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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 18.02.2019

Version number 1

Revision: 18.02.2019

SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Trade name: DAIFLOIL no.1,3,10,20
Article number: DO
1.2 Relevant identified uses of the substance or mixture and uses advised against:
No further relevant information available.
1.3 Details of the supplier of the safety data sheet
Manufacturer/Supplier:
DAIKIN INDUSTRIES, LTD. CHEMICALS DIVISION:
Umeda Center Bldg., 4-12, Nakazaki-Nishi 2-chome, Kita-Ku, Osaka, JAPAN
Phone: (+81) 6-6373-4345 Fax: (+81) 6-6373-4281
Further information obtainable from: http://www.daikin.com/
1.4 Emergency telephone number:
Japan: +81-6-6349-7521
China: +86-512-5-232-0949, +86-21-34151689
South Korea: +82-2-568-1722
Americas: +1-256-306-5000
Europe: +49-211-179 225-0*

SECTION 2: Hazard identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
The substance is not classified, according to the CLP regulation.
2.2 Label elementsLabelling according to Regulation (EC) No 1272/2008: Not applicable
Signal word: Not applicable*SECTION 3: Composition/information on ingredients
Information on ingredients:
CAS: 9002-83-9 Polychlorotrifluoroethylene

100%SECTION 4: First aid measures
4.1 Description of first aid measures
General information: Seek medical treatment.
After inhalation: Supply fresh air; consult doctor in case of complaints.
After skin contact:
Remove contaminated clothes immediately.
Immediately wash with water and soap and rinse thoroughly.
Consult a doctor in case of complaints.
After eye contact:
Immediately rinse with a lot of water for several minutes. Remove contact lenses if possible. Continue rinsing.
Consult an ophthalmologist in case of complaints.
After swallowing:
Rinse mouth with water. Do not induce vomitting.
Consult a doctor in case of complaints.
4.2 Most important symptoms and effects, both acute and chronic: No further relevant information available.
4.3 Indication of any immediate medical attention and special treatment needed:
No further relevant information available.

SECTION 5: Firefighting measures
5.1 Extinguishing media
Suitable extinguishing agents: Use fire extinguishing methods suitable for surrounding conditions.
(Contd. on page 2)

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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 18.02.2019

Version number 1

Revision: 18.02.2019

Trade name: DAIFLOIL no.1,3,10,20(Contd. of page 1)

5.2 Special hazards arising from the substance or mixture:
Hydrogen chloride (HCl)Hydrogen fluoride (HF)
Formation of toxic gases is possible during heating or in case of fire.
5.3 Advice for firefighters:
Protective equipment:
Wear self-contained breathing apparatus and protective suit.
Do not inhale explosion gases or combustion gases.

SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures:
Ensure adequate ventilation before entering the area.
Stay on the windward side.
Keep out unauthorized persons.
Wear appropriate protective devices (See Section 8 Exposure Controls/Personal Protection).
Avoid contact with eyes and skin.
Do not swallow the product.
6.2 Environmental precautions: Prevent seepage into sewage system, workpits and cellars.
6.3 Methods and material for containment and cleaning up:
For a small amount of leakage: Absorb with liquid-binding material (sand, diatomite, acid binders, universalbinders) or collect in an empty container that can be sealed tightly.
For a large amount of leakage: Enclose with banks to avoid outflow. Lead the leakage to a safe place and collect.
6.4 Reference to other sections:
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.

SECTION 7: Handling and storage
7.1 Precautions for safe handling:
Ensure good ventilation/exhaustion at the workplace.
Do not handle until all safety precautions have been read and understood.
Information about fire - and explosion protection: Keep ignition sources away - Do not smoke.
7.2 Conditions for safe storage, including any incompatibilities:
Storage
Requirements to be met by storerooms and receptacles:
Store in a cool and dry location.
Keep containers tightly sealed.
Information about storage in one common storage facility:
Store away from oxidising agents.
See section 10 for information on incompatible materials.
Further information about storage conditions:Protect from heat and direct sunlight.
Store containers in a well ventilated area.
Store locked up.
7.3 Specific end use(s): No further relevant information available.

SECTION 8: Exposure controls/personal protection
Additional information about design of technical facilities: No further data; see item 7.
8.1 Control parameters No further information available.
Ingredients with limit values that require monitoring at the workplace: Not required.
Additional information: The lists valid during the making were used as basis.
(Contd. on page 3)

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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 18.02.2019

Version number 1

Revision: 18.02.2019

Trade name: DAIFLOIL no.1,3,10,20(Contd. of page 2)

8.2 Exposure controls
Personal protective equipment
General protective and hygienic measures:
Wash hands before breaks and at the end of work.
Do not eat or drink while working.
Keep away from tobacco products.
Respiratory protection:
Use respiratory protective device with filters for organic and acid gas (or airline respirators in some cases), if theproduct is heated above 100 ℃ and toxic gases is formed.
Use respiratory protective device with organic gas cartridge.
Protection of hands:
Synthetic rubber gloves
Protective glovesMaterial of gloves: Rubber
Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed.
Eye protection:
Safety glasses
Body protection: Protective work clothing

SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
General Information
Appearance
LiquidForm:
Clear colorless - light yellow
Colour:OdourlessOdour:
No further information available.
pH-value:No further information available.
Melting point/freezing point:
Initial boiling point and boiling range: No further information available.
Flash point:

Not applicable.

Explosion limits:
Lower explosive limit:
Upper explosive limit:

No further information available.
No further information available.

Vapour pressure:No further information available.

Density:

No further information available.

Solubility in / Miscibility withwater:

No further information available.

Partition coefficient: n-octanol/water: No further information available.
No further relevant information available.
9.2 Other information:

SECTION 10: Stability and reactivity
10.1 Reactivity No further relevant information available.
(Contd. on page 4)

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Page 4/6Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 18.02.2019

Version number 1

Revision: 18.02.2019

Trade name: DAIFLOIL no.1,3,10,20(Contd. of page 3)

10.2 Chemical stability
Thermal decomposition / conditions to be avoided: To avoid thermal decomposition do not overheat.
10.3 Possibility of hazardous reactions: No dangerous reactions known under normal conditions of use.
10.4 Conditions to avoid: Keep away from heat, sparks, flame, high temperature.
10.5 Incompatible materials: No further relevant information available.
10.6 Hazardous decomposition products: Danger of toxic fluorine based pyrolysis products.

SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity Based on available data, the classification criteria are not met.
LD/LC50 values relevant for classification: No further information available.
Primary irritant effectSkin corrosion/irritation No further information available.
Serious eye damage/irritation No further information available.
after inhalation: No further information available.
Respiratory or skin sensitisation Based on available data, the classification criteria are not met.
Additional toxicological information:
General effects:
Fumes generated during burning may cause "polymer fume fever" (flu-like symptons such as fever, chill, cough).
This may last for a whole day and night.
Fumes are not absorbed in skin. No sensitizing effect known.
Effects of hydrogen fluoride:
Low concentration of hydrogen fluoride may cause feeling of dyspnea, cough, irritation in eyes, nose, throat, fever,chill for 1-2 days.
After that, dyspnea, cyanosis and pulmonary edema may be seen.
High concentration of hydrogen fluoride damages liver and kidney.
Effects of carbonyl fluoride:
Skin: Irritation or eruption
Eye: Ulcer in cornea, conjunctiva
Respiratory system: Irritation
Lung: Temporary symptons such as cough, pain, dyspnea
Persons who have experienced lung diseases are vulnerable to toxicity caused by excessive exposure to pyrolysis
products
CMR effects
Carcinogenicity Based on available data, the classification criteria are not met.
Reproductive toxicity Based on available data, the classification criteria are not met.
STOT-single exposure Based on available data, the classification criteria are not met.
STOT-repeated exposure Based on available data, the classification criteria are not met.
Aspiration hazard Based on available data, the classification criteria are not met.
Chronic study No further information available.

SECTION 12: Ecological information
12.1 Toxicity
Aquatic toxicity: No further relevant information available.
12.2 Persistence and degradability: No further relevant information available.
Other information: The product is insoluble in water and the biodegradation and ecotoxicity is expected to be low.
12.3 Bioaccumulative potential: No further relevant information available.
12.4 Mobility in soil: No further relevant information available.
12.5 Results of PBT and vPvB assessment
PBT:
No further relevant information available.
Not applicable.
(Contd. on page 5)

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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 18.02.2019

Version number 1

Revision: 18.02.2019

Trade name: DAIFLOIL no.1,3,10,20(Contd. of page 4)

vPvB:
No further relevant information available.
Not applicable.
12.6 Other adverse effects: No further relevant information available.

SECTION 13: Disposal considerations
13.1 Waste treatment methods
Recommendation: Disposal must be made according to official regulations.
Uncleaned packaging
Recommendation: Disposal must be made according to official regulations.

SECTION 14: Transport information
14.1 UN-Number:
ADR, ADN, IMDG, IATA
14.2 UN proper shipping name:
ADR, ADN, IMDG, IATA
14.3 Transport hazard class(es):Not applicableNot applicable

ADR, ADN, IMDG, IATA
Not applicable
Class:
14.4 Packing group:
Not applicable
ADR, IMDG, IATA
14.5 Environmental hazards:
NoMarine pollutant:
Not applicable.
14.6 Special precautions for user:
14.7 Transport in bulk according to Annex II ofNot applicable.
MARPOL73/78 and the IBC Code:
Avoid direct sunlight. Make sure of no damage, corrosion, leaks on
Transport/Additional information:
the receptacles.
Take necessary measures for preventing cargo shift.
Not applicable
UN "Model Regulation":*SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
No further relevant information available.
Labelling according to Regulation (EC) No 1272/2008 Not applicable
Hazard pictograms Not applicable
Signal word Not applicable
Hazard statements Not applicable15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

SECTION 16: Other information
The product is for the industrial use only. We do not guarantee the safety in case the product is used for the otherpurposes. When using the product for health-care application or food/feed application, consult us in advance.
This information is based on our present knowledge. However, this shall not constitute a guarantee for any specificproduct features and shall not establish a legally valid contractual relationship.
Department issuing SDS: EHS DepartmentContact: http://www.daikin.com/
Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriageof Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
LC50: Lethal concentration, 50 percent(Contd. on page 6)48.0

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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 18.02.2019

Version number 1

Revision: 18.02.2019

Trade name: DAIFLOIL no.1,3,10,20(Contd. of page 5)
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative* Data compared to the previous version altered.