ᄢಽᄢቇᢎ⢒⑔␩⑼ቇㇱ⎇ⓥ♿ⷐ㧔Res. Bull. Fac. Educ.䋧Welf. Sci., Oita Univ.䋩

43ࡉ࡯࠲ࡦߦ߅ߌࠆᄤὼᨴ⦡̆࡜࠶ࠢ㧘ࠕࠞࡀߦࠃࠆᨴ⦡̆ㇺ ↲ ↱ ♿ ሶ㧖࡮㚤 ၔ ⚛ ሶ㧖㧖‫ ⷐޣ‬ᣦ‫₺ࡦ࠲࡯ࡉ  ޤ‬࿖ߦ߅޿ߡᄤὼᨴ⦡ߩ⺞ᩏࠍⴕߞߚ‫ࠢ࠶࡜ޕ‬㧘ࠕࠞࡀߦࠃࠆᨴ⦡ߩᣇᴺߣ㧘ߎࠇࠄߩᄤὼᨴᢱ߆ࠄ᛽಴ߐࠇߚ⦡⚛ߩ⟠Ძ࡮⛚࡮✎ߦኻߔࠆᨴ⦡ᕈࠍ⺞ߴߚ‫ޕ‬ᨴ⦡ᣇᴺߪ㧘ߘࠇߙࠇߩ᧚ᢱ߆ࠄ᳓ߢ⦡⚛
ࠍ᛽಴ߒߚᶎߦ㧘޽ࠄ߆ߓ߼ࠢࡠࡒࡁ࠾ࠪࠧ࡝ߦࠃࠅಣℂ(ਅᨴ߼)ࠍߒߡ߅
޿ߚⵍᨴ‛ࠍ౉ࠇ㧘85͠ߢ 10 ಽᨴ⦡ߒߡߘߩ߹߹᡼⟎ߒߡ಄߹ߒ㧘ߔߔ޿ߢ⛉ߞߚᓟ㧘ੇ῎ߐߖࠆߣ޿߁ᚻ㗅ߢ޽ߞߚ‫ߩࠄߜߤޕ‬ᨴᢱߣ߽⟠Ძߣ⛚ߦߟ޿ߡߪ೨ಣℂ߿ᇦᨴߖߕߦࠃߊᨴ߹ߞߚ߇㧘ᤴߒ✎ߪ߶ߣࠎߤᨴ߹ࠄߥ߆ߞߚ‫ࡦࠝ࠴ࠞߚ߹ޕ‬ൻ೷㧔3-Chloro-2-hydroxypropyltrimethylammoniumChloride㧕ߦࠃࠅỚᨴಣℂࠍߒߚ✎ߣ㧘࠲ࡦ࠾ࡦ㉄࡮㈶㉄ࠕ࡞ࡒ࠾࠙ࡓ೨ಣ
ℂࠍߒߚ✎ߪਅᨴ߼ߦࠃࠅᨴ߹ߞߚ߇㧘ߘࠇߙࠇ⦡๧߇⇣ߥߞߡ޿ߚ‫ޕ‬‫₺ࡦ࠲࡯ࡉ ޤ࠼࡯ࡢ࡯ࠠޣ‬࿖ ᄤὼᨴ⦡ ࡜࠶ࠢ ࠕࠞࡀ1. ߪߓ߼ߦࠗࡦ࠼ߣਛ࿖ߩ㑆㧘ࡀࡄ࡯࡞ࠃࠅ᧲ߦࡉ࡯࠲ࡦ₺࿖ߣ޿߁࿖߇޽ࠆ‫ޕ‬࿖࿯ߪ਻Ꮊ߶ߤߩ㕙Ⓧߢ޽ࠅ㧘66 ਁੱ߶ߤߩ࿖᳃߇૑ࠎߢ޿ࠆ‫ޕ‬࿖᳃ߩᄙߊߪ⥄૞ㄘߢᢘ⯩ߥ࠴ࡌ࠶࠻੽ᢎᓤߢ޽ࠅ㧘⽻ᐊ⚻ᷣߢߪߪ߆ࠇߥ޿⼾߆ߐࠍᜬߜ㧘ਇᕁ⼏ߥᢥൻࠍ⛮ᛚߒߡ޿ࠆ࿖ߢ޽ࠆ‫ࡦ࠲࡯ࡉޕ‬ߪ⥄࿖ᢥൻߩሽ⛯ߩߚ߼㐽㎮⊛ߥ᡽ᴦ૕೙ߩਅߢㄭઍൻ౮⌀ 1 ᳃ᣖ⴩ⵝࠍㄫ߃ߡ޿ࠆ␠ળߢ޽ࠅ㧘ᄖ࿖ੱߩ⸰໧⠪ᢙ߽೙㒢ߐࠇߡ޿ࠆ‫ޕ‬વ⛔⊛ߥ᦯㘼ᢥൻ߿ᨴ❱ᛛⴚߩ⛮ᛚࠍ⋡⊛ߣߒߡ㧘⃻࿷߽ࡉ࡯࠲ࡦߢߪ౏ߩ႐ᚲߦ߅ߌࠆ᳃ᣖ⴩ⵝߩ⌕↪߇࿖᳃ߦ⟵ോઃߌࠄࠇߡ޿ࠆ‫↵ޕ‬ᕈߪࠧߣ޿߁๺᦯ߦૃߚ⴩ⵝ㧘ᅚᕈߪࠠ࡜ߣ޿߁Ꮞ⴩ࠍりߦ߹ߣߞߡ޿ࠆ‫ޕ‬ሶߤ߽ߚߜߪ᳃ᣖ⴩ⵝߩ೙᦯ࠍ⌕ߡㅢቇߒߡ޿ࠆ‫ઁޕ‬࿖ߢᨴ߼ߚ♻ࠍ૶ߞߡࡉ࡯࠲ࡦߢ❱ࠆߣ޿߁ߎߣ߿㧘ᯏ᪾❱ߩャ౉ຠߩᏓࠍ૶߁ߎߣ߽ᄙߊߥߞߡ޿ࠆ߇㧘੹ߥ߅․ߦ᧲ࡉ࡯࠲ࡦߢᏓߩᨴ❱߇ߐ߆ࠎߢߘߩᛛⴚࠍવ߃ߡ޿ࠆ  㧘 ‫ޕ‬ᨴ⦡ߦᄤὼ‛ࠍ᦭ലߦ೑↪ߒߡ߈ߚવ⛔߇⃻ઍߦ߅޿ߡ߽⛯޿ߡ߅ࠅ㧘ᭂ߼ߡ⥝๧ᷓ޿߽ߩߢ޽ࠆ‫ޕ‬
ᐔᚑ 22 ᐕ 11 ᦬ 22 ᣣฃℂ㧖ߣߏ߁࡮ࠁ߈ߎ ᄢಽᄢቇᢎ⢒⑔␩⑼ቇㇱ↢ᵴ࡮ᛛⴚ⻠ᐳ㧔ኅᐸ⑼ᢎ⢒ቇⵍ᦯ಽ㊁㧕㧖㧖ߎ߹߈࡮߽ߣߎ ߅⨥ߩ᳓ᅚሶᄢቇฬ⹷ᢎ᝼

44ㇺ ↲࡮㚤 ၔ2008 ᐕߣ 2009 ᐕߩੑᐲߦࠊߚࠅࡉ࡯࠲ࡦࠍ⸰ࠇߡᄤὼᨴ⦡ߦߟ޿ߡࡈࠖ࡯࡞࠼⺞ᩏࠍⴕ߁ᯏળࠍ޿ߚߛ޿ߚ‫ޕ‬2008 ᐕߦߪ࡜ࡦࠫࡘࡦ᧛ߩ࠽ࡓࠥࠗ࡮ࡍ࠺ࡦ᳁߇ᨴ⦡ߒߡ޿ࠆߣߎࠈࠍ⷗ቇߒ㧘ࡗ࠺ࠖ᧛ߣࡗ࡙ࡓ᧛ߦߡ࡜࠶ࠢ↢↥ߩߚ߼ߦ࡜࠶ࠢࠞࠗࠟ࡜ࡓࠪࠍ㙃ᱺߒߡ޿ࠆ᭽ሶࠍ⺞ᩏߒߚ 3)㧘4)‫ޕ‬2009 ᐕߦߪࡉࡓ࠲ࡦߩ࡟ࠠ࡮ࠝࡦࡕ᳁ߩᎿᚱߦߡ⺞ᩏࠍⴕߞߚ‫ᧄޕ‬ႎߦߪࡉࡓ࠲ࡦߢ⺞ᩏߒߚᨴ⦡ᣇᴺߣታ㛎ߩߚ߼ᜬෳߒߚᏓߩᨴ⦡⚿ᨐࠍႎ๔ߔࠆ‫ޕ‬䊑䊛䉺䊮ਛ࿖䊟䊂䉞᧛䊟䊡䊛᧛䉟䊮䊄䊤䊮䉳䊠䊮᧛࿑ 1 ࡉ࡯࠲ࡦߩ࿾࿑ 㧔⿒ߩ⍫ශߪ 2008 ᐕߩⴕ⒟‫ޕ‬2009 ᐕߪࡉࡓ࠲ࡦ߹ߢⴕߞߡᒁ߈㄰ߒߚ‫ޕ‬㧕 http://www.mofa.go.jp/mofaj/gaiko/oda/shiryo/hyouka/kunibetu/gai/buutan/pdfs/kn06_01_0002.pdf

2. ࡉ࡯࠲ࡦߦ߅ߌࠆᨴ⦡ᣇᴺ
2.1 ࠢࡠࡒࡁ࠾ࠪࠧ࡝ߦࠃࠆਅᨴ߼ ࡜ ࠶ ࠢ ߿ ࠕ ࠞ ࡀ ߢ ᨴ ⦡ ࠍ ⴕ ߁ 㓙 ߦ ߪ 㧘 ⵍ ᨴ ‛ ࠍ ೨ ߽ ߞ ߡ ࠢ ࡠ ࡒ ࡁ ࠾ ࠪ ࠧ ࡝ Symplocos
paniculata㧔⃻࿾ฬ㧦࠯ࡓ㧕ߢਅᨴ߼ߔࠆ‫ߣ⪲ߩ࡝ࠧࠪ࠾ࡁࡒࡠࠢޕ‬᳓ࠍ㍿ߦ౉ࠇ㧘Ἣߦ߆ߌߡᾚߡ㤛⦡ߩ⦡⚛ࠍ᛽಴ߔࠆ‫৻ࠍ⪲ޕ‬ᐲขࠅ಴ߒ㧘ⵍᨴ‛㧔⃻࿾ߢߪ⛚♻㧕ࠍ౉ࠇߡ਄߆ࠄవߦขࠅ಴ߒߚ⪲ࠍ߆߱ߖࠆࠃ߁ߦ౉ࠇࠆ‫ޕ‬10 ಽ߶ߤᾚߚࠄߘߩ߹߹಄߹ߒ㧘♻ࠍขࠅ಴ߒߡ᳓
ᵞ޿ߒߡੇ῎ߐߖࠆ㧔౮⌀ 2㧕‫ޕ‬

2.2 ࡜࠶ࠢߦࠃࠆᨴ⦡ ࡜࠶ࠢߪ㧘ࠞࠗࠟ࡜ࡓࠪ⑼࡜࠶ࠢࠞࠗࠟ࡜ࡓࠪ Coccus cacti LINNE ߇ಽᴲߔࠆ᮸⢽⁁ߩ‛⾰߆ࠄ᛽಴ߐࠇࠆ⦡⚛ߢ޽ࠅ㧘࡜࠶ࠢࠞࠗࠟ࡜ࡓࠪߪࡂ࠽ࡕ࠷ࡗࠢࡁࠠ߿ࠗࡦ࠼࠽࠷ࡔߩᧁߥߤߦ↢ᕷߒ㧘ਛ࿖ධㇱ㧘ࠗࡦ࠼㧘᧲ධࠕࠫࠕߢណ㓸ߐࠇࠆ 5)㧘 6)㧘 7)‫ޕ‬ዊᨑ߆ࠄขࠅᄖߒߚ߽ߩࠍࠬ࠹ࠖ࠶ࠢ࡜࠶ࠢ㧘ߘࠇࠍ᳓ᵞ࡮ੇ῎ߒߚ߽ߩࠍࠪ࡯࠼࡜࠶ࠢ㧘ߐࠄߦ᮸⢽ߛߌࠍขࠅ಴ߒߚ߽ߩࠍࠪࠚ࡜࠶ࠢߣ޿߁‫ߡ޿߅ߦ᧛ࡓ࡙ࡗߣ᧛ࠖ࠺ࡗߪߡ޿߅ߦࡦ࠲࡯ࡉޕ‬ᮡ㜞Ꮕߦࠃࠆ᳇୥ߩ㆑޿ࠍ೑↪ߒߡ㧘࡜࠶ࠢࠞࠗࠟ࡜ࡓࠪࠍ㙃ᱺߒߡ࡜࠶ࠢࠍ↢↥ߒߡ޿ࠆ㧟㧕‫ޕ‬ࡉ࡯࠲ࡦߦ߅ߌࠆᄤὼᨴ⦡45࡜࠶ࠢߩ⿒⦡♽ߩ⦡⚛ᚑಽߪ㧘࡜࠶ࠞࠗࡦ㉄ߢ޽ࠆ‫ޕ‬࿑ 1 ߦ␜ߔߣ߅ࠅ࡜࠶ࠞࠗࡦ㉄ߦߪ஥㎮ߦࠃࠅᢙ⒳㘃ߩ᭴ㅧ߇ሽ࿷ߔࠆ‫ ㉄ࡦࠗࠞ࠶࡜ߦࠢ࠶࡜ߩ↥ࠗ࠲ޕ‬A㧘B ෸߮ C ߇ሽ࿷ߔࠆߎߣ߇⏕⹺ߐࠇߡ޿ࠆ 8)‫ޕ‬D㧘E ߩሽ࿷߽⍮ࠄࠇߡ޿ߚ߇㧘ߐࠄߦ࡜࠶ࠞࠗࡦ㉄ F ߩන㔌㧘᭴ㅧ᳿ቯ߽ߥߐࠇߡ޿ࠆ 9)㧔࿑ 2㧕‫ޕ‬⠴ᾲ㧘⠴శᕈߪ㜞ߊ㧘᛽಴ᶧߩ⦡⺞ߪ pH ߦࠃߞߡ⇣ߥࠅ㧘㉄ᕈߢߪᯍ⦡㧘ਛᕈߢ⿒⦡㧘ࠕ࡞ࠞ࡝ᕈߢߪ⿒⚡⦡ࠍ๒ߔࠆ‫ޕ‬࿑㧞 ࡜࠶ࠞࠗࡦ㉄ߩൻቇ᭴ㅧ㧔C.I. Natural Red 25㧘C.I. 75450㧕
Laccaic acid A, B, C, E, F㩷 㩷 㩷 㩷 㩷 㩷 㩷 㩷 㩷 㩷 㩷 Laccaic acid D
A: R = CH2CH2NHCOCH3

㩷 E: R = CH2CH2NH2

B: R = CH2CH2OH

F: R = CH2CH2OCOCH3

C: R = CH2CH(NH2)COOH࡜࠶ࠢ㧔⃻࿾ฬ㧦ࠫࡖ࠷ࠜ㧕ߩ⦡⚛᛽಴ᣇᴺߪᰴߩߣ߅ࠅߢ޽ࠆ㧔౮⌀ 3㧙8㧕‫ޕ‬Ԙࠬ࠹ࠖ࠶ࠢ࡜࠶ࠢࠍ᳓ߦᶐẃߐߖߚ߹߹৻᥅߅޿ߡߑࠆߢߎߔ‫ޕ‬ԙࠬ࠹ࠖ࠶ࠢ࡜࠶ࠢࠍ౉ࠇߚࡃࠤ࠷ߦ 45͠ߩḡࠍᵈ߉㧘ᠣᜈߒߥ߇ࠄ᫔ߢ࡜࠶ࠢࠍ⎈ߊ‫ޕ‬Ԛߑࠆߢߎߒߡ⦡⚛᛽಴ᶧߣ࿕ᒻಽߦಽߌࠆ‫ޕ‬ԛԙߣԚࠍ 13 ࿁➅ࠅ㄰ߔ‫ޕ‬ḡߩ᷷ᐲߪᓢ‫ߦޘ‬਄ߍߡ޿߈㧘6 ࿁⋡એ㒠ߪ 75͠㧘10 ࿁⋡એ㒠
ߪ 80͠ࠍ⿥߃ࠆ᷷ᐲߩḡࠍട߃ߡ᛽಴ߔࠆ‫ޕ‬1 ࿁⋡᛽಴ᶧ߆ࠄ 13 ࿁⋡᛽಴ᶧ߹ߢ㧘ߔߴߡࠍวࠊߖߡᏓߢߎߒߡᨴᶎߣߒߚ‫ޕ‬Ԝᦨ⚳᛽಴ߩߣ߈ߦߪ㧘࡜࠶ࠢߩ᮸⢽ಽ㧔ࠪࠚ࡜࠶ࠢ㧕߇☼ᕈߩ޽ࠆ‛⾰ߦߥࠆߩߢ㧘ߘࠇࠍᾲ޿߁ߜߦ᫔⁁ߦᚑᒻߒ㧘಄߹ߒߡ࿕߼ࠆ‫ޕ‬᛽಴⦡⚛ߦࠃࠆᨴ⦡ߪᰴߩࠃ߁ߦⴕߞߡ޿ߚ‫ޕ‬Ԙ ᛽಴ᶧࠍ㍿ߦ౉ࠇᴣ㛛ߐߖࠆ‫ޕ‬ԙ ੇ῎ߐߖߚࡏࠤߩታ㧔⃻࿾ฬ㧦ࠦࡑࡦ㧕ࠍ᳓ߢᚯߒߚ߽ߩࠍ౉ࠇߡ㧘pH3 ⒟ᐲߦᨴᶎࠍ⺞⵾ߔࠆ‫ޕ‬
Ԛ ࠯ࡓߢਅᨴ߼ߒߚ♻߿Ꮣࠍ౉ࠇ㧘➅ࠅߥ߇ࠄ 85͠ߢ 10 ಽ߶ߤᾚߚࠄߘߩ߹߹಄߹ߒ㧘♻
߿Ꮣࠍขࠅ಴ߒߡ᳓ᵞ޿ߒߡੇ῎ߐߖࠆ‫ޕ‬ᮡ㜞߇㜞޿ߚ߼㧘85͠ߢ߶߷ᴣ㛛⁁ᘒߦㄭ޿᷷
ᐲߢ޽ࠆ‫ޕ‬2008 ᐕߦ࡜ࡦࠫࡘࡦ᧛ߢ⷗ቇߒߚ࡜࠶ࠢߩ᛽಴ᣇᴺ㧘᛽಴ᶧߦࠃࠆᨴ⦡ᣇᴺߣ߶߷หߓᣇᴺ
ߢࡉࡓ࠲ࡦߢ߽࡜࠶ࠢߩ᛽಴ߣᨴ⦡ࠍߒߡ޿ࠆߎߣ߇ࠊ߆ߞߚ‫ޕ‬᛽಴ߩ㓙㧘ḡߩ᷷ᐲ਄᣹ㅦᐲ
߇✭߿߆ߢ޽ࠅ㧘➅ࠅ㄰ߒߩ࿁ᢙ߇ 5 ࿁ಽჇ߃ߡ޿ߚὐ߇⇣ߥߞߡ޿ߚ‫ޕ‬

46ㇺ ↲࡮㚤 ၔ

2.3 ࠕࠞࡀߦࠃࠆᨴ⦡ ࠕࠞࡀߦߪ㧘࠾ࡎࡦࠕࠞࡀ Rubia akane Nakai㧔ᣣᧄ߆ࠄ᧲ධࠕࠫࠕ㧘ࡅࡑ࡜ࡗߦ߆ߌߡᐢߊಽᏓ㧕㧘ࠗࡦ࠼ࠕࠞࡀ Rubia cordifolia Linn.㧔ਛ࿖㧘ࡅࡑ࡜ࡗ㧘ࠕࡈࠟ࠾ࠬ࠲ࡦߦಽᏓ㧕㧘࠮࡛ࠗ࠙ࠕࠞࡀ㧔౐⪲⨒㧕Rubia tinctorum L.㧔࿾ਛᶏᴪጯ߇ේ↥࿾㧕ߥߤߩ⒳㘃߇޽ࠆ‫࡯ࡉޕ‬࠲ࡦߦ߅޿ߡߪ㔀⨲ߦ੤ߓߞߡࠗࡦ࠼ࠕࠞࡀ߇↢⢒ߒߡ߅ࠅ㧘ߎߩᩮߣ⨍ࠍᨴ⦡ߦ૶߁㧔౮⌀
9㧕‫ߩࡀࠞࠕޕ‬ਥⷐ⦡⚛ᚑಽߪ㧘ࠕ࡝ࠩ࡝ࡦ㧘ࡊ࡞ࡊ࡝ࡦ㧘ࡊ࠰ࠗ࠼ࡊ࡞ࡊ࡝ࡦ㧘ࡓࡦࠫࠬ࠴ࡦ
ߢ޽ࠆ㧔࿑ 3㧕‫㉄ࡦࠗࠞ࠶࡜ߩ᧪↱⯻ޕ‬㧘ᬀ‛↱᧪ߩࠕࠞࡀߩ⦡⚛ߪߤߜࠄ߽⿒♽ߩ⦡⚛ߢࠕࡦ࠻࡜ࠠࡁࡦߩ㘃ૃߩ᭴ㅧࠍߒߡ߅ࠅ㧘ߘࠇࠄࠍਔᣇ೑↪ߒߡ޿ࠆߣ޿߁ߎߣߦߥࠆ‫ޕ‬

࿑ 3 ࠕࠞࡀߩ⦡⚛ᚑಽߩൻቇ᭴ㅧ
 (a)ࠕ࡝ࠩ࡝ࡦ 㧔C.I. Natural Red 8㧘C.I. 75330㧕 (b)ࡊ࡞ࡊ࡝ࡦ㧔C.I. 75410㧕
 (c)ࡊ࠰ࠗ࠼ࡊ࡞ࡊ࡝ࡦ㧔C.I. 75420㧕 (d)ࡓࡦࠫࠬ࠴ࡦ㧔C.I. 75370㧕

ࠕࠞࡀ㧔⃻࿾ฬ㧦࠷ࠚ࡯㧕ߦࠃࠆᨴ⦡ᣇᴺߪᰴߩߣ߅ࠅߢ޽ࠆ㧔౮⌀ 10㧕‫ޕ‬Ԙ ࠕࠞࡀߩᩮߣ⨍ࠍ⚦߆ߊߒߡ߅ߊ‫ޕ‬ԙ ࠕࠞࡀࠍ᳓ߦᶐẃߐߖ㧘Ἣߦ߆ߌߡࠃߊᾚߡ⦡⚛ࠍ᛽಴ߔࠆ‫ޕ‬Ԛ ࠕࠞࡀࠍ಴ߒߡ♻߿Ꮣࠍ౉ࠇ㧘ขࠅ಴ߒߚࠕࠞࡀࠍ਄߆ࠄ߆߱ߖࠆࠃ߁ߦߔࠆ‫ޕ‬ԛ ➅ࠅߥ߇ࠄ 85͠ߢ 10 ಽ߶ߤᾚߚࠄߘߩ߹߹಄߹ߒ㧘♻߿Ꮣࠍขࠅ಴ߒߡ᳓ᵞ޿ߒߡੇ῎ߐ
ߖࠆ‫ޕ‬

47

ࡉ࡯࠲ࡦߦ߅ߌࠆᄤὼᨴ⦡

౮⌀ 3 ᳓ߦᶐẃߒߚࠬ࠹ࠖ࠶ࠢ࡜࠶ࠢ

౮⌀ 2 ࠢࡠࡒࡁ࠾ࠪࠧ࡝ߦࠃࠆਅᨴ߼

౮⌀ 4 ᳓ߦᶐẃߒߚࡏࠤߩታ

౮⌀ 5 ࡜࠶ࠢ᛽಴㧔1 ࿁⋡㧕ߩᓟ㧘ߑࠆߢߎߔ

౮⌀ 6 ࡜࠶ࠢ᛽಴㧔13 ࿁⋡㧕ߩᓟ㧘ᱷߞߚ᮸⢽ಽ

48

ㇺ ↲࡮㚤 ၔ౮⌀ 7 ᮸⢽ಽ㧔ࠪࠚ࡜࠶ࠢ㧕ࠍ࿕߼ߚ߽ߩ౮⌀ 9 ࠗࡦ࠼ࠕࠞࡀ౮⌀ 8 ࡜࠶ࠢᨴ⦡

౮⌀ 10 ࠕࠞࡀᨴ⦡

49ࡉ࡯࠲ࡦߦ߅ߌࠆᄤὼᨴ⦡

3. ᨴ⦡⚿ᨐ⃻࿾ߢߪ⛚♻ࠍᨴ߼ߡ޿ߚ߇㧘ታ㛎ߩߚ߼ߦᜬෳߒߚ⟠Ძ࡮⛚࡮Ớᨴಣℂ✎࡮࠲ࡦ࠾ࡦ㉄࡮㈶㉄ࠕ࡞ࡒ࠾࠙ࡓಣℂ✎ࠍ৻✜ߦᨴ⦡ߒߡ߽ࠄߞߚ‫⚿ߩߘޕ‬ᨐ߇⴫㧝ߢ޽ࠆ‫ࠢ࠶࡜ޕ‬㧘ࠕࠞࡀߣ߽ߦᦨ߽ࠃߊᨴ߹ߞߚߩߪ⟠Ძߢ޽ࠅ㧘ᰴߦ⛚ߢ޽ߞߚ‫ޕ‬ᤴߒ✎ߪߘߩ߹߹ߢߪ߶ߣࠎߤᨴ
߹ࠄߕ㧘ࠞ࠴ࠝࡦൻ೷㧔3-Chloro-2-hydroxypropyltrimethylammonium Chloride㧕ߦࠃࠅỚ
ᨴಣℂߒߚ߽ߩߣ࠲ࡦ࠾ࡦ㉄࡮㈶㉄ࠕ࡞ࡒ࠾࠙ࡓಣℂߒߚ߽ߩࠍᨴ⦡ߒߚ⚿ᨐ㧘⭯޿⦡ߢߪ޽ࠆ߇⌕⦡ߒߡߘࠇߙࠇ⦡๧߇⇣ߥߞߡ޿ߚ‫ޕ‬⴫ 1 ࡜࠶ࠢ㧘ࠕࠞࡀߦࠃࠆᲫ㧘⛚㧘✎ߩᨴ⦡⚿ᨐ
⟠Ძ⛚

Ớᨴಣℂ✎

࠲ࡦ࠾ࡦ㉄
࡮㈶㉄ Al ಣℂ✎࡜࠶ࠢࠕࠞࡀ

㧔ߔߴߡࠢࡠࡒࡁ࠾ࠪࠧ࡝ߩਅᨴ߼ࠍߒߡ޿ࠆ‫ޕ‬㧕

4. ߹ߣ߼ࡉ࡯࠲ࡦߦ߅ߌࠆ⿒⦡♽ᄤὼᨴᢱߦࠃࠆᨴ⦡ߦߟ޿ߡႎ๔ߒߚ‫ߣ⚛⦡ߪࠢ࠶࡜ޕ‬᮸⢽ಽࠍಽ㔌ߒߡ߆ࠄ⦡⚛ṁᶧߩᣇߢᨴ⦡ࠍⴕ޿㧘ࠕࠞࡀߪ⦡⚛᛽಴ߒߚᨴᶎߦⵍᨴ‛ࠍ౉ࠇ㧘᛽಴ߣᨴ⦡ࠍหᶎߢⴕ߁ᣇᴺࠍߣߞߡ޿ߚ‫ߩࡀࠞࠕߣࠢ࠶࡜ޕ‬ਔᣇߣ߽⟠Ძߣ⛚ߦߟ޿ߡߪࠃߊᨴ߹ߞߚ߇㧘ᤴߒ✎ߦߪ೨ಣℂߥߒߢߪ߶ߣࠎߤᨴ߹ࠄߥ߆ߞߚ‫ࡦࠝ࠴ࠞޕ‬ൻ೷ߦࠃࠅỚᨴಣℂࠍߒߚ✎ߣ࠲ࡦ࠾ࡦ㉄࡮㈶㉄ࠕ࡞ࡒ࠾࠙ࡓ೨ಣℂࠍߒߚ✎ߪᨴ߹ߞߚ߇㧘ߘࠇߙࠇ⦡๧߇⇣ߥߞߡ޿ߚ‫ࠢ࠶࡜ޕ‬㧘ࠕࠞࡀߩઁߦߪ࡝ࡘ࠙ࠠࡘ࠙ࠕࠗ߿࠙ࠦࡦ㧘ࠢ࡞ࡒ㧘࠻࠙࠳ࠗࠣࠨࠍᨴ⦡ߦ↪
޿ߡ޿ࠆߣߩߎߣߢ޽ߞߚ‫ߩઁߪࡦࠦ࠙߿⮣ޕ‬ᨴᢱߣ⦡⚛ߩᨴ⌕ᯏ᭴߇⇣ߥࠆߚ߼ᨴ⦡ᣇᴺ߽⇣ߥࠆߩߢ㧘ߘߩᨴ⦡ᣇᴺߦߟ޿ߡ߽੹ᓟ⺞ᩏߒߚ޿‫ޕ‬⻢ㄉ ࡉ࡯࠲ࡦ߳ߩ⺞ᩏ⎇ⓥߪ㧘2008 ᐕᐲ߅⨥ߩ᳓ᅚሶᄢቇᄢቇ㒮ඳ჻ᓟᦼ⺖⒟࿷ቇ↢ߦኻߔࠆ‫ޟ‬ᅚᕈ࡝࡯࠳࡯⢒ᚑࡊࡠࠣ࡜ࡓ‫ࠆࠃߦޠ‬ᡰេ㧘߅ࠃ߮㧘2009 ᐕᐲ․೎ᢎ⢒⎇ⓥ⚻⾌‫ߩޠࠬࡦࠛࠗࠨߩ⦡ޟ‬ಽᜂ⚻⾌ߦࠃࠅታᣉߢ߈ߚߎߣߦᗵ⻢޿ߚߒ߹ߔ‫⺞ߚ߹ޕ‬ᩏߦߏᡰេ࡮ߏදജ޿ߚߛ޿ߚࡗࠢ࡜ࡦ࠼ߩਭ଻ᷕሶ᳁ࠍߪߓ߼ߣߔࠆ㑐ଥ⠪ߩ⊝᭽ߦෘߊᓮ␞↳ߒ਄ߍ߹ߔ‫ޕ‬50ㇺ ↲࡮㚤 ၔ

ᢥ ₂1) ጊᧄߌ޿ߎ㧘ࡉ࡯࠲ࡦߩᨴߣ❱̆ᡷ⸓ ̆㧘ᨴ❱ߣ↢ᵴ␠㧘20012) ਭ଻ᷕሶ㧘ࡉ࡯࠲ࡦᨴ⦡㧔❱㧕ߩᣏ࡟ࡐ࡯࠻㧘ࡗࠢ࡜ࡦ࠼㧘20013) ㇺ↲↱♿ሶ㧘ࡉ࡯࠲ࡦߦ߅ߌࠆ࡜࠶ࠢᨴᢱߩ૏⟎ߠߌ߅ࠃ߮↢↥㧘ᄤὼߩ⦡̆ᄤὼᨴᢱ㗻ᢱળ⼏ႎ๔ 2008㧘11-12㧘20094) ㇺ↲↱♿ሶ㧘ࡉ࡯࠲ࡦߦ߅ߌࠆ࡜࠶ࠢᨴᢱࠍ↪޿ߚᨴ⦡㧘ᄤὼߩ⦡̆ᄤὼᨴᢱ㗻ᢱળ⼏ႎ๔
2008㧘13-15㧘20095) ᷰㄝᒄਯ㧘ࠞࠗࠟ࡜ࡓࠪ߇ᾲᏪᨋࠍᢇ߁㧘᧲ᶏᄢቇ಴ ળ㧘20036) ㇺ↲↱♿ሶ㧘㚤ၔ⚛ሶ㧘⿒⦡♽ߩᄤὼᨴᢱ㧘↢ᵴᎿቇ⎇ⓥ㧘߅⨥ߩ᳓ᅚሶᄢቇ↢ᵴᎿቇ⎇ⓥળ㧘
9 (1)㧘136-139㧘20077) ㇺ↲↱♿ሶ㧘ࠞࠗࠟ࡜ࡓࠪ↱᧪ߩ࡜࠶ࠢᨴᢱߦߟ޿ߡ㧘ᄤὼߩ⦡̆ᄤὼᨴᢱ㗻ᢱળ⼏ႎ๔ 2008㧘
9-10㧘20098) ਛႦㅴ৻㧘ᄢේశ᥍㧘᧛↰ల⦟㧘࡜࠶ࠢࠞࠗࠟ࡜ࡓࠪ㧔Laccifer Lacca㧕ಽᴲ‛ߩ᭴ㅧ⎇ⓥ㧘ጘ㒂ᄢቇ࿾ၞ౒ห⎇ⓥ࠮ࡦ࠲࡯⎇ⓥᚑᨐႎ๔ᦠ No.2㧘19929) C. Hu, A. Hasegawa, S. Nakatsuka, Isolation and Structure Determination of Laccaic Acid
F from Lac-dye Produced from Thai Sticlac, Heterocyclic Communications, 3, 327-330, 1997

Natural Dyeing in Bhutan―Dyeing with Lac and Madder―
TOGO, Yukiko and KOMAKI, Motoko

Abstract
The procedure of natural dyeing with lac and madder isinvestigated in Bhutan.

White fabrics of wool, silk and cotton weredyed for experiment, though the silk yarn was dyed at Bumthang.
Colorants were extracted in hot water, and fabrics pretreated with
Symplocos paniculata were dyed at 85͠ for 10 minutes and then cooleddown.

The fabrics were washed with water and then dried at normal

temperature.

The wool and the silk were dyed satisfactorily, but thecotton was not without mordanting or cationisation (pre-treating with
3-Chloro-2-hydroxypropyltrimethylammonium Chloride).
䇼Key words‫  ޤ‬Bhutan,

Natural dyeing,

Lac,

Madder