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6¥2 GÌêFMÒCMÒCG¼CªCZ_¢(N)D[á] 1)

K. Murakami, M. Hanada, J. Soc. Inorg. Mater., Japan (Gypsum), No. 5, 13_
16 (1952).

2)

H. Monma, J. Soc. Inorg. Mater., Japan (Gypsum & Lime), No. 229, 12_17 (1990).

3)

S. Goto, A. Nakamura, K. Ioku, J. Soc. Inorg. Mater., Japan (Muki­Materiaru), 5, 22_27(1999).

4)
5)

Y. Kojima, A. Matsui, T. Yasue, J. Soc. Inorg. Mater., Japan, 14, 39_43 (2007).
X. H. Wang, J. G. Li, H. Kamiyama, M. Kanda, N. Ohashi, Y. Moriyoshi, T. Ishigaki, J. Am.
Chem. Soc., 127, 10982_10990 (2005).

6)

Q. Bao, K. Ohnishi, Y. Tanabe, E. Yasuda, J. Ceram. Soc. Jpn., 101, 250_255 (1992).

7)ä^ñCZ~bNXC40, 852_854 (2005).

8)ä´êC»wÆHÆC61, 439_441 (2008).

9)
10)

VäSñC¢qVCÁ¡çvCÔ¼CîCZgERN[gCNo. 715, 58_63 (2006).
T. Fukuda, D. Ehrentraut, J. Cryst. Growth, 305, 304_310 (2007).

11)

À]

12)

V. P. McConnell, Fuel Cells Bull., 2008, No. 3, 12_15 (2008).

CC¬FsCräNvCú»C1988, 1556_1564.
(ªÆð¹LµÈ¢ÆõÅ«È¢GÌLÚá)13)

R. Mishima, M. Hino, H. Uzu, T. Meguro, K. Yamamoto, Appl. Phys. Express, 10, 062301(2017). doi:10.7567/APEX.10.062301(ICW[iÅ_¶ÔÌÝÅy[WªÈ¢êÌLÚáFMÒCG¼C_¶
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No. 1_8uÎpv(1950_1953 N) J. Soc. Inorg. Mater., Japan (Gypsum)Journal of the Society of Inorganic Materials, Japan

30, (2023)

245

No. 9_251uÎpÆÎDv(1953_1994 N) J. Soc. Inorg. Mater., Japan (Gypsum & Lime)No. 252_283u³@}eAv(1994_1999 N) J. Soc. Inorg. Mater., Japan (Muki­Materiaru)
No. 284_uJournal of the Society of Inorganic Materials, Japanv(2000 NÈ~) J. Soc. Inorg. Mater.,Japan
6¥3 {Ev|WÌêFMÒ¼Cg^CghCoÅÐ(N) p. ZD[á] 1)³@}eAwïÒCgZgEZbREEÎDnhubNhCZñ°oÅ(1995)
p. 235.

2)

À]

3)

F. Izumi, ``The Rietveld Method'', Ed. by R. A. Young, Oxford Univ. Press, Oxford (1993)

CCräNvCg³@}eAwïæ 94 ñwpuïuv|Wh
C(1997) p. 2.

p.13.
4)

JCPDS card 46_1212.

5)

T. Mitsuda, J. Saito, E. Hattori, ``Proc. Int. Sympo. Hydrothermal Reactions, Yokohama'',(1982) p. 823.

6)

J. Yamaguchi, ``Matrix preparation for biomolecules immobilization by photodimerization
reaction (Ph. D. Thesis)'', åw¼C¼(2007) p. 33.

6¥4 ÁÌê
1999 NæèÈO

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ÁJº 56_012457

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ÁJ½ 05_12222

3)

ÁJ 2003_123456

4)

M. Pechini, U. S. Patent No. 3330697, July 11 (1967).

(COÁÌLÚáF­¾ÒCoè{ÁÔCöJÜ½Í­øNú)
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246

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SampleC3A3ECaSO4 system

Temperature/C
ijl ijl

C11A7ECaF2 system

Hydration products detected by XRD.

5
20
30
5
20
30

Hydration products
10 min30 min

100 min

200 min360 min

\
\
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E
E

E
E
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E
E
E

E
E
E
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E, M
E, M

E
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E, M
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E, M

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E, M
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E, M, C

E: Ettringite, M: Monosulfate hydrate, C: C2AH8[}Ìá]Fig. 1

Fig. 2

Relationships between the amount of CaO and reaction time.
Reaction temp. F10
C, ¡F30
C, £F40
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X­Ray diraction pattern of the sample synthesized by
the solid state reaction.

Fig. 3

TEM micrograph of particles prepared by the chemical
reaction.

30, (2023)

Journal of the Society of Inorganic Materials, Japan

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