Safety Data Sheetaccording to Regulation (EC) No. 1907/2006 (REACH)
bbb

MB ActiveCube
Version number: 6.0
Replaces version of: 2017-02-02 (5)Revision: 2019-04-05
First version: 2011-09-14

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1

1.2

Product identifier
Trade name

MB ActiveCube

Registration number (REACH)

not relevant (mixture)

CAS number

not relevant (mixture)

Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses

1.3

Toilet rim block

Details of the supplier of the safety data sheet
URIMAT Schweiz AG
Etzelstrasse 39
CH-8634 Hombrechtikon
Switzerland

Telephone: +41 (0)55 251 52 30
Telefax: +41 (0)55 251 52 31
e-mail: info@urimat.com
Website: www.urimat.che-mail (competent person)

sdb@csb-online.dePlease do not use this e-mail adress to ask for the latest safety data sheet. For this purpose contact URIMAT Schweiz AG.

1.4

Emergency telephone number
As above or next toxicological information centre.

SECTION 2: Hazards identification

2.1

Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008 (CLP)This mixture does not meet the criteria for classification causes serious eye damage: expert judgement AISE-DetNet
Classification logging number DetNet/148, DetNet/149.
Classification
SectionHazard class

Category

Hazard class andcategory

Hazard statement

3.2

skin corrosion/irritation

2

Skin Irrit. 2

H315

3.3

serious eye damage/eye irritation

2

Eye Irrit. 2

H319

3.4S

skin sensitisation

1

Skin Sens. 1

H317

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Classification
Section

4.1C

Hazard classhazardous to the aquatic environment chronic hazard

Category

3

Hazard class andHazard state-category

ment

Aquatic Chronic 3

H412

for full text of abbreviations: see SECTION 16

The most important adverse physicochemical, human health and environmental effects
Spillage and fire water can cause pollution of watercourses.

2.2

Label elements
Labelling according to Regulation (EC) No 1272/2008 (CLP)
Signal word

warning

Pictograms
GHS07

Hazard statements
H315
H317
H319
H412

Causes skin irritation.
May cause an allergic skin reaction.
Causes serious eye irritation.
Harmful to aquatic life with long lasting effects.

Precautionary statements
P101
P102
P261
P280
P302+P352
P305+P351+P338
P333+P313
P337+P313
P501

If medical advice is needed, have product container or label at hand.
Keep out of reach of children.
Avoid breathing dust/fume/gas/mist/vapours/spray.
Wear protective gloves/protective clothing/eye protection/face protection.
IF ON SKIN: Wash with plenty of soap and water.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contactlenses, if present and easy to do. Continue rinsing.
If skin irritation or rash occurs: Get medical advice/attention.
If eye irritation persists: Get medical advice/attention.
Dispose of contents/container in accordance with local/regional/national/international regulations.

Hazardous ingredients for labelling

2.3

limonene
subtilisin
linalool

Other hazards
There is no additional information.
Results of PBT and vPvB assessment

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This mixture does not contain any substances that are assessed to be a PBT or a vPvB.

SECTION 3: Composition/information on ingredients

3.1

Substances
not relevant (mixture)

3.2

Mixtures
Description of the mixture
Hazardous ingredients
Name of substance

Identifier

Wt%

Classificationacc. to GHS

reaction
product of Benzenesulfonicacid, 4-C10-13sec-alkyl derivs.
and Benzenesulfonic acid, 4methyl- and sodium hydroxide

EC No
932-051-8

25 – 50

Skin Irrit. 2 / H315
Eye Dam. 1 / H318
Aquatic Chronic 3 /H412

2.5 – 10Skin Irrit. 2 / H315
Eye Dam. 1 / H318
Aquatic Chronic 2 /H411

amides, C1218(evennumbered) andC18(unsatd.), Nhydroxyethyl

REACH Reg.
No
01211956511248-xxxx

CAS No90622-77-8
EC No
292-481-0

Pictograms

Specific Conc.
Limits

M-Factors

REACH Reg.
No
01211948941333-xxxx
C16-18 alcohols,
ethoxylated

CAS No68439-49-6

1 – 2.5

Eye Irrit. 2 / H319

limonene

CAS No138-86-3

1 – 2.5

Flam. Liq. 3 / H226
Skin Irrit. 2 / H315
Skin Sens. 1 / H317
Aquatic Acute 1 /H400
Aquatic Chronic 1 /
H410

≤ 0.5

Skin Irrit. 2 / H315
Eye Dam. 1 / H318
Resp. Sens. 1 /H334
STOT SE 3 / H335

EC No
205-341-0
Index No
601-029-00-7
subtilisin

CAS No9014-01-1
EC No
232-752-2
Index No647-012-00-8

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Hazardous ingredients
Name of sub-IdentifierWt%

stancelinaloolClassification

Pictograms

acc. to GHS
CAS No78-70-6

≤ 0.5

EC No
201-134-4

Specific Conc.

M-Factors

LimitsSkin Irrit. 2 / H315
Eye Irrit. 2 / H319
Skin Sens. 1B /H317

Index No603-235-00-2

SECTION 4: First aid measures

4.1

Description of first aid measures
General notes
Take off immediately all contaminated clothing.
In all cases of doubt, or when symptoms persist, seek medical advice.
Following inhalation
Provide fresh air.
If breathing is irregular or stopped, immediately seek medical assistance and start first aid actions.
Following skin contact
Wash with plenty of soap and water.
If skin irritation or rash occurs: Get medical advice/attention.
Following eye contact
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
Remove contact lenses, if present and easy to do. Continue rinsing.
Following ingestion
Rinse mouth. Do not induce vomiting.
Get medical advice/attention if you feel unwell.
Notes for the doctor
none

4.2

Most important symptoms and effects, both acute and delayed
These information are not available.

4.3

Indication of any immediate medical attention and special treatment needed
none

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SECTION 5: Firefighting measures

5.1

Extinguishing media
Suitable extinguishing media
water, foam, alcohol resistant foam, fire extinguishing powder
Unsuitable extinguishing media
water jet

5.2

Special hazards arising from the substance or mixture
Hazardous decomposition products: Section 10.

5.3

Advice for firefighters
In case of fire and/or explosion do not breathe fumes.
Co-ordinate firefighting measures to the fire surroundings.
Do not allow firefighting water to enter drains or water courses.
Collect contaminated firefighting water separately.
Fight fire with normal precautions from a reasonable distance.
Special protective equipment for firefighters
use suitable breathing apparatus

SECTION 6: Accidental release measures

6.1

Personal precautions, protective equipment and emergency procedures
For non-emergency personnel
Remove persons to safety.
Ventilate affected area.
Wearing of suitable protective equipment (including personal protective equipment referred to under
Section 8 of the safety data sheet) to prevent any contamination of skin, eyes and personal clothing.
For emergency responders
Wear breathing apparatus if exposed to vapours/dust/spray/gases.

6.2

Environmental precautions
Keep away from drains, surface and ground water.
Retain contaminated washing water and dispose of it.
If substance has entered a water course or sewer, inform the responsible authority.

6.3

Methods and material for containment and cleaning up
Advices on how to contain a spilltake up mechanically
Advices on how to clean up a spill
Take up mechanically.

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Other information relating to spills and releases
Place in appropriate containers for disposal.
Ventilate affected area.

6.4

Reference to other sections
Personal protective equipment: see section 8.
Incompatible materials: see section 10.
Disposal considerations: see section 13.

SECTION 7: Handling and storage

7.1

Precautions for safe handling
Avoid contact with skin and eyes.
Do not breathe dust.
Measures to prevent fire as well as aerosol and dust generation
Use local and general ventilation.
Specific notes/details
None.
Advice on general occupational hygiene
Do not eat, drink and smoke in work areas.
Wash hands after use.
Preventive skin protection (barrier creams/ointments) is recommended.
Remove contaminated clothing and protective equipment before entering eating areas.

7.2

Conditions for safe storage, including any incompatibilities
Flammability hazards
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
Incompatible substances or mixtures
Incompatible materials: see section 10.
Protect against external exposure, such as
heat
Consideration of other advice
Keep away from food, drink and animal feedingstuffs.
General rule
Keep out of reach of children.
Ventilation requirements
Provision of sufficient ventilation.
Packaging compatibilities
Keep only in original container.

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7.3

Specific end use(s)No information available.

SECTION 8: Exposure controls/personal protection

8.1

Control parameters
Occupational exposure limit values (Workplace Exposure Limits)
Country

Name of agent

GB

dust

WEL

GB

dust

GB

cycloalkanes(>C7)
subtilisin (bacil-

GB

CAS NoIdentifier

TWA
[ppm]

TWA
[mg/m³]

STEL
[ppm]

STEL
[mg/m³]

Notation

Source10iEH40/2005

WEL

4

r

EH40/2005

5989-27-5

WEL

800

EH40/2005

9014-01-1

WEL

0.00004

EH40/2005

lus subtilis carlsberg)
Notationiinhalable fractionr

respirable fraction

STEL

short-term exposure limit: a limit value above which exposure should not occur and which is related to a 15minute period (unless otherwise specified)

TWA

time-weighted average (long-term exposure limit): measured or calculated in relation to a reference period of
8 hours time-weighted average (unless otherwise specified)Relevant DNELs of components of the mixture
Name of substanceEndpointThresholdlevel

Protection goal,route of exposure

Used in

Exposure time

reaction product ofBenzenesulfonicacid, 4-C10-13-secalkyl derivs. andBenzenesulfonicacid, 4-methyl- andsodium hydroxide

DNEL

6 mg/m³

human, inhalatory

worker (industry)

chronic - systemic effects

reaction product ofBenzenesulfonicacid, 4-C10-13-secalkyl derivs. andBenzenesulfonicacid, 4-methyl- andsodium hydroxide

DNEL

85 mg/kg
bw/dayhuman, dermal

worker (industry)

chronic - systemic effects

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Relevant DNELs of components of the mixture
Name of sub-End-

ThresholdProtection goal,

stanceCAS No

point

level

route of exposure

Used in

Exposure time

reaction product ofBenzenesulfonicacid, 4-C10-13-secalkyl derivs. andBenzenesulfonicacid, 4-methyl- andsodium hydroxide

DNEL

1.5 mg/m³

human, inhalatory

consumer(private households)

chronic - systemic effects

reaction product ofBenzenesulfonicacid, 4-C10-13-secalkyl derivs. andBenzenesulfonicacid, 4-methyl- andsodium hydroxide

DNEL

42.5 mg/kg
bw/dayhuman, dermal

consumer(private households)

chronic - systemic effects

reaction product ofBenzenesulfonicacid, 4-C10-13-secalkyl derivs. andBenzenesulfonicacid, 4-methyl- andsodium hydroxide

DNEL

0.425 mg/
kg bw/dayhuman, oral

consumer(private households)

chronic - systemic effects

amides, C1218(even-numbered)and C18(unsatd.), Nhydroxyethyl90622-77-8

DNEL

73.4 mg/m³

human, inhalatory

worker (industry)

chronic - systemic effects

amides, C1218(even-numbered)and C18(unsatd.), Nhydroxyethyl90622-77-8

DNEL

4.16 mg/kg
bw/dayhuman, dermal

worker (industry)

chronic - systemic effects

amides, C1218(even-numbered)and C18(unsatd.), Nhydroxyethyl90622-77-8

DNEL

93.6 µg/
cm²

human, dermal

worker (industry)

chronic - local
effects

amides, C1218(even-numbered)and C18(unsatd.), Nhydroxyethyl90622-77-8

DNEL

21.73 mg/m³

human, inhalatory

consumer(private households)

chronic - systemic effects

amides, C1218(even-numbered)and C18(unsatd.), Nhydroxyethyl90622-77-8

DNEL

2.5 mg/kg
bw/dayhuman, dermal

consumer(private households)

chronic - systemic effects

amides, C1218(even-numbered)and C18(unsatd.), Nhydroxyethyl90622-77-8

DNEL

56.2 µg/
cm²

human, dermal

consumer(private households)

chronic - local
effects

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Relevant DNELs of components of the mixture
Name of sub-CAS NostanceEnd-

ThresholdProtection goal,

point

level

route of exposure

Used in

Exposure time

amides, C1218(even-numbered)and C18(unsatd.), Nhydroxyethyl90622-77-8

DNEL

6.25 mg/kg
bw/dayhuman, oral

consumer(private households)

chronic - systemic effects

subtilisin

9014-01-1

DNEL

1.8 mg/kg
bw/dayhuman, oral

consumer(private households)

chronic - systemic effects

linalool

78-70-6

DNEL

2.8 mg/m³

human, inhalatory

worker (industry)

chronic - systemic effects

linalool

78-70-6

DNEL

2.5 mg/kg
bw/dayhuman, dermal

worker (industry)

chronic - systemic effects

linalool

78-70-6

DNEL

0.7 mg/m³

human, inhalatory

consumer(private households)

chronic - systemic effects

linalool

78-70-6

DNEL

1.25 mg/kg
bw/dayhuman, dermal

consumer(private households)

chronic - systemic effects

linalool

78-70-6

DNEL

0.2 mg/kg
bw/dayhuman, oral

consumer(private households)

chronic - systemic effects

Relevant PNECs of components of the mixture
Name of substanceEndpointThreshold level

Environmental compartment

reaction product of Benzenesulfonic acid, 4-C10-13-sec-alkyl
derivs. and Benzenesulfonicacid, 4-methyl- and sodium hydroxide

PNEC

0.268 mg/l

freshwater

reaction product of Benzenesulfonic acid, 4-C10-13-sec-alkyl
derivs. and Benzenesulfonicacid, 4-methyl- and sodium hydroxide

PNEC

0.027 mg/l

marine water

reaction product of Benzenesulfonic acid, 4-C10-13-sec-alkyl
derivs. and Benzenesulfonicacid, 4-methyl- and sodium hydroxide

PNEC

5.6 mg/l

sewage treatment plant(STP)

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Relevant PNECs of components of the mixture
Name of substance

CAS NoEndpointThreshold level

Environmental compartment

reaction product of Benzenesulfonic acid, 4-C10-13-sec-alkyl
derivs. and Benzenesulfonicacid, 4-methyl- and sodium hydroxide

PNEC

8.1 mg/kg

freshwater sediment

reaction product of Benzenesulfonic acid, 4-C10-13-sec-alkyl
derivs. and Benzenesulfonicacid, 4-methyl- and sodium hydroxide

PNEC

8.1 mg/kg

marine sediment

reaction product of Benzenesulfonic acid, 4-C10-13-sec-alkyl
derivs. and Benzenesulfonicacid, 4-methyl- and sodium hydroxide

PNEC

35 mg/kg

soil

amides, C12-18(evennumbered) and C18(unsatd.),
N-hydroxyethyl90622-77-8

PNEC

0.007 mg/l

freshwater

amides, C12-18(evennumbered) and C18(unsatd.),
N-hydroxyethyl90622-77-8

PNEC

0.001 mg/l

marine water

amides, C12-18(evennumbered) and C18(unsatd.),
N-hydroxyethyl90622-77-8

PNEC

830 mg/l

sewage treatment plant(STP)

amides, C12-18(evennumbered) and C18(unsatd.),
N-hydroxyethyl90622-77-8

PNEC

1.201 mg/kg

freshwater sedimentamides, C12-18(evennumbered) and C18(unsatd.),
N-hydroxyethyl90622-77-8

PNEC

0.12 mg/kg

marine sedimentsubtilisin

9014-01-1

PNEC

1.7 µg/l

freshwater

subtilisin

9014-01-1

PNEC

0.17 µg/l

marine water

subtilisin

9014-01-1

PNEC

65,000 µg/l

sewage treatment plant(STP)

subtilisin

9014-01-1

PNEC

568 µg/kg

soil

linalool

78-70-6PNEC

0.2 mg/l

freshwater

linalool

78-70-6

PNEC

0.02 mg/l

marine water

linalool

78-70-6

PNEC

10 mg/lsewage treatment plant(STP)

linalool

78-70-6

PNEC

2.22 mg/kg

freshwater sediment

linalool

78-70-6

PNEC

0.222 mg/kg

marine sediment

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Relevant PNECs of components of the mixture
Name of substance

CAS NoEndpointThreshold level

Environmental compartment

linalool

8.2

78-70-6

PNEC

0.327 mg/kg

soil

Exposure controls
Appropriate engineering controls
General ventilation.
Individual protection measures (personal protective equipment)
Eye/face protection
In case of spillage: Wear eye/face protection.
Hand protection
Protective gloves
Material

Material thickness

Breakthrough times of the glove
material

no information available

no information available

no information available

Respiratory protection
In case of inadequate ventilation wear respiratory protection.
Particulate filter device (EN 143).
Environmental exposure controls
Use appropriate container to avoid environmental contamination.
Keep away from drains, surface and ground water.

SECTION 9: Physical and chemical properties

9.1

Information on basic physical and chemical properties
Appearance
Physical state

solid

Form

solid matter

Colour

blue

Odour

characteristic

Odour thresholdthese information are not available

Other safety parameters
pH (value)>11

Melting point/freezing point

these information are not available

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Initial boiling point and boiling range

these information are not available

Flash point

not applicable

Evaporation rate

these information are not available

Flammability (solid, gas)

non-combustible

Explosion limits of dust clouds

not determined

Vapour pressure

these information are not available

Densitythese information are not available

Vapour density

these information are not available

Relative density

these information are not available

Solubility(ies)
Water solubility

not miscible in any proportion

Partition coefficientn-octanol/water (log KOW)

these information are not available

Auto-ignition temperature

not relevant(Solid matter)

Relative self-ignition temperature for solids

these information are not available

Decomposition temperaturethese information are not available

Viscosity
Kinematic viscosity

not relevant(solid matter)

Dynamic viscosity

not relevant(solid matter)

9.2

Explosive properties

not explosive

Oxidising properties

shall not be classified as oxidising

Other information
None

SECTION 10: Stability and reactivity

10.1

Reactivity
This material is not reactive under normal ambient conditions.

10.2

Chemical stability
The material is stable under normal ambient and anticipated storage and handling conditions of temperature and pressure.

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10.3

Possibility of hazardous reactions
No known hazardous reactions.

10.4

Conditions to avoid
There are no specific conditions known which have to be avoided.
The product in the delivered form is not dust explosion capable; the enrichment of fine dust howeverleads to the danger of dust explosion.

10.5

Incompatible materials
oxidisers

10.6

Hazardous decomposition products
Reasonably anticipated hazardous decomposition products produced as a result of use, storage, spill
and heating are not known.

SECTION 11: Toxicological information

11.1

Information on toxicological effects
Classification procedure
If not otherwise specified the classification is based on:
Ingredients of the mixture (additivity formula).

Classification according to GHS (1272/2008/EC, CLP)
Acute toxicity
Acute toxicity of components of the mixture
Name of substance

CAS NoExposureroute

Endpoint

Value

Speciesreaction product of Benzenesulfonic acid, 4-C10-13-sec-alkyl derivs.
and Benzenesulfonic acid, 4methyl- and sodium hydroxide

oral

LD50

2,240 mg/kg

rat

reaction product of Benzenesulfonic acid, 4-C10-13-sec-alkyl derivs.
and Benzenesulfonic acid, 4methyl- and sodium hydroxidedermalLD50>2,000 mg/kg

rat

amides, C12-18(even-numbered)and C18(unsatd.), N-hydroxyethyl90622-77-8

oral

LD50

>2,000 mg/kg

rat

amides, C12-18(even-numbered)and C18(unsatd.), N-hydroxyethyl90622-77-8

dermalLD50>2,000 mg/kg

rabbitlinalool

78-70-6

oral

LD50

2,790 mg/kg

rat

linalool

78-70-6

dermalLD50

5,610 mg/kg

rabbitSkin corrosion/irritation
Causes skin irritation.

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Serious eye damage/eye irritation
Causes serious eye irritation.
This mixture does not meet the criteria for classification causes serious eye damage: expert judgement AISE-DetNet
Classification logging number DetNet/148, DetNet/149.
Skin sensitisation
May cause an allergic skin reaction.
Respiratory sensitisation
Classification could not be established because:
Data are lacking, inconclusive, or conclusive but not sufficient for classification.
Germ cell mutagenicity
Classification could not be established because:
Data are lacking, inconclusive, or conclusive but not sufficient for classification.
Carcinogenicity
Classification could not be established because:
Data are lacking, inconclusive, or conclusive but not sufficient for classification.
Reproductive toxicity
Classification could not be established because:
Data are lacking, inconclusive, or conclusive but not sufficient for classification.
Specific target organ toxicity - single exposure
Classification could not be established because:
Data are lacking, inconclusive, or conclusive but not sufficient for classification.
Specific target organ toxicity - repeated exposure
Classification could not be established because:
Data are lacking, inconclusive, or conclusive but not sufficient for classification.
Aspiration hazard
Shall not be classified as presenting an aspiration hazard.

SECTION 12: Ecological information

12.1

Toxicity
Aquatic toxicity (acute)
Test data are not available for the complete mixture.
Aquatic toxicity (acute) of components of the mixture
Name of substancereaction product ofBenzenesulfonic acid,
4-C10-13-sec-alkyl derivs. and Benzenesulfonic acid, 4-methylUnited Kingdom: en

CAS NoEndpoint

Value

Species

Exposure
time

EC50

8.8 mg/l

daphnia magna

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Name of substance

CAS NoEndpoint

Value

Species

Exposuretime

reaction product ofBenzenesulfonic acid,
4-C10-13-sec-alkyl derivs. and Benzenesulfonic acid, 4-methyland sodium hydroxideLC50

3.94 mg/l

daphnia magna

96 hreaction product ofBenzenesulfonic acid,
4-C10-13-sec-alkyl derivs. and Benzenesulfonic acid, 4-methyland sodium hydroxide

ErC50

72 mg/lalgae (Desmodesmus subspicatus)

72 hand sodium hydroxideamides, C12-18(evennumbered) andC18(unsatd.), N-hydroxyethyl90622-77-8

LC50

31 mg/lzebra fish (Daniorerio)

96 h

amides, C12-18(evennumbered) andC18(unsatd.), N-hydroxyethyl90622-77-8

EC50

37.5 mg/l

daphnia magna

24 hamides, C12-18(evennumbered) andC18(unsatd.), N-hydroxyethyl90622-77-8

EbC50

1.1 mg/l

algae (Desmodesmus subspicatus)

72 hamides, C12-18(evennumbered) andC18(unsatd.), N-hydroxyethyl90622-77-8ErC50

8.7 mg/l

algae (Desmodesmus subspicatus)

72 h

C16-18 alcohols, ethoxylated

68439-49-6

LC50>10 mg/l

goldfish (Carassius
auratus)

96 h

C16-18 alcohols, ethoxylated

68439-49-6EC50>10 mg/l

daphnia

48 hlinalool

78-70-6

LC50

27.8 mg/l

rainbow trout (Oncorhynchus mykiss)

96 hlinalool

78-70-6EC5059 mg/ldaphnia magna

48 hlinalool

78-70-6

ErC50

156.7 mg/l

algae (Desmodesmus subspicatus)

96 hAquatic toxicity (chronic)
Harmful to aquatic life with long lasting effects.
Test data are not available for the complete mixture.

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Aquatic toxicity (chronic) of components of the mixture
Name of substance

CAS NoEndpoint

Value

Species

Exposure
time

12.2

reaction product ofBenzenesulfonic acid,
4-C10-13-sec-alkyl derivs. and Benzenesulfonic acid, 4-methyland sodium hydroxide

LC50

1.67 mg/l

daphnia magna

21 dreaction product ofBenzenesulfonic acid,
4-C10-13-sec-alkyl derivs. and Benzenesulfonic acid, 4-methyland sodium hydroxide

EC50

1.5 mg/l

daphnia magna

21 dreaction product ofBenzenesulfonic acid,
4-C10-13-sec-alkyl derivs. and Benzenesulfonic acid, 4-methyland sodium hydroxide

NOEC

0.23 mg/l

rainbow trout (Oncorhynchus mykiss)

72 dreaction product ofBenzenesulfonic acid,
4-C10-13-sec-alkyl derivs. and Benzenesulfonic acid, 4-methyland sodium hydroxide

growth (EbCx)
10%56 mg/lmicroorganisms

17 hPersistence and degradability
Degradability of components of the mixture
Name of substance

CAS Noreaction product ofBenzenesulfonic acid,
4-C10-13-sec-alkyl derivs. and Benzenesulfonic acid, 4-methyland sodium hydroxide

Process

Degradation rateTime

DOC removal

94 %

28 d

amides, C12-18(evennumbered) andC18(unsatd.), N-hydroxyethyl90622-77-8

oxygen depletion

74 – 82 %30 dsubtilisin

9014-01-1

carbon dioxide generation

100 %

29 d

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Name of substance

CAS NoProcess

Degradation rate

Timesubtilisin

9014-01-1

carbon dioxide generation

60 %

7d

linalool

78-70-6oxygen depletion

64.2 %

28 d

Biodegradation
Data are not available.
Persistence
Data are not available.

12.3

Bioaccumulative potential
Test data are not available for the complete mixture.
Bioaccumulative potential of components of the mixture
Name of substance

CAS NoBCF

reaction product of Benzenesulfonic acid, 4-C10-13sec-alkyl derivs. and Benzenesulfonic acid, 4-methyland sodium hydroxide

12.4

Log KOW
0.7 (pH value: 6, 20 °C)

amides, C12-18(evennumbered) andC18(unsatd.), N-hydroxyethyl90622-77-8

56.8

4.3 (25 °C)

subtilisin

9014-01-1-3.1 (pH value: 9.2, 25 °C)

linalool

78-70-6

2.9 (pH value: 7, 20 °C)

Mobility in soil
Data are not available.

12.5

Results of PBT and vPvB assessment
This mixture does not contain any substances that are assessed to be a PBT or a vPvB.

12.6

Other adverse effects
Data are not available.
Endocrine disrupting potential
None of the ingredients are listed.

Remarks
Wassergefährdungsklasse, WGK (water hazard class): 2

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SECTION 13: Disposal considerations

13.1

Waste treatment methods
This material and its container must be disposed of as hazardous waste.
Sewage disposal-relevant information
Do not empty into drains.
Waste treatment of containers/packagings
Handle contaminated packages in the same way as the substance itself.

Remarks
Please consider the relevant national or regional provisions.

SECTION 14: Transport information

14.1

UN numbernot subject to transport regulations

14.2

UN proper shipping name

-

14.3

Transport hazard class(es)

none

Class

-

14.4

Packing group

not assigned to a packing group

14.5

Environmental hazards

non-environmentally hazardous acc. to the dangerous goods regulations

14.6

Special precautions for user
There is no additional information.

14.7

Transport in bulk according to Annex II of MARPOL and the IBC CodeThe cargo is not intended to be carried in bulk.

14.8

Information for each of the UN Model Regulations
Transport of dangerous goods by road, rail and inland waterway (ADR/RID/ADN).
Not subject to ADR, RID and ADN.

International Maritime Dangerous Goods Code (IMDG)
Not subject to IMDG.

International Civil Aviation Organization (ICAO-IATA/DGR)
Not subject to ICAO-IATA.

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SECTION 15: Regulatory information

15.1

Safety, health and environmental regulations/legislation specific for the substance or
mixtureRelevant provisions of the European Union (EU)
Restrictions according to REACH, Annex XVIIName of substanceName acc. to inventory

CAS NoRestriction

C16-18 alcohols, ethoxylated

this product meets the criteria for classification in accordance with Regulation
No 1272/2008/EC

R3

limonene

this product meets the criteria for classification in accordance with Regulation
No 1272/2008/EC

R3

limonene

flammable / pyrophoric

R40

linalool

this product meets the criteria for classification in accordance with Regulation
No 1272/2008/EC

R3

LegendR3

1. Shall not be used in:- ornamental articles intended to produce light or colour effects by means of different phases, for example in ornamental lamps and ashtrays,- tricks and jokes,- games for one or more participants, or any article intended to be used as such, even with ornamental aspects,
2. Articles not complying with paragraph 1 shall not be placed on the market.
3. Shall not be placed on the market if they contain a colouring agent, unless required for fiscal reasons, or perfume, or both, if they:- can be used as fuel in decorative oil lamps for supply to the general public, and,- present an aspiration hazard and are labelled with R65 or H304,
4. Decorative oil lamps for supply to the general public shall not be placed on the market unless they conform to
the European Standard on Decorative oil lamps (EN 14059) adopted by the European Committee for Standardisation (CEN).
5. Without prejudice to the implementation of other Community provisions relating to the classification, packaging and labelling of dangerous substances and mixtures, suppliers shall ensure, before the placing on themarket, that the following requirements are met:(a) lamp oils, labelled with R65 or H304, intended for supply to the general public are visibly, legibly and indelibly marked as follows: ‘Keep lamps filled with this liquid out of the reach of children’; and, by 1 December
2010, ‘Just a sip of lamp oil - or even sucking the wick of lamps - may lead to life-threatening lung damage’;(b) grill lighter fluids, labelled with R65 or H304, intended for supply to the general public are legibly and indelibly marked by 1 December 2010 as follows: ‘Just a sip of grill lighter may lead to life threatening lungdamage’;(c) lamp oils and grill lighters, labelled with R65 or H304, intended for supply to the general public are packaged
in black opaque containers not exceeding 1 litre by 1 December 2010.
6. No later than 1 June 2014, the Commission shall request the European Chemicals Agency to prepare a dossier,in accordance with Article 69 of the present Regulation with a view to ban, if appropriate, grill lighter fluids andfuel for decorative lamps, labelled R65 or H304, intended for supply to the general public.
7. Natural or legal persons placing on the market for the first time lamp oils and grill lighter fluids, labelled with
R65 or H304, shall by 1 December 2011, and annually thereafter, provide data on alternatives to lamp oils andgrill lighter fluids labelled R65 or H304 to the competent authority in the Member State concerned. Member
States shall make those data available to the Commission.

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LegendR40

1. Shall not be used, as substance or as mixtures in aerosol dispensers where these aerosol dispensers are intended for supply to the general public for entertainment and decorative purposes such as the following:- metallic glitter intended mainly for decoration,- artificial snow and frost,- ‘whoopee’ cushions,- silly string aerosols,- imitation excrement,- horns for parties,- decorative flakes and foams,- artificial cobwebs,- stink bombs.
2. Without prejudice to the application of other Community provisions on the classification, packaging and labelling of substances, suppliers shall ensure before the placing on the market that the packaging of aerosol dispensers referred to above is marked visibly, legibly and indelibly with:‘For professional users only’.
3. By way of derogation, paragraphs 1 and 2 shall not apply to the aerosol dispensers referred to Article 8 (1a) of
Council Directive 75/324/EEC (2).
4. The aerosol dispensers referred to in paragraphs 1 and 2 shall not be placed on the market unless they conform to the requirements indicated.

List of substances subject to authorisation (REACH, Annex XIV) / SVHC - candidate list
none of the ingredients are listed

Seveso Directive
2012/18/EU (Seveso III)
No

Dangerous substance/hazard categories

Qualifying quantity (tonnes) for the application of lower and upper-tier re-

Notes

quirements
not assigned

Directive 2011/65/EU on the restriction of the use of certain hazardous substances inelectrical and electronic equipment (RoHS) - Annex IInone of the ingredients are listed

Regulation 166/2006/EC concerning the establishment of a European Pollutant Release
and Transfer Register (PRTR)
none of the ingredients are listed
Regulation 648/2004/EC on detergents
Labelling of contents
Wt%

Constituents≥30%

anionic surfactants<5%

non-ionic surfactants
enzymes (subtilisin)
perfumes (LIMONENE, LINALOOL)

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Directive 2000/60/EC establishing a framework for Community action in the field of water
policy (WFD)
none of the ingredients are listed

Regulation 98/2013/EU on the marketing and use of explosives precursors
none of the ingredients are listed

15.2

Chemical Safety Assessment
No Chemical Safety Assessment has been carried out for this mixture by the supplier.
Chemical safety assessments for substances in this mixture were not carried out.

SECTION 16: Other information

Indication of changes (revised safety data sheet)
SectionFormer entry (text/value)

Actual entry (text/value)

3.2

Hazardous ingredients:change in the listing (table)

8.1

Relevant DNELs of components of the mixture:change in the listing (table)

8.1

Relevant PNECs of components of the mixture:change in the listing (table)

15.1

Restrictions according to REACH, Annex XVII:change in the listing (table)

Abbreviations and acronyms
Abbr.

Descriptions of used abbreviations

ADN

Accord européen relatif au transport international des marchandises dangereuses par voies de navigation intérieures (European Agreement concerning the International Carriage of Dangerous Goods
by Inland Waterways)

ADR

Accord européen relatif au transport international des marchandises dangereuses par route(European Agreement concerning the International Carriage of Dangerous Goods by Road)

Aquatic Acute

Hazardous to the aquatic environment - acute hazard

Aquatic Chronic

Hazardous to the aquatic environment - chronic hazard

BCF

Bioconcentration factor

CAS

Chemical Abstracts Service (service that maintains the most comprehensive list of chemical substances)

CLP

Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures

DGR

Dangerous Goods Regulations (see IATA/DGR)

DNELDerived No-Effect Level

EC No

The EC Inventory (EINECS, ELINCS and the NLP-list) is the source for the seven-digit EC number, an
identifier of substances commercially available within the EU (European Union)

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Abbr.

Descriptions of used abbreviations

EH40/2005

EH40/2005 Workplace exposure limits (http://www.nationalarchives.gov.uk/doc/open-government-licence/)

EINECS

European Inventory of Existing Commercial Chemical Substances

ELINCS

European List of Notified Chemical Substances

Eye Dam.

Seriously damaging to the eye

Eye Irrit.

Irritant to the eye

Flam. Liq.

Flammable liquid

GHS"Globally Harmonized System of Classification and Labelling of Chemicals" developed by the United
Nations

IATA

International Air Transport Association

IATA/DGR

Dangerous Goods Regulations (DGR) for the air transport (IATA)ICAOInternational Civil Aviation Organization

IMDG

International Maritime Dangerous Goods Codeindex NoThe Index number is the identification code given to the substance in Part 3 of Annex VI to Regulation (EC) No 1272/2008

log KOW

n-Octanol/water

MARPOLInternational Convention for the Prevention of Pollution from Ships (abbr. of "Marine Pollutant")

NLP

No-Longer Polymer

PBT

Persistent, Bioaccumulative and Toxic

PNEC

Predicted No-Effect Concentrationppm

Parts per million

REACH

Registration, Evaluation, Authorisation and Restriction of Chemicals

Resp. Sens.

Respiratory sensitisation

RID

Règlement concernant le transport International ferroviaire des marchandises Dangereuses (Regulations concerning the International carriage of Dangerous goods by Rail)Skin Corr.

Corrosive to skin

Skin Irrit.

Irritant to skin

Skin Sens.

Skin sensitisation

STEL

Short-term exposure limit

STOT SESpecific target organ toxicity - single exposure

SVHC

Substance of Very High Concern

TWA

Time-weighted averagevPvB

Very Persistent and very Bioaccumulative

WEL

Workplace exposure limit

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Key literature references and sources for data
Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures.
Regulation (EC) No. 1907/2006 (REACH), amended by 2015/830/EU.
Transport of dangerous goods by road, rail and inland waterway (ADR/RID/ADN).
International Maritime Dangerous Goods Code (IMDG).
Dangerous Goods Regulations (DGR) for the air transport (IATA).

Classification procedure
Physical and chemical properties.
Health hazards.
Environmental hazards.
The method for classification of the mixture is based on ingredients of the mixture (additivity formula).

List of relevant phrases (code and full text as stated in chapter 2 and 3)
Code

Text

H226

Flammable liquid and vapour.

H315

Causes skin irritation.

H317

May cause an allergic skin reaction.

H318

Causes serious eye damage.

H319

Causes serious eye irritation.

H334

May cause allergy or asthma symptoms or breathing difficulties if inhaled.

H335

May cause respiratory irritation.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

H411

Toxic to aquatic life with long lasting effects.

H412

Harmful to aquatic life with long lasting effects.

Responsible for the safety data sheet

C.S.B. GmbH
Düsseldorfer Str. 113
47809 Krefeld, Germany

Telephone: +49 (0) 2151 - 652086 - 0
Telefax: +49 (0) 2151 - 652086 - 9
e-Mail: info@csb-online.de
Website: www.csb-online.de

Disclaimer
This information is based upon the present state of our knowledge.
This SDS has been compiled and is solely intended for this product.

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