AIQS-LC Internal standard Mix
Hayashi Pure Chemical Ind.,Ltd.
Date of issue: 9/15/2020

Revision date: 5/9/2023

SDS code: OA-07

Version: 02

Safety Data Sheet
1. Chemical product and company identification
Product nameSDS code::

AIQS-LC Internal standard Mix
OA-07

Company/undertaking:
identification
HAYASHI PURE CHEMICAL IND.,LTD.
Address : 3-2-12 Uchihiranomachi, Chuo-ku, Osaka, Osaka, Japan
Telephone : 06-6910-7305
E-mail : shiyaku_kikaku@hpc-j.co.jp
URL : https://www.hpc-j.co.jp/
Emergency number
Recommended use
Restrictions on use:::

06-6910-7305
For research and experimental use only.
Do not use for any purpose other than research and experiment. Do not use on ahuman body or for animal medicines, foods, household products, cosmetics, etc.
Do not use in the environment.

2. Hazards identification
GHS classification
Physical hazards

Health hazards

Explosives
Flammable gases
AerosolOxidizing gases
Gases under pressure
Flammable liquids
Flammable solids
Self-reactive substances andmixtures
Pyrophoric liquids
Pyrophoric solids
Self-heating substances andmixtures
Substances and mixtures which incontact with water emit flammablegases
Oxidizing liquids
Oxidizing solids
Organic peroxides
Corrosive to metals
Desensitized explosives
Acute toxicity (oral)
Acute toxicity (dermal)
Acute toxicity (inhalation:gas)
Acute toxicity (inhalation:vapors)
Acute toxicity (inhalation:dust/mist)
Skin corrosion/irritation
Serious eye damage/eye irritation
Respiratory sensitization
Skin sensitization
Germ cell mutagenicity
Carcinogenicity
Reproductive toxicity
Specific target organ toxicity (single
exposure)

No classification
No classification
No classification
No classification
No classification
Category 2
No classification
classification not possible
No classification
No classification
classification not possible
No classification

No classification
No classification
No classification
classification not possible
No classification
Category 4
No classification
No classification
classification not possibleclassification not possibleclassification not possible
Category 2classification not possibleclassification not possibleclassification not possibleclassification not possible
Category 1B
Category 1 (central nervous system, visual organ,
systemic toxicity)
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Hayashi Pure Chemical Ind.,Ltd.

AIQS-LC Internal standard Mix
Revision date: 5/9/2023

Environmental
hazards

Specific target organ toxicity (single
exposure)
Specific target organ toxicity(repeated exposure)
Aspiration hazard
Hazardous to the aquatic
environment, short-term (acute)Hazardous to the aquatic
environment, long-term (chronic)
Hazardous to the ozone layer

SDS code: OA-07

Version: 02

Category 3 (Narcosis)
Category 1 (central nervous system, visual organ)classification not possible
Category 2
Category 3classification not possible

Hazardpictograms(GHS JP)

GHS07

GHS02

GHS08

Signal word (GHS JP):

DangerHazard statements (GHS JP):

Highly flammable liquid and vapor (H225)
Harmful if swallowed (H302)
Causes serious eye irritation (H319)
May cause drowsiness or dizziness (H336)
May damage fertility or the unborn child (H360)
Causes damage to organs (central nervous system, visual organ, systemic
toxicity) (H370)
Causes damage to organs (central nervous system, visual organ) throughprolonged or repeated exposure (H372)
Toxic to aquatic life (H401)
Harmful to aquatic life with long lasting effects (H412)

Prevention:

Response:

Storage:

Obtain special instructions before use. (P201)
Do not handle until all safety precautions have been read and understood.
(P202)
Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking. (P210)
Ground and bond container and receiving equipment. (P240)
Use explosion-proof electrical/ventilating/lighting equipment. (P241)
Use only non-sparking tools. (P242)
Take action to prevent static discharges. (P243)
Do not breathe dust/fume/gas/mist/vapors/spray. (P260)
Wash hands, forearms and face thoroughly after handling. (P264)
Do not eat, drink or smoke when using this product. (P270)
Use only outdoors or in a well-ventilated area. (P271)
Avoid release to the environment. (P273)
Wear protective gloves/protective clothing/eye protection/face protection.
(P280)IF SWALLOWED: Call a POISON CENTER or doctor if you feel unwell.
(P301+P312)
IF ON SKIN (or hair): Take off immediately all contaminated clothing.
Rinse skin with water . (P303+P361+P353)
IF INHALED: Remove person to fresh air and keep comfortable forbreathing (P304+P340)
IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
(P305+P351+P338)
IF exposed or concerned: Call a POISON CENTER or doctor.
(P308+P311)
Get medical advice/attention if you feel unwell. (P314)
Rinse mouth. (P330)
If eye irritation persists: Get medical advice/attention. (P337+P313)
In case of fire: Use specify appropriate media to extinguish. (P370+P378)
Store in a well-ventilated place. Keep container tightly closed.
(P403+P233)
Store in a well-ventilated place. Keep cool. (P403+P235)
Store locked up. (P405)

Precautionary statements (GHS JP)

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Hayashi Pure Chemical Ind.,Ltd.

AIQS-LC Internal standard Mix
Revision date: 5/9/2023

Disposal:

SDS code: OA-07

Version: 02

Dispose of contents/container to hazardous or special waste collection
point, in accordance with local, regional, national and/or international
regulation. (P501)

3. Composition/information on ingredients
Distinction of substance or mixture
Name:

MixtureConcentration orConcentration range

Kanpo number

FormulaCSCL no

ISHL noCAS RN

Methanol

≧98％

CH3OH

(2)-201

Existing
ChemicalSubstance

67-56-1

Methamidophos-d6

About 0.003％

C2H2D6NO2PS--

1219799-41-3

Methomyl-d3

About 0.003％

C5H7D3N2O2S-

2-(5)-130

1398109-07-3

Carbendazim-d4

About 0.003％

C9H5D4N3O2(5)-465

8-(2)-746

291765-95-2

Pirimicarb-d6

About 0.003％

C11H12D6N4O2--

1015854-66-6

Imazalil-d5

About 0.003％

C14H9D5Cl2N2O(5)-6891

8-(2)-2055

1398065-91-2

Ethofenprox-d5

About 0.003％

C25H23D5O3(3)-3981

4-(14)-178

1705649-55-3

The above concentration or concentration range are not product specification.
All percentages listed in the above concentration or concentration range are wt%, unless otherwise specified.

4. First aid measures
First aid measures
First-aid measures after inhalation:

First-aid measures after skincontact:

First-aid measures after eye
contact:

First-aid measures after ingestion:

Remove person to fresh air and keep comfortable for breathing.
Get immediate medical advice/attention.
Remove/Take off immediately all contaminated clothing.
Gently wash with plenty of soap and water.
Get immediate medical advice/attention.
IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
Get immediate medical advice/attention.
Do NOT induce vomiting.
Rinse mouth.
Get immediate medical advice/attention.

5. Fire fighting measures
Suitable extinguishing media
Unsuitable extinguishing media
Fire hazard
Explosion hazard

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:

Hazardous decomposition products
in case of fire
Firefighting instructions:

Protection during firefighting::

Water spray, Alcohol-resistant foam, Dry powder, Carbon dioxide, Sand.
Do not use a heavy water stream.
Extremely flammable liquid and vapor.
Danger of the steam explosion in indoor, outdoor, sewer.
May induce explosion of containers by heating.
In case of fire, product may produce irritative or toxic fumes/gases.
If ignited, for the initial fire-fighting, cut off combustion sources, extinguishfire at a stroke using appropriate fire-extinguishers.
In the case of peripheral fire, quickly remove movable containers to safe
places.
If unable to be moved containers, sprinkle water to containers andsurrounding equipment, etc. to cool.
Even after extinguishing fire, thoroughly cool containers by using plenty ofwater.
Wear appropriate fire-resistant clothing including self containedcompressed air breathing apparatus.

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Hayashi Pure Chemical Ind.,Ltd.

AIQS-LC Internal standard Mix
Revision date: 5/9/2023

SDS code: OA-07

Version: 02

6. Accidental release measures
Personal Precautions, Protective Equipment and Emergency Procedures
General measures: Before entering, ventilate the area.
Do not let unauthorized persons come close to the area.
Immediately place the leakage area in isolation, with taking proper
distances for all directions.
Wear appropriate personal protective devices to prevent inhalation andcontact with eye, skin, and clothing, and never attempt to work on the lee.
Environmental precautions
Environmental precautions:

Avoid release to the environment.
Prevent entry to sewers and public waters.

Methods and Equipment for Containment and Cleaning up
Methods for cleaning up: Clean up any spills as soon as possible, using an absorbent material tocollect it.
Collect leaking and spilled liquid in sealable containers as far as possible.
Wash out the spilled area with large amounts of water.

7. Handling and storage
Handling
Technical measures:

Precautions for safe handling:

Prevents handling of incompatible
substances or mixtures:

Storage
Storage conditions

Material used inpackaging/containers
Technical measures
Storage temperature

:

:
:
:

Work with appropriate personal protective equipment to prevent inhalationor contact to eyes, skin, and clothing.
Handle with care to prevent leakage, overflowing, or scattering, minimize
generation of mist or vapor, and thoroughly ventilate.
Do not eat, drink or smoke when using this product.
Thoroughly wash your hands and gargle after handling.
Ensure good ventilation of the work station.
Do not contact, breathe or swallow.
Take precautionary measures against static discharge.
Use explosion-proof equipment.
Avoid prolonged or repeated exposure.

Store locked up.
Store in a well-ventilated place, away from direct sunlight. Keep container
tightly closed and keep away from fire and heat sources.
Light shielding airtight container.
Comply with applicable regulations.
Freeze: -20℃

8. Exposure controls / Personal protection equipment
Exposure limit values
MethanolJapan administration level
Exposure limits (JSOH)
Exposure limits (ACGIH)
Appropriate engineering controls

Protective equipment
Respiratory protection
Hand protection
Eye protection
Skin and body protection

200ppm200ppm(260mg/m3)(skin)
TWA 200 ppm,STEL 250 ppm (Skin): Cover up tightly the generation source at the handling place or install local
exhaust equipment or overall ventilation equipment. Install safety showers
and eye-fountains near a handling place. Clearly indicate the location.
: Gas mask for organic gases: Impervious protective gloves: Protective glasses (general glasses, glasses with side-shields, goggles): Impervious aprons, Impervious work clothing, Impervious long boots

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Hayashi Pure Chemical Ind.,Ltd.

AIQS-LC Internal standard Mix
Revision date: 5/9/2023

SDS code: OA-07

Version: 02

9. Physical and chemical properties
Physical stateAppearance
Color
Odor
pH
Melting point
Freezing point
Boiling point
Flash point
Auto-ignition temperature
Decomposition temperature
Flammability (solid, gas)
Vapor pressure
Relative density
Density
Relative gas density
Solubility
Partition coefficient noctanol/water (Log Pow)
Explosive limits (vol %)Viscosity, kinematic
Particle characteristics

:
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LiquidLiquidNo data available
No data available
No data available
No data available
No data available
64.7 °C (as methanol)
12 °C (as methanol, tag closed cup)
No data available
No data available
No data available
No data available
No data available
0.79 g/cm³ (as methanol)
No data available
No data available
No data available:::

No data available
No data available
No data available

Reactivity
Chemical stability
Possibility of hazardous reactions:::

Conditions to avoid:

Incompatible materials
Hazardous decomposition
products::

No data available
Stable under normal handling conditions.
Heating decomposes and generates formaldehyde. Reacts violently withoxidizing agents and poses a risk of fire and explosion. Mixing withhydrogen peroxide causes explosion by impact. Aluminium and lead may beeroded.
Sunlight, heat. Ignition sources such as flame, spark and static electricity.
Contact with oxidizing agents, acids, reducing agents and metals.
Oxidizing agents, Acids, Reducing agents, Metals
Formaldehyde

10. Stability and reactivity

11. Toxicological information
The information in this section is based on the "GHS Classification Results" by NITE.
As a productAcute toxicity (oral)
Category 4
Acute toxicity (dermal)
No classification
Acute toxicity (inhalation)
vapors:classification not possible
Gases:No classification
dust, mist:classification not possible
Skin corrosion/irritation
classification not possible
Serious eye damage/irritation
Category 2
Respiratory sensitization
classification not possible
Skin sensitization
classification not possible
Germ cell mutagenicity
classification not possible
Carcinogenicity
classification not possible
Reproductive toxicity
Category 1B
STOT-single exposure
Category 1 Category 3 (Narcosis)
STOT-repeated exposure
Category 1
Aspiration hazard
classification not possible
Methanol
Acute toxicity (oral)
Acute toxicity (dermal)
Acute toxicity (gas)Category 4
No classification
No classification
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Hayashi Pure Chemical Ind.,Ltd.

AIQS-LC Internal standard Mix
Revision date: 5/9/2023

Methanol
Acute toxicity (vapour)
Acute toxicity (inhalation:dust/mist)
Skin corrosion/irritation
Serious eye damage/irritation
Respiratory sensitization
Skin sensitization
Germ cell mutagenicity
Carcinogenicity

No classification
classification not possibleclassification not possible
Category 2classification not possible
No classification
No classification
classification not possible

Reproductive toxicity

Category 1B

STOT-single exposure

Category 1 Category 3 (Narcosis)

STOT-repeated exposure

Category 1

Aspiration hazard

classification not possible

SDS code: OA-07

Version: 02

12. Ecological information
The information in this section is based on the "GHS Classification Results" by NITE.
As a productHazardous to the aquatic environment,
Category 2
short-term (acute)Hazardous to the aquatic environment, Category 3
long-term (chronic)
Persistence and degradability
No data available
Bioaccumulative potential
No data available
Mobility in soil
No data available
Ozone
classification not possible
MethanolHazardous to Aquatic Environment Acute Hazard
Hazardous to Aquatic Environment Chronic Hazard
Persistence and degradability
Bioaccumulative potential
Mobility in soil
Hazardous to the ozone layer

No classification
No classification
No data available
No data available
No data available
classification not possible

13. Disposal considerations
Ecology - waste materials:

Contaminated container andpackaging:With the detail information of the waste, subcontract its disposal to awaste disposer authorized by a Prefectural Governor.
Empty the packaging completely prior to disposal.
Empty containers should be taken for recycle, recovery or waste inaccordance with local regulation.

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1993
FLAMMABLE LIQUID, N.O.S.
II
3
3
3
274
1L
E2
P001
IBC02
T7
TP1, TP28, TP8

14. Transport information
International Regulations
Transport by sea(IMDG)
UN-No. (IMDG)
Proper Shipping Name (IMDG)
Packing group (IMDG)
Transport hazard class(es) (IMDG)
Hazard labels (IMDG)Class (IMDG)
Special provision (IMDG)
Limited quantities (IMDG)
Excepted quantities (IMDG)
Packing instructions (IMDG)
IBC packing instructions (IMDG)
Tank instructions (IMDG)
Tank special provisions (IMDG)

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Hayashi Pure Chemical Ind.,Ltd.

AIQS-LC Internal standard Mix
Revision date: 5/9/2023

Stowage category (IMDG)
MFAG-NoSDS code: OA-07

Version: 02

:
:

B
127

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1993
Flammable liquid, n.o.s.
II
3
3
3
E2
Y341
1L

:
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:

353
5L
364
60L
A3
3H

Marine pollutant:

Not applicable

Regulations in Japan
Regulatory information by sea
Regulatory information by air
MFAG-NoSpecial transport precautions

:
:
:
:

Conform to the provisions of the Ship Safety Law.
Conform to the provisions of the Civil Aeronautics Law.
127
When transporting, load containers so that they do not tip over,damage, drop or collapse. Make sure there is no leak in containers.

::

Priority Assessment Chemical Substances (Law Article 2, Para.5)
Class 2 Organic Solvents etc. (Enforcement Order, Art., Appended
Table 6-2, Ordinance on Prevention of Organic Solvent Poisoning,
Art.1, Para.1, Item 4)
Working Environment Evaluation Standards, Administrative Control
Levels (Law Art.65-2, Para.1)
Harmful Substances Whose Names Are to be Indicated on the Label(Law Art.57, Para.1, Enforcement Order Art.18 Item 1, Item 2,
Attached Table No.9)
Notifiable Substances (Law Art.57-2, Enforcement Order Art.18-2
Item 1, Item 2, Attached Table No.9)
Methanol (Ordinance number : 560)
Dangerous Substances - Flammable Substance (Enforcement Order
Attached Table 1 Item 4)
Substances on Special medical examination, Current handlingworkers (Act, Art.66, Para.2, Enforcement Order, Art.22 Item 1)
Deleterious Substances (Designated Order Art.2)
Preparations containing 45% or less of S-methyl-N[(methylcarbamoyl)-oxy]thioacetimidate(Methomyl)
2-Dimethylamino-5,6-dimethylpyrimidyl-4-N,N-dimethylcarbamate andpreparations containing it
Group 4 - Flammable liquids - Alcohols (Law Art.2 Para.7, Attached
Table 1, Group 4)
Specified substances (Article 17, Paragraph 1 of the Law, Article 10of the Enforcement Ordinance)
Volatile Organic Compounds (Law Art.2 Para.4) (MOE Official Noticeto Prefectures)
Export Trade Control Order, Attached Table 1 Para.2
Export Trade Control Ordinance appendix 1-16
Export Approval (Export Trade Control Order, Attached Table 2)
Flammable liquids (Dangerous Goods Notification Schedule firstsecond and third Article Dangerous Goods Regulations)
Flammable liquids (Hazardous materials notice Appended Table 1
Article 194 of the Enforcement Regulations)
Flammable liquids (Article 21, Paragraph 2 of Law, Article 12 rule,
notice attached table that defines the type of dangerous goods)

Air transport(IATA)
UN-No. (IATA)
Proper Shipping Name (IATA)
Packing group (IATA)
Transport hazard class(es) (IATA)
Hazard labels (IATA)Class (IATA)
PCA Excepted quantities (IATA)
PCA Limited quantities (IATA)
PCA limited quantity max net
quantity (IATA)
PCA packing instructions (IATA)
PCA max net quantity (IATA)
CAO packing instructions (IATA)
CAO max net quantity (IATA)
Special provision (IATA)ERG code (IATA)

15. Regulatory information
National law
Chemical Substances Control Law
Industrial Safety and Health Law

Japanese Poisonous andDeleterious Substances Control Law:

Fire Service Law:

Air Pollution Control Law:

Foreign Exchange and Foreign
Trade Control Act:

Ship Safety Act:

Civil Aeronautics Law:

Port Regulation Law:

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Hayashi Pure Chemical Ind.,Ltd.

AIQS-LC Internal standard Mix
Revision date: 5/9/2023

Road Act:

Waste Management on Public
Cleansing Law
Japanese Pollutant Release andTransfer Register Law (PRTR Law)
Labor Standards Act::

SDS code: OA-07

Version: 02

Restriction for Vehicle Traffic (Enforcement Order Art.19-13,
Publication of Japan Highway Pablic Corp.)
Specially Controlled Industrial Wastes (Act Art.2, para 5, Enfothment
Order Art.2-4 )Not applicable:Chemical Substances Causing Occupational Illnesses (Act Art.75,
Para.2, Ordinance Attached Table 1-2, Item 4-1, MHLW Nortification
No.36 of 1978)

Data sources:

Other information:

Handbook of 17423 Chemical Products, The Chemical Daily Co, Ltd.
International Chemical Safety Cards.
National Institute of Technology and Evaluation (NITE).
2020 Emergency Response Guidebook (ERG 2020).
The SDS is copyrighted material of Hayashi Pure Chemical Ind, Ltd.
This Safety Data Sheet is intended to be provided for business
operators who handle chemical substance products of the relevant
product and is not intended to assure safety in any way. The Safety
Data Sheet does not verify all the information on the applicablechemical substance in the present time. With the recognition in that
unknown danger constantly exists in the relevant chemical substance,
the product shall be used in the principle of self-responsibility of theuser with the highest priority to safety from transport and unpacking todisposal. When the relevant chemical substance is used, the user
him/herself shall collect safety information and shall investigate laws
and regulations at the place, organizations, countries, etc. where thesubstance is actually used and give the highest priority to them. The
Company shall take no responsibility for investigating state and local
regulations and the user shall handle this problem on his/her own
responsibility. In the event that SDS in Japanese and SDS translated
into other languages exist, the document described in Japanese isprior to all other documents whether or not there is any difference incontents, and documents in other languages shall be references.

16. Other information

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