Safety Data Sheet
1. Products and company identification
Product name:

MATTE COVER SPRAY

Recommended use:

Repair of galvanized surface.

Supplier:

Roval Corporation
6-41-1, Ikuno, Katano
Osaka, 5760054, Japan+81-72-892-7791

Emergency phone number:+81-72-892-9955

Date Revised

March 5, 2018

2. Hazards identification
PHYSICAL HAZARDS: Flammable Aerosols

Category 2

HEALTH HAZARDS:
Acute Toxicity

Oral:

Not Classified

Dermal:Not Classified

Inhalation (Gas):

Not Classified

Inhalation (Vapors):

Category 4

Inhalation (Dust/mist):

Not Classified

Skin Corrosion/Irritation:

Category 2

Eye Effects/Serious eye damage/Eye irritation:

Category 2

Skin sensitizer:

Not Classified

Germ Cell Mutagenicity:

Not Classified

Carcinogenicity:

Category 2

Reproductive Toxicity:

Category 1

TOST: Single Exposure:

Category 1 Cause damage to organs(central nerve system, respiratory organs, liver, kidney)
Category 2: (---)
Category 3: May cause drowsiness or dizziness.

Repeated Exposure:

Category 1: Cause damage to organs through prolonged orrepeated exposure (nerve system, respiratory system)
Category 2: (---)

Acute Aquatic Toxicity:

Category 1

Chronic Aquatic Toxicity:

Category 2

Hazard to ozone layer:

Classification not possible

C-38-056-SDS(E)-MATT-SU

Page 1 of 8

11.04.07

Hazard Symbols:

Signal Word:

DANGER

Hazard Statement:-Combustible or flammable aerosol-Harmful if inhaled-Pressurized container: may burst if heated-Causes skin irritation- Suspected of causing cancer-Causes serious eye irritation-Suspected of damaging fertility or the unborn child-Cause damage to organs-Causes damage to organs through prolonged or repeated exposure-Very toxic to aquatic life

- Toxic to aquatic life with long lasting effects

Precautionary Statements:[PREVENTION]-Obtain special instruction before use-Do not handle until all safety precautions have been read and understood-Keep away from heat/sparks/open flames/hot surfaces – No smoking.
-Do not spray on an open flame or other ignition source.
-Do not breathe dust/fume/gas/mist/vapor/spray.
-Wash hands thoroughly after handling.
-Do not eat, drink or smoke when using this product.
-Use only outdoors or in a well-ventilated area.
-Avoid release to the environment.
-Wear protective gloves/protective clothing/eye protection/face protection.
[FIRST AID]-IF ON SKIN: Wash contaminated area with a lot of water.
-IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
-IF IN EYES: Rinse continuously with water for several minutes. Remove contact lenses if present
and easy to do. Continue rinsing.
-IF EXPOSED (or possible): Get medical attention.
-If skin irritation occurred: Get medical attention.
-If eye irritation persists: Get medical advice/attention.
-Take off contaminated clothes. Wash before reusing them.
-Recover the leakage.
[STORAGE]-Store in a well ventilated place, keeping container closed.
-Store locked up. -Protect from sunshine.

-Do not expose to temperatures exceeding 40°C.

[DISPOSAL]-Follow the regulations of your country when disposing of the container.
C-38-056-SDS(E)-MATT-SU

Page 2 of 8

11.04.07

3. Composition/information on ingredients
Substance/Mixture: Mixture
General product description: Paint (420ml = 347.8g)
Chemical Identity

CAS Number% Weigh

Carbon black

1333-86-4<5

Xylene1330-20-712Ethyl benzene

100-41-4

11

Mineral spirit

8052-41-3

1~5

Dimethyl ether

115-10-655 ~ 60

Zinc

7440-66-6

10 ~ 15

4. First-aid measures
Inhalation:

Remove to fresh air at comfortable posture. Seek medical attention if symptoms
persist.

Skin contact: Remove all contaminated clothing and wipe off accretion. Wash the affected area withplenty of water with mild soap. If apparent condition changes or irritation is continued,
refer to medical attention.
Eye contact:

Gently rinse the affected eyes with clean water for at least 15 minutes lifting upperand lower eyelids occasionally. Remove contact lenses if present and easy to do. Get
immediate medical attention.

Ingestion:

Keep rest and get medical attention immediately. Do not induce vomiting without
medical instruction.

For caretaker: Wear proper protective equipment. Keep ventilating.

5. Firefighting measures
Extinguishing Media:

Carbon dioxide, form, dry sand
Water must NOT be used for extinction.

Special protective equipment and precaution for fire fighters: Wear proper protective equipment.
Remove sources of ignition if possible. Use specified extinguishing media. Cool closed containers which
may be exposed to heat. Extinguish from windward side. Keep distant during fire fighting as aheated container may burst.

6. Accidental release measures
Personal precautions:
Use the necessary personal protective equipment (glove, mask, apron, goggle) when handling.
Ventilate well if inside. Operate release measure action from windward wide if outside. Keep away any
person who is not concerned. Prepare extinguishing media for accidental fire. Be careful not to spill
the content when shaking.
C-38-056-SDS(E)-MATT-SU

Page 3 of 8

11.04.07

Environmental precautions:
Avoid spill into waterway not to affect environment.
Equipment and method for containment and cleaning-up:
Contain the leakage into closed container and store in a safe place. Dispose of accretion or waste inaccordance with local regulation. Recover the leakage with equipment which do not spark by impact or
static discharge.

7. Handling and Storage[Handling]
Handle in a well ventilated area. Keep container closed when storage. Do not handle this product in atemperature above 40°C. Do not heat the container above 40°C. Do not keep spraying for more than 30
seconds. Prepare ventilating and personal protective equipment when handing this product in closed
area. Wash hands and face completely after the handling and do not bring contaminated equipment
into rest stations.
[Storage]
Avoid direct sunshine. Store in a well-ventilated, locked-up area. Keep out the reach of children. Keep
containers away from fire/flame. Do not store in a temperature above 40°C. Do not store at the placewith high humidity or near plumbing to avoid the container bursting by corrosion.

8. Exposure controls/ Personal protection
Control parameters:
Chemical Identity

ACGIH TLV (2016)

Carbon black

3.5mg/m3 (TWA)

Xylene100ppm (TWA)

Ethyl benzene

20ppm (TWA)

Mineral spirit

100ppm (TWA)

Dimethyl ether

N/A

Zinc

---

Equipment measure:
Use explosion-proof equipment and ventilating equipment. Earth when using transporting, scooping,or agitating equipment. High-heat or source of ignition must not be put near the handling place.
Use auto-painting equipment or local ventilating equipment to avoid direct contact of workers with the
product in closed place. Prepare the equipment which can ventilate enough at the bottom in case of theoperation inside of tanks.
Personal protection measures:
Respiratory protection:

Wear protective mask for organic gas. Use ventilating mask inclosed place.

Hand protection:

Protective gloves for solvent or chemicals.

Eye protection:

Wear protective goggles.

Skin and body protection: Wear protective clothes for chemicals to avoid direct contact.
C-38-056-SDS(E)-MATT-SU

Page 4 of 8

11.04.07

9. Physical and Chemical Properties
Physical State:

LiquidColor:

Black

Odor:

Smells like solvent.

Boiling Point:-24.8~230°C

Vapor Pressure:506.6kPa (20.8°C)

Density (g/ml):

0.83

Auto-ignition Temp:

190°C

Explosion Limits(vol%):

LEL 0.6 UEL 27

Flash Point:

Paint liquid: 24.7°C Propellant: -41.1°C

10. Stability and Reactivity
Stability:

Stable under normal condition and anticipated storage.

Conditions to avoid:Heat, open fire and sparks. Forming of mixture withatmosphere within flammable limit.

Possibility of Hazardous Reactions:

May react with acid substances.

Hazardous decomposition Products:

Generate carbon monoxide and carbon dioxide by heating.
Generate stimulant gas.

11. Toxicological information[ACUTE TOXICITY]
Material

Oral

Category

Carbon black>8.0 g / kg

Not classified

Classification not possible

Xylene

3.5 g / kg

Not classified

Classification not possible

Ethyl benzene

3.5 g / kg

Not classified

Mineral spirit>5.0g / kg

Not classified

Dimethyl ether
Zinc

Material

Dermal15.4 g / kg

Inhalation
Gas

Classification not possible

Not classified

Category

Not classified

Classification not possible

Classification not possible>2.0 g / kg

Category

Classification not possible

Inhalation
Vapor

Category

Inhalation
Dust/Mist

Category

Carbon black

Conclusive but not sufficientfor classification

Classification not possible

Classification not possible

XyleneConclusive but not sufficientfor classification

6700 ppm

Category4

Classification not possible

Ethyl benzene

Conclusive but not sufficientfor classification

4000 ppm

Category 4

Classification not possible

Mineral spirit

Conclusive but not sufficientfor classification

Classification not possible

Classification not possible

Dimethyl ether

164000 ppmVClassification
not possible

Conclusive but not sufficientfor classification

Conclusive but not sufficient forclassification

Conclusive but not sufficientfor classification

Classification not possible

ZincC-38-056-SDS(E)-MATT-SU

Page 5 of 8

>5.41 mg / L

Not classified

11.04.07

Material

Skin
Corrosion/Irritation

Eye damage/irritation

Respiratory
sensitization

Skin sensitization

Carbon black

Not classified

Not classified

Classification notpossibleClassification not possible

XyleneCategory 2

Category 2AClassification notpossibleClassification not possible

Ethyl benzene

Category 3

Category 2B

Classification notpossibleClassification not possible

Mineral spirit

Category 2

Not classified

Classification notpossible

Not classified

Dimethyl ether

Classification notpossibleClassification notpossibleClassification notpossibleClassification not possible

Zinc

Not classified

Class 2B

Classification notpossible

Not classified

Material

Germ cell mutagenicity

Carcinogenicity

Reproductive toxicity

Carbon black

Classification not possible

Category 2

Classification not possible

XyleneNot classified

Not classified

Category 1B

Ethyl benzene

Not classified

Category 2

Category 1B

Mineral spirit

Not classified

Classification not possible

Not classified

Dimethyl ether

Classification not possible

Classification not possible

Classification not possible

Zinc

Classification not possible

Classification not possible

Classification not possible

TOST (Chronic)

Aspiration hazard

Material
Carbon black

XyleneTOST (Single)
Classification not possible

Category 1 (lung)Classification not possible

Category 1（respiratory system,
liver, Central nerve system,
kidney）

Category 1（respiratory
system、nerve system）

Category 2

Classification not possible

Category 1

Category 3 (anesthetic action)
Ethyl benzene

Category 2 (central nerve
system)Category 3 (anesthetic action)

Mineral spirit

Category 3 (respiratory tract
irritation, anesthetic action)

Category 2 (liver, testis)

Category 1

Dimethyl ether

Class 3 (anesthetic action)

Classification not possible

Classification not possible

Zinc

Classification not possible

Classification not possible

Classification not possible

C-38-056-SDS(E)-MATT-SU

Page 6 of 8

11.04.07

12. Ecological Information
General Precaution: Be careful not to spill or leak product, not to affect environment when
disposal. The product or wash water must not be in touch with ground, river,or water drain.
Ecological Toxicity: Acute harmful effect on aqueous milieu.
Material

Acute Aquatic Toxicity

Chronic Aquatic Toxicity

Hazard to Ozone

Carbon black

Not classified

Classification not possible

Classification not possible

XyleneCategory 2

Category 2

Classification not possible

Ethyl benzene

Category 1

Not classified

Classification not possible

Mineral spirit

Category 1

Category 1

Classification not possible

Dimethyl ether

Not classified

Not classified

Classification not possible

Zinc

Category 1

Category 1

Classification not possible

Persistence and Degradative: No rapid degradative (BOD: 39%) Xylene
Has rapid degradative and volatilize from water; Ethyl benzene
No rapid degradative (BOD: 12-13%) Mineral spirit
No rapid degradative (Metal compound) Zinc
Bioaccumulation potential:

Xylene; may be low potential（log Kow = 3.16）
Ethyl benzene; may be low potential（log Kow = 3.15）
Mineral spirit; no data

13. Disposal considerations[Residual Wastage, Contaiminated Contairer and package]
Follow the local regulation. Waste including residue and container should be disposed by licensed
industrial waste disposer after the consignment contract. Wash water used for cleansing containersand equipment must not be released into environment. For other wastage arouse in effluent
processing or incineration, dispose of them in accordance with the law or entrust it. Disposal of thespray can must be done after making sure it is empty and no gas pressure inside.
The product, its residue, and incinerated ash are specially-controlled industrial wastes, which must be
disposed of by a licensed industrial waste disposer. Disposal of the aerosol can must be done after
emitting all the gas inside, being careful for fire or inhalation of mist.

14. Transport information[Regulation] UN No.: 1950

UN Class: 2.1 (Flammable gas)

PG: ---

General: Read sections concerning handling and storage. Confirm that there is no leakage and load
the products without rolling, falling, or damage. Avoid load collapse.
Land:

Follow local regulation, such as Fire Defense Law, Industrial Safety and Health Act, orPoisonous Material Act. Transporter must follow the precaution on the product labels.

C-38-056-SDS(E)-MATT-SU

Page 7 of 8

11.04.07

Sea:

Follow local regulations, such as Ship Safety Act or Act for the Prevention of Marine Pollution
and Maritime Disasters.

Air:

Follow local regulations, such as Aviation Law.

Other: Keep the container under the temperature less than 40°C. Be careful not to roll, fall, or

damage.
Safety measure: Read the section regarding handling and storage. Confirm that there is no leakage
and load the products without rolling, falling, or damage. Avoid load collapse.

15. Regulatory Information
Classification and labeling in accordance with Labor Safety and Health Act:See Section 2
Other regulation for foreign countries:
Regulatory information with regards to this preparation in your country or region should be
examined by your own responsibility.
16. Other Information
References:
1) GHS Classification Guidance for Enterprises. (United Nations 2009)2) SDS from manufacturers of raw materials3) Roval’s own data
The information herein is given in good faith, but no warranty, express or implied, is made.
The information contained herein is, to the best of Roval’s knowledge and belief, accurate and reliable
as of the data issued. It is the user’s responsibility to determine the suitability of this information for
the adoption of necessary safety precautions. We reserve the right to revise SDS periodically as new
information becomes available.

C-38-056-SDS(E)-MATT-SU

Page 8 of 8

11.04.07