株式会社ダイセル製 高純度キラル試薬

High Enantiomeric Excess Chiral Reagents [Product of Daicel Corporation]

CHIRAL REAGENT
高 純 度 キ ラ ル 試 薬

e.e. Guarantee : >99%
高光学純度
保証

分析チャート
添付

バルク供給
お見積

種々の合成反応に用いられる不斉合成触媒やキラル試薬の光学純度は、生成物の光学純度に大きく影響します。
株式会社ダイセル製のキラル試薬は、全商品に光学純度測定条件・クロマトチャートを添付しており、99% ee以上を保証しています。
特徴■ 高光学純度保証(99% ee以上)■ 光学純度測定クロマトチャートを添付■ バルク量の供給の見積可能

Pybox Ligands ................................................... 1 Chiral Phosphoric Acids ...................... 12, 13, 14
Box Ligands ....................................................... 2 BINAM Ligands .............................................. 15
BINOL Ligands ............................................... 3, 4 BINAP Ligands ............................................... 15
SPINOL-Based Ligands ............................... 4, 5, 6 Ferrocene Ligands .......................................... 15
Chiral Phosphoramidite Ligands ......................... 6 Salen Ligands ................................................ 15
Chiral Auxiliaries ............................................... 7 TADDOLs Ligands ........................................... 15
Chiral Imidazoles ............................................... 7 Trost Ligands ................................................. 16
Chiral Heterocyclic Building Blocks ..................... 8 Pharmaceutical Intermediates ....................... 16
Chiral Amino Amides .......................................... 8 Proline-Based Organocatalysts ....................... 16
Chiral Amino Alcohol Ligands & Building Blocks 9 Squaramide Catalysts ..................................... 17
Chiral Alcohol Ligands & Building Blocks ........... 10 Thiourea-Based Catalysts .................... 17, 18, 19
Chiral Amine Ligands & Building Blocks ............. 11

カタログ掲載内容① (R)-1,1'-Bi(2-naphthol)② 18531-94-7
③

OH
OH

① 化合物名④ 49212-37 ⑥25 g ⑦45,700⑤100021-025G② CAS RNR

③ 構造式

⑤ メーカー品番 ⑥ 包装

④ 製品番号⑦ 価格(円)※表記以外の包装単位はお問合せ下さい。

製品リスト
Pybox Ligands
2-[(4R)-4-Isopropyl-4,5-dihydro-2-oxazolyl]-5-(trifluoromethyl)pyridine

2-[(4R)-4-Isobutyl-4,5-dihydro-2-oxazolyl]-5-(trifluoromethyl)pyridine

-

F3C
O

N

34,10049215-11

135903-100MG

1416819-91-4

131864-67-0

O

N

N

100 mg2,6-Bis[(4R)-isopropyl-2-oxazolin-2-yl]pyr
idine

F3C

O

N

N

49215-08

2-[(4S)-4-tert-Butyl-4,5-dihydro-2-oxazolyl]-5-(trifluoromethyl)pyridine

1428537-19-2
F3C

F3C

135886-100MG

2-[(4R)-4-tert-Butyl-4,5-dihydro-2-oxazolyl]-5-(trifluoromethyl)pyridine

35,300100 mg49215-07

135869-100MG

O

O

N

N

N

37,900100 mg49215-06

135868-100MG

ON
N

34,600100 mgN49212-53

31,9001g

110361-001G

2,6-Bis[(4S)-isopropyl-2-oxazolin-2-yl]pyridine

2,6-Bis[(4R)-4-tert-butyloxazolin-2-yl]pyri
dine

2,6-Bis[(4S)-4-tert-butyloxazolin-2-yl]pyri
dine

2,6-Bis[(4R)-phenyl-2-oxazolin-2-yl]pyridine

2,6-Bis[(4S)-phenyl-2-oxazolin-2-yl]pyridi
ne118949-61-4

185346-17-2

118949-63-6

128249-70-7

174500-20-0

O

O

N
N

N

49212-54

32,6001g

110362-001G

O

O

N
N

N

49214-03

500 mg100821-500MG

O

43,700N

N49214-04

500 mg100822-500MG

O

O

N

37,000O

N
N49212-59

100801-001G

O

N

O

N
N

36,8001g49214-02

100802-500MGN

500 mg30,0002,6-Bis[(4R)-benzyl-2-oxazolin-2-yl]pyridine

2,6-Bis[(4S)-benzyl-2-oxazolin-2-yl]pyridi
ne(3aS,3'aS,8aR,8'aR)-2,2'-(2,6-Pyridinediyl)bis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole](3aR,3'aR,8aS,8'aS)-2,2'-(2,6-Pyridinediyl)bis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole]1-[(4R)-4,5-Dihydro-4-isopropyl-2-oxazolyl]isoquinoline

365215-38-9

151670-69-8

185346-09-2

357209-32-6

280755-83-1

i-Pr
O

O

N
N

O

N
N

N

O

O

N
N

N

O

O

N

O

N
N

O

N

N

N

49212-39

37,8001g

110811-001G

1-[(4S)-4,5-Dihydro-4-isopropyl-2-oxazolyl]isoquinoline

1701405-00-6

i-Pr
O

N
N

49216-30

137602-100MG1

100 mg32,90049212-40

110812-001G

1g

34,00049215-49

134864-500MG

500 mg39,40049215-50

134865-500MG

500 mg39,40049216-28

137601-100MG

100 mg32,900Box Ligands(3aR,3'aR,8aS,8'aS)-2,2'-(1-Methylethylidene)bis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole](3aS,3'aS,8aR,8'aR)-2,2'-(1-Methylethylidene)bis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole]2,2-Bis[(4R)-4-benzyl-2-oxazolin-2-yl]pro
pane

2,2-Bis[(4S)-4-benzyl-2-oxazolin-2-yl]pro
pane(4S,4'S)-2,2'-[2-Phenyl-1-(phenylmethyl)
ethylidene]bis[4-(1-methylethyl)-4,5-dihy
drooxazole]

189623-45-8

175166-51-5

141362-77-8

176706-98-2

444575-98-8

O

O

O

O

O
N

O
N

N

O

N

N

N

O
N

O

N

O
N

49214-97

32,600100 mg135798-100MG

49214-96135797-100MG

32,600100 mg(4S,4'S,5R,5'R)-2,2'-(1-Methylethylidene)bis[4,5-dihydro-4,5-diphenyloxazole](4R,4'R,5S,5'S)-2,2'-(1-Methylethylidene)bis[4,5-dihydro-4,5-diphenyloxazole]

157825-96-2

157904-67-1

O

Ph

O
N

Ph

N

Ph

Ph

Ph

49215-47(4S,4'S)-2,2'-Cyclopentylidenebis[4,5dihydro-4-phenyloxazole]

49215-48NPh49216-60

NN

Bn

49216-57(4R,4'R)-2,2'-Cyclopentylidenebis[4,5dihydro-4-phenyloxazole]

45,4001246401-49-9

O

O
N

N

Bn

49216-58

OO

Bn

28,100100 mg200011-100MG

46,600100 mgN

N

Ph49216-59

Ph

28,100100 mg200012-100MG(4R,4'R,5S,5'S)-2,2'-Cyclopentylidenebis[4,5-dihydro-4,5-diphenyloxazole](4S,4'S,5R,5'R)-2,2'-Cyclopentylidenebis[4,5-dihydro-4,5-diphenyloxazole]2005443-90-1

182122-12-9

-

-

O

O

O

Ph

N

N

N

N

Ph

44,40049215-16135999-100MG

1003886-05-2

Bn

100 mg200010-100MG

26,900100 mg(4S,4'S)-2,2'-Cyclopentylidenebis[4,5dihydro-4-(phenylmethyl)oxazole]

O

O

Ph

35,300100 mgO

100 mg200013-100MG(4R,4'R)-2,2'-Cyclopentylidenebis[4,5dihydro-4-(phenylmethyl)oxazole]

49214-15

110386-100MG(3aS,3'aS,8aR,8'aR)-2,2'Cyclopentylidenebis[3a,8a-dihydro-8Hindeno[1,2-d]oxazole]ON

26,900(3aR,3'aR,8aS,8'aS)-2,2'Cyclopentylidenebis[3a,8a-dihydro-8Hindeno[1,2-d]oxazole]

1639791-77-7

O

N
Ph

134863-100MG

100 mg2005443-99-0

O
N

Ph

35,300100 mg

134862-100MG

O

49214-14

110385-100MG

N

O

O
N

N

Ph

49216-61

200014-100MG

43,400100 mg49216-62

100 mg200015-100MG

43,400Ph

Ph

Ph49216-65

O
N

Ph

N

Ph

44,400100 mg200072-100MG

O

Ph

49216-66

44,400100 mg200073-100MG(4R,4'R)-2,2'-Cyclopentylidenebis[4-tertbutyl-4,5-dihydrooxazole](4S,4'S)-2,2'-Cyclopentylidenebis[4-tertbutyl-4,5-dihydrooxazole](3aR,3a'R,8aS,8a'S)-2,2'-Cyclohexylide
nebis[8,8a-dihydro-3aH-indeno[1,2-d]oxazole](3aS,3a'S,8aR,8a'R)-2,2'-Cyclohexylide
nebis[8,8a-dihydro-3aH-indeno[1,2-d]oxazole](4R,4'R,5S,5'S)-2,2'-Cyclohexylidenebis[4,5-dihydro-4,5-diphenyloxazole]-

298693-03-5-

182122-13-0

-

O

O

O
N

t-Bu

t-Bu

49216-67

100 mg200076-100MG

43,400

O

O

O
N

N
t-Bu

O

O

Ph

N

N

N

N

N
t-Bu

49216-68

200077-100MG

100 mg40,800

O

O
N

N

Ph

49216-69

100 mg200078-100MG

43,90049216-70

43,900100 mg200079-100MG

Ph

Ph49216-71

200084-100MG

46,600100 mg(4S,4'S,5R,5'R)-2,2'-Cyclohexylidenebis[4,5-dihydro-4,5-diphenyloxazole](3aR,3'aR,8aS,8'aS)-2,2'-Cyclohexylide
nebis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole](3aS,3'aS,8aR,8'aR)-2,2'-Cyclohexylide
nebis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole](4R,4'R)-2,2'-(Cycloheptane-1,1-diyl)bis(4-phenyl-4,5-dihydrooxazole)(4S,4'S)-2,2'-(Cycloheptane-1,1-diyl)bis(4-phenyl-4,5-dihydrooxazole)-

2085239-89-8

-

-

-

Ph

O

O
N

N

Ph

O

O
Ph

O

O

N

N

O

N

N

Ph

49216-72

200085-100MG

100 mg49216-75

200236-100MG

100 mg49,90049216-76

100 mg200237-100MG

49,90049216-77

100 mg48,200(4R,4'R,5S,5'S)-2,2'-(Cycloheptane-1,1diyl)bis(4,5-diphenyl-4,5-dihydrooxazole)(4S,4'S,5R,5'R)-2,2'-(Cycloheptane-1,1diyl)bis(4,5-diphenyl-4,5-dihydrooxazole)(3aR,3a'R,8aS,8a'S)-2,2'-(1,3-Dihydro2H-indene-2-ylidene)bis[3a,8a-dihydro8H-indeno[1,2-d]oxazole](3aS,3a'S,8aR,8a'R)-2,2'-(1,3-Dihydro2H-indene-2-ylidene)bis[3a,8a-dihydro8H-indeno[1,2-d]oxazole]

-

-

-

188780-28-1

Ph

O

O
N

Ph

49216-79

200242-100MG

N

Ph

O

O
N

Ph

Ph

100 mgPh45,10049216-80

200243-100MG

N

Ph

O

O
N

49216-78

200241-100MGPh

100 mg48,200

O

O

N

N

Ph

Ph

200240-100MG

O
N

N

Ph

46,600

O

O
N

N

N

Ph

100 mg45,10049216-83

200470-100MG

100 mg44,40049216-84

200471-100MG

100 mg44,4002

BINOL Ligands(R)-3,3'-Dimethyl-[1,1'-binaphthalene]-2,2'-diol(S)-3,3'-Dimethyl-[1,1'-binaphthalene]-2,2'-diol

55515-98-5

55515-99-6(R)-3,3'-Bis(phenyl)-1,1'-bi-2-naphthol(S)-3,3'-Bis(phenyl)-1,1'-bi-2-naphthol(R)-6,6'-Dibromo-1,1'-bi-2-naphthol

102490-05-1

75684-93-4

65283-60-5
Br

OH

OH

OH

OH

OH

OH

OH

OH

OH
OH
Br

49212-92

135830-250MG

46,400250 mg(S)-6,6'-Dibromo-1,1'-bi-2-naphthol

80655-81-8

49212-93135831-250MG

250 mg111822-69-6

111795-33-6

Br

22,1001g

37,0001g(S)-3,3'-Bis(triphenylsilyl)-1,1'-bi-2-napht
hol

OH
OH

49212-73

49212-57

110151-001G(R)-3,3'-Bis(triphenylsilyl)-1,1'-bi-2-napht
holBr100712-001G

46,40049212-62

110021-100MG

Ph
Ph
Si
Ph

Ph
Ph
Si
Ph

OH
OH

OH
OH

Ph
Si
Ph
Ph

Ph
Si
Ph
Ph

100 mg51,20049212-63

110022-100MG

51,200100 mg49212-58

28,9001g

110152-001G(R)-2,2'-Dimethoxy-1,1'-binaphthalene

49212-71

100711-001G

22,1001g(S)-2,2'-Dimethoxy-1,1'-binaphthalene35294-28-1

75640-87-8

O

O

O

O

49212-89

19,4001g

100701-001G

49212-90

100702-001G

16,4001g(R)-3,3'-Dibromo-2,2'-dimethoxy-1,1'-binaphthyl(S)-3,3'-Dibromo-2,2'-dimethoxy-1,1'-binaphthyl(S)-3,3'-Dibromo-bis(methoxymethoxy)1,1'-binaphtyl(R)-6,6'-Dibromo-2,2'-bis(methoxymethoxy)-1,1'-binaphthalene(S)-6,6'-Dibromo-2,2'-bis(methoxymethoxy)-1,1'-binaphthalene

75714-59-975714-60-2

142010-87-5

179866-74-1

211560-97-3

Br

Br

Br

O
O

O
O

O
O

Br

Br

Br

49212-77

100731-001G

25,4001g(R)-2,2'-Dimethyl-1,1'-binaphthalene

19634-89-0

49212-94

110101-001G

24,7001g(R)-2,2'-Dibromo-1,1'-binaphthalene

86688-08-6

28,9001g49212-78

100732-001G

49212-68

135888-250MG

49212-76

Br
O
O

O
O

O
O

Br

22,3001g

110062-001GBr(S)-2,2'-Dibromo-1,1'-binaphthalene

150024-49-0

O
O

O
O

Br

49212-74

42,6001g135870-001G

49212-75

135871-001G

42,6001g(R)-5,5',6,6',7,7',8,8'-Octahydro-1,1'-bi-2naphthol(S)-5,5',6,6',7,7',8,8'-Octahydro-1,1'-bi-2naphthol

65355-14-865355-00-2

Br

Br

OH

OH

Br

Br

OH

OH

250 mg67,40049212-69

135889-250MG

67,400250 mg49213-64

17,5001g

100671-001G

49213-65

100672-001G

1g

17,500(R)-3,3'-Dibromo-5,5',6,6',7,7',8,8'-octahy
dro-[1,1'-binaphthalene]-2,2'-diol(S)-3,3'-Dibromo-5,5',6,6',7,7',8,8'-octahy
dro-[1,1'-binaphthalene]-2,2'-diol(R)-5,5',6,6',7,7',8,8'-Octahydro-3,3'-bis[2,4,6-tris(1-methylethyl)phenyl]-[1,1'-binap
hthalene]-2,2'-diol(S)-5,5',6,6',7,7',8,8'-Octahydro-3,3'-bis[2,4,6-tris(1-methylethyl)phenyl]-[1,1'-binap
hthalene]-2,2'-diol(R)-3,3'-Di-tert-butyl-5,5',6,6'-tetramethyl
biphenyl-2,2'-diol

65355-08-0

765278-73-7

1522367-79-8

1197214-47-3

329735-68-4

49212-79

100681-001G

Br

Br

OH
OH

OH
OH

Br

Br

1g

25,40049212-80

100682-001G

i-Pr

OH
OH

49213-68

134912-100MG

i-Pr

i-Pr

i-Pr

OH
OH

i-Pr

i-Pr

25,400

1g

i-Pr

i-Pr

100 mgi-Pr

i-Pr

51,20049213-69

134913-100MG

OH
OH

i-Pr

i-Pr

100 mg51,20049213-07

135022-250MG

250 mg45,200(S)-3,3'-Di-tert-butyl-5,5',6,6'-tetramethyl
biphenyl-2,2'-diol(R)-3-3'-Bis(3,5-dimethylphenyl)-1,1'-bi2-naphthol(S)-3-3'-Bis(3,5-dimethylphenyl)-1,1'-bi2-naphthol(R)-2,2'-Dihydroxy-α,α,α',α'-tetraphenyl[1,1'-binaphthalene]-3,3'-dimethanol(S)-2,2'-Dihydroxy-α,α,α',α'-tetraphenyl[1,1'-binaphthalene]-3,3'-dimethanol

205927-03-3

215433-51-5

435327-17-6

336185-31-0

309269-73-6

CH3

CH3

CH3

OH

CH3

OH
OH

OH

OH
OH
CH3

CH3

CH3

49213-08135021-250MG

3

250 mg45,20049215-17

110051-100MG

100 mgCH329,80049215-18

110052-100MG

100 mg29,80049215-40

121161-250MG

Ph
OH
Ph

Ph
OH
Ph

OH
OH

OH
OH

Ph
OH
Ph

Ph
OH
Ph

250 mg41,00049215-41

121172-250MG

250 mg41,000BINOL Ligands(R)-[2,3':1',1'':3'',2'''-Quaternaphthalene]2',2''-diol(S)-[2,3':1',1'':3'',2'''-Quaternaphthalene]2',2''-diol(R)-[1,3':1',1'':3'',1'''-Quaternaphthalene]2',2''-diol(S)-[1,3':1',1'':3'',1'''-Quaternaphthalene]2',2''-diol215433-53-7

863659-89-6

851615-07-1

863659-88-5

OHOH49215-59

135003-100MG

OH
OH

100 mg30,500(S)-3,3'-Bis([1,1'-biphenyl]-4-yl)-[1,1'binaphthalene]-2,2'-diol

220486-43-1

49215-60

135004-100MG(R)-3,3'-Bis[4-(2-naphthalenyl)phenyl][1,1'-binaphthalene]-2,2'-diol

309934-86-9

49215-64

100 mg31,90049215-65

135013-100MG

100 mg38,4001041186-22-4

-

Ph
Ph
Si
Ph

Ph
Ph
Si
Ph

OH
OH

OH
OH

Ph
Si
Ph
Ph

Ph
Si
Ph
Ph

100 mg39,40049215-39

121132-100MG

30,500(S)-3,3'-Bis[4-(2-naphthalenyl)phenyl][1,1'-binaphthalene]-2,2'-diol

49215-62

135006-100MG

100 mg49215-66

135014-100MG

100 mgOH
OH

100 mg30,500(1R,1''R)-3,3''-[Oxybis(methylene)]bis[1,1'-binaphthalene]-2,2'-diol265116-85-6

OHOH(S)-3,3'-Bis(triphenylsilyl)-5,5',6,6',7,7',8,8'-octahydro-1,1'-bi-2,2'-naphthol

49215-38

100 mg309934-87-0(R)-3,3'-Bis(triphenylsilyl)-5,5',6,6',7,7',8,8'-octahydro-1,1'-bi-2,2'-naphthol

121121-100MG

49215-61

135005-100MG

OH
OH

OH
OH

135008-100MG

30,500215433-52-6

OH
OH

OH
OH

100 mg(R)-3,3'-Bis([1,1'-biphenyl]-4-yl)-[1,1'binaphthalene]-2,2'-diol

38,40049216-04

135977-100MG

49215-63

135007-100MG

100 mg(1S,1''S)-3,3''-[Oxybis(methylene)]bis[1,1'-binaphthalene]-2,2'-diol

336800-79-4

O

O

OH HO
OH HO

OH HO
OH HO

100 mg31,90043,70049216-05

135978-100MG

100 mg43,70039,400

SPINOL-Based Ligands(R)-2,2',3,3'-Tetrahydro-1,1'-spirobi[1H-indene]-7,7'-diol(S)-2,2',3,3'-Tetrahydro-1,1'-spirobi[1H-indene]-7,7'-diol(R)-6,6'-Bis(3,5-dimethylphenyl)-2,2',3,3'tetrahydro-1,1'-spirobi[1H-indene]-7,7'-diol(S)-6,6'-Bis(3,5-dimethylphenyl)-2,2',3,3'tetrahydro-1,1'-spirobi[1H-indene]-7,7'-diol(R)-6,6'-Bis[3,5-bis(trifluoromethyl)phenyl]-2,2',3,3'-tetrahydro-1,1'-spirobi[1H-indene]-7,7'-diol

223259-62-9223259-63-0

930784-56-8-

1286189-16-9
CF3

OH

OH

OH

OH

OH

OH

OH

CF3

OH

OH

OH

CF3

CF3

49213-90

120071-001G

44,2001g49213-91

120072-001G

1g

44,20049212-49

134872-100MG

100 mg62,80049212-50

134873-100MG

100 mg62,80049212-43134870-100MG

100 mg62,800(S)-6,6'-Bis[3,5-bis(trifluoromethyl)phenyl]-2,2',3,3'-tetrahydro-1,1'-spirobi[1H-indene]-7,7'-diol(R)-2,2',3,3'-Tetrahydro-6,6'-di-9-phenant
hrenyl-1,1'-spirobi[1H-indene]-7,7'-diol(S)-2,2',3,3'-Tetrahydro-6,6'-di-9-phenant
hrenyl-1,1'-spirobi[1H-indene]-7,7'-diol(11aR)-10,11,12,13-Tetrahydro-5-hydrox
y-5-oxide-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin(11aS)-10,11,12,13-Tetrahydro-5-hydrox
y-5-oxide-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin1258327-01-3

1372719-96-4-

1352810-35-5

1258327-03-5

CF3

OH

CF3

OH

OH

OH

CF3

OH

OH

O O
P
O OH

O O
P
O OH

CF3

49212-44134871-100MG

100 mg62,80049213-84

134975-100MG

100 mg68,50049213-85

134976-100MG

100 mg68,50049214-60

135046-100MG

100 mg26,90049214-61

135047-100MG

100 mg26,9004

SPINOL-Based Ligands(11aR)-10,11,12,13-Tetrahydro-5-hydrox
y-3,7-diphenyl-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin(11aS)-10,11,12,13-Tetrahydro-5-hydrox
y-3,7-diphenyl-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin(11aR)-3,7-Bis(4-chlorophenyl)-10,11,12,13-tetrahydro-5-hydroxy-diindeno[7,1-de:
1',7'-fg][1,3,2]dioxaphosphocin(11aS)-3,7-Bis(4-chlorophenyl)-10,11,12,13-tetrahydro-5-hydroxy-diindeno[7,1-de:
1',7'-fg][1,3,2]dioxaphosphocin(11aR)-3,7-Bis((4-(1,1-dimethylethyl)phenyl)-10,11,12,13-tetrahydro-5-hydroxy-dii
ndeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin

1297613-72-9

1258327-04-6-

1258327-05-7

-

Cl
O O
P
O OH

O O
P
O OH

Cl

O O
P
O OH

O O
P
O OH
Cl

49214-43

134852-100MG

62,200100 mg49214-42134851-100MG

100 mg62,20049215-04

135865-100MG

100 mg63,400

O O
P
O OH

Cl

49215-05

135866-100MG

100 mg63,40049214-47

49,90050 mg

134909-50MG(11aS)-3,7-Bis((4-(1,1-dimethylethyl)phenyl)-10,11,12,13-tetrahydro-5-hydroxy-dii
ndeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin(11aR)-3,7-Bis(3,5-dimethylphenyl)-10,1
1,12,13-tetrahydro-5-hydroxy-5-oxide-dii
ndeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin(11aS)-3,7-Bis(3,5-dimethylphenyl)-10,1
1,12,13-tetrahydro-5-hydroxy-5-oxide-dii
ndeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin(11aR)-3,7-Bis[3,5-bis(trifluoromethyl)phenyl]-10,11,12,13-tetrahydro-5-hydroxy-5-oxide-diindeno[7,1-de:1',7'-fg][1,3,2]diox
aphosphocin(11aS)-3,7-Bis[3,5-bis(trifluoromethyl)phenyl]-10,11,12,13-tetrahydro-5-hydroxy-5-oxide-diindeno[7,1-de:1',7'-fg][1,3,2]diox
aphosphocin-

1297613-75-2

1412439-82-7

1297613-76-3

1258327-07-9

CF3

CF3

O O
P
O OH

O O
P
O OH

CF3
O O
P
O OH CF3

O O
P
O OH

CF3
O O
P
O OH CF3

CF349214-46

49,90050 mg

134908-50MG

49212-47

134898-100MG

100 mg80,00049212-48

134899-100MG

100 mg80,00049212-41

134896-100MG

100 mgCF3

80,00049212-42134897-100MG

80,000100 mg(11aR)-10,11,12,13-Tetrahydro-5-hydrox
y-3,7-di-2-naphthalenyl-5-oxide-diindeno[
7,1-de:1',7'-fg][1,3,2]dioxaphosphocin(11aS)-10,11,12,13-Tetrahydro-5-hydrox
y-3,7-di-2-naphthalenyl-5-oxide-diindeno[
7,1-de:1',7'-fg][1,3,2]dioxaphosphocin(11aR)-10,11,12,13-Tetrahydro-5-hydrox
y-3,7-di-1-naphthalenyl-5-oxide-diindeno[
7,1-de:1',7'-fg][1,3,2]dioxaphosphocin(11aS)-10,11,12,13-Tetrahydro-5-hydrox
y-3,7-di-1-naphthalenyl-5-oxide-diindeno[
7,1-de:1',7'-fg][1,3,2]dioxaphosphocin(11aR)-3,7-Bis([1,1'-biphenyl]-4-yl)-10,11,12,13-tetrahydro-5-hydroxy-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin

1297613-74-1-

1297613-73-0

1258327-08-0

1297613-77-4

O O
P
O OH

49214-44

134906-100MG

O O
P
O OH

67,200100 mg49214-45

134907-100MG

100 mgO O
PO OH

67,20049214-41

134850-100MG

100 mg

O O
P
O OH

O O
P
O OH

67,40049214-40

134849-100MG

100 mg67,40049214-53

51,60050 mg134998-50MG(11aS)-3,7-Bis([1,1'-biphenyl]-4-yl)-10,11,12,13-tetrahydro-5-hydroxy-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin(11aR)-3,7-Di-9-anthracenyl-10,11,12,13-tetrahydro-5-hydroxy-5-oxide-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin(11aS)-3,7-Di-9-anthracenyl-10,11,12,13-tetrahydro-5-hydroxy-5-oxide-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin(11aR)-10,11,12,13-Tetrahydro-5-hydrox
y-3,7-di-9-phenanthrenyl-5-oxide-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin(11aS)-10,11,12,13-Tetrahydro-5-hydrox
y-3,7-di-9-phenanthrenyl-5-oxide-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin1258327-06-81345628-08-1

1393527-23-5

1372719-93-1

1585988-92-6

O O
P
O OH

49214-52

O O
P
O OH

51,60050 mg134997-50MG

49215-02135845-50MG

50 mg

O O
P
O OH

O O
P
O OH

58,30049215-03135846-50MG

50 mg

58,30049213-88

135843-100MG

O O
P
O OH

100 mg80,000(11aR)-3,7-Bis(1-pyrenyl)-10,11,12,13-te
trahydro-5-hydroxy-diindeno[7,1-de:1',7'fg][1,3,2]dioxaphosphocin(11aS)-3,7-Bis(1-pyrenyl)-10,11,12,13-te
trahydro-5-hydroxy-diindeno[7,1-de:1',7'fg][1,3,2]dioxaphosphocin(R)-6,6'-Dibromo-2,2',3,3'-tetrahydro-1,1'spirobi[1H-indene]-7,7'-diol(S)-6,6'-Dibromo-2,2',3,3'-tetrahydro-1,1'spirobi[1H-indene]-7,7'-diol--

1286189-15-8

1621066-74-7

Br

Br

OH
OH

OH
OH

Br

Br

49213-89

135844-100MG(R)-2,2',3,3'-Tetrahydro-6,6'-bis(2,4,6trisisopropylphenyl)-1,1'-spirobi[1Hindene]-7,7'-diol

1372719-98-6
i-Pr

O O
P
O OH

49215-09

O O
P
O OH

60,20050 mg135896-50MG(S)-2,2',3,3'-Tetrahydro-6,6'-bis(2,4,6trisisopropylphenyl)-1,1'-spirobi[1Hindene]-7,7'-diol

1258276-31-1
i-Pr

OH
OH

i-Pr

49215-46134859-100MG

549215-10135897-50MG

50 mg

60,20049216-14

137411-500MG

500 mg61,20049216-15

137412-500MG

500 mg80,000100 mg

i-Pr

OH
OH

i-Pr
i-Pr

i-Pr

61,20049215-45134858-100MG

i-Pr

100 mg68,200(R)-6,6'-Bis([1,1'-biphenyl]-4-yl)-2,2',3,3'tetrahydro-1,1'-spirobi[1H-indene]-7,7'diol(S)-6,6'-Bis([1,1'-biphenyl]-4-yl)-2,2',3,3'tetrahydro-1,1'-spirobi[1H-indene]-7,7'diol(R)-2,2',3,3'-Tetrahydro-6,6'-di(1-naphtha
lenyl)-1,1'-spirobi[1H-indene]-7,7'-diol(S)-2,2',3,3'-Tetrahydro-6,6'-di(1-naphtha
lenyl)-1,1'-spirobi[1H-indene]-7,7'-diol

1297613-71-8

1258327-00-2

1292849-40-1

1258327-02-4

OH
OH

OH
OH

i-Pr

i-Pr
i-Pr

OH
OH

OH
OH

i-Pr

100 mg68,20049215-57

134991-100MG

100 mg65,80049215-58

134992-100MG

100 mg65,80049215-88

135832-100MG

100 mg52,80049215-89

135833-100MG

100 mg52,800SPINOL-Based Ligands(R)-6,6'-Bis[4-(1,1-dimethylethyl)phenyl)]-2,2',3,3'-tetrahydro-1,1'-spirobi[1Hindene]-7,7'-diol(S)-6,6'-Bis[4-(1,1-dimethylethyl)phenyl)]-2,2',3,3'-tetrahydro-1,1'-spirobi[1Hindene]-7,7'-diol(11aR)-3,7-Bis(4-(trifluoromethyl)phenyl)-10,11,12,13-tetrahydro-5-hydroxy-5oxide-diindeno[7,1-de:1',7'-fg][1,3,2]
dioxaphosphocin(11aS)-3,7-Bis(4-(trifluoromethyl)phenyl)-10,11,12,13-tetrahydro-5-hydroxy-5oxide-diindeno[7,1-de:1',7'-fg][1,3,2]
dioxaphosphocin(11aR)-3,7-Bis(4-methoxyphenyl)-10,11,
12,13-tetrahydro-5-hydroxy-5-oxidediindeno[7,1-de:1',7'-fg][1,3,2]
dioxaphosphocin

-

-

-

-

-

t-Bu
OH
OH

O

OH
OH

49215-93

47,800100 mg

P

O49215-92

135898-100MG

47,800100 mg

CF3

O

O

OH

O

t-Bu

t-Bu

135899-100MG

CF3

t-Bu

P

O

O

OH

O

49216-39

60,200100 mg

P

O
OH
OMe

CF3

CF3

137721-100MG

OMe

49216-40

137722-100MG

60,200100 mg49216-41

137731-100MG

58,300100 mg(11aS)-3,7-Bis(4-methoxyphenyl)-10,11,
12,13-tetrahydro-5-hydroxy-5-oxidediindeno[7,1-de:1',7'-fg][1,3,2]dioxa
phosphocin(11aR)-3,7-Bis(4-nitrophenyl)-10,11,12,13-tetrahydro-5-hydroxy-5-oxidediindeno[7,1-de:1',7'-fg][1,3,2]dioxaphos
phocin(11aS)-3,7-Bis(4-nitrophenyl)-10,11,12,13-tetrahydro-5-hydroxy-5-oxidediindeno[7,1-de:1',7'-fg][1,3,2]dioxaphos
phocin(11aR)-3,7-Bis(3,5-dichlorophenyl)-10,11,12,13-tetrahydro-5-hydroxy-5-oxidediindeno[7,1-de:1',7'-fg][1,3,2]dioxaphos
phocin(11aS)-3,7-Bis(3,5-dichlorophenyl)-10,11,12,13-tetrahydro-5-hydroxy-5-oxidediindeno[7,1-de:1',7'-fg][1,3,2]dioxaphos
phocin-1352810-37-7

1412439-84-9

-

-

O

P

O

O

O

OH

O

P

O

O

OH

O

OMe

49216-42137732-100MG

100 mg58,300

P

O

O

OH

O

NO2

49216-43137741-100MG

100 mg60,200

Cl

NO2

NO2

OMe

Cl

P

O
OH

NO2

49216-44137742-100MG

100 mg60,200

Cl

O

Cl

O

P

OH

137751-100MG

100 mg

Cl

Cl

Cl49216-45

ClO

63,40049216-46137752-100MG

100 mg63,400(11aR)-3,7-Bis(triphenylsilyl)-10,11,12,13-tetrahydro-5-hydroxy-5-oxide-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin(11aS)-3,7-Bis(triphenylsilyl)-10,11,12,13-tetrahydro-5-hydroxy-5-oxide-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin(11aR)-3,7-Bis([1,1':3',1''-terphenyl]-5'-yl)-10,11,12,13-tetrahydro-5-hydroxy-5oxide-diindeno[7,1-de:1',7'-fg][1,3,2]
dioxaphosphocin(11aS)-3,7-Bis([1,1':3',1''-terphenyl]-5'-yl)-10,11,12,13-tetrahydro-5-hydroxy-5oxide-diindeno[7,1-de:1',7'-fg][1,3,2]
dioxaphosphocin(11aR)-3,7-Bis[3,5-bis(tert-butyl)-4methoxyphenyl]-10,11,12,13-tetrahydro5-hydroxy-5-oxide-diindeno[7,1-de:1',7'fg][1,3,2]dioxaphosphocin1372719-94-2-

1352810-38-8

-

Ph

Ph

SiPh3

SiPh3

O

O

O

OH

O

P

O

SiPh3

P

OMe

O

O

OH

O

P

Ph

O
OH

O
O

Ph

P

49216-47

50 mg

48,20049216-48

50 mg

137762-050MG

48,200(11aR)-3,7-Bis(2,4,6-trimethylphenyl)-10,
11,12,13-tetrahydro-5-hydroxy-5-oxidediindeno[7,1-de:1',7'-fg][1,3,2]dioxaphos
phocin-1801196-27-9
t-Bu

Me

OMe

O

P

O
OH

t-Bu

O
O

t-Bu
OMe

45,80050 mg

137782-050MG

49216-53

P

i-Pr

i-Pr
O
O
P
O
OH
i-Pr

49215-51

OO

77,80049215-52

134901-100MG

t-Bu

49216-50

137772-050MG

50 mg

46,30049216-51

137781-050MG

50 mg

45,800

-

-

-

Me

54,20046,300t-Bu49216-54

137792-050MG

Me

P

Me
O
OH
Me

O
O
P
OH
O

O
O
P
OH
O

Me

50 mg

54,20049216-55

137841-050MG

50 mg

52,60049216-56137842-050MG

50 mg

52,600

i-Pr

P

i-Pr
O
OH
i-Pr

i-Pr

i-Pr

100 mgOH

t-Bu(11aS)-3,7-Bis[4-(2-naphthalenyl)phenyl]-10,11,12,13-tetrahydro-5-hydroxy-diinde
no[7,1-de:1',7'-fg][1,3,2]dioxaphosphocinMe1258276-28-6

134900-100MG

O(11aR)-3,7-Bis[4-(2-naphthalenyl)phenyl]-10,11,12,13-tetrahydro-5-hydroxy-diinde
no[7,1-de:1',7'-fg][1,3,2]dioxaphosphocinO1372719-95-3
i-Pr

50 mg

O

(11aS)-10,11,12,13-Tetrahydro-5hydroxy-3,7-bis[2,4,6-trisisopropylphenyl]-5-oxide-diindeno[7,1-de:1',7'-fg][1,3,2]
dioxaphosphocin

i-Pr

O

Ph

P

Ph

Me

(11aR)-10,11,12,13-Tetrahydro-5hydroxy-3,7-bis[2,4,6-trisisopropylphenyl]-5-oxide-diindeno[7,1-de:1',7'-fg][1,3,2]
dioxaphosphocin

i-Pr

O

(11aS)-3,7-Bis(2,4,6-trimethylphenyl)-10,
11,12,13-tetrahydro-5-hydroxy-5-oxidediindeno[7,1-de:1',7'-fg][1,3,2]dioxaphos
phocin

Me
O
OH
Me

50 mg

137791-050MG

49216-49

137771-050MG

Me

Me

t-Bu

49216-52

OH

Ph

OMe

(11aS)-3,7-Bis[3,5-bis(tert-butyl)-4methoxyphenyl]-10,11,12,13-tetrahydro5-hydroxy-5-oxide-diindeno[7,1-de:1',7'fg][1,3,2]dioxaphosphocin

O

O

SiPh3
Ph

137761-050MG

t-Bu

i-Pr

100 mg77,800Chiral Phosphoramidite Ligands(11bR)-N,N-Dimethyl-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine(11bS)-N,N-Dimethyl-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine

157488-65-8

185449-80-3

OO

49213-52

110291-001G

1g

O

P N

17,600O

49213-53

110292-001G

1g

P N

17,6006

Chiral Auxiliaries(R)-4-Benzyl-2-oxazolidinone(S)-4-Benzyl-2-oxazolidinone

HNO

10,70025 g101711-78-8

O
49212-23

O
10,70025 g100332-025G

O

N

O
49212-26

22,4001g

100641-001G(3aS,8aR)-3,3a,8,8a-Tetrahydro-2H-inde
no[1,2-d]oxazol-2-one

23204-70-8

135969-65-2

135969-64-1

H
N

H
N

H
N

O

49213-04

O

22,4001g

110694-001G(R)-4-Isopropyl-2-oxazolidinethione

49213-86110683-001G

49213-17

36,00049213-18(R)-3-Isopropyl-2,5-piperazinedione

H
N

Boc

O

O

1g

25,4001g

Chiral Imidazoles(4R,5R)-N-(3,5-Bis(trifluoromethyl)phenyl)-4,5-diphenyl-4,5-dihydro-1H-imidazol-2-amine(4S,5S)-N-(3,5-Bis(trifluoromethyl)phenyl)-4,5-diphenyl-4,5-dihydro-1H-imidazol-2-amine

-

-

H
N

F3C

H
N

H
N

F3C

49216-07

136642-100MG

H
N
N

N
CF3

CF3

100 mg49,90049216-06

136641-100MG

100 mgO

1g

22,70049,900O
49212-20

1g120811-001G

H
NS

36,000O
49212-21

1g120822-001GS

36,000100516-54-9

105228-46-4

112741-49-8

Cbz

Cbz

Boc

N

N

N

O

O

49212-24

25,8001g

110643-001G(S)-3-Isopropyl-2,5-piperazinedioneHN

23,500145588-94-9(2R,3S)-6-Oxo-2,3-diphenyl-4-morpholin
ecarboxylic Acid tert-Butyl Ester

O

49213-19(S)-4-Benzyloxazolidine-2-thione

HNO

22,400

1g

Benzyl
(2S,3R)-6-oxo-2,3-diphenyl-4-morpholine
carboxylate

O100991-001G(R)-4-Benzyloxazolidine-2-thione

49213-03

110693-001G

190970-58-2

16944-60-8NH

22,4001g

O

O

Benzyl
(2R,3S)-6-oxo-2,3-diphenyl-4-morpholine
carboxylate

143673-66-9

N49213-71

36,0001g120802-001G

112741-50-1

100512-001G

49213-87

110684-001G

O

S

O

(2S,3R)-6-Oxo-2,3-diphenyl-4-morpholin
ecarboxylic Acid tert-Butyl Ester

O

22,700

H
N
S

1g

1g

104499-08-3

HN

120791-001GO(S)-4-Isopropyl-2-oxazolidinethione

1217463-35-8

OO

49212-27

H
N

O
O

O
100642-001G(4R,5S)-4,5-Diphenyl-2-oxazolidinone

86286-50-2

NO(3aR,8aS)-3,3a,8,8a-Tetrahydro-2H-inde
no[1,2-d]oxazol-2-one(4S,5R)-4,5-Diphenyl-2-oxazolidinone

7131685-53-5

HNO
49212-22(S)-4-Benzyl-3-propionyl-2-oxazolidinone

90719-32-7

102029-44-7

100331-025G(R)-4-Benzyl-3-propionyl-2-oxazolidinone

49213-20

100992-001G

49212-25

110644-001G

25,800O

49213-70

100511-001G

1g

343338-28-3

O
S

O
S

49213-23100531-001G

NH2

1g

7,300

25,400(S)-2-Methyl-2-propanesulfinamide

196929-78-9

NH
23,5001g(R)-2-Methyl-2-propanesulfinamide

O

1g

O

O

49213-24

100532-001G

NH2

1g

7,300

Chiral Heterocyclic Building Blocks(R)-3-Pyrrolidinol Hydrochloride(S)-3-Pyrrolidinol Hydrochloride

122536-94-1

104706-47-0

OH49213-80

19,7001g135279-001G(3S,4S)-1-(Phenylmethyl)-3,4-pyrrolidine
diol49213-81

NH

49213-25

1g110941-001G

20,500(S)-N-Boc-2-methylpiperazine

49213-26

20,8001g(R)-(10-Camphorsulfonyl)oxaziridine

S O
O

49212-66(S)-N-Boc-2-hydroxymethylmorpholine

169447-70-5

135065-71-3

135065-76-8

H
N

O

O

N
Boc

N
Boc

N
Boc

49213-36

15,8001g49213-37

1g

110972-001G

15,80049213-34

OH

N
Boc
1g

100481-001GOH

23,20049213-351g100482-001G

23,200(S)-(10-Camphorsulfonyl)oxaziridine

104322-63-6

N

1g

110981-001G

20,8001g

HN110971-001G

104372-31-8

O49213-78

135322-001G(R)-N-Boc-2-hydroxymethylmorpholine

N

49213-79

20,5001g

110942-001G

170033-47-3

OH135323-001GOHN(R)-N-Boc-2-methylpiperazine

90365-74-5
HO

163439-82-5
HO

NHBoc

N
H
19,7001g135280-001G

122536-76-9

NHBoc

HCl

N
H

(3R,4R)-1-(Phenylmethyl)-3,4-pyrrolidine
diol(S)-3-(N-Boc-amino)pyrrolidine

122536-77-0

OH

HCl

N
H

(R)-3-(N-Boc-amino)pyrrolidineO
19,700S O
O49212-67N

1g110982-001G

19,700Chiral Amino Amides(2R)-2-Amino-3-methyl-N-2-pyridinylbuta
namide(2S)-2-Amino-3-methyl-N-2-pyridinylbuta
namide(2R)-2-Amino-3,3-dimethyl-N-(phenylmethyl)butanamide(2S)-2-Amino-3,3-dimethyl-N-(phenylmethyl)butanamide(2R)-2-Amino-N,3,3-trimethyl-N-(phenyl
methyl)butanamide

1568043-19-5

167261-43-0

268556-62-3

207121-91-3

-

O
H2N

N
H

49212-10135893-250MG

OO

250 mgN45,500

H2N

N
H49212-11

135892-250MG

N

250 mg45,500

H2N

O
H 2N

N
H

49214-881g135564-001G

36,200(2S)-2-Amino-N,3,3-trimethyl-N-(phenyl
methyl)butanamide(2S)-N-[(1R,2S)-2-Hydroxy-1,2-diphenylethyl]-2-pyrrolidinecarboxamide(2S)-N-[(1S,2R)-2-Hydroxy-1,2-diphenylethyl]-2-pyrrolidinecarboxamide

947383-62-2

529486-23-5

529486-25-7

49214-87

135563-100MG

O
H2N

N
H

100 mg29,50049214-75

135397-100MGN

100 mg30,500O
H2N49214-26

120322-100MGN

100 mgHN

30,500O

49215-15

135949-100MG

N
H

H
N

O

OH

100 mg28,30049215-14

135948-100MG

N
H

OH

100 mg28,3008

Chiral Amino Alcohol Ligands & Building Blocks(1R,2S)-1-Amino-2-indanol(1S,2R)-1-Amino-2-indanol

136030-00-7

126456-43-7

OH49212-06

52,60025 g(1S,2S)-2-Aminocyclohexanol
Hydrochloride

13374-30-6

49212-07

25 g100224-025G

13,700322407-34-1

OH
O

OH
O

OH

OH

N
H

N
H

N
H

N
H

49213-401g120525-001G

17,200

OH
O

OH
O

1g

N
H

16,900(S)-2-Amino-3-methyl-1,1-diphenyl-1-but
anol78603-95-949213-16

135126-001G

91g

17,200(1R,2S)-2-Amino-1,2-diphenylethanol

49212-18

135113-001G

20,8001g(1S,2R)-2-Amino-1,2-diphenylethanol

23364-44-5

49212-19

20,8001g

135114-001G(R)-2-Amino-3-methyl-1,1-diphenyl-1-but
anol

86695-06-9
NH2
OH

O

H2N
1g

17,60049212-02100233-025G

OH
25 g

H2N
58,700(S)-2-Amino-1,1,2-triphenylethanol

49212-03

100234-025G

OH
68,90025 g49212-08110471-001G

21,6001g(R)-2-Amino-1,1,3-triphenyl-1-propanol(S)-2-Amino-1,1,3-triphenyl-1-propanol

129704-13-8

86906-05-0

79868-78-3

NH2

NH2

NH2

NH2

OH

21,6001g

79868-79-4

OH49212-09

49213-41120536-001G

23190-16-1(R)-2-Amino-1,1,2-triphenylethanol

NH2110472-001G

13,9001g141553-09-5

198422-64-949213-15

49212-00

110445-001G

190848-36-3

134108-76-2

135125-001G

56,60025 g214348-95-5[(1S,2S)-2-Hydroxycyclohexyl]carbamic
Acid Phenylmethyl Ester

O

49213-39

110422-025G

HCl(1S,2S)-2-Benzylamino-1-cyclohexanol[(1R,2R)-2-Hydroxycyclohexyl]carbamic
Acid Phenylmethyl Ester

N
H

60,700NH2(1R,2R)-2-Benzylamino-1-cyclohexanol

HCl

1g

25 g

OH

OH
NHBoc

N-[(1S,2S)-2-Hydroxycyclohexyl]acetami
deNH249212-01

49213-38

110421-025G

13374-31-7

N-[(1R,2R)-2-Hydroxycyclohexyl]acetamideOH

110446-001G

55,40066605-57-0

OH
NHBoc

NH2

(1R,2R)-2-Aminocyclohexanol
Hydrochloride

N-Boc-L-phenylalaninol

106454-69-7

OH

NH2

100223-025G

N-Boc-D-phenylalaninol

49212-14

110491-001G

1g

OH

OH

23,30049212-15

110492-001G

1g

23,90049212-16110461-001G

1g

OH22,10049212-17110462-001G

1g

23,000Chiral Alcohol Ligands & Building Blocks(αR)-α-Methyl-4-pyridinemethanol(αS)-α-Methyl-4-pyridinemethanol

27854-88-2

54656-96-1

OHOH(R)-1-Phenyl-1,2-ethanediol(S)-1-Phenyl-1,2-ethanediol

16355-00-3

25779-13-9

OH40434-87-5

OH

OH
O

OH

OH
N

(R)-1-Phenyl-1,2-ethanediol 2-TosylateON

49213-94

134923-250MG

250 mg48,10049213-95

134924-250MG

250 mg48,10049213-74

20,8001g

100611-001G(S)-1-Phenyl-1,2-ethanediol 2-Tosylate(R)-1-[3,5-Bis(trifluoromethyl)phenyl]ethanol(S)-1-[3,5-Bis(trifluoromethyl)phenyl]etha
nol40435-14-1

127852-28-2

225920-05-8

OH

OH
O
O

S

49213-77

1g

25,20095061-46-4

49212-60

100961-001G

1g

21,700108998-83-0

49212-61

21,7001g

100962-001G

126577-48-846755-94-6

OH

OH
HO

49213-05

14,2001g135197-001G

49213-06

135198-001G

49213-93

110602-001G

14,200(αR)-Tetrahydro-α-phenyl-2H-pyran-4methanol

127049-50-7

131726-65-3

1800345-36-1

OH
N

1g

1g

(αS,α'S)-α,α'-Bis(tert-butyl)-[2,2'-bipyridine]-6,6'-dimethanolOH

22,20025,200(αR,α'R)-α,α'-Bis(tert-butyl)-[2,2'-bipyridine]-6,6'-dimethanol

HO

1g

1g

(S)-1,1-Diphenyl-1,2-propanediol

OH

HO

O

CF3

(S)-1,1,2-Triphenylethane-1,2-diolOH49213-92

49213-76

135199-001GHO(R)-1,1,2-Triphenylethane-1,2-diol

110601-001G(R)-1,1-Diphenyl-1,2-propanediol

F3C

CF3

135200-001G

20,800

1g

OH

F3C

O

49213-75

120642-001GS

22,20049214-00

135606-100MG

N

N
HO

100 mgOH

47,30049214-01

135605-100MG

N

O

HO
100 mg47,30049216-10137271-001G

1g

48,200(αS)-Tetrahydro-α-phenyl-2H-pyran-4methanol

910629-24-2

OHO
49216-11137272-001G

1g

48,20010Chiral Amine Ligands & Building Blocks(R)-2,3-Dihydro-1H-inden-1-amine
Hydrochloride(S)-2,3-Dihydro-1H-inden-1-amine
Hydrochloride

32457-23-1

10305-73-4

HCl49212-81

1g(1S,2S)-N,N'-Bis(phenylmethyl)-1,2-cycl
ohexanediamine Dihydrochloride(1R,2R)-N-p-Tosyl-1,2-cyclohexanediamine212611-88-6-

174291-96-4

NN
H
H
HCl HClNN
H
H
HCl HCl

HCl
NH2

NH2

110561-001G(1R,2R)-N,N'-Bis(phenylmethyl)-1,2-cycl
ohexanediamine Dihydrochloride

22,00049212-821g110562-001G

22,00049213-46

134910-001G

1g

23,200(1S,2S)-N-p-Tosyl-1,2-cyclohexanediamine(1R,2R)-N,N'-Di-p-tosyl-1,2-cyclohexane
diamine(1S,2S)-N,N'-Di-p-tosyl-1,2-cyclohexane
diamine174291-97-5

143585-47-1

212555-28-7

O
S N
H
O

O
S N
H
O

O
H2N

N S
H
O

49213-61

1g120636-001G

24,50049213-56

120615-001G

O
N S
H
O

1g

23,20049213-57

120606-001G

1g

23,200(1R,2R)-Diphenylethane-1,2-diamine

35132-20-8

O
N S
H
O

1g

49213-47

134911-001G

O
H2N

H2N
23,20049213-01

100245-001G

49213-60

120625-001G

1g

24,500(1S,2S)-Diphenylethane-1,2-diamine

29841-69-8

NH2
1g

N S
H
O

H2N
34,40049213-02

100246-001G

NH2
1g

34,400(1R,2R)-N-p-Tosyl-1,2-diphenylethylened
iamine(1S,2S)-N-p-Tosyl-1,2-diphenylethylened
iamine(1R,2R)-N,N'-Di-p-tosyl-1,2-diphenyl-1,2ethylenediamine(1S,2S)-N,N'-Di-p-tosyl-1,2-diphenyl-1,2ethylenediamine(1R,2R)-N,N'-Bis(trifluoromethanesulfonyl)-1,2-diphenylethylenediamine

144222-34-4

167316-27-0

121758-19-8

170709-41-8

121788-77-0

O
S N
H
O

O
S N
H
O

O
N S
H
O

H2 N

49213-62100265-001G

O
N S
H
O

H2 N

1g

22,00049213-63100266-001G

1g

22,00049213-58

100875-001G

O
N S
H
O

1g

30,800(1S,2S)-N,N'-Bis(trifluoromethanesulfonyl)-1,2-diphenylethylenediamineN-[(1R,2R)-2-Amino-1,2-diphenylethyl]-1,
1,1-trifluoromethanesulfonamideN-[(1S,2S)-2-Amino-1,2-diphenylethyl]-1,
1,1-trifluoromethanesulfonamide

121788-73-6

852212-89-6

167316-28-1

O
CF3 S NH
O

49213-49

135185-001G11O
N S CF3HO
1g

43,100H2 N49214-28

120975-001GO
N S CF3HO
1g26,900H2 N49214-30

120986-001GO
N S CF3HO
1g26,90049213-59100876-001GO
CF3 S N
H
O

O
N S
H
O

1g

30,80049213-48135186-001GO
N S CF3HO
1g

43,100Chiral Phosphoric Acids(11bR)-4-Hydroxy-4-oxide-dinaphtho[2,1d:1',2'-f][1,3,2]dioxaphosphepin(11bS)-4-Hydroxy-4-oxide-dinaphtho[2,1d:1',2'-f][1,3,2]dioxaphosphepin(11bR)-4-Hydroxy-2,6-diphenyl-4-oxide-d
inaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin(11bS)-4-Hydroxy-2,6-diphenyl-4-oxide-d
inaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin(11bR)-4-Hydroxy-2,6-bis(4-methoxyphenyl)-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]
dioxaphosphepin39648-67-4

35193-64-7

695162-86-8

874948-59-1

695162-88-0
O

O
O

P

O

O

OH

O

P

O

O

OH

O

P

O

O

OH

O

O

P

O
O
P
O
OH

OH

O

49212-33

13,7001g

100241-001G

49212-34

13,6001g

100242-001G

49214-23111471-100MG

36,200100 mg49214-24

111472-100MG

100 mg36,20049214-35

121281-100MG

100 mg46,600(11bS)-4-Hydroxy-2,6-bis(4-methoxyphenyl)-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]
dioxaphosphepin(11bR)-2,6-Bis[4-(1,1-dimethylethyl)phenyl]-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin(11bR)-4-Hydroxy-2,6-bis[4-(trifluoromethyl)phenyl]-4-oxide-dinaphtho[2,1-d:1',2'f][1,3,2]dioxaphosphepin(11bS)-4-Hydroxy-2,6-bis[4-(trifluoromethyl)phenyl]-4-oxide-dinaphtho[2,1-d:1',2'f][1,3,2]dioxaphosphepin(11bR)-2,6-Bis(3,5-dimethylphenyl)-4-hy
droxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin

1374030-19-9861909-30-0

791616-59-6

1264573-23-0

861909-53-7

O

CF3

O
O
P
OH
O

O
O
P
O
OH

O
O
P
O
OH

49214-36

100 mg

O
O
P
O
OH

CF3

O

121292-100MG

CF3

46,60049214-22111461-100MG

44,600100 mg49214-58

135042-100MG

CF3

36,200100 mgO
O
PO
OH

49214-59

135043-100MG

100 mg36,20049214-07

110181-100MG

100 mg36,200(11bS)-2,6-Bis(3,5-dimethylphenyl)-4-hy
droxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin(11bR)-2,6-Bis[3,5-bis(trifluoromethyl)phenyl]-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin(11bS)-2,6-Bis[3,5-bis(trifluoromethyl)phenyl]-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin(11bR)-4-Hydroxy-2,6-bis(2,4,6-trimethyl
phenyl)-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin(11bS)-4-Hydroxy-2,6-bis(2,4,6-trimethyl
phenyl)-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin

1170736-59-0

791616-62-1

878111-17-2

695162-87-9

878111-18-3

CF3

CF3

CF3
O
O
P
O
OH

CF3

O
O
P
O
OH
CF3

49214-08

100 mg36,20049214-05

110171-100MG

O

P

O

O

OH

O

P

O
OH

CF3

CF3

110182-100MG

O

O
O
P
O
OH

CF3

36,500100 mg49214-06

110172-100MG

36,500100 mg49214-33

121261-100MG

100 mg53,50049214-34

121272-100MG

100 mg53,500(11bR)-4-Hydroxy-2,6-bis[2,4,6-tris(1methylethyl)phenyl]-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin(11bS)-4-Hydroxy-2,6-bis[2,4,6-tris(1-methylethyl)phenyl]-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin(11bS)-4-Hydroxy-2,6-bis([1,1':3',1''-terphenyl]-5'-yl)-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin(11bR)-4-Hydroxy-2,6-di-2-naphthalenyl4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]diox
aphosphepin(11bS)-4-Hydroxy-2,6-di-2-naphthalenyl4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]diox
aphosphepin

791616-63-2

874948-63-7

1496637-05-8

791616-56-3

874948-60-4

i-Pr

i-Pr

i-Pr

i-Pr
O
O
P
OH
O
i-Pr

i-Pr

49215-26

111441-100MG

i-Pr

i-Pr
O
O
P
OH
O
i-Pr

i-Pr

100 mgi-Pr55,20049214-19111442-100MG

O

O
O
P
O OH

O

P

O

O

OH

O

P

O
OH

i-Pr

100 mg57,80049214-37

121332-100MG

55,200100 mg49214-56

135040-100MG

100 mg40,10049214-57

135041-100MG

100 mg40,100(11bR)-4-Hydroxy-2,6-di-1-naphthalenyl4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]diox
aphosphepin(11bS)-4-Hydroxy-2,6-di-1-naphthalenyl4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]diox
aphosphepin(11bR)-2,6-Bis(triphenylsilyl)-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxa
phosphepin(11bS)-2,6-bis(triphenylsilyl)-4-Hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxa
phosphepin(11bR)-2,6-Di-1-pyrenyl-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphos
phepin864943-23-7

929097-93-8

791616-55-2

929097-92-7

-

Ph
Ph
Si
Ph

Ph
Ph
Si
Ph

O
O
P
O
OH

O
O
P
O
OH

Ph
Si
Ph
Ph

Ph
Si
Ph
Ph

O
O
P
OH
O

49214-54

135038-100MG

100 mgO
O
POOH

40,60049214-55

135039-100MG

100 mg40,60049212-64

110201-100MG

100 mg57,00049212-65

110202-100MG

100 mgO
O
POOH

57,00049214-50

134979-100MG

100 mg55,000(11bS)-2,6-Di-1-pyrenyl-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphos
phepin(11bR)-8,9,10,11,12,13,14,15-Octahydro-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'f][1,3,2]dioxaphosphepin(11bS)-8,9,10,11,12,13,14,15-Octahydro-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'f][1,3,2]dioxaphosphepin(11bR)-8,9,10,11,12,13,14,15-Octahydro-4-hydroxy-2,6-diphenyl-4-oxide-dinapht
ho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin(11bS)-8,9,10,11,12,13,14,15-Octahydro-4-hydroxy-2,6-diphenyl-4-oxide-dinapht
ho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-

297752-25-1

1193697-61-8

791616-65-4

945852-48-2

O

O
O
P
O OH

49214-51

134980-100MG

100 mgO55,00049213-66

100691-100MGP

100 mg

O

O

OH

O

27,00049213-67100692-100MGP

100 mg

O

O

OH

O

27,00049214-93

135625-100MG

P

O

O

OH

O

100 mg38,20049214-94

135626-100MG

P

O
OH

100 mg38,20012Chiral Phosphoric Acids(11bR)-2,6-Bis(3,5-dimethylphenyl)-8,9,1
0,11,12,13,14,15-octahydro-4-hydroxy-4oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxa
phosphepin(11bS)-2,6-Bis(3,5-dimethylphenyl)-8,9,1
0,11,12,13,14,15-octahydro-4-hydroxy-4oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxa
phosphepin(11bR)-8,9,10,11,12,13,14,15-Octahydro4-hydroxy-2,6-di-2-naphthalenyl-4-oxidedinaphtho[2,1-d:1',2'-f][1,3,2]
dioxaphosphepin(11bS)-8,9,10,11,12,13,14,15-Octahydro-4-hydroxy-2,6-di-2-naphthalenyl-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosp
hepin(11bR)-8,9,10,11,12,13,14,15-Octahydro-4-hydroxy-2,6-di-1-naphthalenyl-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosp
hepin

1065214-95-0-

922711-75-9-

1242066-20-1

O
O
P
O
OH

49214-09110241-100MG

O O
P
O OH

O
O
P
O
OH

42,000100 mg49214-10110242-100MG

42,000100 mg49215-19110261-100MG

OO

40,600100 mg49214-13110262-100MG

P

O

O
O
P
O
OH

OH

42,200100 mg49214-20

111451-100MG

42,500100 mg(11bS)-8,9,10,11,12,13,14,15-Octahydro-4-hydroxy-2,6-di-1-naphthalenyl-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosp
hepin(11bR)-8,9,10,11,12,13,14,15-Octahydro-4-hydroxy-2,6-bis[2,4,6-tris(1-methylethyl)phenyl]-4-oxide-dinaphtho[2,1-d:1',2'-f][
1,3,2]dioxaphosphepin(11bS)-8,9,10,11,12,13,14,15-Octahydro-4-hydroxy-2,6-bis[2,4,6-tris(1-methylethyl)phenyl]-4-oxide-dinaphtho[2,1-d:1',2'-f][
1,3,2]dioxaphosphepin(11bR)-2,6-Bis[3,5-bis(trifluoromethyl)phenyl]-8,9,10,11,12,13,14,15-octahydro-4hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin(11bS)-2,6-Bis[3,5-bis(trifluoromethyl)phenyl]-8,9,10,11,12,13,14,15-octahydro-4hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-929294-27-9878111-20-7

1011465-24-9

-

iPr

iPr

iPr

49214-21

iPr

iPr
O
O
P
O
OH
iPr

O
O
P
O
OH

111452-100MG

iPr

42,500100 mg49214-48

134954-100MG

CF3

CF3

iPr
O
O
P
O
OH
iPr

iPr

iPr

61,200100 mg49214-49

134955-100MG

CF3

CF3

O
O
P
O
OH

O
O
P
O
OH

CF3

iPr

61,200100 mgCF3

CF349214-11110251-100MG

CF3

42,200100 mg49214-12110252-100MG

42,200100 mg(11bR)-8,9,10,11,12,13,14,15-Octahydro-4-hydroxy-2,6-bis(triphenylsilyl)-4-oxidedinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosp
hepin(11bS)-8,9,10,11,12,13,14,15-Octahydro-4-hydroxy-2,6-bis(triphenylsilyl)-4-oxidedinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosp
hepin(11bS)-2,6-Bis[4-(1,1-dimethylethyl)
phenyl]-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin(11bR)-4-Hydroxy-2,6-bis(4-nitrophenyl)4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]
dioxaphosphepin(11bS)-4-Hydroxy-2,6-bis(4-nitrophenyl)4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]
dioxaphosphepin

957790-94-2

1157989-25-7

1217901-32-0

695162-89-1

878111-16-1

Ph
Ph
Si
Ph

Ph
Ph
Si
Ph

O
O
P
O
OH

O
O
P
O
OH

Ph
Si
Ph
Ph

Ph
Si
Ph
Ph

49214-31

121201-100MG

65,500100 mg49214-32

121212-100MG

NO2

t-Bu

O O
P
O
OH

O
O
P
O
OH

65,50049215-27111462-100MG

42,700100 mg

O
O
P
O
OH

NO2

t-Bu

100 mgNO249215-42

121221-100MG

NO2

39,400100 mg49215-43121232-100MG

39,400100 mg(11bR)-4-Hydroxy-2,6-bis([1,1':3',1''terphenyl]-5'-yl)-4-oxide-dinaphtho[2,1d:1',2'-f][1,3,2]dioxaphosphepin(11bR)-2,6-Bis[3,5-bis(1,1-dimethylethyl)4-methoxyphenyl]-4-hydroxy-4-oxidedinaphtho[2,1-d:1',2'-f][1,3,2]
dioxaphosphepin(11bS)-2,6-Bis[3,5-bis(1,1-dimethylethyl)4-methoxyphenyl]-4-hydroxy-4-oxidedinaphtho[2,1-d:1',2'-f][1,3,2]
dioxaphosphepin(11bR)-2,6-Bis(3,5-dichlorophenyl)-4hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin(11bS)-2,6-Bis(3,5-dichlorophenyl)-4hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin

361342-55-4

957790-93-1-

1191451-24-7

1374030-20-2

t-Bu

Ph

Ph

52,800100 mg49215-86

t-Bu

t-Bu

OMe

OMe

135824-100MG(11bR)-2,6-Bis(4-chlorophenyl)-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]
dioxaphosphepin(11bS)-2,6-Bis(4-chlorophenyl)-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]
dioxaphosphepin

922711-71-5-

49215-87

135825-100MG(11bR)-4-Hydroxy-2,6-bis(2,3,4,5,6pentafluorophenyl)-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin

49216-08

F137121-100MG(11bS)-4-Hydroxy-2,6-bis(2,3,4,5,6pentafluorophenyl)-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin

1882075-20-8
FCl49216-26

137591-100MG

100 mgFCl39,40049216-27

137592-100MG

100 mg39,400200250-100MG

40,100(11bR,11'bR)-2,2'-[Oxybis(methylene)]bis[4-hydroxy-4,4'-dioxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin]1022915-09-8
F
O

F
O O
P
O
OH
F
F

F

F

F

49216-81

137122-100MG

100 mg

F

F
O O
P
O
OH
F
F

O
O
P
O
OH

33,400

F

F
F

O
O
P
O
OH

Cl

40,100100 mg

F

Cl

Cl

Cl

49,200100 mg1284293-45-3

Cl

O
O
P
O
OH

Cl

t-Bu

49,200100 mg

Cl

Cl
O
O
P
O
OH

O
O
P
O
OH

t-Bu

Ph

121321-100MG

t-Bu

O
O
P
O
OH

Cl

Cl

OMe

t-Bu

Ph
O
O
P
O
OH

49215-44

t-Bu
OMe

O
O
P
O
OH

O
O
P
HO
O

F
F

100 mg53,00049216-82

200251-100MG

100 mg53,00049215-95

135905-025MG

100 mg34,800(11bS,11'bS)-2,2'-[Oxybis(methylene)]bis[4-hydroxy-4,4'-dioxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin](11bR)-2,6-Bis(4-chlorophenyl)-8,9,10,
11,12,13,14,15-octahydro-4-hydroxy-4oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]
dioxaphosphepin(11bS)-2,6-Bis(4-chlorophenyl)-8,9,10,
11,12,13,14,15-octahydro-4-hydroxy-4oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]
dioxaphosphepin(11bR)-8,9,10,11,12,13,14,15-Octahydro4-hydroxy-2,6-di-9-phenanthrenyl-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]
dioxaphosphepin(11bS)-8,9,10,11,12,13,14,15-Octahydro4-hydroxy-2,6-di-9-phenanthrenyl-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]
dioxaphosphepin

1447217-75-5

915038-16-3-

934201-93-1

1028416-47-8

O
O
P
O OH

O
O
P
O OH

O
O
O
P
O
OH

49215-94

135904-025MG

13

O
O
P
HO
O

25 mg

34,80049215-72

135627-100MG

Cl

Cl

O
O P
OH
O

O
O P
OH
O

Cl

Cl

100 mg38,40049215-73

135628-100MG

100 mg38,40049215-74

135629-100MG

100 mg57,80049215-75

135630-100MG

100 mg57,800Chiral Phosphoric Acids(11bR)-2,6-Di-9-anthracenyl-8,9,10,11,
12,13,14,15-octahydro-4-hydroxy-4oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]
dioxaphosphepin(11bS)-2,6-Di-9-anthracenyl-8,9,10,11,
12,13,14,15-octahydro-4-hydroxy-4oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]
dioxaphosphepin(11bR)-2,6-Bis[4-(2-naphthalenyl)phenyl]-8,9,10,11,12,13,14,15-octahydro-4hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin(11bS)-2,6-Bis[4-(2-naphthalenyl)phenyl]-8,9,10,11,12,13,14,15-octahydro-4hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin(11bR)-2,6-Bis[4-(tert-butyl)phenyl]-8,9,
10,11,12,13,14,15-octahydro-4-hydroxy4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]
dioxaphosphepin

1011465-29-4

-

-

-

1569807-27-7
t-Bu

O
O
P
OH
O

O
O
P
OH
O

O
O
P
O
OH

O
O P
OH
O

O
O
P
O
OH

t-Bu

49215-76135631-100MG

100 mg57,10049215-77

135632-100MG

57,100100 mg49216-12137311-100MG

58,600100 mg49216-13137312-100MG

100 mg58,60049216-16

137421-100MG

100 mg38,400(11bS)-2,6-Bis[4-(tert-butyl)phenyl]-8,9,
10,11,12,13,14,15-octahydro-4-hydroxy4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]
dioxaphosphepin(11bR)-8,9,10,11,12,13,14,15-Octahydro-4-hydroxy-2,6-bis([1,1':3',1''-terphenyl]5'-yl)-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin(11bS)-8,9,10,11,12,13,14,15-Octahydro-4-hydroxy-2,6-bis([1,1':3',1''-terphenyl]5'-yl)-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin(11bR)-8,9,10,11,12,13,14,15-Octahydro-4-hydroxy-2,6-bis[4-(trifluoromethyl)
phenyl]-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin(11bS)-8,9,10,11,12,13,14,15-Octahydro-4-hydroxy-2,6-bis[4-(trifluoromethyl)
phenyl]-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-

1569807-15-3

1496637-09-2

791616-70-1

-

Ph

t-Bu

Ph

CF3

Ph
O
O P
OH
O

O
O P
OH
O

O
O P
OH
O

Ph

O
O
P
O
OH

CF3

Ph

49216-17

100 mg

O
O
P
O
OH

Ph

t-Bu

137422-100MG

CF3

Ph

38,40049216-18137471-100MG

CF3

Ph

62,600100 mg49216-19137472-100MG

62,600100 mg49216-20

137521-100MG

100 mg40,30049216-21

137522-100MG

100 mg40,300(11bR)-8,9,10,11,12,13,14,15-Octahydro-4-hydroxy-2,6-bis(4-methoxyphenyl)-4oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]
dioxaphosphepin(11bS)-8,9,10,11,12,13,14,15-Octahydro-4-hydroxy-2,6-bis(4-methoxyphenyl)-4oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]
dioxaphosphepin(11bR)-8,9,10,11,12,13,14,15-Octahydro-4-hydroxy-2,6-bis(4-nitrophenyl)-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]
dioxaphosphepin(11bS)-8,9,10,11,12,13,14,15-Octahydro-4-hydroxy-2,6-bis(4-nitrophenyl)-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]
dioxaphosphepin(11bR)-2,6-Bis([1,1'-biphenyl]-4-yl)-8,9,
10,11,12,13,14,15-octahydro-4-hydroxy4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]
dioxaphosphepin

1011465-27-2-

791616-68-7-

861909-35-5

O
O
P
O
OH

49216-22

100 mgOMe

40,30049216-23137552-100MG(11bS)-2,6-Bis([1,1'-biphenyl]-4-yl)-8,9,
10,11,12,13,14,15-octahydro-4-hydroxy4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]
dioxaphosphepin(11bR)-8,9,10,11,12,13,14,15-Octahydro-4-hydroxy-2,6-bis(2,4,6-trimethylphenyl)-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]
dioxaphosphepin-

1011465-23-8

137642-100MG

100 mg46,60049216-33

137651-100MG

100 mg-

100 mg46,600-49216-34

137652-100MG

100 mg

t-Bu

t-Bu

OMe

OMe

t-Bu

t-Bu

O
O
P
O
OH

O
O
P
O
OH

Me

t-Bu

t-Bu

OMe

OMe
t-Bu

t-Bu

55,20049216-35

137661-100MG

100 mg53,30049216-36

137662-100MG

100 mg53,300

O
O
P
O
OH

O
O
P
O
OH

100 mg49216-31

137641-100MG

Me

Me

1225195-02-7

42,000-Me

55,200100 mg(11bS)-8,9,10,11,12,13,14,15-Octahydro4-hydroxy-2,6-bis(3,5-di-tert-butyl-4methoxyphenyl)-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin

MeO
O P
OH
O
Me

(11bS)-8,9,10,11,12,13,14,15-Octahydro-4-hydroxy-2,6-di-1-pyrenyl-4-oxidedinaphtho[2,1-d:1',2'-f][1,3,2]
dioxaphosphepin

49216-37

49216-25

137572-100MG(11bR)-8,9,10,11,12,13,14,15-Octahydro4-hydroxy-2,6-bis(3,5-di-tert-butyl-4methoxyphenyl)-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepinMe(11bR)-8,9,10,11,12,13,14,15-Octahydro-4-hydroxy-2,6-di-1-pyrenyl-4-oxidedinaphtho[2,1-d:1',2'-f][1,3,2]
dioxaphosphepin

137671-100MG

NO2

42,000100 mgO
O
POOH(11bS)-8,9,10,11,12,13,14,15-Octahydro-4-hydroxy-2,6-bis(2,4,6-trimethylphenyl)-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]
dioxaphosphepin

MeMe

49216-32

49216-24

137571-100MG

MeO
O P
OH
O
Me

O
O
P
O
OH

O
O
P
O
OH

NO2

40,300100 mg

Me

NO2

O
O
P
O
OH

O
O
P
O
OH

OMe

137551-100MG

NO2

OMe

OMe

54,50049216-38

137672-100MG

100 mg54,50014

BINAM Ligands(R)-[1,1'-Binaphthalene]-2,2'-diamine(S)-[1,1'-Binaphthalene]-2,2'-diamine

18531-95-8

18741-85-0

NH2

NH2

NH2

49212-281g100751-001GNH2

18,80049212-301g100752-001G

17,000BINAP Ligands
1,1'-[(1R)-[1,1'-binaphthalene]-2,2'-diyl]bis[1,1-diphenylphosphine]

1,1'-[(1S)-[1,1'-binaphthalene]-2,2'-diyl]bis[1,1-diphenylphosphine](R)-[1,1'-Binaphthalene]-2,2'-diylbis[1,1-diphenyl-1,1'-phosphine oxide](S)-[1,1'-Binaphthalene]-2,2'-diylbis[1,1-diphenyl-1,1'-phosphine oxide]76189-55-4

76189-56-5

94041-16-4

94041-18-6

O
P

P

P

P

P
P
O

49212-51

1g

110231-001G

15,10049212-52

1g

110232-001G

15,40049212-311g135066-001G

O

Ph

P

Ph
Ph

P

Ph

17,000O

49212-321g135067-001G

Ph
Ph
Ph
Ph

17,000Ferrocene Ligands(R)-1-Ferrocenylethanol(S)-1-Ferrocenylethanol

33136-66-2

35025-24-2

OH

OH
Fe
49213-11Fe

1g100291-001G

21,70049213-121g100292-001G

22,400

Salen Ligands(1R,2R)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine(1S,2S)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine

135616-40-9

135616-36-3

N

N

N

OH HO

49213-44

25 g121395-025G

N

OH HO

70,60049213-45

25 g

121406-025G

70,600TADDOLs Ligands(4R,5R)-2,2-Dimethyl-α,α,α',α'-tetrapheny
l-1,3-dioxolane-4,5-dimethanol(4S,5S)-2,2-Dimethyl-α,α,α',α'-tetrapheny
l-1,3-dioxolane-4,5-dimethanol(2R,3R)-1,4-Dioxaspiro[4.5]decane-2,3-diylbis(diphenylmethanol)(2S,3S)-1,4-Dioxaspiro[4.5]decane-2,3-di
ylbis(diphenylmethanol)

93379-48-7

93379-49-8

114026-76-5

123287-35-4

OH HO

OH HO

OHHO

OHHO

O

O

O

O

49212-95

110405-001G

15

O

1g

13,90049212-96

110406-001GO

1g

13,80049212-97135718-001GO

1g

22,20049213-00

135719-001GO

1g

22,200Trost Ligands
N,N'-(1R,2R)-1,2-Cyclohexanediylbis[2-(diphenylphosphino)benzamide]

N,N'-(1S,2S)-1,2-Cyclohexanediylbis[2-(diphenylphosphino)benzamide]

N,N'-[(1R,2R)-1,2-Diphenyl-1,2-ethanediyl]bis[2-diphenylphosphinobenzamide]

N,N'-[(1S,2S)-1,2-Diphenyl-1,2-ethanediyl]bis[2-diphenylphosphinobenzamide]

138517-61-0

169689-05-8

138517-62-1

143668-57-9

NH
P

N
H

O

49213-50

NHO

P

26,4001g

100785-001GP

O

49213-51

100786-001G

N
H

NH

O

P

P

23,3001g

O49213-54

135084-001G

N
H

NH
O

1g

P

P

35,300N
H
O

O

49213-551g135085-001GP

35,300

Pharmaceutical Intermediates(S)-3-(Dimethylamino)-1-(2-thienyl)-1-propanol(R)-Methyl
6-Hydroxy-2,3-dihydrobenzofuran-3-ylac
etate(S)-Methyl
6-Hydroxy-2,3-dihydrobenzofuran-3-ylac
etate132335-44-5

1234474-58-8

1000414-38-9

HO

OH
S

HO

O

N

49212-91

13,4001g

111132-001G

N,N,N',N'-Tetramethyl-L-tartramide

49213-21

135347-250MG

O

49215-67

O

HO

O

O

O
49213-22

135346-250MG

250 mg21,000531-95-3

O

HO

O

OH

49213-09

100151-001G

1g

28,000OH

49213-10100152-001G

1g

42,00063126-52-3

OOH
N(CH3)2
OH O

135328-005G

221054-79-1

O

21,000(S)-Equol

N,N,N',N'-Tetramethyl-D-tartramide

26549-65-5(H3C)2N

250 mg(R)-Equol

5g

18,000(H3C)2N

49215-68

135329-005G

OH
N(CH3)2OH O

1g

18,000

Proline-Based Organocatalysts(2R)-N-Methyl-α,α-diphenyl-2-pyrrolidine
methanol(2S)-N-Methyl-α,α-diphenyl-2-pyrrolidine
methanol

144119-12-0110529-22-1

NN

49213-42

110501-001GOH

1g

22,70049213-43

110502-001GOH

1g

22,60016

Squaramide Catalysts
3-[[(1R,2R)-2-(1-Piperidinyl)cyclohexyl]
amino]-4-[[4-(trifluoromethyl)phenyl]amino]-3-cyclobutene-1,2-dione

3-[[(1S,2S)-2-(1-Piperidinyl)cyclohexyl]amino]-4-[[4-(trifluoromethyl)phenyl]amino]-3-cyclobutene-1,2-dione3-[[3,5-Bis(trifluoromethyl)phenyl]amino]4-[[(1R,2R)-2-(dimethylamino)cyclohexyl]
amino]-3-cyclobutene-1,2-dione3-[[3,5-Bis(trifluoromethyl)phenyl]amino]4-[[(1S,2S)-2-(dimethylamino)cyclohexyl]
amino]-3-cyclobutene-1,2-dione3-[[3,5-Bis(trifluoromethyl)phenyl]amino]4-[[(1R,2R)-2-(1-pyrrolidinyl)cyclohexyl]
amino]-3-cyclobutene-1,2-dione

1211565-08-01312991-08-4

1211565-07-9

1263205-96-4

1211565-10-4

CF3

CF3

HN
N
H

N

O

49215-71

N
H

N

O

37,000100 mg135410-100MG

N

HN

H
N

H
N

O

O

CF3

N
CF3

H
N

H
N

O

O

CF3

HN

O
O

49214-82

38,400100 mg135411-100MG

49214-79

CF3

34,600100 mg135402-100MG

49214-80

34,600100 mg135403-100MG

N

CF3

CF3

N
H

O
O

49215-70

135407-100MG

37,900100 mg3-[[3,5-Bis(trifluoromethyl)phenyl]amino]4-[[(1S,2S)-2-(1-pyrrolidinyl)cyclohexyl]amino]-3-cyclobutene-1,2-dione3-[[3,5-Bis(trifluoromethyl)phenyl]amino]4-[[(1R,2R)-2-(dipentylamino)cyclohexyl]
amino]-3-cyclobutene-1,2-dione3-[[3,5-Bis(trifluoromethyl)phenyl]amino]4-[[(1S,2S)-2-(dipentylamino)cyclohexyl]
amino]-3-cyclobutene-1,2-dione3-[[3,5-Bis(trifluoromethyl)phenyl]amino]4-[[(1R,2R)-2-(dimethylamino)-1,2-diphe
nylethyl]amino]-3-cyclobutene-1,2-dione3-[[3,5-Bis(trifluoromethyl)phenyl]amino]4-[[(1S,2S)-2-(dimethylamino)-1,2-diphe
nylethyl]amino]-3-cyclobutene-1,2-dione

1346683-42-8

1411983-40-81411983-41-9

1223105-89-2

1263205-97-5

N

N

CF3

HN
N
H

N

N
CF3

O

H
N

H
N

O

O

O

49214-81

100 mg135406-100MG

39,4003-[[3,5-Bis(trifluoromethyl)phenyl]amino]4-[[(9R)-6'-methoxycinchonan-9-yl]amino]-3-cyclobutene-1,2-dione

49214-83

135412-100MG

N

H
N

H

49214-39

49214-84

N

H
N

H

3-[[3,5-Bis(trifluoromethyl)phenyl]amino]4-[[(9R)-10,11-dihydro-6'-methoxycincho
nan-9-yl]amino]-3-cyclobutene-1,2-dione

CF3

N

O

H
N

H

O

49214-38

121612-100MG

45,60049214-62

N

47,500100 mg

-

Ph
N

N
H

N
H

49215-54

134948-100MG

CF3

NH2

100 mg34,800

N
H

N
H

CF3

CF3
HCl

49216-74

200217-100MG

100 mg32,900

NH2

O

O

N
H

N
H

49216-73

34,100

CF3

H
N

Ph

O

N

O

CF3

O
Ph

O

N
H

N
H

CF3

49214-63

47,500100 mg135365-100MG

100 mg34,80049215-53

134947-100MG

CF3

CF3
HCl

100 mg200212-100MG

100 mgN

O49215-69

135401-100MG

CF31454257-32-9

H

O

O

1352957-59-5

O

3-[(1S,2S)-2-Aminocyclohexylamino]-4[3,5-bis(trifluoromethyl)phenylamino]
cyclobut-3-ene-1,2-dione Hydrochloride

O

O

CF3

3-[[3,5-Bis(trifluoromethyl)phenyl]amino]-4-[[(1R,2R)-1,2-diphenyl-2-(1-piperidinyl)
ethyl]amino]-3-cyclobutene-1,2-dioneHN

3-[(1R,2R)-2-Aminocyclohexylamino]-4[3,5-bis(trifluoromethyl)phenylamino]
cyclobut-3-ene-1,2-dione Hydrochloride

O
Ph

H
N

3-[[3,5-Bis(trifluoromethyl)phenyl]amino]4-[[(8α,9S)-10,11-dihydro-6'-methoxycin
chonan-9-yl]amino]-3-cyclobutene-1,2-dioneO135364-100MG

35,300100 mgN

100 mg

H
N

CF3

CF3

3-[[3,5-Bis(trifluoromethyl)phenyl]amino]-4-[[(1S,2S)-1,2-diphenyl-2-(1-piperidinyl)
ethyl]amino]-3-cyclobutene-1,2-dione

CF349214-78

O

O

O

135400-100MG

CF3

HN

N

45,60041,000100 mg135413-100MG

O

N
CF3

CF3

CF3

O

100 mgO

1407166-63-5

N121621-100MG

O

H
N

CF3

CF3

HN

O

H
N

1256245-84-7

CF3

O

41,000100 mg

CF3

O

CF3

3-[[3,5-Bis(trifluoromethyl)phenyl]amino]4-[[(8α,9S)-6'-methoxycinchonan-9-yl]amino]-3-cyclobutene-1,2-dione

1256245-79-0

HN

CF3

H
N

H
N

39,100Thiourea-Based Catalysts(R)-1-[3,5-Bis(trifluoromethyl)phenyl]-3-[1-(dimethylamino)-3-methylbutan-2-yl]thio
urea

N-[3,5-Bis(trifluoromethyl)phenyl]-N'-[(1S,2R)-2,3-dihydro-2-hydroxy-1H-inden-1-yl]thiourea

N-[3,5-Bis(trifluoromethyl)phenyl]-N'-[(1R,2S)-2,3-dihydro-2-hydroxy-1H-indene-1yl]thiourea

1-[3,5-Bis(trifluoromethyl)phenyl]-3-[(1R,
2R)-2-(dimethylamino)cyclohexyl]thiourea1-[3,5-Bis(trifluoromethyl)phenyl]-3-[(1S,2S)-2-(dimethylamino)cyclohexyl]
thiourea

1048692-61-0

949480-57-3

871828-95-4

620960-26-1

851477-20-8

CF3

OH

S
N

N
H

49214-18

111401-100MG

N
H

100 mgNH

CF340,10049214-17111384-100MG

CF3

OH

S
N
H

CF3

100 mg34,600N
H49215-22111385-100MG

＊

CF3

CF3

CF3

S

S
N
H

CF3

100 mg33,400NN
H49214-16

111325-100MG

S
N
H

100 mgCF3

N34,600N
H49215-21111326-001G

N
H

CF3

1g

34,600

P16,P17の化合物名の横に「＊」が記載のある14製品は、日本・米国・欧州・中国・インドにおいて、株式会社ダイセルが住友化学株式会社から 特許4384635号 (PCT/JP2004/009350)のライセンスを受け販売しております。
ライセンス料は製品価格に含まれており、試験研究用途の範囲内でご使用いただけます。
試験研究用途以外でご使用になる場合には事前にご相談ください。

17

Thiourea-Based Catalysts
N-[(1R,2R)-2-Aminocyclohexyl]-N'-[3,5-bis(trifluoromethyl)phenyl]thiourea

1-[3,5-Bis(trifluoromethyl)phenyl]-3-[(1R,
2R)-2-(pyrrolidin-1-yl)cyclohexyl]thiourea

N-[3,5-Bis(trifluoromethyl)phenyl]-N'-[(1R,2R)-2-(1-piperidinyl)cyclohexyl]thiourea

N-[3,5-Bis(trifluoromethyl)phenyl]-N'-[(1S,2S)-2-(1-piperidinyl)cyclohexyl]thiourea

N-[3,5-Bis(trifluoromethyl)phenyl]-N'-[(1R,2R)-2-(1,3-dihydro-2H-isoindol-2-yl)cycl
ohexyl]thiourea

860994-58-7

1314743-49-1

1289514-24-4

1244061-69-5

620960-27-2

＊

CF3

CF3
S
CF3

N
H

49214-27

33,600100 mg120925-100MG

CF3

N
H

CF3

100 mg36,700N
H

N49214-95

135707-100MG

＊

N
H

N

49214-68

CF3
S

S
N
H

135389-100MG

＊

CF3

S

S

N
H

NH2

＊

CF3

38,400100 mg

N
H

N

N
H

49214-67

CF3

38,400100 mg135388-100MG

N
H

N

CF3

N
H

49214-69

36,700100 mg135390-100MG

N-[3,5-Bis(trifluoromethyl)phenyl]-N'-[(1S,2S)-2-(1,3-dihydro-2H-isoindol-2-yl)cyclo
hexyl]thiourea

N-[3,5-Bis(trifluoromethyl)phenyl]-N'-[(1R,2R)-2-(dipentylamino)cyclohexyl]thioureaN-[3,5-Bis(trifluoromethyl)phenyl]-N'-[(1S,2S)-2-(dipentylamino)cyclohexyl]thioureaN-[(1R,2R)-2-[Bis(phenylmethyl)amino]c
yclohexyl]-N'-[3,5-bis(trifluoromethyl)phenyl]thiourea

N-[(1S,2S)-2-[Bis(phenylmethyl)amino]cy
clohexyl]-N'-[3,5-bis(trifluoromethyl)phenyl]thiourea--

1429516-79-9

1240466-16-3

1233369-39-5

＊

＊

CF3

CF3

N
H

49214-70

CF3N
H36,700100 mg135391-100MG

NN
H

49214-74

CF3

N
H

N
H

N

38,60049214-73

135394-100MG

＊

CF3

CF3

S

S

100 mg135395-100MG

＊

CF3

S

S
N

＊

CF3

N
H

49214-71

CF3

N
H

N
H

N

38,600100 mgS

100 mg135392-100MG

36,20049214-72

CF3

N
H

N
H

N

36,200100 mg135393-100MG

N,N'-(1R,2R)-1,2-Cyclohexanediylbis[N'-[3,5-bis(trifluoromethyl)phenyl]thiourea](2R)-2-[[[[3,5-Bis(trifluoromethyl)phenyl]amino]thioxomethyl]amino]-3,3-dimethyl-N-(phenylmethyl)butanamide(2S)-2-[[[[3,5-Bis(trifluoromethyl)phenyl]amino]thioxomethyl]amino]-3,3-dimethyl-N-(phenylmethyl)butanamide

N,N'-[(1R,2R)-1,2-Diphenyl-1,2-ethanediyl]bis[N'-[3,5-bis(trifluoromethyl)phenyl]thiourea]N,N'-[(1S,2S)-1,2-Diphenyl-1,2-ethanediyl]bis[N'-[3,5-bis(trifluoromethyl)phenyl]thi
ourea]

743458-79-9-

1490388-03-8

1012051-90-91416334-72-9

CF3
F3C

S
N
H

N
H

CF3

S

N
H

H
N

N
H

F3C

49214-25

34,600100 mg

N
H

O

CF3

120263-100MG

CF3

S49214-90

36,700100 mg135566-100MG

H
N

CF3

N
H

S
N
H

O

49214-89135565-100MG

F3C

S

CF3

N
H

N
H

N
H

N
H

CF3

S

36,700CF349214-85

100 mg135561-100MG

S

N
H

N
H

F3C

100 mg

F3C

N
H

34,100

CF3

S

N
H

N
H

F3C

CF3

49214-86

34,100100 mg135562-100MG

N,N'-(S)-[1,1'-Binaphthalene]-2,2'-diylbis[N'-[3,5-bis(trifluoromethyl)phenyl]thiourea]1-[(1R,2R)-2-(Dimethylamino)cyclohexyl]-3-(perfluorophenyl)thiourea

1-[(1S,2S)-2-(Dimethylamino)cyclohexyl]-3-(perfluorophenyl)thiourea(2R)-2-[[[[(1S,2S)-2-Aminocyclohexyl]amino]thioxomethyl]amino]-N,3,3-trimethyl-N-(phenylmethyl)butanamide(2S)-2-[[[[(1R,2R)-2-Aminocyclohexyl]am
ino]thioxomethyl]amino]-N,3,3-trimethylN-(phenylmethyl)butanamide

914497-25-9

-

-

-

479423-21-7

＊

F3C

F

CF3

S

S

NH

NH
NH

N
H

NH

S

＊

N

CF3

F

F

F

N
H

F
F

S
N

N
H

F

F

N
H

F

S
NH2

F

S

N
H

N

N
H

O

NH2

N
H

N

N
H

O

F3C

49214-66

100 mg135387-100MG

27,40049214-64

29,500100 mg135379-100MG

49214-65135380-100MG

29,500100 mg49214-77

135399-100MG

100 mg43,00049214-76135398-100MG

43,000100 mg(2S)-2-[[[[(1R,2R)-2-Aminocyclohexyl]am
ino]thioxomethyl]amino]-N-(diphenylmethyl)-N,3,3-trimethylbutanamide(2S)-2-[[[[(1S,2S)-2-Aminocyclohexyl]amino]thioxomethyl]amino]-N-(diphenylmethyl)-N,3,3-trimethylbutanamide

N-[3,5-Bis(trifluoromethyl)phenyl]-N'-[(1R,2R)-2-(dimethylamino)cyclohexyl]urea

N-[3,5-Bis(trifluoromethyl)phenyl]-N'-[(1S,2S)-2-(dimethylamino)cyclohexyl]urea(S)-1-[3,5-Bis(trifluoromethyl)phenyl]-3-[1-(dimethylamino)-3-methylbutan-2-yl]
thiourea

1421052-39-2

1421697-46-2

820242-14-6

1221442-12-1

1048692-50-7

S
NH2

N
H

＊

CF3

S
N

N
H

O

NH2

N
H

49214-91

100 mg41,00049214-92

135576-100MG

CF3

O

N

N
H

O

N

135575-100MG＊

41,000100 mgN
H49215-00

135822-100MG

CF3

O
N
H

CF3

33,600100 mgN

N
H49215-01

135823-100MG

i-Pr SN
H

CF3

100 mg33,600NN
H49215-25

111402-100MG

N
H

CF3

100 mg38,400N-[3,5-Bis(trifluoromethyl)phenyl]-N'-[(1R,2R)-2-[(11bR)-3,5-dihydro-4H-dinaphtho[2,1-c:1',2'-e]azepin-4-yl]-1,2-diphenylethyl]thiourea

N-[3,5-Bis(trifluoromethyl)phenyl]-N'-[(1S,2S)-2-[(11bR)-3,5-dihydro-4H-dinaphtho[2,1-c:1',2'-e]azepin-4-yl]-1,2-diphenylethyl]thiourea

N-[3,5-Bis(trifluoromethyl)phenyl]-N'-[(1R,2R)-2-[(11bS)-3,5-dihydro-4H-dinaphtho[2,1-c:1',2'-e]azepin-4-yl]-1,2-diphenylethyl]thiourea

N-[3,5-Bis(trifluoromethyl)phenyl]-N'-[(1S,2S)-2-[(11bS)-3,5-dihydro-4H-dinaphtho[2,1-c:1',2'-e]azepin-4-yl]-1,2-diphenylethyl]thiourea

N-[3,5-Bis(trifluoromethyl)phenyl]-N'-[(1R,2R)-2-[(11bR)-3,5-dihydro-4H-dinaphtho[2,1-c:1',2'-e]azepin-4-yl]cyclohexyl]
thiourea-

1069114-12-0--

1040235-96-8

N

N

N
HN
HN

HN

S

HN

49215-24

111398-100MG

100 mg

HN49215-23

111397-100MG

100 mgHN

49,20049215-33

120308-100MG

100 mg

HN

S

CF3

HN

S

CF3

CF3

F3C

F3C

49,200

HN

S

CF3

CF3
F3C

N

N

HN

S

F3C

F3C

49,20049215-32

120297-100MG

100 mg49,20049215-30

111616-100MG

100 mg49,20018

Thiourea-Based Catalysts
N-[3,5-Bis(trifluoromethyl)phenyl]-N'-[(1S,2S)-2-[(11bR)-3,5-dihydro-4H-dinaphtho[2,1-c:1',2'-e]azepin-4-yl]cyclohexyl]
thioureaN-[3,5-Bis(trifluoromethyl)phenyl]-N'-[(1R,2R)-2-[(11bS)-3,5-dihydro-4H-dinaphtho[2,1-c:1',2'-e]azepin-4-yl]cyclohexyl]
thioureaN-[3,5-Bis(trifluoromethyl)phenyl]-N'-[(1S,2S)-2-[(11bS)-3,5-dihydro-4H-dinaphtho[2,1-c:1',2'-e]azepin-4-yl]cyclohexyl]
thioureaN-[3,5-Bis(trifluoromethyl)phenyl]-N'-[(1R,2R)-2-[(11bR)-3,5-dihydro-4H-dinaphtho[2,1-c:1',2'-e]azepin-4-yl]cyclohexyl]urea

N-[3,5-Bis(trifluoromethyl)phenyl]-N'-[(1S,2S)-2-[(11bR)-3,5-dihydro-4H-dinaphtho[2,1-c:1',2'-e]azepin-4-yl]cyclohexyl]urea

1040245-49-5--

1069115-56-5

1069114-13-1

N

N

N

N

HN
HN

N

HN

S

HN

S

HN

HN

CF3

49215-20

49,20049215-31

48,50049215-28

F3C

F3C

49,200100 mg111615-100MG

CF3

CF3

F3C

100 mg111617-100MG

O

HN

CF3

F3C

100 mg

HN

O

HN

CF3

F3C

111310-100MG

HN

S

49215-56

48,500100 mg

134986-100MG

49215-55

48,500100 mg

134985-100MG

N-[3,5-Bis(trifluoromethyl)phenyl]-N'-[(1R,2R)-2-(dimethylamino)-1,2-diphenylethyl]
thioureaN-[3,5-Bis(trifluoromethyl)phenyl]-N'-[(1S,2S)-2-(dimethylamino)-1,2-diphenylethyl]
thioureaN-[(1R,2R)-2-Amino-1,2-diphenylethyl]-N'-[(S)-1-(1-naphthalenyl)ethyl]thiourea

N-[(1S,2S)-2-Amino-1,2-diphenylethyl]-N'-[(R)-1-(1-naphthalenyl)ethyl]thiourea

1-[(1R,2R)-2-(Dimethylamino)-1,2-diphe
nylethyl]-3-[(S)-1-(naphthalen-1-yl)ethyl]
thiourea

834917-24-7

1233369-41-9-313695-70-4

-

Me2N

CF3

S

HN

HN

Me2N

CF3

S

HN

N
H

HN

CF3

49215-34

120333-100MG

32,900100 mg

CH3 S

CH3 S

N
H

NH2

CF3

49215-35

32,900100 mg120344-100MG

49215-37

33,400100 mg120919-100MG

N
H

49215-36

Me2N

N
H

HN

Me

NH2

33,400100 mg120907-100MG

S

HN

49215-80

43,200100 mg135710-100MG

1-[(1S,2S)-2-(Dimethylamino)-1,2-diphe
nylethyl]-3-[(R)-1-(naphthalen-1-yl)ethyl]
thioureaN-[(1R,2R)-2-(Dimethylamino)-1,2-diphe
nylethyl]-N'-[[(1R,4aS,10aR)-1,2,3,4,4a,9,10,10a-octahydro-1,4a-dimethyl-7-isopr
opyl-1-phenanthrenyl]methyl]thiourea

N-[(1S,2S)-2-(Dimethylamino)-1,2-diphe
nylethyl]-N'-[[(1R,4aS,10aR)-1,2,3,4,4a,9,10,10a-octahydro-1,4a-dimethyl-7-isopr
opyl-1-phenanthrenyl]methyl]thiourea

N-[(1R,2R)-2-[[[[(1R,2R)-2-(Dimethylamino)cyclohexyl]amino]thioxomethyl]amino]-1,2-diphenylethyl]-3,5-bis(trifluoromethyl)benzenesulfonamideN-[(1S,2S)-2-[[[[(1R,2R)-2-(Dimethylamino)cyclohexyl]amino]thioxomethyl]amino]-1,2-diphenylethyl]-3,5-bis(trifluoromethyl)benzenesulfonamide

-

-

-

1020665-73-9

1448608-06-7

i-Pr

Me2N

S

HN

49215-81

135711-100MG

HN

S

Me

S

HN

HN

H

43,200

HN

HN

N
H

N

H

Ph

S

Ph

N
H

HN

N

N

100 mgSi-Pr49215-82

45,400100 mg135727-100MG

49215-83

45,400100 mg135728-100MG

49215-96

135906-100MG

N

SO2

F3C

CF3

100 mg47,300

N
H

Ph
Ph

N
H

49215-97

135907-100MG

HN

SO2

F3C

CF3

100 mg47,300N-[(1R,2R)-2-[[[[(1S,2S)-2-(Dimethylamino)cyclohexyl]amino]thioxomethyl]amino]-1,2-diphenylethyl]-3,5-bis(trifluoromethyl)benzenesulfonamideN-[(1S,2S)-2-[[[[(1S,2S)-2-(Dimethylamino)cyclohexyl]amino]thioxomethyl]amino]-1,2-diphenylethyl]-3,5-bis(trifluoromethyl)benzenesulfonamideN-[(1R,2R)-2-(Dimethylamino)cyclohexyl]-N'-[(1R,2S)-2-hydroxy-1,2-diphenylethyl]
thioureaN-[(1S,2S)-2-(Dimethylamino)cyclohexyl]-N'-[(1R,2S)-2-hydroxy-1,2-diphenylethyl]
thioureaN-[(1R,2R)-2-Amino-1,2-diphenylethyl]-N'-[3,5-bis(trifluoromethyl)phenyl]thiourea
Hydrocholoride

1448608-07-8

1449480-55-0

1046493-36-0

-

-

S

S

S
N

N
H

Ph

S

Ph

N
H

HN

N
H

N

SO2

Ph
Ph

N
H

HN

SO2

N
H

N

49216-01

135909-100MG

F3C

CF3

100 mg47,30049216-00

135908-100MG

F3C

CF3

100 mg47,300Ph49216-03

Ph

N
H

OH

45,400100 mg135911-100MG

N
H

N

49216-02

S

Ph

N
H

OH

100 mg135910-100MG

CF3

Ph
N
H

NH2

45,400

N
H

CF3
HCl

49216-63

200043-100MG

100 mg29,500N-[(1S,2S)-2-Amino-1,2-diphenylethyl]-N'-[3,5-bis(trifluoromethyl)phenyl]thiourea
HydrocholorideN-[(1R,2R)-2-(Dimethylamino)-1,2-diphe
nylethyl]-N'-(2,3,4,6-tetra-O-acetyl-β-Dglucopyranosyl)thiourea

N-[(1S,2S)-2-(Dimethylamino)-1,2-diphe
nylethyl]-N'-(2,3,4,6-tetra-O-acetyl-β-Dglucopyranosyl)thiourea

N-[3,5-Bis(trifluoromethyl)phenyl]-N'-[(9R)-6'-methoxycinchonan-9-yl]urea

N-[3,5-Bis(trifluoromethyl)phenyl]-N'-[(8α,9S)-6'-methoxycinchonan-9-yl]urea-

1440198-44-6

1414889-04-5

1326239-56-8

957770-66-0

OAc

CF3
S
NH2

49216-64

200044-100MG

N
H

N
H

CF3

O

AcO
AcO

OAc

49215-78

135684-100MG

100 mg35,800(2R)-2-Amino-3,3-dimethyl-N-2-pyridinyl
butanamide(2S)-2-Amino-3,3-dimethyl-N-2-pyridinyl
butanamide

1568087-94-4

171764-07-1

O
t-Bu
NH2

49215-91

135891-100MG

19

O

N
H

100 mg

t-Bu

N

NH2

25,40049215-90135890-100MG

N
H

O

N

100 mg25,400NH

Ph
Ph49215-79

135685-100MG

H

S

NH

OAc

NMe2

Ph

29,500100 mg

AcO
AcO

NH

Ph

HCl

OAc

S

NH

100 mgNMe2

35,800

MeO

H

H
N

N
H

H
N

49215-85

MeO

CF3

N

135817-100MG

CF3

O

100 mg41,000

H
N

N
H

H
N

CF3

N

49215-84

CF3

O135816-100MG

100 mg41,000CAS RN® INDEX®

®

頁

CAS RN

531-95-3

1680655-81-8

CAS RN頁

CAS RN

3®

®

頁

CAS RN

131685-53-5

7182122-13-0頁

210305-73-4

1186286-50-2

7131726-65-3

10185346-17-2

113374-31-7

986688-08-6

3

131864-67-0

1185346-09-2

113374-30-6

986695-06-99132335-44-5

16185449-80-3

616355-00-3

1086906-05-0

9134108-76-2

9188780-28-1

216944-60-8

790365-74-5

8135065-71-3

8189623-45-8

218531-95-8

1590719-32-7

7135065-76-88190848-36-3

918741-85-0

1593379-48-7

15135616-40-915190970-58-2

7

19634-89-0

393379-49-8

15135616-36-3

15196929-78-9723190-16-1

994041-16-4

15135969-65-2

7

198422-64-9923204-70-8

794041-18-6

15135969-64-1

7205927-03-3

323364-44-5995061-46-4

10136030-00-79207121-91-3

825779-13-910100516-54-9

7138517-61-0

16211560-97-3

326549-65-5

16101711-78-8

7138517-62-1

16212555-28-7

1127854-88-2

10102029-44-7

7141362-77-8

2212611-88-6

1129841-69-8

11102490-05-1

3141553-09-5

9214348-95-5

932457-23-1

11104322-63-6

8142010-87-5

3215433-51-5

333136-66-2

15104372-31-88143585-47-1

11215433-53-7

435025-24-2

15104499-08-3

7

143668-57-9

16215433-52-6

435132-20-8

11104706-47-0

8143673-66-97220486-43-1

435193-64-7

12105228-46-4

7144119-12-0

16221054-79-1

1635294-28-1

3106454-69-7

9144222-34-4

11223259-62-9

439648-67-4

12108998-83-0

10145588-94-9

7223259-63-0

440434-87-5

10110529-22-1

16150024-49-0

3225920-05-8

1040435-14-1

10111795-33-6

3151670-69-8

1265116-85-6

446755-94-6

10111822-69-6

3157488-65-8

6268556-62-3

854656-96-1

10112741-49-8

7157825-96-2

2280755-83-1

155515-98-5

3112741-50-1

7157904-67-1

2297752-25-1

1255515-99-6

3114026-76-5

15163439-82-5

8298693-03-5

263126-52-3

16118949-63-6

1167261-43-0

8309269-73-6

365283-60-5

3118949-61-4

1167316-27-0

11309934-86-9

465355-14-8

3121758-19-8

11167316-28-1

11309934-87-0

465355-00-2

3121788-77-0

11169447-70-5

8313695-70-4

1965355-08-0

3121788-73-6

11169689-05-8

16322407-34-1

966605-57-0

9122536-77-0

8170033-47-3

8329735-68-4

375640-87-8

3122536-76-98170709-41-8

11336185-31-0

375684-93-4

3122536-94-1

8171764-07-1

19336800-79-4

475714-59-9

3123287-35-4

15174291-96-4

11343338-28-3

775714-60-2

3126456-43-7

9174291-97-5

11357209-32-6

176189-55-4

15126577-48-810174500-20-0

1361342-55-4

1376189-56-5

15127049-50-7

10175166-51-5

2365215-38-9

178603-95-9

9127852-28-2

10176706-98-2

2435327-17-6

379868-78-3

9128249-70-7

1179866-74-1

3444575-98-8

279868-79-4

9129704-13-8

9182122-12-92479423-21-7

18

20

CAS RN® INDEXCAS RN

®

529486-25-7

頁

CAS RN

8®

®

頁

CAS RN929097-93-8

121233369-41-9®

頁

CAS RN191372719-98-6

頁
5529486-23-5

8929294-27-9

131234474-58-8

161372719-93-1

5620960-26-1

17930784-56-8

41240466-16-3

181372719-95-3

6620960-27-2

18934201-93-1

131242066-20-1

131372719-94-2

6695162-86-8

12945852-48-2

121244061-69-5

181374030-19-9

12695162-87-9

12947383-62-2

81246401-49-921374030-20-2

13695162-88-0

12949480-57-3

171256245-84-7

171393527-23-5

5695162-89-1

13957770-66-0

191256245-79-0

171407166-63-5

17743458-79-9

18957790-94-2

131258276-31-1

51411983-40-8

17765278-73-7

3957790-93-1

131258276-28-6

61411983-41-917791616-62-1

121000414-38-9

161258327-01-3

41412439-82-7

5791616-55-2

121003886-05-2

21258327-03-5

41412439-84-9

6791616-63-2

121011465-24-9

131258327-00-2

51414889-04-5

19791616-56-3

121011465-29-4

141258327-02-4

51416334-72-9

18791616-59-6

121011465-27-2

141258327-08-0

51416819-91-4

1791616-65-4

121011465-23-8

141258327-04-6

51421052-39-2

18791616-70-1

141012051-90-9

181258327-07-951421697-46-2

18791616-68-7

141020665-73-9

191258327-06-851428537-19-2

1820242-14-6

181022915-09-8

131258327-05-7

51429516-79-9

18834917-24-7

191028416-47-8

131263205-97-5

171440198-44-6

19851477-20-8

171040235-96-8

181263205-96-4

171447217-75-5

13851615-07-1

41040245-49-5

191264573-23-0

121448608-06-7

19852212-89-6

111041186-22-4

41284293-45-3

131448608-07-8

19860994-58-7

181046493-36-0

191286189-16-9

41449480-55-0

19861909-53-7

121048692-61-0

171286189-15-851454257-32-917861909-30-0

121048692-50-7

181289514-24-4

181490388-03-818861909-35-5

141065214-95-0

131292849-40-1

5

1496637-05-812863659-89-6

41069114-12-0

181297613-71-8

51496637-09-2

14863659-88-5

41069114-13-1

191297613-73-0

51522367-79-8

3864943-23-7

121069115-56-5

191297613-72-951568043-19-5

8871828-95-4

171157989-25-7

131297613-76-3

51568087-94-4

19874948-63-7

121170736-59-0

121297613-75-2

51569807-27-7

14874948-59-1

121191451-24-7

131297613-74-1

51569807-15-3

14874948-60-4

121193697-61-8121297613-77-4

51585988-92-6

5878111-17-2

121197214-47-3

31312991-08-4

171621066-74-7

5878111-18-3

121211565-07-9

171314743-49-1

181639791-77-7

2878111-16-1

131211565-10-4

171326239-56-8

191701405-00-6

1878111-20-7

131211565-08-0

171345628-08-1

51800345-36-1

10910629-24-2

101217463-35-8

71346683-42-8

171801196-27-9

6914497-25-9181217901-32-0

131352810-35-5

41882075-20-8

13915038-16-3

131221442-12-1

181352810-37-7

62005443-99-0

2922711-75-9131223105-89-2

171352810-38-8

62005443-90-1

2922711-71-5

131225195-02-7

141352957-59-5

172085239-89-82929097-92-7

121233369-39-5

181372719-96-4

4

21

memo

22

OEC-05 (202407)