A．査読付き原著論文
1)“Facile synthesis of trifluoromethyl-substituted enynes: Remarkable reactivity and stereoselectivity oftributyl(3,3,3-trifluoropropynyl)stannane in carbostannylation of alkynes”
S. Shimizu,* G. Jiang, M. Murai, Y. Takeda, Y. Nakao, T. Hiyama, E. Shirakawa, Chemistry Letters, 34,
1700−1701 (2005).

2)“Copper-catalyzed transformation of carbonyl-ene-nitrile compounds: Vinylation, imino ene reaction, andalkynylation of 2-aza-2,4-cyclopentadienone intermediates generated via Ritter-type hydration anddehydrative cyclization reactions”
M. Murai, S. Kawai, K. Miki, K. Ohe,* Journal of Organometallic Chemistry, 692, 579−584 (2007).

3)“Novel generation of 3,3,3-trifluoropropynyllithium and transformation of the carbonyl adducts totrifluoromethyl-substituted allenes”
M. Shimizu,* M. Higashi, Y. Takeda, G. Jiang, M. Murai, T. Hiyama, Synlett, 1163−1165 (2007).

4)“Transition metal-catalyzed ring-opening, substitution, and cyclopropanation reactions via vinylcarbene
complexes generated from O-propargyl thiocarbamates”
Y. Ikeda, M. Murai, T. Abo, K. Miki, K. Ohe,* Tetrahedron Letters, 48, 6651−6654 (2007).

5)“Copper-catalyzed addition reactions of aromatics and ketones to 2-aza-2,4-cyclopentadienone: Facile andefficient transformation of carbonyl-ene-nitriles to 1H-pyrrolin-2(5H)-ones”
M. Murai, K. Miki, K. Ohe,* The Journal of Organic Chemistry, 73, 9174−9176 (2008).

6)“A new route to 3-acyl-2-aminobenzofurans: Palladium-catalyzed cycloisomerisation of 2-(cyanomethyl)phenyl esters”
M. Murai, K. Miki, K. Ohe,* Chemical Communications, 45, 3466−3468, (2009).

7)“New preparation and synthetic reactions of 3,3,3-trifluoropropynyllithium, -borate and -stannane: Facile
synthesis of trifluoromethylated allenes, arylacetylenes and enynes”
M. Shimizu,* M. Higashi, Y. Takeda, M. Murai, G. Jiang, Y. Asai, Y. Nakao, E. Shirakawa, T. Hiyama,
Future Medicinal Chemistry, 1, 921−945 (2009).

8)“Atom-efficient synthesis of -alkylidene-N-furylimines via catalytic vinylcarbene-transfer reactions tocarbonyl-ene-nitrile compounds”
M. Murai, S. Yoshida, K. Miki, K. Ohe,* Chemical Communications, 46, 3366−3368 (2010).

9)“A stereoselective cyclization cascade mediated by SmI2-H2O: Synthetic studies towards Stolonidiol”
T. M. Baker, L. A. Sloan, L. H. Choudhury, M. Murai, D. J. Procter,* Tetrahedron: Asymmetry, 21,1246−1261 (2010).

10) “Gallium(III)-catalyzed bromocyanation of alkynes: Regio- and stereoselective synthesis of -bromo-,unsaturated nitriles”
M. Murai, R. Hatano, S. Kitabata, K. Ohe,* Chemical Communications, 47, 2375−2377 (2011).
11) “Rhodium-catalyzed carbene transfer reactions via thienylcarbene complexes generated from thiocarbamoylene-yne compounds”
A. Tsuneishi, K. Okamoto, Y. Ikeda, M. Murai, K. Miki, K. Ohe,* Synlett, 655−658 (2011).
12) “Practical synthesis of aromatic nitriles via gallium-catalyzed electrophilic cyanation of aromatic C–H bond”
K. Okamoto, M. Watanabe, M. Murai, R. Hatano, K. Ohe,* Chemical Communications, 48, 3127−3129(2012).
13) “Pd- and Cu-catalyzed one-pot multicomponent synthesis of hetero ,’-dimers of heterocycles”
T. Murata, M. Murai, Y. Ikeda, K. Miki, K. Ohe,* Organic Letters, 14, 2296−2299 (2012).
14) “Azulene-based conjugated polymers: Unique seven-membered ring connectivity leading tostimuli-responsiveness”
M. Murai, E. Amir, R. J. Amir, C. J. Hawker,* Chemical Science, 3, 2721−2725 (2012).
15) “Gold-catalyzed cycloisomerization reactions of 2-(2-propynyl)pyridine N-oxides leading to indolizinones”
M. Murai, S. Kitabata, K. Okamoto, K. Ohe,* Chemical Communications, 48, 7622−7624 (2012).
16) “Zinc-porphyrins functionalized with redox-active peripherals: Enhancement of d-p interaction leading tounique assembly and redox-triggered remote switching of fluorescence”
M. Murai, M. Sugimoto, M. Akita,* Dalton Transactions, 42, 16108−16120 (2013).
17) “Copper-catalyzed C−H cyanation of terminal alkynes with cyanogen iodide”
K. Okamoto,* M. Watanabe, N. Sakata, M. Murai, K. Ohe,* Organic Letters, 15, 5810−5813 (2013).
18) “Bismuth(III)-catalyzed dehydrative etherification and thioetherification of phenolic hydroxy groups”
M. Murai,* K. Origuchi, K. Takai,* Organic Letters, 16, 3828−3831 (2014).
19) “Modulating structure and properties in organic chromophores: Influence of azulene as a building block”
M. Murai, S.-Y. Ku, N. D. Treat, M. J. Robb, M. L. Chabinyc, C. J. Hawker,* Chemical Science, 5,3753−3760 (2014).
20) “Bismuth-catalyzed synthesis of PAHs with a phenanthrene backbone via cyclization and aromatization of
2-(2-arylphenyl)vinyl ethers”
M. Murai,* N. Hosokawa, D. Roy, K. Takai,* Organic Letters, 16, 4134−4137 (2014).
21) “Conjugated oligomers incorporating azulene building blocks –Seven- vs five-membered ring connectivity”
E. Amir, M. Murai, R. J. Amir, R. J. S. Cowart Jr, M. L. Chabinyc, C. J. Hawker,* Chemical Science, 5,4483−4489 (2014).
22) “Modulating the properties of azulene-containing polymers through controlled incorporation ofregioisomers”
K. Tsurui, M. Murai, S.-Y. Ku, C. J. Hawker,* M. J. Robb,* Advanced Functional Materials, 24,
7338−7347 (2014).
23) “Rhenium-catalyzed synthesis of 2H-1,2-oxaphosphorin 2-oxides via the regio- and stereoselective addition
reaction of -keto phosphonates with alkynes”
M. Murai,* M. Nakamura, K. Takai,* Organic Letters, 16, 5784−5787 (2014).
24) “Rhodium-catalyzed dehydrogenative germylation of C−H bonds: New entry to unsymmetricallyfunctionalized 9-germafluorenes”
M. Murai,* K. Matsumoto, R. Okada, K. Takai,* Organic Letters, 16, 6492−6495 (2014).
25) “Iridium-catalyzed intermolecular dehydrogenative silylation of polycyclic aromatic compounds without
directing group”
M. Murai,* K. Takami, K. Takai,* Chemistry –A European Journal, 21, 4566−4570 (2015).
26) “Isolation and structural characterization of gem-di(iodozincio)methane complexes stabilized with nitrogen
ligands”
Y. Nishida, N. Hosokawa, M. Murai,* K. Takai,* Journal of the American Chemical Society, 137,
114−117 (2015).
27) “Rhenium-catalyzed anti-Markovnikov addition reaction of methanetricarboxylates to unactivated terminal
acetylenes”
S. Hori, M. Murai,* K. Takai,* Journal of the American Chemical Society, 137, 1452−1457 (2015).
28) “Transition metal-catalyzed facile access to 3,11-dialkylfulminenes for transistor application”
M. Murai,* H. Maekawa, S. Hamao, Y. Kubozono, D. Roy, K. Takai,* Organic Letters, 17, 708−711(2015).

29) “Rhenium-catalysed dehydrogenative borylation of primary and secondary C(sp3)−H bonds adjacent to anitrogen atom”
M. Murai,* T. Omura, Y. Kubozono, K. Takai,* Chemical Communications, 51, 4583−4586 (2015).
30) “Palladium-catalyzed three-component coupling reactions of 2-(cyanomethyl)phenol, aryl halides, andcarbon monooxide”
M. Murai, K. Okamoto, K. Miki, K. Ohe,* Tetrahedron, 71, 4432−4437 (2015).
31) “Iridium-catalyzed dehydrogenative silylation of azulenes based on the regioselective C−H bonds activation”
M. Murai,* K. Takami, H. Takeshima, K. Takai,* Organic Letters, 17, 1798−1801 (2015).
32) “Acceleration effects of phosphine ligands on the rhodium-catalyzed dehydrogenative silylation andgermylation of unactivated C(sp3)−H bonds”
M. Murai,* H. Takeshima, H. Morita, Y. Kuninobu, K. Takai,* The Journal of Organic Chemistry, 80,
5407−5414 (2015). Selected as a Featured Article and ACS Editor’s Choice.
33) “Rhodium-catalyzed synthesis of benzosilolometallocenes via the dehydrogenative silylation of C(sp2)−Hbonds”
M. Murai,* K. Matsumoto, K. Takeuchi, K. Takai,* Organic Letters, 17, 3102−3105 (2015).
34) “Stereospecific deoxygenation of aliphatic epoxides to alkenes under rhenium catalysis”
T. Nakagiri, M. Murai,* K. Takai,* Organic Letters, 17, 3346−3349 (2015).
Highlight in "Organic Chemistry Highlights".
35) “Short synthesis of [5]- and [7]phenacenes with silyl groups at the axis positions”
D. Roy, H. Maekawa, M. Murai,* K. Takai,* Chemistry –An Asian Journal, 10, 2518−2524 (2015).
36) “Rhodium-catalyzed synthesis of chiral spiro-9-silabifluorenes via dehydrogenative silylation: Mechanistic
insights into the construction of tetraorganosilicon stereocenters”
M. Murai,* Y. Takeuchi, K. Yamauchi, Y. Kuninobu, K. Takai,* Chemistry –A European Journal, 22,6048−6058 (2016). Selected as a Hot Paper.
37) “Palladium-catalyzed direct arylation of azulene based on the regioselective C−H bond activation”
M. Murai,* M. Yanagawa, M. Nakamura, K. Takai,* Asian Journal of Organic Chemistry, 629−635(2016).
38) “Synthesis and properties of sila[n]helicenes via dehydrogenative silylation of C−H bonds under rhodium
catalysis”
M. Murai,* R. Okada, A. Nishiyama, K. Takai,* Organic Letters, 18, 4380−4383 (2016).
39) “Molybdenum-catalyzed stereospecific deoxygenation of epoxides to alkenes”
S. Asako,* T. Sakae, M. Murai, K. Takai,* Advanced Synthesis and Catalysis, 358, 3966−3970 (2016).
Selected as a Very Important Paper.
40) “Rhenium-Catalyzed Construction of Polycyclic Hydrocarbon Frameworks by a Unique Cyclization of
1,n-Diynes Initiated by 1,1-Difunctionalization with Carbon Nucleophiles”
M. Murai,* E. Uemura, S. Hori, K. Takai,* Angewandte Chemie International Edition, 56, 5956−5960(2017).
41) “Iridium-catalyzed dehydrogenative dimerization of benzylmethylsilanes via silylation of C(sp3)−H bonds
adjacent to a silicon atom”
M. Murai,* Y. Takeuchi, K. Takai,* Chemistry Letters, 46, 1044−1047 (2017).
42) “Rhodium-catalyzed silylative and germylative cyclization with dehydrogenation leading to 9-sila- and9-germafluorenes: A combined experimental and computational mechanistic study”
M. Murai,* R. Okada, S. Asako, K. Takai,* Chemistry –A European Journal, 23, 10861−10870 (2017).

Selected as a Hot Paper.
43) “Iridium-catalyzed hydrosilylation of cyclopropanes via regioselective carbon−carbon bond cleavage”
M. Murai,* A. Nishiyama, N. Nishinaka, H. Morita, K. Takai,* Chemical Communications, 53, 9281−9284(2017).
44) “Structural characterization and unique catalytic performance of reactive silyl-substituted geminal
dichromiomethane complexes stabilized with diamine ligand”
M. Murai,* R. Taniguchi, N. Hosokawa, Y. Nishida, H. Mimachi, T. Oshiki, K. Takai,* Journal of theAmerican Chemical Society, 139, 13184−13192 (2017).
Selected as JACS Spotlights (J. Am. Chem. Soc., 139, 12863−12864 (2017)).
45) “Azulene-fused linear-shaped polycyclic aromatic hydrocarbons with low bandgap and uniquestimuli-responsiveness”
M. Murai,* S. Iba, H. Ota, K. Takai,* Organic Letters, 19, 5585−5588 (2017).
46) “Rhenium-catalyzed ortho-alkylation of phenols”
Y. Kuninobu,* M. Yamamoto, M. Nishi, T. Yamamoto, T. Matsuki, M. Murai,* K. Takai,* Organic
Syntheses, 94, 280−291 (2017).
47) “Straightforward approach to borylcyclopropanes by chromium-promoted cyclopropanation of unactivatedalkenes”
M. Murai,* C. Mizuta, R. Taniguchi, K. Takai,* Organic Letters, 19, 6104−6107 (2017).
48) “Iridium-catalyzed sequential silylation and borylation of heteroarenes based on the regioselective C−H bondactivation”
M. Murai,* N. Nishinaka, K. Takai,* Angewandte Chemie International Edition, 57, 5843−5847 (2018).
49) “Amine-promoted anti-Markovnikov addition reaction of 1,3-dicarbonyl compounds with terminal alkynes underrhenium catalysis”
M. Murai,* E. Uemura, K. Takai,* ACS Catalysis, 8, 5454−5459 (2018).
50) “Catalytic cleavage and reformation of ethereal -bonds”
M. Murai,* K. Origuchi, K. Takai,* Chemistry Letters, 47, 927−930 (2018).
51) “Unsymmetrical difunctionalization of two different C−H bonds in one-pot under transition metal catalysis”
M. Murai,* K. Takai,* Synthesis (Mini review), 51, 40−54 (2019).
Invited contribution to the “Golden Synthesis Anniversary Special Issue” (P. Knochel, Ed.).
52) “Regioselective arene homologation through rhenium-catalyzed deoxygenative aromatization of
7-oxabicyclo[2.2.1]hepta-2,5-diene”
M. Murai,* T. Ogita, K. Takai,* Chemical Communications, 55, 2332−2335 (2019).
53) “Palladium-catalyzed double-bond migration of unsaturated hydrocarbons controllable by second metal
catalysts”
M. Murai,* K. Nishimura, K. Takai,* Chemical Communications, 55, 2769−2772 (2019).
54) “Chromium-mediated stannylcyclopropanation of alkenes with (diiodomethyl)stannanes”
M. Murai,* R. Taniguchi, C. Mizuta, K. Takai,* Organic Letters, 21, 2668−2672 (2019).
55) “Regioselective functionalization of 9,9-dimethyl-9-silafluorenes by borylation, bromination, and nitration”
M. Murai,* N. Nishinaka, M. Kimura, K. Takai,* The Journal of Organic Chemistry, 84, 5667−5676(2019).
56) “Rhenium-catalyzed regioselective ortho-alkenylation and [3+2+1]cycloaddition of phenols with internalalkynes”
M. Murai,* M. Yamamoto, K. Takai,* Organic Letters, 21, 3441−3445 (2019).

57) “Rhenium-catalysed cyclization via 1,2-iodine and 1,5-hydrogen migration for the synthesis of
2-iodo-1H-indenes”
M. Murai,* K. Takai,* Organic Letters, 21, 6756−6760 (2019).
58) “Mechanistic insights into rhenium-catalyzed regioselective C-alkenylation of phenols with internal alkynes”
M. Murai,* M. Yamamoto, K. Takai,* Chemistry –A European Journal, 25, 15189−15197 (2019).
59) “Regioselective sequential silylation and borylation of aromatic aldimines as a strategy for programming
synthesis of multifunctionalized benzene derivatives”
M. Murai,* N. Nishinaka, T. Enoki, K. Takai,* Organic Letters, 22, 316−321 (2020).
60) “Cyclization of 1,n-enynes initiated by the addition reaction of gem-dichromiomethane reagents to alkynes”
M. Murai,* R. Taniguchi, K. Takai,* Organic Letters, 22, 3985−3988 (2020).
61) “Cyclization of 5-alkynones with chromium alkylidene equivalents generated in situ fromgem-dichromiomethanes”
M. Murai,* R. Taniguchi, T. Kurogi, S. Moritani, K. Takai,* Chemical Communications, 56, 9711−9714(2020).
62) “Regiodivergent carbene/alkyne metathesis in chromium-mediated coupling and cyclization with 1,6-enynes”
M. Murai,* R. Taniguchi, K. Takai,* Bulletin of the Chemical Society of Japan, 94, 2848−2852 (2021).
63) “Silylative cyclization with dehydrogenation leading to benzosilole-fused azulenes showing uniquestimuli-responsive fluorescence”
M. Murai,* Asian Journal of Organic Chemistry, 11, 262−266 (2022).
64) “Diazulenylmethyl cations with a silicon bridge: A -extended cationic motif to form J-aggregates withnear-infrared absorption and emission”
M. Murai,* M. Abe, S. Ogi, S. Yamaguchi,* Journal of the American Chemical Society, 144, 20385−
20393 (2022).
Press released by Nagoya Univ.
65) “Germanium- and tin-bridged diazulenylmethyl cations: Effects of the group 14 element on the structure andproperties of the -extended cation”
M. Murai,* M. Ito, S. Takahashi, S. Yamaguchi,* Dalton Transactions, 52, in press (2023).
66) “A kinetically stabilized nitrogen-doped triangulene cation: Stable and NIR fluorescent diradical cation withtriplet ground state”
S. Arikawa, A. Shimizu,* D. Shiomi, K. Sato,* T. Takui, H. Sotome,* H. Miyasaka, M. Murai, S.
Yamaguchi, S. Shintani,* Angewandte Chemie International Edition, 62, e202302714 (2023).
67) “Azulene-fused linearly -extended polycyclic aromatic hydrocarbons: Synthesis, photophysical properties,
and OFETs applications”
M. Murai,* S. Iba, S. Hamao, Y. Kubozono, H. Ota, K. Takai,* Bulletin of the Chemical Society of Japan,
96, 1077 (2023).
Invited contribution to the “Controlled Chemical Construction (C3) for Advanced Functions” (Sawamoto, M.
Ed.), and highlighted as a “Selected Paper”.
68) “Dithienoazepine-based near-infrared dyes: Janus-faced effects of thiophene-fused structure on antiaromatic
azepines”
M. Murai,* T. Enoki, S. Yamaguchi,* Angewandte Chemie International Edition, 62, e202311445 (2023).
Selected as a Very Important Paper and Inside Cover.
Highlighted in Angew. Chem. Int. Ed. 2024, 63, e202317060 and ChemStation.
Press released by Nagoya Univ.
69) “Dithieno[3,2-b;2’,3’-f]phosphepinium-Based Near-Infrared Fluorophores: px−* Conjugation Inherent toSeven-Membered Phosphacycles”
K, Andoh, M. Murai,* P.-A. Bouit, M. Hissler, S. Yamaguchi,* Angewandte Chemie International Edition,
63, e202410204 (2024).
70) “Controlling Redox and Wire-Like Charge-Delocalization Properties of Dinuclear Mixed-Valence
Complexes with MCp*(dppe) (M = Fe, Ru) Termini Bridged by Metalloporphyrin Linkers”
M. Murai, K. Ono, Y. Tanaka, M. Akita,* ACS Organic & Inorgnic Au, 4, accepted (2024).
Invited contribution to virtual special issue “Electrochemical Explorations in Organic and Inorganic
Chemistry”.
71) “Sulfur-Bridged Cationic Diazulenomethenes: Charge-Segregated Assembly of -Conjugated Cations
Toward Charge-Carrier Transport Application”
S. Takahashi, M. Murai,* T. Hattori, S. Seki,* T. Yanai, S. Yamaguchi,* Journal of the American Chemical
Society, 146, 22642−22649 (2024). ChemRxiv 2024, preprint (DOI: 10.26434/chemrxiv-2024-k45wj).
Press released by Nagoya Univ., Kyoto Univ., and JST.

B. 招待 or 依頼講演
1)

“遷移金属触媒を用いる多環芳香族炭化水素の効率的合成法とその官能基化法の開発”
村井征史, 第 3 回化学フロンティア研究会
岡山, 2014年 7月

2)“9-シラフルオレンの用途と脱水素を伴うケイ素化反応を利用した最近の研究の展開”
村井征史, 田岡化学工業講演会
田岡化学工業株式会社, 2016年 1月

3)“Rhenium-catalyzed anti-Markovnikov addition reaction of carbon nucleophiles to unactivated terminal
acetylenes”
M. Murai, International Symposium on Pure & Applied Chemistry (ISPAC)
Ho Chi Minh, Vietnam, June, 20174)

“Transition metal-catalyzed intermolecular dehydrogenative silylation of aromatic compounds without
directing groups based on the regio- and chemoselective C−H bond activation”
M. Murai, 8th Annual Global Congress of Catalysis 2017
Shanghai, China, October, 20175)“金属触媒を用いた炭化水素の効率的な機能化法の開発”
村井征史, 第 13 回触媒相模セミナー
東ソー東京研究センター (山川哲 主席研究員), 2017 年 11 月

6)

“金属活性種の設計に基づく炭化水素の選択的な直截官能基化”
村井征史, 日本化学会第 98 春季年会 (進歩賞受賞講演)
日本大学, 2018 年 3 月

7)“Rhenium-catalyzed intermolecular anti-Markovnikov addition reaction of 1,3-dicarbonyl compounds withterminal alkynes”
M. Murai, K. Takai, 28th International Conference on Organometallic Chemistry (ICOMC 2018)
Florence, Italy, July, 20188)

“金属触媒による配向基を用いない不飽和炭化水素の官能基化”
村井征史, 京大人環 分子環境相関論サマーセミナー2018
京都大学 (藤田健一 教授), 2018 年 9 月

9)“ヘテロ配向基を用いない不飽和分子の位置選択的な直截官能基化”

村井征史, 第 45 回オルガノメタリックセミナー
広島大学 (吉田拡人 教授), 2018 年 10 月
10) “Gem-ジクロムメタン反応剤から発生するクロムアルキリデン種による1,n-エンインの環化反応”
村井征史, 第 9 回有機分子構築法 夏の勉強会
湯河原, 2019 年 5 月
11) “Regioselective benzannulation of PAHs via rhenium-catalyzed deoxygenation of 7-oxabicyclo[2.2.1]hepta2,5-diene”
M. Murai, International Congress on Pure & Applied Chemistry (ICPAC)
Yangon, Myanmar, August, 201912) “酸素や水素の脱離を伴う官能基化芳香族化合物の触媒的な迅速合成”
村井征史, 第 8 回化学フロンティア研究会
有馬, 2019年 8月
13) “7員環と電荷の組み込みを設計戦略とする機能性色素の開発”
村井征史, 第 12 回化学フロンティア研究会
名古屋, 2023年10月
14) “Design and synthesis of key nonbenzenoid core units realizing near-infrared emission”
M. Murai, 2023 International IRCCS–IRTG–ILR Symposium on “New Horizons of Molecular Functions”
Nagoya, December, 2023

C．招待講演を除く口頭発表 (本人による主要学会での発表分のみ)
1)“アズレン骨格を有する新規共役ポリマー: 7員環連結によって発現する特異な刺激応答性”
村井征史, Craig J. Hawker, 第 23 回基礎有機化学討論会
京都, 2012 年 9 月

2)“Development of azulene-based novel -conjugated molecules: Enhancement of dipolar leading to uniquestimuli-responsiveness”
M. Murai, C. J. Hawker, 12th International Kyoto Conference on New Aspects of Organic Chemistry(IKCOC 12)
Kyoto, November, 20123)

“Bismuth(III)-catalyzed dehydrative etherification and thioetherification of phenolic hydroxy groups”
村井征史, 折口和希, 高井和彦, 第 61 回有機金属化学討論会
九州大学, 2014 年 9 月

4)“Iridium-catalyzed intermolecular dehydrogenative silylation of polycyclic aromatic hydrocarbons based on
the regio- and chemoselective C−H bond activation”
M. Murai, K. Takami, K. Takai, 第 62 回有機金属化学討論会
関西大学, 2015 年 9 月

5)“Regioselective benzoannulation of PAHs via the rhenium-catalyzed deoxygenation of 7-oxabicyclo[2.2.1]hepta-2,5-diene”
M. Murai, K. Takai, International Symposium on JST ACT-C Project ~Invention of -Electronic Organic
Molecules toward Electronic Energy Devices~
Okayama, July, 2017

6)

“Rhenium-catalyzed anti-Markovnikov addition reaction of carbon nucleophiles to unactivated terminal
acetylenes”
M. Murai, K. Takai, 14th International Kyoto Conference on New Aspects of Organic Chemistry (IKCOC

14)
Kyoto, November, 20187)

“Cyclization of 1,n-enynes and 5-alkynylketones initiated by the addition reaction of gem-dichromiomethane
reagents to alkynes”
M. Murai, R. Taniguchi, K. Takai, 第 66 回有機金属化学討論会
首都大学, 2019 年 9 月

8)“Silicon-bridged diazulenylmethyl cations as a -extended cationic motif to form J-aggregates withnear-infrared emission”
M. Murai, S. Yamaguchi, 15th International Symposium on Functional  Electron Systems (F-15)
Raleigh, USA, June, 2023

9)“カチオン性近赤外色素の設計と合成”
村井征史, 持続社会発展のための機能化学研究委員会 第 8 回定期研究会
東京, 2023年10月

10) “Alignment of azulene-based cationic -skeletons toward functional -materials”
M. Murai, 15th International Kyoto Conference on New Aspects of Organic Chemistry (IKCOC 15)
Kyoto, November, 2023
11) “Group 14 element-bridged cationic diazulenylmethenes forming J-aggregates with near-infrared emission”
M. Murai, S. Yamaguchi, 14th Japan-China Joint Symposium on Conduction and Photoconduction in
Organic Solids and Related Phenomena
Nagoya, December 2023
12) “Si, Ge, and Sn-bridged -conjugated carbocations: Azulene-fusing strategy for designing near-infrared dyes”
M. Murai, The 20th International Symposium on Silicon Chemistry (ISOS-2024)
Hiroshima, May 2024

D．解説記事1)“Photoinitated click reactions for the creation of spatially defined materials”
D. Miyajima, M. Murai, C. J. Hawker, Koubunshi, 61, 862−864 (2012), 高分子学会発行.

2)“Manchester大学Procter研究室(UK)とUCSB Hawker研究室(USA)での研究と留学生活”
村井征史, Organometallic News, 99−100 (2013), 近畿化学協会 有機金属部会発行.

3)“元素の個性の再探求による新反応の確立と新物質の創製”
村井征史, 化学 (3月号), 70, 61−62 (2015), 化学同人発行.

4)“電子供与性配位子としてのカルボジカルベンの化学”
村井征史, Organometallic News, 118 (2015), 近畿化学協会 有機金属部会発行.

5)“多環芳香族炭化水素の効率的な機能化法の開発 (飛翔する若手研究者欄)”
村井征史, 化学と工業 (11月号), 69, 981−982 (2016), 日本化学会発行.

6)“新たな視点から (インタビュー記事)”
村井征史, 現代化学 (11月号) (2023), 東京化学同人発行.

7)“ケイ素機能性化学：ケイ素を含むπ電子系の発展と展望”
村井征史, 山口茂弘, 化学 (4月号), 79, 35−37 (2024), 化学同人発行.

E．特許
1)

“多環芳香族化合物及びその製造方法”
村井征史, 伊場真志, 高井和彦, 特願 2014-47900 (Jpn. Kokai Tokkyo Koho (2015), JP 2015-172009 A
20151001).

2)“ニトロ基を有する9-シラフルオレン化合物及びその製造方法”
村井征史, 高井和彦, 特願 2018-209329.

3)“トロピリウム化合物及びそれを用いた蛍光色素”
村井征史, 伊藤優衣, 山口茂弘, 特願 2023-034651.

4)“カチオン性ホスホニウムで架橋したラダー型蛍光色素”
多喜正泰, 山口茂弘, 村井征史, 袴田綾人, 特願 2023

F．競争的資金の取得状況
1)

日本学術振興会 特別研究員奨励費 (DC2), 2008−2009年度, 研究代表者

2)

日本学術振興会 特別研究員奨励費 (PD), 2010−2012年度, 研究代表者

3)

岡山大学 若手研究者スタートアップ研究支援, 2013−2014年度, 研究代表者

4)

有機合成化学協会 ADEKA研究企画賞2014, 2014−2015年度, 研究代表者

5)

科学研究費補助金 若手(B), 2014−2015年度, 研究代表者

6)

科学研究費補助金 基盤(A), 2014−2017年度, 研究分担者

7)

岡山工学振興会 研究奨励賞, 2014−2015年度, 研究代表者

8)

公益財団法人ウエスコ学術振興財団 学術研究費助成, 2015−2016年度, 研究代表者

9)

岡山工学振興会 国際研究集会等派遣助成金, 2015年, 代表者

10) 住友財団2015年度基礎科学研究助成, 2015−2016年度, 研究代表者
11) 科学研究費補助金 基盤(C), 2016−2018年度, 研究代表者
12) 八雲環境財団 国際研究交流助成, 2017年, 代表者
13) 科学研究費補助金 基盤(A), 2018−2021年度, 研究分担者
14) 公益財団法人京都技術科学センター研究開発助成, 2019 年度, 研究代表者
15) 科学研究費補助金 基盤(B), 2019−2022年度, 研究代表者
16) 東京生化学研究会 研究奨励金 I, 2020年度, 研究代表者
17) 豊田理研スカラー, 2021年度, 研究代表者
18) 池谷科学技術振興財団 単年度研究助成A, 2021年度, 研究代表者
19) 総合工学振興財団 研究奨励金, 2021年度, 研究代表者
20) 立松財団 一般研究助成, 2022年度, 研究代表者
21) 科学研究費補助金 学術変革領域研究(A), 公募研究, 2023−2024年度, 研究代表者
22) 2023年度創発的研究支援事業, 2024年度~, 研究代表者