Safety Data Sheet[Mixture (Paint)]
１． Products and company identification
Product nameSupplier
Address
Section in charge
Phone number
Fax number
e-mail address
Emergency Phone Number
Preparation, revision, and confirmation
Product type
Recommended use

EPO ROVAL
Roval Corporation
1-1, Nomuramotomachi, Hirakata, Osaka
Technical service department+81-72-894-7590+81-72-894-7593
jp-info@roval-group.com+81-72-894-7191
May 8, 2023
One-component organic zincrich paint (with high-content of zinc powder)
Rust prevention of iron and galvanizing surfaces

２． HAZARDS IDENTIFICATION[GHS Classification]
PHYSICAL HAZARDS

Flammable Liquid

Category 2

Oral

DermalInhalation (Gases)

Inhalation (Vapours)

Inhalation (Dust/Mist)

Classification not possible

Classification not possible

Classification not possible

Category 4

Classification not possible

Skin corrosive

Serious eye damage/irritating/eye Irritation

Solid/Liquid

Gas

Skin sensitisation

Category 2

Category 2

Classification not possible

Classification not possible

Category 1

Acute toxicity

Respiratory/Skin sensitization

Germ cell mutagenicity

Carcinogenicity

Reproductive toxicity

Effects on or via lactation

HEALTH

Category 2

Classification not possible

Category 2

Classification not possible

HAZARDS

STOT

Category 1(Single exposure)respiratory system

Category 2

Category 3

central nervous system, kidney,

May cause drowsiness and dizzinesssystemic toxicity
STOT

Category 1(Repeated exposure)

central nervous system, skeleton

Aspiration hazard

Hazardous to the aquatic environment

Hazardous to the aquatic environment

Short-term (Acute)Long-term (Chronic)

Category 1

Category 1

Classification not possible

Category 2
nervous system
Hazardous to the ozone layer
Classification not possible[GHS Symbols]
Pictogram:

Signal word:
Hazard statement:
H225：Highly flammable liquid and vapour.
H331：Toxic if inhaled.
H315：Causes skin irritation.
H319：Causes serious eye irritation.
H317：May cause an allergic skin reaction.
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H341：Suspected of causing genetic defects.
H361：Suspected of damaging fertility or the unborn child.
H370：Causes damage to organs (central nervous system).
H371：May cause damage to organs(central nerve system, kidney, systemic toxicity).
H336：May cause drowsiness or dizziness.
H372：Causes damage to organs (central nerve system, skeleton) through prolonged or repeated exposure.
H373：May cause damage to organs (nervous system) through prolonged or repeated exposure.
H410：Very toxic to aquatic life with long lasting effects.

Precautionary Statement:[SAFETY MEASURES]
P201：Obtain special instructions before use.
P202：Do not handle until all safety precautions have been read and understood.
P210：Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233：Keep container tightly closed.
P240：Ground and bond container and receiving equipment.
P241：Use explosion-proof electrical/ventilating/lighting/equipment.
P242：Use non-sparking tools.
P243：Take action to prevent static discharges.
P260：Do not breathe dust/fume/gas/mist/vapours/spray.
P264：Wash hands thoroughly after handling.
P270：Do not eat, drink or smoke when using this product.
P271：Use only outdoors or in a well-ventilated area.
P272：Contaminated work clothing should not be allowed out of the workplace.
P273：Avoid release to the environment.
P280：Wear protective gloves/protective clothing/eye protection/face protection.
[FIRST AID]
P302+P352：IF ON SKIN: Wash with plenty water/shower.
P303+P361+P353：IF ON SKIN(or hair): Take off immediately all contaminated clothing.
Rinse affected areas with water [or shower].
P304＋P340：IF INHALED: Remove person to fresh air and Keep comfortable for breathing.
P305+P351+P338：IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses,if present and eazy to do. Continue rinsing.
P308+P313：IF exposed or concerned: Get medical advice/attention.
P333+P313：If skin irritation or rash occurs: Get medical advice/attention.
P337+P313：If eye irritation persists: Get medical advice/attention.
P362+P364：Take off contaminated clothing and wash it before reuse.
P370+P378：In case of fire: Use carbon dioxide, foam, powder, dry sand, or atomized reinforcing liquid to extinguish.
P391：Collect spillage.
[STORAGE]
P403+P235：Store in well-ventilated place. Keep cool.
P405：Store locked up.
[DISPOSAL]
P501：Appropriately dispose of the contents/containers in accordance with laws and regulations.

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３． Composition/information on ingredients
Distinguishing Chemicals and Mixtures: Mixtures
Substance name
Cyclohexanone
Butyl acetate
Methyl ethyl ketone
Ethanol
Zinc
Zinc oxide%WeighCAS No.

10 ～ 15
5 ～ 101 ～5<170 ～ 75
1 ～5

108-94-1
123-86-4
78-93-3
64-17-5
7440-66-6
1314-13-2

４． First-aid measures
Inhaled:Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Contact a doctor when you feel ill.
Skin contact:
Wipe off the adherent quickly with a cloth.
Wash the affected area with plenty of water with mild soap.
Do not use solvents or thinners.
If there is any change in appearance, irritation, or pain, consult a physician when mood is bad.
If skin irritation occurs:Get medical advice/attention.
Take off contaminated clothing and wash it before reuse.
If skin irritation or rash occurs: consult/receive medical attention.
If it gets on the skin (or hair): remove all contaminated clothing immediately.
Wash skin with water or shower.
Eye contact:
Wash immediately with plenty of clean running water for at least 15 minutes.
Remove contact lenses, if present and easy to do.
Consult a doctor immediately.
If eye irritation persists: Get medical advice/attention.
If on clothing:
Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
Swallowed:
If swallowed incorrectly, allow the patient to rest and consult a physician immediately.
Do not induce vomiting.
Emergency measures:
Wear appropriate protection equipment (e.g. protective glasses, protective masks, gloves, etc.).
Ventilation is performed.
５． Fire-fighting measures
Suitable extinguishing agents:
Carbon dioxide, foam, powder, dry sand, and atomized reinforcing liquid.
Fire extinguishing agents not to be used:
Water (rod-shaped water, high-pressure water)/rod-shaped reinforcing liquid.
Special methods for extinguishing fires, protection of persons who extinguish fires:
Wear proper protective equipment.
Quickly remove flammable materials from the surroundings if safe to deal with.
Use specified extinguishing media.
Cool closed containers which may be exposed to heat.
Extinguish from windward side.

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６． Accidental release measures
Precautions for the Human Body, Protective Equipment, and Emergency Measures:
Appropriate protective equipment (protective gloves, protective masks, aprons, goggles, etc.) should be worn during work.
Ventilating firmly indoors In outdoor cases, work from the windward as much as possible.
Prevent secondary disasters by prohibiting access to the surrounding area and keeping other people away.
Avoid sparks, flames and anything which can cause fire. Prepare extinguishing media for accidental fire.
Environmental precautions:
Be careful not to cause environmental effects due to discharge into rivers, etc.
Containment and Purification Methods and Equipment:
For small spill, absorb spills with inert materials, then place in a chemical waste containers.
Disposal of deposits, waste, etc. shall be made in accordance with relevant laws and regulations.
Collect by using a tool made of a material that does not generate sparks due to impact or static electricity.
Absorb in dry sand, soil, or other non-combustible materials for recovery.
A large amount of leakage is prevented by surrounding with embankment.
７． Handling and storage
Handling:
Handle in a well-ventilated area.
The container is sealed each time.
Keep away any source of flame, sparks, and heat.
Wear antistatic cloths and shoes.
Use sparkless equipment.
For countermeasures against static electricity, the equipment, etc. shall be grounded, and explosion-proof type shall be used forthe electrical equipment, etc.
Used waste, paint waste, spray dust, etc. should be kept in water until discarded.
Wear protective equipment to keep skin, mucous membranes, or clothing from touching or coming into the eyes.
Wash hands and face completely after the handling.
Handle in a well-ventilated area.
Wear personal protective cloths.
Do not handle people who have developed allergic symptoms in the past.
Storage:
Avoid direct sunlight.
Store in a dry, well-ventilated area.
Take necessary measures to prevent leakage, overflow, or splashing.
Keep locked to prevent theft.
Keep out of the reach of children.
Keep containers away from fire/flame.
８． Exposure controls/Personal protection
Substance name

ACGIH

Cyclohexanone
Butyl acetate
Methyl ethyl ketone
Ethanol
Zinc
Zinc oxide

20 ppm(TWA)―
200 ppm(TWA)
1000 ppm(STEL)―
2 mg /㎥(TWA)[Equipment Measures]
Use air extractors to prevent fume formation.
Equipment for transporting, pumping, agitation, etc. of liquids shall be equipped to be grounded.
Equipment shall be installed in the vicinity of the handling site so as not to be subject to high temperatures or ignition sources.
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In the case of indoor painting work, equipment that does not expose workers directly, such as by using automatic painting
machines, etc., or equipment that avoids workers from exposure by local exhaust ventilation systems, etc., shall be used.
When working in a sealed place such as the inside of a tank, install a device that can sufficiently ventilate to the bottom of thesealed place.
[Protection]
Respiratory protection:
Wear gas masks for organic gases.
In cases of inadequate ventilation, a respiratory protective device should be worn to prevent overexposure.
Hand protection:
Wear gloves made of organic solvents or chemicals that do not penetrate.
Eye protection:
Wear protective glasses for handling.
Skin and body protection:
When handled, wear clothing that does not directly expose the skin.
Further, it is desirable that the material is a material that does not permeate the chemical.
Other:
Wear antistatic clothing and electrostatic shoes when performing electrostatic painting operations.
９． Physical and Chemical Properties and safety characteristics
Physical state:Liquid
ColourOdor:Solvent odor
Boiling point
Flammability:Flammable Liquid
Explosion Limits
Flash point:15.3℃
Auto-ignition temperature
Decomposition temperature :No data
Kinematic viscosity
Vapor pressure:5.85kPa(20℃)
Densities (g/ml)
Relative vapour density:No data:Gray:78.3℃~156℃: LEL 0.6 vol% UEL 19 vol %:240℃:No data:2.60

１０． Stability and Reactivity
Reactivity: No self-reactivity.
Chemical Stability: Stable in normal handling.
Hazardous Reaction Potential: No data.
Conditions to avoid: Heating, high temperature, contact with incompatible substances.
Forming of mixture with atmosphere within flammable limit.
Incompatible substances: Risk of reacting on contact with oxidizing substances, water, etc.
Hazardous decomposition products: Heat decomposition produces carbon monoxide, carbon dioxide. Generate stimulant gas.
１１． Toxicological information
ACUTE TOXICITY
Substance name
Cyclohexanone
Butyl acetate
Methyl ethyl ketone
Ethanol
Zinc
Zinc oxide

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Oral

Classification

1.296 g / kg
10.736 g / kg
2.737 g / kg
6.2 g / kg
> 2.0 g / kg
> 5.0 g / kg

Category 4
Not calassified
Not calassified
Not calassified
Not calassified
Not calassified

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DermalClassification

0.947 g / kg
Category 3> 5.0 g / kg
Not calassified> 5.0 g / kg
Not calassified
20.0 g / kg
Not calassified
Classification not possible> 5.0 g / kg
Not calassified

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ACUTE TOXICITY
Substance name
Cyclohexanone
Butyl acetate
Methyl ethyl ketone
Ethanol
Zinc
Zinc oxide
Substance name
Cyclohexanone
Butyl acetate
Methyl ethyl ketone
Ethanol
Zinc
Zinc oxide

Inhalation(Gas)

Classific
ation

Not calassified
Not calassified
Not calassified
Not calassified
Not calassified
Not calassified
Skincorrosive/Irritating
Category 2
Not calassified
Category 2
Not calassified
Not calassified
Not calassified

Inhalation(Vapors)

Inhalation(dust, mist)

Classification

2450 ppm
Category 3
Classification not possible
11700 ppm
Category 4
63000 ppm
Not calassified
Classification not possible
Not calassified
Serious eye damage/eye Irritation
Category 2ACategory 2B
Category 2ACategory 2B
Category 2B
Not calassified

Classification

Not calassified
Classification not possible
Classification not possible
Classification not possible> 5.4 mg / L
Not calassified> 5.7 mg / L
Not calassified

Respiratory sensitisation

Skin sensitisation

Classification not possible

Category 1

Classification not possible

Classification not possible

Classification not possible

Not calassified

Classification not possible

Classification not possible

Classification not possible

Not calassified
Not calassified

Classification not possible

Substance nameGerm cell mutagenicity

Carcinogenicity

Reproductive toxicity

Cyclohexanone
Butyl acetate
Methyl ethyl ketone
Ethanol
Zinc
Zinc oxide

Category 2
Classification not possible
Classification not possible
Classification not possible
Classification not possible
Classification not possible

Not calassified
Classification not possible
Classification not possible
Classification not possible
Classification not possible
Classification not possible

Category 2
Classification not possible
Classification not possible
Classification not possible
Classification not possible
Category 2

Substance name

STOT (Single exposure)

Cyclohexanone

Butyl acetate

Methyl ethyl ketone
Ethanol
Zinc
Zinc oxide

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Category 1 (respiratory system)
Category 2 (central nervous system)
Category 3 (anaesthetic effect)
Category 3 (irritating to therespiratory tract, anaesthetic effect)
Category 2 (kidney)
Category 3 (irritating to therespiratory tract, anaesthetic effect)
Category 3 (anaesthetic effect)
Classification not possible
Category 1 (respiratory,
systemic toxicity)

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STOT (Repeat exposure)

Aspiration hazard

Category 1(central nervous system, bone)

Classification not possible

Classification not possible

Classification not possible

Category 1(central nervous system)

Classification not possible

Classification not possible
Classification not possible

Not calassified
Classification not possible

Classification not possible

Classification not possible

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１２． Ecological information
General precautions: When leaking or disposing of the product, be careful to handle it because it may affect the environment.
The product may have adverse effect on environment.
Hazardous to the aquatic
Hazardous to the aquatic
Substance name
Hazardous to the ozone layer
environment(Acute)environment (Chronic)
Cyclohexanone
Not calassified
Not calassified
Classification not possible
Butyl acetate
Category 3
Not calassified
Classification not possible
Methyl ethyl ketone
Not calassified
Not calassified
Classification not possible
Ethanol
Not calassified
Not calassified
Classification not possible
Zinc
Category 1
Category 1
Classification not possible
Zinc oxide
Category 1
Category 1
Classification not possible
Ecotoxicity:
No datePersistence and degradability:
Has rapid decomposition《Butyl acetate》
No rapid degradability (metal compound)《zinc》
Bioaccumulation:
May be low potential (log Kow = 1.78) 《Butyl acetate》
Mobility in soil:
No data
１３． Disposal considerations[Residual Waste, Contamination Containers and Packaging]
In the case of disposal, the relevant laws and regulations and the standards of local governments shall be complied with. Waste
including residue and container should be disposed by licensed industrial waste disposer after the consignment contract. Wash
water used for cleansing containers and equipment must not be released into environment. For other wastage arouse in effluent
processing or incineration, dispose of them in accordance with the law or entrust it. Dispose of the empty container after the restof paint completely removed. It is recommended to recycle empty containers and packaging. When there is a possibility ofgenerating toxic gases such as dioxin, enter into a contract with a licensed industrial waste disposal company and dispose of it.
Dispose of the empty container after the rest of paint completely removed. Empty container should be disposed of by industrial
waste disposal contractor after the consignment contract.
１４． Transport information
UN No. 1263 Proper shipping name: Paint or Paint related material Hazard class: 3
PG :II
Special precautions for transport or means of transport:
Follow the instructions in the Handling and Storage Precautions section.
Check that there is so leaking in the container,and load.
Prevent collapse of the container so that there is no falling or damage.
[Regulations]Land transport:
Follow the transport methods stipulated in the Fire Service Law and the Industrial Safety and Health Law, if applicable.
The consignor shall issue the Carriage Precautions (Yellow Card) to the Carrier.
Maritime transport:
In accordance with the Ship Safety Law.
Air transport:
In accordance with the provisions of the Aeronautical Law

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１５． Regulatory information
Classification and labeling in accordance with Labor Safety and Health Act:See Section 2
Other regulation for foreign countries:
Regulatory information with regards to this preparation in your country or region should be examined by your own
responsibility.
１６． Other information
References:
1) GHS Classification Guidance for Enterprises.
2) SDS from manufacturers of raw materials3) Roval’s own data
The information herein is given in good faith, but no warranty, express or implied, is made.
The information contained herein is, to the best of Roval’s knowledge and belief, accurate and reliable as of the data issued. It is theuser’s responsibility to determine the suitability of this information for the adoption of necessary safety precautions. We reserve theright to revise SDS periodically as new information becomes available.

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