Joint Symposium on Fundamental Aspects of
Nanostructured Materials and Electrocatalysis

19th CRC International Symposium
and

CHAIRS
K. Uosaki (Division of Chemistry, Graduate School of Science, Hokkaido University)
M. Osawa (Catalysis Research Center, Hokkaido University)

INVITED SPEAKERS
P. Allongue (Palaiseau)
A. Cuesta (Madrid)
K. Hara (Sapporo)
T. Inabe (Sapporo)
S. Kuwabata (Osaka)
M. Osawa (Sapporo)
S. G. Sun (Xiamen)
T. Takeguchi (Sapporo)
M. Watanabe (Kofu)

K. Asakura (Sapporo)
J. Feliu (Alicante)
A. Hillman (Leicester)M. Kiguchi (Sapporo)
N. Markovic (Argonne)
D. Scherson (Cleveland)
T. Suzuki (Sapporo)
K. Tanaka (Saitama)
A. Wieckowski (Urbana)

H. Baltruschat (Bonn)
A. Gewirth (Urbana)N. Hoshi (Chiba)
M. T. Koper (Leiden)
T. Morikawa (Osaka)
K. Shimazu (Sapporo)
J. Switzer (Rolla)
R. Yamada (Osaka)

Contactt: ICEI_2007_sec@pcl.sci.hokudai.ac.jp

E. Borguet (Philadelphia)
J. Gooding (Sydney)
K. Ikeda (Sapporo)
M. Kubo (Sendai)
H. Noguchi (Sapporo)
J. Stickney (Athens)
S. Takeda (Sapporo)
S. Ye (Sapporo)Joint Symposium on
Fundamental Aspects of Nanostructured Materials andElectrocatalysis
June 22-23, 2007
Catalysis Research Center and Graduate School of Science
Hokkaido University

Symposium site:
Graduate School of Science, Hokkaido University (N10W8, Sapporo)
Bld. # 7 (room 7-310): Registration, Plenary Lectures, and Electrocatalytic Session
Bld. # 7 (room 7-219): Nanostructured Material Session)
Bld. #6 : Poster presentation

URL: http://www.cat.hokudai.ac.jp/osawa/pre_symposium2007.pdf
Chairs:Kohei Uosaki (Nanostructured Materials Session)
Division of Chemistry, Graduate School of Science, Hokkaido University, Sapporo
060-0810
Phone: +81-11-706-3812, FAX: +81-11-706-3440
E-mail: uosaki@pcl.sci.hokudai.ac.jp
Masatoshi Osawa (Electrocatalysis Session)
Catalysis Research Center, Hokkaido University, N21W10, Sapporo 001-0021
Phone : +81-11-706-9123; Fax : +81-11-706-9123
E-mail: osawam@cat.hokudai.ac.jp

Contact : ICEI_2007_sec@cl.sci.hokudai.ac.jp
Registration Fees : Free
Banquet :General :Student :4,000 yen
1,000 yen

Time Table
June 22 (Friday)
9:30

Registration

10:00

Open Ceremony

10:15

PL1 (Marković)

11:15

PL2 (Scherson)

12:15-13:30

Lunch

Nanostructured Material

Electrocatalysis

13:30

Switzer

13:30

Koper

14:00

Inabe

14:00

Hoshi

14:30

Stickney

14:20

Sun

15:00-16:15

Short presentation for
poster by students(P11-P24)

14:50

Kubo

15:20

Morikawa

16:30-19:00

Poster Session

19:00-20:30

BanquetJune 23 (Saturday)
Nanostructured Material
Electrocatalysis
9:30

Gooding

9:30

Wieckowski

10:00

Kiguchi

10:00

Noguchi

10:20

Yamada10:20

Takeguchi

10:40

Coffee Break

11:00

Borguet11:00

Asakura11:30

Kuwabata

11:30

Cuesta12:00

Allongue

12:00

Watanabe

12:30-13:45

Lunch

13:45

Takeda13:45

Tanaka

14:15

Ye

14:15

Baltruschat

14:45

Ikeda

14.45

Gewirth

15:05-15:35

Coffee break

15:15-15:35

Coffee break

15:35

Suzuki

15:35

Feliu

16:05

Hara

16:05

Shimazu

16:25

Hillman

16:35

Osawa

ProgramJune 22 (Fri.)
9:30–

Registration (7-310)

10:00–10:15

Opening address
Prof. Keizo Yamaguchi(Dean, Graduate School of Science, Hokkaido University)
Prof. Wataru Ueda
(Director, Catalysis Research Center, Hokkaido University)

Plenary Lectures (7-310)
Chair: Kohei Uosaki
PL1

10:15–11:15
Nenad M. Marković (Argonne National Laboratory, USA)
“Surface science of fuel cell reactions: from model systems to real catalysts”

PL2

11:15–12:15
Daniel A. Scherson (Case Western Reserve University, USA)“In situ real-time microspectroscopy”
12:15–13:30

Lunch

Nanostructured material session (7-219)
Chair: Tetsuya Taketsugu
N1

13:30–14:00
Jay A. Switzer (University of Missouri-Rolla, USA)
“Epitaxial electrodeposition of nanostructured zinc oxide from alkaline solution”

N2

14:00–14:30
Tamotsu Inabe (Hokkaido University, Japan)“Electrode surfaces for the electrochemical crystallization of molecular conductors”

N3

14:30–15:00
John L. Stickney (University of Georgia, USA)
“Electrochemical ALD of metals and semiconductors”
15:00–16:15

Short presentation by graduate students of Graduate School of
Science presentation (5 min. / poster)Electrocatalysis session (7-310)
Chair: Masatoshi Osawa
E1

13:30–14:00
Marc T. M. Koper (Leiden University, Netherlands)"Structure sensitivity of electrocatalytic reactions"E2

14:00–14:20
Nagahiro Hoshi (Chiba University, Japan)“Surface electrochemistry on high index planes”

E3

14:20–14:50
Shi-Gang Sun (Xiamen University, China)“Electrocatalysts of well-defined structure — From single crystal planes to shapecontrolled nanoparticles”

E4

14:50–15:20
Momoji Kubo (Tohoku University, Japan)“Quantum chemical molecular dynamics approach to electrode reaction dynamics inpolymer electrolyte fuel cell”

E5

15:20–15:50
Yoshitada Morikawa (Osaka University, Japan)“First-principles molecular dynamics simulation of chemical reactions at electrodesurfaces”

16:30–19:00

Poster session (Bld. #6)

19:00–20:30

Banquet (Bld. #6)

June 23 (Sat.)
Nanostructured material session (7-219)
Chair: Susumu Kuwabata
N6

9:30–10:00
J. Justin Gooding (The University of New South Wales, Australia)“The electrochemical performance of electrodes modified with carbon nanotubes”

N7

10:00–10:20
Manabu Kiguchi (Hokkaido University, Japan)“Conductance of a single molecule bridging metal electrodes”

N8

10:20–10:40
Ryo Yamada (Osaka University, Japan)“Conductance of oligothiophene molecules”
10:40–11:00

Coffee break

Chair: Jay A. Switzer
N9

11:00–11:30
Eric U. Borguet (Temple University, USA)
“Nanostructured materials by electrodeposition onto molecular scale templates”

N10

11:30–12:00
Susumu Kuwabata (Osaka University, Japan)“Photoelectrochemical preparation of emissive semiconductor Q-dots using as
fluorescence reagents”

N11

12:00–12:30
Philippe Allongue (CNRS, France)“Electrochemical lithography using ns voltage pulses”
12:30–13:45

Lunch

Chair: Kei Murakoshi
N12

13:45–14: 15
Sadamu Takeda (Hokkaido University)“Surface of antiferromagnetic nano particles and gold nano particles as studied bysolid-state NMR”
N13

14:15–14:45
Shen Ye (Hokkaido University, Japan)“Interfacial structures of thin film materials probed by sum frequency generation(SFG) spectroscopy”

N14

14:45–15:05
Katsuyoshi Ikeda (Hokkaido University, Japan)“Hyper-Raman spectroscopy for carbon nanomaterials”
15:05–15:35

Coffee break

Chair: Masako Kato
N15

15:35–16:05
Takanori Suzuki (Hokkaido University, Japan)“Toward the realization of unimolecular memory: novel approach from organic
chemistry by using “Dynamic redox system” ”

N16

16:05–16:25
Kenji Hara (Hokkaido University, Japan)“Densely-packed self-assembled monolayer of phosphine-terminated alkanethiolate
on gold surface”

N17

16:25–16:55
A. Robert Hillman (University of Leicester, UK)“EQCM studies of dopant and solvation dynamics in p- and n-doping of PEDOT films”

Electrocatalysis session (7-310)
Chair: Shen Ye
E6

9:30–10:00
Andrzej Wieckowski (University of Illinois, USA)
“Details in Use of BB-SFG for Studies of Adsorption on Electrochemical Surfaces”

E7

10:00–10:20
Hidenori Noguchi (Hokkaido University, Japan)“SFG study on potential and time dependent structures of electrochemical interfaces”

E8

10:20–10:40
Tatsuya Takeguchi (Hokkaido University, Japan)“Preparation of CO-tolerant Multicomponent Anodes Modified with Metal oxide forPEFC”
10:40–11:00

Coffee break

Chair: Bunsho Ohtani
E9

11:00–11:30
Kiyotaka Asakura (Hokkaido University, Japan)“The growth mechanism of metal clusters on TiO2 surface”

E10

11:30–12:00
Angel Cuesta (CSIC, Spain)“Use of Chemically Modified Surfaces to Study Atomic Ensemble Effects inElectrocatalysis”

E11

12:00–12:30
Masahiro Watanabe (University of Yamanashi, Japan)“CO-Tolerant Anode Catalysis at Pt and Pt based Alloys”
12:30–13:45

Lunch

Chair: Tamotsu Takahashi
E12

13:45–14:15
Ken-ichi Tanaka (Saitama Institute of Technology, Japan)“Preferential Oxidation (PROX) Reaction of CO Catalyzed by H2O Molecule”

E13

14:15–14:45
Helmut Baltruschat (University of Bonn, Germany)“Size effects in methanol electrocatalysis: From nanostructured , bimetallic single
crystalline model catalysts to nanoparticles”

E14

14:45–15:15
Andrew A. Gewirth (University of Illinois, USA)
“Electrocatalytic reduction of oxygen, peroxide, and nitrate on electrode surfaces”
15:15–15:35

Coffee break

Chair: Angel Cuesta
E15

15:35–16:05
Juan M. Feliu (Universidad de Alicante, Spain)“The surface acid-base equilibrium of dicarboxilic acids”

E16

16:05–16:35
Katsuaki Shimazu (Hokkaido University, Japan)“Reduction of Nitrate Ions on Sn/Noble Metal Binary Electrodes”

E17

16:35–17:05
Masatoshi Osawa (Hokkaido University, Japan)“Hydrogen evolution reaction on a Pt electrode: A surface-enhanced infrared
study”

Poster session (June 22, 16:30-18:30 at Bld. #6)
P-1
Shengjun Huang, Tadashi Oshio, and Atsushi Fukuoka (Catalysis Research Center,
Hokkaido University)"“Preferential Oxidation of CO by Pt Nanoparticles in Mesoporous Silica”"
P-2
Tatsuya Takeguchi, Norikzu Yamamoto, and Wataru Ueda (Catalysis Research Center,
Hokkaido University)“Internal reforming SOFC with the Ni cermet anode prepared from nanoparticle YSZ”
P-3
Masahiro Sadakane, Toshitaka Horiuchi, Nobuyasu Kato, Chigusa Takahashi, Tahahito
Asanuma, and Wataru Ueda (Catalysis Research Center, Hokkaido University)“Facile fabrication of three-dimensionally ordered macroporous mixed metal oxide”
P-4
Ryu Abe and Bunsho Ohtani (Catalysis Research Center, Hokkaido University)"Polyhydroxylation of benzenes over tungsten oxide photoelectrodes under visible-lightirradiation"
P-5
Taro Uchida, Akira Yamakata, and Masatoshi Osawa (Catalysis Research Center, Hokkaido
University)“Acceleration of hydrogen evolution reaction on Ag electrodes by the adsorption of

4,4’-bipyridine: A combined electrochemical and infrared study
P-6
Leilei Lu, Yujin Tong, Yi Zhang, Shen Ye, and Masatoshi Osawa (Catalysis Research Center,
Hokkaido University)“Electrochemical behavior of Dimethyl Ether on Pt(111) electrode”
P-7
Takeshi Miyamoto, Hideyuki Sugawara, Toshio Naito, and Kiyotaka Asakura (Graduate
School of Engineering, Graduate School of Science and Catalysis Research Center,
Hokkaido University)“Photo-tunable conduction changing mechanisms of silver-containing molecular conductors”
P-8
Yujin Tong, Takuma Nishida, Eric Tyrode, Shen Ye, Masatoshi Osawa, Naoya Yoshida(Catalysis Research Center, Hokkaido University)“Sum-frequency generation (SFG) study of the molecular structures on a fused quartz surface
modified by mixed self-assembled monolayer (SAM)”
P-9
Yi Zhang, Shen Ye, Masaaki Abe, Masatoshi Osawa, Kohei Uosaki, and Yoichi Sasaki,(Catalysis Research Center, Hokkaido University)“In situ infrared study of self-assembled monolayers of triruthenium clusters on gold
electrodes: reactivity and pattern formation”
P-10
Hua-Xin Zhang, Masaaki Abe, Kiyoshi Tsuge, Masatoshi Osawa, and Yoichi Sasaki (Catalysis
Research Center and Graduate School of Science, Hokkaido University, and Graduate
School of Engineering, Kyushu University)“Preparation, structures, and properties of some new oxo-bridged dinuclear ruthenium
complexes”
P-11
Takanori Suzuki, Tomohiro Iwai, Eisuke Ohta, Hidetoshi Kawai, and Kenshu Fujiwara(Graduate School of Science, Hokkaido University)“Electrochiroptical Systems Based on Hexaphenylethane Derivatives: Strong Chiroptical
Signals through the Transmission of Point Chirality to Axial Chirality”
P-12
Baku Takimoto, Hideki Nabika, and Kei Murakoshi (Graduate School of Science, Hokkaido
University)“Characterization of Molecular Motion at Metal Nanogap in Lipid Bilayer via Single Molecule
Tracking”
P-13
Tatsuya Konishi, Manabu Kiguchi, and Kei Murakoshi (Graduate School of Science, Hokkaido
University)“Fabrication of atomic size ferromagnetic metal contact in solution”
P-14
Eisuke Ohta, Hidetoshi Kawai, Kenshu Fujiwara, and Takanori Suzuki (Graduate School of
Science, Hokkaido University)“Molecular Switching Behavior over Three States: Electrochiroptical and Fluorescence
ON/OFF Response of Chiral Dihydrodibenzo[c,g]phenanthrene Derivatives”

P-15
Keirei Uruma, Hiroyuki Noda, Kiyoshi Tsuge, Yoichi Sasaki, and Taira Imamura (Graduate
School of Science, Hokkaido University)“Arrangement of Box-shaped Pentaporphyrins in the Single Crystal State and on Goldsurfaces”
P-16
Y. Hashimoto, Y. Matsuo, and K. Ijiro (Research Institute for Electronic Science, Hokkaido
University)“Nano Electroless Plating of DNA toward Fabrication of Nano Wires”
P-17
A.Tanaka, Y. Matsuo, and K. Ijiro (Graduate of School of Science and Research Institute forElectronic Science, Hokkaido University)“Enzymatic Synthesis of DNA Block Copolymers for Site-Selective Metal Deposition”
P-18
Daisuke Kina, Akira Nakayama, Takeshi Noro, and Tetsuya Taketsugu (Graduate School of
Science, Hokkaido University)“Ab initio molecular dynamics simulation on the excited state proton transfer in 7-azaindole insolution”
P-19
Y. Nakamura, R. Washiya, G. Maruta, and S. Takeda (Graduate School of Science, Hokkaido
University)“Surface spins and magnetic ordering of antiferromagnetic nano particles as studied bysolid-state NMR”
P-20
K. Konno, M. Yamada, S. Ishizaka, and N. Kitamura (Graduate School of Science, Hokkaido
University)“Laser-Induced Single Microdroplet Formation and Its Application to Liquid/Liquid Extractionin Microflow Device”
P-21
Masaya Tsukamoto, Satoru Takakusagi, Yoshiro Chuman, Kazuyasu Sakaguchi, and Kohei
Uosaki (Graduate School of Science, Hokkaido University)“Study of the Interaction between Amyloid Fibrils and Self-assembled Monolayers with
Various Functional Groups”
P-22
Hiroshi Minowa, Hidenori Noguchi, Naoyuki Takedomi, Kousuke Kamada, Taiki Tominaga,
Jian Ping Gong, Yoshihito Osada, and Kohei Uosaki (Graduate School of Science, Hokkaido
University and CREST JST)“Characterization of interfacial water structure at low friction gel/solid interfaces by sum
frequency vibrational spectroscopy”
P-23
Motoko Harada, Nikolas Tzanetakis, Masayuki Okamura, Satoru Takakusagi, Hidenori
Noguchi, and Kohei Uosaki (Graduate School of Science, Hokkaido University)“Electrocatalytic Properties of Multilayer Assemblies of Pd Modified Au Nanoclusters”
P-24
H. Fukumitsu, T. Masuda, and K. Uosaki (Graduate School of Science, Hokkaido University)“Construction and Electronic Property of Pt/Organic Monolayer/Si(111) Junctions”

Map of Hokkaido University

Poster Site
Symposium Site

CRC

Campus Gate

Sapporo Station

Toyoko Inn
Subway N12

Subway N18

0

100

2 00

300 m