Program Overview

Special Keynote Lecture<SKL> Muon Spin Resonance Spectroscopy of Muoniated Radicals of Various Phosphoruscontaining Rings
Robert West, Paul W. Percival, Kerim Samedov, Charles MacDonald, and Christopher
RusselPlenary Lectures<PL01> The Magic of Five-fold Symmetry
Manfred Scheer, Barbara Krämer, Eugenia Peresypkina, and Sebastian Heinl<PL02> Magnesium(I) Dimers 10 Years on: Universal Reductants for the Synthetic Chemist?
Cameron Jones<PL03> Unsaturated Chains, Rings and Clusters of SiliconDavid Scheschkewitz<PL04> Pnictogen Centered Cyclic Biradicals: Switching Chemical Reactions and Activating
Small Molecules
Axel Schulz<PL05> Silicon Clusters: Synthesis, Structures, and Properties
Soichiro Kyushin

Invited Lectures<IL01> Reactions of a Cyclic (Alkyl)(amino)silylene and Its Derivatives
Takeaki Iwamoto

<IL02> Using Anionic N-Heterocyclic Olefins to Access New Cyclic Bonding Motifs in theMain Group
Eric Rivard, Paul Lummis, Matthew Roy, Emanuel Hupf, Felix Kaiser, and Fritz Kühn
<IL03> Advanced Synthetic Approaches to Acyclic and Cyclic Polyphosphorus Compounds
Robin Schoemaker, Clemens Taube, Kai Schwedtmann, Felix Hennersdorf, David Harting,and Jan J. Weigand<IL04> Inorganic Rings and Clusters Comprising Heavy Element Atoms
Stefanie Dehnen<IL05> Synthesis and Characterization of a New Form of Silicon Cage Compounds
Atsushi Nakajima<IL06> 1,2-Oxaphosphetane Complexes: Synthesis, Reactions and Perspectives
Andreas W. Kyri, A. Espinosa Ferao, and Rainer Streubel<IL07> Synthesis of A Cyclic 1,3-Digerma-2-silaallene: A Cyclic Silylone
Takahiro Sasamori<IL08> Reactions of a Silylyne Complex with Alkynes and Azides: Formation of Four- andThree-Membered-Ring Complexes
Hisako Hashimoto, Kohei Watanabe, Takashi Yoshimoto, Naoki Hayakawa, Tsukasa
Matsuo, and Hiromi Tobita<IL09> Divalent Bismuthenium and Stibenium Ions: Carbene Analogs with a Positive Charge
Jens Beckmann<IL10> Metalloradicals and Metal-medidated Main Group Radicals
Xinping Wang, Gengwen Tan, Wenqing Wang, Yuanting Su, and Tao Li<IL11> Molecular Metal-Chalcogenides for Bio-inspired Nitrogen Activation
Yasuhiro Ohki
<IL12> Insertion and Addition Chemistry of Silylated Germylenes
Małgorzata Walewska, Judith Baumgartner, and Christoph Marschner

<IL13> Multiple-bonded Aluminium Complexes: Reactive Species for Novel Ring Formation
Shigeyoshi Inoue<IL14> The Reactivity of iso-Chalcogenazole N-Oxides and their Supramolecular Aggregates
Ignacio Vargas-Baca and Peter C. Ho<IL15> Double Aromaticity in Polyselanyl-substituted Benzene Dications Arising from σ- andπ-Rings
Masaichi Saito

Oral Presentation Program<A01>

Synthesis and Reactivity of an Amido-substituted Silicon Ring Compound
Felicitas Lips

<A02>

Heavy Cyclobutadienes, E4(EMind)4 (E = Si and Ge)
Tsukasa Matsuo, Yasuyuki Numata, Naoki Hayakawa, and Daisuke Hashizume<A03>

Aryltin Hydrides: Synthons for Oligotin Rings, Cages and Elementoid Clusters
Beate G. Steller and Roland C. Fischer<A04>

Cages with Metallic Main-group Elements and Applications
Michael Veith, Awadelkareem Ali, Andreas Walgenbach, and Carsten Bubel<A05>

Tetrahedanes and Cyclobutadienes Linked a π-System: Diradical Character of paraPhenylene-linked Cyclobutadiene
Masaaki Nakamoto, Yuzuru Kobayashi, Kenta Okaniwa, and Akira Sekiguchi<A06>

Silylene in C–F, C–H, and B–H Bond Activations and Subsequent Catalytic
Applications
V. S. V. S. N. Swamy and Sakya S. Sen<A07>

Heteroldianions as Precursors for Unusual Silicon and Germanium Compounds
Zhaowen Dong, Crispin Reinhold, Patrik Tholen, Lena Albers, and Thomas Müller

<A08>

Three-coordinated Cyclic Chlorogermylenes and -stannylenes Supported by N,N’Chelating Ligands: Synthesis and Property
Norio Nakata, Shintaro Takahashi, Narimi Hosoda, Kazuki Nakaya, and Akihiko Ishii<A09>

Based-Stabilized Silicon(I) Dimer for Catalytic C–C Bond Formation
Cheuk-Wai So<A10>

Mechanochemical Syntheses of Cyclodiphosphazane-based Frameworks
Ying Sim and Felipe García<A11>

Disilene vs Silylsilylene: Substituted Analogues of the Si2H4 Rearrangement
Martin W. Stanford, Gary S. Nichol, and Michael J. Cowley<A12>

Synthesis and Structure of a Stable Dithiagermirane
Fumiaki Suzuki and Mao Minoura<A13>

Limitations of Steric Bulk: Towards Phospha-Germynes and Phospha-Stannynes
Alexander Hinz and Jose M. Goicoechea<A14>

Cyclic and Linear Germoxane Formation Catalyzed by an Iron Complex
Hiroshi Nakazawa, Masahiro Kamitani, and Masumi Itazaki<A15>

B–H Bond Activation by an Amidinate-Stabilized Amidosilylene: Non-Innocent
Amidinate Ligand
Sabrina Khoo and Cheuk-Wai So<A16>

Synthesis of Silacyclic Compounds Utilizing Cumulated Double-Bond Compounds
Activated by In-situ Generated Silyl Cations
Takayuki Kawashima and Hidekazu Arii

<A17>

Radicals and Tetrylenes Based on a [3]Ferrocenophane Scaffold with Functional PEP
Bridge (E = group 13, 14, 15 element)
Denis Kargin, Stefan Isenberg, Zsolt Kelemen, and Rudolf Pietschnig

<A18>

Ir(I)-Mediated Bond Activation of E–F Bond (E = Si, Ge, Sn): A Key Intermediate
Bearing a Z-type Interaction
Hajime Kameo, Hiroshi Nakazawa, and Hiroyuki Matsuzaka<A19>

From Aryl-substituted Group 14 Rings and Hydrides Towards Energy Storage
Frank Uhlig<A21>

Electrochemical and Spectroelectrochemical Investigations of Sulfur-Nitrogen Chains
and Rings
René T. Boeré and Nathan D. D. Hill

<A22>

Deltaarenes; Novel Sulfur-containing Macrocyclic Compounds
Akio Kamimura, Kazuki Ikeda, and Takuji Kawamoto<A23>

Mono- and Ditellurophenes Containing π-Conjugated Backbones
Emanuel Hupf, Robert McDonald, Michael J. Ferguson, and Eric Rivard<A24>

Physical Modification of Carbon Nanotubes with Dendrimer Having Mercaptoundecahydrododecaborates (Na2B12H11S) at Terminals
Masahiro Yamagami, Tomoyuki Tajima, Hideaki Miyake, Kango Ishimoto, and Yutaka
Takaguchi<A25>

Cross-conjugated and Heterofulvenoid Phospha- and Arsaalkene Motifs
Muhammad Anwar Shameem, Daniel Morales Salazar, Joshua Green, and Andreas Orthaber<A26>

Design and Synthesis of Tellurophenes to Advance Optoelectronic Applications
Christina A. Braun, Michael J. Ferguson, Robert McDonald, Gang He, and Eric Rivard<B01>

Reversible B2C2 Four-Membered Ring Formation by Dimerization of Boryl- andAmino-substituted Acetylenes
Katsunori Suzuki, Ryo Kitamura, and Makoto Yamashita<B02>

Cleavage of Very Strong Bonds by Low-valent Group 13 Compounds
Georgii Nikonov

<B03>

Chemistry of Low Valance Phosphorus, Silicon and Aluminum
Herbert W. Roesky<B04>

Gold(I) Facilitated Formation of a Heterocyclic 5-Membered Ring from Tri(tertbutyl)azadiboriridine and Isonitrile
Rong Shang, Souta Saito, Yohsuke Yamamoto, and J. Oscar. C Jiminez-Halla<B05>

Phosphaborenes – Accessible Reagents for P–B Isosteres of Cyclobutene and Benzene
Amy N. Price, Gary S. Nichol, and Michael J. Cowley<B06>

Synthesis of a Phosphinoboronate Ester Bearing Fused Ring Structure
Naokazu Kano and Nathan J. O’Brien<B07>

RʹEʹ[C4R4] (Eʹ = Group 13 or 15 element) Cages and Clusters
Vladimir Ya. Lee, Haruka Sugasawa, Kei Ota, Yuki Ito, Akira Sekiguchi, Olga A.
Gapurenko, Ruslan M. Minyaev, and Vladimir I. Minkin<B08>

Antiaromatic Dithieno-1,2-dihydro-1,2-diborin Splits Diatomic Hydrogen
Takafumi Araki, Masato Hirai, Atsushi Wakamiya, Warren E. Piers, and Shigehiro
Yamaguchi<B09>

Construction of Extended π-Conjugated Systems by a Boron Cation
Naoki Tanaka, Shoji Yoshiaki, and Takanori Fukushima<B10>

Silicon/Boron Exchange Routes to Conjugated Cyclolinear Organoboron Polymers
Holger Helten, Ozan Ayhan, Artur Lik, Thomas Lorenz, Merian Crumbach, Lars Fritze, andNicolas A. Riensch<B11>

Synthesis, Structures, and Reactivity of Dicarbondiphosphide Stabilized with NHeterocyclic Carbenes
Zhongshu Li<B12>Synthesis and Properties of Phosphinines Bearing Amine Substituents
Noriyoshi Nagahora, Shoko Goto, Tomoko Kushida, Takahiro Inatomi, Kouki Matsubara,
Kosei Shioji, and Kentaro Okuma

<B13>

Tricoordinate Phosphorus Species: From Lewis Superbases to Lewis Superacids
Fabian Dielmann, Marius Wünsche, Paul Mehlmann, and Tim Witteler<B14>

Molecular Beryllium Fluorides
Dominik Naglav, Kevin Dzialkowski, Briac Tobey, and Stephan Schulz<B15>

Beryllium Complexes with O-Donor Ligands
Magnus R. Buchner and Matthias Müller

<B16>

Isolation of a Low-valent Silver(I) Cation using an Extremely Bulky N-Heterocyclic
CarbeneMatthew M. D. Roy, Michael J. Ferguson, Robert McDonald, and Eric Rivard<B17>

Synthesis, Structure, and Reactions of Ruthenium Complexes Bearing PS3-type
Tripodal Tetradentate Ligand
Nobuhiro Takeda, Shungo Tsuchiya, Ryo Mimaru, Natsuko Uekusa, and Masafumi Unno

<B18>

Reactivity and Regioselectivity of Novel Superbasic Mixtures
Kathrin Louven, Lukas Brieger, Rebecca Scheel, and Carsten Strohmann<B19>

Enhancing the Reactivity of Alkyllithium Reagents to Enable Hindered Deprotonation
Reactions
Lena Knauer and Carsten Strohmann<B20>

Isolable Radicals of Main-Group Elements
Gengwen Tan and Xinping Wang

<B21>

Novel Synthetic Approaches to Robust Main group Phosphazane Macrocycles
Felipe Garcia<B22>

Aluminium Hydrides Stabilised by Mixed NP Donor Ligands
Rosalyn L. Falconer, Stephanie J. Urwin, Martin W. Stanford, and Michael J. Cowley<B23>

Use of SNOOPy Ligand in Coordination Chemistry of Main Group Elements
Kamila Bubnova, Iva Vranova, and Ales Ruzicka

<B24>

Illuminating the Origins of Phosphorescence in Bismoles and Bismole Polymers
Sarah M. Parke, Emanuel Hupf, Gunwant Matharu, Michael P. Boone, Robert McDonald,
Michael J. Ferguson, Gang He, and Eric Rivard<B25>

Donor-Acceptor Stabilized Phosphanylboranes and Alanes: Stability and Reactivity
Alexey Y. Timoshkin<B26>

Reactivity of Low-valent Pnictogen Compounds with Unsaturated Bonds – Formationof New Heterocycles
Libor Dostál, Monika Kořenková, and Vít Kremláček

Poster Presentation Program<PA01> Mechanistic Studies on the Hydrodefluorination Reaction Performed by Chalcogenyl
Stabilized Silyl Cations
Saskia Rathjen and Thomas Müller
<PA02> High Oxidation State Main Group Cations: Towards A New Class of Lewis Superacids
Paul A. Gray, Riccardo Suter, Neil Burford, Brian O. Patrick, Robert McDonald, andMichael J. Ferguson<PA03> Chalcogenyl Stabilized Silyl Cations as Catalysts in Hydrosilylation Reactions of
NitrilesSandra Künzler and Thomas Müller
<PA04> Synthesis and Structure of Hexa-coordinated Germanate Complex Having
Phenanthrenedialkoxido Ligands
Tomoka Yoneda and Masato Nanjo<PA05> Hollowed Triangulenes
Olga A. Gapurenko, Ruslan M. Minyaev, and Vladimir I. Minkin<PA06> Synthesis, Structures, and Reactivity of Germa- and Stannabenzenyl Anions
Shiori Fujimori, Yoshiyuki Mizuhata, and Norihiro Tokitoh

<PA07> Synthesis, Characterization, and Reactivity of Diaryltetrylenes, (Rind)2E: (E = Si, Ge,
Sn, and Pb)
Shigeaki Konaka, Yasuyuki Numata, Ryoma Ohno, Naoki Hayakawa, Tatsuto Morimoto,Tomoharu Tanikawa, Daisuke Hashizume, and Tsukasa Matsuo<PA08> Reactions of Siloxanediols and a Lewis Acid Stabilized Silylene towards Water
Philipp Roesch and Thomas Braun<PA09> NHC-stabilized Silyliumylidene Ions and Their Coordination Chemistry
Philipp Frisch and Shigeyoshi Inoue<PA10> Cobaltosilylene with Rhombic Si2Co2 Ring: Synthesis and Catalysis
Sabrina Khoo and Cheuk-Wai So<PA11> Reactivity of Chlorosilylene Stabilized by an Iminophosphonamide Ligand
Shintaro Takahashi, Norio Nakata, and Akihiko Ishii<PA12> Reactivity Study of N-Heterocyclic Carbene Stabilized Silylene Hydride: A Systematic
Study of NHC-coordinate Hydrosilylene Transition Metal Complexes
Gizem Dübek, Carsten Eisenhut, and Shigeyoshi Inoue<PA13> Activation of Molecular H2 by an N-Heterocyclic Silylene (NHSi)-Stabilized Boronium
CationSabrina Khoo and Cheuk-Wai So<PA14> S–H bond activation in Hydrogen Sulfide by NHC-stabilized Silyliumylidene Ions
Amelie Porzelt and Shigeyoshi Inoue<PA15> A Dimeric NHC-Silicon Monotelluride: Synthesis, Isomerization and Reactivity
Bi-Xiang Leong and Cheuk-Wai So<PA16> Isolation and Reactivity Studies of Acyclic Three-Coordinate Silanones
Dominik Reiter, Amelie Porzelt, and Shigeyoshi Inoue<PA17> α-Phosphinoamido- and α-Borylamido-Germylenes: Tuning HOMO-LUMO Gap with
Substituent Change for Catalytic SignificanceShiv Pal, Rajarshi Dasgupta, and Shabana Khan
<PA18> Trapping a Highly Electrophilic Germacarbonate
Ying Kai Loh and Simon Aldridge<PA19> Reactivity of a Zero-Valent Tin Complex Stabilized by a Butadiene Ligand
Shinya Kobayashi, Shunsuke Furukawa, and Masaichi Saito<PA20> Synthesis and Reactivity of Dodecaallylhexasilacyclohexane
Yamato Omatsu, Yoshiyuki Mizuhata, and Norihiro Tokitoh<PA21> Synthesis, Structures, and Reactivity of 1,2-Dibromoditetrenes with Bulky MPind
Groups, (MPind)BrE=EBr(MPind) (E = Si and Ge)
Ryoma Ohno, Kousuke Magami, Shigeaki Konaka, Yasuyuki Numata, Naoki Hayakawa,
Daisuke Hashizume, and Tsukasa Matsuo<PA22> The [2+2] Cycloaddition of Alkynes to Si=Si Moieties Revisited
Andreas Kell, Naim Obeid, and David Scheschkewitz<PA23> Synthesis and Reactivity of Tetragermacyclobutadiene
Yasuyuki Numata, Naoki Hayakawa, Daisuke Hashizume, and Tsukasa Matsuo<PA24> Inhibited Cyclization of Peripherally Functionalized Digermenes
Lukas Klemmer, Yvonne Kaiser, and David Scheschkewitz<PA25> Synthesis and Properties of Stable 1,4-Digermabenzenes
Tomohiro Sugahara, Jing-Dong Guo, Takahiro Sasamori, and Norihiro Tokitoh<PA26> Synthesis of Germabenzenes having Various Aryl Groups by Reaction of in-situ
Generated Chlorogermabenzene
Canon Kaiya, Katsunori Suzuki, and Makoto Yamashita<PA27> Platinum-Catalyzed Reactions of 2,3-Bis(diisopropylsilyl)thiophene with Alkynes
Takashi Mihara, Hisayoshi Kobayashi, and Akinobu Naka

<PA28> Synthesis and Characterization of New Polyhedral Structures Based on Double-decker
Silsesquioxane
Kunthom Rungthip, Nobuhiro Takeda, and Masafumi Unno
<PA29> Grafting of Germanium-based Groups to a Si6 Siliconoids: Side Chain Attachment vs.
Core Expansion
Nadine Poitiers, Kinga Leszczyńska, Volker Huch, Michael Zimmer, and David
Scheschkewitz<PA30> Transition Metal Complexes of Siliconoids
Luisa Giarrana, Nadine Poitiers, Volker Huch, Michael Zimmer, and David Scheschkewitz<PA31> Atom by Atom Selective Expansion of Unsaturated, Anionic Silicon Cluster Si6Tip5– toGive Highly Unsaturated Clusters: Si7Tip5Cp*, Si7Tip5–, Si8Tip5Cp*
Kinga Leszczyńska, Raphael J. F. Berger, Volker Huch, Carsten Präsang, and David
Scheschkewitz<PA32> Six- and Eight-Membered Rings of Germanium and Copper as well as Phosphorous
Atoms Comprising Homoatomic Ge9 Clusters
Lorenz J. Schiegerl, Felix S. Geitner, Kerstin Mayer, Christoph Wallach, and Thomas F.
Fässler<PA33> Synthesis and Characterization of Methylated Sulfidometalate Compounds
Bertram G. H. Peters and Stefanie Dehnen<PA34> A Molecular Construction Kit for Metalloid Tin Clusters: From Organotin Hydrides
to Polyhedral Structures
Beate G. Steller and Roland C. Fischer<PA35> Tin Sulfide Clusters Thrive Towards Their Watersolubility
Annikka Kreher, Jan-Philipp Berndt, Radim Hrdina, Peter R. Schreiner, and Stefanie
Dehnen<PA36> Intermetalloid Clusters of Group 15 Elements
Armin Rainer Eulenstein, Lukas Guggolz, Werner Massa, Florian Weigend, and Stefanie
Dehnen<PA37> Al and Al-Siloxaneclusters as Model Systems for Condensation and Hydrolysis
Reactions
Philipp Wittwer and Thomas Braun<PA38> Iron-Bisphosphine-Catalyzed Cross-Coupling Reaction toward Synthesis of Natural
Triene Urushiol
Ryosuke Agata, Hiroshi Matsuda, Katsuhiro Isozaki, and Masaharu Nakamura<PA39> Move Over Transition Metals: Calcium Compound for Catalytic Hydroboration and
Cyanosilylation Reactions
Sandeep Yadav and Sakya S. Sen<PA40> Iron-Catalysed Asymmetric Carbometalation of Azabicyclic Alkenes
Jan Geldsetzer, Katsuhiro Isozaki, Laksmikanta Adak, Shota Saito, Nicholas J. Gower, Paul
Cogswell, Tatsuya Kawabata, Masayoshi Jin, Takuma Itoh, Shingo Ito, and Masaharu
Nakamura<PB01> Synthesis and Structure of 9,10-Dihydro-9-aza-10-boraanthracene
Yutaro Ishikawa, Shin-ya Nema, Kohei Hayashi, Katsunori Suzuki, and Makoto Yamashita<PB02> Photophysical Properties of Benzo[d]dithieno[d,f]borepins
Yohei Adachi and Joji Ohshita<PB03> Varied Reactivity of closo-Thiaboranes
Jan Vrána, Zdenka Růžicková, Josef Holub, and Drahomír Hnyk
<PB04> Catalytic Hydroboration of Carbon Dioxide Using an Aluminium Carbenoid Complex
Cher-Chiek Chia and Cheuk-Wai So<PB05> Synthesis, Structures and Properties of Borane-Based Diradical and Triradical
Lei Wang, Gengwen Tan, and Xinping Wang
<PB06> Recombination of an aluminum-iron complex with EBr3 (E = Al, Ga)
Tatsuya Yanagisawa, Yoshiyuki Mizuhata, and Norihiro Tokitoh

<PB07> Synthesis and Photoreaction of a Half-Parent Diazomethane Bearing the Bulky EMind
Group, (EMind)CHN2
Kohei Yamada, Yuya Sano, Naoki Hayakawa, Takayoshi Yoshimura, Miho Hatanaka, andTsukasa Matsuo<PB08> Synthesis and Coordination Properties of Multi-dentate Phosphanyl Phosphinines:
Xiaodan Chen
<PB09> Synthesis and Reactivity of Phosphorus Compounds with a Tridentate Ligand
Shuhei Maeda, Tomomi Kukita, and Yohsuke Yamamoto<PB10> Generation and Reactivity of 1,2-Oxaphosphetanes Bearing A Phosphaheteratriptycene Skeleton Containing Sb or Sn
Yosuke Uchiyama, Suguru Kuniya, Ryo Watanabe, and Takemaru Ohtsuki<PB11> Syntheses of Cyclodiphosphazane-based Macromolecules
Ying Sim and Felipe García<PB12> Synthesis and Reactions of Oxaphosphirane Iron(0) Complexes
Niklas Volk, Alexander Schmer, and Rainer Streubel<PB13> Hetero-Cyclopentane-1,3-diyls: Modification of Molecular Switches with Different
Sterically Demanding Groups
Henrik Müller, Jonas Bresien, Thomas Kröger-Badge, Dirk Michalik, Anne-Kristin Rölke,Axel Schulz, Alexander Villinger, Ronald Wustrack, and Edgar Zander<PB14> A New and Facile Synthetic Approach to Azadiphosphiridine Complexes
Alexander Schmer, Tatjana Terschüren, and Rainer Streubel<PB15> Mechanochemical Syntheses of Cyclophosphazane Compounds
Felipe Garcia<PB16> [E(µ-NBbp)]2

Group 15 Biradicals Synthesized from Acyclic Precursors

Lilian Sophie Szych, Jonas Bresien, Axel Schulz, Alexander Villinger, and Ronald Wustrack<PB17> Hetero-Cyclopentane-1,3-diyls as Molecular Switches: A Theoretical Study
Jonas Bresien, Stefan Lochbrunner, Henrik Müller, Axel Schulz, and Edgar Zander<PB18> Oxidation of the Tetrahedral Molybdenum Complexes [{CpRMo(CO)2}2(µ,η2:η2-EE’)](E, E’ = P, As, Sb, Bi)
Luis Dütsch and Manfred Scheer<PB19> Reactivity Studies of a DBU-functionalized Phosphaalkene towards Strong Acids andPalladium: Stabilized Hydrogen-Bonded Adducts and Supramolecular Hydrogen
Bonding Interactions
D. Morales Salazar, A. Kumar Gupta, and A. Orthaber<PB20> Synthesis and Characterization of Cyclopentadithiophen Heterofulvenes: Design Tool
for Light-Activated Processes
Muhammad Anwar Shameem, Amal El- Nahhas, Pavel Chabera, Jens Uhlig, and Andreas
Orthaber<PB21> Cleavage of Heavier Double Bonds Mediated by NHC
Kazuya Sadamori, Naoki Hayakawa, Miho Hatanaka, and Tsukasa Matsuo<PB22> Synthesis of Novel Ring Systems Including Antimony Atoms by Reactions of a
Dialkyldistibene
Ryohei Nishino and Mao Minoura<PB23> Synthesis and Characterization of Stibinyl Dications [12–Sb–6]2+
Masato Sakabe, Kazuki Ichimura, Wataru Fujita, and Soichi Sato
<PB24> Synthesis of Iridium Complexes Bearing New SiS3-type Tripodal Tetradentate Ligand
and Their Application to Catalysts for Hydrosilylation
Nozomi Ito, Fumiaki Kobayashi, Nanami Shoda, Nobuhiro Takeda, and Masafumi Unno
<PB25> A Cyclic Tetranuclear Gold Complex [(PPh3)4Au4(SPh)2](NTf2)2: A Novel Catalyst for
Anti-Markovnikov Hydrothiolation of Unactivated Alkenes
Shintaro Kodama, Taichi Tamai, Keiko Fujiwara, Akihiro Nomoto, Michio Ueshima, andAkiya Ogawa

<PB26> Synthesis and Properties of Rhodium Complexes with PS3-type Tripodal Tetradentate
LigandHiroki Hiyama, Yuto Todoroki, Nobuhiro Takeda, and Masafumi Unno
<PB27> Syntheses, Crystal Structures, and Photophysical Properties of Platinum(II)Complexes Containing a Disulfanenitrile
Hiroya Honda and Takayoshi Fujii<PB28> Dynamic Behavior of Hydrogen Bonds on a Sulfur-Containing Open-Cage Fullerene
C60 Derivative
Shota Hasegawa, Yoshifumi Hashikawa, and Yasujiro Murata<PB29> Synthesis of Octakis(arylselanyl)naphthalene Dications and Evaluation of their
Extended Double Aromatic Character
Soshi Mibu, Shunsuke Furukawa, Kazuya Ishimura, Mao Minoura, and Masaichi Saito<PB30> Reaction of Acetophenone Hydrazones with TeCl4: Novel Formation of 2,5Diaryltellurophenes
Kentaro Okuma, Shuhei Yahata, Noriyoshi Nagahora, and Kosei Shioji<PB31> Synthesis and Photophysical Properties of 5-Aminothiazole Derivatives Having
Pyridyl Groups
Khurnia Krisna Puji Pamungkas, and Toshiaki Murai<PB32> Synthesis and ICT-Based Sensing Properties of 1,3,5-Triazine-cored Star-shaped (Dπ)3-A Molecules with Various Amino-type Donor Receptors
Hiroki Muraoka and Satoshi Ogawa<PB33> Development of Functional Dye Compounds Bearing 2,1,3-Benzochalcogenadiazole
MoietyHideaki Miyake, Ito Tomoka, Shibata Masaru, Noritake Murakami, Kango Ishimoto,
Takumi Izawa, Tomoyuki Tajima, and Yutaka Takaguchi<PB34> Synthesis and Properties of Unsaturated Thiacrown Ethers Possessing p-Substituted
Benzene Rings
Toshio Shimizu, Eri Kamimaki, and Kazunori Hirabayashi

<PB35> Synthesis and Properties of Chromium Radical Cations
Wenqing Wang and Xinping Wang
<PB36> Strain-induced Double Carbon-Carbon Bond Activations of Cycloparaphenylenes(CPPs) by a Platinum Complex
Eiichi Kayahara, Toshiki Hayashi, and Shigeru Yamago<PB37> Development of Transparent Organic Hole-Transporting Materials Containing
Partially Oxygen-bridged Triethylamine Skeletons
Minh Anh Truong and Atsushi Wakamiya<PB38> trans-bis(R-ethynyl)(porphyrinato)E(IV) and the Kozeschkow-Reaction
Stefan Stadlbauer, Roland Fischer, Thomas Rath, Gregor Trimmel, and Frank Uhlig<PB39> Molecular Orientation Control in Naphthalene Diimides
Tomoya Nakamura, Nobutaka Shioya, Takafumi Shimoaka, Takeshi Hasegawa, Yasujiro
Murata, and Atsushi Wakamiya<PB40> Efficient Lead Free Perovskite Solar Cells with Highly Purified Solvent-CoordinatedTin Halide Complexes as Precursors
Jiewei Liu, Masashi Ozaki, Yukie Katsuki, Taketo Handa, Ryosuke Nishikubo, Yoshihiko
Kanemitsu, Akinori Saeki, Yasujiro Murata, and Atsushi Wakamiya<PB41> Investigation of the reactivity of [Cp’’’Co(η4-P4)]
Martin Piesch and Manfred Scheer<PB42> Effect of Aurophilic interaction and ligand substitution on luminescence property ofgold(I) complexes
Neha Kathewad, Shiv Pal, Rajarshi Dasgupta and Shabana Khan