Green Procurement Guidelines
Annex
Ver.3.0
Appendix

Title

Rev.

Date

Page

-

Revision History

-

-

2

1

Level 1(Prohibited substance group)2.0

2023.10.1

3

2

Level 2 (Controlled substance group)2.0

2023.10.1

53-1

The exemptions of RoHSⅡ Annex3

2.0

2023.10.1

7

3-2

The exemptions of RoHSⅡ Annex4(The exemptions of category 8&9)

1.0

2022.1.4

114

Ozone depleting substances

0.0

2021.11.1

15

PFOS／PFOS relative compounds〈Perfluorooctane sulfonates〉
REACH Annex XVII Restriction of placing on themarket and use
REACH-Annex XIV Authorization and Candidate(SVHC) List

0.0

2021.11.1

19

1.0

2023.10.1

23

2.0

2023.10.1

27

List of aromatic amines

0.0

2021.11.1

34

List of Hexabromocyclododecane（HBCD or
HBCDD）
List of Perfluorooctanoic acid (PFOA),its salts
and PFOA-related compounds

0.0

2021.11.1

35

0.0

2021.11.1

36

5
6
7
8
9
10

rev.
1.0

date
2021.11.1

1.1

2022.3.22

2.02023.1.4

3.0

2023.10.1

Revision History
New Publication
The change of Appendix 6: No.68, 76
The change of Appendix 7: The addition of No.220-223 (26th addition)
Change of Company name,
The change of Appendix 1: The addition of No.24, 25
The change of Appendix 3-1: No.1(a)-(g), 2(a)(b), 3(a)(b)(c),4(a)(b)(c)(e)(f), the addtion of No.45
The change of Appendix 3-2: The addition of No. 45, 46, 47
The change of Appendix 7: The addition of No.224 (27th addition)
Change of Appendix 1: No.6 and Addition of No.26, 27
Change of Appendix 2: Addition of No.21, 22
Change of Appendix 3-1: No.5(a)(b), 6(c), 7(b)(c)-II, IV, 8(b), 9, 9(b), 15,
17, 18(b), 21, 25, 29, 30, 31, 32, 33, 34, 37, 38, 41
Change of Appendix 6: No. 63
Change of Appendix 7: Addition of No.234, 235 (29th addition)

Annex 1_Level 1（Prohibited）

Annex 1. Level 1(Prohibited substance group)NO

Substance group (English)

Scope of regulation concerning use andhandling

3/42

rev..2.0 2023.10.1
Control value of Hitachi group *Remarks

Reference laws and regulations

Cadmium and its compounds
Common1

Packaging materials

EU RoHS Directive
EU ELV Directive
EU Packaging Directive
No more than 100ppm in total with 4
USA State law (e.g. FL, GA, IA, IL, NH,
substances of Cd, Cr(VI), Pb, Hg
MO, PA, WI, etc.)
No more than 100ppm

Hexavalent chromium compounds
2

EU RoHS Directive
EU ELV Directive

CommonNo more than 1000ppm

Packaging materials

No more than 100ppm in total with 4
EU Packaging Directive
substances of Cd, Cr(VI), Pb, Hg

CommonNo more than 1000 ppm

Packaging materials

No more than 100ppm in total with 4
EU Packaging Directive
substances of Cd, Cr(VI), Pb, Hg

CommonNo more than 1000 ppm

Lead and its compounds

3-

EU RoHS Directive
EU ELV Directive
GER Prohibition of Chemicals
Ordinance - ChemVerbotsV

Mercury and its compounds
4

Packaging materials

5
6

7

Polybrominated biphenyls （PBBs）
Polybrominated diphenyl ethers (PBDEs)
DecaBDE
Tri-substituted organostannic compounds
7-1

Bis(tributyltin)=Oxide （TBTO）

7-2

Tributyltin (TBT) compounds

7-3

Triphenyltin (TPT) compounds

CommonCommonArticlesOther tri-substituted organostannic
compounds
Polychlorinated biphenyls （PCBs）

9

-

11

12

-

CommonAlkanes, C10 -C13 , chloro (short-chain chlorinated paraffins) (SCCPs)
CommonAsbestos
12-1 Asbestos
CAS:1332-21-4
12-2 Amosite
CAS:12172-73-5
12-3 Crocidolite
CAS:12001-28-4
Common12-4 Chrysotile
CAS:12001-29-5
12-5 Anthophyllite
CAS:17068-78-9、77536-67-5
12-6 Tremolite
CAS:14567-73-8、77536-68-6
Actinolite
12-7
CAS:12172-67-7、77536-66-4
Ozone layer depleting substances （See Appendix 4 for the applicable substances）
Correspond to Montreal Protocol ClassⅠ
Common（CFCs, HCFCs, HBFCs, carbon
tetrachloride, etc.）

13

14

CommonPolychlorinated terphenyls （PCTs）
Equipments
Other than equipments
Polychlorinated naphthalenes (with 1 or more chlorines)

10-

2-(2H-1,2,3-benzotriazole-2-yl)-4,6-di- Common
tert-butylphenol

16-

Hexachlorobenzene

EU RoHS Directive
TSCA PBT Regulation

Intentional use prohibitedPOPｓ
JPN Chemical Examination Law/Type 1
Specified Chemical Substances
GER Prohibition of Chemicals
Ordinance - ChemVerbotsV

No more than 50 ppm
Intentional use prohibited

EU REACH Regulation/Restriction No.1
EU REACH Regulation/Restriction No.1

Intentional use prohibited

Apply fromJPN Chemical Examination Law/Type 1 Oct. 1st,
2016
Specified Chemical Substances

Intentional use prohibited

POPｓ

Intentional use prohibitedand no more than 1000 ppm

EU REACH Regulation/Restriction No.6
JPN Industrial Safety and Health Law（Prohibition of Manufacturing, etc.）
JPN Industrial Safety and Health Law（Asbestos Ordinance）
GER Prohibition of Chemicals
Ordinance - ChemVerbotsVIntentional use prohibited

Intentional use prohibited

CommonArticlesDimethylfumarate (DMF)
No more than 0.1ppm
Hexabromocyclododecane （HBCD or HBCDD, See Appendix 9 for the applicable substances）

18

EU RoHS Directive

JPN Chemical Examination Law/Type 1
specified chemical substances
EU REACH Regulation/Restriction
No.20
Intentional use prohibited, andEU REACH Regulation/Restriction
no more than 1000 ppm by weight of No.20
tin
JPN Chemical Examination Law/Type 2
specified chemical substances
EU REACH Regulation/Restriction No.20

PFOS <Perfluorooctanesulfonic acid> and its analogous compounds （See Appendix 5 for the applicable substances）
Common<Exemption usage>
Semiconductor, Photoresists, Photo
imaging, Metal plating, Medical devices,
Intentional use prohibited
Electric and electronic parts for colour
printer, Fire-fighting foams

15

17

No more than 1000 ppm

CommonNo more than 1000 ppm
Articles only for the U.S covered by TSCA
Use prohibited
PBT

7-4

8

EU RoHS Directive
EU ELV Directive
No more than 100ppm in total with 4 EU Packaging Directive
substances of Cd, Cr(VI), Pb, Hg-

CommonIntentional use prohibited19-

Bis (2-ethylhexyl) phthalate（DEHP）

CommonNo more than 1000ppm

20-

Benzyl butyl phthalate （BBP）

CommonNo more than 1000ppm

21-

Dibutyl phthalate （DBP）

CommonNo more than 1000ppm

22-

Diisobutyl phthalate (DIBP)

CommonNo more than 1000ppm

Montreal Protocol on Substances that
Deplete the Ozone Layer
JPN Ozone Layer Protection Law

JPN Chemical Examination Law/Type 1
Specified Chemical SubstancesPOPｓ
EU Regulation No.757/2010
CAN Perfluorooctane Sulfonate and its
Salts and Certain Other Compounds
Regulations SOR /2008-178. Canadian
Environmental Protection Act, 1999
JPN Chemical Examination Law/Type 1
Specified Chemical Substances
EU REACH Authorisation/SVHCJPN Chemical Examination Law/Type 1
Specified Chemical Substances
EU REACH/Ristriction
EU CLP Annex I
EU REACH Regulation/Restriction
No.61
JPN Chemical Examination Law/Type 1
Apply fromSpecified Chemical Substances
April 1st,
POPｓ
2016
EU REACH Regulation/SVHC（See Appendix 7 for the applicable
substances）
EU RoHS Directive (from July,2019)
EU REACH Regulation/SVHC（See Appendix 7 for the applicable
substances）
EU REACH Regulation/Restriction No.51
EU RoHS Directive (from July,2019)
EU REACH Regulation/SVHC（See Appendix 7 for the applicable
substances）
EU REACH Regulation/Restriction No.51
EU RoHS Directive (from July,2019)
EU REACH Regulation/SVHC（See Appendix 7 for the applicable
substances）
EU REACH Regulation/Restriction No.51
EU RoHS Directive (from July,2019)
EU REACH Regulation/SVHC（See Appendix 7 for the applicable

Translation
to Level 1 atfollowingdate:
Products or
parts
correspond
to EU
RoHS/Cat8&9:
18/Jan/2021
Products orparts otherthan above:
14/Jan/2019

Annex 1_Level 1（Prohibited）

NO

Substance group (English)

Scope of regulation concerning use andhandling

4/42

Control value of Hitachi group *Intentional use prohibited andPOPｓ
0.025ppm (25ppb) or less of PFOA JPN Chemical Examination Law/Type 1
including its salts
Specified Chemical Substances
Domestic low in Norway
or 1ppm (1000ppb) of one or a
（See Appendix 6 & 10 for the applicablecombination of PFOA-related
substances）
compounds
Intentional use prohibited and lessthan 0.025ppm of C9-C14 PFCAs
EU REACH Regulation/Restriction No.68
including its salts or 0.26ppm of
one or a combination of C9-C14
PFCA related substances

23-

Perfluorooctanoic acid (PFOA)
and its salts and PFOA-related
compounds

24-

Perfluorocarboxylic acids containing 9
to 14 carbon atoms in the chain (C9C14 PFCAs), their salts and C9-C14
PFCArelated substances

25-

Perfluorohexane sulfonic acid (PFHxS),
Commonits salts and PFHxSrelated compounds

Intentional use prohibited

CommonCommonReference laws and regulations

POPs
EU REACH Regulation/SVHC
Domestic law in Switzerland

26

Dechlorane Plus (DP)CommonIntentional use prohibited・POPs
・EU REACH/Authorization,SVHC

27

2-(2H-benzotriazol-2-yl)-4,6ditertpentylphenol(UV-328)

CommonIntentional use prohibited・POPs
・EU REACH/Authorization,SVHC*

This is specified as control value for PROTERIAL group in reference to related laws and regulations (Reference laws and regulations column).

Remarks

Annex 2_Level 2 (Controlled)

5/42

Annex 2. Level 2 (Controlled substance group)
No
1

2

3

4

5
6
7

Substance group (English)

Reference laws and regulations or Industrial
standards

Antimony and its compounds （which include alloys）
EU Safety of toys Directive
Arsenic and its compounds （which include alloys）
EU REACH Regulation/Restriction （SeeAppendix 6 for the applicable substances）
EU Safety of toys Directive
JPN Industrial Safety and Health Law (Labelling
2-1
duty of notifiable substances and Specified
Group-2 Substances of Ordinance on Preventionof Hazards Due to Specified Chemical
Substances)
Diarsenic pentaoxide and Diarsenic
EU REACH Regulation/SVHC （See Appendix 7
2-2
trioxidefor the applicable substances）
Beryllium and its compounds （which include alloys）
JPN Industrial Safety and Health Law（Manufacturing licence)
Nickel and its compounds （which include alloys）
EU REACH Regulation/Restriction （SeeAppendix 6 for the applicable substances）
EU Safety of toys Directive
JPN Industrial Safety and Health Law (Labelling
duty of notifiable substances and Specified
Group-2 Substances of Ordinance on Preventionof Hazards Due to Specified Chemical
Substances)
Selenium and its compounds （which include alloys）
EU Safety of toys Directive
Un-specifc brominated frame retardants
Unspecific brominated frame retardants
JEDEC JS709
which excepted PBBs and PBDEs
IPC-4101 and IEC61249-2-21
Polyvinyl chloride （PVC） and its mixture, its copolymer
JS709
Phthalate esters other than No.1 - No.4 of this List
8-1

Bis(2-methoxyethyl) phthalate

8-2
8-3

Diisopentylphthalate
Dipentyl phthalate (DPP)

8-４

Dihexyl phthalate

8-5
8-6
8

rev.2.0 2023.10.01

1,2-Benzenedicarboxylic acid, di-C7-11- EU REACH Regulation/SVHC（See Appendix 7 for the applicable substances）
branched and linear alkyl esters
1,2-Benzenedicarboxylic acid, di-C6-8branched alkyl esters, C7-rich Diisoheptyl
phthalate (DIHP)

8-７

1,2-Benzenedicarboxylic acid, dipentylester,branched and linear

8-８

1,2-Benzenedicarboxylic acid,dihexyl ester, branched and linear

8-9

Di-“isononyl” phthalate (DINP)

8-10 Di-“isodecyl” phthalate (DIDP)EU REACH Regulation/Restriction（See Appendix 6 for the applicable substances）

8-11 Di-n-octyl phthalate (DNOP)
8-12 Other pfthalate esters
Ozone layer depleting substances
9

HCFCs(Fall into Montreal Protocol ClassⅡ)

Montreal Protocol on Substances that Deplete
the Ozone Layer
JPN Ozone Layer Protection Law（Content
controlled substances）

Radioactive substances
1011

Di-substituted organostannic compounds
11-1 Dibutyltin compounds （DBT）
11-2 Dioctyltin compounds （DOT）

JPN Nuclear Reactor Regulation Law
JPN Radiation Hazard Prevention Act
EU REACH Regulation/Restriction （SeeAppendix 6 for the applicable substances）

Remarks

Annex 2_Level 2 (Controlled)

No
11

6/42

Substance group (English)

Reference laws and regulations or Industrial
standards

Other di-substituted organostannic
compounds
Cobalt and its compounds （which include alloys）

12

13

14

15

16
17

11-3

-

12-1

EU Safety of toys Directive
JPN Industrial Safety and Health Law (Labelling
duty of notifiable substances and Specified
Group-2 Substances of Ordinance on Preventionof Hazards Due to Specified Chemical-

12-2 Cobalt(II) chloride
12-3 Cobalt(II) sulfate
EU REACH Regulation/SVHC （See Appendix 7
12-4 Cobalt(II) nitrate
for the applicable substances）
12-5 Carbonic acid cobalt(II)12-6 Cobalt(II) acetate
Azodyes and azocolourants which form specified amines（Specified amines ：See Appendix 8 for the applicable substances）
EU REACH Regulation/Restriction （SeeAppendix 6 for the applicable substances）
JPN Law for the Control of Household Products
containing Harmful Substances
Formaldehyde
GER Prohibition of Chemicals Ordinance ChemVerbotsVJPN Industrial Safety and Health Law (Labelling
duty of notifiable substances and Specified
BenzeneGroup-2 Substances of Ordinance on Preventionof Hazards Due to Specified Chemical
Substances)
Fluorine based greenhouse gasses (HFC, PFC, SF6)
JPN Law Concerning the Promotion of Measures
Against Global Warming
EU Regulation （EC）No.842/2006
2,4,6-tris(tert-butyl)phenol （2,4,6-TTBP） TSCA PBT Regulation

18
19
20

-

Isopropylphenyl phosphate (PIP(3:1))
Pentachlorothiophenol (PCTP)
Hexachlorobutadiene (HCBD)TSCA PBT Regulation
TSCA PBT Regulation
TSCA PBT Regulation

21-

Per/polyfluoroalkyl compounds (PFAS)・EU REACH/Restriction

22
23

24

25

26
27

Decabromodiphenylethane (DBDPE)・Canada CTSR
Polycyclic-aromatic hydrocarbons (PAHs) corresponding to REACH/restriction substanceSee Appendix 6 for the applicable
EU REACH Regulation/Restriction
substances（See Appendix 6 for the applicable substances）
REACH/Restriction substances
See Appendix 6 for the applicable
EU REACH Regulation/Restriction （Seesubstances
Appendix 6 for the applicable substances）
REACH/Authorization substances
See Appendix 7 for the applicable
EU REACH Regulation/Authorization （Seesubstances
Appendix 7 for the applicable substances）
REACH/SVHC
See Appendix 7 for the applicable
EU REACH Regulation/SVHC （See Appendix 7
substances
for the applicable substances）
JAMP declarable substances (Including chemSHERPA)
JAMP declarable substances (Including
chemSHERPA#10)(Notes)I n relation to REACH/restriction substance group
Although this substance group belongs to the Level 2 (Controlled substance group), it may be prohibited to use in some particular applications.
Each substance in this group is restricted to be banned etc. When the substance is used under the condition of restriction which is individually specified in REACH
Regulation.
Therefore, when one or more of the substances is contained in a product, it is necessary to compare the use of the relevant product with the restricted use of thesubstance, and to determine whether the regulation shoule be applied or not.

Remarks

3-1_RoHS Exclusion

7/42

Appendix 3-1. The exemptions of RoHSⅡ Annex3
rev.2.0/2023.10.1
About exemptions already expired, these exempions
may be used in spare parts for EEE placed on themarket before expired day of each exemption
continuously.
(from 4(f) of Article4)

No

Substance

Scope and dates of applicability

Exemption
Mercury in single capped (compact) fluorescent lamps not exceeding (per burner):

1

5 mg
1(a)

For general lighting purposes < 30 W: 5 mg

3.5 mg
2.5 mgExoires on 24 February 2023

5 mg

Expired on 31
December 2011

3.5 mgExoires on 24 February 2023

For general lighting purposes ≥ 30 W and < 50 W: 5 mg

1(b)Expired on 31
December 2011
Expires on 31
December 2012

1(c)For general lighting purposes ≥ 50 W and < 150 W: 5 mg

5 mg

Exoires on 24 February 2023

1(d)For general lighting purposes ≥ 150 W: 15 mg

15 mg

Exoires on 24 February 2023

1(e)For general lighting purposes with circular or square structural shape andtube diameter ≤ 17 mm

No limitation of use

until 31 december 2011

7 mg

Exoires on 24 February 2023

1(f)-IFor lamps designed to emit mainly light in the ultraviolet spectrum

5 mg

Expires on 24 February 2027

1(f)-IIFor special purposes

5mg

Expires on 24 February 2025

1(g)For general lighting purposes < 30 W with a lifetime equal or above 20000 h

3.5 mgExpires on 31 December 2017
⇒Remain in force until the decision on2(a)Mercury in double-capped linear fluorescent lamps for general lighting purposes not exceeding (perlamp):

2(a)(1)Tri-band phosphor with normal lifetime and a tube diameter < 9 mm
(e.g. T2): 5 mg

Tri-band phosphor with normal lifetime and a tube diameter ≥ 9 mm and≤ 17 mm (e.g. T5): 5 mg

2(a)(2)Tri-band phosphor with normal lifetime and a tube diameter > 17 mm and≤ 28 mm (e.g. T8): 5 mg

2(a)(3)Tri-band phosphor with normal lifetime and a tube diameter > 28 mm(e.g. T12): 5 mg

2(a)(4)2(a)(5)5 mg

Expired on 31December 2011

4mg

Exoires on 24 February 2023

5 mg

Expired on 31December 2011

4mg

Exoires on 24 February 2023

5.0mg

Expired on 31December 2011

3.5mg

Exoires on 24 February 2023

5.0mg

Expired on 31December 2012

3.5mg

Exoires on 24 February 2023

8.0mg

Expired on 31December 2011

5.0mg

Exoires on 24 February 2023

Tri-band phosphor with long lifetime (≥ 25000h): 8 mg

Mercury in other fluorescent lamps not exceeding (per lamp):2(b)2(b)(1)

Linear halophosphate lamps with tube >,28 mm (e.g. T10 and T12): 10
mg

10 mg

Expires on 13 April
2012

2(b)(2)Non-linear halophosphate lamps (all diameters): 15 mg

15 mg

Expires on 13 April
2016

2(b)(3)Non-linear tri-band phosphor lamps with tube diameter > 17 mm (e.g. T9)

No limitation of use

15 mg

Expired on 31December 2011
Expires on 24 February 2023(*Applies from 25 February 2023 and expires 24
February 2025)

No limitation of use

Expired on 31December 2011

15 mg

Exoires on 24 February 2023

Lamps emitting mainly light in the ultraviolet spectrum

15 mg

Expires on 24 February 2027

2(b)(4)-III

Emergency lamps

15mg

Expires on 24 February 2027

3(a)Short length ( ≤500 mm)

2(b)(4)-I2(b)(4)-II

Lamps for other general lighting and special purposes (e.g. induction
lamps)

Hg

No limitation of use
3.5mg
No limitation of use3(b)Expired on 31December 2011
Expires on 24 February 2025

Expired on 31December 2011

Medium length ( >500mm and ≤ 1500 mm)
5mg
No limitation of use

3(c)Long length ( > 1500 mm)

4(a)Mercury in other low pressure discharge lamps (per lamp)

13mg
No limitation of use

Expires on 24 February 2025

Expired on 31December 2011
Expires on 24 February 2025

Expired on 31December 2011

3-1_RoHS Exclusion

No

8/42

Substance

Scope and dates of applicability

Exemption

4(a)Mercury in other low pressure discharge lamps (per lamp)

4(a)-I

Low pressure non-phosphor coated discharge lamps, where theapplication requires the main range of the lamp-spectral output to be in
the ultraviolet spectrum

4(b)Mercury in High Pressure Sodium (vapour) lamps for general lighting purposes not exceeding (perburner) in lamps with improved colour rendering index Ra > 60:

4(b)-IP ≤ 155 W

15mg

Expires on 24 February 2023

15mg

Expires on 24 February 2027

No limitation of use
30mg
No limitation of use
4(b)-ⅡNo limitation of use

4(c)Mercury in other High Pressure Sodium (vapour) lamps for general lighting purposes not exceeding(per burner):4(c)-IP ≤ 155 W

4(c)-Ⅲ4(d)Expires on 24 February 2023

Expired on 31December 2011
Expires on 24 February 2023

Expired on 31December 2011

P > 405 W
40mg

4(c)-Ⅱ

Expired on 31December 2011

155W < P ≤ 405 W
40mg

4(b)-Ⅲ

Expires on 24 February 2027

Expires on 24 February 2023

No limitation of use

Expired on 31December 2011

25mg

Expires on 30 September 2022

20mg

Expires on 24 February 2027

No limitation of use

Expired on 31December 2011

30mg

Expires on 30 September 2022

155W < P ≤ 405W

25mg

Expires on 24 February 2027

No limitation of use

Expired on 31December 2011

40mg

Expires on 30 September 2022

25mg

Expires on 24 February 2027

P > 405 W

Expires on 13 April 2015
(the exclusion abolition)

Mercury in High Pressure Mercury (vapour) lamps (HPMV)

Categories 8 and 9 except for the following;
Expired on 21 July 2021
(exclusion abolition)

4(e)Mercury in metal halide lamps(MH)4(f)-I

Other discharge lamps for special purposes not specifically mentioned in this Annex

4(f)-IIHigh pressure mercury vapour lamps used in projectors where an output >= 2000 lumen ANSI is
Expires on 24 February 2027
required4(f)-IIIHigh pressure sodium vapour lamps used for horticulture lighting

Expires on 24 February 2027

4(f)-IV

Lamps emitting light in the ultraviolet spectrum

Expires on 24 February 2027

4(g)Mercury in hand crafted luminous discharge tubes used for signs, decorative or architectural andspecialist lighting and light-artwork, where the mercury content shall be limited as follows:(a) 20 mg per electrode pair + 0,3 mg per tube length in cm, but not more than 80 mg,
for outdoor applications and indoor applications exposed to temperatures below 20 °C;(b) 15 mg per electrode pair + 0,24 mg per tube length in cm, but not more than 80 mg,
for all other indoor applications.

Expires on 31
December 2018

Lead in glass of cathode ray tubes

Cat.1-7 and 10 :Expired on 21 July 2016
Cat. 8 and 9 except for the following:Expiredon 21 July 2021
In vitro diagnostic medical devices:
Expires on 21 July 2023
(exclusion abolition)
Industrial monitoring and control instruments:
Expires on 21 July 2024

Expires on 24 February 2027

5(a)Lead in the glass of fluorescent tubes not exceeding 0,2% by weigh
5(b)

6(a)

Lead as an alloying element in steel for machining purposes and in
galvanized steel containing up to 0,35% lead by weight

up to 0.35 % lead byweight6(a)-I

Lead as an alloying element in steel for machining purposes containing
up to 0.35 % lead by weight and in batch hot dip galvanised steel
components containing up to 0.2% lead by weight

up to 0.35 % lead byweightExpires on 24 February 2025

Categories 8 and 9 except for the following;
Expired on 21 July 2021
Category 8 in vitro diagnostic medical devices;
Expires on 21 July 2023
(exclusion abolition)
Categories 1- 7,10;
Remain in force until the decision on extension
application continuously
Category 9 industrial monitoring and control
instruments and Category 11;
Expires on 21 July 2024
Categories 1- 7 and 10;Expired on 30 June 2019
Category 8 in vitro diagnostic medical devices;
Expires on 21 July 2023
(exclusion abolition)
Categories 8 and 9 except for the following;
Remain in force until the decision on extension
application continuously
Category 9 industrial monitoring and control
instruments and Category 11;
Expires on 21 July 2024

Categories 1-7 and 10;
Remain in force until the decision on extension
application continuously
Categories 1- 7 and 10; Expired on 30 June 2019
Category 8 in vitro diagnostic medical devices;
Expires on 21 July 2023
(exclusion abolition)

6(b)Lead as an alloying element in aluminium containing up to 0,4% lead byweightup to 0.4 % by weight

3-1_RoHS Exclusion

No

9/42

Substance

Exemption

Scope and dates of applicability

6(b)Lead as an alloying element in aluminium containing up to 0,4% lead byweightup to 0.4 % by weight6(b)-I

Lead as an alloying element in aluminium containing up to 0.4% lead byweight, provided it stems from lead-bearing aluminium scrap recycling

up to 0.4 % by weight6(b)-II

Lead as an alloying element in aluminium for machining purposes with alead content up to 0.4% by weight

up to 0.4 % by weight

Copper alloy containing up to 4% lead by weight

6(c)

Pb

Lead in high melting temperature type solders(i.e. lead-based alloys containing 85% by weight or more lead)

7(a)Categories 1-7 and 10;
Remain in force until the decision on extension
application continuously
Categories 1-7 and 10;
Remain in force until the decision on extension
application continuously

Categories 1-7,10 and Categories 8, 9 except for
the following;
Remain in force until the decision on extension
up to 4 % lead by weight application continuously
Category 8 in vitro diagnostic medical devices,
Category 9 industrial monitoring and control
instruments and Category 11
Categories 1-7 and 10 (Except applications
covered by point 24) and Categories 8, 9 except for
the following;
Remain in force until the decision on extension
application continuously
Category 8 in vitro diagnostic medical devices;
Expires on 21 July 2023
Category 9 industrial monitoring and control
instruments and Category 11;
Expires on 21 July 2024

Lead in solders for servers, storage and storage array systems, network infrastructure equipment
for switching, signalling, transmission, and network management for telecommunications

7(b)Categories 8 and 9 except for the following;
Remain in force until the decision on extension
application continuously
Category 9 industrial monitoring and control
instruments and Category 11;
Expires on 21 July 2024

Cat.1-7 and 10 :Expires on 21 July 2016
Cat. 8 and 9 except for the following:
Expires on 21 July 2021
In vitro diagnostic medical devices:
Expires on 21 July 2023
(the exclusion abolition)
Industrial monitoring and control instruments:
Expires on 21 July 2024

Categories 1-7 and 10 (Except applications
covered by point 34) and Categories 8, 9 except for
the following;
Remain in force until the decision on extension
Electrical and electronic components containing lead in a glass or ceramic other than dielectric application continuously
Category 8 in vitro diagnostic medical devices;
ceramic in capacitors, e.g. piezoelectronic devices, or in a glass or ceramic matrix compound
Expires on 21 July 2023
Category 9 industrial monitoring and control
instruments and Category 11;
Expires on 21 July 2024
Categories 1-7,10 and Categories 8, 9 except for
the following;
Remain in force until the decision on extension
application continuously
Lead in dielectric ceramic in capacitors for a rated voltage of 125 V AC or 250 V DC or higher
Category 8 in vitro diagnostic medical devices;
Expires on 21 July 2023
Category 9 industrial monitoring and control
instruments and Category 11;
Expires on 21 July 20247(c)-I7(c)-II7(c)(III)

Expires on 1 Janualy 2013
(the exclusion abolition)
Expired on:— 21 July 2021 for categories 1-7 and 10— 21 July 2021 for categories 8 and 9 except
for the following;
Lead in PZT based dielectric ceramic materials for capacitors being part of integrated circuits or — 21 July 2023 for category 8 in vitro
discrete semiconductors’
diagnostic medical devices(exclusion abolition)
Lead in dielectric ceramic in capacitors for a rated voltage of less than 125 V AC or 250 V DC

7(c)(Ⅳ)

Expires on:— 21 July 2024 for category 9 industrial monitoring
and control instruments, and for category 11

8(a)

8(b)

Cadmium and its compounds in one shot pellet type thermal cut-offs

Expires on 1 Janualy 2012
(the exclusion abolition)

Cadmium and its compounds in electrical contacts- 29 Feb 2020 for categories 1-7 and 10(the exclusion abolition)
Categories 8 and 9 except for the following;
Remain in force until the decision on extension
application continuously
Category 8 in vitro diagnostic medical devices;
Expires on 21 July 2023
Category 9 industrial monitoring and control
instruments and Category 11;
Expires on 21 July 2024

Cd

8(b)-I99(a)-I

Cadmium and its compounds in electrical contacts used in:— circuit breakers,— thermal sensing controls,— thermal motor protectors (excluding hermetic thermal motor protectors),— AC switches rated at:— 6 A and more at 250 V AC and more, or— 12 A and more at 125 V AC and more,— DC switches rated at 20 A and more at 18 V DC and more, and— switches for use at voltage supply frequency ≥ 200 Hz.

Categories 1-7 and 10;
Remain in force until the decision on extension
application continuously
Apply from March 1, 2020

Expired on:— 21 July 2021 for categories 8 and 9 other than
the following;
Hexavalent chromium as an anticorrosion agent of the carbon steel cooling systems in absorption — 21 July 2023 for category 8 in vitro diagnostic
medical devices;
refrigerators up to 0.75 % by(exclusion abolition)weight in the cooling solution
Expires on:— 21 July 2024 for category 9 industrial
monitoring and control instruments, and for
Cr(Ⅵ)
category 11
Applies to categories 1-7 and 10 and expired on 5
Up to 0,75 % hexavalent chromium by weight, used as an anticorrosion agent in the cooling solution ofcarbon steel cooling systems of absorption refrigerators (including minibars) designed to operate fully or March 2021.
partly with electrical heater, having an average utilised power input <75W at constant running conditions (exclusion abolition)

3-1_RoHS Exclusion

No

10/42

Cr(Ⅵ)

Substance

Exemption

Scope and dates of applicability

9(a)-II

Up to 0,75 % hexavalent chromium by weight, used as an anticorrosion agent in the cooling solution ofcarbon steel cooling systems of absorption refrigerators: — designed to operate fully or partly withelectrical heater, having an average utilised power input ≥75 W at constant running conditions, —designed to fully operate with non-electrical heater9(b)Expired on:— 21 July 2021 for categories 8 and 9 other than
the following;
Applies to categories 8, 9 and 11; expires on:— 21 July 2023 for category 8 in vitro diagnostic
Lead in bearing shells and bushes for refrigerant-containing compressors for heating, ventilation, air medical devices,conditioning and refrigeration (HVACR) applications(exclusion abolition)
ー21 July 2024 for category 9 industrial monitoring
and control instruments and for category 11,—21 July 2021 for other subcategories ofcategories 8 and 9.

9(b)(1)

Lead in bearing shells and bushes for refrigerant-containing hermetic scroll compressors with a statedelectrical power input equal or below 9kW for heating, ventilation, air conditioning and refrigeration(HVACR) applications

Applies to category 1; expires on 21 July 2019.’

11(a)Lead used in C-press compliant pin connector systems

Expires on 24 September 2010
(the exclusion abolition)

11(b)Lead used in other than C-press compliant pin connector systems

Expires on 1 Janualy 2013
(the exclusion abolition)

12

Lead as a coating material for the thermal conduction module C-ring

Categories 1-7 and 10;
Remain in force until the decision on extension
application continuously

Pb

Lead in white glasses used for optical applications

13(a)

Cd
Pb

Cadmium and lead in filter glasses and glasses used for reflectance standards

13(b)(I)

Pb

Lead in ion coloured optical filter glass types

13(b)(II)Cd

Cadmium in striking optical filter glass types; excluding applications falling under point 39

Cd
Pb

Cadmium and lead in glazes used for reflectance standards

13(b)13(b)(III)Expires on 24 September 2010
(the exclusion abolition)
Categories 1-7,10 and Categories 8, 9 except for
the following;
Remain in force until the decision on extension
application continuously
Category 8 in vitro diagnostic medical devices;
Expires on 21 July 2023
Category 9 industrial monitoring and control
instruments and Category 11;
Expires on 21 July 2024
Categories 8, 9 except for the following;
Remain in force until the decision on extension
application continuously
Category 8 in vitro diagnostic medical devices;
Expires on 21 July 2023
Category 9 industrial monitoring and control
instruments and Category 11;
Expires on 21 July 2024
Categories 1-7 and 10;
Remain in force until the decision on extension
application continuously
Categories 1-7 and 10;
Remain in force until the decision on extension
application continuously
Categories 1-7 and 10;
Remain in force until the decision on extension
application continuously

14

Lead in solders consisting of more than two elements for the connection
80 % and less than 85 % Expires on 1 Janualy 2011
between the pins and the package of microprocessors with a lead content
by weight(the exclusion abolition)of more than 80% and less than 85% by weight

15

Expires on— 29 Feb 2020 for categories 1-7 and 10(the exclusion abolition)
Categories 8, 9 except for the following;
Lead in solders to complete a viable electrical connection between semiconductor die and carrier Remain in force until the decision on extension
application continuously
within integrated circuit flip chip packages
Category 8 in vitro diagnostic medical devices;
Expires on 21 July 2023
Category 9 industrial monitoring and control
instruments and Category 11;
Expires on 21 July 2024

15(a)Lead in solders to complete a viable electrical connection between the semiconductor die andcarrier within integrated circuit flip chip packages where at least one of the following criteria applies:— a semiconductor technology node of 90 nm or larger;—a single die of 300 mm2 or larger in any semiconductor technology node;—stacked die packages with die of 300 mm2 or larger, or silicon interposers of 300 mm2 or larger.

Categories 1-7 and 10;
Remain in force until the decision on extension
application continuously
Apply from March 1, 2020

16

Lead in linear incandescent lamps with silicate coated tubes

Expired on 1
September 2013

Lead halide as radiant agent in high intensity discharge (HID) lamps used for professional
reprography applications

Cat.1,7 and 10 :Expires on 21 July 2016
Cat. 8 and 9 except for the following:
Expires on 21 July 2021
In vitro diagnostic medical devices:
Expires on 21 July 2023
(the exclusion abolition)
Industrial monitoring and control instruments:
Expires on 21 July 2024

17
Pb

18(a)

18(b)

18(b)-I

Lead as activator in the fluorescent powder (1 % lead by weight or less) of discharge lamps whenused as speciality lamps for diazoprinting reprography, lithography, insect traps, photochemical and ・Expires on 1 January 2011
curing processes containing phosphors such as SMS ((Sr,Ba
Categories 1-7,10 and Categories 8, 9 except for
the following;
Remain in force until the decision on extension
Lead as activator in the fluorescent powder (1% lead by weight or less) of discharge lamps when application continuously
Category 8 in vitro diagnostic medical devices;used as sun tanning lamps containing phosphors such as BSP (BaSi2O5:Pb)
Expires on 21 July 2023
Category 9 industrial monitoring and control
instruments and Category 11;
Expires on 21 July 2024
Category 8 in vitro diagnostic medical devices;
Expired on 21 July 2021
Lead as activator in the fluorescent powder (1 % lead by weight or less) of discharge lamps(exclusion abolition)

containing phosphors such as BSP(BaSi2O5:Pb) when used in medical phototherapy equipment

3-1_RoHS Exclusion

No

11/42

SubsScope and dates of applicability
Exemption
tance Lead as activator in the fluorescent powder (1 % lead by weight or less) of discharge lamps

18(b)-I

containing phosphors such as BSP(BaSi2O5:Pb) when used in medical phototherapy equipment

Categories 5 and 8 (except applications coveredby entry 34 of Annex IV);
Remain in force until the decision on extension
application continuously

19

Lead with PbBiSn-Hg and PbInSn-Hg in specific compositions as main amalgam and with PbSn-Hg as
auxiliary amalgam in very compact energy saving lamps (ESL)

20

Lead oxide in glass used for bonding front and rear substrates of flat fluorescent lamps used for
Expired on 1 June 2011
Liquid Crystal Displays (LCDs)

21

Expired on:- 29 Feb 2020 for categories 1-7 and 10- 21 July 2021 for categories 8 and 9 other than
the following;— 21 July 2023 for category 8 in vitro diagnostic
Lead and cadmium in printing inks for the application of enamels on glasses, such as borosilicate medical devices
and soda lime glasses(exclusion abolition)
expires on:— 21 July 2024 for category 9 industrial
monitoring and control instruments, and for
category 11

Cd
Pb

21(a)

21(c)

Pb

2011

Cadmium when used in colour printed glass to provide filtering functions, used as a component inlighting applications installed in displays and control panels of EEE

Expires on 21 July 2021 for Categories 1 to 7
and 10 except applications covered by entry
21(b) or entry 39

Cadmium in printing inks for the application of enamels on glasses, such as borosilicate and soda lime
glasses

Apply from March 20, 2020
Expires on 21 July 2021 for Categories 1 to 7
and 10 except applications covered by entry
21(a) or 39

Lead in printing inks for the application of enamels on other than borosilicate glasses

Apply from March 20, 2020
expires on 21 July 2021 for categories 1 to 7
and 10Cd21(b)Expired on 1 June

Apply from March 20, 2020
Expires on 24 September 2010
(the exclusion abolition)

23

Lead in finishes of fine pitch components other than connectors with a pitch of 0,65 mm and less

24

Categories 1-7,10 and Categories 8, 9 except for
the following;
Remain in force until the decision on extension
Lead in solders for the soldering to machined through hole discoidal and planar array ceramic application continuously
Category 8 in vitro diagnostic medical devices;multilayer capacitors
Expires on 21 July 2023
Category 9 industrial monitoring and control
instruments and Category 11;
Expires on 21 July 2024

Lead oxide in surface conduction electron emitter displays (SED) used in structural elements,
notably in the seal frit and frit ring25
Pb

Categories1-7 and 10:
Expired on 21 July 2016
Categories 8 and 9 except for the following:
Expired on 21 July 2021
Category 8 in vitro diagnostic medical devices;
Expires on 21 July 2023
(exclusion
abolition)monitoring and control
Category
9 industrial
instruments and Category 11;
Expires on 21 July 2024

26

Lead oxide in the glass envelope of black light blue lamps

27

Lead alloys as solder for transducers used in high-powered (designated to operate for several Expired on 24
hours at acoustic power levels of 125 dB SPL and above) loudspeakers
September 2010

29

Categories 8 and 9 except for the following;
Expired on 21 July 2021
Category 8 in vitro diagnostic medical devices;
Expires on 21 July 2023
Lead bound in crystal glass as defined in Annex I (Categories 1, 2, 3 and 4) of Council Directive (exclusion abolition)
Categories 1- 7,10;
69/493/EEC
Remain in force until the decision on extension
application continuously
Category 9 industrial monitoring and control
instruments and Category 11;
Expires on 21 July 2024

30

Cd

Cadmium alloys as electrical/mechanical solder joints to electrical conductors located directly on
the voice coil in transducers used in high-powered loudspeakers with sound pressure levels of 100
dB (A) and more

Lead in soldering materials in mercury free flat fluorescent lamps (which e.g. are used for liquid
crystal displays, design or industrial lighting)31

Expired on 1 June 2011

Categories1-7 and 10:
Expired on 21 July 2016
Categories 8 and 9 except for the following:
Expired on 21 July 2021
Category 8 in vitro diagnostic medical devices;
Expires on 21 July 2023
(exclusion
abolition)monitoring and control
Category
9 industrial
instruments and Category 11;
Expires on 21 July 2024
Categories1-7 and 10:
Expired on 21 July 2016
Categories 8 and 9 except for the following:
Expired on 21 July 2021
Category 8 in vitro diagnostic medical devices;
Expires on 21 July 2023
(exclusion
abolition)monitoring and control
Category
9 industrial
instruments and Category 11;
Expires on 21 July 2024
Category 8 in vitro diagnostic medical devices;
Expired on 21 July 2023
(exclusion abolition)

32

Lead oxide in seal frit used for making window assemblies for Argon and Krypton laser tubes

Pb

Categories 1-7,10 and Categories 8, 9 except for
the following;
Remain in force until the decision on extension
application continuously
Category 9 industrial monitoring and control
instruments and Category 11;
Expires on 21 July 2024

3-1_RoHS Exclusion

No

12/42

Substance
Pb

Lead in cermet-based trimmer potentiometer elements

34

37

Scope and dates of applicability

Lead in solders for the soldering of thin copper wires of 100 μm diameter and less in powertransformers

33

36

Exemption

Hg

Pb

38

39
39(a)
40

the following;
Remain in force until the decision on extension
application continuously
Category 8 in vitro diagnostic medical devices;
Expires on 21 July 2023
Category 9 industrial monitoring and control
instruments and Category 11;
Expires on 21 July 2024

Mercury used as a cathode sputtering inhibitor in DC plasma displays with a content up to 30 mg Expires on 1 Juｌｙ
per display
2010

Lead in the plating layer of high voltage diodes on the basis of a zinc borate glass body

Cadmium and cadmium oxide in thick film pastes used on aluminium bonded beryllium oxide

Cd

Categories1-7 and 10:
Expired on 21 July 2016
Categories 8 and 9 except for the following:
Expired on 21 July 2021
(exclusion abolition)
Category 8 in vitro diagnostic medical devices;
Expires on 21 July 2023
Category 9 industrial monitoring and control
instruments and Category 11;
Expires on1-7,10
21 July
2024
Categories
andCategories 8, 9 except for

Categories1-7 and 10:
Expired on 21 July 2021
Categories 8 and 9 other than the following:
Expired on 21 July 2021
— 21 July 2023 for category 8 in vitro diagnostic
medical devices(exclusion abolition)
Expires on:— 21 July 2024 for category 9 industrial
monitoring and control instruments, and for
category 11

Categories1-7 and 10:
Expired on 21 July 2016
Categories 8 and 9 except for the following:
Expired on 21 July 2021
Category 8 in vitro diagnostic medical devices;
Expires on 21 July 2023
(exclusion
abolition)monitoring and control
Category
9 industrial

instruments and Category 11;
Expires on 21 July 2024
Cadmium in colour converting II-VI LEDs (< 10 μ g Cd per mm2 of light-emitting area) for use in
Expires on 1 July 2014solid state illumination or display systems
Cadmium selenide in downshifting cadmium-based semiconductor nanocrystal quantum dots for
Remain in force until the decision on extension
use in display lighting applications (< 0,2 μg Cd per mm2 of display screen area)
application continuously
Expires on 31
Cadmium in photoresistors for analogue optocouplers applied in professional audio equipment
December 2013
Applies to all categories and expires on:- 31 March 2022 for categories 1 to 7, 10 and 11;

Lead in solders and termination finishes of electrical and electronic components and finishes of - 21 July 2021 for categories 8 and 9 other than inprinted circuit boards used in ignition modules and other electrical and electronic engine control vitro diagnostic medical devices and industrial
monitoring and control instruments;
systems, which for technical reasons must be mounted directly on or in the crankcase or cylinder ofhand-held combustion engines (classes SH:1, SH:2, SH:3 of Directive 97/68/EC of the European - 21 July 2023 for category 8 in vitro diagnostic
medical devices;
Parliament and of the Council

41

Pb

42

43

Applies to all categories and expires on:— 21 July 2024 for category 9 industrial
monitoring and control instruments.

Lead in bearings and bushes of diesel or gaseous fuel powered internal combustion engines
applied in non-road professional use equipment:— with engine total displacement ≥ 15 litres; orExpires on 21 July 2024 for Category 11,— with engine total displacement < 15 litres and the engine is designed to operate in applications
excluding applications covered by entry 6(c )where the time between signal to start and full load is required to be less than 10 seconds; orregular maintenance is typically performed in a harsh and dirty outdoor environment, such as
mining, construction, and agriculture applications.
Bis (2-ethylhexyl) phthalate in rubber components in engine systems, designed for use in equipmentthat is not intended solely for consumer use and provided that no plasticised material comes into
contact with human mucous membranes or into prolonged contact with human skin and theconcentration value of bis(2-ethylhexyl) phthalate does not exceed:(a) 30% by weight of the rubber for(i) gasket coatings;
Applies to category 11 and expires on 21 July
DEHP(ii) solid-rubber gaskets; or2024(iii) rubber components included in assemblies of at least three components using electrical,
mechanical or hydraulic energy to do work, and attached to the engine.
(b) 10% by weight of the rubber, for rubber-containing components not referred to in point (a).
For the purposes of this entry, ‘ prolonged contact with human skin’ means continuous contact ofmore than 10 minutes duration or intermittent contact over a period of 30 minutes, per day.

44

Pb

Lead in solder of sensors, actuators, and engine control units (ECUs) of combustion engines within
the scope of Regulation (EU) 2016/1628 of the European Parliament and of the Council , installed in Applies to category 11 and expires on 21 Julyequipment used at fixed positions while in operation which is designed for professionals, but also 2024
used by non-professional users

45

Pb
Cr

Lead diazide, lead styphnate, lead dipicramate, orange lead (lead tetroxide), lead dioxide in electricand electronic initiators of explosives for civil (professional) use and barium chromate in long time Expires on 20 April 2026
pyrotechnic delay charges of electric initiators of explosives for civil (professional) use（Disclaimers）
PROTERIAL group does not guarantee any contents in exemption of RoHSⅡ described above.
Please refer to the original law text regarding the latest information.

3-2_RoHS Exclusion（Annex4)

13/42

Appendix 3-2. The exemptions of RoHSⅡ Annex4(The exemptions of category 8&9)
rev.1.0/2023.1.4

No.

Exemption

Equipment utilising or detecting ionising radiation
1
2

Lead, cadmium and mercury in detectors for ionising radiation.
Lead bearings in X-ray tubes.
Lead in electromagnetic radiation amplification devices: micro-channel plate

3 and capillary plate.

4

5
6
7
8

Lead in glass frit of X-ray tubes and image intensifiers and lead in glass fritbinder for assembly of gas lasers and for vacuum tubes that convert
electromagnetic radiation into electrons.
Expires on 21 July 2021 for medical devices other than in-vitro diagnostic
medical devices and industrial instruments other than monitoring and control
Lead in shielding for ionising radiation.
Lead in X-ray test objects.
Expires on 21 July 2021 for medical devices other than in-vitro diagnostic
medical devices and industrial instruments other than monitoring and control
Lead stearate X-ray diffraction crystals.
Expires on 21 July 2021 for medical devices other than in-vitro diagnostic
medical devices and industrial instruments other than monitoring and control
Radioactive cadmium isotope source for portable X-ray fluorescence
spectrometers.
Expires on 21 July 2021 for medical devices other than in-vitro diagnostic

Sensors, detectors and electrodes
1a
1b
1c

Lead and cadmium in ion selective electrodes including glass of pH electrodes.
Lead anodes in electrochemical oxygen sensors.
Lead, cadmium and mercury in infra-red light detectors.

Mercury in reference electrodes: low chloride mercury chloride, mercury
sulphate and mercury oxide.
1d
Expires on 21 July 2021 for medical devices other than in-vitro diagnostic
medical devices and industrial instruments other than monitoring and control

OthersCadmium in helium-cadmium lasers.

9 Expires on 21 July 2021 for medical devices other than in-vitro diagnostic
medical devices and industrial instruments other than monitoring and control
Lead and cadmium in atomic absorption spectroscopy lamps.
10 Expires on 21 July 2021 for medical devices other than in-vitro diagnostic
medical devices and industrial instruments other than monitoring and control
Lead in alloys as a superconductor and thermal conductor in MRI.

11

Lead and cadmium in metallic bonds creating superconducting magnetic
circuits in MRI, SQUID, NMR (Nuclear Magnetic Resonance) or FTMS (Fourier
12 Transform Mass Spectrometer) detectors.
Expires on 21 July 2021 for medical devices other than in-vitro diagnostic
medical devices and industrial instruments other than monitoring and control
Lead in counterweights.

13
14
15

Lead in single crystal piezoelectric materials for ultrasonic transducers.
Lead in solders for bonding to ultrasonic transducers.

Mercury in very high accuracy capacitance and loss measurement bridges andin high frequency RF switches and relays in monitoring and control instruments
16 not exceeding 20 mg of mercury per switch or relay.
Expires on 21 July 2021 for medical devices other than in-vitro diagnostic
medical devices and industrial instruments other than monitoring and control
17 Lead in solders in portable emergency defibrillators.

3-2_RoHS Exclusion（Annex4)

No.
18

19
20
21

22

23
24

25

26

27

14/42

Exemption
Lead in solders of high performance infrared imaging modules to detect in therange 8-14 μm.
Expires on 21 July 2021 for medical devices other than in-vitro diagnostic
medical devices and industrial instruments other than monitoring and control
Lead in Liquid crystal on silicon (LCoS) displays.
Expires on 21 July 2021 for medical devices other than in-vitro diagnostic
medical devices and industrial instruments other than monitoring and control
Cadmium in X-ray measurement filters.
Expires on 21 July 2021 for medical devices other than in-vitro diagnostic
medical devices and industrial instruments other than monitoring and control
Cadmium in phosphor coatings in image intensifiers for X-ray images until 31
December 2019 and in spare parts for X-ray systems placed on the EU market
before 1 January 2020.
Lead acetate marker for use in stereotactic head frames for use with CT and
MRI and in positioning systems for gamma beam and particle therapy
equipment.
Expires on 30 June 2021.
Lead as an alloying element for bearings and wear surfaces in medical
equipment exposed to ionising radiation.
Expires on 30 June 2021.
Lead enabling vacuum tight connections between aluminium and steel in X-ray
image intensifiers.
Expires on 31 December 2019.
Lead in the surface coatings of pin connector systems requiring nonmagnetic
connectors which are used durably at a temperature below – 20 ° C undernormal operating and storage conditions.
Expires on 30 June 2021.
Lead in— solders on printed circuit boards,— termination coatings of electrical and electronic components and coatings ofprinted circuit boards,— solders for connecting wires and cables,— solders connecting transducers and sensors,that are used durably at a temperature below – 20 ° C under normal operating
and storage conditions.
Lead in solders of electrical connections to temperature measurement sensors
in devices which are designed to be used periodically at temperatures below –150 °C.
Expires on 30 June 2021.
For in-vitro diagnostic medical devices; Expires on 30 June 2021
For others in Categories 8 and 9; Remain in force until the decision on
Lead in— solders,— termination coatings of electrical and electronic components and printed
circuit boards,— connections of electrical wires, shields and enclosed connectors,
which are used in(a) magnetic fields within the sphere of 1 m radius around the isocentre of themagnet in medical magnetic resonance imaging equipment, including patientmonitors designed to be used within
this sphere, or(b) magnetic fields within 1 m distance from the external surfaces ofcyclotron magnets, magnets for beam transport and beam direction control
applied for particle therapy.
Lead in solders for mounting cadmium telluride and cadmium zinc telluride

28 digital array detectors to printed circuit boards.
Expires on 31 December 2017.

3-2_RoHS Exclusion（Annex4)

No.

15/42

Exemption

Lead in alloys, as a superconductor or thermal conductor, used in cryo-cooler
cold heads and/or in cryo-cooled cold probes and/or in cryo-cooled
equipotential bonding systems, in medical devices (category 8) and/or in
29 industrial monitoring and control instruments.
Expires on 30 June 2021.
For others in Categories 8 and 9; Remain in force until the decision on
extension application continuously.
Hexavalent chromium in alkali dispensers used to create photocathodes in X30 ray image intensifiers until 31 December 2019 and in spare parts for X-ray
systems placed on the EU market before 1 January 2020.
Lead, cadmium, hexavalent chromium, and polybrominated diphenyl ethers(PBDE) in spare parts recovered from and used for the repair or refurbishmentof medical devices, including in vitro diagnostic medical devices, or electron
microscopes and their accessories, provided that the reuse takes place inauditable closed-loop business-to-business return systems and that eachreuse of parts is notified to the customer.
31a
For the use in medical devices other than in vitro diagnostic medical devices;
Remain in force until the decision on extension application continuously
For the use in in vitro diagnostic medical devices; Remain in force until thedecision on extension application continuously
For the use in electron microscopes and their accessories; Expires on 21 July
2024.
Lead in solders on printed circuit boards of detectors and data acquisition units
for Positron Emission Tomographs which are integrated into Magnetic
32
Resonance Imaging equipment.
Expires on 31 December 2019.
Lead in solders on populated printed circuit boards used in Directive
93/42/EEC class IIa and IIb mobile medical devices other than portable
33
emergency defibrillators.
Expires on

34

35

36

37

30 June 2016 for class IIa
31 December 2020 for class IIb.
Lead as an activator in the fluorescent powder of discharge lamps when used
for extracorporeal photopheresis lamps containing BSP (BaSi 2 O 5 :Pb)
phosphors.
Mercury in cold cathode fluorescent lamps for back-lighting liquid crystal
displays, not exceeding 5 mg per lamp,
used in industrial monitoring and control instruments placed on the market
before 22 July 2017
Expires on 21 July 2024.
Lead used in other than C-press compliant pin connector systems for industrial
monitoring and control instruments.
Expires on 31 December 2020.
May be used after that date in spare parts for industrial monitoring and control
instruments placed on the market before 1 January 2021.
Lead in platinized platinum electrodes used for conductivity measurements
where at least one of the following conditions applies:(a) wide-range measurements with a conductivity range
covering more than 1 order of magnitude (e.g. range between 0,1 mS/mand 5 mS/m) in laboratory applications for unknown concentrations;(b) measurements of solutions where an accuracy of +/– 1 % of the sample
range and where high corrosion resistance of the electrode are required forany of the following:(i) solutions with an acidity < pH 1;(ii) solutions with an alkalinity > pH 13;(iii) corrosive solutions containing halogen gas;(c) measurements of conductivities above 100 mS/m that must be performed
with portable instruments.
Expires on 31 December 2025.

3-2_RoHS Exclusion（Annex4)

No.

16/42

Exemption

Lead in solder in one interface of large area stacked die elements with morethan 500 interconnects per interface which are used in X-ray detectors ofcomputed tomography and X-ray systems.
38 Expires on 31 December 2019.
May be used after that date in spare parts for CT and X-ray systems placed on
the market before 1 January 2020.
Lead in micro-channel plates (MCPs) used in equipment where at least one of
the following properties is present:(a) a compact size of the detector for electrons or ions, where the space for thedetector is limited to a maximum of 3 mm/MCP(detector thickness + space for installation of the MCP), a maximum of 6 mm
in total, and an alternative design yielding more space forthe detector is scientifically and technically impracticable;(b) a two-dimensional spatial resolution for detecting electrons or ions,where at least one of the following applies:(i) a response time shorter than 25 ns;
39(ii) a sample detection area larger than 149 mm2;(iii) a multiplication factor larger than 1,3 × 103.
(c) a response time shorter than 5 ns for detecting electrons or ions;(d) a sample detection area larger than 314 mm2 for detecting electrons orions;(e) a multiplication factor larger than 4,0 × 107.

40

41

42

43

44

45
46

47

The exemption expires on the following dates:(a) 21 July 2021 for medical devices and monitoring and control instruments;
Lead in dielectric ceramic in capacitors for a rated voltage of less than 125 V
AC or 250 V DC for industrial monitoring and control instruments.
Expires on 31 December 2020.
May be used after that date in spare parts for industrial monitoring and control
instruments placed on the market
before 1 January 2021.
Lead as a thermal stabiliser in polyvinyl chloride (PVC) used as base material
in amperometric, potentiometric and conductometric electrochemical sensors
which are used in in-vitro diagnostic medical devices for the analysis of bloodand other body fluids and body gases.
Expires on 31 Dec 2018.
⇒Remain in force until the decision on extension application continuously
Mercury in electric rotating connectors used in intravascular ultrasound imaging
systems capable of high operating frequency (> 50 MHz) modes of operation.
Expires on 30 June 2019.
Remain in force until the decision on extension application continuously
Cadmium anodes in Hersch cells for oxygen sensors used in industrial
monitoring and control instruments, where sensitivity below 10 ppm isrequired.
Expires on 15 July 2023.
Cadmium in radiation tolerant video camera tubes designed for cameras
with a centre resolution greater than 450 TV lines which are used inenvironments with ionising radiation exposure exceeding 100 Gy/hour
and a total dose in excess of 100kGy. Applies to category 9. Expires on
Bis(2-ethylhexyl) phthalate (DEHP) in ion-selective electrodes applied inpoint of care analysis of ionic substances present in human body fluids
and/or in dialysate fluids.
Expires on: 21 July 2028
Bis(2-ethylhexyl) phthalate (DEHP) in plastic components in MRI detector
coils.
Bis(2-ethylhexyl) phthalate (DEHP), butyl benzyl phthalate (BBP), dibutyl
phthalate (DBP) and diisobutyl phthalate (DIBP) in spare parts recoveredfrom and used for the repair or refurbishment of medical devices,
including in vitro diagnostic medical devices, and their accessories,
provided that the reuse takes place in auditable closed-loop business-tobusiness return systems and that each reuse of parts is notified to thecustomer.

（Disclaimers）

3-2_RoHS Exclusion（Annex4)

No.

17/42

Exemption

PROTERIAL group does not guarantee any contents in exemption of RoHSⅡ described above.
Please refer to the original law text regarding the latest information.

4_Ozon

18/42

Appendix 4. Ozone depleting substances
rev..0 2021.11.01
Montreal Protocol
Class Annex Group
Ⅰ

Ⅰ

Ⅰ

A

A

B

Ⅰ

Ⅱ

Ⅰ

Ⅰ
Ⅰ
Ⅰ
Ⅰ

B
B
C
E

Ⅱ
Ⅲ
Ⅲ
Ⅰ

Ⅰ

C

Ⅱ

Sample substances

Chemical formula Sample CAS No

CFC [Chlorofluorocarbon]
CFCl3
CFC-11Trichlorofluoromethane
CF2Cl2
CFC-12
Dichlorodifluoromethane
C2F3Cl3
CFC-113Trichlorotrifluoroethane (CFC-113)
1,1,2-Trichloro-1,2,2-trifluoroethane (CFC-113)(CAS No 76-13-1)
1,1,1-Trichloro-2,2,2-trifluoroethane (CFC-113a)(CAS No 354-58-5)
Trichlorotrifluoroethane (CFC-113) (CAS No 26523-64-8)
C2F4Cl2
CFC-114
Dichlorotetrafluoroethane (CFC-114)
1,2-Dichloro-1,1,2,2-tetrafluoroethane (CFC-114)(CAS No 76-14-2)
1,1-Dichloro-1,2,2,2-tetrafluoroethane (CFC-114a) (CAS No 1320-37-2, 374Dichlorotetrafluoroethane (CFC-114) (CAS No 1320-37-2, 374-07-2)
C2F5Cl
CFC-115Chloropentafluoroethane (CFC-115)
1-Chloro-1,1,2,2,2-pentafluoroethane (CFC-115)
Halon
CF2BrCl
Halon-1211
Bromochlorodifluoromethane
CF3Br
Halon-1301
Bromotrifluoromethane
C2F4Br2
Halon-2402
Dibromotetrafluoroethane
1,2-Dibromo-1,1,2,2-tetrafluoroethane (CAS No 124-73-2)
2,2-Dibromo-1,1,1,2-tetrafluoroethane (CAS No 27336-23-8)
Dibromotetrafluoroethane (CAS No 25497-30-7)
Other completely halogenated CFC
CF3Cl
CFC-13Chlorotrifluoromethane
C2FCl5
CFC-111
Pentachlorofluoroethane (CFC-111) (CAS No 354-56-3)
1,1,1,2,2-Pentachloro-2-fluoroethane (CAS No 354-56-3, 29756-45-4)
1,1,2,2,2-Pentachloro-1-fluoroethane (CAS No 354-56-3)
Chlorofluorocarbon-111 (CAS No 954-56-3)
C2F2Cl4
CFC-112
Tetrachlorodifluoroethane (CFC-112)
1,1,2,2-Tetrachloro-1,2-difluoroethane (CFC-112) (CAS No 76-12-0)
1,1,1,2-Tetrachloro-2,2-difluoroethane (CFC-112a) (CAS No 76-11-9)
C3FCl7
CFC-211Heptachlorofluoropropane (CFC-211)
1,1,1,2,2,3,3-Heptachloro-3-fluoropropane (CFC-211aa) (CAS No 422-78-6)
1,1,1,2,3,3,3-Heptachloro-2-fluoropropane (CFC-211ba) (CAS No 422-81-1)
Heptachlorofluoropropane (CFC-211) (CAS No 135401-87-5)
C3F2Cl6
CFC-212
Hexachlorodifluoropropane (CFC-212)
1,1,1,3,3,3-Hexachloro-2,2-difluoropropane (HCFC-212) (CAS No 3182-26-1)
Hexachlorodifluoropropane (CFC-212) (CAS No 134452-44-1)
C3F3Cl5
CFC-213
Pentachlorotrifluoropropane (CFC-213)
1,1,1,3,3-Pentachloro-2,2,3-trifluoropropane (CFC-213) (CAS No 2354-06-5)
Pentachlorotrifluoropropane (CFC-213) (CAS No 134237-31-3)
C3F4Cl4
CFC-214
Tetrachlorotetrafluoropropane (CFC-214)
1,2,2,3-Tetrachloro-1,1,3,3-tetrafluoropropane (CFC-214aa) (CAS No 677-681,1,1,3-Tetrachloro-2,2,3,3-tetrafluoropropane (CFC-214cb) (CAS No 2268Tetrachlorotetrafluoropropane (CFC-214) (CAS No 29255-31-0, Mixed
C3F5Cl3
CFC-215
Trichloropentafluoropropane (CFC-215)
1,2,2-Trichloro-1,1,3,3,3-pentafluoropropane (CFC-215aa) (CAS No 1599-411,2,3-Trichloro-1,1,2,3,3-pentafluoropropane (CFC-215ba) (CAS No 76-17-5)
1,1,2-Trichloro-1,2,3,3,3-pentafluoropropane (CFC-215bb) (CAS No 812-30-6)
1,1,3-Trichloro-1,2,2,3,3-pentafluoropropane (CFC-215ca) (CAS No 1652-811,1,1-Trichloro-2,2,3,3,3-pentafluoropropane (CFC-215cb) (CAS No 4259-43C3F6Cl2
CFC-216
Dichlorohexafluoropropane
1,2-Dichloro-1,1,2,3,3,3-hexafluoropropane (CFC-216ba) (CAS No 661-97-2)
1,3-Dichloro-1,1,2,2,3,3-hexafluoropropane (CFC-216ca) (CAS No 662-01-1)
C3F7Cl
CFC-217
Chloroheptafluoropropane (CFC-217)
2-Chloro-1,1,1,2,3,3,3-heptafluoropropane (CFC-217ba) (CAS No 76-18-6)
1-Chloro-1,1,2,2,3,3,3-heptafluoropropane (CFC-217ca) (CAS No 422-86-6)
CCl4
CFC-10Carbon tetrachloride－
C2H3Cl3
1,1,1-Trichloroethane (1,1,2-Trichloroethane is excepted)－－
CH2BrCl
Halon-1011
Bromochloromethane－
CH3Br
Halon-1001
Methyl bromide－
Bromomethane
HBFC [Hydrobromofluorocarbon]
CHFBr2
Halon-1102
Dibromofluoromethane (HBFC-21 B2)CHF2BrHalon-1201
Bromodifluoromethane (HBFC-22 B1)CH2FBrHalon-1101
Bromofluoromethane (HBFC-31 B1)C2HFBr4
Halon-2104
Tetrabromofluoroethane (HBFC-121 B4)
1,1,2,2-Tetrabromo-1-fluoroethane (CAS No 306-80-9)
Tetrabromofluoroethane (CAS No 353-93-5)
C2HF2Br3
Halon-2203
Tribromodifluoroethane (HBFC-122 B3)
1,1,2-Tribromo-1,2-difluoroethane (CAS No 353-97-9)
1,2,2-Tribromo-1,1-difluoroethane (CAS No 677-34-9)
Tribromodifluoroethane (CAS No 7304-53-2)
C2HF3Br2
Halon-2302
Dibromotrifluoroethane (HBFC-123 B2)
1,2-Dibromo-1,1,2-trifluoroethaneC2HF4Br
Halon-2401
Bromotetrafluoroethane (HBFC-124B1)
2-Bromo-1,1,1,2-trafluoroethane (CAS No 124-72-1)
1-Bromo-1,2,2,2-trafluoroethane (CAS No 354-07-4)
C2H2FBr3
Halon-2103
Tribromofluoroethane (HBFC-131B3)
1,1,2-tribromo-1-fluoroethane (CAS No 420-88-2)
1,1,2-tribromo-2-fluoroethane (CAS No 598-67-4)
C2H2F2Br2
Halon-2202
Dibromodifluoroethane (HBFC-132 B2)
1,2-Dibromo-1,1-difluoroethane (CAS No 75-82-1)
1,1-Dibromo-2,2-difluoroethane (CAS No 359-19-3, 430-85-3)
C2H2F3Br
Halon-2301
Bromotrifluoroethane (HBFC-133B1)
1-Bromo-2,2,2-trifluoroethane (HBFC-133a B1)(CAS No 421-06-7)
2-Bromo-1,1,1-trifluoroethane (HBFC-133a B1)(CAS No 421-06-7)
C2H3FBr2
Halon-2102
Dibromofluoroethane (HBFC-141 B2)
1,2-Dibromo-1-fluoroethane
C2H3F2Br
Halon-2201
Bromodifluoroethane (HBFC-142 B1)
2-Bromo-1,1-difluoroethane
C2H4FBr
Halon-2101
Bromofluoroethane (HBFC-151 B1)
1-Bromo-2-fluoroethane
C3HFBr6
Halon-3106
Hexabromofluoropropane (HBFC-221 B6)
C3HF2Br5
Halon-3205
Pentabromodifluoropropane (HBFC-222 B5)

75-69-4
75-71-826523-64-8
354-58-5
76-13-1
1320-37-2
374-07-2
76-14-2
76-15-3

353-59-3
75-63-8
124-73-2
25497-30-7
27336-23-8

75-72-9354-56-3
954-56-3
29756-45-4
76-11-9
76-12-0422-78-6
422-81-1
135401-87-5
134452-44-1
3182-26-1
134237-31-3
2354-06-5
2268-46-4
29255-31-0
677-68-9
1599-41-3
1652-81-94259-43-2
76-17-5
812-30-6
661-97-2
662-01-1
422-86-6
76-18-6
56-23-5
71-55-6
74-97-5
74-83-9

1868-53-7
1511-62-2
373-52-4
306-80-9
353-93-5
353-97-9
677-34-9
7304-53-2
354-04-1
124-72-1
354-07-4
420-88-2
598-67-4
359-19-3
430-85-3
75-82-1
421-06-7

358-97-4
359-07-9
762-49-2

4_Ozon

19/42

Montreal Protocol
Class Annex Group

Sample substances
Halon-3304
Halon-3403
Halon-3502
Halon-3601

Halon-3105
Halon-3204
Halon-3303
Halon-3402
Halon-3501

Halon-3104
Halon-3203
Halon-3302

Halon-3401

Halon-3103
Halon-3202
Halon-3301

Halon-3102

Halon-3201

C

Ⅰ

C3HF3Br4
C3HF4Br3C3HF5Br2

Tetrabromofluoropropane (HBFC-241 B4)
1,1,1,3-tetrabromo-3-fluoropropane
Tribromodifluoropropane (HBFC-242 B3)
1,1,1-Tribromo-2,2-difluoropropane (CAS No 70192-80-2)
Dibromotrifluoropropane (HBFC-243 B2)
2,3-Dibromo-1,1,1-trifluoropropane (CAS No 431-21-0)
1,2-Dibromo-3,3,3-trifluoropropane (CAS No 431-21-0)
Bromotetrafluoropropane (HBFC-244 B1)
2-Bromo-1,1,1,3-tetrafluoropropane (CAS No 29151-25-5)
3-Bromo-1,1,1,3-tetrafluoropropane (CAS No 460-67-3)
3-Bromo-1,1,2,2-tetrafluoropropane (CAS No 679-84-5)
1-Bromo-1,1,2,2-tetrafluoropropane (CAS No 70192-84-6)

C3H3FBr4

Tribromofluoropropane (HBFC-251 B1)
1,2,3-Tribromo-1-fluoropropane
Dibromodifluoropropane (HBFC-252 B2)
1,3-Dibromo-1,1-difluoropropane (CAS No 460-25-3)
Bromotrifluoropropane (HBFC-253 B1)
3-Bromo-1,1,1-trifluoropropane (CAS No 460-32-2)
2-Bromo-1,1,1-trifluoropropane (CAS No 421-46-5)
Dibromofluoropropane (HBFC-261 B2)
1,3-Dibromo-2-fluoropropane (CAS No 1786-38-5)
1,2-Dibromo-3-fluoropropane (CAS No 453-00-9)
1,3-Dibromo-1-fluoropropane (CAS No 51584-26-0)
1,2-Dibromo-1-fluoro-(R*,R*)-propane (CAS No 62135-11-9)
1,2-Dibromo-1-fluoro-(R*,S*)-propane (CAS No 62135-10-8)
Bromodifluoropropane (HBFC-262 B1)
1-Bromo-2,3-difluoropropane (CAS No 111483-20-6)
2-Bromo-1,3-difluoropropane (CAS No 2195-05-3)
1-Bromo-2,2-difluoropropane (CAS No 420-98-4)
3-Bromo-1,1-difluoropropane (CAS No 461-49-4)

C3H4FBr3

19041-01-1
29151-25-5
460-67-3
679-84-5
70192-71-1
70192-84-6
75372-14-4

C3H4F2Br2

460-25-3

C3H4F3Br

421-46-5
460-32-2

C3H5FBr2

1786-38-5
453-00-951584-26-0
62135-10-8
62135-11-9

C3H5F2Br

111483-20-6
2195-05-3
420-89-3
420-98-4
430-87-5
461-49-4
1871-72-3
352-91-0

C3HF6Br

666-48-8
431-78-7
2252-78-0
2252-79-1

C3H2FBr5C3H2F2Br4

148875-98-3

C3H2F3Br3

421-90-9

C3H2F4Br2

460-86-6

C3H2F5Br

22692-16-6
26391-11-7
422-01-5
460-88-853692-43-6
53692-44-7
677-52-1
677-53-2
679-94-7
148875-95-0

C3H3F2Br3
C3H3F3Br2

C3H3F4Br

C3H6FBr
Bromofluoropropane (HBFC-271 B1)
1-Bromo-2-fluoropropane (CAS No 1871-72-3)
1-Bromo-3-fluoropropane (CAS No 352-91-0)
HCFC [Hydrochlorofluorocarbon]
CHFCl2
HCFC-21
Dichlorofluoromethane
CHF2Cl
HCFC-22Chlorodifluoromethane
CH2FCl
HCFC-31Chlorofluoromethane
C2HFCl4
HCFC-121
Tetrachlorofluoroethan (HCFC-121)
1,1,2,2-Tetrachloro-1-fluoroethan (HCFC-121) (CAS No 354-14-3, 134237-321,1,1,2-Tetrachloro-2-fluoroethan (HCFC 121a) (CAS No 354-11-0)
C2HF2Cl3
HCFC-122
Trichlorodifluoroethane (HCFC-122)
1,2,2-Trichloro-1,1-difluoroethane (HCFC-122) (CAS No 354-21-2, 134237-331,1,2-Trichloro-1,2-difluoroethane (HCFC-122a) (CAS No 354-15-4)
1,1,1-Trichloro-2,2-difluoroethane (HCFC-122b) (CAS No 354-12-1)
Trichlorodifluoroethane (HCFC-122) (CAS No 354-15-4, 354-21-2, 134237-33C2HF3Cl2
HCFC-123
Dichlorotrifluoroethane (HCFC-123)
CHCl2CF3 (*)
2,2-Dichloro-1,1,1-trifluoroethane (HCFC-123) (CAS No 306-83-2)
1,2-Dichloro-1,1,2-trifluoroethane (HCFC-123a) (CAS No 354-23-4)
1,1-Dichloro-1,2,2-trifluoroethane (HCFC-123b) (CAS No 812-04-4)
Dichlorotrifluoroethane (HCFC-123) (CAS No 34077-87-7)
C2HF4Cl
HCFC-124
Chlorotetrafluoroethane (HCFC-124)
CHFClCF3 (*)
2-Chloro-1,1,1,2-tetrafluoroethane (HCFC-124) (CAS No 2837-89-0)
1-Chloro-1,1,2,2-tetrafluoroethane (HCFC-124a) (CAS No 354-25-6)
Chlorotetrafluoroethane (HCFC-124) (CAS No 63938-10-3)
C2H2FCl3
HCFC-131
Trichlorofluoroethane (HCFC-131)
1,1,2-Trichloro-2-fluoroethane (HCFC-131) (CAS No 359-28-4, 134237-34-6)
1,1,2-Trichloro-1-fluoroethane (HCFC-131a) (CAS No 811-95-0)
1,1,1-Trichloro-2-fluoroethane (HCFC-131b) (CAS No 2366-36-1)
Trichlorofluoroethane (HCFC-131) (CAS No 27154-33-2)
C2H2F2Cl2
HCFC-132
Dichlorodifluoroethane (HCFC-132)
1,2-Dichloro-1,2-difluoroethane (HCFC-132) (CAS No 431-06-1)
1,1-Dichloro-2,2-difluoroethane (HCFC-132a) (CAS No 471-43-2)
1,2-Dichloro-1,1-difluoroethane (HCFC-132b) (CAS No 1649-08-7)
1,1-Dichloro-1,2-difluoroethane (CAS No 1842-05-3)
Dichlorodifluoroethane (HCFC-132) (CAS No 25915-78-0)
C2H2F3Cl
HCFC-133
Chlorotrifluoroethane (HCFC-133)
1-Chloro-1,2,2-trifluoroethane (HCFC-133) (CAS No 431-07-2)
2-Chloro-1,1,1-trifluoroethane (HCFC-133a) (CAS No 75-88-7)
1-Chloro-1,1,2-trifluoroethane (HCFC-133b) (CAS No 421-04-5)
Chlorotrifluoroethane (HCFC-133) (CAS No 1330-45-6)
Halon-3101

Ⅱ

Chemical formula Sample CAS No

Tetrabromotrifluoropropane (HBFC-223 B4)Tribromotetrafluoropropane (HBFC-224 B3)
Dibromopentafluoropropane (HBFC-225 B2)
1,2-Dibromo-1,1,3,3,3-pentafluoropropane
Bromohexafluoropropane (HBFC-226 B1)
1-Bromo-1,1,2,3,3,3-hexafluoropropane (CAS No 2252-78-0)
2-Bromo-1,1,1,3,3,3-hexafluoropropane (CAS No2252-79-1)
Pentabromofluoropropane (HBFC-231 B5)Tetrabromodifluoropropane (HBFC-232 B4)
1,1,1,3-Tetrabromo-3,3-difluoropropane
Tribromotrifluoropropane (HBFC-233 B3)
2,2,3-Tribromo-1,1,1-trifluoropropane (CAS No 421-90-9)
Dibromotetrafluoropropane (HBFC-234 B2)
1,3-Dibromo-1,1,3,3-tetrafluoropropane
Bromopentafluoropropane (HBFC-235 B1)
3-bromo-1,1,1,2,2-pentafluoropropane (CAS No 422-01-5)
1-bromo-1,1,3,3,3-pentafluoropropane (CAS No 460-88-8)
1-bromo-1,1,2,2,3-pentafluoropropane (CAS No 677-53-2)
1-bromo-1,2,2,3,3-pentafluoropropane (CAS No 679-94-7)

666-25-1
70192-80-2
431-21-0

75-43-4
75-45-6
593-70-4
134237-32-4
354-11-0
354-14-3
354-12-1
354-15-4
354-21-2

306-83-2
34077-87-7
354-23-4
812-04-4
2837-89-0
354-25-6
63938-10-3
134237-34-6
2366-36-1
27154-33-2
359-28-4
811-95-0
1649-08-7
1842-05-3
25915-78-0
431-06-1
471-43-2
1330-45-6
421-04-5
431-07-2
75-88-7

4_Ozon

20/42

Montreal Protocol
Class Annex Group

Sample substances
HCFC-141

Dichlorofluoroethane (HCFC-141)

Chemical formula Sample CAS No
C2H3FCl2
CH3CFCl2 (*)

1,2-Dichloro-1-fluoroethane (HCFC-141) (CAS No 430-57-9)
1,1-Dichloro-2-fluoroethane (HCFC-141a) (CAS No 430-53-5)
1,1-Dichloro-1-fluoroethane (HCFC-141b) (CAS No 1717-00-6)
Dichlorofluoroethane (HCFC-141) (CAS No 25167-88-8)
HCFC-142

HCFC-151

HCFC-221

HCFC-222

HCFC-223

Chlorodifluoroethane (HCFC-142)
2-Chloro-1,1-difluoroethane (HCFC-142) (CAS No 338-65-8)
1-Chloro-1,2-difluoroethane (HCFC-142a) (CAS No 338-64-7)
1-Chloro-1,1-difluoroethane (HCFC-142b) (CAS No 75-68-3)
Chlorodifluoroethane (HCFC-142) (CAS No 25497-29-4)
Chlorofluoroethane (HCFC-151)
1-Chloro-2-fluoroethane (HCFC-151) (CAS No 762-50-5)
1-Chloro-1-fluoroethane (HCFC-151a) (CAS No 1615-75-4)
Chlorofluoroethane (HCFC-151) (CAS No 110587-14-9)
Hexachlorofluoropropane (HCFC-221)
1,1,1,2,2,3-Hexachloro-3-fluoropropane (HCFC-221ab) (CAS No 422-26-4)
Hexachlorofluoropropane (HCFC-221) (CAS No 134237-35-7)
Pentachlorodifluoropropane (HCFC-222)
1,2,2,3,3-Pentachloro-1,1-difluoropropane (HCFC-222aa) (CAS No 422-30-0)
1,1,1,3,3-Pentachloro-2,2-difluoropropane (HCFC-222ca) (CAS No 422-49-1)
Pentachlorodifluoropropane (HCFC-222) (CAS No 134237-36-8)
Tetrachlorotrifluropropane (HCFC-223)

25167-88-8
430-53-5
430-57-9
C2H3F2Cl
CH3CF2Cl (*)

Trichlorotetrafluoropropane (HCFC-224)

C2H4FCl762-50-5
1615-75-4
110587-14-9

C3HFCl6134237-35-7
422-26-4

C3HF2Cl5

134237-36-8
422-30-0
422-49-1

C3HF3Cl4

134237-37-9
422-52-6
134237-38-0
422-51-5
422-54-8

C3HF4Cl3

1,3,3-Trichloro-1,1,2,2-tetrafluoropropane (HCFC-224ca) (CAS No 134237-38-0, 422-54-8)

1,1,1-Trichloro-2,2,3,3-tetrafluoropropane (HCFC-224cc) (CAS No 422-51-5)
HCFC-225

HCFC-226

HCFC-231
HCFC-232
HCFC-233

HCFC-234

HCFC-235

HCFC-241

HCFC-242

C3HF5Cl2

Dichloropentafluoropropane (HCFC-225)

CF3CF2CHCl2(*) 111512-56-2
CF2ClCF2CHClF(*)
2,2-Dichloro-1,1,1,3,3-pentafluoropropane (HCFC-225aa) (CAS No 128903127564-92-5
2,3-Dichloro-1,1,1,2,3-pentafluoropropane (HCFC-225ba) (CAS No 422-48-0)
128903-21-9
1,2-Dichloro-1,1,2,3,3-pentafluoropropane (HCFC-225bb) (CAS No 422-44-6)
13474-88-9
3,3-Dichloro-1,1,1,2,2-pentafluoropropane (HCFC-225ca) (*) (CAS No 422-56136013-79-1
1,3-Dichloro-1,1,2,2,3-pentafluoropropane (HCFC-225cb) (*) (CAS No 507-55422-44-6
1,1-Dichloro-1,2,2,3,3-pentafluoropropane (HCFC-225cc) (CAS No 13474-88422-48-0
1,2-Dichloro-1,1,3,3,3-pentafluoropropane (HCFC-225da) (CAS No 431-86-7)
422-56-0
1,3-Dichloro-1,1,2,3,3-pentafluoropropane (HCFC-225ea) (CAS No 136013431-86-7
1,1-Dichloro-1,2,3,3,3-pentafluoropropane (HCFC-225eb) (CAS No 111512507-55-1
Dichloropentafluoropropane (HCFC-225) (CAS No 127564-92-5)
C3HF6Cl
Chlorohexafluoropropane (HCFC-226)
134308-72-8
3-Chloro-1,1,1,2,2,3-hexafluoropropane (HCFC-226ca) (CAS No 422-57-1)
359-58-0
1-Chloro-1,1,2,2,3,3-hexafluoropropane (HCFC-226cb) (CAS No 359-58-0,
422-55-9
2-Chloro-1,1,1,3,3,3-hexafluoropropane (HCFC-226da) (CAS No 134308-72-8, 431-87-8)
422-57-1
431-87-8
C3H2FCl5
Pentachlorofluoropropane (HCFC-231)
134190-48-0
Pentachlorofluoropropane (HCFC-231) (CAS No 134190-48-0, 421-94-3)
421-94-3
C3H2F2Cl4
Tetrachlorodifluoropropane (HCFC-232)
134237-39-1
Tetrachlorodifluoropropane (HCFC-232) (CAS No 134237-39-1, 460-89-9)
460-89-9
C3H2F3Cl3
Trichlorotrifluoropropane (HCFC-233)
134237-40-4
1,1,1-Trichloro-3,3,3-trifluoropropane (HCFC-233fb) (CAS No 7125-83-9)
7125-83-9
Trichlorotrifluoropropane (HCFC-233) (CAS No 134237-40-4)
C3H2F4Cl2
Dichlorotetrafluoropropane (HCFC-234)
127564-83-4
2,2-Dichloro-1,1,3,3-tetrafluoropropane (HCFC-234aa) (CAS No 17705-30-5)
146916-90-7
1,1-Dichloro-2,2,3,3-tetrafluoropropane (HCFC-234cb) (CAS No 4071-01-6)
17705-30-5
2,3-Dichloro-1,1,1,3-tetrafluoropropane (HCFC-234da) (CAS No 146916-90-7)
4071-01-6
1,1-ジクロロ-1,3,3,3-tetrafluoropropane (HCFC-234fb) (CAS No 64712-27-2)
425-94-5
Dichlorotetrafluoropropane (HCFC-234) (CAS No 127564-83-4, 425-94-5)
64712-27-2
C3H2F5Cl
Chloropentafluoropropane (HCFC-235)
134237-41-5
1-Chloro-1,2,2,3,3-pentafluoropropane (HCFC-235ca) (CAS No 679-99-2)
422-02-6
3-Chloro-1,1,1,2,3-pentafluoropropane (HCFC-235cb) (CAS No 422-02-6)
460-92-4
1-Chloro-1,1,2,2,3-pentafluoropropane (HCFC-235cc) (CAS No 677-55-4)
677-55-4
1-Chloro-1,1,3,3,3-pentafluoropropane (HCFC-235fa) (CAS No 460-92-4)
679-99-2
Chloropentafluoropropane (HCFC-235) (CAS No 134237-41-5)
C3H3FCl4
Tetrachlorofluoropropane (HCFC-241)
134190-49-1
Tetrachlorofluoropropane (HCFC-241) (CAS No 134190-49-1, 666-27-3)
666-27-3
Trichlorodifluoropropane (HCFC-242)

C3H3F2Cl3

Trichlorodifluoropropane (HCFC-242) (CAS No 127564-90-3, 134237-42-6, 460-63-9)

HCFC-243

HCFC-244

HCFC-251

HCFC-252

HCFC-253

HCFC-261

HCFC-262

25497-29-4
338-64-7
338-65-8
75-68-3

1,1,3,3-Tetrachloro-1,2,2-trifluropropane (HCFC-223ca) (CAS No 134237-37-9, 422-52-6)

HCFC-224

1717-00-6

Dichlorotrifluoropropane (HCFC-243)
2,3-Dichloro-1,1,1-trifluoropropane (HCF-243db) (CAS No 338-75-0)
3,3-Dichloro-1,1,1-trifluoropropane (HCF-243fa) (CAS No 460-69-5)
Dichlorotrifluoropropane (HCFC-243) (CAS No 134237-43-7)
Chlorotetrafluoropropane (HCFC-244)
2-Chloro-1,1,3,3-tetrafluoropropane (HCFC-244da) (CAS No 19041-02-2)
1-Chloro-1,1,3,3-tetrafluoropropane (HCFC-244fb) (CAS No 2730-64-5)
Chlorotetrafluoropropane (HCFC-244) (CAS No 134190-50-4）
Trichlorofluoropropane (HCFC-251)
1,1,2-Trichloro-1-fluoropropane (HCFC-251dc) (CAS No 421-41-0)
1,1,3-Trichloro-1-fluoropropane (HCFC-251fb) (CAS No 818-99-5)
Trichlorofluoropropane (HCFC-251) (CAS No 134190-51-5)
Dichlorodifluoropropane (HCFC-252)
1,2-Dichloro-1,1-difluoropropane (HCFC-252dc) (CAS No 7126-15-0)
1,3-Dichloro-1,1-difluoropropane (HCFC-252fb) (CAS No 819-00-1)
Dichlorodifluoropropane (HCFC-252) (CAS No 134190-52-6)
Chlorotrifluropropane (HCFC-253)
3-Chloro-1,1,1-trifluropropane (HCFC-253fb) (CAS No 460-35-5)
Chlorotrifluropropane (HCFC-253) (CAS No 134237-44-8)
Dichlorofluropropane (HCFC-261)
1,2-Dichloro-2-fluropropane (HCFC-261ba) (CAS No 420-97-3)
1,1-Dichloro-1-fluropropane (HCFC-261fc) (CAS No 7799-56-6)
Dichlorofluropropane (HCFC-261) (CAS No 7799-56-6)
Chlorodifluropropane (HCFC-262)
2-Chloro-1,3-difluropropane (HCFC-262da) (CAS No 102738-79-4)
1-Chloro-1,1-difluropropane (HCFC-262fc) (CAS No 421-02-3)

C3H3F3Cl2

127564-90-3
134237-42-6
460-63-9134237-43-7
338-75-0
460-69-5

C3H3F4Cl

134190-50-4
19041-02-2

C3H4FCl3

134190-51-5
421-41-0
818-99-5

C3H4F2Cl2

134190-52-6
819-00-1
7126-15-0

C3H4F3Cl

134237-44-8
460-35-5

C3H5FCl2

134237-45-9
420-97-3
7799-56-6

C3H5F2Cl

102738-79-4
134190-53-7
421-02-3

4_Ozon

21/42

Montreal Protocol
Class Annex Group

Sample substances
HCFC-271

Chlorodifluropropane (HCFC-262) (CAS No 134190-53-7)
Chlorofluoropropane (HCFC-271)
2-Chloro-2-fluoropropane (HCFC-271ba) (CAS No 420-44-0)
1-Chloro-1-fluoropropane (HCFC-271fb) (CAS No 430-55-7)
Chlorofluoropropane (HCFC-271) (CAS No 134190-54-8)(*)The substance name and the other information like CAS No etc. listed in this table are examples from the contents
which our company has investigated. These do not always cover all information. Some of the substances may becustomarily called by a name of the article on behalf. For details, we hope that your company will confirm it by the
information obtained from the upper stream of the supply chain.

Chemical formula Sample CAS No
C3H6FCl

134190-54-8
420-44-0
430-55-7

5_PFOSAppendix 5. PFOS／PFOS relative compounds〈Perfluorooctane sulfonates〉

22/42

rev..0 2021.11.01

No

Substance name
例示 CAS No
2-Propenoic acid, 2-methyl-, polymers with Bu methacrylate, lauryl methacrylate and 2127133-661[methyl[(perfluoro-C4-8-alkyl)sulphonyl]amino]ethyl methacrylate(PFOS)
8
129813-712 Sulphonamides, C4-8-alkane, perfluoro, N-methyl-N-(oxiranylmethyl)(PFOS)
1-Octanesulphonamide, N-[3-(dimethylamino)propyl]-1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,813417-01-1
3heptadecafluoro-(PFOS)
14650-24-9
4 2-Propenoic acid, 2-methyl-, 2- [[(heptadecafluorooctyl)sulphonyl]methylamino]ethyl
Fatty acids, C18-unsatd., trimers, 2-[[heptadecafluorooctyl)sulphonyl]methylamino]ethyl 148240-785
esters(PFOS)
2
Sulphonamides, C4-8-alkane, perfluoro, N-(hydroxyethyl)-N-methyl, reaction products
148684-796
with 1,6-diisocyanatohexane homopolymer and ethylene glycol(PFOS)
1
Sulphonamides, C4-8-alkane, perfluoro, N-ethyl-N-(hydroxyethyl), reaction products with 160901-257
2-ethyl-1-hexanol and polymethylenepolyphenylene isocyanate(PFOS)
7
1-Propanaminium, 3-[[(heptadecafluorooctyl)sulphonyl]amino]-N,N,N-trimethyl-,
1652-63-7
iodide(PFOS)

8

1-Octanesulphonamide, N-ethyl-1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-N-(2hydroxyethyl)-(PFOS)
1-Octanesulphonic acid, 1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-(PFOS);
10
Perfluoroctane sulfonate acid
1-Octanesulphonamide, N-[3-(dimethyloxidoamino)propyl]11
1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-,potassium salt(PFOS)
Sulphonamides, C4-8-alkane, perfluoro, N-ethyl-N-(hydroxyethyl)-, polymers with 1,1'12 methylenebis[4-isocyanatobenzene] and polymethylenepolyphenylene isocyanate, 2ethylhexyl esters, Me Et ketone oxime-blocked(PFOS)
1-Octanesulphonamide, 1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-N-methyl-,
13
reaction products with benzene-chlorine-sulphur chloride (S2Cl2) reaction(PFOS)
14 Glycine, N-ethyl-N-[(heptadecafluorooctyl)sulphonyl]-, ethyl ester(PFOS)
Sulphonamides, C4-8-alkane, perfluoro, N-[3-(dimethylamino)propyl], reaction products
15with acrylic acid(PFOS)
1-Octanesulphonamide, N,N',N''- [phosphinylidynetris(oxy-2,1-ethanediyl)]tris[N-ethyl16
1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-(PFOS)
1-Octanesulphonamide, N-butyl-1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-N-(217hydroxyethyl)-(PFOS)
1-Octanesulphonamide, 1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-N-(218hydroxyethyl)-N-methyl-(PFOS)
1-Octanesulphonamide, N-ethyl-1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-N-219
propenyl-(PFOS)
1-Decanaminium, N-decyl-N,N-dimethyl-, salt with 1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,820 heptadecafluoro-1-octanesulphonic acid (1:1)(PFOS)

9

21 2-Propenoic acid, 2-[[(heptadecafluorooctyl)sulphonyl]methylamino]ethyl ester(PFOS)
1-Octanesulphonic acid, 1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-, potassium
22
salt(PFOS); Perfluorooctane sulfonate potasium salt
1-Octanesulphonic acid, 1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-, ammonium
23
salt(PFOS); Perfluorooctane sulfonate ammonium saltPoly(oxy-1,2-ethanediyl), alpha-[2-[ethyl[(heptadecafluorooctyl)sulphonyl]amino]ethyl]24
omega-hydroxy-(PFOS)
1-Octanesulphonic acid, 1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-, lithium
25
salt(PFOS); Perfluorooctane sulfonate lithium salt
26 Glycine, N-ethyl-N-[(heptadecafluorooctyl)sulphonyl]-(PFOS)
27 Glycine, N-ethyl-N-[(heptadecafluorooctyl)sulphonyl]-, potassium salt(PFOS)
1-Octanesulphonamide, N-[3-(dimethyloxidoamino)propyl]28
1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-(PFOS)
1-Octanesulphonamide, N,N'-[phosphinicobis(oxy-2,1-ethanediyl)]bis[N-ethyl29
1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-, ammonium salt(PFOS)
Fatty acids, linseed-oil, dimers, 2- [[(heptadecafluorooctyl)sulphonyl]methylamino]ethyl
30esters(PFOS)
Sulphonamides, C4-8-alkane, perfluoro, N-(hydroxyethyl)-N-methyl, reaction products
31with 12-hydroxystearic acid and 2,4-TDI, ammonium salts(PFOS)
Sulphonamides, C4-8-alkane, perfluoro, N-methyl-N-[(3-octadecyl-2-oxo-532
oxazolidinyl)methyl](PFOS)
Siloxanes and Silicones, di-Me, mono[3-[(2-methyl-1-oxo-2-propenyl)oxy]propylgroup] 33 terminated, polymers with 2-[methyl[(perfluoro-C4-8-alkyl)sulphonyl]amino]ethyl acrylate
and stearyl methacrylate(PFOS)

1691-99-2
1763-23-1
178094-694
178535-223
182700-909
1869-77-8
192662-296
2250-98-8
2263-09-4
24448-09-7
24924-36-5
251099-168
25268-77-3
2795-39-3
29081-56-9
29117-08-6
29457-72-5
2991-50-6
2991-51-730295-51-3
30381-98-7
306973-466
306973-477
306974-196
306974-287

5_PFOS

23/42

No

Substance nameSulphonic acids, C6-8-alkane, perfluoro, compounds with polyethylene-polypropylene
34
glycol bis(2-aminopropyl) ether(PFOS)
Fatty acids, C18-unsatd.,dimers, 2-[methyl[(perfluoro-C4-8-alkyl)sulphonyl]amino] ethyl
35
esters(PFOS)
Propanoic acid, 3-hydroxy-2- (hydroxymethyl)-2-methyl-, polymer with 2-ethyl-2(hydroxymethyl)-1,3-propanediol and N,N',2-tris(6-isocyanatohexyl)imidodicarbonicdiamide, reaction products with N-ethyl-1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8heptadecafl(PFOS)

例示 CAS No
306974-458
306974-630
306975-564

36

Propanoic acid, 3-hydroxy-2-(hydroxymethyl)-2-methyl-, polymer with 1,1'306975-57methylenebis[4isocyanatobenzene]and
1,2,3-propanetriol,
reaction
products
with
5
37
Nethyl-1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-N-(2-hydroxyethyl)-1octanesulphon(PFOS)
2-Propenoic acid, 2-methyl-, dodecyl ester, polymers with 2- [methyl[(perfluoro-C4-8306975-6238
alkyl)sulphonyl]amino]ethyl acrylate and vinylidene chloride(PFOS)
2
Poly(oxy-1,2-ethanediyl), alpha-hydro-omega-hydroxy-, polymer with 1,6306975-8439
diisocyanatohexane, N-(hydroxyethyl)-N-methyl perfluoro C4-8-alkane
82-Propenoic acid, 2-methyl-, dodecyl ester, polymers with N-(hydroxymethyl)-2306975-85propenamide, 2-[methyl[(perfluoro-C4-8-alkyl)sulphonyl]amino]ethyl methacrylate, stearyl
940 methacrylate and vinylidene chloride(PFOS)
1-Hexadecanaminium, N,N-dimethyl-N-[2-[(2-methyl-1-oxo-2-propenyl)oxy]ethyl]-,bromide, polymers with Bu acrylate, Bu methacrylate and 2-methyl[(perfluoro-C4-841 alkyl)sulphonyl]amino]ethyl acrylate(PFOS)

306976-250

2-Propenoic acid, 2-methyl-, 2-methylpropyl ester, polymer with 2,4-diisocyanato-1methylbenzene, 2-ethyl-2-(hydroxymethyl)-1,3-propanediol and 2-propenoic acid, N42 ethyl-N-(hydroxyethyl)perfluoro-C4-8-alkanesulphonamides(PFOS)

306976-556

2-Propenoic acid, 2-methyl-, 3-(trimethoxysilyl)propyl ester, polymers with acrylic acid, 2- 306977-582
monoacrylate, hydrolysed, compounds with 2,2'-(methylimino)bis(PFOS)
2-Propenoic acid, butyl ester, polymers with acrylamide, 2-[methyl[(perfluoro-C4-8306978-0444
alkyl)sulphonyl]amino]ethyl acrylate and vinylidene chloride(PFOS)
1Hexane, 1,6-diisocyanato-, homopolymer, N-(hydroxyethyl)-N-methyl perfluoro-C4-8306978-6545
alkane sulphonamides- and stearyl alc.-blocked(PFOS)
4
Poly(oxy-1,2-ethanediyl), alpha-[2-(methylamino)ethyl]-omega-[(1,1,3,3306979-4046
tetramethylbutyl)phenoxy]-, N-[(perfluoro-C4-8-alkyl)sulphonyl](PFOS)
8
Sulphonamides, C4-8-alkane, perfluoro, N,N'-[1,6-hexanediylbis[(2-oxo-3,5306980-2747
oxazolidinediyl)methylene]]bis[N-methyl-(PFOS)
8
1-Octanesulphonyl fluoride, 1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-(PFOS);
307-35-7
48 Perfluoro-1-octanesulfonyl fluoride

43 [methyl[(perfluoro-C4-8-alkyl)sulphonyl]amino]ethyl acrylate and propylene glycol

49 1-Octanesulphonamide, 1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-N-methyl2-Propenoic acid, 2-methyl-, 2-[ethyl[(heptadecafluorooctyl)sulphonyl]amino]ethyl
50 ester(PFOS)

31506-32-8
376-14-7

1-Propanaminium, 3-[[(heptadecafluorooctyl)sulphonyl]amino]-N,N',N''-trimethyl-,chloride(PFOS)
1-Octanesulphonamide, N-ethyl-1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-N-[252 (phosphonooxy)ethyl]-(PFOS)

38006-74-5

53 2-Propenoic acid, 2-[butyl[(heptadecafluorooctyl)sulphonyl]amino]ethyl ester(PFOS)
54 Glycine, N-ethyl-N-[(heptadecafluorooctyl)sulphonyl]-, sodium salt(PFOS)
55 Sodium perfluorooctanesulfonate
56 1-Octanesulphonamide, N-ethyl-1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-383-07-3
3871-50-9
4021-47-0
4151-50-2
423-82-5

51

2-Propenoic acid, 2-[ethyl[(heptadecafluorooctyl)sulphonyl]amino]ethyl ester(PFOS)

3820-83-5

57
1-Octanesulphonamide, 1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-N-2-propenyl(PFOS)
59 Perfluoroctane sulfonate anion(PFOS)

58

423-86-945298-90-6

5_PFOS

24/42

No

Substance name
1-Octanesulphonamide, 1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-N60(phenylmethyl)-(PFOS)
Poly(oxy-1,2-ethanediyl), alpha-[2-[[(heptadecafluorooctyl)sulphonyl]propylamino]ethyl]61
omega-hydroxy-(PFOS)
Ethanaminium, N,N',N''-triethyl-, salt with 1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,862
heptadecafluoro-1-octanesulphonic acid (1:1)(PFOS);
Benzoic acid, 2,3,4,5-tetrachloro-6-[[[363[[(heptadecafluorooctyl)sulphonyl]oxy]phenyl]amino]carbonyl]-, monopotassium
64 2-Propenoic acid, 4-[[(heptadecafluorooctyl)sulphonyl]methylamino]butyl ester(PFOS)
65 2-Propenoic acid, 2-methyl-, 4-[[(heptadecafluorooctyl)sulphonyl]methylamino]butyl
1-Octanesulphonamide, N-ethyl-1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-N-[366(trimethoxysilyl)propyl]-(PFOS)
1-Octanesulphonamide, N-ethyl-1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-N-[367 (trichlorosilyl)propyl]-(PFOS)

例示 CAS No
50598-29-3

1-Octanesulphonamide, N-[3-(dimethylamino)propyl]- 1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8heptadecafluoro-, monohydrochloride(PFOS)
1-Octanesulphonamide, N-ethyl-1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-N-[269(phosphonooxy)ethyl]-, diammonium salt(PFOS)
Carbamic acid, (4-methyl-1,3-phenylene)bis-, bis[2-[ethyl[(perfluoro-C4-870
alkyl)sulphonyl]amino]ethyl] ester(PFOS)
1-Octanesulphonamide, 1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-N-(471hydroxybutyl)-N-methyl-(PFOS)
1-Propanaminium, 3-[[(heptadecafluorooctyl)sulphonyl](3-sulphopropyl)amino]-N-(272hydroxyethyl)-N,N-dimethyl-, hydroxide, inner salt(PFOS)
1-Propanaminium, 3-[[(heptadecafluorooctyl)sulphonyl]amino]-N,N',N''-trimethyl-, iodide,73 ammonium salt(PFOS)

67939-88-2

2-Propenoic acid, eicosyl ester, polymer with 2-[[(heptadecafluorooctyl)sulphonyl]
methylamino]ethyl 2-propenoate, hexadecyl 2-propenoate, 274 [methyl[(nonafluorobutyl)sulphonyl]amino]ethyl 2-propenoate, 2[methyl[(pentadecafluoroheptyl)sulphonyl](PFOS)

68329-56-6

6852550-45-5
56773-42-3
57589-85-2
58920-31-3
61577-14-8
61660-12-6
67939-42-8

67969-69-1
68081-83-4
68239-73-6
68298-11-3
68310-75-8

2-Propenoic acid, polymer with 2-[ethyl[(heptadecafluorooctyl)sulphonyl]amino]ethyl 2methyl-2-propenoate and octadecyl 2-propenoate(PFOS)

68541-80-0

2-Propenoic acid, butyl ester,polymer with 2-

68555-90-8

75

76 [[(heptadecafluorooctyl)sulphonyl]methylamino]ethyl 2-propenoate, 2methyl[(nonafluorobutyl)sulphonyl]amino]ethyl 2-propenoate, 22-Propenoic acid, 2-methyl-, 2-[ethyl[(heptadecafluorooctyl)sulphonyl]amino]ethyl ester, 68555-91-9
77 polymer with 2-[ethyl[(nonafluorobutyl)sulphonyl]amino] ethyl 2-methyl-2-propenoate, 2[ethyl[(pentadecafluoroheptyl)sulphonyl]amino]ethyl 2-methyl-2-propeno(PFOS)
2-Propenoic acid, 2-methyl-, 2-[[(heptadecafluorooctyl)sulphonyl]methylamino]ethyl
68555-92-0
ester, polymer with 2- [methyl[(nonafluorobutyl)sulphonyl]amino]ethyl 2-methyl-278
propenoate, 2- [methyl[(pentadecafluoroheptyl)sulphonyl]amino]ethyl 2-methyl-2-(PFOS)
Sulphonamides, C4-8-alkane, perfluoro, N-ethyl-N-(hydroxyethyl), reaction products with 68608-14-0
1,1'-methylenebis[4-isocyanatobenzene](PFOS)
N-(2-hydroxyethyl)-1-butanesulphonamide, N-ethyl-1,1,2,2,3,3,4,4,5,5,6,6,7,7,768649-26-3
pentadecafluoro-N-(2-hydroxyethyl)- 1-heptanesulphonamide, N-ethyl80 1,1,2,2,3,3,4,4,5,5,6,6,6-tridecafluoro-N-(2-hydroxyethyl)-1-hexanesulphonamide, Nethyl-1,1,2,(PFOS)

79

2-Propenoic acid, 2-[[(heptadecafluorooctyl)sulphonyl]methylamino]ethyl ester, polymer
with 2-[methyl[(nonafluorobutyl)sulphonyl]amino]ethyl 2-propenoate, 281[methyl[(pentadecafluoroheptyl)sulphonyl]amino]ethyl 2-propenoate, 2[methyl[(trideca(PFOS)
2-Propenoic acid, 2-methyl-, 2-[ethyl[(heptadecafluorooctyl)sulphonyl]amino]ethyl ester,
82 polymer with 2-[ethyl[(nonafluorobutyl)sulphonyl]amino]ethyl 2-methyl-2-propenoate,2[ethyl[(pentadecafluoroheptyl)sulphonyl]amino]ethyl 2-methyl-2-prope(PFOS)

83

68867-60-7

68877-32-7

Chromium, diaquatetrachloro[mu-[N-ethyl-N- [(heptadecafluorooctyl)sulphonyl] glycinato- 68891-96-3
kappaO:kappaO']]-mu-hydroxybis(2-methylpropanol)di-(PFOS)

5_PFOS

25/42

No

Substance name2-Propenoic acid, eicosyl ester, polymers with branched octylacrylate, 2[[(heptadecafluorooctyl)sulphonyl]methylamino]ethyl acrylate, 284 [methyl[(nonafluorobutyl)sulphonyl]amino]ethyl acrylate, 2[methyl[(pentadecafluoroheptyl)sulphonyl]amino](PFOS)

例示 CAS No
68909-15-9

Poly(oxy-1,2-ethanediyl), alpha-[2-[ethyl[(heptadecafluorooctyl)sulphonyl]amino]ethyl]68958-61-2
omega-methoxy-(PFOS)
70225-14-8
86 Bis(2-hydroxyethyl)ammonium perfluorooctanesulfonate
2-Propenoic acid, 2-methyl-, octadecyl ester, polymer with 1,1-dichloroethene, 270776-36-2[[(heptadecafluorooctyl)sulphonyl]methylamino]ethyl 2-propenoate, N-(hydroxymethyl)-287 propenamide, 2-[methyl[(nonafluorobutyl)sulphonyl]amino]ethyl 2-propenoate, 2-(PFOS)

85

1-Octanesulfonic acid, 1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-, compd. withpiperidine (1:1)
89 Phosphonic acid, [3-[ethyl[(heptadecafluorooctyl)sulphonyl]amino]propyl]-(PFOS)
90 Phosphonic acid, [3-[ethyl[(heptadecafluorooctyl)sulphonyl]amino]propyl]-, diethyl
2-Propenoic acid, 2-methyl-, methyl ester, polymer with ethenylbenzene, 2[[(heptadecafluorooctyl)sulphonyl]methylamino]ethyl 2-propenoate, 2[methyl[(nonafluorobutyl)sulphonyl]amino]ethyl 2-propenoate, 291 [methyl[(pentadecafluoroheptyl)sulphonyl](PFOS)

71463-74-6

92 1-Octanesulphonamide, 1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-(PFOS)

754-91-6
91036-71-4

88

93

Magnesium bis[heptadecafluorooctanesulphonate]

Sulphonamides, C4-8-alkane, perfluoro, N-(hydroxyethyl)-N-methyl, reaction productswith epichlorohydrin, adipates (esters)(PFOS)
Ethanaminium, N,N,N-trimethyl-2-[(2-methyl-1-oxo-2-propenyl)oxy]-, chloride, polymer
with 2-ethoxyethyl 2-propenoate, 2-[[(heptadecafluorooctyl)sulphonyl] methylamino]ethyl
95 2-propenoate and oxiranylmethyl 2-methyl-2-(PFOS)

94

71463-78-0
71463-80-4
71487-20-2

91081-99-1
92265-81-1
修1-Propanesulphonic acid, 3-[[3-(dimethylamino)propyl][(heptadecafluorooctyl)
94133-90-1
sulphonyl]amino]-2-hydroxy-, monosodium salt(PFOS)
Carbamic acid, [5-[[[294313-84-5
97[[(heptadecafluorooctyl)sulphonyl]methylamino]ethoxy]carbonyl]amino]-2-methylphenyl]-,Sulphonamides, C7-8-alkane, perfluoro, N-methyl-N-[2-[(1-oxo-2-propenyl)oxy]ethyl],98999-57-6
polymers with 2-ethoxyethyl acrylate, glycidyl methacrylate and N,N,trimethyl-2-[(2methyl-1-oxo-2-propenyl)oxy]ethanaminium chloride(PFOS)

96

98

99

Perfluorooctane sulfonates(PFOS) C8F17SO2X (X = OH, Metal salt (O-M+), halide,
amide, and other derivatives including polymers) [group]?

JAMPSN0035

6 REACH AnnexVXII

26/42

Appendix 6：
REACH Annex XVII Restriction of placing on the market and use*Refer the original text about the each restriction of use.
http://ec.europa.eu/enterprise/sectors/chemicals/reach/restrictions/index_en.htm
No.

Chemical Name

1 Poly chlorinated terphenyls (PCTs)
2 Chloro-1-ethylene (monomer vinyl chloride)
3 Liquid substances or mixtures fulfilling the criteria for

SampleCAS No.

Main use of restriction

rev.1.0/2023.10.1
Maximum
acceptablevalue

61788-338*
75-01-4－

Substances, mixtures, including waste oils, 50ppm
or equipment
Banning the use
Aerosols dispensers
Banning the use
Ornamental oil lamps, etc.

126-72-7
71-43-2

Textile articles coming into contact with theSubstances or mixtures
Toys
Articlesany of the following hazard classes or categories set
out inAnnex I to Regulation (EC) No 1272/2008:

4 Tris(2,3-dibromopropyl)phosphate
5 Benzene
6 Asbestos(a) Crocidolite(b) Amosite(c) Anthophylite asbestos(d) Actinolite asbestos(e) Tremolite asbestos(f) Chrysotile

12001-28-4
12172-73-5
77536-67-5
77536-66-4
77536-68-6
12001-29-5
132207-327 Tris-aziridinyl-phosphinoxide
545-55-1 Textile articles, come into contact with the
8 Polybromobiphenyls (PBB)
59536-65-1 Textile articles, come into contact with the
9 (a) Soap bark powder (Quillaja saponaria) 68990-67-0 Mixtures or articles in amenity goods likeand its derivatives containing saponines
sneezing powder and stink bombs－(b) Powder of the roots of Helleborus viridisand Helleborus niger－(c) Powder of the roots of Veratrum album
and Veratrum nigrum
92-87-5(d) benzidine and/or its derivatives
552-89-6(e) o-nitrobenzaldehyde－(f) Wood powder
10 (a) Ammonium sulphide12135-76-1
12124-99-1(b) Ammonium hidrogen sulphide9080-17-5(c) Ammonium polysulphide
11 Volatile esters of bromoacetic acids
96-32-2(a) Methyl bromoacetate105-36-2(b) Ethyl bromoacetate
35223-80-4(c) Propyl bromoacetate
18991-98-5(d) Butyl bromoacetate
12 2-naphthylamine and its salts
91-59-8 Substances or mixtures
13 Benzidine and its salts
92-87-5
14 4-nitrobiphenyl
92-93-3
15 4-aminobiphenyl and its salts
92-67-1
16 Lead carbons
Substances or mixtures, where the598-63-0 substance or mixture is intended for use as(a) Neutral anhydrous carbonate (PbCO3)
1319-46-6 paint(b) Trilead-bis(carbonate)-dihydroxide
2PbCO3-Pb(OH)2
17 Lead sulphates
7446-14-2(a) Lead sulphates(PbSO4)
15739-80-7(b) Lead sulphates(PbxSO4)
18a7439-97-6 Ffever thermometers, measuring devices
including mercury
18 Mercury compounds
19 Arsenic compounds
20 Organostannic compounds
Trisubstituted organostannic compounds
Tributyltin (TBT) compounds,
Triphrnyltin (TPT) compounds etc.
Dibutyltyltin (DBT) compounds
Dioctyltin (DOT) compounds

－
－
－
－

Banning the use
1000ppm
5ppm
Banning the use

Banning the use
Banning the use
Banning the use(stink bombs :under 1.5ml)

1000ppm

Banning the use

Banning the use(*) from 2014/4/10

boats and ships, equipment used for fish or Banning the use
shellfish farming, preservation of wood, theBiocide ,the treatment of industrial waters Banning the use
1000ppm of Sn
Articles－－Mixtures or articles
Articles intended to come into contact withthe skin
21 Di-μ-oxo-di-n-butylstanniohydroxyborane (DBB) 75113-37-0 Substances or mixtures
22 Pentachlorophenol and its esters
87-86-5 Substances or mixtures
23 Cadmium and its compounds
7440-43-9 Plastic, brazing fillers, jewelry goods,
etc.
cadmium plating except special use
Paint

1000ppm
100ppm100ppm1000ppm6 REACH AnnexVXII
No.

Chemical Name

24 Monomethyl-tetrachloridiphenyl methane
25 Monomethyl-dichlorodiphenyl methane
26 Monomethyl-dibromo-diphenyl methane
27 Nickel and its compounds

28 Substances which appear in Part 3 of Annex VI
to Regulation (EC) No 1272/2008 classified as
carcinogen category 1A or 1B (Table 3.1) or
carcinogen category 1 or 2 (Table 3.2) andlisted as follows:
29 Substances which appear in Part 3 of Annex VI
to Regulation (EC) No 1272/2008 classified as
germ cell mutagen category 1A or 1B (Table
3.1) or mutagen category 1 or 2 (Table 3.2) and
30 Substances which appear in Part 3 of Annex VI
to Regulation (EC) No 1272/2008 classified as
toxic to reproduction category 1A or 1B (Table
3.1) or toxic to reproduction category 1 or 2
(Table 3.2) and listed as follows:

27/42
SampleCAS No.

Main use of restriction

76253-60-6 Substances, mixtures or articles containing－
the substance99688-47-8
7440-02-0 The use intended to come into direct andetc.
prolonged contact with the skin
(Discharge > 0.2μg/cm2/week)－
Supplies to the general public(As substances or in mixtures)－

41 Hexachloroethane

42(Missing number)
43 Azo colourants and azo dyes

67-72-1－(may release the aromatic amines listed inAppendix 8)4-aminoazobenzene
o-anisidine;
2-methoxyaniline
2-naphthylamine
3,3'-dichlorobenzidine;
3,3'-dichlorobiphenyl-4,4'-ylenediamine
4-aminobiphenyl
benzidineo-toluidine;
2-aminotoluene
4-chloro-o-toluidine
4-methyl-m-phenylenediamineo-aminoazotoluene;
4-amino-2',3-dimethylazobenzene;
4-o-tolylazo-o-toluidine
5-nitro-o-toluidine
2,2'-dichloro-4,4'-methylenedianiline;
4,4'-methylene bis(2-chloroaniline)
4,4'-diaminodiphenylmethane;
4,4'-methylenedianiline
4,4'-oxydianiline

Banning the use

Banning the use(0.2μg/cm2/week)
The
concentration
limit specified inRegulation (EC)No－

31 (a) Creosote, wash oil
8001-58-9 Substances or mixtures where the61789-28-4 substance or mixture is intended for the(b) Creosote oil
84650-04-4 treatment of wood(c) Distillates (coal tar), naphthalene oils
90640-84-9(d) Creosote oil, acenaphthene fraction,
wash oil
65996-91-0(e) Distillates (coal tar), upper, heavy
anthracene oil
90640-80-5(f) Anthracene oil
65996-85-2(g) Tar acids, coal, crude, crude phenols
8021-39-4(h) Creosote, wood(i) Low temperature tar oil, alkaline, extract 122384-78-5
residues (coal), low temperature coal
32 Chloroform
67-66-3 Surface treatment , cleaner
33(Missing number)
34 1,1,2-trichloroethane79-00-5
35 1,1,2,2-tetrachloroethane
79-34-5
36 1,1,1,2-tetrachloroethane630-20-6
37 Pentachloroethane76-01-7
38 1,1-dichloroethylene
75-35-4
39(Missing number)－
40 Substances meeting the criteria of flammability
Substances or mixtures in aerosol
in Directive 67/548/EEC and classified as
dispensers for the general public for
flammable, highly flammable or extremely
entertainment and decorative purposes
flammable regardless of whether they appear inPart 3 of Annex VI to Regulation (EC) No

Maximum
acceptablevalue

60-09-3
90-04-0
91-59-8
91-94-1
92-67-1
92-87-5
95-53-4
95-69-2
95-80-7
97-56-3

99-55-8
101-14-4
101-77-9
101-80-4

Banning the use

1000ppm

Banning the use

substance or mixtures where the substance Banning the use
or mixture is intended for the manufacturing
or processing of non-ferrous metals
Articles intended to come into direct andprolonged contact with the skin(textile and leather articles)

30ppm

6 REACH AnnexVXII
No.

Chemical Name

4-chloroaniline
o-dianisidine;
3,3'-dimethoxybenzidine
4,4'-bi-o-toluidine;
3,3'-dimethylbenzidine
p-cresidine;
6-methoxy-m-toluidine
2,4,5-trimethylaniline
4,4'-thiodianiline
4-methoxy-m-phenylenediamine
4,4'-methylenedi-o-toluidine
44(Missing number)
45 Diphenyl ether, octabromo derivative
46 (a) Nonylphenol(b) Nonylphenol ethoxylates
46a Nonylphenol ethoxylates (NPE)
47 Chromium VI compounds

28/42
SampleCAS No.

119-93-7
120-71-8
137-17-7
139-65-1
615-05-4
838-88-0
Substances, mixtures or articles
25154-52-3 Cleaner, etc.
－
Textile articles
after 2021/Feb/3
Cement108-88-3

49 Trichlorobenzene
50 Polycyclic-aromatic hydrocarbons (PAH)

120-82-1－(a) Benzo(a)pyrene (BaP)

50-32-8(b) Benzo(e)pyrene (BeP)

192-97-2(c) Benzo(a)anthracene (BaA)

56-55-3(d) Chrysene (CHR)

218-01-9(e) Benzo(b)fluoranthene (BbFA)

205-99-2(f) Benzo(j)fluoranthene (BjFA)

205-82-3(g) Benzo(k)fluoranthene (BkFA)

207-08-9(h) Dibenzo(a, h)anthracene (DBAhA)

53-70-3

51 The following phthalates(a) Bis(2-ethylhexyl) phthalate (DEHP)

117-81-7(b) Dibutyl phthalate (DBP)

84-74-2(c) Benzyl butyl phthalate (BBP)

85-68-7(d) Diisobutyl phthalate (DIBP)

84-69-5(b) Di-isodecyl phthalate (DIDP)(c) Di-n-octyl phthalate (DNOP)
53(Missing number)
54 2-(2-methoxyethoxy)ethanol (DEGME)
55 2-(2-butoxyethoxy)ethanol (DEGBE)
56 Methylenediphenyl diisocyanate (MDI)
including the following specific isomers(a) 4,4’-Methylenediphenyl diisocyanate(b) 2,4’-Methylenediphenyl diisocyanate(c) 2,2’-Methylenediphenyl diisocyanate
57 Cyclohexane
58 Ammonium nitrate (AN)Maximum
acceptablevalue

106-47-8
119-90-4

48 Toluene

52 The following phthalates(a) Di-isononyl phthalate (DINP)

Main use of restriction- Leather articles coming into contact
with the skin
- Articles containing leather parts coming
into contact with the skin
Adhesives or spray paints(for supply to the general public)
As substances, in mixtures
The production of tyres

1000ppm
1000ppm

100ppm2ppm of the total
dry weight
3ppm of the total
dry weight of theleather
1000ppm
1000ppm

1ppm(BaP)
10ppm(the totalof PAH)

Articles for supply to the general public, if any 1ppm
of their rubber or plastic components thatcome into direct as well as prolonged or
short-term repetitive contact with the humanskin or the oral cavity（Apply after 27 December 2015）
Toys, including activity toys, and childcare
0.5ppmarticle if any of their rubber or plastic
components that come into direct as well as
prolonged or short-term repetitive contact withthe human skin or the oral cavity（Apply27 December
2015）
Shall notafter
be usedas substances
or in mixtures,
1000ppm
individually or in any combination of the phthalates
listed in this entry, in the plasticised material, in toysand childcare articles.
- Shall not be placed on the market in toys andchildcare articles, individually or in any combinationof the phthalates listed in this entry, in the plasticisedmaterial (DIBP shall not be placed on the market
after 7 July 2020).
- Shall not be placed on the market after 7 July 2020
in articles, individually or in any combination of theToys and childcare articles
28553-12-0
68515-48-0
26761-40-0
68515-49-1
117-84-0
111-77-3 Paints, paint strippers, cleaning agents,
self-shining emulsions or floor sealants
112-34-5 Spray paints for supply to the general
26447-40-5 Mixtures for supply to the general public
101-68-8
5873-54-1
2536-05-2
110-82-7 Adhesives
6484-52-2 Sbustances or in mixtures that containmore than 28 % by weight of nitrogen in
relation to AN for use as a solid fertiliser

1000ppm

1000pm
30000ppm
1000ppm

1000ppm
Banning the use

6 REACH AnnexVXII
No.

Chemical Name

59 Dichloromethane
60 Acrylamide
61 Dimethylfumarate (DMF)
62 Phenylmercury compounds*(a) Phenylmercury acetate(b) Phenylmercury propionate(c) Phenylmercury 2-ethylhexanoate(d) Phenylmercury octanoate(e) Phenylmercury neodecanoate

63 Lead and its compounds

64 1,4-dichlorobenzene

64 Inorganic ammmonium salts

29/42
SampleCAS No.

75-09-2
79-06-1
624-49-767

Bis(pentabromophenyl)ether(decabromodiphenyl ether; decaBDE)

Sbustances or in mixtures that containmore than 16 % by weight of nitrogenn inrelation to AN
Paint strippers
Grouting applications
Articles62-38-4 Articles
103-27-5 Mixtures
13302-00-6 Substances
13864-38-5
26545-49-3 *After 10 October 2017
Jewelry articles
Articles or accessible parts thereof may,during normal or reasonably foreseeable7439-92-1 conditions of use, be placed in the mouth
by children.
－
Articles produced from polymers or
copolymers of vinyl chloride (‘PVC’), if theconcentration of lead is equal to or greater- Substance or- Constituent of mixtures in aconcentration equal to or greater than
1% by weight
106-46-7
where the substance or the mixture is placedon the market for use or used as an air
freshener or deodoriser in toilets, homes,
offices or other indoor public areas.
Cellulose Insulation mixtures or cellulose
Insulation articles-

After 14 July 2018

Cellulose insulation mixtures or cellulose
insulation articles
After 14 July 2018

65 Inorganic ammonium salts

66 Bisphenol A

Main use of restriction

thermal paper
After 2 January 2020
Substance
Another substance, as a constituent Mixture1163-19-5 Article, or any part80-05-7

After 2 March 2019.
68 Perfluorocarboxylic acids containing 9 to 14 375-95-1 Substance, mixtures and article
carbon atoms in the chain (C9-C14
335-76-2
PFCAs), their salts and C9-C14 PFCA2058-94-8 After 25 February 2023
related substances
307-55-1
72629-94-8
376-06-7

69 Methanol

67-56-1

Maximum
acceptablevalue
Banning the use
ecceptagriculture
or licensed user
1000ppm
1000ppm
0.1ppm100ppm of
mercury
100ppm of
mercury
Banning the use

500ppm1000ppm
Bannning the useor placing on themarkeTechnical
Specification
CEN/TS 16516
the emission ofammonia fromthose mixture or
articles results in aconcentration ofless than 3 ppm byvolumeTechnical
Specification CEN/TS
16516
the emission ofammoniafrom those
mixtures orarticles
results inaconcentration of

200ppmBannningthemanufactured
orplacing on themarket1000ppm

Bannning the useor placing on themarketSum of C9-C14
PFCAs, theirsalts: <25ppb
Sum of C9-C14
PFCA-related
substances:<260ppb
Shall not be placed on the market to the general COMMISSION
public after 9 May 2018 in windscreen
REGULATION
washing or defrosting fluids, in a concentration (EU) 2018/589
equal to or greater than
0,6 % by weight.’

6 REACH AnnexVXII
No.

30/42

Chemical Name

70 Octamethylcyclotetrasiloxane (D4)
Decamethylcyclopentasiloxane (D5)71 1-methyl-2-pyrrolidone (NMP)

SampleCAS No.
556-67-2
541-02-6

872-50-4

Table in Appendix 12silanetriol Any of its mono-, di- or tri-O- (alkyl)
derivatives (TDFAs)

74 Diisocyanates, O = C=N-R-N = C=O, with R an
aliphatic or aromatic hydrocarbon unit ofunspecified length

75 Substances falling within one or more of the following

points:(1) substances classified as any of the following in Part 3 ofAnnex VI to Regulation (EC) No 1272/2008:a) carcinogen category 1A, 1B or 2, or germ cell mutagen
category 1A, 1B or 2, but excluding any such substancesclassified due to effects only following exposure byinhalationb) reproductive toxicant category 1A, 1B or 2 but excluding
any such substances classified due to effects only following
exposure by inhalationc) skin sensitiser category 1, 1A or 1Bd) skin corrosive category 1, 1A, 1B or 1C or skin irritantcategory 2e) serious eye damage category 1 or eye irritant category 2(2) substances listed in Annex II to Regulation (EC) No
1223/2009 of the European Parliament and of the Council(3) substances listed in Annex IV to Regulation (EC) No
1223/2009 for which a condition is specified in at least oneof the columns g, h and i of the table in that Annex

Maximum
acceptablevalue

1. Shall not be placed on the market in wash-off COMMISSION
cosmetic products in a concentration equal to or REGULATION
greater than 0,1 % by weight of either(EU) 2018/35
substance, after 31 January 2020.
2. For the purposes of this entry, “wash-off
cosmetic products” means cosmetic products as
defined in Article 2(1)(a) of Regulation (EC) No
1223/2009 that, under normal conditions of use,
are washed off with water after application.’
1. Shall not be placed on the market as a substance COMMISSION
on its own or in mixtures in a concentration equal to or REGULATION
greater than 0,3 % after 9 May 2020 unless(EU) 2018/588

manufacturers, importers and downstream users
have included in the relevant chemical safety reports
and safety data sheets, Derived No-Effect Levels(DNELs) relating to exposure of workers of 14,4
mg/m3 for exposure by inhalation and 4,8 mg/kg/day
for dermal exposure.
2. Shall not be manufactured, or used, as a
substance on its own or in mixtures in a concentration
equal to or greater than 0,3 % after 9 May 2020
unless manufacturers and downstream users take theappropriate risk management measures and provide
the appropriate operational conditions to ensure that
exposure of workers is below the DNELs specified inparagraph 1.
3. By way of derogation from paragraphs 1 and 2, theobligations laid down therein shall apply from 9 May
2024 in or
relation
placing on the market for use, orClothing
relatedtoaccessories;
Banning the placing

72 The substances listed in column 1 of the73 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)

Main use of restriction-

Textiles other than clothing which, under normal oron the market
reasonably foreseeable conditions of use, come into contact
with human skin to an extent similar to clothing;
Footwear
if the clothing, related accessory, textile other than clothingor footwear is for use by consumers and the substance ispresent in a concentration, measured in homogeneousmaterial, equal to or greater than that specified for that
substance in Appendix 12.
After 1 November 2020
Banning the

Mixtures containing organic solvents, inspray products.
After 2 January 2021

Substances on their own, as a constituent in othersubstances or in mixtures for industrial and professionaluse(s) after 24 February 2022
(Except the supplier ensures that the recipient of thesubstance(s) or mixture(s) is provided with information on
the requirements and the following statement is placed on
the packaging, in a manner that is visibly distinct from therest of the label information: “As from 24 August 2023
adequate training is required before industrial or
professional use”.) after 24 August 2023
(Except the employer or self-employed ensures thatindustrial or professional user(s) have successfullycompleted training on the safe use of diisocyanates prior to
the use of the substance(s) or mixture(s).)
after 4 January 2022

placing on themarketConcentration
equal to or
greater than 2
ppb by weight ofeither substanceor anyBanning the placing
on the market
Concentration of
diisocyanates
individually and incombination equal toor greater than 0,1 %by weight
Banning the use
Concentration of
diisocyanates
individually and incombination equal toor greater than 0,1 %by weight
Banning the placing
on the market and theuse
Concentration of
mixture equal to or
greater than:(1)a) 0.00005wt%b) 0.001wt%c) 0.001%d) e)
0.1wt% for pH
regulator
0.01wt% for theothers(2) 0.00005wt%(3) (4) see (EU)2020/2081

6 REACH AnnexVXII
No.

Chemical Name

76 N,N-dimethylformamide (DMF)

31/42
SampleCAS No.

Main use of restriction

68-12-2

Substance on its own, constituent of othersubstances, or in mixtures

after 12 December 2023
(Except in the following cases; appropriate
description is included in the relevant
chemical safety reports and safety data
sheets, appropriate risk management
measures are taken,and appropriate*Add a postscript to be plain though it was non-mention in the original
operational conditions are provided.)Maximum
acceptablevalue
Banning theplacing on themarket and the
use
0.3%

7_REACH_SVHC

32/42

Appendix 7：

REACH-Annex XIV Authorisation and Candidate (SVHC) List
Note: Refer the URL below for detail. Attn: SVHC will be updated about every 6 months.
SVHC Candidate List → http://echa.europa.eu/chem_data/authorisation_process/candidate_list_table_en.asp
Annex XIV authorisation List → http://echa.europa.eu/web/guest/addressing-chemicals-of-concern/authorisation/
recommendation-for-inclusion-in-the-authorisation-list/authorisation-list
rev.2.0/2023.10.1
List No.

Chemical Name

1 Anthracene
2 4,4'-Diaminodiphenylmethane
4,4'-Methylenedianiline
3 Dibutylphthalate (DBP)

Abbreviation or
Chemicalformula120-12-7
101-77-9

4 Cobalt Dichloride
5 Diarsenic pentaoxide

7646-79-9
1303-28-2

231-589-4
215-116-9

6 Diarsenic Trioxide

As2O31327-53-3

215-481-4

7 Sodium dichromate, dihydrate

Cr2Na2O7-2H2O 7789-12-0
10588-01-9
Cr2H4Na2O9

234-190-3

16 2,4-Dinitrotoluene
17 Acrylamide
18 Anthracene oil
19 Anthracene oil, anthracene paste, distn. Lights
20 Anthracene oil, anthracene paste, anthracene
fraction
21 Anthraceneoil, anthracene-low
22 Anthracene oil, anthracene paste
23 Diisobutyl phthalate
24 Lead chromate
25 Lead chromate molybdate sulfate red
Molybdate Red(C.I. Pigment Red 104)
26 Lead sulfochromate yellow
Chrome yellow(C.I. Pigment Yellow 34)
27 Tris(2-chloroethyl)phosphate●201-329-4●('15/5)●('15/5)●('17/9)●('14/8)117-81-7

204-211-0●('15/2)●247-148-4
221-695-9

SCCPs

85535-84-8

287-476-5

C24H54OSn2
TBTO
AsHO4Pb

56-35-9200-268-0

7784-40-9

232-064-2

C19H20O4
BBP
C6H15AsO4

85-68-7

201-622-7

15606-95-8

427-700-2

C7H6N2O4
2,4-DNTC3H5NO

121-14-2

204-450-0

79-06-1
90640-80-5

201-173-7
292-602-7

91995-17-4
91995-15-2
90640-82-7
90640-81-6
84-69-5295-278-5
295-275-9
292-604-8
292-603-2
201-553-2

7758-97-6

231-846-0

C.I. Pigment
Red 104

12656-85-8

235-759-9

C.I. Pigment
Yellow 34

1344-37-2

215-693-7●('15/5)C6H12Cl3O4P
TCEP

115-96-8

204-118-5●('15/8)65996-93-2

266-028-2

79-01-6

201-167-4●('20/10)●('16/4)10043-35-3
11113-50-1

233-139-2
234-343-4
215-540-4

C16H22O4DIBP
CrO4Pb

30 Boric acid

C2HCl3TCE
BH3O3

31 Disodium tetraborate, anhydrous

B4Na2O7

32 Tetraboron disodium heptaoxide, hydrate

201-557-4

134237-50-6
134237-51-7
134237-52-8
HBCDD, γ-HBCDD) 25637-99-4
3194-55-6

28 Coal tar pitch, high temperature
29 Trichloroethylene●('15/2)

11 Alkanes, C10-13, chloro
Short Chain Chlorinated Paraffins
12 Bis(tributyltin)oxide (TBTO)

15 Triethyl arsenate

3rd

84-74-2

81-15-2

14 Benzyl butyl phthalate (BBP)

204-371-1
202-974-4

Subject to theauthorization(Sunset date)('14/8)C12H15N3O6
Musk xylene
9 Bis(2-ethylhexyl)phthalate
C24H38O4
Phthalic acid bis(2-ethylhexyl)
DEHP
Dioctyl phthalate
DOP
10 Hexabromocyclododecane and all major
C12H18Br6
diastereisomers identified (α-HBCDD, β-HBCDD, γ HBCDD(α-HBCDD, β-HBCDD)

13 Lead hydrogen arsenate

2nd

EC No.

C14H10C13H14N2
MDA
C16H22O4
DBP
CoCl2
As2O5

8 5-tert-Butyl-2,4,6-trinitro-m-xylene (Musk xylene)

1stSampleCAS No.

('15/8)●('15/2)12179-04-3
1303-96-4
1330-43-4
B4Na2O7, xH2O 12267-73-1

235-541-3●('15/8)●('20/10)●('15/2)●('15/5)●('15/5)

7_REACH_SVHCEC No.

CrNa2O4

7775-11-3

231-889-5

34 Potassium chromate

CrK2O47789-00-6

232-140-5

35 Ammonium dichromate

Cr2H8N2O7

7789-09-5

232-143-1

36 Potassium dichromate

Cr2K2O7

7778-50-9

231-906-6

37 Cobalt(II) sulphate
38 Cobalt(II) dinitrate
39 Cobalt(II) carbonate
40 Cobalt(II) diacetate
41 2-Methoxyethanol
Ethylene glycol monomethyl ether
42 2-Ethoxyethanol
Ethylene glycol monoethyl ether
43 Chromium trioxide
Chromic anhydride
44 Acids generated from chromium trioxide and their

CoO4S
CON2O6
CCoO3
C4H6CoO4
C3H8O210124-43-3
10141-05-6
513-79-1
71-48-7
109-86-4

233-334-2
233-402-1
208-169-4
200-755-8
203-713-7

C4H10O2

110-80-5

203-804-1

CrO3

1333-82-0

215-607-8

CrH2O4
Cr2H2O713530-68-2
7738-94-5

231-801-5
236-881-5

Cl2Co
C6H12O37646-79-9
111-15-9

231-589-4
203-839-2

CrO4Sr7789-06-2

232-142-6

DHNUP

68515-42-4

271-084-6

H4N2

206-114-9

C5H9NOC3H5Cl3
DIHP

302-01-2
7803-57-8
872-50-4
96-18-4
71888-89-6

C12H4N6O14Pb
C6HN3O8Pb

6477-64-1
15245-44-0

229-335-2
239-290-0

N6Pb
C20H14O4
C13H12Cl2N2MOCA
C4H9NODMAC
As2O8Pb3
As2Ca3O8
AsH3O413424-46-9
77-09-8
101-14-4

236-542-1
201-004-7
202-918-9

127-19-5

204-826-4

3687-31-8
7778-44-1
7778-39-4

222-979-5
231-904-5
231-901-9

61 Bis(2-methoxyethyl) ether
Diethylene glycol dimethyl ether
62 1,2-Dichloroethane

C6H14O3

111-96-6

203-924-4

C2H4Cl2

107-06-2

203-458-1

63 4-(1,1,3,3-Tetramethylbutyl)phenol,(4-tert-Octylphenol)
64 2-Methoxyaniline
o-Anisidine
65 Bis(2-methoxyethyl) phthalate

C14H22O

140-66-9

205-426-2

C7H9NO

90-04-0

201-963-1

C14H18O6

117-82-8

204-212-6

66 Formaldehyde, oligomeric reaction products withaniline (technical MDA)
67 Zirconia Aluminosilicate Refractory Ceramic Fibres (Zr-RCF)(C6H7N.CH2O)x 25214-70-4
MDA－
Zｒ-RCFoligomers:

5th-Chromic acid
-Dichromic acid
4 Cobalt dicholride
45 2-Ethoxyethyl acetate
Ethylene glycol monoethyl ether acetate
46 Strontium chromate(C.I.Pigment yellow 32)
47 1,2-Benzenedicarboxylic acid, di-C7-11-branched
and linear alkyl esters
Di(heptyl, nonyl, undecyl) phthalate (DHNUP)
48 Hydrazine
49 1-Methyl-2-pyrrolidone
50 1,2,3-Trichloropropane
51 1,2-Benzenedicarboxylic acid, di-C6-8-branchedalkyl esters, C7-rich
Diisoheptyl phthalate (DIHP)
52 Lead dipicrate
53 Lead styphnate
2,4,6-Trinitro-1,3-phenylenedioxylead(II)2,4,6-Trinitroresorcinol lead salt
54 Lead diazide
55 Phenolphthalein
56 2,2'-Dichloro-4,4'-methylenedianiline
4,4'-Methylene bis(2-chlorobenzenamine)
57 N,N-Dimethylacetamide
58 Trilead diarsenate
59 Calcium arsenate
60 Arsenic acid6th

Abbreviation or
ChemicalformulaSampleCAS No.

List No.
Chemical Name
3rd
33 Sodium chromate

4th

33/42

a length less than 6μm(Na2O+K2O+CaO+MgO+BaO) less or equal to 18%

68 Aluminosilicate Refractory Ceramic Fibres (RCF)
a length less than 6μm(Na2O+K2O+CaO+MgO+BaO) less or equal to 18%

RCF－

212-828-1
202-486-1
276-158-1

500-036-1(650-01700-8*)(650-01700-8*)

Subject to theauthorization(Sunset date)●('17/9)●('17/9)●('17/9)●('17/9)●('17/9)●('17/9)●('19/1)●('20/7)●('20/7)●('17/11)●('17/8)●('17/8)●('17/11)●('20/7)●('17/8)

7_REACH_SVHC
List No.

7th

34/42
Chemical Name

Abbreviation or
ChemicalformulaSampleCAS No.

EC No.

Subject to theauthorization(Sunset date)

69 Pentazinc chromate octahydroxide(C. I. Pigment Yellow 36)

CrH8O12Zn5

49663-84-5

256-418-0●('19/1)

70 Potassium hydroxyoctaoxodizincatedichromate
Potassium zinc chromate hydroxide
71 Dichromium tris(chromate)
Chromic acid,chromium(3+)salt(3:2)
72 1,2-Bis(2-methoxyethoxy)ethane
Triethylene glycol dimethyl ether ［TEGDME，triglyme］
73 1,2-Dimethoxyethane
Ethylene glycol dimethyl ether ［EGDME］
74 Diboron trioxide
75 Formamide
76 Lead(II) bis(methanesulfonate)

Cr2HKO9Zn2

11103-86-9

234-329-8

Cr5O1224613-89-6

246-356-2●('19/1)●('19/1)

C8H18O4
TEGME(triglyme)
C4H10O2
EGDME
B2O3
CH3NO
C2H6O6PbS2

112-49-2

203-977-3

110-71-4

203-794-9
215-125-8
200-842-0
401-750-5

77 1,3,5-Tris(oxiranylmethyl)-1,3,5-triazine2,4,6(1H,3H,5H)-trione
1,3,5-Trisglycidylisocyanuric acid[TGIC]
78 1,3,5-Tris[(2S and 2R)-2,3-epoxypropyl]-1,3,5triazine-2,4,6-(1H,3H,5H)-trione[β-TGIC]C12H15N3O6
TGIC

1303-86-2
75-12-7
17570-76-2
95860-12-1
2451-62-959653-74-6

423-400-0

79 4,4'-Bis(dimethylamino)benzophenone[Michler's ketone]Bis[4-(dimethylamino)phenyl] ketone
80 N,N,N',N'-Tetramethyl-4,4'-methylenedianiline
4,4'-Bis(dimethylamino)diphenylmethane[Michler's base]81 [4-[4,4'-Bis(dimethylamino)
benzhydrylidene]cyclohexa-2,5-dien-1ylidene]dimethylammonium chloride[C.I. Basic Violet 3]
82 [4-[[4-Anilino-1-naphthyl][4(dimethylamino)phenyl]methylene]cyclohexa-2,5dien-1-ylidene] dimethylammonium chloride[C.I. Basic Blue 26]
83 α,α-Bis[4-(dimethylamino)phenyl]-4(phenylamino)naphthalene-1-methanol[C.I. Solvent Blue 4]
84 4,4'-Bis(dimethylamino)-4''-(methylamino)trityl
alcohol[ with ≥ 0.1% of Michler's ketone (EC No. 202-0275) or Michler's base (EC No. 202-959-2)][C.I. Solvent Violet 8]
Bis(4-dimethylaminophenyl)(4methylaminophenyl)methanol
α,α-Bis[4-(dimethylamino)phenyl]-4(methylamino)benzenemethanol
85 Bis(pentabromophenyl) ether
Decabromodiphenylether
86 Pentacosafluorotridecanoic acid
Perfluorotridecanoic acid
87 Tricosafluorododecanoic acid
Perfluorododecanoic acid
88 Henicosafluoroundecanoic acid

C17H20N2O
90-94-8
Micheler's
ketoneC17H22N2
101-61-1
Micheler's base202-027-5

C25H30N3Cl
548-62-9
C.I. Basic Violet
3

208-953-6

ClC33H32N3
C.I. Basic Blue26

2580-56-5

219-943-6

C33H33N3O
C.I. Solvent
Blue 4
C24H29N3O
C.I. Solvent
Violet 8

6786-83-0

229-851-8

561-41-1

209-218-2

C12Br10O
DecaBDEC13HF25O2

1163-19-5

214-604-972629-94-8

276-745-2

C12HF23O2PFUA
C11HF21O2

307-55-1

206-203-2

2058-94-8

218-165-4

89 Heptacosafluorotetradecanoic acidC14HF27O2
Perfluorotetradecanoic acid90 4-(1,1,3,3-Tetramethylbutyl)phenol, ethoxylated(C14H22O他)[covering well-defined substances and UVCB
substances, polymers and homologues]
91 4-Nonylphenol, branched and linear
C15H24O[substances with a linear and/or branched alkyl
chain with a carbon number of 9 covalently boundin position 4 to phenol, covering also UVCB(*)- andwell-defined substances which include any of theindividual isomers or a combination thereof]

376-06-7

206-803-4

C12H15N3O6
β-TGIC

219-514-3

202-959-2(140-66-9他) (205-426-2
他)
104-40-5(84852-15-3
他)(284-325-5
他)●('25/5)●('21/1)

7_REACH_SVHC
List No.

35/42
Chemical Name

92 Diazene-1,2-dicarboxamide (C,C'azodi(formamide))

EC No.
204-650-8

93 Cyclohexane-1,2-dicarboxylic anhydride [1]C8H10O3
cis-cyclohexane-1,2-dicarboxylic anhydride [2]HHPA
trans-cyclohexane-1,2-dicarboxylic anhydride [3][The individual cis- [2] and trans- [3] isomer
substances and all possible combinations of thecis- and trans-isomers [1] are covered by this entry](Hexahydrophthalic anhydride - HHPA)
94 Hexahydromethylphathalic anhydride [1],C9H12O3Hexahydro-4-methylphathalic anhydride [2],Hexahydro-1-methylphathalic anhydride [3],Hexahydro-3-methylphathalic anhydride [4][The individual isomers [2], [3] and [4] (including
their cis- and trans- stereo isomeric forms) and all
possible combinations of the isomers [1] arecovered by this entry]

13149-00-3
14166-21-3
85-42-7

201-604-9
236-086-3
238-009-9

19438-60-9
25550-51-0
48122-14-1
57110-29-9

247-094-1
243-072-0
256-356-4
260-566-1

95 Methoxy acetic acid
96 1,2-Benzenedicarboxylic acid, dipentylester,branched and linear
97 Diisopentylphthalate (DIPP)C3H6O3
C18H26O4

625-45-6
84777-06-0

210-894-6
284-032-2

C18H26O4
DIPP
C18H26O4

605-50-5

210-088-4

C6H14O2

629-14-1

211-076-1

C3H7NODMF
C8H18Cl2Sn
DBT
C2H4O3Pb
C2H2O8Pb3
White lead
O5Pb2S

68-12-2

200-679-5

683-18-1

211-670-0

51404-69-4
1319-46-6

257-175-3
215-290-6

12036-76-9

234-853-7

C8H4O6Pb3

69011-06-9

273-688-5

C36H70O6Pb3

12578-12-0

235-702-8

108 Lead bis(tetrafluoroborate)

B2F8Pb91031-62-8
13814-96-5

292-966-7
237-486-0

109 Lead cynamidate

CH2N2Pb

20837-86-9

244-073-9

N2O6PbOPb

10099-74-8
1317-36-8

233-245-9
215-267-0

O4Pb3

1314-41-6

215-235-6

O3PbTiO2PbTiZr
PZT
O8Pb5S
C.I. Pigment
Yellow 4112060-00-3
12626-81-2

235-038-9
235-727-4

12065-90-6
8012-00-8

235-067-7
232-382-1

68784-75-8
11120-22-2
62229-08-7
78-00-2

272-271-5
234-363-3
263-467-1
201-075-4

12202-17-4
12141-20-7
110-00-975-56-9235-380-9
235-252-2
203-727-3
200-879-2

64-67-5

200-589-6

99 1,2-Diethoxyethane
Ethylene glycol diethyl ether
100 N,N-Dimethylformamide; dimethyl formamide
101 Dibutyltin dichloride (DBT)102 Acetic acid, lead salt, basic
103 Basic lead carbonate

Trilead bis(carbonate)dihydroxide
104 Lead oxide sulfate

Basic lead sulfate
105 [Phthalato(2-)]dioxotrilead
Dibasic lead phthalate
106 Dioxobis(stearato)trilead

C2H4N4O2

SampleCAS No.

123-77-3

98 N-Pentyl-isopentylphtalate

8th

Abbreviation or
Chemicalformula107 Fatty acids, C16-18, lead salts

Lead cyanamide
110 Lead dinitrate
111 Lead oxide(Lead monoxide)
112 Lead tetraoxide (orange lead)
Lead(II,IV) oxide
113 Lead titanium trioxide
114 Lead Titanium Zirconium Oxide
115 Pentalead tetraoxide sulphate
116 Pyrochlore, antimony lead yellow(C.I. Pigment yellow 41)
117 Silicic acid, barium salt, lead-doped
118 Silicic acid, lead salt
119 Sulfurous acid, lead salt, dibasic
120 Tetraethyllead
121 Tetralead trioxide sulphate
122 Trilead dioxide phosphonate
123 Furan
124 Propylene oxide;

1,2-Epoxypropane;
Methyloxirane
125 Diethyl sulphate

H2O5Pb2S
C8H20Pb
TEL
O7Pb4S
HO5PPb3
C4H4O
C3H6O

C4H10O4S
DES

776297-69-9 -Subject to theauthorization(Sunset date)●('20/7)●('20/7)●('20/7)●(25/5)

7_REACH_SVHC
List No.

36/42
Chemical Name

126 Dimethyl sulphate
127 3-Ethyl-2-methyl-2-(3-methylbutyl)-1,3-oxazolidine
128 Dinoseb

6-sec-Butyl-2,4-dinitrophenol
129 4,4'-Methylenedi-o-toluidine
3,3'-Dimethyl-4,4'-diaminodiphenylmethane
130 4,4'-Oxydianiline and its salts
4,4'-Diaminodiphenyl ether
131 4-Aminoazobenzene;
4-Phenylazoaniline
132 4-Methyl-m-phenylenediamine
2,4-Toluenediamine
133 6-Methoxy-m-toluidine
2-Methoxy-5-methylaniline
p-Cresidine
134 4-Aminobiphenyl
Xenylamine
Biphenyl-4-ylamine
135 o-Aminoazotoluene
4-Amino-2',3-dimethylazobenzene
4-o-Tolylazo-o-toluidine
136 o-Toluidine;
2-Aminotoluene
137 N-Methylacetamide
138 1-Bromopropane;n-Propyl bromide
139 Cadmium
140 Cadmium oxide
141 Dipentyl phthalate (DPP)

Abbreviation or
ChemicalformulaSampleCAS No.

C2H6O4S
C11H23NO

77-78-1
201-058-1
143860-04-2 421-150-7

C10H12N2O5
DNSBP
C15H18N2
MBOT
C12H12N2O
DADPE
C12H11N3

88-85-7

201-861-7

838-88-0

212-658-8

101-80-4

202-977-0

60-09-3

200-453-6

C7H10N2

95-80-7

202-453-1

C8H11NO

120-71-8

204-419-1

C12H11N
4-ABP

92-67-1

202-177-1

C14H15N3

97-56-3

202-591-2

C7H9N

95-53-4

202-429-0

C3H7NOC3H7Br

79-16-3
106-94-5

201-182-6
203-445-0

Cd
CdO

7440-43-9
1306-19-0

231-152-8
215-146-2

C18H26O4

131-18-0

205-017-9

142 4-Nonylphenol, branched and linear, ethoxylated

9th(C2H4O)nC15H24 [substances with a linear and/or branched alkyl
O , with n≥1
chain with a carbon number of 9 covalently boundin position 4 to phenol, ethoxylated covering
UVCB- and well-defined substances, polymers andhomologues, which include any of the individual
isomers and/or combinations thereof]
143 Ammonium pentadecafluorooctanoate (APFO)
C8H4F15NO2
3825-26-1
144 Pentadecafluorooctanoic acid (PFOA)C8HF15O2
335-67-1
145 Cadmium sulphide
CdS
1306-23-6
146 Dihexyl phthalate (DnHP)
C20H30O4
84-75-3

223-320-4
206-397-9
215-147-8
201-559-5

147 Disodium 3,3'-[[1,1'-biphenyl]-4,4'-

209-358-4

C32H24N6O6S2.2 573-58-0
diylbis(azo)]bis(4-aminonaphthalene-1-sulphonate) Na(C.I. Direct Red 28)
148 Disodium 4-amino-3-[[4'-[(2,4C34H25N9Na2O7 1937-37-7
diaminophenyl)azo][1,1'-biphenyl]-4-yl]azo] -510th
S2hydroxy-6-(phenylazo)naphthalene-2,7disulphonate (C.I. Direct Black 38)
149 Imidazolidine-2-thione; 2-imidazoline-2-thiol
C3H6N2S
96-45-7
150 Lead di(acetate)-301-04-225155-23-1

206-104-4
246-677-8

152 1,2-Benzenedicarboxylic acid,

C20H30O4

68515-50-4

271-093-5

dihexyl ester, branched and linear (DIHP)
153 Cadmium chloride

CdCl2

10108-64-2

233-296-7

BH3O4.Na
etc.
BO3.Na15120-21-5
11138-47-9
7632-04-4

239-172-9
234-390-0
231-556-4

C22H29N3O

25973-55-1

247-384-8

C20H25N3O

3846-71-7

223-346-6

C36H72O4S2Sn

15571-58-1

239-622-4

CdF2

7790-79-6

232-222-0(UV-328)
157 2-benzotriazol-2-yl-4,6-di-tert-butylphenol(UV-320)158 2-ethylhexyl 10-ethyl-4,4-dioctyl-7-oxo-8-oxa-3,5dithia-4-stannatetradecanoate (DOTE)
159 Cadmium fluoride●(20/7)●(20/7)●(21/1)●(23/2)

202-506-9

C4H6O4Pb
C24H27O4P

156 2-(2H-benzotriazol-2-yl)-4,6-ditertpentylphenol

Subject to theauthorization(Sunset date)

217-710-3

151 Trixylyl phosphate

11th 154 Sodium perborate
Perboric acid, sodium salt
155 Sodium peroxometaborate

12th

EC No.

●(23/5)●(23/2)●(23/5)●(23/5)●(23/11)●(23/11)●(25/5)

7_REACH_SVHC
List No.

37/42
Chemical Name

160 Cadmium sulphate

Abbreviation or
ChemicalformulaCd.H2O4S

165 2,4-di-tert-butyl-6-(5-chlorobenzotriazol-2-yl)phenol(UV-327)
166 2-(2H-benzotriazol-2-yl)-4-(tert-butyl)-6-(secbutyl)phenol
14th(UV-350)
167 Nitrobenzene
168 Perfluorononan-1-oic-acid and its sodium and

169 Benzo[def]chrysene(Benzo[a]pyrene)
170 4,4'-isopropylidenediphenol
171 4-heptylphenol, branched and linear [substanceswith a linear and/or branched alkyl chain with acarbon number of 7 covalently
bound predominantly in position 4 to phenol,
covering also UVCB- and well-defined
16th
substances which include any of the individual
isomers or a combination thereof]
172 Nonadecafluorodecanoic acid (PFDA) and its
sodium and ammonium salts
173 p-(1,1-dimethylpropyl)phenol

17th

174 Perfluorohexane-1-sulphonic acid and its salts-●(25/5)-

68515-51-5
68648-93-1

271-094-0
272-013-1●(23/2)

C17H30O2--●(23/8)C3H6O3S

1120-71-4

214-317-9

C20H24ClN3O

3864-99-1

223-383-8

C20H25N3O

36437-37-3

253-037-1

C6H5NO2

98-95-3

202-716-0

C9HF17O2

206-801-3

C20H12375-95-1
21049-39-8
4149-60-4
50-32-8

C15H16O2-

80-05-7-

201-245-8-

C10H4F19NO2
C10HF19NO2
C10F19NaO2
C11H16OC6HF13O3S

3108-42-7
335-76-2
3830-45-3
80-46-6
355-46-4

221-470-5
206-400-3－
201-280-9
206-587-1－－

200-280-6

209-136-7
208-764-9
208-762-8
231-100-4
234-541-0
205-883-8
262-967-7
203-468-6
209-008-0

cyclo[12.2.1.16,9.02,13.05,10]octadeca-7,15-diene(“Dechlorane Plus”TM) [covering any of its
individual anti- and syn-isomers or any combination
176 Benz[a]anthracene
C18H12175 1,6,7,8,9,14,15,16,17,17,18,18Dodecachloropenta

177 Cadmium nitrate

Cd(NO3)2

18th 178
Cadmium carbonate
180 Chrysene

CCdO3
Cd(OH)2
C3H8O3181 Reaction products of 1,3,4-thiadiazolidine-2,5--56-55-3
1718-53-2
10325-94-7
10022-68-1
513-78-0
21041-95-2
218-01-9
1719-03-5－

C8H24O4Si4
C10H30O5Si5
C12H36O6Si6Pb
B8H8Na2O17
C22H12
C18H22C2H8N2Ｃ9Ｈ4Ｏ5556-67-2
541-02-6
540-97-6
7439-92-1
12008-41-2
191-24-2
61788-32-7
107-15-3
552-30-7

179 Cadmium hydroxide (Cd(OH)2)

dithione, formaldehyde and 4-heptylphenol,
branched and linear (RP-HP) [with ≥0.1% w/w 4heptylphenol, branched and linear]
182 Octamethylcyclotetrasiloxane (D4)183 Decamethylcyclopentasiloxane (D5)184 Dodecamethylcyclohexasiloxane (D6)185 Lead
186 Disodium octaborate
19th 187 Benzo[ghi]perylene
188 Terphenyl, hydrogenated
189 Ethylenediamine (EDA)
190 Benzene-1,2,4-tricarboxylic acid 1,2 anhydride(Trimellitic Anhydride (TMA)）

Subject to theauthorization(Sunset date)233-331-6

ammonium salts
15th

EC No.

10124-36-4
31119-53-6-

12th 161 Reaction mass of 2-ethylhexyl 10-ethyl-4,4-dioctyl- C H O S Sn
36 72 4 27-oxo-8-oxa-3,5-dithia-4-stannatetradecanoate and C38H74O6S3Sn
2-ethylhexyl 10-ethyl-4-[[2-[(2-ethylhexyl)oxy]-2oxoethyl]thio]-4-octyl-7-oxo-8-oxa-3,5-dithia-4stannatetradecanoate (reaction mass of DOTE andMOTE)(*)As the identification and naming of substancesby ECHA, "Reaction mass" means the multiconstituent substance (mixture)
162 1,2-benzenedicarboxylicacid, di-C6-10-alkyl
esters; 1,2-benzenedicarboxylic acid, mixed decyl
and hexyl and octyl diesters with ≥ 0.3% of dihexyl
phthalate (EC No. 201-559-5)
13th 163 5-sec-butyl-2-(2,4-dimethylcyclohex-3-en-1-yl)-5methyl-1,3-dioxane [1], 5-sec-butyl-2-(4,6dimethylcyclohex-3-en-1-yl)-5-methyl-1,3-dioxane[2] [covering any of the individual isomers of [1]and [2] or any combination thereof]
164 1,3-propanesultone

SampleCAS No.

●(23/11)●(23/11)200-028-5

233-710-6
208-168-9
244-168-5
205-923-4－●(25/5)

19th
7_REACH_SVHC
List No.

38/42
Chemical Name

191 dicyclohexyl phtahlates (DCHP)
192 1,7,7-trimethyl-3-

Abbreviation or
ChemicalformulaSampleCAS No.

EC No.

Ｃ20Ｈ26Ｏ4
C17H20O

84-61-7
15087-24-8

201-545-9
239-139-9

C18H22O2

6807-17-6

401-720-1

C20H12
C16H10207-08-9
206-44-0
93951-69-0
85-01-8
129-00-0
1718-52-1-

205-916-6
205-912-4

C10H14O
C5H10O3
C23H30N2O2
C15H21NO2S
C20H30O4

98-54-4
110-49-6
71850-09-4
119313-12-1
71868-10-5

202-679-0
203-772-9
276-090-2
404-360-3
400-600-6

C5H6N2C4H6N2
C18H32O4Sn
C11H14O3

1072-63-5
693-98-1
22673-19-4
94-26-8

214-012-0
211-765-7
245-152-0
202-318-7

C10H22O5-

143-24-8-

205-594-7-(phenylmethylene)bicyclo[2.2.1]heptan-2-one
193 2,2-bis(4'-hydroxyphenyl)-4-methylpentane
194 Benzo[k]fluoranthene
20th
195 Fluoranthene
196 Phenanthrene
197 Pyrene

C14H10
C16H10

24th

23rd

22nd

21ｔｈ

198 Tris(4-nonylphenyl, branched and linear) phosphite -25th(TNPP) with ≥ 0.1% w/w of 4-nonylphenol,
branched and linear (4-NP)
199 4-tert-butylphenol
200 2-methoxyethyl acetate
201 4-tert-butylphenol
202 Diisohexyl phthalate
203 2-benzyl-2-dimethylamino-4'204 2-methyl-1-(4-methylthiophenyl)-2morpholinopropan-1-one
205 Perfluorobutane sulfonic acid (PFBS) and its salts
206 1-vinylimidazole
207 2-methylimidazole
208 Dibutylbis(pentane-2,4-dionato-O,O')tin
209 Butyl 4-hydroxybenzoate(Butylparaben)
210 Bis(2-(2-methoxyethoxy)ethyl)ether
211 Dioctyltin dilaurate, stannane, dioctyl-, bis(cocoacyloxy) derivs., and any other stannane, dioctyl-,bis(fatty acyloxy) derivs. wherein C12 is the
predominant carbon number of the fatty acyloxy
212 1,4-dioxane

28th

-

C4H8O2123-91-1

204-661-8

213 2,2-bis(bromomethyl)propane-1,3-diol (BMP); 2,2-

-

-

-

dimethylpropan-1-ol, tribromo derivative/3-bromo2,2-bis(bromomethyl)-1-propanol (TBNPA); 2,3dibromo-1-propanol (2,3-DBPA)
214 2-(4-tert-butylbenzyl)propionaldehyde and its
individual stereoisomers
215 4,4'-(1-methylpropylidene)bisphenol

-

-

-

C16H18O2

77-40-7

201-025-1

216 glutaral

C5H8O2111-30-8

203-856-5

217 Medium-chain chlorinated paraffins (MCCP)

-

-

-

-

-

-

-

119-47-1
1067-53-4-

204-327-1
213-934-0--

255881-94-8 401-850-9[UVCB substances consisting of more than orequal to 80% linear chloroalkanes with carbon
chain lengths within the range from C14 to C17]
218 orthoboric acid, sodium salt
219 Phenol, alkylation products (mainly in para
position) with C12-rich branched alkyl chains fromoligomerisation, covering any individual isomers
and/ or combinations thereof (PDDP)
220 6,6′-di-tert-butyl-2,2′-methylenedi-p-cresol (DBMC)
221 tris(2-methoxyethoxy)vinylsilane
222 (±)-1,7,7-trimethyl-3-[(4methylphenyl)methylene]bicyclo[2.2.1]heptan-226th
one covering any of the individual isomers and/or
combinations thereof (4-MBC)
223 S-(tricyclo[5.2.1.0’2,6]deca-3-en-8(or 9)-yl) O(isopropyl or isobutyl or 2-ethylhexyl) O-(isopropyl
or isobutyl or 2-ethylhexyl) phosphorodithioate
27th 224 N-(hydroxymethyl)acrylamide

29th

201-581-5
204-927-3

225 1,1'-[ethane-1,2-diylbisoxy]bis[2,4,6-tribromobenzene]
226 2,2',6,6'-tetrabromo-4,4'-isopropylidenediphenol[Tetrabromobisphenol A]
227 4,4'-sulphonyldiphenol[bisphenol S]
228 Barium diboron tetraoxide
229 Bis(2-ethylhexyl) tetrabromophthalate covering any of theindividual isomers and/or combinations thereof
230 Isobutyl 4-hydroxybenzoate
231 Melamine
232 Perfluoroheptanoic acid and its salts
233 reaction mass of 2,2,3,3,5,5,6,6-octafluoro-4-(1,1,1,2,3,3,3heptafluoropropan-2-yl)morpholine and 2,2,3,3,5,5,6,6octafluoro-4-(heptafluoropropyl)morpholine
234 Diphenyl(2,4,6trimethylbenzoyl)phosphine oxide

C4H8O2
C15H12Br4O2
TBBPA
C12H10O4S
BPS
B2BaO4
TBPH

924-42-5

213-103-2

37853-59-1
79-94-7

253-692-3
201-236-9

80-09-1

201-250-5

13701-59-2-

237-222-4-

C3H6N6PFHpA-

4247-02-3
108-78-1-

224-208-8
203-615-4
473-390-7

C22H21O2P

75980-60-8

278-355-8

Subject to theauthorization(Sunset date)7_REACH_SVHC

29th

List No.

39/42
Chemical Name

235 Bis(4-chlorophenyl) sulphone

Abbreviation or
ChemicalformulaC12H8Cl2O2S

SampleCAS No.
80-07-9

EC No.

Subject to theauthorization(Sunset date)

201-247-9* The date in the ( ) is the sunset date.
The deadline of application for authorisation is 18 months before*UVCB
Substances of Unknown or Variable composition, Complex reaction products or Biological materials

Appendix 8. List of aromatic amines
No.
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24

Substance Name
4-Aminoazobenzene
4-Phenylazoaniline
2-Methoxyaniline
o-Anisidine
2-Naphthylamine
3,3'-Dichlorobenzidine
3,3'-Dichlorobiphenyl-4,4'-diamine
4-Aminobiphenyl
Xenylamine
Biphenyl-4-ylamine
Benzidine
4,4'-Biphenyldiamine
4,4'-Diaminobiphenyl
o-Toluidine
2-Aminotoluene
4-Chloro-o-toluidine
4-Methyl-m-phenylenediamine
2,4-Toluenediamineo-Aminoazotoluene
4-Amino-2',3-dimethylazobenzene
4-o-Tolylazo-o-toluidine
5-Nitro-o-toluidone
2-Amino-4-nitrotoluene
2,2'-Dichloro-4,4'-methylene-dianiline
4,4'-Methylene-bis-(2-chloro-aniline)
4,4'-Diaminodiphenylmethane
4,4'-Methylenedianiline
4,4'-Oxydianiline
4,4'-Diaminodiphenylether
4-Chloroaniline
p-Chloroaniline
3,3'-Dimethoxybenzidine
o-Dianisidine
4,4'-Bi-o-toluidine
3,3'-Dimethylbenzidine
6-Methoxy-m-toluidine
2-Methoxy-5-methylaniline
p-Cresidine
2,4,5-Trimethylaniline

rev..0 2021.11.01
CAS No60-09-3
90-04-0
91-59-8
91-94-1
92-67-1
92-87-5
95-53-4
95-69-2 [1]3165-93-3 [2]95-80-7
97-56-3
99-55-8 [1]51085-52-0 [2]101-14-4
101-77-9
101-80-4
106-47-8
119-90-4
119-93-7
120-71-8
137-17-7 [1]21436-97-5 [2]
139-65-1

4,4'-Thiodianiline
4,4'-Diaminodiphenyl sulfide
2,4-Diaminoanisole
615-05-4 [1]
4-Methoxy-m-phenylenediamine
39156-41-7 [2]4,4'-Methylenedi-o-toluidine
838-88-0
3,3'-Dimethyl-4,4'-diaminodiphenylmethane
2,6-Xylidine
87-62-7
2,6-Dimethylaniline
2,4-Xylidine
95-68-1
2,4-Dimethylaniline*: Although these substances are not subject to the
Restriction of REACH regulation in EU,
they are applicable in China and South Korea.

**

Appendix 9. List of Hexabromocyclododecane（HBCD or HBCDD）
rev..0 2021.11.01
No.

物質名Alpha-hexabromocyclododecane;1rel-(1R,2R,5S,6R,9R,10S)-1,2,5,6,9,10-Hexabromocyclododecane
Beta-hexabromocyclododecane;2rel-(1R,2S,5R,6R,9R,10S)-1,2,5,6,9,10-Hexabromocyclododecane
Gamma-hexabromocyclododecane;3rel-(1R,2R,5R,6S,9S,10R)-1,2,5,6,9,10-Hexabromocyclododecane
4 (1R,2R,5R,6S,9S,10S)-1,2,5,6,9,10-Hexabromocyclododecane
5 (1R,2R,5R,6S,9R,10S)-1,2,5,6,9,10-Hexabromocyclododecane
6 (1R,2S,5S,6R,9S,10S)-1,2,5,6,9,10-Hexabromocyclododecane
7 (1R,2S,5S,6S,9S,10R)-1,2,5,6,9,10-Hexabromocyclododecane
8 Hexabromocyclododecane
9 1,2,5,6,9,10-hexabromocyclododecane
10 rel-(1R,2S,5R,6S,9R,10S)-1,2,5,6,9,10-Hexabromocyclododecane
11 rel-(1R,2S,5R,6S,9S,10R)-1,2,5,6,9,10-Hexabromocyclododecane
12 (1R,2R,5S,6R,9R,10S)-1,2,5,6,9,10-Hexabromocyclododecane
13 (1R,2S,5R,6S,9S,10S)-1,2,5,6,9,10-Hexabromocyclododecane
14 (1R,2R,5R,6S,9S,10R)-1,2,5,6,9,10-Hexabromocyclododecane

CAS No134237-50-6
134237-51-7
134237-52-8138257-17-7
138257-18-8138257-19-9
169102-57-2
25637-99-4
3194-55-6
4736-49-6
65701-47-5
678970-15-5
678970-16-6
678970-17-7

Appendix 10. List of Perfluorooctanoic acid (PFOA)
and its salts and its esters
rev..0 2021.11.01
No.
物質名
1 Perfluorooctanoic acid (PFOA)
2 Perfluorooctanoic acid ammonium salt
3 Perfluorooctanoic acid sodium salt
4 Perfluorooctanoic acid potassium salt
5 Perfluorooctanoic acid silver salt
6 Perfluorooctanoic acid fluoride
7 Perfluorooctanoic acid methyl ester
8 Perfluorooctanoic acid ethyl ester

CAS No335-67-1
3825-26-1
335-95-5
2395-00-8
335-93-3
335-66-0
376-27-2
3108-24-5