Safety Data Sheet[Mixture (Paint)]
１． Products and company identification
Product nameSupplier
Address
Section in charge
Phone number
Fax number
e-mail address
Emergency Phone Number
Preparation, revision, and confirmation
Product type
Recommended use

ALMZ SPRAY
Roval Corporation
6-41-1, Ikuno, Katano, Osaka
Technical service department
072-892-7791
072-892-6391
jp-info@roval-group.com
072-892-9955
Nov. 1, 2019
One-component organic zincrich paint (high-concentration zinc dust paint)
Anti-corrosion of steel/iron

２． HAZARDS IDENTIFICATION[GHS Classification]
PHYSICAL

Flammable aerosol

Category 2

HAZARDSHEALTH HAZARDS
Acute toxicity

TOST

Oral

DermalInhalation (Gas)

Inhalation (Vapors)

Inhalation (Dust/Mist)

Not classified

Not classified

Not classified

Category 4

Not classified
Skin sensitisation

Skin Corrosion/

Serious eye

Respiratory sensitisation

Respiratory sensitisation

Irritation

damage/ irritation(Solid/Liquid)(Gas)

Category 2

Category 2

Not classified

Not classified

Germ Cell Mutagenicity

Carcinogenicity

Reproductive toxicity

Effects on or via lactation

Not classified

Not classified

Classification not possible

Classification not possible

Category 1(Single exposure)

Category 2―――

Not classified

Category 3
Systemic toxicity

May cause respiratory irritation
May cause drowsiness or dizziness

TOST

Category 1(Repeated exposure)
Aspiration hazard
Not classified

Category 2

―――

―――
Hazardous to the aquatic environment

Hazardous to the aquatic environment(Acute)(Chronic)

Category 1

Category 1

Hazardous to the ozone layer
Classification not possible[GHS Symbols]
Pictogram

Signal word

WARNING

Hazard statement:
・Aerosols that are highly Combustible or flammable.
・Pressurized container: may burst if heated ・Harmful if inhaled・Intense eye irritation ・May cause damage to organs ・Very strong toxicity to aquatic organisms
・Very strong toxicity to aquatic organisms due to long-term continuous effects
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Precautionary Statement:[SAFETY MEASURES]
・Keeping away from ignition sources, such as heat/sparks/open flames/ hot surfaces. No smoking.
・Do not spray on an open flame or other ignition source.
・Avoid breathing dust/fume/gas/mist/vapours/spray.
・Wash hands thoroughly after handling.
・Use only outdoors or in a well-ventilated area.
・Avoid release to the environment.
・Wear protective gloves/protective clothing/eye protection/face protection.
[FIRST AID]・IF ON SKIN : Wash with plenty of water and soap.
・IF INHALED: Remove person to fresh air and Keep comfortable for breathing.
・IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses if present and easy to do. Continue rinsing.
・Consult a physician if you feel ill.
・If Skin irritation occurs: to be diagnosed/treated by a physician.
・If eye irritation persists: Get medical advice/attention.
・Take off contaminated clothing and Wash it before reuse.
・Collect spillage.
[STORAGE]
・Protect from sunlight. Do not expose to temperatures exceeding 40°C.
[DISPOSAL]・Appropriately dispose of the contents/containers in accordance with laws and regulations.
３． Composition/information on ingredients
Substance/Mixture: Mixture
General product description: Paint (420 ml = 476 g)
Substance name
Aluminum
Zinc
Zinc oxide
Mixed organic compounds

Dimethyl ether

Ingredient

CAS No.

1~5
30 ~ 35
1~5
20 ~ 2530 ~ 35

7429-90-5
7440-66-6
1314-13-2
Non-disclosure115-10-6

４． First-aid measures
Inhaled:If you feel ill after breathing in steam or gas, remove to fresh air and rest in a respirable position. Seek medical attention if
symptoms persist or if unconscious.
Skin contact:
Remove all contaminated clothing. Wash the affected area with plenty of water with mild soap. Do not use solvents or thinners. If
irritation is continued, refer to medical attention.
Eye contact:
Gently rinse the affected eyes with clean water for at least 15 minutes lifting upper and lower eyelids occasionally. Remove contactlenses, if present and easy to do. Remove contact lenses if present and easy to do. Do not induce vomiting.
Swallowed:
Get immediate medical advice/attention.
Do not induce vomiting. Do not induce vomiting.
Emergency measures:
Wear proper protective equipment. Keep ventilation.

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５． Fire-fighting measures
Extinguishing media:
Carbon dioxide, foam and powder
Fire extinguishing agents not to be used:
Water (rod-shaped water, high-pressure water)/rod-shaped reinforcing liquid
Special methods for extinguishing fires, protection of persons who extinguish fires:
Wear proper protective equipment.
Remove sources of ignition.
Use specified extinguishing media.
Cool closed containers which may be exposed to heat.
Extinguish from windward side.
Keep distant during fire fighting, heated container may burst.
６． Accidental release measures
Precautions for the Human Body, Protective Equipment, and Emergency Measures:
Use the necessary personal protective equipment when handling. Ventilating firmly indoors. In outdoor cases, working from thewindward. Prevent secondary disasters by prohibiting access to the surrounding area and keeping other people away. Avoid
sparks, flames and anything which can cause fire.
Prepare extinguishing media for accidental fire. Be careful not to spill the content when shaking.
Environmental precautions:
Be careful not to cause environmental effects due to discharge into rivers, etc.
Containment and Purification Methods and Equipment:
For small spill, absorb spills with inert materials, then place in a chemical waste containers. Disposal of deposits, waste, etc. shallbe made in accordance with relevant laws and regulations. Collect by using a tool made of a material that does not generate
sparks due to impact or static electricity.
Absorb in dry sand, soil, or other non-combustible materials for recovery. A large amount of leakage is prevented by surrounding
with embankment.
７． Handling and storage
Handling:
Handle in a well-ventilated place. The container is sealed each time. Keep away any source of flame, sparks, and heat.
Wear antistatic cloths and shoes. Use sparkless equipment.
For countermeasures against static electricity, the equipment, etc. shall be grounded, and explosion-proof type shall be used forthe electrical equipment, etc.
Soak used wiping cloths, paint film, and spray dust in water until disposal.
Do not handle this product in a temperature above 40°C. Do not warm to 40℃ or more. Do not keep spraying for more than 30
seconds.
Handle in a well-ventilated area. Wear personal protective cloths.
Wash hands and face completely after the handling.
Storage:
Avoid direct sunlight. Store in a dry, well-ventilated area. Keep locked to prevent theft.
Keep out of reach of children. Keep containers away from fire/flame.
Do not store in a temperature above 40°C. If the product is stored in a humid place, the container may corrode and burst.

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８． Exposure controls/Personal protection
Substance name

Exposure limits
ACGIH (FY2016)

Aluminum
Zinc

1 mg /㎥(TWA)-

Zinc oxide

2 mg /㎥(TWA)

Mixed organic compounds
Dimethyl ether―-[Equipment Measures]
Use air extractors to prevent fume formation.
Use electrical grounding equipment to transport/pump/stir the liquid.
Equipment shall be installed in the vicinity of the handling site so as not to be subject to high temperatures or ignition sources.
In indoor painting operation, automatic painting equipment or local wake-up device should be used to avoid direct exposure of
the operator.
When working in a sealed place such as the inside of a tank, install a device that can sufficiently ventilate to the bottom of thesealed place.
[Protection]
Respiratory protective equipment:
Wear gas masks for organic gases. In cases of inadequate ventilation, a respiratory protective device should be worn to prevent
overexposure.
Hand protectors:
Wear gloves made of a material that is impermeable to organic solvents or chemicals.
Eye protection:
Wear protective glasses for handling.
Skin and body protection:
When handling, wear clothing that does not expose the skin directly. It is best to wear the clothing made of a material that can
prevent the penetration of chemical reagents.
９． Physical and Chemical Properties
Physical State:Liquid
Physical property (color)
Odor:Solvent odor
Densities (g/ml)
Vapor pressure:506.6kPa(20.8℃)
Auto-ignition temp
Flash point: (Stock solution) 23.0℃(Propellant)-41.1℃
Explosion Limits: LEL 1.0vol %UEL 27 vol %Boiling point:-24.8℃:Silver:1.13: ≥200℃

１０． Stability and Reactivity
Stability:
Stable in normal handling.
Conditions to avoid :Heating, high temperature, contact with incompatible hazardous materials.
Forming of mixture with atmosphere within flammable limit.
Incompatible materials : May react with oxidizers.
Hazardous decomposition products:
Thermal decomposition produces carbon monoxide and carbon dioxide. Generate stimulant gas

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１１． Toxicological information
ACUTE TOXICITY
Substance name
Aluminum
Zinc
Zinc oxide
Mixed organic compounds

Dimethyl ether
ACUTE TOXICITY
Substance name
Aluminum
Zinc
Zinc oxide

Oral

Classification

DermalClassification not possible> 2.0 g / kg
Not classified> 5.0 g / kg
Not classified
Category 5
Classification not possible
Inhalation(Gas)

Classification not possible
Classification not possible> 5.0 g / kg
Not classified
Not classified
Classification not possible

Inhalation(Vapors)

Classification

Classification

Classification

Classification

Dimethyl ether

Not applicableNot applicableNot applicable
Classification not possible
164,000 ppm Not classified

Substance name

Skin corrosion/irritantSerious eye
damage/eye irritant

Respiratory
sensitisation

Skin sensitisation

Aluminum
Zinc
Zinc oxide

Classification not possible

Classification not possible

Classification not possible

Classification not possible

Category 2B
Not classified
Category 2B

Classification not possible

Mixed organic compounds

Not classified
Not classified
Category 2

Classification not possible

Not classified

Not classified
Not classified
Not classified

Dimethyl ether

Classification not possible

Classification not possible

Classification not possible

Classification not possible

Mixed organic compounds

Not applicable
Classification not possible
Not applicable
Category 4
Not applicable

Inhalation(Dust/Mist)

Classification not possible> 5.41 mg / L
Not classified> 5.7 mg / L
Not classified
Classification not possible
Not applicable

Substance nameGerm Cell Mutagenicity

Carcinogenicity

Reproductive toxicity

Aluminum
Zinc
Zinc oxide
Dimethyl ether

Classification not possible
Classification not possible
Classification not possible
Not classified
Classification not possible

Classification not possible
Classification not possible
Classification not possible
Not classified
Classification not possible

Classification not possible
Classification not possible
Category 2
Not classified
Classification not possible

Substance nameTOST (Single)

TOST (Repeat)

Aspiration hazard

Aluminum
Zinc

Category 1 (Respiratorys)
Classification not possible
Category 1

Category 1 (Respiratorys)
Classification not possible

Classification not possible
Classification not possible

Classification not possible

Classification not possible

Not classified

Category 1

Classification not possible

Classification not possible

Mixed organic compounds

Zinc oxide
Mixed organic compounds

Dimethyl ether

C-351-056-SDS(E)-ALMZ-SU(respiratory, systemic toxicity)

Category 3(anaesthetic effect, respiratory tract irritation)

Category 3 (anesthetic effect)

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１２． Ecological information
General Precautions:Handle the product carefully in case of leakage, disposal, etc., as this may affect the environment.
The product may have adverse effect on environment.
Ecotoxicity
Substance name
Acute Aquatic Toxicity
Chronic Aquatic Toxicity
Hazardous to the ozone layer
Aluminum
Zinc
Zinc oxide

Classification not possible
Category 1
Category 1
Mixed organic compounds
Category 2
Dimethyl ether
Not classified
Persistence and degradability:
No rapid degradability (metal compound) <zinc>

Classification not possible
Category 1
Category 1
Not classified
Not classified

Classification not possible
Classification not possible
Classification not possible
Classification not possible
Classification not possible

１３． Disposal considerations[Residual Waste, Contamination Containers and Packaging]
In the case of disposal, the relevant laws and regulations and the standards of local governments shall be complied with. Waste
including residue and container should be disposed by licensed industrial waste disposer after the consignment contract. Wash
water used for cleansing containers and equipment must not be released into environment. For other wastage arouse in effluent
processing or incineration, dispose of them in accordance with the law or entrust it. Dispose of the empty container after the restof paint completely removed. It is recommended to recycle empty containers and packaging.
Dispose of the empty container after the rest of paint completely removed. Empty container should be disposed of by industrial
waste disposal contractor after the consignment contract.
Disposal of the spray can must be done after making sure it is empty and no gas pressure inside. Be careful of inhaling fire andmist when venting gas (until no injection noise occurs).
１４． Transport information[Regulation]
UN No.: 1950
UN Classification: 2.1
PG:-Transport:
Follow the instructions in the Handling and Storage Precautions section.
Check that there is no leaking in the container, and load. Prevent collapse of the container so that there is no falling or damage.
Land transport
Pursuant to the Fire Defense Law, the Industrial Safety and Health Law, and other transportation methods stipulated in therelevant laws. The consignor shall issue the Carriage Precautions (Yellow Card) to the Carrier.
Maritime transportation:
In accordance with the Ship Safety Law.
Air Transportation:
In accordance with the provisions of the Aeronautical Law.
Other:
Keep the container below 40°C for transportation and take care not to overturn, fall, or damage the container.
Safety measures:
Follow the instructions in the Handling and Storage Precautions section.
Check that there is no leaking in the container, and load. Prevent collapse of the container so that there is no falling or damage.
１５． Regulatory information
Classification and labeling in accordance with Labor Safety and Health Act:See Section 2
Other regulation for foreign countries:
Regulatory information with regards to this preparation in your country or region should be examined by your own
responsibility.
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１６． Other information
References:
1) GHS Classification Guidance for Enterprises. (United Nations 2009)2) SDS from manufacturers of raw materials3) Roval’s own data
The information herein is given in good faith, but no warranty, express or implied, is made.
The information contained herein is, to the best of Roval’s knowledge and belief, accurate and reliable as of the data issued. It is theuser’s responsibility to determine the suitability of this information for the adoption of necessary safety precautions. We reserve theright to revise SDS periodically as new information becomes available.

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