞
ࠞ࡝࿯㘃㊄ዻ߇㔚ሶଏਈ૕ߣߒߡౖဳర⚛߳㔚ሶࠍଏਈߒߡ᳓⚛ߣߩ⚿วࠍ฽߻ᄙේሶࠗࠝࡦࠍᒻ
ᚑߒߡ޿ࠆ߽ߩ߇⃻⁁ߢߪᄢඨߢ޽ࠆ㧚 ࠕ࡜ࡀࠗ࠻(Alanate)ߪ㧘྾᳓⚛ൻࠕ࡞ࡒ࠾࠙ࡓ
ࠗࠝࡦ㧔AlH4㧙㧕ࠍ฽߻ൻว‛ߩ✚⒓ߢ޽ࠆ㧚
LiAlH4 ߪ 10.6 ⾰㊂㧑㧘NaAlH4 ߪ 7.5 ⾰㊂㧑ߩ᳓⚛
ࠍ฽߻㧚ߎࠇࠄߩࠕ࡜ࡀࠗ࠻ߪ᦭ᯏวᚑ෻ᔕߩ᳓
⚛ൻ⹜⮎ߣߒߡᢙචᐕએ਄ߩᱧผࠍ߽ߟ߇㧘นㅒ⊛ߥ᳓⚛⾂⬿᧚ᢱߣߒߡߪᵈ⋡ߐࠇߥ߆ߞߚ㧚ߒ߆ߒ㧘1997 ᐕ㧘Bogdanovic ࠄ[11]ߪ㧘ࠛ࡯࠹࡞ਛߢ NaAlH4 ߦ⸅ᇦߣߒߡ Ti ࠍᷝടߔࠆߎߣߦࠃߞ
ߡ㧘⪺ߒߊ෻ᔕㅦᐲ߇ᡷༀߐࠇࠆߎߣࠍ␜ߒߚ㧚
NaAlH4 ߪએਅߦ␜ߔ 2 Ბߩ෻ᔕߦࠃߞߡ᳓⚛ࠍๆ⬿᡼಴ߔࠆ㧚
3NaAlH4㧩Na3AlH6㧗2Al + 3H2 (3.7 ⾰㊂%) (4)Na3AlH6㧩3NaH+Al+1.5H2 ( 1.8 ⾰㊂% )   (5) ਄⸥ߩ෻ᔕ㧔4㧕(5)ߦ߅޿ߡ᳓⚛ᐔⴧ࿶ജ߇
0.1MPa ߦߥࠆ᷷ᐲߪߘࠇߙࠇ 30͠߅ࠃ߮ 100͠ߢ޽ࠆ㧚᳓⚛ߩ᡼಴㊂ߪో૕ߢ 5.6 ⾰㊂㧑ߢ޽ࠆ㧚ߘࠇ߹ߢ㐿⊒ߐࠇߡ߈ߚ᳓⚛⾂⬿ว㊄ߦᲧߴߡ㜞
޿㊀㊂᳓⚛ࠛࡀ࡞ࠡ࡯ኒᐲࠍ᦭ߒߡ޿ࠆߎߣ߆ࠄ
ᄙߊߩᵈ⋡ࠍ㓸߼ߚ㧚

J. HTSJ, Vol. 48, No. 203

․㓸㧦᳓⚛ߩ‛ᕈ߅ࠃ߮᧚ᢱ
ਇ⚐‛ߣߒߡߩࠕࡦࡕ࠾ࠕߪ 0.1㨪0.3ppm ⒟ᐲߩߚ߼㧘ࠕࡒ࠼♽᧚ᢱ߆ࠄ᡼಴ߐࠇߚ᳓⚛ࠍߘߩ߹߹࿕૕㜞ಽሶဳΆᢱ㔚ᳰߦዉ౉ߢ߈ࠆ߆ุ߆ߦߟ
޿ߡߪ੹ᓟߩᬌ⸛߇ᔅⷐߢ޽ࠆ㧚 ᳓⚛ኒᐲߩ㜞޿ήᯏ♽᳓⚛ൻ‛ߣߒߡ㧘ࡏࡠࡂࠗ࠼࡜ࠗ࠼♽᳓⚛⾂⬿᧚ᢱ߇޽ࠆ㧚ࡏࡠࡂࠗ࠼࡜
ࠗ࠼♽᧚ᢱߪ㧘྾᳓⚛ൻࡎ࠙⚛㍲ࠗࠝࡦ㧔BH4㧙㧕ࠍ฽߻ήᯏൻว‛ߢ޽ࠆ㧚NaBH4 ߪ 7.4 ⾰㊂㧑ߩ᳓⚛⾂⬿㊂ࠍ᦭ߔࠆ㧚ࠕ࡜ࡀࠗ࠻߿ࠗࡒ࠼࡮ࠕࡒ
࠼♽᧚ᢱ߇᳓ಽߣỗߒߊ෻ᔕߔࠆߦᲧセߒߡࡏࡠࡂࠗ࠼࡜ࠗ࠼♽᳓⚛⾂⬿᧚ᢱߪࠕ࡞ࠞ࡝᳓ṁᶧਛߢ቟ቯߥߚ߼㧘ขᛒ޿ߪࠆ߆ߦኈᤃߢ޽ࠆ㧚NaBH4
ߩ᳓ṁᶧߪㆡಾߥ⸅ᇦߩሽ࿷ਅ㧘ਅ⸥ߩട᳓ಽ⸃
෻ᔕߦࠃࠅ᳓⚛ࠍ↢ᚑߔࠆ㧚
NaBH4 + 2H2O ψ 4H2 + NaBO2 (10.8 ⾰㊂%) (9) ߎߩ႐วߩ᡼಴᳓⚛㊂ߪ㧘ࡏࡠࡂࠗ࠼࡜ࠗ࠼߫
߆ࠅߢߪߥߊട᳓ಽ⸃ߦ↪޿ߚ᳓߆ࠄߩነਈ߇޽
ࠆ㧚ߘࠇࠍ฽߼ߡ᡼಴᳓⚛㊂ߪ 10.8 ⾰㊂㧑ߦ㆐ߔࠆ㧚ߎߩ෻ᔕߩᦨᄢߩ⺖㗴ߪ᳓⚛᡼಴෻ᔕᓟߩ↢ᚑ‛ NaBO2 ࠍ NaBH4 ߳ߩ‫ޟ‬ౣ↢‫ߦߣߎࠆߖߐޠ‬޽ࠆ㧚ࠛࡀ࡞ࠡ࡯ᇦ૕ߣߒߡࡏࡠࡂࠗ࠼࡜ࠗ࠼ࠍ
೑↪ߔࠆߩߢ޽ࠇ߫㧘ో૕ߣߒߡߩࠛࡀ࡞ࠡ࡯ല
₸ߦ㑐ߔࠆᬌ⸛߇ᔅⷐߢ޽ࠈ߁㧚 LiBH4 ߪࡏࡠࡂࠗ࠼࡜ࠗ࠼ߩਛߢ߽ᦨ߽㜞޿᳓⚛⾂⬿㊂㧔18.2 ⾰㊂%㧕ࠍ᦭ߒߡ޿ࠆ㧚LiBH4 ߪ㧘
110͠㧘280͠߅ࠃ߮ 480͠ߦ߅޿ߡ㧘ๆᾲ෻ᔕࠍ
઻ߞߡ᳓⚛ࠍ᡼಴ߔࠆߎߣ߇ႎ๔ߐࠇߡ޿ࠆ[18]㧚
ߒ߆ߒ㧘110͠߅ࠃ߮ 280͠ߢߪ LiBH4 ߩ⚿᥏᭴ㅧߩᄌൻ߅ࠃ߮Ⲣ⸃ߦ઻߁᳓⚛᡼಴ߢ޽ࠅ㧘480͠ߢ
ೋ߼ߡಽ⸃෻ᔕߦࠃࠆ᳓⚛᡼಴߇⷗ࠄࠇߚ㧚
LiBH4 㧩LiH + B + (3/2) H2 (13.5 ⾰㊂%)  (10) LiBH4 ߪ㧘ߎࠇ߆ࠄ߽ಽ߆ࠆࠃ߁ߦ቟ቯߥ᳓⚛
ൻ‛ߢ޽ࠅ㧘଀߃นㅒᕈ߇޽ߞߚߣߒߡ߽࿕૕㜞ಽሶဳΆᢱ㔚ᳰߣ⚵ߺวࠊߖߡ೑↪ߔࠆߎߣߪ࿎
㔍ߦ⷗߃ࠆ㧚 ࠕ࡞ࡒ࠾࠙ࡓߩ᳓⚛ൻ‛ߢ޽ࠆ AlH3㧔ࠕ࡟ࠗࡦ㧕߇ᦨㄭ㧘ᵈ⋡ࠍ㓸߼ߡ޿ࠆ[19]㧚ߎߩ‛⾰ߩ᳓⚛ൻࠛࡦ࠲࡞ࡇ࡯ᄌൻߪ-7.6kJ/molH2 ߢ޽ࠆ㧚ߔߥࠊߜ㧘ᾲജቇ⊛ߦߪቶ᷷ߢಽ⸃ߒߡ᳓⚛ߣࠕ࡞ࡒ࠾࠙ࡓࠍ↢ߓࠆߪߕߢ޽ࠆ߇㧘ታ㓙ߦߪ
100͠એ਄ߦടᾲߩᔅⷐ߇޽ࠆ㧚߹ߚ㧘㊀㊂᳓⚛ࠛࡀ࡞ࠡ࡯ኒᐲߪ 10.1 ⾰㊂㧑ߢ޽ࠅ㧘᦭ᦸߥ᧚ᢱߢ
޽ࠆ㧚ゞ਄ߦ߅ߌࠆ᳓⚛⊒↢ߦ㑐ߒߡߪ਄⸥ߩࠃ
߁ߥℂ↱ߢᅢ߹ߒ޿߇㧘ౣ߮ AlH3 ࠍ‫ޟ‬ౣ↢‫ࠆߔޠ‬ ᦭ᯏൻቇߩಽ㊁ߢࠃࠅᐢ▸ߦ૶↪ߐࠇߡ޿ࠆ
LiAlH4 ߪ㧘ᭂ߼ߡಽ⸃ߒ߿ߔ޿ߚ߼㧔᳓⚛ൻ‛ߩ↢ᚑࠛࡦ࠲࡞ࡇ࡯ᄌൻ߇ᱜ㧕นㅒ⊛ߥ᳓⚛⾂⬿ャㅍ↪᧚ᢱߣߒߡߪㆡߐߥ޿㧚Ti ⸅ᇦߩ෻ᔕᯏ᭴ߦ
ߟ޿ߡߪ Ti3㧗ࠗࠝࡦ߇ Na㧗ࠨࠗ࠻ߦ⟎឵ߒߡⓨሹࠍ↢ᚑߒ㧘෻ᔕ․ߦ᜛ᢔࠍടㅦߔࠆߣߩ⠨߃ᣇ[12]ߣ㧘NaAlH4 ߣ TiCl3 ߣߩ෻ᔕߦࠃߞߡ Ti(Al)ว㊄߇↢ᚑߒ㧘ߘߩ⸅ᇦലᨐ߇⊒⃻ߒߡ޿ࠆߣߩ
⠨߃ᣇ[13]߇᦭ജⷞߐࠇߡ޿ࠆ߇㧘ᧂߛ⸃᣿ߐࠇ
ߡ޿ࠆߣߪ⸒޿߇ߚ޿㧚 2002 ᐕ Chen[14]ࠄߪ᳓⚛⾂⬿᧚ᢱߣߒߡ Li3N
㧔⓸ൻ࡝࠴࠙ࡓ㧕߇ 200㨪400͠ߢ l0.4 ⾰㊂㧑ߩ᳓⚛ࠍนㅒ⊛ߦๆ⬿࡮᡼಴ߔࠆߎߣࠍታ㛎⊛ߦ␜ߒ᦭ᦸߥ᧚ᢱߢ޽ࠆߎߣࠍႎ๔ߒߚ㧚 Li3N ߩ᳓⚛ൻ࡮⣕᳓⚛ൻ෻ᔕࠍᰴᑼߦ␜ߒߚ㧚
Li3N + 2H2㧩Li2NH + LiH + H2 (5.2 ⾰㊂%)(6)(7)
Li2NH + H2 㧩LiNH2 + LiH (6.5 ⾰㊂%) Chen ࠄߪ᳓⚛ᐔⴧ࿶ജ߇ 0.1MPa ࠍ␜ߔ᷷ᐲߪ
߅ࠃߘ 285͠ߣផቯߒߚ㧚෻ᔕᑼ㧔6㧕ߩ෻ᔕߢߪ
᳓⚛ൻࠛࡦ࠲࡞ࡇ࡯ᄌൻߪ㧙148kJ/molH2 ߣႎ๔ߐࠇࠆߩߢฝㄝ߆ࠄᏀㄝ߳ߩ෻ᔕߦߪ 400͠એ਄ߩ㜞᷷ߦߔࠆᔅⷐ߇޽ࠆߎߣ߇ಽ߆ࠆ㧚ᓥߞߡ㧘ᑼ㧔7㧕ߩ೑↪߇นㅒ⊛᳓⚛⾂⬿ߦߪᦸ߹ߒ޿㧚ᏒᎹࠄߪࠕ࡜ࡀࠗ࠻ߣห᭽ߦ Ti ♽ߩ⸅ᇦ߇ߎߩ♽ߦ߽᦭ലߢ㧘ᑼ㧔7㧕ߩ෻ᔕ߇ 150͠ߦ߅޿ߡ߽ㅴ
ⴕߔࠆߎߣࠍ᣿ࠄ߆ߦߒߚ[15]㧚
 Leng ࠄߪ෻ᔕ᷷ᐲࠍਅߍࠆߚ߼ߦ Li ࠨࠗ࠻ࠍMg ߢ⟎឵ߒߚ෻ᔕࠍឭ᩺ߒߚ[16]㧚
3Mg(NH2)2 + 8LiH 㧩Mg3N2 + 4Li2NH + 8H2(8) ߎߩ෻ᔕߪᦨೋߦ Mg(NH2)2 ߣ LiH ࠍ᳓⚛ਛߢ 2ᤨ㑆ࡏ࡯࡞ࡒ࡝ࡦࠣⵝ⟎ߦࠃߞߡᯏ᪾⊛ᷙวಣℂߔࠆߎߣ߇ᔅⷐߢ޽ࠆ㧚↢ᚑ‛ࠍᾲಽ⸃ߔࠆߣ㧘120͠ࠍ㐿ᆎ᷷ᐲߦ᳓⚛߇⚂ 7 ⾰㊂㧑᡼಴ߐࠇߚ㧚᡼಴ᓟߩ↢ᚑ‛ߪ Li2NH ߣ Mg3N2 ߢ޽ߞߚ㧚߹ߚ㧘ฝ ㄝ ߆ ࠄ Ꮐ ㄝ ߳ ߩ ౣ ↢ ෻ ᔕ ࠍ 200 ͠ ߦ ߅ ޿ ߡ
10MPa ߩ᳓⚛࿶ജਅߢⴕ޿㧘᳓⚛߇⚂ 6.5 ⾰㊂㧑ๆ⬿ߐࠇߚߎߣ߆ࠄ෻ᔕߩนㅒᕈࠍ⏕⹺ߒߚ㧚ߎߩ෻ᔕߩ᳓⚛ൻࠛࡦ࠲࡞ࡇ࡯ᄌൻߪ-34kJ/ molH2ߣߩႎ๔߽޽ࠅ[17]㧘᦭ᦸߥ♽ߣߐࠇߡ޿ࠆ㧚 ࠕࡒ࠼࡮ࠗࡒ࠼♽ߦ߅ߌࠆ⺖㗴ߪ෻ᔕㅦᐲ߇ㆃ
޿ߣ޿߁ὐߢ޽ࠆ߇㧘ࠕ࡜ࡀࠗ࠻ߢ᦭ലߥ Ti ⸅ᇦ߇ᔅߕߒ߽ Mg ࠍ฽߻♽ߢ᦭ലߢߪߥ߆ߞߚ㧚߹ߚ㧘෻ᔕߩㅜਛߦࠕࡦࡕ࠾ࠕ߇↢ᚑߔࠆ߽⺖㗴ߣߐࠇߡ޿ࠆ㧚࿕૕㜞ಽሶဳΆᢱ㔚ᳰ߇ฃ౉น⢻ߥ

વᾲ 2009 ᐕ 4 ᦬- 24 -J. HTSJ, Vol. 48, No. 203

․㓸㧦᳓⚛ߩ‛ᕈ߅ࠃ߮᧚ᢱ
ࡊࡠ࠮ࠬߦ㑐ߒߡߪ੹ᓟ⸃᳿ߔࠆߴ߈⺖㗴߇ᄙ޿㧚 ࠕࡦࡕ࠾ࠕ࡮ࡏ࡟ࠗࡦ㧔NH3BH3㧕ߩ෻ᔕߦߪੑ
ㅢࠅ޽ߞߡ㧘‫ੇޟ‬ᑼ‫ߣޠ‬๭߱ߴ߈᳓⚛ࠟࠬߣߩ෻ᔕ
߅ࠃ߮᳓߇ടࠊࠆ‫ޟ‬ട᳓ಽ⸃෻ᔕ‫ࠆ޽ߢޠ‬㧚޿ߕࠇߩ႐ว߽ኈᤃߦ᳓⚛߇⊒↢ߔࠆߎߣ߇․ᓽߢ޽
ࠆ㧚ゞ਄ߢ᳓⚛ࠍขࠅ಴ߔ⋡⊛ߦߪㆡߒߡ޿ࠆ߇㧘రߩࠕࡦࡕ࠾ࠕ࡮ࡏ࡟ࠗࡦ᳓⚛ൻ‛ߩ‫ޟ‬ౣ↢‫ࠍޠ‬ല₸⦟ߊⴕ߁ߎߣ߇ᦨᄢߩ⺖㗴ߢ޽ࠆ㧚ߎߩ߶߆ߦ߽㧘⴫㕙Ⓧ߇ᄢ߈ߊๆ⌕⃻⽎ࠍ೑↪ߔࠆ㜞Ყ⴫㕙Ⓧ᧚ᢱ߿᦭ᯏࡂࠗ࠼࡜ࠗ࠼ߥߤ߇᳓⚛
⾂⬿᧚ᢱߣߒߡ⎇ⓥ߇ㅴ߼ࠄࠇߡ޿ࠆ[20]㧚
㧚᳓⚛⾂⬿᧚ᢱߩᾲવዉ₸᳓⚛ๆ⬿ว㊄߇ᦨೋߦ᳓⚛ࠍๆ⬿ߔࠆ㓙ߦ㧘᳓⚛ൻߦࠃࠆ 20㨪30%ߩ૕Ⓧ⤘ᒛߦࠃߞߡ㧘100 ࡒ
ࠢࡠࡦ⒟ᐲߦ☸ᓘߩߘࠈߞߚᓸ☳૕ߣߥࠆ㧚ᓸ☳
૕ߪ 100nm ⒟ᐲߩ⚿᥏ሶ߆ࠄᒻᚑߐࠇߡ޿ࠆ㧚⚿᥏ሶߪ᳓⚛ߩๆ⬿᡼಴ࠍ➅ࠅ㄰ߒߡ߽㧘ࠨࠗ࠭ߦᄌൻ߇ߥ޿ߎߣ߇㧘࿁᛬ታ㛎߆ࠄಽ߆ߞߡ޿ࠆ㧚ߔߥࠊߜ㧘⚿᥏ሶߪ᳓⚛ๆ⬿᡼಴ߦ઻߁ᩰሶߩ⤘ᒛ෼❗ࠍฃߌ౉ࠇ㧘ߘࠇએ਄ዊߐߊߥࠆߎߣߪή
޿㧚߹ߚ㧘ᓸ☳૕ߣߒߡߩࠨࠗ࠭ߪว㊄ߦ᳓⚛ࠍๆ⬿ߐߖߡᢙ࿁ߪᷫዋߔࠆ߇㧘ߘࠇએ㒠ߪ߶߷৻ቯߢ޽ࠆߎߣ߇⍮ࠄࠇߡ޿ࠆ㧚

0.65

LaNi5 [22]0.2~0.8

LaNi5Hx [22]0.1~0.75

NaAlH4 [23]0.46~0.75

⴫ 6 ߦߪ㧘᳓⚛ๆ⬿ว㊄ࠍ฽߻᳓⚛⾂⬿᧚ᢱߩᾲવዉ₸ࠍ␜ߒߚ㧚਄⸥ߩࠃ߁ߦ㧘ᓸ☳૕ߢ޽ࠆߎ
ߣ߆ࠄ㧘᳓⚛ๆ⬿ว㊄ߪ㧘᳓⚛ൻ೨ߪ㊄ዻߢ޽ࠆߦ߽߆߆ࠊࠄߕ࠮࡜ࡒ࠶ࠢࠬߣห╬ߩᾲવዉ₸ߒ߆ᜬߚߥ޿ߎߣߪ⥝๧ᷓ޿㧚[20] ᳓⚛ࠛࡀ࡞ࠡ࡯⺒ᧄ, ࠝ࡯ࡓ␠ (2007).
[21] Suissa, E. et al., J. Less-Common Met., 104,
(1985) 369.
[22] Tarasevich, V. L. ‘Protessy Perenosa Tepla I Massy
Veshchestva Kapollyarnikh-Poristykh Telyakh’, (1982)
64.
[23] Dedrick, D. E., J. Alloys Comp., 389, (2005) 299.

㧚߹ߣ߼
᳓⚛⾂⬿᧚ᢱߪ᳓⚛ࠍ㜞޿૕Ⓧኒᐲߢ⾂⬿ャㅍน⢻ߥ᧚ᢱߣߒߡᵈ⋡ߐࠇߡ޿ࠆ㧚ߒ߆ߒ㧘᳓⚛
㊀㊂ኒᐲߦߪ⺖㗴߇޽ࠅ㧘ߘߩ⸃᳿ࠍ⋡ᜰߒߚ⎇વᾲ 2009 ᐕ 4 ᦬ෳ⠨ᢥ₂
[1] http://www.fccj.jp/pdf/20080704sks1j.pdf[2] http://cocn.jp/common/pdf/fcv.pdf[3]http://www.jhfc.jp/data/seminor/fy2007/pdf/h19_3.
pdf[4] Reilly, J. J., Wiswall, Jr. R. H., Inorg. Chem., 6,(1967) 2220.
[5] Vucht, V., et al., Philips .Res ., 25, (1970) 133.
[6] Akiba, E., Iba, H., Intermetallics, 6, (1998) 461.
[7] ᫪ᄢ੖㇢ઁ㧘ᣣᧄ㊄ዻቇળ⹹㧘69, (2005)308.
[8] ᫪ᄢ੖㇢ઁ㧘ᣣᧄᯏ᪾ቇળ⺰ᢥ㓸㧔B ✬㧕, 73,(2007) 1236.
[9] Mori, D. et al., Abstract of International Symposium
on Metal-Hydrogen Systems, Iceland, 2008.
[10] Grochala, W., Edwards, P. P., Chem. Rev., 104,
(2004) 1283.
[11] Bogdanovic, B., et al., J . Alloy Comp., 253 – 254,
( 1997 ) 1.
[12] Sun, D., et al., J. Alloys Comp., 337, (2002) L8.
[13] Bogdanovic, B., et al., J. Alloys Comp., 350,
(2003) 246.
[14] Chen, P., et al., Nature, 420, (2002) 302.
[15] Ichikawa, T., et al., J. Alloys Comp., 365, (2004)
271.
[16] Leng, H., et al., J. Phys. Chem., B., 108, (2004)
8763.
[17] W. Luo, J. Alloys Comp., 381, (2004) 284.
[18] Fedneva, E. M., J. Inorg. Chem., 9, (1964) 826.
[19] Sandorock, G., et al., Appl. Phys. A80, (2005)687.

⴫ 6 ᳓⚛⾂⬿᧚ᢱߩᾲવዉ₸ᾲવዉ₸᳓⚛⾂⬿᧚ᢱ
(W/(m࡮K))
Mg2NiHx [21]ⓥ߇⋓ࠎߢ޽ࠆ㧚੹ᓟߪ㧘᧚ᢱߩߺߥࠄߕߘࠇࠍ
᦭ലߦᵴ↪ߔࠆߚ߼ߩࠪࠬ࠹ࡓᛛⴚߩ⏕┙߇ਇนᰳߢ޽ࠆ㧚☨࿖ߢߪ᳓⚛⾂⬿᧚ᢱߩࠛࡦࠫ࠾ࠕ࡝
ࡦࠣߩߚ߼ߩ COE ߇ᤓᐕ㧘ᣂߚߦ⸳┙ߐࠇߎߣߪ
ߘࠇࠍ‛⺆ߞߡ޿ࠆߣ⸒߃ࠃ߁㧚- 25 -J. HTSJ, Vol. 48, No. 203

․㓸㧦᳓⚛ߩ‛ᕈ߅ࠃ߮᧚ᢱ

᳓⚛ߪෂߥ޿߆
Safety Research on Hydrogen Fueled Vehicleਃ⍹ ᵗਯ㧔㧔⽷㧕ᣣᧄ⥄േゞ⎇ⓥᚲ㧕
Hiroyuki MITSUISHI (Japan Automobile Research Institute)e-mail: hmituisi@jari.or.jp᳓⚛ߩᕈ⾰᳓⚛ߦߟ޿ߡߪ㧘⟵ോᢎ⢒ߩㆊ⒟ߢ᳓ߩ㔚᳇ಽ⸃ߣߘࠇߦࠃࠅ⊒↢ߒߚ᳓⚛߳ߩ⌕Ἣታ㛎ߦࠃࠅ㧘῜⊒ᕈߩ㜞޿นΆᕈࠟࠬߢ޽ࠆߎߣ߇ᢎ⢒ߐࠇߡ߅ࠅ㧘ዊߐ޿ߎࠈ߆ࠄ⺕߽߇ෂ㒾ߥࠟࠬߢ޽ࠆߣ
⹺⼂ߒߡ޿ࠆ㧚ߐࠄߦ᳓⚛߳ߩ⌕Ἣ߇⋥ធߩ੐᡿ේ࿃ߢߥ޿ߎߣ߇ㄭᐕߦߥߞߡႎ๔ߐࠇߡ޿ࠆ߽
ߩߩ㧘ᧂߛߦ㘧ⴕ⦁ࡅࡦ࠺ࡦࡉ࡞ࠣภߩ῜⊒੐᡿߽᳓⚛ߦࠃࠆ߽ߩߣߒߡ৻⥸ߦߪ⹺⼂ߐࠇߡ߅ࠅ㧘᳓⚛߇㕖Ᏹߦෂ㒾ᕈߩ㜞޿ࠟࠬߣ޿߁ශ⽎ࠍߐࠄߦ᳿ቯ⊛ߥ߽ߩߦߒߡ޿ࠆ㧚ߘߩࠃ߁ߥⅣႺߩਛߢ㧘ᣣᏱ↢ᵴߦりㄭߥሽ࿷ߢ޽ࠆ⥄േゞߦ᳓⚛ࠍ៞タߔࠆߚ߼ߦߪ㧘᳓⚛ࠍ቟ోߦ៞タߔࠆᛛⴚ㐿⊒ߩઁߦ㧘೨ㅀߩ৻⥸⹺⼂ߦߟ޿ߡ߽‫ޟ‬᳓⚛ߪ቟ో߆㧫ෂ㒾߆㧫‫ⷰ߁޿ߣޠ‬ὐ߆ࠄ੐ታࠍ߈ߜࠎߣ⏕⹺ߒ㧘᳓⚛߇೑↪น⢻ߥΆᢱߢ޽ࠆߎߣ㧘ߟ߹ࠅ᳓⚛ߩ␠ળฃኈᕈ߽㜞߼ߡ޿ߊᔅⷐ߇޽ࠆ㧚એਅߦ᳓⚛ࠟࠬߩ৻⥸⊛ߥᕈ⾰[2]ࠍ␜ߔ㧚ⓨ᳇ਛߩ῜⊒▸࿐㧦4.0㨪75.0[%]ⓨ᳇ਛߩ῜ߏ߁▸࿐㧦18.3㨪59.0[%]ᦨዊ⊒Ἣࠛࡀ࡞ࠡ࡯㧦0.02[mJ]ⓨ᳇ਛߩἫἻ᷷ᐲ㧦2318K
᳓⚛ߩนΆ▸࿐ߪࠟ࠰࡝ࡦ߿ᄤὼࠟࠬߥߤ㧘ߎࠇ߹ߢߩ⥄േゞ↪ΆᢱߣᲧߴߡᐢߊ㧘Ά὾ㅦᐲ߇
ㅦߊߡ῜ߏ߁ࠍ⿠ߎߒ߿ߔߊ㧘ಽሶࠨࠗ࠭߇ዊߐ
ߊߡṳࠇ߿ߔߊ㧘㕒㔚᳇ߥߤߩࠊߕ߆ߥࠛࡀ࡞ࠡ
࡯ߢ⌕Ἣߒ㧘ߐࠄߦߪ᳓⚛ߩἻߪ᷷ᐲ߇㜞ߊߡἻ⦡߇ㅘ᣿ߥߎߣ߆ࠄ㧘㜞᷷ߩἻ߇ᒻᚑߐࠇߡ߽⷗
߃ߥ޿ߚ߼㕖Ᏹߦෂ㒾㧘ߥߤߣ޿ߞߚߎߣ߇৻⥸ߦߪ⠨߃ࠄࠇߡ޿ࠆࠃ߁ߢ޽ࠆ㧚JARI ߢߪ㧘⥄േゞ↪Άᢱߣߒߡߩ᳓⚛ߩ೑↪ࠍផㅴߔࠆߦ޽ߚࠅ㧘⥄േゞ߳ߩ៞タ㊂ࠍᗐቯߒߚ
᳓⚛⾂⬿㊂ߩ▸࿐ౝߢ㧘ታ㓙ߦ᳓⚛߇ߤߩ⒟ᐲෂ
㒾ߥߩ߆㧘ṳࠇ಴ߒߚ᳓⚛ߪߤߩࠃ߁ߦ᜛ᢔߔࠆ
ߩ߆㧘⌕Ἣᕈߪ৻⥸ߦ⸒ࠊࠇࠆࠃ߁ߦ㕒㔚᳇ߢ߽ߪߓ߼ߦ
࿾⃿ⷙᮨߢᐕ‫ޘ‬ᷓೞൻߔࠆ᷷ᥦൻኻ╷ߣߒߡ㧘὇㉄ࠟࠬ㧔CO2㧕ឃ಴ૐᷫߦะߌߚขࠅ⚵ߺ߇ฦᣇ㕙ߢ⋓ࠎߦㅴ߼ࠄࠇߡ޿ࠆ㧚⥄േゞߦߟ޿ߡ߽
଀ᄖߢߪߥߊ㧘ൻ⍹Άᢱࠍ૶↪ߔࠆ⃻ⴕߩౝΆᯏ
㑐⥄േゞߦኻߒߡ㧘὇㉄ࠟࠬࠍឃ಴ߖߕ㧘ࠢ࡝࡯ࡦߥࠛࡀ࡞ࠡ࡯ߩ೑↪߇น⢻ߥゞਔߩ㐿⊒߇ㅴ߼ࠄࠇߡ޿ࠆ㧚ߘߩࠢ࡝࡯ࡦߥࠛࡀ࡞ࠡ࡯Ḯߣߒߡ㧘ౣ↢น⢻ߥ᳓⚛ߩ೑↪ࠍ⥄േゞಽ㊁ߢ߽ታ⃻ߔߴߊ㧘ᛛⴚ㐿⊒߇↥ቇቭ౒หߢⓍᭂ⊛ߦㅴ߼ࠄࠇߡ
޿ࠆ㧚ߘߩᛛⴚ㐿⊒ߩᚑᨐߢ޽ࠆ᳓⚛࡮Άᢱ㔚ᳰ⥄േゞߩታ⸽⿛ⴕ⹜㛎ߪᣢߦ౏㆏ࠍ૶↪ߒߡⴕߥࠊࠇߡ߅ࠅ[1]㧘߹ߚ㧘᳓⚛࡮Άᢱ㔚ᳰ⥄േゞߩဳᑼขᓧߦᔅⷐߥⷙ೙ߦ㑐ߒߡ߽㧘2005 ᐕ 3 ᦬ߦߪ㆏〝ㆇㅍゞਔᴺߥࠄ߮ߦ㜞࿶ࠟࠬ଻቟ᴺߣ޿ߞߚ㑐ㅪᴺⷙߩᢛ஻߇ቢੌߒߡ޿ࠆ㧚⃻࿷ߪ㧘ࠃࠅ೑ଢᕈߩ㜞޿᳓⚛࡮Άᢱ㔚ᳰ⥄േゞߩ㐿⊒ߦะߌߡ㧘଀߃߫⥶⛯〒㔌ߩિ㐳߿ࠦࠬ࠻ߩ㕙ߥߤ߆ࠄ㧘᥉෸ߦㆡߒߚゞਔ㐿⊒ߩขࠅ⚵ߺ߇ㅴ߼ࠄࠇߡ޿ࠆ㧚߹ߚ㧘หᤨߦ೨ㅀߩ㑐ㅪᴺ
ⷙߦ㑐ߒߡ߽㧘቟ోᕈߣࠦࠬ࠻߇ࠃࠅ᥉෸ߦㆡߒ
ߚ߽ߩߣߥࠆࠃ߁ߦ㧘ⷙ೙ߩߐࠄߥࠆวℂൻߦะߌߚขࠅ⚵ߺ߇ⴕߥࠊࠇߡ޿ࠆ㧚ߎߩࠃ߁ߥฦᣇ㕙ߩขࠅ⚵ߺߦኻߒߡ㧘㧔⽷㧕ᣣᧄ⥄േゞ⎇ⓥᚲ㧔એਅ㧘JARI ߣ޿߁㧕ߢߪ 2000
ᐕ߆ࠄᣂࠛࡀ࡞ࠡ࡯࡮↥ᬺᛛⴚ✚ว㐿⊒ᯏ᭴㧔એਅ㧘NEDO ߣ޿߁㧕߆ࠄߩᆔ⸤ࠍฃߌߡ㧘᳓⚛࡮Άᢱ㔚ᳰ⥄േゞߩ᥉෸ߦะߌߚฦ⒳ၮ␆࠺࡯࠲ߩ
෼㓸ࠍⴕ޿㧘ၮḰ╷ቯ߿วℂൻ૞ᬺߦขࠅ⚵ࠎߢ߈ߡ޿ࠆ㧚એਅߢߪ㧘 NEDO ߆ࠄߩᆔ⸤੐ᬺߣߒߡ㧘ߎࠇ߹ߢ JARI ߇ⴕߞߡ߈ߚ᳓⚛࡮Άᢱ㔚ᳰ⥄േゞߩ቟ోᕈߦ㑐ߔࠆ⎇ⓥᵴേߩᚑᨐߩ৻ㇱࠍㅀߴࠆߣߣ߽ߦ㧘‫ޟ‬᳓⚛ߪෂߥ޿߆‫ⷰߚߞ޿ߣޠ‬ὐߦߟ޿
ߡ߽ᢛℂߔࠆ㧚વᾲ 2009 ᐕ 4 ᦬- 26 -J. HTSJ, Vol. 48, No. 203

․㓸㧦᳓⚛ߩ‛ᕈ߅ࠃ߮᧚ᢱ
⋥ߜߦᄢἫἴߦߥߞߡߒ߹߁ߩ߆ߥߤ㧘᳓⚛ߩᕈ⾰ߦߟ޿ߡ⺞ᩏߔࠆߣߣ߽ߦ㧘⥄േゞ߳ߩ቟ోߥ
᳓⚛៞タᛛⴚ߿૶↪ᣇᴺߩ㐿⊒ߦะߌߚ࠺࡯࠲෼
㓸ࠍⴕߥߞߡ߈ߚ㧚ᰴ┨ߢߪ㧘᳓⚛࡮Άᢱ㔚ᳰ⥄േゞߩ቟ోᕈ⹏ଔ
ࠍ⋡⊛ߣߒߡ㐿⊒ߒߚ᳓⚛࡮Άᢱ㔚ᳰ⥄േゞ቟ోᕈ⹏ଔ⹜㛎ᣉ⸳=?㧔એਅ㧘Hy-SEF ߣ޿߁㧕ߦߟ޿ߡㅀߴࠆߣߣ߽ߦ㧘߹ߕߪ᳓⚛ࠟࠬߩ․ᕈߦ㑐ߔࠆ⺞ᩏ⚿ᨐߦߟ޿ߡ␜ߔ㧚᳓⚛ࠟࠬߩ቟ోᕈ ᳓⚛࡮Άᢱ㔚ᳰ⥄േゞ቟ోᕈ⹏ଔ⹜㛎ᣉ⸳
JARI ߪ NEDO ߆ࠄߩᆔ⸤ࠍฃߌߡ 2000 ᐕ߆ࠄㅴ߼ߡ߈ߚ⥄േゞ↪࿕૕㜞ಽሶᒻΆᢱ㔚ᳰࠪࠬ࠹ࡓ᥉෸ၮ⋚ᢛ஻੐ᬺߩਛߢ㧘᳓⚛ߩ቟ోᕈࠍ⺞ᩏߔࠆߚ߼ߦ㧘2003 ᐕߦ᳓⚛࡮Άᢱ㔚ᳰ⥄േゞ቟ోᕈ⹏ଔ⹜㛎ᣉ⸳ࠍቢᚑߐߖߚ㧔࿑ 1 ෳᾖ㧕㧚ߘࠇ߹ߢ JARI ߪᶏᄖߩ⹜㛎ᯏ㑐ࠍ೑↪ߒߡ⹜㛎࠺࡯࠲ߩ෼㓸ࠍㅴ߼ߡ߈ߚ߇㧘Hy-SEF ߩቢᚑߦࠃࠅ㧘቟ోߢࠢ࡝࡯ࡦ਌ߟౣ⃻ᕈߩ㜞޿⹜㛎࠺࡯࠲ߩ෼
㓸߇࿖ౝߢታᣉߢ߈ࠆࠃ߁ߦߥߞߚ㧚᜛ᢔᕈ㧘⌕Ἣᕈߦߟ޿ߡㅀߴࠆ㧚 ᳓⚛ࠟࠬߩ᜛ᢔᕈ߅ࠃ߮⌕Ἣᕈ᳓⚛ߪนΆ▸࿐߇ᐢߊ㧘⌕Ἣࠛࡀ࡞ࠡ࡯߇ዊߐ
޿ߎߣ߆ࠄ㧘᳓⚛ṳ߃޿ᤨߦߪ⌕Ἣ࡮῜⊒ߣ޿ߞߚ㕖Ᏹߦෂ㒾ߥ⁁ᘒߣߥࠆߎߣ߇ᗐቯߐࠇࠆ㧚ߘߎߢ㧘1000[mm]྾ᣇߩⓨ㑆ߩਅㇱ߆ࠄ 10[L/min]ߩᵹ㊂ߢ᳓⚛ࠟࠬࠍ਄ᣇߦะߌߡᵹ౉ߐߖߚ㓙ߩ᳓⚛᜛ᢔࠪࡒࡘ࡟࡯࡚ࠪࡦࠍⴕ޿㧘᳓⚛ߩ᜛ᢔᕈ߅ࠃ߮ỚᐲಽᏓߦߟ޿ߡ⺞ᩏߒߚߩߢ㧘ߘߩ⚿ᨐ
ࠍ࿑ 2 ߦ␜ߔ㧚=OO?
OO
឵᳇⓹

ᵹ౉㊂㧦=.OKP?
(a)Ớᐲ▸࿐㧦0.01- 4[%](b)Ớᐲ▸࿐㧦4[%]࿑  ᳓⚛ࠟࠬߩ᜛ᢔᕈⓨ㑆ౝߦᵹ౉ߒߚ᳓⚛ࠟࠬߪ㧘(a)ߦ␜ߔࠃ߁ߦ
߹ߞߔߋ਄ᣇ߳਄ࠅ㧘ᄤ੗ㇱߢ᳓ᐔᣇะߦ᜛ᢔߒ
ߡ޿ࠆ㧚นΆਅ㒢୯ߢ޽ࠆỚᐲ 4[%]ߩ㗔ၞࠍᛮ߈಴ߔߣ㧘(b)ߦ␜ߔࠃ߁ߦߘߩ㗔ၞߪ᳓⚛ᵹ౉ㇱ߆ࠄ਄ᣇߦะߌߚ৻ㇱߩⓨ㑆ߦ㒢ቯߐࠇߡ߅ࠅ㧘ⓨ㑆ౝߢ᳓⚛ߪဋ৻ᷙว⁁ᘒߦήߊ㧘೔㆐ߒߚ᳓⚛
ߪ⋥ߜߦ᳓ᐔᣇะߦ᜛ᢔߒߡỚᐲ߇ૐਅߒߡ޿ࠆ㧚ᰴߦ㧘᳓⚛᜛ᢔࠪࡒࡘ࡟࡯࡚ࠪࡦߩ⚿ᨐࠍᬌ⸽ߔࠆߚ߼ߦታᣉߒߚ᳓⚛ṳ߃޿ᒁἫ⹜㛎⚿ᨐࠍ࿑
3 ߦ␜ߔ㧚࿑  *[5'( ో᥊=OO?

Hy-SEF ߪ㧘⥄േゞ↪࿶❗᳓⚛ኈེࠍ៞タߒߚ᳓⚛࡮Άᢱ㔚ᳰ⥄േゞߩゞਔἫἴ⹜㛎߇㧘᳓⚛ኈེ߇⎕ⵚߔࠆࠃ߁ߥ੐⽎߇⊒↢ߒߚ႐วߢ߽቟ో
ߦታᣉߢ߈ࠆደౝဳߩ⠴῜Ἣἴ⹜㛎⸳஻ࠍᦨᄢߩ
․ᓽߦ㧘ߘߩ๟࿐ߦ਎⇇ᦨ㜞ᕈ⢻ࠍ᦭ߔࠆ⸳஻⟲ߣߒߡ㧘100MPa ⚖ߩ㜞࿶᳓⚛߇૶↪น⢻ߥ᳓⚛
లߡࠎ⹜㛎⸳஻㧘ᶧൻ᳓⚛లߡࠎ⸳஻㧘ߐࠄߦߪ㜞࿶ኈེߩ቟ోᕈ⹏ଔ⹜㛎↪ߣߒߡ৻⥸⊛ߦⴕࠊࠇߡ޿ࠆᶧ૕ߩ࿶ജࠍ૶↪ߒߚ⎕ⵚ࡮∋ഭ⹜㛎⸳஻߆ࠄᚑࠆ㧚
એਅߢߪ㧘Hy-SEF ߩ⹜㛎࡮⸃ᨆᛛⴚࠍ೑↪ߒߡⴕߞߚ⎇ⓥᵴേߩਛ߆ࠄ㧘߹ߕߪ㧘᳓⚛ࠟࠬߩ

䋱[m]

䋱[m]

䋱[m]

L

឵᳇ญ

⌕Ἣⵝ⟎

વᾲ 2009 ᐕ 4 ᦬

OO

䋰.䋵[m]*ࡆ࠾࡯࡞ო

⒖േ
䋰.䋵[m]

᳓⚛ᵹ౉ญᓘ7.6䇮29[mm]⹜㛎ⵝ⟎⹜㛎ⵝ⟎ᄖⷰ

᳓⚛᜛ᢔ㩆㩚㨷㩤㨺㩆㨸㩧᳓⚛Ớᐲ㧦4[%]᳓⚛Ớᐲ㧦8[%]࿑  ᳓⚛ṳ߃޿ᒁἫ⹜㛎- 27 -J. HTSJ, Vol. 48, No. 203

․㓸㧦᳓⚛ߩ‛ᕈ߅ࠃ߮᧚ᢱ

O

U            

  

 



         UGE࿑  ኈེ቟ోᑯ߆ࠄߩ᡼಴᳓⚛ἫἻ㧔਄ᣇะ߳ߩ᡼಴㧕Ἣ߇ߟ޿ߡ߽ἫἻߪㅘ᣿ߢ⋡ⷞߢ⏕⹺ߢ߈ߥ޿ߣ
ߐࠇ㧘᳓⚛ṳᵨߣ⌕Ἣࠍߤߩࠃ߁ߦ⏕⹺ߔࠆ߆߇
᳓⚛ߩ೑↪᜛ᄢߦะߌߚ቟ో਄ߩ⺖㗴ߩ৻ߟߣߥࠆ㧚᳓⚛ṳᵨߩᬌ⍮ᚻᲑߣߒߡઃ⥇೷ߦࠃࠆᣇᴺߩ
⎇ⓥ߇ㅴ߼ࠄࠇߡ޿ࠆ߇㧘Άᢱ㔚ᳰߦᖡᓇ㗀ࠍਈ߃ߕਸ਼ຬ߇ෂ㒾ࠍኤ⍮ߢ߈ࠆࠃ߁ߥਇᔟߥ⥇᳇ࠍ߽ߞߚઃ⥇೷ߪ⃻࿷ߩߎࠈߣ⷗಴ߖߡ޿ߥ޿ߚ߼㧘᳓⚛ṳ߃޿ߦߟ޿ߡߪ᳓⚛࠮ࡦࠨ࡯ߦࠃࠅᬌ⍮ߔ
ࠆᣇᴺࠍၮḰߢߪⷙቯߒߡ޿ࠆ㧚ἫἻߦߟ޿ߡߪ㧘ゞਔߩ᳓⚛⾂⬿ࠪࠬ࠹ࡓߩ቟
ోᑯ૞േߦࠃࠆ᳓⚛᡼಴ᤨ߇ᦨᄢⷙᮨߣߥࠅ㧘⌕Ἣߦࠃࠆ๟࿐ᓇ㗀ߪᦨᄢߣߥࠆ㧚ゞਔ߳ߩ᳓⚛៞タᣇᴺߣߒߡߪ㧘࿶❗᳓⚛ኈེ㧘ᶧൻ᳓⚛ኈེ㧘᳓⚛⾂⬿ว㊄ኈེߥߤߩᣇᴺ߇ᬌ
⸛ߐࠇ㧘࿶❗᳓⚛ኈེߦߟ޿ߡߪ㧘ᣢߦၮḰ߇ᢛ஻ߐࠇߡ޿ࠆ㧚⥄േゞ↪࿶❗᳓⚛ኈེߦߪ㧘110͠⒟ᐲߢ૞േߔࠆṁᩖᑼ㧔᷷ᐲ૞േᑼ㧕ߩ቟ోᑯ߇
ⵝ஻ߐࠇߡ߅ࠅ㧘ゞਔἫἴ੐᡿ߩ㓙ߦ߽ኈེ߇⎕ⵚߔࠆߎߣߥߊ᳓⚛߇ᄖㇱߦ᡼಴ߐࠇࠆ᭴ㅧߦߥ
ߞߡ޿ࠆ㧚৻ᣇߢ቟ోᑯߩ૞േߦࠃࠅ᳓⚛ߪἫἴ⃻႐ߦ᡼಴ߐࠇ㧘⌕Ἣߔࠆߎߣߦߥࠆ߇㧘᳓⚛ἫἻ߇⷗߃ߥ޿ߣߥࠆߣ㧘๟ㄝߦ޿ࠆᱠⴕ⠪߿ᶖ㒐㓌ߦࠃࠆᶖἫᵴേᤨߥߤߦἫ்ߥߤߩⵍኂࠍ᜛ᄢ
ߐߖࠆน⢻ᕈ߇޽ࠆ㧚ߘߎߢ㧘᳓⚛ࠍలߡࠎߒߚ 35MPa ⥄േゞ↪࿶❗
᳓⚛ኈེߩ቟ోᑯࠍ૞േߐߖ㧘᡼಴ߒߚ᳓⚛ߦἫࠍߟߌߡἫἻߩ⁁ᘒࠍⷰኤߒߚ⚿ᨐࠍ࿑ 4 ߦ␜ߔ㧚᳓⚛ἫἻߪ⡺⌒ߢⷰኤߢ߈ߡ߅ࠅ㧘㐳ߐ 10[m]⒟ᐲߩἻ߇቟ోᑯ૞േᤨ߆ࠄ 2 ⑽⒟ᐲᜬ⛯ߔࠆ߇㧘ߔߋߦἻߪ⍴ߊߥߞߡ޿ࠆ㧚ߥ߅㧘⿒ᄖ✢ᾲ↹௝ⵝ⟎ߢἫἻߩ㗔ၞࠍ⏕⹺ߒߚߣߎࠈ㧘⡺⌒ߢ⏕⹺ߢ߈ߚ㗔ၞߣหߓߢ޽ߞߚ㧚ᬌ⸽⹜㛎ߪ㧘᳓⚛᜛ᢔࠪࡒࡘ࡟࡯࡚ࠪࡦߢࡕ࠺
࡞ൻߒߚ৻ㄝ 1000[mm]ߩ┙ᣇ૕ߢ஥㕙ࠍࡆ࠾࡯࡞᧼ߢⷒߞߚ▫ဳߩ⹜㛎ⵝ⟎ౝߢⴕߞߚ㧚⹜㛎᧦ઙߪ㧘⹜㛎ⵝ⟎ߩᐩ㕙ਛᄩㇱ߆ࠄ 10[L/min]ߩᵹ㊂ߢ⹜㛎ⵝ⟎ౝߦᵹ౉ߐߖ㧘ᐔဋỚᐲ߇ 4[%]ߦߥࠆ
40[L] ߩ᳓⚛ࠍᵹ౉ߐߖࠆࠤ࡯ࠬߣ㧘ᐔဋỚᐲ߇
8[%]ߦߥࠆ 80[L]ߩ᳓⚛ࠍᵹ౉ߐߖࠆࠤ࡯ࠬߣߒ
ߚ㧚⌕Ἣߪ㧘ⷙቯ㊂ߩ᳓⚛ࠍ⹜㛎ⵝ⟎ౝߦᵹ౉ߐ
ߖߚ⌕ᓟߦ᳓⚛ࠍㆤᢿߒ㧘⹜㛎ⵝ⟎ߩ਄㕙ਛᄩㇱߦขࠅઃߌߚὐἫⵝ⟎ߩ㔚᳇Ἣ⧎ߦࠃࠆᣇᴺߢⴕ
ߞߚ㧚ߘߩ⚿ᨐߣߒߡ㧘᳓⚛᜛ᢔࠪࡒࡘ࡟࡯࡚ࠪ
ࡦߣห৻᧦ઙߣߥࠆ 40[L]ߩ᳓⚛ࠍᵹ౉ߐߖࠆࠤ
࡯ࠬߢߪ㧘⿒ᄖ✢ᾲ↹௝ⵝ⟎㧔ࠨ࡯ࡕࠣ࡜ࡈ㧕ߩᤋ௝߆ࠄ㧘᳓⚛᜛ᢔࠪࡒࡘ࡟࡯࡚ࠪࡦ߇␜ߔนΆ
㗔ၞߦ⌕Ἣ߇ⷰኤߐࠇߚ㧚ߒ߆ߒߥ߇ࠄ㧘ᒝᐲߩૐ޿ო㕙ߩࡆ࠾࡯࡞᧼ߦߪ⌕Ἣߦࠃࠆ៊்ߪߺࠄ
ࠇߥ߆ߞߚ㧚
৻ᣇ㧘ᐔဋỚᐲ߇ 8[%]ߦߥࠆ 80[L]ߩ᳓⚛ࠍᵹ౉ߐߖࠆࠤ࡯ࠬߢߪ㧘ἫἻߩ㗔ၞߪ 40[L]ߩࠤ࡯
ࠬࠃࠅᐢߊߥࠅ㧘ߐࠄߦࡆ࠾࡯࡞᧼߇⎕៊ߒ㧘ἫἻ߇⹜㛎ⵝ⟎ߩᄖㇱߦ㆐ߒߚ㧚એ਄ࠍ߹ߣ߼ࠆߣ㧘੹࿁ߩ⹜㛎᧦ઙߩ▸࿐ౝߢߪ㧘᳓⚛᜛ᢔࠪࡒࡘ࡟࡯࡚ࠪࡦߦࠃࠆ⸃ᨆߩ᦭ല
ᕈ߇⏕⹺ߢ߈㧘㐽㎮ߐࠇߚⓨ㑆ౝߦ᳓⚛߇ṳࠇ಴ߒߚ႐วߢ߽㧘᳓⚛ߪㅦ߿߆ߦ᜛ᢔߒỚᐲ߇ૐਅߔࠆߎߣ㧘ṳᵨߒߚ᳓⚛ߩỚᐲߪဋ৻ߢߪߥߊ㧘᳓⚛ṳᵨㇱ߆ࠄ਄ᣇߦะߌߡ㜞Ớᐲ㗔ၞ߇ሽ࿷ߔ
ࠆỚᐲಽᏓ߇޽ࠅ㧘㜞Ớᐲߩㇱಽߦ⌕Ἣߩน⢻ᕈ߇޽ࠆߎߣ㧘ߒ߆ߒ㧘ᐔဋỚᐲ 4[%]⋧ᒰಽߩ᳓⚛
ߦἫ߇ߟ޿ߡ߽㧘‫ޟ‬᳓⚛ߦἫ߇ߟߊߣ㧘ᄢ῜⊒ߦߥࠆ‫⁁ߚߞ޿ߣޠ‬ᘒߦߪή޿ߎߣߥߤ߇ࠊ߆ߞߚ㧚ᰴߦ㧘᳓⚛ἫἻߦߟ޿ߡ⺞ᩏߒߚ⚿ᨐ[4]ࠍ࿑ 4ߦ␜ߔ㧚᳓⚛ߪή⥇ߢ㧘ߐࠄߦṳࠇ಴ߒߚ᳓⚛ߦ

વᾲ 2009 ᐕ 4 ᦬- 28 -J. HTSJ, Vol. 48, No. 203

․㓸㧦᳓⚛ߩ‛ᕈ߅ࠃ߮᧚ᢱ
ᧄ⹜㛎ߢߪ㧘ࡁ࠭࡞ߩ᧚⾰ߦᲧᾲߩ⇣ߥࠆ᧚ᢱએ਄ߩ⚿ᨐ߆ࠄ㧘଀߃߫᳓⚛ࠍΆᢱߣߔࠆࡠࠤߣߒߡ㧘㋕߿ࡊ࡜ࠬ࠴࠶ࠢߥߤߦߟ޿ߡ߽Ყセࠍ࠶࠻ࠛࡦࠫࡦߩἻߪㅘ᣿ߢ⷗߃ߥ޿߇㧘⥄േゞ↪
ⴕߞߡ߅ࠅ㧘ߘߩ⚿ᨐߣߒߡ㧘᳓⚛ߩᓸዊṳ߃޿Άᢱࠍᗐቯߒߚ႐วߦ㒢ߞߡߪ㧘⥄േゞ↪࿶❗᳓ߦߟ޿ߡߪ㧘᳓⚛ṳ߃޿ㇱߦ⌕ἫḮࠍㄭߠߌߡ߽㧘⚛ኈེߩ቟ోᑯ߇૞േߒ㧘᡼಴ߒߚ᳓⚛߇⌕Ἣߒṳ߃޿ㇱߩࡁ࠭࡞╬ߩๆᾲߦࠃࠅ᳓⚛߇⌕Ἣߒߚߚ႐วߢ߽㧘᳓⚛ἫἻߪ⡺⌒ߢ⏕⹺ߢ߈㧘⋡ⷞߦ႐วߦ߅޿ߡ߽⥄ὼᶖἫߔࠆߎߣ߇⏕⹺ߢ߈㧘ᓸࠃࠆㆱ㔍㗔ၞߩ⏕଻߇น⢻ߢ޽ࠆߎߣ߇ࠊ߆ߞߚ㧚ዊṳ߃޿ߦኻߔࠆෂ㒾ᕈߪ㜞ߊߥ޿ߎߣ߇ࠊ߆ߞ
೨ㅀߩ᳓⚛ߩᄢ㊂ṳᵨߦኻߒߡ㧘ᓸዊṳᵨᤨߩߚ㧚⌕Ἣ⁁ᴫߦ㑐ߔࠆ⺞ᩏ⚿ᨐࠍᰴߦㅀߴࠆ㧚᳓⚛࡮ߎࠇ߹ߢߪ᳓⚛ἫἻߦߟ޿ߡㅀߴߡ߈ߚ߇㧘ᰴΆᢱ㔚ᳰ⥄േゞߪ㧘᳓⚛ࠬ࠹࡯࡚ࠪࡦߢ⃻ⴕゞਔߦ㧘⃻ⴕߩ⥄േゞߩΆᢱߢ޽ࠆࠟ࠰࡝ࡦ߿ᄤὼࠟ
ߣห᭽ߦ᳓⚛⵬⛎ࠍฃߌࠆ㧚᳓⚛ߪ㧘᳓⚛ࠬ࠹࡯ࠬ㧔ࡔ࠲ࡦ㧕ߦኻߒߡ㧘᳓⚛ἫἻߩෂ㒾ᕈࠍ⺞ᩏ࡚ࠪࡦߩ࠺ࠖࠬࡍࡦࠨ࡯ߦขࠅઃߌࠄࠇߚలߡࠎ
ߒߚ⚿ᨐߩ৻ㇱࠍㅀߴࠆ㧚ࡁ࠭࡞ߣゞਔߩ࡟࠮ࠢ࠲ࡊ࡞߇ធ⛯ߐࠇ㈩▤ࠍ⚻⃻ⴕߩࠟ࠰࡝ࡦゞߢߪ㧘ⴣ⓭⹜㛎ߩ㓙ߩΆᢱṳ↱ߒߡ᳓⚛⾂⬿࠲ࡦࠢߦలߡࠎߐࠇࠆ㧚߹ߚ㧘⿛ࠇߩ⸵ኈ㊂߇ 30[g/min]એਅߢ޽ࠆߎߣ߇᳞߼ࠄ
ⴕਛߪ㧘᳓⚛⾂⬿࠲ࡦࠢ߆ࠄਥᱛᑯ㧘ᷫ࿶ᑯ㧘㈩ࠇߡ޿ࠆ㧚ߎࠇߦኻߒߡ㧘ᄤὼࠟࠬ⥄േゞߢ߽Ά▤㘃ࠍ⚻↱ߒߡΆᢱ㔚ᳰ㧔ࠬ࠲࠶ࠢ㧕ߦ᳓⚛ߪଏᢱṳࠇ㊂߇ 30[g/min]ߩࠟ࠰࡝ࡦߣ╬ଔ⊒ᾲ㊂ߩ⛎ߐࠇࠆ㧚᳓⚛⾂⬿࠲ࡦࠢߩ቟ోᕈߪ㧘᳓⚛ࠍ⥄40[NL/min]એਅߣߥࠆࠃ߁ߦ᳞߼ࠄࠇߡ߅ࠅ㧘᳓േゞߢ቟ోߦ೑↪ߔࠆߚ߼ߦ㊀ⷐߢ޽ࠆ߇㧘࡟࠮⚛ߦߟ޿ߡ߽ห᭽ߩ⠨߃ᣇ߆ࠄ 131[NL/min]એਅ
ࠢ࠲ࡊ࡞㧘ᷫ࿶ᑯ㧘⛮߉ᚻ㘃߆ࠄߩᓸዊߥ᳓⚛ṳߩṳࠇ㊂ߦߥࠆߎߣ߇ⴣ⓭⹜㛎ᴺߢⷙቯߐࠇߡ޿
߃޿ߦኻߔࠆ቟ోᕈߦߟ޿ߡ߽⺞ᩏߔࠆᔅⷐ߇޽
ࠆ㧚ߘߎߢ㧘〝਄੐᡿ߩ㓙ߦṳ߃޿ߒߚ᳓⚛ߦߟࠆ㧚એਅߢߪ㧘࡟࠮ࠢ࠲ࡊ࡞ߩㅒᱛᑯߥߤ߆ࠄ 1޿ߡ㧘ઁߩΆᢱߣᲧߴߡㅌㆱ〒㔌ࠍᄢ߈ߊߔࠆࠃ
ᤨ㑆ᒰߚࠅ 250[cc]⒟ᐲߩ᳓⚛ṳ߃޿߇⊒↢ߒߚ߁ߥᔅⷐ߇޽ࠆߩ߆ࠍ⺞ߴࠆߚ߼ߦ㧘೨ㅀߩṳ߃႐วࠍᗐቯߒ㧘⌕ἫḮ߇ṳ߃޿୘ᚲߩㄭறߦ޽ߞ
޿㊂ߢࠟ࠰࡝ࡦ㧘ࡔ࠲ࡦ㧘᳓⚛ߘࠇߙࠇߩἫἻߩ
ߡ㧘ṳ߃޿ߒߚ᳓⚛߇⌕Ἣߒߚ႐วߩἻߩᜬ⛯⁁[5]ᄢ߈ߐࠍ⺞ᩏߒ㧘Ყセߒߚ⚿ᨐࠍ࿑ 6 ߦ␜ߔ[6]㧚
ᴫߥߤߦ㑐ߔࠆ⺞ᩏ⚿ᨐࠍㅀߴࠆ 㧚⹜㛎ߪ㧘ญᓘ 0.16[mm]ߩࡁ࠭࡞߆ࠄ 250[cc/h]ߩᵹ㊂ߢ᳓⚛ࠍ᡼಴ߒ㧘㔚᳇Ἣ⧎߿ዊⷙᮨߩἫἻ
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ዊἫἻߦࠃࠆ⌕Ἣ㧔ࡁ࠭࡞ญߦធ⸅㧕D  ਅᣇ߳ߩ᡼಴ἫἻ࿑  ╬ଔ⊒ᾲ㊂ߦ߅ߌࠆἫἻⷙᮨߩᲧセ⌕Ἣ⋥ᓟ      ⑽ᓟ     㧝⑽ᓟ㧔ࡁ࠭࡞ᓘOO㧘᡼಴ⷺᐲq㧘ᵹ㊂0ONJT㧕࿑  ᳓⚛⌕Ἣ⹜㛎㧔ࠪࡘ࡝࡯࡟ࡦ↹௝㧕

વᾲ 2009 ᐕ 4 ᦬- 29 -J. HTSJ, Vol. 48, No. 203

․㓸㧦᳓⚛ߩ‛ᕈ߅ࠃ߮᧚ᢱ
㖸࿶⸘㧘ⴣ᠄࿶ജ⸘㧘ᾲᵹ᧤⸘ࠍ⸳⟎ߒߡ⸘᷹ߒ
ߚ㧔࿑ 9 ෳᾖ㧕㧚߹ߚ㧘⌕Ἣߩ⁁ᴫࠍⷰኤߔࠆߚ߼㧘⿒ᄖ✢ᾲ↹௝ⵝ⟎ߦࠃࠆ᠟ᓇ߽ⴕ޿㧘ゞਔ๟ㄝߩἫἻߩ⁁ᘒߦߟ޿ߡ߽ⷰኤߒߚ㧚╬ଔ⊒ᾲ㊂ߩࡔ࠲ࡦߣ᳓⚛ߩ਄ะ߈ߩ᡼಴ἫἻࠍᲧセߔࠆߣ㧘࿑ 6(a)ߦ␜ߔࠃ߁ߦ㧘ห৻ࡁ࠭࡞
ᓘ߆ࠄࡔ࠲ࡦߣ᳓⚛ࠍ᡼಴ߒߡ⌕Ἣߐߖߚ㓙ߩἫἻߩ㐳ߐߪ߶߷ห৻ߦߥߞߡ޿ࠆ㧚߹ߚ㧘࿑ 6(b)ߦ␜ߔࠃ߁ߦ㧘ᶧ૕Άᢱߢ޽ࠆࠟ࠰࡝ࡦߣ߽Ყセߔࠆߚ߼㧘ࡔ࠲ࡦ㧘᳓⚛㧘ࠟ࠰࡝ࡦࠍਅᣇ߳᡼಴
ߐߖߚ႐วߩἫἻߩᄢ߈ߐ߽㧘᳓⚛߇․ߦᄢ߈ߊ
ߥࠆߣ޿ߞߚߎߣߪߥߊ㧘᳓⚛ࠍΆᢱߣߔࠆ⥄േゞߪࠟ࠰࡝ࡦゞ߿ᄤὼࠟࠬゞߣห᭽ߦᛒ߃ࠆߎߣ
߇ࠊ߆ߞߚ㧚
ᰴߦ㧘ゞਔࠍ૶↪ߒߚ᳓⚛ṳᵨ࡮⌕Ἣ⹜㛎ߩ৻ㇱߦߟ޿ߡㅀߴࠆ㧚

࿶ജ⸘
࿶ജ࠮ࡦࠨ

ᾲ㔚ኻ
ᾲ㔚ኻ

࿑  ゞਔߩ⸘᷹⁁ᴫ᳓⚛࡮Άᢱ㔚ᳰ⥄േゞߩ቟ోᕈ ᳓⚛ṳ߃޿ߦኻߔࠆ቟ోᕈ
᳓⚛࡮Άᢱ㔚ᳰ⥄േゞߦߪⴣ⓭⹜㛎ߩ㓙ߦ᳓⚛
ṳࠇ⸵ኈ㊂߇ⷙቯߐࠇߡ޿ࠆ㧚ߎߎߢߪ᳓⚛߇ゞਔߩ᳓⚛⾂⬿ࠪࠬ࠹ࡓ߆ࠄṳࠇ಴ߒ㧘ゞਔߩ৻ㇱߦṛ⇐ߒߡ⌕Ἣߒߚ㓙ߩ๟ㄝ߳ߩⵍኂߥߤߦ㑐ߔࠆ⺞ᩏ⚿ᨐ[7]ߦߟ޿ߡㅀߴࠆ㧚᳓⚛ṳᵨ࡮⌕Ἣ⹜㛎ߪ㧘࿑ 7 ߦ␜ߔ࠮࠳ࡦဳ㧔FRゞ㧦೨ㇱࠛࡦࠫࡦ࡮ᓟベ㚟േ㧕ߩ⃻ⴕࠟ࠰࡝ࡦゞࠍଏ⹜ゞਔߣߒߡ㧘ゞ૕ਅㇱߩࡎࠗ࡯࡞ࡌ࡯ࠬਛ
ᄩㇱ߆ࠄ᳓⚛ࠍ৻ቯᵹ㊂㧔5, 20, 50, 100, 131
NL/min㧕ߢ 10 ಽ㑆᡼಴ߒ㧘ࠛࡦࠫࡦ࡞࡯ࡓౝߩ
᳓⚛ߩಽᏓ⁁ᴫࠍ⺞ᩏߔࠆߣߣ߽ߦ㧘ࠛࡦࠫࡦࡈ
࡯࠼ਛᄩਅ 100[mm]ߩ૏⟎ߦขࠅઃߌߚὐἫⵝ⟎ߦࠃࠅ㧘᳓⚛ߦ⌕Ἣߐߖࠆᣇᴺߢⴕߞߚ㧚࿑  ゞਔ๟ㄝߩ⸘᷹⁁ᴫ᳓⚛ṳᵨ㊂ 131[NL/min]ߦ߅ߌࠆࠛࡦࠫࡦ࡞࡯
ࡓౝߩ᳓⚛Ớᐲߩ⸘᷹⚿ᨐࠍ࿑ 10 ߦ␜ߔ㧚

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㧔᳓⚛ṳᵨ㊂㧦0.OKPOKP㧕࿑  ࠛࡦࠫࡦ࡞࡯ࡓౝߩ᳓⚛Ớᐲゞਔᐩㇱ᳓⚛Ớᐲߦߟ޿ߡߪ㧘⹜㛎㐿ᆎ⚂ 100 ⑽ᓟ߹ߢߪჇട௑ะߦ޽ࠆ߇㧘ߘࠇએ㒠㧘᳓⚛᡼಴ࠍ஗ᱛ
ߔࠆ 600 ⑽߹ߢߪቯᏱỚᐲߦߥߞߡ޿ࠆ㧚᳓⚛ỚᐲಽᏓߦߟ޿ߡߪ㧘ࠛࡦࠫࡦ࡞࡯ࡓ਄ㇱߦ⋧ᒰߔࠆὐἫⵝ⟎ㄭறߩࠛࡦࠫࡦࡈ࡯࠼ਛᄩ߇㜞ߊߥߞ࿑  ゞਔਅㇱߩ᳓⚛ṳᵨ૏⟎ਥߥ⸘᷹㗄⋡ߣߒߡߪ㧘ゞਔ஥ߦߟ޿ߡߪ㧘ࠛࡦࠫࡦ࡞࡯ࡓౝߩ᳓⚛Ớᐲ߅ࠃ߮࿶ജߣߒ㧔࿑ 8ෳᾖ㧕㧘๟ㄝ߳ߩᓇ㗀ࠍ⺞ᩏߔࠆߚ߼㧘ゞਔ๟ㄝߦવᾲ 2009 ᐕ 4 ᦬- 30 -J. HTSJ, Vol. 48, No. 203

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ߡ޿ࠆ㧚৻ᣇ㧘ࠛࡦࠫࡦ࡞࡯ࡓਅㇱߦ⋧ᒰߔࠆ࡜ࠫࠛ࠲࡯ਅㇱߩ᳓⚛Ớᐲߪ㕖Ᏹߦૐߊߥߞߡ߅ࠅ㧘ṳࠇ಴ߒߚ᳓⚛߇਄ᣇߦṛ⇐ߒ߿ߔ޿᳓⚛᜛ᢔࠪࡒࡘ࡟࡯࡚ࠪࡦߩ⚿ᨐߣ৻⥌ߒߡ޿ࠆ㧚ࠛࡦࠫࡦࡈ࡯࠼ਛᄩㇱߩ᳓⚛Ớᐲ 23.8[%]ߪ㧘ⓨ᳇ਛߢߩ῜ߏ߁▸࿐ߦ౉ߞߡ߅ࠅ㧘⌕Ἣߐߖߚ႐
วߦߪゞਔࠍ⎕უߔࠆࠃ߁ߥ⁁ᘒߣߥࠆߎߣ߇੍
ᗐߐࠇࠆ㧚ߘߎߢ㧘600 ⑽ᓟߦ᳓⚛᡼಴ࠍ஗ᱛߐ
ߖࠆߩߣหᤨߦ㧘㔚᳇Ἣ⧎ߦࠃࠅ᳓⚛ߦ⌕Ἣߐߖߚ㓙ߩ㧘⿒ᄖ✢ᾲ↹௝ⵝ⟎ߦࠃࠆⷰኤ⚿ᨐࠍ࿑ 11ߦ␜ߔ㧚⿒ᄖ✢ᾲ↹௝ⵝ⟎ߦࠃࠆᤋ௝ߦߪ㧘ࡈࡠࡦ࠻ࠟ
࡜ࠬㄭறߣゞਔਅㇱߦ᳓⚛⌕Ἣߦࠃࠆ㜞᷷㗔ၞ߇᠟ᓇߐࠇߡ޿ࠆ㧚ߒ߆ߒߥ߇ࠄ㧘᳓⚛ṳ߃޿㊂
131[NL/min]એਅߩ㗔ၞߢߪ㧘᳓⚛⌕Ἣߦࠃࠆᓇ㗀ߣߒߡ㧘଀߃߫῜㘑࿶ߦࠃࠅࠛࡦࠫࡦࡈ࡯࠼߇ᄌ
ᒻߔࠆ㧘޽ࠆ޿ߪ็߈㘧߫ߐࠇࠆߣ޿ߞߚ⃻⽎ߪ↢ߓߥ߆ߞߚ㧚ኈེ߇⎕ⵚߔࠆߎߣߥߊ㧘ኈེౝߦᱷߞߡ޿ࠆ᳓
⚛߇ゞᄖߦ᡼಴ߐࠇࠆ᭴ㅧߦߥߞߡ޿ࠆ㧚ߘߩ㓙㧘᳓⚛ߪἫἻਛߦ᡼಴ߐࠇࠆߎߣߦߥࠆߎߣ߆ࠄ⌕Ἣߔࠆߎߣߦߥࠆ㧚৻⥸ߦ᳓⚛ࠟࠬߩΆ὾᷷ᐲߪ
㕖Ᏹߦ㜞᷷ߢ޽ࠅ㧘㍑᧼߽ṁ⸃ߐߖࠆߣ⸒ࠊࠇ㧘㜞᷷ߩΆ὾ࠟࠬߦࠃࠅ๟ㄝ߳ߩⵍኂࠍ᜛ᄢߐߖࠆ
߽ߩߣᗐ௝ߐࠇ߇ߜߢ޽ࠆߎߣ߆ࠄ㧘ታ㓙ߦゞਔἫἴ⹜㛎ࠍⴕ޿‫ࡦ࡝࠰ࠟߩⴕ⃻ޔ‬ゞ߿ᄤὼࠟࠬ⥄േゞߣ 35MPa ⥄േゞ↪࿶❗᳓⚛ኈེࠍ࠻࡜ࡦࠢ
ߦ 2 ᧄ៞タߒߚ᳓⚛⥄േゞߩἫἴ⹜㛎[8]ߩᦨᄢἫ
Ἳⷙᮨ㧔࿑ 12 ෳᾖ㧕߿ᾲᵹ᧤㧔࿑ 13 ෳᾖ㧕ߦࠃࠆᲧセࠍⴕߞߚ㧚C ࠟ࠰࡝ࡦゞD ᳓⚛⥄േゞ㧔᳓⚛᡼಴ᣇะ㧦਄ะ߈㧕㧔᳓⚛ṳᵨ㊂㧦0.OKP㧕࿑  ⌕Ἣ⹜㛎⁁ᴫ㧔⿒ᄖ✢ᾲ↹௝㧕E ᳓⚛⥄േゞ㧔᳓⚛᡼಴ᣇะ㧦ਅะ߈㧕᳓⚛ṳᵨ㊂ 131[NL/min]ߦ߅ߌࠆ๟ㄝ߳ߩᓇ㗀ߦߟ޿ߡߪ㧘ᾲᵹ᧤⸘ߩ⸘᷹⚿ᨐ߆ࠄ㧘ユ኿ᾲߦߟ޿ߡߪᄥ㓁߆ࠄฃߌࠆᾲ㊂ߩ 1 ഀએਅ㧘ⴣ᠄࿶ജߪᱴߤᬌ⍮ߐࠇߕ㧘㖸࿶ߦߟ޿ߡ߽ 120[dB]⒟ᐲߢ޽ࠅ㥏⤑߇៊்ߔࠆࠃ߁ߥ࡟ࡌ࡞ߦߪߥ߆ߞ
ߚ㧚એ਄ߩ⚿ᨐ߆ࠄ㧘ⴣ⓭⹜㛎ߢⷙቯߔࠆ᳓⚛ṳࠇ
⸵ኈ㊂ 131[NL/min]߇ゞਔߩ๟ㄝߦኻߒߡ߽లಽ
቟ోߥ࡟ࡌ࡞ߦ޽ࠆߎߣ߇⏕⹺ߢ߈ߚ㧚 ゞਔἫἴ⹜㛎ⴣ⓭੐᡿ߥߤߦࠃࠅ᳓⚛࡮Άᢱ㔚ᳰ⥄േゞ߇Ἣἴࠍ⿠ߎߒߚ㓙ߦߪ㧘Άᢱ࠲ࡦࠢߢ޽ࠆ⥄േゞ↪
࿶❗᳓⚛ኈེߩ⎕ⵚࠍ㒐ᱛߔࠆߚ߼ߦ㧘ኈེߦขࠅઃߌࠄࠇߚ቟ోᑯ߇⚂ 110͠ߦߥࠆߣ૞േߒ㧘વᾲ 2009 ᐕ 4 ᦬

F ᄤὼࠟࠬ⥄േゞ㧔ࠟࠬ᡼಴ᣇะ㧦ਅะ߈㧕࿑  ᦨᄢἫἻߩᲧセࠟ࠰࡝ࡦゞߩ႐ว㧘ࠟ࠰࡝ࡦ࠲ࡦࠢ߆ࠄ᳇ൻߔ
ࠆߥߤߒߡṳࠇ಴ߒߚࠟ࠰࡝ࡦ߇นΆ㔓࿐᳇ߦߥࠆߎߣߢ⌕Ἣ࡮Ά὾ࠍ㐳ᤨ㑆ߦࠊߚߞߡ➅ࠅ㄰ߒߥ߇ࠄหⷙᮨߩἫἻߩ⁁ᘒߢゞ૕ߩΆ὾߇ㅴ߻㧚৻ᣇ㧘ࠟࠬΆᢱߩ᳓⚛߅ࠃ߮ᄤὼࠟࠬ⥄േゞߩ႐

- 31 -J. HTSJ, Vol. 48, No. 203

․㓸㧦᳓⚛ߩ‛ᕈ߅ࠃ߮᧚ᢱ㪉2]
㪴Heatユ኿㪲㪢㪮㪆㫄
Flux [kW/m㪉2]㪴Heat ユ኿㪲㪢㪮㪆㫄
Flux [kW/m㪉2]㪴Heat ユ኿㪲㪢㪮㪆㫄
Flux [kW/m㪉
2]Heatユ኿㪲㪢㪮㪆㫄
Flux [kW/m㪴ว㧘ኈེ㧔Άᢱ࠲ࡦࠢ㧕ߦขࠅઃߌࠄࠇߚ቟ోᑯ
߇૞േ᷷ᐲ㧔⚂ 110͠㧕ߦ㆐ߒߚᲑ㓏ߢኈེౝߩ
ࠟࠬ߇ᄖㇱߦ᡼಴ߐࠇࠆߚ߼㧘቟ోᑯ૞േᤨߩἫ
Ἳ߇ᦨᄢⷙᮨߣߥࠆ㧚᳓⚛⥄േゞߩἫἻⷙᮨ㧔c㧕ߣᄤὼࠟࠬ⥄േゞߩἫἻⷙᮨ㧔d㧕ࠍᲧセߔࠆߣ㧘᳓⚛ߩΆ὾ㅦᐲ߇ㅦ޿ߚ߼㧘᳓⚛⥄േゞߩἫἻⷙᮨߪᄤὼࠟࠬ⥄േゞࠃࠅዊߐߊߥߞߡ޿ࠆ㧚ᰴߦ๟ㄝ߳ߩᓇ㗀ࠍᾲᵹ᧤ߦࠃࠅᲧセߔࠆ㧚

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Time
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ᤨ㑆 [min.]C ࠟ࠰࡝ࡦゞ
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ᤨ㑆䇭㪲ಽ㪴D ᳓⚛⥄േゞ㧔᳓⚛᡼಴ᣇะ㧦਄ะ߈㧕

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ᤨ㑆䇭㪲ಽ㪴
TimeE ᳓⚛⥄േゞ㧔᳓⚛᡼಴ᣇะ㧦ਅะ߈㧕
㪉㪌㪇 
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ᤨ㑆䇭㪲ಽ㪴
F ᄤὼࠟࠬ⥄േゞ㧔ࠟࠬ᡼಴ᣇะ㧦ਅะ߈㧕࿑  ᾲᵹ᧤ߩᲧセࠟ࠰࡝ࡦゞߩᾲᵹ᧤ߪ㧘Άᢱ࠲ࡦࠢ߆ࠄṳࠇ಴ߒߚࠟ࠰࡝ࡦ߳ߩ⌕Ἣ߇㐳ᤨ㑆ߦࠊߚߞߡ➅ࠅ㄰

વᾲ 2009 ᐕ 4 ᦬- 32 -

ߐࠇ㧘ᢿ⛯⊛ߦ㜞޿⁁ᘒ߇⊒↢ߒߡ޿ࠆ㧚৻ᣇ᳓⚛⥄േゞߪ㧘㧔b㧕ߦ␜ߔ਄ᣇ᡼಴ߩ႐ว㧘⚂ 17ಽ⚻ㆊᓟߩ቟ోᑯ૞േᤨߦᾲᵹ᧤ߩ਄᣹߇ߺࠄࠇ
ࠆ㧚㧔c㧕ߩਅᣇ᡼಴ߢߪ㧘቟ోᑯ૞േᤨߦᾲᵹ᧤
⸘߇ἫἻߩਛߦ౉ߞߡߒ߹޿৻⍍㜞޿ᾲᵹ᧤ࠍ␜
ߔ߇㧘ᄤὼࠟࠬ⥄േゞࠃࠅߪૐ޿୯ߣߥߞߡ޿ࠆ㧚ߎߩߎߣ߆ࠄ㧘ᾲᵹ᧤ߦࠃࠆἫἴᤨߩ᳓⚛⥄േゞߩ๟ㄝⵍኂ੍᷹ߣߒߡߪ㧘⃻ⴕߩࠟ࠰࡝ࡦゞ߿ᄤὼࠟࠬ⥄േゞߣᄢ߈ߊᄌࠊࠄߥ޿ߣ⠨߃ߡ޿ࠆ㧚ߚߛߒ㧘᳓⚛ߩΆ὾ߦࠃࠅ↢ߓࠆ㜞᷷᳓⫳᳇ߩ๟࿐߳ߩᓇ㗀ߦߟ޿ߡߪ㧘੹ߩߣߎࠈ⍮⷗ࠍ᦭ߒߡ޿ߥ޿㧚 ⥄േゞ↪࿶❗᳓⚛ኈེߩ቟ోᕈ
࿖ౝߩ⥄േゞ↪࿶❗᳓⚛ኈེߣߒߡߪ㧘㊄ዻ࡜ࠗ࠽࡯ࠍ CFRP㧔὇⚛❫⛽ᒝൻࡊ࡜ࠬ࠴࠶ࠢ㧕ߢᒝൻߒߚ VH3 ኈེ㧔ᶏᄖߢߪ Type-3㧕㧘ࡊ࡜ࠬ࠴࠶ࠢ࡜ࠗ࠽࡯ࠍ CFRP ߢᒝൻߒߚ VH4 ኈེ㧔ᶏᄖߢߪ Type-4㧕ߩ 2 ⒳㘃߇૶↪ߢ߈ࠆ㧚ߎࠇࠄߩኈ
ེߦߪ㧘࿶❗᳓⚛⥄േゞΆᢱⵝ⟎↪ኈེߩᛛⴚၮ
Ḱ㧔JARI S001㧕ߦࠃࠅ㧘⎕ⵚᒝᐲ㧘⠴ਭᕈ㧘ㆊ㉃᷷ᐲⅣႺਅߢߩ⠴ਭᕈߥߤ㧘ᄙߊߩ቟ోᕈߦ㑐ߔࠆ⹏ଔ㗄⋡߇޽ࠆ㧚৻ᣇߢ㧘೨ㅀߩ 2 ⒳㘃ߩኈེߪ৻⥸⊛ߦߪⶄวኈེߣ߽๭߫ࠇ㧘ߘߩ࡞࡯࠷ߪ
ァ੐↪ߦ㐿⊒ߐࠇߚ⿥シ㊂ኈེߦ┵ࠍ⊒ߔࠆࠃ߁ߢ޽ࠆ㧚ߒߚ߇ߞߡ㧘ᶏᄖߩⶄวኈེߩⷙᩰߦߪ
ࠟࡦࡈࠔࠗࡗ⹜㛎ߣ๭߫ࠇࠆᭂ߼ߡ㜞޿⽾ㅢജ߇޽ࠆᔀ↲ᒢ㧔࿑ 14 ෳᾖ㧕ࠍ૶↪ߒߡኈེࠍᛂߜᛮ
ߊ⽾ㅢ⹜㛎߇ណ↪ߐࠇߡ߈ߚ㧚એਅߢߪࠟࡦࡈࠔ
ࠗࡗ⹜㛎ߩ⚿ᨐߩ৻ㇱࠍ⚫੺ߔࠆ㧚







࿑  ࠟࡦࡈࠔࠗࡗ⹜㛎ߢ૶↪ߔࠆᔀ↲ᒢᶏᄖߢߩࠟࡦࡈࠔࠗࡗ⹜㛎ߪ㧘࿑ 15 ߩࠃ߁ߦ኿
᠄ᚻߦࠃࠆ࡜ࠗࡈ࡞㌂ࠍ૶↪ߒߚ኿᠄ߦࠃࠅታᣉ
ߐࠇߡ޿ࠆ㧚኿᠄ᚻߪ᳓⚛ࠍలߡࠎߒߚኈེ߆ࠄ
100[m]⒟ᐲ㔌ࠇߚ႐ᚲࠃࠅ㧘ኈེߦኻߒߡᢳ߼
45qߩ᳓ᐔᣇะ߆ࠄኈེࠍ⋥ធ኿᠄ߔࠆ㧚

J. HTSJ, Vol. 48, No. 203

․㓸㧦᳓⚛ߩ‛ᕈ߅ࠃ߮᧚ᢱ߃ࠆ㧚
3. Ꮧ⭯ߥ᳓⚛㧔Ớᐲ 10%⒟ᐲએਅ㧕ߪߎࠇ߹ߢ
⸒ࠊࠇߡ߈ߚ߶ߤෂ㒾ߢߪߥߊ㧘ᄤὼࠟࠬߥ
ߤઁߩนΆᕈࠟࠬߣห⒟ᐲߩෂ㒾ᕈߣ޿߃ࠆ㧚᳓⚛࡮Άᢱ㔚ᳰ⥄േゞ߇᥉෸ߔࠆߚ߼ߦߪ㧘ㆡᱜߥ቟ోᕈࠍ⏕଻ߒߟߟࠦࠬ࠻೥ᷫߣ೑ଢᕈߩะ
਄ࠍߪ߆ࠆᔅⷐ߇޽ࠆ㧚੹ᓟߪ᳓⚛࡮Άᢱ㔚ᳰ⥄േゞ↪ߣߒߡ㧘ࠃࠅㆡᱜߥ቟ోᕈࠍ⷗ᭂ߼ࠆߚ߼
ߦ㧘ߐࠄߦㆊ㉃ߥ⁁ᴫਅߢߩ⹜㛎࠺࡯࠲ߩขᓧ߇
ᔅⷐߦߥߞߡ߅ࠅ㧘ߘߩߚ߼ߩᵴേࠍ⃻࿷߽ㅴ߼ߡ޿ࠆ㧚࿑  ኿᠄ᚻෳ⠨ᢥ₂[1] ጤἑቁ㇌, Άᢱ㔚ᳰ⥄േゞታ⸽⎇ⓥߩᗧ⟵ߣᵴേ, ⥄േゞ⎇ⓥ╙ 30 Ꮞ ╙ 7 ภ,2008.7[2] ᳓⚛଻቟ᛛⴚࡂࡦ࠼ࡉ࠶ࠢ 㜞࿶ࠟࠬ଻቟ߦ
㑐ߔࠆᖱႎ⚫੺ No.94,㜞࿶ࠟࠬ଻቟දળ,1984
ᐕ 12 ᦬
[3] Shogo Watanabe et al., The New Facility for
Hydrogen and Fuel Cell Vehicle Safety Evaluation,2005 ICHS Proceeding[4] Yosuke Tamura et al., The Fire Tests with
High-Pressure Hydrogen Gas Cylinders for
Evaluating the Safety of Fuel-cell Vehicles, 2004
SAE Word Congress Proceeding (2004-01-1013)[5] Masashi Takahashi et al., Investigation of the
Allowable Flow Rate of Hydrogen Leakage on
Receptacle, 2008 SAE Word Congress Proceeding[6] Masashi Takahashi et al., Investigation of the
Allowable Amount of Hydrogen Leakage upon
Collision, 2005 SAE World Congress Proceeding(2005-01-1885)[7] Yasumasa Maeda et al., Test of Vehicle Ignition
Due to Hydrogen Gas Leakage, Jinji Suzuki,
Yohsuke Tamura, Shogo Watanabe, and Masaru
Takabayashi, Kenji Sato, Fire Safety Evaluationof a Vehicle Equipped with Hydrogen Fuel
Cylinders: Comparison with Gasoline and CNG
Vehicles,
2006
SAE
World
Congress
Proceeding(2006-01-0129)

࿑  ⽾ㅢ⋥ᓟߩ⁁ᴫࠟࡦࡈࠔࠗࡗ⹜㛎ߢߪ㧘ᒢਣ߇ኈེࠍ⽾ㅢߒ㧘ኈེ߇⎕ⵚߔࠆߎߣߥߊౝㇱߩ᳓⚛߇᡼಴ߐࠇࠆ
ߎߣࠍⷐ᳞ߒߡ޿ࠆ㧔࿑ 16 ෳᾖ㧕㧚৻ᣇ㧘᡼಴ߐࠇߚ᳓⚛ߩ߰ࠆ߹޿ߣߒߡߪ㧘㜞ㅦߢ᡼಴ߐࠇࠆ
᳓⚛߇Ꮺ㔚ߒ㧘⌕Ἣ࡮῜⊒ߣ޿ߞߚߎߣ߇ᗐ௝ߐ
ࠇ߇ߜߢ޽ࠆ߇㧘ታ㓙ߦߪ㧘࿑ 16 ߦ␜ߔ࿶ജ
35[MPa]㧘ౝኈⓍ 65[L]ߩࡊ࡜ࠬ࠴࠶ࠢ࡜ࠗ࠽࡯ߩ
VH4 ኈེߢ޽ߞߡ߽㧘᳓⚛߇᡼಴ߐࠇࠆ㓙ߦᏪ㔚ߒߡ⌕Ἣߔࠆߣ޿ߞߚ⃻⽎ߪߺࠄࠇߕ㧘චᢙ⑽ߢ
ౝㇱߩࠟࠬࠍోߡ᡼಴ߔࠆ⚿ᨐߣߥߞߚ㧚߅ࠊࠅߦ
ᧄႎ๔ߢߪ㧘NEDO ߆ࠄᆔ⸤ࠍฃߌߡ 2000 ᐕ
߆ࠄ JARI ߇ታᣉߒߡ߈ߚ᳓⚛ߘߩ߽ߩߩᕈ⾰߿᳓⚛࡮Άᢱ㔚ᳰ⥄േゞߩ቟ోᕈ⹏ଔ⹜㛎ߩ৻ㇱࠍ⚫੺ߒߚ㧚᳓⚛ߩ቟ోᕈ࡮ෂ㒾ᕈߦߟ޿ߡߪ㧘ߎࠇ߹ߢߩ
⎇ⓥᵴേߦࠃࠅ⥄േゞ↪Άᢱߣߒߡߩ᳓⚛㊂ߦ㒢
ቯߒߚ႐ว㧘એਅߩࠃ߁ߦ⠨߃ߡ޿ࠆ㧚
1. ᳓⚛ߪⓨ᳇ਛߢㅦ߿߆ߦ᜛ᢔߒนΆਅ㒢⇇એਅߦᏗ㉼ߐࠇࠆ㧚
2. ゞタኈེߩ቟ోᑯ߆ࠄߩ᡼಴᳓⚛ἫἻߪ⷗

વᾲ 2009 ᐕ 4 ᦬- 33 -J. HTSJ, Vol. 48, No. 203

․㓸㧦᳓⚛ߩ‛ᕈ߅ࠃ߮᧚ᢱ

⢻േ⊛ߥ὇⚛ᓴⅣࠛࡀ࡞ࠡ࡯ࠪࠬ࠹ࡓߩน⢻ᕈᬌ⸛
Feasibility Study of Active Carbon Recycle Energy Systemട⮮ ਯ⾆㧔᧲੩Ꮏᬺᄢቇ㧕
Yukitaka KATO (Tokyo Institute of Technology)
e-mail: yukitaka@nr.titech.ac.jpߪߓ߼ߦ
৻ᰴࠛࡀ࡞ࠡ࡯ߩᄙߊࠍᶏᄖߦ㗬ࠆࠊ߇࿖ߦߣ
ߞߡࠛࡀ࡞ࠡ࡯ߩଏ⛎቟ో଻㓚ߪ↥ᬺ࡮⚻ᷣ⊒ዷߩߚ߼ߦ㊀ⷐߢ޽ࠆ㧚ේᴤ࡮⾗Ḯଔᩰߩ㜞㛛ߦࠃࠆ⚻ᷣᷙੂߪᤨઍߦଐࠄߕ㧘ࠊ߇࿖ߩᄢ߈ߥ⺖㗴ߢ޽ࠆ㧚ᧄⓂߢߪ὇⚛ଏ⛎ߩⷰὐ߆ࠄࠛࡀ࡞ࠡ࡯
ଏ⛎቟ో଻㓚ߩ⏕┙ߦ߻ߌߡࠪࠬ࠹ࡓឭ᩺ࠍߔࠆ㧚↥ᬺߩߺߥࠄߕੱ㘃ߩ↢ᵴߦ߅޿ߡ὇⚛ߪΆᢱḮ㧘᧚ᢱ⚛᧚ߣߒߡᦨ߽᥉ㆉ⊛ߢ㊀ⷐߥࠛࡀ࡞ࠡ
࡯ᇦ૕ߢ޽ࠆ㧚ᜬ⛯⊛ߥ␠ળߩᒻᚑߩߚ߼ߦߪ὇
⚛ߩ቟ቯଏ⛎߇ᔅ㗇ߢ޽ࠆ㧚ࠊ߇࿖ߢ೑↪ߔࠆൻ⍹৻ᰴࠛࡀ࡞ࠡ࡯ߪ߶߷ో㊂ャ౉ߦଐሽߒߡ߅ࠅ㧘ߘߩᾲ㊂ߪోࠛࡀ࡞ࠡ࡯ߩ 82㧑㧔18.91018 J㧕ߦ⋧ᒰߔࠆ[1]㧚⍹ᴤ⵾ຠߣߒߡ೑↪ߐࠇࠆߩߪൻ⍹ࠛࡀ࡞ࠡ࡯ߩ 17㧑㧔3.31018 J㧕ߢ޽ࠅ㧘ᱷࠅߪΆᢱߣߒߡᾲḮߦ೑↪ߐࠇߡ޿ࠆ㧚৻ᣇߢ੩ㇺ⼏
ቯᦠ߇ 2005 ᐕߦ⊒ലߒ㧘ࠊ߇࿖ߪߘߩㆩ቞ߦ⟵ോ
ࠍ⽶޿㧘޿ࠃ޿ࠃᛮᧄ⊛ߥੑ㉄ൻ὇⚛㧔CO2㧕ឃ಴೥ᷫ߇ᔅⷐߣߥߞߡ޿ࠆ㧚⵾ㅧ↥ᬺ㧘ࠨ࡯ࡆࠬ↥ᬺߦߣߞߡ CO2 ឃ಴೥ᷫߪ὇⚛೑↪ߩ೙㒢ߦ⋥⚿ߒ㧘↥ᬺᵴേߩ஗ṛࠍ᜗ߊᄢ߈ߥ⺖㗴ߢ޽ࠆ㧚
ࠃߞߡ CO2 ߩឃ಴೥ᷫߣ὇⚛ଏ⛎቟ో଻㓚ߩਔ┙ߣ޿߁ࠫ࡟ࡦࡑ߇↥ᬺ⊒ዷߩ㊀ⷐߥ⺖㗴ߦߥߞߡ޿ࠆ㧚ߘߎߢ╩⠪ߪ὇⚛ࠍᓴⅣ೑↪ߔࠆࠛࡀ࡞ࠡ࡯ࠪ
ࠬ࠹ࡓࠍᬌ⸛ߒߚ㧚ᣢߦ⥄ὼߩᬀ‛⇇ߦ߅޿ߡࠞ
࡯ࡏࡦ࠾ࡘ࡯࠻࡜࡞ߣߒߡ὇⚛ᓴⅣ♽߇ሽ࿷ߔࠆ
߇㧘ߎߎߢߪ⢻േ⊛ߥ὇⚛ᓴⅣࠛࡀ࡞ࠡ࡯ࠪࠬ࠹
ࡓ㧔Active Carbon Neutral Energy System, ACRES㧕
ࠍឭ᩺ߒߚ㧚ACRES ߪੑ㉄ൻ὇⚛ࠍ὇ൻ᳓⚛ߦౣ↢ߒ㧘ౣ೑↪ߔࠆ߽ߩߢ޽ࠆ㧚ߎߩࠪࠬ࠹ࡓ߇ᚑ
┙ߔࠆߎߣߢ὇⚛߇♽ౝࠍᓴⅣౣ೑↪ߐࠇ㧘♽ᄖ߳ߩ CO2 ឃ಴ήߊࠛࡀ࡞ࠡ࡯ଏ⛎߇น⢻ߣߥࠅ㧘਄⸥ߩࠫ࡟ࡦࡑࠍ⸃᳿ߔࠆߎߣ߇ᦼᓙߢ߈ࠆ㧚ᧄ
Ⓜߢߪࠛࡦ࠲࡞ࡇ࡯෼ᡰߩⷰὐ߆ࠄ ACRES ߩᚑ┙น⢻ᕈࠍㅀߴࠆ㧚વᾲ 2009 ᐕ 4 ᦬- 34 -

#%4'5 ߩឭ᩺ ᣢሽࠛࡀ࡞ࠡ࡯ࠪࠬ࠹ࡓߣ #%4'5
ACRES ߩ૏⟎ઃߌࠍ␜ߔߚ߼ߦ㧘߹ߕᓥ᧪ߩࠛ
ࡀ࡞ࠡ࡯ᄌ឵ࠪࠬ࠹ࡓࠍ࿑ 1 ߦ␜ߔ㧚࿑ 1 (a)ߪ㧘ᓥ᧪ߩ⊒㔚ߢ↪޿ࠄࠇߡ߈ߚ⫳᳇ᯏ㑐ߢ޽ࠆ㧚ߎߩ♽ߢߪ᳓ߩ᳇ᶧ⋧ᄌൻࠍ೑↪ߒߡ޿ࠆ㧚౉ജࠛࡀ࡞ࠡ࡯ߢ᳓⫳᳇ࠍ↢ᚑߐߖ㧘⫳᳇߆ࠄ᳓ߦᚯࠆ
㓙ߩಝ❗ẜᾲࠍ઀੐ߣߒߡขࠅ಴ߒ㧘㔛ⷐ஥ߢ೑↪ߔࠆ㧚ߎࠇߦኻߔࠆㄭᐕߩᣂߒ޿ขࠅ⚵ߺߢ޽ࠆ㧘᳓⚛ࠛࡀ࡞ࠡ࡯ࠪࠬ࠹ࡓࠍ࿑ 1(b)ߦ␜ߔ㧚᳓ࠍ౉ജࠛࡀ࡞ࠡ࡯ߦࠃߞߡ㧘᳓⚛㧘㉄⚛ߦಽ⸃ߒ㧘᳓⚛߇᳓ߦᚯࠆ㓙ߩ෻ᔕ߆ࠄ઀੐ࠍขࠅ಴ߒߡ
޿ࠆ㧚᳓⚛ࠪࠬ࠹ࡓߩ⫳᳇ࠪࠬ࠹ࡓߦኻߔࠆ೑ὐ
ߪ㧘↢ᚑੑᰴࠛࡀ࡞ࠡ࡯㧔᳓⚛㧕ࠍ㐳ᦼ㑆៊ᄬήߊ⾂⬿ߢ߈ࠆߎߣ㧘ߘߒߡන૏㊂޽ߚࠅߩࠛࡀ࡞
ࠡ࡯ኒᐲ߇㜞ߊ㧘ࠦࡦࡄࠢ࠻㧘㜞ኒᐲߥࠛࡀ࡞ࠡ
࡯ࠪࠬ࠹ࡓࠍᒻᚑ߇น⢻ߢ޽ࠆ㧚ߒ߆ߒߥ߇ࠄ㧘᳓⚛ࠪࠬ࠹ࡓߩታ↪ࠍ⠨߃ࠆߣ㧘᳓⚛න૕⾂⬿ߢߪㆊᄢߥ࿶❗઀੐ࠍⷐߔࠆߎߣ㧘᳓⚛῜⊒࡝ࠬࠢ߇޽ࠆߎߣ㧘ߐࠄߦ᳓⚛߆ࠄߩ㔚᳇ࠛࡀ࡞ࠡ࡯ข
಴ߒߦߪΆᢱ㔚ᳰߩࠃ߁ߥⶄ㔀㧘㜞ଔߥ᳓⚛ᄌ឵ᛛⴚࠍⷐߔࠆߥߤߩ⺖㗴߇޽ࠆ㧚᳓⚛ࠪࠬ࠹ࡓ⎇ⓥ㐿⊒ߢߪߎࠇ߹ߢߦᄢ߈ߥᚑᨐ߇↢߹ࠇߡ޿ࠆ߇㧘␠ળ᥉෸ߩߚ߼ߩᛛⴚ⊛ᬌ⸛ߪ੹߽ᔅⷐߢ
޽ࠆ㧚
H2 + O2H2O(v)
Work, W

Energy,E

E

W

H2O(l)

H2O

Water phase change

Water decomposition /oxidation(a) Steam engine system(b) Hydrogen system࿑ 1 ࿷᧪ߩ᳓/᳓⫳᳇ߣ᳓/᳓⚛ࠛࡀ࡞ࠡ࡯ࠪࠬ࠹ࡓ

J. HTSJ, Vol. 48, No. 203

․㓸㧦᳓⚛ߩ‛ᕈ߅ࠃ߮᧚ᢱ
߅޿ߡ㧘CO2 ࿁෼ߦߪๆ෼㧘෼⌕㧔‛ℂๆ⌕㧘ൻቇ෻ᔕࠍ฽߻ⶄวๆ෼⃻⽎㧕ߩ೑↪߇޽ࠆ㧚࿁෼ߒߚ CO2 ߪๆ෼ᇦ૕߆ࠄಽ㔌ߔࠆㆊ⒟߇ᔅⷐߣߥ
ࠆ㧚‛⾰ಽ㔌ߦߪᾲߩ౉ജࠍⷐߔࠆ㧚ߎߩㆊ⒟ߢ
CO2 ߩ㜞Ớᐲൻ߇ⴕࠊࠇࠆ㧚࿁෼ߐࠇߚ CO2 ߪ὇ൻ᳓⚛ౣ↢ㆊ⒟ߦ߅޿ߡ὇ൻ᳓⚛ߦౣ↢ߐࠇࠆ㧚ౣ↢ㆊ⒟ߪๆᾲ෻ᔕߢ޽ࠅ㧘ᾲ౉ജࠍⷐߔࠆ㧚ߎߩࠪࠬ࠹ࡓߢߪ CO2 ࿁෼࡮ಽ㔌ࠛࡀ࡞ࠡ࡯㧔ES㧕ߣ㧘὇ൻ᳓⚛ౣ↢ࠛࡀ࡞ࠡ࡯㧔ER㧕ߩ✚๺ߪ೑↪
஥ߢᓧࠄࠇࠆ઀੐࡮ᾲ㧔EU㧕ߦኻߒߡᔅߕᄢ߈ߊ
ߥࠆ㧔౉ജࠛࡀ࡞ࠡ࡯(ES+ER) > ಴ജࠛࡀ࡞ࠡ࡯
㧚ࠃߞߡ㧘ߎߩࠪࠬ࠹ࡓߪࠛࡀ࡞ࠡ࡯ᶖ⾌ࠪ(EU)㧕
ࠬ࠹ࡓߢ޽ࠆ㧚ࠪࠬ࠹ࡓߩ᦭ലᕈߩ⹏ଔߦߪࠛࡀ
࡞ࠡ࡯෼ᡰߩᬌ⸛߇ᔅⷐߢ޽ࠆ㧚╩⠪߇ឭ᩺ߔࠆ ACRES ࠍ࿑ 2 ߦ␜ߔ㧚CO2 ߇ၮᐩ⁁ᘒߢ㧘ᔅⷐߦᔕߓߡ᳓ࠍ౒ߦ↪޿ࠆ㧚౉ജࠛࡀ࡞ࠡ࡯ߦࠃߞߡࠕ࡞ࠦ࡯࡞ࠍ฽߻὇ൻ᳓⚛
ࠍ↢ᚑߐߖࠆ㧚ㄭᐕߩ⸅ᇦᛛⴚࠍ↪޿ࠆߎߣߢ㧘↢ᚑᱠ⇐߹ࠅߦ೙㒢߇޽ࠆ߇㧘᳓⚛ࠍᷙวߒߡ
⒳‫ߩޘ‬὇ൻ᳓⚛ߩ૞ᚑ߇น⢻ߢ޽ࠆ[2]㧚ᓧࠄࠇߚ὇ൻ᳓⚛߇ CO2 ߣ᳓ߦᚯࠆ㓙ߩࠛࡀ࡞ࠡ࡯಴ജࠍ
೑↪ߢ߈ࠆ㧚หᤨߦ὇ൻ᳓⚛ߪൻቇ᧚ᢱ⚛᧚ߣߒߡ೑↪߇น⢻ߢ޽ࠆ㧚ߎߩࠪࠬ࠹ࡓߪ⾂⬿㧘ャㅍ߇ኈᤃߢ޽ࠆߎߣ㧚὇ൻ᳓⚛㘃ߪᾲḮ㧘㔚ജḮߦߥࠆߣߣ߽ߦ᧚ᢱ⚛᧚ߦߥࠅ߃ࠆ㧚὇ൻ᳓⚛㘃ߪᓥ᧪ߩ↥ᬺࠗࡦࡈ࡜ߢ⦟ߊ೑↪ߐࠇߡ߅ࠅ㧘ታ↪
ᕈ㧘೑↪ⷫ๺ᕈ߇㕖Ᏹߦ㜞޿ߎߣ߇೑ὐߦߥࠆ㧚ࠃߞߡ㧘߽ߒߎߩࠪࠬ࠹ࡓ߇ࠛࡀ࡞ࠡ࡯⊛ߦ㧘෻ᔕേജቇ⊛ߦᚑ┙ߔࠆߩߢ޽ࠇ߫㧘᥉෸߇ኈᤃߥ
৻⥸ᕈߩ޽ࠆࠛࡀ࡞ࠡ࡯ࠪࠬ࠹ࡓߦߥࠆߣᦼᓙ
ߢ߈ࠆ㧚὇⚛ᓴⅣࠛࡀ࡞ࠡ࡯ࠪࠬ࠹ࡓߪᬀ‛⇇ߢࠞ࡯ࡏࡦ࠾ࡘ࡯࠻࡜࡞ࠪࠬ࠹ࡓߣߒߡታ⃻ߒߡ޿ࠆ㧚ࡃࠗࠝࡑࠬࠍ↪޿ߚ὇⚛ᓴⅣࠛࡀ࡞ࠡ࡯ࠪ
ࠬ࠹ࡓ߇ࠞ࡯ࡏࡦ࠾ࡘ࡯࠻࡜࡞ߢ޽ࠅ㧘ℂᗐ⊛ߢ޽ࠆ㧚ߒ߆ߒࠊ߇࿖ߩᚲⷐࠛࡀ࡞ࠡ࡯ߦኻߒ㧘ࡃࠗࠝࡑࠬߪ㊂⊛ߦዋߥߊ㧘࿖ߩਥⷐࠛࡀ࡞ࠡ࡯ࠪ
ࠬ࠹ࡓ߳ߩ⊒ዷߪ࿎㔍ࠍ઻߁㧚ߘߎߢ㧘ߎߎߢߪ⢻േ⊛ߦ὇⚛ࠍᓴⅣߐߖࠆ὇⚛ᓴⅣࠛࡀ࡞ࠡ࡯
ࠪࠬ࠹ࡓ㧘ߔߥࠊߜ ACRES ࠍឭ᩺ߒ㧘ࠛࡀ࡞ࠡ࡯⊛ߥⷰὐ߆ࠄᚑ┙ᕈࠍᬌ⸛ߒߚ㧚

Recovery andseparation

Effluent CO2

Separated CO2
Regen. energy

Usage
Materials
EnergyRegeneration
Hydro carbon
Input E > output E

Carbon flow࿑ 3 ACRES ߩਃߟߩⷐ⚛ㆊ⒟ #%4'5 ߩࠛࡦ࠲࡞ࡇ࡯⹏ଔACRES ߩᚑ┙ᕈࠍ⹏ଔߔࠆߚ߼㧘ౕ૕⊛ߥ὇ൻ᳓⚛᧚ᢱߦߟ޿ߡࠛࡦ࠲࡞ࡇ࡯෼ᡰࠍᬌ⸛ߒߚ㧚 ࡔ࠲ࡦ♽ #%4'5ၮᧄ⊛ߥ὇ൻ᳓⚛ߣߒߡࡔ࠲ࡦߦߟ޿ߡవߕᬌ
⸛ߒߚ㧚࿑ 4 ߦࡔ࠲ࡦࠍኻ⽎ߣߒߚ ACRES ߩ᭴ᚑࠍ␜ߔ㧚೑↪ㆊ⒟ߦ߅޿ߡ㉄ൻߦࠃࠅΆ὾ᾲࠛ
ࡀ࡞ࠡ࡯(ᑼ(1))ࠍ↢ᚑߒ㧘᳓⫳᳇ᡷ⾰෻ᔕߢ᳓⚛
(ᑼ(2))߇⵾ㅧߢ߈ࠆ㧚ߐࠄߦ㊀วߦࠃࠅ㜞ಽሶ᧚ᢱߦᄌ឵(ᑼ(3))ߢ߈ࠆ㧚

CxHyOz + O2
W
Material

E

Recov./Sep. energy

CO2 + H2O
CO2 reduction/oxidation
Carbon dioxide system࿑ 2 ACRES ߩၮ␆᭎ᔨߩ᭴ᚑ
CH4+2O2 ψ CO2+4H2O
CH4+H2O ψ 4H2+CO2
xCH4 ψ (-CH2-)x + x/2H2

#%4'5 ߩ᭴ᚑACRES ߩࠪࠬ࠹ࡓ᭴ᚑࠍ࿑ 3 ߦ␜ߔ㧚ࠪࠬ࠹ࡓߪਃߟߩࡊࡠ࠮ࠬ߆ࠄߥࠆ㧚ߔߥࠊߜ὇ൻ᳓⚛೑↪ㆊ⒟㧘CO2 ࿁෼࡮ಽ㔌ㆊ⒟㧘὇ൻ᳓⚛ౣ↢ㆊ⒟ߢ޽ࠆ㧚὇ൻ᳓⚛ߪ೑↪ㆊ⒟ߦ߅޿ߡߪᾲḮ㧘᧚ᢱ⚛᧚ߩ෺ᣇߣߒߡ೑↪߇ߢ߈ࠆ㧚ࠛࡀ࡞ࠡ࡯ᶖ
⾌ᓟߩ὇⚛ߪ CO2 ߦߥࠆ㧚CO2 ࿁෼࡮ಽ㔌ㆊ⒟ߦ

વᾲ 2009 ᐕ 4 ᦬

(1)
(2)
(3)

CO2 ࿁෼㨯ಽ㔌ㆊ⒟ߦߪᵴᕈ὇㧘࠯ࠝ࡜ࠗ࠻ߥߤ
ߦࠃࠆ‛ℂๆ⌕㧘㉄ൻࠞ࡞ࠪ࠙ࡓߥߤߦࠃࠆൻቇ
ๆ⌕㧔ᑼ(4)㧕߇᦭ലߢ޽ࠆ㧚㉄ൻࠞ࡞ࠪ࠙ࡓߪ 500
㨪800͠ߩ㜞᷷ၞߢ CO2 ߩๆ෼߇น⢻ߢ޽ࠆߩߢ㧘- 35 -J. HTSJ, Vol. 48, No. 203

․㓸㧦᳓⚛ߩ‛ᕈ߅ࠃ߮᧚ᢱ
޽ࠆ 4mol ߩ᳓⚛⵾ㅧߦߪ㔚ജ߹ߚߪᾲൻቇ⊛ߥ᳓ߩಽ⸃߇೑↪ߢ߈㧘967 kJ/mol-CH4 ߇ᔅⷐߢ޽
ࠆ㧚ࡔ࠲ࡦൻߪ⊒ᾲ෻ᔕߢ޽ࠅ㧘165 kJ/mol-CH4߇ ᡼ ಴ ߐ ࠇ ࠆ 㧚 ᓧ ࠄ ࠇ ߚ ࡔ ࠲ ࡦ ߆ ࠄ 802
kJ/mol-CH4 ߩᾲ㊂߇ᓧࠄࠇࠆ㧚ߎߎߢᓴⅣࠪࠬ࠹
ࡓߢߩᛩ౉ࠛࡀ࡞ࠡ࡯㧔᳓⚛⵾ㅧࠛࡀ࡞ࠡ࡯㧕ߣᓧࠄࠇࠆ὇ൻ᳓⚛ߩᾲࠛࡀ࡞ࠡ࡯ߩᲧࠍᓴⅣ₸[-]ߣቯ⟵ߔࠆ㧚὇ൻ᳓⚛ߩ೑↪෻ᔕ႐ߢ㗼ᾲ៊ᄬήߊ CO2 ߩ㒰෰߇น⢻ߢ޽ࠆ㧚ൻቇᐔⴧ⊛ߦ߽ CO2 ߇ࠃࠅჇᄢߔ
ࠆᣇะ߳ߩ෻ᔕ߇ଦㅴߐࠇࠆߚ߼㧘ᱜ෻ᔕߩ෻ᔕ
ㅦᐲ㧘὇ൻ᳓⚛ᶖ⾌㊂ߩଦㅴലᨐ߽ᦼᓙߢ߈ࠆ[3]㧚
CaO+CO2 ψ CaCO3(4)

ࡔ࠲ࡦౣ↢ㆊ⒟ߦߪ㧘᳓ߩ㔚᳇ಽ⸃ߦࠃࠆ᳓⚛
↢ᚑ෻ᔕߣ㧘᳓⚛ߦࠃࠆ CO2 ࡔ࠲ࡀ࡯࡚ࠪࡦߩ 2Ბ㓏෻ᔕ㧔ᑼ(5)㧘(6)㧕߇᦭ലߢ޽ࠆ㧚
4H2O ψ 4H2+2O2
CO2+4H2 ψ CH4+2H2O
Recovery andseparation

ᓴⅣ₸ =

(5)
(6)

Recov./Sep. energy

CO2

Usage
4H2O

Regen. energy
4H2O
Regeneration

Materials

CH4

Energy2H2O+2O2

࿑ 4 ࡔ࠲ࡦ♽ ACRES ߩ᭴ᚑ

CO2+4H2, +2O2

-165 Thermally reversible
CH4+2H2O, +2O2

Metanation
Electricity+967 Water
decompositionCO2+4H2O(g)Work/heat-802
Oxidation

Partial pressure in equilibrium[HHV-kJ/mol-CO2]࿑ 5 ࡔ࠲ࡦ♽ ACRES ߩࠛࡦ࠲࡞ࡇ࡯෼ᡰ
ࡔ࠲ࡦ♽ ACRES ߩࠛࡦ࠲࡞ࡇ࡯෼ᡰࠍ࿑ 5 ߦ␜ߔ㧚὇⚛ 1 mol ޽ߚࠅߩౣ↢㧘೑↪ᤨߩᚲⷐࠛ
ࡦ࠲࡞ࡇ࡯㧔㜞૏⊒ᾲ㊂ၮḰ㧘HHV㧕ࠍ␜ߒߚ㧚࿁෼࡮ಽ㔌ᠲ૞ߩ઀੐ߪᚲⷐࠛࡀ࡞ࠡ࡯㊂߇ઁߩ
ㆊ⒟ߦᲧߴߡᲧセ⊛ዊߐߊ㧘߹ߚߪૐ᷷ឃᾲߩ೑
↪߇น⢻ߢ޽ࠆ㧚ߎߩᠲ૞ߩࠛࡀ࡞ࠡ࡯㊂ߩ⹏ଔߪਇ⏕ቯⷐ⚛߇ᄙ޿ߩߢ੹ᓟߩᬌ⸛⺖㗴ߣߒ㧘ߎߎߢߪ⋭⇛ߒߡ޿ࠆ㧚߹ߚ㧘὇ൻ᳓⚛ౣ↢ߦߪ᳓⚛ߩ೑↪ࠍၮḰߦ⹏ଔߒߚ㧚ࡔ࠲ࡦౣ↢ߦᔅⷐߢવᾲ 2009 ᐕ 4 ᦬(7)ࡔ࠲ࡦ♽ߩᓴⅣ₸ߪ 82.9%ߢ޽ࠅ㧘᳓⚛߆ࠄߩࡔ࠲ࡦ⵾ㅧߦ߅޿ߡࠛࡦ࠲࡞ࡇ࡯៊ᄬ߇޽ࠆ㧚ߒ߆ߒ࿶❗⾂⬿ߩ႐ว㧘᳓⚛ߩ⾂⬿࿶ജߦኻߒߡ㧘ࡔ࠲ࡦߪ 1/3 એਅߩ࿶ജߢห╬ߩᾲࠛࡀ࡞ࠡ࡯ࠍ
⾂⬿ߢ߈ࠆ㧚ࠃߞߡࡔ࠲ࡦߪ᳓⚛ߦኻߒߡ࿶❗઀੐ࠍシᷫߢ߈ࠆ㧚ᓴⅣࠛࡀ࡞ࠡ࡯ᇦ૕ߩല₸Ყセߪ㧘↪޿ᣇߣ⵬ᯏࠍ฽߼ߚ✚ว⊛ߥࠛࡀ࡞ࠡ࡯⹏
ଔ߽ᔅⷐߢ޽ࠅ㧘੹ᓟᬌ⸛ࠍⷐߔࠆ㧚
CO2/ࡔ࠲ࡦߩ෻ᔕ᷷ᐲߦኻߔࠆ෻ᔕᐔⴧ㑐ଥࠍ
࿑ 6 ߦ␜ߔ㧔Aspen plus ver. 11 ߢߩ UNIFAC ផ▚
ᴺߦࠃࠆ㧕㧚ߎߎߢߪᑼ(5)(6)ߩᒰ㊂෻ᔕ⚵ᚑ㧘ో
࿶ 100 kPa ߢߩ୯ࠍ᳞߼ߚ㧚CO2/ࡔ࠲ࡦߪ 500͠೨ᓟߢᾲ⊛ߦนㅒߢ޽ࠆߩߢ㧘ࡔ࠲ࡦ᳓⫳᳇ᡷ⾰࡮᳓⚛⵾ㅧߢߩߎߩ᷷ᐲၞߩᾲ࿁෼㧘߹ߚࡔ࠲ࡦ↢ᚑᤨߩ⊒ᾲࠛࡦ࠲࡞ࡇ࡯ࠍ೎ߩ෻ᔕࡊࡠ࠮ࠬߦ
ࠞࠬࠤ࡯࠼೑↪ߔࠆߎߣߢ㧘ࠛࡦ࠲࡞ࡇ࡯៊ᄬࠍ
ዊߐߊߔࠆߎߣ߇น⢻ߢ޽ࠆ㧚

Physical and chemical sorptions

Effluent CO2ౣ↢὇ൻ᳓⚛ߩ↢ᚑᾲᚲⷐ᳓⚛ߩ↢ᚑᾲ

0.7

CH4 rich

0.6

H2O

H2 richH2

0.5

4H2+CO2 <=> CH4+2H2O

0.4

Pini,CO2=20 kPa

CH4Pini,H2=80 kPa

0.3

Total P=100 kPa

0.2
CO

0.1
0

0

500

CO2
1000

1500

Reaction temperature [oC]

࿑ 6 CO2/ࡔ࠲ࡦߩ෻ᔕᐔⴧ㑐ଥ- 36 -J. HTSJ, Vol. 48, No. 203

․㓸㧦᳓⚛ߩ‛ᕈ߅ࠃ߮᧚ᢱ
ᓟ㧘CO ↢ᚑߦߪߐࠄߦᾲ౉ജ߇ᔅⷐߢ޽ࠅ㧘COߪ⋧ኻ⊛ߦ㜞ኒᐲߥࠛࡀ࡞ࠡ࡯ᇦ૕ߢ޽ࠆߣ޿߃
ࠆ㧚↥ᬺࡊࡠ࠮ࠬߦ߅޿ߡ㊀↪ߐࠇߡ޿ࠆᚲએߢ
޽ࠆ㧚ᓴⅣ₸ࠍ HHV ၮḰߢࡔ࠲ࡦ㧘
৻㉄ൻ὇⚛
㧔CO㧕㧘
ࠕ࡞ࠦ࡯࡞㘃ߩ὇ൻ᳓⚛ߦ㑐ߒߡ᳞߼ߚ㧚ᓴⅣ₸
ߪᄢ߈޿㗅ߦ㧘CO(104%) 㧪ࡔ࠲ࡁ࡯࡞(93%)
㧪 ࠛ࠲ࡁ࡯࡞(88%) 㧪ࡔ࠲ࡦ(83%)(8)

Recovery andseparationߢ޽ߞߚ㧚ᓴⅣ₸߇ᄢ߈޿߶ߤࠛࡦ࠲࡞ࡇ࡯෼
ᡰ߇㜞ߊ㧘᳓⚛߇ᜬߟࠛࡀ࡞ࠡ࡯ࠍή㚝ߥߊォ឵⾂⬿ߢ߈ࠆߎߣࠍᗧ๧ߔࠆ㧚ࡔ࠲ࡁ࡯࡞㧘ࠛ࠲ࡁ࡯࡞ߪᶧ૕Άᢱߣߒߡャㅍ㧘⾂⬿߇ኈᤃߢ޽ࠅ㧘⒖േ૕Άᢱߦ೑↪ߢ߈ࠆߎߣ߇ᄢ߈ߥ೑ὐߢ޽
ࠆ㧚ߘߒߡ৻㉄ൻ὇⚛ߪᦨ߽ᓴⅣ₸߇㜞ߊ㧔104㧑㧕
㧘᳓⚛ߦᲧߴߡ㜞ኒᐲߩࠛࡀ࡞ࠡ࡯ࠠࡖ
࡝ࠕߢ޽ࠆߣ޿߃ࠆ㧚߹ߚ㧘CO ೑↪ߪ↥ᬺࡊࡠ࠮ࠬߢ৻⥸⊛ߦ᥉෸ߒߡ߅ࠅ㧘᳢↪ᕈ߇㜞޿ࠛࡀ࡞ࠡ࡯ᇦ૕ߢ޽ࠆ㧚ߘߎߢ㧘એਅߢߪ CO ♽ߩ
ACRES ߩน⢻ᕈࠍᬌ⸛ߒߚ㧚COEnergy(H2O+)1/2O2

࿑ 7 ৻㉄ൻ὇⚛ ACRES ߩ᭴ᚑ

Thermally
regenerative+41

CO+H2O, +1/2O2

CO2+H2, +1/2O2

CO production
Work/Heat/
Reductant

Electricity
+242

-283
Oxidation

Water decomposition
CO2+H2O(g)[HHV-kJ/mol-CO2]࿑ 8 ৻㉄ൻ὇⚛♽ ACRES ߩࠛࡦ࠲࡞ࡇ࡯෼ᡰ

(9)
(10)
(11)

Partial pressure in equilibrium(12)߹ߚߪ㧘᳓ߩಽ⸃ߣ↢ᚑ᳓⚛ߦࠃࠆ CO2 ㆶరߩ
2 Ბ㓏෻ᔕ㧔ᑼ(13)㧘(14)㧕߇᦭ലߢ޽ࠆ㧚CO2 rich

CO rich
H2+CO2 <=> CO+H2O

0.5
CO2

0.4

Pini,CO2=50 kPa

Pini,H2=50 kPa

Total P=100 kPa

H2O

0.3
CH4

0.2

H2
CO

0.1
0

0

500

1000

1500

Reaction temperature [oC]

(13)
(14)

࿑ 9 CO2/CO ߩ෻ᔕᐔⴧ㑐ଥߎߩੑᲑ㓏෻ᔕߦߟ޿ߡߩ CO ♽὇⚛ᓴⅣࠪࠬ
࠹ࡓߩࠛࡦ࠲࡞ࡇ࡯෼ᡰࠍ࿑ 8 ߦ␜ߔ㧚᳓⚛↢ᚑ

વᾲ 2009 ᐕ 4 ᦬

Regen. energy(H2O)
Regeneration

Materials

0.6

H2OψH2+1/2O2
CO2+H2 ψCO+H2O

CO2

Usage

ౣ↢ߦߪ࿕૕㉄ൻ‛Άᢱ㔚ᳰᛛⴚࠍ↪޿ߚ㔚᳇
ಽ⸃ᴺ߇น⢻ߢ޽ࠆ[4]㧚
CO2ψCO+1/2O2

Recov./Sep. energy

Effluent CO2 ৻㉄ൻ὇⚛♽ #%4'5
ᓴⅣ₸ߩᲧセ⊛㜞޿ CO ߦߟ޿ߡ㧘ࡔ࠲ࡦ♽ߣหߓᬌ⸛ࠍⴕ߁㧚CO ߩ὇⚛ᓴⅣࠛࡀ࡞ࠡ࡯ࠪࠬ
࠹ࡓࠍ࿑ 7 ߦ␜ߔ㧚CO ߪ೑↪ㆊ⒟ߦ߅޿ߡ㉄ൻߦࠃࠆΆ὾ࠛࡀ࡞ࠡ࡯(ᑼ(9))㧘᳓⫳᳇ォ឵෻ᔕߢ᳓⚛ࠍ↢ᚑ(ᑼ(10))ߔࠆ㧚ߐࠄߦ᳓⚛㧘㉄⚛ߥߤߣߩ㊀วߦࠃࠅ㜞ಽሶ᧚ᢱߦᄌ឵(ᑼ(11))ߢ߈ࠆ㧚
CO+1/2O2 ψCO2
CO+H2O ψ H2+CO2
xCO+yH2+zO2 ψ CxH2yO(2z+x)

Physical and chemical sorptions

ᑼ(13)(14)ߩᒰ㊂෻ᔕ⚵ᚑ㧘ో࿶ 100 kPa ߢߩ෻ᔕ᷷ᐲߦኻߔࠆ෻ᔕᐔⴧ㑐ଥࠍ࿑ 9 ߦ␜ߔ㧚- 37 -J. HTSJ, Vol. 48, No. 203

․㓸㧦᳓⚛ߩ‛ᕈ߅ࠃ߮᧚ᢱ
ᇦ૕߇৻ᰴࠛࡀ࡞ࠡ࡯Ḯߦኻߒߡ㧘ࠛࡀ࡞ࠡ࡯㔛ⷐ஥ߦ೑ὐ߇޽ࠆ႐วߦଔ୯ࠍᜬߟ㧚ߣߊߦ COߪᣢሽߩࡊࡠ࠮ࠬ↥ᬺߦኻߒߡⷫ๺ᕈ߇㜞޿ߩߢ㧘⵾㋕㧘ൻቇࡊ࡜ࡦ࠻㧘㜞᷷ࡊࡠ࠮ࠬߦ߅޿ߡ CO♽ ACRES ߩᵴ↪ߩ႐߇ẜ࿷ߔࠆߣ⠨߃ࠄࠇࠆ㧚੹ᓟ㧘೑↪వߩ㐿⊒ߣᠲ૞ߩᦨㆡൻ߇ᔅⷐߢ޽ࠆ㧚

CO2/CO ෻ᔕߪ 700͠೨ᓟߢนㅒߢ޽ࠆ㧚ࠃߞߡ㧘
࿑ 8 ߢߩ CO ↢ᚑߩߚ߼ߦߪ 700͠એ਄ߩᾲ౉ജ
߇ᔅⷐߢ޽ࠆߎߣ߇ࠊ߆ࠆ㧚CO ♽ ACRES ߪ CO↢ᚑᤨߦߪ᳓⚛߆ࠄߩࠛࡦ࠲࡞ࡇ࡯ࠍో㊂೑↪ߢ߈ࠆ㧚߹ߚ㧘㜞᷷ࡊࡠ࠮ࠬߦࠃࠆ૛೾ឃᾲ߇޽ࠆ
႐วߦߪ CO ↢ᚑ෻ᔕߦᵴ↪ߢ߈㧘ࡊࡠ࠮ࠬߩ⋭ࠛࡀ࡞ࠡ࡯ൻ߇࿑ࠇࠆ㧚CO ߪ᳓⚛ߦᲧߴߡ㜞ࠛࡀ࡞ࠡ࡯ኒᐲߢ㧘߹ߚ㜞෻ᔕᵴᕈߥ෻ᔕᇦ૕ߣߒ
ߡ㧘ᣢሽ↥ᬺߦ߅޿ߡ᳓⚛ߦኻߒߡ⋧ኻ⊛ߦ⦟ߊ೑↪ߐࠇߡ߅ࠅ㧘ᣢሽ↥ᬺࡊࡠ࠮ࠬ߳ߩᔕ↪߇ኈᤃߢ޽ࠆ㧚ߎࠇࠄߩ㐳ᚲ߆ࠄ CO ߇ ACRES ߩ὇ൻ᳓⚛ᓴⅣᇦ૕ߩ╙৻୥⵬ߣ⠨߃ࠄࠇࠆ㧚
 #%4'5 ߩᗧ⟵
ACRES ߪᒰೋㅀߴߚࠃ߁ߦࠛࡀ࡞ࠡ࡯ᶖ⾌ࠪࠬ࠹ࡓߢ޽ࠆ㧚ACRES ߩଔ୯ߪ὇⚛ࠍᓴⅣ೑↪ߒ㧘ᄖㇱߦ CO2 ࠍឃ಴ߒߥ޿ࠛࡀ࡞ࠡ࡯ᄌ឵ࠪࠬ࠹ࡓ
ߣߒߡଔ୯߇޽ࠆ㧚ACRES ߩ૞േߦߪ CO2 ࠍឃ಴ߒߥ޿㕖ൻ⍹♽৻ᰴࠛࡀ࡞ࠡ࡯Ḯ߇ᔅ㗇ߢ޽ࠆ㧚೨┨߹ߢߩᬌ⸛ߢ㧘৻㉄ൻ὇⚛ᓴⅣࠨࠗࠢ࡞߇ᦨ
߽ࠛࡀ࡞ࠡ࡯ኒᐲ߇㜞ߊ㧘↥ᬺ᦭↪ᕈ߇ᦨ߽㜞޿㧚
700͠એ਄ߩ㜞᷷ᾲࠍᔅⷐߣߔࠆߎߣ߆ࠄ㧘㜞᷷ࠟࠬἹ㧔High Temperature Gas Reactor, HTGR㧕ဳߩේሶἹ߇৻ᰴࠛࡀ࡞ࠡ࡯ଏ⛎ᣇᴺߣߒߡ᦭↪ߢ޽ࠆ㧚ࠊ߇࿖ߢߪ⨙ၔ⋵ᄢᵞߦ㜞᷷Ꮏቇ⹜㛎⎇ⓥἹ
㧔 High Temperature engineering Test Reactor,
HTTR㧕߇޽ࠅ㧘਎⇇ᦨ㜞ߩ 950͠ߩේሶἹ಴ญ᷷
ᐲࠍቯᏱ⊛ߦ಴ജߔࠆߎߣ߇ߢ߈ࠆ[5]㧚ߎߩἹߪ
ᓴⅣᇦ૕ߦࡋ࡝࠙ࡓࠟࠬࠍ೑↪ߒߡ߅ࠅ㧘Ἱࠪࠬ࠹ࡓ᭴ᚑ߇◲ᤃߢ㧘੐᡿ᤨߩේሶἹ஗ᱛ߇ኈᤃߥ
೑ὐ߇޽ࠅ㧘100 MW ಴ജ⒟ᐲߩಽᢔ೑↪ะߌዊဳἹߣߒߡߩ↪ㅜߦㆡߒߡ޿ࠆ㧚ේሶജࠛࡀ࡞ࠡ
࡯ߪઁߩ㕖ൻ⍹Άᢱ♽ࠛࡀ࡞ࠡ࡯Ḯߦኻߒߡ␠ળ
㔛ⷐߦ㊂⊛ߦᔕ߃ࠆߎߣ߇ߢ߈㧘߆ߟ಴ജߩ቟ቯ
ߒߚଏ⛎߇น⢻ߥὐߦ೑߇޽ࠆ㧚CO ♽ ACRES ߢߪᑼ(14)ߩㆊ⒟ߢ HTGR ߆ࠄߩ㜞᷷৻ᰴࠛࡀ࡞ࠡ
࡯ࠍ೑↪ߢ߈ࠆ㧚ߎߎߢߪ㜞᷷ᾲࠍൻቇᄌൻߢ⋥ធ೑↪ߢ߈ࠆߚ߼㧘ᯏ᪾ᄌ឵ߦኻߒߡ㜞ല₸ߥᾲ೑↪߇ᦼᓙߢ߈ࠆ㧚ACRES ߪ HTGR ߩᣂߚߥᾲ
೑↪ᚻᴺߦ߽ߥࠅ߃ࠆ㧚
ACRES ߪ৻ᰴࠛࡀ࡞ࠡ࡯ᶖ⾌ࠪࠬ࠹ࡓߢ޽ࠆ
ߩߢ㧘৻ᰴࠛࡀ࡞ࠡ࡯ࠍ ACRES ߦㅢߔߎߣήߊ
⋥ធ㔛ⷐ஥ߢ೑↪ߔࠆᣇ߇ࠛࡀ࡞ࠡ࡯೑↪ല₸ߪၮᧄ⊛ߦ㜞߹ࠆ㧚ࠃߞߡ㧘ACRES ߪᄌ឵ߒߚ὇⚛

વᾲ 2009 ᐕ 4 ᦬- 38 -

 ߹ߣ߼ACRES ߩᚑ┙ᕈࠍࠛࡦ࠲࡞ࡇ࡯෼ᡰߩⷰὐ߆
ࠄᬌ⸛ߒߚ㧚ᚑ┙ߦߪ㔛ⷐ஥ߦㆡᔕߒߚᓴⅣ὇ൻ᳓⚛ᇦ૕ߩㆬᛯߣ㧘৻ᰴࠛࡀ࡞ࠡ࡯Ḯߩㆬᛯ߇㊀ⷐߢ޽ࠆ㧚ᧄⓂߢߪᓴⅣ₸ߩ⹏ଔ߆ࠄᓴⅣ὇ൻ᳓
⚛ᇦ૕ߣߒߡ CO㧘ࠛࡀ࡞ࠡ࡯Ḯߣߒߡ㊂⊛ߥචಽߐ߆ࠄේሶജࠍ↪޿ߚේሶജ೑↪ဳ CO ♽ACRES ࠍ╙৻୥⵬ߣߒߡឭ᩺ߔࠆ㧚৻ᣇߢ ACRES ߩ㐿⊒ߦߪ㧘ᒁ߈⛯߈ᓴⅣ὇ൻ᳓⚛ᇦ૕ߩᬌ⸛߇ᔅⷐߢ޽ࠆ㧚ࡔ࠲ࡦߪᣢሽߩ෻
ᔕᠲ૞ᛛⴚߢᲧセ⊛ኈᤃߦኻᔕ߇น⢻ߥᛒ޿߿ߔ
޿ᓴⅣᇦ૕ߢ޽ࠆ㧚ࡔ࠲ࡁ࡯࡞㧘ࠛ࠲ࡁ࡯࡞ߪᶧ
૕ߩߚ߼⒖േ૕೑↪ߩน⢻ᕈ߇޽ࠆ㧚߹ߚ㧘਄ㅀߩ CO ߪࠛࡀ࡞ࠡ࡯㧘‛⾰෺ᣇߩ↢↥߳᳓⚛ߦᲧߴߡ㜞ࠛࡀ࡞ࠡ࡯ኒᐲ㧘㜞෻ᔕᵴᕈߢኻᔕน⢻ߢ޽ࠅ↥ᬺ೑↪߻߈ߢ޽ࠆ㧚ⷐ⚛ᛛⴚߣߒߡੑ㉄ൻ὇⚛࿁෼ᛛⴚ㧘὇ൻ᳓⚛ౣ↢ᛛⴚߩ㐿⊒߇ᔅⷐߢ޽ࠆ㧚ේሶജ߇೑↪ߐࠇࠆߣߔࠇ߫㧘Άᢱല₸ߩ㜞޿㕟ᣂ⊛ේሶജᛛⴚ߽ᔅⷐߢ޽ࠆ㧚หᤨߦේሶ
ജ೑↪ࠪࠬ࠹ࡓߩଔ୯ߩℂ⸃᥉෸߇ᔅⷐߢ޽ࠆ㧚
ACRES ᥉෸ߦ߻ߌߡߪਥߦ὇ൻ᳓⚛೑↪↥ᬺಽ
㊁ߦ߅޿ߡᔕ↪వ㐿⊒ࠍᬌ⸛ߔࠆᔅⷐ߇޽ࠆ㧚ᧄឭ᩺ߪࠊ߇࿖ߩ CO2 ឃ಴೥ᷫߣ὇⚛ଏ⛎቟ో଻㓚ߩਔ┙ߩⷰὐ߆ࠄ᩺಴ߐࠇߚࠛࡀ࡞ࠡ࡯ࠪࠬ
࠹ࡓߢ޽ࠆ㧚੹ᓟ㧘Ꮏᬺ࡮⚻ᷣߩ቟ቯߒߚ⊒ዷࠍᜂ଻ߒ߁ࠆวℂ⊛ߥࠛࡀ࡞ࠡ࡯ࠪࠬ࠹ࡓ߇޿ࠃ޿
ࠃᦸ߹ࠇࠆ㧚ᧄឭ᩺߇ߘߩࠪࠬ࠹ࡓㆬᛯߩ৻୥⵬
ߣߥࠇ߫ᐘ޿ߢ޽ࠆ㧚ෳ⠨ᢥ₂
[1] ⚻ ᷣ ↥ ᬺ ⋭  ⾗ Ḯ ࠛ ࡀ ࡞ ࠡ ࡯ ᐡ , ‫╙ ޣ‬
201-1-3‫ޤ‬ᚒ߇࿖ߩࠛࡀ࡞ࠡ࡯ࡃ࡜ࡦࠬ࡮ࡈࡠ
࡯᭎ⷐ㧔2004 ᐕᐲ㧕,ࠛࡀ࡞ࠡ࡯⊕ᦠ 2006 ᐕ, ⚻ᷣ↥ᬺ⋭ (2006)[2] Kusama, H. et al., CO2 hydrogenation to ethanol
over promoted Rh/SiO2 catalysts, Catalysis
Today, 28 (1996) 261.

J. HTSJ, Vol. 48, No. 203

․㓸㧦᳓⚛ߩ‛ᕈ߅ࠃ߮᧚ᢱ
Hydrogen Energy, 32(2007), 3253.
[5] Fujikawa, S. et Al., Achievement of ReactorOutlet Coolant Temperature of 950°C in HTTR,[3] Kato, et. Al., Study on a Regenerative Fuel
Reformer for a Zero-Emission Vehicle System, J.
Chem. Eng. Japan, 36 (2003) pp. 860.
[4] Jensen, S et al., Hydrogen and synthetic fuelproduction from renewable energy sources, Int. J.

વᾲ 2009 ᐕ 4 ᦬

J. Nucl. Sci. Technol., 41(2004), 1245.

- 39 -J. HTSJ, Vol. 48, No. 203

․㓸㧦᳓⚛ߩ‛ᕈ߅ࠃ߮᧚ᢱ

㜞࿶࡮㜞᷷᧦ઙਅߩ᳓⚛ߩᾲ‛ᕈ⸘᷹
Measurements of Thermophysical Properties of Hydrogenat High Pressure and High Temperature⮮੗ ਍ᄦ㧔↥✚⎇㧕㜞↰ ଻ਯ㧔਻Ꮊᄢቇ㧕ᣂ㉿ ኡ⧷㧔↥✚⎇㧕Motoo FUJII(AIST) Yasuyuki TAKATA(Kyushu University) Kan-ei SINZATO (AIST)
e-mail: fujii-motoo@aist.go.jpߪߓ߼ߦ
᧪ࠆߴ߈᳓⚛ࠛࡀ࡞ࠡ࡯␠ળࠍ᭴▽ߔࠆߚ߼ߩ
ၮ⋚ᛛⴚߩ⏕┙ߦะߌߚ⎇ⓥߩផㅴࠍ⋡⊛ߣߒߚNEDO ੐ ᬺ 㧘‫ ޟ‬᳓ ⚛ వ ┵ ⑼ ቇ ၮ ␆ ⎇ ⓥ ੐ ᬺ ‫ޠ‬“Fundamental Research Project on Advanced Hydrogen
Science” ߩ৻Ⅳߣߒߡ㧘2006 ᐕ 7 ᦬ߦ‫ޟ‬᳓⚛᧚ᢱవ┵⑼ቇ⎇ⓥ࠮ࡦ࠲࡯㧔HYDROGENIUS㧕
‫਻߇ޠ‬Ꮊ
ᄢቇߩદㇺࠠࡖࡦࡄࠬߦ⸳┙ߐࠇߚ㧚ߎߩ⎇ⓥ࠮ࡦ
࠲࡯ߢߪ㧘᳓⚛ߩࠦࡦࡄࠢ࠻ߥャㅍ߿⾂⬿ᚻᲑࠍታ⃻ߔࠆߚ߼ߦ㧘 ᳓⚛ߩၮ␆⑼ቇߦ߅޿ߡᧂ⸃᳿ߩ
໧㗴㧘ߔߥࠊߜ㧘㊄ዻߩ᳓⚛ߦࠃࠆ⣀ൻ㧘᳓⚛㔓࿐᳇ਛߩ࠻࡜ࠗࡏࡠࠫ࡯㧘㜞᷷࡮㜞࿶ਅߩ᳓⚛ߩᾲ‛ᕈߥߤߦ㑐ߔࠆၮ␆⊛ߥ⎇ⓥࠍⴕߞߡ޿ࠆ㧚ਥⷐߥ⎇ⓥ࠹࡯ࡑߩ৻ߟߢ޽ࠆᾲ‛ᕈ⸘᷹ࠍᜂ߁‛ᕈ࠴࡯ࡓߦߪ㧘᳓⚛ߩ PVT㧔࿶ജ㧘ኈⓍ㧘᷷ᐲߩ㑐ଥ㧕࠺࡯࠲㧘Ყᾲ߅ࠃ߮㖸ㅦߥߤߩᾲജቇ⊛ᕈ⾰㧘☼ᐲ߿ᾲવዉ₸ߥߤߩャㅍ⊛ᕈ⾰㧘ߐࠄߦ᳓⚛ߩ᳓߳ߩṁ⸃ᐲ߿㜞࿶᳓⚛ਛߩ㜞ᴣὐࠟࠬߩ㔺ὐ╬ߩ‛ᕈ୯ࠍ㧘100ΜPa 㧘500°C ߹ߢߩ࿶ജ㧘᷷ᐲ▸࿐ߢ᷹ቯߔࠆߎߣ߇⺖ߖࠄࠇߡ޿ࠆ[1]㧚ߎࠇࠄߩ᷹ቯߪ
HYDROGENIUS ઃዻߩታ㛎᫟ߢⴕࠊࠇ㧘․ߦ㜞࿶ၞ㧔1MPa એ਄㧕ߢߩ⸘᷹ߪ․ᱶ઀᭽ߩ㜞࿶ታ㛎ቶౝߢⴕࠊࠇߡ޿ࠆ㧚ߎࠇ߹ߢߦᾲ‛ᕈ୯ߩ᷹ቯߦ↪޿ࠆ 100MPa ߹ߢߩ㜞࿶ኻᔕߩⵝ⟎߇޿ߊߟ߆ቢᚑߒ㧘⌕ታߦ࠺࡯࠲ߩขᓧ߇ⴕࠊࠇߡ޿ࠆ㧚ᧄⓂߢߪߎࠇࠄߩ᷹ቯߩ
ౝ㧘PVT ࠺࡯࠲㧘☼ᐲ㧘ṁ⸃ᐲ߅ࠃ߮ᾲવዉ₸ߦߟ޿ߡ㧘ߘࠇߙࠇ᷹ቯේℂ㧘᷹ቯᴺ߅ࠃ߮ⵝ⟎ߩ᭎ⷐࠍ⚫੺ߔࠆߣߣ߽ߦ᷹ቯ⚿ᨐߩ⧯ᐓ଀ࠍ␜ߔ㧚

1. Fill the sample into
the sample cell
Close286 㑐ଥߩ᷹ቯ ᣢሽߩ᷹ቯ୯
᳓⚛ߩᾲജቇᕈ⾰ߦ㑐ߔࠆ᷹ቯ୯ߪචಽߣߪ੔
߃ߕ㧘ᣂߒ޿ታ᷹୯ߩ㓸Ⓧ߇ᔅⷐߣߐࠇߡ޿ࠆ㧚
PVT ࠺࡯࠲ߦߟ޿ߡߪ㧘Michels [2,3]ࠄߩࠣ࡞࡯
ࡊߦࠃࠆ 98 K㨪423 K㧘300 MPa ߩ㗔ၞߦ߅ߌࠆ
వ㚟⊛ߥ᷹ቯ୯߇޽ࠆ㧚߹ߚ㧘1970 ᐕઍߦߪ☨࿖ߩࠬࡍ࡯ࠬࠪࡖ࠻࡞㐿⊒ߦ㑐ㅪߒߡ㧘ਃ㊀ὐ᷷ᐲ
ߢ޽ࠆ 14 K㨪300 K㧘100 MPa ߹ߢߩ㗔ၞߦ߅ߌવᾲ 2009 ᐕ 4 ᦬ࠆ૕♽⊛ߥ᷹ቯ߇ߥߐࠇߡ޿ࠆ[4, 5]㧚ߒ߆ߒ㧘423
K એ਄ߩ᷷ᐲၞߦ߅ߌࠆ᷹ቯ୯ߪᱴߤߥ޿㧚৻ᣇ㧘ߎࠇ߹ߢ᳓⚛ߩᾲ‛ᕈ⸘▚ߦᐢߊ↪޿ࠄࠇߡ޿ࠆ
Younglove [6]ߩ⁁ᘒᣇ⒟ᑼߪ㧘ㆡ↪▸࿐߇ 14 K㨪
400 K㧘121 MPa ߹ߢߦ㒢ቯߐࠇߡ޿ࠆ㧚ߎߩ▸࿐ࠍ⿥߃ߚ㜞᷷㧘㜞࿶ߩ‛ᕈ୯ߪ⵬ᄖߦࠃߞߡ⸘▚ߐࠇߡ޿ࠆ㧚2007 ᐕߦ Leachman [7]ߦࠃߞߡ 14 K
㨪1000 K㧘2000 MPa ߹ߢㆡ↪นߣߔࠆ⁁ᘒᣇ⒟ᑼ
߇ឭ᩺ߐࠇߡ޿ࠆ߇㧘ߎࠇ߽਄ㅀߩታ᷹୯㧘ߔߥࠊߜ㧘ᄢㇱಽ߇ 30 ᐕએ਄߽೨ߩ᷹ቯߢߒ߆߽⚐ᐲ
߇ 99.8%ߣૐ޿᳓⚛ߦኻߔࠆታ᷹୯ߦၮߠ޿ߚ߽
ߩߢ޽ࠆ㧚ᧄ⎇ⓥߢߪᦨ⚳⊛ߦᏱ᷷㨪500 °C㧘100
MPa ߹ߢߩ PVT ᷹ቯࠍⴕ߁㧚 ᷹ቯේℂ࡯ࡃ࡯ࡀ࠶࠻ᴺ࡯
ᧄ᷹ቯߩ᷷ᐲ࿶ജ▸࿐ߢߪ᳓⚛ߪ⿥⥃⇇⁁ᘒߦ޽ࠅ㧘
100 MPa ߩ㜞࿶ၞߢ߽ 25 °C ߢ 24.5 mol dm-3(= 49.4 kg m-3) ⒟ᐲߣኒᐲߪዊߐ޿㧚ߘߎߢ PVT
ߩ᷹ቯߦߪ㧘ૐኒᐲၞߢ᦭ലߢ㧘⹜ᢱߩలႯ⾰㊂߿ኈེߩ૕Ⓧࠍᱜ⏕ߦ᷹ቯߔࠆᔅⷐ߇ߥ޿೑ὐࠍ
߽ߟࡃ࡯ࡀ࠶࠻ᴺࠍណ↪ߔࠆ㧚ࡃ࡯ࡀ࠶࠻ᴺߦࠃࠆ᷹ቯᚻ㗅ࠍ Fig. 1 ߦ␜ߔ㧚ࡃ࡯ࡀ࠶࠻ᴺߢߪ⹜ᢱኈེ(A)㧘⤘ᒛኈེ(B)ߩᄢ
ዊ 2 ୘ߩኈེࠍ↪޿ࠆ㧚⹜ᢱኈེߦలႯߒߚ᳓⚛

sampleV2

constant
temperature
Close
V1

(A) sample cell

evacuated V3(B) expansion cell

2. Open the V1 andexpand the sample
Close

sample3. Evacuate the sample
in the expansion cell
Open
V1

V2
(A) sample cell

Close

sample

Close
V3(B) expansion cell

Figure 1 Procedures of the Burnett method.

- 40 -J. HTSJ, Vol. 48, No. 203

․㓸㧦᳓⚛ߩ‛ᕈ߅ࠃ߮᧚ᢱ
ࠍ⤘ᒛኈེߦ╬᷷⤘ᒛߐߖ㧘ᐔⴧ࿶ജࠍ᷹ቯߔࠆ㧚ߎߩᠲ૞ࠍ♽ౝߩ᳓⚛߇ℂᗐ᳇૕ߣ⷗ߥߖࠆ⒟ᐲ
ߦ࿶ജ߇ૐਅߔࠆ߹ߢ➅ࠅ㄰ߔߎߣߦࠃߞߡ㧘ฦ⤘ᒛᤨߦ߅ߌࠆ࿶❗ଥᢙ Z ߥࠄ߮ߦኒᐲρ ߇એਅߩᚻ㗅ߢ▚಴ߐࠇࠆ㧚ኈⓍ VA ߩ⹜ᢱኈེߦ⾰㊂ m ߩ⹜ᢱ߇᷷ᐲ T㧘
࿶ജ Pi-1 ߢలႯߐࠇߡ޿ࠆߣ߈㧘ታ࿷᳇૕ߩ⁁ᘒᑼߪ࿶❗ଥᢙ Zi-1 ࠍ↪޿ߡ㧘ᰴᑼߢ⴫ࠊߐࠇࠆ㧚Pi −1VA = Z i −1mRT(1)ߎߎߢ R ߪࠟࠬቯᢙ㧘ਅઃ߈ߩ i ߪ⤘ᒛ࿁ᢙࠍ⴫
ߔ㧚ߎߩ⹜ᢱࠍኈⓍ VB ߩ⤘ᒛኈེߦ╬᷷⤘ᒛߐߖࠆߣ㧘⁁ᘒᑼߪᰴᑼߢ⸥ㅀߐࠇࠆ㧚

Pi (VA + VB ) = Z i mRT(2)

Eq. (2) ࠍ Eq. (1)ߢഀࠆߣᰴᑼ߇ᓧࠄࠇࠆ㧚

Pi (VA + VB ) Z i=
Pi −1VA
Z i −1(3)ߎߎߢ㧘(VA + VB ) / VA = N ߣ߅޿ߡ(N ߪⵝ⟎ቯᢙ)㧘

Pi
Z
N= i
Pi −1
Z i −1(4)⹜ᢱኈེ߆ࠄ⤘ᒛኈེ߳ߩ╬᷷⤘ᒛࠍή㒢࿁ⴕߞߚߣߔࠆߣ㧘ℂᗐ᳇૕⁁ᘒߣߥࠅ㧘Z = 1 ߣߺߥߖ㧘⤘ᒛ೨ᓟߩ࿶ജᲧ߆ࠄ N ߇᳿ቯߢ߈ࠆ㧚N = limi →∞Z i Pi −1P= lim i −1→∞i
Z i −1 Pi
Pi(5)৻ᣇ㧘Eq. (4) ߦ߅޿ߡ㧘i = 1㨪n ߹ߢਔㄝࠍដߌ
วࠊߖࠆߣ㧘

Pn n Z nN =P0Z0(low pressure)(high pressure)(6)ߣߥࠆ㧚lim Zn = 1 ߣߔࠆߣ㧘ᰴᑼ߆ࠄೋᦼ࿶❗ଥn →∞ᢙ Z0 ߇᳞߹ࠆ㧚⎛P⎞ 1
lim ⎜⎜ n N n ⎟⎟ =
n→∞ P
⎝ 0
⎠ Z0

(7)

Z0 ߇᳞߹ࠆߣ㧘Zn ߪ Eq. (6)ࠃࠅ

⎛P⎞
Z n = Z 0 ⎜⎜ n N n ⎟⎟
⎝ P0
⎠

(8)

ߣߒߡ㧘ోߡߩ⤘ᒛㆊ⒟ߦ߅ߌࠆ࿶❗ଥᢙࠍ᳞߼
ࠆߎߣ߇ߢ߈ࠆ㧚ߒߚ߇ߞߡ㧘ኒᐲρ ߪᰴᑼߢ▚
಴ߐࠇࠆ㧚

ρ=

m
P
=
V ZRT

વᾲ 2009 ᐕ 4 ᦬

 ᷹ቯⵝ⟎ᧄ᷹ቯߢߪ㧘߹ߕᏱ᷷߆ࠄ 250 ºC ߹ߢߩ᷷ᐲ೙
ᓮ߇ߢ߈ࠆᶧ૕ᕡ᷷ᮏ߅ࠃ߮ 1 MPa ᧂḩߩૐ࿶ၞߩ᷹ቯ߇น⢻ߥⵝ⟎ࠍ⵾૞ߒ㧘᷹ቯᴺߩᅷᒰᕈࠍ
⏕⹺ߒߚߩߜ㧘 100 MPa ߹ߢߩ㜞࿶઀᭽ߩࡃ࡯ࡀ
࠶࠻ᴺ PVT ⵝ⟎ࠍ⵾૞ߒߚ㧚᷹ቯࠪࠬ࠹ࡓߩ᭎ⷐ
ࠍ Fig. 2 ߦ␜ߔ㧚࿶ജኈེ㧘㈩▤߅ࠃ߮ࡃ࡞ࡉߪ
ߔߴߡ㜞࿶઀᭽ߣߥߞߡ޿ࠆ㧚ᧄⵝ⟎ߪታ㛎᫟ߩ㜞࿶᳓⚛ታ㛎ኾ↪ߩታ㛎ቶߦ⸳⟎ߐࠇߡ޿ࠆ㧚㜞࿶ታ㛎ቶߦߪ 100 MPa ߩ㜞࿶᳓⚛ࠍ⵾ㅧߔࠆࠦࡦ
ࡊ࡟࠶ࠨ࡯߇޽ࠅ㧘㜞࿶᳓⚛ߪࠕࠠࡘࡓ࡟࡯࠲㧔ኈ
㊂ 100MPa, 1.0 l㧕ߦ⫾߃ࠄࠇࠆ㧚ⵝ⟎߳ߩ㜞࿶ࠟࠬߩଏ⛎ࠍߪߓ߼㧘ࡃ࡞ࡉᠲ૞╬ߪࠛࠕ࡯ࠕࠢ࠴
ࡘࠛ࡯࠲ߦࠃߞߡߔߴߡ㆙㓒ᠲ૞ߢⴕࠊࠇࠆ㧚
PVT ᷹ቯⵝ⟎ߦ߅ߌࠆ⹜ᢱኈེ(A)߅ࠃ߮⤘ᒛኈ
ེ(B)ߩౝኈⓍߪߘࠇߙࠇ㧘250 cc ߅ࠃ߮ 100 ccߢ޽ࠆ㧚࿶ജ᷹ቯߦߪ㜞♖ᐲߩ᳓᥏⊒ᝄᑼ࿶ജ࠮
ࡦࠨࠍ↪޿㧘ߘߩਇ⏕߆ߐߪ 0.01 %ߢ޽ࠆ㧚᷷ᐲߪᮡḰ⊕㊄ᛶ᛫᷹᷷૕ߣ♖ኒ⚖੤ᵹࡉ࡝࠶ࠫࠍ↪
޿ߡ ITS-90 ࿖㓙᷷ᐲ⋡⋓ߦḰ᜚ߒߚ᷹ቯࠍⴕߞ
ߡ޿ࠆ㧚


R

F

V13E
V17 K
L
G

Q
V11
V12
sample outlet V9 MV2
V10
V4
M
V6
V5
sample inlet V8
MV3
Q
sample inlet
V7

C
V1
D

MV1
V2
V3

B
J
J

P
A
I
H
N

O
A: sample cell
B: expansion cell
C: platinum resistance thermometer D: thermometer
E: thermometer bridge F: temperature controller G: DC power supply H: main heater
I: subheater J: stirrer
K: quartz pressure transducer L: digital pressure indicator
M: vacuum pump
N: vacuum pump O: constant temperature bath P: circulation bath
Q: pressure gauge R: personal computer V1䌾V17, MV1䌾3: valves
Figure 2 Outline of PVT measurement system.
 ᷹ቯ଀
᷹ቯᚻ㗅ߩ⏕⹺߿ⵝ⟎ߩஜోᕈࠍ⺞ߴࠆߚ߼ߦ㧘߹ߕࡋ࡝࠙ࡓ߅ࠃ߮⓸⚛ࠟࠬࠍ↪޿ߚ੍஻⊛᷹ቯࠍⴕ޿㧘⛯޿ߡ᳓⚛ߩ᷹ቯࠍⴕߞߚ㧚᳓⚛ߦߟ޿ߡߪ⃻࿷߽᷹ቯ࠺࡯࠲ࠍ⫾Ⓧߒߟߟ޽ࠆ߇㧘ߎࠇ߹ߢ᷷ᐲ 160 ºC ߢ࿶ജ 96.7MPa ߹ߢߩ᷹ቯ߇ߥߐ

(9)- 41 -J. HTSJ, Vol. 48, No. 203

․㓸㧦᳓⚛ߩ‛ᕈ߅ࠃ߮᧚ᢱ

μ=

0

20

40

60

80

100

P / MPaH2, 200.022 °C, 50 MPa
H2, 120.062 °C, 96 MPa

H2, 160.037 °C, 96 MPa
H2, 80.073 °C, 96 MPa

Leachman (2007, p-H 2), 160.037 °C
Leachman (2007, n-H 2), 160.037 °C
GERG (2007, n-H2), 160.037 °C
Michels (1959, normal), 100 °C, 125 °C, 150 °C
Michels (1941, normal), 100 °C, 125 °C, 150 °C
Wiebe (1938, normal), 100 °C, 200 °C, 300 °C
Bartlett (1928, normal), 99.85°C, 198.90°C, 299.10°C, 399.30 °C

Figure 3 Comparison of measured densities
with existing EOS and data.

Outlet⢻ߥ࿕૕ᕡ᷷ᮏࠍ㐿⊒ߒ㧘㜞᷷ၞߢߪቯኈⓍᴺߦ
ࠃࠆ᷹ቯࠍⴕ߁੍ቯߢ޽ࠆ㧚☼ᐲߩ᷹ቯ ᷹ቯේℂ ☼ᐲߩ᷹ቯߪ⚦▤ᴺࠍ↪޿ߡⴕ߁㧚ߎࠇߪ⚦▤ౝߩᵹ૕ߩᵹࠇ߇ Poiseuelle Flow ߢㄭૃߢ߈ࠆߎ
ߣࠍ೑↪ߒߚ᷹ቯᴺߢ޽ࠆ㧚⚦▤ౝߩᵹࠇ߇ℂᗐ⊛ߥ Poiseuelle Flow ߢ޽ࠆ႐ว㧘ᵹ૕ߩ☼ᐲμR ߪᰴᑼߢ᳞߼ࠄࠇࠆ[8]
πr 4 ΔP
(10)
μp =
8QL

ߎߎߢ㧘Tߪ⚦▤ඨᓘ㧘ΔP ߪ⚦▤ߦ߅ߌࠆ࿶ജ
㒠ਅ㧘Q ߪ⚦▤ࠍᵹࠇࠆ᳇૕ߩ૕Ⓧᵹ㊂㧘L ߪ⚦▤ߩ㐳ߐߢ޽ࠆ㧚ታ㓙ߩᵹࠇߪℂᗐ⊛ߥ߽ߩߣߪ
⇣ߥࠅ㧘ㆇേ㊂⵬ᱜ߿౉ญㄭறߩᵹേ⊒㆐ၞߩ⵬ᱜ߇ᔅⷐߢ㧘☼ᐲߪᰴᑼߢ▚಴ߐࠇࠆ㧚

વᾲ 2009 ᐕ 4 ᦬(11)ߎߎߢ㧘m ߪㆇേ㊂㧘 n ߪ⊒㆐ၞߩ⵬ᱜଥᢙߢ㧘ℂ⺰⊛ߥ⠨ኤߦࠃࠅ㧘ߘࠇߙࠇ 1.12 ߅ࠃ߮ 0.57
ߣߔࠇ߫ࠃ޿ߣߐࠇߡ޿ࠆ[9,10]㧚 ߒ߆ߒ㧘ᧄ᷹ቯߢߪᮡḰ⹜ᢱࠍ↪޿ߡ☼ᐲ᷹ቯࠍⴕ޿㧘ߎࠇࠄ
ߩ୯ࠍ৻⒳ߩⵝ⟎ቯᢙߣߒߡ᳿ቯߒߡ޿ࠆ㧚ߐࠄߦ㧘⚦▤ߦធ⛯ߔࠆ㈩▤ߦ߅ߌࠆ⒳‫ߩޘ‬࿶ജ៊ᄬࠍ⵬ᱜߔࠆᔅⷐ߽޽ࠅ㧘࿶ജ㒠ਅ߅ࠃ߮૕Ⓧᵹ㊂ߩ᷹ቯ୯ߦߎࠇࠄߩ⵬ᱜࠍⴕߞߡ☼ᐲࠍ▚಴ߒߚ㧚 ᷹ቯⵝ⟎ ⚦▤ᴺߦࠃࠆ☼ᐲ᷹ቯࠪࠬ࠹ࡓߩ᭎⇛ࠍ Fig.4
ߦ␜ߔ㧚⚦▤ߪࠟࠬߩᵹ౉ㇱߣ಴ญㇱߦ઀ಾࠄࠇ
ߚ㧘ౝᓘ 9mm㧘⡺ෘ 25mm ߩ౞╴⁁㜞࿶ኈེౝߦ
⸳⟎ߐࠇߡ޿ࠆ㧚ߎߩࠃ߁ߥ᭴ㅧߦߔࠆߎߣߢ㧘⚦▤⥄૕ߩ⠴࿶ᕈߪਇᔅⷐߢ㧘⍹⧷ࠟ࡜ࠬ⚦▤ࠍ૶↪ߢ߈ࠆ㧚⚦▤ߪ㐳ߐ 501.6mm㧘ౝᓘ 0.462mm㧘
⡺ෘ⚂ 0.25mm ߢ㧘ߎࠇࠄߩ୯ߪࠞ࠮࠻ࡔ࡯࠲߅
ࠃ߮᳓㌁లႯᴺߢ᷹ቯߒߚ㧚㜞࿶ࠟࠬߪࠦࡦࡊ࡟࠶ࠨ࡯಴ญߦ޽ࠆࠕࠠࡘࡓ
࡟࡯࠲߆ࠄଏ⛎ߐࠇ㧘⚦▤ࠍ⚻ߡᵹ㊂⸘ߢ⾰㊂ᵹ
㊂޽ࠆ޿ߪ૕Ⓧᵹ㊂߇᷹ቯߐࠇߚᓟឃ಴ߐࠇࠆ㧚⚦▤಴౉ࠅญߩ࿶ജᏅߪᏅ࿶⸘߹ߚߪ⛘ኻ࿶⸘ߢ᷹ቯߐࠇࠆ㧚Ꮕ࿶⸘ߩ⠴࿶߇ 8MPa એਅߢ޽ࠆߩ
ߢ㧘⃻࿷߹ߢߩߣߎࠈ 8MPa ߹ߢߩ᳓⚛ߩ☼ᐲ߇᷹ቯߐࠇߡ޿ࠆ㧚PC
Controlled by PC
P, TVacuum
P
P
T
Pump

Flow
P
meter

V
Heat
 Exchanger
V
RV
Capillary Tube

RV
V
V
V

Temperature Controlled Bath
Figure 4 Outline of viscosity measurement system.


1

-1
0

mρQ
πr 4 ΔP−
8Q (L + nr ) 8π (L + nr )Outlet

out

in

diff

Gas Supply

100(ρ exp - ρcal) / ρcalࠇ㧘ᦨ㜞᷷ᐲ 200ºC ߢߪ 50MPa ߹ߢߩ࠺࡯࠲߇ᓧ
ࠄࠇߡ޿ࠆ㧚ኒᐲߩ᷹ቯ୯ࠍᣢሽߩ᷹ቯ୯߅ࠃ߮
Younglove [6] ߩ⁁ᘒᣇ⒟ᑼߦࠃࠆ୯ߣᲧߴߚ⚿ᨐࠍ Fig. 3 ߦ␜ߔ㧚120 ºC ߩ႐ว㧘ᧄ᷹ቯ୯ߣ⁁ᘒᑼߩ୯ߩ஍Ꮕߪ 60 MPa ߢᦨᄢߣߥࠅ⚂ 0.7%᷹ቯ୯߇ዊߐ޿㧚 PVT ᷹ቯߦߟ޿ߡߪ 500 ºC ߹ߢߩ᷷ᐲ೙ᓮ߇น

6

5

2

1

7

4

3

 ᷹ቯ଀ ߹ߕ㧘⓸⚛ࠟࠬࠍ↪޿ߚ᷹ቯߦࠃߞߡⵝ⟎ߩஜోᕈࠍ⏕߆߼㧘ⵝ⟎ቯᢙࠍ᳿ቯߒߚ㧚᳓⚛ߩ᷹ቯߦ߅޿ߡ㧘㜞࿶ࠟࠬࠕࠠࡘࡓ࡟࡯࠲ߩኈ㊂߇ዊߐߊ㧘ቯᏱᵹߦࠃࠆ᷹ቯ߇࿎㔍ߥߎߣ߇್᣿ߒߚ㧚- 42 -J. HTSJ, Vol. 48, No. 203

․㓸㧦᳓⚛ߩ‛ᕈ߅ࠃ߮᧚ᢱ
ᵹ㊂᷹ቯࠍ૕Ⓧဳ߆ࠄ⾰㊂ᵹ㊂᷹ቯဳߦᄌᦝߒ㧘࿶ജᄌൻ߇✭߿߆ߢ޽ࠆߣߒߡ㧘ḰቯᏱ⁁ᘒߢߩ᷹ቯࠍ⹜ߺߚ㧚Fig.5 ߦ 8MPa એਅ㧘200 ºC ߹ߢߩ᳓⚛ߩ☼ᐲ᷹ቯ⚿ᨐߩ଀ࠍ␜ߔ㧚᷹ቯߪ౉ࠅญ࿶
ജ߇ 8MPa ߆ࠄᓢ‫ߦޘ‬ૐਅߔࠆ⁁ᴫߢߥߐࠇߡ޿
ࠆ㧚ᧄ᷹ቯ୯ߪ NIST ߩ୯ߦㄭ޿߇㧘࿶ജଐሽᕈ
ߦߟ޿ߡߪਇ⥄ὼߥ௑ะࠍ␜ߒߡ޿ࠆ㧚ߎߩߎߣߪḰቯᏱ⁁ᘒߢߪ♖ᐲߩ⦟޿᷹ቯߪߢ߈ߥ޿ߎߣ
ࠍᗧ๧ߒߡ޿ࠆ㧚 ☼ᐲ᷹ቯߩ♖ᐲࠍ㜞߼ࠆߚ߼ߦߪ㧘᷹ቯⵝ⟎ߩᡷㅧ߇ᔅⷐߢ㧘ࠕࠠࡘࡓ࡟࡯࠲⋥ᓟߦ࿶ജ⺞ᢛᑯ

Viscosity, ǴPa.s㪭㪧㪋㪟㫐㪻㫉㫆㪾㪼㫅㪮 㪫 㪧㪟㫀㪾㪿㩷㫇㫉㪼㫊㫊㫌㫉㪼㩷㪺㪼㫃㫃㪭㪤㪈㪪㪸㫄㫇㫃㪼㩷㫋㫌㪹㪼㪧㪭㪧㪍㪭㪤㪊 㪭㪧㪎

㪭㪤㪍

㪭㪧㪌
㪭㪤㪌
㪧㫃㫌㫅㪾㪼㫉
㫇㫌㫄㫇

㪭㪤㪋

㪭㪤㪎
㪺㪈
㫋㫆
㪭㪸㫇㫆㫉㫀㫑㪼㫉㪻㫉㪸㫀㫅(a) Apparatus for gas-liquid equilibrium
at high pressures.
㫋㫆㪪㪸㫄㫇㫃㪼㩷㫋㫌㪹㪼

200 oC㪟㪼㫃㫀㫌㫄㩷㪺㫐㫃㫀㫅㪻㪼㫉
㪭㪤㪌

o

㪺㪊

㪭㪤㪋

o

㪺㪈

㪺㪊 㪭㪤㪊㪺㪉 㪺㪉 㪭㪤㪈126 C

㪪㪺㫉㫆㫃㫃㩷㫇㫌㫄㫇㪩㫆㫋㪸㫉㫐㩷㫇㫌㫄㫇
㪭㪤㪎

㪧 㪫

㪭㪤㪏

㪭㪤㪉 㪭㪤㪍

100 C

9

㪭㪧㪉

㪛㫀㪸㫇㪿㫉㪸㪾㫄㩷㫇㫌㫄㫇o10㪭㪧㪑㩷㪧㫅㫌㪼㫄㪸㫋㫀㪺㩷㫍㪸㫃㫍㪼㪭㪤㪑㩷㪤㪸㫅㫌㪸㫃㫍㪸㫃㫍㪼㪮㪑㩷㪮㪸㫋㪼㫉㩷㫃㪼㫍㪼㫃㩷㪾㪸㫌㪾㪼㪫㪑㩷㪫㪿㪼㫉㫄㫆㩷㫉㪼㫊㫀㫊㫋㪼㫉㪧㪑㩷㪧㫉㪼㫊㫊㫌㫉㪼㩷㫋㫉㪸㫅㫊㪻㫌㪺㪼㫉㪚㪿㪼㪺㫂㩷㫍㪸㫃㫍㪼
㪭㪤㪉
㪭㪧㪊

㪧

㪭㪧㪈

㫍㪼㫅㫋

150 C

11

㪪㪸㪽㪼㫋㫐
㫍㪸㫃㫍㪼㪥㫀㫋㫉㫆㪾㪼㫅

Present works
Chapman-Enskog + Excess viscosity
NIST WebBook

13
12

㫍㪼㫅㫋

㪺㪋

㪺㪋 㪭㪤㪈㪇

㪭㪥㪈

㪭㪤㪐
㪺㪉

㪭㪤㪈㪈

㪨㫌㪸㪻㫉㫌㫇㫆㫃㪼㫄㪸㫊㫊㩷㫊㫇㪼㪺㫋㫉㫆㫄㪼㫋㪼㫉㪭㪤㪈㪉㪦㫉㫀㪽㫀㪺㪼
o

60 C

0

㪫㫌㫉㪹㫆
㫄㫆㫃㪼㪺㫌㫃㪸㫉㩷㫇㫌㫄㫇

2

4
6
Pressure, MPa㪚㫆㫃㪻㩷㫋㫉㪸㫇(b) Sample inlet and pre-treatment for mass
Spectrometry.

8

Figure 5 Measured viscosity of hydrogen.

Figure 6 Schematics of solubility measurement
System.

ࠍߟߌࠆߎߣ㧘㜞࿶ߦ⠴߃ࠆᏅ࿶⸘ࠍ㐿⊒ߔࠆߎߣ㧘♖ᐲߩ㜞޿ᵹ㊂᷹ቯࠍน⢻ߦߔࠆߎߣߥߤ⸃
᳿ߔߴ߈ᄙߊߩ⺖㗴߇ᱷߐࠇߡ޿ࠆ㧚ߒߚߣ߈ߩ᳓ࠍࠨࡦࡊ࡞ᶧߣߒߡណขߔࠆ㧚ᰴߦᶧਛߩ᳓⚛ߩࡕ࡞ಽ₸ࠍ྾㊀ᭂ⾰㊂ಽᨆ⸘ࠍ↪޿ߡ᷹ቯߔࠆ㧚ߘߩ㓙㧘ࠨࡦࡊ࡞ᶧߪ㊀㊂ࠍ᷹ቯߐࠇߚᓟ㧘⾰㊂ಽᨆ⸘ߦዉ߆ࠇࠆ೨ߦ᳇ൻེߢ᳇ൻ
ߐࠇ㧘ߐࠄߦࠟࠬਛߩ᳓ಽߪࠦ࡯࡞࠼࠻࡜࠶ࡊߢ
㒰෰ߐࠇࠆ㧚Fig.6 (a), (b) ߦߎߩࠃ߁ߥᚻ㗅ࠍታ⃻ߔࠆ᷹ቯⵝ⟎ߩ᭎⇛ࠍ␜ߔ. ࿑(a) ߪ㜞࿶ਅߢߩ᳇ᶧᐔⴧࠍ㆐ᚑߔࠆ♽ߢ㧘(b)ߪࠨࡦࡊ࡞ᶧߩᚑ
ಽࠍಽᨆߔࠆ♽ߢ޽ࠆ㧚⾰㊂ಽᨆ⸘߇␜ߔᚑಽାภߩ⛘ኻᒝᐲߪ⒳‫ߩޘ‬ⷐ࿃ߦࠃߞߡᓇ㗀ࠍฃߌࠆ㧚ߒߚ߇ߞߡ㧘ᧄ᷹ቯߢߪࡋ࡝࠙ࡓ He ࠍෳᾖࠟࠬߣߒߡ↪޿㧘᳓⚛ߩᒝᐲࠍ He ߩᒝᐲߦ⋧ኻ⊛ߥ୯ߣߒߡ᷹ቯߔࠆ㧚 ⚐᳓߳ߩ᳓⚛ṁ⸃ᐲߩ᷹ቯ଀
 Fig. 7ߦ᷷ᐲ 25°C ߦ߅ߌࠆṁ⸃ᐲߩ࿶ജଐሽ
ᕈࠍ␜ߔ㧚ṁ⸃ᐲߪ࿶ജ߇㜞ߊߥࠆߦߟࠇߡ㧘ૐ࿶㗔ၞߢᚑ┙ߔࠆࡋࡦ࡝࡯ߩᴺೣ߆ࠄ஍୦ߒ㧘⋧ኻ⊛ߦዊߐߊߥࠆ㧚ߘߒߡ㧘ߎߩ᷷ᐲၞߢߪᣢሽ

᳓⚛ࠟࠬߩṁ⸃ᐲߩ᷹ቯ
᳓⚛ࠛࡀ࡞ࠡ࡯೑↪ߦ߅ߌࠆฦⷐ⚛ᛛⴚߦ߅ߌ
ࠆ቟ోᕈ㧘ᯏ⢻ᕈ㧘⠴ਭᕈࠍ⹏ଔߔࠆ਄ߢ᳓⚛ࠟࠬߩ⒳‫ߦ⾰‛ߩޘ‬ኻߔࠆṁ⸃ᐲߪ㕖Ᏹߦ㊀ⷐߥ‛ᕈ୯ߢ޽ࠆ㧚ߎߎߢߪ㜞࿶᳓⚛ߩ᳓ߦኻߔࠆṁ⸃ᐲߩ᷹ቯ଀ࠍ␜ߔ㧚 ᷹ቯේℂ߅ࠃ߮ⵝ⟎᳓ߦኻߔࠆ᳓⚛ߩṁ⸃ᐲφߪṁ⸃᳓⚛ߩࡕ࡞ಽ₸ߢቯ⟵ߐࠇ㧘ᰴᑼߢ⴫ࠊߐࠇࠆ
φ = nH 2 (nH 2 + nH 2 O )(12)ṁ⸃ᐲߩ᷹ቯߪ㧘᷷ᐲ㧘࿶ജ߇⸳ቯߐࠇߚ㜞࿶ኒ㐽࠮࡞ౝߦኻ⽎ߣߥࠆ⚐᳓߅ࠃ߮᳓⚛ࠟࠬࠍኽ౉
ߒ㧘᳓ࠍᓴⅣߐߖߡ᳓⚛㧙᳓ߩ᳇ᶧᐔⴧ⁁ᘒߦ㆐

વᾲ 2009 ᐕ 4 ᦬㪭㪸㫇㫆㫉㫀㫑㪼㫉- 43 -J. HTSJ, Vol. 48, No. 203

․㓸㧦᳓⚛ߩ‛ᕈ߅ࠃ߮᧚ᢱ
ߩ᷹ቯ⚿ᨐ[11,12]ߣ߆ߥࠅ⦟ߊ৻⥌ߔࠆ⚿ᨐ߇ᓧࠄࠇߡ޿ࠆ㧚ṁ⸃ᐲߦ㑐ߒߡߪ㧘੹ᓟ㧘᳓એᄖߩ⒳‫⾰‛ߩޘ‬ߦኻߔࠆ᷹ቯࠍ⸘↹ߒߡ߅ࠅ㧘࿕૕ౝߩࡊࡠ࠻ࡦ

4500

6

Solubility φ×10 (mol/mol)

4000

Extrapolation of low pressure relation
Fit (Vap.-Liq. Equilibrium / k = -1.52)

3500
3000
2500
2000
1500
1000
500
0
0

Present Study
Wiebe,R. et al. (1934)
Suciu,S. et al. (1951,1952)

10
20
Pressure (MPa)30

Figure 7 Hydrogen solubility in water withvarying pressure at 25°C.
Ớᐲࠍ⸘᷹ߢ߈ࠆࠃ߁ߦᡷㅧࠍ⚳߃ߚ NMR ⵝ⟎ࠍ↪޿ߡ㧘㜞ಽሶ᧚ᢱߔߥࠊߜ㧘ࠧࡓ᧚ᢱ߿㜞ಽሶ㔚⸃⾰߳ߩ᳓⚛ṁ⸃ᐲࠍ᷹ቯߔࠆ੍ቯߢ޽ࠆ㧚ᾲવዉ₸ߩ᷹ቯ᳓⚛ߩᾲવዉ₸ߩ᷹ቯ୯ߪߘߩᄢㇱಽ߇ૐ᷷㗔ၞߦ㒢ࠄࠇߡ޿ߡ᷹ቯᐕઍ߽ฎ޿[13,14]㧚ᦨㄭߢߪ 1987 ᐕߦ 10MPa, 150°C ߹ߢߩ᷹ቯ଀[15]߇ႎ
๔ߐࠇߡ޿ࠆ߽ߩߩ㧘㜞᷷࡮㜞࿶ၞߦ߅ߌࠆᾲવ
ዉ₸ߪ Enskog ℂ⺰ߦࠃߞߡૐ᷷࡮ૐ࿶ၞߩ୯߆ࠄ
ផ▚ߐࠇࠆ୯߇↪޿ࠄࠇߡ޿ࠆ㧚ᧄ⎇ⓥߢߪ㧘㜞᷷࡮㜞࿶ၞߢ᳓⚛ߩᾲવዉ₸ࠍ㜞♖ᐲߢ᷹ቯߒ㧘᷷ᐲ㧘࿶ജ߳ߩଐሽᕈࠍ᣿ࠄ߆ߦߔࠆ㧚 ᷹ቯᣇᴺ
᷹ቯᴺߣߒߡߪ㧘ᵹ૕ߩᾲવዉ₸ࠍ♖ᐲ⦟ߊ᷹ቯߢ߈㧘ᄙߊߩ᷹ቯ଀߇޽ࠆ㕖ቯᏱ⚦✢ടᾲᴺߣ
ේℂ⊛ߦߪหߓߢ޽ࠆ߇㧘ዋ㊂ߩ⹜ᢱߦㆡ↪ߢ߈ࠆ㕖ቯᏱ⍴⚦✢ടᾲᴺ[16]ࠍ↪޿ࠆ㧚ߎߩᣇᴺߪ㧘ㅢᏱߩ⚦✢㐳ߐ(ࠕࠬࡍࠢ࠻Ყ l/d >104)ࠍᭂ┵ߦ⍴ߊ(l/d~103)ߒߚ߽ߩߢ㧘⚦✢┵ㇱߩᓇ㗀ࠍߢ߈ࠆߛ
ߌ෩ኒߦ⠨ᘦߔࠆߚ߼㧘㜞♖ᐲߩᢙ୯⸃ᨆ⚿ᨐߦၮߠ޿ߡᾲવዉ₸߅ࠃ߮ᾲ᜛ᢔ₸ࠍ▚಴ߔࠆ߽ߩ

વᾲ 2009 ᐕ 4 ᦬ߢ޽ࠆ㧚㕖ቯᏱ⍴⚦✢ടᾲᴺߪዊߐ޿⹜ᢱኈེ߇
૶↪ߢ߈㧘ࡊࡠ࡯ࡉߩࠦ࡯࠹ࠖࡦࠣ߇ኈᤃߦߥࠆ
ߚ߼ዉ㔚ᕈᵹ૕߿⣣㘩ᕈᵹ૕߳ㆡ↪ߢ߈ࠆߣ޿߁
․ᓽࠍ߽ߟ㧚ߒ߆ߒ㧘᳓⚛ߪઁߩᵹ૕ߣߪᄢ߈ߊ
⇣ߥࠅ㧘ᾲવዉ₸߇ⓨ᳇ߦᲧߴ 1 ᩴ߶ߤᄢ߈ߊ㧘ᾲ᜛ᢔ₸ߪ㊄ዻਗߺߦᄢ߈޿㧚ߘߩߚ߼㧘㕖ቯᏱ⍴⚦✢ടᾲᴺࠍ᳓⚛ࠟࠬߦㆡ↪ߔࠆ㓙ߦߪ․೎ߥ
Ḱ஻߇ᔅⷐߦߥࠆ㧚߹ߕ㧘ᢙ୯⸃ᨆߦ߅ߌࠆႺ⇇᧦ઙߩᅷᒰᕈߩᬌ⸛߇ᔅⷐߢ޽ࠅ㧘ߐࠄߦᅷᒰߥ
Ⴚ⇇᧦ઙߦㆡวߔࠆ⹜ᢱኈེߩኈ㊂߿ࡊࡠ࡯ࡉኸ
ᴺࠍᢙ୯⸃ᨆ⚿ᨐߦၮߠ޿ߡㆡಾߦ᳿ቯߔࠆߎߣ
߇㊀ⷐߣߥࠆ㧚ߎࠇࠄߩ੐㗄ࠍ⹦⚦ߦᬌ⸛ߔࠆߚ
߼ߩᣂߒ޿ᢙ୯⸃ᨆᴺ߇㐿⊒ߐࠇߡ޿ࠆ[17,18]㧚
 ᷹ቯⵝ⟎
Fig.8(a) ߦᾲવዉ₸᷹ቯࠪࠬ࠹ࡓߩ᭎ⷐࠍ␜ߔ㧚ⵝ⟎ߪ⍴⚦✢ࡊࡠ࡯ࡉ߇ᝌ౉ߐࠇߚ⹜ᢱኈེ㧔ࠬ࠹ࡦ࡟ࠬ⵾⠴࿶ኈེ㧘ౝᓘ 30mm㧘ᷓߐ 40mm㧕㧘⋥ᵹ㔚Ḯ㧘2Ch. 24bit AD ࡏ࡯࠼߅ࠃ߮ᮡḰᛶ᛫ེ߆ࠄᚑࠆ㧚⹜ᢱኈེߪࠪ࡝ࠦࡦࠝࠗ࡞ߩᕡ᷷ᮏౝ
ߦᶐẃߐࠇࠆ㧚᷹ቯߩࠪ࡯ࠤࡦࠬ߿ାภߩ᝼ฃߪ
ߔߴߡ PC ߦࠃࠅ⥄േ⊛ߦ೙ᓮߐࠇࠆ㧚Fig.8(b) ߪ⍴⚦✢ࡊࡠ࡯ࡉߩ౮⌀ߢ޽ࠆ㧚⍴⚦✢ߪ⋥ᓘ 10μm,
㐳ߐ⚂ 15mm ߩ⊕㊄✢ߢ㧘⋥ᓘ 1.5mm ߩ⊕㊄࡝࡯(a) Outline of measuring system.

(b) Photos of short hot wire probe.
Figure 8 Apparatus of thermal conductivity
Measurement.

- 44 -J. HTSJ, Vol. 48, No. 203

․㓸㧦᳓⚛ߩ‛ᕈ߅ࠃ߮᧚ᢱ
߮ d ߩᩞᱜ୯߇ᓧࠄࠇࠆ㧚 ߔߥࠊߜ㧘࠼┵ሶߦṁ⌕ߐࠇߡ޿ࠆ㧚౮⌀߆ࠄࠊ߆ࠆࠃ߁ߦ㧘⍴⚦✢ߦߪ⧯ᐓߩߚࠊߺ߇޽ࠅ㧘߹ߚ࡝࡯࠼┵ሶ߳ߩṁ⌕ࡐࠗࡦ࠻߽᣿⏕ߢߪߥ޿㧚ߎࠇࠄߩᓇ㗀ࠍ㒰෰ߔࠆߚ߼㧘ᮡḰ‛⾰㧔ᾲવዉ₸߇ᣢ⍮ߩ࠻࡞ࠛࡦ߿ࡋ࡝࠙ࡓࠟࠬ㧕ࠍ↪޿ߚ᷹ቯࠍⴕ޿㧘⍴⚦✢ߩ᦭ല㐳ߐ߅ࠃ߮⋥ᓘࠍᩞᱜߔࠆ㧚ᩞᱜߐࠇߚ㐳ߐ߅ࠃ߮⋥ᓘߪ᷹ቯ୯ߦᲧߴߡߘࠇߙࠇ⚂5%㧘0.5%⒟ᐲ⇣ߥࠆ㧚 ᾲવዉ₸ߩ▚಴ᴺᕡ᷷ᮏߩ᷷ᐲࠍ⸳ቯߒ㧘⊕㊄ߩ⍴⚦✢ࡊࡠ࡯ࡉߩᛶ᛫୯߇ᄌേߔࠆߎߣߥߊ৻ቯ୯ߣߥߞߚᓟ㧘ߔߥࠊߜኈེౝ⹜ᢱ᷷ᐲ߇ቯᏱߦ㆐ߒߚߎߣࠍ⏕⹺ߒߚᓟ㧘⋥ᵹ㔚Ḯ߆ࠄࠬ࠹࠶ࡊ⁁ߩ৻ቯ㔚ᵹࠍ⚦✢ࡊࡠ࡯ࡉߦଏ⛎ߒടᾲߔࠆ㧚ߎߩߣ߈ߩ㔚ᵹ࡮㔚࿶ߩㆊᷰᔕ╵ࠍ㜞ㅦ A/D ࡏ࡯࠼ߦࠃࠅ᷹ቯ
ߔࠆ㧚ߎࠇ߆ࠄ᳞߹ࠆᛶ᛫୯߆ࠄ⊕㊄⚦✢ߩ㕖ቯᏱ᷷ᐲᔕ╵߇▚಴ߐࠇࠆ㧚ߥ߅㧘㔚ᵹ୯ߪടᾲ㐿ᆎ 1 ⑽ᓟߦ߅ߌࠆ⚦✢ߩ᷷ᐲ਄᣹߇ 2K એਅߣߥࠆࠃ߁ߦ⸳ቯߒ㧘⥄ὼኻᵹ⊒↢ߩᓇ㗀߇⴫ࠇߥ޿
1s એౝߩ᷹ቯ࠺࡯࠲ࠍ↪޿ࠆ㧚ᾲવዉ₸߅ࠃ߮ᾲ᜛ᢔ₸ߪࠞ࡯ࡉࡈࠖ࠶࠹ࠖࡦ
ࠣߩᚻᴺࠍ↪޿ߡ▚಴ߔࠆ㧚A/D ࡏ࡯࠼ߩ࠺࡯࠲
ࠨࡦࡊ࡝ࡦࠣ࡟࡯࠻ߪ 50000/⑽ߢ޽ࠆ㧚ฦࠨࡦࡊ࡝ࡦࠣߦ߅ߌࠆ⚦✢᷷ᐲߩ᷹ቯ୯ࠍ Texp,i ߣߒ㧘ᢙ୯⸃߆ࠄ᳞߼ࠄࠇࠆߘࠇߙࠇߩ᷹ቯὐߦኻᔕߔ
ࠆᤨ㑆ߦ߅ߌࠆ⚦✢ߩ૕Ⓧᐔဋ᷷ᐲࠍ Ti ߣߔࠆ㧚ࡊࡠ࡯ࡉߩኸᴺ╬߇ᣢ⍮ߢ޽ࠆߣߔࠆߣ㧘Ti ߪ⹜ᢱߩᾲવዉ₸λ߅ࠃ߮ᾲ᜛ᢔ₸α ߩߺߩ㑐ᢙߣߥࠅ Ti(λ,α)ߢ⴫ߐࠇࠆ㧚Texp,i ߣ Ti (λ,α)ߣ߇৻⥌ߔࠆࠃ߁ߦࠞ࡯ࡉࡈࠖ࠶࠹ࠖࡦࠣࠍⴕ߁㧚ᑼ(13)ߦ␜
ߔࠃ߁ߦ㧘ࡄ࡜ࡔ࡯࠲ λ ߅ࠃ߮α ࠍᄌൻߐߖߚ⸘
▚ߦࠃࠅ㧘 Texp,i ߣ Ti (λ,α) ߩᱷᏅߩ 2 ਸ਼๺ S ࠍᦨዊߣߔࠆࠃ߁ߥ୯ߣߒߡᾲવዉ₸ߣᾲ᜛ᢔ₸߇᳞
߼ࠄࠇࠆ㧚



i =1

Fig. 9 ߦࡋ࡝࠙ࡓߩ‛ᕈ୯߇ᣢ⍮ߣߒߡ⚦✢ࡊࡠ
࡯ࡉߩኸᴺࠍᩞᱜߔࠆߚ߼ߩࠞ࡯ࡉࡈࠖ࠶࠹ࠖࡦ
ࠣ(a)ߣߘߩ⚿ᨐࠍ↪޿ߚࠞ࡯ࡉࡈࠖ࠶࠹ࠖࡦࠣߢ
ࡋ࡝࠙ࡓߩᾲવዉ₸ߣᾲ᜛ᢔ₸ࠍ▚಴ߒߚ⚿ᨐ(b)ࠍ␜ߔ㧚ߘࠇߙࠇߩࡈࠖ࠶࠹ࠖࡦࠣࡊࡠ࠮ࠬ߇㕖Ᏹߦ⦟޿♖ᐲߢ㆐ᚑߐࠇߡ޿ࠆߎߣ߇ࠊ߆ࠆ㧚৻ᣤ㧘⚦✢ߩ᦭ല⋥ᓘߣ㐳ߐ߇᳞߹ࠆߣ㧘⹜ᢱᵹ૕ߩ᷷ᐲ
਄᣹ߩ᷹ቯ୯ߦ࿑(b)ߩࡈࠖ࠶࠹ࠖࡦࠣⴕ߁ߎߣߦ
ࠃࠅ㧘ᾲવዉ₸߅ࠃ߮ᾲ᜛ᢔ₸߇หᤨߦ▚಴ߐࠇࠆ㧚
2
Fit
Experimenttemperature rise, K

1.75
1.5
1.25

Calibration
Helium 61.0°C, 0.3 MPa
L = 16.708 mm
d = 9.985 μm
h = 0.957 mm
2
Scal = 1.02 K-1 -1
λ = 0.16785 W⋅m ⋅K
α = 7.465×10-5 m2⋅s-1

1
0.75
0.5
0.25

10-3

(a) Calibration

10-2

time, s

10-1

100

2
Fit
Experiment

1.75

(13)

㜞޿᷹ቯ♖ᐲࠍᓧࠆߚ߼ߦߪ⍴⚦✢ࡊࡠ࡯ࡉߩ
᦭ല⋥ᓘߣ㐳ߐࠍᮡḰ⹜ᢱࠍ↪޿ߡ♖ኒߦᩞᱜߔ
ࠆᔅⷐ߇޽ࠆ㧚ߎߩᩞᱜߦ߅޿ߡ߽ࠞ࡯ࡉࡈࠖ࠶࠹
ࠖࡦࠣᚻᴺࠍㆡ↪ߔࠆ㧚ᮡḰ‛⾰ߣߒߡࡋ࡝࠙ࡓࠟ
ࠬࠍ૶↪ߒ㧘ᾲવዉ₸߅ࠃ߮ᾲ᜛ᢔ₸߇ᣢ⍮ߣߔࠆߣ㧘ᑼ(13)ߩࡄ࡜ࡔ࡯࠲ࠍλ, α ߆ࠄ l, d ߦ⟎߈឵߃ࠆߎߣ߇ߢ߈㧘ߎߩࡈࠖ࠶࠹ࠖࡦࠣ߆ࠄ l ߅ࠃવᾲ 2009 ᐕ 4 ᦬

(14)

i =1

temperature rise, K

N exp

N exp

2

S = ∑ (Texp,i − Ti (λ ,α )) → Min

2

S = ∑ (Texp, i − Ti (l , d )) → Min

1.5
1.25
Measurement
Helium 61.0°C, 0.3 MPa
L = 16.71 mm
d = 9.99 μm
h = 0.94 mm
Smeas = 1.02 K2-1 -1
λ = 0.16781 W⋅m ⋅K (-0.02%)-5
2 -1
α = 7.468×10 m ⋅s (+0.04%)

1
0.75
0.5
0.25

10-3

10-2

time, s10-1100(b) Check using calibrated effective geometry

Figure 9 Calibrated fit and back check for helium.

- 45 -J. HTSJ, Vol. 48, No. 203

․㓸㧦᳓⚛ߩ‛ᕈ߅ࠃ߮᧚ᢱ

-1-1

thermal conductivity, W⋅m ⋅K

Present
Roder
Assael

0.22
0.21

±1%

0.2
0.19
0.18

H 2 gas0.3 MPa
Calibrated using helium

20

(a)

40

60

80

temperature, °C

100

8E-05
H2
0.3 MPa
Calibrated in helium

7.5E-05
7E-05
6.5E-05
6E-05±5%

5.5E-05
5E-05
NIST Webbook
Present

4.5E-05
4E-05

20
(b)

߅ࠊࠅߦ
 ᧄⓂߢߪ HYDROGENIUS ߩ‛ᕈ࠴࡯ࡓߢⴕࠊ
ࠇߡ޿ࠆ㜞࿶࡮㜞᷷ၞߢߩ᳓⚛ߩᾲ‛ᕈ⸘᷹ߦߟ
޿ߡ㧘᷹ቯⵝ⟎߿᷹ቯ⚿ᨐߩ৻ㇱࠍ⚫੺ߒߚ㧚ߎߎߢ⸥ߒߚ᷹ቯߩ߶߆ߦ㧘‛ᕈ࠴࡯ࡓߢߪ㜞࿶᳓⚛ਛߩ㜞ᴣὐࠟࠬߩ㔺ὐ⸘᷹㧔૒⾐ᄢ㧕㧘᳓⚛ߩ㖸ㅦ᷹ቯ㧔㐳ፒᄢ㧕ᣂߒߊ᷹ቯߐࠇߚ࠺࡯࠲ࠍട߃
ߚ᳓⚛ᾲ‛ᕈ࠺࡯࠲ࡌ࡯ࠬߩ᭴▽㧔㐳ፒᄢ㧕ߥߤ᳓⚛‛ᕈߦ㑐ߔࠆ✂⟜⊛ߥ⎇ⓥ߇ⴕࠊࠇߡ޿ࠆ㧚⎇ⓥߪ⸘↹ߦᓥߞߡㆀⴕߐࠇߡ޿ࠆ߇㧘੍ቯߤ߅ࠅߦㅴ߹ߥ޿ߎߣ߇ዋߥߊߥ޿㧚‛ᕈ୯ߩ᷹ቯ㗄⋡ߪ⋡ᣂߒ޿߽ߩߢߪߥߊ㧘ᒰೋߪ᷹ቯᣇᴺ߽޽
ࠆ⒟ᐲ⏕┙ߐࠇߚᣇᴺࠍ↪޿ࠆߎߣ߇ߢ߈ࠆߣ⠨߃ߡ޿ߚ㧚ߒ߆ߒ㧘500°C ⒟ᐲߩ㜞᷷ߪߣ߽߆ߊ
100MPa ߩ㜞࿶᧦ઙߢߩ᷹ቯߢߒ߆߽ኻ⽎߇᳓⚛
ࠟࠬߢ޽ࠆߣ޿߁ߎߣߪ㧘᷹ቯߩ㐿ᆎߦ⥋ࠆ߹ߢߩḰ஻Ბ㓏ߢߐ߃㕖Ᏹߥ࿎㔍ࠍ઻߁߽ߩߢ޽ࠆߎ
ߣࠍ∩ᗵߒߚ㧚㜞࿶ࠟࠬ଻቟ᴺߦࠃࠆⷙ೙ࠍࠢ࡝
ࠕߔࠆߚ߼ߩ⠴࿶ኈེ߿๟ㄝⵝ⟎ߩ⸳⸘⵾૞㧘㔚᳇ࡅ࡯࠲ࠍ஻߃ߚ㜞᷷ᕡ᷷ᮏߐࠄߦ࠮ࡦࠨ߿㔚ሶ

વᾲ 2009 ᐕ 4 ᦬

0.23

thermal diffusivity, m2⋅s-1

 ᾲવዉ₸߅ࠃ߮ᾲ᜛ᢔ₸ߩ᷹ቯ଀ ਄ㅀߩᣇᴺߢ᳿ቯߐࠇߚࡊࡠ࡯ࡉߩኸᴺࠍ↪޿ߡ㧘᳓⚛ߩᾲવዉ₸߅ࠃ߮ᾲ᜛ᢔ₸ߩ᷹ቯࠍⴕߞ
ߚ㧚0.3MPa ߩૐ࿶ၞߢ㧘᷷ᐲ 20㨪100°C ߩ▸࿐ߢߩ᷹ቯ⚿ᨐࠍ Fig. 10 ߦ␜ߔ㧚࿑ߦߪ Roder[19]߅
ࠃ߮ Assael ࠄ[20]ߩ᷹ቯ୯ࠍߘࠇߙࠇታ✢߅ࠃ߮⎕✢ߢ⸥౉ߒߡ޽ࠆ㧚ߥ߅㧘ᾲ᜛ᢔ₸ߦ߅ߌࠆታ
✢ߪ Roder ߩᾲવዉ₸ࠍ Leachmann ߩ⁁ᘒᑼ߆ࠄ⸘▚ߐࠇࠆ ρCp ߢ㒰ߒߚ୯ߢ޽ࠆ㧚ᧄ᷹ቯ୯ߪ
ߎࠇࠄᣢሽߩ᷹ቯ⚿ᨐߣᾲવዉ₸ߪr1㧑⒟ᐲ㧘ᾲ᜛ᢔ₸ߪr5㧑⒟ᐲߩ஍Ꮕߢ৻⥌ߒߡ޿ࠆ㧚♖ᐲߩࠃ޿᷹ቯ߇࿎㔍ߣߐࠇߡ޿ࠆᾲ᜛ᢔ₸ߦߟ޿ߡ߽
ౣ⃻ᕈߩ⦟޿᷹ቯ୯߇ᓧࠄࠇߡ޿ࠆߎߣ߆ࠄ㧘᷹
ቯᴺ߅ࠃ߮ࠞ࡯ࡉࡈࠖ࠶࠹ࠖࡦࠣߩᚻᴺ߇㕖Ᏹߦ᦭ലߢ޽ࠆߎߣ߇⏕⹺ߢ߈ߚ㧚Ᏹ᷷ߢߩᐔⴧ᳓⚛ߢ޽ࠆࡁ࡯ࡑ࡞᳓⚛ߪࠝ࡞࠰㧘ࡄ࡜ߩ 2 ߟߩ⇣ᕈ૕ߩᷙว‛ߢ޽ࠆ㧚ᾲવዉ₸߅ࠃ߮ᾲ᜛ᢔ₸ߟ޿ߡߪ㧘ࡄ࡜᳓⚛߅ࠃ߮ᐔⴧ᳓⚛
ࠍኻ⽎ߦ㧘1MPa એਅ㧘80K㨪360K ߩ▸࿐ߢߩ᷹ቯࠍ⸘↹ߒߡ޿ࠆ㧚ߐࠄߦ 100MPa, 500°C ߩ㜞᷷࡮㜞࿶㗔ၞߩ᷹ቯߪ㧘⃻࿷⹜ᢱኈེ߅ࠃ߮㜞᷷ᕡ᷷ᮏߥߤߩⵝ⟎ࠍ⵾૞ਛߢ㧘᷹ቯࠪࠬ࠹ࡓ߇ቢ
ᚑᰴ╙㐿ᆎߔࠆ੍ቯߢ޽ࠆ㧚

40

60

80

temperature, °C

100

Figure 10 Thermal conductivity and thermal
diffusivity of hydrogen for 0.3MPa.

ᯏེߩ㒐῜ኻ╷ߩᔀᐩߥߤ㧘੍ᗐએ਄ߦ࿎㔍ߥ⺖㗴߇ጊⓍߒߡ޿ߚ㧚ࡊࡠࠫࠚࠢ࠻㐿ᆎᣧ‫ⵝࠄ߆ޘ‬⟎ߩ⸳⸘࡮⵾૞㧘⚊౉ߦ 㕖Ᏹߥ⧰ഭࠍᒝ޿ࠄࠇߚ㧚⿷߆ߌ 3 ᐕࠍ⚻ߡ߿ߞߣᧄⓂߢ⚫੺ߒߚ‛ᕈߩ⸘᷹߇゠㆏ߦਸ਼ࠅ߆ߌߚ⁁ᴫߦ޽ࠆ㧚ߘࠇߦߒߡ߽㧘
100MPa㧘500°C ߩ㜞࿶࡮㜞᷷᧦ઙਅߩ᳓⚛ߩᾲ‛ᕈ⸘᷹ߦ㑐ࠊࠇࠆߎߣߪ╩⠪ࠄߦߣߞߡජタ৻ㆄߩ࠴ࡖࡦࠬ߇ਈ߃ࠄࠇߚߣ޿߁ߎߣߢ㧘⒳‫ߩޘ‬࿎㔍ࠍస᦯ߒߟߟ㧘ᦨ⚳⋡ᮡߢ޽ࠆ᳓⚛‛ᕈߩ࿖㓙ᮡḰߣ߽⷗ߥߐࠇࠆ࠺࡯࠲ࡌ࡯ࠬߩቢᚑߦะߌߡ
ദജߔࠆᔃߠ߽ࠅߢ޿ࠆ㧚 ᧄⓂߢ␜ߒߚฦ᷹ቯ୯ߪ‛ᕈ࠴࡯ࡓߩ᭴ᚑຬో
ຬߩദജߦࠃߞߡߎࠇ߹ߢߦ෼㓸ߐࠇߚ࠺࡯࠲ߩ
৻ㇱߢ޽ࠅ㧘⹦⚦ߥਇ⏕߆ߐ⸃ᨆ⚿ᨐࠍ઻߁᷹ቯ
୯ߣߪ੔߃ߥ޿㧚࠺࡯࠲ࡌ࡯ࠬߩቢᚑߩߚ߼ߦߪ
ߐࠄߦ♽⛔⊛ߥ᷹ቯࠍⓍߺ㊀ߨࠆߣหᤨߦਇ⏕߆- 46 -J. HTSJ, Vol. 48, No. 203

․㓸㧦᳓⚛ߩ‛ᕈ߅ࠃ߮᧚ᢱ
ߐ⸃ᨆߦࠃࠅ࠺࡯࠲ࠍี๧ߔࠆᔅⷐ߇޽ࠆ㧚ᦨᓟߦ㧘ᧄ⎇ⓥߩᯏળࠍឭଏ㗂޿ߚ NEDO ࡊࡠࠫࠚࠢ࠻ߩ‫ޟ‬᳓⚛వ┵⑼ቇၮ␆⎇ⓥ੐ᬺ‫ޠ‬㑐ଥฦ૏ߦᷓ↟ߩ⻢ᗧࠍ⴫ߔ㧚

Sci. Res. 27 (1973) 241.
[9] J. Boussinesq, Compt. Rend. 110(1890)1160.
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[12] Suciu,S.Ph.D. Thesis, Purdue University 1951 &Zoss,L.M.Ph.D. Thesis, Purdue University 1952[13] H. M. Roder, D. E. Diller, J. Chemical Physics,
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[14] M. J. Assael and W. A. Wakeham, J. Chem. Soc.,
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J. Phys. Chem. Ref. Data 15, 1315 (1986).

ෳ⠨ᢥ₂
[1] M. Fujii, Y. Takata and K. Shinzato, Proc. 27th
Jpn. Symp. Thermophys. Prop., Kyoto(2006)
Z114.
[2] A. Michels and M. Goudeket, Physica, 8 (1941)
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[3] A. Michels, W. De Graaff, T. Wassenaar, J.M.H.
Levelt and P. Louwerse, Physica, 25 (1959) 25.
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A. Weber, J. Res. Natl. Bur. Stand., Sect., A 67
(1963) 173.
[5] L. A. Weber, NASA-SP-3088 (1975).
[6] B. A. Younglove, J. Phys. Chem. Ref. Data, 11(1982) 1.
[7] J. Leachman, Fundamental Equations of State for
Parahydrogen, Normal Hydrogen, and Orthohydrogen, Master's Thesis, University of Idaho(2007).
[8] J. Kestin, M. Sokolov, and W. Wakeham, Appl.

વᾲ 2009 ᐕ 4 ᦬- 47 -J. HTSJ, Vol. 48, No. 203

ࡊࡠࠫࠚࠢ࠻ Qᄢቇࠠࡖࡦࡄࠬߩ᳓⚛ࠬ࠹࡯࡚ࠪࡦ
Hydrogen Refueling Station in University Campus᧖᧛ ਂ৻㧘ጟ↰ િᑝ㧘દ⮮ ⴧᐔ㧔਻Ꮊᄢቇ㧕
Joichi SUGIMURA, Nobuhiro OKADA, Kohei ITO (Kyushu University)e-mail: sugi@mech.kyushu-u.ac.jpદㇺᣂࠠࡖࡦࡄࠬߪ㧘⑔ጟᏒߩ⷏ߩ┵㧘♻ፉඨፉߩਐ㒺࿾Ꮺߦ૏⟎ߒ㧘275 ࡋࠢ࠲࡯࡞ߦ߅ࠃ߱
ᐢᄢߥᢝ࿾ࠍ᦭ߒߡ޿߹ߔ㧚ߘߩ࿾ߩ೑ࠍᵴ߆ߒ
ߡ㧘᳓⚛㑐ㅪߩฦ⒳⎇ⓥࠍ᏷ᐢߊዷ㐿ߔߴߊ㧘਄ㅀߩ࠮ࡦ࠲࡯ߩ⎇ⓥ᫟ᑪ⸳߿㧘᳓⚛ࠬ࠹࡯࡚ࠪࡦ㧘ቯ⟎↪Άᢱ㔚ᳰታ⸽⹜㛎⸳஻ߥߤߩዉ౉ࠍⴕ޿㧘ᄢቇߢߪ‫ޟ‬᳓⚛ࠠࡖࡦࡄࠬ‫ߣޠ‬૏⟎ߠߌߡ޿߹ߔ㧚ߘߩߥ߆ߢ㧘ታ⸽⹜㛎⸳஻ߣߒߡᦨೋߦዉ౉⸘↹ࠍㅴ߼ߚߩ߇᳓⚛ࠬ࠹࡯࡚ࠪࡦߢߒߚ㧔࿑ 1㧕㧚᳓⚛ࠬ࠹࡯࡚ࠪࡦߪ㧘2004 ᐕ 7 ᦬ߦ࿾ၞᣂ↢ࠦࡦ࠰࡯ࠪࠕࡓ⎇ⓥ㐿⊒੐ᬺߣߒߡ਻Ꮊ↥ᬺ⚻ᷣዪ߆ࠄߩᆔ⸤ࠍฃߌߡ⸘↹߇ᆎ߹ࠅ㧘2005 ᐕ 1 ᦬ߦદㇺᣂࠠࡖࡦࡄࠬߦ߅޿ߡᑪ⸳Ꮏ੐㐿ᆎ㧘ห 11᦬ߦ┫Ꮏ㧘㜞࿶ࠟࠬ⵾ㅧቢᚑᬌᩏߦวᩰߒ㧘ห 12᦬ᧃ߹ߢߩ੍ቯߢ⸳஻ߩ⹜ㆇォࠍⴕߞߡ߅ࠅ߹ߒ
ߚ㧚12 ᦬ 7 ᣣߦ⊒↢ߒߚ੐᡿ߩߚ߼㧘ታ⸽⹜㛎ߪਛᢿߖߑࠆࠍᓧ߹ߖࠎߢߒߚ߇㧘ߎߩ੐᡿ߦࠃߞ
ߡᄙߊߩ⺖㗴ߣᢎ⸠ࠍᓧ߹ߒߚ㧚
ᧄⓂߢߪ㧘᳓⚛ࠬ࠹࡯࡚ࠪࡦߩዉ౉߆ࠄ㧘੐᡿ߣߘߩේ࿃⺞ᩏ㧘෸߮ᣂߚߥ⺖㗴ߩ⎇ⓥߦ៤ࠊߞߡ߈ߚ┙႐߆ࠄ㧘ߘߩ⚻✲ࠍߏ⚫੺ߔࠆߣߣ߽ߦ㧘ᄢቇࠠࡖࡦࡄࠬߢߩ⎇ⓥ㐿⊒ߦౝ࿷ߔࠆ໧㗴ὐߦߟ޿ߡ߽ዋߒ⸅ࠇߚ޿ߣᕁ޿߹ߔ㧚ߪߓ߼ߦ
࿾⃿ⅣႺ㧘ࠛࡀ࡞ࠡ࡯໧㗴ߩᷓೞൻࠍ⢛᥊ߦ㧘ᄙ᭽ߥࠛࡀ࡞ࠡ࡯Ḯ߆ࠄ⵾ㅧߢ߈ࠆ᳓⚛ࠛࡀ࡞ࠡ࡯߳ߩᦼᓙ߇㜞߹ߞߡ޿߹ߔ㧚Άᢱ㔚ᳰ⥄േゞߩ㐿⊒ߣਗⴕߒߡ㧘᳓⚛ࠬ࠹࡯࡚ࠪࡦߩታ⸽⹜㛎߿㧘㑐ㅪᯏེߩ㐿⊒߇࿖ౝᄖߢㅴ߼ࠄࠇߡ޿߹ߔ㧚਻Ꮊᄢቇߢߪ㧘દㇺᣂࠠࡖࡦࡄࠬߦ߅޿ߡ㧘᳓⚛ࠛࡀ࡞ࠡ࡯㑐ㅪߩ⎇ⓥᢎ⢒ࠍᄙⷺ⊛ߦዷ㐿ߒߡ޿߹ߔ㧚ߎߩᄢ߈ߥേ߈ߩ⊒┵ߪ㧘2003 ᐕᐲߦណᛯߐࠇߚᢥㇱ⑼ቇ⋭ߩ 21 ਎♿ COE ࡊࡠࠣ࡜ࡓ‫ޟ‬᳓⚛೑↪ᯏ᪾ࠪࠬ࠹ࡓߩ⛔วᛛⴚ‫ߔߢޠ‬㧚หࡊࡠࠣ࡜ࡓߩ 5 ᐕ㑆ߩታᣉᦼ㑆ߩ㑆ߦ㧘Ꮏቇ⎇ⓥ㒮ߩᯏ᪾♽ㇱ㐷ࠍਛᔃߣߒߡ㧘ᄢቇ㒮ᢎ⢒ߣၮ␆⎇ⓥߪ
߽ߜࠈࠎߩߎߣ㧘᳓⚛೑↪ᛛⴚ⎇ⓥ࠮ࡦ࠲࡯ߩ⸳
⟎㧘ฦ⒳ታ⸽⹜㛎㧘ੱ᧚⢒ᚑ㧘↥ᬺᛛⴚ✚ว⎇ⓥᚲߩ᳓⚛᧚ᢱవ┵⑼ቇ⎇ⓥ࠮ࡦ࠲࡯ߩ⸳⟎ߥߤ㧘᳓⚛ߦ߆߆ࠊࠆ⎇ⓥᢎ⢒᜚ὐߩ᭴▽ࠍ߼ߑߒߚᵴ
േࠍ⛯ߌߡෳࠅ߹ߒߚ[1]㧚
ߎࠇߣᤨࠍหߓߊߒߡ㧘਻Ꮊᄢቇߩࠠࡖࡦࡄࠬ
⒖ォ߇ 2005 ᐕ 9 ᦬߆ࠄᆎ߹ࠅ߹ߒߚ㧚▫ፒ࿾඙ߣ౐ᧄ᧻࿾඙ߩㇱዪ߇㧘චᢙᐕߩ⒖ォ⸘↹ߦᓥߞߡ⒖േߔࠆჽᄢߥ⸘↹ߢ㧘Ꮏቇ♽ߪߘߩవ㒯ࠍಾߞ
ߡ 2007 ᐕ 3 ᦬߹ߢߦ⒖ォࠍ߶߷ቢੌߒ߹ߒߚ㧚᳓⚛ࠬ࠹࡯࡚ࠪࡦߩࡊࡠࠫࠚࠢ࠻
**')
᳓⚛ߪߐ߹ߑ߹ߥᣇᴺߢ⵾ㅧߢ߈߹ߔ߇㧘CO2ࡈ࡝࡯ߩౣ↢น⢻ߥࠛࡀ࡞ࠡ࡯ߩⷰὐ߆ࠄߪ㧘᳓
㔚⸃ᴺ߇߭ߣߟߩℂᗐᒻߣ⠨߃ࠄࠇ߹ߔ㧚৻ᣇ㧘Άᢱ㔚ᳰ⥄േゞߩΆᢱߣߒߡߩ᳓⚛ߪ㧘࿶❗᳓⚛
ߩᒻᘒߣߔࠆߩ߇ᦨ߽ല₸⊛ߣ⠨߃ࠄࠇߡ߅ࠅ㧘ᓥ᧪ᛛⴚߢߪ࠳ࠗࡗࡈ࡜ࡓᑼ߿ᓔᓳᑼߩࠦࡦࡊ࡟
࠶ࠨ࡯߇೑↪ߐࠇߡ޿߹ߔ㧚ߒ߆ߒ㧘ߎࠇࠄߩ⠴ਭᕈߩ໧㗴߿࿶❗ߔࠆߚ߼ߦࠛࡀ࡞ࠡ࡯ࠍᔅⷐߣ
ߔࠆὐ߆ࠄ㧘ࠃࠅല₸ߩࠃ޿㜞࿶᳓⚛⵾ㅧᛛⴚߩ
಴⃻߇᳞߼ࠄࠇߡ߈߹ߒߚ㧚࿑ 1 ਻Ꮊᄢቇ᳓⚛ࠬ࠹࡯࡚ࠪࡦ[3]વᾲ 2009 ᐕ 4 ᦬- 48 -J. HTSJ, Vol. 48, No. 203

ࡊࡠࠫࠚࠢ࠻ Q㈩▤⎕ⵚ▎ᚲ
᳓⚛᡼ᢔ丘丱万义ደᄖ乊᳓⚛䉧䉴㈩▤♽㉄⚛᡼ᢔ丘丱万义ደᄖ乊㉄⚛䉧䉴㈩▤♽

ᢛᵹེ

Ꮕ࿶⸃ᶖེ

⚐᳓
⚐᳓ଏ⛎
䊘䊮䊒

㔚⸃䉶䊦䉺䊮䉪
ECT-1

᳓⚛᡼ᢔᮏ

⫾࿶ེ䷄

᳓
⚛
㘻
๺
᳓

㉄
⚛
㘻
๺
᳓

⣕㉄⚛╴

㉄⚛ಽ㔌䉺䊮䉪
OST-1

㔚⸃䉶䊦

᳓⚛䷫䷸

㉄⚛᡼ᢔᮏ

ᵹ㊂೙ᓮ

㉄⚛䉧䉴

㉄
⚛
㘻
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᳓
䋫
㉄
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䉧
䉴

಄ළེ
⣕Ḩ╴

䊋䉟䊋䉴ᑯ
᳓ᓴⅣ䊘䊮䊒

࿑ 2 HHEG ߩ᭎ⷐ [5]㧔⿒㧦᳓⚛ࠟࠬ㈩▤㧘✛㧦㉄⚛ࠟࠬ㈩▤㧘㕍㧦᳓ᓴⅣ㈩▤㧘⚬㧦Ꮕ࿶ᬌ಴↪㈩▤㧕ⅣႺߢߩᕈ⢻߿㧘㜞࿶ജਅߢߩ᳓㔚⸃․ᕈߦߟ޿ߡߩᛛⴚ⊛ߥⵣઃߌ߇ᔅⷐਇนᰳߢߔ㧚߹ߚ㧘ታ㓙ߩ૶↪ࠍᗐቯߒߚታ⸽⹜㛎ࠍⴕ޿㧘⵾ㅧല₸߿⠴ਭᕈ㧘቟ోᕈࠍ⏕⹺ߔࠆᔅⷐ߇޽ࠅ߹ߔ㧚ߐࠄߦ㧘⥄ὼࠛࡀ࡞ࠡ࡯ᵴ↪ߩⷰὐ߆ࠄ㧘㘑ജߥߤߩᄌേߔࠆࠛࡀ࡞ࠡ࡯Ḯߣ᳓⚛⵾ㅧⵝ⟎ߣߩࡑ࠶࠴
ࡦࠣߦ㑐ߒߡᛛⴚ⊛ߥᬌ⸛߇ᔅⷐߢߔ㧚ߘߎߢ㧘਻Ꮊᄢቇ㧘਻Ꮊ㔚ജ㧘ਃ⪉໡੐㧘ࠠࡘ࡯ࠠ㧘෸߮
⽷࿅ᴺੱ⑔ጟ⋵↥ᬺ࡮⑼ቇᛛⴚㅴⴕ⽷࿅ߢ࠴࡯ࡓ
ࠍ⚵ߺ㧘‫ߩࠬ࡟࡯ࠨ࠶࡟ࡊࡦࠦޟ‬㜞࿶᳓㔚⸃᳓⚛
ࠬ࠹࡯࡚ࠪࡦߩ㐿⊒‫౒ߩޠ‬ห⎇ⓥࡊࡠࠫࠚࠢ࠻߇
┙ߜ਄߇ࠅ߹ߒߚ㧚ߎߩࡊࡠࠫࠚࠢ࠻ߢߪ㧘HHEG ߩ㜞࿶࡮ᄢဳൻ
㧔࿶ജ 40MPa㧘᳓⚛⵾ㅧ⢻ജ 30Nm3/h㧕ࠍ࿑ࠅ㧘ታ⸽࠺࡯࠲ࠍขᓧߔࠆߣߣ߽ߦ㧘㔚᳇ಽ⸃߿᧚ᢱ
ᒝᐲ㧘㘑ജ⊒㔚ߥߤߩ⎇ⓥ⠪ߦࠃࠅ㔚⸃․ᕈ㧘᧚ᢱᒝᐲ࡮⠴ਭᕈ㧘቟ోᕈ╬ߩ⹏ଔ⸃ᨆߣ㧘㘑ജ╬ߩ⥄ὼࠛࡀ࡞ࠡ࡯ߩ೑↪น⢻ᕈࠍត᳞ߔࠆߎߣߦ
ߥࠅ߹ߒߚ㧚߹ߚ㧘⎇ⓥ㐿⊒ߣߒߡߩᗧ⟵ߛߌߢߥߊ㧘਻Ꮊೋߩ᳓⚛ࠬ࠹࡯࡚ࠪࡦߣߒߡ㧘࿾ၞߩᛛⴚ࡮ੱ᧚⢒ᚑߩ᜚ὐ㧘ᣂߚߥଔ୯ⷰഃㅧߣ␠ળ
ฃኈᕈะ਄ߩ᜚ὐߣߒߡ㊀ⷐߥᓎഀࠍᜂ߁߽ߩߣ
ᦼᓙߐࠇ߹ߒߚ㧚᳓⚛ࠬ࠹࡯࡚ࠪࡦߩࠃ߁ߥታ⸽ࠪࠬ࠹ࡓߩዉ౉
ߪ㧘ᄢቇߦ߅ߌࠆㅢᏱߩ⎇ⓥ⸳஻ዉ౉ߦᲧߴߡߪ

ਃ⪉໡੐ߢߪ㧘ࠦࡦࡊ࡟࠶ࠨ࡯ࠍ૶↪ߖߕߦ࿕૕㜞ಽሶ⤑ࠍ↪޿ߚ᳓ߩ㔚᳇ಽ⸃ߦࠃࠅ㜞࿶᳓⚛
ࠍ⊒↢ߔࠆ HHEG㧔㜞࿶❗᳓⚛ࠛࡀ࡞ࠡ࡯⊒↢ⵝ⟎㧕ࠍ㧘਎⇇ߦߐ߈߇ߌߡ㐿⊒ߒ߹ߒߚ[2]㧚HHEG
ߩ⹜૞ᯏߪ 35MPa ߢ 2.5Nm3/h ߩ᳓⚛⵾ㅧࠍ㆐ᚑߒ߹ߒߚ㧚
HHEG ߩߒߊߺߪᰴߩߣ߅ࠅߢߔ㧚࿕૕㜞ಽሶ⤑ࠍ↪޿ߚ㔚⸃࠮࡞ߦ᳓ߣ㔚᳇ࠍଏ⛎ߔࠆߣ᳓ߩ
㔚᳇ಽ⸃ߦࠃߞߡ᳓⚛ࠟࠬߣ㉄⚛ࠟࠬ߇⊒↢ߒ߹ߔ㧚ߎࠇࠍ࿑ 2 ߩࠃ߁ߦ㐽ߓߚ࠲ࡦࠢ㧔࿑ਛ㧘㔚⸃࠮࡞࠲ࡦࠢ㧕ౝߢⴕ߁ߣ㧘ࠟࠬߩ࿶ജߪ਄᣹ߒ
ߡ޿߈߹ߔ㧚ᔅⷐߥ࿶ജ 40MPa㧔⚂ 400 ᳇࿶㧕ߦ㆐ߒߚߣߎࠈߢ㧘᳓⚛ࠟࠬࠍᄖㇱߦขࠅ಴ߒߡ߿
ࠇ߫㧘ࠦࡦࡊ࡟࠶ࠨ࡯ࠍ૶ࠊߕߦ㜞࿶ߩ᳓⚛ࠟࠬࠍᓧࠆߎߣ߇ߢ߈߹ߔ㧚৻ᣇ㧘⊒↢ߒߚ㉄⚛ࠟࠬߪ᳓ߦㆇ߫ࠇ㧘߽߁߭ߣߟߩ࠲ࡦࠢ‫⚛㉄ޟ‬ಽ㔌࠲ࡦࠢ‫ࠍޠ‬ㅢߞߡᄢ᳇ߦ᡼಴ߐࠇ߹ߔ㧚㔚⸃࠮࡞ߩ⤑ߪ᳓⚛஥ߣ㉄⚛஥ߩ࿶ജᏅ߇ᄢ߈ߊߥࠆߣუࠇ
ߡߒ߹߁ߚ߼㧘Ᏹߦੑߟߩ࠲ࡦࠢߩ࿶ജᏅࠍᏅ࿶
⸃ᶖ࠮ࡦࠨߢߣࠄ߃㧘ขࠅ಴ߔ᳓⚛ߣ㉄⚛ߩ㊂ࠍ⺞ᢛߒߥ߇ࠄ࿶ജࡃ࡜ࡦࠬࠍߣࠆὐ߇ HHEG ߩ․㐳ߢߔ㧚 ⎇ⓥ㐿⊒ࡊࡠࠫࠚࠢ࠻HHEG ࠍ↪޿ߚ᳓⚛ࠬ࠹࡯࡚ࠪࡦߩ㐳ᦼ቟ోㆇォࠍ଻⸽ߔࠆߚ߼ߦߪ㧘᭴ᚑᯏེߩ㜞࿶᳓⚛ࠟࠬ

વᾲ 2009 ᐕ 4 ᦬

- 49 -J. HTSJ, Vol. 48, No. 203

ࡊࡠࠫࠚࠢ࠻ Q

વᾲ 2009 ᐕ 4 ᦬

- 50 -

⸳஻ߢᓧࠄࠇߚ࠺࡯࠲߆ࠄ㘑࡟ࡦ࠭㘑ゞߩ⊒㔚㊂ߩ⍴ᦼᄌേߣ㐳ᦼᄌേࠍ▚಴ߒ㧘㘑ജ⊒㔚ߣ
HHEG ߩࡑ࠶࠴ࡦࠣߩน⢻ᕈࠍᬌ⸛ߒ߹ߒߚ㧚Ԛ᳓⚛ࠬ࠹࡯࡚ࠪࡦ࡮ࠪࠬ࠹ࡓߦ㑐ߔࠆ⎇ⓥ㐿⊒㧦᳓⚛ࠬ࠹࡯࡚ࠪࡦߩ᧚ᢱᒝᐲ࡮⠴ਭᕈ⹏ଔ㧘ല₸⹏ଔ㧘੐ᬺᕈ⹏ଔ㧘቟ోᕈ⹏ଔࠍታᣉߒ߹ߒߚ㧚᧚ᢱᒝᐲ࡮⠴ਭᕈ⹏ଔߦ߅޿ߡߪ㧘᳓⚛ࠬ࠹࡯࡚ࠪࡦߢ૶↪ߐࠇࠆ㋕㍑᧚ᢱߩ∋ഭᒝᐲ․ᕈࠍ᣿ࠄ߆ߦߒ㧘⫾࿶ེ㧘෸߮㊄ዻࡌࡠ࡯࠭ߩᒝᐲ⹏ଔࠍ
ⴕ޿߹ߒߚ㧚ല₸⹏ଔߦ߅޿ߡߪ㧘᳓⚛⊒↢㊂߿⸳஻ᶖ⾌㔚ജࠍ⸘᷹ߒ᳓⚛ࠬ࠹࡯࡚ࠪࡦߩࡊ࡜ࡦ
࠻ല₸ࠍ⹜▚ߒ߹ߒߚ㧚੐ᬺᕈ⹏ଔߦ߅޿ߡߪ㧘㜞࿶᳓㔚⸃᳓⚛ࠬ࠹࡯࡚ࠪࡦߦߟ޿ߡ㧘ⅣႺ․ᕈ
ߣ⚻ᷣᕈߩ㕙߆ࠄ੐ᬺᕈࠍᬌ⸛ߒ߹ߒߚ㧚቟ోᕈ⹏ଔߦ߅޿ߡߪ㧘ㆇォ⠪ᢎ⢒ߦ⌕⋡ߒ㧘ㆇォࡑ࠾ࡘࠕ࡞ߩᬌ⸛ߣㆇォࠪࡒࡘ࡟࡯࠲ߩ૞ᚑࠍⴕ޿߹
ߒߚ㧚੐᡿ߣ੐᡿⺞ᩏ੐᡿ߩ⊒↢
࿑ 3 ߦ᳓⚛ࠬ࠹࡯࡚ࠪࡦታ⸽⹜㛎⸳஻ߩᄢ߹߆
ߥ᭴ᚑࠍᐔ㕙࿑ߢ␜ߒ߹ߔ㧚HHEG ߇ᝪ߃ઃߌࠄ
ࠇߚㇱደߪ㜞࿶ࠟࠬࠍ⵾ㅧߔࠆߚ߼㓒ოߢ࿐߹ࠇ㧘ߘߩ⷏஥ߣർ஥ߦ๟ㄝᯏེ߇⸳⟎ߐࠇߡ޿߹ߔ㧚
HHEG ߇⊒↢ߒߚ᳓⚛ࠟࠬߪ⫾࿶ེߦ⫾߃ࠄࠇ߹ߔ㧚࠺ࠖࠬࡍࡦࠨ࡯ߪ⫾࿶ེߦ⾂⬿ߒߚ᳓⚛ࠟࠬࠍΆᢱ㔚ᳰ⥄േゞߦలႯߔࠆ⸳஻ߢߔ㧚HHEG ߪో⥄േߢേߊⵝ⟎ߢ޽ࠅ㧘ㆇォਛߪ HHEG ቶߪ┙ߜ౉ࠅ⑌ᱛߣߒߡ޿߹ߒߚ㧚

㉄⚛ಽ㔌
䉺䊮䉪

20 m

ࠆ߆ߦᄙߊߩ૞ᬺࠍⷐߒ߹ߒߚ㧚ડᬺߩᛛⴚ㒯ߣߩ⎇ⓥ㕙࡮ᛛⴚ㕙ߩᛂวߖߪ⸒߁߹ߢ߽ߥߊ㧘⎇ⓥㆀⴕߣ⸳஻ዉ౉ߩߚ߼ߩ⚻ℂ߿⍮⊛⽷↥ߥߤߩ᛬ⴣ㧘⸳⸘࡮ᑪ⸳ߦ߆߆ࠊࠆᬌ⸛߿ᴺ⊛ߥኻᔕ㧘⾗ᩰࠍ߽ߞߚࠬ࠲࠶ࡈߦࠃࠆㆇ↪૕೙ߩ⏕┙ߥߤ㧘ᄙጘߦࠊߚࠆ૞ᬺࠍਗⴕߒߡⴕ߁ᔅⷐ߇޽ࠅ߹ߒ
ߚ㧚߹ߚ㑐ଥ⠪ߛߌߢߥߊ㧘ᄢ൓ߩ੐ോ⡯ຬ㧘ᛛⴚ⡯ຬߩදജࠍઔߋߎߣߣߥࠅ߹ߒߚ㧚ᦼ㑆ਛ㧘࠴࡯ࡓࠍ⚵ࠎߛડᬺ࡮⽷࿅ߩᣇ‫ߣޘ‬ㅪᣣᅁ⿛ߒߚ
ߎߣࠍᕁ޿಴ߒ߹ߔ㧚ᄙߊߩੱ‫ߣޘ‬ᄙߊߩᯏ㑐ߩදജࠍ޿ߚߛ߈㧘┫Ꮏ㧘ߘߒߡ⹜ㆇォ㐿ᆎߦߎ߉ߟߌ߹ߒߚ߇㧘ࡊࡠࠫࠚࠢ࠻ߪᐔᚑ 17 ᐕ 12 ᦬ 7ᣣߦᕁࠊߧ੐ᘒߦ㒱ࠆߎߣߦߥࠅ߹ߒߚ㧚⎇ⓥᚑᨐ
⎇ⓥࡊࡠࠫࠚࠢ࠻ߩ⎇ⓥ㕙ߦߟ޿ߡ◲නߦ⚫੺ߒ߹ߔ㧚એਅߩߣ߅ࠅ㧘ߐ߹ߑ߹ߥᛛⴚ⊛ⷰὐ߆ࠄߩᬌ⸛ࠍⴕ޿߹ߒߚ[3]㧚
ԘHHEG ߩ⎇ⓥ㐿⊒㧦HHEG ߩㆇォᕈ⢻⹏ଔ㧘ᾲᵹേ․ᕈ⹏ଔ㧘㔚᳇ൻቇ․ᕈ⹏ଔ㧘࠻࡜ࠗࡏࡠࠫ
࡯․ᕈ⹏ଔࠍⴕ޿߹ߒߚ㧚ㆇォᕈ⢻⹏ଔߦ߅޿ߡ
ߪ㧘߹ߕ HHEG ታ⸽ᯏߩ⎇ⓥ⸘᷹ࠪࠬ࠹ࡓࠍ᭴▽ߒ㧘᣹࿶ㆇォ⹜㛎࡮᳓⚛ଏ⛎ㆇォ⹜㛎࡮㒠࿶ㆇォ⹜㛎ࠍታᣉߒߡ㧘ⵝ⟎ฦㇱ૏ߢߩ࿶ജ㧘⚐᳓㊂㧘᷷ᐲ㧘᳓⚛ࠟࠬ⊒↢㊂㧘㔚ജ╬ߩ࠺࡯࠲ࠍขᓧߒ㧘ታ⸽ᯏ߇ၮᧄ⊛ߥ⢻ജ㧔40MPa㧘30Nm3/h㧕ࠍ᦭ߔࠆߎߣ⏕⹺ߒ߹ߒߚ㧚㔚᳇ൻቇ․ᕈ⹏ଔߦ߅޿ߡ
ߪ㧘ዊဳߩࡕ࠺࡞࠮࡞ࠍ૶↪ߒߡ㧘ട࿶ߦࠃࠆ࠽
ࡈࠖࠝࡦ⤑ߩવዉᐲ㧘ࠛࡀ࡞ࠡ࡯ല₸ߥߤ߳ߩᓇ
㗀ߦߟ޿ߡ⍮⷗ࠍᓧ߹ߒߚ㧚ᾲᵹേ․ᕈ⹏ଔߦ߅
޿ߡߪ㧘᳓㔚⸃ߦ㑐ࠊࠆᾲᵹേ໧㗴ߩℂ⺰⸃ᨆߣߒߡ㧘᳓㔚⸃࠮࡞ᾲᵹേ⸃ᨆࡊࡠࠣ࡜ࡓࠍ㐿⊒ߒ㧘࠮࡞ౝߩ᳓⚛㧘㉄⚛㧘᳓㧘⫳᳇ߩᵹ㊂߿᷷ᐲಽᏓ
ࠍᮨᡆߔࠆߎߣ߇ߢ߈߹ߒߚ㧚࠻࡜ࠗࡏࡠࠫ࡯․ᕈ⹏ଔߦ߅޿ߡߪ㧘ᵹ㊂⺞▵ᑯߢ૶↪ߐࠇࠆ᠁േ
᧚ᢱࠬ࠹࡜ࠗ࠻ߩ᳓⚛ਛߢߩ៺ᡂ៺⠻ߦߟ޿ߡߩ
⍮⷗ࠍᓧ߹ߒߚ㧚ԙHHEG࡮⥄ὼࠛࡀ࡞ࠡ࡯ߩࡑ࠶࠴ࡦࠣߦ㑐ߔࠆ⎇ⓥ㐿⊒㧦㘑ജ⊒㔚⸳஻න૕⹏ଔߣ HHEG 㔚ജᄌേ⹏ଔࠍⴕ޿߹ߒߚ㧚㘑ജ⊒㔚⸳஻න૕⹏ଔߦ߅
޿ߡߪ㧘2 ⒳㘃ߩ㘑࡟ࡦ࠭ࡑࠗࠢࡠ㘑ゞࠍ㐿⊒ߒ㧘ߘࠇߙࠇߩ⊒㔚ᕈ⢻⹜㛎ࠍ㘑ᵢ㧘ߥࠄ߮ߦ㊁ᄖߢⴕ޿߹ߒߚ㧚㔚ജᄌേ⹏ଔߦ߅޿ߡߪ㧘HHEG ታ⸽ᯏߩㆇォᤨߦ෼㓸ߐࠇߚ࠺࡯࠲ࠍ↪޿ߡ㧘᳓⚛
⵾ㅧߩࡕ࠺࡝ࡦࠣࠍታᣉߔࠆߣߣ߽ߦ㧘㘑ജ⊒㔚

㔚⸃䉶䊦
䉺䊮䉪

䌈䌈䌅䌇๟ㄝᯏེ

䊂䉞䉴䊕䊮䉰䊷

⫾࿶ེ

೙ᓮቶ

䌈䌈䌅䌇
31 m

࿑ 3 ᳓⚛ࠬ࠹࡯࡚ࠪࡦߩ㈩⟎ [5]J. HTSJ, Vol. 48, No. 203

ࡊࡠࠫࠚࠢ࠻ Q࿑ 4 ੐᡿⋥ᓟߩ᳓⚛ࠬ࠹࡯࡚ࠪࡦ㧔ධ஥ࠃࠅ᠟ᓇ㧕㧦⊕ᾍߣ㤥ᾍ߇ߺ߃ࠆ [4]2005 ᐕ 11 ᦬ 14 ᣣߦ㜞࿶ࠟࠬ⵾ㅧᣉ⸳ߩቢᚑᬌ
ᩏวᩰ⸽ࠍฃߌߚᓟ㧘⠉ 15 ᣣ߆ࠄ⵾ㅧࡔ࡯ࠞ࡯ߦ
ࠃࠆ HHEG ߩ⹜ㆇォ߇㐿ᆎߒ߹ߒߚ㧚⹜ㆇォߢߪ㧘ฦᯏེߩ૞േࠍ⏕⹺ߒߥ߇ࠄᓢ‫ߦޘ‬᳓⚛࿶ജࠍ਄ߍ㧘40MPa ߩ᳓⚛ߩ⊒↢߇⏕⹺ߢ߈߹ߒߚ㧚ߘߒߡ㧘12 ᦬ 7 ᣣ㧘HHEG ߆ࠄ⫾࿶ེ߳ߩ᳓⚛ଏ⛎࠹ࠬ࠻ࠍⴕߞߡ޿ࠆᦨਛ㧘ඦᓟ 1 ᤨ 22 ಽߦ⓭ὼ੐᡿߇⊒↢ߒ߹ߒߚ㧚ᄢ߈ߥ῜⊒㖸ߣߣ߽ߦ㧘㉄⚛ಽ㔌࠲ࡦࠢ಴ญ஥
ߩ㉄⚛᡼಴࡜ࠗࡦߩ㈩▤߇⎕ⵚߒ㧘࿶ജ⸘ߥߤߩ
ᯏེ߇⎕უߒ HHEG ቶౝߦ㘧ᢔߔࠆߣߣ߽ߦ㧘⎕៊▎ᚲߣࠟࠬ᡼ᢔࡌࡦ࠻߆ࠄࠟࠬߣ᳓߇ྃ಴ߒ߹
ߒߚ㧔࿑ 1㧘4㧘5㧘6 ෳᾖ㧕㧚ߎߩ᳓ߣ⧯ᐓᢙߩࠟ࡜ࠬዊ ߇ࠬ࠹࡯࡚ࠪࡦᄖㇱ 10m એౝߩ▸࿐ߦ߽㘧ᢔߒ㧘᳓ߦߪ⣣㘩ᕈߩ‛⾰߇฽߹ࠇߡ޿ߚߚ
߼㧘᳓ߩ㘧ᴜߦࠃߞߡ๟ㄝߩ㚢ゞゞਔ 5 บߩ⓹ࠟ࡜ࠬߥ޿ߒࡏࡦࡀ࠶࠻ߦᓸዊ⣣㘩∥ࠍ↢ߓ߹ߒߚ㧚ᐘ޿㧘๟ㄝߦᱠⴕ⠪߇޿ߥ߆ߞߚߚ߼ੱ⊛ⵍኂߪ޽ࠅ߹ߖࠎߢߒߚ[4]㧚
ቇౝߦ޿ߚࡊࡠࠫࠚࠢ࠻㑐ଥ⠪㧘੐ോ⡯ຬ㧘߹ߚㅢႎߦࠃࠅᶖ㒐⟑㧘⼊ኤ⟑㧘ႎ㆏㑐ଥߩᣇ‫߇ޘ‬ߔߋߐ߹㚟ߌߟߌ㧘ቇ↢߿⡯ຬߥߤ߽๟࿐ߦ㓸߹ࠅ㧘⃻႐ߪ㛍ὼߣߥࠅ߹ߒߚ㧚⹜ㆇォߩ㑐ଥ⠪ߪ૗߇⿠ߎߞߚߩ߆⋥ߜߦߪᛠីߢ߈߹ߖࠎߢߒߚ㧚㑐ଥ⠪ߪ⪭⢙ߔࠆ૛⵨ߔࠄߥߊ㧘ߘߩᣣߩ᥅߆ࠄ
ේ࿃ⓥ᣿ࠍ㐿ᆎߒ߹ߒߚ㧚੐᡿ේ࿃ߩ⺞ᩏᧂ᧪ߩࠛࡀ࡞ࠡ࡯ߣߒߡᦼᓙߐࠇߡ޿ࠆ᳓⚛ࠛࡀ࡞ࠡ࡯ߩ⎇ⓥߦ߅޿ߡ㧘੐᡿ࠍ⿠ߎߒߚ⽿છࠍ
ᄢቇߪ㊀ߊฃߌߣ߼㧘੐᡿ߩේ࿃ࠍⓥ᣿ߔࠆߣߣ

વᾲ 2009 ᐕ 4 ᦬

- 51 -

࿑ 5 ㉄⚛㈩▤ߩ੐᡿೨㧔਄㧕ߣ੐᡿ᓟ㧔ਅ㧕ߩ⁁ᴫ [4]࿑ 6 HHEG ቶౝߦ㘧ᢔߒߚ࿶ജ⸘㧔ਛᄩ㧕ߣ㈩▤㧔ฝ਄㧕[4]߽ߦ㧘੐᡿ߩౣ⊒㒐ᱛߦะߌߡਁోߥኻ╷ࠍ⻠ߓࠆߴߊ㧘ቇౝߦ‫ޟ‬੐᡿⺞ᩏᆔຬળ‫ޠ‬෸߮ᄖㇱߩਛ┙⊛┙႐߆ࠄ੐᡿ේ࿃ⓥ᣿ߦଥࠊࠆ૞ᬺ࡮ౝኈࠍ
⹏ଔߔࠆ⚵❱ߣߒߡ‫ޟ‬ᄖㇱ⹏ଔᆔຬળ‫ߩ⟎⸳ࠍޠ‬਄㧘⺞ᩏߦขࠅ⚵ߺ߹ߒߚ㧚੐᡿⺞ᩏᆔຬળߪ㧘

J. HTSJ, Vol. 48, No. 203

ࡊࡠࠫࠚࠢ࠻ Q
ߎߩ෻ᔕ㐿ᆎߩᒁ߈㊄ߣߥߞߚ⋥ធ⊛ේ࿃ߪ㧘࠮࡞ౝߩ޽ࠆ৻ㇱߦ߅ߌࠆ㧘40MPa ߩ㜞࿶ਅߦ߅ߌࠆ࠴࠲ࡦ㔚ᭂߩ⊒ᾲ෻ᔕߣ㧘㉄⚛ߣ᳓⚛ߩᷙว᳇ߩ⊒ᾲ෻ᔕߩ޿ߕࠇ߆ߢ޽ߞߚน⢻ᕈ߇㜞޿㧚࠴࠲ࡦ㔚ᭂߩ෻ᔕߪ㧘㜞࿶㉄⚛㧘ࡈ࠶⚛㧘᳓ߣߩ෻ᔕߩน⢻ᕈ߇⠨߃ࠄࠇ㧘㉄⚛ߣ᳓⚛ߩᷙว᳇߇
↢ߓߚේ࿃ߪ㧘㓁ᭂ஥ߣ㒶ᭂ஥ߩ㑆ߩᢙච kPa ⒟ᐲߩᏅ࿶ߦࠃߞߡ㧘㓁ᭂ஥ߩᓴⅣ᳓ਛߦሽ࿷ߒߚ
㉄⚛᳇ᵃ߇ MEA ߥ޿ߒߪࠪ࡯࡞ㇱߩߥࠎࠄ߆ߩ
ᰳ㒱ࠍㅢߞߡ㒶ᭂ஥ߦṳᵨߒߚߎߣ߇ᦨ߽น⢻ᕈ߇㜞޿㧚MEA ߩࡇࡦࡎ࡯࡞ࠍㅢߒߡ㒶ᭂ஥ߦ⒖േߒߚ႐ว㧘㉄⚛ࠍ↢ߓࠆ㓁ᭂ߇ MEA ߩਅ஥ߦ㈩⟎ߐࠇߡ޿ࠆߎߣߦࠃࠅṳᵨࠍഥ㐳ߒߚߣ߽⠨߃ࠄࠇࠆ㧚(3) 㔚⸃࠮࡞ߩ৻ㇱߢ⇣Ᏹ෻ᔕ߇㐿ᆎߒߚᓟ㧘࿶ജߩ⇣Ᏹ߇ᬌ⍮ߐࠇ㔚ᵹ߇஗ᱛߐࠇߚ߇㧘㔚⸃ࠍ஗ᱛߒߚᓟ߽෻ᔕߪ⛯޿ߚ㧚(4) 㔚⸃࠮࡞ߩ⇣Ᏹ෻ᔕߦࠃߞߡ㧘㜞᷷㧘㜞࿶߇⊒↢ߒ㧘᳓⚛㈩▤㧘㉄⚛㈩▤ߦ߅޿ߡ቟ోᑯ߇
૞േߒߚ㧚ߎࠇߦࠃࠅ࿶ജߪ৻ᣤ㒠ਅߒߚ߇㧘㔚⸃࠮࡞ߩ෻ᔕ߇⛯޿ߚߚ߼ౣ߮♽ో૕ߩ࿶ജ߇਄
᣹ߒߚ㧚৻ᣇ㧘㔚⸃࠮࡞⇣Ᏹ߇↢ߓߚ⋥ᓟ߆ࠄ㧘෻ᔕ↢ᚑ‛ߣ㔚⸃࠮࡞ߩ⎕უߢ↢ߓߚ⎕ 㧘෸߮᳓⚛߇ᓴⅣ᳓ߦㆇ߫ࠇ㉄⚛ಽ㔌࠲ࡦࠢߦ㆐ߒ㧘ߐࠄߦ቟ోᑯߦ⥋ࠆ㉄⚛㈩▤ߦ߹ߢ೔㆐ߒߚ㧚ߎࠇࠄ߇㉄⚛㔓࿐᳇ਛߢΆ὾ߔࠆߎߣߦࠃࠅዪᚲ⊛ߥㆊᄢ࿶ജࠍ⊒↢ߒ㧘ߐࠄߦߪ࿶ജᵄ߇㧘వ┵߇㐽ߓߚ㈩▤ౝߦવࠊࠅᕆỗߥ࿶❗ࠍ↢ߓߡዪᚲ⊛ߥㆊᄢ࿶ജࠍ⊒↢ߒ㧘㉄⚛㈩▤ߩᑧᕈ⎕უࠍ߽ߚࠄߒߚ㧚(5) HHEG ߪ㔚⸃࠮࡞ౝߩᏅ࿶ࠍ৻ቯ▸࿐ౝߦ೙ᓮߔࠆᯏ⢻ࠍ߽ߟ߇㧘ᕆỗߥ࿶ജ਄᣹ࠍㆱߌࠄ
ࠇߥ߆ߞߚߎߣߦ߽੹࿁ߩ㈩▤ߩ⎕უߩේ࿃ߩ৻
┵߇޽ߞߚ㧚ᓴⅣ᳓㈩▤ߦߪ࿶ജߩ⸃᡼ᯏ᭴߇ߥ
ߊ㧘᳓⚛ࠟࠬߣ㉄⚛ࠟࠬ㈩▤ߩ቟ోᑯߪ࿶ജ߇㒠ਅߒߚߚ߼৻ᣤ㐽ᱛߒߚߣផቯߐࠇ㧘ߘߩᓟ߽ᒁ
߈⛯޿ߡ㔚⸃࠮࡞ߩ⇣Ᏹ෻ᔕ߇⛮⛯ߒߚߚ߼ߦ㧘ౣᐲ࿶ജ਄᣹߇⿠ߞߚ㧚(6) ㈩▤⎕ⵚߦࠃߞߡ㧘ᓴⅣ᳓ߣߣ߽ߦ㔚⸃࠮࡞ߩ෻ᔕ↢ᚑ‛߇㈩▤ᄖߦྃ಴ߒߚ㧚㔚⸃࠮࡞ߢ↢ߓߚ↢ᚑ‛ߦߪ㧘࿕૕ߣߒߡߪ࠴࠲ࡦߩൻว‛ߣ὇ൻ‛㧘ᶧ૕ߦߪ⣣㘩ᕈߩ޽ࠆࡈ࠶ൻ᳓⚛㉄㧘
ࠬ࡞ࡎࡦ㉄ࠗࠝࡦߥߤߣ㧘㋕ߥߤߩ㜞࿶ኈེߩ᭴
ᚑర⚛߇฽߹ࠇߡ޿ߚ㧚ᄢቇ߆ࠄ᧚ᢱᒝᐲ㧘ᾲᵹ૕Ꮏቇ㧘Ά὾㧘Άᢱ㔚ᳰ㧘㔚᳇ൻቇ㧘቟ోᎿቇ㧘᧚ᢱ⑼ቇߥߤߩኾ㐷ኅߣ㧘㑐ଥડᬺߩᛛⴚ⠪㧘῜⊒቟ో⎇ⓥߩኾ㐷ኅߦടࠊߞߡ޿ߚߛ߈߹ߒߚ㧚⺞ᩏߪ৻ᐕ૛ࠅߦࠊߚߞߡ
⛯ߌࠄࠇ㧘⑔ጟ⋵Ꮏᬺ଻቟⺖ࠍߪߓ߼㑐ㅪ⋭ᐡߦ⺞ᩏ⚿ᨐࠍႎ๔ߔࠆߣߣ߽ߦ㧘ႎ㆏ᯏ㑐߿࿾ၞ૑᳃⺑᣿ળ㧘ቇౝળ⼏ࠍㅢߓߡ⺞ᩏౝኈࠍ౏⴫ߒ߹
ߒߚ㧚ᦨ⚳⊛ߥ⺞ᩏ⚿ᨐߪ 2007 ᐕ 3 ᦬ 30 ᣣઃ‫਻ޟ‬Ꮊᄢቇ᳓⚛ࠬ࠹࡯࡚ࠪࡦ੐᡿⺞ᩏႎ๔ᦠ㧔╙ 3ႎ㧕‫[ߚߒ߹߼ߣ߹ࠅߣߦޠ‬5]㧚
੐᡿ේ࿃⺞ᩏߪਥߦએਅߩᛛⴚ⊛⺞ᩏ㗄⋡ߦߟ޿ߡⴕ޿߹ߒߚ㧚(1) HHEG ⸥㍳࠺࡯࠲㧘⋙ⷞࡆ࠺ࠝ⸥㍳ߩಽᨆ
(2) ㈩▤㧘ᯏེ㧘ᱷ⇐‛ߩ⺞ᩏߣൻቇಽᨆ
(3) ᧚ᢱᒝᐲߦ㑐ߔࠆᬌ⸛(4) ᾲᵹ૕㑐ଥߩᬌ⸛(5) 㔚⸃࠮࡞ߩ⺞ᩏ੐᡿ㆊ⒟ߩ᭎ⷐ
਄⸥ߩಽᨆࠍ✚วߒߡ㧘੐᡿ߩㆊ⒟ߪ᭎ߨᰴߩ
ࠃ߁ߦផቯߐࠇ߹ߒߚ㧚એਅߪႎ๔ᦠ[5]߆ࠄߩᛮ☴ߢߔ㧚(1) ੐᡿ߪ㧘13 ᤨ 22 ಽ 36 ⑽㗃߆ࠄ㔚⸃࠮࡞ߩ⇣Ᏹߦࠃࠅ㜞᷷㜞࿶߇⊒↢ߒߡ቟ోᑯ߇૞േߒߚ
ㆊ⒟㧔╙৻Ბ㓏㧕ߣ㧘ߎࠇߦ઻ߞߡ⊒↢ߒߚ㜞᷷㜞࿶ߣ‛⾰⒖േ㧔㈩▤ࠍㅢߓߚ᳓㧘ࠟࠬ㧘⇣‛ߩ
⒖േ㧕ߦࠃߞߡᦨ⚳⊛ߦ 13 ᤨ 23 ಽ 18 ⑽ߦ㉄⚛஥㈩▤ߢΆ὾ߣ⎕ⵚ߇⿠ߎߞߚㆊ⒟㧔╙ੑᲑ㓏㧕ߦಽߌߡᢛℂߢ߈ࠆ㧚(2) 㔚⸃࠮࡞࠲ࡦࠢౝߦ߅޿ߡ㧘㔚⸃࠮࡞ߪ߶
߷ో὾ߒ㧘㔚ᭂߩ࠴࠲ࡦߩᄢඨߪ෻ᔕߒߚ㧔࿑ 7㧕㧚

࿑ 7 㔚⸃࠮࡞ߩ⎕៊⁁ᘒ [5]વᾲ 2009 ᐕ 4 ᦬- 52 -J. HTSJ, Vol. 48, No. 203

ࡊࡠࠫࠚࠢ࠻ Qࠍ⠨ᘦߦ޿ࠇߡ૕೙ࠍ᭴▽ߒߡ޿ߊᔅⷐ߇޽ࠆߎ
ߣ߇᣿ࠄ߆ߦߥࠅ߹ߒߚ㧚ߎߩࠃ߁ߥ㧘቟ోߦኻߔࠆข⚵ߺߦߟ޿ߡߩᢎ⸠ߪ㧘ߘߩᓟߩદㇺࠠࡖࡦࡄࠬߦ߅ߌࠆ቟ో▤ℂ૕೙᭴▽ߣታ〣ߩᒁ߈㊄ߣߥࠅ߹ߒߚ㧚(7) ⹜ㆇォࠍ㐿ᆎߒߡ߆ࠄ೨ᣣ߹ߢ㧘෸߮੐᡿ᒰᣣߦ㔚⸃࠮࡞ߩ⇣Ᏹ෻ᔕ߇⊒↢ߔࠆ⋥೨߹ߢ㧘
HHEG ߩ⇣Ᏹ⃻⽎ߪ⹺߼ࠄࠇߥ߆ߞߚ㧚એ਄ߩ⺞ᩏ߆ࠄ㧘੐᡿ߩㆊ⒟ߪ᣿ࠄ߆ߦߐࠇ߹
ߒߚ߇㧘㔚⸃࠮࡞⇣Ᏹ෻ᔕߩ⊒↢ේ࿃ࠍቢోߦ․ቯߔࠆߦߪ⥋ࠄߕ㧘⇣Ᏹߦߟߥ߇ࠆน⢻ᕈߩ޽ࠆ޿ߊߟ߆ߩ㗄⋡ߦߟ޿ߡߩ⺖㗴߇ᶋ߈ᓂࠅߦߥࠅ
߹ߒߚ㧚 MEA ߿ࠪ࡯࡞᧚ᢱߥߤ᧚ᢱߦ㑐ㅪߔࠆ੐ᨩ߿㧘᳇ᶧᵹࠇߥߤ㧘޿ߕࠇ߽ 40MPa ߩ㜞࿶ਅߣ޿߁᧦ઙߦ߅ߌࠆ‛⾰ߩᝄࠆ⥰޿ߩℂ⸃ߩ߁߃ߦߚߞߡⓥ᣿ߐࠇࠆߴ߈߽ߩߢߔ߇㧘ߘߩߚ߼ߩ
ᢥ₂ᖱႎ߇⃻ᤨὐߢሽ࿷ߒ߹ߖࠎ㧚ߘߩߚ߼਻Ꮊ
ᄢቇߢߪ㧘㜞࿶ਅߢߩ㔚⸃࠮࡞᭴ᚑㇱ᧚ߩ෻ᔕ㧘㔚⸃࠮࡞ౝߩᵹേ㧘㜞࿶ਅߢߩ᳓⚛ߩၮ␆‛ᕈߥߤߦߟ޿ߡ㧘ၮ␆⎇ⓥߦขࠅ⚵ࠎߢ޿߹ߔ㧚▤ℂㆇ༡ߩ⺖㗴ᛛⴚ⊛ߥ⺞ᩏߦട߃ߡ㧘▤ℂㆇ༡ߦ㑐ߔࠆ⺞ᩏࠍⴕ޿߹ߒߚ㧚ߎࠇߪ㧘ߘߩᩮᐩߦ޽ࠆ቟ో▤ℂ
਄ߩ໧㗴ࠍ᣿ࠄ߆ߦߔࠆߎߣߢ㧘ౣ⊒㒐ᱛߣ㧘ࠠࡖࡦࡄࠬో૕ߩ੐᡿㒐ᱛ૕೙ߩ৻ጀߩะ਄ߦ⾗ߔࠆߚ߼ߢߔ㧚
߹ߕ㧘ߒ߫ߒ߫ᜰ៰ߐࠇࠆࠃ߁ߦ㧘ᣂᛛⴚߩ㐿⊒ߦ߅޿ߡߪ㑐ଥ⠪㑆ߩචಽߥᖱႎ౒᦭߇ߥߐࠇ
ߡ޿ߥ޿ߎߣ߇੐᡿ߦߟߥ߇ࠆߎߣ߇᜼ߍࠄࠇ߹
ߔ㧚߹ߚ㧘ᧂ⍮ߩ਎⇇ߦ޿ߤ߻ᣂⷙᛛⴚ㐿⊒ߦ߅޿ߡߪෂ㒾ߪߟ߈߽ߩߣߪ⸒߃㧘චಽߥ቟ోᬌ⸽
ࠍⴕ޿㧘Ბ㓏ࠍ〯ࠎߢታ⸳஻ߣߔߴ߈ߢ޽ߞߚߎ
ߣ߇ᜰ៰ߐࠇ߹ߒߚ㧚⸳஻ߩ▤ℂㆇ༡ߪડᬺਥዉߢታᣉߐࠇߡ޿߹ߒ
ߚ߇㧘ᒰ੐⠪ߢ޽ࠆᄢቇߦࠃࠆ࡝ࠬࠢࠕ࠮ࠬࡔࡦ
࠻㧘቟ో▤ℂ૕೙㧘ἴኂᤨߩኻᔕߥߤ߇ਇ⿷ߒߡ
޿߹ߒߚ㧚․ߦ㧘ᄢቇߩ቟ో▤ℂ૕೙ߪ᳃㑆ડᬺߦᲧߴߡᔅߕߒ߽චಽߣߪ⸒߃ߕ㧘ᄢቇߩ․ᱶᕈ

વᾲ 2009 ᐕ 4 ᦬߅ࠊࠅߦ
ᛛⴚ⊛ⷰὐ߆ࠄ㧘 HHEG ߩᣧᦼᓳᣥߪᢿᔨߔ
ࠆߎߣߦߥࠅ߹ߒߚ㧚ߒ߆ߒ㧘ࠠࡖࡦࡄࠬߩ᳓⚛
ࠬ࠹࡯࡚ࠪࡦߩ⸳஻ࠍ᦭ലߦᵴ߆ߒߡ዁᧪ߦߟߥ
ߍࠆߴߊ㧘⃻࿷㧘ᣂⷙ⺖㗴ࠍ⸳ቯߒ቟ోߥㆇォࠍ߼ߑߒߚౣ㐿⸘↹߇ㅴ߼ࠄࠇߡ޿߹ߔ㧚એ਄ㅀߴߚᄢቇࠠࡖࡦࡄࠬߢߩ⚻㛎߇㧘ᧂ᧪ߩࠛࡀ࡞ࠡ࡯
ᛛⴚߩ⊒ዷߩߚ߼ߦዋߒߢ߽ᓎ┙ߟߎߣࠍ㗿ߞߡ
޿߹ߔ㧚
ෳ⠨ᢥ₂
[1] 21 ਎♿ COE ࡊࡠࠣ࡜ࡓ ᳓⚛೑↪ᯏ᪾ࠪࠬ࠹
ࡓߩ⛔วᛛⴚ ᦨ⚳ᚑᨐႎ๔ᦠ㧘਻Ꮊᄢቇ(2008).
[2] ᳓ߩ㔚᳇ಽ⸃ߩߺߢ㜞࿶ߩ᳓⚛ࠍ⊒↢ ਃ⪉໡੐߇㔚⸃ⵝ⟎ࠍ㐿⊒㧘ᣣ⚻߽ߩߠߊࠅ㧘
2004.6㧘ᣣ⚻ BP ␠ (2004) 83.
[3] ᐔᚑ 17 ᐕᐲ࿾ၞᣂ↢ࠦࡦ࠰࡯ࠪࠕࡓ⎇ⓥ㐿⊒੐ᬺ‫ߩࠬ࡟࡯ࠨ࠶࡟ࡊࡦࠦޟ‬㜞࿶᳓㔚⸃᳓⚛ࠬ࠹࡯࡚ࠪࡦߩ㐿⊒‫ޠ‬ᚑᨐႎ๔ᦠ㧘ᆔ⸤⠪㧦਻Ꮊ⚻ᷣ↥ᬺዪ (2006).
[4] ᧖᧛ਂ৻㧘੐᡿ߩ᭎ⷐ㧙╙ 2 㧙㧔ᐔᚑ 17
ᐕ 12 ᦬ 26 ᣣ㧕㧘਻Ꮊᄢቇࡎ࡯ࡓࡍ࡯ࠫ(2005).
[5] ਻Ꮊᄢቇ᳓⚛ࠬ࠹࡯࡚ࠪࡦ੐᡿⺞ᩏᆔຬળ㧘੐᡿⺞ᩏႎ๔ᦠ㧔╙ 3 ႎ㧕2007 ᐕ 3 ᦬ 30 ᣣ㧘(2007).㧔ⷐ⚂ ߪ਻Ꮊᄢቇࡎ࡯ࡓࡍ࡯ࠫߦឝ
タ㧕

- 53 -J. HTSJ, Vol. 48, No. 203

ࡊࡠࠫࠚࠢ࠻ Q

᡼ᾲᕈ㍑᧼‫࠷ࡀ࡯ࡎࡌ࡯ࠦޟ‬տ‫ߩޠ‬㐿⊒Development of “KOBEHONETSU” Heat Releasing Steel Sheet㜞ᯅ ๺㓶㧔␹ᚭ⵾㍑㧕
Kazuo Takahashi (Kobe Steel Ltd.)ߪߓ߼ߦ
ㄭᐕ㧘࠺࡯࠲ࠬ࠻࡟࡯ࠫ࠺ࡃࠗࠬ㧘࠺ࠖࠬࡊ࡟
ࠗ╬ߩ㔚ሶᯏེ߿㧘ኅ㔚⵾ຠߩ㜞ᕈ⢻ൻߦ઻ߞߡ㧘IC ߿ඨዉ૕ߥߤߩ⊒ᾲ㊂߇ᄢ߈ߊߥࠆ௑ะߦ޽
ࠅ㧘߭޿ߡߪߎࠇࠄߩ㔚ሶ࡮㔚᳇ᯏེߦ↪޿ࠄࠇࠆ♖ኒㇱຠߩ⠴ᾲᕈ㧘ኼ๮߇໧㗴ߦߥࠅߟߟ޽ࠆ㧚ߎߩ⊒ᾲ㊂ߩჇടߦኻᔕߔࠆߚ߼ߦ㧘ࡈࠔࡦߦࠃ
ࠆᒝ೙ឃᾲ㧘ⵝ⟎ߘߩ߽ߩߦⓣࠍ޽ߌౝㇱߩᾲࠍ⥄ὼ᡼ᢔߔࠆߥߤߩኻ╷߇ታᣉߐࠇߡ޿ࠆ߇㧘ടᎿ⾌ߩჇട㧘᳇ኒᕈ߿㔚⏛ᵄࠪ࡯࡞࠼ᕈߩਇ⿷ߥ
ߤߩ໧㗴߇↢ߓߡ޿ࠆ㧚ߎߩࠃ߁ߥᾲ໧㗴߳ߩኻ╷ߣߒߡ㧘㔚ሶᯏེ߿ኅ㔚⵾ຠߩ╲૕ߦ↪޿ࠄࠇߡ޿ࠆ⭯㍑᧼ߦ⴫㕙ಣ
ℂࠍ߶ߤߎߔߎߣߦࠃࠅ㧘╲૕ౝㇱߩᾲࠍല₸⊛㧔એᓟ ᡼ᾲᕈ
ߦ᡼ᢔߐߖࠆ‫࠷ࡀ࡯ࡎࡌ࡯ࠦޟ‬տ‫ޠ‬㍑᧼ߣ⸒߁㧚㧕ࠍ㐿⊒ߒߚ㧚

Q12 =

(

4

4

)

A1σ T1 − T2 (1)⎞
1 A1 ⎛ 1⎜ − 1⎟⎟+
ε 1 A2 ⎜⎝ ε 2⎠ߣߥࠆ㧚߹ߚ㧘╲૕߆ࠄᄖㇱⓨ㑆߳ߩ᡼኿ᾲ Q34
ߪ㧘

Q34 =

(

4

A3σ T3 − T44

)  (2)⎞
1 A3 ⎛ 1⎜⎜ − 1⎟⎟+ε 3 A4 ⎝ ε 4⎠ߣ⴫ࠊߔߎߣ߇ߢ߈ࠆ㧚ߎߎߢσߪࠬ࠹ࡈࠔࡦࡏ
࡞࠷ࡑࡦቯᢙߢ޽ࠆ㧚ᑼ(1)㧘(2)ࠃࠅ㧘ᾲ᡼኿ߢવ
ࠊࠆᾲ㊂ࠍᄢ߈ߊߔࠆߚ߼ߦߪ㧘╲૕㕙ߩ᡼኿₸ࠍᄢ߈ߊߔࠇ߫ࠃ޿ߎߣ߇ࠊ߆ࠆ㧚㧚᡼ᾲᕈ㍑᧼ߩ⠨߃ᣇᾲ߇વࠊࠆࡔࠞ࠾࠭ࡓߦߪᾲવዉ㧘ኻᵹવᾲ㧘ᾲ᡼኿ߩ 3 ߟ߇޽ࠆߎߣ߇⍮ࠄࠇߡ޿ࠆ㧚᡼ᾲᕈ
㍑᧼ߪߎߩ߁ߜᾲ᡼኿ߦࠃࠆ᡼ᾲࠍଦㅴߔࠆߚ߼
ߦ㐿⊒ߐࠇߚ㧚࿑ 1 ߦ␜ߒߚ◲ᤃࡕ࠺࡞ߦၮߠ޿
ߡ㧘᡼ᾲᕈ㍑᧼ߩലᨐߩ᭎ⷐࠍ⺑᣿ߔࠆ[1]㧚ᾲ᡼኿ߢવࠊࠆᾲ㊂ࠍ㧘࿑ 1 ߩࠃ߁ߦඨ౞╴⁁ߢ㧘ౝ஥߆ࠄ⊒ᾲ૕㧘╲૕᧚ᢱ㧘ᄖㇱⓨ㑆ߩ㗅⇟ߢ㈩⟎ߐࠇߡ޿ࠆࡕ࠺࡞ࠍ↪޿ߡ⠨߃ࠆ㧚⊒ᾲ૕ߩ᡼ᾲ㕙ࠍԘ㧘╲૕᧚ᢱߩౝ㕙ࠍԙ㧘ᄖ㕙ࠍԚ㧘ᄖㇱⓨ㑆㕙ࠍԛߣߔࠆ㧚߹ߚ㧘ߘࠇߙࠇߩ㕙ߩ㕙Ⓧࠍ A1㧘A2㧘A3㧘A4㧘⴫㕙᷷ᐲࠍ T1㧘T2㧘
T3㧘T4㧘᡼኿₸ࠍε1㧘ε2㧘ε3㧘ε4 ߣߔࠆ㧚ᾲવዉߣኻᵹߦࠃࠆવᾲࠍήⷞߔࠆߣ㧘⊒ᾲ૕߆ࠄ╲૕߳ߩ᡼኿ᾲ Q12 ߪ㧘

╲૕
⊒ᾲ૕

ԛ

Ԛԙ

Ԙ
Q12

Q34

‫ڏ‬ᾲ᡼኿

࿑ 1 ╲૕ߩᾲ᡼኿ࡕ࠺࡞
ᑼ(2)ࠍ↪޿ߡ㧘╲૕߆ࠄᄖㇱⓨ㑆߳ߩ᡼኿ᾲ
Q34 ࠍ⷗Ⓧ߽ࠆ㧚⸘▚ࠍ◲නߦߔࠆߚ߼ߦᄖㇱⓨ㑆߇㕖Ᏹߦචಽߦᄢ߈޿㧘ߔߥࠊߜ A4 = пߣߔࠆߣ㧘න૏㕙Ⓧᒰߚࠅߩ᡼ᾲ㊂ Q34/A3 ߪ㧘

(

4

Q34 A3 = ε 3σ T3 − T4

વᾲ 2009 ᐕ 4 ᦬ᄖㇱⓨ㑆- 54 -

4) (3)J. HTSJ, Vol. 48, No. 203

ࡊࡠࠫࠚࠢ࠻ Qߎߩࠃ߁ߥ⴫㕙ಣℂߦࠃࠅ㧘⴫ⵣਔ㕙ߩ᡼኿₸ࠍ
0.86 ߣߒߡ޿ࠆ㧚ߣߥࠆ㧚ߎߩᑼ߆ࠄ╲૕᷷ᐲߣᄖㇱⓨ㑆ߩ᷷ᐲߦᄌൻ߇ߥߌࠇ߫㧘᡼ᾲ㊂ߪ᡼኿₸ߦᲧ଀ߔࠆ㧘ߔߥࠊߜ╲૕᧚ᢱߩ᡼኿₸߇㜞ߊߥࠆߣ᡼ᾲ㊂߇Ⴧടߔࠆߎߣ߇ࠊ߆ࠆ㧚ߣߎࠈ߇㧘⴫ 1 ߦ␜ߔࠃ߁
ߦ╲૕᧚ᢱߣߒߡ૶ࠊࠇࠆ㊄ዻ᧚ᢱߩ᡼኿₸[1]ߪ
৻⥸ߦዊߐ޿୯ߢ޽ࠆ㧚߹ߚ㧘㔚ሶᯏེߩ╲૕ߦࠃߊ૶ࠊࠇߡ޿ࠆ੝㋦߼ߞ߈㍑᧼ߩ᡼኿₸߽ዊߐ޿㧚ߎࠇࠄߩߎߣ߆ࠄ╲૕᧚ᢱߦࠃࠆᾲ᡼኿ߪᯏ
ེౝㇱߩ᡼ᾲߦᵴ↪ߐࠇߡ޿ߥ޿ߎߣ߇ផቯߐࠇ
ࠆ㧚

᡼኿ᕈ⊹⤑
ਅ࿾ಣℂ
੝㋦߼ߞ߈
㍑᧼
੝㋦߼ߞ߈
ਅ࿾ಣℂ
᡼኿ᕈ⊹⤑

⴫ 1 ฦ⒳㊄ዻ᧚ᢱߩ᡼኿₸
᧚ᢱ
エ㍑
ࠬ࠹ࡦ࡟ࠬ
ࠕ࡞ࡒ࠾࠙ࡓ
㌃
੝㋦߼ߞ߈㍑᧼*㧔⠴ᜰ⚉ಣℂ㧕*ᵄ㐳▸࿐ 4.5㨪15.4 μm ߩᐔဋ୯

᡼኿₸
0.05
0.10
0.03
0.03
0.12

࿑ 2 ᡼ᾲᕈ㍑᧼ߩᢿ㕙᭴ㅧ᡼ᾲᕈ⊹⤑ߦߪ㧘ᾲ᡼኿ߦነਈߔࠆ‛⾰ߣߘߩ‛⾰ࠍ࿕ቯߔࠆ᧚ᢱ╬ߩᷝട೷߇ᔅⷐߢ޽ࠅ㧘⁛⥄ߦ‛⾰ߩㆬቯࠍⴕߞߡ޿ࠆ㧚߹ߚ㧘㔚ሶᯏེ߿ኅ㔚⵾ຠߩ╲૕ߣߒߡ໧㗴ߣߥࠆ⵾ຠടᎿᤨߩ೸
߇ࠇ߿ࠢ࡜࠶ࠢࠍ㒐ᱛߔࠆߚ߼ߦ㧘⴫㕙ಣℂᛛⴚ
ߦࠃߞߡടᎿᕈࠍ㜞߼ࠆᎿᄦࠍⴕߞߡ޿ࠆ㧚╲૕᧚ᢱߩ᡼኿₸ߩ㆑޿ߦࠃࠆ᡼ᾲ㊂ߩᄌൻࠍ㧘T4 = 300 K
⷗Ⓧ߽ࠆߚ߼ߦ㧘T3 = 323 K㧔50 ͠㧕㧔23 ͠㧕ࠍ઒ቯߒ㧘᡼኿₸߇ 0.12 ߣ 0.8 ߩ╲૕᧚ᢱࠍ↪޿ߚ႐วߩવᾲ㊂ࠍ㧘ᑼ(3)ࠍ↪޿ߡ⸘▚ߒᓟ⠪ߩ႐วߪ 126 W/m2ߚ㧚೨⠪ߩ႐วߪ 19 W/m2㧘ߣߥߞߚ㧚ߎߩߎߣ߆ࠄ㧘╲૕ߦ㔚᳇੝㋦߼ߞ߈㍑᧼߇૶ࠊࠇߡ޿ࠆ㔚ሶᯏེߦ߅޿ߡ㧘╲૕᧚ᢱ߇᡼኿₸ 0.8 ⒟ᐲߩ᧚ᢱߦ⟎߈឵߃ࠆߎߣߢ㧘᡼
ᾲ㊂ࠍᄢ߈ߊჇടߐߖࠆߎߣ߇ᦼᓙߢ߈ࠆ㧚᡼ᾲ
ᕈ㍑᧼ߪ㧘ߎߩࠃ߁ߥ⠨߃ߦၮߠ߈㧘㜞޿᡼኿₸
ࠍ㍑᧼ߦᜬߚߖࠆߎߣߢᾲ᡼኿ߦࠃࠆ᡼ᾲ㊂ࠍჇ߿ߔߎߣߦ⌕⋡ߒߚ㍑᧼ߢ޽ࠆ㧚㧚᡼ᾲ․ᕈߩ⹏ଔߣߘߩᎿᄦ
ᯏེ╲૕ߩ᡼ᾲᕈࠍะ਄ߐߖࠆߎߣߦࠃࠅ㧘ᯏེౝㇱⓨ㑆ߩ᷷ᐲࠍૐਅߐߖ⸥ᙘᇦ૕߿ᾲߦᒙ޿
ㇱຠࠍ଻⼔ߔࠆߎߣ㧘޽ࠆ޿ߪ IC ߥߤߩ⊒ᾲ૕⥄૕ߩ᷷ᐲ਄᣹ࠍᛥ߃ࠆߎߣߦࠃࠆ቟ቯേ૞߿ㇱຠ଻⼔߇ᦼᓙߐࠇࠆ㧚㐿⊒ߒߚ᡼ᾲᕈ㍑᧼ߪ㧘೨଀
ߩߥ޿㍑㊳ߢ޽ࠆߛߌߦ㧘ฦ⒳ߩ㔚ሶᯏེߩᾲኻ
╷ⷐ᳞ߦᔕߓࠆߚ߼ߦ㧘᡼ᾲᕈ㍑᧼ߦ᭽‫ߩޘ‬ᾲ⊒↢⁁ᴫ㧘ᾲḮߩ㈩⟎ߦ߅޿ߡ᡼ᾲᕈะ਄ߩലᨐࠍ
ታ⸽ߒߡ޿߆ߥߌࠇ߫ߥࠄߥ߆ߞߚ㧚ߎࠇ߹ߢ᭽‫ߥޘ‬ታ⸽⹜㛎ࠍⴕ޿᡼ᾲᕈะ਄ߩലᨐࠍ⏕⹺ߒߡ߈ߚ㧚ߎߎߢߪ㧘ߎࠇ߹ߢߦⴕߞߡ߈ߚታ⸽⹜
㛎ߩ੐଀ࠍ␜ߔ㧚߹ߕ㧘ᯏེౝㇱⓨ㑆ߩ᷷ᐲ߇㧘╲૕᧚ᢱߩ᡼ᾲ
ᕈࠍะ਄ߐߖࠆߎߣߦࠃࠅߤߩ⒟ᐲૐਅߐߖࠆߎ
ߣ߇ߢ߈ࠆ߆ࠍ⹏ଔߒߚ⚿ᨐߦߟ޿ߡ⚫੺ߔࠆ㧚
࿑ 3 ߦ⹏ଔⵝ⟎ߩ᭎⇛࿑ࠍ␜ߔ㧚ᾲḮߦߪ㧘㐳
ߐ 130 mm㧘᏷ 100 mm ߩᾲ᧼ࠍ 120 ͠ߩ৻ቯ᷷
ᐲߦߥࠆࠃ߁ߦࠦࡦ࠻ࡠ࡯࡞ߒߚ߽ߩࠍ↪޿ߚ㧚஥㕙ߩოߪᢿᾲ᧚ߦߒߡ㧘⹏ଔߔࠆ╲૕᧚ᢱࠨࡦ
ࡊ࡞ࠍ਄⬄ߣߥࠆࠃ߁ߦ⟎޿ߡ޿ࠆ㧚ᾲḮ߆ࠄ㧘㜞ߐ 100 mm ߩߣߎࠈߩ᷷ᐲࠍ㧘T1 ߣߒߡ㧘ߎߩ᷷ᐲߢ᧚ᢱߩ᡼ᾲᕈߩലᨐࠍ⹏ଔߒߚ[2]㧚

㧚᡼ᾲᕈ㍑᧼ߩ᭴ㅧߣᎿᄦὐ
࿑ 2 ߦ᡼኿₸ࠍ㜞߼ࠆಣℂࠍ߶ߤߎߒߚ᡼ᾲᕈ
㍑᧼ߩ᭴ㅧࠍ␜ߔ㧚߹ߕ㧘㍑᧼ߩ⴫㕙ߦ੝㋦߼ߞ߈ࠍ߶ߤߎߒ㧘ᔅⷐߥ⠴㘩ᕈࠍᜬߚߖߡ޿ࠆ㧚ߐࠄߦ㧘੝㋦߼ߞ߈ߣ᡼ᾲᕈ⊹⤑ߣߩធ⌕ᕈࠍᜬߚߖࠆߚ߼ߩਅ࿾ಣℂࠍ߶ߤߎߒ㧘ᦨ⴫㕙ߦ᡼ᾲᕈߩ⊹⤑ࠍಣℂߒߡ޿ࠆ㧚߹ߚ㧘᡼ᾲᕈ⊹⤑ߪ㍑᧼
ߩ⴫ⵣਔ㕙ߦಣℂߐࠇߡ޿ࠆߩ߇ᅢ߹ߒ޿㧚ߎࠇߪ㧘ᑼ(1)߅ࠃ߮(2)ߦ߅ߌࠆε2㧘ε3 ߩਔᣇࠍᄢ߈ߊ
ߔࠆߎߣߦ⋧ᒰߒ㧘ౝㇱߩᾲࠍല₸ࠃߊๆ෼ߒߡ㧘ᄖㇱߦ᡼಴ߢ߈ࠆࠃ߁ߦߥࠆ㧚᡼ᾲᕈ㍑᧼ߢߪ㧘વᾲ 2009 ᐕ 4 ᦬- 55 -J. HTSJ, Vol. 48, No. 203

ࡊࡠࠫࠚࠢ࠻ Qቶ᷷ 2㧡͠

ࠨࡦࡊ࡞
120×150mm ᷹ቯ㕙Ⓧ
100×130mm
ᢿᾲ᧚
T1

ᾲḮ
䋨120㷄䇮80W䋩

࿑ ᡼ᾲᕈ⹏ଔⵝ⟎᭎⇛࿑ߥ߅㧘T1 ߩ᷷ᐲࠍ᷹ࠆ࠮ࡦࠨ࡯ߪ㧘ᾲḮ߆ࠄߩᾲユ኿ߦ⋥ធᦑߐࠇߥ޿ࠃ߁ߦߒߚ㧚⹏ଔߒߚ╲૕᧚ᢱߪ㧘1㧕᡼ᾲᕈ㍑᧼‫࠷ࡀ࡯ࡎࡌ࡯ࠦޟ‬տ‫ޠ‬㧔᡼኿₸㧦0.86㧕
㧘2㧕ࠕ࡞ࡒ᧼㧔᡼኿₸㧦0.03㧕㧘3㧕⠴ᜰ⚉ᕈ੝㋦߼ߞ߈㍑᧼㧔᡼኿₸㧦0.12㧕ߢ޽ࠆ㧚᧼ෘߪߔߴߡ 0.6 mm ߢ޽ࠆ㧚ߥ߅㧘᧼ෘߩᓇ㗀ࠍ⺞ߴࠆߚ߼ߦ㧘᡼ᾲᕈ㍑᧼ߩߺ㧘ෘߐ߇ 1.2 mm
ߩ߽ߩ߽⹏ଔߒߚ㧚࿑ 4 ߦ㧘ᾲḮߩࡅ࡯࠲࡯ࠍࠝࡦߦߒߡ߆ࠄߩᤨ㑆ࠍᮮゲߦߣࠅ㧘❑ゲߦߪⵝ⟎ౝㇱਛᄩߩ᷷ᐲ T1
ࠍߣߞߚ⚿ᨐࠍ␜ߔ㧚᡼ᾲᕈ㍑᧼㧔ෘߐ 0.6 mm㧕
ࠍ↪޿ࠆߎߣߦࠃࠅ㧘ࠕ࡞ࡒ߿⠴ᜰ⚉ᕈ੝㋦߼ߞ
߈㍑᧼ߦᲧߴߡ㧘⚂ 5 ͠ౝㇱ᷷ᐲ߇ૐߊߥࠆߎߣ
߇␜ߐࠇߚ㧚ෘߐ 1.2 mm ߩ᡼ᾲᕈ㍑᧼ߢߪ㧘┙ߜ਄߇ࠅߩೋᦼߪ㧘ᾲኈ㊂߇ᄢ߈޿ߚ߼ࠊߕ߆ߦ
᷷ᐲ߇ૐߊߥߞߡ޿ࠆ߇㧘ᤨ㑆ߩ⚻ㆊߣߣ߽ߦ㧘ౝㇱ᷷ᐲߪ 0.6 mm ෘߩ᡼ᾲᕈ㍑᧼ߦ╬ߒߊߥߞߚ㧚᡼ᾲᕈ߇⴫㕙ߦࠃߞߡ᳿߹ࠆ․ᕈߢ޽ࠆߎߣ
ࠍ␜ߔ৻ߟߩ࠺࡯࠲ߣ߽ߥߞߡ߅ࠅ㧘╲૕೰ᕈߥߤߩઁߩᔅⷐᕈ⢻߆ࠄ᧼ෘࠍㆬ߱ߎߣ߇น⢻ߢ޽ࠆߎߣࠍ␜ߒߡ޿ࠆ㧚ᾲḮ᷷ᐲࠍ 100 ͠޽ࠆ޿ߪ
140 ͠ߣߒߡ߽㧘㔚᳇੝㋦߼ߞ߈㍑᧼ߦߊࠄߴߡ
ౝㇱ᷷ᐲ߇ਅ߇ࠆߎߣ߽␜ߐࠇߚ㧔⴫ 2㧕㧚⹜㛎ߪ
25 ͠ߦ଻ߞߚቶౝߢ߅ߎߥࠊࠇߡ߅ࠅ㧘ᾲḮ᷷ᐲ߇㜞ߊߥࠅ㧘ᯏེౝㇱ᷷ᐲߣቶ᷷ߣߩᏅ߇ᄢ߈ߊ
ߥࠆ߶ߤ㧘᡼ᾲᕈ㍑᧼ߦࠃࠆ᷷ᐲ㒠ਅߪᄢ߈ߊߥߞߡ޿ࠆ㧚

࿑ 4 ᡼ᾲᕈ⹏ଔ⚿ᨐ
⴫ 2 ౝㇱᾲḮ᷷ᐲ߇⇣ߥࠆ႐วߩ   ᡼ᾲᕈ㍑᧼ߦࠃࠆ᷷ᐲ
100 ͠

120 ͠

140 ͠

ࠨࡦࡊ࡞
ⵝ⟎ౝ
᷷ᐲ

ΔT

ⵝ⟎ౝ
᷷ᐲ

ΔT

ⵝ⟎ౝ
᷷ᐲ

ΔT

᡼ᾲᕈ㍑᧼

56.3

-3.8

65.4

-4.9

74.6

-6.3

㔚᳇੝㋦
߼ߞ߈㍑᧼

60.1

㧙

70.3

㧙

80.9

㧙

৻ᣇ㧘ㄭᐕߩ㧘㔚ሶᯏེߩ㜞޿⊒ᾲߦࠃࠅ㧘㍑
᧼ߩ᡼ᾲ᧼ߣߒߡߩᕈ⢻ⷐ᳞߽ᄙ޿㧚౮⌀ 1 ᡼ᾲᕈ㍑᧼ߩ᡼ᾲ᧼ߣߒߡߩᕈ⢻⏕⹺ߘߎߢ㧘౮⌀ 1 ߩ᭽ߥ᡼ᾲ᧼ߣߒߡߩ૶↪ࠍᗐቯߒߚታ㛎ࡕ࠺࡞ࠍ⵾૞ߒߡ੝㋦߼ߞ߈㍑᧼ߣ᡼

વᾲ 2009 ᐕ 4 ᦬- 56 -J. HTSJ, Vol. 48, No. 203

ࡊࡠࠫࠚࠢ࠻ Q
ᾲᕈ㍑᧼ߩᕈ⢻Ყセࠍⴕߞߡ޿ࠆ[3]㧚ߎߎߢߪ౉
ജᾲ㊂ࠍ 9.2 W ߢ৻ቯߣߒߡ޿ࠆ㧚ߎߩ⹏ଔߢߪ㧘⊒ᾲ૕߆ࠄߩᾲߪᾲવዉߦࠃߞߡ㍑᧼ߦ೔㆐ߒ㧘㍑᧼⴫㕙߆ࠄᾲ᡼኿෸߮ኻᵹߦࠃߞߡ᡼኿ߐࠇߡ
޿ࠆ㧚⹜㛎ߩ⚿ᨐ㧘᡼ᾲᕈ㍑᧼ߩ⴫㕙᷷ᐲߪ㧘੝㋦߼ߞ߈㍑᧼ߣᲧセߒߡ 14 ͠㒠ਅߔࠆߎߣ߇⏕⹺ߐࠇߡ߅ࠅ㧘╲૕ߦ⋥ធⵝ⌕ߐࠇߚ⊒ᾲㇱຠߩ᷷ᐲ㒠ਅ߳ߩᵴ↪߽น⢻ߢ޽ࠆߎߣ߇␜ߐࠇߚ㧚ߘࠇએᄖߩ੐଀ߦ߅޿ߡ㧘᡼ᾲᕈ㍑᧼ߩ․ᕈࠍ
ᒁ߈಴ߔᛛⴚ⊛ᬌ⸛ࠍㅴ߼ߡ߅ࠅ㧘᡼ᾲᕈ㍑᧼ߩ㧘᭽‫ߥޘ‬᡼ᾲኻ╷߳ߩㆡ↪ࠍታ⸽ߒߡ߈ߡ޿ࠆ㧚ߎߩࠃ߁ߦ㧘᡼ᾲᕈ㍑᧼ࠍ㐿⊒ߒߚᓟߢ㧘㔚ሶᯏེ╬ߩㆡ↪వ߳ߩ᡼ᾲᕈലᨐߩታ⸽ߣߘߩ᧦ઙߩ᛽
಴ߦᎿᄦߣᬌ⸛ࠍⴕߞߡ߅ࠅ㧘ߘߩᵴേߪ⃻࿷߽⛮⛯ਛߢ޽ࠆ㧚㧚߹ߣ߼
᡼ᾲᕈ㍑᧼ߪߘߩ㜞޿ᾲ᡼኿ᕈ⢻ߦࠃࠅ㧘㔚᳇࡮㔚ሶᯏེߩౝㇱ⊒↢ᾲࠍല₸ࠃߊ᡼ᢔߐߖࠆ
ߎߣ߇น⢻ߢ޽ࠆ㧚⠴㘩ᕈ㧘ടᎿᕈ㧘ዉ㔚ᕈ╬ࠍᜬߚߖߡ޿ࠆߩߢ᏷ᐢ޿㔚ሶ࡮㔚᳇ᯏེߦ೑↪ߔࠆߎߣ߇ߢ߈ࠆ㧚߹ߚ㧘ᗧඅᕈߦ߽㈩ᘦߒߡᄖⵝ
ㇱຠ߳ߩᔕ↪߽น⢻ߣߥߞߡ߅ࠅ㧘ߐࠄߦⅣႺ⽶⩄ߩૐᷫࠍ⠨ᘦߒߚࠢࡠࡓࡈ࡝࡯ኻᔕߩ㍑᧼ߣߒߡ޿ࠆ㧚ߎࠇ߹ߢߦ᡼ᾲᕈ㍑᧼߇ណ↪ߐࠇߚ଀㧘޽ࠆ޿ߪ⃻࿷ណ↪߇ᬌ⸛ߐࠇߡ޿ࠆ߽ߩߦ㧘DVD ᯏེߩ࠻࠶ࡊࠞࡃ࡯߿ਛ᧼㧘ࠞ࡯࠽ࡆߩࡋ࠶࠼࡙࠾࠶࠻
ߩ╲૕㧘ࡊ࡜࠭ࡑ࠺ࠖࠬࡊ࡟ࠗߩࡃ࠶ࠢࡄࡀ࡞㧘ᶧ᥏ߩࡃ࠶ࠢࡄࡀ࡞ߥߤ߇޽ࠆ㧚ታᯏߦ߅޿ߡ߽㧘ᓥ᧪૶ࠊࠇߡ߈ߚ੝㋦߼ߞ߈㍑᧼ߥߤߦᲧߴߡ
5 ͠೨ᓟߩ᷷ᐲ㒠ਅ߇޽ࠆߎߣ߇⹺߼ࠄࠇߡ߅ࠅ㧘ࡈࠔࡦ࡟ࠬൻ߇ታ⃻ߐࠇߚࠤ࡯߽ࠬ޽ࠆ㧚
᡼ᾲᕈ㍑᧼‫࠷ࡀ࡯ࡎࡌ࡯ࠦޟ‬տ‫ߣߎࠆ޿↪ࠍޠ‬ߦࠃࠅ㧘㔚ሶᯏེౝߩ᷷ᐲࠍਅߍࠆߎߣ߇ߢ߈ࠆ
ߚ߼㧘಄ළࡈࠔࡦࡕ࡯࠲࡯ߩኈ㊂࠳࠙ࡦ߿಄ළࡈ
ࠔࡦ࡟ࠬ㧘޽ࠆ޿ߪ᡼ᾲࡈࠖࡦߥߤߩ⋭⇛╬ߩࠦࠬ࠻࠳࠙ࡦߦ߽⽸₂ߢ߈㧘߭޿ߡߪ㜞ㅦൻ㧘㜞ᯏ⢻ൻ㧘ዊဳൻ㧘޽ࠆ޿ߪ⋭㔚ജ㧘ૐ㛍㖸╬ߩ࠾࡯࠭ߦኻᔕߢ߈ࠆߣᦼᓙߒߡ޿ࠆ㧚㧚ᔕ↪਄ߩ⻉․ᕈ
᡼ᾲᕈ㍑᧼ࠍ㔚ሶᯏེ╬ߩ╲૕ߣߒߡㆡ↪ߔࠆߦ޽ߚߞߡߪ⒳‫․ߩޘ‬ᕈ߇ᔅⷐߣߥࠆ㧚ߔߥࠊߜ㧘㜞޿᡼ᾲᕈߦട߃ߡ㧘(1)ዉ㔚ᕈࠍ᦭ߒࠕ࡯ࠬ߇ߣ
ࠇࠆߎߣ㧘(2)ടᎿᕈߦఝࠇ㧘଻⼔ࡈࠖ࡞ࡓߥߒߢ
ᦛߍ࡮⛉ࠅ࡮ᒛ಴ߒടᎿ╬߇น⢻ߢ޽ࠆߎߣ㧘(3)ⅣႺ⽶⩄ࠍ⠨ᘦߒߚ᧚ᢱ⚵ᚑߢ޽ࠆߎߣ㧘(4)ᗧඅ
ᕈࠍ᦭ߔࠆߎߣ㧘ߥߤ߇᳞߼ࠄࠇࠆ႐ว߇ᄙߊ㧘ߎߩࠃ߁ߥታ↪․ᕈࠍ᦭ߔࠆࠃ߁ߥ⴫㕙⊹⤑⸳⸘߇ߥߐࠇߡ޿ࠆߎߣ߇㊀ⷐߣߥࠆ㧚࿑ 5 ߦ㧘᡼ᾲ
ᕈ㍑᧼ߩᔕ↪․ᕈ߅ࠃ߮ടᎿ଀ࠍ␜ߔ㧚㔚ሶᯏེ╲૕ߣߒߡචಽߥᕈ⢻ࠍ᦭ߒߡ޿ࠆߣ޿߃ࠆ㧚⠴㘩ᕈ㧔5 %⊕㍕⊒↢㧕ෳ⠨ᢥ₂[1] ᣣᧄᯏ᪾ቇળ✬,વᾲᎿቇ⾗ᢱ㧔ᡷ⸓╙ 4 㧕㧘ਣༀ㧔1986㧕
[2] ᐔ㊁ᐽ㓶߶߆,⴫㕙ᛛⴚ㧘Vol.54,No.5 (2003),
p.20

㧿㧿㨀 120 hr એ਄0.01㨪0.1 mΩ
0.5㧾90°ᦛߍน⢻ዉ㔚ᕈ㧔 ㊎ᴺ㧕ടᎿᕈ㧔᧼ෘ 0.6 t㧕

[3] ᐔ㊁ᐽ㓶߶߆,R&D ␹ᚭ⵾㍑ᛛႎ㧘Vol.55,No.2(2005), p.42-p.45











࿑ 5 ᔕ↪․ᕈߣടᎿ଀

વᾲ 2009 ᐕ 4 ᦬- 57 -J. HTSJ, Vol. 48, No. 203

ࡊࡠࠫࠚࠢ࠻ Q

߈ߊ 8 ภ៞タዷ㐿ဳ࡜ࠫࠛ࡯࠲ߩ゠㆏਄ㆇ↪ߣ 1 ᐕ⋡ߩേ૞․ᕈ
The First Annual Characteristics Test of Deployable Radiator (DPR)
of Kiku-Ϊ on Geo Stationary Orbit
Ꮉፒᤐᄦ, ⍫ㇱ㜞ብ, ጟᧄ◊, ㊄᫪ᐽ㇢㧔ቝቮ⥶ⓨ⎇ⓥ㐿⊒ᯏ᭴㧕 ⍹Ꮉඳ┨, ㊁᧛ᱞ⑲㧔ਃ⪉㔚ᯏ㧕, ᢪ⮮ᐽਯ ਃ⪉㔚ᯏࠛࡦࠫ࠾ࠕ࡝ࡦࠣ
Haruo KAWASAKI, Takahiro YABE, Atsushi OKAMOTO and Yasurou KANAMORI(JAXA)
Hiroaki ISHIKAWA, Takehide NOMURA(MELCO), Yasuyuki SAITO (MEE)
e-mail: Kawasaki.haruo@jaxa.jp

ࠍߒߥߊߡߪߥࠄߥ޿.
 ࡅ࡯࠻ࡄࠗࡊࠍ૶↪ߒߚੱᎿⴡᤊߩ႐ว㧘ឃᾲߢ߈ࠆ㕙ߪ㧘ੱᎿⴡᤊᧄ૕஥㕙ߩ࡜ࠫࠛ࡯࠲㕙ߩߺߛߌߢ޽ࠆ㧚߆ߟ᦭ലߥ࡜ࠫࠛ࡯࠲㕙ߪ㧘ᭂജᄥ㓁శߩ޽ߚࠄߥ޿㕙ߢ޽ࠆ㧚ߎߩߚ߼࡜ࠫࠛ࡯
࠲㕙ࠍ⸳⟎ߢ߈ࠆ㕙Ⓧߪ㧘ੱᎿⴡᤊߩࠨࠗ࠭ߩ೙
⚂ࠍฃߌࠆ㧚߹ߚ㧘ߎߩੱᎿⴡᤊߩࠨࠗ࠭ߪ㧘࿑
2 ߦ␜ߔࡠࠤ࠶࠻ߩࡈࠚࠕ࡝ࡦࠣߩᄢ߈ߐߦ߽೙
⚂ࠍฃߌࠆߚ߼㧘࡜ࠫࠛ࡯࠲ߩ㕙Ⓧ߽೙⚂ࠍฃߌࠆ㧚㧚ߪߓ߼ߦ
ዷ㐿ဳ࡜ࠫࠛ࡯࠲㧔DPR㧕㨇1-5㨉ߪ㧘ᰴ਎ઍੱᎿⴡᤊߦ߅޿ߡ㧘ߐࠄߥࠆ㜞ኒᐲ㜞⊒ᾲൻ߇੍ᗐ
ߐࠇ㧘᦭ലߥ᡼ᾲ㕙ࠍ⏕଻ߔࠆᚻᲑߣߒߡᦼᓙߐ
ࠇߡ޿ࠆ㧚ᄙߊߩੱᎿⴡᤊߪ㧘ࠛࡀ࡞ࠡ࡯Ḯߣߒߡ㧘࿾਄߆ࠄᜬߞߡ޿ߊផㅴ⮎ߥߤࠍ㒰ߊߣ㧘ᄥ㓁ࠛࡀ࡞ࠡ࡯ߢ޽ࠅ㧘ᄥ㓁㔚ᳰߢ㔚᳇ࠛࡀ࡞ࠡ࡯ߦᄌ឵ߒ
ߡ૶↪ߒߡ޿ࠆ㧚ߎߎߢᓧࠄࠇߚ㔚᳇ࠛࡀ࡞ࠡ࡯
ࠍ㧘ㅢାᯏེ㧘᷹ⷰᯏེ㧘ੱᎿⴡᤊߩ೙ᓮ߿଻᷷
ߥߤߦ↪޿ࠆ㧚߹ߚ㧘ߎࠇࠄ㔚ሶᯏེ߇േ૞ߔࠆ
ߎߣߦࠃࠅ⊒↢ߔࠆਇⷐߥᾲߪ㧘ቝቮⓨ㑆ߦ᡼಴ߔࠆ㧚⑳ߚߜߩりߩ๟ࠅߢ૶↪ߔࠆ㔚ሶᯏེ߽⊒ᾲߔࠆ߇㧘ਇⷐߥᾲߪⓨ᳇ਛߦ᡼಴ߔࠆߎߣ߇ߢ߈ࠆ㧚ห᭽ߦੱᎿⴡᤊ߽ᄖㇱߦ᡼ᾲࠍߒߥߊߡߪߥࠄߥ
޿߇㧘๟࿐ⅣႺ߇㧘⌀ⓨߢ޽ࠆߚ߼㧘ኻᵹߦࠃࠆ
᡼ᾲߪᦼᓙߢ߈ߥ޿㧚ߎߩߚ߼ੱᎿⴡᤊ߆ࠄቝቮⓨ㑆ߦ᡼ᾲߔࠆߦߪ㧘ユ኿વᾲߢ࡜ࠫࠛ࡯࠲߆ࠄ
᡼ᾲߔࠆߒ߆ߥ޿㧚߹ߚ㧘ⴡᤊౝㇱ߽⌀ⓨߢ޽ࠆߚ߼㧘ឃᾲ߽ኻᵹ
ߥߤߦࠃࠆឃᾲ߇ⴕ߃ߥ޿㧚ߎߩߚ߼㧘ᣣᧄߩ⃻࿷ߩੱᎿⴡᤊߪ⊒ᾲᯏེ߆ࠄ࡜ࠫࠛ࡯࠲߹ߢ㧘વዉ߿ࡅ࡯࠻ࡄࠗࡊߥߤߢᾲャㅍࠍⴕߞߡ޿ࠆ.ੱ
Ꮏⴡᤊߩࡅ࡯࠻ࡄࠗࡊࠍ↪޿ߚᾲャㅍߪ㧘ᣣᧄ࿖ౝߢߪ ETS- III ߢၮ␆⊛ߥታ㛎߇ⴕࠊࠇ㧘ETS- Vߢታ↪ൻߐࠇ㧘⃻࿷ߪ߶ߣࠎߤߩⴡᤊߢ૶↪ߐࠇߡ޿ࠆ㧚⃻࿷ߪ㧘ਃᰴర⊛ߦࡅ࡯࠻ࡄࠗࡊࠍㅪ⚿ߒߚⴡᤊ߽޽ࠅㅴൻߒߟߠߌߡ޿ࠆ㧚ߎߎߢ㧘࡜ࠫࠛ࡯࠲ߩ⹤ߦᚯߔ߇㧘࡜ࠫࠛ࡯࠲
ߩ᡼ᾲవߩᷓቝቮߩ᷷ᐲߪ⚂ 4 K ߩૐ᷷ߢ޽ࠆߚ
߼㧘᷷ᐲᏅ߇ᄢ߈ߊ᡼ᾲߪኈᤃ߆ߣ⺋⸃ߐࠇ߿ߔ
޿㧚࿾⃿๟࿁ߔࠆੱᎿⴡᤊߩ႐ว㧘࿑ 1 ߦ␜ߔࠃ߁ߦᄥ㓁శߩᓇ㗀ࠍᄢ߈ߊฃߌ㧘ૐ゠㆏ߦߥࠆߣ
ߐࠄߦ࿾⃿߆ࠄߩ⿒ᄖ᡼኿ߥߤߩᓇ㗀ࠍฃߌࠆ㧚ߎࠇࠄߩᓇ㗀ࠍዊߐߊߔࠆࠃ߁ߦ࡜ࠫࠛ࡯࠲⸳⸘

વᾲ 2009 ᐕ 4 ᦬

࿑ 1 ቝቮߢߩੱᎿⴡᤊߩⅣႺߣឃᾲ(a) ៞タ⁁ᴫ(b)ࡈࠚࠕ࡝ࡦࠣౝㇱ࿑ 2 ੱᎿⴡᤊߩࡠࠤ࠶࠻៞タ⁁ᴫ- 58 -J. HTSJ, Vol. 48, No. 203

ࡊࡠࠫࠚࠢ࠻ Q⃻࿷㧘ⴡᤊߩ㐿⊒ߪ㧘㜞ኒᐲൻߩᵹࠇߢㅴࠎߢ
޿ࠆ㧚ⴡᤊߩࠨࠗ࠭ߪᄌࠊࠄߥߊߣ߽㧘ⴡᤊߩ⊒㔚㊂࡮ឃᾲ㊂߇Ⴧടߒߡ޿ࠆ㧚ߎߩࠃ߁ߥ⢛᥊߆ࠄ㧘ᧄ૕ߩߺߢߪ೙⚂ࠍฃߌࠆ࡜ࠫࠛ࡯࠲㕙Ⓧࠍ
Ⴧ߿ߔߎߣ߇ߢ߈ࠆዷ㐿ဳ࡜ࠫࠛ࡯࠲ߩ㐿⊒߇᳞߼ࠄࠇߡ߈ߚ㧚ߎߎߢዷ㐿ဳߩ࡜ࠫࠛ࡯࠲ߣߒߚ႐ว㧘ߤߩࠃ߁ߦ⊒ᾲㇱ߆ࠄ࡜ࠫࠛ࡯࠲㕙ߦᾲࠍャㅍߔࠆ߆߇㧘໧㗴ߦߥࠆ㧚ዷ㐿ߐߖࠆߚ߼ߦߪ,นേㇱ߇ሽ࿷ߔࠆߚ߼㧘಄ᇦߩㅢࠆ㈩▤߽นേߢ߈ࠆ᭴ㅧߢߥߊ
ߡߪߥࠄߥ޿㧚ߎߩߚ߼ߦߪ㧘޽ࠆ⒟ᐲߩ㐳ߐߩ޽ࠆࡈ࡟ࠠࠪࡉ࡞࠴ࡘ࡯ࡉߥߤࠍ↪޿ߡ㧘นേߢ߈ࠆࠃ߁ߦߔࠆߎߣ߇ᔅⷐߣߥࠆ㧚ㅢᏱߩࡅ࡯࠻
ࡄࠗࡊߩ႐ว㧘࡝ࠫ࠶࠻ߥ᫔⁁ኈེ߇↪޿ࠄࠇࠆߚ߼㧘ዷ㐿ဳ࡜ࠫࠛ࡯࠲ߩᾲャㅍߦ૶↪ߔࠆߎߣߪ࿎㔍ߢ޽ࠆ㧚৻ᣇ㧘࡞࡯ࡊࡅ࡯࠻ࡄࠗࡊߪ㧘ᾲャㅍ〒㔌ࠍ㐳ߊߣࠇࠆߚ߼㧘ዷ㐿࡜ࠫࠛ࡯࠲߳ߩᾲャㅍߦ૶↪
ߔࠆߦߪㆡߒߡ޿ࠆ㧚ߘߩਛߢ߽ ࿑ 3 ߦ␜ߔ࡝ࠩ
࡯ࡃౝ⬿࠲ࠗࡊߩ࡞࡯ࡊࡅ࡯࠻ࡄࠗࡊߪ㧘࡝ࠩ࡯ࡃᄖ಴࠲ࠗࡊߣᲧセߒߡ㧘⿠േߒ߿ߔ޿ߥߤߩ೑
ὐ߇޽ࠆ㧚Evaporator

Heat

Vapor Line

Evaporator ዷ㐿࡜ࠫࠛ࡯࠲ߣ࡞࡯ࡊࡅ࡯࠻ࡄࠗࡊ
DPR ߪ࡞࡯ࡊࡅ࡯࠻ࡄࠗࡊ㧔LHP㧕㧘ࡌ࡯ࠬࡄࡀ࡞㧘࡜ࠫࠛ࡯࠲ࡄࡀ࡞㧘࡜ࠫࠛ࡯࠲଻ᜬዷ㐿ᯏ᭴㧘࠮ࡦࠨ㧘ࡅ࡯࠲ߥߤ߆ࠄ᭴ᚑߐࠇߡ޿ࠆ㧚ࡌ࡯ࠬࡄࡀ࡞ߪ࿑ 5 ߦ␜ߔࠃ߁ߦⴡᤊ⷏㕙ߩⴡᤊ᭴૕ߦขࠅઃߌࠄࠇߡ޿ࠆ㧚࿑ 4 ߈ߊ 8 ภߩࡠࠤ࠶࠻៞タߣᛂߜ਄ߍ

ᄢဳዷ㐿ࠕࡦ࠹࠽

ዷ㐿ဳ࡜ࠫࠛ࡯࠲

(LDR) (෼⚊⁁ᘒ)DPR (෼⚊⁁ᘒ)

Vapor Line

BayonetTubeBayonetTube
Heat

Reservoirᄥ㓁㔚ᳰࡄ࠼࡞

Wick

Wick

(෼⚊⁁ᘒ)

Reservoir


Liquid Line

Condenser

Liquid LineaCondenser࿑ 3 ࡞࡯ࡊࡅ࡯࠻ࡄࠗࡊ
㧔࡝ࠩ࡯ࡃᄖ಴࠲ࠗࡊߣౝ⬿࠲ࠗࡊ㧕៞タ૏⟎ᄢဳዷ㐿䍏䍻䍡䍣
㩿ฃା↪䋩

㫄
㪋㪇

ዷ㐿ဳ䊤䉳䊷䉺

ᄥ㓁㔚ᳰ䍨䍽䍢䍼䍷⴫㗴ߩዷ㐿ဳ࡜ࠫࠛ࡯࠲㧔DPR㧕ߪ࿑ 4 ߦ␜ߔࠃ߁ߦ㧘2006 ᐕ 12 ᦬ߦᛂߜ਄ߍࠄࠇߚ̌߈ߊ 8
ภ(ETS- VIII)̍ߦ៞タߐࠇߚ࡝ࠩ࡯ࡃౝ⬿ဳ࡞࡯ࡊࡅ࡯࠻ࡄࠗࡊࠍ⚵ߺㄟࠎߛቝቮታ⸽↪ߩታ㛎ᯏེߢ޽ࠆ㧚ߎࠇ߹ߢߦ 2007 ᐕ߆ࠄߩቯᏱㆇ↪㐿ᆎ߆ࠄᲤᐕ㧘ᤐᄐ⑺౻ߩᐕ 4 ࿁ߩታ㛎ࠍⴕߞߡ߈ߚ㧚એਅߦ㧘ߎߩዷ㐿࡜ࠫࠛ࡯࠲ߦ↪޿ࠄࠇߡ޿ࠆ
࡞࡯ࡊࡅ࡯࠻ࡄࠗࡊߣ㕒ᱛⴡᤊ゠㆏਄ߢߩታ㛎ߦߟ޿ߡㅀߴࠆ㧚ⴡᤊ᭴૕㪋㪇㫄ᄢဳዷ㐿䍏䍻䍡䍣䋨ㅍା↪䋩᷹૏ታ㛎↪ 䍏䍻䍡䍣⛎㔚ㇱ䉝䊮䊁䊅㧔b㧕 ߈ߊ 8 ภߣ DPR
࿑ 5 ዷ㐿ဳ࡜ࠫࠛ࡯࠲ (DPR)ߣⴡᤊ៞タ૏⟎વᾲ 2009 ᐕ 4 ᦬- 59 -J. HTSJ, Vol. 48, No. 203

ࡊࡠࠫࠚࠢ࠻ Q࡜ࠫࠛ࡯࠲ࡄࡀ࡞ߪ,ࡠࠤ࠶࠻៞タᤨߦߪ㧘࡜ࠫࠛ࡯࠲߇㐽ߓࠄࠇߚ⁁ᘒߢ៞タߐࠇߡ޿ࠆ߇㧘ዷ㐿ᓟߪർ㕙ࠍᜰะߔࠆࠃ߁ߦขࠅઃߌࠄࠇߡ޿ࠆ㧚߈ߊ 8 ภߪ㕒ᱛ゠㆏ߩߚ߼ዷ㐿ᓟߪ࿑ 6 ߦ␜ߔࠃ߁ߦⴡᤊᧄ૕ߣ࡜ࠫࠛ࡯࠲૏⟎㧘ᄥ㓁ߩ૏⟎㑐ଥࠍ␜ߔߎߣ߇ߢ߈ࠆ㧚ᤐ⑺ಽᦼߦߪ㧘ᄥ㓁శ߇࡜ࠫࠛ࡯࠲ߩ⌀ᮮ߆ࠄ౉኿ߔࠆ㧚ߎߩߚ߼㧘ߎߩᤨᦼߪ㧘ᄥ㓁శ߇࡜ࠫࠛ࡯࠲ߦ౉኿ߔࠆ㊂߇ᦨ߽ૐߊߥࠆ㧚߹ߚ㧘ᄐ⥋ᦼߪ㧘ᄥ㓁శ߇ᦨ߽࡜ࠫࠛ࡯
࠲㕙ߦ౉኿ߔࠆᤨᦼߢ㧘࡜ࠫࠛ࡯࠲᷷ᐲ߇㜞ߊߥࠆ㧚৻ᣇ㧘౻⥋ߪ㧘ᄙጀᢿᾲ᧚㧔MLI㧕߇ขࠅઃߌࠄࠇߚ࡜ࠫ࡯࠲ⵣ㕙߆ࠄ㧘ᄥ㓁శ߇౉኿ߔࠆߚ
߼㧘ᄐ⥋߶ߤ᷷ᐲ߇਄᣹ߒߥ޿߇㧘ᤐ⑺ಽᦼࠃࠅ
߽࡜ࠫࠛ࡯࠲᷷ᐲߪ㜞ߊߥࠆ㧚৻ᣣߩᄌൻߪ㧘ඦ೨ਛߪⴡᤊᧄ૕㧔᭴૕㧕ߩᓇߦ㓝ࠇࠆߚ߼㧘᷷ᐲߪૐߊߥࠆ௑ะ߇޽ࠆ߇㧘৻ᣇ㧘ඦᓟߪ᷷ᐲ߇㜞ߊߥࠆ௑ะ߇޽ࠆ㧚䇭㪉㪋㪑㪇㪇

㪛㪧㪩䋨䊤䉳䉣䊷䉺䊌䊈䊦䋩㧚゠㆏਄ታ㛎⸘↹ߣേ૞ታ㛎㐳ᦼߩታ㛎ࠬࠤࠫࡘ࡯࡞ߪ㧘ᄢ߈ߊಽߌߡ 3 ߟߩࡈࠚࠗ࠭߆ࠄᚑߞߡ޿ࠆ㧚ᛂߜ਄ߍ߆ࠄቯᏱㆇ
↪߹ߢߩ࠴ࠚ࠶ࠢࠕ࠙࠻ࡈࠚࠗ࠭, ߘߩᓟߩ 2007
ᐕ 4 ᦬ߩቯᏱㆇ↪㐿ᆎ߆ࠄ 1 ᐕ⋡ߩേ૞ታ㛎ࡈࠚࠗ࠭, ߘߒߡቯᏱㆇ↪ 2 ᐕ⋡߆ࠄߩ㐳ᦼㆇ↪ታ㛎ࡈࠚࠗ࠭ߢ޽ࠆ㧚ߎߎߢߪኼ๮⹏ଔߦ㑐ߔࠆታ㛎ߥߤࠍⴕ߁㧚
ᧄⓂߢߪേ૞ታ㛎ࡈࠚࠗ࠭ߦߟ޿ߡㅀߴࠆ㧚േ૞ታ㛎ߢߪᄖㇱᾲ౉ജߩቄ▵ᄌേࠍ⠨ᘦߒ㧘ᤐᄐ⑺౻ߩ 4 ࿁ߣߘߩ⋥ᓟߩ 1 ࡩ᦬㑆േ૞ߐߖࠆታ㛎ࠍⴕߞߚ㧚ᤐ⑺ಽᦼ㧘ᄐ⥋౻⥋ᦼߦⴕࠊࠇࠆታ㛎ߪ㧘એਅߦ␜ߔ․ᕈታ㛎ߣ৻ࡩ᦬ㅪ⛯ታ㛎߆ࠄᚑࠅ┙ߞߡ޿ࠆ㧚࿾⃿䇭㪈㪏㪑㪇㪇

䇭㪍㪑㪇㪇㪜㪫㪪㪄㸎᭴૕

䇭㪈㪉㪑㪇㪇ᄥ㓁శ࿑ 6 ゠㆏਄ߢߩ࡜ࠫࠛ࡯࠲૏⟎㑐ଥᰴߦ㧘DPR ߦ઀ㄟ߹ࠇߡ޿ࠆ࡞࡯ࡊࡅ࡯࠻ࡄࠗ
ࡊߦߟ޿ߡ◲නߦ⺑᣿ࠍߔࠆ㧚
LHP ߪ㧘࿑ 3 ߦ␜ߔࠃ߁ߦ⫳⊒ེ㧘⫳᳇▤㧘ಝ❗ེ㧘ᶧ▤߆ࠄ᭴ᚑߐࠇߡ޿ࠆ㧚⫳⊒ེߪࡌ࡯ࠬ
ࡄࡀ࡞ߦขࠅઃߌࠄࠇߡ߅ࠅ㧘ታ㛎↪ࡅ࡯࠲
(0W-400W)ߢടᾲߢ߈ࠆࠃ߁ߦߒߡ޽ࠆ㧚߹ߚ㧘⫳⊒ེߪ㧘ᄙጀᢿᾲ᧚ߥߤߢࡌ࡯ࠬࡄࡀ࡞߅ࠃ߮
ⴡᤊ᭴૕߆ࠄᢿᾲߒߡ޿ࠆ㧚ಝ❗ེߪ㧘㐳ߐ⚂ 1.8m 㧘᏷⚂ 0.5m ߩࡂ࠾ࠞࡓ
ࡄࡀ࡞ߦၒ߼ㄟ߼ࠄࠇߡ޿ࠆ㧚ߎߩࡂ࠾ࠞࡓࡄࡀ
࡞ߪ㧘ࠕ࡞ࡒ࠾࠙ࡓ⵾ߩࡂ࠾ࠞࡓࠦࠕߦ㧘⴫⊹ߦ

વᾲ 2009 ᐕ 4 ᦬㜞ᾲવዉࡇ࠶࠴♽὇⚛❫⛽ᒝൻࡊ࡜ࠬ࠴࠶ࠢ
㧔CFRP㧕[6]߇૶↪ߐࠇߡ޿ࠆ㧚ⴡᤊߦ↪޿ࠄࠇࠆࡅ࡯࠻ࡄࠗࡊၒ߼ㄟߺဳߩ࡜ࠫࠛ࡯࠲ࡄࡀ࡞ߩ
ᄙߊߪ㧘ࠕ࡞ࡒ࠾࠙ࡓ⴫⊹ࠍ↪޿ࠆ߇㧘シ㊂㧘⭯ဳൻߩߚ߼ߦ DPR ߩ࡜ࠫࠛ࡯࠲ࡄࡀ࡞⴫⊹ߦ
CFRP ࠍ૶↪ߒߡ޿ࠆ㧚࡜ࠫࠛ࡯࠲⴫஥ߩ CFRP ᄖ⴫㕙ߦߪ㧘ᄥ㓁శ߆ࠄߩ౉኿శߩᓇ㗀ࠍᛥ߃㧘᡼ᾲ⢻ജࠍ⛽ᜬߔࠆߚ߼ߦ OSR㧔Optical Solar Reflector㧕߇⾍ࠅઃߌࠄࠇ
ߡ޿ࠆ.
⫳⊒ེߣಝ❗ེߪ㧘ߘࠇߙࠇ 3 m ߩ▤ߢ⚿߫ࠇߡ߅ࠅ㧘1 ߟߩ࡞࡯ࡊࠍᒻᚑߒߡ޿ࠆ㧚ߥ߅▤ߩ৻ㇱߪ㧘࡜ࠫࠛ࡯࠲ࡄࡀ࡞ࠍዷ㐿ߐߖࠆߚ߼ߦ㧘ࡈ࡟ࠠࠪࡉ࡞᭴ㅧߣߥߞߡ޿ࠆ㧚⫳⊒ེߪ㧘ᣢߦႎ๔[2]ߐࠇߡ޿ࠆࠃ߁ߦ㧘᳇ሹ
ᓘ 1 μm ߩ SUS ⵾ሹ⾰᧚ߢߢ߈ߚ৻૕ဳߩ࠙ࠗ࠶
ࠢ߇⚵ߺㄟ߹ࠇߡ޿ࠆ㧚࡝ࠩ࡯ࡃߪ㧘࠙ࠗ࠶ࠢߩ
ਛᔃㇱߩⓨ㑆ࠍභ߼ߡ޿ࠆ㧚૶↪಄ᇦߪ㧘ቝቮ↪ߩࡅ࡯࠻ࡄࠗࡊߩ಄ᇦߣߒ
ߡ߽ᄙߊ૶↪ߐࠇߡ޿ࠆࠕࡦࡕ࠾ࠕࠍ↪޿ߚ㧚(1) ․ᕈታ㛎Ԙ࡜ࠫࠛ࡯࠲ࡄࡀ࡞ឃᾲ․ᕈታ㛎㧦࡜ࠫࠛ࡯࠲
ࡄࡀ࡞ታ㛎ࡅ࡯࠲ߦ৻ቯߩᾲ౉ജࠍⴕ޿㧘࡜ࠫࠛ࡯࠲ࡄࡀ࡞ߩ᷷ᐲᄌൻ߅ࠃ᷷߮ᐲಽᏓ
ࠍ⸘᷹ߔࠆታ㛎㧚ԙ⽶⩄ᄌേታ㛎㧦 ⫳⊒ེߩᾲ⽶⩄ࠍᄌൻߐߖ
ߡ㧘ᾲャㅍ㊂ᄌൻߥߤߩ․ᕈ⏕⹺ߔࠆታ㛎㧚- 60 -J. HTSJ, Vol. 48, No. 203

ࡊࡠࠫࠚࠢ࠻ Qེ߅ࠃ߮ಝ❗ེ᷷ᐲߪ 50͠⒟ᐲߣ቟ቯߒߡ޿ࠆ㧚
11 ᤨࠍ⚻ㆊߔࠆߣ 18 ᤨ߆ࠄ 19 ᤨߩ㑆ࠍࡇ࡯ࠢߦ
᷷ᐲ߇਄᣹ߔࠆ㧚ߎࠇߪ㧘DPR ߇ขࠅઃߌࠄࠇߡ
޿ࠆੱᎿⴡᤊ߆ࠄߩ෻኿శߥߤߩᓇ㗀ߣ⠨߃ࠆߎߣ߇ߢ߈ࠆ㧚ߎߎߢᾲ⽶⩄߇ή޿⁁ᘒߢ߽㧘ಝ❗
ེߩ᷷ᐲᄌൻࠍ⷗ࠆߣ㧘18 ᤨ߆ࠄ 19 ᤨߩ㑆ࠍࡇ࡯ࠢߦ᷷ᐲ߇㜞ߊߥߞߡ޿ࠆߎߣ߇ಽ߆ࠆ㧚ߎߩߎߣ߆ࠄ߽ඦᓟߩ⸘᷹⚿ᨐߪ෻኿శߩᓇ㗀ࠍฃߌߡ޿ࠆߎߣࠍ␜ߒߡ޿ࠆ㧚Ԛᦨᄢᾲャㅍታ㛎㧦ᦨᄢᾲャㅍ㊂㧔300W㧕ߢߩࠝࡦ㧛ࠝࡈㅪ⛯ታ㛎㧚ԛ⿠േ․ᕈታ㛎㧦⫳⊒ེߦ 50W એ਄ߩᚲቯߩ
ᾲࠍട߃㧘⿠േ․ᕈࠍ⸘᷹ߔࠆታ㛎㧚Ԝ⫳⊒ེㇱಽടᾲታ㛎㧦⫳⊒ེߩࡅ࡯࠲ടᾲ૏
⟎ࠍᄌᦝߒ㧘േ૞․ᕈࠍ⸘᷹ߔࠆታ㛎㧚(2) 1 ࡩ᦬ㅪ⛯ታ㛎㧦1 ࡩ᦬㑆ㅪ⛯ߒߡ⫳⊒ེߦ
300W ߩ৻ቯᾲ౉ജࠍⴕ޿㧘ᕈ⢻ᄌൻࠍⷰኤߔࠆ
ታ㛎㧚㧚േ૞․ᕈታ㛎⚿ᨐേ૞ታ㛎ߩઍ⴫࠺࡯࠲ߣߒߡᤐಽ㧘ᄐ⥋㧘⑺ಽ
ᦼߦ߅ߌࠆ 300W ⿠േ․ᕈߩ⚿ᨐࠍ࿑ 8 ߦ␜ߔ㧚⫳⊒ེߩᾲ⽶⩄߇ή޿ೋᦼ⁁ᘒ(0W)ߢߪ㧘⫳⊒ེߣಝ❗ེߩ᷷ᐲߪᄢ߈ߊ㔌ࠇߡ޿ࠆ߇㧘ᾲ⽶⩄߇
ടࠊࠆߣౝㇱߩ಄ᇦ߇ᓴⅣߒ㧘⫳⊒ེߣಝ❗ེ᷷ᐲ߇߶߷╬ߒߊߥࠆ㧚ᾲ⽶⩄ࠍട߃ߡ 4 ᤨ㑆⒟ᐲߢᐔⴧ⁁ᘒߦ㆐ߒߡ޿ࠆ㧚߹ߚ࿑ 8 ߢ␜ߐࠇߚߣ
߅ࠅ㧘ᄖㇱᾲⅣႺ߇หߓߢ޽ࠆᤐಽ㧘⑺ಽᦼߩ⿠
േ․ᕈߩ⚿ᨐߪ㧘ห৻ߢ޽ࠅ㧘ᐔⴧ᷷ᐲ߽╬ߒߊ㧘ඨᐕ㑆ߢᕈ⢻ߩᄌൻߪ⷗ࠄࠇߡ޿ߥ޿㧚ᄐ⥋ᦼߩ⚿ᨐߪ㧘࡜ࠫࠛ࡯࠲㕙ߦᄥ㓁శ߇౉኿ߔࠆߚ߼㧘⿠േ೨ᓟߢ⫳⊒ེ߅ࠃ߮࡜ࠫࠛ࡯࠲ߩ᷷ᐲ߇㜞ߊߥߞߡ޿ࠆߎߣ߇ࠊ߆ࠆ.


࿑ 9 ⑺ಽᦼߩ  ᣣߩ᷷ᐲᄌൻ㧔0 W㧕ߣ
300W ᛩ౉ᤨߩ᷷ᐲᄌൻ
߹ߚ㧘ᾲ⽶⩄ߩ᦭ήߦ߆߆ࠊࠄߕ㧘0 ᤨ೨ᓟߢ㧘ಝ❗ེ᷷ᐲ߇ਅ߇ߞߡ޿ࠆߩߪ㧘ੱᎿⴡᤊ߇࿾⃿ߩᓇ㧔㘩㧕ߣߥࠆߚ߼ߢ޽ࠆ㧚ߎࠇࠄ࿑ 9 ߦ␜ߔ⚿ᨐࠃࠅᾲ⽶⩄߇޽ࠆ႐วߪ㧘ᄖㇱⅣႺ᷷ᐲ߇ᄌ
ൻߔࠆߣ㧘⫳⊒ེ᷷ᐲ߽ᄌൻߔࠆ߇㧘ᾲ⽶⩄߇ή޿႐วߪ㧘⫳⊒ེߪᄖㇱⅣႺ᷷ᐲߦᏀฝߐࠇߦߊ
޿ߎߣࠍ␜ߒߡ޿ࠆ㧚ㆇ↪ 1 ᐕ⋡ߩ⑺ಽᦼ৻ࡩ᦬ㅪ⛯ታ㛎ਛߩ 744 ᤨ㑆ߩ⫳⊒ེ߅ࠃ߮ಝ❗ེߩ᷷ᐲᄌൻࠍ࿑ 10 ߦ␜ߒߚ㧚᷷ᐲ߇ 24 ᤨ㑆๟ᦼߢᝄേߒߡ޿ࠆߩߪ㧘೨
ㅀߩ࿑ 9 ߩ⺑᣿ߢㅀߴߚ 1 ᣣߩᄖㇱⅣႺߩᄌൻߦ
ࠃߞߡᒁ߈⿠ߎߐࠇࠆ߽ߩߢ޽ࠆ㧚߹ߚᤨ㑆ߩ⚻ㆊߦࠃߞߡ᷷ᐲߩᝄࠇ᏷߇ᄌൻߔࠆ߇㧘ߎࠇߪ㘩ᦼ㑆ߩᄌൻߦࠃࠆ߽ߩߢ޽ࠆ㧚ߎߩࠃ߁ߥ᷷ᐲᄌ
ൻߪ޽ࠆ߇㧘․೎ߥᠲ૞ࠍട߃ࠆߎߣߥߊ DPR ߪ
300 W ߩឃᾲ߇น⢻ߢ޽ࠆߎߣࠍ⏕⹺ߢ߈ߚ㧚߹ߚᄐ⥋ᦼ㧘౻⥋ᦼ߽᷷ᐲ࡟ࡌ࡞ߪ⇣ߥࠆ߇㧘߶߷ห᭽ߥ቟ቯߒߚേ߈ߢ޽ࠆߎߣ߇ࠊ߆ߞߚ.


࿑ 8 ᤐಽ㧘ᄐ⥋㧘⑺ಽᦼߩ 300W ᛩ౉ᤨߩ⿠േ․ᕈᾲ⽶⩄ 300W ࠍട߃ߚ⑺ಽᦼߩ৻ࡩ᦬ㅪ⛯ታ㛎ߩਛߢ㧘޽ࠆ 1 ᣣߩ⫳⊒ེ߅ࠃ߮ಝ❗ེ಴ญㇱߩ᷷ᐲᄌൻࠍ࿑ 9 ߦ␜ߒߚ㧚߹ߚ࿑ 9 ߦߪหᤨߦ㧘ᾲ⽶⩄߇ή޿⁁ᘒ㧔0W㧕ߢߩ᷷ᐲᄌൻ߽␜ߒߚ㧚ᾲ⽶⩄ 300W ߩ႐ว㧘ᤨೞ 0 ᤨ߆ࠄ 11 ᤨ߹ߢ⫳⊒વᾲ 2009 ᐕ 4 ᦬- 61 -J. HTSJ, Vol. 48, No. 203

ࡊࡠࠫࠚࠢ࠻ Qࠍⷰኤߔࠆߚ߼ߦ゠㆏਄࠺࡯࠲ࠍขᓧߒ㧘⹏
ଔࠍⴕ߁㧚
ෳ⠨ᢥ₂
[1] Ꮉፒᤐᄦ㧘㊁↰ᶈᐘ㧘⍫ㇱ㜞ብ㧘⍹Ꮉඳ┨㧘
㊁᧛ᱞ⑲㧘ᢪ⮮ᐽਯ㧘
̌ETS-Ϊ៞タዷ㐿ဳ࡜ࠫࠛ࡯࠲ߩ゠㆏਄ᾲ․ᕈ̍
㧘╙ 51 ࿁ቝቮ⑼ቇᛛⴚㅪ
ว⻠Ṷળ㧘2JC13 (2007)㧚
[2] ⍹Ꮉඳ┨㧘ᄢਠື㇢㧘㊁᧛ᱞ⑲㧘㊁↰ᶈᐘ㧘Ꮉፒᤐᄦ㧘⍫ㇱ㜞ብ㧘㊄᫪ᐽ㇢㧘̌߈ߊ 8 ภዷ㐿ဳ࡜ࠫࠛ࡯࠲ߩ゠㆏਄ᾲ․ᕈ̍
㧘╙ 45 ࿁ᣣᧄવᾲࠪࡦࡐࠫ࠙ࡓ⻠Ṷ⺰ᢥ㓸㧘(2008-5)㧚
[3] ᄢਠື㇢㧘⍫የᓆ㧘Jason Xu㧘Ⴧᧄඳశ㧘Ꮉ〝ᱜ⵨㧘ቝቮ↪ࡈ࡟ࠠࠪࡉ࡞࡞࡯ࡊᒻࡅ࡯࠻ࡄࠗ
ࡊߩ⎇ⓥ㧘ᣣᧄᯏ᪾ቇળ⺰ᢥ㓸 B ✬㧘66 (2000)㧘
1488-1493㧚
[4] ㊁↰ᶈᐘ㧘̌ETS-Ϊዷ㐿࡜ࠫࠛ࡯࠲ߩ㐿⊒᭎ⷐ̍㧘ᣣᧄ⥶ⓨቝቮቇળ⹹㧘Vol55 (No636)㧘(2007)㧘
16-19㧚
[5] ㊁↰ᶈᐘ㧘Ꮉፒᤐᄦ㧘⍫ㇱ㜞ብ㧘ጟᧄ◊߶߆㧘̌ᛛⴚ⹜㛎ⴡᤊΪဳ៞タዷ㐿࡜ࠫࠛ࡯࠲ߩ㐿⊒㧔㐿⊒⁁ᴫ㧕̍㧘╙ 49 ࿁ቝቮ⑼ቇᛛⴚㅪว⻠Ṷળ㧘
3C01 (2005)㧘1176-1181㧚
[6] Tsuyoshi.Ozaki㧘Akira Yao,Yoshiyuki Ohkawa㧘
Hiromi Seko 㧘 Akio Tsujihata 㧘 Hiroyuki Noda 㧘̌ Graphite Faceskin Deployable Radiator Panels
For ETS-VIII Structures̍㧘51th Int. Astronautical㧚࿑ 10 ⑺ಽᦼ৻ࡩ᦬ㅪ⛯ታ㛎ߦ߅ߌࠆ᷷ᐲᄌൻ
㧔Eva1:⫳⊒ེ᷷ᐲ㧘Con3: ⫳⊒ེ಴ญ᷷ᐲ㧕㧚߹ߣ߼ߣ੹ᓟ
ᛂߜ਄ߍ߆ࠄ⚂ 2 ᐕ㑆ߩታ㛎ࠍⴕ޿㧘એਅߩ⚿ᨐࠍᓧߚ㧚Ԙ ࡝ࠩ࡯ࡃౝ⬿ဳ࡞࡯ࡊࡅ࡯࠻ࡄࠗࡊߩ゠㆏਄
400 ᣣએ਄ߩ቟ቯㆇォࠍ⏕⹺ߢ߈ߚ㧚࡞࡯ࡊࡅ࡯࠻ࡄࠗࡊࠍ฽߻ੑ⋧ᵹ૕࡞࡯ࡊߪ㧘ߎࠇ߹ߢᧄ DPR ࠍ฽߼゠㆏਄ታ㛎ߪ࿖ౝߢߪᢙዋ
ߥ޿㧚ߎߩਛߢ㧘゠㆏਄ߩታ⸽ᦼ㑆߇㐳ߊ㧘ታ↪ൻߦㄭߠߊߎߣ߇ߢ߈ߚ㧚ԙ ታ㛎 1 ᐕ⋡ߦቯᩰ⽶⩄ 300 W ߢߩ৻ࡩ᦬ㅪ⛯ታ㛎ࠍ 3 ࿁ⴕ޿㧘DPR ߢណ↪ߒߡ޿ࠆౝ⬿ဳ࡞࡯ࡊࡅ࡯࠻ࡄࠗࡊߩ㐳ᤨ㑆ߩേ૞቟ቯᕈࠍ
ታ⸽ߔࠆߎߣ߇ߢ߈ߚ㧚Ԛ ᛂߜ਄ߍ߆ࠄ⚂ 2 ᐕ㑆ߢߩ DPR ߩᕈ⢻ഠൻߪ߶ߣࠎߤ⷗ࠄࠇߥ߆ߞߚ㧚੹ᓟ߽㧘ᕈ⢻ᄌൻ

વᾲ 2009 ᐕ 4 ᦬- 62 -J. HTSJ, Vol. 48, No. 203

․೎ነⓂ

⠴ᾲశࡈࠔࠗࡃ

Heat-resistant Glass Optical Fiber᧛਄ ᵏ㧔ାᎺᄢቇ㧕
Yasushi MURAKAMI (Shinshu University)e-mail: yasmura@shinshu-u.ac.jpߞߚߩߢߔ㧚ෘ⤑ߦߔࠆߚ߼ߦߪ㧘⭯⤑᧚ᢱࠍߟߥ߉᧚ߣߒߡ☸ሶߣ⚵ߺวࠊߖࠆߎߣ߇᦭ലߢߔ㧚☸ሶߦߪ࠮࡜ࡒ࠶ࠢࠬࠍ↪޿ࠆߩ߇৻⥸⊛ߢߔ㧚࠮࡜ࡒ࠶ࠢࠬߪ⛘✼ᕈࠍ᦭ߔࠆߣߣ߽ߦ㧘⿒ᄖ✢߿㆙⿒ᄖ✢ࠍ᡼኿ߔࠆߎߣߢ㆙㓒࿾ߦ᡼ᾲߢ߈ࠆ
ߣ޿߁೑ὐࠍ߽ߞߡ޿߹ߔ㧚ࠕ࡞ࡒ࠽ߩࠃ߁ߦᾲ
વዉᕈߩࠃ޿߽ߩ߽޽ࠅ߹ߔ㧚ෘ⤑ߦߔࠆߚ߼ߦ
࠮࡜ࡒ࠶ࠢ☸ሶࠍട߃ࠆߎߣߢ㧘᡼ᾲߣ޿߁ⷐ⚛
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ᢥㇱ⑼ቇ⋭ߢߪ㧘⍮⊛ࠢ࡜ࠬ࠲࡯ࠍഃᚑߒ㧘࿾ၞ⚻ᷣߩᵴᕈൻࠍ࿑ࠆߎߣࠍ⋡⊛ߣߒߡ㧘ᐔᚑ 14ᐕᐲ߆ࠄ‫ޟ‬⍮⊛ࠢ࡜ࠬ࠲࡯ഃᚑ੐ᬺ‫ࠍޠ‬ታᣉߒߡ޿߹ߔ㧚㐳㊁࡮਄↰࿾ၞߢ߽㧘㐳㊁⋵࠹ࠢࡁ⽷࿅ߩࠗ࠾ࠪࠕ࠹ࠖࡉߩਅߢ㧘ାᎺᄢቇ߇᦭ߔࠆ⁛ഃ⊛ߥᛛⴚࠪ࡯࠭ߣ࿾ၞౝᄖߩડᬺߩታ↪ൻ࠾࡯࠭ࠍⲢวߒߡᛛⴚ㕟ᣂࠍ⿠ߎߒ㧘ᣂ↥ᬺࠍഃ಴ߒࠃ
߁ߣߔࠆ⹜ߺ߇ᆎ߹ࠅ߹ߒߚ㧚╙Σᦼ 5 ᐕ㑆ߩᓟ㧘
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ਛߢ㐿⊒ߐࠇ߹ߒߚ㧚⍮⊛ࠢ࡜ࠬ࠲࡯ഃᚑ੐ᬺߦ
ෳ↹ߒߡ޿ߚ࿾ၞߩડᬺߣ⹤ࠍ੤ࠊߔਛߢ㧘శࡈࠔࠗࡃࠍขࠅᛒߞߡ޿ࠆߎߣࠍ⍮ࠅᕁ޿ߟ޿ߚ߽
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ᄙሹ⤑ߪ㧘᦭ᯏ EL ߩ๟ㄝㇱ᧚ߢ޽ࠆૐዮ᛬⤑ߣߒߡ㐿⊒ߐࠇߚ߽ߩߢ޽ࠅ㧘⠴ᾲߦ᦭ᦸߥ᧚ᢱߛ
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વᾲ 2009 ᐕ 4 ᦬⠴ᾲశࡈࠔࠗࡃ శࡈࠔࠗࡃⵍⷒ᧚
శࡈࠔࠗࡃߪࡉࡠ࡯࠼ࡃࡦ࠼ࠨ࡯ࡆࠬߩឭଏߦ
ㆡߒߚવㅍᇦ૕ߣߒߡ↪޿ࠄࠇߡ޿߹ߔ㧚శࡈࠔࠗࡃߪ㧘વㅍ៊ᄬࠍਅߍࠆᔅⷐ߇޽ࠆߚ߼㧘ᦨᄢߩㅘ᣿ᐲ߇ᓧࠄࠇࠆࠃ߁ߦ㜞⚐ᐲߩ⍹⧷ࠟ࡜ࠬ߇
↪޿ࠄࠇߡ޿߹ߔ㧚ઁߩ‛૕╬ߣធ⸅ߒߡ்߇ߟ
޿ߚ႐วߦߪ㧘శࡈࠔࠗࡃߩᯏ᪾⊛ߥജߦኻߔࠆ
⠴ᕈ߇⪺ߒߊഠൻߒ߹ߔ㧚ߎߩߚ߼㧘ㅢᏱߪశࡈ
ࠔࠗࡃߩ๟࿐ߦㆡᒰߥෘߐߩⵍⷒࠍᣉߒ㧘శࡈࠔࠗࡃࠍ଻⼔ߒߡ޿߹ߔ㧚               ⵍⷒ᧚            ࠦࠕ           ࠢ࡜࠶࠼࿑ 1 శࡈࠔࠗࡃߩ᭴ㅧ

- 63 -J. HTSJ, Vol. 48, No. 203

․೎ነⓂ
ലᨐ߇޽ࠅ߹ߒߚ㧚ࠪ࡝ࠞࡒࠢࡠᄙሹ⤑ߪ᧚⾰߇శࡈࠔࠗࡃߣหߓߢ޽ࠆߩߢ㧘᧚⾰⊛ߥ⠴ᾲᕈߦߪ໧㗴߇޽ࠅ߹ߖࠎ㧚࡝ࠨࠗࠢ࡞ᕈ߇㜞޿ߣ޿߁ࡔ࡝࠶࠻߽޽ࠅ߹ߔ㧚໧㗴ߪ⚦ሹߩ቟ቯᕈߢߔ㧚ᐘ޿ߦ߽⚦ሹߪ⚦ሹᓘ߇ዊߐ޿߶ߤ቟ቯߢ޽ࠆߎ
ߣ߇ࠊ߆ࠅ߹ߒߚ㧚ࠪ࡝ࠞࡒࠢࡠᄙሹ⤑ࠍⵍⷒ᧚ߦ↪޿ࠆߎߣߦࠃߞߡ㧘శࡈࠔࠗࡃߩ⠴ᾲᕈࠍᦨᄢ㒢ߦᒁ߈಴ߖࠆ⠴ᾲశࡈࠔࠗࡃ߇ᓧࠄࠇ߹ߒߚ
[4]㧚

ⵍⷒ᧚ߦߪࡐ࡝ࡑ࡯߇↪޿ࠄࠇߡ߅ࠅ㧘Ყセ⊛⠴ᾲᕈ߇޽ࠆࡐ࡝ࠗࡒ࠼᮸⢽ࠍ↪޿ߚ߽ߩߢ߽
300͠߹ߢߒ߆⠴߃ࠄࠇ߹ߖࠎ㧚ߐࠄߦ⠴ᾲᕈ߇㜞޿߽ߩߦߪ㧘㊄ࠍⵍⷒߒߚ߽ߩ߇޽ࠅ㧘600͠߹ߢߪ⠴߃ࠄࠇ߹ߔ㧚శࡈࠔࠗࡃߘߩ߽ߩߪ 1000͠߹ߢߩ⠴ᾲᕈࠍ᦭ߒߡ޿߹ߔ㧚శ߇ㅢࠆࠦࠕߦߪ㧘߹ࠊࠅࠃࠅ߽
ዮ᛬₸ࠍ㜞߼ࠆᔅⷐ߇޽ࠅ㧘ࠥ࡞ࡑ࠾࠙ࡓࠍᷝട
ߒߡ޿߹ߔ㧚ࠥ࡞ࡑ࠾࠙ࡓߩ᜛ᢔࠍ⠨߃ߡ߽㧘
800͠߹ߢߪ⠴߃ࠄࠇ߹ߔ㧚ߒߚ߇ߞߡ㧘ⵍⷒ᧚ߩ⠴ᾲᕈ߇㜞߹ࠇ߫㧘శࡈࠔࠗࡃߩ⠴ᾲᕈ߇㜞߹ࠆߎߣߦߥࠅ߹ߔ㧚శࡈࠔࠗࡃߪ㧘᷷ᐲ㧘࿶ജ㧘ᱡ╬ࠍశߢᬌ಴ߔ
ࠆ࠮ࡦࠨߦ೑↪ߐࠇ߹ߔ㧚㜞᷷Ἱ㧘ᾲಣℂⵝ⟎㧘⍹ᴤࡊ࡜ࡦ࠻ᣉ⸳㧘࠻ࡦࡀ࡞Ἣἴ㒐ᱛ㧘ේሶἹ㑐ଥ㧘⊒㔚ᚲ㧘ࠫࠚ࠶࠻ࠛࡦࠫࡦ╬㧘㜞᷷ⅣႺਅߦ߅ߌࠆ↪ㅜߪᢙᄙߊ⠨߃ࠄࠇ㧘⠴ᾲశࡈࠔࠗࡃ߇
᦭ലߦᯏ⢻ߔࠆߣᦼᓙߢ߈߹ߔ㧚࿑ 2 ࡒࠢࡠ⚦ሹߦࠃߞߡ੉ⵚߩㅴⴕࠍᛥ೙ ࠪ࡝ࠞࡒࠢࡠᄙሹ⤑ᚒ‫ߪޘ‬㧘࠱࡞㧙ࠥ࡞ᴺߦࠃࠆࠪ࡝ࠞࡒࠢࡠᄙሹ
૕ߩวᚑߦߟ޿ߡ⎇ⓥߒߡ޿߹ߒߚ[1]㧚 ࡒࠢࡠᄙሹ૕ߣߪ㧘⚦ሹᓘ߇ 2 nm એਅߩࡒࠢࡠሹߩߺ
߆ࠄߥࠆᄙሹ૕ࠍᗧ๧ߒ߹ߔ㧚Si(OCH3)4 ࠍේᢱߦ↪޿ߚ႐ว㧘H2O ߩ㊂߇ᭂዊ㊂ߩ႐วߦࠪ࡝ࠞࡒ
ࠢࡠᄙሹ૕߇ߢ߈ࠆߎߣࠍ⷗಴ߒߚߩߢߔ㧚ߣߎ
ࠈ߇ H2O ߩ㊂߇ᭂዊ㊂ߢߪ Si(OCH3)4 ߇ߔߴߡ෻
ᔕߔࠆߦᔅⷐߥ H2O ߩ㊂ߦዯ߆ߕ㧘ᓧࠄࠇࠆࠪ࡝
ࠞߩ෼₸߇ૐ޿ߣ޿߁⥌๮⊛ߥᰳὐ߇޽ࠅ߹ߒߚ㧚ߐࠄߦᄙሹ૕ߪ☸ሶߣߒߡᓧࠄࠇߚߚ߼⤑ൻߢ߈߹ߖࠎߢߒߚ㧚ߎߩ໧㗴ࠍ⸃᳿ߒߚߩߪ㧘ࡅ࠼ࡠࠠࠪࠕ࠮࠻ࡦ
ߣ޿߁⸅ᇦߢߔ㧚ࡅ࠼ࡠࠠࠪࠕ࠮࠻ࡦࠍ⸅ᇦߣߔ
ࠆߎߣߢ㧘H2O ߩ㊂߇චಽߦᄙߊߡ߽ࠪ࡝ࠞࡒࠢ
ࡠᄙሹ૕߇ᓧࠄࠇࠆࠃ߁ߦߥࠅ߹ߒߚ㧚ߐࠄߦ㧘࠱࡞ߣߒߡᓧࠄࠇࠆࠃ߁ߦߥࠅ⤑ൻ߽น⢻ߦߥࠅ߹ߒߚ[2]㧚ߎߩ⤑ߪ㧘⿥ⷫ᳓ᕈࠍ␜ߔߎߣࠍ⷗಴
ߒߡ޿߹ߔ[3]ࠪ࡝ࠞࡒࠢࡠᄙሹ⤑߇ߢ߈ࠆࠃ߁ߦߥߞߚߣ߈
ߦ㧘⠴ᾲశࡈࠔࠗࡃߩ⺖㗴ߦ಴ળߞߚߩߢߔ㧚2
nm એਅߩࡒࠢࡠ⚦ሹࠍήᢙߦౝ൮ߒߚࠪ࡝ࠞࡒ
ࠢࡠᄙሹ⤑߇ഀࠇࠍ㒐ᱛߢ߈ࠆߣ޿߁઒⺑ߩ߽ߣߦ㧘శࡈࠔࠗࡃ⴫㕙߳ߩࠦ࡯࠹ࠖࡦࠣࠍ⹜ߺ߹ߒ
ߚ㧚⁓޿ㅢࠅࠪ࡝ࠞࡒࠢࡠᄙሹ⤑ߦߪഀࠇ㒐ᱛߩ

વᾲ 2009 ᐕ 4 ᦬- 64 -

 ⠴ᾲశࡈࠔࠗࡃߩታ↪ൻ߳ߩ㆏
⠴ᾲశࡈࠔࠗࡃߩታ↪ൻࠍ⋡ᜰߒߡ⧰ഭߒߚߩ
ߪ㧘߫ࠄߟ߈ࠍᛥ߃ࠆߎߣߢߒߚ㧚ᒰೋ㧘ࠪ࡝ࠞࡒࠢࡠᄙሹ⤑ߩ⚦ሹᓘߦߪ߫ࠄߟ
߈߇޽ࠅ߹ߒߚ㧚߫ࠄߟ߈ࠍዋߥߊߔࠆߚ߼ߦߪ㧘ࠪ࡝ࠞࡒࠢࡠᄙሹ⤑ߩ೨㚟૕ࠍวᚑߔࠆൻቇ෻ᔕ
ࠍߢ߈ࠆߛߌဋ৻ߦߔࠆᔅⷐ߇޽ࠅ߹ߔ㧚߆ߊߪࠎߦᤨ㑆ࠍ߆ߌࠆߥߤߩᎿᄦࠍߔࠆߎߣߢ⸃᳿ߒ
߹ߒߚ㧚శࡈࠔࠗࡃߣࠪ࡝ࠞࡒࠢࡠᄙሹ⤑ߩኒ⌕ᕈߦ߽߫ࠄߟ߈߇޽ࠅ߹ߒߚ㧚ߎߩ߫ࠄߟ߈ߪ㧘ࠪ࡝ࠞࡒࠢࡠᄙሹ⤑ߩ೨㚟૕ࠍశࡈࠔࠗࡃߦႣᏓ㧘὾ᚑ
ߔࠆᎿ⒟ߦ໧㗴߇޽ࠅ߹ߔ㧚ࠟ࡜ࠬ᧼ߦࠪ࡝ࠞࡒ
ࠢࡠᄙሹ⤑ࠍႣᏓߒࡎ࠶࠻ࡊ࡟࡯࠻ߢടᾲߒߚߣ
ߎࠈ㧘ኒ⌕ᒝᐲߪ㜞޿ߎߣ߇ࠊ߆ࠅ߹ߒߚ㧚ႣᏓṁᇦ߇⫳⊒ߔࠆ㓙ߦᾲࠍᅓ߁ߚ߼㧘㔚᳇Ἱ߇⍴޿ߣశࡈࠔࠗࡃ߇ടᾲߐࠇࠆ೨ߦ㔚᳇Ἱࠍㅢㆊߒߡ
ߒ߹߁ࠃ߁ߢߒߚ㧚㔚᳇Ἱࠍ㐳ߊߔࠇ߫㧘ࠪ࡝ࠞࡒࠢࡠᄙሹ⤑ߣశࡈࠔࠗࡃߩ㑆ߦᒝ޿⚿ว߇ᒻᚑߐࠇࠆߣ੍ᗐߐࠇ߹ߒߚ㧚ߣߎࠈ߇㧘శࡈࠔࠗࡃߩ✢ᒁ߈ⵝ⟎ߣ޿߁ߩߪ
ᄢဳߢ޽ࠅ㧘◲නߦⵝ⟎ࠍᡷ⦟ߔࠆߎߣ߇ߢ߈߹
ߖࠎ㧚✢ᒁ߈Ꮏ⒟ߩᓟߦ㧘ႣᏓ㧘὾ᚑᎿ⒟ࠍㅪ⛯ߒߡ߅ߊᔅⷐ߇޽ࠆߚ߼㧘㔚᳇Ἱߪ✢ᒁ߈ⵝ⟎ߩਅߩ㒢ࠄࠇߚ႐ᚲߦ⟎߆ߥߌࠇ߫ߥࠅ߹ߖࠎߢߒ
ߚ㧚㐳޿㔚᳇Ἱࠍ⟎ߊߎߣ߇ߢ߈ߕ㧘ടᾲᤨ㑆ࠍචಽߦߣࠆߎߣ߇ߢ߈߹ߖࠎߢߒߚ㧚ᒝᐲߪᦨ߽

J. HTSJ, Vol. 48, No. 203

․೎ነⓂ
ᒙ޿ㇱಽ߇⹏ଔߩኻ⽎ߦߥࠅ߹ߔ㧚ႣᏓṁᶧߦᷝട೷ࠍട߃ࠆߣ޿߁ᰴༀߩ╷ߢਸ਼ࠅಾࠅ߹ߒߚ߇㧘ᦨᓟ߹ߢᒝᐲ߇໧㗴ߦߥࠅ߹ߒߚ㧚᧚ᢱߩࡐ࠹ࡦࠪࡖ࡞ࠍᒁ߈಴ߔߚ߼ߦߪ㧘ࡊࡠ
࠮ࠬ߇㊀ⷐߢ޽ࠆߣ∩ᗵߒ߹ߒߚ㧚ࡊࡠ࠮ࠬߪᄢ
ⷙᮨߦߥࠇ߫ᛩ⾗߇ᔅⷐߢ޽ࠅ㧘ᛩ⾗ߩߚ߼ߦߪ
ᄢⷙᮨߥ㔛ⷐ߇⏕଻ߐࠇߥߌࠇ߫ߥࠅ߹ߖࠎ㧚ߣߎࠈ߇㧘ࡊࡠ࠮ࠬ߇᧚ᢱߩࡐ࠹ࡦࠪࡖ࡞ࠍචಽߦ
ᒁ߈಴ߒߡ޿ߥ޿ߣ㔛ⷐ߇ᐢ߇ࠄߥ޿ߩߢߔ㧚ታ↪ൻᲑ㓏ߦ㜞߼ࠆߩߪ৻╭✽ߢߪ޿߆ߥ޿ߣᗵߓ߹ߒߚ㧚 ⠴ᾲ⛘✼᧚ᢱ߳ߩዷ㐿ᖱႎᯏེߩ㜞㓸Ⓧൻ㧘⥄േゞߩ㔚᳇㚟േൻߦߣ߽ߥ޿㧘ᾲߩࡑࡀࠫࡔࡦ࠻߇㊀ⷐߦߥߞߡ޿߹ߔ㧚㜞಴ജߩ႐ว㧘⊒ᾲ㊂߽ᄢ߈ߊߥࠆߚ߼㧘⠴ᾲ⛘✼᧚ᢱ߇ᔅⷐߣߐࠇ߹ߔ㧚⠴ᾲశࡈࠔࠗࡃߦ↪޿ߚࠪ࡝ࠞࡒࠢࡠᄙሹ⤑ࠍ⠴ᾲ⛘✼᧚ᢱߣߒߡዷ㐿ߔࠆߦߪ㧘޿ߊߟ߆ߩ໧
㗴߇޽ࠅ߹ߒߚ㧚ࠪ࡝ࠞࡒࠢࡠᄙሹ⤑߇ᢙ⊖ nm ⒟ᐲߩ⤑ෘߢ޽ࠆߩߦኻߒߡ㧘⛘✼᧚ᢱߪᢙ μm એ਄ߩ⤑ෘ߇ᔅⷐߣߐࠇ߹ߔ㧚ߎߩߚ߼㧘ࠪ࡝ࠞࡒࠢࡠᄙሹ⤑ߩߺߢෘ⤑ߣߔࠆߎߣߪ࿎㔍ߢߔ㧚ࠪ࡝ࠞࡒࠢࡠᄙ
ሹ⤑ߩਛߦ☸ሶࠍᷙวߔࠆߎߣߢ㧘ෘ⤑ߣߔࠆߎߣ߇ߢ߈߹ߔ㧚⇣ߥࠆ᧚ᢱࠍធวߔࠆ႐วߦᾲ⤘ᒛ₸߇⇣ߥࠅᱡࠍ↢ߓ߹ߔ㧚ࠪ࡝ࠞࡒࠢࡠᄙሹ⤑ߪ⚦ሹࠍᄙߊ฽߻ߚ߼㧘ߎߩᱡࠍ✭๺ߔࠆലᨐࠍ
⊒ើߒ߹ߔ㧚৻ᣇ㧘☸ሶߪ⛘✼ᕈࠍ⠨ᘦߔࠆߣ࠮
࡜ࡒ࠶ࠢࠬ☸ሶࠍ↪޿ࠆߎߣߦߥࠅ߹ߔ㧚࠮࡜ࡒ
࠶ࠢࠬߩ⒳㘃ࠍㆬᛯߔࠆߎߣߢ㧘⤑ߩᕈ⾰ࠍᄌ߃ࠆߎߣ߇ߢ߈߹ߔ㧚ߚߣ߃߫㧘࠮࡜ࡒ࠶ࠢࠬߪ㧘㊄ዻ㧙㉄⚛⚿ว߇޽ࠆߚ߼㧘ߎߩ⚿วࠛࡀ࡞ࠡ࡯ߦኻᔕߒߚ⿒ᄖ✢

વᾲ 2009 ᐕ 4 ᦬ߩๆ෼߿᡼಴߇ⴕࠊࠇ߹ߔ㧚ߎߩ૞↪߇᦭ലߦᯏ
⢻ߔࠆ࠮࡜ࡒ࠶ࠢࠬ☸ሶࠍㆬᛯߔࠇ߫㧘⤑ߦᷙวߒߚ࠮࡜ࡒ࠶ࠢࠬ☸ሶ߆ࠄ⿒ᄖ✢ࠍ᡼಴ߔࠆߎߣ
ߢ㆙㓒࿾ߦ᡼ᾲߔࠆߎߣ߇น⢻ߦߥࠅ㧘ᾲ᡼኿⛘✼⤑ߣߥࠅ߹ߔ㧚৻ᣇ㧘ᾲવዉᕈߩ㜞޿࠮࡜ࡒ࠶
ࠢࠬ☸ሶࠍㆬᛯߔࠇ߫㧘⤑ߩᾲવዉᕈ߇㜞߹ࠅ㧘ᾲવዉ⛘✼⤑ߣߥࠅ߹ߔ㧚߽߁߭ߣߟߩ໧㗴ߪ㧘ࠪ࡝ࠞࡒࠢࡠᄙሹ⤑ߪ⴫㕙ߦ OH ၮ߇ሽ࿷ߔࠆߚ߼ߦⷫ᳓ᕈߢ޽ࠅ㧘⚦ሹౝߦ᳓߇ๆ⌕ߐࠇ߿ߔ޿ߣ޿߁ߎߣߢߔ㧚᳓߇ๆ⌕ߔࠆߣ⪺ߒߊ⛘✼ᕈ߇៊ߥࠊࠇ߹ߔ㧚⤑ࠍ⇹᳓ൻߔࠆᔅⷐ߇޽ࠅ߹ߔ㧚⃻࿷㧘࠮࡜ࡒ࠶ࠢࠬ☸ሶߩᷙวߦࠃࠆෘ⤑ൻߣ⤑ߩ⇹᳓ൻߩ⺖㗴ࠍ⸃᳿ߒ㧘⠴ᾲ⛘✼᧚ᢱ߳ߩዷ
㐿ࠍ࿑ߞߡ޿߹ߔ[5]㧚
㩷ෳ⠨ᢥ₂
[1] Murakami, Y. et al., Microporous silica particles
prepared by the salt-catalytic sol-gel process withextremely low content of water, J. Sol-Gel Sci.
Tech., 29 (1999) 19.
[2] ᧛਄ ᵏ㧘ઁ㧘ੑ㉄ൻࠤࠗ⚛⭯⤑ߣߘߩ⵾ㅧ
ᣇᴺ㧘․㐿 2004-292190㧚
[3] Simizu, W. et al., Superhydrophilic microporous
silica coatings on polymer substrate, J. Ceram.
Soc. Jpn ., 115 (1999) 712.
[4] ⊝ἑචਃᄦ㧘ઁ㧘⠴ᾲశࡈࠔࠗࡃ߅ࠃ߮ߘߩ
⵾ㅧᣇᴺ㧘․㐿 2006-47933㧚
[5] ‫ࠬ࡟ࡊޟ‬ടᎿࠦࠗ࡞ߣᣂⷙ⛘✼᧚ᢱࠍ↪޿ߚᄢ㔚ᵹࠗࡦ࠳ࠢ࠲㐿⊒‫ޠ‬㧘ᐔᚑ 19 ᐕᐲ࿾ၞᣂ↢ࠦࡦ࠰࡯ࠪࠕࡓ⎇ⓥ㐿⊒੐ᬺ㧘⚻ᷣ↥ᬺ⋭㧧ᐔᚑ 20 ᐕᐲ࿾ၞࠗࡁࡌ࡯࡚ࠪࡦഃ಴⎇ⓥ㐿⊒੐ᬺ㧘⚻ᷣ↥ᬺ⋭㧚- 65 -J. HTSJ, Vol. 48, No. 203

ⴕ੐ࠞ࡟ࡦ࠳࡯
ᧄળਥ௅ⴕ੐
㐿௅ᣣ
2008 ᐕ
6᦬

2(Ἣ)
ޯ4(ᧁ)

ⴕ੐ฬ

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ේⓂ✦ಾ

໧วవ
Email: info@nhts2009.me.kyoto-u.ac.jp
http://nhts2009.me.kyoto-u.ac.jp/index.html╙ 46 ࿁ᣣᧄવᾲࠪࡦࡐࠫ࠙ࡓ
㧔㐿௅႐ᚲ㧦࿖┙੩ㇺ࿖㓙ળ㙚㧕

2009.1.19

2009.3.16

↳ㄟ✦ಾ

ේⓂ✦ಾ

ឝタภ

10 ᦬ภ
1 ᦬ภ

ᧄળ౒௅㧘ද⾥㧘ᓟេⴕ੐㐿௅ᣣ
2009 ᐕ

ⴕ੐ฬ

໧วవ

5 ᦬㩷

12(Ἣ㧕㩷
ޯ14(ᧁ)㩷

╙ 14 ࿁⸘▚Ꮏቇ⻠Ṷળ㧔㐿௅႐ᚲ㧦᧲੩ᄢቇ↢↥ᛛⴚ⎇ⓥᚲ㧕㩷

2009.1.30㩷

5᦬

13(᳓䋩
ޯ14(ᧁ)

⻠⠌ળ㩷 นⷞൻ䊐䊨䊮䊁䉞䉝䇸ᵹ૕䈱↹௝⸘᷹
䋨PIV/LIF䋩䈱ၮ␆䈫ᔕ↪䇹䋨㐿௅႐ᚲ䋺᧲੩Ꮏᬺᄢቇᄢጟጊ䉨䊞䊮䊌䉴䋩

2009.5.6

㩷

6᦬

5(㊄)

ᣣᧄᷙ⋧ᵹቇળ ᷙ⋧ᵹ䊧䉪䉼䊞䊷䉲䊥䊷䉵䇸䊙䉟䉪䊨䊶䊅䊉䊋䊑䊦䈫․ᕈ䈫䈠䈱ᔕ↪䇹䋨㐿௅႐ᚲ䋺ᄢ㒋⑳┙ᄢቇᢥൻ੤ᵹ䉶䊮䉺䊷䋩

2009.5.22

㩷

6᦬

9(Ἣ)
ޯ11(ᧁ)╙ 58 ࿁ℂ⺰ᔕ↪ജቇ⻠Ṷળ䋨㐿௅࿾䋺᧲੩ㇺ᷼඙䋩

2009.3.57᦬

29(᳓)ޯ30(ᧁ)

⻠⠌ળ䇸ᾲ⸳⸘䉕ᡰេ䈜䉎ᾲᵹ૕⸘᷹ᛛⴚ䇹䋨㐿௅႐ᚲ䋺᧲੩Ꮏᬺᄢቇᄢጟጊ䉨䊞䊮䊌䉴䋩

2009.7.19

2009.4.3㩷

2009.4.16㩷⸘▚Ꮏቇ⻠Ṷળ੐ോዪ㩷‫ޥ‬101-8449 ᧲੩ㇺජઍ↰඙␹↰㍪↸ 3-24૑෹໡੐␹଻↸ࡆ࡞ (ᩣ)ICS ࠦࡦࡌࡦ࡚ࠪ
ࡦ࠺ࠩࠗࡦ᳇ઃ㩷
TEL 03-3219-3541 FAX 03-3292-1811㩷
Email: jsces@ics-inc.co.jp㩷นⷞൻᖱႎቇળ੐ോዪ
‫ޥ‬114-0034 ᧲੩ㇺർ඙਄ච᧦ 3-29-20 ࠕ࡞ࡏࠜ࡞਄ච᧦ 103
TEL: 03-5993-5020
Email: info@vsj.or.jp
http://www.visualization.jp/㩷㩷␠࿅ᴺੱ࿯ᧁቇળ㩷 䋨ᜂᒰ:Ⴧ᳗䊶┻↰䋩䇾160-0004㩷 ᧲੩ㇺᣂኋ඙྾⼱৻ৼ⋡ᄖủ౏࿦ౝ
TEL:㩷 03-3355-3559㩷 㩷 FAX:㩷 03-5379-0125
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tam.html

㩷(␠䋩ᣣᧄᯏ᪾ቇળ
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㩷ਣጊ ⋥᮸㩷
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ਃ㊀ᄢቇᄢቇ㒮Ꮏቇ⎇ⓥ⑼ᯏ᪾Ꮏቇኾ᡹㩷
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NURETH-13 ⃻࿾⚵❱ᆔຬળᆔຬ㐳 ᧛ἑ㆏㓶(ᩣ)ේሶജ቟ోࠪࠬ࠹ࡓ⎇ⓥᚲ ᛛⴚࠪࠬ࠹ࡓ⎇ⓥᚲ㩷
TEL: 0770-37-9110㩷
Email: murase@inss.co.jp
Web: http://www.nureth13.org/2(ᣣ)㩷
ޯ5(᳓)㩷

7th Annual International Energy Conversion Engineering
Conference (IECEC2009)㧔㐿௅࿾㧦Denver, CO, USA㧕㩷2008.12.7㩷

2009.5.19㩷

8 ᦬㩷

7(㊄)㩷
ޯ9(ᣣ)㩷

ᣣᧄᷙ⋧ᵹቇળᐕળ⻠Ṷળ 2009╙ 28 ࿁ᷙ⋧ᵹࠪࡦࡐࠫ࠙ࡓ
㧔㐿௅႐ᚲ㧦ᾢᧄᄢቇ㧕

2009.3.30㩷

2009.6.5㩷

9᦬
㩷
10 ᦬

27(ᣣ)㩷
ޯ
2(㊄)╙ 13 ࿁ේሶἹᾲᵹേ࿖㓙ળ⼏㧔NURETH13㧕㧔㐿௅࿾㧦㊄ᴛᏒ㧕2008.10.31

2009.1.31

10 ᦬

7(᳓)
ޯ9(㊄)

15th International Workshop on Thermal Investigationsof ICs and Systems䋨㐿௅࿾䋺Leuven, Belgium䋩2009.4.30

2009.8.29

http://cmp.imag.fr/conferences/therminic/therminic2009

11 ᦬

16(᦬)
ޯ19(ᧁ)The 7th Pacific Symposium on Flow Visualization andImage Processing (PSFVIP-7)㧔㐿௅࿾㧦Kaohsiung, Taiwan, ROC㧕2008.10.31

2009.4.15

Dr. Tai, C.H., National Pingtung Univ. of
Science and Technology (Taiwan, ROC)
Email: chtai@mail.npust.edu.tw
Web: http://www.tuat.ac.jp/%7Epctfe/

11 ᦬㩷

16(᦬)㩷
ޯ20(㊄)㩷

International Conference on Power Engineering-09,
Kobe (ICOPE-09)
㧔㐿௅࿾㧦␹ᚭᏒ㧕㩷

2008.12.31

2009.3.31㩷

Ryosuke Matsumoto㩷
Kansai University㩷
Email: matumoto@kansai-u.ac.jp㩷

- 67 -

㩷䊧䉪䉼䊞䊷䉲䊥䊷䉵ㆇ༡ᆔຬળ੐ോዪ
TEL & FAX: 06-6879-7316
lecture-ser@mech.eng.osaka-u.ac.jp

8 ᦬㩷વᾲ 2009 ᐕ 4 ᦬

ឝタภ

㩷

㩷

㩷

㩷

J. HTSJ, Vol. 48, No. 203

߅⍮ࠄߖ

The 14th International Heat Transfer Conference㧔╙ 14 ࿁࿖㓙વᾲળ⼏㧦IHTC-14㧕⺰ᢥ൐㓸ߩ߅⍮ࠄߖ╙ 14 ࿁࿖㓙વᾲળ⼏㧔IHTC-14㧕߇㧘2010 ᐕ 8 ᦬ 7ޯ13 ᣣߦ☨࿖ࡢࠪࡦ࠻ࡦ DC ߢ㐿௅ߐࠇ߹ߔ㧚IHTC-14
ߢߪ㧘ᓥ᧪ߩવᾲ⃻⽎ߩၮ␆㧘વᾲᔕ↪ᛛⴚߦട߃ߡ㧘࠽ࡁ᧚ᢱ㧘ࡃࠗࠝ㧘MEMS ╬ߩࡑࠗࠢࡠࠪࠬ࠹ࡓ㧘ᖱႎᯏེ߿ࠛࡀ࡞ࠡ࡯ᄌ឵ᯏེ㧘⥶ⓨቝቮ㧘ⅣႺߥߤߩ⊒ዷߩ߼ߑ߹ߒ޿ಽ㊁ߦ߅ߌࠆᾲᵹേ⃻⽎ߩ⊒⴫߇ᦼᓙߐࠇߡ޿߹ߔ㧚㑐ㅪฦ૏ߩⓍᭂ⊛ߥߏෳടࠍ߅㗿޿޿ߚߒ߹ߔ㧚 ߥ߅㧘⺰ᢥᛩⓂߩࠬࠤࠫࡘ࡯࡞ߪએਅߩㅢࠅߢߔ㧚̒ ࠕࡉࠬ࠻࡜ࠢ࠻↳ߒㄟߺ✦߼ಾࠅ㧦2009 ᐕ 8 ᦬ 28 ᣣ̒ ࠕࡉࠬ࠻࡜ࠢ࠻ណᛯㅢ⍮㧦2009 ᐕ 10 ᦬ 2 ᣣ̒ ᩏ⺒↪ࡈ࡞ࡍ࡯ࡄ࡯ឭ಴✦߼ಾࠅ㧦2009 ᐕ 12 ᦬ 31 ᣣ̒ ᩏ⺒⚿ᨐㅢ⍮㧦2010 ᐕ 3 ᦬ 26 ᣣ
̒ ࠦࡇ࡯࡜ࠗ࠻⒖⼑↪⚕ឭ಴✦߼ಾࠅ㧦2010 ᐕ 3 ᦬ 31 ᣣ
̒ ࡈ࡞ࡍ࡯ࡄ࡯ᦨ⚳ේⓂឭ಴✦߼ಾࠅ㧦2010 ᐕ 4 ᦬ 30 ᣣ ⺰ᢥᛩⓂߩ⹦⚦╬ߦߟ߈߹ߒߡߪ㧘એਅߩࡎ࡯ࡓࡍ࡯ࠫࠍߏⷩߊߛߐ޿㧚
http://www.asmeconferences.org/IHTC14/

વᾲ 2009 ᐕ 4 ᦬- 68 -J. HTSJ, Vol. 48, No. 203

߅⍮ࠄߖ


╙ 46 ࿁ᣣᧄવᾲࠪࡦࡐࠫ࠙ࡓ㐿௅⋥೨ߩߏ᩺ౝ
╙ 46 ࿁ᣣᧄવᾲࠪࡦࡐࠫ࠙ࡓታⴕᆔຬળᆔ ຬ 㐳 ’㊁ବ㇢੐ോዪ㐳 ਛㇱਥᢘ‫ޣ‬㐿 ௅ ᣣ‫ ޤ‬ᐔᚑ 21 ᐕ 6 ᦬ 2 ᣣ㧔Ἣ㧕ޯ 6 ᦬ 4 ᣣ㧔ᧁ㧕
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‫ ࠫ࡯ࡍࡓ࡯ࡎޣ‬URL‫ ޤ‬http://nhts2009.me.kyoto-u.ac.jp/‫․ޣ‬೎⻠Ṷ‫ ޤ‬6 ᦬ 3 ᣣ㧔᳓㧕㧘15:10㨪16:10㧘D ቶߦߡ       㐷ౝ ノⴕ ᢎ᝼㧔੩ㇺᄢቇ㧕  ‫ޟ‬ᱧผㇺᏒ࡮੩ㇺߩ᥊ⷰ࡮ⅣႺߩഃ↢‫ޠ‬‫  ✚ޣ‬ળ‫ ޤ‬6 ᦬ 3 ᣣ㧔᳓㧕㧘16:20㨪17:40㧘D ቶߦߡ‫ߩࡓ࠙ࠫࡐࡦࠪޣ‬ᒻᑼ‫ޤ‬࡮ ⻠Ṷᒻᑼߣߒߡ㧘a) ৻⥸࠮࠶࡚ࠪࡦ㧔ญ㗡⊒⴫㧕b) ࠝ࡯ࠟ࠽ࠗ࠭࠼࠮࠶࡚ࠪࡦ㧔ญ㗡⊒⴫㧕c) ቇ↢࡮⧯ᚻ⎇ⓥ⠪ࠍኻ⽎ߣߔࠆఝ⑲ࡊ࡟࠯ࡦ࠹࡯࡚ࠪࡦ⾨࠮࠶࡚ࠪࡦ
ࠍ⸳ߌ߹ߔ㧚
࡮ 1 ⻠Ṷ޽ߚࠅߩ⻠Ṷᤨ㑆ߪ㧘৻⥸࠮࠶࡚ࠪࡦߦߟ޿ߡߪ 15 ಽ㧔⊒⴫ 10 ಽ㧘୘೎⸛⺰ 5 ಽ㧕ߣߒ㧘ฦ࠮࠶࡚ࠪࡦߩᦨᓟߦ✚ว⸛⺰ߩᤨ㑆㧔5 ಽ࠮࠶࡚ࠪࡦౝߩ⻠Ṷઙᢙ㧕ࠍ⸳ߌ߹ߔ㧚ࠝ࡯ࠟ࠽ࠗ࠭࠼࠮
࠶࡚ࠪࡦߦߟ޿ߡߪ㧘ࠝ࡯ࠟ࠽ࠗࠩ࡯ߩᜰ␜ߦᓥߞߡਅߐ޿㧚ࠝ࡯ࠟ࠽ࠗࠩ࡯ߩㅪ⛊వ╬ߪࡎ࡯ࡓࡍ࡯
ࠫࠍߏෳᾖਅߐ޿㧚࡮ ఝ⑲ࡊ࡟࠯ࡦ࠹࡯࡚ࠪࡦ⾨࠮࠶࡚ࠪࡦߦߟ޿ߡߪ㧘ᧄภឝタߩ߅⍮ࠄߖ‫ޟ‬ఝ⑲ࡊ࡟࠯ࡦ࠹࡯࡚ࠪࡦ⾨ߦߟ޿ߡ‫ߏࠍޠ‬ෳᾖਅߐ޿㧚࡮ ࠪࡦࡐࠫ࠙ࡓߩ࠲ࠗࡓ࠹࡯ࡉ࡞෸߮ࡊࡠࠣ࡜ࡓߦߟ޿ߡߪᧄภߩ̌߅⍮ࠄߖ㧔೎ᷝ㧕̍ࠍߏⷩਅߐ޿㧚‫ޣ‬ෳട⾌╬‫ޤ‬࡮ ࠪࡦࡐࠫ࠙ࡓෳട⾌৻⥸㧔14,000 ౞㧕ቇ↢㧔6,000 ౞㧕࡮ ⻠Ṷ⺰ᢥ㓸ᣣᧄવᾲቇળળຬ㧦 ήᢱ㧔㔚ሶ ߪ㧘੐೨ߦ J-Stage ਄ߢ౏㐿ߒ߹ߔ㧚ෳട⠪ߦߪᒰᣣߦౠሶ૕࡮

વᾲ 2009 ᐕ 4 ᦬- 69 -J. HTSJ, Vol. 48, No. 203

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CD-ROM ࠍ㈩Ꮣߒ߹ߔ㧚ਇෳട⠪ߩ߁ߜߩᏗᦸ⠪ߦߪ㧘CD-ROM ࠍ੐ᓟߦ㈩Ꮣߒ߹ߔߩߢ㧘㐿௅ᓟ 1 ࡨ᦬એౝߦ㧘ᣣᧄવᾲቇળተߡߦߏ᳁ฬ࡮ㅍઃవࠍ᣿
⸥ߩ਄㧘ࡔ࡯࡞ߦߡ߅↳ߒㄟߺਅߐ޿㧚㧕㕖  ળ  ຬ㧦 8,000 ౞㧔ౠሶ૕㧕㧚ળ႐ฃઃߦߡᣣᧄવᾲቇળ߳ߩ౉ળࠍ↳ߒㄟ߹ࠇࠆ႐วߦ
ߪ㧘ήᢱߣߒ߹ߔ㧚‫ޣ‬ᙣⷫળ‫ޤ‬࡮ 㐿 ௅ ᣣ㧦 ᐔᚑ 21 ᐕ 6 ᦬ 3 ᣣ㧔᳓㧕
㧘18:00㨪20:00
࡮ ળ  ႐㧦 ࿖┙੩ㇺ࿖㓙ળ㙚㧔ኃળ႐‫ޠࠄߊߐޟ‬㧕࡮ ᙣⷫળ⾌㧦৻⥸㧔10,000 ౞㧚㈩஧⠪ήᢱ㧕ቇ↢㧔5,000 ౞㧕‫ޣ‬ෳട⾌╬ߩᝄㄟߺᣇᴺ‫ޤ‬࡮ ੐೨ෳട↳ㄟߪ 4 ᦬ 13 ᣣߢ✦߼ಾࠅ߹ߒߚ㧚ߒ߆ߒ㧘ߘࠇએ㒠ߢ߽ 5 ᦬ 29 ᣣ߹ߢߪ㧘਄⸥ߩෳട⾌╬ߩᛒ޿ߢ⊓㍳น⢻ߢߔ㧚ߎߩ႐ว㧘ᒰᣣߦฃઃߢ߅ᷰߒߔߴ߈߽ߩࠍ੍߼Ḱ஻ߒߡ߅ߊ╬ߩ૞ᬺࠍ޿
ߚߒ߹ߔ㧚߽ߜࠈࠎ㧘଀ᐕߩࠃ߁ߦ㧘ࠪࡦࡐࠫ࠙ࡓᒰᣣߩෳട↳ㄟ߽ߢ߈߹ߔ㧚࡮ ࠬ࠹࠶ࡊ 1㧦߹ߕ㧘ࡎ࡯ࡓࡍ࡯ࠫ߆ࠄෳട⊓㍳ࠍⴕߞߡਅߐ޿㧚᛬ࠅ㄰ߒ㧘ෳട⊓㍳ ID ⇟ภ㧔4 ᩴߩᢙ㧘଀㧦1234㧕ߣ㊄㗵߇⸥タߐࠇߚ㔚ሶࡔ࡯࡞ࠍ߅ㅍࠅߒ߹ߔ㧚࡮ ࠬ࠹࠶ࡊ 2㧦ߟ߉ߦ㧘ਅ⸥ߩ㌁ⴕญᐳߦ㧘㔚ሶࡔ࡯࡞ߦᜰቯߩ㊄㗵ࠍᝄㄟࠎߢਅߐ޿㧚ߘߩ㓙㧘ᔅߕ㧘᳁ฬߩ೨ߦෳട⊓㍳ ID ⇟ภࠍઃߌߡਅߐ޿㧚ᝄㄟవ㧦 ߺߕ߶㌁ⴕ
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㧔ATM ᯏߦࠃߞߡߪㅜਛ߹ߢߒ߆⴫␜ߐࠇߥ޿߆߽⍮ࠇ߹ߖࠎ߇ᄢਂᄦߢߔ㧚㧕ATM ᯏߢߩᝄㄟੱߩᜰቯ଀㧦 ‫ޟ‬㧝㧞㧟㧠 ࠹̍ࡦࡀ࠷࠲ࡠ࠙‫ޠ‬ᵈᗧ 1㧦㌁ⴕᝄㄟߺࠍ߽ߞߡ‫ޟ‬ෳട⊓㍳ቢੌ‫ߔ߹ߒߣޠ‬㧚ࡎ࡯ࡓࡍ࡯ࠫ߆ࠄߩ⊓㍳ߛߌߢߪ‫ޟ‬ቢੌ‫ߪߢޠ‬޽ࠅ߹ߖࠎ㧚5 ᦬ 29 ᣣ߹ߢߦ㧘㌁ⴕᝄㄟߺ߹ߢߩᚻ⛯߈ࠍⴕߞߡਅߐ޿㧚ᵈᗧ 2㧦⚻ℂಣℂߩㇺว਄㧘ⶄᢙߩ⊓㍳⠪ߩಽࠍ߹ߣ߼ߡᝄㄟ߻ߎߣߪߏ㆙ᘦਅߐ޿㧚߅ᚻᢙߢߔ߇㧘ᔅ
ߕ 1 ઙߕߟ‫ޟ‬ෳട⊓㍳ ID ⇟ภߣ᳁ฬ‫ࠍޠ‬ᜰቯߒߡ߅ᝄㄟߺਅߐ޿㧚ᵈᗧ 3㧦੹࿁ߩࠪࡦࡐࠫ࠙ࡓߢߪ㌁ⴕญᐳߩߺࠍ㐿⸳ߒߡ޿߹ߔߩߢ㧘ᓥ᧪㧘ቇળ⹹ߦ᜽ߺㄟࠎߢ޿ߚ‫ޟ‬ㇷଢᝄᦧ↪⚕‫ࠎߖ߹ࠅ޽ߪޠ‬㧚‫⻠ޣ‬Ṷ⺰ᢥ㓸㧔㔚ሶ 㧕‫ޤ‬࡮ ⻠Ṷ⺰ᢥ㓸㧔㔚ሶ 㧕ߦߟ޿ߡߪ㧘ᣣᧄવᾲቇળળຬ㧔2009 ᐕᐲળຬ㧕ߩᣇ‫ߦޘ‬ኻߒ㧘ࡎ࡯ࡓࡍ࡯ࠫ
ߦ࡝ࡦࠢߐࠇߚ J-Stage ߩࠨࠗ࠻ࠍㅢߓߡ౏㐿ߒ߹ߔ㧚౏㐿ᣣߪ 2009 ᐕ 5 ᦬ 26 ᣣ㧔Ἣ㧕ࠍ੍ቯߒߡ޿߹
ߔ㧚․⸵ߦ㑐ࠊࠆ౏⍮ᣣ߽ߎߩᣣߦߥࠅ߹ߔ㧚࡮ 㔚ሶ ߪ㧘ࡎ࡯ࡓࡍ࡯ࠫߩ࠻࠶ࡊࡍ࡯ࠫ㧔ᣣᧄવᾲቇળߩࡎ࡯ࡓࡍ࡯ࠫ߆ࠄ߽࡝ࡦࠢ߇ᒛࠄࠇߡ޿߹
ߔ㧚ߎߩ႐วߦߪ㧘ᣣᧄવᾲࠪࡦࡐࠫ࠙ࡓ㧕 ψ ⻠Ṷࡊࡠࠣ࡜ࡓ ψ ⻠Ṷ⺰ᢥ㓸㧔㔚ሶ 㧕㧘ߣㄡߞߡ޿
ߚߛ߈㧘J-Stage ߩᒰ⹥ࡍ࡯ࠫߦ౉ࠅ㧘એਅߩ⾼⺒⠪ࠦ࡯࠼ߣࡄࠬࡢ࡯࠼ࠍ↪޿ߡࡠࠣࠗࡦߩ਄㧘࠳࠙ࡦࡠ࡯࠼ߔࠆߎߣ߇ߢ߈߹ߔ㧚ߥ߅㧘ߎߩࠨࠗ࠻਄ߢߩ⻠Ṷ⺰ᢥ౏㐿ߪ㧘ᓥ᧪߆ࠄⴕߞߡ߈߹ߒߚᣣᧄવ
ᾲቇળળຬ߳ߩㇷㅍߦࠃࠆ⻠Ṷ⺰ᢥ㓸 CD-ROM ੐೨㈩Ꮣߦઍࠊࠆ߽ߩߢߔ㧚વᾲ 2009 ᐕ 4 ᦬- 70 -J. HTSJ, Vol. 48, No. 203

߅⍮ࠄߖ࡮ J-Stage㧦⾼⺒⠪ࠦ࡯࠼㧘ࡄࠬࡢ࡯࠼㧦࡮ ࠪࡦࡐࠫ࠙ࡓߢᐳ㐳ࠍߏᜂᒰਅߐࠆవ↢ᣇߦߪ㧘ߎߩ㔚ሶ ࠍ߽ߞߡᒰᣣߩ࠮࠶࡚ࠪࡦߩෳ⠨⾗ᢱߣߒߡਅߐ޿㧚
‫⻠ޣ‬Ṷ⺰ᢥߩ౏㐿ᣣ‫ޤ‬࡮ ⻠Ṷ⺰ᢥߪ㧘ળຬࠍኻ⽎ߦ㧘ࠪࡦࡐࠫ࠙ࡓ㐿௅ᣣߩ 1 ㅳ㑆⒟೨߆ࠄ J-Stage ਄ߢ౏㐿ߒ߹ߔ㧚࡮ ߒߚ߇ߞߡ㧘․⸵ߦ㑐ࠊࠆ౏⍮ᣣߪ㧘ࠪࡦࡐࠫ࠙ࡓ㐿௅ᣣࠃࠅ߽ᣧߊߥࠅ߹ߔߩߢߏᵈᗧਅߐ޿㧚‫ޣ‬੤ㅢߣኋᴱ‫ޤ‬࡮ ੩ㇺߪ਎⇇߆ࠄߩᣏⴕ⠪߇Ᏹᤨ㧘ᄙᢙ㧘⸰ࠇࠆ࿖㓙ᢥൻㇺᏒߢߔ㧚ߘߩߚ߼㧘ࡎ࠹࡞ߩ੍⚂ߪኈᤃߢߪ޽ࠅ߹ߖࠎ㧚޿߹ߔߋߦ߽ᚻ㈩ߐࠇࠆߎߣࠍᒝߊ߅൘߼ߒ߹ߔ㧚ࠪࡦࡐࠫ࠙ࡓታⴕᆔຬળߢ߽ 250 ቶ⒟ᐲߩㇱደࠍ⏕଻ߒߡ߅ࠅ߹ߔ㧚ࡎ࡯ࡓࡍ࡯ࠫࠍ߅⸰ߨਅߐ޿㧚‫ߏޣ‬ᵈᗧ‫ޤ‬࡮ ญ㗡⊒⴫↪ߣߒߡታⴕᆔຬળ߇Ḱ஻ߔࠆᯏེߪ㧘ᶧ᥏ࡊࡠࠫࠚࠢ࠲࡯ߩߺߣߒ߹ߔ㧚ࡄ࡯࠰࠽࡞ࠦࡦ
ࡇࡘ࡯࠲࡯ߪฦ⥄ߏᜬෳਅߐ޿㧚࡮ ෳട⾌࡮ᙣⷫળ⾌ߪෳടขᶖߩ႐วߦ߽߅㄰ߒߒ߹ߖࠎ㧚࡮ ᄌᦝ੐㗄╬ߦߟ޿ߡߪ㧘㓐ᤨࡎ࡯ࡓࡍ࡯ࠫ਄ߦឝタߒ߹ߔߩߢ㧘ࡎ࡯ࡓࡍ࡯ࠫࠍߏෳᾖਅߐ޿㧚࡮ ߘߩઁ㧘ߏਇ᣿ߥὐ߇޽ࠅ߹ߒߚࠄ㧘ታⴕᆔຬળߦ E-mail ߹ߚߪ Fax ߢ߅໧޿วࠊߖਅߐ޿㧚‫߅ޣ‬໧޿วࠊߖవ‫ޤ‬ ╙ 46 ࿁ᣣᧄવᾲࠪࡦࡐࠫ࠙ࡓታⴕᆔຬળ  ੩ㇺᄢቇ ᄢቇ㒮Ꮏቇ⎇ⓥ⑼ ᯏ᪾ℂᎿቇኾ᡹ౝ
  E-mail: info@nhts2009.me.kyoto-u.ac.jp
  Fax: 075-753-5209

વᾲ 2009 ᐕ 4 ᦬- 71 -J. HTSJ, Vol. 48, No. 203߅⍮ࠄߖ

ఝ⑲ࡊ࡟࠯ࡦ࠹࡯࡚ࠪࡦ⾨㧔╙ 46 ࿁ᣣᧄવᾲࠪࡦࡐࠫ࠙ࡓ㧕ߦߟ޿ߡ
ᣣᧄવᾲቇળ ቇ↢ળᆔຬળᆔຬ㐳 ၳㇱ᣿ᒾ╙ 46 ࿁ᣣᧄવᾲࠪࡦࡐࠫ࠙ࡓߢߪ㧘ਅ⸥ߩⷐ㗔ߢ㧘ቇ↢࡮⧯ᚻ⎇ⓥ⠪ࠍኻ⽎ߦఝ⑲ࡊ࡟࠯ࡦ࠹࡯࡚ࠪࡦ
⾨࠮࠶࡚ࠪࡦࠍ⸳ߌ߹ߔ㧚ડᬺ࡮ᄢቇ࡮⎇ⓥᯏ㑐╬ߩᄙᢙߩ⊝᭽ߦߏෳട޿ߚߛ߈ߚߊ߅㗿޿޿ߚߒ߹ߔ㧚ᣣᤨ㧦 ᐔᚑ 21 ᐕ 6 ᦬ 2 ᣣ㧔Ἣ㧕 9:50㨪16:20㧔੍ቯ㧕㧔Ḱ஻㨪᠗෰㧕ߩᤨ㑆Ꮺߦߟ޿ߡߪᧄภߩ̌߅⍮ࠄߖ㧔೎ᷝ㧕̍ߩ࠲ࠗࡓ࠹࡯ࡉ࡞ࠍߏⷩਅߐ޿㧚⻠Ṷ ᒻ ᑼ㧦 ⊒⴫⠪ 1 ੱ޽ߚࠅ 3 ಽߩ࡚ࠪ࡯࠻ࡊ࡟࠯ࡦ࠹࡯࡚ࠪࡦ㧔SP㧕ߣࡐࠬ࠲࡯ࡊ࡟࠯ࡦ࠹࡯ࠪ
࡚ࡦ㧔PP㧕ࠍⴕߞߡ޿ߚߛߊ੍ቯߢߔ㧚ฦ࠮࠶࡚ࠪࡦߪ㧘એਅߩᒻᑼࠍ੍ቯߒߡ߅ࠅ߹
ߔ㧚٤࡚ࠪ࡯࠻ࡊ࡟࠯ࡦ࠹࡯࡚ࠪࡦ㧔SP㧕㩷࡮㩷 1 ੱ޽ߚࠅߩ⊒⴫ᤨ㑆ߪ 3 ಽߢߔ㧚ࠬࠤࠫࡘ࡯࡞߇࠲ࠗ࠻ߥߚ߼㧘⊒⴫ᤨ㑆ߪ෩቞ߢߔߩߢᵈᗧߒߡਅߐ޿㧚ߥ߅㧘࡚ࠪ࡯࠻ࡊ࡟࠯ࡦߢߪ⾰⇼ᔕ╵ߩᤨ㑆ߪ⸳ߌ߹ߖࠎ㧚㩷࡮㩷 ⊒⴫⾗ᢱߪ PDF ࡈࠔࠗ࡞㧔േ↹ਇน㧘਄㒢 3 MB㪆ੱ㧕ࠍ੐೨ឭ಴޿ߚߛ߈߹ߔ㧚ቇ↢ળᆔຬળ஥ߢࡁ࡯࠻ࡄ࠰ࠦࡦࠍ↪ᗧߒ㧘ߘߩਛߦࡈࠔࠗ࡞ࠍࠦࡇ࡯ߒߡ⊒⴫ᤨߦ૶↪ߔࠆ੍ቯߢߔ㧚ߥ߅㧘PDF ࡈࠔࠗ࡞ߩࡍ࡯ࠫㅍࠅߪቇ↢ળᆔຬ߇ᜂᒰߔࠆ੍ቯߢߔ㧚㩷٤ࡐࠬ࠲࡯ࡊ࡟࠯ࡦ࠹࡯࡚ࠪࡦ㧔PP㧕㩷࡮㩷 ࡐࠬ࠲࡯ࡄࡀ࡞ߩᄢ߈ߐߪ❑ 2100 mmᮮ 900 mm ߩ❑㐳ߢߔ㧚㩷ኻ⽎㧦 ડᬺ࡮ᄢቇ࡮⎇ⓥᚲ╬ߩᛛⴚ⠪࡮⎇ⓥ⠪ߢ㧘ᐔᚑ 21 ᐕ 3 ᦬ 31 ᣣ⃻࿷ߢ 28 ᱦએਅߩ⠪㧘߹ߚߪ㧘⻠Ṷ↳ㄟᒰᣣߦቇ↢ߢ޽ࠆ⠪㧔ߚߛߒ㧘␠ળੱᄢቇ㒮↢ࠍ㒰ߊ㧕㧚ᔕ൐ ⾗ ᩰ㧦 ⻠Ṷᤨ㧔㧩ክᩏᤨ㧕ߦ㧘ᣣᧄવᾲቇળߩળຬ㧔ᱜຬ࡮ቇ↢ຬ㧕㧘߹ߚߪ㧘౉ળ↳ㄟਛߢ޽ࠆߎߣ㧔෩቞㧕㧚ࠪࡦࡐࠫ࠙ࡓᒰᣣߩ౉ળ߽น⢻ߢߔ㧚ክᩏ࡮ㆬ⠨ᣇᴺ㧦 ⶄᢙฬߩክᩏຬߦࠃࠆ⹏ଔߦၮߠ޿ߡㆬ⠨ߒ㧘᝼⾨⠪ࠍ᳿ቯߒ߹ߔ㧚⴫ᓆ㧦 ⴫ᓆߪࠪࡦࡐࠫ࠙ࡓ╙ 2 ᣣߩᣣᧄવᾲቇળ✚ળߢⴕ޿߹ߔ㧚㧨ᦨᣂᖱႎߪࠪࡦࡐࠫ࠙ࡓߩࡎ࡯ࡓࡍ࡯ࠫߦ౏㐿ߒ߹ߔ㧪

વᾲ 2009 ᐕ 4 ᦬- 72 -J. HTSJ, Vol. 48, No. 203

߅⍮ࠄߖ

㧔೎ᷝ㧕
╙㪋㪍࿁ᣣᧄવᾲ䉲䊮䊘䉳䉡䊛䇼੩ㇺ䇽䋶᦬䋲ᣣ䋨Ἣ䋩䋺䋱ᣣ⋡
㪙㪈ቶ
㪙㪉ቶ
㪙㪈㪄㪈㪈
ᴣ㛛䋱
㪐㪑㪊㪇㪄㪈㪇㪑㪌㪇

㪙㪈㪄㪈㪉
ᴣ㛛㪉
㪈㪈㪑㪇㪇㪄㪈㪉㪑㪉㪇㪙㪉㪄㪈㪈Ⲣ⸃䊶ಝ࿕䋱
㪐㪑㪊㪇㪄㪈㪇㪑㪌㪇㪙㪉㪄㪈㪉Ⲣ⸃䊶ಝ࿕㪉
㪈㪈㪑㪇㪇㪄㪈㪉㪑㪇㪇

㪚㪈ቶ

㪚㪉ቶ

㪛ቶ

㪚㪈㪄㪈㪈
䈸䈒኿‛ᕈ䋱
㪐㪑㪊㪇㪄㪈㪇㪑㪌㪇

㪚㪉㪄㪈㪈
ྃᵹ
㪐㪑㪊㪇㪄㪈㪇㪑㪌㪇㪚㪈㪄㪈㪉䈸䈒኿‛ᕈ㪉
㪈㪈㪑㪇㪇㪄㪈㪉㪑㪉㪇

ఝ⑲䊒䊧䉷䊮
㪝㪄㪈㪉䊁䊷䉲䊢䊮⾨䋺㪚㪉㪄㪈㪉㪞㪄㪈㪉㔚႐䊶㔚⩄⒖䊘䉴䉺䊷䉶䉾
ੂᵹ㪈
‛⾰⒖േേਅ䈪䈱વᾲ
䉲䊢䊮㪈㪈㪈㪑㪇㪇㪄㪈㪉㪑㪉㪇㪈㪈㪑㪇㪇㪄㪈㪉㪑㪉㪇㪈㪈㪑㪇㪇㪄㪈㪉㪑㪉㪇㪈㪈㪑㪇㪇㪄㪈㪉㪑㪉㪇䊘䉴䉺䊷Ḱ஻
㪐㪑㪉㪇㪄㪐㪑㪌㪇㪝ቶ㪞ቶ㪐㪑㪌㪇㪄㪈㪇㪑㪌㪇㪐㪑㪌㪇㪄㪈㪇㪑㪌㪇

㪠ቶ

㪡ቶ
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⥄ὼኻᵹ䊶ⶄ
㪠㪄㪈㪈
㪞㪄㪈㪈
㪝㪄㪈㪈
วኻᵹ㪈
ఝ⑲䊒䊧䉷䊮䊁䊷䉲䊢 ఝ⑲䊒䊧䉷䊮䊁䊷䉲䊢 ಽሶേജቇ㪈㪐㪑㪊㪇㪄㪈㪇㪑㪊㪇䊮⾨䋺䉲䊢䊷䊃䊒䊧䉷 䊮⾨䋺䉲䊢䊷䊃䊒䊧䉷㪐㪑㪊㪇㪄㪈㪇㪑㪌㪇
䊮㪈
䊮㪉
㪡㪄㪈㪉
㪠㪄㪈㪉
⥄ὼኻᵹ䊶ⶄ
ಽሶേജቇ㪉
วኻᵹ㪉㪈㪈㪑㪇㪇㪄㪈㪉㪑㪇㪇㪈㪈㪑㪇㪇㪄㪈㪉㪑㪇㪇䊘䉴䉺䊷౉ᦧ
㪈㪉㪑㪉㪇㪄㪈㪊㪑㪌㪇

㪝㪄㪈㪊
㪙㪈㪄㪈㪊
ᴣ㛛㪊
㪈㪊㪑㪌㪇㪄㪈㪌㪑㪊㪇

㪙㪈㪄㪈㪋
ᴣ㛛㪋
㪈㪌㪑㪋㪇㪄㪈㪎㪑㪉㪇㪙㪉㪄㪈㪊෻ᔕ䊶Ά὾㪈
㪈㪊㪑㪌㪇㪄㪈㪌㪑㪊㪇㪙㪉㪄㪈㪋෻ᔕ䊶Ά὾㪉
㪈㪌㪑㪋㪇㪄㪈㪎㪑㪉㪇䋶᦬䋳ᣣ䋨᳓䋩䋺䋲ᣣ⋡
㪙㪈ቶ
㪙㪉ቶ
㪙㪈㪄㪉㪈
ᴣ㛛㪌
㪐㪑㪇㪇㪄㪈㪇㪑㪉㪇

㪚㪈㪄㪈㪊
ᒝ೙ኻᵹ㪈
㪈㪊㪑㪌㪇㪄㪈㪌㪑㪊㪇

㪚㪈㪄㪈㪋
ᒝ೙ኻᵹ㪉
㪈㪌㪑㪋㪇㪄㪈㪎㪑㪉㪇

㪚㪈ቶ

㪙㪉㪄㪉㪈
㪦㪪㪑㩷᳓⚛䉣䊈䊦䉩䊷ᛛⴚ㪈
㪐㪑㪇㪇㪄㪈㪇㪑㪉㪇

㪚㪈㪄㪉㪈
ᒝ೙ኻᵹ㪊
㪐㪑㪇㪇㪄㪈㪇㪑㪇㪇

㪚㪉㪄㪈㪊
ੂᵹ㪉
㪈㪊㪑㪌㪇㪄㪈㪌㪑㪊㪇㪚㪉㪄㪈㪋䊍䊷䊃䊘䊮䊒䊶ⓨ⺞㪈㪌㪑㪋㪇㪄㪈㪎㪑㪉㪇

㪚㪉ቶ

㪞㪄㪈㪊

ఝ⑲䊒䊧䉷䊮䊁䊷䉲䊢 ఝ⑲䊒䊧䉷䊮䊁䊷䉲䊢䊮⾨䋺䉲䊢䊷䊃䊒䊧䉷 䊮⾨䋺䉲䊢䊷䊃䊒䊧䉷䊮㪊䊮㪋㪈㪊㪑㪌㪇㪄㪈㪋㪑㪌㪇
ఝ⑲䊒䊧䉷䊮
䊁䊷䉲䊢䊮⾨䋺䊘䉴䉺䊷䉶䉾
䉲䊢䊮㪉㪈㪌㪑㪇㪇㪄㪈㪍㪑㪉㪇䊘䉴䉺䊷᠗෰
㪈㪍㪑㪉㪇㪄㪈㪎㪑㪉㪇㪝㪄㪈㪋↢↥䊶ടᎿ䊒
䊨䉶䉴㪈㪌㪑㪋㪇㪄㪈㪎㪑㪉㪇

㪞㪄㪈㪋
⫾ᾲ䊶⫾಄
㪈㪌㪑㪋㪇㪄㪈㪎㪑㪉㪇

㪝ቶ

㪞ቶ

㪛ቶ

㪚㪉㪄㪉㪈
㪦㪪㪑㩷䉣䊈䊦
㪛㪄㪉㪈䉩䊷ᄌ឵䉲䉴 䊙䉟䉪䊨વᾲ㪈䊁䊛㪈㪐㪑㪇㪇㪄㪈㪇㪑㪉㪇㪐㪑㪇㪇㪄㪈㪇㪑㪉㪇㪈㪊㪑㪌㪇㪄㪈㪋㪑㪌㪇

㪝㪄㪉㪈
ᾲ‛ᕈ㪈
㪐㪑㪇㪇㪄㪈㪇㪑㪉㪇㪞㪄㪉㪈䈸䈒኿વᾲ㪈
㪐㪑㪇㪇㪄㪈㪇㪑㪇㪇

䌊㪄㪈㪊
㪠㪄㪈㪊
⥄ὼኻᵹ䊶ⶄ
ಽሶേജቇ㪊
วኻᵹ㪊㪈㪊㪑㪌㪇㪄㪈㪌㪑㪊㪇㪈㪊㪑㪌㪇㪄㪈㪌㪑㪊㪇

㪠㪄㪈㪋
㪡㪄㪈㪋
ಽሶേജቇ㪋
㪈㪌㪑㪋㪇㪄㪈㪍㪑㪋㪇 ⥄ὼኻᵹ䊶ⶄวኻᵹ㪋㪈㪌㪑㪋㪇㪄㪈㪎㪑㪉㪇

㪠ቶ
㪠㪄㪉㪈
ᄙሹ⾰૕䈱
વᾲ㪈
㪐㪑㪇㪇㪄㪈㪇㪑㪇㪇

㪚㪉㪄㪉㪉
㪚㪈㪄㪉㪉
㪙㪉㪄㪉㪉
㪦㪪㪑㩷䉣䊈䊦
㪙㪈㪄㪉㪉
㪛㪄㪉㪉
㪝㪄㪉㪉
ᒝ೙ኻᵹ㪋
㪦㪪㪑㩷᳓⚛䉣䊈ੑ⋧ᵹ㪈䉩䊷ᄌ឵䉲䉴 䊙䉟䉪䊨વᾲ㪉ᾲ‛ᕈ㪉䊦䉩䊷ᛛⴚ㪉 㪈㪇㪑㪊㪇㪄㪈㪈㪑㪌㪇㪈㪇㪑㪊㪇㪄㪈㪉㪑㪈㪇䊁䊛㪉㪈㪇㪑㪊㪇㪄㪈㪉㪑㪈㪇 㪈㪇㪑㪊㪇㪄㪈㪉㪑㪈㪇㪈㪇㪑㪊㪇㪄㪈㪉㪑㪈㪇㪈㪇㪑㪊㪇㪄㪈㪉㪑㪈㪇㪞㪄㪉㪉䈸䈒኿વᾲ㪉
㪈㪇㪑㪊㪇㪄㪈㪉㪑㪈㪇

㪠㪄㪉㪉
ᄙሹ⾰૕䈱
વᾲ㪉
㪈㪇㪑㪊㪇㪄㪈㪉㪑㪈㪇

㪚㪉㪄㪉㪊
㪙㪉㪄㪉㪊
㪚㪈㪄㪉㪊
㪦㪪㪑㩷䉣䊈䊦
㪛㪄㪉㪊
㪝㪄㪉㪊
㪙㪈㪄㪉㪊
㪦㪪㪑㩷᳓⚛䉣䊈 ᾲᯏེ䊶ᾲ੤䉩䊷ᄌ឵䉲䉴 䊙䉟䉪䊨વᾲ㪊
ᾲ‛ᕈ㪊
ੑ⋧ᵹ㪉
䊦䉩䊷ᛛⴚ㪊
឵ེ㪈䊁䊛㪊㪈㪊㪑㪋㪇㪄㪈㪌㪑㪇㪇 㪈㪊㪑㪋㪇㪄㪈㪌㪑㪇㪇㪈㪊㪑㪋㪇㪄㪈㪌㪑㪇㪇㪈㪊㪑㪋㪇㪄㪈㪌㪑㪇㪇 㪈㪊㪑㪋㪇㪄㪈㪌㪑㪇㪇㪈㪊㪑㪋㪇㪄㪈㪌㪑㪇㪇㪞㪄㪉㪊䈸䈒኿વᾲ㪊
㪈㪊㪑㪋㪇㪄㪈㪌㪑㪇㪇

㪠㪄㪉㪊
ᄙሹ⾰૕䈱
વᾲ㪊
㪈㪊㪑㪋㪇㪄㪈㪌㪑㪇㪇

㪡ቶ
㪡㪄㪉㪈
⥄ὼ䉣䊈䊦
䉩䊷㪈
㪐㪑㪇㪇㪄㪈㪇㪑㪉㪇

㪡㪄㪉㪉
⥄ὼ䉣䊈䊦
䉩䊷㪉
㪈㪇㪑㪊㪇㪄㪈㪉㪑㪈㪇․೎⻠Ṷ䋨㪛ቶ䋩㵘੩ㇺᄢቇ㵘㐷ౝ㩷ノⴕ㩷ᢎ᝼㵘䇸ᱧผㇺᏒ䊶੩ㇺ䈱᥊ⷰ䊶ⅣႺ䈱ഃ↢䇹㪈㪌㪑㪈㪇㪄㪈㪍㪑㪈㪇✚ળ䋨㪛ቶ䋩㩷㪈㪍㪑㪉㪇㪄㪈㪎㪑㪋㪇ᙣⷫળ䋨䈘䈒䉌䋩㵘㪈㪏㪑㪇㪇㪄㪉㪇㪑㪇㪇વᾲ 2009 ᐕ 4 ᦬

- 73 -J. HTSJ, Vol. 48, No. 203

߅⍮ࠄߖ


䋶᦬䋴ᣣ䋨ᧁ䋩䋺䋳ᣣ⋡
㪙㪈ቶ
㪙㪉ቶ

㪚㪈ቶ

㪚㪉ቶ

㪛ቶ

㪝ቶ

㪞ቶ

㪠ቶ

㪡ቶ

㪙㪉㪄㪊㪈
㪚㪈㪄㪊㪈
㪦㪪㪑㩷᳓⚛䉣䊈 ᾲᯏེ䊶ᾲ੤䊦䉩䊷ᛛⴚ㪋
឵ེ㪉㪐㪑㪋㪇㪄㪈㪈㪑㪇㪇㪐㪑㪋㪇㪄㪈㪈㪑㪇㪇

䌆㪄㪊㪈
㪚㪉㪄㪊㪈
㪛㪄㪊㪈
㪦㪪㪑㩷㕖✢ᒻᾲ
㪞㪄㪊㪈
㪠㪄㪊㪈
㔚ሶᯏེ䈱
䊙䉟䉪䊨વᾲ㪋 ᵹ૕⃻⽎䈫વ 䊍䊷䊃䊌䉟䊒㪈 䊋䉟䉥વᾲ㪈಄ළ㪈㪐㪑㪋㪇㪄㪈㪈㪑㪇㪇ᾲ㪈㪐㪑㪋㪇㪄㪈㪈㪑㪇㪇㪐㪑㪋㪇㪄㪈㪈㪑㪇㪇㪐㪑㪋㪇㪄㪈㪈㪑㪇㪇㪐㪑㪋㪇㪄㪈㪈㪑㪇㪇

㪡㪄㪊㪈
⸘᷹ᛛⴚ㪈
㪐㪑㪋㪇㪄㪈㪈㪑㪇㪇

㪙㪉㪄㪊㪉
㪚㪈㪄㪊㪉
㪙㪈㪄㪊㪉
㪦㪪㪑㩷᳓⚛䉣䊈 ᾲᯏེ䊶ᾲ੤ಝ❗વᾲ䊦䉩䊷ᛛⴚ㪌
឵ེ㪊㪈㪈㪑㪈㪇㪄㪈㪉㪑㪈㪇㪈㪈㪑㪈㪇㪄㪈㪉㪑㪈㪇 㪈㪈㪑㪈㪇㪄㪈㪉㪑㪈㪇

㪝㪄㪊㪉
㪚㪉㪄㪊㪉
㪞㪄㪊㪉
㪠㪄㪊㪉
㪛㪄㪊㪉
㪦㪪㪑㩷㕖✢ᒻᾲ㔚ሶᯏེ䈱䊙䉟䉪䊨વᾲ㪌 ᵹ૕⃻⽎䈫વ 䊍䊷䊃䊌䉟䊒㪉 䊋䉟䉥વᾲ㪉಄ළ㪉ᾲ㪉㪈㪈㪑㪈㪇㪄㪈㪉㪑㪈㪇 㪈㪈㪑㪈㪇㪄㪈㪉㪑㪈㪇㪈㪈㪑㪈㪇㪄㪈㪉㪑㪈㪇㪈㪈㪑㪈㪇㪄㪈㪉㪑㪈㪇㪈㪈㪑㪈㪇㪄㪈㪉㪑㪈㪇

㪡㪄㪊㪉
⸘᷹ᛛⴚ㪉
㪈㪈㪑㪈㪇㪄㪈㪉㪑㪈㪇

㪙㪈㪄㪊㪊
㪙㪉㪄㪊㪊
㪚㪈㪄㪊㪊
⫳⊒વᾲ 㪦㪪㪑㩷᳓⚛䉣䊈 ᾲᯏེ䊶ᾲ੤㪈㪊㪑㪊㪇㪄㪈㪋㪑㪊㪇 䊦䉩䊷ᛛⴚ㪍឵ེ㪋㪈㪊㪑㪊㪇㪄㪈㪋㪑㪌㪇 㪈㪊㪑㪊㪇㪄㪈㪋㪑㪌㪇

㪚㪉㪄㪊㪊
㔚ሶᯏེ䈱
಄ළ㪊
㪈㪊㪑㪊㪇㪄㪈㪋㪑㪌㪇

㪠㪄㪊㪊
㪛㪄㪊㪊
㪝㪄㪊㪊
㪞㪄㪊㪊
䊋䉟䉥વᾲ㪊
ੑ⋧ᵹ䈱ᢙ ․ᱶⅣႺਅ䈪䊍䊷䊃䊌䉟䊒㪊 㪈㪊㪑㪊㪇㪄㪈㪋㪑㪊㪇୯⸃ᨆ䈱ኻᵹ㪈㪊㪑㪊㪇㪄㪈㪋㪑㪌㪇㪈㪊㪑㪊㪇㪄㪈㪋㪑㪌㪇 㪈㪊㪑㪊㪇㪄㪈㪋㪑㪌㪇

㪡㪄㪊㪊
⸘᷹ᛛⴚ㪊
㪈㪊㪑㪊㪇㪄㪈㪋㪑㪌㪇

㪙㪈㪄㪊㪈
ੑ⋧ᵹ㪊
㪐㪑㪋㪇㪄㪈㪈㪑㪇㪇






╙䋴䋶࿁ᣣᧄવᾲ䉲䊮䊘䉳䉡䊛䊒䊨䉫䊤䊛㩷䋨એਅ䈱䊒䊨䉫䊤䊛䈲 㪋㪆㪍 ᤨὐ䈪䈱ᥳቯ 䈪䈜䋮ᦨᣂ 䈲䊖䊷䊛䊕䊷䉳䈪䈗ⷩਅ䈘䈇䋮䋩㩷㵪㵪㵪㩷 ╙ 䋱ᣣ 㩷 䋶 ᦬ 䋲ᣣ 䋨Ἣ 䋩 㩷 㵪㵪㵪䋼㩷 䌂䋱ቶ㩷 䋾㩷㪙㪈㪄㪈㪈㩷 㩷 㪐䋺㪊㪇㵨㪈㪇䋺㪌㪇㩷 ᴣ㛛䋱㩷

B1-122 MEMSടᎿᛛⴚ䉕↪䈇䈩૞⵾䈚䈢ᓸ⚦᭴ㅧઃ䈐વᾲ㕙䈱ᴣ㛛․ᕈ*૒⮮ 㓉⊓䋨Ꮏቇ㒮ᄢ䋩䋬ዊᴰ ቟㇢䋨ାᎺᄢ䋩䋬ᄢ┻ᶈ㕏䋨Ꮏቇ㒮ᄢ䋩
B1-123 ⍴䈇ု⋥౞▤ౝ᳓䈱ᒝ೙ኻᵹ䉰䊑䉪䊷䊦ᴣ㛛ᾲવ㆐*⇌ ᐘ৻䋨੩ㇺᄢ䋩䋬Ⴧፒ ⾆䋨ᩭⲢว⎇䋩
B1-124 䊚䊆䊶䊙䉟䉪䊨䉼䊞䊮䊈䊦䈮䈍䈔䉎᳇ᵃᓸ⚦ൻᴣ㛛
*㊁᧛ ⍮ᔒ䋨᧲੩ℂᄢ䋩䋬㋈ᧁ ᐽ৻䋬ᵩ ቯ᧜⤑ᴣ㛛⫳᳇⤑፣უㆊ⒟䈮෸䈿䈜䊅䊉☸ሶ Ộ䈱ᓇ㗀*ᣂ੗ ፏᵗ䋨㔚ਛ⎇䋩䋬ฎ⼱ ᱜ⵨
B1-112 㜞᷷ㆊᾲ㕙䈱Ứ䉏㐿ᆎᯏ᭴䈮㑐䈜䉎⎇ⓥᄢ┻ ᶈ㕏䋨Ꮏቇ㒮ᄢ䋩䋬*ዊᨋ ⌀ᖗ䋬ዊᴰ ቟㇢䋨ାᎺᄢ䋩䋬᳗᎒ ᦸ䋨Ꮏቇ㒮ᄢ䋩
B1-113 ᦭㒢ု⋥౞ᩇ䉁䉒䉍䈱⤑ᴣ㛛ᾲવ㆐䋨╙1ႎ䋺ඨ⃿⁁㪙㪈㪄㪈㪊㩷 㩷 㪈㪊䋺㪌㪇㵨㪈㪌䋺㪊㪇㩷 ᴣ㛛䋳㩷䈱ಲᐩ㕙䈱႐ว䋩*ጊ↰ 䈢䈎䈚䋨㐳ፒᄢ䋩䋬⼾↰ 㚅䋬⨃࿾ ᔀ䋬᩶ᧁ ᖗ䋬
B1-131 ᳓䈱䉰䊑䉪䊷䊦䊒䊷䊦ᴣ㛛䈮䈍䈔䉎᳇ᵃ䈱᜼േጊญ ᦺᒾ䋬㊄ਣ ㇌ᐽ*ේ᧛ ཅᒾ䋨␹ᄹᎹᄢ䋩䋬Ἇᧄ ⋥ノ
B1-114 ᦭㒢ု⋥౞ᩇ䉁䉒䉍䈱⤑ᴣ㛛ᾲવ㆐䋨╙2ႎ䋺ᐩ㕙ᒻ
B1-132䊑䉺䊉䊷䊦᳓ṁᶧ䈱㒢⇇ᾲᵹ᧤䈮㑐䈜䉎⎇ⓥ⁁䈱ᓇ㗀䋩*⷏ญ ᣹ᄥᦶ䋨␹ᄹᎹᄢ䋩䋬᪢ᵤ ቁమ䋬ਭ㊁ ஜᄥ䋬*᩶ᧁ ᖗ䋨㐳ፒᄢ䋩䋬⼾↰ 㚅䋬ጊ↰ 䈢䈎䈚䋬⨃࿾ ᔀ䋬ችᧄ┥⍫䋬ᐣม ᱜᒄጊญ ᦺᒾ䋬㊄ਣ ㇌ᐽ
B1-133 ᳓ᐔ⚦✢䈱䊒䊷䊦㘻๺ᴣ㛛㒢⇇ᾲᵹ᧤䈱✢ᓘଐሽᕈ㪙㪈㪄㪈㪉㩷 㩷 㪈㪈䋺㪇㪇㵨㪈㪉䋺㪉㪇㩷 ᴣ㛛䋲㩷*ጊᧄ ජඳ䋨␹ᄹᎹᄢ䋩䋬↰ਛ ᷕᐔ䋬የᒻ ⺈䋬቟⮮
B1-121 ᓸዊᵹ〝䈍䉋䈶᳓ᐔᐔ᧼⁜㑆㓗ౝᴣ㛛ᾲવ㆐䈮㑐లᵗ䋬㜞ጊ ᥓ᣿䋬ᐣม ᱜᒄ䈜䉎⎇ⓥ
B1-134 ടᾲᭂ⚦✢䈱᳓䈱䉰䊑䉪䊷䊦ᴣ㛛䈫♽࿶ജ䈱ᓇ㗀ዊᴰ ቟㇢䋨ାᎺᄢ䋩䋬ᄢ┻ ᶈ㕏䋨Ꮏቇ㒮ᄢ䋩䋬*᛼Ꮉ䋨⛯ႎ䋩㓉᣽*ᐣม ᱜᒄ 䋨␹ᄹᎹᄢ䋩䋬ᩊ↰ ቬቁ䋬㐷㑆 మ⹷䋬

B1-111

વᾲ 2009 ᐕ 4 ᦬- 74 -J. HTSJ, Vol. 48, No. 203߅⍮ࠄߖ㜞ጊ ၮ༹䋬⇌ጊ ᘮテ
B1-135 ᩭᴣ㛛ᾲવ㆐ᯏ᭴⸃᣿䈱䈢䉄䈱ᓸዊ㊀ജታ㛎*ዊ⼱ ఝ੺䋨਻Ꮊᄢ䋩䋬ᴡධ ᴦ䋨౓ᐶ⋵ᄢ䋩䋬ဈ↰ᶻਫ䋬ᵻ↰ ᦭㚅䋬᳗቟ ᔘ䋬ᣂᧄ ᐽਭ䋬ᄢ↰ ᴦᒾ䋬૒⮮ ᵗ৻䋨JAXA䋩䋬䉥䊧䉫 䉦䊗䊐䋨䊑䊥䊠䉾䉶䊦⥄↱ᄢ䋩䋬䉪䉾䉦䊷䉴 䊌䊃䊥䉾䉪䋬䉶䊦䉭䉟 䉼䉮䊐㪙㪈㪄㪈㪋㩷 㩷 㪈㪌䋺㪋㪇㵨㪈㪎䋺㪉㪇㩷 ᴣ㛛䋴㩷
B1-141 2ᚑಽᷙว᳓ṁᶧ䈱ᴣ㛛䈮䈍䈔䉎વᾲ㕙ㄭற䈱᳇ᶧ᭴ㅧ*ဈਅ ᒄੱ䋨ർᶏ㆏ᄢ䋩䋬ዊ㊁ ✍ሶ
B1-142 Pool Boiling Heat Transfer Characteristic of Binary
Refrigerant Mixture R11-R113*Yanhua Diao䋨Beijing Univ. Tech.䋩䋬Yaohua Zhao
B1-143 㘻๺䊒䊷䊦ᴣ㛛♽䈮䈍䈔䉎ੑᚑಽᷙวᶧ䈱ᩭᴣ㛛ᾲવ㆐䈮㑐䈜䉎⎇ⓥ*ᓟ⮮ ᵏ⵨䋨⨙ၔᄢ䋩䋬␹᳗ ᢥੱ䋬᧻᧛ ㇌ੳ
B1-144 ੑᚑಽᷙวᇦ૕䈱䊒䊷䊦ᩭᴣ㛛䈮䈍䈔䉎વᾲഠൻ䈫વᾲଦㅴ䈮㑐䈜䉎⎇ⓥ*⧐੗ ᤯૞䋨਻Ꮊᄢ䋩䋬㈬੗ ፏ䋬᦬ᚑ ാ⿠䋬᫃ᧄ๺೑䋬ᣂᧄ ᐽਭ䋬ᄢ↰ ᴦᒾ
B1-145 ੑᚑಽ♽᳓ṁᶧ䈱ᴣ㛛䈮઻䈉ਃ⋧⇇✢ㄭற䈮⊒⃻䈜䉎䊙䊤䊮䉯䊆ᵹ䈱⸃᣿*㒠☌ ஜม䋨䊂䊮䉸䊷䋩䋬㡞ᔒ↰ 㓳ม䋨⦼ᶆᎿᄢ䋩䋬ᐣม ᱜᒄ䋨␹ᄹᎹᄢ䋩䋬Ꮉญ 㕏ᄦ䋨᧲੩ℂᄢ䋩㩷䋼㩷 䌂䋲ቶ㩷 䋾㩷㪙㪉㪄㪈㪈㩷 㩷 㪐䋺㪊㪇㵨㪈㪇䋺㪌㪇㩷 Ⲣ⸃䊶ಝ࿕䋱㩷⋥ធធ⸅ᾲ੤឵䈮䈍䈔䉎ẜᾲ⫾ᾲ㊂䈱⿥㖸ᵄශട䈮䉋䉎ᓇ㗀᫪↰ ᘕ৻䋨☨ሶ㜞ኾ䋩䋬*㊄↰ ᓆᦶ䋬ᣧ᳓ ᐾ㓉
B2-112 ᳖䈱Ⲣ⸃䉕೑↪䈚䈢䊒䊨䊌䊮䊊䉟䊄䊧䊷䊃䈱↢ᚑଦㅴ䈮㑐䈜䉎⎇ⓥ䋨᳖-䊒䊨䊌䊮⇇㕙䈮䈍䈔䉎䊊䉟䊄䊧䊷䊃䈱↢ᚑ᜼േ䋩*ᵻጟ 㦖ᓼ䋨㕍ጊቇ㒮ᄢ䋩䋬ጟ↰ ᣽ᔒ䋬ዊ㊁ ᱜ༹
B2-113 䉪䊤䉴䊧䊷䊃᳓๺‛↢ᚑ䈮෸䈿䈜⇇㕙ᵴᕈ೷䈱ലᨐ䋨䊜䉺䊮+䉣䉺䊮+䊒䊨䊌䊮ᷙว䉧䉴䈎䉌䈱᳓๺‛↢ᚑ䈮䈧䈇䈩䋩᪀ේ ໑䋨ᘮᙥᄢ䋩䋬*቟᧲ ⋥Პ䋬᫪ ᐽᒾ
B2-114 ⇹᳓ᕈ಄ළᶧ䈏ṡ಴䈜䉎ᄙሹ⾰㕙਄䈻䈱᳓ྃ㔵䈮䉋䉎䊜䉺䊮᳓๺‛↢ᚑ*⮮↰ ⌀਽䋨ᘮᙥᄢ䋩䋬⧎↰ ⚐৻㇢䋬᫪ ᐽᒾ

B2-111㪙㪉㪄㪈㪉㩷 㩷 㪈㪈䋺㪇㪇㵨㪈㪉㪑㪇㪇㩷 Ⲣ⸃䊶ಝ࿕䋲㩷
B2-121 2ᚑಽ♽᳓ṁᶧਛ䈮䈍䈔䉎࿁ォ᳓ᐔ᳖౞ᩇ䈱Ⲣ⸃*ዊ᧻ ༑⟤䋨⑺↰ᄢ䋩䋬⩲ේ ᓕᵗ䋬ਭ଻ ᷕม䋬⮮↰ᔘ
B2-122 ੑᰴరPhase Field Method䉕↪䈇䈢᳓䈱৻ᣇะಝ࿕
䈮㑐䈜䉎ᢙ୯⸃ᨆ
*┙↰ ஜੱ䋨੩ㇺᎿ❫ᄢ䋩䋬ᰞ੗ ੫ 䋨ን჻ㅢ䋩䋬⪤ේ ⦟㆏䋨੩ㇺᎿ❫ᄢ䋩
B2-123 ᳓ṁᶧಓ⚿ᤨ䈱಄ළო㕙਄䈮ᒻᚑ䈘䉏䉎᳖⚿᥏䈫⚿᥏ᣇะᄌൻ⃻⽎*ၳ 㜞⹹䋨ਛᄩᄢ䋩䋬ኹጟ ༑๺䋬᧻ᧄ ᶈੑ䋬␹ፒ

વᾲ 2009 ᐕ 4 ᦬⵨਽䋨䊟䊙䊊⊒േᯏ䋩㪙㪉㪄㪈㪊㩷 㩷 㪈㪊䋺㪌㪇㵨㪈㪌䋺㪊㪇㩷 ෻ᔕ䊶Ά὾䋱㩷
B2-131 ᄙἻሹ䊋䊷䊅䈱ⓨ᳇ട⛎᦭ή䈮䉋䉎ടᾲല₸䈻䈱ᓇ㗀᫪↰ ᘕ৻䋨☨ሶ㜞ኾ䋩䋬*㣔㊁ ዁ᄢ䋬ᣧ᳓ ᐾ㓉
B2-132 ო᷷䉕೙ᓮ䈚䈢⿥⭯ဳ⍹⧷䉼䊞䊈䊦䈮䈍䈔䉎ᝄേἫἻ䈮㑐䈜䉎⎇ⓥ*⨄ ാ䋨᧲੩ᄢ䋩䋬㋈ᧁ 㓶ੑ䋬═ᧁ િ⧷
B2-133 ᷷ᐲಽᏓ೙ᓮဳ䊙䉟䉪䊨䊐䊨䊷䊥䉝䉪䉺䈮䉋䉎n-䊓䊒䉺䊮/ⓨ᳇ᷙว᳇䈱Ά὾*ጊᧄ ᤩ䋨᧲ർᄢ䋩䋬᛼ㇱ ᵗ䋬ਛ᧛ ኼ䋬㐳⼱Ꮉ ㅴ䋬ᚻႦ ථ਽䋬ਣ↰ ⮍B2-134 㜞᷷㜞࿶᳓ਛ䈱䊜䉺䊉䊷䊦㉄ൻ෻ᔕ䈮䈍䈔䉎෻ᔕᾲ䈱࿶ജଐሽᕈ*ㄞᧄ ೰䋨ᐢፉᄢ䋩䋬᧻᧛ ᐘᒾ
B2-135 ᳓ਛ䊒䊤䉵䊙䈮䉋䉎᳇ᵃ⊒↢᭽ᑼ䈫ᾲ෼ᡰ*ะ═ ᔋ䋨ᗲᇫᄢ䋩䋬೨ේ Ᏹᒄ䋬㊁᧛ ା⑔䋬⼾↰ᵗㅢ䋬᦯ㇱ ศᤩ䋬ਃቛ ብᐘ㪙㪉㪄㪈㪋㩷 㩷 㪈㪌䋺㪋㪇㵨㪈㪎䋺㪉㪇㩷 ෻ᔕ䊶Ά὾䋲㩷
B2-141 ᄢⷙᮨ᷵᭴ㅧ䈱ᠲ૞䈮䉋䉎ᣓ࿁หゲྃᵹᷙว䈱⢻േ೙ᓮ*㥲ᧁ ᖘ䋨᧲੩ᄢ䋩䋬㋈ᧁ 㓶ੑ䋬═ᧁ િ⧷
B2-142 DNS䈮䉋䉎HCCI䉣䊮䉳䊮ౝੂᵹΆ὾ᯏ᭴䈱⸃᣿⑔ᧄ ᶈ┨䋨᧲੩Ꮏᄢ䋩䋬*ἑየ ஜᒾ䋬ᐫᯅ ⼔䋬ችౝ
ᢅ㓶
B2-143 ᣓ࿁ᵹ䉕઻䈉Ꮧ⭯੍ᷙวἫἻ䈱䉦䉥䉴․ᕈ
*ᣂᧁᧄ ኡਯ䋨┙๮㙚ᄢ䋩䋬ᓟ⮮↰ ᶈ䋬ች㊁ ዏ຦
B2-144 ᵄ㐳ᄌ⺞ಽశᴺ䉕↪䈇䈢Ά὾೙ᓮ↪ඨዉ૕䊧䊷䉱ๆ෼ಽశ䉶䊮䉰䊷*ᔒ᧛ ␭ᐽ䋨᧲੩Ꮏᄢ䋩䋬ἑየ ஜᒾ䋬ᐫᯅ ⼔䋬ችౝ
ᢅ㓶
B2-145 䊏䊨䊷䊦ဳ⓸⚛䈎䉌䈱Fuel NO↢ᚑᯏ᭴䈮䈍䈔䉎෻ᔕേജቇ⊛ᬌ⸛*᪀ේ ථ਽䋨਻Ꮊᄢ䋩䋬ጊᧄ ೰䋬ᷓ੗ Ả䋼㩷 㪚䋱ቶ㩷 䋾㩷㪚㪈㪄㪈㪈㩷 㩷 㪐䋺㪊㪇㵨㪈㪇䋺㪌㪇㩷 䈸䈒኿‛ᕈ䋱㩷ᣣ኿෻኿Ⴃᢱ䈱෻኿₸᷹ቯ䈫䈠䈱⹏ଔ*ᐔỈ ⦟↵䋨ንጊᄢ䋩䋬ਃᶆ ⵨ੱ䋬ᷡ᳓ ቁᢥ
C1-112 ㊄ዻⵍ⤑䉲䊥䉮䊮䊙䉟䉪䊨䉨䊞䊎䊁䉞䈱䈸䈒኿䉴䊕䉪䊃䊦䈮ኻ䈜䉎⴫㕙☻䈘䈱ᓇ㗀*ಾᦧ ᄢༀ䋨᧲੩ᄢ䋩䋬㋈ᧁ 㓶ੑ䋬═ᧁ િ⧷
C1-113 㜞᷷䉶䊤䊚䉾䉪䉴䈱᡼኿₸⋥ធ᷹ቯ*ᾢ㊁ ᥓਯ䋨␹ᚭᏒ㜞ኾ䋩
C1-114 ቶ᷷䈱⴫㕙䈱ోඨ⃿᡼኿₸᷹ቯེ䈱㐿⊒⧯ᨋ ⧷ା䋨੩ㇺᄢ䋩䋬૒⮮ ໪ᄥ䋬*ජ↰ ዏਯ䋬’㊁ବ㇢

C1-111㪚㪈㪄㪈㪉㩷 㩷 㪈㪈䋺㪇㪇㵨㪈㪉䋺㪉㪇㩷 䈸䈒኿‛ᕈ䋲㩷
C1-121 Comparison of Spectral Radiative Properties ofDifferent Titanium Dioxide Powders in Absorbing
Host Medium- 75 -J. HTSJ, Vol. 48, No. 203

߅⍮ࠄߖ*Mehdi Baneshi䋨Tohoku Univ.䋩䋬Shigenao Maruyama,*೨↰ ⑲೰䋨ᄢ㒋ᄢ䋩䋬ᱞ⍹ ⾫৻㇢䋬ዊ↰ ⼾䋬ศ↰
Atsuki Komiya⋥᮸C1-122 䋵▵ὐ᦭㒢ⷐ⚛䉕↪䈇䈢㔚⏛ᵄേ⸃ᨆ䈮䉋䉎⭯⤑♽ C2-112 䉲䉢䉟䊒䊃䊐䉞䊦䊛಄ළሹ䈱ᷙว⃻⽎䈮㑐䈜䉎⎇ⓥ
䈮䉋䉍᡼኿䈘䉏䉎ᾲ䈸䈒኿⠀↰ ື䋨ᄢ㒋ᄢ䋩䋬*᫪ ⠍ᐔ䋬ᱞ⍹ ⾫৻㇢䋬ዊችጊጊ↰ ⚐䋨⦼ᶆᎿᄢ䋩䋬*᳗੗ ┥ੑᱜᴦ䋬ዊ↰ ⼾C1-123 㜞᷷ⅣႺਅ䈮䈍䈔䉎Ni䈫Pd䈱ᾲ䈸䈒኿䉴䊕䉪䊃䊦⃻⽎ C2-113 䉥䊥䊐䉞䉴ྃᵹ䈱ⴣ⓭ᾲવ㆐䈮㑐䈜䉎೙ᓮ*⧯ᨋ㩷 ⧷ା䋨੩ㇺᄢ䋩䋬૒⮮㩷 ໪ᄥ䋬’㊁㩷 ବ㇢㩷*㊄᫪ ᪧ䋨ਃ⪉㊀Ꮏ䋩䋬ᯫ๺↰ ቬᒾ䋨ጘ㒂ᄢ䋩䋬ਃ᧻
C1-124 ⍹὇䉼䊞䊷ⶄว☸ሶ⟲䈱ユ኿․ᕈ
㗅ᴦ䋬ⷫᎹ ౗ാ䋨℄⃿ᄢ䋩*㜞ဈ ᢥ຦䋨ฬฎደᄢ䋩䋬ዊᨋ ା੺䋬⠀ᄙ㊁ ㊀ା䋬 C2-114 ኒᐲᚑጀᵹ૕ਛ䉕㋦⋥⒖േ䈜䉎⃿䈱ᓟᵹ䉳䉢䉾䊃↰ㆻ 㕏ඳ䋬᧼⼱ ⟵♿
*ጟ᧛ ᔀ䋨੩ㇺᄢ䋩䋬✜ᣇ ᱜᐢ䋬⧎ፒ ⑲ผ㪚㪈㪄㪈㪊㩷 㩷 㪈㪊䋺㪌㪇㵨㪈㪌䋺㪊㪇㩷 ᒝ೙ኻᵹ䋱㩷㪚㪉㪄㪈㪉㩷 㩷 㪈㪈䋺㪇㪇㵨㪈㪉䋺㪉㪇㩷 ੂᵹ䋱㩷

C1-131 䊚䊥䉴䉬䊷䊦ᵹ〝䈮⊒㆐䈜䉎᷷ᐲႺ⇇ጀ䈱᷷ᐲ᷹ቯ䋨ੑ䈧䈱ო㕙䉕ടᾲ䈜䉎႐ว䋩*ਛᎹ ᩕ৻䋨หᔒ␠ᄢ䋩䋬ᚑ↰ 㓶ᄢ䋬Ⓑጟ ᕶੑ䋬ජ↰ ⴤ
C1-132 ዮᦛဳಾᰳ䈐䊐䉞䊮ઃ⸳ᵹ〝ౝ䈱ᾲᵹേ․ᕈ
*Ꮟ ๺਽䋨੩ㇺᄢ䋩䋬᧻ፒ ᘕᄥᦶ䋬᧛↰ ㆐຦䋬ਛㇱਥᢘ
C1-133 ౝ஥ო㕙䈏࿁ォ䈜䉎Ⅳ⁁ᦛ㕙᜛ᄢᵹ〝ౝᵹ䉏䈮䈍䈔䉎ᵹ〝ᒻ⁁䈱ᓇ㗀*ᳰ⼱ ᜏᏈ䋨᧲੩ㄘᎿᄢ䋩䋬᧛↰ ┨䋬㥲⮮ ඳผ䋬ጤ
ᧄ ⮍C1-134 䉻䉪䊃ౝ䊋䉾䉪䉴䊁䉾䊒ᵹ䉏䈱ᵹേ᭴ㅧ䈫ᾲવ㆐․ᕈ
*Ꮍጊ 㗉ᢥ䋨หᔒ␠ᄢ䋩䋬⷏੗ ศિ䋬Ⓑጟ ᕶੑ䋬ජ↰ ⴤ
C1-135 ⿥⥃⇇࿶᳓䉕↪䈇䈢න৻ᮨᡆΆᢱ᫔䊍䊷䉺๟䉍䈱ᾲવ㆐ታ㛎*㑐 ᵗᴦ䋨ේሶജᯏ᭴䋩䋬ᳯ㉿ ᐘ৻㇢䋬㋈ᧁ ື䋬᭑ᨑ ᐙ↵䋬ᄢᭉ ᱜᐘ

C2-121 MHD䉼䊞䊮䊈䊦ੂᵹ႐䈮䈍䈔䉎㜞䊒䊤䊮䊃䊦ᢙᾲવ㆐․ᕈ
*ጊᧄ ⟵ᥰ䋨੩ㇺᄢ䋩䋬ഞಷ ⾗ᓆ
C2-122 ടᾲ䈘䉏䈢䋲ᰴరਐ䈱ᾲャㅍ䈮෸䈿䈜਄ᵹ䈱ੂᵹႺ⇇ጀ䈱ᓇ㗀*଻ᶆ ⍮਽䋨ฬฎደᎿᄢ䋩䋬⨲㊁ ᢥᒾ䋬↰Ꮉ ᱜੱ䋬
㐳㊁ 㕏ዏ
C2-123 䊥䊑ઃ䈐ㅘㆊᕈო㕙ᵹ䉏䈱PIV⸘᷹*ን᳗ ⡡䋨ᄢ㒋ᐭᄢ䋩䋬᧻᧛ ᐽᒄ䋬㊄↰ ᣽ਯ䋬㗇⾐৻ᒾ
C2-124 ⿥㖸ㅦ䊉䉵䊦ო㕙᷷ᐲ੍᷹ᣇᴺ䈱ᬌ⸛*੉⼱ 㓶᮸䋨IHI䋩䋬੹੗ ⦟ੑ䋬⍹Ꮉ ᐽᒄ䋬᫪ ೋ↵㪚㪈㪄㪈㪋㩷 㩷 㪈㪌䋺㪋㪇㵨㪈㪎䋺㪉㪇㩷 ᒝ೙ኻᵹ䋲㩷
C1-141 䉧䉴䉺䊷䊎䊮⠢䊐䉞䊦䊛಄ළ䈮䈍䈔䉎಄ළ᳇⋧䊚䉴䊃ᷝട䈮㑐䈜䉎ၮ␆⎇ⓥ*㢬↰ ๺ቁ䋨Ꮏቇ㒮ᄢ䋩䋬ᄢ┻ ᶈ㕏䋬ዊᴰ ቟㇢䋨ାᎺᄢ䋩
C1-142 ௑ᢳ䊏䊮䊐䉞䊮䉕↪䈇䈢ᵹ〝䈱ᾲવ㆐․ᕈ
*ᆎ↰ ␭テ䋨ᄢ㒋ᄢ䋩䋬ᱞ⍹ ⾫৻㇢䋬ዊ↰ ⼾䋬ਃቛᘮ᣿䋨ਃ⪉㊀Ꮏ䋩C1-143 ㆊᷰᔕ╵ᴺ䉕↪䈇䈢䊁䉞䉝䊄䊨䉾䊒ᒻ⁁䊂䉞䊮䊒䊦㕙䈱ੂᵹᾲવ㆐₸⸘᷹*⷏↰ ᕀ⟤䋨᧲੩ㄘᎿᄢ䋩䋬᧛↰ ┨䋬㥲⮮ ඳผ䋬ጤ
ᧄ ⮍C1-144 ਃⷺ㍙ဳ᷵⊒↢૕䈮䉋䉎䊏䊮䊐䉞䊮಄ළㅢ〝䈱વᾲଦㅴ*᫪ፒ ື㇢䋨ᣣ┙⵾૞ᚲ䋩䋬ၳౝ ᐽᐢ䋬↰Ꮉ ਭੱ
C1-145 ኻ⒓⠢೨✼䈱⠢┵ㇱ䈮↢䈛䉎㚍か᷵䈮䉋䉎ੂᵹᾲવ㆐䈱LES*ዊ↰ ⼾䋨ᄢ㒋ᄢ䋩䋬ᱞ⍹ ⾫৻㇢䋬⠀↰ ື䋬ᔶ↰ᚑൟ䋼㩷 㪚䋲ቶ㩷 䋾㩷㪚㪉㪄㪈㪈㩷 㩷 㪐䋺㪊㪇㵨㪈㪇䋺㪌㪇㩷 ྃᵹ㩷
C2-111䉪䊨䉴䊐䊨䊷䈏ᄙሹⴣ⓭ྃᵹવᾲ䈮෸䈿䈜ᓇ㗀䈮㑐䈜䉎⎇ⓥ

વᾲ 2009 ᐕ 4 ᦬㪚㪉㪄㪈㪊㩷 㩷 㪈㪊䋺㪌㪇㵨㪈㪌䋺㪊㪇㩷 ੂᵹ䋲㩷
C2-131 ੂᵹྃᵹἫἻ䈮䈍䈔䉎ዪᚲἫἻⷐ⚛䈱䉻䉟䊅䊚䉪䉴*ጊ⣁ ቁ᣿䋨᧲੩Ꮏᄢ䋩䋬ἑየ ஜᒾ䋬ᐫᯅ ⼔䋬ችౝᢅ㓶
C2-132 ㆫ⒖䊧䉟䊉䊦䉵ᢙၞ䈱ᐔⴕᐔ᧼㑆ᵹ䉏䈮䈍䈔䉎ੂᵹᾲવ㆐䈱DNS䋨╙3ႎ䋺䊘䉝䉵䉟䊡ᵹ䈫䉪䉣䉾䊃ᵹ䈮䈍䈔䉎ੂᵹ❋䈱Ყセ䋩*Ⴆේ 㓉⵨䋨᧲੩ℂᄢ䋩䋬Ꮉญ 㕏ᄦ䋬ᴡ᧛ ᵗ䋨⺪⸰᧲੩ℂᄢ䋩C2-133 ᷷ᐲᚑጀੂᵹႺ⇇ጀ䈮䈍䈔䉎Ớᐲ᜛ᢔ႐䈱DNS*᦯ㇱ ඳᢥ䋨ฬฎደᎿᄢ䋩䋬ጊፒ ⡛䋬↰Ꮉ ᱜੱ䋬㐳㊁ 㕏ዏC2-134 ૐ䊶ਛ䊒䊤䊮䊃䊦ᢙ䈱ᐔⴕᐔ᧼㑆ੂᵹᾲવ㆐䈱DNS
䊂䊷䉺䊔䊷䉴䉕↪䈇䈢ੂᵹ䊒䊤䊮䊃䊦ᢙ䈱⸃ᨆ*㒙ㇱ ᶈᐘ䋨JAXA䋩
C2-135 ⍱ᒻḴㇱ䉕᦭䈜䉎䉼䊞䊈䊦ᵹ䈱ᢙ୯⸃ᨆ*ᄢፉ ⵨ผ䋨ർᶏ㆏ᄢ䋩䋬㤥↰ ᣿ᘏ㪚㪉㪄㪈㪋㩷 㩷 㪈㪌䋺㪋㪇㵨㪈㪎䋺㪉㪇㩷 䊍䊷䊃䊘䊮䊒䊶ⓨ⺞㩷C2-141 䊊䉟䊑䊥䉾䊄䊂䉲䉦䊮䊃ⓨ⺞↪䊂䉲䉦䊮䊃䈱ๆ⣕⌕․ᕈ*ർ᧛ ᒄㅢ䋨᧲੩Ꮏᄢ䋩䋬૒⮮ ൟ䋬ᢧ⮮ ථᔒ䋬Ꮉญ㆐਽䋬ᨰᧁ ቁᄦC2-142 ᦭ᯏ♽෼⌕೷䊨䊷䉺䊷䈻䈱ಣℂⓨ᳇ੑ㊀ㅢ㘑䈮䈍䈔䉎㒰Ḩ․ᕈ
*㜞ᧁ ⽵↵䋨ጟጊᄢ䋩䋬ၳㇱ ᣿ᒾ䋬Ⓑ⪲ ⧷↵䋨ᵤጊ㜞ኾ䋩䋬ᤐᧁ ⋥ੱ䋨ጟጊᄢ䋩
C2-143 ᦭ᯏ♽෼⌕೷䉕ႣᏓ䈚䈢ᾲ੤឵ེ䈱ᒝ೙ኻᵹਅ䈮䈍䈔䉎෼⌕᜼േၳㇱ ᣿ᒾ䋨ጟጊᄢ䋩䋬Ⓑ⪲ ⧷↵䋨ᵤጊ㜞ኾ䋩䋬ᤐᧁ⋥ੱ䋨ጟጊᄢ䋩䋬*⩲ ᄢテ- 76 -J. HTSJ, Vol. 48, No. 203

߅⍮ࠄߖ
C2-144 R-290䈱᳓ᐔ⚦▤ౝᴣ㛛ᾲવ㆐䈮ኻ䈜䉎ẢṖᴤ䈱ᓇ㗀*ᢪ⮮ 㕒㓶䋨᧲੩ᄢ䋩䋬↰ਛ ජᱦ䋬ౄ ⿥㍋䋬㘧ේ⧷ᴦ
C2-145 䊐䉞䊮䉦䊤䊷ᒻ⁁䈏ធ⸅ᾲᛶ᛫䈮෸䈿䈜ᓇ㗀*᧻የ ฀⟤䋨૒⾐ᄢ䋩䋬ᬞ ⠹ᄥ㇢䋬ች⦟ ᣿↵

F-1113F-1114䋼㩷 㪛 ቶ㩷 䋾㩷㪈㪈䋺㪇㪇㵨㪈㪉䋺㪉㪇㩷 ఝ⑲䊒䊧䉷䊮䊁䊷䉲䊢䊮⾨䋺䊘䉴䉺䊷䉶䉾䉲䊢䊮䋱㩷㩷㪈㪌䋺㪇㪇㵨㪈㪍䋺㪉㪇㩷 ఝ⑲䊒䊧䉷䊮䊁䊷䉲䊢䊮⾨䋺䊘䉴䉺䊷䉶䉾䉲䊢䊮䋲㩷㪝㪄㪈㪉㩷 㩷䋼㩷 㪝 ቶ㩷 䋾㩷

F-121䌆㪄㪈㪈㩷 㩷 㪐䋺㪌㪇㵨㪈㪇䋺㪌㪇㩷 ఝ⑲䊒䊧䉷䊮䊁䊷䉲䊢䊮⾨䋺䉲䊢䊷䊃䊒䊧䉷䊮䊁䊷䉲䊢䊮䋱㩷

F-122

F-1101F-1102F-1103F-1104F-1105F-1106F-1107F-1108F-1109F-1110F-1111F-1112䉺䊷䊎䊮⠢೨✼ᒻ⁁䈏┵ო㕙਄䈱ᾲવ㆐䈮෸䈿䈜ᓇ㗀*ἑญ ᷕ৻䋨ᄢ㒋ᄢ䋩䋬⠀↰ ື䋬ᱞ⍹ ⾫৻㇢䋬ᔶ↰ᚑൟ⳱േㆇേဳ䊘䊮䊒䈱ᾲᵹേ․ᕈ䈮㑐䈜䉎ᢙ୯⸃ᨆ䋨╙3ႎ䋩*㤥ᧁ ㆯ䋨੩ㇺᄢ䋩䋬Ꮟ ๺਽䋬ਛㇱ ਥᢘౣጀᵹൻㆊ⒟䈮䈅䉎䊘䉝䉵䉟䊡ੂᵹ䈱㕖ኻ⒓ᕈ䈫䉣䊈䊦䉩䊷ャㅍ*⑔⇐ ഞੑ䋨ฬฎደᎿᄢ䋩䋬㘵↰ 㓶┨䋬㐳㊁ 㕏ዏ䊐䊤䉪䉺䊦ᩰሶੂᵹ䈮䉋䉎㜞Scᢙ䉴䉦䊤䊷ᷙว*㋈ᧁ ඳ⾆䋨ฬฎደᄢ䋩䋬㐳↰ ቁੑ䋬㈬੗ ᐽᒾ䋬㡻㘺 ᶭᄥ䋬ਭ଻ ⾆න৻/ⶄᢙ䊥䊑ઃ䉼䊞䊈䊦ੂᵹᾲવ㆐䈱ⓨ㑆⊒ዷဳDNS*ਃᶆ ⾆ᐢ䋨ᣂẟᄢ䋩䋬᧻ේ ᐘᴦ䋬ᰞ੗ ◊╬᷷ᐲᏅ䉼䊞䊈䊦ᵹ䈮䈍䈔䉎ㅴⴕᵄ⁁็಴䈚䊶ๆㄟ䉂䉕↪䈇䈢៺ᡂᛶ᛫ૐᷫ䈫વᾲଦㅴ䈱หᤨ೙ᓮ*᧲ ቁ␭䋨ᘮᙥᄢ䋩䋬቞ ⵨਽䋬ᷓẟ ᐽੑ䋬ዊየ ᤯ਯ੺㜞᷷᳓ṁᶧ႙䈱ੑ㊀᜛ᢔ⥄ὼኻᵹ䈮㑐䈜䉎ᢙ୯⸃ᨆ*૒䇱ᧁ ৻઀䋨ጊᒻᄢ䋩䋬⿒᧻ ᱜੱ3-䊑䊨䉾䉪ဳടᾲḮ䉋䉍↢䈛䉎䉰䊷䊙䊦䊒䊦䊷䊛䈱᜼േ䋨ടᾲḮኸᴺ䈱ᓇ㗀䋩*ጤ㑆 ⡛ม䋨ጊ᪸ᄢ䋩䋬৻ች ᶈᏒᵹേጀౝ䊐䉞䊮ઃવᾲ▤䈮㑐䈜䉎⎇ⓥ䋨䊐䉞䊮䊏䉾䉼䈱ᓇ㗀䋩*⮈↰ ᒏ䋨㑐⷏ᄢ䋩䋬ᧄ↰ ੫૓䋬᪢Ꮉ ዏ༹䋬ዊỈ቞䊉䉵䊦಴ญ䈮⊒↢䈜䉎CO2ੑ⋧ᵹᢳ䉄ⴣ᠄ᵄ䈮㑐䈜䉎⎇ⓥਛᎹ ൎᢥ䋨⼾ᯅᛛ⑼ᄢ䋩䋬*⨆㊁ ᶈਯ䋬ේ↰ ᢕผ᷷ᐲ೙ᓮน⢻䈭⥄ബᝄേဳ䊍䊷䊃䊌䉟䊒䈱ታ㛎⊛⎇ⓥ*ጤ↰ ⋥ሶ䋨JAXA䋩䋬ዊᎹ ඳਯ䋬ችፒ ⧐㇢䋨⑔੗Ꮏᄢ䋩Modeling of Bubble Generation and Growth in
Self-Oscillating Heat Pipe
*Raffles Senjaya 䋨 Tokyo Inst. Tech. 䋩 䋬 Kentaro
Mushiga䋬Tomiaki Kouduma䋬Yuji Suzuki䋬TakayoshiInoueવᾲ 2009 ᐕ 4 ᦬

F-123

F-124

಄ᇦᵹ䉏䈮ၮ䈨䈒䊍䊷䊃䊘䊮䊒䉰䉟䉪䊦䈱䉲䊚䊠䊧䊷䉲䊢䊮䈫䈠䈱ᔕ↪
*ችᧄ ᐕ↵䋨ฬฎደᄢ䋩䋬ᄢౝ↰ ⡡䋨IHI䋩䋬㐳⼱Ꮉ㆐਽䋨ฬฎደᄢ䋩᳇ᵃ㚟േဳᓴⅣᑼ䊍䊷䊃䊌䉟䊒(BACH)䈱૞േේℂᬌ⸛ጤᧄ ᤩ๺䋨⑔੗ᄢ䋩䋬*ᵻ㊁ ⌀⤿䋬᳗੗ ੑ㇢䋬ᄢ⷏᧲ᵗม䋨⧯⁜ḧ䉣䊈䊦䉩䊷⎇ⓥ䉶䊮䉺䊷䋩䋬ᣂች ⑲ᄦ㪈㪈䋺㪇㪇㵨㪈㪉䋺㪉㪇㩷 㔚႐䊶㔚⩄⒖േਅ䈪䈱વᾲ㩷䊙䉟䉪䊨ᵄടᾲ䈮䈍䈔䉎⴫㕙᭴ㅧ䈱ലᨐ㕍ᧁ ๺ᄦ䋨㐳ጟᛛ⑼ᄢ䋩䋬⿒ၳ ආବ䋬*⼱ญ ᘕᒎ䊙䉟䉪䊨ᵄടᾲ䈮䈍䈔䉎ౝㇱ᭴ㅧ䈱ലᨐ*㕍ᧁ ๺ᄦ䋨㐳ጟᛛ⑼ᄢ䋩䋬⿒ၳ ආବ䋬*⼱ญ ᘕᒎ
TiO2☸ሶలႯጀౝ䈪䈱䉮䊨䊅㔚ᭂ䉕↪䈇䈢ᄢ᳇࿶᡼㔚䈮䉋䉎䉥䉹䊮↢ᚑ䈱․ᕈ
*⍹ਣ ๺ඳ䋨ጘ㒂㜞ኾ䋩䋬⥓੗ ⾆຦
㔚᳇⒖േᐲ䈱㆑䈇䉕೑↪䈚䈢䊅䊉☸ሶ䈱䉰䉟䉵ㆬ೎*Ꮉේ ㋕ᐔ䋨਻Ꮊᄢ䋩䋬ᐔ ᙗ૞䋬෹↰ ᱜ⵨䋬㜞↰଻ਯ䋬ᴡ㊁ ᱜ㆏㪝㪄㪈㪊㩷 㩷㪈㪊䋺㪌㪇㵨㪈㪋䋺㪌㪇㩷 ఝ⑲䊒䊧䉷䊮䊁䊷䉲䊢䊮⾨䋺䉲䊢䊷䊃䊒䊧䉷䊮䊁䊷䉲䊢䊮䋳㩷

F-1301䊙䉟䉪䊨䉼䊠䊷䊑䈮䈍䈔䉎䉧䉴ᵹ䈱ᵹേ․ᕈ
*ศ↰ ᵏᶈ䋨᧲੩ℂᄢ䋩䋬ᵩ ቯ᧜䋬ᵻฎ ⼾䋨㚂ㇺ
ᄢ䋩䋬㋈ᧁ ᐽ৻䋨᧲੩ℂᄢ䋩ะᵹဳ䉧䉴䋭䉧䉴䊙䉟䉪䊨䉼䊞䊮䊈䊦ᾲ੤឵ེ䈱વᾲ․ᕈ䈮෸䈿䈜㓒ოෘ䈘䈱ᓇ㗀*ዊጊ ᐘᐔ䋨㚂ㇺᄢ䋩䋬ᵩ ቯ᧜䋨᧲੩ℂᄢ䋩䋬ᵻฎ⼾䋨㚂ㇺᄢ䋩
ᓸ⚦᭴ㅧ⴫㕙䈮䈍䈔䉎䊙䉟䉪䊨ᶧṢ䈱Ứ䉏․ᕈ
*቟⮮ 㓉ᴦ䋨਻ᎺᎿᄢ䋩䋬ศ↰ ⌀৻ᦶ䋬㐳ጊ ᥙሶ䋬㢬↰ 㓉ᴦ
⊕㊄♽㊄ዻ฽᦭䉦䊷䊗䊮䊅䊉䉼䊠䊷䊑䈱วᚑ*દ⮮ ᕶᐔ䋨ᐢፉᄢ䋩䋬੗਄ ୃᐔ䋬᧻᧛ ᐘᒾᄢ᳇࿶䊒䊤䉵䊙䈮䉋䉎䉻䊜䊷䉳䊐䊥䊷䊒䊤䉵䊙CVD䋺ု⋥㈩ะනጀ䉦䊷䊗䊮䊅䊉䉼䊠䊷䊑วᚑ䊜䉦䊆䉵䊛*໊ᵤ ᜏ਽䋨᧲੩Ꮏᄢ䋩䋬ጟፒ ஜ䋬㊁ፒ ᥓᵗᵹ〝ᒻ⁁䈮․ᓽ䈨䈔䉌䉏䈢੤ᵹ㕖৻᭽㔚⇇ਛ䈱ᵹ૕䈍䉋䈶ᶋㆆ☸ሶ䈱᜼േ*ફ⷗ శ᣿䋨ᘮᙥᄢ䋩䋬ฎᏒ ᦮ሶ䋬ཅ೽ ⵨䋬૒⮮ᵗᐔ䊥䊒䊨䊮⴫㕙శᢔੂᴺ䉕↪䈇䈢䊙䉟䉪䊨䊚䉨䉲䊮䉫ᷙวᶧ૕䈱⴫㕙‛ᕈ䉶䊮䉲䊮䉫䈮㑐䈜䉎⎇ⓥ䋨᷹ⷰᵄ㐳นᄌⵝ⟎䈱㐿⊒䈫䉣䉺䊉䊷䊦᳓ṁᶧ䈻䈱ᔕ↪䋩␹ᵤ ፏ䋨ᘮᙥᄢ䋩䋬*⷏᧛ ᖘ䋬ችᧄ ື㇢䋨ᣣ┙⵾૞ᚲ䋩䋬ਃቛ ੫䋨ᐢፉᄢ䋩䋬㐳ဈ 㓶ᰴ䋨ᘮᙥᄢ䋩὇⚛䊅䊉☸ሶ䈱ო㕙ⴣ⓭᜼േ䈮㑐䈜䉎ಽሶേജቇ⊛⎇ⓥ*ᚭ᎑ 㓉ᄦ䋨ᄢ㒋ᄢ䋩䋬⦼ේ ᱜᒾ䋬ਛ᧛ ៺ℂሶ䊅䊉ᄙሹ૕ౝᵹ䉏䈱MD䉲䊚䊠䊧䊷䉲䊢䊮䋨MD䈫LBM䈱Ყセᬌ⸛䋩*┻ਛ ᅑ䋨ᄢ㒋ᐭᄢ䋩䋬㗇⾐ ৻ᒾ䋬㊄ၔ ෹ਯ䋨⼾↰ਛ⎇䋩䋬౓㗡 ᔒ᣿

F-1302F-1303F-1304F-1305F-1306F-1307F-1308F-1309- 77 -J. HTSJ, Vol. 48, No. 203

߅⍮ࠄߖF-1310F-1311

F-1312නጀ䉦䊷䊗䊮䊅䊉䉼䊠䊷䊑䈮䈍䈔䉎䊐䉤䊉䊮ᢔੂ᧦ઙ䈱⛔ว*੗਄ ੳੱ䋨਻Ꮊᄢ䋩䋬દ⮮ ᵗᐔ䋬㜞ᯅ ෘผ
G-1107䊙䉟䉪䊨ᵄ-䊘䊥䉥䊷䊦ᴺ䈮䉋䉍วᚑ䈚䈢㌁䊅䊉☸ሶ䉕฽䉃Self-rewettingᵹ૕䈱㕖✢ᒻ⴫㕙ᒛജ․ᕈ䈱೙ᓮ
G-1108*㋈ᧁ ᥓ⵨䋨ቝㇺችᄢ䋩䋬૒⮮ ᱜ⑲䋬ⅶ↰ ଆᏆ䋬㒙ㇱ ቱਯ䋨↥✚⎇䋩䋬㘵᧛ ౗৻䋨ቝㇺችᄢ䋩䋬䊂䊶䊌䊨䊙 䊨䊔䊦䊃䋨䊅䊘䊥ᄢ䋩䋬䉼䉢䉼䉢䊷䊧 䉝䊮䉶䊦䊝䋬䉰䊯䉞䊷䊉 䊤䊐䉜䉣䊨䋬ᄢ↰ ᴦᒾ䋨਻Ꮊᄢ䋩䋬ᣂᧄ ᐽਭ䋬 G-1109
ᷓ⪨ ᱜੱ䋨SHOKi䋩䋬ฎỈ Პ䋨ቝㇺችᄢ䋩䋬㋈ᧁ ᣹㔚ሶ✢䉕↪䈇䈢䉦䊷䊗䊮䈱䊅䊉䉴䉬䊷䊦䉣䉾䉼䊮䉫
G-1110*ᑝ⼱ Ả䋨਻Ꮊᄢ䋩䋬↢↰ ┥਽䋬㜞ᯅ ෘผ䋬᳗ጊ㇌ੳ㪝㪄㪈㪋㩷 㩷㪈㪌䋺㪋㪇㵨㪈㪎䋺㪉㪇㩷 ↢↥䊶ടᎿ䊒䊨䉶䉴㩷F-141㜞⌀ⓨ䉝䊦䉮䊷䊦⸅ᇦCVDᴺ䉕↪䈇䈢නጀ䉦䊷䊗䊮䊅䊉䉼䊠䊷䊑䈱ૐ᷷วᚑ*ጟㇱ ኡੱ䋨᧲੩ᄢ䋩䋬ጊᧄ ᵗᐔ䋬੗䊉਄ ᵏノ䋬䉣䉟䊅䊦䉸 䉣䊥䉾䉪䋬ᷰㄝ ⺈䋬ਣጊ ⨃ᄦ䉸䊦䊗䉰䊷䊙䊦ᴺ䈮䉋䉎䊋䊦䉪න⚿᥏⢒ᚑᤨ䈱ਃᰴరવᾲ⸃ᨆ*Ⴧ↰ ༀ㓶䋨↥✚⎇䋩䋬㋈ᧁ ᣿䋬ਃᎹ ⼾䋨ਃ⪉ൻቇ䋩䋬㏜⼱ ാੑ䋨᧲ർᄢ䋩䋬⍹㤥 ᔀ䋬ᮮጊ ජᤘ䋬Ⴆ↰ 㓉ᄦ䊧䊷䉱䊷䊙䉟䉪䊨ḴടᎿ䈮䉝䊑䊧䊷䉲䊢䊮䊜䉦䊆䉵䊛䈏෸䈿䈜ᓇ㗀*ਸ⮮ ᜏੱ䋨਻Ꮊᄢ䋩䋬Ꮉౝ ㅴม䋬㜞↰ ଻ਯ䋬ᴡ㊁ᱜ㆏⊒ᾲᄌേ䈅䉎ᐔ᧼䈱᷷ᐲᄌൻ䉕ᦨዊ䈮䈜䉎ᾲ೙ᓮᛛⴚ䈱ᬌ⸛䋨䊝䊂䊦੍᷹೙ᓮᴺ䋩*ᐔỈ ⨃᮸䋨␹ᚭᄢ䋩䋬દ⮮ ᔃ਽ᵹേ⸅ᇦ䈮䉋䉎䉦䊷䊗䊮䊅䊉‛⾰䈱Ά὾วᚑ*ᅏጊ ᱜ᣿䋨ጊᒻᄢ䋩䋬ን᧛ ኼᄦ䋨਻Ꮊᄢ䋩䋬Ⓑንᐽ೑䋨਻㔚Ꮏ䋩

F-142

F-143

F-144

F-145

䋼㩷 㪞 ቶ㩷 䋾㩷

ൻቇ⒳䈱⸘᷹*᧻ᶆ ኡਯ䋨ฬฎደᄢ䋩䋬ఽ₹ ᙗᴦ䋬ർᎹ ㇌ⴕᓸ☳὇Ά὾䉲䊚䊠䊧䊷䉲䊢䊮䈮䉋䉎䊜䉺䊮䊥䊋䊷䊆䊮䉫ᛛⴚ䈱ല₸ൻ*ᨹᧁ ໪ᄥ䋨਻Ꮊᄢ䋩䋬ጊᧄ ೰䋬ᷓ੗ Ả䉬䊚䉦䊦⺞Ḩ䉲䉴䊁䊛䈮↪䈇䉎䊨䊷䉺䊥䊷䉨䊦䊮෻ᔕེ䈱‛⾰⒖േ․ᕈ
*⊕੗ ᶈ৻䋨ᐢፉᄢ䋩䋬᧻᧛ ᐘᒾ䋬ർේ ඳᐘ䋨䊃䊷䉺䊦䉲䉴䊁䊛⎇ⓥᚲ䋩Ḩᑼ㒰Ḩᯏ䈱㒰Ḩ/ౣ↢ེ䈮䈍䈔䉎‛⾰⒖േ․ᕈ
*ᒛ ⩐䋨᧲੩ᄢ䋩䋬ౄ ⿥㍋䋬㘧ේ ⧷ಃ䊦䊷䊒ဳᾲ㖸㗀䉣䊮䉳䊮䈱㜞ല₸ൻ䈫ゞਔ៞タ䈮ะ䈔䈢⎇ⓥ䋨ឃ䉧䉴䈎䉌䈱ᾲ䉣䊈䊦䉩䊷࿁෼䉲䉴䊁䊛䈱᭴▽䋩⚊ን ା䋨ᣧⒷ↰ᄢ䋩䋬ൎ↰ ᱜᢥ䋬㋈ᧁ ໪ผ䋬*ᐔỈ㗼䋬ᩉ ኼቱ䋬᧻ᐔ ▸శ䋨䉦䊦䉸䊆䉾䉪䉦䊮䉶䉟䋩䋬ᐔἑ ⾆ਯ
G-1111 䊦䊷䊒▤ᣇᑼᾲ㖸㗀಄ළ䉲䉴䊁䊛䈱ታ↪ൻ䈮ะ䈔䈢⎇ⓥ䋨ᾲ㖸㗀⃻⽎䈮䈍䈔䉎䉴䉺䉾䉪䈱᷷ᐲ൨㈩䈫㖸ᵄ⊒↢䈱㑐ଥ䋩*ዊች ᘕᄥ㇢䋨หᔒ␠ᄢ䋩䋬ဈᧄ ⋿৻䋨ṑ⾐⋵ᄢ䋩䋬Ⴆᧄ ᄢ࿾䋨หᔒ␠ᄢ䋩䋬ᷰㄝ ᅢ┨
G-1112 ૐ࿶᳓⚛䉧䉴䈱ᾲવዉ₸᷹ቯ*⻉ᳯ ዁๋䋨਻Ꮊᄢ䋩䋬䉡䉾䊄䊐䉞䊷䊦䊄 䊏䊷䉺䊷䋨↥✚⎇䋩䋬ᧁ᧛ ᶈ৻䋨਻Ꮊᄢ䋩䋬ᷓ੗ Ả䋬ᣂ㉿ ኡ⧷䋨↥✚⎇䋩䋬ᴡ㊁ ᱜ㆏䋨਻Ꮊᄢ䋩䋬⮮੗ ਍ᄦ䋨↥✚⎇䋩䋬㜞↰ ଻ਯ䋨਻Ꮊᄢ䋩
G-1113 ੱ૕ᾲ෼ᡰ䈮ၮ䈨䈒᷷ᾲⅣႺ⹏ଔ*ፉ㦮 ᐽᒄ䋨ᄢ㒋ᐭᄢ䋩䋬ศ↰ ◊ᱜ䋬㋈ᧁ ⦟ᄥ䋬ᧁਅ ㅴ৻㪞㪄㪈㪉㩷 㩷
G-121

G-122

㪞㪄㪈㪈㩷 㩷 㪐䋺㪌㪇㵨㪈㪇䋺㪌㪇㩷 ఝ⑲䊒䊧䉷䊮䊁䊷䉲䊢䊮⾨䋺䉲䊢䊷䊃䊒䊧䉷䊮䊁䊷䉲䊢䊮䋲㩷
G-1101 䈸䈒኿ᯏ⢻ᕈ⴫㕙䈱᡼኿䉲䊚䊠䊧䊷䉲䊢䊮*ᐔፉ ᄢテ䋨᧲੩Ꮏᄢ䋩䋬⧎᧛ సᖗ
G-1102 䊙䉟䉪䊨⃿⥄Ꮖ⚵❱ൻ᭴ㅧ䈱ᾲ䈸䈒኿․ᕈ⹏ଔ
*⣁↰ ஜᄥ㇢䋨਻ᎺᎿᄢ䋩䋬ችፒ ᐽᰴ䋬Ⴆᧄ ኡ
G-1103 ᳓⫳᳇ๆ⌕૕䈮䉋䉎శ䈱න⦡෻኿₸䊶ๆ෼₸䈍䉋䈶ㅘㆊ₸䈱᷹ቯựᧄ ⧐ᓼ䋨਻Ꮊᄢ䋩䋬᫪ ⧷ᄦ䋬⿒੗ 㓉ᢥ䋬*⑔↰㆐ብ
G-1104 W/Oဳ䉣䊙䊦䉳䊢䊮ᶧṢ䈱ടᾲㆊ⒟䈮䈍䈔䉎᣹᷷ㅦᐲ䈏ᴤਛ᳓Ṣ䈱ಝ㓸䈮෸䈿䈜ᓇ㗀
*㋈ᧁ ⧐ⴕ䋨᧲ർᄢ䋩䋬ේ↰ ᜏ⥄䋬ᷰㇱ ᒄ㆐䋬᧻ਅᵗ੺䋬㕍ᧁ ⑲ਯ䋬ਃᶆ 㓉೑
G-1105 䊙䊦䉼䊋䊷䊅䊷਄䈮ᒻᚑ䈘䉏䉎䊜䉺䊮䊶ⓨ᳇੍ᷙวἫ
Ἳ䈱᜼േ䈫䉉䉌䈑*ਣጊ ବౖ䋨㐳ጟᛛ⑼ᄢ䋩䋬㐷⣁ ᢅ
G-1106 ੍ᷙว᳓⚛㉄⚛Ἳਛ䈮䈍䈇䈩㜞᷷᧚ᢱ䈎䉌⊒↢䈜䉎

વᾲ 2009 ᐕ 4 ᦬

G-123

G-124

㪈㪈䋺㪇㪇㵨㪈㪉䋺㪉㪇㩷 ‛⾰⒖േ㩷฽᳓᧦ઙਅ䈮䈍䈔䉎ᓸ⚦ᄙሹ૕ౝ䈱㉄⚛᜛ᢔଥᢙ᷹ቯᴺ*ጤፒ ᄢ೰䋨ᮮᵿ࿖ᄢ䋩䋬ቝ㜞 ⟵㇢䋬↰ፒ ⼾䋨ᣣ↥⥄േゞ䋩䉸䊷䊧䊷ᒝ೙䊧䉟䊥䊷ᢔੂᴺ䈮䉋䉎䊘䊥䊙䊷㔚⸃⾰⤑ౝ䈱‛⾰᜛ᢔଥᢙ᷹ቯᴺ䈱㐿⊒䋨䉻䉟䊟䊝䊮䊄⓹䉶䊦䈮䉋䉎᷹ቯ䋩↰ਛ ㆯᐔ䋨ᘮᙥᄢ䋩䋬*ၳ↰ ⚐ᐔ䋬㐳ဈ 㓶ᰴ࿕૕㜞ಽሶ㔚⸃⾰⤑ౝ䈮䈍䈔䉎᳓䈱᜛ᢔャㅍ․ᕈ
䈱⸃ᨆൎ↰ ᱜᢥ䋨ᣧⒷ↰ᄢ䋩䋬ጊᎹ ⵨ᔒ䋬*ᷰㆻ ๺਽䋬᧖ේ ᖘᄥ䋬㕍⼱ ᐘ৻㇢䋨ᣣ↥⥄േゞ䋩䋬ਭ଻ ೣᄦ
PEFC䉦䉸䊷䊄⸅ᇦጀ᭴ㅧ䈱⊒㔚․ᕈ䈮෸䈿䈜ᓇ㗀䋨䉝䉟䉥䊉䊙䊷฽᦭₸䈫ャㅍ․ᕈ䈫䈱㑐ଥ⸃᣿䋩*᧻↰ ⑲ବ䋨᧲੩Ꮏᄢ䋩䋬ᄢ㑆 ᢕผ䋨᧲੩Ꮏᄢ䋬ᣣ↥䋩䋬ફା ৻ᘮ䋨᧲੩Ꮏᄢ䋩䋬ጟፒ ஜ㪞㪄㪈㪊㩷 㩷 㪈㪊䋺㪌㪇㵨㪈㪋䋺㪌㪇㩷 ఝ⑲䊒䊧䉷䊮䊁䊷䉲䊢䊮⾨䋺䉲䊢䊷䊃䊒䊧䉷䊮䊁䊷䉲䊢䊮䋴㩷
G-1301 ↢૕⚵❱䉕↪䈇䈢䊕䊦䉼䉢䉪䊤䉟䉥䊒䊨䊷䊑䈮䉋䉎㜞♖ᐲಓ⚿ᚻⴚ䈱⎇ⓥ*ᱞ↰ ᵗ᮸䋨᧲ർᄢ䋩䋬⋧႐ ▵਽䋬ዊች ᢕ᮸䋬࿧ጊ㊀⋥- 78 -J. HTSJ, Vol. 48, No. 203

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G-1302 ᓸ⚦ᵹ〝䈫⋧ᄌൻ䊙䉟䉪䊨䉦䊒䉶䊦䉕೑↪䈚䈢㔚ሶᯏེ಄ළ䈮㑐䈜䉎ၮ␆⎇ⓥ
ᯅᧄ ᱞ⵨䋨ንጊ⋵ᄢ䋩䋬᧻ᧄ శม䋬ਛᎹ ᘕੑ䋬⍹Ⴆ ൎ
G-1303 䉣䊥䉴䊥䊃䊷䊦૶↪ဳẜᾲ⫾ᾲャㅍ䉲䉴䊁䊛*⢻᧛ ⾆ብ(ർᶏ㆏ᄢ)䋬㐿Ỉ ᤘ⧷䋬㊍㊁ ඳ⤿䋨ᩙᧄ㐅Ꮏᚲ䋩䋬ᴡว ◊䋬ቯႦ ᔀᴦ䋨ਃᯏᎿᬺ䋩䋬ජ↰ᱞᔒ䋬ᴒਛ ᙗਯ䋨ർᶏ㆏ᄢ䋩䋬⑺ጊ㩷 ෹ብ
G-1304 ↢ᚑ䊶ಽ⸃䊝䊂䊦䈮ၮ䈨䈒CO2䊊䉟䊄䊧䊷䊃⤑ෘᄌൻ᜼േ䈱੍᷹*᧻ర ૓᮸䋨╳ᵄᄢ䋩䋬㊄ሶ ᥙሶ䋬㒙ㇱ ⼾䋬ጊᩮஜᰴ䋨ᶏ਄ᛛⴚ቟ో⎇ⓥᚲ䋩G-1305 MEMS䉶䊮䉰䈮䉋䉎ᩭᴣ㛛ᾲવ㆐ᯏ᭴䈱⎇ⓥ䋨᷷ᐲ೙ᓮᕈ䈱ᡷ⦟䈫ᾲᵹ⹏ଔᚻᴺ䈱ᬌ⸛䋩*⍫็ ᥓ⧷䋨᣿ᴦᄢ䋩䋬ਛ೎ᐭ ୃ
G-1306 න৻⚦▤ౝ䈱ᒝ೙ᵹേᴣ㛛ᾲવ㆐䈮෸䈿䈜⾰㊂ㅦᐲ䈱ᓇ㗀*㚍႐ ቬ᣿䋨਻Ꮊᄢ䋩䋬Ⓑ↰ ᐘඳ䋬Ỉ↰ ஜ৻㇢䋬੗਄ ᶈ৻䋬ᄢ↰ ᴦᒾ
G-1307 䊊䊆䉦䊛⁁ᄙሹ⾰૕䈱䉶䊦᏷䈏㘻๺䊒䊷䊦ᴣ㛛㒢⇇ᾲᵹ᧤䈮ਈ䈋䉎ᓇ㗀᫪ ᣽ม (ᮮᵿ࿖ᄢ)䋬*ᴉ 䊨䊷䉳䉢䋬⑔↰ ⋥਽䋬ᅏጊ ㇌ੱ
G-1308 䊒䊤䉴䉼䉾䉪䉕↪䈇䈢ᷫ࿶ᴣ㛛ᄙ㊀ല↪᷆᳓ൻⵝ⟎䈱㐿⊒ጟ↰ ᵏਯ䋨ᘮᙥᄢ䋩䋬*᫪Ꮉ ๺Ꮖ䋬૒⮮ ᤐ᮸䋬₹੗ବᵗ䋨Ⓧ᳓ൻቇᎿᬺ䋩䋬ᄢ᧖ 㜞ᔒ
G-1309 ⎇೥ടᎿᤨ䈮䈍䈔䉎᳓䊚䉴䊃಄ළ䈏ⵍടᎿ‛䈻෸䈿䈜ലᨐ䈮㑐䈜䉎⎇ⓥ䋨᳓䊚䉴䊃․ᕈ䈱ᓇ㗀䈮䈧䈇䈩䋩⏷ㇱ ૫ᚑ䋨ጊญ⋵↥ᬺᛛⴚ䉶䊮䉺䊷䋩䋬*ᑿ┙ ৻຦䋨ጊญᄢ䋩䋬ട⮮ ᵏ↢
G-1310 ฽᳓ᄙሹ⾰䉕೑↪䈚䈢ㆊᾲ᳓⫳᳇䈱↢ᚑㆊ⒟᫪ ᣽ม䋬*ጯ ୶ੱ䋨ᮮᵿ࿖ᄢ䋩䋬↰ਛ ⟤㚅ሶ䋬ᅏጊ㇌ੱ
G-1311 ࿕૕㜞ಽሶᒻΆᢱ㔚ᳰ䈱᳖ὐਅ⿠േᓇ㗀䈫ಓ⚿⃻⽎*㥲⮮ ᱜዛ䋨ർᶏ㆏ᄢ䋩䋬↰ㇱ ⼾䋬⩵↰ ๺㊀䋬ㄭਭᱞ⟤
G-1312 ㉄⚛ᷝട䈍䉋䈶᷷ᐲ䈱ലᨐ䈮䉋䉎Άᢱ㔚ᳰ䈱৻㉄ൻ὇⚛ⵍᲥᛥ೙*⨹੗ 㓳ੱ䋨ฬฎደᄢ䋩䋬᫪↰ ᚑᤘ䋬ች↰ ᐽผ䋬ർᎹ ㇌ⴕ
G-1313 エ䌘✢䈮䉋䉎PEFCౝᶧ᳓ಽᏓ䈱นⷞൻ*╣ㇱ ፏ䋨᧲੩Ꮏᄢ䋩䋬ᵤፉ ዁ม䋬ᐔ੗ ⑲৻㇢䋬ධൎ೑䋨᧲⎇䋩䋬⍫↰ ᘮᴦ

G-143

G-144

G-145

䋼㩷 㪠 ቶ㩷 䋾㩷䌉㪄㪈㪈㩷 㩷㪐䋺㪊㪇㵨㪈㪇䋺㪌㪇㩷 ಽሶേജቇ䋱㩷

I-111࿕ᶧធ⸅᜼േ䈮෸䈿䈜ო㕙㔚⩄䈱ᓇ㗀䈮㑐䈜䉎ಽሶേജቇ⸃ᨆ*ዊᎹ ๺਽䋨ᄢ㒋ᄢ䋩䋬ጊญ ᐽ㓉䋬㤥↰ ቁੑ䋨ᄢᣣᧄශ೚䋩䋬ਛፉ ૉ䋬ᄢ㊁ ᶈᐔ䋬⮮᧛ ⑲ᄦ䊙䉫䊈䉺䉟䊃-᳓⇇㕙䈮䈍䈔䉎ṁ಴ಽሶ䈱‛⾰ャㅍ․ᕈ*⩵Ꮉ ⽕ᄥ䋨᧲ർᄢ䋩䋬ട⮮ ᖳᐔ䋬ዊේ ᜏ䈞䉖ᢿᵹਛ䈮䈍䈔䉎⢽⾰ੑ㊀⤑䈱ㆇേ㊂વ៝․ᕈ
*ਛ㊁ 㓶ᄢ䋨᧲ർᄢ䋩䋬⩵Ꮉ ⽕ᄥ䋬ዊේ ᜏო㕙䊅䊉᭴ㅧ‛㑆㓒䈏࿕ᶧ⇇㕙ᾲᛶ᛫䈻ਈ䈋䉎ᓇ㗀*┻ౝ ᷡ䋨ᄢ㒋ᄢ䋩䋬⦼ේ ᱜᒾ

I-112

I-113
I-114

㪠㪄㪈㪉㩷 㩷㪈㪈䋺㪇㪇㵨㪈㪉㪑㪇㪇㩷 ಽሶേജቇ䋲㩷I-121㔚⏛ᵄ䈫䈱⋧੕૞↪䈎䉌⷗䈢᳓䈱Ყᾲ*↰ਛ ୃ䋨ਃᧁౣ↢䉣䊈䊦䉩䊷㐿⊒⎇ⓥᚲ䋩䉦䊷䊗䊮䊅䊉䉼䊠䊷䊑䈻䈱㊄ዻ⫳⌕䈱ಽሶേജቇ*᧻የ ືᐔ䋨᧲੩ᄢ䋩䋬Ⴎ⷗ ᷕ৻㇢䋬ਣጊ ⨃ᄦᢳ䉄⫳⌕䈮䉋䉎䉡䉞䉴䉦↢ᚑ䈱ಽሶᯏ᭴*ᅏ᧛ ବ᣿䋨੩ㇺᄢ䋩䋬᧻ᧄ లᒄ

I-122
I-123

㪠㪄㪈㪊㩷 㩷㪈㪊䋺㪌㪇㵨㪈㪌䋺㪊㪇㩷 ಽሶേജቇ䋳㩷

I-131ᓸዊᶧṢ䈱࿕૕ო㕙䈻䈱ⴣ⓭䉲䊚䊠䊧䊷䉲䊢䊮*↰ᶆ ೰䋨੩ㇺᄢ䋩䋬᧻ᧄ లᒄ
Isotropic Periodic Sumᴺ䈍䉋䈶Wolfᴺ䉕↪䈇䈢MD䉲
䊚䊠䊧䊷䉲䊢䊮*㜞ᯅ ๺⟵䋨ᘮᙥᄢ䋩䋬ᚑ⷗ ື䋬ᵏጟ 㗼ᴦฦ⒳ടᾲ䊌䊦䉴䈮䈍䈔䉎વ៝䈱ᾲ䉣䊈䊦䉩䊷વ㆐․ᕈ*⮀ ᢅ⿥䋨ንጊᄢ䋩䋬䉹䊨䊃䉨䊍䊅 䉺䉼䉝䊅᳓/䊜䉺䊮᳇ᶧ⇇㕙䈱ಽሶേജቇ䉲䊚䊠䊧䊷䉲䊢䊮*ဈ’ 㓉ม䋨ᘮᙥᄢ䋩䋬ᚑ⷗ ື䋬ᄢ᧛ ੫䋬ᵏጟ 㗼ᴦ䊅䊉䉴䊒䊤䉾䉲䊠*ⓣ⷗ ⌀ታሶ䋨੩ㇺᄢ䋩䋬᧻ᧄ లᒄ

I-132

I-133

I-134

㪞㪄㪈㪋㩷 㩷 㪈㪌䋺㪋㪇㵨㪈㪎䋺㪉㪇㩷 ⫾ᾲ䊶⫾಄㩷
G-141

G-142

Feasibility Study of Heat Pipe Ice Storage System
Using Natural Energy for Large-Sized Data Center
Cooling System*Gerald Cabusao 䋨Fujikura䋩 䋬Masataka Mochizuki䋬
Koichi Mashiko䋬Tetsuya Kobayashi⚦▤ౝ䈮䈍䈔䉎䉝䉟䉴䉴䊤䊥䊷䈱ᵹേ䈍䉋䈶ᾲવ㆐․ᕈ*ዊ〝 ㆯᄥ䋨ାᎺᄢ䋩䋬ᾢ㊁ ኡਯ䋬ᐔ↰ ືᄦ䋬⊕Ꮉ㆏ੱ䋬⪤ේ 㓁੺વᾲ 2009 ᐕ 4 ᦬ౣ↢ක≮↪ᕡ᷷ャㅍኈེ䈱㐿⊒䋨╙3ႎ䋬ዊဳャㅍኈེ䈱⹜૞䈫ᕈ⢻⹏ଔ䋩*⮮ዬ ㆐㇢䋨ᣣ┙⵾૞ᚲ䋩䋬㑐⼱ ⑓ᄦ䋬ᬮᧄ ኡ䋬੗ᴧ ବ᣿䋨ᣣ┙‛ᵹ䋩⃿䉦䊒䉶䊦ౝ⋧ᄌൻ‛⾰䈻䈱ẜᾲ⫾ᾲଦㅴዊᴰ ඳ⟵䋨㔚᳇ㅢାᄢ䋩䋬*᧻↰ ๺਽䋬㊄ ੔ᶏ䋬⋧㚍 ਭ⟤ሶㆊ಄ළ⫾ᾲ೑↪ᐥᥦᚱ䊌䊈䊦䈱േ૞․ᕈ
*ᐔ㊁ ⡡䋨↥✚⎇䋩䋬ᩊ㦮 ೣ㓶䋨䉝䊦䉴䋩䋬Ꮏ⮮ ๺᣿䋨䉻䊁䉾䉪䉴䋩

I-135

㪠㪄㪈㪋㩷 㩷㪈㪌䋺㪋㪇㵨㪈㪍㪑㪋㪇㩷 ಽሶേജቇ䋴㩷

I-141ಽሶേജቇᴺ䈮䉋䉎⊕㊄⴫㕙਄䈱᳓⚛⸃㔌⃻⽎*ᓼჇ ፏ䋨᧲ർᄢ䋩䋬દ⮮ ᄢ๋Ni䉪䊤䉴䉺䊷䈫O2䈱⴫㕙⋧੕૞↪䋨ജ䈫䉣䊈䊦䉩䊷․ᕈ䋩*䉹䊨䊃䉨䊍䊅 䉺䉼䉝䊅䋨ንጊᄢ䋩

I-142- 79 -J. HTSJ, Vol. 48, No. 203

߅⍮ࠄߖ
I-143

ኒᐲ᳢㑐ᢙᴺ䈮䉋䉎Pt⸅ᇦ⴫㕙ઃㄭ䈮䈍䈔䉎㉄⚛ಽሶ⚿ว⁁ᘒ䈱⎇ⓥ*ጊ↰ ஜᄥ㇢䋨᧲੩Ꮏᄢ䋩䋬ફା ৻ᘮ䋬ጟፒ ஜ㪡㪄㪈㪈㩷 㩷㪐㪑㪊㪇㵨㪈㪇䋺㪊㪇㩷 ⥄ὼኻᵹ䊶ⶄวኻᵹ䋱㩷J-111

2ᨎ䈱ု⋥ടᾲᐔ᧼਄┵㑆䈮⸳⟎䈘䉏䈢᳓ᐔ਄ะ䈐ടᾲᐔ᧼䉁䉒䉍䈱⥄ὼኻᵹ䈱ᵹേ䈫વᾲ*ᧁ᧛ ᢥ⟵䋨౓ᐶ⋵ᄢ䋩䋬੗਄ ବ䋬ർ᧛ ஜਃ䋨⼾ᯅ
ᛛ⑼ᄢ䋩ਛ๺෻ᔕ䈮䈍䈔䉎ᾲ䊶‛⾰ャㅍ䈮෸䈿䈜㉄⸃㔌䈱ᓇ㗀*↰ਯ਄ ஜ৻㇢䋨ጊญᄢ䋩䋬ศ౷ 㓷᣿䋬↰᧛ ⼾૫䋬⷏᧛ 㦖ᄦ䋬䉝䊧䉨䉰䊮䊄䊦 䊝䊧䉧䋨䊑䉦䊧䉴䊃Ꮏ⑼ᄢ䋩ᐔ᧼೉ᝌ౉䈮䉋䉎⥄ὼኻᵹጀᵹᾲવ㆐䈱ଦㅴ䈫䈠䈱ᢙ୯⸃ᨆ*᫃↰ ᰵ䋨ฬฎደᏒᎿ⎇䋩䋬ㄞ ବඳ䋨ฬฎደᎿᄢ䋩䋬
᧻㊁ ආテ

J-131

䋼㩷 㪡 ቶ㩷 䋾㩷

J-112

J-113

J-132

㪡㪄㪈㪉㩷 㩷㪈㪈䋺㪇㪇㵨㪈㪉㪑㪇㪇㩷 ⥄ὼኻᵹ䊶ⶄวኻᵹ䋲㩷J-121ടᾲ࿁ォ႐䈮䈍䈔䉎౒ሽኻᵹᾲવ㆐䈮㑐䈜䉎⎇ⓥ*❱ᳯ Ả৻䋨ጤᚻᄢ䋩䋬ዊ㊁ኹ 㜞ਯ䋨ਃ⪉㔚ᯏ䋩䋬ᑝἑ ብ৻䋨ጤᚻᄢ䋩ᮮ㘑䉕ฃ䈔䉎ἫἻᓟᵹ䈮⊒↢䈜䉎┥Ꮞ⁁䈱᷵䈱⊒↢ᒻᘒ*◉ේ 㓷ᒾ䋨ᶖ㒐⎇ⓥ䉶䊮䉺䊷䋩䋬᧻ፉ ᣧ⧣ᝄേ┙ᣇ૕ౝ䈱ᾲኻᵹ䈮෸䈿䈜ᝄ᏷ലᨐ䈱ᢙ୯⊛⎇ⓥ*⮮↰ ⼂ม䋨หᔒ␠ᄢ䋩䋬ਛ᧛ ᙗㅢ䋬⥱ᧁ ᴦ㇢䋬⼱Ꮉ ඳ຦䋨⥰㢬㜞ኾ䋩䋬ᐔ↰ ൎ຦䋨หᔒ␠ᄢ䋩

J-133

J-134

J-135

㪡㪄㪈㪋㩷 㩷㪈㪌䋺㪋㪇㵨㪈㪎㪑㪉㪇㩷 ⥄ὼኻᵹ䊶ⶄวኻᵹ 㪋㩷J-141ኒ㐽ⓨ㑆ౝ䈱⥄ὼኻᵹ䈮෸䈿䈜ౝㇱ‛૕䈱ᄢ䈐䈘䈫㈩⟎䈱ᓇ㗀*ർ ੨ᐘ䋨ንጊ⋵ᄢ䋩䋬⷏಴ ⍮᮸䋬⥱ᷰ ⵨৻
᳓ᐔੑ㊀౞▤ౝ䈱ំേ䈜䉎ᶋജ䊒䊦䊷䊛䈱ㅦᐲ䊶᷷ᐲหᤨ⸘᷹*↰ਛ ⵨ม䋨หᔒ␠ᄢ䋩䋬⍹↰ ዛᐾ䋬ජ↰ ⴤ䋬Ⓑጟᕶੑ㋦⋥ੑᐔ᧼㑆ኒᐲᚑጀౝ⥄ὼኻᵹᾲવ㆐䈮෸䈿䈜ೋᦼ᷷ᐲ䈱ᓇ㗀䋨વᾲ㕙㑆〒㔌䈱ᓇ㗀䉕฽䉄䈢⹦⚦䈭ᬌ⸛䋩
ᆢ㊁ ୃᑝ䋨ାᎺᄢ䋩䋬*᧖ᧄ ᄥ㇢䋬᳓᎑ ᐽᄦਇಝ❗ᕈ䉧䉴䉕฽䉃ᶧ૕䉺䊮䉪ౝ࿶ജᄌൻ䈱⹏ଔ੉⼱ 㓶᮸䋨IHI䋩䋬*੹੗ ⦟ੑ቟ቯᚑጀౝ䈱᳇૕ᷙวㆊ⒟䈮㑐䈜䉎⎇ⓥ*ᱞ↰ ື᣿䋨ጊ᪸ᄢ䋩

J-142

J-122

J-123

㪡㪄㪈㪊㩷 㩷㋦⋥ᐔ᧼਄䈱⥄ὼ䊶౒ሽኻᵹੂᵹႺ⇇ጀ䈱⋥ធᢙ୯⸃ᨆ*䉝䊔䊂䉞䊮 䊝䊊䊙䊄 䉳䊢䉟䊅䊦䋨ฬฎደᎿᄢ䋩䋬ㄞବඳ䋬ᢧᧁ ᐽੱ䋬᦯ㇱ ᐽ↵䋨㔚ਛ⎇䋩䈸䈒኿䉕઻䈉ᶋജੂᵹ䈱⋥ធ䉲䊚䊠䊧䊷䉲䊢䊮*㜞᪀ ⾫ੑ䋨ᣂẟᄢ䋩䋬ᰞ੗ ◊䋬᧻ේ ᐘᴦ䋬࿧ጊ㊀⋥䋨᧲ർᄢ䋩஥ო㕖ኻ⒓ടᾲ䈘䉏䉎᳓ᐔᱜᣇᒻᵹ〝ౝ䈱ਃᰴరⶄวኻᵹ䈮෸䈿䈜䊒䊤䊮䊃䊦ᢙ䈱ᓇ㗀*㠽ጊ ቁม䋨ጊ᪸ᄢ䋩䋬৻ች ᶈᏒ৻᭽䈭㋦⋥ਅ㒠᳇ᵹਛ䈮⸳⟎䈘䉏䈢᳓ᐔ਄ะ䈐ടᾲᐔ᧼䉁䉒䉍䈱౒ሽኻᵹ䈱ᵹേ䈫વᾲർ᧛ ஜਃ䋨⼾ᯅᛛ⑼ᄢ䋩䋬*ᄢ⇌ ੫␭䋬శ⍹ ᥙᒾ৻᭽䈭㋦⋥ਅ㒠᳓ᵹਛ䈮⸳⟎䈘䉏䈢᳓ᐔ਄ะ䈐ടᾲᐔ᧼䉁䉒䉍䈱౒ሽኻᵹ䈱ᵹേ䈫વᾲ*ർ᧛ ஜਃ䋨⼾ᯅᛛ⑼ᄢ䋩䋬੗ዥ 㗅┨䋬శ⍹ ᥙᒾ

J-143

J-144
J-145

㪈㪊䋺㪌㪇㵨㪈㪌䋺㪊㪇㩷 ⥄ὼኻᵹ䊶ⶄวኻᵹ䋳㩷㩷㩷㵪㵪㵪㩷 ╙ 䋲ᣣ 㩷 䋶᦬ 䋳ᣣ 䋨᳓ 䋩 㩷 㵪㵪㵪㩷㪙㪈㪄㪉㪉㩷 㩷 㪈㪇䋺㪊㪇㵨㪈㪉䋺㪈㪇㩷 ੑ⋧ᵹ䋱㩷䋼㩷 䌂䋱ቶ㩷 䋾㩷㪙㪈㪄㪉㪈㩷 㩷 㪐䋺㪇㪇㵨㪈㪇䋺㪉㪇㩷 ᴣ㛛䋵㩷
B1-211 ṁ኿⊹⤑䉕᦭䈜䉎⁜㓖ᵹ〝ౝᴣ㛛ᾲવ㆐䈮෸䈿䈜ᵹ〝ᆫ൓䈱ᓇ㗀*౷↰ ੫ᐔ䋨␹ᚭᄢ䋩䋬❥ේ 㗔ᄥ䋬ᵻ㊁ ╬, ᧖ᧄൎ⟤, ┻ਛ ାᐘ
B1-212 ᭂ⚦䉪䊤䉟䉥䊒䊨䊷䊑㐿⊒䈱䈢䉄䈱ᴣ㛛વᾲၮ␆ታ㛎*ጟፉ ᷕਯ੺䋨᧲ർᄢ䋩䋬౞ጊ ㊀⋥䋬ዊች ᢕ᮸
B1-213 䊚䊆䉼䊞䊈䊦ౝᴣ㛛⃻⽎䈮䈍䈔䉎⭯ᶧ⤑ෘ䈘䈱᷹ቯ*ᒛ ⠦⪇䋨ᮮᵿ࿖ᄢ䋩䋬ᨰේ 㓶⾆䋬ቝ㜞 ⟵㇢
B1-214 䊚䊆䉼䊞䊈䊦ౝᴣ㛛⃻⽎䈮䈍䈔䉎⭯ᶧ⤑ᒻᚑᯏ᭴䈫․ᕈᒛ ⠦⪇䋨ᮮᵿ࿖ᄢ䋩䋬*਄⿒ අ䋬ቝ㜞 ⟵㇢

વᾲ 2009 ᐕ 4 ᦬- 80 -

B1-221 ㆇേ㊂䈫ᾲャㅍ䉕⠨ᘦ䈚䈢ੑᰴరੑ⋧ᵹ⤘ᒛᵄ䈱⸃ᨆ*ේ↰ ᢕผ(⼾ᯅᛛ⑼ᄢ)䋬ਛᎹ ൎᢥ䋬⨆㊁ ᶈਯ
B1-222 ᳇ᵃ䉕฽䉖䈣䉼䊞䊈䊦ౝ਄᣹ੂᵹ䈱ᾲᵹേ․ᕈ䈮㑐䈜䉎⋥ធᢙ୯䉲䊚䊠䊧䊷䉲䊢䊮*↰ਛ㩷 ḩ䋨੩ㇺᎿ❫ᄢ䋩䋬᧻੗ ೣ᡽䋬ች᎑ 㓁䋬⪤ේ⦟㆏
B1-223 ᓸ⚦᳇ᵃ䉕฽䉃㋦⋥䉼䊞䊈䊦ౝጀᵹ౒ሽኻᵹ䈱ᵹേ䈍䉋䈶ᾲવ㆐․ᕈ
*㆙⮮ ᒄ᮸䋨੩ㇺᎿ❫ᄢ䋩䋬ᧁ᧛ స਽䋬ർᎹ ⍹⧷䋬⪤ේ ⦟㆏
B1-224 ಴ജ䊶ᵹ㊂ᷫዋ੐⽎䈮䈍䈔䉎 BWR Ἱౝᵹേㆊᷰᔕ╵J. HTSJ, Vol. 48, No. 203߅⍮ࠄߖ*ฎ⼱ ᱜ⵨䋨㔚ਛ⎇䋩䋬ේ ⾆䋨᧲੩㔚ജ䋩䋬Ḵ਄ િ਽
B1-225 ⿥㖸ᵄᵹㅦಽᏓ⸘䉕↪䈇䈢ᵹ᳓ਛන৻ᄢ᳇ᵃ೨ᣇ䈱ᵹ䉏႐䈱⸘᷹*ධᎹ ਭੱ䋨ṑ⾐⋵ᄢ䋩䋬⍹↰ ᥓᏆ䋬቟↰ ቁብ㪙㪈㪄㪉㪊㩷 㩷 㪈㪊䋺㪋㪇㵨㪈㪌䋺㪇㪇㩷 ੑ⋧ᵹ䋲㩷
B1-231 㜞಴ญੇ䈐ᐲ᧦ઙ䈮䈍䈔䉎䊙䉟䉪䊨▤ౝᒝ೙ᵹേᴣ㛛*⑔↰ ஜᄥ㇢䋨᧲੩ᄢ䋩䋬㣮࿦ ⋥Პ䋬ᣂጊ ᵏᓼ䋨䊂䊮䉸䊷䋩䋬౎᧤ ⌀৻
B1-232 ု⋥⍱ᒻ⚦▤ౝ਄᣹ᵹ䈱ᴣ㛛ᾲવ㆐䈫࿶ജ៊ᄬ*ች↰ ৻ม䋨਻Ꮊᄢ䋩䋬᭑ᧁ శᴦ䋬᫪ ⧷ᄦ䋬ựᧄ⧐ᓼ
B1-233 㕖✢ᒻṁᶧ䈱ዪᚲടᾲᤨ䈱ᓸ⚦▤ౝᵹേᴣ㛛⃻⽎*㊄ሶ 㜞ᐢ䋨⦼ᶆᎿᄢ䋩䋬ዊ㊁ ⋥᮸䋬⷏ญ ᣹ᄥᦶ䋨␹ᄹᎹᄢ䋩䋬ᐣม ᱜᒄ
B1-234 䊙䉟䉪䊨▤ౝ䉴䊤䉫ᵹ䈱ᶧ⤑ෘ䈘䈮෸䈿䈜ടㅦᐲ䈱ᓇ㗀*㖧 ᩕၭ䋨᧲੩ᄢ䋩䋬㣮࿦ ⋥᮸䋼㩷 䌂䋲ቶ㩷 䋾㩷㪙㪉㪄㪉㪈㩷 㩷 㪐䋺㪇㪇㵨㪈㪇䋺㪉㪇㩷 䌏䌓䋺㩷 ᳓⚛䉣䊈䊦䉩䊷ᛛⴚ䋱㩷
B2-211 ᳓⚛ๆ⬿᡼಴䈮䈫䉅䈭䈉᳓⚛ๆ⬿ว㊄ጀ䈱⤘ᒛ䊶෼❗₸䈱᷹ቯựᧄ ⧐ᓼ䋨਻Ꮊᄢ䋩䋬᫪ ⧷ᄦ䋬ᳯ⮮ ᷕᦶ䋬*ਃ⼱⾫ผ䋬㊄⍫ ଆᏆB2-212 ᳇ᶧੑ⋧ᵹ䈏᳓㔚⸃䉶䊦䈮ਈ䈋䉎ᓇ㗀ฎ⾐ ⾫䋨਻Ꮊᄢ䋩䋬૒䇱ᧁ ৻ᚑ䋬*દ⮮ ⴧᐔ
B2-213 ࿕૕㜞ಽሶဳΆᢱ㔚ᳰ䉧䉴᜛ᢔጀౝ⚦ሹ᦭ലඨᓘಽᏓ䈮෸䈿䈜䉶䊌䊧䊷䉺䊶䊥䊑䈱ലᨐ*ਛᎹ ඳผ䋨ർᶏ㆏ᄢ䋩䋬Ꮏ⮮ ৻ᒾ䋬㤥↰ ᣿ᘏ䋬⊕⍹ㆯᄥ㇢
B2-214 PEFC න䉶䊦ౝ᷷ᐲ䊶‛⾰䊶㔚ᵹኒᐲಽᏓ䈮෸䈿䈜䉧䉴ଏ⛎ᣇᴺ䈱ᓇ㗀⹏ଔ*᫪ᧄ ᷕᔒ䋨ਃ㊀ᄢ䋩䋬⷏᧛ 㗼䋬ằ⼱ ஜ৻䋬ᑝ↰⌀ผ䋬ਛ᧛ ⟵ᒄ䋨᧲㇌䉧䉴䋩䋬ዊፉ ᱜ༹䋬ᚑ↰ 㓷ᒾ಴․ᕈ䋩Ꮏ⮮ ৻ᒾ䋨ർᶏ㆏ᄢ䋩䋬㤥↰ ᣿ᘏ䋬㋈ᧁ 㓳ੱ䋬*ᩊ⼱ ┨ੳ
B2-225 ᗵ᳓⹜㛎⚕䈮䉋䉎 PEFC 䉝䊉䊷䊄஥᳓ಽ⁁ᘒ䈱นⷞൻ⸘᷹*ᮮ੗ 㓁㚍䋨੩ㇺᎿ❫ᄢ䋩䋬⷏↰ ⠹੺䋬ᵤፉ ዁ม䋨᧲੩Ꮏᄢ䋩䋬ᐔ੗ ⑲৻㇢㪙㪉㪄㪉㪊㩷 㩷 㪈㪊䋺㪋㪇㵨㪈㪌䋺㪇㪇㩷 䌏䌓䋺㩷 ᳓⚛䉣䊈䊦䉩䊷ᛛⴚ䋳㩷
B2-231 䊧䊷䉱⺃⿠Ⱟశ䉕↪䈇䈢Άᢱ㔚ᳰౝ䉧䉴ᵹേ䈱⸘᷹
*㋈ᧁ ፏᒄ䋨᧲੩Ꮏᄢ䋩䋬ᵤፉ ዁ม䋬ᐔ੗ ⑲৻㇢
B2-232 䊤䊙䊮ಽశ䈮䉋䉎 PEFC 㔚⸃⾰⤑ౝ᳓䈱േ⊛᜼േ⸃ᨆ*દ⮮ ␞䋨᧲੩Ꮏᄢ䋩䋬↰ᷗ 㓶৻㇢䋬ᵤፉ ዁ม䋬
ᐔ੗⑲৻㇢
B2-233 ㄭ⿒ᄖๆ෼ಽశᴺ䈮ၮ䈨䈒 PEFC 䉦䉸䊷䊄஥㔚ᭂౝ䈱᳓ಽ㊂᷹ቯ*⍹દ ᔒⴕ䋨੩ㇺᎿ❫ᄢ䋩䋬⷏↰ ⠹੺䋬ᵤፉ ዁ม䋨᧲੩Ꮏᄢ䋩䋬ᐔ੗ ⑲৻㇢
B2-234 㪥㪤㪩 䉶䊮䉰䊷䈮䉋䉎Άᢱ㔚ᳰ䈱⊒㔚㔚ᵹ䈫 㪧㪜㪤 ౝ฽᳓㊂䈱ⓨ㑆ಽᏓ䈫ᤨ㑆ᄌൻ䈱⸘᷹* ᮮ ౝ ᐽ ᄦ 䋨ᘮ ᙥ ᄢ 䋩 䋬 ዊᎹ ㇌ ᐽ 䋬 ᜙Ꮷ ᥓ ਯ
䋨MRTechnology䋩䋬દ⮮ ⴧᐔ䋨਻Ꮊᄢ䋩䋼㩷 㪚㪈 ቶ㩷 䋾㩷㪚㪈㪄㪉㪈㩷 㩷 㪐䋺㪇㪇㵨㪈㪇䋺㪇㪇㩷 ᒝ೙ኻᵹ䋳㩷
C1-211 ⥄േゞ↪⸅ᇦ䉮䊮䊋䊷䉺䈱᳇ᵹ䊂䊐䊧䉪䉺ᕈ⢻䈮䈍䉋䈿䈜⣂േᵹ䈱ᓇ㗀*ᄢ↰ ආ຦䋨หᔒ␠ᄢ䋩䋬↰ਛ ᘕ਽䋬⼱Ꮉ ඳ຦䋨⥰㢬㜞ኾ䋩䋬⥱ᧁ ᴦ㇢䋨หᔒ␠ᄢ䋩䋬ᐔ↰ ൎ຦
C1-212 ო㕙䈎䉌䈱䊘䊥䊙䊷ṁᶧṡ಴䈮䉋䉎ੂᵹ៺ᡂᛶ᛫ૐ
ᷫ䈱ታ㛎⊛⎇ⓥ䋨ო㕙៺ᡂଥᢙ䈫䊘䊥䊙䊷ỚᐲಽᏓ䈱᷹ቯ䋩*ዊ㊁ἑ ᵏᐘ䋨᧲੩ℂᄢ䋩䋬ᧄỈ ᡽᣿䋬᧖↰ ᅑ䋬ጤᧄ ⮍䋨᧲੩ㄘᎿᄢ䋩䋬቟⮮ ⵨෹䋨ᶏᛛ⎇䋩䋬ජ↰ື਽䋬Ꮉญ 㕏ᄦ䋨᧲੩ℂᄢ䋩
C1-213 ᦛ▤ㇱ䈮䈍䈔䉎಄ᚱ↪ẜᾲ䊙䉟䉪䊨䉦䊒䉶䊦䉴䊤䊥䊷䈱ᾲવ㆐䈮㑐䈜䉎⎇ⓥၳㇱ ᣿ᒾ䋨ጟጊᄢ䋩䋬ᤐᧁ ⋥ੱ䋬*⮮ේ ⵨৻㪙㪉㪄㪉㪉㩷 㩷 㪈㪇䋺㪊㪇㵨㪈㪉䋺㪈㪇㩷 䌏䌓䋺㩷 ᳓⚛䉣䊈䊦䉩䊷ᛛⴚ䋲㩷㪚㪈㪄㪉㪉㩷 㩷 㪈㪇䋺㪊㪇㵨㪈㪈䋺㪌㪇㩷 ᒝ೙ኻᵹ䋴㩷
B2-221 ᩭ䊤䊔䊥䊮䉫⸘᷹䈮䉋䉎 PEFC 㔚⸃⾰⤑ౝ᳓ಽャㅍ⸃ᨆ*⮮੗ ⟵༑䋨᧲੩Ꮏᄢ䋩䋬ᵤፉ ዁ม䋬ᐔ੗ ⑲৻㇢
B2-222 PEFC ౝ᳓⫳᳇䊶ᶧ૕᳓ㅘㆊ䈮ኻ䈜䉎䉧䉴᜛ᢔጀ䈱ౝㇱ᭴ㅧ䈱ᓇ㗀*ችᧄ ᷕ৻䋨↥✚⎇䋩䋬ᄢᐔ ᷕᐔ䋬ᷰㇱ ㇊⟤䋬ᮮጊ ᶈม䋬ጊᧄ ⟵᣿
B2-223 ࿕૕㜞ಽሶᒻΆᢱ㔚ᳰౝ䈱᳓ಽ᜼േ䈮෸䈿䈜䉶䊌䊧䊷䉺䊥䊑䈱ᓇ㗀*⼱Ꮉ ᵗᢥ䋨਻ᎺᎿᄢ䋩䋬ችፒ ⵨᮸䋬㢬↰ 㓉ᴦ
B2-224 ⷫ᳓ᕈಾ䉍ᰳ䈐ᢿ㕙❫⛽䈱᳓ಽ⫳ᢔ․ᕈ䊝䊂䊦ൻ䋨࿕૕㜞ಽሶဳΆᢱ㔚ᳰⷫ᳓ᕈ䉧䉴᜛ᢔጀ䈱᳓ឃ

વᾲ 2009 ᐕ 4 ᦬- 81 -

C1-221 ᦛ䈏䉍䉼䊞䊈䊦ੂᵹᾲવ㆐䈱೙ᓮ䈮㑐䈜䉎ၮ␆⊛⎇ⓥ*ౝ↰ 㜞ᔒ䋨ᣂẟᄢ䋩䋬᧻ේ ᐘᴦ䋬ਃᶆ ⾆ᐢ䋬ᰞ੗ ◊C1-222 䊂䊦䉺⠢೉䈮䉋䉎 T ᒻวᵹ▤ౝ䈱ੂᵹᷙวଦㅴᲫ೑ ᳯ㉿䋨ฬฎደᄢ䋩䋬⮮᳗ ⚔ၮ䋬ች⿧ ᥓ਽䋨ਃ㊀ᄢ䋩䋬*ᑝ↰ ⌀ผ䋬ᵻ㊁ ⑲ᄦ䋨䊂䊮䉸䊷䋩
C1-223 䊅䊉᭴ㅧવᾲ㕙䈱વᾲ․ᕈ䈮㑐䈜䉎⎇ⓥ*ᳯ㉿ ᐘ৻㇢䋨ේሶജᯏ᭴䋩䋬⼱Ꮉ ዏ䋬᭑ᨑ ᐙ↵
C1-224 㘑ะ䈐䈏ᄌൻ䈜䉎ᮮ㘑䉕ฃ䈔䉎㜞᷷ྃᵹ䈱᷷ᐲ႐ផቯ䋨䉴䊁䊧䉥↹௝䈮䉋䉎㘑ะ䈐䈱᛽಴䈫᷷ᐲផቯ

J. HTSJ, Vol. 48, No. 203

߅⍮ࠄߖ
ᴺ䈱ᡷༀ䋩
*ਛ⼱ ᕺਃ䋨ᘮᙥᄢ䋩䋬ᚻႦ ⧷ᤘ䋬᫪ ᴦ༹䋨᧲੩㔚ജ䋩䋬⪉↰ ౏৻䋨ᘮᙥᄢ䋩㪚㪈㪄㪉㪊㩷 㩷 㪈㪊䋺㪋㪇㵨㪈㪌䋺㪇㪇㩷 ᾲᯏེ䊶ᾲ੤឵ེ䋱㩷
C1-231 ᄙ⋡⊛ᦨㆡᛛⴚ䉕↪䈇䈢䊏䊮䊐䉞䊮䊍䊷䊃䉲䊮䉪䈱⸳⸘*ၳౝ ᢘ੺䋨ᣣ┙⵾૞ᚲ䋩䋬⷏ේ ᷕᄦ䋬᧖᧛ ๺ਯ
C1-232 ᾲ㖸㗀⥄ബᝄേ䈱ᢙ୯䉲䊚䊠䊧䊷䉲䊢䊮*ዊᷡ᳓ ቁᄦ䋨ർ਻Ꮊ㜞ኾ䋩䋬═የ ᄢ૞䋬ਭ଻↰⵨Ꮘ䋨਻Ꮊᄢ䋩䋬㜞↰ ଻ਯ䋬દ⮮ ⁴ብ䋨᧲੝ᄢ䋩
C1-233 䊪䉟䊟䊷ဳ䌊䌔䊙䉟䉪䊨಄ಓᯏ䈱⎇ⓥ*ᴡ㊁ ᱜ㆏䋨਻Ꮊᄢ䋩䋬↰ㄝ ෘ䋬㎓ᧄ ዁ᔒ䋬ਭ଻↰ ⵨Ꮘ䋬㜞↰ ଻ਯ
C1-234 ⍱ᒻᢿ㕙䉕ᜬ䈧䊙䉟䉪䊨䉫䊦䊷䊑ౝ䈱⫳⊒䈮䈍䈔䉎ᾲ‛⾰ャㅍ․ᕈ*ᷰㄝ ⵨Ꮖ䋨᧲੩ᄢ䋩䋬⊕ᮯ ੌ䋬⷏የ ⨃ᢥ䋼㩷 㪚䋲ቶ㩷 䋾㩷㪚㪉㪄㪉㪈㩷 㩷 㪐䋺㪇㪇㵨㪈㪇䋺㪉㪇㩷 䌏䌓䋺㩷 䉣䊈䊦䉩䊷ᄌ឵䉲䉴䊁䊛䋱㩷
C2-211 ⋥ធౝㇱᡷ⾰䉕ⴕ䈉ਛૐ᷷૞േᐔ᧼ဳ SOFC 䈱ᢙ୯⸃ᨆጊᧄ ᐽᒄ䋨੩ㇺᄢ䋩䋬*ጤ੗ ⵨䋬㥲⮮ రᶈ䋬ศ↰⧷↢
C2-212 SOFC 㔚ᭂᕈ⢻䈫෻ᔕ㗔ၞ䈮ኻ䈜䉎․ᕈ㐳䈘䈱ᓇ㗀
*⚬㊁ ᤘ↢䋨੩ㇺᄢ䋩䋬ጤ੗ ⵨䋬㥲⮮ రᶈ䋬ศ↰⧷↢
C2-213 Pt(111)⴫㕙䈮䈍䈔䉎㉄⚛ㆶర෻ᔕ⚻〝䈫ㆊ㉄ൻ᳓⚛䈱↢ᚑ᜼േ*ᄢ㑆 ᢕผ䋨᧲੩Ꮏᄢ䋬ᣣ↥䋩䋬Ꮢደ ථ䋨᧲੩Ꮏᄢ䋩䋬ફା ৻ᘮ䋬ጟፒ ஜ
C2-214 Άᢱ㔚ᳰ䈱ಽశ⸘᷹ [12] 䊤䊙䊮ಽశᴺ䈮䉋䉎䈠䈱႐᷷ᐲ⸘᷹*᫪↰ ᚑᤘ䋨ฬฎደᄢ䋩䋬㊁↰ ๺ቁ䋬ች↰ ᐽผ䋨ฬฎደᏒᎿ⎇䋩䋬ർᎹ ㇌ⴕ䋨ฬฎደᄢ䋩*ᄢ⍹ 㓶䋨หᔒ␠ᄢ䋩䋬ဈᧄ ⋿৻䋨ṑ⾐⋵ᄢ䋩䋬ർ⼱ ⵨ᰴ䋨หᔒ␠ᄢ䋩䋬ᷰㄝ ᅢ┨
C2-225 ⿥⥃⇇ CO2 䉕૞േᇦ૕䈫䈜䉎䉧䉴䉺䊷䊎䊮䈱ේℂᬌ⸽ታ㛎⸘↹*ቝᄙ᧛ రᤘ䋨᧲੩Ꮏᄢ䋩㪚㪉㪄㪉㪊㩷 㩷 㪈㪊䋺㪋㪇㵨㪈㪌䋺㪇㪇㩷 䌏䌓䋺㩷 䉣䊈䊦䉩䊷ᄌ឵䉲䉴䊁䊛䋳㩷
C2-231 䉸䊉䉬䊚䉴䊃䊥ലᨐ䈮䉋䉎䊋䉟䉥䊂䉞䊷䉷䊦Άᢱ䋨䌂䌄䌆䋩䈱㜞ല₸วᚑ䈍䉋䈶ᔕ↪
ᧇ ካ䋨㕒ጟℂᎿ⑼ᄢ䋩䋬*⿧೨ ෹♿䋬࿯ደ 㜞ᔒ䋬ᒛ ᆭ❀䋨ධบ⑼ᛛᄢ䋩䋬⫟ ാ䋨ਛ࿖⑼ᛛᄢ䋩
C2-232 ᳓䉣䊙䊦䉳䊢䊮Άᢱ䈱䊗䉟䊤䈻䈱೑↪䈮㑐䈜䉎⎇ⓥ*䉼䊦䊛䉫䋨᧲੩Ꮏᄢ䋩䋬ศᎹ ㇌ᄦ䋬┻ਅ ᣽ᓼ䋨䉪䊥䊷䊮䊜䉦䊆䉦䊦䋩䋬⮮ේ ᶈ৻
C2-233 ᄙሹ⾰ Ni ⸅ᇦ䉕↪䈇䈢䉶䊦䊨䊷䉴䈱ᾲಽ⸃䈮㑐䈜䉎৻⠨ኤ*૒⮮ ⠍䋨᧲੩Ꮏᄢ䋩䋬㕍ᧁ ৻ᤩ䋬⧎᧛ సᖗ
C2-234 ㆊᾲ᳓⫳᳇䉕↪䈇䈢㜞฽᳓ᑄ᫈‛ౣΆᢱൻ䉲䉴䊁䊛䈱ᦨㆡㆇォᚻᴺ䈱ឭ᩺*ਣጊ ⋥᮸䋨ਃ㊀ᄢ䋩䋬↰ਛ ᄢテ䋬₹↰ ల䋬ᷡ᳓ବ♿䋨䉝䊷䉻䋩䋬ᑝ↰ ⌀ผ䋨ਃ㊀ᄢ䋩䋼㩷 㪛 ቶ㩷 䋾㩷㪛㪄㪉㪈㩷 㩷 㪐䋺㪇㪇㵨㪈㪇䋺㪉㪇㩷 䊙䉟䉪䊨વᾲ䋱㩷
D-211

D-212

D-213

D-214

㪚㪉㪄㪉㪉㩷 㩷 㪈㪇䋺㪊㪇㵨㪈㪉䋺㪈㪇㩷 䌏䌓䋺㩷 䉣䊈䊦䉩䊷ᄌ឵䉲䉴䊁䊛䋲㩷
C2-221 ㅴൻ⊛䉝䊦䉯䊥䉵䊛䈮䉋䉎䉸䊷䊤䊷䉮䊮䉶䊮䊃䊧䊷䉺䈱ᦨㆡ⸳⸘*ጊ↰ ᣹䋨㐳ጟᛛ⑼ᄢ䋩䋬ዊᎹ ᢘਭ䋬⷏Ꮉ ᄥᦶ
C2-222 ᄥ㓁䉣䊈䊦䉩䊷㜞ല₸೑↪䈱䈢䉄䈱ᾲ㔚ᄌ឵䉲䉴䊁䊛䈱ᬌ⸛*㜞ự ㆯᐔ䋨ችၔᄢ䋩䋬⍫㊁ ᱦ๺䋬㋈ᧁ ৻ⴕ
䋨JAST)䋬ᧁ⋁ ਌ੱ䋨JAXA)䋬ਭ଻ ೣᢥ䋨䉳䊷䉟䊷䉣䉴䋩䋬⍹Ꮉ ᧲৻㇢䋨JAST䋩䋬ᣂ㊁ ᱜਯ
C2-223 䊒䊧䊷䊃ᑼᾲ੤឵ེౝㇱᾲᵹേ䈮෸䈿䈜䊒䊧䊷䊃ᒻ⁁䈱ᓇ㗀*㠽ዬ ୃ৻䋨ᾢᧄᄢ䋩䋬ᴰ ໪ᄥ䋬ዊ♻ ᐽᔒ䋬ን᧛ኼᄦ
C2-224 䊦䊷䊒▤ᣇᑼᾲ㖸㗀಄ළ䉲䉴䊁䊛䈱ታ↪ൻ䈮ะ䈔䈢⎇ⓥ䋨ᝄേᵹ႐䈮䈍䈇䈩ᾲ੤឵ེ䈱ᒻ⁁䈏಄ළ⢻ജ䈍䉋䈶▤ౝ㖸႐䈮ਈ䈋䉎ᓇ㗀䋩

વᾲ 2009 ᐕ 4 ᦬- 82 -ု⋥㈩ะනጀ䉦䊷䊗䊮䊅䊉䉼䊠䊷䊑⤑䈱ᾲવዉ․ᕈ䈮䈧䈇䈩*⍹Ꮉ ᩵䋨᧲੩ᄢ䋩䋬↰ਛ ਃ㇢䋨਻ᎺᎿᄢ䋩䋬ችፒᐽᰴ䋬Ⴎ⷗ ᷕ৻㇢䋨᧲੩ᄢ䋩䋬ਣጊ ⨃ᄦp ဳ䊎䉴䊙䉴䊁䊦䊤䉟䊄䉕↪䈇䈢䊅䊉ᄙሹ૕⭯⤑䈱ᾲવዉ₸⸘᷹*↰ਛ ਃ㇢䋨਻ᎺᎿᄢ䋩䋬ችፒ ᐽᰴ䋬Ⴆᧄ ኡ
㐳〒㔌䊋䊥䉴䊁䉞䉾䉪ᾲવዉ䉕䉅䈢䉌䈜ᣂ᧚ᢱ䋨䋱䋮䊅䊉䉶䊮䉰䉕↪䈇䈢ᾲવዉ₸⸘᷹䋩*㜞ᯅ ෘผ䋨਻Ꮊᄢ䋩䋬↢↰ ┥਽䋬દ⮮ ᵗᐔ䋬ᒛ⥝䋨ᷡ⪇ᄢ䋩䋬⮮੗ ਍ᄦ䋨↥✚⎇䋩
㐳〒㔌䊋䊥䉴䊁䉞䉾䉪ᾲવዉ䉕䉅䈢䉌䈜ᣂ᧚ᢱ䋨䋲䋮㕖ᐔⴧಽሶേജቇᴺ䈮䉋䉎ᾲャㅍ⸃ᨆ䋩*દ⮮ ᵗᐔ䋨਻Ꮊᄢ䋩䋬੗਄ ੳੱ䋬㜞ᯅ ෘผ㪛㪄㪉㪉㩷 㩷 㪈㪇䋺㪊㪇㵨㪈㪉䋺㪈㪇㩷 䊙䉟䉪䊨વᾲ䋲㩷
D-221

D-222
D-223

D-224

D-225

䉦䊷䊗䊮䊅䊉䉼䊠䊷䊑ౝㇱ䈮䈍䈔䉎නጀ䉦䊷䊗䊮䊅䊉䉼䊠䊷䊑䈱↢ᚑ*દ⼺ ᅢผ䋨᧲੩ᄢ䋩䋬Ⴎ⷗ ᷕ৻㇢䋬ਣጊ ⨃ᄦ࿕૕ᾲવዉ⸃ᨆ䈱䈢䉄䈱䌄䌓䌍䌃ᴺ䈱㐿⊒ጟ㊁ ⌀ᒎ䋨੩ㇺᄢ䋩䋬☿↰ ␭੺䋬*᧻ᧄ లᒄ䊙䉟䉪䊨䊃䊧䊮䉼ౝㇱ䈱 SBA-15 ⤑䈱 1 ᰴర㈩ะ*Ꮟ ⋥਽䋨᧲੩ᄢ䋩䋬ᄢችม ໪ᢥ䋬 ጟ 㦷䋨↥✚⎇䋩䋬㆙⮮ ᣿ု⋥㈩ะනጀ䉦䊷䊗䊮䊅䊉䉼䊠䊷䊑⤑䈱⦡⚛Ⴧᗵဳᄥ㓁㔚ᳰ㔚ᭂ䈻䈱ᔕ↪
ᄢᎹ Ả䋨᧲੩ᄢ䋩䋬*䉣䊥䉾䉪 䉣䉟䊅䊦䉸䊮䋬Ⴎ⷗ ᷕ৻㇢䋬ਣጊ ⨃ᄦ䉦䊷䊗䊮䊅䊉䉼䊠䊷䊑䈮䈍䈔䉎৻ᰴరബ⿠ሶỚᐲ

J. HTSJ, Vol. 48, No. 203߅⍮ࠄߖ਄㒢䈱ሽ࿷䋨㕖✢ᒻⰯశബ⿠ಽశ䈫ℂ⺰䊝䊂䊦䋩*᧛਄ 㓁৻䋨᧲੩ᄢ䋬䊤䉟䉴ᄢ䋩䋬ᴡ㊁ ᷕ৻㇢䋨䊤䉟
䉴ᄢ䋩

F-225

㪛㪄㪉㪊㩷 㩷 㪈㪊䋺㪋㪇㵨㪈㪌䋺㪇㪇㩷 䊙䉟䉪䊨વᾲ䋳㩷
D-231

D-232

D-233

D-234

ੑṁᶧᷙว႐䈮䈍䈔䉎ო㕙䉷䊷䉺㔚૏䈍䉋䈶㔚᳇ᶐㅘᵹㅦᐲ䈱หᤨ⸘᷹↰ਛ 㓶ᄥ䋨ᘮᙥᄢ䋩䋬ችᎹ ୃ䋬ཅ೽ ⵨䋬૒⮮ ᵗᐔ
Experimental Investigation of Microchannel Fluid
Flow
Ying Wang (Beijing Univ. Tech.), Yanhua Diao,*Yaohua Zhao
䊙䉟䉪䊨䉼䊠䊷䊑䉕ᵹ䉏䉎䉧䉴ᵹ䈱ᾲવ㆐․ᕈ
*ጊᧄ ⾆᥍䋨᧲੩ℂᄢ䋩䋬ᵩ ቯ᧜䋬ᵻฎ ⼾䋨㚂ㇺ
ᄢ䋩䋬㋈ᧁ ᐽ৻䋨᧲੩ℂᄢ䋩࿕૕ၮ᧼਄䉕᜛䈏䉎ᶧṢ䉮䊮䉺䉪䊃䊤䉟䊮೨ᣇ䈪䈱వⴕ⭯⤑ᒻᚑㆊ⒟*਄㊁ ৻㇢䋨᧲੩ℂᄢ䋩䋬ᑝἑ ኡੑ䋬ᧁፒ ⵨੺㪝㪄㪉㪈㩷 㩷㪐䋺㪇㪇㵨㪈㪇䋺㪉㪇㩷 ᾲ‛ᕈ䋱㩷

F-211⭯᧼᧚ᢱ䈱⺃ዉടᾲታ㛎㩷*᧻ፉ ᩕᰴ䋨ᄢ㒋Ꮏᄢ䋩䋬౎㊀᎑ ⋭๋஍శㄭធ႐䉕↪䈇䈢㜞ᗵᐲ䊅䊉䉴䉬䊷䊦᷷ᐲ᷹ቯ
ᚻᴺ䈱㐿⊒䋨╙৻ႎ㩷 ᷹ቯේℂ䈱ᬌ⸽䈍䉋䈶ᓥ᧪ᴺ䈫䈱ᗵᐲᲧセ䋩═ដ ೑ᓆ䋨ᘮᙥᄢ䋩䋬*଻ဈ ବテ䋬↰ญ ⦟ᐢ䋬ᢪᧁ ᢅᴦ䋬㐳ဈ 㓶ᰴ䉴䉺䊮䊒ဳធ⸅䉶䊮䉰䈮䉋䉎࿕૕䈱ᾲャㅍᕈ⾰䈱᷹ቯ䈮㑐䈜䉎⸃ᨆ
*ᄢ๺↰ ⍮Ꮧ䋨਻Ꮊᄢ䋩䋬ศ↰ ື㇢䋬ౝ↰ᖗ䋬㜞᧻ ᵗ䊗䉟䊄䉴䊤䊑䈱᦭ലᾲવዉ₸䈱ផ▚ᑼ䈮䈧䈇䈩*ን᧛ ኼᄦ䋨ᾢᧄᄢ䋩䋬ዊ♻ ᐽᔒ䋬㠽ዬ ୃ৻䋬ᩉ⻞৻䋨਻Ꮊᄢ䋩䋬ጊ㦮 ⾫ᴦ䋨䉻䉟䉰䊮䋩䋬ጼర ᐙ਽

F-212

F-213

F-214

㩷
㪝㪄㪉㪉㩷 㩷
F-221
F-222

F-223

F-224

㪈㪇䋺㪊㪇㵨㪈㪉䋺㪈㪇㩷 ᾲ‛ᕈ䋲㩷

F-231

F-232

F-233

- 83 -

䊧䊷䉱䊷⺃⿠⺃㔚ᵒേ䉕↪䈇䈢ᣂ䈚䈇శቇ⊛ዊဳ᜛ᢔ䉶䊮䉰䊷䈱⎇ⓥ䋨╙৻ႎ䋺᷹ቯේℂ䈱ᅷᒰᕈ䈱ᬌ⸽෸䈶⋧੕᜛ᢔ⃻⽎䈱ⷰኤ䋩ⱃሶ੗ ᣿䋨ᘮᙥᄢ䋩䋬*ⁿ⼱ ᕡ৻䋬↰ญ ⦟ᐢ䋬㐳ဈ 㓶ᰴᑄ㘩ᴤ䊋䉟䉥䊂䉞䊷䉷䊦Άᢱ䈍䉋䈶☻䉫䊥䉶䊥䊮䈱ኒᐲ䈱᷷ᐲଐሽᕈ㗇⍮ ᚑశ䋨⑺↰⋵ᄢ䋩䋬*ട⮮ ᘕ਽䋬ᣣะ㊁ ਃ㓶ᷙว䊒䊤䉴䉼䉾䉪లႯጀ䈱᣹᷷ㆊ⒟䈮䈍䈔䉎ᷫኈㅦᐲ䈱ᚑಽỚᐲଐሽᕈ*ศ↰ ◊ผ䋨ጊญᄢ䋩䋬↰ਯ਄ ஜ৻㇢䋬⷏᧛ 㦖ᄦ䋬ጊፒ ᘮ䋬Ꮉਛ 㓉ม䋬ᮮ↰ ቞ਭ䋨ቝㇱ⥝↥䋩ૐ᷷㜞࿶ၞ䈮䈍䈔䉎㔺ὐ᷹ቯ䈫㔺ὐផ▚ᴺ*⍹↰ ⾫ᴦ䋨૒⾐ᄢ䋩䋬㐷಴ ᡽ೣ䋬᭢᧛ ቁၮ䋬⍹ේ ᄢኡ䋼㩷 䌇ቶ㩷 䋾㩷㪞㪄㪉㪈㩷 㩷 㪐䋺㪇㪇㵨㪈㪇䋺㪇㪇㩷 䈸䈒኿વᾲ䋱㩷
G-211

G-212
G-213

᷷ᐲ䊶Ớᐲ䈱ੂᵹᄌേ䈏Ἱౝ᡼኿વᾲ䈮෸䈿䈜ᓇ㗀䈱ၮ␆⊛ᬌ⸛㩷*ዊ⷏ ஜ਽䋨੩ㇺᎿ❫ᄢ䋩䋬ጟᧄ ㆐ᐘ䉡䉤䊷䉺䊷䉦䊷䊁䊮䊊䉡䉴䈮䉋䉎᡼኿વᾲ೙ᓮ*દ็ ┥ᄥ䋨ችၔᄢ䋩䋬ጤፒ ᵏ᳗䋨ችၔㄘ࿦⎇䋩㜞᷷᧦ઙਅ䈮䈍䈔䉎ᄢⷙᮨ䈭䉲䉢䊦䉝䊮䊄䉼䊠䊷䊑ဳᾲ੤឵ེ䈱䋳ᰴరᢙ୯⸃ᨆ*ඨ↰ 㓷ੱ䋨ᣣ┙䋩䋬ጊᧄ ⎇ੑ䋬ਅ㇭ ཅᄢ䋨䊋䊑ᣣ┙䋩㩷㪞㪄㪉㪉㩷 㩷 㪈㪇䋺㪊㪇㵨㪈㪉䋺㪈㪇㩷 䈸䈒኿વᾲ䋲㩷
G-221

MEMS 䉕↪䈇䈢ⶄวᾲಽᨆᴺ䈱⎇ⓥ㩷*᧖ᧄ ᜏ਽䋨᣿ᴦᄢ䋩䋬ችᎹ ᐘᒄ䋬ਛ೎ᐭ ୃ䊙䉟䉪䊨䊎䊷䊛䉶䊮䉰䈮䉋䉎ᭂᓸ㊂ᵹ૕䉰䊮䊒䊦䈱ᾲવዉ₸᷹ቯᴺ䋨ℂ⺰⸃ᨆ䈮䉋䉎ᬌ⸛䋩*↰ਛ ೑ᐘ䋨਻Ꮊᄢ䋩䋬Ⓑ↰ ᢎ੺䋬ౝ↰ ᖗ䋬㜞ᯅෘผ䋬⮮੗ ਍ᄦ䋨↥✚⎇䋩䋬㜞᧻ ᵗ䋨਻Ꮊᄢ䋩ᾲવዉ⇣ᣇᕈ䉕᦭䈜䉎ฦ⒳㊄ዻ❫⛽᧚ᢱ䈱ᾲવዉ₸᷹ቯ*ᤐᧁ ⋥ੱ䋨ጟጊᄢ䋩䋬Ⓑ⪲ ⧷↵䋨ᵤጊ㜞ኾ䋩䋬ၳㇱ ᣿ᒾ䋨ጟጊᄢ䋩䋬Ꮉᧄ ⵨ᄥ
Comparison of Calculation Methods for the Transient
Short-Hot-Wire Thermal Conductivity Measurement
Problem*Peter Lloyd Woodfield (AIST), Shogo Moroe(Kyushu Univ.), Jun Fukai䋬Motoo Fujii (AIST)䋬
Yasuyuki Takata (Kyushu Univ.) 䋬 Kanei Shinzato

વᾲ 2009 ᐕ 4 ᦬䌆㪄㪉㪊㩷 㩷 㪈㪊䋺㪋㪇㵨㪈㪌䋺㪇㪇㩷 ᾲ‛ᕈ䋳㩷

F-234

䋼㩷 䌆ቶ㩷 䋾㩷(AIST)
ㆊᷰ䊧䊮䉵ലᨐ䈮䈍䈔䉎శ䊶‛⾰䊶᷷ᐲ႐䈱⋧੕૞↪䈱ၮ␆⎇ⓥ*䊄䉝䊮䊖䊮 䊄䉪䋨᧲੩Ꮏᄢ䋩䋬ජ䇱ጤ ቬᒄ䋬ጊፒ౏᥍䋬ફା ৻ᘮ䋬ጟፒ ஜ

G-222

G-223

G-224

G-225

䉣䊋䊈䉾䉶䊮䊃ᵄ䈮䉋䉎ᾲశ⿠㔚ജ⊒㔚䈱㜞ኒᐲൻ䈮㑐䈜䉎⎇ⓥ㩷*ᵻ㊁ 㓷ᄦ䋨᧲੩Ꮏᄢ䋩䋬⼱ญ ␭ม䋬Ⴧේ ㋕ᐔ䋬⧎᧛సᖗ䉮䊮䊘䉳䉾䊃㕙䈪ⷒ䉒䉏䈢ᄥ㓁ᾲᧁ᧚ੇ῎䊊䉡䉴䈱ᕈ⢻⸃ᨆ䈫ታ⸽⹜㛎㚍႐ ᒄ䋨రർ⷗Ꮏᄢ䋩䋬*㊄ጊ ౏ᄦ䋬ฎ⾐ା਽䋨਻Ꮊᄢ䋩䋬⩲ේ ᥓ⟤䋨䊙䊦䉲䊢䉡ᛛ⎇䋩䉮䊮䊘䉳䉾䊃㕙䈪ⷒ䉒䉏䈢ਇㅘ᣿䊊䉡䉴䈻䈱ᄥ㓁శ䈱౉኿෸䈶㓸ᾲ⸃ᨆ*㊄ጊ ౏ᄦ䋨రർ⷗Ꮏᄢ䋩䋬㚍႐ ᒄ䋬ฎ⾐ ା਽䋨਻ᄢ䋩䋬⩲ේ ᥓ⟤䋨䊙䊦䉲䊢䉡ᛛ⎇䋩᡼኿಄ළ
* AhmadJalilvand 䋨 Fujikura 䋩 䋬 Masataka
Mochizuki 䋬 Aliakbar Akbarzadeh 䋨 RMIT Univ. 䋩 䋬Raneep Singh౻䈱ᶎቶ䈱ო䈱᷷ᐲಽᏓ䈫䈠䈱ო䈫૕⴫㕙䈫䈱㑆䈱䈸䈒኿વᾲ

J. HTSJ, Vol. 48, No. 203߅⍮ࠄߖ*’㊁ ବ㇢䋨੩ㇺᄢ䋩
I-232㪞㪄㪉㪊㩷 㩷 㪈㪊䋺㪋㪇㵨㪈㪌䋺㪇㪇㩷 䈸䈒኿વᾲ䋳㩷
G-231

G-232

G-233

G-234

ደᩮⲢ㔐䈮䈍䈇䈩ౝㇱ᭴ㅧ䈏Ⲣ㔐䈮෸䈿䈜ᓇ㗀㩷቟ේ ⮍䋨ጊᒻᄢ䋩䋬*ᩉ↰ ᐽ৻䋬Ꮉᵤ ૓ᄥ䋬ᮮጊቁ↵䋬㒙ㇱ ୃ䋨㒐ἴ⑼⎇䋩ಝ❗ᇦ૕Ⴚ⇇㕙䉕฽䉖䈣㐽ⓨ㑆䈮䈍䈔䉎䈸䈒኿䋭ኻᵹⶄวવᾲᢙ୯⸃ᨆᄢ᎑ ஜᄥ㇢䋨ᮮᵿ࿖ᄢ䋩䋬*㈬੗ ๋ᷡ䋬౞ጊ ㊀⋥䋨᧲ർᄢ䋩ᒝ䈇ᄙ㊀ᢔੂലᨐ䉕઻䈉☸ሶ⟲ਛ䈱䈸䈒኿વᾲ໧㗴䈻䈱⸘▚㔚⏛᳇ቇ䈎䉌䈱䉝䊒䊨䊷䉼*ጟᧄ ㆐ᐘ䋨੩ㇺᎿ❫ᄢ䋩䋬ฬႮ ඳผⶄว䋲㊀䉰䉟䉪䊦Ⴚ⇇᧦ઙ䉕䉅䈧 Stokes ╙䋲໧㗴*⿧ᓟ ੫ਃ

I-233

I-234

䋼㩷 㪡 ቶ㩷 䋾㩷㪡㪄㪉㪈㩷 㩷㪐䋺㪇㪇㵨㪈㪇䋺㪉㪇㩷 ⥄ὼ䉣䊈䊦䉩䊷䋱㩷J-211ᢙ୯䉲䊚䊠䊧䊷䉲䊢䊮䈮䉋䉎ฦ⒳⥩ⵝ૕䈱Ⲣ㔐⢻ജᬌ⸛*ጊญ ᱜᢅ䋨JGD䋩䋬ᮮጊ ቁ↵䋨ጊᒻᄢ䋩䋬ᴧỈ ༑
৻䋨JGD䋩䋬ၳ㊁ ⟵ੱ䋬቟ᒾ ብੱ䋬቟ේ ⮍䋨ጊᒻᄢ䋩࿾ਅ᳓䉕฽䉃ᄢ࿾ᾲ೑↪䈮䉋䉎䊍䊷䊃䊌䉟䊒ደᩮⲢ㔐*ᮮጊ ቁ↵䋨ጊᒻᄢ䋩䋬⩵࿾ ዂశ䋨⥱ᒻ䉣䉮䋩䋬ᚭᵤᐢม䋨ጊᒻᄢ䋩䋬ᄢਅ ⌀ผ䋬౎㊀ᮯ ஜᄥ䋬቟ේ ⮍⦡⚛Ⴧᗵᄥ㓁㔚ᳰ䈮䈍䈔䉎㔚⸃⾰ᷝട‛䈱ലᨐ䈮㑐䈜䉎⎇ⓥ*↰ᶆ ⑲ବ䋨᧲੩ᄢ䋩䋬ᄢችม ໪ᢥ㐳ᦼ⫾ᾲ䈱䈢䉄䈱䉸䊷䊤䊷䉲䉴䊁䊛䈱Ⓙ௛․ᕈ
*㚍႐ ᒄ䋨రർ⷗Ꮏᄢ䋩䋬㊄ጊ ౏ᄦ䋼㩷 㪠 ቶ㩷 䋾㩷㪠㪄㪉㪈㩷 㩷㪐䋺㪇㪇㵨㪈㪇䋺㪇㪇㩷 ᄙሹ⾰૕䈱વᾲ䋱㩷

䌉-211

ᄙሹ⾰ౝ䈮䈍䈔䉎᳇ᵃ䊃䊤䉾䊒䊜䉦䊆䉵䊛䈫቟ቯᕈ㩷*⚦Ꮉ ⾆ኡ䋨ᓼፉᄢ䋩䋬ᧃ൮ ື਽䊙䉟䉪䊨䊐䉤䊷䉦䉴 X ✢ CT 䈮䉋䉎᳓㘻๺⍾ጤ䈮ᵈ౉䈘䉏䈢㕖ᷙ๺ᵹ૕䈱นⷞൻ⸃ᨆ* ጟ ੫ੱ䋨᧲੩Ꮏᄢ䋩䋬ᬀ᧛ ⽕䋬ᵤፉ ዁ม䋬ᐔ੗ ⑲৻㇢଻᳓ᕈ䊑䊨䉾䉪䈱ᾲ䊶᳓ಽャㅍ㊂ደᄖታ᷹⹏ଔ䈮㑐䈜䉎⎇ⓥ*ᧁਅ ㅴ৻䋨ᄢ㒋ᐭᄢ䋩䋬ᅏ㊁ ⋥᮸䋬┻⣶ ஜ৻䋬
ศ↰◊ᱜ

J-212

䌉-212

䌉-213

㩷
㪠㪄㪉㪉㩷 㩷
I-221

I-222

I-223

I-224

I-225

㪈㪇䋺㪊㪇㵨㪈㪉䋺㪈㪇㩷 ᄙሹ⾰૕䈱વᾲ䋲㩷

J-213

J-214
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㪡㪄㪉㪉㩷 㩷J-221

X ✢䊤䉳䉥䉫䊤䊐䉞䊷䈮䉋䉎ⓨሹᓘಽᏓ䉕ઃട䈚䈢ᓸ⚦ᄙሹ૕ౝ䈱ᶧ᳓นⷞൻ⸃ᨆ↰ፒ ⼾䋨ᣣ↥⥄䋩䋬㕍ᧁ ᢕ䋬ች↰ ᥓ↢䋬ቝ㜞 ⟵㇢䋨ᮮᵿ࿖ᄢ䋩䋬ጤፒ ᄢ೰䋬*ㄭ⮮ ବ੺䋬㕍ᧁ ᐽ␭LES 䈮䉋䉎ᄙሹ⾰ౝੂᵹ䈱ᢙ୯⸃ᨆ*ᳯේ ⌀ม䋨᧲ർᄢ䋩䋬ᮮፃ ஜᒾ䋨਻Ꮊᄢ䋩䋬ᷡ᳓ᤘᲧฎੑ㊀᭴ㅧᄙሹ⾰૕䈱ㅘㆊ₸*૒㊁ ศᒾ䋨㕒ጟᄢ䋩䋬᪀ේ ਇੑᦶ䋬㊁ญ ᐽᄥ䋬ਛጊ㗼䉮䉝ㇱ䈮ᄙሹ᧚䉕᦭䈜䉎▤〝ౝᒝ೙ኻᵹ䈱ᢙ୯⸃ᨆ䋨╙䋱ႎ䋺⸃ᨆ⊛ᬌ⸛䋩
*Chen Yang䋨㕒ጟᄢ䋩, Wei Liu䋨HUST䋩, ਛጊ 㗼䋨㕒ጟᄢ䋩䊑䊥䊮䉪䊙䊮䊶䊐䉤䊦䉪䊊䉟䊙䊷ᣇ⒟ᑼ䉕↪䈇䈢ᩰሶ䊗䊦䉿䊙䊮ᴺ䈮䉋䉎⇣ᣇᕈᄙሹ⾰૕ౝ⥄ὼኻᵹ⸃ᨆ*ἑ↰ ೰䋨ንጊᄢ䋩㪠㪄㪉㪊㩷 㩷㪈㪊䋺㪋㪇㵨㪈㪌䋺㪇㪇㩷 ᄙሹ⾰૕䈱વᾲ䋳㩷

I-231

ᄙሹ⾰ⷺᩇ䉁䉒䉍䈱ᾲᵹേ․ᕈ
*ᩑᧄ ⋉ᔒ䋨㕒ጟᄢ䋩䋬ጤญ ᵏテ䋬๺ᴰ ൘䋬Ⴧጟ㓉჻䋨ർ਻ᎺᏒᄢ䋩⃿లႯ▤䉕↪䈇䈢㜞䊒䊤䊮䊃䊦ᢙᵹ૕䈱વᾲଦㅴᴺ䈮㑐䈜䉎⎇ⓥ*ᷡ᳓ స⍫䋨᧲ർᄢ䋩䋬⚿ၔ ๺ਭ䋬ᯅῪ ⑲೑䋬⋧⦟ ᣿↵䋨NIFS䋩ㅪ⚿䈍䉋䈶㕖ㅪ⚿ᄙሹ᧚䈱⇇㕙ᾲવ㆐*᪀ේ ਇੑᦶ䋨㕒ጟᄢ䋩䋬૒㊁ ศᒾ䋬Liu Jianjun䋨ᱞṽᎿቇ㒮䋩䋬ਛጊ 㗼䋨㕒ጟᄢ䋩⤘Ả䉕઻䈉☸ሶలႯጀ䈱ㅘ᳓䈫㔚᳇ᶐㅘ*⿒ၳ ආବ䋨㐳ጟᛛ⑼ᄢ䋩䋬㕍ᧁ ๺ᄦ䋬ะ੗ ാ૞

J-222

J-223

J-224

J-225

㪈㪇䋺㪊㪇㵨㪈㪉䋺㪈㪇㩷 ⥄ὼ䉣䊈䊦䉩䊷䋲㩷࿾ਛᾲ䊶ᄥ㓁ᾲ䉕↪䈇䈢Ⲣ㔐䉲䉴䊁䊛䈱㐿⊒*ጊ┵ ା਽䋨⑔੗ᄢ䋩䋬ᐔự ᵏᓼ䋬᳗੗ ੑ㇢䋬ችᧄ ㊀ା䋨⑔੗⋵䋩䋬ጊፒ ਃ⍮ᦶᄢ࿾䈱ᵺൻലᨐ䉕౗䈰䈢ⓣ㐿䈐ᥧᷯ▤䈮䉋䉎㔐᳖಄ᾲណข䈫㒰Ḩᮮጊ ቁ↵䋨ጊᒻᄢ䋩䋬*⧔Ỉ ዏቱ䋬੗ጊ ᶈ৻䋬቟ේ⮍䋬᧖Ỉ 㓉ብ䋨ጊᒻㄘᄢ䋩㔐᳖಄ᾲ䈫⥄ὼ឵᳇䉕೑↪䈚䈢ⓨ⺞䉲䉴䊁䊛ᮮጊ ቁ↵䋨ጊᒻᄢ䋩䋬*㋈ᧁ િᐘ䋬ᣣਅ 㓉ᢥ䋬ᅏጊ ඳᐽ䋨ᷡ᳓ᑪ⸳䋩䋬ች㦮 ஜ䋨ጊ㓁♖ᯏ䋩䋬቟ේ⮍䋨ጊᒻᄢ䋩
㔐ጊ಄ᚱ䉲䉴䊁䊛䈮䈍䈔䉎Ⲣ㔐᳓䈱᦭ല೑↪
ᮮጊ ቁ↵䋨ጊᒻᄢ䋩䋬*ਛ᧛ ੫䋬㒙ㇱ ᄢ૓䋬቟ේ⮍䋬૒⮮ ㊀శ䋨የ⧎ᴛ䋩ᶏᵗ䊋䉟䉥䊙䉴೑↪䈮䉋䉎 CO2 ๆ෼䈫ᣂ䉣䊈䊦䉩㐿⊒䈮㑐䈜䉎⎇ⓥ*ἑฬᵄ ಴䋨℄⃿ᄢ䋩䋬ⴕᧄ ᱜ㓶䋨ਛㇱᄢ䋩䋬ᐔጟ㓷ⷙ䋨㜞⍮ᄢ䋩㪈㪌䋺㪈㪇㵨㪈㪍䋺㪈㪇㩷 䋼㩷 㪛 ቶ㩷 䋾㩷 ․೎⻠Ṷ㩷䇸ᱧผㇺᏒ䊶੩ㇺ䈱᥊ⷰ䊶ⅣႺ䈱ഃ↢䇹㩷੩ㇺᄢቇ㩷 㐷ౝ㩷 ノⴕ㩷 ᢎ᝼㩷㪈㪍䋺㪉㪇㵨㪈㪎䋺㪋㪇㩷 䋼㩷 㪛 ቶ㩷 䋾㩷 ✚ળ㩷વᾲ 2009 ᐕ 4 ᦬- 84 -

㪈㪏䋺㪇㪇㵨㪉㪇䋺㪇㪇㩷 䋼㩷 䈘䈒䉌㩷 䋾㩷 ᙣⷫળ㩷

J. HTSJ, Vol. 48, No. 203

߅⍮ࠄߖ
㩷

㩷
㩷
㵪㵪㵪㩷 ╙ 䋳ᣣ 㩷 䋶᦬ 䋴ᣣ 䋨ᧁ 䋩 㩷 㵪㵪㵪㩷䋼㩷 䌂䋱ቶ㩷 䋾㩷㪙㪈㪄㪊㪈㩷 㩷 㪐䋺㪋㪇㵨㪈㪈䋺㪇㪇㩷 ੑ⋧ᵹ䋳㩷
B1-311 ಽጘ▤䉕↪䈇䈢࿕ᶧੑ⋧ᵹ䈱ಽ㈩․ᕈ䋨☸ሶ䈱ᵹ䉏䈫ಽ㔌䋩ᅏ੗ 㓉ቬ䋨⑔੗ᄢ䋩䋬*↰਄ 㓉ੑ䋬ᣂ↰ 㜞჻䋬ᄥ↰ᷕ৻
B1-312 ᶋㆆ䈜䉎ᶧṢ䈱⇇㕙ᝄേ䈮㑐䈜䉎⎇ⓥ*㋈ᧁ ብᐘ䋨᧲ᣣᧄ䊃䊤䊮䉴䊘䊷䊁䉾䉪䋩䋬਄㊁ ⟵ผ䋨䉴䉵䉨䋩䋬ੑች ዏ䋨ቝㇺችᄢ䋩
B1-313 㔚⸃⾰᳓ṁᶧ⴫㕙䈪䈱᳇ᵃ䈱ኼ๮᷹ቯ*Ꮉፉ ㆐↢䋨੩ㇺᄢ䋩䋬↰ਛ ᐽᄥ㇢, ᧻ᧄ లᒄ
B1-314 2 ᰴర⍱ᒻኈེౝ䈮䈍䈔䉎࿕૕ᓸ☸ሶ⟲䈱㔌ᢔ☸ሶ
ᴺ䈮䉋䉎ᾲᵹേ⸃ᨆ*ጊญ ᦺᒾ䋨㐳ፒᄢ䋩䋬㊄ਣ ㇌ᐽ㪙㪈㪄㪊㪉㩷 㩷 㪈㪈䋺㪈㪇㵨㪈㪉䋺㪈㪇㩷 ಝ❗વᾲ㩷
B1-321 䉧䉴䉪䊷䊤䈮䈍䈔䉎⿥⥃⇇࿶ੑ㉄ൻ὇⚛಄ළᾲવ㆐
䈻䈱ẢṖᴤ⒳䈱ᓇ㗀ᤊട ໪ᄥ㇢䋨᧲੩ᄢ䋩䋬*ౄ ⿥㍋䋬㘧ේ ⧷ᴦ
B1-322 ᓸ⚦᭴ㅧ㕙䈱ಝ❗ᾲવ㆐䈮㑐䈜䉎⎇ⓥᄢ┻ ᶈ㕏䋨Ꮏቇ㒮ᄢ䋩䋬ዊᴰ ቟㇢䋨ାᎺᄢ䋩䋬*ਃቛ⡡৻㇢䋨Ꮏቇ㒮ᄢ䋩
B1-323 䊙䊤䊮䉯䊆Ṣ⁁ಝ❗䈮䈍䈔䉎વᾲ㕙᷷ᐲ൨㈩ਅ䈱⴫㕙ᒛജᏅᶧ૕⒖േᯏ᭴
*㒸 ᔒ⽕䋨ᮮᵿ࿖ᄢ䋩䋬ቝ㜞 ⟵㇢㪙㪈㪄㪊㪊㩷 㩷 㪈㪊䋺㪊㪇㵨㪈㪋䋺㪊㪇㩷 ⫳⊒વᾲ㩷
B1-331 㜞᷷㕙䈮ⴣ⓭䈜䉎ᓸዊᶧṢ䈮䈍䈔䉎⴫㕙ᕈ⁁䈱ᓇ㗀㩷*ᣣ㜞 Ẵౕ䋨਻Ꮊᄢ䋩䋬⍹ේ㩷 ኡ਽䋬↰㗡 ࿻␭䋬ᴡ㊁ᱜ㆏䋬㜞↰ ଻ਯB1-332 䉴䊒䊧䊷ᶧṢ䉕↪䈇䈢㜞᷷㕙䈱㕖ቯᏱ಄ළવᾲ*శᱞ 㓶৻䋨૒⾐ᄢ䋩䋬㐷಴ ᡽ೣ䋬◉ේ ⠢䋬૒⮮ᓼᦶ
B1-333 ⴫㕙䈏䊉䉮䉩䊥಺⁁䈱㜞᷷㕙਄䈮Ṣਅ䈘䉏䈢ᶧṢ䈱᜼േ*㜞ፉ ᱞ㓶䋨ዊጊ㜞ኾ䋩*ဝ↰ ᥏ඳ䋨᧲੩Ꮏᄢ䋩䋬↰ᷨ 㓶৻㇢䋬ᵤፉ ዁ม䋬
ᐔ੗⑲৻㇢
B2-313 PEFC ⵍᲥ䈮෸䈿䈜ⓨ᳇ਛᷙ౉ਇ⚐‛Ớᐲ䈫ടḨ᧦ઙ䈱ᓇ㗀
*㊄ሶ ૫੫䋨᧲੩Ꮏᄢ䋩䋬ᵤፉ ዁ม䋬ᐔ੗ ⑲৻㇢
B2-314 ࿕૕㜞ಽሶᒻΆᢱ㔚ᳰ䈮䈍䈔䉎⊕㊄㜞ല₸೑↪䈱䈢䉄䈱䋳⋧⇇㕙䊝䊂䊦⸃ᨆ*↰ㇱ ⼾䋨ർᶏ㆏ᄢ䋩䋬㜞᧻ ብⴕ䋬ㄭਭ ᱞ⟤㪙㪉㪄㪊㪉㩷 㩷 㪈㪈䋺㪈㪇㵨㪈㪉䋺㪈㪇㩷 䌏䌓䋺㩷 ᳓⚛䉣䊈䊦䉩䊷ᛛⴚ䋵㩷
B2-321 ㆙㓒ᠲ૞ᯏ⢻䉕౗䈰஻䈋䈢㜞࿶ PVT ᷹ቯⵝ⟎䈱㐿⊒䈍䉋䈶᳓⚛䈱 PVT ᷹ቯ*ㄼ↰ ⋥਽䋨਻Ꮊᄢ䋩䋬ㅴ⮮ ஜᄥ䋬ᣂ㉿ ኡ⧷䋨↥✚⎇䋩䋬ᴡ㊁ ᱜ㆏䋨਻Ꮊᄢ䋩䋬㜞↰ ଻ਯ䋬⮮੗ ਍ᄦ䋨↥✚⎇䋩
B2-322 ᄙሹ⾰૕䉕↪䈇䈢ᶧ૕䊜䉺䊉䊷䊦䈎䉌䈱᳓⚛䈱䊌䉾䉲䊑↢ᚑᅏጊ ㇌ੱ䋨ᮮᵿ࿖ᄢ䋩䋬᫪ ᣽ม䋬*↰ਛ ⟤㚅ሶ
B2-323 ⚦▤ᴺ䈮䉋䉎㜞࿶᳓⚛䉧䉴䈱☼ᕈଥᢙ䈱᷹ቯ
Elin Yusibani (AIST, Kyushu Univ.), Peter Llyod
Woodfield (AIST), Kan’ei Shinzato, Masamichi Kohno(Kyushu Univ.), Yasuyuki Takata, Fujii Motoo (AIST)㪙㪉㪄㪊㪊㩷 㩷 㪈㪊䋺㪊㪇㵨㪈㪋䋺㪌㪇㩷 䌏䌓䋺㩷 ᳓⚛䉣䊈䊦䉩䊷ᛛⴚ䋶㩷
B2-331 ᄙሹ૕䉶䊌䊧䊷䉺䉕᦭䈜䉎࿕૕㜞ಽሶᒻΆᢱ㔚ᳰ䈱ᕈ⢻䈍䉋䈶ౝㇱ⃻⽎⸃ᨆ*᫪ጟ ᕀผ䋨ർᶏ㆏ᄢ䋩䋬↰ㇱ ⼾䋬⩵↰ ๺㊀䋬ㄭਭᱞ⟤䋬ዊႺ ᱜ਽䋨ᣣ┙⵾૞ᚲ䋩
B2-332 ࿕૕㜞ಽሶ㔚⸃⾰⤑䈱ㅘḨㆊ⒟䈮䈍䈔䉎Ớᐲ᜛ᢔ䈫‛⾰વ㆐*ᵤፉ ዁ม䋨᧲੩Ꮏᄢ䋩䋬㢬ᧄ ⌀੺䋬Ἇ↰ ᤯ᐔ䋬ᐔ
੗ ⑲৻㇢䋬↰ᷨ 㓶৻㇢䋬ਭ଻ ೣᄦ䋨ᣣ↥⥄േゞ䋩䋬㕍⼱ᐘ৻㇢
B2-333 㜞ಽሶᒻΆᢱ㔚ᳰ䈱ᄙሹ⾰ౝ䈱‛⾰⒖േ䊝䊂䊥䊮䉫*ᄢፉ િⴕ䋨ർᶏ㆏ᄢ䋩䋬ഏ ᆻ⧐䋬䉲䊞䊊 䊥䉺䊮 䉪䊙䋬ᩙේ ᄩᵹ
B2-334 PEFC 䉦䉸䊷䊄⸅ᇦጀ䈮䈍䈔䉎‛⾰⒖േ䊶ㆊ㔚࿶ಽᏓ
䈱 3 ᰴర LBM 䉲䊚䊠䊧䊷䉲䊢䊮Ἇ↰ ᤯ᐔ䋨᧲੩Ꮏᄢ䋩䋬ᵤፉ ዁ม䋬*ᐔ੗ ⑲৻㇢䋼㩷 䌂䋲ቶ㩷 䋾㩷䋼㩷 䌃䋱ቶ㩷 䋾㩷㪙㪉㪄㪊㪈㩷 㩷 㪐䋺㪋㪇㵨㪈㪈䋺㪇㪇㩷 䌏䌓䋺㩷 ᳓⚛䉣䊈䊦䉩䊷ᛛⴚ䋴㩷㪚㪈㪄㪊㪈㩷 㩷 㪐䋺㪋㪇㵨㪈㪈䋺㪇㪇㩷 ᾲᯏེ䊶ᾲ੤឵ེ䋲㩷

B2-311 ⤑㔚ᭂធว૕⇇㕙䈱ャㅍᛶ᛫䈏 PEFC 㕖ቯᏱ⊒㔚․ᕈ䈮෸䈿䈜ᓇ㗀*⋿㍿ ჽ䋨ᮮᵿ࿖ᄢ䋩䋬਄᧛ ᦭ノ䋬ᄢᵢ ஜᴦ䋬⨹ᧁᜏੱ䋬ᕲ↰ ๺ᄦ䋨⼾ᯅᛛ⑼ᄢ䋩
B2-312 ේሶ㑆ജ㗼ᓸ㏜䈮䉋䉎ടḨ᧦ઙਅ PEFC 㔚⸃⾰⤑⴫㕙䊅䊉䉪䊤䉴䉺䊷᭴ㅧ⸃ᨆવᾲ 2009 ᐕ 4 ᦬

C1-311 ಄ಓᯏ↪䊐䊤䉾䊃䉼䊠䊷䊑ᾲ੤឵ེ䈱⌕㔮䉕઻䈉વᾲ․ᕈ䋨䊐䉞䊮䉼䊠䊷䊑ᾲ੤឵ེ䈫䈱ᕈ⢻Ყセ䋩*ᄢ⷏ ర䋨㊄ᴛᄢ䋩䋬ᓮၴ ⠍ᄥ䋬ᄙ↰ ᐘ↢䋬Ἇᧄᤘ
C1-312 ⌕㔮⃻⽎䈮෸䈿䈜಄ළ㕙⴫㕙䈱䈯䉏ᕈ䈱ᓇ㗀*੗਄ ⠍䋨₹Ꮉᄢ䋩䋬ᄢਭ଻ ⧷ᢅ- 85 -J. HTSJ, Vol. 48, No. 203

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C1-313 ⁜㓖౞▤⟲ౝ᷷ᐲ䊶ㅦᐲ႐䈱หᤨ⸘᷹*ᩮጯ ⍮ᐢ䋨ᘮᙥᄢ䋩䋬ጊ↰ ⋥ੱ䋬⪉↰ ౏৻
C1-314 Effect of Number of Tube Rows on Heat Transfer
Enhancement and Flow Field with Different Vortex
Generator Geometries in Fin-and-tube Heat
Exchangers*Mohammad Mustafa Akbari (Tokyo Univ. A&T),
Akira Murata, Kaoru Iwamoto, Hiroshi Saito㪚㪈㪄㪊㪉㩷 㩷 㪈㪈䋺㪈㪇㵨㪈㪉䋺㪈㪇㩷 ᾲᯏེ䊶ᾲ੤឵ེ䋳㩷
C1-321 Ḩᐲᠲ૞䈮䉋䉎ⓨ᳇ᷡᵺ䈱⎇ⓥ䋨ᶋㆆᓸ☸ሶ䈱☸ᓘಽᏓᄌൻ䋩*ዊ㊁↰ ᷪ䋨᣿ᴦᄢ䋩䋬ਛ೎ᐭ ୃ
C1-322 Ḩᐲᠲ૞䈮䉋䉎ⓨ᳇ᷡᵺ䈱⎇ⓥ䋨╙ 2 ႎ䋺㒰Ḩ䈮઻䈉ᓸ☸ሶ㒰෰ലᨐ䈱⸃ᨆ䋩*ਛ೎ᐭ ୃ䋨᣿ᴦᄢ䋩䋬ዊ㊁↰ ᷪ
C1-323 䉲䊞䊪䊷䉪䊥䊷䊆䊮䉫䈮䉋䉎ⅣႺᳪᨴ‛⾰㒰෰䈮㑐䈜䉎ታ㛎⊛⎇ⓥ䋨ᖡ⥇ᚑಽ䈮ኻ䈜䉎᳓⫳᳇ᷝട䈱ലᨐ䋩
ᆢ㊁ ୃᑝ䋨ାᎺᄢ䋩䋬*ጊᧄ ␭ੑᦶ䋬ኹ⼱ ⨃㪚㪈㪄㪊㪊㩷 㩷 㪈㪊䋺㪊㪇㵨㪈㪋䋺㪌㪇㩷 ᾲᯏེ䊶ᾲ੤឵ེ䋴㩷
C1-331 ಄ᇦᵹ〝䉕᦭䈜䉎ᐔ᧼䊐䉞䊮䈪᭴ᚑ䈘䉏䈢ᾲ੤឵ེ䈱વᾲ․ᕈ
⮮㊁ ብ๺䋨䉻䉟䉨䊮䋩䋬㊄ ㋚᳗䋬*ศጟ ବ䋬ਛ↰ ᤐ↵
C1-332 ᾲ੤឵ེ৻૕ဳ㆙ᔃ䊐䉜䊮䈱ዪᚲᾲવ㆐․ᕈ䈫ౝㇱᵹ䉏*Ꮉญ ᷡม䋨ንጊᄢ䋩䋬┻↰ ⍮ᒄ
C1-333 ᮨᡆ䉴䉺䉾䉪䉕↪䈇䈢ዊဳ SOFC 䈱ᾲ೙ᓮታ㛎*਄ญ ⡡䋨੩ㇺᄢ䋩䋬ጤ੗ ⵨䋬㥲⮮ రᶈ䋬ศ↰ ⧷↢䋬ዊ⼱ ๺ผ䋨ᄢᣣᧄශ೚䋩䋬⧐㇌⡡
C1-334 ⿥ዊဳㆊᾲ⫳᳇⊒↢ེ䈱㐿⊒*㘵የ ೰▸䋨㑐⷏ᄢ䋩䋬᧻ᧄ ੫੺䋬ዊỈ ቞䋬┻᫪೑๺䋨ᄢ㒋䉧䉴䋩䋬ਭⷺ ༑ᓼ䋬Ძ═ ᣿ᔒ

C2-321 HFE 䉕↪䈇䈢ᒝ೙ᵹേᴣ㛛䈮䉋䉎ᾲャㅍ*ᨋ ◊ผ䋨ጊᒻᄢ䋩䋬㣮㊁ ৻㇢䋬㜞ᯅ ৻㇢
C2-322 ု⋥䉼䊞䊈䊦䊝䊂䊦ౝ䈱⥄ὼⓨ಄䈮ኻ䈜䉎䉼䊞䊈䊦ო㕙㑆〒㔌䈱ᦨㆡ୯*⷏㊁ ᵏผ䋨ንጊ⋵ᄢ䋩䋬⍹Ⴆ ൎ䋬ਛᎹ ᘕੑ
C2-323 ⋧ᄌൻ᧚䉕↪䈇䈢ㆊᷰ಄ළᛛⴚ䈱㐿⊒䋨ᾲ࿁〝✂ᴺ
䈮䉋䉎ᾲ⸃ᨆ䋩*㜞᪁ ⽵৻䋨ንጊ⋵ᄢ䋩䋬⍹Ⴆ ൎ䋬ਛᎹ ᘕੑ䋬㜞ᧁኡੑ䋨䉥䊛䊨䊮䋩
㪚㪉㪄㪊㪊㩷 㩷 㪈㪊䋺㪊㪇㵨㪈㪋䋺㪌㪇㩷 㔚ሶᯏེ䈱಄ළ䋳㩷
C2-331 ᾲ⸳⸘↪ⓨ಄䊐䉜䊮䈱ᕈ⢻੍᷹䊝䊂䊦䋨╲૕䈍䉋䈶
ᵹ౉ญኸᴺ䈱ᓇ㗀䈱䊝䊂䊦ൻ䈫⹏ଔ䋩*⑔ᳯ 㜞ᔒ䋨ንጊ⋵ᄢ䋩䋬ዊᴰ 㓶ᄢ䋨䉮䊷䉶䊦䋩䋬⍹Ⴆ ൎ䋨ንጊ⋵ᄢ䋩䋬ਛᎹ ᘕੑ
C2-332 䊂䊷䉺䉶䊮䉺⋭䉣䊈䈱䈢䉄䈱䉰䊷䊋వㅴ಄ළ䉲䉴䊁䊛䈱㐿⊒*㒙ㇱ ቱਯ䋨↥✚⎇䋩䋬ᷓ⪨ ᱜੱ䋨SOHKi䋩䋬ർᎹ㓉䋨ᴡ᧛㔚↥䋩䋬ᄢ↰ ᴦᒾ䋨਻Ꮊᄢ䋩䋬ᣂᧄ ᐽਭ䋬૒
⮮ ᱜ⑲䋨ቝㇺችᄢ䋩䋬㘵᧛ ౗৻
C2-333 䊔䊷䊌䊷䉼䊞䊮䊋䊷ᾲ⸳⸘䈻䈱 Excel ᯏ⢻䈱ㆡ↪
*ዊ♻ ᐽᔒ䋨ᾢᧄᄢ䋩䋬ን᧛ ኼᄦ䋬ᔒጘ ᦭ᄥ䋬ᦸ᦬ᱜቁ䋨䊐䉳䉪䊤䋩䋬㠽ዬ ୃ৻䋨ᾢᧄᄢ䋩
C2-334 㓚ኂ‛⸳⟎䈮䉋䉎ⓨ಄䊐䉜䊮䈱ᕈ⢻ૐਅ*ਛ᧛ ర䋨㒐ⴡᄢ䋩䋼㩷 㪛 ቶ㩷 䋾㩷㪛㪄㪊㪈㩷 㩷 㪐䋺㪋㪇㵨㪈㪈䋺㪇㪇㩷 䊙䉟䉪䊨વᾲ䋴㩷
D-311

D-312

䋼㩷 㪚䋲ቶ㩷 䋾㩷㪚㪉㪄㪊㪈㩷 㩷 㪐䋺㪋㪇㵨㪈㪈䋺㪇㪇㩷 㔚ሶᯏེ䈱಄ළ䋱㩷

D-313

C2-311 䊑䊨䉾䉪ဳ㔚⸃䉮䊮䊂䊮䉰䈱ᾲ⸃ᨆ䊝䊂䊦⹏ଔ↪䊔䊮䉼䊙䊷䉪ታ㛎*ዊᴰ 㓶ᄢ䋨䉮䊷䉶䊦䋩䋬⍹Ⴆ ൎ䋨ንጊ⋵ᄢ䋩䋬ਛᎹᘕੑ
C2-312 ᾲ䊶㔚᳇ㅪᚑ⸃ᨆ䈮䈍䈔䉎✭๺ᤨ㑆䈏⊒ᾲ䈮ਈ䈋䉎ᓇ㗀*⇗ጊ ෹ⴕ䋨᧲੩Ꮏᄢ䋩䋬ફା ৻ᘮ䋬ጟፒ ஜ䋬⍹Ⴆൎ䋨ንጊ⋵ᄢ䋩
C2-313 ૐធ⸅࿶㗔ၞ䈮䈍䈔䉎ធ⸅ᾲ䉮䊮䉻䉪䉺䊮䉴䈮෸䈿䈜ធ⸅࿶ജ䈫ធ⸅⇇㕙ⓨ㓗ෘ䈘䈱ᓇ㗀*ᄢਠ ືᦶ䋨ᐢፉ࿖㓙ᄢ䋩
C2-314 㔚ሶᯏེะ䈔ᾲ䉮䊈䉪䉺䈱⸳⸘ᚻᴺ䈱ᬌ⸛*ᨋ ⍮↢䋨ᣣ┙ᯏ᪾⎇䋩

D-314

㪛㪄㪊㪉㩷 㩷 㪈㪈䋺㪈㪇㵨㪈㪉䋺㪈㪇㩷 䊙䉟䉪䊨વᾲ䋵㩷
D-321

D-322

㪚㪉㪄㪊㪉㩷 㩷 㪈㪈䋺㪈㪇㵨㪈㪉䋺㪈㪇㩷 㔚ሶᯏེ䈱಄ළ䋲㩷

વᾲ 2009 ᐕ 4 ᦬䊙䉟䉪䊨䊋䊑䊦䉕೑↪䈚䈢ਛⓨ䊘䊥੃㉄䊙䉟䉪䊨䉦䊒䉶䊦䈱⵾ㅧ*㜞↰ ⌀๋䋨᧲੩ᄢ䋩䋬ᄢችม ໪ᢥ䋬┻᧛ ᢥ↵䋨↥✚⎇䋩න৻ㅘ᣿વᾲᓸ⚦▤䈮䈍䈔䉎 FC-72 䉕↪䈇䈢ᒝ೙ኻᵹᴣ㛛ᾲવ㆐*ᴡධ ᴦ䋨౓ᐶ⋵ᄢ䋩䋬㤛 ჻ື䋬Ꮉ਄ ๺ᚑ䋬ᧄ↰ㅺ㇢䋬Ꮉፉ 㓁੺䋬ᄢ↰ ᴦᒾ䋨਻Ꮊᄢ䋩శ⺃⿠䊙䊤䊮䉯䊆ኻᵹ䉕೑↪䈚䈢䊙䉟䉪䊨䉼䊞䊈䊦ౝ᳇ᵃ䈱ᠲ૞┻ౝ ᵗਯ䋨᧲੩ℂᄢ䋩䋬*ర␭ ᣽ᑝ䋬ᧄ㒙ᒎ ⋿ᴦන৻ⓨ᳇䊙䉟䉪䊨䊋䊑䊦䈱᳓ਛ䈻䈱ṁ⸃ᤨ䈱᷷ᐲᄌൻ*⍹ේ ൟ䋨㑐⷏ᄢ䋩䋬᧲ ⑲ᤘ

- 86 -ု⋥㈩ะනጀ䉦䊷䊗䊮䊅䊉䉼䊠䊷䊑⤑䈫㊄ዻ㕙䈫䈱ធว*ᷰㄝ ⺈䋨᧲੩ᄢ䋩䋬⍹Ꮉ ᩵䋬ᄢᎹ Ả䋬Ⴎ⷗ ᷕ৻㇢䋬ਣጊ ⨃ᄦ䉦䊷䊗䊮䊅䊉䉼䊠䊷䊑䈫๟࿐᧚ᢱ䈱⇇㕙䈮䈍䈔䉎ᾲャㅍ․ᕈ
*Ⴎ⷗ ᷕ৻㇢䋨᧲੩ᄢ䋩䋬Fredrik Carlborg (KTH)䋬ਣጊ⨃ᄦ䋨᧲੩ᄢ䋩

J. HTSJ, Vol. 48, No. 203

߅⍮ࠄߖ
D-323

ᓸ⚦᭴ㅧ䈲䈦᳓㕙ౝ䈮䈍䈔䉎Ứ䉏䈮㑐䈜䉎⎇ⓥ㐳⼱Ꮉ 㓷ੱ䋨㊄ᴛᄢ䋩䋬*੩⼱ ૫᣿䋬ᢪ↰ ⵨ⷙ

F-334ᄖㇱශട⏛႐䈮䉋䉎ၮ᧼਄㜞ಽሶṁᶧṢౝㇱ䈱ᵹേ೙ᓮ㩷*᧻ፉ ૓੺䋨ᄢ㒋ᐭᄢ䋩䋬㊄↰ ᣽ਯ䋬㗇⾐ ৻ᒾ㪛㪄㪊㪊㩷 㩷 㪈㪊䋺㪊㪇㵨㪈㪋䋺㪌㪇㩷 ੑ⋧ᵹ䈱ᢙ୯⸃ᨆ㩷䋼㩷 㪞 ቶ㩷 䋾㩷
D-331

D-332

D-333

D-334

ੑ⋧♽ᩰሶ䊗䊦䉿䊙䊮ᴺ䈮䉋䉎ᩭᴣ㛛ㆊ⒟䈱ᢙ୯䉲䊚䊠䊧䊷䉲䊢䊮㩷*↰ਛ ⟵ੱ䋨ାᎺᄢ䋩䋬ศ㊁ ᱜੱ䋬ᐔ↰ ືᄦ䉰䊑䉪䊷䊦䊶䊒䊷䊦ᴣ㛛䈮䈍䈔䉎ᴣ㛛䊶ಝ❗䊝䊂䊦䈱᭴▽*ዊἑ ⵨↵䋨੩ㇺᄢ䋩䋬ᴡේ ో૞䋬ഞಷ ⾗ᓆᩰሶ䊗䊦䉿䊙䊮ᴺ䈮䉋䉎Ứ䉏ᕈ䈱⇣䈭䉎䊌䉺䊷䊮ၮ᧼਄䈪䈱ᶧ⤑ಽⵚ᜼േ䈱ᢙ୯⸃ᨆ*ਔⷺ ੳᄦ䋨㜞⍮Ꮏᄢ䋩䋬᧻ጟ ᤩ
CIP-LSM 䈮䉋䉎࿕૕ო䈮ⴣ⓭䈜䉎ᶧṢ䈱ᢙ୯⸃ᨆ*ဈ ஜᄥ㇢䋨ർᶏ㆏ᄢ䋩䋬㤥↰ ᣿ᘏ䋼㩷 㪝 ቶ㩷 䋾㩷㪐䋺㪋㪇㵨㪈㪈䋺㪇㪇㩷 䌏䌓䋺㩷 㕖✢ᒻᾲᵹ૕⃻⽎䈫વᾲ䋱㩷

F-311

ᶧ૕㊄ዻ䈱ᾲኻᵹ䊌䉺䊷䊮䈮ኻ䈜䉎⏛႐䈱ᓇ㗀㩷*ᩉỈ ቁኼ䋨ᶏᵗᯏ᭴䋩䋬ጊጯ ଻ሶ䋬ᵿ㊁ ᵗਃ䋬↰ဈ ⵨ม䋨ർᶏ㆏ᄢ䋩䋬⍫㊁ นධሶ䋬ᱞ↰ 㕏⏛႐䈱ᓇ㗀䉕ฃ䈔䈢䊨䊷䊧䊮䉿ᣇ⒟ᑼ䈱ಽጘ⸃*┻ౝ ੫ᄥ䋨┙๮㙚ᄢ䋩䋬ች㊁ ዏ຦䋬ᓟ⮮↰ ᶈౝㇱ⊒ᾲኻᵹ䈮䈍䈔䉎䊌䉺䊷䊮ᒻᚑ䈫ㅦᐲ႐䈱ᄌൻ*↰ဈ ⵨ม䋨ർᶏ㆏ᄢ䋩䋬㜞ᯅ Ảᐔ䋬᧛੗ ␭৻䋬ᱞ↰ 㕏䋬ᩉỈ ቁኼ䋨ᶏᵗᯏ᭴䋩ጀᵹ㗔ၞ䈮䈍䈔䉎ᾲ⚵ᚑ䊒䊦䊷䊛䈱᜼േ䈮䈧䈇䈩*ᾢ⼱ ৻㇢䋨ർᶏ㆏ᄢ䋩䋬Davaille Anne䋨䊌䊥࿾⃿‛ℂቇ⎇ⓥᚲ䋩䋬ᩙ↰ ᢘ䋨᧲੩ᄢ䋩

F-313

F-314

G-311
G-312

G-313

G-314

㪝㪄㪊㪈㩷 㩷F-312

㪞㪄㪊㪈㩷 㩷 㪐䋺㪋㪇㵨㪈㪈䋺㪇㪇㩷 䊍䊷䊃䊌䉟䊒䋱㩷㪞㪄㪊㪉㩷 㩷 㪈㪈䋺㪈㪇㵨㪈㪉䋺㪈㪇㩷 䊍䊷䊃䊌䉟䊒䋲㩷
G-321

G-322

G-323
㪝㪄㪊㪉㩷 㩷㪈㪈䋺㪈㪇㵨㪈㪉䋺㪈㪇㩷 䌏䌓䋺㩷 㕖✢ᒻᾲᵹ૕⃻⽎䈫વᾲ䋲㩷

F-321

Ⅳ⁁䉶䊦䈮䈍䈔䉎䊙䊤䊮䉯䊆ኻᵹ䈱นⷞൻታ㛎*⋉ሶ ጪผ䋨㕒ጟᄢ䋩䋬દ᧲ ବల᷷ᐲᏅ䊙䊤䊮䉯䊆ലᨐ䈮䉋䉎⥄↱ᶧ⤑ౝ㕖✢ᒻኻᵹ႐䈫䈠䈱ㆫ⒖ㆊ⒟*ᷰㄝ ବ⾆䋨᧲੩ℂᄢ䋩䋬਄㊁ ৻㇢ᒝ೙ኻᵹ䊋䊦䉪ᶧጀ䈮ⴣ⓭䈜䉎ᶧ૕䉳䉢䉾䊃䈱േ⊛᜼േ*ጟ ⋥ੱ䋨᧲੩ℂᄢ䋩䋬਄㊁ ৻㇢

F-322

F-323

㪝㪄㪊㪊㩷 㩷㪈㪊䋺㪊㪇㵨㪈㪋䋺㪌㪇㩷 ․ᱶⅣႺਅ䈪䈱ኻᵹ㩷

F-331ṁⲢ㊄ዻ䈮䈍䈔䉎ᶧᩇ䊙䊤䊮䉯䊆ኻᵹㆫ⒖⃻⽎㩷*᧻ᧄ ⡡䋨ቝቮᯏ᭴䋩䋬⍹Ⴆ ඳᒎ䋬ଐ↰ ⋿৻䋬ଐ↰⧷㉿㚅䋨AES䋩䋬੹⍹ ትਯ䋨਻Ꮊᄢ䋩ዉ㔚ᕈ䊊䊷䊐䉹䊷䊮ᶧᩇ䈱ᝄേ䊙䊤䊮䉯䊆ኻᵹ䈮෸䈿䈜ᄖㇱ⏛႐䈱ᓇ㗀᭑ᧄ ᜏ㇢䋨㚂ㇺᄢ䋩䋬*↰Ꮉ ବᄦ㕖ቯᏱ⏛ൻജኻᵹ䋨Pr>1䋩䈮䈍䈔䉎᷷ᐲႺ⇇ጀ䈱⠨ኤBednarz Tomasz (James Cook Univ.) 䋬 *Kaneda
Masayuki (Osaka Pref. Univ.)䋬Lin Wenxian (James
Cook Univ.)䋬Dranga Octavian (Edith Cowan Univ.)

F-332

F-333

વᾲ 2009 ᐕ 4 ᦬න౞▤ౝ⥄ബᝄേᵹ䈮䉋䉎ᾲャㅍ․ᕈ
*ᄢች ⺬䋨ජ⪲ᄢ䋩䋬⬒ᳰ ᶈ㐳䋬↰ਛ ቇ䊦䊷䊒䊍䊷䊃䊌䉟䊒䈱ᾲ․ᕈ䈮䈍䈔䉎૞േᵹ૕ኽ౉
㊂䈱ᓇ㗀*ዊ㊁Ꮉ ⧷䋨ฬฎደᄢ䋩䋬㐳㊁ ᣇᤊ䋬⑔ศ ⦹↱ሶ䋨JAXA䋩䋬ዊᎹ ඳਯ䋬᳗੗ ᄢ᮸䋨᧲ർᄢ䋩㌁䊅䊉☸ሶ䉕฽䉃૞േᶧ䉕↪䈇䈢ᐔ᧼ဳ䊙䉟䉪䊨䊍䊷䊃䊌䉟䊒䈱વᾲ․ᕈ
ൎ↰ ᱜᢥ䋨ᣧⒷ↰ᄢ䋩䋬ᳰ↰ ආⷞ䋨ฎᴡ㔚Ꮏ䋩䋬ศᎹ ๺༑䋨ᣧⒷ↰ᄢ䋩䋬*᫪ᧄ ⵨ਭ⥄ബᝄേ䊍䊷䊃䊌䉟䊒䈱⎇ⓥ*ችፒ ⧐㇢䋨⑔੗Ꮏᄢ䋩䋬೨↰ ⌀స䋨JAXA䋩䋬⍫ㇱ㜞ብᾲ㔚ᄌ឵䊝䉳䊠䊷䊦䉕↪䈇䈢䊦䊷䊒䊍䊷䊃䊌䉟䊒േ૞․ᕈ䈱䉝䉪䊁䉞䊑೙ᓮ㩷*⑔ศ ⦹↱ሶ䋨JAXA䋩䋬㐳㊁ ᣇᤊ䋨ฬฎደᄢ䋩䋬ዊᎹ ඳਯ䋨JAXA䋩䋬᳗੗ ᄢ᮸䋨᧲ർᄢ䋩นᄌ䉮䊮䉻䉪䉺䊮䉴䊍䊷䊃䊌䉟䊒䋨VCHP䋩቟ቯൻᛛⴚ
䈱㐿⊒䋨╙䋱ႎ䋺᳇ᶧಽ㔌᭴ㅧ䈱⹏ଔ䋩*᳗቟ ື਽䋨ਃ⪉㔚ᯏ䋩䋬৻ᴺᏧ ⨃ବ䋬᧖ᧄ ൎ⟤䋨␹ᚭᄢ䋩䋬ᵻ㊁ ╬䋬᧛Ꮉ ⧷᮸䋬┻ਛ ାᐘนᄌ䉮䊮䉻䉪䉺䊮䉴䊍䊷䊃䊌䉟䊒䋨VCHP䋩቟ቯൻᛛⴚ
䈱㐿⊒䋨╙䋲ႎ䋺ਛᕈሶ䊤䉳䉥䉫䊤䊐䉞䈮䉋䉎ౝㇱᵹ૕᜼േ䈱นⷞൻ䋩*᧖ᧄ ൎ⟤䋨␹ᚭᄢ䋩䋬ᵻ㊁ ╬䋬᧛Ꮉ ⧷᮸䋬┻ਛାᐘ䋬᳗቟ ື਽䋨ਃ⪉㔚ᯏ䋩䋬৻ᴺᏧ ⨃ବ㪞㪄㪊㪊㩷 㩷 㪈㪊䋺㪊㪇㵨㪈㪋䋺㪌㪇㩷 䊍䊷䊃䊌䉟䊒䋳㩷
G-331

G-332

G-333

G-334

- 87 -

䈐䈒䋸ภ៞タዷ㐿ဳ䊤䉳䉣䊷䉺䈱゠㆏਄ᾲ․ᕈ㩷*⍹Ꮉ ඳ┨䋨ਃ⪉㔚ᯏ䋩䋬㊁᧛ ᱞ⑲䋬ᢪ⮮ ᐽਯ䋨ਃ⪉㔚ᯏ䉣䊮䉳䊆䉝䊥䊮䉫䋩䋬Ꮉፒ ᤐᄦ䋨JAXA䋩䋬⍫ㇱ㜞ብ䋬ጟᧄ ◊䋬㊄᫪ ᐽ㇢
Visualization of a Parallel-Tube Heat Transport Device
by Using a High-Speed Camera*Phan Thanh-Long 䋨 Tokyo Univ. A&T 䋩 䋬 Murata
Akira䋬㩷 Mochizuki Sadanari䋬Iwamoto Kaoru䋬Saito
Hiroshiዊဳ䊦䊷䊒䊍䊷䊃䊌䉟䊒䈱㊀ജലᨐ䈮䉋䉎ᾲャㅍ․ᕈ⹏ଔ*᳗੗ ᄢ᮸䋨᧲ർᄢ䋩䋬㐳㊁ ᣇᤊ䋨ฬฎደᄢ䋩䋬⑔ศ⦹↱ሶ䋨JAXA/ISAS䋩䋬ዊᎹ ඳਯ䊚䊆䊦䊷䊒䊍䊷䊃䊌䉟䊒䈱વᾲ⢻ജ↰ਛ ᷡᔒ䋨ᯏ᪾ᝄ⥝දળ䋩䋬 ൎ↰ ᱜᢥ䋨ᣧⒷ↰ᄢ䋩䋬ᄢౝ ఝ䋬ᢧ⮮ ࿻␭䋬*ᶏ⠧ේ ஜ੺

J. HTSJ, Vol. 48, No. 203߅⍮ࠄߖ䋼㩷 㪠 ቶ㩷 䋾㩷㪠㪄㪊㪈㩷 㩷㪐䋺㪋㪇㵨㪈㪈䋺㪇㪇㩷 䊋䉟䉥વᾲ䋱㩷I-311㈩ะනጀ⚦⢩䈱ಓ⚿଻ሽ䈮䈍䈇䈩ಓ⚿ᣇะ䈏↢ሽ₸䈮ਈ䈋䉎ᓇ㗀㩷*ጤ㑆 ノ䋨ർ㉿ᄢ䋩䋬㔎᫪ ᓀ䋬᧻੗ ବ᮸䋬᳁ᐔ ᡽િ㕖ቯᏱ᷷ᾲ䉴䊃䊧䉴䈮䉋䉎⚦⢩៊்䊶ᱫṌ䈱੍᷹䋨෻ᔕㅦᐲ⺰⊛ᢙቇ䊝䊂䊦䈱ㆡ↪䋩⍹㤥 ඳ䋨਻ᎺᎿᄢ䋩䋬*㊁Ỉ ᱜ๺䋨᧲ർᄢ䋩᷷ᾲ䉴䊃䊧䉴䈮䉋䉎⚦⢩៊்䊶ᱫṌ䈱෻ᔕㅦᐲ⺰⊛ቯᑼൻ䈮ၮ䈨䈒ᢙቇ䊝䊂䊦䈫䈠䈱․ᕈ
*⍹㤥 ඳ䋨਻ᎺᎿᄢ䋩䋬㊁Ỉ ᱜ๺䋨᧲ർᄢ䋩
Hep G2 ⚦⢩䈱ო㕙ઃ⌕․ᕈ䈱᷹ቯ*㜞㊁ ᷡ䋨᧲੩ᄢ䋩䋬Provin Christophe䋬㈬੗ ᐽⴕ䋬⮮੗ ノᄦ䋬⊕ᮯ ੌ

I-312

I-313

I-314

J-314

᳓䈱ㄭ⿒ᄖๆ෼․ᕈ䉕೑↪䈚䈢ᓸ㊂᳓ṁᶧ䈱᷷ᐲ䉟䊜䊷䉳䊮䉫䋨᷹ቯ♖ᐲ䈫⹜ᢱෘ䈘䈱㑐ଥ䋩ⷺ↰ ⋥ੱ䋨਻Ꮊᄢ䋩䋬የፒ ᢕਯ䋬⑔ේ ᖘሶ䋬ㄭ⮮స຦䋨㠽ขᄢ䋩䋬᦭ᧄ ⧷િ䋨↥✚⎇䋩䋬*ጊ↰ ᐘ↢䋨㔚ㅢᄢ䋩㪡㪄㪊㪉㩷 㩷㪈㪈䋺㪈㪇㵨㪈㪉䋺㪈㪇㩷 ⸘᷹ᛛⴚ䋲㩷J-321䊧䊷䉱ᐓᷤ↹௝ᴺ䈮䉋䉎ྃ㔵ᵹਛ䈱ᶧṢ૏⟎ᬌ಴䈱♖ᐲะ਄㩷*㊀↰ 㓶ၮ䋨ᘮᙥᄢ䋩䋬ၳᳯ ୃ৻䋬৻ᩉ ḩਭ䋬⪉↰౏৻ዮ᛬₸䊙䉾䉼䊮䉫ᴺ䉕↪䈇䈢ⶄ㔀ᵹ〝ౝ䈮䈍䈔䉎㕖ᷙ๺ᕈੑᶧ૕䈱นⷞൻᚻᴺ㐿⊒*ᬀ᧛ ⽕䋨᧲੩Ꮏᄢ䋩䋬ਛ⋓ ⍮䋬ᵤፉ ዁ม䋬ᐔ੗
⑲৻㇢
ᄙ㊀ᢔੂ䈏䊐䊤䉡䊮䊖䊷䊐䉜䊷࿁᛬ᴺ䈮䉋䉎శቇ☸ᐲಽᏓ⸘᷹䈮෸䈿䈜ᓇ㗀䈱⸘▚㔚⏛᳇ቇ䈮䉋䉎ᬌ⸛*ᶆ↰ ⵨੺䋨੩ㇺᎿ❫ᄢ䋩䋬ጟᧄ ㆐ᐘ䋬㥲⮮ ᄢ੺

J-322

J-323
㪠㪄㪊㪉㩷 㩷㪈㪈䋺㪈㪇㵨㪈㪉䋺㪈㪇㩷 䊋䉟䉥વᾲ䋲㩷

I-321㕖䊆䊠䊷䊃䊮☼ᕈ䉕᦭䈜䉎䉼䊞䊈䊦ੂᵹ䈱⋥ធ䉲䊚䊠䊧䊷䉲䊢䊮㩷
*⍫Ỉ ⑲᣿䋨ᣂẟᄢ䋩䋬ਛ↰ ⵨Ꮧ䋬᧻ේ ᐘᴦ䋬㡆ᶏᢘ୶䋬ᰞ੗ ◊䋬ᣂ↰ ാ⿥㖸ᵄ㖸႐䈮⟎䈎䉏䈢↢‛⹜ᢱ䈱಄ළㆊ⒟䈱ᢙ୯䉲䊚䊠䊧䊷䉲䊢䊮*ᄙ↰ ᐘ↢䋨㊄ᴛᄢ䋩䋬Ἇᧄ ᤘ䋬㤥Ꮉ ⺈䋨ᣩ⎣ሶ䋩䋬ᄢ⷏ ర䋨㊄ᴛᄢ䋩䊧䊷䉱䊷ᴦ≮䈱䈢䉄䈱↢૕శવ᠞䊶ᾲવዉㅪᚑ䉲䊚䊠䊧䊷䉲䊢䊮*ᰞ੗ ◊䋨ᣂẟᄢ䋩䋬ᣂ↰ ാ䋬࿧ጊ ㊀⋥䋨᧲ർᄢ䋩䋬ዊ═ේ ⋥਽䋬ጟፉ ᷕਯ੺䋬᧻ේ ᐘᴦ䋨ᣂẟᄢ䋩

I-322

I-323

㪡㪄㪊㪊㩷 㩷㪈㪊䋺㪊㪇㵨㪈㪋䋺㪌㪇㩷 ⸘᷹ᛛⴚ䋳㩷J-331

㆙⿒ᄖ✢䊍䊷䉺䈱ಽశ᡼኿․ᕈ䈱◲ᤃ⹏ଔᣇᴺ㩷ዊ═ේ ᳗ਭ䋨㒐ⴡᄢ䋩䋬ᧁ᧛ ཅቁ䋨ᧁ᧛ᛛⴚ੐ോ
ᚲ䋩⺃㔚ಽశ᷹ቯ䈮䉋䉎↢૕‛⾰ౝ䈱⚿ว᳓䈱᷹ቯ*⊕ᮯ ੌ䋨᧲੩ᄢ䋩䋬Ꮢୖ ఝᄥ䋨᧲੩ㄘᎿᄢ䋩䋬㒋ᩮ੫ᄥ䋨⦼ᶆᎿᄢ䋩䋬ጊ↰ ⚐Fan-beam ᛩᓇ䊂䊷䉺䈮ၮ䈨䈒⿥㖸ᵄ䌃䌔䈮䉋䉎᷷ᐲ႐䈱⸘᷹*ᧇ ካ䋨㕒ጟℂᎿᄢ䋩
NMR 䉶䊮䉰䊷䉕↪䈇䈢㜞ಽሶ㔚⸃⾰⤑ਛ䈪䈱䊜䉺䊉䊷䊦ᶐㅘᕈ䈫᜛ᢔଥᢙ䈱⹏ଔ* ዊ Ꮉ ㇌ ᐽ 䋨 ᘮ ᙥ ᄢ 䋩 䋬 ᜙ Ꮷ ᥓ ਯ 䋨 MRTechnology䋩䋬દ⮮ ⴧᐔ䋨਻Ꮊᄢ䋩

J-332

J-333

J-334
㪠㪄㪊㪊㩷 㩷㪈㪊䋺㪊㪇㵨㪈㪋䋺㪊㪇㩷 䊋䉟䉥વᾲ䋳㩷

I-331䊙䉟䉪䊨ᵄᏱ᷷ੇ῎ᯏ᭴䈱⎇ⓥ㩷
*ᴡ㊁ ⾫ᴦ䋨਻ᎺᎿᄢ䋩䋬᫪ᧄ ┥ᐢ䋬⼱Ꮉ ᵗᢥ䋬㢬↰ 㓉ᴦੱ૕䈱↥ᾲ䉕⠨ᘦ䈚䈢ḡ䈢䉖䉀䈱ᥦᚱലᨐ*⮮੗ 㓷㓶䋨ㄭ⇰ᄢ䋩ቅ┙䈚䈢ᬀ‛䈱ᾲャㅍ․ᕈ䈮㑐䈜䉎ታ㛎⊛⎇ⓥ*ᣂዬ ብ੫䋨ᄢ㒋ᐭᄢ䋩䋬 ጟ ↱⟤䋬ศ↰ ◊ᱜ䋬ᧁ
ਅ ㅴ৻

I-332
I-333

䋼㩷 㪡 ቶ㩷 䋾㩷㪡㪄㪊㪈㩷 㩷㪐䋺㪋㪇㵨㪈㪈䋺㪇㪇㩷 ⸘᷹ᛛⴚ䋱㩷J-311ㄭ⿒ᄖశ䉕↪䈇䈢㕖ធ⸅ဳᓸ㊂ᵹ㊂⸘䈱⎇ⓥ㩷*ᵿፒ ⧷ม䋨㔚ㅢᄢ䋩䋬ጊਅ ஜ૞䋬ᄢᎹ ᤯ᐔ䋬⊕⍹๺䋨᧲੩⸘ⵝ䋩䋬⪭ว ᵗ䋬ጊ↰ ᐘ↢䋨㔚ㅢᄢ䋩⿒ᄖ✢䉰䊷䊝䉫䊤䊐䈮䉋䉎䉧䉸䊥䊮䉣䊮䉳䊮䈎䉌䈱ឃ᳇䉧䉴ᵹേ᷹ቯ*ᅏ⷏ ⦟テ䋨หᔒ␠ᄢ䋩䋬⥱ᧁ ᰴ㇢䋬ᐔ↰ ൎ຦ᗵ᷷⊒శ䊘䊥䊙䉕↪䈇䈢࿁ォ‛૕⴫㕙䈱㕖ធ⸅᷷ᐲ⸘᷹*ဈ᧛ ⧐ቁ䋨ንጊ⋵ᄢ䋩䋬⋿ᧁ ⵨ᢎ䋬㘵ፉ ↱⟤䋨JAXA䋩

J-312

J-313

વᾲ 2009 ᐕ 4 ᦬- 88 -J. HTSJ, Vol. 48, No. 203

੐ോዪ߆ࠄߩㅪ⛊✬㓸಴ㇱળ߆ࠄߩ߅⍮ࠄߖ㧙ฦ⒳ⴕ੐࡮ᐢ๔ߥߤߩឝタߦߟ޿ߡ㧙 ࠗࡦ࠲࡯ࡀ࠶࠻ߩ᥉෸ߦࠃࠅᖱႎ⊒ା࡮੤឵⢻ജߩᲧ㘃ߥ޿ㅴዷ߇߽ߚࠄߐࠇ߹ߒߚ㧚৻ᣇ㧘ࡂ࡯࠼ࠦࡇ࡯ߣߒߡߩቇળ⹹ߦߪ㧘ࠕ࡯ࠞࠗࡉ⊛ߥଔ୯ ߩ ޽ࠆౝኈࠍᚻߦߣߞߡᾫ⺒ߢ߈ࠆὐ߿㧘৻ㅪߩࡍ࡯ࠫࠍ⌑߼ߡో⽩߇ኈᤃߦℂ⸃ߢ߈ࠆὐߥߤ㧘޿ߊࠄ㔚ሶᇦ૕߇⊒㆐ߒߡ߽߆ߥࠊߥ޿㐳ᚲ߇޽ࠆߩ
ߢߪߥ޿߆ߣᕁ޿߹ߔ㧚ߚߛߒ㧘ቇળ⹹ߩශ೚࡮⊒ㅍߦߪᄙ㗵ߩ⚻⾌߽઻޿߹ߔߩߢ㧘ᒰㇱળߢߪߎߩ߶ߤ㧘ኒᐲߩࠃࠅ㜞޿⹹㕙㧘ߔߥࠊߜࡂ࡯࠼ࠦࡇ࡯ߣߒߡߗ߭ߣ߽ᱷߔߴ߈ౝኈࠍ෩ㆬߒ㧘ࠗࡦ࠲࡯ࡀ࠶࠻ (HP㧦ࡎ࡯ࡓࡍ࡯ࠫ㧘ML㧦ࡔ࡯࡝ࡦࠣ࡝ࠬ࠻) ߢᛒ߁ᖱႎߣߩ᫮ߺಽߌࠍߒߚ✬㓸ᣇ㊎ࠍᬌ⸛޿ߚߒ߹ߒߚ㧚 ߎߩ⚿ᨐ㧘ߎࠇ߹ߢળ๔ࡍ࡯ࠫߢขࠅᛒߞߡ߈ߚฦ⒳ⴕ੐࡮ᐢ๔ߥߤߩឝタߦߟ߈㧘એਅߩࠃ߁ߥ
ᣇ㊎ߢኻᔕߐߖߡ޿ߚߛ߈ߚߊ㧘ߏℂ⸃ߣߏදജࠍ߅㗿޿ߔࠆᰴ╙ߢߔ㧚
ኻ ⽎

ኻ ᔕ

ᧄળ (ᡰㇱ) ਥ௅ߦࠃࠆⴕ੐

ή᧦ઙߢ⹦⚦ࠍ㧘ળ⹹ߣHPߦឝタ㧘MLߢ߽㈩ା

㑐ଥቇળ߿ᧄ
ળળຬ߇㑐ଥ
ߔࠆ⚵❱ߦࠃ
ࠆ࿖ౝᄖߩળ
⼏࡮ࠪࡦࡐࠫ࠙
ࡓ࡮࠮ࡒ࠽࡯
ᄢቇ߿౏⊛⎇ⓥᯏ㑐ߩੱ੐౏൐ (વᾲߦ
㑐ଥߩ޽ࠆಽ
㊁ߦ㒢ࠆ)᧦ઙઃ߈ឝタ৻⥸ᐢ๔᳞ੱᐢ๔ળ⹹㧦1ઙᒰߚࠅ4ಽߩ1ࡍ࡯ࠫ⒟ᐲߢឝタ (ήᢱ)
HP㧦ⴕ੐ࠞ࡟ࡦ࠳࡯ߦឝタߒ࡝ࡦࠢᒻᚑ (ήᢱ)ળ⹹㧦ឝタߖߕ
HP㧦᧦ઙઃ߈ឝタ (ήᢱ)
ML㧦᧦ઙઃ߈㈩ା (ήᢱ)ળ⹹㧦᧦ઙઃ߈ឝタ (᦭ᢱ)
HP㧦᧦ઙઃ߈ឝタ (ࡃ࠽࡯ᐢ๔ߩߺ㧘᦭ᢱ)ౕ૕⊛ߥᚻ⛯߈(㔚ሶࡔ࡯࡞ߢߩㅪ⛊ࠍ೨ឭߣߒߡ޿߹ߔ㧚) ↳ㄟ⠪ߪ㧘✚ോㇱળ㐳࡮✬㓸಴ ㇱળ㐳࡮ᐢႎᆔຬળ
ᆔຬ㐳࡮✚ോᜂᒰ೽ળ㐳⵬૒⹏⼏ຬߦ⸥੐ࠍหᤨㅍାߒ
ߡߊߛߐ޿㧚 ↳ㄟ⠪ߪ㧘߹ߕౝኈࠍ⺑᣿ߔࠆ⾗ᢱࠍ✚ോㇱળ㐳ߦㅍାߒߡߊߛߐ޿㧚ክ⼏ߩ⚿ᨐ㧘ឝタนߣߥߞߚ႐วߦߪ
✚ോㇱળ㐳ࠃࠅ↳ㄟ⠪ߦߘߩᣦㅢ⍮ߒ߹ߔߩߢ㧘↳ㄟ⠪ߪ⸥੐ࠍ✬㓸಴ ㇱળ㐳㧔ળ⹹ᜂᒰ㧕ߣᐢႎᆔຬળᆔຬ
㐳㧔HP ᜂᒰ㧕ߦㅍାߒߡߊߛߐ޿㧚 ↳ㄟ⠪ߪ㧘౏൐ౝኈࠍ✚ോㇱળ㐳ߦㅍାߒߡߊߛߐ
޿㧚ክ⼏ߩ⚿ᨐ㧘ឝタนߣߥߞߚ႐วߦߪ✚ോㇱળ㐳ࠃࠅ↳ㄟ⠪ߦߘߩᣦㅢ⍮ߒ߹ߔߩߢ㧘↳ㄟ⠪ߪ⸥੐ࠍᐢႎ
ᆔຬળᆔຬ㐳㧔HPᜂᒰ㧕࡮✚ോᜂᒰ೽ળ㐳⵬૒⹏⼏ຬ㧔MLᜂᒰ㧕ߦㅍାߒߡߊߛߐ޿㧚 ↳ㄟ⠪ߪ㧘✬㓸಴ ㇱળ㐳㧔ળ⹹ᜂᒰ㧕߹ߚߪᐢႎᆔ
ຬળᆔຬ㐳㧔HPࡃ࠽࡯ᐢ๔ᜂᒰ㧕ߦᐢ๔ౝኈࠍㅍାߒ
ߡߊߛߐ޿㧚ឝタนߣߥߞߚ႐วߦߪ✬㓸಴ ㇱળ㐳߹ߚߪᐢႎᆔຬળᆔຬ㐳ࠃࠅ↳ㄟ⠪ߦߘߩᣦㅢ⍮ߒ߹ߔߩߢ㧘↳ㄟ⠪ߪේⓂࠍ✬㓸಴ ㇱળ㐳߹ߚߪᐢႎᆔຬળ
ᆔຬ㐳ߦㅍାߒߡߊߛߐ޿㧚ឝタᢱᡰᛄ޿ᚻ⛯߈ߦߟ޿ߡߪ੐ോዪ߆ࠄߏㅪ⛊޿ߚߒ߹ߔ㧚ࡃ࠽࡯ᐢ๔ߩขࠅᛒ
޿ߦߟ޿ߡߪ http://www.htsj.or.jp/banner.pdf ࠍߏෳᾖਅߐ޿㧚‫ޣ‬ㅪ⛊వ‫ޤ‬࡮✚ോㇱળ㐳㧦ේ᧛ ཅᒾ㧔␹ᄹᎹᄢቇ㧕㧦haramy01@kanagawa-u.ac.jp࡮✬㓸಴ ㇱળ㐳㧦ㄭਭᱞ⟤㧔ർᶏ㆏ᄢቇ㧕㧦takemi@eng.hokudai.ac.jp࡮ᐢႎᆔຬળᆔຬ㐳㧦૒⮮ᵗᐔ㧔ᘮᙥ⟵Ⴖᄢቇ㧕㧦yohei@sd.keio.ac.jp࡮✚ോᜂᒰ೽ળ㐳⵬૒⹏⼏ຬ㧦ዊᎹ㇌ᐽ㧔ᘮᙥ⟵Ⴖᄢቇ㧕㧦ogawa@mech.keio.ac.jp࡮੐ോዪ㧦ୖ᳓⵨ሶ㧦office@htsj.or.jp‫ޣ‬ᵈᗧ‫ޤ‬
࡮ේⓂߪWordࡈࠔࠗ࡞߹ߚߪtextࡈࠔࠗ࡞ߢ߅㗿޿ߒ߹ߔ㧚
࡮HPߪࡔࡦ࠹࠽ࡦࠬߩㇺว਄㧘ឝタߪ↳ㄟ᦬ߩ⠉᦬㧘߹ߚ೥㒰߽Ꮧᦸឝタᦼ㒢ߩ⠉᦬⒟ᐲߩᤨ㑆ㆃࠇ߇޽ࠆߎߣࠍߏੌᛚ㗿޿߹ߔ㧚࡮ ML ߢߪ㧘ේೣߣߒߡ࠹ࠠࠬ࠻ᢥߩㅍାߣߥࠅ߹ߔ㧚pdf ╬ߩᷝઃࡈࠔࠗ࡞ߢㅍାࠍᏗᦸߐࠇࠆ႐วߪߏ⋧⺣ߊߛߐ޿㧚
વᾲ 2009 ᐕ 4 ᦬- 89 -J. HTSJ, Vol. 48, No. 203

੐ോዪ߆ࠄߩㅪ⛊࡮ ᦼᣂ౉ળຬ㧔㨪㧕ᱜ  ฬ࡮ቇ↢  ฬ࡮⾥ഥ  ␠
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᳁ฬ
⍹␹ ᔀᮘญ ⌀ม㚍႐ ᒄ
ട⮮ ๺ᙗ↰ਛ ൎਯ
੹㊁ ᱞᔒᴉ ቿᥢ
⢻᧛ ⾆ብ໊ᵤ ᜏ਽
㋈ᧁ ⧐ⴕ᧻ర ૓᮸╣ㇱ ፏ㜞ဈ ᢥ຦ችᧄ ᐕ↵ർ᧛ ᒄㅢ⍫็ ᥓ⧷ᯅᧄ ᱞ⵨

ᚲዻ␹ᚭᄢቇ 㧶㧲㧱ᛛ⎇ᩣᑼળ␠ ጊᒻ⋵┙↥ᬺᛛⴚ⍴ᦼᄢቇᩞᐣౝᩞ
޿ࠊ߈᣿ᤊᄢቇ
㧔⁛㧕‛⾰࡮᧚ᢱ⎇ⓥᯏ᭴
᧲੩Ꮏᬺᄢቇ
ർᶏ㆏ᄢቇ
᧲੩Ꮏᬺᄢቇ
᧲ർᄢቇ╳ᵄᄢቇ ᧲੩Ꮏᬺᄢቇ
ฬฎደᄢቇ
ฬฎደᄢቇ
᧲੩Ꮏᬺᄢቇ
᣿ᴦᄢቇ౷ጊ⋵┙ᄢቇ

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ᚲዻ
ศ↰ ᵏᶈ
᧲੩ℂ⑼ᄢቇ᧖ᧄ ᄥ㇢
ାᎺᄢቇ 㤥ᧁ ㆯ੩ㇺᄢቇጯ ୶ੱ
ᮮᵿ࿖┙ᄢቇ⷏᧛ ᖘ
ᘮᙥ⟵Ⴖᄢቇ᧛Ꮉ ⧷᮸
␹ᚭᄢቇᷓ੗ ዆ผ ᧲੩Ꮏᬺᄢቇ
ᳰ↰ ආⷞ
ฎᴡ㔚᳇Ꮏᬺ㧔ᩣ㧕⻉ᳯ ዁๋਻Ꮊᄢቇᳯ⋡ ብ᮸᧲ർᄢቇᴉ ⅎᧁ
ᮮᵿ࿖┙ᄢቇ
ਃᶆ ⾆ብ
ᣂẟᄢቇᄢቇ
ዊ㊁↰ ᷪ
᣿ᴦᄢቇፃ᧛ ᣿ᙗ
㧔ᩣ㧕࠺ࡦ࠰࡯
㐳㊁ ᣇᤊ
ฬฎደᄢቇ
㧔ᩣ㧕ࡈࠔࡦ࡚ࠢࠪ࠽࡞࡮ࡈ࡞ࠗ࠶࠼
㧔ᩣ㧕࠰ࡈ࠻࠙ࠚࠕࠢ࡟ࠗ࠼࡞



વᾲ 2009 ᐕ 4 ᦬- 90 -J. HTSJ, Vol. 48, No. 203

熱流束センサーは、熱エネルギーの移動密度（W/cm2 ）に比例した直流電圧を出力します。弊社の製品は米国バージニア工科大学が開発した新しい技術をVatell社で商品化したもので、大変手軽に高速・高精度で熱流量の測定をすることができます。
特に応答速度の早いこと、センサーからの出力レベルが高いことが特徴で、熱流束
マイクロセンサー（ HFM）では、応答速度最高６マイクロ秒を達成しています。

熱流束マイクロセンサー
特 徴

使用例

● 最高速の応答（約 6μ秒）
● 850℃まで外部冷却不要● 低雑音 / 高感度● 熱流束と温度を測定● 伝導、対流、輻射に等感度● エンジン内壁の熱伝達状態観察● ロケットエンジンのトラバース実験●タービンブレード熱風洞試験● 自動車用エアーバッグ安全性試験●ジェットエンジンバックファイヤー試験

ガードン型円形フォイルセンサー
水冷却型

センサー本体の構造は、薄膜フォイル･ディスクの中心と周囲の温度差を測定する、差動型熱電対をとなっています。フォイル･ディスクはコンスタンタンで作られており、銅製の円柱形ヒートシンクに取り付けられています。水冷式
は取付け場所の自由度が高く長時間の測定が可能です。
使用例

熱伝導
冷却型

● 焼却炉・溶鉱炉の熱量測定● 火災実験の際の輻射熱ゲージ● バーナーなど熱源の校正用基準器● 着火性・燃焼性試験（ISO5657,5658,5660）● 米国連邦航空局のファイヤー･スモークテスト

シート状熱流束センサー
センサーは銅とニッケルのサーモパイルから構成されており、測定対象物に貼付けて使います。センサーは厚さが 0 . 2 mmと薄いので、柔 軟 性に富んでおり、直径1インチの円筒形に湾曲させる事が出来ますので、パイプなどに貼り付けてお使いになるには最適です。
使用例

熱流束センサー
校 正サ ービス● 電気・電子機器内の発熱・放熱状態測定● 熱交換器の効率測定● パイプの放熱状況測定

熱流束センサーの校正作業をお引き受けいたします。校正証明書は
米国基準局NISTにトレーサブルです。校正設備の物理的な制約で、お引き受けできない場合もあります。ご相談ください。

〒106-0031 東京都港区西麻布 3-24 -17 霞ビル 4F
TEL: 03-5785-2424 FAX: 03-5785-2323

URL

E-mailsenstech@td6.so-net.ne.jp䮍䭶䮕䭱䮜䭪䮀䬾䯸⁛⥄䬽㜞ᐲᛛⴚ䭡ᜬ䬳ᶏᄖ䮨䯃䭲䯃䬽ᾲᵹ⸘䯻ᾲᵹ᧤䮂䮺䭼䯃䭡䬣⚫੺䬦䬵䬓䭍䬨䫻䎃 CAPTEC ␠ 䯴䮜䮰䮺䮀䯵䎃
CAPTEC ␠䬾䯸⁛⥄䬽㜞ᐲᛛⴚ䬺䭗䭙䯸ૐᾲᛶ᛫䬶㜞ᗵᐲ䬹ᾲᵹ᧤䮂䮺䭼䯃䭡㐿⊒䯂⵾ㅧ⥌䬦䬵䬙䭙䭍䬨䫻ⅣႺ᷷ᐲ䬛ᄌൻ䬦䬵䭑ᗵᐲ䬾Ᏹ䬺৻ቯ䬶䯸ᾲᵹ᧤୯䬺Ყ଀䬦䬮㔚࿶䭡㜞♖ᐲ䬺಴ജ䬦䭍䬨䫻ユ኿䮂䮺䭼䯃䬾䯸ユ኿ᾲ䬽䭎䭡⸘᷹䬨䭚↹ᦼ⊛䬹䮂䮺䭼䯃䬶䬨䫻․ᵈᒻ⁁䭑ᛚ䬲䬵䬙䭙䭍䬨䫻䎃 ᾲᵹ᧤䮂䮺䭼䯃䎃 䎃
䭼䭫䮁䰆
ᾲᛶ᛫୯䰆
ᾲવዉ₸䰆
᷷ᐲ▸࿐䰆
ᔕ╵ㅦᐲ䰆
ᨵエᕈ䰆
䭱䮞䭾䮮䮺䰆․ᵈຠ䰆5䐙5䱊300䐙300 [mm] 䯴ෘ䭎䰆0.4 [mm]䯵
0.00015 [䛐/(W/m2)]
2.7 䰧W/mK䰩
䯹200䱊200 [䛐]⚂ 200 [ms]䮜䮳䭴䭾䮝䮲䯹⋥ᓘ 30 [mm] 䬺ᒭᦛ䮱䭿䮊䮐䯹ᐔ㕙↪
᷷ᐲ⸘᷹↪ T ဳᾲ㔚ኻౝ⬿ᦨ㜞᷷ᐲ 350 [䛐]䭍䬮䬾 380 [䛐]䯸㒐᳓ടᎿ䎃 ユ኿䮂䮺䭼䯃䎃 䎃
䭼䭫䮁䰆
ෘ䭎䰆
᷷ᐲ▸࿐䰆
ᔕ╵ㅦᐲ䰆
ᨵエᕈ䰆
䭱䮞䭾䮮䮺䰆․ᵈຠ䰆ᵄ㐳㗔ၞ䰆5䐙5䱊50䐙50 [mm]0.25 [mm]䯹200䱊250 [䛐]⚂ 50 [ms]⋥ᓘ 30 [mm] 䬺ᒭᦛ᷷ᐲ⸘᷹↪ T ဳᾲ㔚ኻౝ⬿ᦨ㜞᷷ᐲ 350 [䛐]䭍䬮䬾 380 [䛐]ᐢᏪၞ䯴นⷞ䯷⿒ᄖ䯵䯻ᮡḰ䯴⿒ᄖ䯵䬈䭩䮞䮱䭸䯃䭾䮮䮺䬉䧆વᾲ৻⥸䎃 䎃 䧆᷷ᾲⅣႺ䎃 䎃 䧆䭼䯃䮥䮲䮥䮔䭴䮺䎃 䎃 䧆㘩ຠ䯻⺞ℂ䯹὾ᚑ䭱䯃䮝䮺䎃 䎃 䧆䭺䮺䭶䮱䯃䮏䯂࿾ਛၒ⸳䧊ᒰ␠䬶䬾䫺CAPTEC ⵾ຠ䬺ᦨㆡ䬹䮎䯃䮆䮴䭳䯃䭑ขᛒ䬲䬵䬙䭙䭍䬨䫻䎃 䬙᳇シ䬺䬙໧䬓ว䭞䬪ਅ䬤䬓䫻᦭㒢ળ␠ 䮍䭶䮕䭱䮜䭪䮀䎃 䎃 䯴CAPTEC ␠ᣣᧄ✚ઍℂᐫ䯵䎃 䎃 䎃 䎃 䎃 䎃 䎃 䎃 䎃 䎃 URL: http://www.techno-office.com/
ᧄ␠䰆 䬊225-0011䎃 ␹ᄹᎹ⋵ᮮᵿᏒ㕍⪲඙䬑䬥䭎㊁ 3-20-8-B

TEL. 045 (901) 9861䎃 䎃 FAX. 045 (901) 9522

LaVision␠䊧䊷䉱䊷䉟䊜䊷䉳䊮䉫⵾ຠ䈱ᣣᧄ✚ઍℂᐫ䈮䈭䉍䉁䈚䈢
PIV䇮LIF䇮Raman䇮Rayleigh䇮LII䇮╬䈱ᛛⴚ䉕⚵䉂ว䉒䈞䈢ⶄว⸘᷹䉲䉴䊁䊛䉕᭴▽䈚䇮⒳䇱䈱䉝䊒䊥䉬䊷䉲䊢䊮䈪䈱䉸䊥䊠䊷䉲䊢䊮䉕ឭଏ䈚䉁䈜䇯

Laser Imaging Solution䉝䊒䊥䉬䊷䉲䊢䊮

Laser Imaging Techniques
Mie

LIF

PIV

Raman

Rayleigh

ᵹ䉏
ᵹ૕ജቇ

ᵹ䉏᭴ㅧ
䊌䉺䊈䊷䉲䊢䊮

ᵹ䉏䈱นⷞൻ
䊚䉨䉲䊮䉫

ᵹ䉏႐

⚵ᚑ
᷷ᐲ

᳇૕Ớᐲ
᳇૕᷷ᐲ

ྃ㔵

ᶧṢ
䊌䉺䊈䊷䉲䊢䊮

ᶧ૕䋨Άᢱ䋩⾰㊂
ᶧ૕䋯⫳᳇

ᵹ䉏႐

䊒䊧䊷䊅䊷ᶧṢ䉰䉟䉵⸘᷹

⾰㊂ᵹ᧤

Ά὾
䉣䊮䉳䊮

☸ሶ
ᶧṢ

䊤䉳䉦䊦䇮Άᢱ
ൻቇ䊒䊨䉶䉴

ᵹ䉏႐

䊒䊤䉵䊙

☸ሶ
↢ᚑ

⒳
෻ᔕ↹௝

ᵹ䉏႐

᧚ᢱ⹜㛎
⴫㕙ᄌᒻ
਄⸥ో䈩䈱
䉝䊒䊥䉬䊷䉲䊢䊮

LII

FlowMaster
FluidMaster
SprayMaster
SizingMaster

ᶧ૕䋯⫳᳇
᷷ᐲ
䉧䉴⚵ᚑ
᷷ᐲ

⸘᷹䉲䉴䊁䊛

᳇૕Ớᐲ
᳇૕᷷ᐲ

䈜䈜

FlameMaster
EngineMaster
PlasmaMaster㜞ᐲ↹௝⋧㑐

StrainMaster䋲ᰴర䋧䋳ᰴర䈱ᄌᒻ䇮ᱡ䉂႐䇮ᔕജ䋨⿥䋩㜞ㅦ䉟䊜䊷䉳䊮䉫High-Speed
Master Systemㆊᷰ⃻⽎䇮ᤨ㪄ⓨ㑆⋧㑐䈱ᤨ♽೉ㆊ⒟ᧄᐢ๔䈱⵾ຠ઀᭽䈲ᡷༀ䈱䈢䉄੍๔ή䈒ᄌᦝ䈜䉎႐ว䈏䈅䉍䉁䈜ᣣᧄ䉦䊉䊙䉾䉪䉴ᩣᑼળ␠ᵹ૕⸘᷹䊂䉞䊯䉞䉳䊢䊮䈍໧䈇ว䉒䈞䈲䇮䉦䉴䉺䊙䊷䉰䊷䊎䉴⓹ญ䈻
Email fluids@kanomax.co.jp
TEL. (03)6825-9090 FAX. (03)5371-7680
URL http://www.kanomax.co.jp/fgroup.html

✬㓸಴

ㇱળࡁ࡯࠻

Note from the Editorial Board✬㓸಴ ㇱળ㐳ߣߒߡߩ 2 ᐕ㑆ߩછᦼ߽ᓟࠊߕ߆ߣߥࠅ㧘ߎࠇ߹ߢ૗ߣ߆ή੐ߦળ⹹ࠍ⊒ⴕߢ߈ߚߎߣ
ߦ቟႑ߒߡ߅ࠅ߹ߔ㧚ߎࠇ߽㧘ߏၫ╩⠪ߩᣇ‫ߪޘ‬൩⺰ߢߔ߇㧘ㇱળᆔຬߩߏദജߥࠄ߮ߦߏදജߦࠃࠆߣ
ߎࠈ߇ᭂ߼ߡᄢ߈ߊ㧘ߎߩ႐ࠍ୫ࠅߡᗵ⻢↳ߒ਄ߍ߹ߔ㧚6 ᦬ߩℂ੐ળߢᰴᦼㇱળ㐳ߣᒁ⛮߉㧘7 ᦬ภߩ಴ ࠍቢੌߒߚߣߎࠈߢ ⑳ߩછോࠍ⚳ੌߔࠆ੍ቯߢߔ㧚೨଀ߦࠃࠅ߹ߔߣ㧘ᰴภߩㇱળࡁ࡯࠻ߪᰴᦼㇱળ㐳߇ᦠߊߎߣߦߥߞߡ߅ࠅ߹ߔߩߢ㧘ߎߩ႐ࠍ߅୫ࠅߒ㧘ߏ᜿ᜦߐߖߡ޿ߚߛ߈߹ߔ㧚ඳ⼂ߢળ⹹✬㓸ㇱળ㐳ߦᦨㆡછߩศ↰೨ㇱળ㐳߆ࠄᒁ⛮߉㧘ᔅߕߒ߽లታߒߚળ⹹ߦ઀਄ߍࠄࠇߥ߆ߞߚߩߢߪߥ޿߆ߣ
ਇ቟ࠍᗵߓ߹ߔ߇㧘⺒⠪ߩ⊝᭽ߦߪࠃࠈߒߊߏኈ⿔㗂ߌࠇ߫ᐘ↟ߢߔ㧚⚕⾰ࠍ⛽ᜬߒ㧘ࠞ࡜࡯ࡍ࡯ࠫࠍ੍
▚ߩ⸵ߔ▸࿐ౝߢขࠅ౉ࠇ߹ߒߚߩߢ㧘Ყセ⊛਄⾰ߩળ⹹ߦߔࠆߎߣ߇ߢ߈ߚ߽ߩߣᕁߞߡ߅ࠅ߹ߔ㧚ᤓ
ᐕ㧘ᴺੱⷙቯߩᄌᦝ߿੐ോᚲ⒖ォߥߤ߇޽ࠅ㧘੹ᓟߩવᾲቇળߩㆇ༡ߪᔅߕߒ߽ኈᤃߢߪߥ޿ߎߣߣᕁ޿
߹ߔ߇㧘ᒁ߈⛯߈ߏᡰេ⾦ࠅ߹ߔࠃ߁߅㗿޿޿ߚߒ߹ߔ㧚ߐߡ㧘ળຬߩ⊝᭽ߦ߅߆ࠇ߹ߒߡߪ㧘⎇ⓥߩ㓐ᗐ߿⧰ഭ⹤㧘޽ࠆ޿ߪ⎇ⓥᚑᨐߩਥⷐㇱಽࠍ߹ߣ߼ߚ‛ߥߤ㧘⺰ᢥ㓸ߢߪᦠߌߥ޿ࠃ߁ߥ⸥੐ࠍ‫․ޟ‬೎ነⓂ‫ߏߡߒߣޠ‬ၫ╩㗂߈㧘ߏ⥄りߩ⸥㍳ߣߒߡ߽ߏ೑↪㗂ߌࠇ߫⺈ߦᐘ޿ߢߔ㧚․ߦ㧘ቯᐕㅌ⡯೨ᓟߩળຬߦߪߎ߁ߒߚ⸥੐ࠍߏၫ╩㗂ߌࠇ߫㧘ળຬ߽ᄢ༑߮ߢߔ㧚ߏ⥄りߦࠃࠆᛩⓂߪ൩⺰㧘りㄭߦ⹥ᒰߔࠆᣇ߇߅ࠄࠇ߹ߒߚࠄ㧘ߏㅪ⛊㗂ߌࠇ߫⺈ߦ޽ࠅ߇ߚߊᕁ޿߹ߔ㧚ળຬ㑆ߩ᳇シߥᗧ⷗੤឵ߩ႐ߣߒߡ㧘Heart Transfer ߣ޿ߞߚᰣ߽↪ᗧߒߡ߅ࠅ߹ߔߩߢ㧘߅᳇シߦ⒳‫ߩޘ‬ߏᗧ⷗߿⸥੐ᛩⓂࠍ㗂ߌࠇ߫ᐘ޿ߢߔ㧚ߢߪ㧘੹ᓟߣ߽વᾲቇળࠍࠃࠈߒߊ߅㗿޿޿ߚߒ߹ߔ㧚ㄭਭᱞ⟤ 㧔ർᶏ㆏ᄢቇ㧕
Takemi Chikahisa (Hokkaido University)e-mail: takemi@eng.hokudai.ac.jp೽ળ㐳 Ἇᧄ ᤘ㧔㊄ᴛᄢ㧕      ㇱળ㐳 ㄭਭᱞ⟤㧔ർᶏ㆏ᄢቇ㧕ᆔ ຬ㧔ℂ ੐㧕ᆢ㊁ୃᑝ㧔ାᎺᄢቇ㧕    ᯅᧄᓞ↵㧔ᐢፉᄢቇ㧕    ජ↰ ⴤ㧔หᔒ␠ᄢ㧕⮮ጟᕺሶ㧔㧔ᩣ㧕㩖㨱㩧㩂㩆㨸㩏㩣㨯㩖㩣㨼㨹㩎㩨㧕㧔⹏⼏ຬ㧕ᄢ㤥ፏᒄ㧔ᣣ┙࿖㓙㔚᳇㧕   ⷺญൎᒾ㧔↥ᬺ✚ว⎇ⓥᚲ㧕㣮࿦⋥Პ㧔᧲੩ᄢቇ㧕     ਛ೎ᐭ ୃ㧔᣿ᴦᄢቇ㧕ศ↰◊ᱜ㧔ᄢ㒋ᐭ┙ᄢቇ㧕   㐳⼱Ꮉ㆐਽㧔ฬฎደᄢቇ㧕  ⧎᧛సᖗ㧔᧲Ꮏᄢ㧕      ৻ᴺᏧ⨃ବ㧔ਃ⪉㔚ᯏ㧕   ⑔⼱๺ਭ㧔␹ᚭ⵾㍑㧕
ਭⷺ༑ᓼ㧔ᄢ㒋ࠟࠬ㧕    
TSE ࠴࡯ࡈࠛ࠺ࠖ࠲࡯  㐷಴᡽ೣ㧔૒⾐ᄢቇ㧕✬㓸ᐙ੐ ጤᧄ ⮍㧔᧲੩ㄘᎿᄢቇ㧕 ⍹↰⾫ᴦ㧔૒⾐ᄢቇ㧕✬㓸಴ ੐ോዪ㧦ർᶏ㆏ᄢቇᄢቇ㒮Ꮏቇ⎇ⓥ⑼ࠛࡀ࡞ࠡ࡯ⅣႺࠪࠬ࠹ࡓኾ᡹ ㄭਭᱞ⟤‫ޥ‬060-8628 ᧅᏻᏒർ඙ർ 13 ᧦⷏ 8 ৼ⋡ 
Tel: 011-706-6785 Fax: 011-706-7889㧘takemi@eng.hokudai.ac.jp

વᾲ 2009 ᐕ 4 ᦬- 95 -J. HTSJ, Vol. 48, No. 203