વᾲ
Journal of the Heat Transfer Society of Japan
ISSN 1344-8692

Vol. 45, No. 190
2006. 1٠ๆ⌕䈱਎⇇㩷 䋭䊚䉪䊨䈎䉌䊙䉪䊨䋬䈠䈚䈩䉲䉴䊁䊛䋭٠‫ޟ‬વᾲ‫ޠ‬ේⓂߩᦠ߈ᣇHow to Write a Manuscript of Dennetsuવᾲ ᄥ㇢㧔વᾲᄢቇ㧕
Taro DENNETSU (Dennetsu University)⪺⠪߇ੌ⸃ߔࠆߣ߈ߪ⸥౉ψ e-mail: taro@dennetsu.ac.jpߪߓ߼ߦ
એਅߩᵈᗧ੐㗄ߦ⇐ᗧߒߡේⓂࠍ૞ᚑߔࠆߎߣ㧚‫ޟ‬વᾲ‫↪ޠ‬ේⓂ૞ᚑ਄ߩᵈᗧ ᮡḰᒻᑼ
ේⓂߪ Microsoft Word ╬ࠍ↪޿ߡ૞ᚑߒ㧘࿑߿౮⌀╬ߪේⓂߦᒛࠅㄟߺ৻ߟߩࡈࠔࠗ࡞ߣߒߡቢ
⚿ߐߖࠆ㧚ේⓂߩᮡḰᒻᑼࠍ⴫ 1 ߦ␜ߔ㧚

↪⚕ࠨࠗ࠭
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Ꮐ૛⊕ 20mm㧘ฝ૛⊕ 20mm
1 Ბ⚵㧘45mm ೨ᓟ޽ߌࠆ㧔10 ࡐࠗࡦ
࠻(100.3514mm)ߢ 8 ⴕಽ㧕
2 Ბ⚵㧘1 Ბ 80mm㧘Ბ㑆㓒૛⊕ 10mm
10 ࡐࠗࡦ࠻(100.3514mm)
ᧄᢥ(Windows) MS ᣿ᦺ૕(Macintosh) ⚦᣿ᦺ૕⷗಴ߒ(Windows) MS 䉯䉲䉾䉪૕
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Times New Roman ߹ߚߪ Symbol
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1 ࡍ࡯ࠫ޽ߚࠅ 45 ⴕߚߛߒ㧘⷗಴ߒߩ೨ߪ 1 ⴕࠍᝌ౉ ⷗಴ߒߥߤ
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ⷺߣߔࠆ㧚ⴕߩᆎ߼ߦ㧘᜝ᒐ߿ࡂࠗࡈࡦ╬߇ߎߥ޿ࠃ߁ߦ⑌ೣಣℂࠍⴕ߁ߎߣ㧚 ฏ⺒ὐฏ⺒ὐߪ 㧘߅ࠃ߮ 㧚ࠍ↪޿㧘 ‫ߪޕ ߿ޔ‬ㆱߌࠆߎߣ㧚
࿑ߦߟ޿ߡ
࿑ਛߩࡈࠜࡦ࠻ߪᧄᢥਛߩࡈࠜࡦ࠻ߣหߓ߽ߩ
ࠍ↪޿ࠆߎߣ㧚 ෳ⠨ᢥ₂ߦߟ޿ߡ
 ⇟ภߩઃߌᣇ
ෳ⠨ᢥ₂ߪᧄᢥਛߩ⹥ᒰߔࠆ୘ᚲߦ[1]㧘[2, 4]㧘
[6-10]ߩࠃ߁ߦ⇟ภࠍ౉ࠇߡ␜ߔ㧚 ෳ⠨ᢥ₂ߩᒁ߈ᣇ
⪺⠪ฬ㧘⹹ฬ㧘Ꮞ㧘ᐕ㧘㗁ߩ㗅ߣߔࠆ㧚Ფภ㗁ߩᡷ߹ࠆ㔀⹹(Therm. Sci. Eng.ߥߤ)ߪᏎ-ภᢙߩࠃ߁ߦߒߡภᢙ߽౉ࠇࠆ㧚⪺⠪ฬߪ㧘ฬሼ㧘ฬ೨ߩࠗ࠾ࠪࡖ࡞㧚ߩࠃ߁ߦ⸥ㅀߔࠆ㧚࠲ࠗ࠻࡞ߩ᦭ή
ߪ⥄↱㧚㔀⹹ฬߩ⋭⇛ᴺߪ⑼ቇᛛⴚᢥ₂ㅦႎ
(JICST)ߦḰ᜚ߔࠆ㧚ᣣᧄ⺆ߩ㔀⹹࡮ᦠ☋ߩ႐วߪ⪺⠪ฬ࡮ᦠฬߣ߽⋭⇛ߒߥ޿㧚ෳ⠨ᢥ₂
[1] વᾲᄥ㇢㧘વᾲ⧎ሶ㧘વᾲߩࡈࠜ࡯ࡑ࠶࠻ߦ
㑐ߔࠆขࠅ᳿߼㧘ᣣᧄᯏ᪾ቇળ⺰ᢥ㓸 B ✬㧘
80-100 (1999) 3000㧚
[2] Incropera, F. P. and Dewitt, D. P., Fundamentals
of Heat and Mass Transfer, John Wiley & Sons
(1976).
[3] Smith, A. et al., How to Write a Manuscript ofDennetsu, Therm. Sci. Eng., 7-5 (1999) 10.
[4] ጊ↰ᄥ㇢㧘߿ߐߒ޿વᾲ㧘ᾲ⻠␠ (1980).
ේⓂ૞ᚑ↪ߩ࠹ࡦࡊ࡟࡯࠻㧔MS-WORD㧕ߪવᾲቇળߩࡎ࡯ࡓࡍ࡯ࠫࠃࠅ࠳࠙ࡦࡠ࡯࠼ߢ߈߹ߔ㧚
ේⓂߪ㧘․ߦᜰቯߩߥ޿㒢ࠅ㧘಴ ㇱળ㐳ተߡߦ e-mail ߢឭ಴ߒߡਅߐ޿㧚ߥ߅㧘ࡋ࠶࠳࡯࡮ࡈ
࠶࠲࡯߿ᦨᓟߩᮮ᫔ߪ㧘✬㓸಴ ㇱળߢᢛ߃߹ߔ
ߩߢ㧘⸥౉ߔࠆᔅⷐߪ޽ࠅ߹ߖࠎ㧚

Vol. 452006

No. 190

Januaryવ  ᾲ⋡ ᰴ‫⺰ޛ‬ს‫ޜ‬ ᚢ⇛ߣᚢⴚ ································································································ൎ↰ ᱜᢥ㧔ᣧⒷ↰ᄢቇ㧕·················1‫ޛ‬ㅊᖬ㧦ዊ┻ ㅴ వ↢‫ޜ‬ ዊ┻ㅴవ↢ߩߏㅤ෰ࠍᖬ߻ ·································································੗਄ ೰⦟㧔᧲੩Ꮏᬺᄢቇ㧕·················3 ዊ┻ㅴవ↢ߣᣣᧄવᾲቇળ ·····································································ᴡ᧛ ᵗ㧔᧲੩ℂ⑼ᄢቇ㧕·················5‫․ޛ‬㓸㧦ๆ⌕ๆ⌕ߩ਎⇇ 㧙ࡒࠢࡠ߆ࠄࡑࠢࡠ㧘ߘߒߡࠪࠬ࠹ࡓ㧙‫ޜ‬ ๆ⌕ࡅ࡯࠻ࡐࡦࡊ↪ᯏ⢻ᕈๆ⌕᧚ߩ㐿⊒
 ·············································· ਅጟ ㉿⟤㧘ᄢፉ ৻ౖ㧘ᱞ⣁ 㓉ᒾ㧘၂ౝ ඳⴕ㧔ࢃਃ⪉ൻቇ㧕·················8 ᄙሹ૕ౝㇱߩๆ⌕⃻⽎·············································································ᄢችม ໪ᢥ㧔᧲੩ᄢቇ㧕···············14 㜞ኒᐲൻቇ⫾ᾲ᧚ߩ㐿⊒ ·········································································ഏ ㉍৻㧔᧲੩Ꮏᬺᄢቇ㧕···············21 ๆ⌕ࡅ࡯࠻ࡐࡦࡊߩๆ⌕ེౝᾲ㨯‛⾰⒖േ⃻⽎ ············ ᷰㄝ ⮮㓶㧘┄↰ శብ㧔ฬฎደᄢቇ㧕···············27 ⫳᳇ๆ⌕⃻⽎ࠍ↪޿ߚẜᾲ࡮㗼ᾲߩ⁛┙೙ᓮ ······················ ựᧄ ⧐ᓼ㧘᫪ ⧷ᄦ㧔਻Ꮊᄢቇ㧕···············33
 ๆ⌕ᑼ࠺ࠪࠞࡦ࠻㒰Ḩ࡮ⓨ⺞ࡊࡠ࠮ࠬ······················································ఽ₹ ᤘ㓶㧔㊄ᴛᄢቇ㧕···············39
 ๆ⌕಄ಓࠨࠗࠢ࡞߅ࠃ߮ߘߩዷ㐿··························································⑺Ỉ ᷕ㧔᧲੩ㄘᎿᄢቇ㧕···············45‫․ޛ‬೎ነⓂ‫ޜ‬ ᴣ㛛ߩ⑼ቇ㧔㧡㧕········································································· ↲⮮ ᅢ㇢㧔᧲੩ᄢቇฬ⹷ᢎ᝼㧕···············50 ࠬࠤ࡯࠻ߪߤ߁ߒߡṖࠆߩߢߔ߆㧫··························································ኻ㚍 ൎᐕ㧔ንጊᄢቇ㧕···············56‫࡯ࡖ࠴ࠗࡀޛ‬㧽‫ޜ‬ ቝቮ‛ℂቇߣᾲജቇ·····················································································㒋਄ 㓷ᤘ㧔੩ㇺᄢቇ㧕···············60‫࠻ࠢࠚࠫࡠࡊޛ‬㧽‫ޜ‬ ᄙᲑ⫳᳇ࠗࡦࠫࠚࠢ࠲ߩ㐿⊒ߣવᾲ············· ᄹ⦟ᨋ ⋥㧔ർᶏ㆏ᄢቇ㧕㧘᫪ ᴦ༹㧔᧲੩㔚ജ㧕···············65‫ޛ‬࿖㓙ᵴേ࡮ળ⼏ႎ๔‫ޜ‬ ૒⾐ᄢቇߩ㐷಴᡽ೣᢎ᝼ߣశᱞ㓶৻ഥᢎ᝼߇ ASME 2005 Best Paper Award ࠍฃ⾨
 ························································································································᳗੗ ੑ㇢㧔⑔੗ᄢቇ㧕···············70

T V 6TCPUHGT‫ޜ‬‫*ޛ‬GC< ࡁࠗ࠭ ········································································································ᑝ↰ ⌀ผ㧔ฬฎደᄢቇ㧕···············71‫ⴕޛ‬੐ࠞ࡟ࡦ࠳࡯‫············································································································································ ޜ‬73
‫߅ޛ‬⍮ࠄߖ‫ޜ‬ ╙ 43 ࿁ᣣᧄવᾲࠪࡦࡐࠫ࠙ࡓෳട↳ㄟᣇᴺ ······································································································75
 International Heat Transfer Conference 2006 ಴Ꮸ࠷ࠕ࡯ߩߏ᩺ౝ㧔੍๔ 㧕·····················································82
 ੐ോዪ߆ࠄߩㅪ⛊···················································································································································83
 ✬㓸಴ ㇱળࡁ࡯࠻㧦ๆ⌕ߦ㑐ߔࠆ․㓸߳ߩ߅߽޿·································· ዊጊ ❥㧔਻Ꮊᄢቇ㧕···············92ᣣᧄવᾲቇળ  ᐕᐲ㧔╙  ᦼ㧕ળ㐳࡮೽ળ㐳࡮ℂ੐࡮⋙੐ٟળ 㐳 ᐣม ᱜᒄ㧔↥ᬺᛛⴚ✚ว⎇ⓥᚲ㧕ٟ೽ળ㐳 ൎ↰ ᱜᢥ㧔ᣧⒷ↰ᄢቇ㧕ਭⷺ ༑ᓼ㧔ᄢ㒋ࠟࠬ㧕ችౝ ᢅ㓶㧔᧲੩Ꮏᬺᄢቇ㧕ٟℂ ੐ ૒⮮ ൟ㧔᧲੩Ꮏᬺᄢቇ㧕ศ↰ ⧷↢㧔੩ㇺᄢቇ㧕⧎᧛ సᖗ㧔᧲੩Ꮏᬺᄢቇ㧕ᳰᎹ ᣽ᒄ㧔ർᶏ㆏ᄢቇ㧕౞ጊ ㊀⋥㧔᧲ർᄢቇ㧕ㄞ ବඳ㧔ฬฎደᎿᬺᄢቇ㧕㕍ᧁ ๺ᄦ㧔㐳ጟᛛ⑼ᄢቇ㧕┻ਛ ାᐘ㧔␹ᚭᄢቇ㧕ㅩဈ ᤘᴦ㧔ᓼፉᄢቇ㧕ዊጊ ❥㧔਻Ꮊᄢቇ㧕㐳㊁ 㕏ዏ㧔ฬฎደᎿᬺᄢቇ㧕↰ਛ ෼㧔ਃᶆᎿᬺ㧕᫪ ᴦ༹㧔᧲੩㔚ജ㧕ᐽ ୶᣿㧔࠳ࠗࠠࡦ㧕ٟ⋙ ੐ Ꮏ⮮ ৻ᒾ㧔ർᶏ㆏ᄢቇ㧕㕍ᧁ ඳผ㧔⼾↰ਛᄩ⎇ⓥᚲ㧕Vol. 45, No. 190, January 2006
CONTENTS< Opinion >Strategy and Tactics
Masafumi KATSUA (Waseda University) ·························································································1< Memorial >Mourn over the Death of Prof. Susumu Kotake
Takayoshi INOUE (Tokyo Institute of Technology) ··········································································3Contributions of the late Professor Kotake to HTSJ
Hiroshi KAWAMURA (Tokyo University of Science) ······································································5< Field of Adsorption - From Micro to Macro, and Associated Systems ->Development of Functional Adsorbent Material for Adsorption Heat Pump
Satomi SHIMOOKA, Kazunori OSHIMA, Takahiko TAKEWAKI, Hiroyuki KAKIUCHI(Mitsubishi Chemical Group Science and Technology Research Center) ··········································8Adsorotion phenomena inside porous materials
Hirofumi DAIGUJI (The University of Tokyo) ···············································································14Development of materials for high density chemical heat storage
Junichi RYU (Tokyo Institute of Technology) ·················································································21
Heat and Mass Transfer Phenomena in Adsorber for Adsorption Heat Pump
Fujio WATANABE, Mitsuhiro KUBOTA (Nagoya University)·······················································27
The Application of Water Vapor Adsorption Phenomena to the Independent Control of Latent and Sensible Heat
Yoshinori HAMAMOTO, Hideo MORI (Kyushu University)·························································33
Adsorptive Desiccant Cooling / Dehumidification
Akio KODAMA (Kanazawa University)·························································································39
Basics of Adsorption Refrigeration Cycle and Advanced Cycles
Atsushi AKISAWA (Tokyo University of Agriculture and Technology) ··········································45< Contribution >Science of Boiling (5)Yoshiro KATTO (Professor Emeritus of the University of Tokyo)···················································50
Why skate so slippery ?
Katsutosi TUSIMA (University of Toyama) ····················································································56< Nature Q >Astrophysics and Thermodynamics
Masa-aki SAKAGAMI (Kyoto University)··················································································60

< Project Q >Development of Multi-Stage Steam Injectors with Innovative Heat-Transfer
Tadashi NARABAYASHI (HokkaidoUniversity), Michitsugu MORI (TEPCO)·························65< Report on International Conference >Prof. Masanori Monde and Prof. Yuichi Mitsutake of Saga University Received ASME 2005 Best Paper Award
Niro NAGAI (University of Fukui)·································································································70

r t Transfer >< Hea<
Noize
Masafumi HIROTA (Nagoya University)·····················································································71< Calendar > ····························································································································································73< Announcements > ···············································································································································75
Note from the Editorial Board: A Thought for Special Forum on Adsorption Phenomena
Sigeru KOYAMA (Kyushu University)························································································92⺰ სᚢ⇛ߣᚢⴚ
Strategy and Tactics⺰ სൎ↰ ᱜᢥ㧔ᣧⒷ↰ᄢቇ㧕
Masafumi KATSUTA㧔Waseda University)㧝㧚⚻✲ ✬㓸಴ ㇱળ㐳ߩศ↰⧷↢వ↢߆ࠄ㧘੹ᦼ߆ࠄߪ✬㓸಴ ᜂᒰ೽ળ㐳ߚࠆ߽ߩዋߥߊߣ߽৻࿁ߪ
‫ޟ‬વᾲ‫ߦޠ‬૗߆ᛩⓂߖࠃ㧚ߣߩ๮ࠍฃߌ㧘᜕ᢥ߇੹ᓟߦ⑒ᩮࠍᱷߔᖡ଀ߦߥߞߡߒ߹߁ߩߢߪ㧘ߣ޿ߐߐ߆ぷふߒߟߟᐕࠍ〙޿ߢᦨㄭᕁ߁ߣߎࠈࠍ
ขࠅ߹ߣ߼ߚᰴ╙ߢ޽ࠅ߹ߔ㧚ᤚ㕖㧘ߎࠇࠍᄾᯏ
ߦߏᛕ್㧘ߏឭ⸒ࠍ߅ነߖ޿ߚߛߌࠇ߫ߣᕁ޿߹ߔ㧚 ߎߎߢ㧘ᡷ߼ߡᚒ‫ߩޘ‬ቇળߩේὐߢߔ߇㧘ቇߩㅴᱠ᥉෸߅ࠃ߮ቇⴚߩ⊒ዷߪ㧘ᓧࠄࠇߚ⍮⷗߇␠ળ⊛ߥ࠾࡯࠭ߦහߒߚᔕ↪ߦଏߐࠇࠆߎߣ㧘߽߁ዋߒᄢߍߐߦ⸒߃߫㧘↥ᬺൻߦ⚿߮ߟߌ㧘߭޿ߡߪᛛⴚ㕟ᣂ߿ᜬ⛯⊛ߥ⊒ዷߦነਈߔࠆߎߣࠍડ࿑
ߒߡ޿ࠆߦઁߥࠄߥ޿ߣ⠨߃߹ߔ㧚 ߘ߁ߥࠇ߫㧘ቇળߩᐢႎߥߤᔅⷐߥߊߥࠅ㧘વᾲ⎇ⓥࠍ⚻ߡࠛࡦࠫ࠾ࠕߣߥࠆᓟヘߩࠠࡖ࡝ࠕࡄ
߽ࠬ᣿⏕ߦߥࠆ߫߆ࠅߢߥߊ㧘⎇ⓥ⠪ߦߣߞߡߪ㧘ߥߦࠃࠅᰴߩၮ⋚⎇ⓥߩߚ߼ߩ⾗㊄ࠍ߽ᓧࠄࠇࠆ
ߎߣߣߥࠅ߹ߔ㧚 ᚒ‫⎇ߩ┵ᧃޘ‬ⓥ⠪ߪ㧘ᣣ‫ߩޘ‬ᵴേߦㅊࠊࠇߎࠇ
ߦኻᔕߔߴߊ⹦⚦ߥᚢⴚߩߺࠍ⼏⺰ߒ㧘⚦߆ߥኻᔕࠍᒝ޿ࠄࠇߡ޿ࠆߩߢߪߥ޿ߢߒࠂ߁߆㧚 ౝ㑑ᐭߩ✚ว⑼ቇᛛⴚળ⼏⼏ຬߢ޽ࠆరਃ⪉㊀Ꮏߩᨷᬀ᳁ߪ㧘ᦨㄭᣣᧄᯏ᪾ቇળࡎ࡯ࡓࡍ࡯ࠫߩ
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ߦ⑳⷗ߢ޽ࠆ߇ߣᢿࠅߟߟ㧘એਅߩᢥ┨㧔ᛮ☴㧕ࠍነߖߡ߅ࠄࠇ߹ߔ㧚㨬ࠕࠞ࠺ࡒࠕ஥╬ߩၮ␆⎇ⓥታᣉ⠪߽㧘ߘߩᚑᨐࠍ࿖ജߣ↥ᬺൻ߹ߢ⚿߮ߟߌࠆࡠ࡯࠼ࡑ࠶ࡊ߇ਇ㞲᣿ߥ߹߹ߢၮ␆⎇ⓥࠍផㅴ
ߔࠆ௑ะ߇ᒝߊ㧘ฦ⺰ߢߪᚲᦼߩᚑᨐࠍ਄ߍߟߟ
޽ࠆ߽ߩߩ㧘࿖ኅᛩ⾗ߣߒߡߩᚑᨐߦ߹ߢ⚿߮ߟߌࠆ"⋡⊛ᜰะဳၮ␆⎇ⓥ"㊀ὐൻ߳ߩࠗࡦ࠮ࡦ࠴
ࡉߦᰳߌߚ௑ะ߇᦭ࠆ㨭㧚 ߔߥࠊߜ㧘ၮ␆ಽ㊁ߢߪ․ߦᛛⴚ㐿⊒⎇ⓥߩࡠ
࡯࠼ࡑ࠶ࡊ᭴▽㧔৻⒳ߩᚢ⇛㧕߇࿖ኅ⊛ᛩ⾗ࠍଦߔߎߣߩߢ߈ࠆ⎇ⓥ߳ߩᣧ㆏ߢ޽ࠆߣ⸒ߞߡ߅ࠄ
ࠇ߹ߔ㧚ᧄળߦ߅޿ߡ߽㧘ߢ߈ࠆߛߌᣧߊቇળߩ
ᚢ⇛ࠍର਄ߦ਄ߍࠆᔅⷐ߇޽ࠆߩߢߪߥ޿ߢߒࠂ
߁߆㧚㧞㧚ᄢ޿ߥࠆ⍦⋫ ╙ 44 ᦼ಴⊒ภ㧔વᾲ Vol.44 No.187㧕ߩᏎ㗡⸒
ߦ 44 ᦼળ㐳 ᐣมవ↢ߩࡔ࠶࠮࡯ࠫ߇ឝタߐࠇߡ߅ࠅ߹ߔ㧚ߎߩਛߢ㧘‫ޡ‬ේὐߦ┙ߜ㄰ࠅ⠨߃⋥ߒߡߺࠆ‫ࠍߣߎޢ‬ㅀߴߡ߅ࠄࠇ㧘․ߦ㧘ᧄቇળቯ᱅
ࠍᒁ↪ߐࠇ㧘
‫ޡ‬વᾲቇߩㅴᱠ᥉෸㧘ቇⴚߩ⊒ዷߦነਈߔࠆ‫▎ߩޢ‬ᚲࠍᒝ⺞ߐࠇߡ߅ࠅ߹ߔ㧚৻ᣇ㧘⃻ታߦ┙ߜ㄰ߞߡߺࠆߣዊ↢ߥߤቢోߦ਎ߩ㘑ầߦᵹߐࠇ㧔ᄤߩჿߢߒࠂ߁߆㧫㧕㧘޿ߟߩ㑆ߦ߆⡯႐ߩ↥ቇㅪ៤㧘⎇ⓥផㅴ㧘⍮⽷ᧄㇱߥߤߩਛᩭߦ޿
ࠆߎߣࠍᕁ߁ߣ⥄ᚓߩᔨߦ⧦߹ࠇ߹ߔ㧚ߘ߁⸒߃߫㧘ᤘ๺ 40 ᐕઍߩ೨ඨ㧘ᄢቇߩ⎇ⓥᵴേߦ߅ߌࠆ
↥ቇㅪ៤ߦᱤะ߆ߞߚߩߪ㧘ઁߢ߽ߥ޿ᚒ‫ߩޘ‬਎ઍ㧔ଶߦ⸒߁࿅႙ߢߔ㧕ߢ޽ߞߚߩߢߔ㧚ߎࠇߪᄢ޿ߥࠆ⍦⋫ߢߪߥ޿߆ߣ㧚㧟㧚ᚢ⇛ߣᚢⴚ ߒ߆ߒߥ߇ࠄᤨߪᵹࠇ㧘ࠠࡖ࠶࠴ࠕ࠶ࡊߩᤨઍ
߆ࠄ࠻࠶ࡊ࡜ࡦ࠽࡯ࠍ⚻ߡ㧘ⅣႺߣ⚻ᷣߩࡃ࡜ࡦ
ࠬߩขࠇߚᜬ⛯⊛ߥ⊒ዷࠍᦼߔࠆᤨઍߣߥߞߡ޿
ࠆߎߣߪ㧘⚗ࠇ߽ߥ޿੐ታߛߣᕁ޿߹ߔ㧚ߔߥࠊߜ㧘ଔ୯ഃㅧߩḮᴰߦ⑼ቇᛛⴚࠍ૏⟎ߠߌ㧘␠ળ࠾࡯࠭ߦහᔕߒߚᛛⴚ㕟ᣂߦലᨐ⊛ߦߟߥߍߥߌ
ࠇ߫ߥࠄߥ޿ᤨઍߦߥߞߚߣ޿߃ࠆߩߢߪߥ޿ߢ
ߒࠂ߁߆㧔ߎࠇ߽ᄤߩჿߢߒࠂ߁߆㧫㧕㧚

વᾲ 2006 ᐕ 1 ᦬㧠㧚߅ࠊࠅߦ વᾲቇ㧘Ꮏቇ߇ᜏߊ‛ ⪺⠪߇⸒߁ߩ߽ᱤ∣޿ߩߢߔ߇㧘વᾲቇ㧘વᾲᎿቇߪၮ⋚ߣߥࠆቇⴚߢߔ㧚߹ߚ㧘ߤߩࠃ߁ߥᛛ
ⴚߦ߽ᔅߕᔅⷐߥቇ໧૕♽ߢ޽ࠅ㧘ߤߜࠄ߆ߣ޿

-1-

J. HTSJ, Vol. 45, No. 190

⺰ ს ߹ߚ㧘ቇળߣ޿߁႐ࠍ↪޿ߡᄢቇߣડᬺߩᛛⴚ
㐿⊒ജ߿⎇ⓥߦ㑐ߔࠆ㆑޿ࠍℂ⸃ߒ㧘੕޿ߦ␲ߩ
ࠡࡖ࠶ࡊࠍၒ߼ࠆദജࠍߔࠆߣߣ߽ߦ㧘࡝ࠛ࠱ࡦ⊛ߥᯏ⢻ࠍቇળ߇⊒ើߔߴ߈ߛߣᕁ޿߹ߔ㧚ߎࠇߦߪࠕ࠼ࡃࡦࠬࡈࠖ࡞ࠡࡖ࠶ࡊᵴേ߇ᔅⷐߥߩߢ
ߪߥ޿ߢߒࠂ߁߆㧫߁ߣ⴫ߦߪ⃻ࠇߕ㧘㤥ሶߦᔀߒߡ޿ࠆߣ⸒߃߹ߔ㧚ߢ޽ࠆ߆ࠄߎߘ㧘਎ߦ⸒߁వ┵߿㊀ὐ㗔ၞࠍᜎุߔࠆߛߌߢߥߊ㧘Ꮑߺߦขࠅ౉ࠇߟߟ㧘વᾲߣ޿߁વ⛔޽ࠆቇ໧ಽ㊁ߩᐢ߇ࠅࠍᭉߒ߻ࠃ߁ߥߒߚ
ߚ߆ߐࠍᜬߞߡ߅ࠅ߹ߔ㧚੹ᓟߪ㧘ߐࠄߦవ┵ߩⲢว㗔ၞߦ߅ߌࠆࠗࡁࡌ࡯࡚ࠪࡦ߳ߩ⽸₂߇ᦼᓙߐࠇࠆߣᕁ޿߹ߔ㧚✬㓸಴ㇱળ߆ࠄߩ߅⍮ࠄߖ㧦̌વᾲ̍⹹ߪ੹ᐕ߆ࠄቄೀߦ ✬㓸಴ ㇱળߣℂ੐ળߢክ⼏ߒ߹ߒߚ⚿ᨐ㧘੹ᐕ߆ࠄ̌વᾲ̍⹹ߩ⊒ⴕࠍ㧘ߎࠇ߹ߢߩ㓒᦬߆ࠄቄೀ㧔1, 4, 7, 10 ᦬㧕ߦᄌᦝߐߖߡ޿ߚߛߊߎߣߦߥࠅ߹ߒߚ㧚 ߎߩℂ↱ߣߒߡߪ࡮✬㓸૞ᬺߩ⽶ᜂࠍシᷫߔࠆߣߣ߽ߦ㧘1 ࿁ߩ✬㓸ߦචಽߥᤨ㑆ࠍ߆ߌߡ㧘ࠃࠅలታߒߚౝኈߣߔࠆߎߣ
࡮ᦨㄭߩࠗࡦ࠲࡯ࡀ࠶࠻ߣ㔚ሶࡔ࡯࡞ߩ⊒㆐ߦࠃߞߡ㧘ળ๔ߩㄦㅦߥવ㆐ߦߟ޿ߡߩ
ળ⹹ߩᓎഀ߇シᷫߒߚߎߣߥߤߢߔ㧚 ߎߩᄌᦝߦࠃࠅ㧘38 Ꮞ 148 ภ㧔1999 ᐕ 1 ᦬㧕ߢ㧘⹹ฬࠍ̌વᾲ⎇ⓥ̍߆ࠄ̌વᾲ̍
ߦᄌᦝߔࠆߣߣ߽ߦ TSE ߣ߽ಽౠߦߒߡ㓒᦬⊒ⴕߣߥߞߚᧄ⹹ߪ㧘⊒ⴕᒻᘒߦߟ߈
߹ߒߡߪ 7 ᐕએ೨ߣห᭽ߥ߽ߩߦᚯࠅ߹ߔ㧚વᾲ 2006 ᐕ 1 ᦬-2-

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ㅊᖬ㧦ዊ┻ ㅴ వ↢ዊ┻ㅴవ↢ߩߏㅤ෰ࠍᖬ߻
Mourn over the Death of Prof. Susumu Kotake੗਄ ೰⦟㧔᧲੩Ꮏᬺᄢቇ㧕
Takayoshi INOUE (Tokyo Institute of Technology)ᧄળరળ㐳㧘ዊ┻ㅴవ↢ߪ෰ࠆᐔᚑ 17 ᐕ 11 ᦬ 10ᣣඦᓟߏㅤ෰ߐࠇ߹ߒߚ㧚᡿ੱ߅ࠃ߮ߏㆮᣖߩᒝ޿ߏ
Ꮧᦸߦࠃࠅߏ⫋௾ߪߏⷫᣖߢၫࠅⴕࠊࠇ߹ߒߚߎߣ
ࠍߏႎ๔ߐߖߡ޿ߚߛ߈߹ߔ㧚߹ߚ㧘ᧄળߩߎࠇ߹ߢ
ߩᘠ⠌ߢߪ㧘⪺ฬߥవ↢߇ߏㅤ෰ߐࠇߚ႐วㅦ߿߆ߦ
ࡔ࡯࡝ࡦࠣ࡝ࠬ࠻╬ߢߏㅪ⛊ߐߖߡ㗂޿ߡ߅ࠅ߹ߔ
߇㧘ߔߢߦዊ┻వ↢ߪᧄળࠍㅌળߐࠇߡ߅ࠅ㧘߹ߚ↢೨߅ુ޿ߒߡ߅ࠅ߹ߒߚవ↢ߩߏᗧᕁߢߪߘߩࠃ߁
ߥߎߣߪᅢ߹ߥ޿ߣ⸒߁ߎߣߢߒߚߩߢ㧘⑳ߩ್ᢿߢ౏ᑼߩߏㅪ⛊ߪប߃ߐߖߡ޿ߚߛ߈߹ߒߚ㧚ߎߩߚ߼㧘੹࿁ߩ⫋௾ߩઙߢᄙߊߩవ↢ᣇߦߪߏㅅᖺࠍ߅߆ߌ
ߒ߹ߒߚߎߣߣ᜙ኤ޿ߚߒ߹ߔ㧚⺈ߦ↳ߒ⸶޽ࠅ߹ߖ
ࠎߢߒߚ㧚ߐߡ㧘ᤘ๺ 56 ᐕએ᧪੹ᣣ߹ߢߩ㐳߈㑆㧘౏⑳ߦࠊߚࠅᄢᄌ߅਎⹤ߦߥߞߚ߽ߩߣߒߡ㧘వ↢ߩᕁ޿಴ࠍ
ߏ⚫੺ߐߖߡ޿ߚߛ߈㧘ᷓ↟ߥࠆຟᖬߩᗧࠍ⴫ߒ߹ߔ㧚వ↢ߪᤘ๺ 9 ᐕ 6 ᦬ 24 ᣣ⨙ၔ⋵ߦ߅↢߹ࠇߦߥࠅ㧘ᤘ๺ 33 ᐕ᧲੩ᄢቇᎿቇㇱ⥶ⓨቇ⑼ࠍߏතᬺߦߥࠅ㧘หᐕ 4 ᦬ߦᎹፒ⥶ⓨᯏᩣᑼળ␠ߦዞ⡯ߐࠇ߹ߒߚ㧚ߘߩᓟ㧘ᤘ๺ 38 ᐕߦ᧲੩ᄢቇ⥶ⓨ⎇ⓥᚲߩഥᚻߦߥࠄ
ࠇ㧘ᤘ๺ 39 ᐕห⎇ⓥᚲഥᢎ᝼㧘ᤘ๺ 53 ᐕ᧲੩ᄢቇቝ
ቮ⥶ⓨ⎇ⓥᚲ㧔ᣥ⥶ⓨ⎇ⓥᚲ㧕ᢎ᝼ߦછߗࠄࠇ߹ߒߚ㧚ߘߩ㑆㧘ᤘ๺ 39 ᐕ 1 ᦬ߦ᧲੩ᄢቇࠃࠅᎿቇඳ჻ߩቇ
૏ࠍ᝼ਈߐࠇ߹ߒߚ㧚᧲੩ᄢቇቝቮ⥶ⓨ⎇ⓥᚲ߇ᢥㇱ⑼ቇ⋭⋥ロߩቝቮ⑼ቇ⎇ⓥᚲߦᡷ⚵ߐࠇࠆࡊࡠ࠮ࠬ
ߩਛߢ㧘᧲੩ᄢቇႺ⇇㗔ၞ⎇ⓥᣉ⸳ࠍ⚻ߡ㧘ᤘ๺ 56ᐕߦᎿቇㇱᯏ᪾Ꮏቇ⑼ߦ⒖ࠄࠇ㧘ᐔᚑ 7 ᐕ 3 ᦬᧲੩ᄢቇᎿቇㇱࠍቯᐕㅌ⡯ߐࠇ߹ߒߚ㧚ߘߩᓟߪ㧘ᣣᧄේሶജ⎇ⓥᚲ㧘᧲ᵗᄢቇߢ⎇ⓥ㧘ᢎ⢒ߦോ߼ࠄࠇ߹ߒߚ㧚⑳߇వ↢ߦೋ߼ߡ߅⋡ߦ߆߆ߞߚߩߪ㧘ᤘ๺ 56
ᐕ 4 ᦬ߦ⑳߇ᄢቇ㒮ୃ჻⺖⒟ߦㅴቇߔࠆߣ߈ߢߒߚ㧚තᬺ⎇ⓥߩᜰዉᢎ᝼߆ࠄ㧘ಝ❗ߩ⚛ㆊ⒟ࠍ⎇ⓥߒߡ޿ߡ㕙⊕޿ߣ޿߁ߎߣߢዊ┻వ↢ߩ⎇ⓥቶࠍផ⮈ߒߡ޿ߚߛ߈㧘⎇ⓥቶ㈩ዻߦ߅޿ߡዊ┻వ↢ࠍᏗᦸߒ߹ߒߚ㧚4 ᦬ߦᎿቇㇱ 7 ภ㙚ߩ৻ቶߢ㕙ធࠍฃߌߚ

વᾲ 2006 ᐕ 1 ᦬-3-ߩߢߔ߇㧘‫ޟ‬ቇ↢ߪⷐࠄߥ޿㧚⿷ᚻ߹ߣ޿ߛ߆ࠄⷐࠄ
ߥ޿㧚‫ߣޠ‬૗ᐲ߽ᢿࠄࠇ߹ߒߚ㧚ඳ჻⺖⒟ߦㅴቇߒߚ
ᓟᣣ㧘ߎߩ⹤ࠍᜬߜ಴ߔߣ㧘వ↢ߪ‫ޟ‬1 ࿁߿ 2 ࿁ᢿࠄࠇߚ߆ࠄ᧪ߥߊߥࠆ᭽ߥቇ↢ߪⷐࠄߥ޿ࠎߛ㧚ߘࠇߢ߽᧪ࠆߣ޿߁ቇ↢ߥࠄฃߌ౉ࠇࠆ㧚‫ߡࠇࠊ⸒ߣޠ‬㧘‫ߣޠߥ߆ߩ߽ߥࠎߘޟ‬ᾍߦᏎ߆ࠇߚߎߣࠍⷡ߃ߡ޿
߹ߔ㧚੹ߩ⎇ⓥቶ㈩ዻࠍᕁ޿߹ߔߣ㓒਎ߩᗵ߇޿ߚ
ߒ߹ߔ߇㧘వ↢߽ᄤ㇎㝩ߥࠄ߫ቇ↢߽ᗧ࿾ߞᒛࠅߢ
ᄌࠊߞߡ޿ߚߩߢߒࠂ߁㧚⎇ⓥቶߦᚲዻߒߡߔߋߦ㧘ᒰᤨ⎇ⓥቶߦ᧪ࠄࠇߡ޿߹ߒߚ᧲ᶏᄢቇߩ૒㊁ᅱሶవ↢ߦ㧘‫ޟ‬వ↢ߦᔶࠄࠇߡ޿ࠆ߁ߜߪᄢਂᄦ㧚૗߽⸒ࠊࠇߥߊߥߞߚࠄ㧘⦟ߊߥߞߚ߆⷗ᝥߡࠄࠇߚ߆ߩ
ߤߜࠄ߆ߢ㧘⦟ߊߥࠆߎߣߪߥ޿߆ࠄ㧚‫ߚࠇࠊ⸒ߣޠ‬ߎߣࠍⷡ߃ߡ޿߹ߔ㧚ߎߩᓟ⚂྾ඨ਎♿ߦࠊߚߞߡ
ߏᜰዉ޿ߚߛߊߎߣߦߥࠆߩߢߔ߇㧘ᗧ᰼ߩ޽ࠆ⠪㧘ᣂߒ޿ߎߣߦ᜸ᚢߔࠆ⠪ߦኻߒߡߪߚߣ߃ᐕ㦂߇⧯ߊߡ߽ⷫりߦߥߞߡࠨࡐ࡯࠻ߔࠆߌࠇߤ߽㧘ᣂߒ޿ߎߣߦ᜸ᚢߒߥ޿⠪ߪ⋧ᚻߦߒߥ޿㧘ߣ޿߁ᆫ൓ߪ㧘੢ߊߥࠆ߹ߢ৻⽾ߒߡ޿ߚࠃ߁ߦᕁ޿߹ߔ㧚 ⑳߇⎇ⓥቶߦᚲዻߒߡ޿ߚ㗃ߪ㧘ዊ┻వ↢ߪࠢ࡜ࠬ࠲࡯ߩ⎇ⓥࠍᆎ߼ࠄࠇߡ߆ࠄᢙᐕߣ޿߁㗃ߢߒߚ㧚࿷ᄖ⎇ⓥߢࠞ࠽࠳ߦṛ࿷ߐࠇߡฎౖ⊛ᩭ↢ᚑ⺰ࠍ↪
޿ߚಝ❗ߩ⎇ⓥߦᓥ੐ߐࠇ㧘Ꮻ࿖ᓟߪߘߩಝ❗ㆊ⒟ߩᦨೋߢ޽ࠆߴ߈ࠢ࡜ࠬ࠲࡯↢ᚑߦ⥝๧ࠍ߽ߚࠇߡ
߅ࠅ߹ߒߚ㧚
‫ߩ߆ߎߤޟ‬ቇળߢ⊒⴫ߒߚߣ߈ߦߪ㧘ࠢ࡜ࠬ࠲࡯ߣ⸒߁ߎߣߢᩭΆᢱ᫔ߩࠢ࡜ࠬ࠲࡯ߣ㑆㆑߃ࠄࠇߡේሶജߩ࠮࠶࡚ࠪࡦߦ౉ࠇࠄࠇߚ‫߁޿ߣޠ‬ࠃ߁ߥᤨઍߢߒߚ߇㧘ᯏ᪾Ꮏቇߢ߽ߎߩࠃ߁ߥಽሶ
ේሶࠍℂ⸃ߔߴ߈ߣߩᒝ޿ାᔨߛߞߚߣᕁ޿߹ߔ㧚೨ߦ㧘ዊ┻వ↢ߦߥߗࡑࠗࠢࡠࠬࠤ࡯࡞ߩᾲࠍᆎ߼
ࠆࠃ߁ߦߥߞߚߩ߆ુߞߚߎߣ߇޽ࠅ߹ߔ㧚ߘߩߣ߈ߩ⹤ߢߪ㧘ᶧṢΆ὾㧘Ά὾㛍㖸㧘ྃᵹ㛍㖸㧘ή㊀ജൻߢߩᴣ㛛᳇ᵃߩ᜼േ㧔ߎࠇߦߟ޿ߡߪ㧘੹ߩᄤ⊞㒨ਅ߇⊞ᄥሶᤨઍߦቝቮ⥶ⓨ⎇ⓥᚲࠍⷞኤߐࠇߚ
ߣ߈ߦߏ⺑᣿ߐࠇߚߣુ޿߹ߒߚ㧚ᦨㄭߪή㊀ജਅ

J. HTSJ, Vol. 45, No. 190

ㅊᖬ㧦ዊ┻ ㅴ వ↢

1983 ᐕ 6 ᦬㧘ᄥቿᐭᄤḩችߦߡ㧔╙ 20 ࿁વᾲࠪࡦࡐࠫ࠙ࡓ㧕ᒰᤨዊ┻⎇ⓥቶߢ⎇ⓥߒߡ޿ߚࡔࡦࡃ࡯
Ꮐ߆ࠄ㧘ዊ┻వ↢㧔48 ᱦ㧕㧘㜞ᧄవ↢㧘╩⠪㧘૒㊁వ↢㧘㕍ᧁవ↢ߢߩવᾲߩ⎇ⓥ߇ᵴ⊒ߢߔ߇㧘వ↢ߩߏ⎇ⓥߪ޽߹
ࠅߦ߽ᣧ߆ߞߚߩߢ㧘߹ߞߚߊᒁ↪ߐࠇߥ޿ࠃߣ╉ߞߡ߅ࠄࠇ߹ߒߚ㧚㧕㧘෻ᔕࠍ઻߁ᵹࠇ㧘ಝ❗ࠍ઻߁ᵹࠇߥߤ㧘વᾲߩߐ߹ߑ߹ߥಽ㊁ߩ⎇ⓥࠍߒߡ߈ߚ
߇㧘ㅪ⛯૕ߣߒߡขࠅᛒ߁વᾲߩ㒢⇇߇⷗߃ߚߩߢ㧘ߘࠇࠍᛂߜ⎕ࠆߎߣࠍ⠨߃ߚࠄࡑࠗࠢࡠࠬࠤ࡯࡞ߦ
⥋ߞߚ㧘ߣߩߎߣߢߒߚ㧚ዊ┻వ↢ߩ⎇ⓥߪᄙጘߦࠊߚࠆߩߢᢛℂߔࠆߎߣߪ㔍ߒ޿ߩߢߔ߇㧘ᦨㄭߩࡒࠢࡠಽ㊁ߦߟߥ߇ࠆߣ
޿߁ⷰὐߢ㧘⑳ߥࠅߦ⸃㉼ߒߡߺ߹ߔ㧚߹ߕ㧘వ↢ߪᾲᎿቇߦൻቇ෻ᔕࠍขࠅㄟ߻ߣ޿߁ὐߦ߅޿ߡ㧘᧲Ꮏᄢߩ᫪ᐽᄦవ↢ࠄߣߣ߽ߦ߆ߥࠅవ㚟⊛ߢ޽ߞߚࠃ߁ߦᕁ޿߹ߔ㧚߽ߣ߽ߣᶧṢΆ὾ߩ⎇ⓥࠍⴕߞ
ߡጟፒ࡮ዊ┻ߩℂ⺰ࠍ⏕┙ߐࠇ㧘1980 ᐕ㗃߹ߢߪ㧘ൻቇ⚛෻ᔕࠍㅦᐲ⺰ߣߒߡᵹࠇߩၮ␆ᑼߣㅪ┙ߔࠆ

વᾲ 2006 ᐕ 1 ᦬-4-ߎߣߦࠃࠅ㧘෻ᔕࠍ઻߁ᵹࠇߩࠪࡒࡘ࡟࡯࡚ࠪࡦߦ
ᓥ੐ߐࠇߡ޿߹ߒߚ㧚ߎߎߢ৻ᔕߩ࡟ࡌ࡞ߢᵹࠇߣ
ൻቇ෻ᔕࠍ⛔วߔࠆߎߣࠍቢᚑߒߚߩߢߪߥ޿߆ߣ
ᕁ޿߹ߔ㧚ᰴߦ㧘ߐࠄߦ৻Ბᷓ޿࡟ࡌ࡞ߢャㅍ⃻⽎ߣൻቇ෻ᔕࠍ⛔วߔࠆߎߣࠍ⠨߃ࠄࠇߚࠃ߁ߦᕁ޿
߹ߔ㧚ߟ߹ࠅൻቇ෻ᔕ߿ャㅍ⃻⽎ࠍ⛔⸘⊛ߢߪߥߊ㧘୘‫ߩޘ‬ಽሶߩャㅍߣߒߡᛒ߁ߣ޿߁ߎߣߢߔ㧚ߘߩࠃ߁ߥขࠅᛒ޿ࠍ⠨߃ࠆߣ㧘ߘࠇߙࠇߩಽሶߩ୘ᕈ
ࠍᛒ߁ߎߣߦߥࠅ㧘ಽሶേജቇᴺ߿㊂ሶࠪࡒࡘ࡟࡯
࡚ࠪࡦᚻᴺ߳ߣ⊒ዷߒߡⴕߞߚߣℂ⸃ߒߡ޿߹ߔ㧚వ↢ߪ㆏ඨ߫ߢㅤ߆ࠇߡߒ߹޿߹ߒߚ߇㧘ᓟヘߩ
⑳ߚߜߦߪߘߩ㆏ࠍㅴࠎߢ޿ߞߡ᰼ߒ޿ߣ⸤ߐࠇߚ
ߩߢߪߥ޿߆ߣ⠨߃ߡ߅ࠅ߹ߔ㧚వ↢ߩߏ౵⑔ࠍ߅␨ࠅ⥌ߒ߹ߔ㧚

J. HTSJ, Vol. 45, No. 190

ㅊᖬ㧦ዊ┻ ㅴ వ↢ዊ┻ㅴవ↢ߣᣣᧄવᾲቇળ
Contributions of the late Professor Kotake to HTSJᴡ᧛ ᵗ㧔᧲੩ℂ⑼ᄢቇ㧕
Hiroshi KAWAMURA (Tokyo University of Science)Ᏹߢߒߚ߇㧘⎇ⓥ⠪㆐ߪ㧘૗ߣ߆ߒߡࡄ࠰ࠦࡦࠍ
⎇ⓥߣᢥᦠ૞ᚑߩਔᣇߦ૶߅߁ߣߒߡ޿߹ߒߚ㧚ࡄ࠰ࠦࡦᧄ૕ߪ㧘ᣣᧄ⺆⴫␜ߩ◲ଢߐ߆ࠄ NEC
ߩ PC9801 ♽߇ਥᵹߢ㧘ࡢ࡯ࡊࡠ࠰ࡈ࠻ߣߒߡߪ
‫߇࠻ࡈ࠰߁޿ߣޠ᧻ޟ‬ᐢߊ૶ࠊࠇߡ޿߹ߒߚ߇㧘ᰴ╙ߦ‫৻ޟ‬ᄥ㇢‫߇ޠ‬ᐢ߹ࠅߟߟ޽ࠅ߹ߒߚ㧚ߘߩ㗃ߩዊ┻వ↢ߪ㧘‫৻ޟߣޠ᧻ޟ‬ᄥ㇢‫ߪߢޠ‬㧘ฦ‫ߎޘ‬ࠇߪ಴᧪ࠆ߇㧘ߎࠇߪߤ߁ߒߡ߽಴᧪ߥ޿㧘ߣ޿߁ߎߣࠍ⹦⚦ߦ⺞ߴߡ߅ࠄࠇߡ㧘޽ࠆቇળߩේⓂ
↪⚕ߦวࠊߖߡ߯ߞߚࠅᛂߜ಴ߖߚߩߪ㧘৻ᄥ㇢ߛߞߚߣ޿߁ࠃ߁ߥߎߣࠍ㧘ߒ߫ߒ߫ᾲᔃߦ⹤ߒ
ߡ߅ࠄࠇ߹ߒߚ㧚ߎߩࠃ߁ߦ㧘వ↢ߪࠦࡦࡇࡘ࡯࠲࡯ࠍ૶޿ߎߥ
ߔߎߣߦ㑐ߒߡᄢᄌߏᾲᔃߢߒߚߩߢ㧘ᒰὼߩߎߣߥ߇ࠄ㧘ߎࠇࠍવᾲ⎇ⓥߦ߽ะߌࠄࠇߡ㧘ࠦࡦࡇࡘ࡯࠲࡯ࠍ↪޿ߚવᾲᢙ୯⸃ᨆߩ⊒ዷߦ㕖Ᏹߦߏዧജߐࠇ߹ߒߚ㧚⹦⚦ߪ⋭⇛ߒ߹ߔ߇㧘ᣣᧄᯏ᪾ቇળߩਛߦ㧘⎇ⓥળ߿⎇ⓥಽ⑼ળࠍ┙ߜ਄ߍࠄࠇ㧘㧔᡿㧕࿯ᣇ㇌ᄦవ↢㧔᧲Ꮏᄢ㧕ߣ⑳߇㧘ᐙ੐ߣߒߡ߅ᚻવ޿ࠍߐߖߡ޿ߚߛ߈߹ߒߚ㧚ዊ┻వ↢ߪ޿ࠈ޿ࠈߣߏ⊒᩺ߦߥߞߡ㧘⎇ⓥᖱႎߩ੤឵㧘⎇ⓥേะߩዷᦸ㧘ᢙ୯⸃ᨆᚻᴺߩᲧセ㧔ࡌࡦ࠴ࡑ࡯ࠢ࠹ࠬ࠻㧕ߥߤࠍታᣉߒߡ㧘વᾲᢙ୯⸃ᨆߩ⎇ⓥߣታ↪ߩਔ㕙ߢߩ᥉෸ߦദ߼ࠄࠇ߹ߒߚ㧚వ↢ߪ࿖㓙⊛ߦ߽㧘ቇⴚ⹹ Numerical Heat Transfer ߩࠛ࠺ࠖ࠲࡯ࠍോ߼ࠄࠇࠆߥߤߒߡ㧘ߎߩಽ㊁ߢᜰዉ⊛ߥᓎഀࠍᨐߚߒߡ߅ࠄࠇ߹ߒߚ㧚߹ߚ㧘1988 ᐕߦߪ࿯ᣇవ↢ߣ౒⪺ߢ㧘‫ߊ⸃ߢࡦࠦ࠰ࡄޟ‬ᾲߣᵹࠇ ࡈࡠ࠶ࡇ࡯࠺ࠖࠬࠢઃ߈‫[ޠ‬1]ߣ޿߁ᄢᄌ࡙࠾
࡯ࠢߥᧄࠍ಴ ߐࠇ߹ߒߚ㧚ߎߩᧄߢߪ㧘ᓥ᧪ߩࠃ߁ߦᢙ୯⸃ᨆߩ⸘▚ᚻᴺࠍ⺑᣿ߔࠆߛߌߢߪߥ
ߊ㧘ࡊࡠࠣ࡜ࡓࠍࡈࡠ࠶ࡇ࡯࠺ࠖࠬࠢߦᦠ߈ㄟࠎ
ߢᷝઃߒ㧘ታ㓙ߦ⸘▚ࠍߒߡߺࠆߎߣ߇಴᧪ࠆࠃ
߁ߦߐࠇ߹ߒߚ㧚ߎߩᧄߪ㧘ᐢߊ↪޿ࠄࠇߚߛߌ
ߢߥߊ㧘ߘߩᓟᄙߊߩᦠ☋߇ߎߩࡈࡠ࠶ࡇ࡯ઃ߈
ߩࠬ࠲ࠗ࡞ࠍ୮޿߹ߒߚ㧚߅ੑੱ౒⪺ߩ࡙࠾࡯ࠢ

⑳߇ዊ┻ㅴవ↢ߩ⸔ႎࠍ߁߆߇ߞߚߩߪ㧘ߜࠂ߁ߤ㧘ߎߩ‫ޟ‬વᾲ‫ߩ⹹ޠ‬೨ภ㧔44 Ꮞ㧘189 ภ㧕ߦ㧘
TSE ߩวᧄ ߳ߩᓳᏫߦߟ޿ߡߩේⓂࠍḰ஻ߒߡ޿ߚ㗃ߢߒߚ㧚߹ߐߦ㧘ዊ┻వ↢߇ TSE ࠍ┙ߜ਄ߍࠄࠇߚࠅ㧘ߘߩ⊒ዷߦߏዧജߐࠇߚߎߣࠍᕁ޿಴ߒߡᢛℂߒߡ޿ߚᦨਛߢߒߚߩߢ㧘ߏ⸔ႎࠍુ
ߞߚߣߚࠎ㧘ߜࠂ߁ߤᧄቇળߩᄢ߈ߥᄌ㕟ᦼߦዊ┻వ↢ߩ߅ᚻવ޿ࠍߐߖߡ޿ߚߛ޿ߡ޿ߚ㗃ߩߎߣ߇㧘ᰴ‫ߣޘ‬㗡ߩਛߦᶋ߆߮߹ߒߚ㧚ᣣᧄવᾲቇળߦ߅޿ߡߪ㧘ዊ┻వ↢ߪ㧘ᤘ๺ 60
㨪61 ᐕᐲߦ޿ࠊࠁࠆ੐ോᜂᒰߩ೽ળ㐳ࠍ㧘ᐔᚑ 3ᐕᐲߦߪળ㐳ࠍ߅ോ߼ߦߥࠅ߹ߒߚ㧚ߎߩࠃ߁ߥ
㊀ⷐߥᓎ⡯ࠍ߅ോ߼ߦߥࠄࠇߎߣߣਗⴕߒߡ㧘ዊ┻వ↢ߩᧄቇળ߅ࠃ߮વᾲ⎇ⓥ߳ߩᄢ߈ߥߏഞ❣
ߪ㧘⑳ߩሽߓ਄ߍࠆ▸࿐ߢߪ㧘྾ߟ޽ࠆߣᕁ޿߹
ߔ㧚৻ߟ⋡ߪ㧘વᾲᢙ୯⸃ᨆߩ᥉෸㧘ੑߟ⋡ߪᧄቇળߩ␠࿅ᴺੱൻ㧘ਃߟ⋡ߪ⺰ᢥ㓸 TSE ߩ⊒ೀߣ⊒ዷ㧘྾ߟ⋡ߪේሶಽሶ㧔ࡒࠢࡠ㧕વᾲ⎇ⓥߩ┙ߜ਄ߍߣ᥉෸ߢߔ㧚ߎߩ߁ߜ㧘྾ߟ⋡ߩේሶಽሶ
વᾲ⎇ⓥߦߟ޿ߡᦠߊߎߣߪ㧘ߘߩಽ㊁ߢዊ┻వ↢ߩᢎ߃ࠍฃߌࠄࠇߚᣇ߇ߚߊߐࠎ߅ࠄࠇ߹ߔ߆
ࠄ㧘⑳ߩછߢߪ޽ࠅ߹ߖࠎߩߢ㧘ߎߎߢߪ㧘ઁߩਃߟߩ㗄⋡ߦߟ޿ߡ㧘ᦠ߆ߖߡ޿ߚߛ߈ߚ޿ߣሽ
ߓ߹ߔ㧚ߚߛ㧘⺰ᢥ㓸 TSE ߦ㑐ߒߡߪ㧘೨ภߦᦠ߆ߖߡ޿ߚߛ޿ߚߩߢ㧘ߎߩㇱಽߪ৻ㇱ㊀ⶄߔࠆߎߣࠍ߅⸵ߒਅߐ޿㧚⑳߇ᦨೋߦዊ┻వ↢ߦ߅⋡ߦ߆߆ߞߚߩߪ㧘ߪߞ߈ࠅߣߪⷡ߃ߡ޿߹ߖࠎ߇㧘વᾲᢙ୯⸃ᨆߦ㑐ߔࠆ⎇ⓥળࠍᣣᧄᯏ᪾ቇળߩᾲᎿቇㇱ㐷ߦ┙ߜ਄ߍࠃ߁ߣ޿߁ߣ߈ߢ㧘1985 ᐕ೨ᓟߢߒߚ㧚వ↢ߪ㧘ర᧪ߪ᧲੩ᄢቇ⥶ⓨቝቮ⎇ⓥᚲߩߏᚲዻߢߒߚ߇㧘ᒰᤨߪᡷ⚵ߦࠃߞߡᎿቇㇱ㒝ዻႺ⇇㗔ၞ⎇ⓥᣉ⸳
ߩߏᚲዻߢ޽ߞߚߣᕁ޿߹ߔ㧚ߘߩ㗃ߪ㧘ࠃ߁߿ߊ⎇ⓥ⠪߭ߣࠅ߭ߣࠅ߇ࡄ࠰ࠦࡦࠍᜬߞߡ⎇ⓥߔ
ࠆߎߣ߇಴᧪ࠆࠃ߁ߦߥࠅᆎ߼ߚᤨઍߢߒߚ㧚ᒰᤨߪ㧘ᢥᦠ૞ᚑߦߪࡢ࡯ࡊࡠኾ↪ᯏࠍ૶߁ߩ߇ㅢ

વᾲ 2006 ᐕ 1 ᦬-5-

J. HTSJ, Vol. 45, No. 190

ㅊᖬ㧦ዊ┻ ㅴ వ↢ઁᣇ㧘ቇળߣߒߡߩᵴേߪ㧘વᾲࠪࡦࡐࠫ࠙ࡓ
߿࿾ᣇᡰㇱᵴേࠍㅢߓߡ߻ࠈࠎᵴ⊒ߦⴕߞߡ޿߹
ߒߚ߇㧘⺰ᢥ㓸ࠍ⊒ⴕߒߡ޿ߥ޿ߎߣߪ㧘ቇળߣߒߡߪᄙዋᄌೣ⊛ߢ޽ࠅ߹ߒߚߩߢ㧘⺰ᢥ㓸ࠍ⊒ⴕߔࠆߎߣߣߒߡ㧘ߎߩઙߪ㧘࿯ᣇవ↢㧔᧲Ꮏᄢ㧕ߦߏᜂᒰࠍଐ㗬ߐࠇ߹ߒߚ㧚ߎߩࠃ߁ߦߒߡᧄቇ
ળߩ⺰ᢥ㓸 TSE ߇⊒⿷ߔࠆߎߣߦߥࠅ߹ߒߚ㧚ߎߩ⊒⿷ߩ੐ᖱߣߘߩᓟߩ⚻✲ߪ㧘೨ภ㧔44 Ꮞ㧘189
ภ㧕ߦ߿߿⹦ߒߊᦠ߆ߖߡ޿ߚߛ޿ߚߣ߅ࠅߢߔ㧚㧔ߘߩ⸥੐ߩਛߢ㧘TSE ⊒⿷ᒰᤨߩࠛ࠺ࠖ࠲࡯ߩ
߅৻ੱ߇㧘਻Ꮊᄢቇߩ⮮↰ᕶિవ↢ߢ޽ࠅ߹ߒߚ
ߩࠍ㧘หᆓߩ⮮↰వ↢㧔ฬᄢ㧕ߩ߅ฬ೨ࠍᦠ޿ߡ
߅ࠅ߹ߒߚ㧘߅ࠊ߮ߒߡ⸓ᱜߐߖߡ޿ߚߛ߈߹
ߔ㧚㧕ߎߩࠃ߁ߦߒߡ㧘TSE ߩ⺰ᢥౝኈ߿ᛩⓂⷙ⒟╬ߪ࿯ᣇవ↢߇ዊ┻వ↢ߣߏ⋧⺣ߐࠇߡᢛ஻ߐ
ࠇ㧘ዊ┻వ↢ߪ㧘㐳ᐕߦਗ਼ࠅ࠴࡯ࡈࠛ࠺ࠖ࠲࡯ߣ
ߒߡ TSE ߩ⛮⛯࡮⊒ዷߦਗ‫ߏߧࠄߥޘ‬ዧജࠍߐࠇ
߹ߒߚ㧚ߐߡ㧘ኻᢥㇱ⋭ߣߩ੤ᷤߦߟ޿ߡߪ㧘ዊ┻వ↢߇㧘⮮੗㧔ື㧕వ↢㧔਻ᄢ㧕ߦ߈ߞ߆ߌࠍ૞ߞߡ
޿ߚߛߎ߁ߣ߅ߞߒ߾ߞߡ㧘ᐔᚑ 4 ᐕߦ⮮੗వ↢ߣᒰᤨߩ⮮ᳯળ㐳ߣዊ┻వ↢ߣ⑳ߩ 4 ੱ߇ᢥㇱ⋭ߩᜂᒰ⺖ߩ⺖㐳ߦ᜿ᜦߦુ޿㧘ᚻ⛯߈ࠍ㐿ᆎߒ߹ߒߚ㧘ߘߩᓟߪ㧘⑳߇ᢥㇱ⋭ߩᜂᒰቭߩߣߎࠈߦ
૗ᐲ߽ુ޿ߥ߇ࠄ㧘વᾲቇߣߪ૗߆ߩ⺑᣿ࠍߒ㧘ቯ᱅╬ߩ᧦ઙࠍᰴ╙ߦᢛ߃߹ߒߚ㧚ઁᣇ㧘ᧄቇળ
ߩ․ᓽߢ޽ࠆ࿾ᣇᡰㇱߩᵴ⊒ߥᵴേࠍߐࠄߦዷ㐿ߢ߈ࠆ૕೙ࠍ㧘㐳㊁వ↢㧔ฬᎿᄢ㧕߿⧔Ỉవ↢㧔੩ᄢ㧕ߩߏදജࠍᓧߡᢛ஻ߒ߹ߒߚ㧚ߎߩࠃ߁ߥḰ஻ࠍ⚻ߡ㧘ᐔᚑ 6 ᐕߦᢥㇱ⋭ߩᜂᒰ⺖ߩౝ⻌ࠍᓧߡ㧘ᧅᏻߢⴕࠊࠇߚ✚ળߦ߅޿ߡ㧘␠࿅ᴺੱߦ⒖ⴕߒ߹ߒߚ㧚ߎߩ㑆㧘ዊ┻వ↢ߪ㧘⑳㆐ߩࠃ߁ߥ
ታ௛ㇱ㓌߇േ߈߿ߔ޿ࠃ߁ߦߟߨߦ⁁ᴫࠍᢛ߃ߡ
ਅߐ޿߹ߒߚ㧚ߎߩࠃ߁ߦᧄቇળߩ␠࿅ᴺੱൻߦߪ㧘ዊ┻వ↢
ߩߏ⽸₂߇㕖Ᏹߦᄢ߈޿ߩߢߔ߇㧘ᴺੱൻᓟߩᧄ
ቇળߩᵴേߦߟ޿ߡߪ㧘ዊ┻వ↢ߪ㧘߻ߒࠈ෩ߒ
޿⋡ߢߏⷩߦߥߞߡ޿߹ߒߚ㧚ߚߣ߃߫㧘ቇળഃ┙ 40 ๟ᐕࠍ⸥ᔨߒߚ‫ޟ‬વᾲ‫ߩ⹹ޠ‬ᱧઍળ㐳․㓸[2]ߦ㧘‫ߣ߽ߣ߽ޟ‬ᴺੱ߳ߩ⒖ⴕߪ㧘વᾲߣ޿߁⎇ⓥಽ
㊁߽৻ᔕ⺰ℂ૕♽߇ᢛߞߡ߈ߚߩߢ㧘ߎߩㄝߢ੹
߹ߢߩ⥄↱᳇ᭉߥ⎇ⓥળߩ․ᓽࠍ⛽ᜬߒߥ߇ࠄ㧘⎇ⓥ⚿ᨐߣᵴേߩ౏⊛ൻࠍߪ߆ߞߡ߽޿޿ߩߢߪ
ߥ޿߆ߣ޿߁ߎߣࠍਥᣦߣߒߡ޿ࠆ㧚ߒ߆ߒ㧘৻ߥᦠ☋ߪઁߦ߽޽ࠅ߹ߔ߇㧘ߎߩ߅ੑੱ౒߇᡿ੱ
ߦߥߞߡߒ߹ࠊࠇ߹ߒߚ㧚ᣣᧄવᾲቇળߪ㧘ᤘ๺ 37 ᐕ㧔1962 ᐕ㧕ߦᣣᧄવᾲ⎇ⓥળߣߒߡ⊒⿷ߒ߹ߒߚ㧚ᒰೋߪ㧘ቇળߢߪߥߊᲧセ⊛ዊߐߥ⎇ⓥ㓸࿅ߣߒߡ㧘⥄↱ߥ㔓࿐᳇ߢߩ⎇ⓥળᵴേࠍߘߩ⋡ᮡߣ․ᓽߣߒߡ޿߹ߒ
ߚ㧚ߘߩᓟ㧘વᾲቇ߇ၮ␆ࠍࠃࠅᒝ࿕ߦߒߡቇ໧
ߣߒߡ߽⊒ዷߔࠆߣหᤨߦ㧘ᚒ߇࿖ߩ↥ᬺⷙᮨߩ᜛ᄢ㧘ฦ⒳ߩᛛⴚ㕟ᣂ㧘⋭ࠛࡀ࡞ࠡ࡯ߩ㊀ⷐᕈ᜛ᄢߦᡰ߃ࠄࠇߡ㧘વᾲ⎇ⓥળߩᵴേ▸࿐߿ળຬᢙ
߽ᄢ߈ߊჇടߒ߹ߒߚ㧚 ߘߩߚ߼㧘વᾲ⎇ⓥળࠍ
౏⹺ߐࠇߚ␠࿅ᴺੱൻߔߴ߈߆ߤ߁߆ߩ⼏⺰ߪ㧘㐳ᐕߦਗ਼ࠅ૗ᐲ߆‫ޟ‬ᴺੱൻᆔຬળ‫╬ࠆߔ⟎⸳ࠍޠ‬ߒߡክ⼏ߐࠇߡ߈߹ߒߚ㧚ߒ߆ߒ㧘ᴺੱൻࠍߔࠆ
ߦ߽ߎߩ߹߹ߩ⁁ᘒߦ߽౒ߦ೑ኂᓧᄬ߇޽ࠆ㧘ߣ޿߁ࠃ߁ߥ⚿⺰ߩ߹߹ߢ㧘߆ߥࠅߩᐕᢙ߇⚻ㆊߒߡ߅ࠅ߹ߒߚ㧚ߎࠇߦߟ޿ߡ㧘߹ߕ╙ 29 ᦼߩ⍹㤥ળ㐳ߩᤨઍߦ㧘ฬ⒓ࠍ⎇ⓥળ߆ࠄᣣᧄવᾲቇળߦᄌᦝߒ߹ߒߚ㧚ߐࠄߦ㧘ߎࠇߦ⚿⺰ࠍ಴ߘ߁ߣߐࠇߚߩ߇㧘╙ 30ઍߩળ㐳ߦߥࠄࠇߚዊ┻వ↢ߢߒߚ㧚⑳߇ߎߩઙߢᦨೋߦዊ┻వ↢ߦ๭߫ࠇߚߩߪ㧘ߏછᦼਛߩ޿
ߟ㗃ߛߞߚ߆ߪࠃߊⷡ߃ߡ޿߹ߖࠎ߇㧘޿߹ߢ߽⦟ߊ߅߷߃ߡ޿߹ߔߎߣߪ㧘ዊ┻వ↢߇‫ޟ‬વᾲቇ
ળߩᴺੱൻߩ໧㗴ߪ㧘ᬌ⸛ߐࠇߥ߇ࠄ㐳ᐕ߇⚻ㆊߒߡ޿ࠆߩߢ㧘૗ߣ߆ߒߚ޿ߣᕁ߁‫ޠ‬㧘ߣ߅ߞߒ߾
޿߹ߒߚߩߢ㧘⑳߇‫ޟ‬ᆔຬળࠍ߽߁৻ᐲ૞ߞߡ੹
ᐲߪ⚿⺰ࠍ಴ߒߡ߽ࠄ޿߹ߒࠂ߁߆‫ޠ‬㧘ߣ↳ߒ਄ߍߚߣߎࠈ㧘‫߿޿ޟ‬㧘ᬌ⸛ᆔຬળߢߪߥࠎߤ߽ክ⼏ߒߡ߽ࠄߞߚߩߢ㧘߽߁ߤߜࠄ߆ߦ᳿߼ߥ޿ߣ޿ߌ
ߥ޿㧚ᴺੱൻߔࠆߣ޿߁ᣇะߢㅴ߼ߚ޿‫ߞ߅ߣޠ‬ߒ߾޿߹ߒߚ㧚ߟ޿ߡߪ㧘⎇ⓥᚲൕോᤨઍߦડ↹ቶߢኻቭᐡߩ઀੐ࠍ⚻㛎ߒߡ޿ߚ⑳߇ᢥㇱ⋭ߣߩ੤ᷤࠍਛᔃߣߔࠆታോࠍᜂᒰߔࠆࠃ߁ߦߣ๮ߓࠄ
ࠇ߹ߒߚ㧚ߘߎߢቇળߩᴺੱൻߩ᧦ઙࠍߑߞߣ⺞ߴ߹ߒߚߣߎࠈ㧘޿ࠊࠁࠆ౏⹺࿅૕ߣߒߡ⹺นߐࠇࠆ᧦ઙ
ߣ޿߁ߩߪ㧘(1)ቇⴚ࿅૕ߣߒߡᵴ⊒ߦᵴേߒߡ޿
ࠆߎߣ㧘(2)৻ቯᢙએ਄ߩળຬᢙࠍ᦭ߔࠆߎߣ㧘(3)ᵴേࠍ⵬ఘߢ߈ࠆ৻ቯߩ⾗↥ࠍ଻᦭ߔࠆߎߣ㧘╬ߢ޽ࠅ߹ߒߚ㧚ߎࠇࠄߩ߁ߜ㧘ળຬᢙߪචಽḩߚߒߡ߅ࠅ㧘ၮ㊄ߦߟ޿ߡ߽޽ࠆ⒟ᐲߩ஻⫾߇޽ࠅ߹ߒߚ߇㧘ળຬฦ૏ߩ൐㊄ߦࠃࠆߏදജࠍ޿ߚߛ
߈㧘ⷐઙࠍḩߚߔߎߣ߇ߢ߈߹ߒߚ㧚વᾲ 2006 ᐕ 1 ᦬-6-

J. HTSJ, Vol. 45, No. 190

ㅊᖬ㧦ዊ┻ ㅴ వ↢ߥ߇ࠄ㧘߅ੑੱߢ㧘‫ޟ‬᳗㆙ߩ਎⇇ߦ߅ߌࠆࠛࡦ࠻ࡠ
ࡇ࡯ߣࠛࠢ࠮࡞ࠡ࡯‫⎇ߏ߁޿ߣߤߥޠ‬ⓥࠍᆎ߼ߡ߅ࠄࠇࠆ߆߽⍮ࠇ߹ߖࠎ㧚
⑳߇ߎࠎߥ⸥੐ࠍᦠ޿ߡ޿ࠆߩࠍߏⷩߦߥߞߚ
ࠄ㧘ዊ┻వ↢ߪ߈ߞߣ㧘‫ޟ‬ᴡ᧛ߐࠎ㧘߷ߊߪ㧘ߘࠎߥߎߣࠍ޿ࠈ޿ࠈᦠ߆ࠇࠆߩߪᅢ߈ߓ߾ߥ޿ࠎߛ
ߌߤߨ㧚╙৻㧘ߘࠎߥ⸥੐ࠍᦠ޿ߡ߽⺕߽⺒߹ߥ޿߆ࠄ㧘ߘߩᤨ㑆ߢ㧘⦟޿⺰ᢥࠍᦠ߈ߥߐ޿㧚‫ߣޠ‬߅ߞߒ߾ࠆߢߒࠂ߁㧚ߢ߽ዊ┻వ↢㧘వ↢߇➅ࠅ㄰ߒ߅ߞߒ߾ߞߡ᧪ߚߎߣࠍ⸥㍳ߦᱷߔߩߪ㧘ߣߡ߽ᄢಾߥߎߣߥߩߢߔ㧚ੱߩ๮ߪ᦭㒢ߢߔ㧚ߒ߆ߒ㧘ߘߩੱߩ⺆ߞߚ⸒⪲ߪ㧘ᱷߐࠇߚੱ‫ߩޘ‬ਛߦᱷࠅ⛯ߌ߹ߔ㧚వ↢ߩ㡆ࠄߐࠇߚ޿ߊߟ߽ߩ㍈
޿⼊㏹ߪ㧘⺆ࠄࠇߚ߅⸒⪲߿‫ޟ‬વᾲ‫⸥ߩ⹹ޠ‬੐ࠍㅢߒߡ㧘޿ߟ߹ߢ߽ᚒ‫ߩޘ‬ቇળߦᱷࠅ⛯ߌ߹ߔ㧚ߘߒߡ᛬ߦ⸅ࠇߡᕁ޿಴ߐࠇߡ㧘ߎߩቇળߩ޽ࠅ
ᣇߣㅴ߻ߴ߈ᣇะߩ㆏ߒࠆߴߣߥࠅ⛯ߌࠆߢߒࠂ
߁㧚ߎߩࠃ߁ߥㅊᖬᢥߩ✦߼ߊߊࠅߪ㧘቟ࠄ߆ߦ߅
ભߺਅߐ޿ߣ⸒߁ߩ߇Ᏹᅃฏߢߔ߇㧘ዊ┻వ↢ߦߪ㧘ోߊ⋧ᔕߒߊ޽ࠅ߹ߖࠎ㧚ዊ┻వ↢㧘ᣂߒ޿਎⇇ߢ⥄↱ࠍ⻭᱌ߥߐߞߡ㧘߹ߔ߹ߔᣂߒ޿ಽ㊁ߦߏ᜸ᚢਅߐ޿㧚వ↢ߪ㧘߈ߞߣߔߢߦ㧘߽߁৻ߟߩ࡜ࠗࡈࡢ࡯ࠢ[5]ߢ޽ߞߚ̌⟤ߣᗵᕈ̍߿㧘޽ࠆ޿ߪ߽ߞߣ㕙⊕޿࠹࡯ࡑߦ㧘ᣂߒ޿࠴ࡖ࡟ࡦࠫ
ࠍᆎ߼ߡ߅ࠄࠇࠆߎߣߢߒࠂ߁㧚ว᝿㧚ෳ⠨ᢥ₂
[1] ዊ┻ ㅴ㧘࿯ᣇ㇌ᄦ㧘ࡄ࠰ࠦࡦߢ⸃ߊᾲߣᵹࠇ ࡈࡠ࠶ࡇ࡯࠺ࠖࠬࠢઃ߈㧘ਣༀ಴ (1988).

ᣤᒻ߇಴᧪ࠆߣߤ߁ߒߡ߽ᒻߘߩ߽ߩࠍ⛽ᜬߔࠆߩߦജ߇౉ࠅ߇ߜߢ޽ࠆ߇㧘޽ߊ߹ߢ߽ᧄ⾰ߪਛりߢ޽ߞߡ㧘ਛり߇ߥߊߥࠇ߫ᒻߪუߖ߫ࠃ޿ߣ
੔߁ᨵエߥ⊒ᗐ߆ࠄ಴⊒ߒߡ޿ࠆ㧔৻ㇱ⇛㧕㧚‫ߣޠ‬ᦠ޿ߡ߅ࠄࠇ߹ߔ㧚ߎߩࠃ߁ߦ㧘ዊ┻వ↢ߪ㧘ᒻᑼߦߩߺᵹߐࠇࠆߎߣߥߊ㧘ቇળߣߒߡߩౝኈࠍ
లታߐߖࠆߎߣ߇㊀ⷐߢ޽ࠆߎߣࠍ㧘➅ࠅ㄰ߒ⺑޿ߡ᧪ࠄࠇ߹ߒߚ㧚ߎࠇએᄖߦ߽㧘ዊ┻వ↢ߩቇળ߿ቇ໧ߩ޽ࠅᣇ
ߦ㑐ߔࠆ㍈޿߅⸒⪲ߪ㧘ᢙᄙߊ‫ޟ‬વᾲ‫ߦ⹹ޠ‬ᱷߐࠇߡ޿߹ߔ㧚ߚߣ߃߫㧘ቇળߩᒻᑼࠍ଻ߟߚ߼ߛ
ߌߩળ⼏ߦᤨ㑆ࠍ⾌߿ߔߴ߈ߢߥ޿ߎߣ㧘ቇળ⹹ߦᒻᑼ⊛ߥᢥ┨ࠍᦠߊߊࠄ޿ߥࠄౝኈ޽ࠆቇⴚ⺰ᢥࠍᦠߊߴ߈ߎߣ㧘ቇળߢߪߟߨߦ⌀೶ߥቇ໧⊛ߥ⼏⺰ࠍᚢࠊߔߴ߈ߎߣ㧘ౝኈߩ઻ࠊߥ޿ቇળߦ
ߪሽ࿷ᗧ⟵ߪߥ޿╬ߢߔ㧚ߎࠇࠄࠍઍࠊߞߡ߅વ
߃ߢ߈ࠆജߪ㧘⑳ߦߪ೔ᐩ޽ࠅ߹ߖࠎߩߢ㧘వ↢߇߅ᦠ߈ߦߥߞߚ⸥੐㧘ߚߣ߃߫㧘೨ㅀߩᱧઍળ
㐳․㓸[2]߿㧘̌‫ޟ‬વᾲ⎇ⓥ‫ޟߣޠ‬TSE‫ޠ‬̍[3]ࠍߗ߭
⋥ធߦ߅⺒ߺ޿ߚߛ߈ߚ޿ߣᕁ޿߹ߔ㧚ߎࠇࠄߩ⸥੐ߩ޿ߕࠇ߽߇㧘ቇળߣવᾲቇߦኻߔࠆ㍈޿⼊㏹ߢ㧘߹ߐߦᣥ⚂⡛ᦠߩ㗍⸒⠪ߩ⸒⪲ߩࠃ߁ߢ޽ࠅ߹ߔ㧚ዊ┻వ↢߇߅੢ߊߥࠅߦߥߞߡ㧘ቇળ߿⎇ⓥᵴേߩ┙႐߆ࠄߎߩࠃ߁ߥㅊᖬ⸥੐ࠍᦠߊᦨㆡછ⠪ߪ㧘ߓߟߪ㧘㑆㆑޿ߥߊ㧔᡿㧕࿯ᣇ㇌ᄦవ↢㧔᧲Ꮏᄢ㧕ߢ޽ࠅ߹ߔ㧚ߒ߆ߒ㧘࿯ᣇవ↢ߪ㧘㗅ᐨࠍㅒߦߒߡ㧘వߦㅤߞߡߒ߹ࠊࠇ߹ߒߚ㧚ߘߩߚ߼㧘ㅒߦዊ┻వ↢߇㧘࿯ᣇవ↢ߩㅊᖬᢥࠍᦠ޿ߡ߅ࠄ
ࠇ߹ߔ[4㨉㧚ߘߎߦߪ㧘࿯ᣇవ↢ߦኻߔࠆା㗬ߣᢘᗲߩ߅᳇ᜬߜ߇ᥦ߆ߊߦߓߺ಴ߡ޿߹ߔ㧚 ዊ┻వ↢ߩឝߍࠄࠇߚߎߣߪ㧘ߟߨߦᔒ߽⋡ᮡ߽㕖Ᏹߦ㜞ߊ㧘߈߮ߒ޿߽ߩߢ޽ࠅ߹ߒߚ㧚ߘࠇࠍ㧘ᚒ‫߽ߦޘ‬ታⴕน⢻ߥᒻߦࠕ࡟ࡦࠫߒߡታ⃻ߐࠇߚߩ߇࿯ᣇవ↢ߢߒߚ㧚࿯ᣇవ↢ߪ㧘ዊ┻వ↢ߩᦨᒝߩࠨࡐ࡯࠲࡯ߢ޽ࠅ㧘߆ߟᦨ⦟ߩࡄ࡯࠻࠽
࡯ߢ޽ࠅ߹ߒߚ㧚޿߹㧚߅ੑੱߪౣ߮౵⇇ࠍ౒ߦߒߡ߅ࠄࠇ߹ߔ㧚࿯ᣇవ↢߇㧘‫ޟ‬ዊ┻ߐࠎ㧘ߎߎߢߪ߷ߊ߇ዋߒవヘߢߔ߆ࠄߨ‫ޠ‬㧘ߥߤߣ߅ߞߒ߾ࠅ

વᾲ 2006 ᐕ 1 ᦬[2] ᱧઍળ㐳․㓸ภ㧘╙ 30 ᦼዊ┻ㅴవ↢㧘વᾲ㧘
41-168, (2002) 32.
[3] ዊ┻ ㅴ㧘‫ޟ‬વᾲ⎇ⓥ‫ޟߣޠ‬TSE‫ޠ‬㧘વᾲ⎇ⓥ㧘
37-146, (1998) 68-69.
[4] ዊ┻ ㅴ㧘‫ޟ‬࿯ᣇ‫ޠ‬વᾲ⎇ⓥߩ዁᧪௝㧘વᾲ⎇ⓥ㧘36-142, (1997) 90-91.
[5] ዊ┻ ㅴ㧘ᗵᕈᎿቇߩၮ␆㧘⟤ߣࠛࡦ࠻ࡠࡇ
࡯㧘ਣༀ಴  (2005).

-7-

J. HTSJ, Vol. 45, No. 190

․㓸㧦ๆ⌕ߩ਎⇇̆ࡒࠢࡠ߆ࠄࡑࠢࡠ㧘ߘߒߡࠪࠬ࠹ࡓ̆

ๆ⌕ࡅ࡯࠻ࡐࡦࡊ↪ᯏ⢻ᕈๆ⌕᧚ߩ㐿⊒Development of Functional Adsorbent Material for Adsorption Heat Pump






ਅጟ ㉿⟤㧘ᄢፉ ৻ౖ㧘ᱞ⣁ 㓉ᒾ㧘၂ౝ ඳⴕ㧔㧔ᩣ㧕ਃ⪉ൻቇ⑼ቇᛛⴚ⎇ⓥ࠮ࡦ࠲࡯*㧕
Satomi SHIMOOKA, Kazunori OSHIMA, Takahiko TAKEWAKI, Hiroyuki KAKIUCHI(Mitsubishi Chemical Group Science and Technology Research Center*)e-mail: 3803594@cc.m-kagaku.co.jp (၂ౝ)
ᐲ ĳ2 ߪಝ❗ེ᷷ᐲ TM ߣๆ⌕ེ᷷ᐲ TH ߆ࠄ᳿߹ࠆ㧚ߎߩ㑐ଥࠍᑼ(1)߅ࠃ߮ᑼ(2)ߦ␜ߔ‫ᤨߩߎޕ‬㧘ๆ⌕ᤨߣ⣕⌕ᤨߩ⋧ኻḨᐲߩᏅ ǻĳ ߇ๆ⌕ࡅ࡯࠻ࡐࡦࡊߩㆇォ▸࿐ࠍ␜ߒ㧘ๆ⌕ᤨߣ⣕⌕ᤨߩๆ⌕㊂ߩᏅ ǻQ ߇ๆ⌕ࡅ࡯࠻ࡐࡦࡊߩᄢ߈ߐࠍ᳿߼ࠆ
ⷐ⚛ߣߥࠆ㧚ዊߐ޿ ǻĳ ߢ߽㧘ᄢ߈ߥ ǻQ ߇ᓧࠄࠇࠆๆ⌕᧚߇ᅢ߹ߒ޿㧚ߪߓ߼ߦ
࿾⃿᷷ᥦൻࠟࠬߩឃ಴ᛥ೙߿ᦝߥࠆ⋭ࠛࡀ࡞ࠡ࡯ࠍ⋡⊛ߣߒߡ㧘ࠦࠫࠚࡀ࡟࡯࡚ࠪࡦ㧘Άᢱ㔚ᳰ㧘⥄േゞ㧘ᄥ㓁᷷᳓ེߥߤߢᓧࠄࠇࠆ 363K એਅߩૐ᷷ឃᾲߩ᦭ല೑↪߇ᒝߊ᳞߼ࠄࠇߡ޿ࠆ㧚ឃᾲ೑↪ᯏེߣߒߡๆ෼ᑼࡅ࡯࠻ࡐࡦࡊ߇ታ↪ൻߐࠇߡਭߒ޿߇㧘ๆ෼ᑼࡅ࡯࠻ࡐࡦࡊߩല₸߇ૐਅߒᆎ߼ࠆ 358K એਅߩឃᾲ೑↪߿㧘⥄േゞߥߤ
ߩ⒖േ૕ߦߪๆ⌕ࡅ࡯࠻ࡐࡦࡊ߇ㆡߒߡ޿ࠆߣ⠨߃ࠄࠇࠆ㧚ࠪ࡝ࠞࠥ࡞ࠍ↪޿ߚๆ⌕ࡅ࡯࠻ࡐࡦࡊ
ߪ 1920 ᐕઍᓟඨߦၮᧄ᭎ᔨ߇ឭ᩺ߐࠇ㨇1㨉
㧘1980ᐕᓟඨ߆ࠄ໡ຠൻߐࠇߡ޿ࠆ㨇2,3㨉㧚ߒ߆ߒߥ߇
ࠄ㧘ๆ෼ᑼࡅ࡯࠻ࡐࡦࡊߦᲧߴⵝ⟎߇ᄢ߈޿㧘ଔᩰ߇㜞޿ߥߤߩℂ↱ߩߚ߼߆ᐢߊ᥉෸ߒߡ޿ࠆߣ
ߪ⸒߃ߥ޿⁁ᴫߢ޽ࠆ㧚ๆ⌕ࡅ࡯࠻ࡐࡦࡊ߇ᐢߊ᥉෸ߔࠆߦߪ㧘Ԙๆ⌕ࡅ࡯࠻ࡐࡦࡊߩㆇォ▸࿐ߢᄢ߈ߥๆ⌕ኈ㊂Ꮕ߇ᓧࠄࠇࠆᣂⷙๆ⌕᧚㧘ԙᾲ㨯‛⾰⒖േ․ᕈߦఝࠇߚᾲ
੤឵ེ㧘ߩ㐿⊒߇ਇนᰳߣ⠨߃ࠆ㧚ߘߎߢ㧘ᚒ‫ޘ‬ߪๆ⌕ࡅ࡯࠻ࡐࡦࡊߩㆇォ⋧ኻḨᐲ▸࿐ߢๆ⣕⌕ߒ㧘߆ߟ⁜޿Ḩᐲ▸࿐ߢๆ⌕㊂߇ᄢ߈ߊᄌൻߔࠆ
ᣂߒ޿ๆ⌕᧚ߩ㐿⊒ߦขࠅ⚵ࠎߛ㧚ᧄⓂߢߪ㧘㐿⊒ ߦ ᚑ ഞ ߒ ߚ ᯏ ⢻ ᕈ ๆ ⌕ ᧚ FAM(Functional
Adsorbent Material)ߩ․ᓽ߅ࠃ߮ๆ⌕ࡅ࡯࠻ࡐࡦ
ࡊߦㆡᔕߒߚ႐วߩዊဳൻߩน⢻ᕈߥߤߦߟ޿ߡ
᭎⺑ߔࠆ㧚

⣕⌕ㆊ⒟

TM

TM

TL

ๆ⌕ㆊ⒟

a) ๆ⌕䊍䊷䊃䊘䊮䊒䈱ේℂ࿑
㊄ᴛᄢቇᄢቇ㒮 ᳹↰ᐙᄦഥᢎ᝼ 䈗ឭଏ

ๆ⌕╬᷷✢
ๆ⌕᷷ᐲ
ᐔⴧๆ⌕㊂kg/kg

ๆ⌕᷷ᐲTMๆ⌕ࡅ࡯࠻ࡐࡦࡊߩේℂ಄ᾲ↢ᚑࡕ࡯࠼ߩๆ⌕ࡅ࡯࠻ࡐࡦࡊߩേ૞ේ
ℂࠍ࿑ 1 ߦ␜ߔ㧚ๆ⌕ࡅ࡯࠻ࡐࡦࡊߪ㧘ዋߥߊߣ߽ๆ⌕᧚߇లႯߐࠇߚๆ⌕ེ㧘⫳⊒ེ㧘ಝ❗ེ߆ࠄߥࠅ㧘ᠲ૞⋧ኻḨᐲ▸࿐ߪ TL㧦಄ᾲ᷷ᐲ㧘TM㧦
ਛ㑆᷷ᐲ㧘TH㧦ౣ↢᷷ᐲߩ 3 ⒳㘃ߩ᷷ᐲ߆ࠄ᳿ቯ
ߐࠇࠆ㧚ๆ⌕ㆊ⒟ߩ⋧ኻḨᐲ ĳ1 ߪ⫳⊒ེ᷷ᐲ TLߣๆ⌕ེ᷷ᐲ TM ߆ࠄ᳿߹ࠅ㧘⣕⌕ㆊ⒟ߩ⋧ኻḨ

વᾲ 2006 ᐕ 1 ᦬

TH

䂦䌑
䇭䇭

⣕⌕᷷ᐲTH⣕⌕᷷ᐲๆ⌕䊍䊷䊃䊘䊮䊒䈱ᄢ䈐䈘䉕᳿䉄䉎ⷐ⚛
䂦㱂
䇭䇭

㱂䋲

ๆ⌕䊍䊷䊃䊘䊮䊒䈱ㆇォ᧦ઙ䉕᳿䉄䉎ⷐ⚛
㱂䋱

⋧ኻḨᐲ

b) ๆ⣕⌕╬᷷✢䈫ๆ⣕⌕ᠲ૞▸࿐䈱㑐ଥ࿑ a)ๆ⌕ࡅ࡯࠻ࡐࡦࡊߩේℂ࿑߅ࠃ߮ b)ๆ⣕⌕╬᷷✢ߣๆ⣕⌕ᠲ૞▸࿐ߩ㑐ଥ

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․㓸㧦ๆ⌕ߩ਎⇇̆ࡒࠢࡠ߆ࠄࡑࠢࡠ㧘ߘߒߡࠪࠬ࠹ࡓ̆

ĳ1㧩⫳⊒ེ᷷ᐲ㨀㧸ߩ㘻๺⫳᳇࿶ (1)ๆ⌕ེ᷷ᐲ㨀㧹ߩ㘻๺⫳᳇࿶

ĳ2㧩ಝ❗ེ᷷ᐲ㨀㧹ߩ㘻๺⫳᳇࿶ (2)ๆ⌕ེ᷷ᐲ㨀㧴ߩ㘻๺⫳᳇࿶࠻߶ߤᒝ޿ⷫ᳓ᕈߢߪߥ޿᧚ᢱࠍ㐿⊒ߔࠇ߫ࠃ޿
ߎߣ߇ࠊ߆ࠆ㧚╩⠪ࠄߪߎߩⷐ᳞․ᕈࠍḩߚߔ᧚ᢱߣߒߡࠕ࡞ࡒࡁࡈࠜࠬࡈࠚ࡯࠻♽࠯ࠝ࡜ࠗ࠻ߦ
⌕⋡ߒ㧘ᯏ⢻ᕈๆ⌕᧚ FAM ߣ⒓ߔࠆᣂⷙๆ⌕᧚ࠍ㐿⊒ߒߚ㧚ᯏ⢻ᕈๆ⌕᧚ FAM ߩ․ᓽ ၮᧄ‛ᕈᯏ⢻ᕈๆ⌕᧚ FAM-Z01 ߪ 0.73nm ߩ⚦ሹᓘࠍ᦭ߔࠆ AFI ဳࡕ࡟ࠠࡘ࡜࡯ࠪ࡯ࡉߢ޽ࠅ㧘ߘߩ㛽ᩰߪ ㉄ ൻ ࠕ ࡞ ࡒ ߣ ῂ ㉄ ߣ ㉄ ൻ ㋕ ߆ ࠄ ߥ ࠆ 㨇 8㨉㧚
FAM-Z02 ߪ 0.38nm ߩ⚦ሹᓘࠍ᦭ߔࠆ CHA ဳࡕ࡟ࠠࡘ࡜࡯ࠪ࡯ࡉߢ޽ࠅ㧘ߘߩ㛽ᩰߪ㉄ൻࠕ࡞ࡒߣ
ῂ㉄ߣࠪ࡝ࠞ߆ࠄߥࠆ㨇9㨉㧚㧲㧭㧹ߩၮᧄ․ᕈࠍ
⴫ 1 ߦ␜ߔ㧚᳞߼ࠄࠇࠆๆ⌕᧚ߩ․ᕈ
᳓㧙ࠪ࡝ࠞࠥ࡞㨇4㨉㧘᳓㧙࠯ࠝ࡜ࠗ࠻㨇5㨉㧘᳓㧙ᵴᕈ὇㨇6㨉㧘ࠛ࠲ࡁ࡯࡞㧙ᵴᕈ὇㨇7㨉ߥߤ߇ๆ⌕ࡅ࡯࠻ࡐࡦࡊߩๆ⌕⾰߅ࠃ߮ๆ⌕᧚ߩ⚵ߺวࠊߖߣߒߡ⍮ࠄࠇߡ޿ࠆ㧚╩⠪ࠄߪ㧘⫳⊒ẜᾲ㊂߇ᄢ߈޿ߎߣ߅ࠃ߮቟ଔ㧘቟ోߢ޽ࠆߎߣ߆ࠄ᳓ࠍ
ๆ⌕⾰ߣߒߡㆬࠎߛ㧚ઍ⴫⊛ߥๆ⌕᧚ߩๆ⌕╬᷷✢ߣๆ⌕⁁ᘒࠍ࿑  ߦᮨᑼ⊛ߦ␜ߔ㧚

⴫1 FAM-Z01FAM-Z02 ߩၮ␆‛ᕈ᳞䉄䉌䉏䉎ๆ⌕᧚ 䉲䊥䉦䉭䊦䍜䍼䍓䍵䍐䍢䋨ᒝⷫ᳓ᕈ䋩
H2O

H2O

H2O

H2O
H2O

㪝㪘㪤㪄㪱㪇㪈䉷䉥䊤䉟䊃ๆ⌕㊂䍚䍶䍔䍗䍼䍷䋨ⷫ᳓ᕈ䋩
H2O
H2O H2O

ᵴᕈ὇⋧ኻḨᐲૐ䈇⋧ኻḨᐲ䈪⁜䈇ᠲ૞▸࿐

H2O

H2O

Bulk density
Particle size (typical)

kg䍃dm
ȝm

Thermal conductivityW䍃m-1䍃K-1

H2O
H2O H2O H2O

Differential heat ofkJ䍃mol-1
adsorption(H2O, 298 K)

ᵴᕈ὇䋨⇹᳓ᕈ䋩Specific heat

H2O

H2O H2O
H2O
H2O H2O
H2O

ᒝๆ⌕᳓

H2O

ᒙๆ⌕᳓

0.6-0.7
0.6-0.7
5-2,000
5-2,000
0.113(303 K) 0.117(303 K)
0.123(343 K) 0.128(363 K)
56.0

kJ䍃kg-1䍃K-1㪝㪘㪤㪄㪱㪇㪉

58.8

0.805(303 K) 0.822(303 K)
0.896(343 K) 0.942(363 K) 㩷㩷 ๆ⌕․ᕈ
FAM-Z01,FAM-Z02 ߅ࠃ߮ઁߩๆ⌕᧚ߩ - ߩ᳓⫳᳇ๆ⌕╬᷷✢ࠍ࿑ 3 ߦ␜ߔ㧚᳓⫳᳇ๆ⌕╬᷷✢߅ࠃ߮᳓⫳᳇⣕⌕╬᷷✢ߪኈ㊂ᴺ᳓⫳᳇ๆ⌕㊂᷹ቯⵝ⟎㧔Belsorp18㧘ᣣᧄࡌ࡞㧔ᩣ㧕㧕߅ࠃ߮⏛᳇ᶋㆆᑼᄤ⒊㧔࡞ࡏࠨ࡯ࡓ㧔ᩣ㧕㧕ࠍ↪޿ߚ㊀㊂ᴺ⫳᳇ๆ⌕㊂᷹ቯⵝ⟎㧔ਃ⪉ൻቇ㧔ᩣ㧕㧕ࠍ↪޿ߡ᷹ቯߒߚ㧚ᓥ᧪ߩๆ⌕᧚ߣߒߡ㧘FAU ဳࠕ࡞ࡒࡁࠪ
࡝ࠤ࡯࠻㧔⸅ᇦൻᚑᎿᬺ␠⵾㧕㧘A ဳࠪ࡝ࠞࠥ࡞㧔ን჻ࠪ࡝ࠪࠕൻቇ␠⵾㧕㧘ࡗࠪᲖᵴᕈ὇㧔ਃ⪉ൻቇࠞ࡞ࠧࡦ␠⵾㧕ࠍ↪޿ߚ㧚࿑ 3 ࠃࠅ FAM-Z01㧘
FAM-Z02 ߩ᳓⫳᳇ๆ⌕╬᷷✢ߪᓥ᧪ߩๆ⌕᧚ߣᄢ߈ߊ⇣ߥࠅ㧘ૐ޿⋧ኻḨᐲઃㄭߢߪ߶ߣࠎߤ᳓
⫳᳇ࠍๆ⌕ߖߕ㧘ዋߒ⋧ኻḨᐲ߇㜞ߊߥࠆߣᕆỗߦ᳓⫳᳇ࠍๆ⌕ߒᆎ߼ࠆߎߣ߇್ࠆ㧚FAM ߩ᳓⫳᳇ๆ⌕╬᷷✢ߪ S ሼᦛ✢ߩ᭽ߢ޽ࠅ㧘᳞߼ࠄࠇࠆ
ๆ⌕᧚ߦ㕖Ᏹߦㄭ޿ๆ⌕․ᕈࠍ᦭ߔࠆߎߣ߇ࠊ߆ࠆ㧚

࿑ 2 ઍ⴫⊛ߥๆ⌕᧚ߣๆ⌕⁁ᘒߩᮨᑼ࿑
࠯ࠝ࡜ࠗ࠻㧔ࠕ࡞ࡒࡁࠪ࡝ࠤ࡯࠻㧕ߪဋ৻ߢዊ
ߐ޿⚦ሹߢ޽ࠆ߇ᒝⷫ᳓ᕈߢ޽ࠆߚ߼㧘ૐ޿⋧ኻḨᐲߢ᳓⫳᳇ࠍๆ⌕ߔࠆ߇㧘ๆ⌕ജ߇ᒝ޿ߚ߼⣕⌕ߐߖࠆߦߪ 373K એ਄㧘ᅢ߹ߒߊߪ 473K એ਄߇ᔅⷐߣ⠨߃ࠄࠇࠆ㧚ࠪ࡝ࠞࠥ࡞ߪ᏷ᐢ޿ᄢ߈ߐߩ
⚦ሹࠍᜬߜ㧘⴫㕙ߪⷫ᳓ᕈߢ޽ࠆ㧚ߤߩ⋧ኻḨᐲߢ߽ᐔဋ⊛ߦ᳓⫳᳇ࠍๆ⌕ߔࠆߚ߼ๆ⌕ࡅ࡯࠻ࡐࡦࡊ߿࠺ࠪࠞࡦ࠻ⓨ⺞ࠪࠬ࠹ࡓߦ૶↪ߐࠇߡ޿ࠆ㧚ߒ߆ߒ㧘⋡⊛ߣߔࠆࠃ߁ߥ⁜޿⋧ኻḨᐲ▸࿐ߢᄢ߈ߥๆ⌕㊂Ꮕࠍᓧࠆߎߣߪߢ߈ߥ޿㧚ᵴᕈ὇ߪᲧセ⊛ဋ৻ߥ⚦ሹࠍᜬߜ㧘⁜޿⋧ኻḨᐲ▸࿐ߢๆ⌕
ߔࠆ․ᓽࠍ᦭ߔࠆ߇㧘⇹᳓ᕈߢ޽ࠆߚ߼⋡⊛ߣߔࠆૐ޿⋧ኻḨᐲߢ᳓⫳᳇ࠍๆ⌕ߒߥ޿㧚ߘߎߢ㧘᳞߼ࠄࠇࠆๆ⌕․ᕈࠍḩߚߔߦߪ࠯ࠝ
࡜ࠗ࠻ߩࠃ߁ߦဋ৻ߥ⚦ሹࠍ᦭ߒ㧘߆ߟ࠯ࠝ࡜ࠗ

વᾲ 2006 ᐕ 1 ᦬

-3

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․㓸㧦ๆ⌕ߩ਎⇇̆ࡒࠢࡠ߆ࠄࡑࠢࡠ㧘ߘߒߡࠪࠬ࠹ࡓ̆

㪇㪅㪉㪌

㪇㪅㪉

㪇㪅㪊

㪘㫄㫆㫌㫅㫋㩷㫆㪽㩷㪘㪻㫊㫆㫉㪹㪸㫋㪼㩿㪾㪄㪟㪉㪦㪆㪾㪄㪘㪻㫊㫆㫉㪹㪼㫅㫋㪀㪸㪻㫊㫆㫉㫇㫋㫀㫆㫅㩷㪸㫄㫆㫌㫅㫋㩷㫆㪽㩷㫎㪸㫋㪼㫉㩷㪲㫂㪾㪄㪟㪉㪦㪆㫂㪾㪄㪘㪻㫊㫆㫉㪹㪼㫅㫋㪴

㪇㪅㪋

㪇㪅㪉
㪝㪘㪤㪄㪱㪇㪈
㪝㪘㪤㪄㪱㪇㪉

㪇㪅㪈㪝㪘㪬㩷㪸㫃㫄㫀㫅㫆㫊㫀㫃㫀㪺㪸㫋㪼㪘㪄㫋㫐㫇㪼㩷㫊㫀㫃㫀㪺㪸㩷㪾㪼㫃

㪇㪅㪈㪌

㪇㪅㪈

㪇㪅㪇㪌

㪘㪺㫋㫀㫍㪸㫋㪼㪻㩷㪺㪸㫉㪹㫆㫅

㪇
㪇

㪇㪅㪈

㪇㪅㪉
㪇㪅㪊
㪇㪅㪋
㪩㪼㫃㪸㫋㫀㫍㪼㩷㫇㫉㪼㫊㫊㫌㫉㪼㩷㪲㪄㪴

㪇㪅㪌

㪇㪅㪍

࿑3 FAM-Z01㧘FAM-Z02 ߣઍ⴫⊛ߥๆ⌕᧚ߩ
298K ߦ߅ߌࠆ᳓⫳᳇ๆ⌕╬᷷✢㪇㪇㪅㪇㪇 㪇㪅㪇㪌 㪇㪅㪈㪇 㪇㪅㪈㪌 㪇㪅㪉㪇 㪇㪅㪉㪌 㪇㪅㪊㪇 㪇㪅㪊㪌 㪇㪅㪋㪇 㪇㪅㪋㪌 㪇㪅㪌㪇㪩㪼㫃㪸㫋㫀㫍㪼㩷㫇㫌㫉㪼㫊㫊㫌㫉㪼㩷㪲㪄㪴࿑4 FAM-Z01 ߩฦ᷷ᐲߦ߅ߌࠆๆ⌕╬᷷✢ߣ⣕⌕╬᷷✢

ᰴߦ㧘FAM-Z01 ߣ FAM-Z02 ߦߟ޿ߡ⇣ߥࠆ᷷ᐲߢ᳓⫳᳇ๆ⌕╬᷷✢ࠍ᷹ቯߒߚ㧚࿑ 4 ߦ 298K㧘
318K㧘333K ߣ 348K ߢ᷹ቯߒߚ FAM-Z01 ߩ᳓⫳᳇ๆ⌕╬᷷✢ࠍ␜ߔ㧚࿑ 4 ࠃࠅ FAM-Z01 ߩ᳓⫳᳇ๆ⌕╬᷷✢ߪ᷷ᐲߦଐሽߒߡᄌൻߔࠆߎߣ߇್
ࠆ㧚߹ߚ㧘333K ߣ 343K ߢ⣕⌕╬᷷✢ࠍ᷹ቯߒߚ
⚿ᨐ㧘FAM-Z01 ߪๆ⣕⌕ߩࡅࠬ࠹࡝ࠪࠬ߇߶ߣ
ࠎߤߥ޿ߎߣ߇್ࠆ㧚
࿑ 5 ߦ 298K㧘318K㧘328K ߣ 363K ߢ᷹ቯߒߚ
FAM-Z02 ߩ᳓⫳᳇ๆ⌕╬᷷✢ࠍ␜ߔ㧚࿑ 5 ࠃࠅ
FAM-Z02 ߽᳓⫳᳇ๆ⌕╬᷷✢߇᷷ᐲଐሽᕈࠍ᦭
ߔࠆߎߣ߇್ࠆ㧚ห᭽ߦ 363K ߢߩ⣕⌕╬᷷✢ࠍ᷹ቯߒߚ㧚
FAM-Z02 ߪࠊߕ߆ߦๆ⣕⌕ߩࡅࠬ࠹࡝ࠪࠬ߇
ሽ࿷ߔࠆߎߣ߇್ࠆ㧚ᐔⴧ⺰⊛ߦๆ⌕ࡅ࡯࠻ࡐࡦ
ࡊߩ⚵ߺㄟߺ․ᕈࠍ⼏⺰ߔࠆ႐ว㧘FAM-Z02 ߩ⣕⌕ࠨࠗ࠼ߪ⣕⌕╬᷷✢ࠍ↪޿ࠆᣇ߇ࠃࠅᱜ⏕ߦ᜼േࠍ⹏ଔߔࠆߎߣ߇ߢ߈ࠆ㧚
FAM ߦ⷗ࠄࠇࠆๆ⌕╬᷷✢ߩᄢ߈ߥ᷷ᐲଐሽ
ᕈߪࠪ࡝ࠞࠥ࡞㧘ࠕ࡞ࡒࡁࠪ࡝ࠤ࡯࠻߿ᵴᕈ὇ߥ
ߤߎࠇ߹ߢᬌ⸛ߐࠇߡ߈ߚๆ⌕᧚ߦߪߥ޿․ᓽߢ
޽ࠆ㧚ߎߩๆ⌕╬᷷✢ߩᄢ߈ߥ᷷ᐲଐሽᕈߦࠃߞ
ߡ㧲㧭㧹ߪๆ⌕ࡅ࡯࠻ࡐࡦࡊߩๆ⌕᧚ߣߒߡఝࠇ
ߚᕈ⢻ࠍ␜ߔน⢻ᕈ߇⠨߃ࠄࠇࠆ㧚㩷

વᾲ 2006 ᐕ 1 ᦬㪉㪐㪏㪢㩷㪸㪻㫊
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㪊㪋㪏㪢㩷㪸㪻㫊
㪊㪋㪏㪢㩷㪻㪼㫊

㪘㫄㫆㫌㫅㫋㩷㫆㪽㩷㪸㪻㫊㫆㫉㪹㪸㫋㪼㪲㫂㪾㪄㪟㪉㪦㪆㫂㪾㪄㪸㪻㫊㫆㫉㪹㪼㫅㫋㪴

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㪉㪐㪏㩷㪢
㪊㪈㪏㩷㪢
㪊㪉㪏㩷㪢
㪊㪍㪊㩷㪢㩷㪸㪻㫊㪊㪍㪊㩷㪢㩷㪻㪼㫊㪇㪅㪇㪇㪇㪅㪇㪇 㪇㪅㪇㪌 㪇㪅㪈㪇 㪇㪅㪈㪌 㪇㪅㪉㪇 㪇㪅㪉㪌 㪇㪅㪊㪇 㪇㪅㪊㪌 㪇㪅㪋㪇 㪇㪅㪋㪌 㪇㪅㪌㪇㪩㪼㫃㪸㫋㫀㫍㪼㩷㫇㫉㪼㫊㫊㫌㫉㪼㩷㪲㪄㪴࿑ 5 FAM-Z02 ߩฦ᷷ᐲߦ߅ߌࠆๆ⌕╬᷷✢ߣ⣕⌕╬᷷✢
㩷㪋㪄㪊㪅㩷 ๆ⣕⌕⠴ਭᕈ㩷ๆ⌕᧚ߩ⠴ਭᕈߪๆ⌕ࡅ࡯࠻ࡐࡦࡊ߿࠺ࠪࠞ
ࡦ࠻ߩ↪ㅜߢߪ㊀ⷐߥⷐ࿃ߢ޽ࠆ㧚FAM ߣหߓࠕ࡞ࡒࡁࡈࠜࠬࡈࠚ࡯࠻ߩ AlPO-17 ߿ AlPO-18 ߪ᳓⫳᳇ߩๆ⣕⌕ߦኻߒߡਇ቟ቯߢ޽ࠅ㧘ߘࠇࠄߩࠕ
࡞ࡒࡁࡈࠜࠬࡈࠚ࡯࠻ߪๆ⌕᧚ߣߒߡ૶↪ߪ࿎㔍ߢ޽ࠆ㧚ߒ߆ߒߥ߇ࠄ㧘FAM ߪๆ⌕ࡅ࡯࠻ࡐࡦࡊ
߿࠺ࠪࠞࡦ࠻ߩᠲ૞᧦ઙߦ߅޿ߡ㕖Ᏹߦ቟ቯߢ޽
ࠅ㧘ߎࠇ߽ᒝߺߩ৻ߟߢ޽ࠆ㧚
FAM-Z01 ߣ FAM-Z02 ߩ᳓⫳᳇ߩๆ⣕⌕⠴ਭᕈߪ⠴ਭᕈ⹏ଔⵝ⟎㧔ਃ⪉ൻቇ␠⵾㧕ࠍ↪޿ߡ⹏ଔߒߚ㧚FAM-Z01 ߩ⚿ᨐࠍ࿑  ߦ㧘FAM-Z02 ߩ⚿ᨐࠍ࿑  ߦ␜ߔ㧚࿑  ࠃࠅ㧘FAM-Z01 ߪ 20 ਁ࿁➅ࠅ㄰ߒߚᓟߩๆ⌕╬᷷✢ߪೋᦼߩๆ⌕╬᷷✢ߣోߊ⇣ߥࠄߕ㧘᳓⫳᳇ߩๆ⣕⌕ߦኻߒߡ㜞޿⠴ਭᕈࠍ᦭ߔࠆߎߣ߇ࠊ߆ࠆ㧚࿑  ߦ FAM-Z02 ߩೋ- 10 -J. HTSJ, Vol. 45, No. 190

․㓸㧦ๆ⌕ߩ਎⇇̆ࡒࠢࡠ߆ࠄࡑࠢࡠ㧘ߘߒߡࠪࠬ࠹ࡓ̆
࿁㧘2 ਁ࿁ᓟ㧘6 ਁ࿁ᓟ㧘10 ਁ࿁ᓟ߅ࠃ߮ 20 ਁ࿁ᓟߩ᳓⫳᳇ๆ⌕╬᷷✢ࠍ␜ߔ㧚2 ਁ࿁એ㒠ߩ᳓⫳᳇ๆ⌕╬᷷✢ߪ߶ߣࠎߤหߓߢ޽ࠆ߇㧘ೋ࿁ߣߪࠊߕ߆ߦ⇣ߥࠆ․ᕈߣߥߞߡ޿ࠆ㧚╩⠪ࠄߪߎߩ⃻⽎ࠍᰴߩࠃ߁ߦ⠨߃ࠆ㧚FAM-Z02 ߪ᳓⫳᳇ࠍๆ⌕ߔࠆߎߣߦࠃߞߡ㧘ᣧ޿Ბ㓏ߢ⴫㕙߇ⷫ᳓ᕈߦ
ᄌࠊࠅ㧘ߘߩᓟ቟ቯߔࠆ㧚⚿ᨐ㧘2 ਁ࿁߆ࠄ 20 ਁ࿁ߦ߆ߌߡߩᄌൻߪዊߐ޿㧚
 20 ਁ࿁ߪ㧘ߚߣ߃߫ๆ⌕ࡅ࡯࠻ࡐࡦࡊߦ߅޿ߡ
ๆ⌕ 5 ಽ㧛⣕⌕ 5 ಽߩࠨࠗࠢ࡞ߢ 10 ᤨ㑆㧛ᣣ㧘
365ᣣ㧛ᐕߢㆇォߔࠆ႐วߩ⚂ 5 ᐕඨߦ⋧ᒰߔࠆ࿁ᢙ
ߢ޽ࠆ㧚20 ਁ࿁⚻ㆊᤨὐߢోߊᕈ⢻ૐਅ߇ߥ޿ߎ
ߣ߆ࠄ 20 ਁ࿁ࠍㆊ߉ߡᕆỗߦ․ᕈ߇ૐਅߔࠆߎ
ߣߪ⠨߃ߦߊߊ㧘FAM-Z01,FAM-Z02 ߣ߽ታ↪ߢ߈ࠆචಽߥ⠴ਭᕈࠍ᦭ߒߡ޿ࠆߣ⠨߃ࠄࠇࠆ㧚㪋㪄㪋㪅㩷 ๆ⌕䊍䊷䊃䊘䊮䊒䈻䈱ᐔⴧ⺰⊛⚵䉂ㄟ䉂․ᕈ⹏ଔ㩷 ߎߎߢ㧘࿕૕㜞ಽሶΆᢱ㔚ᳰ߿ᄥ㓁᷷᳓ེߢᓧ
ࠄࠇࠆ 333K ߩૐ޿᷷᳓ߢๆ⌕ࡅ࡯࠻ࡐࡦࡊࠍ૞
േߐߖࠆ႐วߦߟ޿ߡ⠨ኤߔࠆ㧚ๆ⌕ࡅ࡯࠻ࡐࡦ
ࡊߩ૞േ᷷ᐲ᧦ઙࠍ TL/TM/TH = 283K/303K/333K
ߣߔࠆߣ㧘ᠲ૞⋧ኻḨᐲ▸࿐ߪI1 = 0.29㧘I2 = 0.21
ߣߥࠆ㧚ߎߩᠲ૞Ḩᐲ▸࿐ߢߩๆ⌕㊂Ꮕ㧔¨Q㧕 ߦߟ޿ߡ FAM-Z01 ߣ A ဳࠪ࡝ࠞࠥ࡞ߦߟ޿ߡᲧセߒߚ㧚¨Q ߪ ĳ1 ߣ ĳ2 ߦᣈߌࠆᐔⴧๆ⌕㊂ߩᏅߢ޽ࠆ㧚࿑ 8 ߦ FAM-Z01㧘ࠪ࡝ࠞࠥ࡞ߩ 303 K ߩๆ⌕╬᷷✢ߣ 333 K ߩ⣕⌕╬᷷✢ࠍ␜ߔ㧚FAM-Z01
ߪᠲ૞᷷ᐲߦࠃߞߡๆ⌕╬᷷✢㧘⣕⌕╬᷷✢߇ᄢ߈ߊ⇣ߥߞߚ߇㧘ࠪ࡝ࠞࠥ࡞ߪ 303 K ߩๆ⌕╬᷷✢ߣ 333K ߩ⣕⌕╬᷷✢߇㊀ߥࠅ㧘ోߊᏅ߇ߥ޿
⚿ᨐߣߥߞߚ㧚࿑ 8 ࠃࠅ FAM-Z01 ߩ᦭ലๆ⌕㊂ǻQ ߪ 0.16 kg/kg ߢ޽ࠅ㧘0.04 kg/kg ߢ޽ࠆࠪ࡝ࠞࠥ࡞ߩ ǻQ ߩ⚂ 4 ୚ߢ޽ࠆߎߣ߇ࠊ߆ࠆ㧚ᧄ⚿ᨐ߆ࠄ FAM-Z01 ࠍๆ⌕ࡅ࡯࠻ࡐࡦࡊߩๆ⌕᧚ߣߒߡ↪޿ࠆߣࠪ࡝ࠞࠥ࡞ࠍ↪޿ߚ႐วߦᲧߴ㧘1/4
ߩๆ⌕᧚㊂ߢห಴ജ߇ᓧࠄࠇࠆน⢻ᕈ߇޽ࠆߎߣ
߇ࠊ߆ߞߚ㧚੹ᓟ㧘FAM-Z01 ߩലᨐࠍ⏕⹺ߔࠆߚ߼ߦๆ⌕ࡅ࡯࠻ࡐࡦࡊࠍ૞⵾ߒߡേ․ᕈߩ⹏ଔࠍ
ⴕ߁ߎߣ߇ᔅⷐߣ⠨߃ࠆ㧚㪘 㫄 㫆 㫌 㫅 㫋㩷㫆 㪽㩷㪸㪻㫊㫆 㫉㪹㪸㫋㪼㩷㪲㫂㪾㪄 㪟 㪉 㪦 㪆 㫂㪾㪄 㪸㪻㫊㫆 㫉㪹㪼 㫋㪴

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㪇㩷㫋㫀㫄㪼㫊
㪈㪌㪇㪃㪇㪇㪇㩷㫋㫀㫄㪼㫊

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㪩㪼㫉㪸㫋㫀㫍㪼㩷㫇㫉㪼㫊㫊㫌㫉㪼㩷㪲㪄㪴㪊㪇㪃㪇㪇㪇㩷㫋㫀㫄㪼㫊㪉㪇㪇㪃㪇㪇㪇㩷㫋㫀㫄㪼㫊㪇㪅㪌㪇㪍㪇㪃㪇㪇㪇㩷㫋㫀㫄㪼㫊㪘㫄㫆㫌㫅㫋㩷㫆㪽㩷㪸㪻㫊㫆㫉㪹㪸㫋㪼㪲㫂㪾㪄㪟㪉㪦㪆㫂㪾㪄㪸㪻㫊㫆㫉㪹㪼㫅㫋㪴㪇㪅㪇㪇#OQWPVQHCFUQTDCVG
=MI*1MICFUQTDGPV?

࿑  FAM-Z01 ߩ⠴ਭᕈ⹏ଔ⚿ᨐ


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䂦㪨 㩿㪪㫀㫃㫀㪺㪸㩷㪾㪼㫃㪀㪔㩷㪇㪅㪇㪋㩷㫂㪾㪆㫂㪾䂦㪨 㩿㪝㪘㪤㪀
㪔㩷㪇㪅㪈㪍㩷㫂㪾㪆㫂㪾㪇㪅㪇㪇 㪇㪅㪇㪌 㪇㪅㪈㪇 㪇㪅㪈㪌 㪇㪅㪉㪇 㪇㪅㪉㪌 㪇㪅㪊㪇 㪇㪅㪊㪌 㪇㪅㪋㪇㪩㪼㫃㪸㫋㫀㫍㪼㩷㫇㫉㪼㫊㫊㫌㫉㪼㩷㪲㪄㪴㪝㪘㪤㪄㪱㪇㪈㩷㪊㪇㪊㩷㪢㩷㪸㪻㫊㪪㫀㫃㫀㪺㪸㩷㪾㪼㫃㩷㪊㪊㪊㩷㪢㩷㪻㪼㫊

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    4GNCVKXGRTGUUWTG=?

VKOGUVKOGUVKOGUVKOGU㪪㫀㫃㫀㪺㪸㩷㪾㪼㫃㩷㪊㪇㪊㩷㪢㩷㪸㪻㫊㱢㪉㩷㪔㩷㪇㪅㪉㪈࿑  FAM-Z01 ߣ # ဳࠪ࡝ࠞࠥ࡞ߩๆ⌕ࡅ࡯࠻ࡐࡦࡊ߳ߩ⚵ߺㄟߺ․ᕈᲧセVKOGU৻ᣇ㧘FAM-Z02 ߪ⥄േゞߩឃᾲ߿ࠟࠬࠛࡦࠫࡦ
ࠦࠫࠚࡀ࡟࡯࡚ࠪࡦߩឃᾲߥߤዋߒ㜞޿ᾲḮࠍ↪
޿ߚๆ⌕ࡅ࡯࠻ࡐࡦࡊߩๆ⌕᧚ߦㆡߒߡ޿ࠆ㧚ߎߎߢๆ⌕ࡅ࡯࠻ࡐࡦࡊߩ૞േ᷷ᐲ᧦ઙࠍ TL/TM/TH= 283K/313K/363K ߣߔࠆߣ㧘ᠲ૞⋧ኻḨᐲ▸࿐࿑ FAM-Z02 ߩ⠴ਭᕈ⹏ଔ⚿ᨐ㩷㩷㩷વᾲ 2006 ᐕ 1 ᦬㪝㪘㪤㪄㪱㪇㪈㩷㪊㪊㪊㩷㪢㩷㪻㪼㫊㱢㪈㩷㪔㩷㪇㪅㪉㪐- 11 -J. HTSJ, Vol. 45, No. 190

․㓸㧦ๆ⌕ߩ਎⇇̆ࡒࠢࡠ߆ࠄࡑࠢࡠ㧘ߘߒߡࠪࠬ࠹ࡓ̆
ߪI1 = 0.17㧘I2 = 0.11 ߣߥࠆ㧚࿑ 9 ߦ FAM-Z02㧘
Y ဳ࠯ࠝ࡜ࠗ࠻㧘ࠪ࡝ࠞࠥ࡞ߩ 313 K ߩ᳓⫳᳇ๆ⌕╬᷷✢ߣ 363 㧷ߩ᳓⫳᳇⣕⌕╬᷷✢ࠍ␜ߔ㧚
FAM-Z02 ߪᠲ૞᷷ᐲߦࠃߞߡ᳓⫳᳇ๆ⌕╬᷷✢㧘᳓⫳᳇⣕⌕╬᷷✢߇ᄢ߈ߊߎߣߥࠆ߇㧘Y ဳ࠯ࠝ࡜ࠗ࠻߅ࠃ߮ࠪ࡝ࠞࠥ࡞ߪᠲ૞᷷ᐲߦࠃߞߡᄢ߈
ߥᏅߪ⷗ࠄࠇߥ߆ߞߚ㧚࿑ 9 ࠃࠅ㧘ᐔⴧ⺰⊛ߦߪ
FAM-Z02 ߪ Y ဳ࠯ࠝ࡜ࠗ࠻ߩ⚂ 4.8 ୚㧘ࠪ࡝ࠞࠥ࡞ߩ⚂ 3.8 ୚ߩ᦭ലๆ⌕㊂ࠍ᦭ߔࠆߎߣ߇ࠊ߆ࠆ㧚ๆ⌕ࡅ࡯࠻ࡐࡦࡊߩ಴ജߪᠲ૞᷷ᐲߦᄢ߈ߊଐሽ
ߔࠆ㧚੹࿁ᗐቯߒߚ⥄േゞߩ಄ළ᳓߿ࠟࠬࠛࡦࠫ
ࡦࠦࠫࠚࡀ࡟࡯࡚ࠪࡦߩ಄ළ᳓ࠍ↪޿ߡ 313 K ߩ಄ළ᷷ᐲߢ㧘283 K ߩ಄ᾲࠍ⵾ㅧߔࠆ႐วߪ૞േ
⋧ኻ࿶▸࿐߇I1 = 0.17㧘I2 = 0.11 ߣ⁜ߊ㧘ߎߩ᧦ઙߢㆇォߔࠆ႐ว㧘FAM-Z02 ߪ Y ဳ࠯ࠝ࡜ࠗ࠻
߿ࠪ࡝ࠞࠥ࡞ߦᲧߴߡ⚂ 1/4-1/5 ߩ૶↪㊂ߢหߓ಴ജ߇ᓧࠄࠇࠆߎߣ߇ࠊ߆ࠆ㧚ߒ߆ߒ㧘಄ළ᷷ᐲ߇ 303 K ߢ ޽ ࠇ ߫ ૞ േ ⋧ ኻ ࿶ ߪ ᐢ ߊ ߥ ࠅ 㧘
FAM-Z02 ߣ Y ဳ࠯ࠝ࡜ࠗ࠻߿ࠪ࡝ࠞࠥ࡞ߣߩ᦭
ലๆ⌕㊂ߩᏅߪዊߐߊߥࠆ㧚FAM-Z02 ߩ․ᓽ߇ᵴ
߆ߐࠇࠆߩߪ㧘੹࿁⸳ቯߒߚ᷷ᐲ᧦ઙߩࠃ߁ߦ㧘ᓥ᧪ߩๆ⌕᧚ߢߪⵝ⟎߇ᄢ߈ߊߥࠅߔ߉ߡታ↪ߦଏߐߥ޿↪ㅜߢ޽ࠆ㧚ߺ․ᕈߦߟ޿ߡᬌ⸛࡮⹏ଔࠍⴕߞߚ㧚ߘߩ⚿ᨐ㧘
1. FAM ߩ᳓⫳᳇ๆ⌕╬᷷✢ߪ S ሼᦛ✢ࠍឬ߈㧘᷷ᐲߦࠃߞߡᄌൻߒ㧘ๆ⣕⌕ߩࡅࠬ࠹࡝ࠪࠬߪ
ߥ޿߆㕖Ᏹߦዊߐ޿㧚ߎࠇࠄߩ․ᓽߦࠃߞߡ㧘
FAM ߪๆ⌕ࡅ࡯࠻ࡐࡦࡊߥߤߦ߅޿ߡ⁜޿ᠲ૞⋧ኻḨᐲ▸࿐ߢ߽ᄢ߈ߥๆ⣕⌕ኈ㊂Ꮕࠍᓧࠆߎߣ߇ߢ߈ࠆ㧚
2. FAM-Z01 ߪ᳓⫳᳇ߩๆ⣕⌕ߦኻߒߡ㜞޿⠴ਭᕈࠍ᦭ߔࠆ㧚⠴ਭᕈ⹜㛎ߦ߅޿ߡ 20 ਁ࿁ߩๆ⣕⌕ࠍ➅ࠅ㄰ߒߡ߽ๆ⌕․ᕈߪೋᦼߣᲧߴᄌ
ൻ߇ߥߊ㧘ታ૶↪ߦ໧㗴ߥ޿࡟ࡌ࡞ߩ⠴ਭᕈࠍ᦭ߒߡ޿ࠆߎߣ߇ࠊ߆ߞߚ㧚
3. FAM-Z02 ߪ⠴ਭᕈ⹜㛎ᓟߩ 2 ਁ࿁㧘6 ਁ࿁10
ਁ࿁ߣ 20 ਁ࿁ߩ᳓⫳᳇ๆ⌕╬᷷✢ߪ߶ߣࠎߤ
หߓߢ޽ࠆ߇㧘ೋ࿁ߣߪࠊߕ߆ߦ⇣ߥࠆ․ᕈߣ
ߥߞߚ㧚ߒ߆ߒ㧘ๆ⌕ኈ㊂ߦᄢ߈ߥᄌൻߪߥߊ㧘᳓⫳᳇ๆ⌕╬᷷✢ߩᄌൻ߽ዊߐߊታ૶↪ߦ໧㗴ߥ޿⠴ਭᕈࠍ᦭ߒߡ޿ࠆߣ⠨߃ࠆ㧚
4. ๆ⌕ࡅ࡯࠻ࡐࡦࡊࠍ TL/TM/TH = 283 K/ 303 K/
333 K ߩ᷷ᐲ᧦ઙߢㆇォߔࠆ႐ว㧘ᐔⴧ⺰⊛ߦߪ FAM-Z01 ߩ᦭ലๆ⌕㊂Ꮕߪࠪ࡝ࠞࠥ࡞ߦᲧ
ߴ㧠୚ᄢ߈޿ߎߣ߇ࠊ߆ߞߚ㧚FAM-Z01 ࠍๆ⌕ࡅ࡯࠻ࡐࡦࡊߩๆ⌕᧚ߣߒߡ↪޿ࠆߎߣߢ㧘ๆ⌕ࡅ࡯࠻ࡐࡦࡊ߇ዊဳൻߢ߈ࠆน⢻ᕈ߇␜ໂߐࠇߚ㧚
5. ๆ⌕ࡅ࡯࠻ࡐࡦࡊࠍ TL/TM/TH = 283 K/313
K/363 K ߩ᷷ᐲ᧦ઙߢㆇォߔࠆ႐ว㧘ᐔⴧ⺰⊛ߦߪ FAM-Z02 ߩ᦭ലๆ⌕㊂Ꮕߪ ; ဳ࠯ࠝ࡜ࠗ
࠻ߦᲧߴ 4.8 ୚㧘ࠪ࡝ࠞࠥ࡞ߦᲧߴ 3.8 ୚ᄢ߈޿ߎߣ߇ࠊ߆ߞߚ㧚ෳ⠨ᢥ₂
[1] Miller, E. B., The Development of Silica Gel

ٌ 3 ;\GQNKVGMIMI#OQWPVQHCFUQTDCVG
=MI*1MICFUQTDGPV?





ٌ 3 (#/<MIMI




ٌ 3 5KNKECIGN
MIMI










4GNCVKXGRTGUUWTG=㨉(#/<-CFU(#/<-FGU;\GQNKVG-CFU;\GQNKVG-FGU
5KNKECIGN-CFU
5KNKECIGN-FGU
Ǿ Ǿ 

࿑㧥 FAM-Z02A ဳࠪ࡝ࠞࠥ࡞߅ࠃ߮ Y ဳ࠯ࠝ࡜ࠗ࠻ߩๆ⌕ࡅ࡯࠻ࡐࡦࡊ߳ߩ⚵ߺㄟߺ․ᕈ

Refrigeration, Refrigerating Eng., 17-4(1929)103.
[2] ᩣ ᑼ ળ ␠ ೨ Ꮉ ⵾ ૞ ᚲ ࡎ ࡯ ࡓ ࡍ ࡯ ࠫ
http://www.mycomj.co.jp[3] ࠛ ࡀ ࠨ ࡯ ࡉ ᩣ ᑼ ળ ␠ ࡎ ࡯ ࡓ ࡍ ࡯ ࠫ
http://www.eneserve.co.jp㧡㧚⚿⸒ࠦࠫࠚࡀ࡟࡯࡚ࠪࡦ㧘Άᢱ㔚ᳰ㧘⥄േゞ㧘ᄥ㓁᷷᳓ེߥߤߢᓧࠄࠇࠆ 363 K એਅߩૐ᷷ឃᾲࠍ᦭ല ߦ ᵴ ↪ ߔ ࠆ ๆ ⌕ ᧚ ߣ ߒ ߡ FAM-Z01 ߅ ࠃ ߮
FAM-Z02 ࠍ㐿⊒ߒ㧘ၮᧄ․ᕈ㧘ๆ⌕╬᷷✢㧘⠴ਭᕈࠍ⹏ଔߒ㧘ᐔⴧ⺰⊛ߥๆ⌕․ᕈ߆ࠄ FAM-Z01
߅ࠃ߮ FAM-Z02 ߩๆ⌕ࡅ࡯࠻ࡐࡦࡊ߳ߩ⚵ߺㄟ

વᾲ 2006 ᐕ 1 ᦬[4] ᷰㄝ⮮㓶㧘ዊႦᷕ㧘᳹↰ᐙᄦ㧘᨞⼱᣽ା㧘ൻቇᎿቇ⺰ᢥ㓸㧘19-6㧔1993㧕1165.
[5] Mizota, T., Zeolite-water heat-pump system foreffective use of waste heat, Proc. 13th IPCWS
Physical Chemistry of Aqueous System, Toronto,- 12 -J. HTSJ, Vol. 45, No. 190

․㓸㧦ๆ⌕ߩ਎⇇̆ࡒࠢࡠ߆ࠄࡑࠢࡠ㧘ߘߒߡࠪࠬ࠹ࡓ̆
Canada (1999) 1-8.

[8] ၂ౝඳⴕ㧘ਅጟ㉿⟤㧘ጤ಴⟤♿㧘ᄢፉ৻ౖ‫ޔ‬ጊፒᱜౖ㧘ኹ↰⑲㧘ᷰㄝዷ㧘ᱞ⣁㓉ᒾ㧘ൻቇᎿቇ⺰ᢥ㓸㧘31-5(2005)361.
[9] ၂ౝඳⴕ㧘ਅጟ㉿⟤㧘ጤ಴⟤♿㧘ᄢፉ৻ౖ㧘ጊፒᱜౖ㧘ኹ↰⑲㧘ᷰㄝዷ㧘ᱞ⣁㓉ᒾ㧘ൻቇᎿቇ⺰ᢥ㓸㧘31-4(2005)273.

[6] ၂ౝඳⴕ㧘ጊፒᱜౖ㧘ጊᧄ⧷㉿㧘ᣣ㜞⑲ੱ㧘ᳰ⇌ን⟤ሶ㧘⿒❥ᖝผ㧘ൻቇᎿቇળࠛࡀ࡞ࠡ࡯
ㇱળࠪࡦࡐࠫ࠙ࡓ⻠Ṷ⺰ᢥ㓸㧘3-1㧔2003㧕11[7] Kumita, M., Mori, S., Yokogoshiya, T. andOtsubo, S., J. Chem. Eng. Japan., 36 (2003) 812

વᾲ 2006 ᐕ 1 ᦬- 13 -J. HTSJ, Vol. 45, No. 190

․㓸㧦ๆ⌕ߩ਎⇇̆ࡒࠢࡠ߆ࠄࡑࠢࡠ㧘ߘߒߡࠪࠬ࠹ࡓ̆

ᄙሹ૕ౝㇱߩๆ⌕⃻⽎
Adsorotion phenomena inside porous materials ᄢችม ໪ᢥ㧔᧲੩ᄢቇ㧕
Hirofumi DAIGUJI (The University of Tokyo)
e-mail: daiguji@k.u-tokyo.ac.jp
࿑ 1 ߪ IUPAC (International Union of Pure andApplied Chemistry)ߩಽ㘃ߦၮߠߊ㧘ฦ⒳ๆ⌕೷߳ߩ᳇⋧ๆ⌕╬᷷✢ࠍ⴫ߔ[3]㧚I ဳߪࡒࠢࡠሹߩᄙ
޿࿕૕ߢߺࠄࠇ㧘Langmuir ဳߣ޿ࠊࠇࠆ㧚৻⥸ߦනಽሶጀๆ⌕ߦၮߠ޿ߚ⠨߃ᣇߢ⺑᣿ߐࠇࠆ㧚II
ဳߪ⚦ሹࠍ߽ߚߥ޿㧘ᓸ☸ሶ⁁ߩ࿕૕߳ߩๆ⌕ߢ⷗ࠄࠇࠆ㧚߹ߚ II ဳߣ IV ဳߪ B ὐߣ๭߫ࠇࠆᄌ
ᦛὐࠍ߽ߟߩ߇․ᓽߢ޽ࠆ㧚III ဳߣ V ဳߪ⫳᳇ๆ⌕ߩౖဳ⊛ߥ╬᷷✢ࠍ⴫ߔ㧚 IV ဳߣ V ဳߪࡔ࠰ሹߩᄙ޿࿕૕ߢ⷗ࠄࠇ㧘ๆ⌕ߣ⣕⌕ߩ╬᷷✢߇৻⥌ߒߥ޿㧘޿ࠊࠁࠆጁᱧ⃻⽎(hysterisis)ࠍ␜ߔ㧚
VI ဳߪ㓏Ბ⁁ߩ╬᷷✢ߢ․ᱶ὇⚛߳ߩ⓸⚛ๆ⌕ߢ⷗ࠄࠇࠆ㧚
ๆ⌕╬᷷ᑼߩቯᑼൻߪ㐳޿ᱧผࠍ߽ߜ㧘ߎࠇ߹ߢᢙᄙߊߩࡕ࠺࡞߇ႎ๔ߐࠇߡ޿ࠆ[4]㧚ߎࠇࠄߩࡕ࠺࡞ߪਥߦᰴߩ 2 ⒳㘃ߦᄢ೎ߐࠇࠆ㧚ߔߥࠊߜ(i)․ቯߩ⴫㕙㗔ၞߦ⌕⋡ߔࠆ߽ߩ㧘(ii)ሹߩ૕Ⓧ߿ᄢ߈ߐߩಽᏓߦ⌕⋡ߔࠆ߽ߩߢ޽ࠆ㧚೨⠪ߪਥߦࡒࠢࡠᄙሹ૕ߦ߅ߌࠆๆ⌕ࡕ࠺࡞ߢ޽ࠅ㧘ઍ⴫⊛ߥࡕ࠺࡞ߣߒߡ‫ޟ‬ᄙಽሶጀๆ⌕ℂ⺰‫ࠆ޽߇ޠ‬㧚৻ᣇ㧘ᓟ⠪ߪਥߦࡑࠢࡠᄙሹ૕ߦ߅ߌࠆๆ⌕ࡕ࠺࡞ߢ޽ࠅ㧘ઍ⴫⊛ߥࡕ࠺࡞ߣߒߡ‫ޟ‬Ძ▤ಝ❗ℂ⺰‫ޠ‬߇޽ࠆ㧚ࡔ࠰ᄙሹ૕ߦ߅޿ߡߪ‫ޟ‬ጀ⁁ๆ⌕‫ޟߣޠ‬Ძ▤ಝ❗‫ߩޠ‬ਔᣇߩ⃻⽎߇⷗ࠄࠇ㧘޿ߕࠇ߆৻ᣇߢ
ๆ⌕⃻⽎ࠍ⺑᣿ߔࠆߩߪ࿎㔍ߢ޽ࠆ㧚ߎߎߢ․ߦ

ߪߓ߼ߦ
ᄙሹ૕ߣߪౝㇱߦᄢዊߐ߹ߑ߹ߥሹࠍ߽ߟ࿕૕
ߩ✚⒓ߢ޽ࠅ㧘ㅢᏱߩ࿕૕ߣߪ⒳‫ࠆߥ⇣ߩޘ‬ᕈ⾰ࠍ߽ߟ㧚ߘߩᕈ⾰ߪሹߩሽ࿷ߦࠃࠅ࿕૕ో૕ߩ᭴
ㅧߦᄌൻ߇↢ߓࠆߎߣߦࠃࠆ߽ߩߢ޽ࠅ㧘߹ߚሹߩ⴫㕙ߩᓸ⚦᭴ㅧ߇߽ߚࠄߔ৻⒳ߩ⇇㕙⃻⽎ߦࠃࠆ߽ߩߢ޽ࠆ㧚৻⥸ߦ㧘࠯ࠝ࡜ࠗ࠻ߥߤߩࠃ߁ߦ
2 nm એਅߩ⚦ሹࠍ߽ߟ‛⾰ࠍࡒࠢࡠᄙሹ૕㧘ᄙሹ⾰ࠟ࡜ࠬߥߤߩࠃ߁ߦ 50 nm એ਄ߩ⚦ሹࠍ߽ߟ‛⾰ࠍࡑࠢࡠᄙሹ૕㧘ߘߩਛ㑆ࠍࡔ࠰ᄙሹ૕ߣ๭߱
[1, 2]㧚ㄭᐕ㧘ᄙሹ૕ߪ᭽‫ߥޘ‬ᣇᴺߢวᚑߐࠇ㧘ಽሶࠬࠤ࡯࡞ߩ᭴ㅧ೙ᓮ߽น⢻ߦߥߞߡ߈ߡ޿ࠆ㧚
ᧄⓂߢߪ㧘ਥߦࡒࠢࡠ㧛ࡔ࠰ᄙሹ૕ࠍኻ⽎ߣߒ㧘ߎࠇࠄߩ‛⾰߇߽ߟ᭽‫ߥޘ‬ᕈ⾰ߩਛ߆ࠄๆ⌕ᕈ⢻ߦ⌕⋡ߒ㧘ߘߩౝㇱߩๆ⌕⃻⽎ߦߟ޿ߡ⸃⺑ߔࠆ㧚೨ඨߪๆ⌕ߩઍ⴫⊛ߥ‛ℂࡕ࠺࡞ࠍ⺑᣿ߒ㧘ᓟඨߪๆ⌕ߩಽሶࠪࡒࡘ࡟࡯࡚ࠪࡦߦߟ޿ߡᦨㄭߩ⎇ⓥേะࠍㅀߴࠆ㧚ๆ⌕ߩ‛ℂࡕ࠺࡞ๆ⌕╬᷷✢ߩಽ㘃ๆ⌕ߩℂ⺰ߪ㧘৻ቯ㊂ߩ࿕૕߇৻ቯߩ᷷ᐲ࡮ๆ
⌕⾰Ớᐲߩ᧦ઙਅߢ㧘ๆ⌕⾰ࠍߤࠇ߶ߤ߹ߢๆ⌕น⢻ߢ޽ࠆ߆ߣ޿߁࿕૕ߩๆ⌕⢻㧔ๆ⌕ኈ㊂㧕ࠍ
⠨߃ࠆๆ⌕ᐔⴧ⺰ߣๆ⌕ᐔⴧߦ㆐ߔࠆ߹ߢߩㅦᐲ
ࠍ໧㗴ߣߔࠆๆ⌕ㅦᐲ⺰ߦಽ߆ࠇࠆ߇㧘ߎߎߢߪๆ⌕ᐔⴧ⺰ߦߟ޿ߡ⠨߃ࠆ㧚᳇૕߇࿕૕ߦๆ⌕ߔࠆ႐ว㧘න૏⾰㊂ߩ࿕૕ߦๆ⌕ߔࠆๆ⌕⾰ߩ㊂ v ߪ᳇⋧ߩᐔⴧ࿶ p ߣ᷷ᐲ Tߩ㑐ᢙߣ޽ࠆ߇㧘ࠃߊ↪޿ࠄࠇࠆቯ᷷ๆ⌕ታ㛎ߩ⚿ᨐߪ p ߩߺߩ㑐ᢙߢ⴫ߐࠇࠆ㧚⥃⇇᷷ᐲએਅߩ
᳇૕㧘ߔߥࠊߜ⫳᳇ߢߪߘߩ㘻๺⫳᳇࿶ࠍ ps ߣߔࠆߣ㧘⋧ኻ࿶ p/ps ߩ㑐ᢙߣߒߡᰴᑼߩࠃ߁ߦ⴫ߐ
ࠇࠆ㧚v

f p / ps T

વᾲ 2006 ᐕ 1 ᦬

ๆ⌕㊂ v



ๆ⌕⾰⫳᳇࿶ p(1)

࿑ 1. IUPAC ᮡḰๆ⌕╬᷷✢[3]- 14 -J. HTSJ, Vol. 45, No. 190

․㓸㧦ๆ⌕ߩ਎⇇̆ࡒࠢࡠ߆ࠄࡑࠢࡠ㧘ߘߒߡࠪࠬ࠹ࡓ̆

⥝๧ᷓ޿ߩߪ㧘‫ޟ‬ጀ⁁ๆ⌕‫ޟߣޠ‬Ძ▤ಝ❗‫߁޿ߣޠ‬2 ߟߩ⇣ߥࠆๆ⌕᭽ᑼߪߤߎߢㆫ⒖ߔࠆ߆ߣ޿߁
ὐߦ޽ࠆ㧚ߎߎߢߪ‫ޟ‬ᄙ㊀ቯᏱ⁁ᘒ㑆ߩㆫ⒖‫ߩޠ‬ࡕ࠺࡞ߦߟ޿ߡ◲නߥๆ⌕ࡕ࠺࡞ࠍ↪޿ߡ⺑᣿ߔࠆ㧚cᄙಽሶጀๆ⌕ℂ⺰ᄙಽሶጀๆ⌕ℂ⺰ߩࡕ࠺࡞ߣߒߡߪ Brunauer㧘
Emmett㧘Teller ߩዉ಴ߒߚ BET ᄙಽሶጀๆ⌕ࡕ࠺࡞߇޽ࠆ[5, 6]㧚ߎߩࡕ࠺࡞ߦ߅޿ߡߪ㧘࿑ 2 ߦ␜ߐࠇࠆࠃ߁ߦ᳇૕ಽሶߪ࿕૕⴫㕙ߢනಽሶጀ߆ࠄ
n ಽሶጀ߹ߢߩ⒳‫ߩޘ‬ᄙಽሶጀࠍᒻᚑߒߡᐔⴧࠍ
଻ߟߣ઒ቯߐࠇࠆ㧚ߔߥࠊߜ Langumuir ߩනಽሶጀๆ⌕㧔ൻቇๆ⌕㧕ࡕ࠺࡞ߦ╙ 2 ጀએ਄ߩ‛ℂๆ⌕ㆊ⒟ࠍട߃ߡࠃࠅ৻⥸ൻߒߚ߽ߩߣ޿߃ࠆ㧚Langmuir ߩ⠨߃ߦၮߠߊߣ㧘ๆ⌕ߒߡ޿ߥ޿႐ᚲ
㧔㕙Ⓧ S0㧕ߦๆ⌕ߒߡනಽሶጀ㧔㕙Ⓧ S1㧕ࠍᒻᚑߔࠆㅦᐲߪ⋧ኻ࿶ p/ps ߣ S0 ߦᲧ଀ߒ㧘නಽሶጀ߆
ࠄߩ⣕㔌ㅦᐲߪ S1 ߦᲧ଀ߔࠆ㧚ᐔⴧ⁁ᘒߢߪๆ⌕ㅦᐲߣ㔌⣕ㅦᐲ߇╬ߒ޿ߎߣ߆ࠄᰴᑼ߇ᚑ┙ߔࠆ㧚
ka 0 p / ps S0

kd1S1

ߚߛߒ㧘ka0㧘kd1 ߪߘࠇߙࠇ S0 ߳ߩๆ⌕ㅦᐲቯᢙ㧘߅ࠃ߮ S1 ߆ࠄߩ⣕㔌ㅦᐲቯᢙߢ޽ࠆ㧚ߥ߅ๆ⌕ᐔ
ⴧቯᢙ K=ka0/ka1 ߪๆ⌕ᾲ Ea ߣߩ㑆ߦᰴᑼߩ㑐ଥ߇޽ࠆ㧚d ln K / dT

Ea / RT 2

g a p / ps exp Ea / RT(3)g l p / p s exp E l / RTn
§ n i· §·(8)¨ c ¦ iy ¸ ¨1  c ¦ y i ¸i 1© i1 ¹ ©
¹ߎߎߢ㧘᳇⋧࿶ p ߇㘻๺⫳᳇࿶ ps ߦ╬ߒ޿ߣ߈㧘vvm

ๆ⌕⾰⫳᳇ߪㅢᏱߩᶧ૕ߣߥߞߡ࿕૕⴫㕙ߦಝ❗
ߔࠆߣ઒ቯߔࠆߣ㧘p/ps=1 ߩߣ߈ y=1 ߣߥࠆ㧚ߔߥࠊߜ y ߪ⋧ኻ࿶ p/ps ࠍ⴫ߔߎߣߦߥࠆ㧚ߘߎߢ㧘
ᑼ 8 ߦ y=p/ps ࠍઍ౉ߒ㧘◲නߥᑼߩᄌᒻࠍⴕ߁ߣ
ᰴᑼ߇ዉ಴ߐࠇࠆ㧚
vm

n
n 1
º
c p / p s ª1  n  1 p / p s  n p / p s(9)«n 1 »
1  p / p s ¬« 1  c  1 p / p s  c p / p s¼»᳇⋧㧔࿶ജ p㧕
nಽሶጀ

3ಽሶጀ
2ಽሶጀ

ಝ❗ᾲEl

නಽሶጀ
ๆ⌕ᾲEa
S0

S1

S2

S3

Sn
…
࿕⋧㧔ో⴫㕙Ⓧ S= S0+ S1+ S2+ S3+ …+Sn㧕(5)ߎߎߢ㧘ᑼ 4㧘5 ߢቯ⟵ߐࠇߚ x ߣ y ߩᲧࠍ c ߣߔࠆߣ㧘c ߪᰴᑼߩࠃ߁ߦ⴫ߐࠇࠆ㧚વᾲ 2006 ᐕ 1 ᦬ߔߣᰴᑼߩࠃ߁ߦߥࠆ㧚৻ᣇ㧘nÆߣߔࠆߣ㧘BET ή㒢ጀᑼ߇ዉ಴ߐࠇࠆ㧚(4)ߚߛߒ㧘ga ߪๆ⌕࡮⣕㔌ߩㅦᐲቯᢙᲧࠍ⴫ߔቯᢙ
ߢ޽ࠆ㧚╙ 2 ጀએ਄ߩๆ⌕࡮⣕㔌ߦኻߒߡ߽ห᭽
ߩ⠨߃ᣇࠍㆡ↪ߔࠆߎߣ߇ߢ߈ࠆ߇㧘ߎߎߢߪ╙2 ጀએ਄ߩోߡߩๆ⌕ጀߦኻߒߡ㧘ๆ⌕ᾲ Ea ߩઍࠊࠅߦಝ❗ᾲ El ࠍ㧘ga ߩઍࠊࠅߦ gl ࠍ↪޿ࠆ㧚੹㧘Si ࠍ i ಽሶጀๆ⌕ߔࠆㇱಽߩ⴫㕙Ⓧߣߔࠆߣ㧘i2ߦ߅޿ߡ㧘Si ߣ Si-1 ߩ㕙ⓍᲧ y (=Si/ Si-1㧕ߦߟ޿ߡᰴᑼ߇ᚑ┙ߔࠆ㧚
y

§ n
· § n
·
(7)
¨ ¦ iS i ¸ ¨ ¦ S i ¸©i 0¹ ©i 0 ¹ᑼ 7 ࠍᑼ 5㧘6 ߢቯ⟵ߐࠇߚቯᢙ y㧘c ࠍ↪޿ߡ⴫v
vm

ߎߩᑼߪ BET ᦭㒢ጀᑼߣ๭߫ࠇ㧘නಽሶጀๆ⌕㊂vm㧘ᦨ㜞ๆ⌕ጀᢙ n㧘ቯᢙ c ߩ 3 ߟߩࡄ࡜ࡔ࡯࠲
ߦࠃߞߡๆ⌕᳇૕ߩోኈⓍ v ߣ⋧ኻ࿶ p/ps ߩ㑐ଥ߇ਈ߃ࠄࠇࠆ㧚BET ᦭㒢ጀᑼߢ n=1 ߣ߅ߊߣ㧘cߩ୯ߦࠃࠄߕ㧘Langmuir ᑼ㧔࿑ 1 ߩ I ဳ㧕߇ዉ಴ߐࠇࠆ㧚
c p / ps
(10)v vm
1  c p / psߒߚ߇ߞߡ㧘S1 ߣ S0 ߩ㕙ⓍᲧࠍ x (=S1/S0)ߣߔࠆߣ
ᑼ 2㧘3 ࠃࠅᰴᑼ߇ᚑ┙ߔࠆ㧚
x(6)

ᑼ 6 ߢቯ⟵ߐࠇߚቯᢙ c ߪ╙ 1 ጀߦ߅ߌࠆಽሶṛ⇐ᤨ㑆ߣ╙ 2 ጀએ਄ߦ߅ߌࠆಽሶṛ⇐ᤨ㑆ߩᲧࠍ␜ߒߡ޿ࠆ㧚੹㧘ๆ⌕᳇૕ߩోኈⓍࠍ v㧘ో⴫㕙ࠍනಽሶጀߢⷒ߁ߩߦⷐߔࠆ᳇૕ߩኈⓍ vm ߣߔࠆߣ㧘ᰴߩ㑐ଥᑼ߇ᚑ┙ߔࠆ㧚v(2)g a / g l exp> E a  E l / RT @x/ y࿑ 2 BET ᄙಽሶጀๆ⌕ℂ⺰ࡕ࠺࡞[5, 6]- 15 -J. HTSJ, Vol. 45, No. 190

․㓸㧦ๆ⌕ߩ਎⇇̆ࡒࠢࡠ߆ࠄࡑࠢࡠ㧘ߘߒߡࠪࠬ࠹ࡓ̆

v vm

c p / ps
>1  p / ps @>1  c  1 p / ps @ᡰ㈩⊛ߢ޽ࠅ㧘Ძ▤ಝ❗ߪήⷞߔࠆߎߣ߇ߢ߈ࠆ㧚ߎߩࠃ߁ߥ႐วߦ‫ޟ‬ᄙಽሶጀๆ⌕ℂ⺰‫߇ޠ‬ㆡ↪ߐࠇࠆ㧚৻ᣇ㧘ࡑࠢࡠᄙሹ૕ߦ߅޿ߡߪ⚦ሹߩኈⓍ
߇⴫㕙Ⓧߦኻߒߡᄢ߈޿ߚ߼㧘Ძ▤ಝ❗߇ᡰ㈩⊛ߢ޽ࠅ㧘⴫㕙ๆ⌕ߪήⷞߔࠆߎߣ߇ߢ߈ࠆ㧚ߎߩࠃ߁ߥ႐วߦ‫ޟ‬Ძ▤ಝ❗ℂ⺰‫߇ޠ‬ㆡ↪ߐࠇࠆ㧚ߒ߆ߒ㧘ࡔ࠰ᄙሹ૕ߦ߅޿ߡߪ‫ޟ‬ጀ⁁ๆ⌕‫ޟߣޠ‬Ძ▤ಝ❗‫ߩޠ‬ਔᣇ߇ห⒟ᐲߦ㊀ⷐߢ޽ࠅ㧘ߤߜࠄ߆৻ᣇࠍήⷞߔࠆߎߣߪߢ߈ߥ޿㧚ߎߎߢ⥝๧ᷓ޿
ߩߪ 2 ߟߩ⇣ߥࠆๆ⌕᭽ᑼߪߤߎߢㆫ⒖ߔࠆ߆ߣ
޿߁ὐߢ޽ࠆ㧚ߎߩࠃ߁ߥ໧㗴ߪ৻⥸ߦ‫ޟ‬ᄙ㊀ቯᏱ⁁ᘒ㑆ߩㆫ⒖‫ߩޠ‬໧㗴ߣߒߡ⍮ࠄࠇߡ޿ࠆ[8]㧚
੹㧘◲නߥࡕ࠺࡞ߣߒߡ㧘N ୘ߩ⚿วㇱಽࠍ᦭ߔࠆᩰሶ⴫㕙ࠍ⠨߃ࠆ㧚ߘߩ♽ߪỚᐲ߇࿕ቯߐࠇߚ
ᚑಽ Xe ߩ‛⾰ᶎߣធ⸅ߒߡ޿ࠆ㧚Xe ߪⓨߩㇱ૏ߦ⚿วߔࠆߎߣߦࠃߞߡᩰሶߦๆ⌕ߔࠆ㧚ߘߩๆ⌕ߒߚᚑಽࠍ X ߣߔࠆ㧚X ߪ⣕⌕ߦࠃߞߡౣ߮ Xeߦ߽ߤࠆ㧚ߎߩ⃻⽎ߪᰴߩᑼߢ⴫ࠊߐࠇࠆ㧚(11)

ߎߩ BET ή㒢ጀᑼߦ߅޿ߡߪ㧘 c d 2 ߢߪ III ဳ㧘c ߩ୯߇ᄢ߈ߊߥࠆߣ II ဳߩ╬᷷ๆ⌕✢ࠍਈ߃ࠆ㧚৻⥸ߦ BET ᦭㒢ጀᑼ㧔ᑼ 9㧕ߦ߅޿ߡߪ㧘n3 ߢቯᢙ c ߦ޽ࠆ․ቯ▸࿐ߩ୯ࠍਈ߃ࠆߣ㧘࿑ 1 ߦ␜ߒߚ VI ဳࠍ㒰޿ߚ 5 ߟߩဳߩๆ⌕╬᷷✢ోߡࠍ⴫⃻ߔࠆߎߣ߇ߢ߈ࠆ㧚ߒ߆ߒ㧘ߚߣ߃ๆ⌕╬᷷✢ࠍࡈࠖ࠶࠹ࠖࡦࠣߔࠆߎߣ߇ߢ߈ߚߣߒߡ߽㧘ߔߴߡߩๆ⌕߇ጀ⁁ߦㅴ߻ߣ⚿⺰ઃߌࠆߎߣߪߢ
߈ߥ޿㧚Ძ▤ಝ❗ℂ⺰Ძ▤ಝ❗ℂ⺰ߪ⫳᳇ߩๆ⌕ࠍᶧ૕ߣߒߡ⚦ሹౝߦಝ❗ߔࠆ‛ℂ⃻⽎ߣ⠨߃ࠆ߽ߩߢ㧘ൻቇๆ⌕ߩ᭎ᔨࠍ฽߹ߥ޿>@㧚ᵴᕈ὇߿ࠪ࡝ࠞࠥ࡞ߥߤࡔ࠰
ሹߩᄙ޿ᄙሹ૕ߦ⿠ߎࠆ႐ว߇ᄙߊ㧘⚦ሹᒻ⁁߇ࠗࡦࠢߟ߷ߩࠃ߁ߦᓘߩ⇣ߥࠆㇱಽࠍ߽ߟ╴ဳ߿ᬥဳߩ⚦ሹߩ㓸ว૕ߢ޽ࠆߣ⠨߃ߡ㧘ᰴߩ Kelvinߩᑼࠍㆡ↪ߔࠆ㧚pª 2V J cosT º(12)
exp « m
»
ps
rRT
¬
¼

k1
F  X e oXߎߎߢ㧘F ߪⓨߩㇱ૏ࠍ⴫ࠊߔ㧚ㅦᐲᑼߪߎߎߢ㧘Vm ߪๆ⌕⾰ߩಽሶኈⓍ㧘Jߪๆ⌕⾰ߩ⴫㕙ᒛജ㧘Tߪធ⸅ⷺߢ޽ࠆ㧚ߎߩᑼ߆ࠄᲫ▤ඨᓘ rߣ⫳᳇ߩ⋧ኻ࿶ p/ps ߩ㑐ଥ߇᳞߼ࠄࠇࠆ㧚߽ߒᲫ▤ߩᒻ⁁ߣߒߡ㧘౉ญ߇⁜ߊ㧘ౝㇱ߇ᐢ޿ࠗࡦࠢ
ߟ߷ဳߢ޽ߞߚ႐ว㧘⫳᳇߇ಝ❗ߒ㧘ౝㇱ߇ᶧߢḩߚߐࠇߡ޿ߊߣ߈ߪౝㇱߩᐢ޿ᓘ߇ᡰ㈩⊛ߦߥࠅ㧘ㅒߦḩߚߐࠇߡ޿ࠆᶧ߇⫳⊒ߔࠆߣ߈ߦߪ౉
ญߩ⁜޿ᓘ߇ᡰ㈩⊛ߦߥࠆ㧚ߘߩ⚿ᨐ㧘⫳᳇⣕㔌ᦛ✢ߪಝ❗ๆ⌕ᦛ✢ࠍ਄߹ࠊࠆߣ޿߁╬᷷✢ߩጁᱧ⃻⽎ࠍ⺑᣿ߔࠆߎߣ߇ߢ߈ࠆ㧚Ძ▤ಝ❗ℂ⺰ߦ߅޿ߡߪ㧘ⶄ㔀ߥๆ⌕․ᕈߪሹߩᒻ⁁߿ᄢ߈ߐߩ
ᄙ᭽ᕈߦ⿠࿃ߔࠆߣ⠨߃ࠆ߇㧘ታ㓙ߦߪඨᓘ߇╬ߒ޿౞╴ᒻߩᲫ▤ߦ߅޿ߡ߽ጁᱧ⃻⽎ߪ⷗ࠄࠇࠆ㧚ᄙሹ૕ౝㇱߩๆ⌕⃻⽎ࠍߔߴߡ‫⚦ޟ‬ሹౝߦ߅ߌࠆ
ಝ❗‫ࠅߪ߿ߪߩࠆ߃ᝒߣޠ‬ήℂ߇޽ࠆ㧚 ᄙ㊀ቯᏱ⁁ᘒ㑆ߩㆫ⒖
⚦ሹౝߩๆ⌕⃻⽎ߪ㧘৻⥸ߦ㧘ๆ⌕㊂߇ዋߥ޿ᤨߪ⚦ሹߩౝოߦ‫ޟ‬ጀ⁁ๆ⌕‫ࠅߎ⿠߇ޠ‬㧘ๆ⌕㊂
߇ᄙߊߥࠆߦᓥߞߡ⚦ሹౝㇱߢ‫ޟ‬Ძ▤ಝ❗‫⿠߇ޠ‬ߎࠆߣ⠨߃ࠄࠇࠆ㧚ࡒࠢࡠᄙሹ૕ߦ߅޿ߡߪ⚦ሹ
ߩኈⓍ߇⴫㕙Ⓧߦኻߒߡዊߐ޿ߚ߼㧘⴫㕙ๆ⌕߇

વᾲ 2006 ᐕ 1 ᦬

(13)

k2
X o
Xe  F- 16 -dX
dt

k1FX e  k2 X



dF
dt

(14)

ߎߎߢ㧘X+F=N (=৻ቯ)ߣߔࠆߣ㧘ᑼ 14 ߪᰴᑼߩࠃ߁ߦߥࠆ㧚
dX
dt

ª
§
k · º
k1 X e « N  ¨¨1  2 ¸¸ X »k1X e ¹
©
¬«
¼»

(15)

ๆ⌕㧘⣕⌕ߩᐔⴧቯᢙࠍ K=k2/k1Xe ߅ࠃ߮ k1Xe =D
ๆ⌕㊂

Ძ▤ಝ❗

N2
ๆ⌕
⣕⌕

N1
ጀ⁁ๆ⌕

K1’
K2’
࿶ജ㧘ൻቇࡐ࠹ࡦࠪࡖ࡞㧘ๆ⌕ᐔⴧቯᢙ╬࿑ 3 ࡔ࠰ᄙሹ૕ߩๆ⌕╬᷷✢㧔V ဳ㧕[8]J. HTSJ, Vol. 45, No. 190

․㓸㧦ๆ⌕ߩ਎⇇̆ࡒࠢࡠ߆ࠄࡑࠢࡠ㧘ߘߒߡࠪࠬ࠹ࡓ̆
ߣߔࠆߣᑼ 15 ߪᰴᑼߩࠃ߁ߦߥࠆ㧚dX
dt

D >N  1  K X @ᣇ᥏ߩวᚑ࠯ࠝ࡜ࠗ࠻ߢ޽ࠆ㧚ᄤὼ࠯ࠝ࡜ࠗ࠻ߩ
ࡎ࡯ࠫࡖࠨࠗ࠻ߣหߓ࠻ࡐࡠࠫ࡯㧔᭴ㅧࠦ࡯࠼
FAU [10]㧕ࠍ߽ߟ㧚৻⇟ᄢ߈ߥሹ㧔ࠬ࡯ࡄ࡯ࠤ࡯
ࠫ㧕ߩ౉ญߪ౞ᒻߩ 12 ຬⅣ㧔⋥ᓘ 0.74 nm㧕ߢ޽ࠅ㧘1 ࠤ࡯ࠫ޽ߚࠅ 4 ߟߩ౉ญߢ㓞ߩࠬ࡯ࡄ࡯ࠤ
࡯ࠫߣㅪ⚿ߒߡ޿ࠆ㧚Na ဳߩ႐ว㧘න૏⚵ᚑߪ
NanAlnSi192-nO384·xH 2O ߢ޽ࠅ㧘 n ߇ 48㨪76 ࠍ Yဳ㧘77㨪96 ࠍ X ဳߣ๭߱㧚n ߩჇടߣߣ߽ߦⷫ᳓
ᕈ߇㜞߹ࠆ߇㧘n=58 ߩࡎ࡯ࠫࡖࠨࠗ࠻ߦ߅޿ߡ߽
x=240 ߣᄙߊߩๆ⌕᳓ࠍ߽ߟ㧚߹ߚਥߥࠞ࠴ࠝࡦ
੤឵ࠨࠗ࠻ߪࠬ࡯ࡄ࡯ࠤ࡯ࠫ߅ࠃ߮࠰࡯࠳࡜ࠗ࠻
ࠤ࡯ࠫౝߦ޽ࠆ㧚࠯ࠝ࡜ࠗ࠻ߩ᳓⫳᳇ๆ⌕╬᷷✢ߪ৻⥸ߦ
Langmuir ဳ㧔࿑ 1 ߩ I ဳ㧕ߢ޽ࠅ㧘නಽሶጀๆ⌕ဳߣ⠨߃ࠄࠇࠆ㧚ߒ߆ߒ㧘ᰴߩ 2 ߟߩታ㛎⚿ᨐߪනಽሶጀๆ⌕ߢߪߥ޿ߎߣࠍ␜ߒߡ޿ࠆ㧚৻ߟ⋡ߪ㧘ಽሶභ᦭ᢿ㕙Ⓧ(0.125nm2 ⒟ᐲ)ࠍ઒ቯߒ㧘ᑼ
10 ߆ࠄ᳞߼ࠄࠇߚ᦭ലๆ⌕㕙Ⓧ߇㧘⚿᥏ቇ⊛ߦ᳞߼ࠄࠇࠆ࠯ࠝ࡜ࠗ࠻⚦ሹߩ⴫㕙Ⓧࠃࠅᄢ߈ߊߥࠆ
ߣ޿߁ታ㛎⚿ᨐߢ޽ࠆ[11]㧚ੑߟ⋡ߪᓸಽๆ⌕ᾲ߇ๆ⌕㊂ߦࠃߞߡᄌൻߔࠆߣ޿߁ታ㛎⚿ᨐߢ޽ࠆ[12-14]㧚ᓸಽๆ⌕ᾲ q ߪ n mol ߩๆ⌕߇⚳ࠊߞߡ޿ࠆߣߎࠈ߳㧘ߐࠄߦๆ⌕⾰'n mol ࠍๆ⌕ߐߖߚߣ߈ߩ⊒↢ᾲ㊂ࠍ'q ߣߒ㧘q='q/'n ߣቯ⟵ߐࠇࠆ㧚ታ㛎ߦ߅޿ߡߪ㧘ๆ⌕ߩㆊ⒟ߢ⊒↢ߔࠆᾲࠍᾲ㊂⸘ߢ᷹ቯߔࠆߎߣߦࠃࠅ᳞߼ࠄࠇࠆ㧚߽ߒ᳓⫳᳇߇ߔߴߡනಽሶጀๆ⌕ࠍߔࠆߥࠄ߫㧘ᓸಽๆ⌕ᾲߪๆ⌕㊂ߦଐሽߖߕߦ৻ቯߦߥࠄߥߌࠇ߫ߥ
ࠄߥ޿߇㧘ታ㓙ߪ㧘ๆ⌕㊂ߩᄌൻߦ઻޿ᓸಽๆ⌕ᾲ߇ᄌൻߔࠆ㧚ή᳓࠯ࠝ࡜ࠗ࠻㧘߅ࠃ߮⚿᥏᳓ࠍ઻߁࠯ࠝ࡜ࠗ

(16)ߐࠄߦๆ⌕㧘⣕⌕߇දห⊛ߢ޽ࠆߣ઒ቯߔࠆ㧚ߔߥࠊߜ k ߇ᣢߦๆ⌕ߒߡ޿ࠆ X ߩᢙߦଐሽߔࠆߣ
⠨߃㧘એਅߩࠃ߁ߦ઒ቯߔࠆ㧚
(17)
K K X
K c exp> KX / N @ߛߚߒ㧘K’ߣKߪቯᢙߢ޽ࠆ㧚੹㧘ᑼ 17 ࠍᑼ 16ߦઍ౉ߒ㧘dX/dt=0 ߣߔࠆߣ㧘ቯᏱ⁁ᘒߦ߅ߌࠆๆ
⌕㊂ X ߣᐔⴧቯᢙ K’ߩ㑐ଥ߇᳞߼ࠄࠇࠆ㧚K>4 ߩ႐ว㧘K1’< K’< K2’ߩ㑆ߩ୯ߦኻߒߡ 3 ߟߩᐔⴧ⸃
߇ሽ࿷ߔࠆ㧔࿑ 3 ෳᾖ㧕㧚ߘߩ߁ߜߩ 2 ߟߩ⁁ᘒߪ቟ቯߢ㧘╙ 3 ߩ߽ߩߪਇ቟ቯߢ޽ࠆ㧔࿑ 3 ߩὐ✢ߩ㗔ၞߪਇ቟ቯ㗔ၞߣߥࠆ㧕㧚ߎࠇߪ㧘1 ᰴ⋧ォ⒖
ߩ van der Waals ߩℂ⺰ߣ㕖Ᏹߦ⦟ߊૃߡ޿ࠆ߇㧘෩ኒߦኻᔕߟߌࠆߩߪ࿎㔍ߢ޽ࠆ㧚৻ᣇ㧘K4 ߩ႐ว㧘ๆ⌕㊂ߪๆ⌕ᐔⴧቯᢙ K’ߩ৻ଔ㑐ᢙߣߥࠆߚ߼㧘ጁᱧ⃻⽎ߪ⃻ࠇߥ޿㧚ߎߎߢขࠅ਄ߍߚࡕ
࠺࡞ߦ߅޿ߡߪ㧘̌ๆ⌕㧘⣕⌕߇දหᕈ̍ࠍ⴫ࠊߔ
ࡄ࡜ࡔ࡯࠲K߇ጁᱧ⃻⽎ࠍ․ᓽઃߌߡ޿ࠆ߇㧘ಽሶ⺰⊛ߦ⠨߃ࠆߣ㧘ๆ⌕೷㧙ๆ⌕⾰ߩ⋧੕૞↪ߣๆ⌕⾰㧙ๆ⌕⾰ߩ⋧੕૞↪ߩᄢዊ㑐ଥ㧘޽ࠆ޿ߪ㧘⚦ሹߩ⴫㕙Ⓧߣ૕Ⓧߩᄢዊ㑐ଥ㧘ࠃࠅ⹦⚦ߦߪ㧘⴫㕙ߩ᭴ㅧ߿⚦ሹߩᒻ⁁߇‫ޟ‬ጀ⁁ๆ⌕‫ޟߣޠ‬Ძ▤ಝ❗‫ޠ‬㑆ߩጁᱧ⃻⽎ߦᓇ㗀ࠍਈ߃ࠆߣ⠨߃ࠄࠇࠆ㧚ߘߎߢ㧘ᰴߦๆ⌕ߩಽሶࠪࡒࡘ࡟࡯࡚ࠪࡦߦߟ޿
ߡᦨㄭߩ⎇ⓥേะࠍㅀߴ㧘ߤߩ⒟ᐲ߹ߢℂ⺰⸘▚ߦࠃࠅๆ⌕⃻⽎ࠍ⴫⃻ߢ߈ࠆ߆⠨ኤߔࠆ㧚ๆ⌕⃻⽎ߩಽሶࠪࡒࡘ࡟࡯࡚ࠪࡦ
ࡒࠢࡠᄙሹ૕
ࡒࠢࡠᄙሹ૕ߣߒߡ X ဳ߅ࠃ߮ Y ဳ࠯ࠝ࡜ࠗ࠻
߳ߩ᳓⫳᳇ๆ⌕ߦߟ޿ߡ⠨߃ࠆ㧚࠯ࠝ࡜ࠗ࠻ߪᄙ
ሹ⾰⚿᥏ᕈߩࠕ࡞ࡒࡁࠤࠗ㉄Ⴎ߅ࠃ߮ࡔ࠲ࡠࠤࠗ
㉄Ⴎߩ✚⒓ߢ޽ࠅ㧘ᄙሹ⾰ߩⓣߩ౉ญᓘ߇ 0.4㨪
0.8 nm ⒟ᐲߢ޽ࠆߚ߼㧘ߘߩⓣߩ౉ญࠃࠅዊߐߥ
ಽሶߪ⚦ሹౝߦㅴ౉ߢ߈ࠆ߇㧘ᄢ߈ߥಽሶߪㅴ౉
ߢ߈ߥ޿ߣ޿߁ಽሶ߰ࠆ޿ߩ૞↪ࠍ߽ߟ[9]㧚߹ߚๆ⌕࡮⸅ᇦ૞↪ߥߤߦኻߔࠆ᧚ᢱߣߒߡ೑↪ߐࠇߡ޿ࠆ㧚࠯ࠝ࡜ࠗ࠻ߦߪ᭽‫ߥޘ‬⒳㘃߇޽ࠅ㧘ߘߩᕈ⾰ߪߘߩ⚦ሹ᭴ㅧߦᄢ߈ߊଐሽߒߡ޿ࠆ߇㧘ߎߎߢߪᲧセ⊛ᄢ߈ߥ⚦ሹࠍ߽ߟ X ဳ߅ࠃ߮ Y ဳߩ࠯ࠝ࡜ࠗ࠻ߦߟ޿ߡ⠨߃ࠆ㧚X ဳ߅ࠃ߮ Y ဳߩ࠯ࠝ࡜ࠗ࠻ߪ࿑ 4 ߦ␜ߐࠇࠃ߁ߦ࠰࡯࠳࡜ࠗ࠻ࠤ࡯
ࠫߩ 6 ຬⅣߤ߁ߒ߇ㅪ⚿ߒ㧘3 ᰴర⚦ሹࠍ߽ߟ┙વᾲ 2006 ᐕ 1 ᦬

࿑ 4 ࠯ࠝ࡜ࠗ࠻ FAU㧔Ꮐ࿑㧕ߣ࠰࡯࠳࡜ࠗ࠻ࠤ
࡯ࠫ㧔ฝ࿑㧕ߩ㛽ᩰ᭴ㅧ㧚T ේሶ㧔Si ේሶ㧘޽ࠆ
޿ߪ Al ේሶ㧕ߪ⋥✢ߩ੤ὐߦ޽ࠅ㧘㉄⚛ේሶߪฦ✢ಽߩਛὐߦ޽ࠆ㧚- 17 -J. HTSJ, Vol. 45, No. 190

․㓸㧦ๆ⌕ߩ਎⇇̆ࡒࠢࡠ߆ࠄࡑࠢࡠ㧘ߘߒߡࠪࠬ࠹ࡓ̆

વᾲ 2006 ᐕ 1 ᦬- 18 -

ࠇࠄߩᓸಽๆ⌕ᾲ߆ࠄ੍ᗐߐࠇࠆ᭴ㅧ⊛ᕈ⾰ߪ㧘ಽሶࠪࡒࡘ࡟࡯࡚ࠪࡦߩ⸘▚⚿ᨐࠍ⸃ᨆߔࠆߎߣ
ߦࠃࠅᬌ⸽ߐࠇߚ㧚Shirono ࠄ[22]ߪߐࠄߦ㧘᳓ಽሶࡕ࠺࡞ߣߒߡ㧘ࡃ࡞ࠢߩ᳓ಽሶࡕ࠺࡞ߢ޽ࠆ
SPC/E ߩઍࠊࠅߦ᳓ಽሶౝߩ㔚⩄ᄌേࠍ⸵ߒߚࡕ
࠺ ࡞ SPC-FQ[23] ࠍ ↪ ޿ߡ ห ᭽ߩ ⸘▚ ࠍ ⴕ޿㧘
SPC-FQ ࡕ࠺࡞ࠍ↪޿ߚᣇ߇㧚ᓸಽๆ⌕ᾲߩ N ߦኻߔࠆᄌേ߇ᄢ߈ߊ㧘ታ㛎୯ߦࠃߊ৻⥌ߔࠆߎߣࠍ᣿ࠄ߆ߦߒߚ㧚ߎࠇࠄߩ⸘▚⚿ᨐߪࡒࠢࡠᄙሹ
૕ౝㇱߩๆ⌕ߢ޽ߞߡ߽㧘න⚐ߥනಽሶጀๆ⌕ߢߪߥ޿ߎߣࠍ␜ߒߡ޿ࠆ㧚150|dH/dN|, -dUi-j/dN /kJ·mol-1|dH/dN|-dUW-W /dN-dUW-Z /dN-dUZ-Z /dN

100

50
Heat of Vaporization of Water

0

-50
0

50

100

150

200

N

150

-1

|dH/dN|-dUW-W /dN|dH/dN|, -dUi-j/dN /kJ·mol࠻ߩ⚿᥏᭴ㅧ㧔㘻๺⁁ᘒ߹ߢ᳓⫳᳇ࠍๆ⌕ߒߚ⁁ᘒ㧕ߦߟ޿ߡߪ⹦⚦ߦߘߩ᭴ㅧ߇⍮ࠄࠇߡ޿ࠆ߇
[10]㧘ή᳓⁁ᘒ߆ࠄ㘻๺⁁ᘒߦ⥋ࠆ߹ߢ㧘ߤߩࠃ߁ߦ࠯ࠝ࡜ࠗ࠻ౝㇱߢ᳓⫳᳇ๆ⌕߇ㅴࠎߢ޿ߊ߆
ߦߟ޿ߡߩಽሶ⺰⊛ឬ௝ߪᔅߕߒ߽᣿ࠄ߆ߢߪߥ
޿㧚ߎߩࠃ߁ߥߣ߈㧘ಽሶࠪࡒࡘ࡟࡯࡚ࠪࡦߪ᦭
ലߥ⸃ᨆᚻᴺߣߥࠆ㧚࠯ࠝ࡜ࠗ࠻ߩ㛽ᩰ᭴ㅧࠍౣ
⃻ߔࠆࡐ࠹ࡦࠪࡖ࡞㑐ᢙߪߎࠇ߹ߢᢙᄙߊឭ᩺ߐ
ࠇߡ޿ࠆ߇[15-19] 㧘᭽‫ߥޘ‬㛽ᩰ᭴ㅧࠍ߽ߟ࠯ࠝ࡜
ࠗ࠻ࠍߔߴߡ⴫⃻ߢ߈ࠆࠃ߁ߥ᳢↪ᕈߩ޽ࠆࡐ࠹
ࡦࠪࡖ࡞㑐ᢙߣ޿߁߽ߩߪሽ࿷ߒߥ޿㧚ߐࠄߦ㧘‫ߣ࠻ࠗ࡜ࠝ࠯ޟ‬᳓‫ޟߥ߁ࠃߩޠ‬ๆ⌕೷ߣๆ⌕⾰‫ޠ‬ߩಽሶࠪࡒࡘ࡟࡯࡚ࠪࡦߦ߅޿ߡߪ㧘ๆ⌕೷㧙ๆ⌕⾰㑆ߩࡐ࠹ࡦࠪࡖ࡞㑐ᢙࠍߤߩࠃ߁ߦቯ߼ࠆ߆
߇ࡐࠗࡦ࠻ߣߥࠆ㧚 Shirono ࠄ[20]ߪ᳓ಽሶࡕ࠺
࡞ߣߒߡ SPC/E [21]ࠍ↪޿ߡ㧘300K ߦ߅ߌࠆ᭽‫ޘ‬ߥ ฽ ᳓ ㊂ ߩ NaX ဳ (Si/Al=1.0) ߅ ࠃ ߮ NaY ဳ(Si/Al=2.0) ࠯ࠝ࡜ࠗ࠻ߩಽሶേജቇࠪࡒࡘ࡟࡯
࡚ࠪࡦࠍⴕߞߚ㧚࿑ 5 ߪ࠯ࠝ࡜ࠗ࠻ߦ᳓⫳᳇߇ๆ⌕ߐࠇࠆ㓙ߦ⊒↢ߔࠆᓸಽๆ⌕ᾲߦߟ޿ߡߩ⸘▚⚿ᨐߢ޽ࠆ㧚⸘▚୯ߪታ㛎୯[12-14]ࠃࠅ⧯ᐓᄢ߈
޿߇㧘ࠣ࡜ࡈߩ௑ะ㧘޽ࠆ޿ߪ NaX ဳ࠯ࠝ࡜ࠗ࠻
ߩᓸಽๆ⌕ᾲߩᣇ߇ NaY ဳ࠯ࠝ࡜ࠗ࠻ߩߘࠇࠃ
ࠅ߽ᄢ߈޿ὐߪታ㛎⚿ᨐߣ৻⥌ߒߡ޿ࠆ㧚߹ߚߎࠇࠄߩࠣ࡜ࡈࠃࠅ㧘NaX ဳ㧘NaY ဳ࠯ࠝ࡜ࠗ࠻߳
ߩ᳓⫳᳇ๆ⌕ߪએਅߩ 3 ߟߩ㗔ၞߦಽߌߡ⠨߃ࠆߎߣ߇ߢ߈ࠆߎߣ߇ࠊ߆ࠆ㧚ߔߥࠊߜ(1)㕖Ᏹߦᄢ߈ߥๆ⌕ᾲࠍ⊒↢ߔࠆ㗔ၞ㧔ⷫ᳓ᕈࠨࠗ࠻߳ߩๆ
⌕㧕㧘(2)ᓸಽๆ⌕ᾲ߇ๆ⌕㊂ߦࠃࠄߕߦ৻ቯߩ㗔ၞ㧘(3)ๆ⌕ᾲ߇ᷫዋߒ㧘᳓ߩಝ❗ᾲߦㄭߠߊ㗔ၞ㧔Ძ▤ಝ❗㧕ߩ 3 ߟߩ㗔ၞߢ޽ࠆ㧚ߐࠄߦ㧘ᓸಽๆ⌕ᾲ߇ߤߩಽሶ㑆ߩ⋧੕૞↪ߦࠃߞߡ⊒↢ߒߚ߆ࠍ⺞ߴࠆߚ߼ߦ㧘ᓸಽๆ⌕ᾲࠍ᳓ಽሶ㧙࠯ࠝ࡜ࠗ࠻ේሶ㑆㧘᳓ಽሶ㑆㧘࠯ࠝ࡜ࠗ࠻ේሶ㑆ߦ௛ߊ⋧੕૞↪ߦ⿠࿃ߔࠆᓸಽๆ⌕ᾲߦಽ⸃ߒߚ㧚᳓ಽሶ㧙࠯ࠝ࡜ࠗ࠻ේሶ㑆ߩ⋧੕૞↪ߦ⿠࿃ߔࠆᓸಽ
ๆ⌕ᾲߦ߅޿ߡ㧘NaX ဳ࠯ࠝ࡜ࠗ࠻ߢߪਛ㑆ߩ฽
᳓㊂ၞߦᐔမߥ㗔ၞ߇޽ࠆ߇㧘NaY ဳ࠯ࠝ࡜ࠗ࠻
ߢߪᐔမߥ㗔ၞ߇ߥ޿㧚NaX ဳ࠯ࠝ࡜ࠗ࠻ߢߪ㧘ๆ⌕㊂ߦࠃࠄߕ৻ቯߩๆ⌕ᾲ߇⊒↢ߔࠆߎߣ߆ࠄ㧘࠯ࠝ࡜ࠗ࠻ߩౝოߦනಽሶጀๆ⌕ࠍߒߡ޿ࠆߣ੍
ᗐߐࠇࠆ߇㧘NaY ဳ࠯ࠝ࡜ࠗ࠻ߢߪ㧘ๆ⌕㊂߇Ⴧ
߃ࠆߣๆ⌕ᾲ߇ዊߐߊߥࠆߎߣ߆ࠄ㧘㒰‫ߦޘ‬ਇ቟ቯߥ૏⟎ߦๆ⌕ߔࠆࠃ߁ߦߥࠆߣ⠨߃ࠄࠇࠆ㧚ߎ-dUW-Z /dN-dUZ-Z /dN

100

50
Heat of Vaporization of Water

0

-50
0

50

100

150

200

N

࿑ 5 NaX ဳ㧔਄࿑㧕㧘 NaY ဳ㧔ਅ࿑㧕࠯ࠝ࡜ࠗ࠻߳ߩ᳓⫳᳇ๆ⌕ߦ߅ߌࠆᓸಽๆ⌕ᾲ㧘|H/N|㧘߅ࠃ߮᳓㧙࠯ࠝ࡜ࠗ࠻㧘᳓㧙᳓㧘࠯ࠗ࡜ࠗ࠻㧙࠯ࠝ࡜ࠗ࠻⋧੕૞↪ߦၮߠߊᓸಽๆ⌕ᾲ㧘-UW-Z/N㧘-UW-W/㧘-UZ-Z/N ߣන૏ᩰሶౝߩ᳓ಽሶᢙ N ߩ㑐ଥ㧚᳓ಽሶߪ SPC/E ࡕ࠺࡞ߢ޽ࠆ [20]㧚

J. HTSJ, Vol. 45, No. 190

․㓸㧦ๆ⌕ߩ਎⇇̆ࡒࠢࡠ߆ࠄࡑࠢࡠ㧘ߘߒߡࠪࠬ࠹ࡓ̆

ࡔ࠰ᄙሹ૕
ࡔ࠰ᄙሹ૕ߣߒߡࠝ࡯࠳࡯࠼ࡔ࠰ࡐ࡯࡜ࠬࠪ࡝
ࠞࠍ⠨߃ࠆ㧚ࠝ࡯࠳࡯࠼ࡔ࠰ࡐ࡯࡜ࠬࠪ࡝ࠞߪဋ
৻ߥ౞╴ᒻߩࡔ࠰ሹࠍ߽ߟੑ㉄ൻࠤࠗ⚛ߩࡔ࠰ᄙሹ૕ߢ޽ࠆ㧚࠯ࠝ࡜ࠗ࠻ߩ⚦ሹߢߪኻᔕߢ߈ߥ޿
ᄢ߈ߥಽሶ߇㑐ਈߔࠆๆ⌕࡮⸅ᇦ૞↪ߥߤߦኻߔ
ࠆᣂ᧚ᢱߣߒߡᦼᓙߐࠇߡ޿ࠆ [9]㧚᳓ߩๆ⌕ߦኻߒߡߪࡔ࠰ሹߩࠨࠗ࠭ߦߒߚ߇ߞߡ⇣ߥߞߚๆ⌕╬᷷✢ࠍ߽ߟߎߣ㧘ࠪ࡝ࠞࠥ࡞ࠃࠅ߽ᄢ߈ߥᦨ
ᄢๆ⌕㊂ࠍ߽ߟ႐ว߇޽ࠆߎߣ㧘ጁᱧ⃻⽎ࠍ␜ߔ႐ว߇޽ࠆߎߣ╬߇ႎ๔ߐࠇߡ޿ࠆ[24]㧚ࡔ࠰ᄙሹ૕ߪ৻⥸ߦࠕࡕ࡞ࡈࠔࠬߢ޽ࠆ߇㧘⵾ᴺߦࠃߞ
ߡߪ⚿᥏ᚑಽ߇ᄙߊ฽߹ࠇࠆ㧚ࡔ࠰ᄙሹ૕ߩಽሶࡕ࠺࡞ߣߒߡߪ㧘ࠕࡕ࡞ࡈࠔ
ࠬ⁁ߩ౞╴ࠍ⸘▚ߦࠃࠅ૞ࠅ಴ߔᣇᴺ㧘ℂᗐ⊛ߥ౞╴ᒻࠍ઒ቯߔࠆᣇᴺߥߤ᭽‫߇ࠆ޽ߢޘ‬㧘Shirono
ࠄ [25] ߪ D ⍹⧷ߩ⚿᥏ߦ౞╴⁁ߩⓣࠍ㐿ߌࠆߎߣߢࠝ࡯࠳࡯࠼ࡔ࠰ࡐ࡯࡜ࠬࠪ࡝ࠞߩಽሶࡕ࠺࡞ߣ
ߒߚ㧚ಽሶࠪࡒࡘ࡟࡯࡚ࠪࡦߩࠕࡦࠨࡦࡉ࡞ߣߒ
ߡߪ㧘ࠣ࡜ࡦ࠼ࠞࡁ࠾ࠞ࡞㓸࿅㧔PVT ৻ቯ)ࠍ↪޿ࠆߣๆ⌕╬᷷✢ࠍ᳞߼ࠆߎߣ߇ߢ߈㧘ࠞࡁ࠾ࠞ࡞
㓸࿅㧔NVT ৻ቯ㧕ࠍ↪޿ࠆߣ㧘࿑ 3 ߦ␜ߐࠇࠆࠃ
߁ߥ S ሼᦛ✢߇᳞߼ࠄࠇࠆ㧚㧔ᱜ⏕ߦߪ㧘࿑ 3 ߦ߅ߌࠆᮮゲߪࠛࡀ࡞ࠡ࡯ߢߪߥߊ㧘⥄↱ࠛࡀ࡞ࠡ࡯ߢ޽ࠆߚ߼㧘ࠞࡁ࠾ࠞ࡞㓸࿅ߩ⸘▚ߦട߃ߡ㧘⥄↱ࠛࡀ࡞ࠡ࡯ߩ⸘▚ࠍߔࠆᔅⷐ߇޽ࠆ㧚㧕
Shirono ࠄ[25]ߪ⋥ᓘ߇ 2.0 nm ߣ 2.86 nm ߩࠝ࡯

(a-I)

(b-I)

(a-II)(b-II)

࠳࡯࠼ࡔ࠰ࡐ࡯࡜ࠬࠪ࡝ࠞ߳ߩ᳓⫳᳇ๆ⌕ࠍኻ⽎ߣߒߡ㧘300 K ߦ߅ߌࠆ NVT ࠕࡦࠨࡦࡉ࡞ߩಽሶ
േജቇࠪࡒࡘ࡟࡯࡚ࠪࡦࠍⴕߞߚ㧚࿑ 6 ߪ⸘▚⚿ᨐߩ৻଀ߢ޽ࠆ㧚⋥ᓘ߇ 2.0 nm ߩ႐วߪ㧘ߪߓ߼ߦጀ⁁ๆ⌕߇⿠ߎࠆ߇㧘⚦ሹ⴫㕙߇ߔߴߡ᳓ߢⷒ
ࠊࠇࠆ೨ߦಝ❗߇ᆎ߹ࠆ᭽ሶ߇ᝒ߃ࠄࠇߡ޿ࠆ㧚ߐࠄߦ㧘࿑ 3 ߦ␜ߐࠇࠆࠃ߁ߥൻቇࡐ࠹ࡦࠪࡖ࡞
㧙ๆ⌕㊂ᦛ✢ߪ޽߹ࠅ᣿⏕ߥ S ሼᦛ✢ߦߥࠄߥ޿
ߎߣ߇␜ߐࠇߚ㧚৻ᣇ㧘⋥ᓘ߇ 2.86 nm ߩ႐วߪ㧘ߪߓ߼ߦጀ⁁ๆ⌕߇⿠ߎࠅ㧘⚦ሹ⴫㕙߇ߔߴߡ᳓
ߢⷒࠊࠇߚᓟ㧘Ძ▤ಝ❗߳⒖ࠆ᭽ሶ߇ᝒ߃ࠄࠇߚ㧚߹ߚ㧘ൻቇࡐ࠹ࡦࠪࡖ࡞㧙ๆ⌕㊂ᦛ✢ߪ᣿⏕ߥ Sሼᦛ✢ߦߥࠅ㧘࿑ 3(b-II)ߦ␜ߐࠇࠆࠃ߁ߥ⁁ᘒߪਇ቟ቯߢ޽ࠆߎߣ߇␜ߐࠇߚ㧚ታ㛎ߦ߅޿ߡߪ㧘
1.4 nm એਅߩ⋥ᓘߩࠝ࡯࠳࡯࠼ࡔ࠰ࡐ࡯࡜ࠬࠪ࡝
ࠞߢߪ╬᷷ๆ⌕✢ߦࡅࠬ࠹࡝ࠪࠬ߇⷗ࠄࠇߥ޿߇㧘ߘࠇએ਄ߩᄢ߈ߐߩ⚦ሹᓘࠍ߽ߟ߽ߩߢߪࡅࠬ࠹
࡝ࠪࠬ߇⷗ࠄࠇࠆߎߣ߇⍮ࠄࠇߡ޿ࠆ[26]㧚⋥ᓘ߇ᄢ߈޿ᣇ߇᣿⏕ߥ S ሼᦛ✢ߦߥࠆߣ޿߁⸘▚⚿ᨐߪᅷᒰߥ⚿ᨐߣ޿߃ࠆ㧚߹ߚᓸಽๆ⌕ᾲߦߟ޿ߡߪ㧘2 ߟߩ⚦ሹߣ߽ๆ⌕㊂ߦࠃࠄߔ߶߷৻ቯߦ
ߥࠆߣ޿߁௑ะ㧘ߘߩ୯ߪታ㛎⚿ᨐ[27]ࠍࠃߊౣ
⃻ߒߡ޿ࠆ㧚
߅ࠊࠅߦ
ᄙሹ૕ౝㇱߩๆ⌕⃻⽎ߦߟ޿ߡ㧘ๆ⌕ࡕ࠺࡞ߩ⸃⺑㧘߅ࠃ߮ಽሶࠪࡒࡘ࡟࡯࡚ࠪࡦߩᦨㄭߩ⎇ⓥ
ࠍ⚫੺ߒߚ㧚ࡒࠢࡠᄙሹ૕㧘ࡑࠢࡠᄙሹ૕ߩߺߥ
ࠄߕ㧘ࡔ࠰ᄙሹ૕ߦߟ޿ߡ߽᭴ㅧ߿⚵ᚑߣๆ⌕․ᕈߩ㑐ଥ߇ᰴ╙ߦ᣿ࠄ߆ߦߥࠅߟߟ޽ࠆ㧚ㄭ޿዁᧪㧘↪ㅜߦᔕߓߚ᧚ᢱ⸳⸘߇⥄↱ߢ߈ࠆࠃ߁ߦߥ
ࠆߎߣ߇ᦼᓙߐࠇࠆ㧚ෳ⠨ᢥ₂
[1] Raman, N. K., Anderson, M. T. and Brinker, C. J.,(a-III)

Chem. Mater., 8 (1996) 1682.
[2] Davis, M. E., Nature, 417 (2002) 813.
[3] Sing, K. S. W., Everett, D. H., Havic, R. A. W.,
Moscou, L., Pierotti, R. A., Rouquerol, J. and(b-III)

Siemieniewska, T., Pure Appl. Chem., 57 (1985)603.

࿑ 6 (a) ⋥ᓘ߇ 2 nm ߣ(b) 2.86 nm ߩࠝ࡯࠳࡯࠼ࡔ
࠰ࡐ࡯࡜ࠬࠪ࡝ࠞ߳ߩ᳓⫳᳇ๆ⌕ߩ NVT ಽሶࠪࡒࡘ࡟࡯࡚ࠪࡦ㧔᏷ 0.5 nm ߩᢿ㕙࿑㧕㧚᳓ಽሶߩᢙߪ
਄࿑߇ (a-I) 48㧘(a-II) 144㧘(a-III) 288㧘ਅ࿑߇(b-I)
384㧘(b-II) 480㧘(b-III) 672 [25]㧚

વᾲ 2006 ᐕ 1 ᦬[4] Dąbrowski, A., Adv. Coll. Interface Sci., 93(2001) 135.
[5] Brunauer, S., Emmett, P. H. and Teller, E., J. Am.

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[16] Demontis, P., Sufftirri, G. B., Bordiga, S. andChem. Soc., 60 (1938) 309.
[6] 㜞ᯅస᣿㧘ႮᎹੑᦶ✬㧘⃻ઍߩ‛ℂൻቇΤ㧘ᦺୖᦠᐫ (1987).
[7] Zsigmondy, R., Z. Anorg. Chem., 71 (1911) 356.
[8] Nicolis, G. and Prigogine, I., Self-Organization in
Nonequilibrium System –From Dissipative
Structure to Order through Fluctuations, John
Wiley & Sons (1977).

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[17] Auerbach, S. M., Henson, N. J., Cheetham, A. K.
and Metiu, H. I., J. Phys. Chem., 99 (1995) 10600.
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[19] Jaramillo, E. and Auerbach, S. M., J. Phys. Chem.
B, 103 (1999) 9586.
[20] Shirono, K., Endo, A. and Daiguji, H., J. Phys.

[9] ዊ㊁ཅᄦ㧘౎ፉᑪ᣿✬㧘࠯ࠝ࡜ࠗ࠻ߩൻቇߣ
Ꮏቇ㧘⻠⺣␠ࠨࠗࠛࡦ࠹ࠖࡈࠖࠢ (2000).
[10] http://www.iza-structure.org/

Chem. B, 109 (2005) 3446.
[21] Brendsen, H. J. C., Grigera, J. R. and Straatsma, T.

[11] ㄭ⮮♖৻㧘⍹Ꮉ㆐㓶㧘቟ㇱ㇚ᄦ✬㧘ๆ⌕ߩ⑼ቇ㧔╙ 2 㧕㧘ਣༀ (2001).
[12] Chuikina, V. K., Kiselev, A. V., Mineyeva, L. V.

P., J. Phys. Chem., 91 (1987) 6269.
[22] Shirono, K. and Daiguji, H., Chem. Phys. Lett.,
417 (2006) 251.
[23] Rick, S. W., Stuart, S. J. and Berne, B. J., J. Chem.

and Muttik, G. G., J. Chem. Soc. Far. Trans. I, 72(1976) 1345.
[13] Dzhigit, O. M., Kieselev, A. V., Mikos, K. N.,
Muttik, G. G. and Rahmanova, T. A., Trans.

Phys., 101 (1994) 6141.
[24] Endo, A., Miyata, T., Inagi, Y., Yamamoto, T.,
Ohmori, T., Akiya, T. and Nakaiwa, M., Proc. of
9th International Conference on Thermal Energy
Storage, Warsaw, Poland (2003) 425.
[25] Shirono, K. and Daiguji, H., Proc. of 2005 AIChE
Annual Meeting (2005) 612f.
[26] Inagaki, S. and Fukushima, Y., Microporous andFaraday Soc., 67 (1971) 458.
[14] Moïse, J. C., Bellat, J. P. and Méthivier, A.,
Microporous and Mesoporous Mater., 43 (2001)
91.
[15] Jackson, R. A. and Catlow, C. R. A., Mol. Simul.,

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[27] Matsumoto, A., Sasaki, T., Nishimiya, N. and1 (1988) 207.

Tsutsumi, K., Coll. Surf. A, 203 (2002) 185.

વᾲ 2006 ᐕ 1 ᦬- 20 -J. HTSJ, Vol. 45, No. 190

․㓸㧦ๆ⌕ߩ਎⇇̆ࡒࠢࡠ߆ࠄࡑࠢࡠ㧘ߘߒߡࠪࠬ࠹ࡓ̆

㜞ኒᐲൻቇ⫾ᾲ᧚ߩ㐿⊒Development of Materials for High Density Cchemical Heat Storageഏ ㉍৻㧔᧲੩Ꮏᬺᄢቇ㧕
Junichi RYU (Tokyo Institute of Technology)
e-mail: cyliu@nr.titech.ac.jp
ᔕ[4,5]㧘㧟ߟ⋡ߪႮൻࠞ࡞ࠪ࠙ࡓ╬ߩ㊄ዻႮߩ᳓๺෻ᔕ[6-9]ߢ޽ࠅ㧘ߘࠇߙࠇએਅߩࠃ߁ߥ෻ᔕᑼ
ߢ⴫ߐࠇࠆ㧚
Zeolite + nH2O ĺ Zeolite•nH2O(1)
MgO + H2O ĺ Mg(OH)2(2)
CaCl2 + nH2O ĺ CaCl2•nH2O(3)ߪߓ߼ߦ
2005 ᐕ 2 ᦬ߦ੩ㇺ⼏ቯᦠ߇⊒ലߐࠇߚ㧚ᛕಎ࿖ᢙߩ໧㗴߿ᢙ୯⋡ᮡߩᩮ᜚ߪߣ߽߆ߊ㧘ᣣᧄߢߪ2012 ᐕ߹ߢߦੑ㉄ൻ὇⚛ឃ಴㊂ࠍ 1990 ᐕᲧߢ 6㧑ߩ೥ᷫ߇᳞߼ࠄࠇߡ޿ࠆ㧚ߒ߆ߒߥ߇ࠄ㧘ੑ㉄ൻ὇⚛ឃ಴㊂ߪჇടߔࠆ৻ᣇߢ޽ࠅ㧘ᢙ୯⋡ᮡߩ㆐ᚑߪ࿎㔍ߢ޽ࠆ㧚ߎߩ໧㗴ࠍ⸃᳿ߔࠆߚ߼ߦߪ㧘⃻ⴕߩൻ⍹ΆᢱߩΆ὾㧔ᶖ⾌㧕ߦࠃࠆࠛࡀ࡞ࠡ࡯ଏ⛎ࠪࠬ࠹ࡓ߆
ࠄ㧘ᧂ೑↪ࠛࡀ࡞ࠡ࡯ࠍ᦭ല೑↪ߔࠆࠛࡀ࡞ࠡ࡯
ଏ⛎ࠪࠬ࠹ࡓ߳ߩォ឵߇ਇนᰳߢ޽ࠆ㧚ᧂ೑↪ࠛࡀ࡞ࠡ࡯ࠍ೑↪ߔࠆᣇᴺߩ৻ߟߣߒߡ㧘↥ᬺឃᾲ╬ߩ⫾ᾲᛛⴚ߿ࠤࡒࠞ࡞ࡅ࡯࠻ࡐࡦࡊᛛⴚߩ㐿⊒߇㊀ⷐߢ޽ࠅ㧘ߔߢߦᄙߊߩ⎇ⓥ߇ㅴ߼ࠄࠇߡ޿
ࠆ[1]㧚߹ߚ㧘ߏߊᦨㄭߢߪ㚂ㇺ࿤ߦ߅ߌࠆ಄ᚱ↪
ߩ಄ᾲḮߣߒߡ㧘ർᶏ㆏ߢ౻႐ߦ⵾ㅧߒߚ᳖ࠍ↪
޿ࠆ‫ޟ‬㔐᳖ャㅍ‛ᵹࠪࠬ࠹ࡓ‫ߩޠ‬ታ⸽⹜㛎߽ᆎ߼ࠄࠇߡ޿ࠆ[2]㧚
ൻቇ⫾ᾲ㧘ߔߥࠊߜ૗ࠄ߆ߩൻቇ෻ᔕߦࠃࠆᾲ
ߩ಴౉ࠅࠍ↪޿ߡ⫾ᾲࠍߔࠆ႐ว㧘ߘߎߢ↪޿ࠆ
෻ᔕߦߪⅣႺ⽶⩄߇ዋߥߊ቟ోߥ᧚ᢱ㧔‛⾰㧕ࠍ↪޿ࠆߎߣ߇␠ળ߳ߩ᥉෸ߦ߅޿ߡ㊀ⷐߢ޽ࠆ㧚ߎߎߢߪ㧘╩⠪ࠄ߇ⴕߥߞߡ޿ࠆ㊄ዻႮ♽᧚ᢱ㐿⊒ߩ᭎ⷐࠍ⚫੺ߒ㧘ߘߩ․ᓽ߿໧㗴ὐ╬ߦߟ޿ߡ⺰ߓࠆ㧚࿕૕ߣ᳓⫳᳇ߣߩ෻ᔕ
ൻቇ⫾ᾲߦ↪޿ࠆ෻ᔕߦߪᄙߊߩ⎇ⓥ଀߇޽ࠆ㧚ߒ߆ߒߥ߇ࠄ , ⅣႺ⽶⩄߿቟ోᕈ╬ࠍ⠨ᘦߔࠆߣ෻ᔕᇦ૕ߣߒߡ᳓⫳᳇ࠍ↪޿ࠆߩ߇ታ↪⊛ߢ޽ࠅ㧘࿕૕᧚ᢱ㧔⫾ᾲ᧚㧕ߣߩ෻ᔕᾲࠍ↪޿ߡ⫾ᾲߔࠆ
ᣇᴺ߇ᅢ߹ߒ޿㧚࿕૕ߣ᳓⫳᳇ߣߩ෻ᔕ᭽ᑼߪ㧘ᄢ߈ߊಽߌߡ㧟ߟߦಽ㘃ߐࠇࠆ㧚㧝ߟ⋡ߪ࠯ࠝ࡜ࠗ࠻߿ࠪ࡝ࠞࠥ
࡞╬ߩ㜞⴫㕙Ⓧ‛⾰⴫㕙߳ߩๆ⌕[3]㧘㧞ߟ⋡ߪ㉄ൻࡑࠣࡀࠪ࠙ࡓ╬ߩ㊄ዻ㉄ൻ‛ߩ᳓㉄ൻ‛ᒻᚑ෻

વᾲ 2006 ᐕ 1 ᦬- 21 -

ߎߎߢ࠯ࠝ࡜ࠗ࠻⴫㕙߳ߩ᳓⫳᳇ๆ⌕ࠍଢቱ⊛
ߦ෻ᔕᑼ(1)ߢ⴫ߒߡ޿ࠆ㧚ߎࠇࠄߩ෻ᔕ߇ᱜ෻ᔕ
㧔᳓๺㧕஥ߦㅴ߻߆㧘ㅒ෻ᔕ㧔⣕᳓㧕஥ߦㅴ߻߆
ߪ㧘෻ᔕ᷷ᐲߣ᳓⫳᳇࿶ߦଐሽߒ㧘෻ᔕᑼ(2)ߣ(3)ߦߟ޿ߡߪᾲജቇ⊛ߦ⸘▚ߔࠆߎߣ߇น⢻ߢ޽ࠆߎߣ߆ࠄ㧘⫾ᾲᠲ૞ࠍⴕߥ߁ᾲḮߩ᷷ᐲߦࠃߞߡ
ㆡቱ᧚ᢱࠍㆬᛯߔࠆߎߣ߇น⢻ߢ޽ࠆ㧚޿ߕࠇߩ෻ᔕߦ߅޿ߡ߽㧘⫾ᾲ⁁ᘒ㧔⣕᳓⁁ᘒ㧕ߦ޽ࠆ᧚ᢱߣ᳓⫳᳇ߣࠍធ⸅ߐߖࠆߎߣߦࠃߞߡ
↢ߕࠆ෻ᔕᾲࠍขࠅ಴ߒ㧔᡼ᾲᠲ૞㧕㧘૶↪ᓟߩ᧚
ᢱࠍടᾲᠲ૞㧔⫾ᾲᠲ૞㧕ߦࠃߞߡౣ↢ߒ㧘ౣᐲ᳓⫳᳇ߣ෻ᔕߐߖࠆߎߣߦࠃߞߡᾲࠍขࠅ಴ߔߎ
ߣ߇ߢ߈ࠆ㧚
࿑㧝ߦ㧘ᐔᚑ 12 ᐕߩ↥ᬺឃᾲ᷷ᐲಽᏓ[10]ࠍ␜
ߔ㧚౞ࠣ࡜ࡈߩᄖ஥߇ో↥ᬺ߆ࠄߩ᷷ᐲಽᏓ㧘ౝ஥߇ᷡ᝹ᬺ߆ࠄߩ᷷ᐲಽᏓࠍ␜ߔ㧚↥ᬺឃᾲో૕
ߢߪ 150͠એਅߩឃᾲ߇ 40㧑⒟ᐲࠍභ߼ࠆ߇㧘ᷡ᝹ᬺߦ⌕⋡ߔࠇ߫Ყセ⊛㜞᷷㧔200͠⒟ᐲ㧕ߩᾲ߇ᄙߊឃ಴ߐࠇߡ޿ࠆߎߣ߇ࠊ߆ࠅ㧘ᧂ೑↪ࠛࡀ࡞ࠡ࡯ࠍ᦭ല೑↪ߔࠆ਄ߢߪᵈ⋡ߔߴ߈ߢ޽ࠆ㧚╩⠪ࠄߪ㧘ߎߩ᷷ᐲၞߢ⫾ᾲᠲ૞߇น⢻ߥ⫾ᾲ᧚ߩ㐿⊒[7-9]ࠍㅴ߼ߡ޿ࠆ㧚ߎߎߢ↪޿ࠆ⫾ᾲ᧚ߦߪ㧘Ԙࠃࠅૐ޿᳓⫳᳇࿶ߦ߅޿ߡ᳓⫳᳇ߣߩ෻ᔕ㊂߇ᄙߊ㧘න૏㊀㊂ᒰߚࠅ㧔߽ߒߊߪන૏૕Ⓧ޽ߚࠅ㧕⊒ᾲ㊂㧘ߔߥࠊߜ⫾ᾲኒᐲ߇㜞޿ߎߣ㧘ԙ⫾ᾲࠍⴕߥ߁᷷ᐲၞߦ߅޿ߡ㧘⫾ᾲ᧚ߩ⣕᳓㧔⫾ᾲ㧕߇น⢻ߢ޽ࠆߎߣ㧘Ԛ෻ᔕㅦᐲ߿વᾲㅦᐲ߇
චಽߦㅦ޿ߎߣ㧘ߥߤ߇᳞߼ࠄࠇࠆ㧚ᾲജቇ⸘▚ߩ⚿ᨐࠃࠅ㧘200͠⒟ᐲߩ᷷ᐲၞߢ⫾ᾲᠲ૞ࠍⴕߥ߁෻ᔕߣߒߡߪ㧘వߦ⎇ⓥ଀ߩ޽ࠆJ. HTSJ, Vol. 45, No. 190

․㓸㧦ๆ⌕ߩ਎⇇̆ࡒࠢࡠ߆ࠄࡑࠢࡠ㧘ߘߒߡࠪࠬ࠹ࡓ̆

ᄖ஥㧦ో࿖✚ឃᾲ 1.02106 TJ/yearౝ஥㧦ᷡ᝹ᬺ 8.48104 TJ/year㧔ᐔᚑ㧝㧞ᐕ㧕ࠟࠬ㧦 100 ~ 150 ࠟࠬ͠㧦 150 ~ 200 ࠟࠬ͠㧦 200 ~ 250 ࠟࠬ͠㧦 250 ~ 300 ࠟࠬ͠㧦 300͠ એ਄᷷᳓㧦 100͠ એਅ࿕૕࿑㧝 ↥ᬺឃᾲߩ᷷ᐲಽᏓ㧔ᐔᚑ 12 ᐕ㧕[10]෻ᔕᑼ (2) ߢ⴫ߐࠇࠆ㊄ዻ㉄ൻ‛ߩ᳓㉄ൻ‛ᒻᚑ෻ᔕࠃࠅ߽㧘෻ᔕᑼ (3) ߢ⴫ߐࠇࠆ㊄ዻႮߩ᳓๺
㧔⣕᳓㧕෻ᔕ߇ㆡߒߡ޿ࠆ㧚⠪ࠄߪ㧘Ⴎൻࠞ࡞ࠪ࠙ࡓߩ᳓๺෻ᔕߣ㘃ૃߩ෻ᔕߢ޽ࠆࠕࡦࡕ࠾ࠕๆ෼෻ᔕ㧔ࠕࡦࡒࡦ㍲૕ᒻᚑ෻ᔕ㧕ߦ߅޿ߡ㧘⥇ൻࠞ࡞ࠪ࠙ࡓࠍႮൻࠞ࡞ࠪ࠙ࡓ
ߣⶄวߔࠆߎߣߦࠃߞߡࠕࡦࡕ࠾ࠕๆ෼࿶ജ߇ᄌ
ൻߔࠆߎߣࠍ⷗಴ߒߡ޿ࠆ㧚ߎߩ⃻⽎ߪࠞ࡞ࠪ࠙
ࡓࠗࠝࡦㄭறߩ㒶ࠗࠝࡦߩ⒳㘃ߣᢙߦࠃߞߡ㧘ࠞ࡞ࠪ࠙ࡓࠗࠝࡦߣࠕࡦࡕ࠾ࠕߣߩ㑆ߩ⋧੕૞↪߇ᄌൻߔࠆߚ߼ߢ޽ࠆߣ⚿⺰ߠߌߡ޿ࠆ[11,12]㧚
ߘߩ৻ᣇߢ㧘㊄ዻႮࠍ↪޿ࠆᰳὐ߽ሽ࿷ߔࠆ㧚㧝ߟ⋡ߪ㧘వߦ᜼ߍߚầ⸃ߦࠃߞߡ↢ᚑߔࠆ㊄ዻႮ᳓ṁᶧ߇㧘⫾ᾲࠍⴕߥ߁෻ᔕེࠍ⣣㘩ߔࠆน⢻ᕈ߇᜼ߍࠄࠇࠆ㧚ߎߩ໧㗴ࠍ࿁ㆱߔࠆߚ߼ߦߪ㧘⠴⣣㘩ᕈ᧚ᢱ⵾ߩ෻ᔕེ╬߇ᔅⷐߢ޽ࠆ㧚㧞ߟ⋡ߣߒߡ㧘㊄ዻႮߩടᾲߦࠃࠆಽ⸃߿᣹⪇߇᜼ߍࠄࠇࠆ㧚଀߃߫㊄ዻ⎣㉄Ⴎߪ 300͠⒟ᐲߢ
ಽ⸃ߒ⓸⚛㉄ൻ‛ࠍ᡼಴ߒ㊄ዻ㉄ൻ‛ߣߥࠆ㧚߹ߚ㧘ㆫ⒖㊄ዻߩࡂࡠࠥࡦൻ‛╬ߪടᾲߦࠃߞߡ᣹
⪇ߔࠆ߽ߩ߇޽ࠅ㧘⫾ᾲᠲ૞ߩ᧦ઙߦࠃߞߡߪ૶
↪ߔࠆߎߣ߇ߢ߈ߥ޿㧚㧟ߟ⋡ߪ᳓๺෻ᔕߩㅦᐲߩ໧㗴ߢ޽ࠆ㧚࠯ࠝ࡜ࠗ࠻߿ࠪ࡝ࠞࠥ࡞߳ߩ᳓⫳᳇ๆ⌕ߪ࿕૕⴫㕙ߩߺߢ߅ߎࠆߩߦኻߒ㧘㊄ዻႮߩ᳓๺෻ᔕߪ⚿᥏᭴ㅧߩᄌൻࠍ઻޿ߥ߇ࠄ㧘㊄ዻႮ☸ሶ⴫㕙ߛߌߢߥߊ
⚿᥏ౝㇱ߹ߢ෻ᔕ߇ㅴⴕߔࠆߚ߼㧘෻ᔕ߇⚳ੌߔࠆ߹ߢߩᤨ㑆߇࿕૕⴫㕙߳ߩๆ⌕ߦᲧߴߡㆃߊ㧘⍴ᤨ㑆ߢォൻ₸ 100㧑ࠍ㆐ᚑߔࠆߩߪኈᤃߢߪߥ޿㧚 ෻ᔕߦ↪޿ࠆ㊄ዻႮߩㆬᛯ
వߦㅀߴߚࠃ߁ߦ㊄ዻႮࠍ⫾ᾲ᧚ߣߒߡ૶↪ߔ

㊄ዻႮߩ᳓๺෻ᔕ
 ㊄ዻႮࠍ↪޿ࠆ೑ὐߣᰳὐ
㊄ዻႮߩ᳓๺෻ᔕߪりㄭߢⷰኤߔࠆߎߣ߇ߢ߈
ࠆ㧚ౖဳ⊛ߥ଀ߣߒߡߪ㧘Ⴎൻࠞ࡞ࠪ࠙ࡓߩ᳓๺
෻ᔕࠍ᛼౉ࠇߩੇ῎೷ߦ೑↪ߔࠆ⵾ຠ߇Ꮢ⽼ߐࠇߡ޿ࠆ㧚߹ߚዊቇᩞߩℂ⑼ᢎ⢒ߢߪ㧘ᬀ‛ߩ⪲߆ࠄ⫳ᢔߔࠆ᳓⫳᳇ߩᬌ಴ᴺߣߒߡႮൻࠦࡃ࡞࠻⚕
ߩᄌ⦡㧔Ⴎൻࠦࡃ࡞࠻ߩ᳓๺෻ᔕߦࠃߞߡ㧘㕍߆ࠄࡇࡦࠢߦᄌ⦡㧕߇↪޿ࠄࠇߡ޿ࠆ㧚ߎߎߢ㧘⫾ᾲ᧚ߣߒߡ㊄ዻႮࠍ↪޿ࠆ႐วߩ೑
ὐߣᰳὐࠍᢛℂߔࠆ㧚㧝ߟ⋡೑ὐߩߣߒߡ㧘‛⾰㧝ࡕ࡞ᒰߚࠅߩ᳓⫳᳇෻ᔕ㊂߇ᄙ޿ߎߣ߇᜼ߍࠄ
ࠇࠆ㧚Ⴎൻࠞ࡞ࠪ࠙ࡓࠍ଀ߦขࠆߣ㧘቟ቯߒߚ᳓
๺‛ߣߒߡ㧝᳓๺‛㧘㧞᳓๺‛㧘㧠᳓๺‛㧘㧢᳓๺‛ߩሽ࿷߇⍮ࠄࠇߡ޿ࠆ㧚CaCl2 + H2O ĺ CaCl2•H2O(4a)
CaCl2•H2O + H2O ĺ CaCl2•2H2O(4b)
CaCl2•2H2O + 2H2O ĺ CaCl2•4H2O(4c)
CaCl2•4H2O + 2H2O ĺ CaCl2•6H2O(4d)ߐࠄߦ㧘৻ቯߩ᳓⫳᳇࿶એ਄ߦߥࠆߣầ⸃ߦࠃߞߡߐࠄߦᄙߊߩ᳓⫳᳇ߣ෻ᔕߒ㧘Ⴎൻࠞ࡞ࠪ࠙
ࡓ᳓ṁᶧࠍ↢ᚑߔࠆߎߣ߇ߢ߈ࠆ㧚CaCl2•6H2O + nH2O ĺ CaCl2 aq(5)㧞ߟ⋡ߩ೑ὐߣߒߡ㧘㧞⒳㘃㧔߽ߒߊߪߘࠇએ
਄㧕ߩ㊄ዻႮࠍⶄวߔࠆߎߣߦࠃࠅ㧘㊄ዻႮߣ᳇૕ߣߩ෻ᔕᕈࠍ೙ᓮߢ߈ࠆߎߣ߇᜼ߍࠄࠇࠆ㧚╩વᾲ 2006 ᐕ 1 ᦬- 22 -J. HTSJ, Vol. 45, No. 190

․㓸㧦ๆ⌕ߩ਎⇇̆ࡒࠢࡠ߆ࠄࡑࠢࡠ㧘ߘߒߡࠪࠬ࠹ࡓ̆

ࠆ႐วߦߪ㧘޿ߊߟ߆ߩᰳὐ߇ሽ࿷ߔࠆ㧚․ߦ㧘ടᾲಽ⸃߿᣹⪇ߩน⢻ᕈߩ޽ࠆ㊄ዻႮߪ૶↪ߢ߈ߥ޿㧚଀߃߫ 200͠⒟ᐲߢ⫾ᾲᠲ૞ࠍⴕߥ߁႐ว
ߪ㧘⎣㉄Ⴎߩ૶↪ߪ࿎㔍ߢ޽ࠆ㧚⫾ᾲ᧚ߣߒߡ↪޿ࠆㆡಾߥ㊄ዻႮࠍㆬᛯߔࠆߦ
ߪ㧘㧞ߟߩᣇᴺ߇޽ࠆ㧚㧝ߟ⋡ߪᾲജቇ⸘▚㧘㧞ߟ⋡ߪᾲᄤ⒊ߦࠃࠆࠬࠢ࡝࡯࠾ࡦࠣߢ޽ࠆ㧚㊄ዻႮߩ᳓๺෻ᔕߪ㧘એਅߩᑼߢ⴫ߐࠇࠆ㧚salt•mH2O + (ním)H2O ĺ salt•nH2O(4)

Ca(OH)2㊀㊂ᷫዋㅦᐲ㧔⋧ኻ୯㧕ߎߩ෻ᔕߩᐔⴧ᧦ઙߪ㧘᷷ᐲߩㅒᢙ㧔1/T㧕ߣ࿶ജߩኻᢙ㧔lnP㧕ߣ߇⋥✢㑐ଥߦ޽ࠅ㧘એਅߦ␜ߔ
ᑼߢ⴫ߐࠇࠆ㧚lnP = í 'H / RT + 'S / R(5)ߎߎߢ㧘'H ߣ'S ߪߘࠇߙࠇ㧘෻ᔕߦ߅ߌࠆࠛ
ࡦ࠲࡞ࡇ࡯ߣࠛࡦ࠻ࡠࡇ࡯ߩᄌൻߢ޽ࠅ㧘޿ߊߟ߆ߩ෻ᔕߦߟ޿ߡߪ୯߇᳞߼ࠄࠇߡ޿ࠆߎߣ߆ࠄ㧘⋡⊛ߩ᷷ᐲߣ᳓⫳᳇࿶ߦวࠊߖߚ㊄ዻႮߩㆬᛯ߇
น⢻ߢ޽ࠆ[13]㧚
ߎࠇࠄߩ୯߇ᓧࠄࠇߥ޿႐วߪ㧘㊄ዻႮ᳓๺‛ߩ⣕᳓᜼േࠍ㧘ᾲᄤ⒊ࠍ↪޿ߡ᷹ቯߔࠆߎߣߦࠃ
ߞߡ㧘⣕᳓෻ᔕߩ᜼േࠍኈᤃߦ⍮ࠆߎߣ߇ߢ߈ࠆ㧚߹ߚ㧘ᾲᄤ⒊ࠍ↪޿ࠆߎߣߦࠃߞߡ㧘ಽ⸃᷷ᐲ߿
᣹⪇᷷ᐲࠍ⍮ࠆߎߣ߽ߢ߈ࠆ㧚ᣂⷙ⫾ᾲ᧚ߩ㐿⊒
 ㊄ዻႮᷝടᄙሹ૕ߩ⺞⵾⃻࿷╩⠪ࠄߪ㧘200͠⒟ᐲߢ⫾ᾲน⢻ߥᣂⷙ⫾ᾲ᧚ߩ㐿⊒[7-9]ࠍㅴ߼ߡ޿ࠆ㧚߹ߕೋ߼ߦ㧘ᢙ⒳㘃ߩ㊄ዻࡂࡠࠥࡦൻ‛ߩ᳓๺‛ߣ㊄ዻ᳓㉄ൻ‛ߩ⣕᳓᜼േࠍ㧘ᾲᄤ⒊ࠍ↪޿ߡ᷹ቯߒߚ⚿ᨐࠍ࿑㧞ߦ␜ߔ㧚࿑㧞ߩ❑ゲߪ᷷ᐲ㧘ᮮゲߪടᾲߦࠃࠆ㊀㊂ᷫዋㅦᐲࠍ⴫ߔ㧚࿑㧞ࠃࠅ㧘Ⴎൻ࡝࠴࠙ࡓ㧘Ⴎൻࠞ࡞ࠪ࠙ࡓ㧘Ⴎൻࠬ࠻ࡠࡦ࠴࠙ࡓ߇ 200͠⒟ᐲߢ⣕᳓น⢻ߢ޽ࠆߎߣ߇ࠊ߆ࠆ㧚ߎߎߢߪኈᤃߦ౉ᚻน⢻ߥႮൻࠞ࡞ࠪ࠙ࡓࠍ㊄ዻႮߣߒߡ↪޿ࠆ㧚ߒ߆ߒߥ߇ࠄ㧘Ⴎൻࠞ࡞ࠪ࠙
ࡓߪ 25͠ߦ߅޿ߡ᳓⫳᳇࿶ 6.6 Torr㧔⋧ኻḨᐲ
28%㧕એ਄ߢầ⸃ߔࠆߚ߼㧘ߘߩ߹߹↪޿ࠆߎߣߪߢ߈ߥ޿㧚╩⠪ࠄߪầ⸃ߦࠃࠆ෻ᔕེߩ⣣㘩ࠍ㒐ߋߴߊ㧘ᵴᕈ὇߿ࡔ࠰ࡐ࡯࡜ࠬࠪ࡝ࠞ╬ࠍ㧘Ⴎൻࠞ࡞ࠪ࠙ࡓࠍ࿕ቯൻߔࠆᜂ૕ߣߒߡ↪޿ߚ᧚ᢱࠍ㧘ᣂߚߥ⫾ᾲ᧚ߣߒߡ↪޿ߚ㧚ߎࠇࠄߩᜂ૕ߪ
㜞⴫㕙Ⓧ㧔1000m2/g એ਄㧕ࠍᜬߟᄙሹ૕ߢ޽ࠅ㧘વᾲ 2006 ᐕ 1 ᦬

Mg(OH)2
SrBr2•6H2O
SrCl2•6H2O
CaBr2•2H2O
CaCl2•2H2O
MgCl2•6H2O
LiCl•H2O
0

100

200
300
᷷ᐲ㧔͠㧕

400

࿑㧞 ᾲᄤ⒊ߦࠃࠆ⣕᳓᷹ቯ⚿ᨐ

H2O

Heat
CaCl2
࿑㧟 ㊄ዻႮᷝടᄙሹ૕ࡕ࠺࡞࿑ [7]ߘߩ⚦ሹౝ߿⚿᥏☸ሶ㑆ߦႮൻࠞ࡞ࠪ࠙ࡓࠍ࿕ቯ
ൻߔࠆߎߣߦࠃࠅ㧘ㅢᏱߩ࿕૕᧚ᢱߣห᭽ߦᛒ߁
ߎߣ߇น⢻ߣߥࠆ㧔࿑㧟㧕㧚㊄ዻႮߣᄙሹ૕ߣߩⶄว᧚ᢱߪ㧘฽ᶐᴺߦࠃߞ
ߡኈᤃߦ⺞⵾ߢ߈ࠆ㧚ᚲቯỚᐲߩ㊄ዻႮṁᶧਛߦᄙሹ૕ߩ☳ᧃ㧔߽ߒߊߪࡍ࡟࠶࠻㧕ࠍട߃㧘⫳⊒ੇ࿕ߒߡᓧࠄࠇࠆࠬ࡜࡝࡯ࠍ㧘ੇ῎㧘὾ᚑߔࠆߎ
ߣߦࠃߞߡ⹜ᢱ߇ᓧࠄࠇࠆ㧚 ‛ᕈ⹏ଔ
ߎߩࠃ߁ߦߒߡᓧࠄࠇߚ⹜ᢱߩ‛ᕈ⹏ଔߪ㧘෻ᔕᾲ᷹ቯ㧘᳓⫳᳇᣹᷷⣕㔌᷹ቯ㧘᳓⫳᳇෼⌕╬᷷✢ߦࠃߞߡⴕߥߞߡ޿ࠆ㧚- 23 -J. HTSJ, Vol. 45, No. 190

․㓸㧦ๆ⌕ߩ਎⇇̆ࡒࠢࡠ߆ࠄࡑࠢࡠ㧘ߘߒߡࠪࠬ࠹ࡓ̆⴫㧝 25͠ߦ߅ߌࠆ⊒ᾲ㊂⫾ᾲ᷷ᐲ Ḩᐲ⊒ᾲ㊂78 %1.08 kJ/g࠯ࠝ࡜ࠗ࠻
450 ͠
11 %0.87 kJ/g
78 %2.10 kJ/gࡔ࠰ࡐ࡯࡜ࠬ
450 ͠
ࠪ࡝ࠞ
11 %0.56 kJ/g⹜ᢱ

200 ͠

78 %2.03 kJ/g

11 %1.26 kJ/g

78 %
11 %

1.18 kJ/g
0.90 kJ/g

(b)
(a)

0


⴫ਛߩ⹜ᢱߦߟ޿ߡ㧘‫ߪޠ࠻ࠗ࡜ࠝ࠯ޟ‬Ꮢ⽼ߩ Yဳ࠯ࠝ࡜ࠗ࠻㧘ࡔ࠰ࡐ࡯࡜ࠬࠪ࡝ࠞߣࡔ࠰ࡐ࡯࡜
ࠬࠕ࡞ࡒ࠽ߪ㧘ߘࠇߙࠇ 33 ㊀㊂㧑ߩႮൻࠞ࡞ࠪ࠙
ࡓࠍᷝടߒߚᄙሹ૕ߢ޽ࠆ㧚޿ߕࠇߩႮൻࠞ࡞ࠪ
࠙ࡓᷝടᄙሹ૕߽࠯ࠝ࡜ࠗ࠻⴫㕙߳ߩ᳓⫳᳇ๆ⌕ࠃࠅ߽㜞޿⊒ᾲ㊂ࠍ␜ߔߎߣ߇ࠊ߆ࠆ㧚Ⴎൻࠞ࡞ࠪ࠙ࡓᷝടࡔ࠰ࡐ࡯࡜ࠬࠕ࡞ࡒ࠽ߩ⫾ᾲ᷷ᐲࠍ͠ߦਅߍߚ႐วߢ߽㧘࠯ࠝ࡜ࠗ࠻ߩ୯ࠃࠅ߽㜞޿⊒ᾲ㊂ࠍ␜ߔߎߣ߇ࠊ߆ࠆ㧚࿑㧠ߦ㧘ߘࠇߙࠇߩ⹜ᢱߩ᳓⫳᳇᣹᷷⣕㔌᷹ቯߩ⚿ᨐࠍ␜ߔ㧚᣹᷷⣕㔌᷹ቯߪ࿕૕ࠍ৻ቯߩ᣹᷷
ㅦᐲടᾲߔࠆߎߣߦࠃߞߡ⣕㔌ߔࠆ᳇૕ᚑಽࠍ⾰㊂ಽᨆ⸘߿ࠟࠬࠢࡠࡑ࠻ࠣ࡜ࡈࠍ↪޿ߡಽᨆߒ㧘࿕૕ߣ᳇૕ᚑಽߩ⋧੕૞↪ߩᒝߐࠍ⹏ଔߔࠆᚻᴺ
ߢ޽ࠆ㧚ᾲᄤ⒊ࠍ↪޿ߚ⹏ଔᴺߪടᾲಣℂߦࠃࠆ
㊀㊂ᄌൻߒ߆ᬌ಴ߢ߈ߥ޿߇㧘ߎߩᣇᴺߢߪⶄᢙߩ᳇૕ᚑಽ߇⣕㔌ߔࠆ႐ว߽⹏ଔน⢻ߢ޽ࠆ㧚ߎࠇࠄߩ᧚ᢱߦኻߒ㧘Ḩᐲ㧑ߢ෻ᔕߐߖߚᓟ
ߦ᷹ቯࠍⴕߞߚ⚿ᨐ㧘᳓⫳᳇એᄖߩ᳇૕ߪᬌ಴ߐ
ࠇߥ߆ߞߚ㧚޿ߕࠇߩ⹜ᢱ߽ 200͠߹ߢߩടᾲಣ
ℂߦࠃߞߡ 75㧑એ਄ߩ᳓⫳᳇߇⣕㔌ߒߚߎߣ߆
ࠄ㧘200͠ߢߩ⫾ᾲᠲ૞߇น⢻ߢ޽ࠆߎߣ߇ࠊ߆ࠆ㧚
 ㊄ዻႮᷝടᄙሹ૕ߩ໧㗴ὐߎߎ߹ߢߦㅀߴߚࠃ߁ߦ㧘㊄ዻႮᷝടᄙሹ૕ߪ
࠯ࠝ࡜ࠗ࠻ࠃࠅ߽᷷๺ߥ⫾ᾲ᧦ઙߢ㜞޿⊒ᾲ㊂ࠍ␜ߔߎߣ߇ࠊ߆ߞߚ㧚ߒ߆ߒߥ߇ࠄ㧘㜞᳓⫳᳇࿶᧦ઙߦ߅޿ߡߪ㧘૶↪ᓟߩ⹜ᢱߩ⴫㕙ߦႮൻࠞ࡞
ࠪ࠙ࡓ᳓ṁᶧߦࠃࠆ‫ޟ‬Ứࠇ‫ⷰ߇ޠ‬ኤߐࠇߚ㧚ߎࠇ

વᾲ 2006 ᐕ 1 ᦬(c)- 24 -

100

200
300
᷷ᐲ䋨㷄䋩

400

࿑㧠 ᣹᷷⣕㔌᷹ቯ⚿ᨐ㧚㧔㨍㧕࠯ࠝ࡜ࠗ࠻㧘
㧔㨎㧕10 ㊀㊂㧑Ⴎൻࠞ࡞ࠪ࠙ࡓᷝടࡔ࠰ࡐ࡯࡜
ࠬࠕ࡞ࡒ࠽㧘
㧔㨏㧕33 ㊀㊂㧑Ⴎൻࠞ࡞ࠪ࠙ࡓᷝ
ടࡔ࠰ࡐ࡯࡜ࠬࠕ࡞ࡒ࠽㧘
㧔㨐㧕33 ㊀㊂㧑Ⴎൻࠞ࡞ࠪ࠙ࡓᷝടࡔ࠰ࡐ࡯࡜ࠬࠪ࡝ࠞ

600᳓⫳᳇ๆ⌕㊂ mm3/g

ࡔ࠰ࡐ࡯࡜ࠬ
ࠕ࡞ࡒ࠽

450 ͠

(d)᳓⣕㔌㊂䋨⋧ኻ୯䋩⴫㧝ߦ㧘ᚲቯ᷷ᐲߢ⣕᳓㧔⫾ᾲ㧕ߒߚ᧚ᢱߦኻ
ߒߡ㧘͠ߢ᳓⫳᳇ߣ෻ᔕߐߖߚ႐วߩ⊒ᾲ㊂ࠍ߹ߣ߼ߚ㧚

500
400
300
200
100
0
0

20

40
60
%
Ḩᐲ

80

࿑㧡 25͠ߦ߅ߌࠆ᳓⫳᳇෼⌕╬᷷✢㧚㧔٨㧕࠯ࠝ࡜ࠗ࠻㧘
㧔٤㧕33 ㊀㊂㧑Ⴎൻࠞ࡞ࠪ࠙ࡓᷝ
ടࡔ࠰ࡐ࡯࡜ࠬࠕ࡞ࡒ࠽㧘ὐ✢ߪࡔ࠰ࡐ࡯࡜
ࠬࠕ࡞ࡒ࠽ߩ⚦ሹኈⓍࠍ⴫ߔߪ㧘ầ⸃ߦࠃߞߡ↢ߓߚႮൻࠞ࡞ࠪ࠙ࡓ᳓ṁᶧ߇ᄙሹ૕ߩ⚦ሹ߽ߒߊߪ☸ሶ㑆ߩⓨ㓗߆ࠄ޽߰ࠇ಴
ߚ߽ߩߢ޽ࠆ㧚࿑㧡ߦ㧘Ⴎൻࠞ࡞ࠪ࠙ࡓᷝടࡔ࠰ࡐ࡯࡜ࠬࠕ࡞
ࡒ࠽ߣ࠯ࠝ࡜ࠗ࠻ߩ᳓⫳᳇෼⌕╬᷷✢ࠍ␜ߔ㧚ߎߎߢ㨬෼⌕㨭㧔 sorption㧕ߪ㧘‫ޟ‬ๆ෼‫ޠ‬㧔 absorption㧕

J. HTSJ, Vol. 45, No. 190

․㓸㧦ๆ⌕ߩ਎⇇̆ࡒࠢࡠ߆ࠄࡑࠢࡠ㧘ߘߒߡࠪࠬ࠹ࡓ̆
ߣ‫ޟ‬ๆ⌕‫ޠ‬㧔adsorption㧕ߩਔᣇߩᗧ๧ࠍ฽ߺ㧘㊄ዻႮߩ᳓๺ߪ‫ޟ‬ๆ෼‫ߦޠ‬ಽ㘃ߐࠇࠆ㧚޿ߕࠇߩ⹜
ᢱ߽Ḩᐲ 20㧑એਅߩૐḨᐲ᧦ઙߦ߅޿ߡ߽᳓⫳᳇ࠍ෼⌕ߔࠆ߇㧘࠯ࠝ࡜ࠗ࠻ߩ᳓⫳᳇෼⌕㊂ߪḨ
ᐲ 20㧑⒟ᐲߢ㘻๺ߔࠆ৻ᣇߢ㧘Ⴎൻࠞ࡞ࠪ࠙ࡓᷝ
ടࡔ࠰ࡐ࡯࡜ࠬࠕ࡞ࡒ࠽ߩ᳓⫳᳇෼⌕㊂ߪḨᐲ
20㧑એ਄ߦ߅޿ߡ߽Ⴧᄢߔࠆ㧚ߎࠇߪႮൻࠞ࡞ࠪ
࠙ࡓ᳓๺‛ߩ↢ᚑ㧘ầ⸃ߦࠃࠆႮൻࠞ࡞ࠪ࠙ࡓ᳓
ṁᶧߩ↢ᚑߦࠃࠆ߽ߩߢ޽ࠆ㧚ߎߎߢ㧘Ⴎൻࠞ࡞ࠪ࠙ࡓᷝടࡔ࠰ࡐ࡯࡜ࠬࠕ࡞
ࡒ࠽ߩ⚦ሹኈⓍߣ᳓⫳᳇෼⌕㊂ߣࠍᲧセߔࠆߣ㧘Ḩᐲ 40㧑એਅߦ߅޿ߡ⹜ᢱߩ⚦ሹኈⓍ߇᳓⫳᳇෼⌕㊂ࠍ਄࿁ࠆߎߣ߇ࠊ߆ࠆ㧚ߔߥࠊߜ㧘᳓⫳᳇෼⌕㊂߇⚦ሹኈⓍࠍ਄࿁ࠆ႐วߪ↢ᚑߔࠆႮൻࠞ
࡞ࠪ࠙ࡓ᳓ṁᶧ߇⚦ሹౝ߆ࠄ޽߰ࠇ಴ߒߡ⹜ᢱ⴫
㕙ߦᨆ಴ߒ㧘
‫ޟ‬Ứࠇ‫ⷰߡߒߣޠ‬ኤߐࠇࠆ㧚ࠃߞߡ㧘᳓⫳᳇෼⌕㊂߇⚦ሹኈⓍࠍ਄࿁ࠄߥ޿᧦ઙߦ߅޿
ߡ㧘ߎߩ᧚ᢱࠍ⫾ᾲ᧚ߣߒߡ૶↪ߔࠆߎߣ߇น⢻ߢ޽ࠆ㧚੹ᓟߩ⎇ⓥ㐿⊒⺖㗴 ᣂⷙᄙሹ૕ߩวᚑ
⃻࿷߹ߢߦᬌ⸛ࠍⴕߞߚᄙሹ૕㧔ࡔ࠰ࡐ࡯࡜ࠬ
ࠪ࡝ࠞ㧘ࡔ࠰ࡐ࡯࡜ࠬࠕ࡞ࡒ࠽㧕ߪ⚦ሹኈⓍ߇චಽߦᄢ߈ߊߥ޿ߚ߼㧘Ⴎൻࠞ࡞ࠪ࠙ࡓ᳓ṁᶧ߇⹜ᢱ⴫㕙ߦ޽߰ࠇ಴ߔߣ޿߁໧㗴߇޽ࠆ㧚ߎߩ໧㗴ࠍ⸃᳿ߔࠆߚ߼ߦߪ㧘ߐࠄߦ⚦ሹኈⓍߩᄢ߈ߥᄙ
ሹ૕ࠍ૶↪ߔࠆᔅⷐ߇޽ࠆ㧚߹ߚ㧘ᄙሹ૕߳ߩ᳓
⫳᳇ๆ⌕᜼േߪ⚦ሹᓘߦଐሽߔࠆߎߣ߆ࠄ㧘ᄙሹ૕ߩ⚦ሹᓘߩᦨㆡൻࠍߔࠆᔅⷐ߽޽ࠆ㧚ᄙሹ૕ߩ⴫㕙㧔⚿᥏ᄖ⴫㕙㧘⚦ሹౝ⴫㕙㧕ߩ㊄ዻႮಽᢔࠍะ਄ߒ㧘㊄ዻႮࠍᓸ⚿᥏ߣߒߡ⴫㕙਄ߦ࿕ቯൻߔࠆߦߪ㧘⴫㕙߇ⷫ᳓ᕈࠍᜬߜ㊄ዻႮߣ⋧੕૞↪ߔࠆᔅⷐ߇޽ࠆ㧚⫾ᾲࠪࠬ࠹ࡓߩᕈ⢻ࠍะ਄ߔࠆ਄ߢ㧘චಽߥવᾲࠍⴕߥ߁ߚ߼ߩⵝ⟎⸳⸘ߪᔅⷐਇนᰳߢ޽ࠆ߇㧘ታ㓙ߦ↪޿ࠆ⫾ᾲ᧚ߘߩ߽ߩߩવᾲᕈ⢻ࠍ㜞߼ࠆߎߣ߽ᔅⷐߢ޽ࠅ㧘ߎߩࠃ߁ߥⷰὐ߆ࠄߩ᧚ᢱ⸳
⸘㧘଀߃߫὇⚛♽᧚ᢱߩ૶↪߽㊀ⷐߢ޽ࠆߣ⠨߃ࠄࠇࠆ㧚 ૶↪᧦ઙߦวࠊߖߚ᧚ᢱ⸳⸘
వߦㅀߴߚࠃ߁ߦ㧘㊄ዻႮࠍ㧞⒳㘃એ਄ⶄวߔ
ࠆߎߣߦࠃߞߡ㧘㊄ዻႮߣ᳇૕ߣߩ෻ᔕᕈࠍ೙ᓮ

વᾲ 2006 ᐕ 1 ᦬- 25 -

ߔࠆߎߣ߇ߢ߈ࠆ㧚ᓥߞߡ㧘⫾ᾲ᷷ᐲ᧦ઙߦวࠊ
ߖߚⶄว㊄ዻႮߩวᚑ߿㧘ᄙሹ૕ౝߦ࿕ቯൻߦࠃ
ߞߡ㧘ᣂߚߥ⫾ᾲ᧚ࠍᓧࠄࠇࠆߣ⠨߃ࠄࠇࠆ㧚ᄙሹ૕ౝߦ߅ߌࠆ㊄ዻႮߩ᳓๺෻ᔕߪ㧘ㅢᏱߩ᳓๺෻ᔕߣ᜼േ߇⇣ߥࠅ㧘ᧂ⸃᣿ߥㇱಽ߇ᄙ޿㧚
⿒ᄖಽశᴺ߿㔚㗼ⷰኤ╬ߦࠃࠆࠠࡖ࡜ࠢ࠲࡝࠯࡯
࡚ࠪࡦߦࠃߞߡᣂߚߥ⍮⷗ࠍᓧࠆߎߣ߇ߢ߈ࠆ㧚 ࠬࠤ࡯࡞ࠕ࠶ࡊߦࠃࠆታ⸽
ᧄ⎇ⓥߪਥߦ‛ℂൻቇ⊛ߥᚻᴺࠍ↪޿ߡᢙචࡒ
࡝ࠣ࡜ࡓࠬࠤ࡯࡞ߩታ㛎ߦࠃߞߡ⫾ᾲ᧚ߩᕈ⢻⹏ଔࠍㅴ߼ߡ߈ߚ㧚᧚ᢱߩታ↪ൻߦ޽ߚߞߡߪᢙ⊖ࠣ࡜ࡓ㨪ᢙࠠࡠࠣ࡜ࡓࠬࠤ࡯࡞ߩలႯጀ෻ᔕེ╬ࠍ↪޿ߚታ⸽⹜㛎߇ᔅⷐߢ޽ࠆ㧚లႯጀ෻ᔕེౝ
ߦ߅ߌࠆ᳓๺෻ᔕ߿⣕᳓෻ᔕߩ᜼േࠍ⸃ᨆߔࠆߎ
ߣߦࠃߞߡ෻ᔕㅦᐲ߿વᾲㅦᐲ߇ᓧࠄࠇࠆ㧚ߎߎߢ⊒↢ߔࠆ໧㗴ὐࠍ᧚ᢱ㐿⊒ߦࡈࠖ࡯࠼ࡃ࠶ࠢߔ
ࠆߎߣߦࠃࠅ㧘㜞ᕈ⢻⫾ᾲ᧚ߩታ↪ൻࠍ⋡ᜰߒߚ
޿㧚

⻢ㄉ
ᧄ⎇ⓥߪ㧘ട⮮ਯ⾆᧲੩Ꮏᬺᄢቇഥᢎ᝼㧘⑺㣮
⎇৻᧲੩Ꮏᬺᄢቇฬ⹷ᢎ᝼ࠍߪߓ߼㧘ᄙߊߩᄢቇ
㒮↢ߣ౒หߢㅴ߼ߡ޿ࠆ߽ߩߢ޽ࠆ㧚ߎߎߦ⻢ᗧࠍ⴫ߔࠆ㧚ෳ⠨ᢥ₂
[1] ᨞⼱᣽ା㧘␹ᴛᷕ㧘⫾ᾲᛛⴚ㧙ℂ⺰ߣߘߩᔕ↪㧘ାጊ␠ࠨࠗ࠹࠶ࠢ (2001).
[2] ർ ᶏ ㆏ 㐿 ⊒ ዪ ࡎ ࡯ ࡓ ࡍ ࡯ ࠫ 㧘 http://
www.hkd.mlit.go.jp/kanribu/chosei/yusou.html[3] Ḵ↰ᔘੱ㧘࠯ࠝ࡜ࠗ࠻㧙᳓♽ࡅ࡯࠻ࡐࡦࡊߩ
㐿⊒ߣ⺖㗴㧘વᾲ㧘40 (2001) 18.
[4] Y. Kato et al., Kinetic study of the hydration ofmagnesium oxide for a chemical heat pump, Appl.
Therm. Eng., 16 (1996) 853.
[5] Y. Kato et al., Magnesium oxide/water chemicalheat pump to enhance energy utilization of acogeneration system, Energy, 30 (2005) 2144.
[6] Y. Hirata et al., Preparation of fine particles ofcalcium chloride with expanded graphite forenhancement of the driving reaction for chemicalheat pumps, J. Chem. Eng. Jpn., 36 (2003) 827.
[7] C. Y. Liu et al., Water sorption of CaCl2

J. HTSJ, Vol. 45, No. 190

․㓸㧦ๆ⌕ߩ਎⇇̆ࡒࠢࡠ߆ࠄࡑࠢࡠ㧘ߘߒߡࠪࠬ࠹ࡓ̆

containing materials as heat storage media, Chem.

[11] C. Y. Liu et al., Effect of the Cl/Br molar ratio of
a CaCl2-CaBr2 mixture used as an ammonia

Lett., 33 (2004) 292.
[8] ഏ㉍৻ ઁ㧘㊄ዻႮᷝടᄙሹ૕ߦࠃࠆ᳓෼⌕ဳ⫾ᾲߦ㑐ߔࠆ⎇ⓥ㧘⸅ᇦ㧘46 (2004) 480.
[9] C. Y. Liu et al, Water sorption into metal salt
added porous materials as heat storage media.,
Pacifichem 2005, #1396, Honolulu (2005).

storage material, Ind. Eng. Chem. Res., 43 (2004)
6994.
[12] C. Y. Liu et al., Ammonia absorption into alkaline
earth metal halide mixtures as an ammonia storage[10] ⽷࿅ᴺੱ⋭ࠛࡀ࡞ࠡ࡯࠮ࡦ࠲࡯ࡎ࡯ࡓࡍ࡯ࠫ㧘
http://www.eccj.or.jp/wasteheat/index.html

material, Ind. Eng. Chem. Res., 43 (2004) 7484.
[13] International Critical Tables of Numerical data,
Physics, Chemistry and Technology, McGraw-Hill,
New York, 7 (1929) 224.

વᾲ 2006 ᐕ 1 ᦬- 26 -J. HTSJ, Vol. 45, No. 190

․㓸㧦ๆ⌕ߩ਎⇇̆ࡒࠢࡠ߆ࠄࡑࠢࡠ㧘ߘߒߡࠪࠬ࠹ࡓ̆

ๆ⌕ࡅ࡯࠻ࡐࡦࡊߩๆ⌕ེౝᾲ㨯‛⾰⒖േ⃻⽎Heat and Mass Transfer Phenomena in Adsorber for Adsorption Heat Pumpᷰㄝ ⮮㓶㧘┄↰ శብ㧔ฬฎደᄢቇ㧕
Fujio WATANABE, Mitsuhiro KUBOTA (Nagoya University)e-mail: watanabf@nuce.nagoya-u.ac.jpߪߓ߼ߦ
ๆ࡮⣕⌕⃻⽎ࠍ೑↪ߒߚᾲ೑↪ᛛⴚߣߒߡ‫ޟ‬ๆ⌕ ࡅ ࡯ ࠻ ࡐ ࡦ ࡊ ࠪ ࠬ ࠹ ࡓ ‫ޠ‬㧔 Adsorption Heat
Pump㧦એਅ AHP㧕㧘‫࠻ࡦࠞࠪ࠺ޟ‬ⓨ⺞ࠪࠬ࠹ࡓ‫ޠ‬߇⍮ࠄࠇߡ޿ࠆ㧚ߎࠇࠄߪ޿ߕࠇ߽ࠪ࡝ࠞࠥ࡞㧘ᵴᕈ὇㧘࠯ࠝ࡜ࠗ࠻ߥߤߩๆ⌕᧚ߦࠃࠆๆ⌕⾰㧔ਥߣߒߡ᳓㧘ઁߦࠕ࡞ࠦ࡯࡞ߥߤ㧕ߩๆ࡮⣕⌕ߦ઻޿⊒↢࡮ๆ෼ߐࠇࠆๆ⌕ᾲ࡮⣕⌕ᾲࠍ↪޿ߡ಄ᚱ࡮
ᥦᚱ↪ᾲߩ↢ᚑ޽ࠆ޿ߪ᷷Ḩᐲࠦࡦ࠻ࡠ࡯࡞ࠍⴕ
߁ࠪࠬ࠹ࡓߢ޽ࠆ㧚․㐳ߣߒߡ 1㧕ⅣႺ᷷ᐲએ਄
100 ͠એਅߩૐ᷷ᾲḮߩߺߢ㚟േน⢻㧘2㧕ᾲḮ᷷ᐲߩૐਅߦࠃࠆ಴ജᕈ⢻ߩૐਅ߇ዊߐ޿㧘3㧕ๆ࡮⣕⌕ߩนㅒᕈߦఝࠇ㧘೽෻ᔕ߽↢ߓߥ޿㧘4㧕ๆ⌕᧚࡮ๆ⌕⾰߇ήᲥ࡮㕖⣣㘩ᕈ㧘ߥߤ߇޽ߍࠄࠇࠆ
ߎߣ߆ࠄⅣႺ౒↢ဳᾲࠛࡀ࡞ࠡ࡯ࠪࠬ࠹ࡓߣߒߡ
ᵈ⋡ߐࠇߡ޿ࠆ㧚ߎߩࠃ߁ߥⷰὐ߆ࠄ㧘ᚒ‫⎇ߩޘ‬ⓥቶߢߪๆ⌕ࡅ࡯࠻ࡐࡦࡊߩ㐿⊒ࠍ⛮⛯⊛ߦታᣉߒߡ߈ߚ㧚ߎࠇ߹ߢߩ⎇ⓥᚑᨐߦߟ޿ߡߪ㧘વᾲ⎇ⓥ╙ 36 Ꮞ 140 ภ㧔1997 ᐕ㧕ߦ߅޿ߡ‫ޟ‬ๆ⌕ࡅ࡯࠻ࡐࡦࡊߩๆ⌕೷లႯๆ⌕ེౝᾲ㨯‛⾰⒖േ‫ߣޠ‬㗴ߒߡ㧘AHP ߩ૞േේℂ㧘లႯጀౝߩᾲ࡮‛⾰⒖േଦㅴࠍ⋡⊛ߣߒߚࡕࠫࡘ࡯࡞ൻᚻᴺߦߟ޿ߡ৻
ㇱࠍነⓂߐߖߡ޿ߚߛ޿ߡ޿ࠆ[1]㧚ߒ߆ߒ㧘೨࿁
ߩነⓂ߆ࠄߔߢߦ 10 ᐕㄭߊ߇⚻ㆊߒߡ޿ࠆߎߣ
߆ࠄ㧘೨Ⓜߣ㊀ⶄߔࠆㇱಽ߽޽ࠆ߇㧘ᧄⓂߢߪᡷ
߼ߡ AHP ᛛⴚߦߟ޿ߡ᭎⺑ࠍߒߚᓟ㧘ᐔᚑ 13㨪
15 ᐕᐲߦ NEDO ߆ࠄߩഥᚑࠍฃߌߡታᣉߒߚ㜞ᕈ⢻ AHP 㐿⊒ߩ⎇ⓥᚑᨐߩ৻ㇱࠍᾲ࡮‛⾰⒖േߩⷰὐ߆ࠄ⚫੺ߒߚ޿[2]㧚

ⓨ⺞↪߳ߩㆡ↪߇⷗ㄟ߹ࠇࠆ಄ᾲ↢ᚑߦߟ޿ߡ⸃
⺑ߔࠆ[3]㧚࿑ 1 ߪ㧘޽ࠆᐔⴧๆ⌕㊂ q ߦߥࠆᐔⴧ
᷷ᐲߣ⫳᳇࿶ജߩ㑐ଥࠍ␜ߒߚๆ⌕╬㊂✢࿑ߢ޽ࠆ㧚AHP ߢߪๆ⌕♽ߣኻߦߥࠆ෻ᔕ♽ߣߒߡๆ⌕⾰ߩ⫳⊒㧛ಝ❗⃻⽎ࠍ೑↪ߔࠆߚ߼㧘࿑ 1 ߦߪๆ⌕⾰ߩ㘻๺⫳᳇࿶ᦛ✢߽␜ߐࠇߡ޿ࠆ㧚࿑ 1 ๆ⌕ࡅ࡯࠻ࡐࡦࡊߩ૞േේℂ⫾ᾲㆊ⒟ߢߪ㧘ᐔⴧ⁁ᘒߦ޽ࠆԚ㧔᷷ᐲ㧦TM㧘
࿶ജ㧦P3㧕ߦ߅޿ߡ㧘ๆ⌕ེ㧘ಝ❗ེߘࠇߙࠇߦ
᷷ᐲ TH㧔ๆ⌕᧚ౣ↢ᾲḮ᷷ᐲ㧦Ꮏ႐ឃᾲߥߤ㧕߅ࠃ߮ TM㧔ⅣႺᾲḮ᷷ᐲ㧦ᄢ᳇᷷ᐲ㧕ߩᾲࠍട߃㧘ๆ⌕ེࠍԛ㧔TH㧘P4㧕ߦ㧘ಝ❗ེࠍ㧔TM㧘P1㧕ߣߔࠆ㧚ߎߎߢๆ⌕ེߣಝ❗ེࠍㅪ⚿ߔࠆߣ㧘ਔኈེ㑆ߩ࿶ജᏅ㧔P4- P1㧕ߦࠃࠅๆ⌕ེ߆ࠄๆ⌕⾰߇⣕⌕㧘ಝ❗ེ߳⒖േߒߡ⫾ᾲ⁁ᘒߦߥࠆ㧔Ԙ㧕㧚᡼ᾲㆊ⒟ߢߪࡃ࡞ࡉࠍ㐽ߓߚ⁁ᘒߢ㧘ๆ⌕ེ㧘⫳⊒ེߦ TM ߅ࠃ߮ TL㧔⊒↢಄ᾲ᷷ᐲ㧦಄ᚱ߳ߩଏ⛎᷷ᐲ㧕ߩᾲḮࠍଏ⛎ߔࠆߎߣߦࠃࠅ㧘ๆ⌕ེࠍԙ㧔TM㧘P2㧕ߦ㧘⫳⊒ེࠍ㧔TL㧘P3㧕ߣߔࠆ㧚ߎߎߢࡃ࡞ࡉࠍ㐿ߊߣ㧘ๆ⌕⾰߇⫳⊒ེ߆ࠄๆ⌕ེ߳⒖േߒ㧘ๆ⌕᧚ߦๆ⌕ߐࠇߡ⫳᳇࿶ P3 ߦኻߔࠆᐔⴧๆ⌕㊂ q2 ߦߥࠆ㧔Ԛ㧕㧚ߎߩ㑆ߩ⫳⊒ߦ઻߁⫳⊒ẜᾲ'Heva ߦࠃࠅ⫳⊒ེߢ಄ᾲ߇↢ᚑߔࠆ㧚ๆ⌕ࡅ࡯࠻ࡐࡦࡊߩ૞േේℂๆ⌕ࡅ࡯࠻ࡐࡦࡊߢߪ᡼ᾲㆊ⒟ߢ᷷ᾲ߹ߚߪ಄
ᾲࠍ↢ᚑߒ㧘⫾ᾲㆊ⒟ߢๆ⌕᧚ߩౣ↢ࠍⴕ߁㧚ㅢ
Ᏹ㧘AHP ߪๆ⌕ེ 2 ེߣ⫳⊒ེ㧘ಝ❗ེฦ 1 ེ߆ࠄ᭴▽ߐࠇ㧘ฦ‫ߩޘ‬ๆ⌕ེߢ᡼ᾲ࡮⫾ᾲࠍ੤੕ߦ
ಾࠅᦧ߃ߥ߇ࠄㅪ⛯⊛ߦ಴ജࠍᓧࠆ㧚ߎߎߢߪ㧘વᾲ 2006 ᐕ 1 ᦬- 27 -J. HTSJ, Vol. 45, No. 190

․㓸㧦ๆ⌕ߩ਎⇇̆ࡒࠢࡠ߆ࠄࡑࠢࡠ㧘ߘߒߡࠪࠬ࠹ࡓ̆
ๆ⌕ࡅ࡯࠻ࡐࡦࡊߩ಴ജߣߒߡ㧘એਅߩ 2 ߟߩ⹏ଔᜰᮡ߇޽ࠆ㧚1) ๆ⌕᧚ߣๆ⌕⾰ߩๆ⌕ᐔⴧ㑐ଥߥࠄ߮ߦๆ⌕⾰ߩ‛ᕈ୯ߦࠃࠅ᳿ቯߐࠇࠆᐔⴧ⺰⊛಴ജ2) ๆ࡮⣕⌕ㅦᐲߥࠄ߮ߦ⊒࡮ๆᾲㅦᐲߦࠃࠅ᳿ቯ
ߐࠇࠆㅦᐲ⺰⊛಴ജ
1㧕ߩᐔⴧ⺰⊛಴ജߪ㧘޿ࠊ߫ AHP ߩℂᗐ⊛ߥ಴ജߢ޽ࠆ㧚ߎࠇߦኻߒߡ㧘2㧕ߩㅦᐲ⺰⊛಴ജߪ
AHP ࠍታ㓙ߦ㚟േߐߖߚ႐วߩታ಴ജߢ޽ࠆ㧚ߎࠇߪๆ⌕ེౝߦ߅ߌࠆᾲߣ‛⾰ߩ⒖േㅦᐲ߇⋧੕ߦᓇ㗀ߒ޽ߞߚ✚᜝ㅦᐲߣߒߡ᳿ቯߐࠇࠆ㧚AHP
ߩታ↪ൻߦะߌߡߪ 2㧕ߩㅦᐲ⺰⊛಴ജߩะ਄߇
ਇนᰳߢ޽ࠆߎߣ߆ࠄ㧘ᧄⓂߢߪ 2㧕ࠍᡰ㈩ߔࠆ
ๆ⌕ེౝߢߩᾲ㨯‛⾰⒖േ⃻⽎ߦ⌕⋡ߒ㧘ᰴ▵߆ࠄ⸃⺑ࠍⴕ߁㧚

ࠄࠇࠆ㧚ࠃߞߡ㧘✚᜝ߩ‛⾰⒖േㅦᐲߪలႯጀౝ
ߩ⫳᳇࿶Ꮕࠍផㅴജߣߔࠆๆ⌕⾰ߩలႯጀౝ⒖േ
ߢ޽ࠆ M-1 ߅ࠃ߮☸ሶౝߩๆ⌕㊂Ꮕࠍផㅴജߣߔ
ࠆๆ⌕⾰ߩ☸ሶౝ⒖േߢ޽ࠆ M-3 ߦࠃࠅᡰ㈩ߐࠇ
ࠆ㧚ߥ߅㧘M-1 ߣ M-3 ߩฦ‛⾰⒖േㅦᐲߪ☸ሶᓘߩᓇ㗀ࠍᒝߊฃߌ㧘☸ሶᓘ߇ዊߐߊߥࠆ߶ߤ☸ሶౝ‛⾰⒖േ㧔M-3㧕߇ㄦㅦߦߥࠆ৻ᣇ㧘లႯጀౝ‛⾰⒖േ㧔M-1㧕ㅦᐲߪዊߐߊߥࠆ㧚ߎߩ⋧෻㑐ଥߩߚ߼ߦ㧘‛⾰⒖േߩⷰὐ߆ࠄߪᦨㆡߥ☸ሶᓘ߇ሽ࿷ߔࠆ㧚ࠪ࡝ࠞࠥ࡞లႯጀߦ߅ߌࠆታ㛎ߣᢙ୯⸃ᨆߩ⚿ᨐࠃࠅ㧘☸ሶᓘ 500 Pm એ਄ߢߪጀౝ
‛⾰⒖േᛶ᛫ߪ✭๺ߐࠇࠆ߽ߩߩ☸ሶౝ‛⾰⒖േ
ㅦᐲ߇ૐਅߔࠆߎߣ߇␜ߐࠇߡ߅ࠅ[4]㧘AHP ߢߪ☸ሶᓘ 100㨪500 Pm ߩๆ⌕᧚߇↪޿ࠄࠇߡ޿ࠆ㧚ᾲ⒖േߦ㑐ߒߡ㧘M-2 ߩๆ⌕ߦ઻޿⊒↢ߒߚๆ⌕ᾲߪ☸ሶౝࠍવᾲߒߡ޿ߊ߇㧔H-1㧕
㧘਄ㅀߒߚ
ࠃ߁ߦ AHP ߢߪ☸ሶᓘ 100㨪500 Pm ߩዊ☸ᓘߩๆ⌕᧚ࠍ૶↪ߔࠆߎߣ߇ᄙ޿ߚ߼㧘☸ሶౝ᷷ᐲࠍ
ဋ৻ߣߔࠆ lumped heat capacity model ߇ᚑ┙ߔࠆ႐ว߇ᄙ޿㧚ߎࠇߦኻߒߡ㧘లႯጀౝવᾲߢ޽ࠆ
H-2 ߪ㧘☸ሶలႯጀߩ᦭ലᾲવዉᐲ߇ዊߐ޿ߚ߼
㧔ࠪ࡝ࠞࠥ࡞♽㧦⚂ 0.15 W/m K㧕㧘ᾲ⒖േߩᓞㅦᲑ㓏ߣߥࠆ㧚

ๆ⌕ེౝߩᾲ࡮‛⾰⒖േๆ⌕ࡅ࡯࠻ࡐࡦࡊߩๆ⌕ེߪၮᧄ⊛ߦๆ⌕᧚☸
ሶలႯጀߣߥࠆ㧚ߎߩ☸ሶలႯጀౝࠍๆ⌕⾰⫳᳇
߇⒖േߒߥ߇ࠄๆ࡮⣕⌕߇ㅴⴕߒߡ޿ߊ߇㧘ๆ⌕㧔⣕⌕㧕⃻⽎ߢߪๆ⌕᧚߇ๆ⌕⾰⫳᳇ࠍๆ⌕㧔⣕⌕㧕ߔࠆ㓙ߦ⊒ᾲ㧔ๆᾲ㧕߇↢ߓࠆ㧚ᓥ᧪ๆ⌕߇ᔕ↪ߐࠇߡ߈ߚๆ⌕ಽ㔌࡮♖⵾ࡊࡠ࠮ࠬߥߤߢߪ㧘ๆ⌕⾰ߩࡃ࡞ࠢỚᐲ߇ૐߊ⊒ᾲ㊂߇ዊߐ޿ߚ߼㧘╬᷷ๆ⌕♽ߣߒߡߩขࠅᛒ޿߇ߢ߈ࠆ㧚ߎࠇߦኻߒߡ㧘නᚑಽ♽ߩๆ⌕ࡅ࡯࠻ࡐࡦࡊߢߪๆ⌕ᾲߩ⊒↢ࠍήⷞߢ߈ߥߊߥࠅ㧘㕖╬᷷ๆ⌕♽ߣߒߡขࠅᛒ߁ᔅⷐ߇޽ࠆ㧚ߎߩࠃ߁ߥๆ⌕᧚☸ሶలႯጀౝߦ߅ߌࠆᾲ࡮‛⾰⒖േࠍࡕ࠺࡞⊛ߦ࿑ 2 ߦ␜ߔ㧚વᾲ▤M-1㧦ጀౝ‛⾰⒖േ
ๆ⌕

‛⾰⒖േ
ᾲ⒖േ

M-2㧦ๆ⌕

M-3㧦☸ሶౝ‛⾰⒖േๆ⌕᧚☸ሶలႯጀ

ᾲ
੤
឵
ᇦ
૕

࿑ 3 లႯጀဳๆ⌕ེߩ᷷ᐲ࡮ๆ⌕㊂ߩ⚻ᤨᄌൻ
࿑ 3 ߪᄖㇱᾲ੤឵ᑼߩలႯጀဳๆ⌕ེ㧔⋥ᓘ㧦
54 mm㧘ጀ㜞㧦208 mm㧕ߩጀౝ᷷ᐲ࡮ๆ⌕㊂ߩ⚻ᤨᄌൻࠍ␜ߒߡ޿ࠆ߇㧘ታ㛎㐿ᆎ⋥ᓟ߆ࠄๆ⌕ߦ઻߁⊒ᾲߦࠃࠅጀౝ᷷ᐲ߇ 30㨪70 K ߽਄᣹ߒ㧘ጀౝ᦭ലᾲવዉᐲ߇ૐ޿ߚ߼ߦೋᦼ᷷ᐲ߳ߩ࿁ᓳ߹
ߢߦ 10 ᤨ㑆એ਄ࠍⷐߒߡ޿ࠆ㧚ߎࠇߦ઻޿ๆ⌕ߩㅴⴕ߽ᄢ߈ߊᅹߍࠄࠇߡ޿ࠆߎߣ߇ಽ߆ࠆ[5]㧚
ᧄ࿑ߩࠃ߁ߦ㧘ๆ⌕⃻⽎ߪ᷷ᐲߦኻߔࠆଐሽᕈ
߇ᒝߊ㧘☸ሶలႯጀߩ㒰ᾲ㧔ๆ⌕ᤨ㧕࡮⛎ᾲ㧔⣕⌕
ᤨ㧕⢻ജߩਇ⿷ߪ‛⾰⒖േㅦᐲߦ߽ᄢ߈ߥᓇ㗀ࠍ

H-2㧦ጀౝᾲ⒖േ

H-1㧦☸ሶౝᾲ⒖േ
H-3㧦વᾲ▤ᾲ⒖േ

࿑ 2 ๆ⌕᧚లႯጀౝߩᾲ࡮‛⾰⒖േ㧔ๆ⌕ᤨ㧕
‛⾰⒖േߦߟ޿ߡ㧘ㅢᏱߩ‛ℂๆ⌕ߢߪ M-2 ߩๆ⌕㧔⣕⌕㧕ߪㄦㅦߦㅴⴕߔࠆߚ߼㧘⚦ሹ⴫㕙ߩฦὐߦ߅޿ߡዪᚲ⊛ߥๆ⌕ᐔⴧ߇ᚑ┙ߔࠆߣ⠨߃

વᾲ 2006 ᐕ 1 ᦬- 28 -J. HTSJ, Vol. 45, No. 190

․㓸㧦ๆ⌕ߩ਎⇇̆ࡒࠢࡠ߆ࠄࡑࠢࡠ㧘ߘߒߡࠪࠬ࠹ࡓ̆
⚫੺ߒߚ ST ࡕࠫࡘ࡯࡞ߣᲧセߔࠆߣ㧘FST ࡕࠫࡘ࡯࡞ߩᣇ߇ๆ⌕᧚లႯ㊂߇ 3 ୚߽ᄢ߈ߊߥߞߡ
޿ࠆߦ߽㑐ࠊࠄߕ㧘᷷ᐲ਄᣹᏷߇ዊߐߊ㧔FST ࡕࠫࡘ࡯࡞㧦8.0 K㧘ST ࡕࠫࡘ࡯࡞㧦9.4㨪13.5 K㧕㧘ࡈࠖࡦઃ߈વᾲ▤ߩવᾲଦㅴലᨐ߇⏕⹺ߢ߈ࠆ㧚߹ߚ㧘FST ࡕࠫࡘ࡯࡞ߩᄖ๟ㇱߣਛᔃㇱߩ᷷ᐲᏅ߽ 1 K ⒟ᐲߣዊߐߊߥߞߡ޿ࠆߎߣ߆ࠄ㧘ඨᓘᣇะߢ߶߷৻᭽ߦๆ⌕߇ㅴⴕߒߡ޿ࠆ᭽ሶ߇⷗ߡߣ
ࠇࠆ㧚ๆ⌕㊂ߦߟ޿ߡߪ㧘ታ㛎㐿ᆎ 10 ಽߢᐔⴧๆ
⌕ኈ㊂ߩ 60 %ߦ߹ߢ㆐ߒߡ߅ࠅ㧘ๆ⌕߇ㄦㅦߦㅴ
ࠎߢ޿ࠆߎߣ߇ಽ߆ࠆ㧚એ਄ࠃࠅ㧘FST ࡕࠫࡘ࡯࡞ߪ AHP ߩๆ⌕ེ↪ࡕࠫࡘ࡯࡞ߣߒߡఝࠇߚᕈ
⢻ࠍ᦭ߔࠆߎߣ߇᣿ࠄ߆ߣߥߞߚ[8]㧚

ਈ߃ࠆߎߣ߆ࠄ㧘ๆ⌕ེߩᕈ⢻ߪలႯጀౝᾲ⒖േ
ㅦᐲߦࠃࠅᡰ㈩ߐࠇࠆߣ޿ߞߡ߽ㆊ⸒ߢߪߥ޿㧚ߎߩలႯጀౝߩૐવᾲᕈߣ⸒ߞߚ໧㗴ὐࠍ〯߹߃㧘ᚒ‫ߪޘ‬లႯጀߦ߅ߌࠆ㒰ᾲ࡮⛎ᾲㅦᐲߩะ਄
ࠍ⋡⊛ߣߒߡ㧘ࡃࠗࡦ࠳࡯ࠍ↪޿ߡๆ⌕᧚ࠍ⋥ធવᾲ▤ߦႣᏓߔࠆ⋥ធᾲ੤឵ဳࡕࠫࡘ࡯࡞㧔 DSࡕࠫࡘ࡯࡞㧕[6]߿ๆ⌕᧚ࠍવᾲ▤ߣ৻૕ߦߒߚવ
ᾲ▤৻૕᭴ㅧဳᾲ੤឵ๆ⌕᧚ࡕࠫࡘ࡯࡞㧔ST ࡕࠫࡘ࡯࡞㧕ࠍ㐿⊒ߒߡ߈ߚ[7]㧚ST ࡕࠫࡘ࡯࡞ߦߟ
޿ߡߪ೨Ⓜߢ⚫੺ࠍⴕߞߚ㧚ᧄⓂߢߪ ST ࡕࠫࡘ࡯࡞ߩ⊒ዷᒻߣߒߡ㧘ߐࠄߥࠆવᾲଦㅴࠍ⋡⊛ߣߒߡવᾲ▤ߦࡈࠖࡦࠍ⸳⟎ߒߚࡈࠖࡦઃ ST ࡕࠫࡘ࡯࡞㧔FST㧕ࡕࠫࡘ࡯࡞ߦߟ޿ߡ᭎ⷐࠍㅀߴࠆ㧚
(56 ࡕࠫࡘ࡯࡞ߩ㐿⊒(56 ࡕࠫࡘ࡯࡞ߩ᭎ⷐ
࿑ 4 ߦ㧘FST ࡕࠫࡘ࡯࡞ߩ౮⌀߅ࠃ߮᭎⇛࿑ࠍ
␜ߔ㧚FST ࡕࠫࡘ࡯࡞ߪࡈࠖࡦઃ߈㌃⵾વᾲ▤㧘ࠪ࡝ࠞࠥ࡞㧘ࠬ࠹ࡦ࡟ࠬ✂߆ࠄ᭴ᚑߐࠇࠆ㧚ࠪ࡝ࠞࠥ࡞ߪࡈࠖࡦߣࡈࠖࡦߦ᜽߹ࠇߚ㓗㑆ㇱಽߦలႯߐࠇߡ߅ࠅ㧘ߘߩ๟ࠅࠍࠬ࠹ࡦ࡟ࠬ✂ߢ൮߻ߎߣߦࠃࠅ㧘ࠪ࡝ࠞࠥ࡞ࠍࡈࠖࡦ㑆ߦ଻ᜬߒߟߟ⫳᳇ㅘㆊᕈࠍ⛽ᜬߒߡ޿ࠆ㧚ࡈࠖࡦઃ߈વᾲ▤ߪ㌃▤߆ࠄࡈࠖࡦ߇ォㅧടᎿߐࠇߡ߅ࠅ㌃▤ - ࡈࠖࡦㇱߩធ⸅ᾲᛶ᛫߇ᭂ߼ߡዊߐߊఝࠇߚવᾲᕈ⢻ࠍ᦭ߒߡ޿ࠆ㧚

࿑ 5 FST ࡕࠫࡘ࡯࡞ߩๆ⌕㊂࡮᷷ᐲᄌൻ
વᾲ▤

ࠪ࡝ࠞࠥ࡞

㌃ࡈࠖࡦ

ࠬ࠹ࡦ࡟ࠬ✂

ᦨㆡ (56 ࡕࠫࡘ࡯࡞᭴ㅧߩ᳿ቯ
೨▵ߢ FST ࡕࠫࡘ࡯࡞ߩ᦭ലᕈ߇␜ߐࠇߚ߇㧘
FST ࡕࠫࡘ࡯࡞ߩ႐ว㧘વᾲ▤ߩߺߢߥߊࡈࠖࡦ
ߦࠃࠆ㒰ᾲ࡮⛎ᾲലᨐ߽ട߃ߡ޿ࠆߎߣ߆ࠄ㧘ࡈࠖࡦࡇ࠶࠴㧔లႯጀෘߺ㧕߇ጀౝવᾲㅦᐲߦᓇ㗀ࠍਈ߃ࠆ㧚߹ߚ㧘ࡈࠖࡦ㐳ߐ㧔లႯጀ㜞ߐ㧕߅ࠃ߮☸ሶᓘߪๆ⌕⾰ߢ޽ࠆ᳓⫳᳇ߩጀౝ‛⾰⒖േߦᓇ㗀ࠍਈ߃ࠆ㧚ߟ߹ࠅ㧘ࡈࠖࡦࡇ࠶࠴㧘ࡈࠖࡦ㐳ߐ㧘☸ሶᓘࠍࡄ࡜ࡔ࡯࠲࡯ߣߔࠆߎߣߦࠃࠅࡕࠫ
ࡘ࡯࡞᭴ㅧߩᦨㆡൻ߇࿑ࠇ㧘ߐࠄߥࠆๆ⌕ེᕈ⢻ߩะ਄߇⷗ㄟ߼ࠆ㧚ߎߩߚ߼ߦⴕߞߚℂ⺰⊛ᬌ⸛ߦߟ޿ߡ⚫੺ߔࠆ[9]㧚਄ㅀߒߚࠃ߁ߦ FST ࡕࠫࡘ࡯࡞ߪࡈࠖࡦ㑆ߦ☸ሶలႯጀ߇ᒻᚑߐࠇࠆߎߣ߆ࠄ㧘ၮᧄ⊛ߦߪ 3ߢ⺑᣿ߒߚᾲ࡮‛⾰⒖േࡕ࠺࡞߇ㆡ↪ߐࠇࠆ㧚FSTᾲ੤឵ᇦ૕

࿑ 4 FST ࡕࠫࡘ࡯࡞
(56 ࡕࠫࡘ࡯࡞ߩᾲ࡮‛⾰⒖േ᜼േ
FST ࡕࠫࡘ࡯࡞ࠍ↪޿ߡๆ⌕ታ㛎ࠍⴕߞߚ㓙ߩࡕࠫࡘ࡯࡞ౝ᷷ᐲ߅ࠃ߮ๆ⌕㊂ߩታ᷹୯ࠍ࿑ 5 ߦ␜ߔ㧚ᧄ࿑ߦߪ 4.3 એ㒠ߢ⚫੺ߔࠆᢙ୯⸃ᨆߦࠃ
ࠆ⸃ᨆ⚿ᨐ߽૬␜ߒߡ޽ࠆ㧚ᧄ࿑ࠃࠅ㧘ࡕࠫࡘ࡯࡞ౝ᷷ᐲߪๆ⌕㐿ᆎ⋥ᓟߦๆ⌕ߩㅴⴕߦ઻߁⊒ᾲߦࠃࠅᦨᄢߩ᷷ᐲ਄᣹ࠍ⚻ߚᓟ㧘ೋᦼ᷷ᐲߦ࿁ᓳߒߡ޿ࠆ㧚ߥ߅㧘ᧄ࿑ߦߪ␜ߐࠇߡ޿ߥ޿߇㧘ߎߩᦨᄢ᷷ᐲ਄᣹᏷ࠍ೨Ⓜߢ

વᾲ 2006 ᐕ 1 ᦬- 29 -J. HTSJ, Vol. 45, No. 190

․㓸㧦ๆ⌕ߩ਎⇇̆ࡒࠢࡠ߆ࠄࡑࠢࡠ㧘ߘߒߡࠪࠬ࠹ࡓ̆
ࡕࠫࡘ࡯࡞ߩ⸃ᨆࡕ࠺࡞ࠍ࿑ 6 ߦ␜ߔ㧚ᧄ⸃ᨆߢߪࡈࠖࡦߣࡈࠖࡦߦ᜽߹ࠇߡᒻᚑߐࠇࠆ 1 ࡈࠖࡦࡇ࠶࠴㑆ߩ☸ሶలႯጀߦߟ޿ߡߩ⸃ᨆࠍታᣉߒߚ㧚٤ᾲ੤឵ᇦ૕ߩᾲ෼ᡰᑼ§ wTW

UW C p,W ¨

© wT

 uW

wTW ·
¸
wZ ¹

w 2TW (6)4hTW , R Ri  TW  Ow
D
wZ 2

>

@

R=0
Fin length, L⴫ 1 ⸃ᨆߦ↪޿ߚਥߥ‛ᕈ୯Db'H
Ds(200 Pm)
OB[m2][W/(m K)][kJ/kg][m2/s]
2,500
0.14
2.310-13
1.3210-11

Z

Water vapor

Fin pitch, Z

Z=Z0

Z=0
Ri=8 mm
Rm=9 mm

R
R=Ri R=Rm

Copper fin
R=R0࿑ 6 FST ࡕࠫࡘ࡯࡞ᢙ୯⸃ᨆࡕ࠺࡞
ߎߎߢ㧘એਅߩ઒ቯࠍ߅ߊߣๆ⌕ེߩᾲ࡮‛⾰⒖േᣇ⒟ᑼߪᑼ(1)㨪(6)ߢ⴫ߐࠇࠆ㧚1㧚ๆ⌕᧚☸ሶౝ‛⾰⒖േߪ⴫㕙᜛ᢔᡰ㈩ߢ޽ࠆ
2㧚ࠬ࠹ࡦ࡟ࠬ✂ߢߩ⫳᳇⒖േᛶ᛫ߪήⷞߢ߈ࠆ
3㧚ࡕࠫࡘ࡯࡞ᄖ⴫㕙߆ࠄߩᾲ៊ᄬߪήⷞߢ߈ࠆ
4㧚ࠬ࠹ࡦ࡟ࠬ✂ߩᾲኈ㊂ߪήⷞߢ߈ࠆ
5㧚ᾲ੤឵ᇦ૕ߪ㕖࿶❗ᕈߢᩖᵹᵹࠇߢ޽ࠆ٤ ๆ⌕᧚☸ሶలႯጀߩ‛⾰෼ᡰᑼ2
Db ª §¨ w 2 U v 1 wU v w 2 U v ·¸ § wU v ·
«U v
 ¨¨


¸¸
PU 0 «¬ ¨© wR 2 R wRwZ 2 ¸¹ © wR ¹

wU
H v
wT

2
wq
§ wU · º ¨¨ v ¸¸ »  1  H U AwT© wZ ¹ »¼(1)٤ๆ⌕᧚☸ሶౝߩ‛⾰෼ᡰᑼ

wq
wT
q

1 w §
2 wq ·¸¨ DS r2
wr ¹
r wr ©
3

r0

(2)

2

0.03

(3)

³ r qdrr03 0

qw ='q  Ws

wTB
wT

2

ª§ w TBO B «¨¨«¬© wR2

qw [kg/module]٤ๆ⌕᧚☸ሶలႯጀߩᾲ෼ᡰᑼU B C p, B

2



1 wTB ·¸ w TB º»
R wR ¸¹ wZ 2 »¼

wq
 U B 'HwTª§ w 2T
1 wTC ·¸ w 2TC ºCOC «¨¨
»2
R wR ¸¹ wZ 2 »¼«¬© wRવᾲ 2006 ᐕ 1 ᦬

dp
200 PmP
dp == 200
O

0.02

0.01
Fin length
L=10mm
L=12mm
L=14mm(4)٤વᾲ▤ߩᾲ෼ᡰᑼwTU C C p ,C CwT⸘▚ߦ૶↪ߒߚઍ⴫⊛ߥ‛ᕈ୯ࠍ⴫ 1 ߦ␜ߔ㧚ࠪ࡝ࠞࠥ࡞లႯጀߩᾲવዉᐲߪታ᷹୯ࠍ૶↪ߒߚ㧚ๆ⌕ᾲ'H ߪ᳓ߩ⫳⊒ẜᾲߣ╬ߒ޿߽ߩߣ઒ቯߒ
ߚ㧚☸ሶౝ᜛ᢔଥᢙ Ds ߪᣢႎߩᚻᴺߦࠃࠅታ᷹୯
߆ࠄ▚಴ߒߚ‫ߚ߹ޕ‬㧘ࡕࠫࡘ࡯࡞ౝߩࠪ࡝ࠞࠥ࡞વᾲ▤㨯ࡈࠖࡦᄖოߦߪធ⸅ᾲᛶ᛫߇ሽ࿷ߔࠆߣ
ߒ㧘hc=20 W/(m2 K)ߣߒߚ㧚⸘▚ߪ‫ޔ‬ᑼ(1)㨪(6)ࠍ
೨ㅴᏅಽᴺߦࠃࠅ⸃޿ߚ㧚ᧄ⸃ᨆߩ⹦⚦ߦߟ޿ߡߪ㧘ෳ⠨ᢥ₂[8]ࠍෳᾖߒߡ޿ߚߛ߈ߚ޿㧚వㅀߒߚ࿑ 5 ߦᧄ⸃ᨆߦࠃࠆ⸘▚⚿ᨐࠍታ᷹୯
ߣ౒ߦ␜ߒߡ޿ࠆ߇㧘ታ㛎⚿ᨐߣ⸘▚⚿ᨐߪ⦟ᅢߦ৻⥌ߒߡ߅ࠅ㧘ᧄ⸃ᨆߩᅷᒰᕈ߇␜ߐࠇߚ㧚ߘߎߢ㧘ᧄ⸃ᨆࠍ↪޿ߡ FST ࡕࠫࡘ࡯࡞ߩᦨㆡ
᭴ㅧߩ᳿ቯࠍⴕߞߚ㧚ߎߩ㓙㧘AHP ߩⒿേ᧦ઙߣߒߡ TL/TM/TH=15/30/80 ͠㧘ๆ࡮⣕⌕ᤨ㑆 600 s ߣߒߚ㧚ᦨㆡൻߩᜰᮡߣߒߡߪ㧘ࡕࠫࡘ࡯࡞ 1 ࡈࠖࡦࡇ࠶࠴㑆ߩ᳓⫳᳇ๆ⌕ኈ㊂ࠍ↪޿㧘ၮᧄ⊛ߦߪߎࠇ߇ᄢ߈޿߶ߤఝࠇߚᕈ⢻ࠍ᦭ߔࠆߣ್ᢿߒߚ㧚ᦨㆡࡈࠖࡦࡇ࠶࠴
࿑ 7 ߦ㧘ๆ⌕ㆊ⒟ 600 s 㑆ߦ߅ߌࠆࠪ࡝ࠞࠥ࡞ 1
kg ޽ߚࠅߩ᳓⫳᳇ๆ⌕㊂'q [kg/kg]ߣࡕࠫࡘ࡯࡞
৻ᧄ޽ߚࠅߦలႯน⢻ߥࠪ࡝ࠞࠥ࡞ߩ㊀㊂ Ws[kg/module]ߩⓍ㧘ߔߥࠊߜࡕࠫࡘ࡯࡞৻ᧄ޽ߚࠅ
ߩ᳓⫳᳇ๆ⌕㊂ qw='qWs [kg/module]ࠍ␜ߔ㧚

0

0

1

2

Fin length
L=16mm
L=18mm
L=20mm3

4

5

Fin pitch Z   [mm](5)

࿑ 7 ᦨㆡࡈࠖࡦࡇ࠶࠴ߩ᳿ቯ㧔dp=200 Pm㧕

- 30 -J. HTSJ, Vol. 45, No. 190

․㓸㧦ๆ⌕ߩ਎⇇̆ࡒࠢࡠ߆ࠄࡑࠢࡠ㧘ߘߒߡࠪࠬ࠹ࡓ̆ᧄ ࿑ ࠃ ࠅ 㧘 ฦ ‫ ࡦ ࠖ ࡈ ߩ ޘ‬㐳 ߐ ߦ ߅ ޿ ߡ qw
[kg/module]߇ᦨᄢ୯ࠍ␜ߔࡈࠖࡦࡇ࠶࠴߇ሽ࿷ߔ
ࠆߎߣ߇ಽ߆ࠆ㧚ߎࠇߪ㧘ࡈࠖࡦࡇ࠶࠴ߩჇᄢߦ
઻޿'q [kg/kg]ߪᷫዋߒ㧘Ws [kg/module]ߪჇᄢߔࠆ
ߣ޿߁⋧෻㑐ଥߦࠃࠆ㧚೨⠪ߩℂ↱ߪ㧘ࡈࠖࡦࡇ࠶࠴ߩჇᄢߦ઻޿ࡈࠖࡦߦࠃࠆવᾲଦㅴߩነਈ߇
ዊߐߊߥࠆߚ߼ߢ޽ࠅ㧘ᓟ⠪ߩℂ↱ߪන৻ࡕࠫࡘ
࡯࡞޽ߚࠅߩᝌ౉ࡈࠖࡦᢙߩᷫዋߦࠃࠆ㧚ᧄ࿑ࠃࠅ㧘ࡈࠖࡦ㐳ߐߦࠃࠄߕᦨㆡࡈࠖࡦࡇ࠶࠴ߪ 1.0
㨪2.0 mm ߢ޽ࠆߎߣ߇᣿ࠄ߆ߣߥߞߚ㧚ᦨㆡࡈࠖࡦ㐳ߐ
࿑ 8 ߦ㧘න৻ࡕࠫࡘ࡯࡞޽ߚࠅߩ᳓⫳᳇ๆ⌕㊂
qw [kg/module] ߣන৻ࡕࠫࡘ࡯࡞޽ߚࠅߩᔅⷐⵝ
⟎㕙Ⓧ S [m2]㧔࿑ 9 ෳᾖ㧕ߩㅒᢙ 1/S [1/m2] ߩⓍ
qw/S [kg/(m2 module)]ࠍ␜ߔ㧚ᧄ࿑ࠃࠅ㧘ࡈࠖࡦࡇ࠶࠴ߩ႐วߣห᭽ߦ㧘ߘࠇߙࠇߩࡈࠖࡦࡇ࠶࠴ߦ
ኻߒߡᦨㆡߥࡈࠖࡦ㐳ߐ߇ሽ࿷ߔࠆߎߣ߇ಽ߆ࠆ㧚ߎࠇߪࡈࠖࡦ㐳ߐߩჇᄢߦ઻޿ qw [kg/module]߇
Ⴧᄢߔࠆ৻ᣇ㧘1/S [m-2]߇ᷫዋߔࠆߣ޿߁⋧෻㑐ଥߦࠃࠆ㧚ߥ߅㧘qw ߪࡈࠖࡦ㐳ߐߩჇᄢߦ઻ߞߡ
⫳᳇ㅘㆊᕈ߇ૐਅߔࠆߚ߼ๆ⌕᧚ߩ೑↪₸ߪૐਅߔࠆ߇㧘৻ᣇߢๆ⌕᧚ߩలႯ㊂߇Ⴧടߔࠆߚ߼㧘⚿ᨐ⊛ߦๆ⌕㊂ߪන⺞Ⴧടߔࠆߎߣߣߥࠆ㧚ᧄ࿑ࠃࠅ㧘ᦨㆡࡈࠖࡦ㐳ߐߪ 11㨪14 mm ߣ᳿ቯߐࠇߚ㧚7

qw/S [kg/(m2 module)]

ddp
200Pm
Pm
p ==200

6

5
Fin pitch
Z=1.0mm
Z=1.5mm
Z=2.0mm
Z=2.5mm
Z=3.0mm

4

3

0

5

10

15

20

Fin length L [mm]࿑ 7 ᦨㆡࡈࠖࡦ㐳ߐߩ᳿ቯ㧔dp=200 Pm㧕
S

2

1

18

 ᦨㆡ (56 ࡕࠫࡘ࡯࡞ߩᕈ⢻⹏ଔ
4.3.1㧘4.3.2 ߦࠃࠅ᳿ቯߐࠇߚ FST ࡕࠫࡘ࡯࡞᭴
ㅧߩᦨㆡൻߩലᨐߦߟ޿ߡ⹏ଔࠍⴕ߁㧚ᧄᬌ⸛ࠍⴕ߁ߦ޽ߚࠅ㧘೨▵ߢߩๆ⌕ེන૏㕙Ⓧ޽ߚࠅߩ᳓⫳᳇ๆ⌕㊂Ꮕ qw/S [kg/(m2 module)]ࠍ↪޿ߡ㧘ᰴᑼߦࠃࠅๆ⌕ེන૏ኈⓍ޽ߚࠅߩ಄ᾲ಴ജ Qoutput[kW/m3]ࠍ▚಴ߒߚ㧚
Qoutput ,1

1
q w S  H 01  'H eva W cycle

ᑼ(7)ߦ߅޿ߡ㧘Ho ߪ FST ࡕࠫࡘ࡯࡞ߩో㐳㧔= 0.5m㧕㧘'H ߪ᳓ߩ⫳⊒ẜᾲ㧔= 2,500 kJ/kg㧕㧘Wcycle ߪࠨࠗࠢ࡞ᤨ㑆㧔= 600 s㧕ߢ޽ࠆ㧚
⴫ 2 ᦨㆡൻߦࠃࠆ FST ࡕࠫࡘ࡯࡞ߩ಴ജะ਄
Qoutput,1
qw/S
V102
2
3
[kW/m ]
[kg/m ]
[m3/kW]
3.01
25.1
3.98
ᦨㆡൻ೨
6.44
53.7
1.86
ᦨㆡൻᓟ
⴫ 2 ࠃࠅ㧘FST ࡕࠫࡘ࡯࡞᭴ㅧߩᦨㆡൻߦࠃࠅ㧘ᦨㆡൻ೨ߩᣢሽ FST ࡕࠫࡘ࡯࡞ߦᲧߴߡๆ⌕ེኈⓍࠍ⚂ 1/2 ߦࠦࡦࡄࠢ࠻ൻߔࠆߎߣ߇น⢻ߢ޽ࠆߎߣ߇᣿ࠄ߆ߣߥߞߚ㧚ᦨㆡ (56 ࡕࠫࡘ࡯࡞ࠍ↪޿ߚ #*2 ߩㅪ⛯ㆇォ
4 ▵ߢᦨㆡߥ FST ࡕࠫࡘ࡯࡞ߩ᭴ㅧ߇᳿ቯߐࠇ
ߚߎߣ߆ࠄ㧘ታ㓙ߦᦨㆡ FST ࡕࠫࡘ࡯࡞ࠍ↪޿ߚ
AHP ࠍ⹜૞ߒ㧘ㅪ⛯ㆇォ⹜㛎ࠍታᣉߒߚ㧚 ㅪ⛯ㆇォ⹜㛎ⵝ⟎
AHP ߩㅪ⛯ㆇォ⹜㛎ߢߪ㧘Ꮢ⽼વᾲ▤ߩਛ߆ࠄᦨㆡ FST ࡕࠫࡘ࡯࡞᭴ㅧߦᦨ߽ㄭ޿ࡈࠖࡦࡇ࠶࠴
=2.3 mm‫ࡦࠖࡈޔ‬㐳ߐ=11 mm ߩࡈࠖࡦઃવᾲ▤ࠍㆬቯߒ㧘࿑ 9 ߦ␜ߔๆ⌕ེࠍ⹜૞ߒߚ㧚ๆ⌕ེߪ
2 ེߩๆ⌕ེ߆ࠄ᭴ᚑߐࠇߡ߅ࠅ㧘ฦེߦᦨㆡ FSTࡕࠫࡘ࡯࡞ࠍ 3 ਗ೉ 12 ⋥೉ߢ 36 ᧄߕߟ⚵ߺㄟࠎߛ㧚ࠪ࡝ࠞࠥ࡞㊀㊂ߪ 5.8 kg-dry basis ߢ޽ߞߚ㧚
Water in

FST module

Water outL

Condenser
797

Stainless
mesh

94

750A

400

Evaporator

I800

࿑ 8 ᔅⷐⵝ⟎㕙Ⓧ S ߩቯ⟵

વᾲ 2006 ᐕ 1 ᦬(7)

࿑ 9 ᦨㆡ FST ࡕࠫࡘ࡯࡞⚵ߺㄟߺๆ⌕ེ- 31 -J. HTSJ, Vol. 45, No. 190

․㓸㧦ๆ⌕ߩ਎⇇̆ࡒࠢࡠ߆ࠄࡑࠢࡠ㧘ߘߒߡࠪࠬ࠹ࡓ̆

ฦๆ⌕ེߪๆ⌕࡮⣕⌕ㆊ⒟ߦ߅޿ߡ⫳⊒ེ࡮ಝ❗ེߦㅪ⚿ߐࠇ㧘FST ࡕࠫࡘ࡯࡞ߦలႯߐࠇߚࠪ
࡝ࠞࠥ࡞߇᳓⫳᳇ߩๆ࡮⣕⌕ࠍ੤੕ߦⴕ߁ߎߣߦ
ࠃࠅ㧘⫳⊒ེ߆ࠄㅪ⛯⊛ߦ಄ᚱ↪ߩ಄ᾲࠍขࠅ಴
ߔߎߣ߇น⢻ߣߥߞߡ޿ࠆ㧚ታ㛎ߪ⒳‫ߩޘ‬ㆇォ᧦ઙߢⴕߞߚ߇㧘৻଀ߣߒߡ TL/TM/TH=14/30/75 ͠㧘ๆ࡮⣕⌕ᤨ㑆 300 s㧘ࠨࠗࠢ࡞Ḱ஻ᤨ㑆 30 s ߢߩቯᏱࠨࠗࠢ࡞ㆇォᤨߦ߅ߌࠆๆ⌕ེ 1㧘ಝ❗ེ㧘⫳⊒ེߩᾲ੤឵ᵹ૕౉ญ࡮಴ญ᷷ᐲࠍ࿑ 10 ߦ␜ߔ㧚ᧄ࿑ࠃࠅ㧘ಝ❗ེ㧘⫳⊒ེߦߪߘࠇߙࠇᚲቯ᷷ᐲ
ߩ಄ළ᳓㧔TM㧕߅ࠃ߮಄᳓㧔TL㧕߇ଏ⛎ߐࠇߡ޿ࠆ㧚৻ᣇ㧘ๆ⌕ེߦߪๆ࡮⣕⌕ㆊ⒟ߢ಄ළ᳓߅ࠃ
߮㜞᷷᳓㧔TH㧕߇੤੕ߦᵹㅢߒߡ޿ࠆ㧚ಝ❗ེߢߪ㧘ๆ⌕᧚߆ࠄ⣕⌕ߒߚ᳓⫳᳇ߩಝ❗ߦ઻߁⊒ᾲߦࠃࠅ಴ญ᷷ᐲ߇਄᣹ߒߡ޿ࠆ㧚ๆ⌕ེߢߪๆ⌕ㆊ⒟ߢߪๆ⌕ᾲߩ㒰ᾲ㧘⣕⌕ㆊ⒟ߢߪ⣕⌕ᾲߩ⛎
ᾲߦࠃࠅ಴ญ᷷ᐲ߇਄᣹࡮ਅ㒠ߒߡ޿ࠆ㧚৻ᣇ㧘⫳⊒ེߢߪ᳓ߩ⫳⊒ߦ઻߁ๆᾲ߇↢ߓ㧘ࠊߕ߆ߥᄌേߪ⷗ࠄࠇࠆ߽ߩߩ㧘10 ͠೨ᓟߩ಄ᾲ߇቟ቯߦ
ᓧࠄࠇߡ޿ࠆ㧚AHP ߢߪ㧘ߎߩ಄ᾲࠍ಄ᚱⓨ⺞↪
ߣߒߡ೑↪ߔࠆߎߣ߆ࠄ㧘ᧄ⹜㛎ⵝ⟎ߦࠃࠅ AHP
ߩㅪ⛯⊛ߥ಄ᾲ↢ᚑ߇ታ⸽ߐࠇߚ㧚Temperature [oC]

80

Ads.

kW/m3-adsorber ߣߥࠆ㧚৻ᣇ㧘Ꮢ⽼ߐࠇߡ޿ࠆ AHPߩᲧ಴ജߪ 48 kW/m3-adsorber ⒟ᐲߣផ᷹ߐࠇࠆ㧚એ਄ࠃࠅ㧘ᦨㆡൻߐࠇߚ FST ࡕࠫࡘ࡯࡞ࠍ⚵ߺㄟࠎߛๆ⌕ࡅ࡯࠻ࡐࡦࡊߩๆ⌕ེߪ㧘Ꮢ⽼ AHP ߩๆ⌕ེߩ⚂ 2 ୚ߩᲧ಴ജࠍ᦭ߔࠆߎߣ߇ታ⸽ߐࠇ㧘ᧄ FST ࡕࠫࡘ࡯࡞߇ AHP ߩࠦࡦࡄࠢ࠻ൻߦኻߒ
ߡ㧘߈ࠊ߼ߡነਈ߇ᄢ߈޿ߎߣ߇᣿ࠄ߆ߣߥߞߚ㧚߅ࠊࠅߦ
ᧄⓂߢߪ㧘ๆ࡮⣕⌕ࠍ೑↪ߒߚᾲ೑↪ᛛⴚߩ৻ߟߢ޽ࠆๆ⌕ࡅ࡯࠻ࡐࡦࡊߦߟ޿ߡ㧘ๆ⌕ེౝߩᾲ࡮‛⾰⒖േ⃻⽎ߩℂ⸃ߣߘߩଦㅴߣ⸒߁⌕⌒ὐߦ┙ߜ㧘ᚒ‫ߢ߹ࠇߎ߇ޘ‬ታᣉߒߡ߈ߚ⎇ⓥ⚿ᨐࠍਛᔃߦ᭎⺑ߒߡ߈ߚ㧚ๆ⌕ࡅ࡯࠻ࡐࡦࡊߪⅣႺ᷷
ᐲߦㄭ޿ૐ᷷ឃᾲߩ᦭ല೑↪߇น⢻ߣ޿߁ὐߢ㧘ⅣႺ౒↢ဳᾲࠛࡀ࡞ࠡ࡯ࠪࠬ࠹ࡓߣߒߡᄢ߈ߥน
⢻ᕈࠍ⒁߼ߡ޿ࠆߣ⏕ାߒߡ޿ࠆ㧚੩ㇺ⼏ቯᦠߩ⊒ലߦࠃࠅੑ㉄ൻ὇⚛ឃ಴㊂ߩ೥ᷫ㧘ߟ߹ࠅߪࠛ
ࡀ࡞ࠡ࡯ᶖ⾌㊂ߩ೥ᷫ߇᳞߼ࠄࠇߡ޿ࠆᤓ੹㧘᏷
ᐢ޿ಽ㊁ߩ⎇ⓥ⠪ࠄߩදജߦࠃࠆᮮᢿ⊛ߥ⎇ⓥផ
ㅴߦࠃࠅ㧘ๆ⌕ࡅ࡯࠻ࡐࡦࡊߩታ↪⊛ߥ㐿⊒߇৻ጀㅴዷߔࠆߎߣࠍಾᦸߒ㧘⚿߮ߣߔࠆ㧚

Des.

ෳ⠨ᢥ₂
[1] ᷰㄝ⮮㓶㧘᨞⼱᣽ା㧘વᾲ⎇ⓥ㧘36-140 (1997)
12-17.

Adsorber-1 inAdsorber-1 out
Condenser inCondenser out
Evaporator in
Evaporator out

6040࿑ 10 AHP ߦࠃࠆㅪ⛯಄ᾲ↢ᚑߩታ⸽[2] NEDO㧘ࠛࡀ࡞ࠡ࡯૶↪วℂൻᛛⴚᚢ⇛⊛㐿⊒ ᐔᚑ 15 ᐕᐲႎ๔ᦠ(100003368) (2004).
[3] ൻቇᎿቇળ⫾ᾲ࡮Ⴧᾲ࡮ᾲャㅍᛛⴚ․೎⎇ⓥ
ળ✬㧘⫾ᾲᛛⴚ㧙ℂ⺰ߣߘߩᔕ↪ ╙ II ✬‫ޟ‬ẜᾲ⫾ᾲ‫ޔ‬ൻቇ⫾ᾲ‫ޠ‬㧘ାጊ␠ࠨࠗ࠹࠶ࠢ (2001).
[4] Yamamoto, E., et al., J. Chem. Eng. Japan, 33-1
(2000) 12-18.

ߎߎߢ㧘ᓧࠄࠇߚ಄ᾲ಴ജࠍᰴᑼߦࠃࠅ▚಴ߔࠆ㧚[5] ᷰㄝ⮮㓶ࠄ㧘ൻቇᎿቇ⺰ᢥ㓸㧘19-1 (1993)
83-90.

TL/TM/TH=14/30/75 oC
Wcycle=300 s
Wprepare=30 s

20
0
165

Qoutput , 2

170

175
180
Time [min]185

U W  C p ,W  Feva  'Teva,ave[6] દ⮮⌬ᒄࠄ㧘ൻቇᎿቇ⺰ᢥ㓸㧘22-1 (1996)
163-170(8)[7] ᷰㄝ⮮㓶ࠄ㧘ൻቇᎿቇ⺰ᢥ㓸㧘20-3 (1994)
339-345.

ᑼ(8)ߦ߅޿ߡ㧘Feva ߪ⫳⊒ེߩᾲ੤឵ᇦ૕ᵹ㊂㧘'Teva,ave ߪๆ⌕ᦼ㑆ߦ߅ߌࠆᾲ੤឵ᇦ૕ߩ౉ญ࡮಴
ญ᷷ᐲᏅߩᐔဋ୯ߣߒߡቯ⟵ߐࠇࠆ㧚਄⸥ㆇォ᧦ઙߢߩ಄ᾲ಴ജࠍ▚಴ߔࠆߣ㧘Qoutput,2=2.76 kW ߣߥࠅ㧘ߎߩ಄ᾲ಴ജߣๆ⌕ེኈⓍ߆ࠄᧄ AHP ߦߟ޿ߡๆ⌕ེၮḰߩᲧ಴ജࠍ▚಴ߔࠆߣ㧘107

વᾲ 2006 ᐕ 1 ᦬[8] ⮮ ᴛ ੫ ࠄ 㧘 ൻ ቇ Ꮏ ቇ ⺰ ᢥ 㓸 㧘 28-3 (2002)
247-254.
[9] Li, J., et al., J. Chem. Eng. Japan, 37-4 (2004)
551-557.

- 32 -J. HTSJ, Vol. 45, No. 190

․㓸㧦ๆ⌕ߩ਎⇇̆ࡒࠢࡠ߆ࠄࡑࠢࡠ㧘ߘߒߡࠪࠬ࠹ࡓ̆

⫳᳇ๆ⌕⃻⽎ࠍ↪޿ߚẜᾲ࡮㗼ᾲߩ⁛┙೙ᓮ
The Application of Water Vapor Adsorption Phenomena to
the Independent Control of Latent and Sensible Heatựᧄ ⧐ᓼ㧘᫪ ⧷ᄦ㧔਻Ꮊᄢቇ㧕
Yoshinori HAMAMOTO, Hideo MORI (Kyushu University)e-mail: y-hama@mech.kyushu-u.ac.jpߪߓ߼ߦ
ᦨㄭߪ㧘૑ⅣႺߩᔟㆡᕈ㧘㘩ຠߩടᎿ࡮▤ℂߦ
߅ߌࠆ቟ోᕈ߅ࠃ߮↥ᬺᯏེߩ↢↥ᕈะ਄ߦ㑐ߔࠆ㔛ⷐ߇Ⴧടߒߡ߅ࠅ㧘㜞ᕈ⢻࡮㜞ല₸ߢ޽ࠅߥ߇ࠄหᤨߦឃᾲߥߤࠍᵴ↪ߒߚ⋭ࠛࡀ࡞ࠡ࡯ဳߩ
ẜᾲ࡮㗼ᾲߩ೙ᓮᛛⴚߩ㐿⊒߇ᕆോߣߥߞߡ޿ࠆ㧚⫳᳇ๆ⌕⃻⽎ࠍᔕ↪ߒߚẜᾲ࡮㗼ᾲߩ⁛┙೙ᓮᛛⴚߣߒߡๆ⌕㒰ടḨᯏߣๆ⌕಄ಓ࡮ࡅ࡯࠻ࡐࡦ
ࡊ[1-3]߇޽ࠆ㧚৻⥸ߦ೨⠪ߪࠝ࡯ࡊࡦࠨࠗࠢ࡞ߣ
๭߫ࠇ㧘ⓨ᳇ਛߩḨಽ߇ๆ⌕᧚ߣๆ⣕⌕ߔࠆ㧚ᓟ⠪ߪࠢࡠ࡯࠭࠼ࠨࠗࠢ࡞ߣ๭߫ࠇ㧘ᄖ᳇ߣኒ㐽ߐࠇߚኈེౝߢ㧘વᾲ㕙਄ߦలߡࠎߐࠇߚๆ⌕᧚ߦ⫳᳇߇ๆ⣕⌕ߔࠆ㧚ਔ⠪ߩๆ⣕⌕⃻⽎ߪၮᧄ⊛ߦหߓߢ޽ࠆ㧚߹ߚ㧘ߎࠇࠄߪࠦ࡯ࠫࠚࡀ࡟࡯࡚ࠪ
ࡦࠪࠬ࠹ࡓ߿Άᢱ㔚ᳰߣߩⶄวൻߦࠃߞߡᾲࠛࡀ
࡞ࠡ࡯ߩࠞࠬࠤ࡯࠼⊛೑↪ࠍଦㅴߔࠆᛛⴚߣߒߡ
૏⟎ߠߌࠄࠇ㧘ⷐ⚛ᯏེౝߩવᾲ㧔ᾲߣ‛⾰⒖േ㧕․ᕈ߇ᕈ⢻ߦᄢ߈ߊ㑐ਈߔࠆ㧚
ᧄⓂߢߪ㧘ਥߦࠝ࡯ࡊࡦࠨࠗࠢ࡞ߦᵈ⋡ߒߡ㧘⫳᳇ߩๆ⣕⌕ߣẜᾲ࡮㗼ᾲߩ⁛┙೙ᓮ㧘⫳᳇ߩ⒖
േේℂߣๆ⌕᧚ߦߟ޿ߡ㧘ߐࠄߦๆ⌕ࠍᔕ↪ߒߚ㒰ടḨᯏེߩⷐ⚛ߣࠪࠬ࠹ࡓߦ㑐ߔࠆ⎇ⓥࠍ⚫੺ߔࠆ㧚ߥ߅㧘ẜᾲ࡮㗼ᾲߩ⁛┙೙ᓮߣߪ㧘ⓨ᳇ࠍ㒰ടḨߔࠆẜᾲಣℂᠲ૞ߣ㧘ⓨ᳇ߩ᷷ᐲࠍ਄ߍਅ
ߍߔࠆ㗼ᾲಣℂᠲ૞ࠍ㧘ߘࠇߙࠇㆡߒߚᣇᴺߦࠃ
ߞߡ୘೎ߦⴕ߁ߎߣߢ޽ࠆ㧚⌕᧚లߡࠎጀࠍㅢㆊߔࠆ㧚ߘߩߣ߈ๆ⌕᧚ߪടᾲߐࠇ㧘Ḩಽ߇⣕⌕ߒߡౣ↢ߐࠇࠆ㧚৻ᣇ㧘⫳᳇࿶❗ߦ߅ߌࠆଏ⛎ⓨ᳇ߪ㧘߹ߕ㔺ὐ᷷ᐲએਅߩવᾲ
㕙ߦធ⸅ߒߡㆊ಄ළߐࠇ㧘Ḩಽ߇⚿㔺ߒߡขࠅ㒰߆ࠇࠆ㧚ߘߩᓟ㧘ଏ⛎ⓨ᳇᷷ᐲ߹ߢౣᾲߐࠇࠆ㧚ࠛࡀ࡞ࠡ࡯ᶖ⾌ߩⷞὐ߆ࠄ࿑ 2 ߦ␜ߔࠃ߁ߦ㧘࠺ࠪࠞࡦ࠻ߦ߅ߌࠆ⣕⌕ౣ↢ㆊ⒟ߣଏ⛎ⓨ᳇ߩ಄
ළㆊ⒟ߦⷐߔࠆࠛࡀ࡞ࠡ࡯߇㧘⫳᳇࿶❗ߦ߅ߌࠆㆊ಄ළߣౣᾲᠲ૞ߦⷐߔࠆࠛࡀ࡞ࠡ࡯ࠃࠅ߽ዊߐ
޿႐วߦ㧘ๆ⌕ᑼߩ⋭ࠛࡀ࡞ࠡ࡯ᕈߪఝ૏ߣߥࠆ㧚ឃᾲࠍ᦭ലᵴ↪ߔࠆๆ⌕ᑼߪ㧘⋭ࠛࡀ࡞ࠡ࡯ᕈߩ
㜞޿᷷Ḩᐲ೙ᓮᛛⴚߢ޽ࠆ㧚
Relative⋧ኻḨᐲhumidity I 100%
30

10

40

80%
60%
40% 120

ಣℂ
ⓨ᳇
㸣

ౣ↢

140
ⓨ᳇
ടᾲ

20%
㗼ᾲ੤឵

60

10%

ㆊ
಄
ළ

䊂
䉲䉦

䊮䊃

4%

20
㸡
ଏ⛎
ⓨ᳇

0
0

80

[kJ
/kg
䊦lp
䊏y
䊷h

20

E䉣n
th䉺a
䊮

Humidity⛘ኻḨᐲ x [g/kg']

']

100

0

಄ළ

㗼ᾲ੤឵

2%

50
Dry–bulb temperature
T [͠]
᷷ᐲ

࿑ 1ๆ⌕ᑼߣ಄ළᑼߩⓨ᳇⁁ᘒẜᾲ࡮㗼ᾲߩ⁛┙೙ᓮߣ⫳᳇ߩๆ⣕⌕ ⁛┙೙ᓮߣ⋭ࠛࡀ࡞ࠡ࡯ᕈ
࿑ 1 ߦߪๆ⌕ᑼ㧔࠺ࠪࠞࡦ࠻㧕ߣ⫳᳇࿶❗ᑼ㧔಄ළᑼ㧕ߩߘࠇߙࠇߦࠃߞߡ೙ᓮߐࠇࠆⓨ᳇ߩ᷷Ḩᐲ⁁ᘒࠍⓨ᳇✢࿑਄ߦ␜ߒߚ㧚ๆ⌕ᑼߦ߅޿ߡಣ
ℂⓨ᳇ߪๆ⌕᧚ߢ㒰Ḩߐࠇ㧘⊒↢ߔࠆ෻ᔕᾲߪ㗼ᾲ੤឵ེߢᾲ࿁෼ߐࠇ㧘ߐࠄߦ಄ළེߢଏ⛎᷷ᐲߦ೙ᓮߐࠇࠆ㧚߹ߚ㧘ౣ↢ⓨ᳇ߪ㗼ᾲ੤឵ེߦߡ
ᾲ࿁෼ߒ㧘ടᾲ᣹᷷ߐࠇ㧘ๆ⌕ࡠ࡯࠲޽ࠆ޿ߪๆ

વᾲ 2006 ᐕ 1 ᦬⋭䉣䊈䊦䉩䊷ᕈ䈱್ᢿၮḰ⫳᳇࿶❗䉲䉴䊁䊛䈮䈍䈔䉎ㆊ಄ළᷫḨᠲ૞
ౣᾲᠲ૞䈮ⷐ䈜䉎䉣䊈䊦䉩䊷䋾䊂䉲䉦䊮䊃䉲䉴䊁䊛䈮䈍䈔䉎ౣ↢ടᾲᠲ૞
ଏ⛎ⓨ᳇಄ළᠲ૞
䈮ⷐ䈜䉎䉣䊈䊦䉩䊷䉮䉳䉢䊈䊧䊷䉲䊢䊮䋬Άᢱ㔚ᳰ䈱ឃᾲ䋬ౣ↢䉣䊈䊦䉩䊷䈱ᵴ↪
䊂䉲䉦䊮䊃ౣ↢ടᾲᠲ૞䈮ᛩ౉⋭䉣䊈ᕈ䈱᧦ઙ䉕䉪䊥䉝

࿑ 2 ⋭ࠛࡀ࡞ࠡ࡯ᕈߩၮḰߣឃᾲ೑↪- 33 -J. HTSJ, Vol. 45, No. 190

․㓸㧦ๆ⌕ߩ਎⇇̆ࡒࠢࡠ߆ࠄࡑࠢࡠ㧘ߘߒߡࠪࠬ࠹ࡓ̆

ዊ

⫳᳇࿶

⫳᳇࿶

ๆḨ㊂ ᄢ

ടḨ䋬
⣕⌕⃻⽎

 ౣ↢᷷ᐲߣ㒰ടḨ⢻ജߩ㑐ଥ㒰ടḨߪๆ⌕ߣ⣕⌕ࠍ੤੕ߦ➅㄰ߒߡⴕࠊࠇࠆ㧚ๆ⌕ᤨߣ⣕⌕ᤨߩᐔⴧๆ⌕㊂㧔ๆ⌕᧚ߣធ⸅ߔࠆⓨ᳇ߩ⋧ኻḨᐲߦኻᔕߔࠆᐔⴧ⁁ᘒߩๆ⌕㊂㧕ߩᏅǍq*max ߣౣ↢᷷ᐲߩ㑐ଥࠍ⊕ᛮ߈⸥ภߢ࿑ 5 ߦ␜ߔ㧚ߎࠇߪ㧘᷷ᐲ߇ 24oC ߢ⋧ኻḨᐲ߇ 60%ߩⓨ᳇㧔⛘ኻḨᐲ߇ 11.2g/kg’㧕߇ๆ⌕ߐࠇ㧘ߎࠇߣหߓ⛘ኻḨᐲࠍ߽ߟⓨ᳇ࠍടᾲߒߡๆ⌕᧚ࠍౣ↢ߒߚ႐วߩ⚿ᨐߢ޽ࠆ㧚ߥ߅㧘࿑ਛߩ㤥Ⴃࠅ⸥ภߦߟ޿ߡߪᓟㅀߔࠆ㧚㒰ടḨ⢻ജߪⓨ᳇᧦ઙߦ߽ଐሽߔࠆ߇㧘⚦ሹᓘ߇೙ᓮߐࠇߚๆ⌕᧚ߣࠪ࡝ࠞࠥ࡞ߪ㧘ౣ↢᷷ᐲ߇ૐߊߡ߽⢻ജ߇޽ࠅ㧘೨⠪ߪ 60oC ⒟ᐲએਅ㧘ᓟ⠪ߪ 80oC ⒟ᐲએਅߦㆡߒߡ޿ࠆ=8?㧚ߎߩࠃ߁ߦౣ
↢᷷ᐲߣ㒰ടḨߐࠇࠆⓨ᳇᧦ઙߦᔕߓߡㆡಾߥ․ᕈࠍ␜ߔๆ⌕᧚ࠍㆬᛯߔࠆߎߣ㧘߹ߚߪߘߩࠃ߁
ߥ․ᕈࠍ߽ߟ᧚ᢱࠍ㐿⊒ߔࠆߎߣ߇㊀ⷐߢ޽ࠆ㧚ᐔⴧๆ⌕㊂ q *[kg-᳓/kg-ੇ῎⁁ᘒ䈱ๆ⌕᧚] ⫳᳇ߩๆ⣕⌕⃻⽎ߣๆ⌕᧚ ⫳᳇ߩ⒖േේℂ᳇⋧ߣๆ⌕᧚ߣߩ㑆ߩ᳓ಽሶ㧔⫳᳇㧕ߩ⒖േߪ㧘᳇⋧ਛߩḨಽߩಽ࿶ߣๆ⌕᧚⴫㕙ߩ⫳᳇࿶ߦଐሽ
ߒ㧘ߘߩ⫳᳇࿶ߪ᷷ᐲߣๆ⌕㊂ߦଐሽߔࠆ㧚ๆ⌕᧚⴫㕙ߩౖဳ⊛ߥ⫳᳇࿶ᦛ✢ࠍ࿑ 3 (a)ߦ␜ߔ㧚⫳᳇࿶ߪ㧘᷷ᐲߣๆ⌕㊂ߩჇടߣߣ߽ߦჇടߔࠆ㧚࿑ 3 (b)ߦߪ㧘⫳᳇߇ๆ⌕᧚⴫㕙ߦធ⸅ߒߚߣ߈ߩ
ߘࠇߙࠇߩ⫳᳇࿶ࠍ␜ߔ㧚⫳᳇ߪ㧘ๆ⌕᧚⴫㕙ߣⓨ᳇ਛߩ⫳᳇࿶ߩᏅߢ⒖േߔࠆ㧚ߒߚ߇ߞߡ㧘ๆ⌕᧚᷷ᐲ߇ TA ࠃࠅ߽ዊߐ޿ߣ߈㧔࿑ਛߩ㒰Ḩ㧘ๆ⌕⃻⽎ߩ㗔ၞ㧕㧘⫳᳇ߪ᳇⋧߆ࠄๆ⌕᧚߳⒖േߔࠆ㧚ๆ⌕߇ㅴ߻ߣๆ⌕㊂߇ᄢ߈ߊߥࠆߩߢ㧘หߓ᷷ᐲߢ޽ߞߡ߽㧘⴫㕙ߩ⫳᳇࿶ߪᓢ‫ߦޘ‬ᄢ߈ߊߥࠅ㧘߿߇ߡ๟࿐ߩ⫳᳇࿶ߦ೔㆐ߔࠆߣ⒖േߪ⚳ੌߔࠆ㧚ㅒߦ᷷ᐲ߇ TA ࠃࠅ߽ᄢ߈޿ߣ߈㧔࿑ਛߩടḨ㧘⣕⌕⃻⽎ߩ㗔ၞ㧕㧘⫳᳇ߪๆ⌕᧚߆ࠄ᳇⋧߳⒖േߔࠆ㧚⣕⌕߇ㅴ߻ߣๆ⌕㊂ߪዊߐߊߥࠆߩߢ⴫㕙ߩ⫳᳇࿶ߪૐਅߒ㧘߿߇ߡ๟࿐ߩ⫳᳇࿶ߦ೔㆐ߔࠆߣ⒖േߪ⚳ੌߔࠆ㧚ๆ⌕⃻⽎ߪ㧘Ᏹߦ⊒ᾲࠍ㧘⣕⌕ߪๆᾲࠍߣ߽ߥ
߁ߩߢ㧘⫳᳇ߩ⒖േଦㅴߦߪ㧘ๆ⌕ᤨߩ㒰ᾲ㧘⣕⌕ᤨߩടᾲ߇㊀ⷐߢ޽ࠆ㧚⚦ሹᓘ䈏೙ᓮ䈘䉏䈢ๆ⌕᧚

0.4

䉲䊥䉦䉭䊦
0.3
䉝䊦䊚䊅䉭䊦
0.2

䉷䉥䊤䉟䊃

0.1

๟࿐䈱⫳᳇࿶

0

A

0

0.2

0.4

0.6

0.8

1

⋧ኻḨᐲ㩷[ - ]

㒰Ḩ䋬ๆ෼
ๆ⌕⃻⽎

࿑ 4 ๆ⌕᧚ߩᐔⴧๆ⌕㊂

TA ᷷ᐲ


(a)ๆ⌕᧚ߩ⫳᳇࿶ (b)ๆ⌕᧚ߣ๟࿐ߩ⫳᳇࿶
࿑ 3 ᷷ᐲ㧙⫳᳇࿶㧙ๆḨ㊂ߩ㑐ଥߣ⒖േේℂ ๆ⌕᧚ๆ⌕᧚ߪࠪ࡝ࠞࠥ࡞㧘ࠕ࡞ࡒ࠽ࠥ࡞߅ࠃ߮࠯ࠝ
࡜ࠗ࠻ߥߤ߇ઍ⴫⊛ߢ޽ࠆ㧚ߎࠇࠄߩๆ⌕ᐔⴧᦛ✢ࠍ࿑ 4 ߦ␜ߔ㧚ࠪ࡝ࠞࠥ࡞ߣࠕ࡞ࡒ࠽ࠥ࡞ߪ࠯
ࠝ࡜ࠗ࠻ࠃࠅ߽Ყセ⊛㜞޿⋧ኻḨᐲߢᄢ߈޿ᐔⴧ
ๆ⌕㊂ࠍ␜ߔ㧚߹ߚ㧘࿑ਛߩ⚦ሹᓘ߇೙ᓮߐࠇߚ
ๆ⌕᧚ߣ⸥ߒߚᦛ✢ߪ㧘ࡔ࠰ࡐ࡯࡜ࠬࠪ࡝ࠞ[4]߇
␜ߔ․ᕈࠍᮨᡆߒߚ߽ߩߢ޽ࠆ㧚ߥ߅㧘ߎࠇࠄߩ߶߆ߦ߽㜞ಽሶ♽[5]߿ᯏ⢻ᕈ᧚ᢱ[6,7]߇޽ࠆ㧚

વᾲ 2006 ᐕ 1 ᦬

0.5

Amount of adsorbed water㰱M [kg/h]2

Pore size controlled material
Silica gel
Zeolite

0.45
0.4
0.35

1.5

0.3
0.25

1

0.2
0.15

0.5

0.1
L =0.02m-4

0.05

Difference of the equilibrium
adsorbed water between adsorption
and regeneration process㰱㫈 㪁㫄㪸㫏㩷[(kg/kg-ads)/rev]᷷ᐲk b =1x10 m/s

0
20

40

60

80

100

0
120

o

Regeneration temperature T de [ C]

࿑ 5 㒰ടḨ⢻ജߦ෸߷ߔౣ↢᷷ᐲߩᓇ㗀- 34 -J. HTSJ, Vol. 45, No. 190

․㓸㧦ๆ⌕ߩ਎⇇̆ࡒࠢࡠ߆ࠄࡑࠢࡠ㧘ߘߒߡࠪࠬ࠹ࡓ̆

વᾲ 2006 ᐕ 1 ᦬- 35 -

z
ⓨ᳇ᵹ〝
䊂䉲䉦䊮䊃
䉲䊷䊃
z
䊨䊷䉺ᢿ㕙

ⓨ᳇ᵹ䉏

ᐔ᧼䊝䊂䊦

䊂䉲䉦䊮䊃䊨䊷䉺

࿑ 6 ⸃ᨆኻ⽎ߩࡠ࡯࠲ߣࡕ࠺࡞ߩࠗࡔ࡯ࠫ
⴫ 1 ࠪࡒࡘ࡟࡯࡚ࠪࡦߩၮ␆ᑼ[14]Mass balance
wx
wx ab
wq
 U aua

Ub
wt
wz aa
wt

Ua

(1)

0

Adsorption rate
wq
wt

(2)

kb
q * qab

Heat balance in the air sideU a c pa

wTa
wTq
 U aua c pa a  s
wt
wz
aa

(3)

0

Heat balance in the bed
Ubc pb

wTb
wt

Us

(4)

wq
q
qh  swt
abHeat transfer between the air and the bed
qs(5)

D s Ta  Tb

Equilibrium adsorptionq*(6)

f x, Tba: ෘߐ[m]㧘cp: Ყᾲ[J/(kg㨯K)]㧘kb: ╬ଔ‛⾰વ㆐ଥᢙ[m/s]㧘L: ࡠ࡯࠲㐳ߐ[m]㧘q: ๆ⌕㊂[kg- ᳓ /kg- ๆ⌕᧚ ] 㧘 q*: ᐔⴧๆ⌕㊂ [kg- ᳓ /kgๆ⌕᧚]㧘qh: ๆ⌕⊒ᾲ㊂[J/kg]㧘T: ᷷ᐲ[oC]㧘
t: ᤨ㑆[s]㧘x: ⛘ኻḨᐲ[kg/kg’]㧘z: ࡠ࡯࠲㐳ߐᣇะߩ૏⟎ [m] 㧘 u: 㘑ㅦ [m/s] 㧘 Įs: ᾲવ㆐₸[W/(m2㨯K)]㧘ȡ: ኒᐲ[kg/m3]ߢ޽ࠆ㧚ᷝሼ a: ⓨ᳇㧘b: ๆ⌕᧚ࠍ⴫ߔ㧚

100
Pore size controled material
Silica gel
Zeolite90
Dehumidification efficiency [%]ๆ⌕㒰ടḨߩⷐ⚛ᯏེߣࠪࠬ࠹ࡓߩᛛⴚ⎇ⓥ ⎇ⓥౝኈߩಽ㘃ๆ⌕㒰ടḨߦ㑐ߔࠆ⎇ⓥࠍᄢ߹߆ߦಽ㘃ߔࠆߣ(1) 㒰ടḨࡠ࡯࠲ߩᕈ⢻੍᷹ߩߚ߼ߩࡕ࠺࡝ࡦࠣ㧘⸘▚߅ࠃ߮ᦨㆡൻߩᬌ⸛㧘(2) ᾲ੤឵ㆊ⒟߿ᾲ࡮
‛⾰⒖േߦ㑐ߔࠆⷐ⚛⎇ⓥ㧘(3) ๆ⌕㒰Ḩߣᓥ᧪ߩ಄ᚱᯏࠍ⚵ߺวࠊߖߚࡂࠗࡉ࡝࠶࠼ࠪࠬ࠹ࡓߩ
ᕈ⢻⹏ଔ[9]㧘(4) ࿾ၞߩ᳇୥᧦ઙࠍ⠨ᘦߒߚࠪࠬ
࠹ࡓߩ⋭ࠛࡀ࡞ࠡ࡯ࡐ࠹ࡦࠪࡖ࡞⹏ଔ[10]㧘(5) ๆ⌕㒰Ḩࠪࠬ࠹ࡓߩዉ౉ߣᕈ⢻⹏ଔ[11]ߦಽ㘃ߢ߈ࠆ㧚એਅߢߪⷐ⚛ߦㄭ޿(1)㧘(2)߅ࠃ߮(3)ߦ㑐ㅪߔࠆ⎇ⓥߦߟ޿ߡ◲නߦ⚫੺ߔࠆ㧚 ๆ⌕ࡠ࡯࠲ߩ․ᕈ⸃ᨆ
 ℂ⺰⸃ᨆๆ⌕᧚ߪ߶ߣࠎߤߩታ↪ᯏེߢࡠ࡯࠲ߦടᎿߐ
ࠇߡ߅ࠅ㧘ࡠ࡯࠲ౝዪᚲߦ߅ߌࠆๆ⌕᧚ߣ⫳᳇ߩๆ⣕⌕⃻⽎߇㒰ടḨᕈ⢻ߦᄢ߈ߊᓇ㗀ߔࠆ㧚ߒߚ߇ߞߡ㧘ᾲߣ‛⾰ߩ⒖േଦㅴߩᜰ㊎ᬌ⸛߇㊀ⷐߢ޽ࠅ㧘ታ㛎߿⸘▚ߦࠃߞߡࡠ࡯࠲ߩᕈ⢻ߦ෸߷ߔࡠ࡯࠲ߩᲧᾲ㧘㐳ߐ㧘ๆ⌕ᾲ㧘࿁ォㅦᐲ㧘ᐔⴧๆ⌕․ᕈ㧘ౣ↢᷷ᐲ㧘ๆ⣕⌕㕙ⓍᲧ₸߅ࠃ߮⣕⌕ⓨ᳇ᵹ㊂ߩᓇ㗀ߥߤ߇᣿ࠄ߆ߦߐࠇߡ޿ࠆ[12-14]㧚
଀߃߫࿑ 6 ߦ␜ߔࠃ߁ߥࡠ࡯࠲ࠍ⸃ᨆኻ⽎ߣߒ㧘ๆ⌕᧚ߣࡃ࡞ࠢⓨ᳇㑆ߩᾲ࡮‛⾰⒖േߩᛶ᛫ࠍ⠨ᘦߒߡᕈ⢻ࠍ੍᷹ߒߚ㧚⴫ 1 ߦࠪࡒࡘ࡟࡯࡚ࠪࡦ
ߩၮ␆ᑼ[14]ߩ଀ࠍ␜ߔ㧚࿑ 5 ߦࡠ࡯࠲㐳ߐ߇ 0.02m㧘╬ଔ‛⾰વ㆐ଥᢙ
߇ 1x10-4m/s ߩ႐วߦ߅ߌࠆฦๆ⌕ࡠ࡯࠲ߩ㒰ടḨㅦᐲǍM ࠍ㤥Ⴃࠅ⸥ภߢ␜ߔ㧚㒰ടḨㅦᐲߪන૏ᤨ㑆޽ߚࠅߩ㒰ടḨ㊂ߢ޽ࠅ㧘ࡠ࡯࠲ߩๆ⌕஥಴౉ญߩᐔဋߩ⛘ኻḨᐲᏅߦⓨ᳇ߩ⾰㊂ᵹ㊂ࠍដߌߡ᳞߼ࠄࠇࠆ㧚߹ߚ㧘࿑ 7 ߦߪ㒰Ḩല₸ࠍ␜ߔ㧚ߎࠇߪ㧘ๆ⌕஥ࡠ࡯࠲౉ญⓨ᳇ߩ⋧ኻḨᐲ߇಴ญ߹ߢߦᄌൻߒ߁ࠆ⋧ኻḨᐲߣߩᏅ㧔ๆ⌕஥ߣౣ↢஥ߩ⋧ኻḨᐲᏅ㧕ߦኻߒߡታ㓙ߦ೔㆐ߒߚ⋧ኻḨᐲߣߩᏅ㧔ๆ⌕஥ߩ಴౉ญߩ⋧ኻḨᐲᏅ㧕ߩᲧߢ᳞߼ࠄࠇࠆ㧚
ࠪ࡝ࠞࠥ࡞߿⚦ሹᓘࠍ೙ᓮߒߚๆ⌕᧚ߪ㧘ౣ↢᷷ᐲ߇ૐߊߡ߽㒰ടḨㅦᐲߪᄢ߈޿㧚ല₸߇ᦨᄢߣߥࠆౣ↢᷷ᐲߪ 55oC ⒟ᐲߢ޽ࠅ㧘ߎߩ᷷ᐲၞߢ
ౣ↢↪ߩᾲࠛࡀ࡞ࠡ࡯ߪല₸ࠃߊᄌ឵ߐࠇࠆ[8]㧚
ߐࠄߦ㧘㒰ടḨㅦᐲߦ෸߷ߔ⒖േଥᢙߩᓇ㗀ࠍᬌ⸛ߒߚ⚿ᨐ㧘ๆ⌕᧚ߩ⴫㕙᜛ᢔଥᢙߩ୯ࠍ⃻⁁ߩ 10 ୚ߦᄢ߈ߊߔࠆߣ⒖േㅦᐲߪ⚂ 35%Ⴧᄢߒ㧘

80
70
60
50
40
30
20
10
0
20

40

60

80

100

120

o

Regeneration temperature T de [ C]

࿑ 7 㒰Ḩല₸ߦ෸߷ߔౣ↢᷷ᐲߩᓇ㗀

J. HTSJ, Vol. 45, No. 190

․㓸㧦ๆ⌕ߩ਎⇇̆ࡒࠢࡠ߆ࠄࡑࠢࡠ㧘ߘߒߡࠪࠬ࠹ࡓ̆

1

1

Sh

0.664 Re 2 Sc 3

Nu

0.664 Re 2 Pr 3 

11ᱜߒߚࠪࡖ࡯࠙࠶࠼ᢙߩታ㛎୯ߪ 20 ୚⒟ᐲߦ⵬
ᱜߔࠆߎߣߢ◲ᤃ⊛ߦଥᢙࠍផቯߢ߈ࠆ߇㧘੹ᓟ㧘߽ߞߣ⹦⚦ߥᬌ⸛ࠍⴕ߁ᔅⷐ߇޽ࠆ㧚㕙㘑ㅦ[m/s] 0.5
q
kb

1.0

1.E-04

ๆ⌕㊂q [kg/kg]

0.014
0.012
0.01
0.008

1.E-05

0.006
0.004
0.002
0
0

20

40

60

80

100

1.E-06120

ๆ⌕㐿ᆎᓟ䈱ᤨ㑆 [s]࿑ 8 㕙㘑ㅦ߇ㅦᐲߣ⒖േଥᢙߦ෸߷ߔᓇ㗀 ๆ⌕಄ಓᯏߣ⚵วߖߚẜᾲ࡮㗼ᾲ⁛┙೙ᓮࡂࠗࡉ࡝࠶࠼࠺ࠪࠞࡦ࠻ࠪࠬ࠹ࡓ
ࡂࠗࡉ࡝࠶࠼ࠪࠬ࠹ࡓߣߒߡߪᣢߦ⫳᳇࿶❗಄ಓᯏߣ⚵วߖߚࠪࠬ࠹ࡓ㧔ๆ⌕㒰Ḩᯏߦࠃࠆẜᾲ೙ᓮߣ⫳᳇࿶❗಄ಓࠨࠗࠢ࡞ߦࠃࠆ㗼ᾲ೙ᓮࠍ⚵วߖߚ಄ᚱࠪࠬ࠹ࡓ㧕ߩᕈ⢻⸃ᨆࠪࡒࡘ࡟࡯࡚ࠪ
ࡦ߇ⴕࠊࠇߡ߅ࠅ㧘ẜᾲ࡮㗼ᾲߩ⁛┙೙ᓮࠍⴕࠊ
ߥ޿ࠪࠬ࠹ࡓߣᲧߴࠆߣ 24%ߩࠛࡀ࡞ࠡ࡯ᶖ⾌㊂ߩ೥ᷫലᨐ߇⷗ㄟ߹ࠇߚ[19]㧚߹ߚ㧘ᄥ㓁ᾲߣ⵬ഥᾲḮߢ㚟േߔࠆๆ෼಄ಓᯏߣ⚵วߖߚࠪࠬ࠹ࡓ
ߦߟ޿ߡ߽ᬌ⸛ߐࠇߡ޿ࠆ㧚ᄥ㓁ᾲᧂ೑↪ࠪࠬ࠹ࡓߣᲧߴߡ㧘ẜᾲ࡮㗼ᾲ⁛┙೙ᓮߦࠃࠆࠛࡀ࡞ࠡ
࡯ᶖ⾌㊂ߩ೥ᷫലᨐߪ㧘8 ᦬ߩ᳇୥᧦ઙߢߪ 10%⒟ᐲ㧘9 ᦬ߢߪ 35%⒟ᐲߢ޽ߞߚ[20]㧚
ߎߎߢߪ 60oC ߩૐ᷷ឃᾲߩ᦭ല೑↪ࠍ⋡⊛ߣߒߚࠪࠬ࠹ࡓߩታ㛎ߦߟ޿ߡ⚫੺ߔࠆ㧚࿑ 9 ߦࠪࠬ࠹ࡓߩ᭎ⷐ࿑ࠍ␜ߔ㧚․ᓽߪ 60oC ⒟ᐲߩ᷷᳓ࠍ
ᾲḮߣߔࠆੑᲑဳๆ⌕಄ಓᯏ㧔࿑ 10 (a)㧕ߦࠃࠅ㗼ᾲಣℂࠍ㧘หߓᾲḮߢౣ↢ߔࠆ㒰ടḨࡠ࡯࠲㧔࿑10 (b)㧕ߦࠃࠅẜᾲಣℂࠍⴕ߁㧚ㆇォታ㛎ߪ㧘᷷᳓᷷ᐲ߇ 55oC㧘ಣℂⓨ᳇᷷ᐲ߇26.5oC㧘Ḩᐲ߇ 10.5g/kg´ߩ᧦ઙߢⴕࠊࠇߚ㧚࿑ 11ߦฦⷐ⚛ᯏེߩ಴౉ญߦ߅ߌࠆⓨ᳇ߩ᷷Ḩᐲࠍ㤥ਣශߢⓨ᳇✢࿑਄ߦ␜ߔ㧚࿑ਛ A ߪಣℂⓨ᳇㧘Bߪଏ⛎ⓨ᳇ߩ⁁ᘒࠍ␜ߔ㧚ὐ A ߩ⁁ᘒߦ޽ࠆⓨ᳇ߪ㧘㒰ടḨࡠ࡯࠲ߢ㒰Ḩߐࠇ㧘ᾲ੤឵ᓟߐࠄߦ಄
ළེߢὐ B ߩଏ⛎ⓨ᳇ߩ⁁ᘒ߹ߢ಄ළߐࠇߚ㧚ߘ

(7)
(8)

ߎߎߦ Sh(=(kbL/Da)㨯(Da /Ds))ߪୃᱜߒߚࠪࡖ࡯࠙
࠶࠼ᢙ㧘Nu(=(ĮsL/Ȝa))ߪ࠿࠮࡞࠻ᢙ㧘Re(=uaL/Ȟa)ߪ
࡟ࠗࡁ࡞࠭ᢙ㧘Sc(=(Ȟa/Da)㨯(Da /Ds))ߪୃᱜߒߚࠪ
ࡘࡒ࠶࠻ᢙ㧘Pr(=Ȟaȡacpa/Ȝa)ߪࡊ࡜ࡦ࠻࡞ᢙࠍ⴫ߒ㧘ua ߪⓨ᳇ᵹㅦ㧘L ߪᵹࠇᣇะߩᵹ〝㐳ߐ㧔ߎߎߢ
ߪ 0.04m㧕㧘Ȟa ߪⓨ᳇ߩേ☼ᕈଥᢙߢ޽ࠆ㧚Ds ߪ⴫㕙᜛ᢔଥᢙߢ޽ࠅ㧘ๆ⌕᧚ߩ᷷ᐲ߇ 30oC ߢ⚂
1.5x10-11m2/s㧘80oC ߢ⚂ 1.5x10-10m2/s ߢ޽ࠆ㧚࠿࠮࡞࠻ᢙߩታ㛎୯ߪℂ⺰୯ߩ 2 ୚⒟ᐲߦ㧘ୃવᾲ 2006 ᐕ 1 ᦬

0.75╬ଔ‛⾰વ㆐ଥᢙ k b [m/s]ㅒߦ 1/10 ୚ߦߔࠆߣ 1/5 ⒟ᐲߦૐਅߔࠆ[15]㧚ߎߩࠃ߁ߦ⒖േଥᢙߩะ਄߇㜞ᕈ⢻ൻߦߪ㊀ⷐߢ޽ࠅ㧘ଥᢙߩផቯ߇ᕈ⢻੍᷹ߦᔅⷐߢ޽ࠆ㧚ߥ߅㧘ߎߎߢߪ⚫੺ߒߥ޿߇㧘ࠪࡒࡘ࡟࡯࡚ࠪ
ࡦߦࠃࠅࡠ࡯࠲ౝዪᚲߩ᷷Ḩᐲ㧘ๆ⌕㊂ߩಽᏓ߅ࠃ߮ࡠ࡯࠲࿁ォᣇะߩߘࠇࠄߩಽᏓ߽ኈᤃߦ੍᷹
ߐࠇߡ߅ࠅ㧘ߎࠇࠄߩ࠺࡯࠲ࠍ↪޿ߡ⒖േଦㅴߩ
ߚ߼ߩᜰ㊎߇ᬌ⸛ߐࠇߡ޿ࠆ[15]㧚 ᾲ࡮‛⾰ߩ⒖േଦㅴߣ⒖േଥᢙ
⒖േଦㅴߦ㑐ߔࠆ⎇ⓥߣߒߡߪ㧘ๆ⌕ᤨߩ⊒ᾲ㒰෰ߣ⣕⌕ᤨߩᾲଏ⛎߇ㅦ߿߆ߦⴕࠊࠇࠆࠃ߁ߦ
⸳⸘ߐࠇߚๆ⌕Ⓧጀ૕߿หᤨᾲ੤឵㒰Ḩᯏߩ㐿⊒߅ࠃ߮ߘࠇࠄߩᕈ⢻⹏ଔ߇ⴕࠊࠇߡ޿ࠆ[16, 17]㧚⒖േଥᢙߦ㑐ߒߡߪ㧘ࡠ࡯࠲ⷐ⚛߳ߩၮ␆⊛ߥๆ⌕ታ㛎㧘ߔߥࠊߜๆ⌕ᐔⴧ⁁ᘒ㧔ౣ↢ᓟߦ⋧ᒰ㧕ߦ޽ࠆⷐ⚛ߦᚲቯߩ᷷Ḩᐲߩⓨ᳇ࠍࠬ࠹࠶ࡊ⁁ߦਈ߃㧘ๆ⌕ߦࠃࠆ⾰㊂ᄌൻߣ᷷Ḩᐲࠍ⸘᷹ߔࠆታ
㛎߇ⴕࠊࠇ㧘ᓧࠄࠇߚ࠺࡯࠲߆ࠄ╬ଔ‛⾰વ㆐ଥ
ᢙ kb ߣᾲવ㆐ଥᢙ Įs ߇▚಴ߐࠇߡ޿ࠆ[18]㧚╬ଔ‛⾰વ㆐ଥᢙߪ㧘ᑼ(2)ߢਈ߃ߚๆ⌕ㅦᐲᑼߩ㚟േജ q*- q ߦ߆߆ࠆଥᢙߢ޽ࠅ㧘ᾲવ㆐ଥᢙߪᑼ(5)ߢਈ߃ࠄࠇࠆ㧚࿑ 8 ߦߪ㕙㘑ㅦࠍᄌ߃ߡᓧߚ㐿ᆎᓟߩๆ⌕㊂ߣ╬ଔ‛⾰વ㆐ଥᢙࠍ␜ߔ㧚㕙㘑ㅦ߇ᄢ߈ߊߥࠆߣ
ๆ⌕ㅦᐲߣଥᢙߪᄢ߈ߊߥࠆ௑ะ߇ᓧࠄࠇߚ㧚࿑␜ߒߡ޿ߥ޿߇⋧ኻḨᐲ߇Ⴧട㧘߹ߚ᷷ᐲ߇ૐਅ
ߔࠆߣଥᢙߪჇടߔࠆ௑ะ߇ᓧࠄࠇ㧘ᾲવ㆐ଥᢙ
߽㕙㘑ㅦߦଐሽߒߡ޿ࠆ㧚ߎࠇࠄߩଥᢙࠍήᰴరൻߒߡ㧘ᑼ(7)ߣᑼ(8)ߢ⴫
ߐࠇࠆ৻⥸⊛ߥᐔ᧼ጀᵹߦ߅ߌࠆᢛℂᑼ߆ࠄߩ୯ߣᲧセߒߚ㧚- 36 -J. HTSJ, Vol. 45, No. 190

․㓸㧦ๆ⌕ߩ਎⇇̆ࡒࠢࡠ߆ࠄࡑࠢࡠ㧘ߘߒߡࠪࠬ࠹ࡓ̆

᷷᳓ᵹ〝 55㷄
ๆ⌕
಄ಓᯏ
50㷄

⋧ኻḨᐲ [%] 100 80 60

40 30

20

80

8

6

4

䊊䉟䊑䊥䉾䊄䉲䉴䊁䊛᳓ྃ㔵䉲䉴䊁䊛

[kJ/kg']
䊏䊷 60
䉺䊦
䉣䊮
Ყ
40

ૐ᷷ឃᾲḮ

10

0.02

0.015
A

಄᳓ᵹ〝
12㷄
24㷄

0.025

0.01

20
2.3

B

0.005

0

0

ឃ᳇

ᄖ᳇

-10

0

10

20

30

40

50

60

70

80

90

100

o

ᄖ᳇

᷷ᐲ [ C]ടᾲེ䊂䉲䉦䊮䊃䊨䊷䉺

ଏ⛎ⓨ᳇
㗼ᾲ੤឵ེ

࿑ 11 ๆ⌕ࡂࠗࡉ࡝࠶࠼㒰ടḨࠪࠬ࠹ࡓߩ
ታ㛎⚿ᨐ߅ࠃ߮ࠪࠬ࠹ࡓᲧセ಄ළེ

࿑ 9 ๆ⌕ࡂࠗࡉ࡝࠶࠼㒰ടḨࠪࠬ࠹ࡓߩ᭎⇛߹ߚ㧘ᓥ᧪ߩ᳓ྃ㔵ᑼ࠺ࠪࠞࡦ࠻ࠪࠬ࠹ࡓߣߩ
ᕈ⢻ࠍᲧセߒߚ㧚᳓ྃ㔵ᑼߩࠪࠬ࠹ࡓߢᓧࠄࠇࠆ
ಣℂⓨ᳇ߩ᷷Ḩᐲ߇ B ὐߣߥࠆࠃ߁ߦㆇォߒߚ႐ว㧘ฦὐߩ⁁ᘒߪ⊕ਣශߢ␜ߔࠃ߁ߦߥࠆ㧚᳓ྃ㔵ᑼߢߪᧄࠪࠬ࠹ࡓߦᲧߴߡ㒰ടḨࡠ࡯࠲ߢૐḨᐲߩⓨ᳇ࠍ૞ࠆᔅⷐ߇޽ࠅ㧘ߘߩߚ߼ߦ 97oC㧔᷷ᐲᏅ 5K㧕ߩౣ↢ᾲḮ߇ᔅⷐߣߥࠆ㧚ߒߚ߇ߞߡ㧘ᧄࠪࠬ࠹ࡓߪ 40 K ߽ૐ޿ᾲḮߢ㚟േน⢻ߢ޽ࠆ㧚ߐࠄߦ㧘ๆ⌕಄ಓᯏߛߌߢẜᾲ࡮㗼ᾲಣℂࠍⴕ߁ㆊ಄ළᑼࠪࠬ࠹ࡓߣᲧセߒߚ㧚ㆊ಄ළᑼߢߪⓨ᳇ࠍ 8oC ઃㄭ߹ߢ಄ළߔࠆᔅⷐ߇޽ࠅ㧘ߘߩ႐ว㧘ๆ⌕಄ಓᯏߩ಄ᇦ⫳⊒᷷ᐲߪૐ޿᧦ઙߢㆇォߐࠇࠆ㧚ߒߚ߇ߞߡ㧘ᧄࠪࠬ࠹ࡓࠃࠅ߽಄ಓᯏߩᚑ❣
ଥᢙ COP ߪૐߊߥࠆ㧚ᧄࠪࠬ࠹ࡓߢᔅⷐߣߔࠆ࠺
ࠪࠞࡦ࠻ౣ↢ᾲ㊂ࠍ⠨ᘦߒߡ߽ㆊ಄ළᑼߩ COP
ߪ 23%߽ૐ޿ߚ߼㧘ᧄࠪࠬ࠹ࡓߩ⋭ࠛࡀ࡞ࠡ࡯ᕈ
⢻ߪ 30%㜞޿ߎߣ߇᣿ࠄ߆ߦߥߞߚ㧚ߎߩࠃ߁ߦ㗼ᾲߣẜᾲߩ⁛┙ಣℂ߇ⴕࠊࠇࠆᧄ
ࠪࠬ࠹ࡓߪ㧘ᓥ᧪ߩๆ⌕㒰Ḩࠪࠬ࠹ࡓߦᲧߴߡૐ
᷷ౣ↢߇น⢻ߢଏ⛎ⓨ᳇ߩ᷷Ḩᐲ߽⥄↱ߦ⸳ቯߢ߈㧘߆ߟㆊ಄ළᑼࠃࠅ߽⋭ࠛࡀ࡞ࠡ࡯ߢ޽ࠆߩߢ㧘ᰴ਎ઍߩⓨ⺞ᛛⴚߣߒߡ᦭ലᕈ߇㜞޿㧚(a)߻ߔ߮
ๆ⌕᧚ߩๆ⌕․ᕈߩⷞὐ߆ࠄߪ㧘㒰ടḨߐࠇࠆⓨ᳇ߩ᷷Ḩᐲ᧦ઙߦኻߒߡᦨㆡߥᐔⴧๆ⌕ᦛ✢ࠍឬߊๆ⌕᧚ࠍ㧘⚦ሹᓘߥߤࠍ೙ᓮߔࠆߎߣߦࠃߞ
ߡ㧘㐿⊒ߔࠆߎߣ߇㊀ⷐߢ޽ࠆ㧚ⷐ⚛ߩ᭴ᚑ߿ㆇォߩⷞὐ߆ࠄߪ㧘ࡠ࡯࠲ߣⓨ᳇ߣߩ㑆ߩᾲߣ‛⾰ߩ⒖േㅦᐲࠍᦨᄢ㒢ᒁ߈಴ߔߚ(b)࿑ 10 ੑᲑဳๆ⌕಄ಓᯏ(a)ߣๆ⌕㒰ടḨࠪࠬ࠹ࡓ(b)ߩ౮⌀વᾲ 2006 ᐕ 1 ᦬

- 37 -J. HTSJ, Vol. 45, No. 190⛘ኻḨᐲ [kg/kg']ߩ⚿ᨐ㧘ࡠ࡯࠲ߪ 50oC ⒟ᐲߩⓨ᳇ߦࠃࠅടᾲౣ↢ߐࠇ㧘਄⸥᧦ઙߢㆇォน⢻ߢ޽ࠆߎߣ߇ታ⸽ߐࠇ
ߚ㧚․㓸㧦ๆ⌕ߩ਎⇇̆ࡒࠢࡠ߆ࠄࡑࠢࡠ㧘ߘߒߡࠪࠬ࠹ࡓ̆

[7] ၂ౝඳⴕ, ਅጟ㉿⟤, ጤ಴⟤♿, ᄢፉ৻ౖ, ጊፒᱜౖ, ኹ↰⑲, ᷰㄝዷ, ᱞ⣁㓉ᒾ, ൻቇᎿቇ⺰ᢥ㓸, 31-5 (2005) 361.
[8] ựᧄ⧐ᓼ, ᫪⧷ᄦ, ਛፉᵗ৻, ᧻ጟᢥ㓶, ᣣᧄ಄ ಓ ⓨ ⺞ ቇ ળ ᐕ ᰴ ᄢ ળ ⻠ Ṷ ⺰ ᢥ 㓸 , C114
(2005).

߼ߩㆇォ᧦ઙࠍࠪࡒࡘ࡟࡯࡚ࠪࡦߦࠃߞߡ੍᷹ಽ
ᨆߒ㧘ૐ᷷ឃᾲߢല₸ࠃߊ㚟േߔࠆ᷷Ḩᐲߩ⁛┙೙ᓮࠪࠬ࠹ࡓࠍ㐿⊒ߒ㧘ታ↪ㆇォߔࠆߎߣ߇⺖㗴ߢ޽ࠆ㧚ߪߓ߼ߦㅀߴߚࠃ߁ߦએ਄ߩࠃ߁ߥ⋭ࠛࡀ࡞ࠡ࡯ဳߩẜᾲ࡮㗼ᾲߩ⁛┙೙ᓮᛛⴚߩዉ౉ߦࠃߞߡ
ૐ᷷ᐲߩឃᾲࠛࡀ࡞ࠡ࡯ࠍ߁߹ߊᵴ߆ߔߎߣ߇ᦸ
߹ࠇࠆ㧚଀߃߫↥ᬺಽ㊁ߩឃᾲ㊂[21]ࠍෳ⠨ߦߔࠆߣ㧘ᐕ㑆ߩ✚᷷᳓ឃᾲ㊂ 94.2PJ/year ߩ߁ߜ㧘᷷
ᐲ߇ 40-60oC ߩ᷷᳓ឃᾲ㊂ߪ 46.1PJ/year㧘60-80oC
ߢߪ⚂ 15.1PJ/year㧘80-99oC ߢߪ⚂ 12.6PJ/year ߢ޽ࠅ㧘ߘࠇߙࠇో૕ߩ⚂ඨಽ㧘16%߅ࠃ߮ 13%ࠍභ߼ࠆ㧚ߒߚ߇ߞߡ㧘ᧄࠪࠬ࠹ࡓߩࠃ߁ߥᾲ㚟േဳߦࠃࠅ✚᷷᳓ឃᾲ㊂ߩ߁ߜ⚂ 3 ഀ㧔᷷ᐲ▸࿐߇
60㨪99oC ߩឃᾲ㧕⒟ᐲߪᵴ↪ߔࠆߎߣ߇ߢ߈ࠆ㧚ᦨᓟߦ਄ㅀߩឃᾲ㊂ߪ㧘ᣣᧄߩ↥ᬺㇱ㐷ో૕ߩᐕ㑆ࠛࡀ࡞ࠡ࡯ᶖ⾌㊂ 7534PJ/year[22]ߩ߁ߜߩ⚂0.4%ߢ޽ࠅ㧘␠ળో૕ߦኻߔࠆࠗࡦࡄࠢ࠻߇ᄢ߈
޿ߣߪ⸒߃ߥ޿㧚ߘߎߢ㧘ᧄࠪࠬ࠹ࡓߩࠃ߁ߥૐ
᷷ឃᾲ㚟േࠪࠬ࠹ࡓߪ㧘㔚᳇ߩ૶↪߇࿎㔍ߥ࿾ၞ߿↪ㅜవ߳ߩዉ౉ࠍ〯߹߃ߡ㐿⊒ߔࠆߎߣ߽㊀ⷐߣᕁࠊࠇࠆ㧚

[9] ଀ ߃ ߫ Dhar, P. L. and Singh, S. K., App.
Thermal Eng., 21 (2001) 119.
[10] ଀߃߫ Joudi, K. A. and Dhaidan, N. S., Energy
Conversion and Management, 42 (2001) 995.
[11] ଀߃߫ Mazzei, P., Minichiello, F. and Palma, D.,
App. Thermal. Eng., 22 (2002) 545.
[12] Kodama, A., Hirayama, T., Goto, M., Hirose, T.
and Critoph, R. E., App. Thermal Eng., 21 (2001)
1657.
[13] Dai, Y.J., Wang, R.Z. and Zhang. H.F., Int. J.
Thermal Sci., 40, (2001) 400.
[14] ựᧄ⧐ᓼ, ጟፉᰴ㇢, ᧻ጟᢥ㓶, ⑺Ỉᷕ, ᨰᧁቁᄦ , ᣣᧄ಄ಓⓨ⺞ቇળ⺰ᢥ㓸 , 19-3 (2002)
281.
[15] ựᧄ⧐ᓼ, ᧛ἑჽ੺, ᧻ጟᢥ㓶, ጟፉᰴ㇢, ⑺Ỉᷕ , ᨰᧁቁᄦ , ᣣᧄ಄ಓⓨ⺞ቇળ⺰ᢥ㓸 ,21-1 (2004) 63.
[16] ఽ₹ᤘ㓶, ᩙደࠆߺ, ᓟ⮮రା, ᐢἑീ, ጟ㊁
ᶈᔒ, ൻቇᎿቇળ╙ 66 ᐕળ⎇ⓥ⊒⴫⻠Ṷⷐᣦ㓸, C314 (2001).
[17] ఽ₹ᤘ㓶, ⑺Ỉᷕ, ựᧄ⧐ᓼ, ᐔᚑ 16 ᐕᐲ⎇ⓥഥᚑ੐ᬺᚑᨐႎ๔ળ੍Ⓜ㓸 ↥ᬺᛛⴚ⎇ⓥഥᚑ੐ᬺ ╙ 2 ಽౠ (2005) 208.
[18] ⍹Ꮉᗉ৻㇢, ựᧄ⧐ᓼ, ⑺Ỉᷕ, ᨰᧁቁᄦ, ᣣᧄ಄ಓⓨ⺞ቇળᐕᰴᄢળ⻠Ṷ⺰ᢥ㓸 , B202
(2004).

ෳ⠨ᢥ₂
[1] Saha, B. B., Alam, K. C. A., ựᧄ⧐ᓼ, ⑺Ỉᷕ,ᨰ ᧁ ቁ ᄦ , ᣣ ᧄ ಄ ಓ ⓨ ⺞ ቇ ળ ⺰ ᢥ 㓸 , 18-1
(2001) 1.

[2] ఽ₹ᤘ㓶, ᐢἑീ, ಄ಓ, 77 (2002) 226-234.
[3] Kashiwagi, T., Akisawa, A., Yoshida, S.,
Hamamoto, Y. and Alam, K. C. A., Proc. of Int.
Sorption Heat Pump Conf., (2002) 50.
[4] ㆙⮮᣿, ች↰┥ᒾ, ጊᧄᜏม, ᄢ᫪㓉ᄦ, ⑺⼱
㣔ੑ , ਛጤൎ , ᣣᧄ಄ಓⓨ⺞ቇળቇⴚ⻠Ṷળ⻠Ṷ⺰ᢥ㓸, D202 (2002) 577.
[5] Ⓑ⪲⧷↵, ᣣᧄᯏ᪾ቇળ⹹, 104-987 (2001) 86.
[6] ၂ౝඳⴕ, ਅጟ㉿⟤, ጤ಴⟤♿, ᄢፉ৻ౖ, ጊፒᱜౖ, ኹ↰⑲, ᷰㄝዷ, ᱞ⣁㓉ᒾ, ൻቇᎿቇ⺰ᢥ㓸, 31-4 (2005) 273.

[19] ựᧄ⧐ᓼ, ಄ಓ, 78 (2003) 586.
[20] Tran, T. N., ựᧄ⧐ᓼ, ⑺Ỉᷕ, ᨰᧁቁᄦ, ᣣᧄ಄ಓⓨ⺞ቇળ⺰ᢥ㓸, 20-4, (2003) 497.
[21] ⋭ࠛࡀ࡞ࠡ࡯࠮ࡦ࠲࡯ , ⺞ᩏႎ๔ ⋭ࠛࡀ࡞ࠡ ࡯ ᛛ ⴚ ᚢ ⇛ , http://www.eccj.or.jp/strategy/
chr33-a1.html (2003).
[22] ⾗Ḯࠛࡀ࡞ࠡ࡯ᐡ , ⛔⸘ᖱႎ 2003 ᐕᐲࠛࡀ࡞ࠡ࡯㔛⛎ታ❣ , http://www.enecho.meti.go.jp/
info/statistics/2003ygaiyou.pdf (2005).

વᾲ 2006 ᐕ 1 ᦬- 38 -J. HTSJ, Vol. 45, No. 190

․㓸㧦ๆ⌕ߩ਎⇇̆ࡒࠢࡠ߆ࠄࡑࠢࡠ㧘ߘߒߡࠪࠬ࠹ࡓ̆

ๆ⌕ᑼ࠺ࠪࠞࡦ࠻㒰Ḩ࡮ⓨ⺞ࡊࡠ࠮ࠬ
Adsorptive Desiccant Cooling / Dehumidificationఽ₹ ᤘ㓶㧔㊄ᴛᄢቇ㧕Akio KODAMA (Kanazawa University)e-mail: kodama@t.kanazawa-u.ac.jpߪߓ߼ߦ
2005 ᐕ 2 ᦬ 16 ᣣ㧘੩ㇺ⼏ቯᦠ߇⊒ലߒߚ㧚ࠊ߇࿖ߦ⺖ߖࠄࠇߚ᷷ᥦൻലᨐࠟࠬឃ಴㊂ߩ೥ᷫ⋡ᮡࠍ㆐ᚑߔࠆߦߪ੹߿ 13㨪14㧑ߩឃ಴㊂ᛥ೙߇ᔅⷐߣߐࠇߡ޿ࠆ㧚ߘߒߡ㧘ߘࠇߦߪ੩ㇺࡔࠞ࠾࠭ࡓߩㆇ↪ߣਗⴕߒߡ⋭ࠛࡀ࡞ࠡ࡯ലᨐߩ㜞޿ࡊࡠ࠮ࠬߩ㐿⊒ߣ᥉෸߇ਇนᰳߢ޽ࠆ㧚ࠛࡀ࡞ࠡ࡯೑↪ߩല₸ൻࠍ⋡ᜰߒߡฦ⒳ࠦࠫࠚ
ࡀ࡟࡯࡚ࠪࡦࠪࠬ࠹ࡓ߿ࡅ࡯࠻ࡐࡦࡊᑼ⛎ḡེߩ᥉෸߇ㅴࠎߢ޿ࠆ߇㧘ߘߩࠛࡀ࡞ࠡ࡯೑↪ല₸ࠍ㜞ߊ⛽ᜬߔࠆߚ߼ߦߪ૛೾᷷ᾲࠍⓍᭂᵴ↪ߔࠆߎߣ߇ᔅⷐߢ޽ࠆ㧚․ߦ૛೾᷷ᾲ㊂߇Ⴧടߔࠆᄐቄ
ߦߪ㧘಄ᚱⵝ⟎ߩ㚟േᾲḮߣߒߡᵴ↪ߔࠆߎߣ߇
วℂ⊛ߣ⸒߃ࠆ㧚ᾲ㚟േ಄ᚱⵝ⟎ߩਛߢ߽࠺ࠪࠞ
ࡦ࠻㒰Ḩⓨ⺞ࡊࡠ࠮ࠬߪ឵᳇ဳ߆ߟ㒰Ḩ㊀ⷞߩࠪࠬ࠹ࡓߢ޽ࠅ㧘ቶౝⓨ᳇ຠ⾰ߩᡷༀലᨐ߽ᓧࠆߎ
ߣ߇ߢ߈ࠆߣߒߡᵈ⋡ߐࠇߡ޿ࠆ㧚࠺ࠪࠞࡦ࠻ⓨ⺞ࠪࠬ࠹ࡓߪ࿑㧝ߦ␜ߔࠃ߁ߦၮᧄ⊛ߦ㒰Ḩᯏ㧘ᾲ੤឵ེ㧘಄ළེ㧔ࠝࡊ࡚ࠪࡦ㧕㧘ടᾲེ㧘ㅍ㘑ᯏ߆ࠄ᭴ᚑߐࠇߡ߅ࠅ㧘⁁ᴫߦᔕߓߡ᭽‫⚵ߥޘ‬วߖ㧘޽ࠆ޿ߪᄙ᭽ߥᵹ〝᭴ᚑ߇น⢻ߢ޽ࠆ㧚ߘߩ㒰Ḩᠲ૞ߪๆ⌕೷޽ࠆ޿ߪๆ෼ᶧ߳ߩ᳓⫳᳇ߩๆ⌕㧛ๆ෼૞↪ࠍ೑↪ߒߡ߅ࠅ㧘․ߦẜᾲ⽶⩄ߩᄢ߈ߥⓨ㑆ߢ᦭ലߢ޽ࠆ㧚ᓥ᧪ⓨ⺞ᯏߣߩ⚵ߺวࠊߖ㧔ࡂࠗࡉ࡝࠶࠼ൻ㧕ߢߪ㧘᷷ᐲߣḨᐲߩ⁛┙೙ᓮ߇ኈᤃߦߥࠆߣߣ߽ߦ㧘ᓥ᧪ⓨ⺞ᯏߪ㗼ᾲಣℂߦኾᔨߢ߈ࠆߎߣ߆ࠄ㧘COP ୯ߩะ਄߇ᦼᓙߢ߈ࠆ[2]㧚
ߥ߅㧘࠺ࠪࠞࡦ࠻ⓨ⺞ᯏߪߘߩ㒰Ḩᠲ૞ߦ࿕૕ๆ
Ḩ᧚ࠍ↪޿ࠆๆ⌕ᑼࡊࡠ࠮ࠬߣႮൻ࡝࠴࠙ࡓ╬ߩᶧ૕ๆḨ᧚ࠍ↪޿ࠆๆ෼ᑼࡊࡠ࠮ࠬߦᄢ೎ߢ߈ࠆ
߇㧘⸳஻⾌޽ࠆ޿ߪࡔࡦ࠹࠽ࡦࠬߩὐ߆ࠄߪๆ⌕೷㒰Ḩࡠ࡯࠲࡯ࠍ↪޿ߚๆ⌕ᑼ࠺ࠪࠞࡦ࠻ⓨ⺞ᯏ߇᦭೑ߣߐࠇࠆ㧚᥉෸ߒߟߟ޽ࠆ࠺ࠪࠞࡦ࠻ⓨ⺞ᯏߢߪ޽ࠆ߇㧘㚟േᾲḮߣߥࠅᓧࠆࠦࠫࠚࡀ࡟࡯࡚ࠪࡦࠪࠬ࠹ࡓ
ߩዉ౉ᢙߦ㆙ߊ෸߫ߥ޿㧚ߎࠇߪᠲ૞ේℂ㧛⸳⸘વᾲ 2006 ᐕ 1 ᦬䊊䊆䉦䊛䊨䊷䉺䊷㒰Ḩᯏ ᾲ੤䉮䉟䊦 㗼ᾲ੤឵䊨䊷䉺䊷ᄖ᳇䉁䈢䈲ㆶ᳇ឃ᳇ᔟㆡੇ῎ⓨ᳇

ᄖ᳇䉁䈢䈲ㆶ᳇

䉮䉳䉢䊈ឃᾲ䊶ૐ᷷ឃᾲ䊶ᄥ㓁ᾲ㪉㪌㪄㪊㪇㷄

㪊㪇㪄㪋㪇㷄

㪋㪇㪄㪍㪇㷄

㪎㪇㪄㪐㪇㷄࿑   ࡠ࡯࠲࡯ᑼ࠺ࠪࠞࡦ࠻ⓨ⺞ࡊࡠ࠮ࠬ[1]
ᜰ㊎߇⏕┙ߐࠇߡ޿ߥ޿ߎߣ㧘ⵝ⟎߇ᄢဳߢ޽ࠆ
ߎߣ㧘㜞ࠦࠬ࠻߇ᦨᄢߩℂ↱ߢ޽ࠆ㧚ߎࠇࠄߩ⺖㗴⸃᳿ߦട߃ߡ㧘੹ᓟ᥉෸߇ᦼᓙߐࠇࠆኅᐸ↪Άᢱ㔚ᳰ߿ዊဳࠦࠫࠚࡀ࡟࡯࡚ࠪࡦࠪࠬ࠹ࡓߣ⚵ߺวࠊߖࠍ⠨߃ࠆߣ 50㧙60͠⒟ᐲߩᾲ㚟േߢ߽චಽߥ㒰Ḩᕈ⢻߇⊒ើߢ߈ࠆๆ⌕೷㧘ᵹ〝࡮ࠪࠬ࠹ࡓ᭴ᚑ㧘ㆇォᚻᴺࠍ㐿⊒ߒߡ߅ߊᔅⷐ߇޽ࠆ㧚
ᧄⓂߢߪ㜞Ḩᐲኻᔕߣᦝߥࠆૐ᷷ᾲ㚟േࠍ⋡ᜰߒߚᒰ⎇ⓥቶߢߩขࠅ⚵ߺ㧔࿑ 2㧕ࠍਛᔃߦๆ⌕ᑼ࠺ࠪࠞࡦ࠻ⓨ⺞ࡊࡠ࠮ࠬߩ⎇ⓥ㐿⊒⁁ᴫࠍ⚫੺ߔࠆ㧚⹦ߒߊߪෳ⠨ᢥ₂=?ࠍߏⷩ㗂߈ߚ޿㧚ᮡḰဳࡊࡠ࠮ࠬ㧔㒰Ḩᯏ㧝㧗㗼ᾲ੤឵ེ㧝㧕ᄥ㓁ᾲ㚟േဳ࠺ࠪࠞࡦ࠻ⓨ⺞ᯏߩታ⸽⹜㛎㜞Ḩᐲᄖ᳇߳ߩኻᔕ߅ࠃ߮ᕈ⢻ᡷༀㆇォ᧦ઙߩᦨㆡൻ

ᵹ〝᭴ᚑߩᬌ⸛

࡮㒰Ḩᯏᦨㆡ࿁ォᢙ࡮ᄙᲑ㒰Ḩဳࡊࡠ࠮ࠬ
࡮ౣ↢ⓨ᳇㊂ߩᦨㆡൻ ࡮ోᾲ੤឵ེዉ౉ဳ
࡮㒰Ḩᯏౣ↢ߩ㜞ᐲൻ ࡮㑆ធ᳇ൻ಄ළེߩዉ౉
ࡂࠗࡉ࡝࠶࠼ൻ
Ბ㓏ౣ↢ဳ࡮᷷ᐲಽ
Ꮣઃਈဳ࠺ࠪࠞࡦ࠻ⓨ⺞ᯏߩ㐿⊒

ฦ⒳಄ಓᯏߣߩ⚵วߖๆ⌕ᾲߩㅪ⛯㒰෰࠺ࠪࠞࡦ࠻ⓨ⺞ߦㆡߒߚๆ⌕೷․ᕈߩ᣿⏕ൻ㒰Ḩᕈ⢻࡮಄ᚱᕈ⢻ߦਈ߃ࠆๆ⌕೷․ᕈ㧔ๆ⌕╬᷷✢ᒻ⁁‫ޔ‬ๆ⌕ㅦᐲ‫ޔ‬ᾲኈ㊂㧕ߩᓇ㗀ࠍᱜ⏕ߦផ▚ߢ߈ࠆᚻᴺߩ᭴▽หᤨᾲ੤឵ဳ㒰Ḩࡠ࡯࠲࡯ࠍ↪޿ߚ㧝ࡠ࡯࠲࡯࠺ࠪࠞࡦ࠻ⓨ⺞ᯏߩ㐿⊒࿑ 2 ᒰ⎇ⓥቶߦ߅ߌࠆ࠺ࠪࠞࡦ࠻ⓨ⺞ᯏߩ㐿⊒- 39 -J. HTSJ, Vol. 45, No. 190

․㓸㧦ๆ⌕ߩ਎⇇̆ࡒࠢࡠ߆ࠄࡑࠢࡠ㧘ߘߒߡࠪࠬ࠹ࡓ̆

ᓥ᧪ဳ࠺ࠪࠞࡦ࠻ⓨ⺞ᯏߩ㜞ᐲൻ ⓥᭂᕈ⢻ߣ㒰Ḩᯏߩᕈ⢻ะ਄࿑ 3(a)ߦℂᗐ⊛ߥ㒰Ḩᯏ㧘᷷ᐲല₸ 100㧑ߩ㗼ᾲ੤឵ེ㧘ടḨല₸ 100㧑ߩ಄ළེࠍ↪޿ߚ಄ළེ ઃ ࠺ ࠪ ࠞ ࡦ ࠻ ⓨ ⺞ ᯏ 㧔 Desiccant Evaporative
Cooling㧕ߩⓨ᳇⁁ᘒᄌൻࠍ␜ߔ㧚ߎߩ࠺ࠪࠞࡦ࠻ⓨ⺞ᯏߩⓥᭂᕈ⢻ߪᄖ᳇᷷Ḩᐲ 35͠࡮14.2g/kg㧘ቶౝ᷷Ḩᐲ 26.7͠࡮11.2g/kg ߣ޿߁ ARI ᧦ઙߦ߅޿ߡౣ↢᷷ᐲ 80͠ߩ႐ว㧘಄ළലᨐ㧔⛎᳇ߣㆶ᳇ߩࠛࡦ࠲࡞ࡇ࡯Ꮕ㧕 CE=23kJ/kg 㧘ቶౝⓨ᳇ၮḰ
COP=1.5 ߢ޽ࠆ㧚ᱷᔨߥ߇ࠄ㧘ታ㓙ߩࡊࡠ࠮ࠬౝⓨ᳇⁁ᘒᄌൻߪ࿑ 3(b)ߦ␜ߔࠃ߁ߦℂᗐ᜼േߣߪ
⇣ߥࠅ㧘ℂᗐᕈ⢻ߦᲧߴߡᭂ߼ߡૐ޿ࡊࡠ࠮ࠬᕈ
⢻ࠍ␜ߔ㧚

⒖േᛶ᛫㧘ߦࠃࠅ㒰Ḩᕈ⢻߇ૐਅߔࠆ㧚ߎࠇߦኻߔࠆᡷ⦟╷ߩ৻଀ߣߒߡ㧘ๆ⌕࠱࡯ࡦೋᦼㇱಽ߳ߩࡄ࡯ࠫ࠱࡯ࡦ⸳⟎߇޽ࠆ㧚߹ߚ㧘‫ޟ‬ๆ⌕᧚‫ߩޠ‬ᡷ⦟ߦࠃߞߡ߽ኻᔕน⢻ߢ޽ࠆ㧚ߔߥࠊߜ㧘ๆ⌕ኈ
㊂߇ᄢ߈ߊๆ⌕ㅦᐲ߇ㅦ޿ๆ⌕ࡠ࡯࠲࡯ࠍ↪޿ࠆߎߣߦࠃߞߡ㧘ᦨዊḨᐲࠍ␜ߔ㒰Ḩࡠ࡯࠲࡯ߩ࿁
ォᢙߔߥࠊߜᦨㆡ࿁ォᢙ߇ૐߊߢ߈㧘࿁ォߦࠃߞߡᜬߜㄟ߹ࠇࠆᾲ㊂ࠍૐᷫߔࠆߎߣ߇ߢ߈ࠆ㧚ᒰὼ㧘ๆ⌕᧚ߩᡷ⦟ߪ‛⾰⒖േଦㅴߩὐ߆ࠄ߽㊀ⷐߢ޽ࠅ㧘࠺ࠪࠞࡦ࠻ࡠ࡯࠲࡯ߩᕈ⢻੍᷹߿ᦨㆡൻ
ߥߤๆ⌕᧚㐿⊒ߦߟߥ߇ࠆ⎇ⓥ߇ᄙߊߥߐࠇߡ޿
ࠆ㧚ๆ⌕᧚⥄૕ߩ㐿⊒ߣߒߡ㧘ᐔⴧๆ⌕․ᕈࠍ೙ᓮߔࠆߚ߼ߦ㧘ᗵ᷷ᕈ᧚ᢱࠍណ↪ߒߚ⎇ⓥ߿ሹᓘ
߇ဋ⾰ߥࡔ࠰ࡐ࡯࡜ࠬๆ⌕૕ߩណ↪ߥߤ߇ឭ᩺ߐ
ࠇߡ޿ࠆ㧚޿ߕࠇ߽ኻ⽎ⓨ㑆ߩ᷷Ḩᐲߦኻߒߡ㧘ᦨ߽ലᨐ⊛ߦๆ⣕⌕㊂ࠍⒿߋๆ⌕᧚ߩ․ᕈ⊒⃻߇⋡⊛ߢ޽ࠆ㧚 㒰Ḩᯏౣ↢ߩല₸ൻല₸⊛ߥ㒰Ḩᯏౣ↢ᣇᴺߣߒߡౣ↢࠱࡯ࡦࠍ 2ಽഀߒߡᲑ㓏⊛ߦๆ⌕᧚ౣ↢ࠍⴕ߁‫ޟ‬Ბ㓏ౣ↢ᚻ
ᴺ‫᦭߇ޠ‬ലߢ޽ࠆ[4]㧚Ბ㓏ౣ↢ᚻᴺߣߪ࿑ 4 ߦ␜ߔࠃ߁ߦ㗼ᾲ੤឵ེࠍㅢㆊߒߚㆶ᳇ࠍౣ↢ࡅ࡯࠲࡯ᚻ೨ߢ 2 ߟߦಽߌ㧘1 ߟߪടᾲེߦࠃࠅ᣹᷷ߒ
ߡᧄౣ↢ⓨ᳇ߣߒ㧘߽߁৻ᣇߪ㗼ᾲ੤឵ེߩᾲ࿁
෼ߦࠃࠅ૛ᾲߐࠇߚⓨ᳇ࠍࡊ࡟ౣ↢ⓨ᳇ߣߒߡട
ᾲེࠍㅢㆊߐߖߕ㒰Ḩᯏߩౣ↢೨Ბㇱಽߦㅢ᳇ߐ
ߖࠆߎߣߢౣ↢ല₸ߩะ਄߇ᦼᓙߢ߈ࠆ㧚
㪌㪇㷄

1

㪌㪇㷄

RA

ㆶ᳇

ឃ᳇
EA
㪏㪇㷄

2
ᄖ᳇
OA

Dehumidifier㒰Ḩࡠ࡯࠲࡯

SA⛎᳇

Heat exchanger㗼ᾲ੤឵ࡠ࡯࠲࡯࿑  㒰ḨᯏߩᲑ㓏ౣ↢࿑ ో឵᳇࠺ࠪࠞࡦ࠻ⓨ⺞ᯏౝߩⓨ᳇⁁ᘒᄌൻ
C ℂᗐ⊛ߥᄌൻߣ D ታ㓙࿑ 5 ߪ㒰Ḩ㊂ߦਈ߃ࠆടᾲౣ↢࠱࡯ࡦ㕙ⓍᲧ₸ߩᓇ㗀ߩ৻଀ߢ޽ࠆ㧚ᄖ᳇Ḩᐲ߇ૐ޿႐ว㧘ടᾲౣ↢࠱࡯ࡦ㕙ⓍᲧ₸ߩᓇ㗀߇ዊߐ޿㧚ߎࠇߪૐ޿
ᄖ᳇Ḩᐲ㗔ၞߢߪๆ⌕㊂߇ዋߥߊ㧘ടᾲౣ↢࠱࡯
ࡦ㕙Ⓧ߇ዊߐߊߡ߽ࡊ࡟ౣ↢ㆊ⒟ߣߣ߽ߦ⣕⌕ߦᔅⷐߥࠛࡀ࡞ࠡ࡯ࠍଏ⛎ߔࠆߎߣ߇ߢ߈ࠆ߆ࠄߢ
޽ࠆ㧚ߒ߆ߒߥ߇ࠄ㜞޿ᄖ᳇Ḩᐲ㗔ၞߢߪᄢ߈ߥ

଀߃߫㧘࠺ࠪࠞࡦ࠻ࡠ࡯࠲࡯ߢߪ߶߷ᢿᾲ⁁ᘒߢ㒰Ḩ߇ㅴⴕߔࠆߚ߼㧘ᓧࠄࠇࠆⓨ᳇Ḩᐲߩਅ㒢⇇ߪ࿑ 3(a)ਛԙߢ␜ߐࠇࠆ߇㧘ታ㓙ߩ㒰Ḩᠲ૞ߢߪ(1) ๆ⌕᧚ࡠ࡯࠲࡯ࠍ੺ߒߚౣ↢஥߆ࠄ⛎᳇஥߳ߩ㗼ᾲ⒖േߦࠃࠆ㒰Ḩ಴ญⓨ᳇ߩࠛࡦ࠲࡞ࡇ࡯Ⴧ
ട㧘(2)᳓ߩ⫳⊒ẜᾲࠃࠅ߽ᄢ߈޿ๆ⌕ᾲ㧘(3)‛⾰વᾲ 2006 ᐕ 1 ᦬

Heater- 40 -J. HTSJ, Vol. 45, No. 190

․㓸㧦ๆ⌕ߩ਎⇇̆ࡒࠢࡠ߆ࠄࡑࠢࡠ㧘ߘߒߡࠪࠬ࠹ࡓ̆
࡯࡚ࠪࡦ⚿ᨐ߆ࠄ 5%ߩ᷷ᐲല₸ߩะ਄ߦࠃࠅࡊ
ࡠ࠮ࠬᕈ⢻߇ᩰᲑߦ਄᣹ߔࠆߎߣ߇੍ᗐߐࠇߡ޿
ࠆ㧚߹ߚ㧘࿁ォဳᾲ੤឵ེߪ㒰Ḩࡠ࡯࠲࡯ߦᲧߴ
ߡᢙච୚㜞ㅦߢ࿁ォߔࠆߚ߼ߦౣ↢஥ⓨ᳇߆ࠄ⛎
᳇஥߳ߩḨಽߩ⒖േߪㆱߌࠄࠇߥ޿㧚ߎߩḨಽ⒖േࠍᛥ೙ߔࠆߚ߼ߦࡊ࡟࡯࠻ࡈࠖࡦᒻߥߤߩ㕒ᱛᒻᾲ੤឵ེߩ೑↪߇ᛮᧄ⊛ߥ⸃᳿ᴺߦߥࠆߣᕁࠊ
ࠇࠆ߇㧘࿁ォဳࠃࠅ߽ૐ޿᷷ᐲല₸߇㔍ὐߢ޽ࠆ㧚




IMI IMI
IMI
kW/kW'
IMI


IMIIMI
CE/CE'
IMI
 
IMI



 
#KT8GNQEKV[ 5# OU‫ޓ‬
20#KT8GNQEKV[ 4# OU
4GIGPGTCVKQP6GOR͠
15

#KT6GOR
1#4#
͠
10
5

 
10
10 10 10 10 

 Area ratio of heating zone to the regeneration zone [-]࿑ 6 Ბ㓏ౣ↢ᚻᴺߦࠃࠆ⋭ࠛࡀ࡞ࠡ࡯ലᨐ

ടᾲౣ↢࠱࡯ࡦ㕙ⓍᲧ₸߇ᔅⷐߣߥࠆ㧚ࠃߞߡ㧘᳞߼ࠄࠇࠆ⛎᳇Ḩᐲߦࠃߞߡߪടᾲౣ↢࠱࡯ࡦ㕙
Ⓧࠍ⺞ᢛߔࠆߎߣߢࠛࡀ࡞ࠡ࡯ᛩ౉㊂ߩ೥ᷫ߇น
⢻ߢ޽ࠆ㧚߹ߚ㧘㜞޿ᄖ᳇Ḩᐲ㗔ၞߢߪ㒰Ḩ㊂ᄌൻ߇ዊߐ޿߇㧘ߎࠇߪๆ⌕᧚ߩๆ⌕╬᷷✢ᒻ⁁߅ࠃ߮ๆ⌕ㅦᐲߦ⿠࿃ߒ㧘੹ᓟߩ࠺ࠪࠞࡦ࠻ⓨ⺞ࡊࡠ࠮ࠬ↪ㅜๆ⌕᧚㐿⊒ߩ㊀ⷐߥᬌ⸛⺖㗴ߩ৻ߟߢ޽ࠆ㧚㪟㪼㪸㫋㪼㫉㩷㫀㫅㫇㫌㫋
㪦㪥
㪦㪝㪝
䋱䋭䋲
䋳䋭䋶
䋱䋭䋳
䋴䋭䋶
䋱䋭䋴
䋵䋭䋶
䋱䋭䋵
䋶
䋱䋭䋶
䋭

㪌

㪈

㪍

㪘㫉㪼㪸㩷㫉㪸㫋㫀㫆㪱㫆㫅㪼㩷㫉㪸㫋㫀㫆
㪩㪸㫋㫀㫆
䋱䋺䋲
㪊㪊㩼
䋱䋺䋱
㪌㪇㩼
䋲䋺䋱
㪍㪍㩼
䋵䋺䋱
㪏㪊㩼
䋱䋺䋰
㪈㪇㪇㩼

㪛㪼㪿㫌㫄㫀㪻㫀㪽㫀㪺㪸㫋㫀㫆㫅
#KTXGNQEKV[OU





*GVGT
*GCVKPI
101((
CTGCTCVKQ
10٤‫ޓޓ‬10‫ޓޓغ‬10٠‫ޓޓ‬10‫ޓޓ‬10ٌ












#ODKGPVJWOKFKV[=IMI?

⋧ኻḨᐲ 100 80 60 50 40

100



10

20

140

6

30

160

Enthalpy (kJ/kg)

2580㒰Ḩኻ⽎ⓨ᳇

࿑ 5 㒰Ḩ㊂ߦਈ߃ࠆടᾲౣ↢㕙ⓍᲧ₸ߩᓇ㗀㧔ࡠ࡯࠲࡯ᢿ㕙࿑ߪౣ↢஥౉ญ߆ࠄ⷗ߚ߽ߩ㧕20ౣ↢ⓨ᳇᷷ᐲ䋵䋰㷄

60

A

40

࿑ 6 ߪടᾲౣ↢࠱࡯ࡦ㕙ⓍᲧ₸ߣ⋧ኻ಄ළലᨐ
CE/CẺ(࠱࡯ࡦ 1-6 ోߡࠍടᾲౣ↢ߒߚ႐วߦᓧ
ࠄࠇࠆ಄ළലᨐࠍ 1 ߣߔࠆ ) ߅ࠃ߮ᛩ౉ᾲ㊂ᲧkW/kW̉(࠱࡯ࡦ 1-6 ోߡࠍടᾲౣ↢ߒߚ႐วߩᛩ
౉ᾲ㊂ࠍ 1 ߣߔࠆ)ߩ㑐ଥߢ޽ࠆ㧚ടᾲౣ↢࠱࡯ࡦ
㕙ⓍᲧ₸߇ዊߐߊߥࠆߦߟࠇߡᾲᛩ౉㊂ߪ⋥✢⁁ߦᷫዋߒߡ޿ࠆߩߦኻߒ㧘⋧ኻ಄ළലᨐߪᒰೋ✭߿߆ߦᷫዋߔࠆ㧚ߎߩ⚿ᨐ㧘଀߃߫ടᾲౣ↢࠱࡯
ࡦ㕙ⓍᲧ₸ 0.67 ߩ႐ว㧘ᛩ౉ᾲ㊂Ყߪ 0.75 ߦኻߒߡ⋧ኻ಄ළലᨐߪ 0.9 ⒟ᐲࠍ⛽ᜬߢ߈ߡ߅ࠅ㧘
COPm ୯ߪ 20㧑ะ਄ߢ߈ࠆߎߣߦߥࠆ㧚 ᾲ੤឵ེ
ቶౝ߳ߩ⛎᳇ߩࠛࡦ࠲࡞ࡇ࡯ࠍਅߍߡ޿ࠆߩߪ
㗼ᾲ੤឵ེߩ௛߈ߦࠃࠆ߽ߩߢ޽ࠅ㧘ߘߩ᷷ᐲല
₸ะ਄ߩ㊀ⷐᕈߪ⸒߁߹ߢ߽ߥ޿㧚ᢙ୯ࠪࡒࡘ࡟

વᾲ 2006 ᐕ 1 ᦬

30

120

15

ᢿᾲ㒰Ḩ䈱㒢⇇210⛘ኻḨᐲ IMI㪋

Ratio of heat energy supplied
to the process kW/kW' [-]㪉㪊

Relative cooling effect CE/CE' [-]㪩㪼㪾㪼㫅㪼㫉㪸㫋㫀㫆㫅㩷

20P╬᷷㒰Ḩ䈱㒢⇇

5

0
-10

0

10

20

30 40 50 60ⓨ᳇᷷ᐲ Q%7080

090 100࿑ 7 ᢿᾲ㒰Ḩ㒢⇇ߣ╬᷷㒰Ḩߩ᦭ലᕈᢿᾲ㒰Ḩ㒢⇇ߩస᦯࿑ 7 ߦ␜ߔࠃ߁ߦ㒰Ḩ߇ᢿᾲ⊛ߦㅴⴕߔࠆ㒢ࠅߪ㒰Ḩ಴ญḨᐲߩਅ㒢⇇ߪᄖ᳇ⓨ᳇ߣ╬ߒ޿ࠛࡦ࠲࡞ࡇ࡯✢ߣౣ↢ⓨ᳇ߣ╬ߒ޿⋧ኻḨᐲ✢ߩ੤ὐ㧔㧭ὐ㧕ߢ޽ࠆ㧚ࠃߞߡᓥ᧪ߩᵹ〝᭴ᚑߢߪ
50-60 ͠⒟ᐲߩౣ↢᷷ᐲߢߪචಽߥ㒰Ḩ㊂߇ᓧࠄ

- 41 -J. HTSJ, Vol. 45, No. 190

․㓸㧦ๆ⌕ߩ਎⇇̆ࡒࠢࡠ߆ࠄࡑࠢࡠ㧘ߘߒߡࠪࠬ࠹ࡓ̆

ࠇߥ޿㧚ߎߩᢿᾲ㒰Ḩ㒢⇇ࠍస᦯ߔࠆߚ߼ߦߪ㒰Ḩߦ઻ߞߡ⊒↢ߔࠆๆ⌕ᾲࠍ㒰෰ߔࠆ઀⚵ߺ߇ᔅⷐߢ޽ࠆ㧚଀߃߫㧘࿑ 1 ߩⵝ⟎ᒻᑼߩ߹߹ߢ޽ࠇ
߫㧘ቶౝ߳ߩଏ⛎ⓨ᳇ߩ৻ㇱࠍ㒰Ḩࡠ࡯࠲࡯౉ญ
ߦౣᓴⅣߐߖࠆߎߣߢ㧘㒰Ḩᕈ⢻ࠍᐞಽ߆ะ਄ߢ
߈ࠆ߇㧘⛎᳇㘑㊂߇ᷫዋߔࠆߣ޿߁ᰳὐ߇޽ࠆ㧚ᒰ⎇ⓥቶߢߪ⛎᳇㘑㊂ߩᷫዋࠍ઻ࠊߥ޿ᚻᴺߣߒ
ߡ㒰Ḩᠲ૞ߩᄙᲑൻࠍᬌ⸛ߒߚ㧚  Ბ㒰Ḩဳࡊࡠ࠮ࠬ
࿑ 8 ߪ㒰Ḩᠲ૞ࠍ㧞Ბߦߒߚๆ⌕ᑼ࠺ࠪࠞࡦ࠻ⓨ⺞ࡊࡠ࠮ࠬߩ᭎⇛࿑ߢ޽ࠆ㧚ߎߩᵹ〝᭴ᚑߢߪ㧘߹ߕ৻Ბ⋡ߩ㒰Ḩᯏߢ㜞Ḩᐲߥᄖ᳇"1"ࠍ"A"ߩ⁁ᘒߦ߹ߢ㒰Ḩߒ㧘ᄖ᳇ߣᾲ੤឵ߒߚᓟߦߐࠄߦ㒰Ḩߣᾲ੤឵ࠍⴕ޿㧘ᓧࠄࠇࠆૐḨᐲߥⓨ᳇"3"ࠍᓧ
ࠆ߽ߩߢ޽ࠆ㧚
Heater

Z

X

Y

1

7

ࠃߞߡⓨ᳇ᵹࠇᣇะߦⓨ᳇ߩ⋧ኻḨᐲ߇ᕆỗߦૐਅߔࠆߚ߼㧘㒰Ḩࡠ࡯࠲࡯ਅᵹၞߩๆ⌕㊂ߪ਄ᵹၞߦᲧߴߡዋߥ޿ߚ߼ߢ޽ࠆ㧚⸒޿឵߃ࠇ߫㧘࠺ࠪࠞࡦ࠻ⓨ⺞ߩࠃ߁ߦⓥᭂ⊛ߥੇ῎߇ᔅⷐߥ޿㒰Ḩᠲ૞ߢߪࡠ࡯࠲࡯ߦ฽߹ࠇࠆๆ⌕᧚ߩඨಽߪല
₸ࠃߊᯏ⢻ߒߡ޿ߥ޿㧚ᢙ୯⸘▚ߦࠃࠆߣ㒰Ḩᯏౣ↢᷷ᐲ߇㜞޿߶ߤߎߩ௑ะߪᒝߊߥࠆ=?㧚Heat supply
Parallel
Serial(2-1mode)
Conventional
Mark 1st 2nd Mark 1st 2nd Mark 1st 2nd䂾
50 50 䂺50 60 䃂50 䂔60 60 ×60 80 䂓
60 䂦
80 80
䂥
80 -

Parallel: 㒰Ḩᯏ 2 บߣ߽หߓౣ↢᷷ᐲ
Serial: ࡊࡠ࠮ࠬౝᾲࠞࠬࠤ࡯࠼೑↪
㧔㒰Ḩᯏ 2 บߩౣ↢᷷ᐲߪ⇣ߥࠆ㧕

Heater

6

5

4 RA


1

A

B

2

3 SA



Dehumidifier Heat Exchanger Dehumidifier Heat Exchanger㧔Ბ⋡㒰Ḩ㧧ᄖ᳇஥㧕㧔Ბ⋡㒰Ḩ㧧ቶౝ஥㧕࿑   Ბ㒰Ḩဳ࠺ࠪࠞࡦ࠻ⓨ⺞ࡊࡠ࠮ࠬ

㧕
͠
⋡
Ბ
㧘
㧕
͠
↢
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ࠆߎߣ߇࿎㔍ߥ㜞Ḩᐲ᧦ઙਅߢ߽ 2 Ბ㒰Ḩဳࡊࡠ࠮ࠬߪ㜞޿㒰Ḩᕈ⢻ࠍ⛽ᜬߒߚ㧚ߎࠇߪ 2 ᐲߩ㒰Ḩᠲ૞ߦട߃㧘㒰Ḩᯏ㑆ߩ㗼ᾲ੤឵ེߦࠃࠅๆ⌕ᾲ߇㒰෰ߐࠇ㧘᦭ലๆ⌕㊂ߩૐਅ߇ᛥ೙ߐࠇߚߚ
߼ߢ޽ࠆ㧚߹ߚ㧘ታ⾰⊛ߥᾲࠛࡀ࡞ࠡ࡯೑↪ല₸ߩะ਄ࠍ⋡⊛ߣߒߚ⇣᷷ᐲౣ↢ᣇᑼ ( ࡊࡠ࠮ࠬౝ
ᾲࠞࠬࠤ࡯࠼೑↪ဳ”2-1 ࡕ࡯࠼”)߽ 2 ߟߩടᾲེ
ߦห᷷ᐲߩᾲࠍଏ⛎ߔࠆห᷷ᐲౣ↢ᣇᑼ(Parallel)ߦߪ⧯ᐓഠࠆ߇㧘⦟ᅢߥ㒰Ḩ㊂ࠍᓧࠆߎߣ߇ߢ߈
ߚ㧚߹ߚ㧘COPm ୯߽㜞ߊ㧘ታ⾰⊛ߥࠛࡀ࡞ࠡ࡯
೑↪ല₸ߩⷰὐ߆ࠄߪ᦭ലߥᵹ〝᭴ᚑߢ޽ࠆߣ޿
߃ࠆ㧚৻ᣇߢ  Ბ㒰Ḩဳ࠺ࠪࠞࡦ࠻ⓨ⺞ࡊࡠ࠮ࠬߪⵝ⟎߇ᄢဳൻߒ㧘᥉෸ߩᅹߍߩ৻࿃ߣߥࠆ㧚ߘߎߢ㧘ⵝ⟎ߩ⋭ࠬࡍ࡯ࠬൻࠍ࿑ࠆߚ߼ߦ㧘ㅢᏱߩඨಽߢ޽ࠆࡠ࡯࠲࡯᏷ O ߩ㒰Ḩࡠ࡯࠲࡯ࠍዉ
౉ߒߚ⚿ᨐ㧘㜞Ḩᐲ᧦ઙਅߢ߽ᕈ⢻ૐਅߪ ⒟ᐲߦ⇐߹ߞߚ㧚ߎࠇߪᢿᾲ㒰Ḩߢߪๆ⌕ᾲ⊒↢ߦ

વᾲ 2006 ᐕ 1 ᦬

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࿑   Ბ㒰Ḩဳࡊࡠ࠮ࠬߩ㒰Ḩᕈ⢻߅ࠃ߮ %12

- 42 -J. HTSJ, Vol. 45, No. 190

․㓸㧦ๆ⌕ߩ਎⇇̆ࡒࠢࡠ߆ࠄࡑࠢࡠ㧘ߘߒߡࠪࠬ࠹ࡓ̆

વᾲ 2006 ᐕ 1 ᦬

࿑ 10 หᤨᾲ੤឵ဳ࠺ࠪࠞࡦ࠻ࡠ࡯࠲࡯
㪈㪇㪇㪩㪼㫃㪸㫋㫀㫍㪼㩷㪟㫌㫄㫀㪻㫀㫋㫐㪲㩼㪴

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࿑ 7 ߦ␜ߒߚࠃ߁ߦ╬᷷ᠲ૞ߦ߅ߌࠆ㒰Ḩⓨ᳇Ḩᐲߩਅ㒢⇇ߪ㧘ὐ㧼ߢ޽ࠆ㧚ߔߥࠊߜ 50͠ߩౣ↢ⓨ᳇ߦࠃࠆ╬᷷㒰Ḩߢߪ㧘90͠ߩౣ↢ⓨ᳇ߦࠃࠆᢿᾲ㒰Ḩߣหߓ㒰Ḩᕈ⢻߇ᓧࠄࠇࠆߎߣߦߥࠆ㧚߹ߚ㧘╬᷷㒰Ḩߣᢿᾲ㒰Ḩߢᓧࠄࠇࠆ㒰Ḩ㊂ࠍᲧセߔࠆߣ㧘ૐ᷷ᐲౣ↢ߦߥࠆ߶ߤ╬᷷㒰Ḩߩ᦭೑ᕈߪ㗼⪺ߦߥࠆߎߣ߇ࠊ߆ࠆ㧚ߥ߅㧘╬᷷㒰Ḩࠍ㆐ᚑߔࠆߚ߼ߦߪๆ⌕Ꮏ⒟ߦ౉ࠆ೨ߦๆ⌕೷ߩ಄ළ㧘ๆ⌕Ꮏ⒟ਛߦߪๆ⌕ᾲߩㅪ⛯㒰෰߇ᔅⷐߢ޽
ࠅ㧘ๆ⌕᧚ߩવᾲଦㅴ߅ࠃ߮ᾲ੤឵ᕈ⢻ะ਄ߩߚ߼ߩᎿᄦ߇ਇนᰳߣߥࠆ㧚⎇ⓥ㐿⊒ߩ৻଀ߣߒߡ
࿑ 10 ߦหᤨᾲ੤឵ဳ㒰Ḩࡠ࡯࠲࡯ࠍ␜ߔ㧚╬㑆㓒ߢ᡼኿⁁ߦ 60 ୘⸳⟎ߒߚࠕ࡞ࡒ⵾ߩࠬ࡝࠶࠻ߩ
㑆ߦᚸᒻߩࡂ࠾ࠞࡓๆ⌕೷߇⚵ߺㄟ߹ࠇߡ޿ࠆ㧚ౣ↢↪᷷᳓ࠍߎߩࠬ࡝࠶࠻ౝߦㅢㆊߐߖ㧘ო߆ࠄߩᾲ੤឵ߦࠃࠅๆ⌕᧚ࠍടᾲߔࠆߎߣ߽น⢻ߢ޽ࠆ㧚ߎߩ႐ว㧘ടᾲ޽ࠆ޿ߪߘߩ߹߹ߩ᷷ᐲߩᄖ
᳇ࠍๆ⌕೷ጀߦଏ⛎ߒ㧘᳓⫳᳇ࠍ⣕⌕㒰෰ߔࠆ㧚৻ᣇ㧘ๆ⌕஥ߢߪࠬ࡝࠶࠻ౝߦ಄ළⓨ᳇ࠍᵹߒ㧘ๆ⌕ᾲࠍ㒰෰ߒߡๆ⌕᧚ࠍ಄ළߔࠆ㧚ߎߩߣ߈ౣ
↢஥ߢ↪޿ߚ᷷᳓߇ࠬ࡝࠶࠻ߩౝოߦᱷሽߒߡ߅
ࠅ㧘಄ළⓨ᳇ߩᵹࠇߦ઻߁ᱷሽ᳓ߩ᳇ൻᾲߦࠃࠅ㧘ๆ⌕ᾲࠍࠃࠅലᨐ⊛ߦขࠅ㒰ߊߎߣ߇ߢ߈ࠆ㧚࿑ 11 ߦ㒰Ḩታ㛎⚿ᨐߩ৻଀ࠍ␜ߔ㧚ౣ↢ㆊ⒟ߢ
ߪࠬ࡝࠶࠻ߦ᷷᳓ࠍଏ⛎ߒ㧘߆ߟๆ⌕᧚ጀߦߪᄖ
᳇ࠍ᷷᳓ߣหߓ᷷ᐲ߹ߢടᾲߒߡଏ⛎ߒߚ㧚ๆ⌕ᾲ㒰෰ߪචಽߢߪߥߊ╬᷷㒰Ḩߪ㆐ᚑߢ߈ߡ޿ߥ
޿߇㧘ࠬ࡝࠶࠻ౝߦᱷሽߒߚ᳓ߩ⫳⊒ẜᾲߦࠃࠆๆ⌕᧚ߩ಄ළലᨐ߽޽ࠅ㧘45-50͠ߣ޿߁ૐ޿ౣ↢᷷ᐲߢ߽⦟ᅢߥ㒰Ḩᕈ⢻ࠍᓧࠆߎߣ߇ߢ߈ߚ㧚଀
߃߫ 45 ͠ౣ↢ߢ 23g/kg ߣ޿߁㜞Ḩᐲᄖ᳇߆ࠄ
8g/kg 㒰Ḩߒߡ޿ࠆ߇㧘ߎࠇߪᓥ᧪ߩ㒰Ḩࡠ࡯࠲࡯ࠍห᷷ᐲߢౣ↢ߒߚ႐วߦߪ᳿ߒߡᓧࠆߎߣߩ
ߢ߈ߥ޿㒰Ḩ㊂ߢ޽ࠆ㧚৻ᣇ㧘㒰Ḩ㊂ߦਈ߃ࠆౣ
↢᷷ᐲߩᓇ㗀ߪዊߐߊ㧘․ߦේᢱⓨ᳇Ḩᐲ߇㜞޿㗔ၞߢߘߩ௑ะ߇ᒝ޿㧚ߎࠇߪ㧘ࠕ࡞ࡒࠬ࡝࠶࠻
╬ߩዉ౉ߦࠃࠅๆ⌕᧚ࡠ࡯࠲࡯ߩᾲኈ㊂߇Ⴧടߒߚߎߣ߽ᓇ㗀ߒߡๆ⌕᧚ߩ಄ළ߇ㄦㅦߢߪߥߊ㧘ౣ↢᷷ᐲ߇㜞޿߶ߤๆ⌕᧚ጀ᷷ᐲ߇㜞޿߹߹ߢๆ
⌕Ꮏ⒟ࠍ⒖േߔࠆߎߣࠍ␜ໂߔࠆ㧚߹ߚ㧘ਛ㑆Ḩᐲၞߢ㒰Ḩᕈ⢻ߩૐਅ߇⷗ࠄࠇࠆ߇㧘ߎࠇߪ㒰Ḩࡠ࡯࠲࡯ߦᜂᜬߒߚๆ⌕೷ߩ․ᕈ߇ᓇ㗀ߒߡ޿ࠆ㧚਄⸥⚿ᨐ߆ࠄࡠ࡯࠲࡯ౝવᾲᛶ᛫ߩ೥ᷫߣๆ⌕- 43 -

ේᢱⓨ᳇
20g/kg㪍㪇㪈㪌᷷᳓ᵹ㊂⚂㪈㪅㪇㫂㪾㪆㫄㫀㫅

15g/kg಄ළⓨ᳇᷷ᐲ䍃㘑ㅦ㪊㪉㷄㪃㩷㪊㫄㪆㫊㪋㪇㪈㪇

10g/kgౣ↢ⓨ᳇㘑ㅦ
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45㷄
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50㷄

㒰Ḩᓟⓨ᳇
55㷄

↪ⓨ
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᳓᷷

60㷄

5g/kg

ᐲ

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㪫㪼㫄㫇㪼㫉㪸㫋㫌㫉㪼䇭䋨㷄䋩㪋㪇㪌㪇

࿑ 11 หᤨᾲ੤឵ဳๆ⌕᧚ࡠ࡯࠲࡯ߩ㒰Ḩᕈ⢻᧚․ᕈߩᬌ⸛ߦࠃࠅ㒰Ḩᕈ⢻ߩᡷༀ߇ᦼᓙߢ߈ࠆ㧚ߘߎߢ㧘ๆ⌕᧚ጀߣࠕ࡞ࡒࠬ࡝࠶࠻㑆ࠍᾲવዉᕈ
ߩ㜞޿᧚ᢱߢធว㧘વᾲᛶ᛫ߩ೥ᷫࠍ࿑ߞߚ㧚߹ߚ㧘╬᷷㒰Ḩߦㆡߒߚๆ⌕᧚․ᕈߣߒߡߪ㧘⦟ᅢߥๆ⣕⌕ㅦᐲߦട߃ߡ㧘ౣ↢ⓨ᳇ߩ⋧ኻḨᐲࠍႺߦᐔⴧๆ⌕㊂߇ᄢ߈ߊᄌൻߔࠆߎߣ߇ᦸ߹ࠇࠆ㧚ࠃߞߡ㧘ߎߩࠃ߁ߥ․ᕈࠍ᦭ߔࠆࢃਃ⪉ൻቇ⵾ߩᣂⷙๆ⌕᧚ FAM-Z ࠍήᯏࡃࠗࡦ࠳࡯ߦࠃࠅࠕ࡞
ࡒ࠾࠙ࡓ⵾ߩࡂ࠾ࠞࡓࡑ࠻࡝ࠢࠬߦᜂᜬߒߚ㧚ߎߩๆ⌕᧚ߢߪ㧘᷷ᐲ਄᣹ߦࠃࠅ╬᷷✢߇┙ߜ਄߇

J. HTSJ, Vol. 45, No. 190

․㓸㧦ๆ⌕ߩ਎⇇̆ࡒࠢࡠ߆ࠄࡑࠢࡠ㧘ߘߒߡࠪࠬ࠹ࡓ̆

㪩㪼㫃㪸㫋㫀㫍㪼㩷㪟㫌㫄㫀㪻㫀㫋㫐㪲㩼㪴

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㒰Ḩ㊂䇭㒰Ḩ㊂㪲㪾㪆㫂㪾㪄㪛㪘㪴12೅ોᑣ‫׹‬ӷ଺༏ʩ੭ᨊ฻ȭȸǿȸ

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14 16 18 20ᄖ᳇Ḩᐲ䇭㪲㪾㪆㫂㪾㪄㪛㪘㪴

22

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㪫㪼㫄㫇㪼㫉㪸㫋㫌㫉㪼䇭䋨㷄䋩ⓨ᳇᷷ᐲ [㷄]

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࿑ વᾲଦㅴߣᣂⷙๆ⌕᧚ዉ౉ߦࠃࠆหᤨᾲ੤឵㒰Ḩࡠ࡯࠲࡯ߩᕈ⢻ᡷༀࠆ⋧ኻḨᐲၞ߇ടᾲౣ↢ߦᅢㇺวߥᣇะߦ⒖േߔ
ࠆ㧚࿑ 12 ߦᡷ⦟ဳ㒰Ḩࡠ࡯࠲࡯ߩᕈ⢻ࠍ␜ߔ㧚ߎߎߢๆ⌕᧚ౣ↢ߪടᾲⓨ᳇ߛߌߢⴕߞߚ㧚ๆ⌕᧚ߩ಄ළലᨐࠍ㜞߼ࠆߚ߼ߦዋ㊂ߩ಄ළ᳓ࠍㅊടଏ
⛎ߒߚߎߣ߽޽ࠅ㧘ᣥᾲ੤឵㒰Ḩࡠ࡯࠲࡯ߣᲧߴ
ߡ߽㒰Ḩᕈ⢻ߪᄢ߈ߊะ਄ߒߚ㧚߹ߚ㧘หᤨᾲ੤឵ဳ㒰Ḩᯏߪᓥ᧪ဳߦᲧߴๆ⌕࠱࡯ࡦߩᢿ㕙Ⓧ߇
⚂ 40%ዊߐ޿߽ߩߩ㧘2 ୚ㄭ޿㒰Ḩ㊂ࠍ㆐ᚑߒߡ
߅ࠅ㧘ⵝ⟎ߩዊဳൻߦ߽ߟߥ߇ࠆ⚿ᨐߣߥߞߚ㧚ߒ߆ߒߥ߇ࠄ㧘⎇ⓥ㐿ᆎᒰೋߦᦼᓙߒߚ㜞ㅦๆ⣕⌕ࠨࠗࠢ࡞ߣߪ⒟㆙޿ࡠ࡯࠲࡯࿁ォᢙߢߩᠲ૞ߢ
޽ࠆ㧚 㗄ߦ߽⸥ߒߚࠃ߁ߦ⹜૞ߒߚ EO ጀ㜞ߩ㒰Ḩࡠ࡯࠲࡯ߢߪⓨ᳇ᵹࠇᣇะᓟඨㇱಽߩๆ⌕೷߇ല₸ࠃߊ௛޿ߡ޿ߥ޿ߎߣ㧘߹ߚ㧘ߘߩㇱಽ߳ߩ⫾ᾲ߇㜞ㅦࠨࠗࠢ࡞ൻࠍᅹߍߡ޿ࠆߎߣ߇੍
ᗐߐࠇࠆ㧚ߎߩὐߢๆ⌕᧚ጀ㜞ߐߩᕁ޿ಾߞߚ೥
ᷫߪዊဳ㜞ᕈ⢻࠺ࠪࠞࡦ࠻ⓨ⺞ࡊࡠ࠮ࠬࠍዉߊ߽
ߩߣߒߡ㧘⃻࿷ᬌ⸛ਛߢ޽ࠆ㧚࿖ౝ᥉෸ᢙߪᄢⷙᮨᣉ⸳ࠍਛᔃߦ 200 ઙ⒟ᐲߦ⇐߹ߞߡ޿ࠆ߇㧘80͠⒟ᐲએ਄ߩౣ↢᷷ᐲ߇޽ࠇ
߫ᣢߦታ↪ᕈ⢻ၞߦ޽ࠆ࠺ࠪࠞࡦ࠻ⓨ⺞ࡊࡠ࠮ࠬߢ޽ࠆ㧚੹ᓟ㧘ࠦࠫࠚࡀ࡟࡯࡚ࠪࡦࠪࠬ࠹ࡓߩ᥉
෸ߣߣ߽ߦ࠺ࠪࠞࡦ࠻ⓨ⺞ᯏߩ․㐳߇⹺⍮ߐࠇࠇ߫㧘ᔟㆡⅣႺࠍᔅⷐߣߔࠆቇᩞ߿഍႐߳ߩዉ౉߽
ㅴ߻㧚⑳ߚߜߩኅᐸࠍ⠨߃ࠆߣዋߥ޿ࠛࡀ࡞ࠡ࡯
ᶖ⾌㊂ߢ 24 ᤨ㑆឵᳇ⓨ⺞߇ታᣉߢ߈㧘ߐࠄߦߪ⚿㔺ࠍ㒐ߋߎߣߢᑪ‛ߘߩ߽ߩߩኼ๮߽㐳ߊߢ߈ࠆ㧚ࠝࡈࠖࠬߢߪ࠺ࠪࠞࡦ࠻ⓨ⺞ᯏߦࠃࠆ㜞᷷ૐḨᐲⓨ᳇ߩଏ⛎ߢ಄ᚱߦࠃࠆஜᐽⵍኂ߇ዋߥߊߥࠆ㧚⥄േゞ߳ߩㆡ↪ߦߪዊဳൻߪਇนᰳߢ޽ࠆ߇Ყセ⊛㜞᷷ߩࠛࡦࠫࡦឃᾲ߇೑↪ߢ߈ࠆ㧚࠺ࠪࠞࡦ࠻ⓨ⺞ᯏߪ⋭ࠛࡀ࡞ࠡ࡯ߛߌߢߪߥߊ㧘ᔟㆡⓨ⺞߽ឭଏߔࠆ߽ߩߢ޽ࠅ㧘ᦝߥࠆ⎇ⓥ㐿⊒߇ᦸ߹ࠇࠆ㧚ෳ⠨ᢥ₂
[1] ᩣ ᑼ ળ ␠ ⷏ ㇱ ᛛ ⎇ ࡎ ࡯ ࡓ ࡍ ࡯ ࠫ
http://www.seibu-giken.co.jp/߅ࠊࠅߦ
ᒰ⎇ⓥቶߦ߅ߌࠆๆ⌕ᑼ࠺ࠪࠞࡦ࠻ⓨ⺞ᯏߩ㜞ᐲൻ⎇ⓥࠍ⚫੺ߐߖߡ㗂޿ߚ߇㧘Ḩᐲࠬࠗࡦࠣๆ
⌕㧔ን჻ࠪ࡝ࠪࠕൻቇ㧕㧘㜞ಽሶ෼⌕೷ᔕ↪ࡊࡠ࠮ࠬ㧔ጟጊᄢቇ㧕㧘ࡃ࠶࠴ᑼ╬᷷㒰Ḩࡊࡠ࠮ࠬ㧔ฬฎደᄢ㧕, ๆ⌕ࡅ࡯࠻ࡐࡦࡊߣߩࡂࠗࡉ࡝࠶࠼ൻ㧔᧲੩ㄘᎿᄢ࡮਻Ꮊᄢ㧕ߥߤ࿖ౝߢ߽ᵈ⋡ߔߴ߈࠺ࠪ
ࠞࡦ࠻㑐ㅪ⎇ⓥ߇ᢙᄙߊㅴࠎߢ޿ࠆ㧚ߎߩਛߢૐ
᷷ᾲ㚟േࠍ⋡ᮡߣߒߚ⎇ⓥ㐿⊒ߩᄙߊߪๆ⌕ᾲ㒰෰ߦࠃࠆ╬᷷㒰Ḩࠍ⋡ᜰߒߡ߅ࠅ㧘ࠃࠅࠪࡦࡊ࡞
ߥⵝ⟎᭴ㅧߢ޿߆ߦല₸ࠃߊๆ⌕ᾲࠍ㒰෰ߔࠆ߆߇ࡉ࡟࡯ࠢࠬ࡞࡯ߩ㎛ߣߥߞߡ޿ࠆ㧚[2] L. Z. Zhang and J. L. Niu, Energy, 28, (2003) 275.
[3] Kodama, A. et al., J. Chem. Eng. Japan, 36,(2003) 819.

વᾲ 2006 ᐕ 1 ᦬[4] ఽ₹ᤘ㓶㧘቟⮮ᐘഥ㧘ᐢἑ ീ㧘ᓟ⮮రା㧘ጟ
㊁ᶈᔒ㧘ᣣᧄ಄ಓⓨ⺞ቇળ⺰ᢥ㓸, 22-1, (2005)
33.
[5] Kodama, A. et al., Adsorption, 11-Supplement 1,(2005) 603.
[6] Ando, K. et al., Adsorption, 11-Supplement 1,(2005) 631.
[7] ㄞญᜏ਽㧘ఽ₹ᤘ㓶㧘ᣣᧄ಄ಓⓨ⺞ቇળ⺰ᢥ㓸, 22-4, (2005) 49- 44 -J. HTSJ, Vol. 45, No. 190

․㓸㧦ๆ⌕ߩ਎⇇̆ࡒࠢࡠ߆ࠄࡑࠢࡠ㧘ߘߒߡࠪࠬ࠹ࡓ̆

ๆ⌕಄ಓࠨࠗࠢ࡞߅ࠃ߮ߘߩዷ㐿
Basics of Adsorption Refrigeration Cycle and Advanced Cycles⑺Ỉ ᷕ㧔᧲੩ㄘᎿᄢቇ㧕
Atsushi AKISAWA (Tokyo University of Agriculture and Technology)
e-mail: akisawa@cc.tuat.ac.jp㧚ߪߓ߼ߦ ㆊ෰ 20 ᐕߩ᳃↢ㇱ㐷ߦ߅ߌࠆࠛࡀ࡞ࠡ࡯㔛ⷐߩേะࠍߺࠆߣ㧘Ყ₸⊛ߦᦨ߽િ߮ߡ޿ࠆߩߪ಄ᚱ⽶⩄ߢ޽ࠆ㧚ᣢߦ๟⍮ߩㅢࠅ㧘ࠝ࠱ࡦጀࠍ⎕უߒߥ޿ઍᦧࡈࡠࡦ߽࿾⃿᷷ᥦൻࠍᒁ߈⿠ߎߒߡߒ߹߁㧚ߒߚ߇ߞߡ㧘ࠣࡠ࡯ࡃ࡞ߥⅣႺ໧㗴ߢ޽ࠆࠝ࠱ࡦጀ⎕უߩ㒐ᱛ㧘࿾⃿᷷ᥦൻᛥ೙ߩⷰὐ߆ࠄ಄ಓᯏߩ੹ᓟ
ߩേะߪ㊀ⷐߥᗧ๧ࠍᜬߞߡ޿ࠆ㧚ߎࠇࠄࠍหᤨߦ
ḩ⿷ߐߖࠆ಄ᇦߪ࿾⃿਄ߦᄤὼߦሽ࿷ߔࠆ‛⾰㧘ߔߥࠊߜ⥄ὼ಄ᇦߢ޽ࠆ㧚⥄ὼ಄ᇦߦߪ᳓㧘ࠕࡦࡕ࠾ࠕ㧘ࠕ࡞ࠦ࡯࡞㧘὇ൻ᳓⚛㧘ⓨ᳇ߥߤ᭽‫߇ߩ߽ߥޘ‬޽ࠆ߇㧘ᧄⓂߢߪ᳓ࠍ಄ᇦߣߒ㧘࿕૕ๆ⌕᧚㧔ࠪ࡝ࠞࠥ࡞㧕ࠍ↪޿ߡ಄ᾲࠍ⊒↢ߐߖࠆๆ⌕಄ಓᯏߦߟ
޿ߡ⸃⺑ߔࠆ㧚 ๆ⌕಄ಓᯏߪๆ෼಄ಓᯏߣਗࠎߢᾲ㚟േࡅ࡯࠻ࡐ
ࡦࡊߦ૏⟎ߠߌࠄࠇࠆ㧚ߎࠇࠄߪࠦ࡯ࠫࠚࡀ࡟࡯ࠪ
࡚ࡦ߿Ꮏ႐ឃᾲߥߤ㧘৻ᐲ೑↪ߐࠇߡ߆ࠄឃ಴ߐࠇ
ߚᾲࠍ᦭ല೑↪ߢ߈ࠆᛛⴚߢ޽ࠅ㧘ࡅ࡯࠻ࠞࠬࠤ࡯
࠺ࠖࡦࠣ㧔ᾲߩᄙᲑ㓏೑↪㧕ࠍ᭴ᚑߒ㧘ૐ᷷ឃᾲ߆
ࠄ಄ᾲࠍ⊒↢ߔࠆᓎഀࠍᜂߞߡ޿ࠆ㧚․ߦࠪ࡝ࠞࠥ
࡞ࠍ↪޿ߚๆ⌕಄ಓᯏߪᣢሽߩๆ෼಄ಓᯏࠃࠅ߽ૐ
᷷ߩ㚟േᾲḮߢㆇォน⢻ߢ޽ࠆߎߣ߆ࠄ㧘ૐຠ⾰ߩᾲࠍౣᵴ↪ߔࠆࡅ࡯࠻ࠞࠬࠤ࡯࠺ࠖࡦࠣߩᦨ⚳Ბߣߒߡᦼᓙߐࠇߡ޿ࠆ㧚㧚ๆ⌕಄ಓࠨࠗࠢ࡞
 േ૞ේℂ ᐢߊ᥉෸ߒߡ޿ࠆๆ෼಄ಓᯏ߇ LiBr ᳓ṁᶧ޽ࠆ޿ߪࠕࡦࡕ࠾ࠕ᳓ṁᶧߥߤߩๆ෼ṁᶧࠍ૶߁ߩߦኻ
ߒ㧘ๆ⌕಄ಓᯏߪ࿕૕ߩๆ⌕᧚ࠍ↪޿ࠆ㧚ๆ⌕᧚ߣߒߡߪࠪ࡝ࠞࠥ࡞㧘ᵴᕈ὇㧘࠯ࠝ࡜ࠗ࠻ߥߤ߇૶ࠊ
ࠇࠆ㧚৻ᣇ㧘಄ᇦߣߒߡߪࠪ࡝ࠞࠥ࡞ߦߪ᳓߇㧘ᵴᕈ὇ߦߪࡔ࠲ࡁ࡯࡞߇૶ࠊࠇࠆ㧚ࠪ࡝ࠞࠥ࡞ߪᲧセ⊛ૐ᷷㧔80͠એਅ㧕ߢๆ⣕⌕ߔࠆߚ߼㧘ૐ᷷ឃᾲ೑
↪ߦㆡߒߚ᧚ᢱߢ޽ࠆ㧚વᾲ 2006 ᐕ 1 ᦬- 45 -(a) ๆ⌕ࡊࡠ࠮ࠬ    (b) ⣕⌕ࡊࡠ࠮ࠬ࿑ 1 ๆ⌕಄ಓࠨࠗࠢ࡞ߩേ૞ ࿑㧝ߦၮᧄ⊛ߥേ૞ේℂࠍ␜ߔ㧚ๆ⌕಄ಓᯏߪ⫳⊒ེ㧔Eva㧕㧘ๆ⣕⌕෻ᔕེ㧔Ads/Des㧕㧘ಝ❗ེ㧔Cond㧕߆ࠄ᭴ᚑߐࠇࠆ㧚ࠪ࡝ࠞࠥ࡞ᮏࠍ಄ළߔࠆߎߣߦࠃ
ߞߡ಄ᇦ⫳᳇߇ๆ⌕ߐࠇࠆ㧚ߘߩ㓙㧘⫳⊒ེߢẜᾲࠍᅓ߁ߚ߼಄ᾲ߇↢ߓࠆ㧚ߘߩᓟ㧘ࠪ࡝ࠞࠥ࡞ᮏࠍ
ടᾲߔࠆߣ಄ᇦߪ⣕⌕ߐࠇ㧘⫳᳇ߪಝ❗ེߦ⒖ⴕߒ
ߡᶧൻߐࠇࠆ㧚ߎࠇࠍߊࠅ㄰ߔߎߣߦࠃߞߡ಄ළല
ᨐࠍ⊒↢ߐߖࠆ㧚 ߎߩ᭽ሶࠍ࿑␜ߒߚ߽ߩ߇࿑㧞ߦ␜ߔ࠺ࡘ࡯࡝ࡦ
ࠣ✢࿑ߢ޽ࠆ㧚ᮮゲߪࠪ࡝ࠞࠥ࡞ߩ᷷ᐲ㧘❑ゲߪ㘻๺᳓⫳᳇࿶ࠍ⴫ߒ㧘ᢳ߼ߩᢳ✢ߪๆ⌕╬Ớᐲ✢ࠍ␜ߔ㧚ฝ஥ߩ྾ⷺᒻߪࠪ࡝ࠞࠥ࡞߇᳓⫳᳇ࠍๆ߁⁁ᘒ㧔ૐ࿶ߢỚᐲ߇㜞ߊߥࠆ㧕ߣฯߊ⁁ᘒ㧔㜞࿶ߢỚᐲ

࿑ 2 ࠺ࡘ࡯࡝ࡦࠣ✢࿑ߦ⴫ߒߚๆ⌕ࠨࠗࠢ࡞

J. HTSJ, Vol. 45, No. 190

․㓸㧦ๆ⌕ߩ਎⇇̆ࡒࠢࡠ߆ࠄࡑࠢࡠ㧘ߘߒߡࠪࠬ࠹ࡓ̆

߇ૐߊߥࠆ㧕ߩ㑆ࠍᤨ⸘࿁ࠅߦᄌൻߔࠆ᭽ሶࠍ␜ߒ
ߡ޿ࠆ㧚৻ᣇ㧘Ꮐ஥ߩ⋥✢ߪ᳓ 100%ߩ⁁ᘒߢ޽ࠅ㧘಄ᇦ⫳᳇߇ಝ❗ߒߡ⫳⊒ེߦᚯࠆᎿ⒟ࠍ⴫ߒߡ޿ࠆ㧚྾ⷺᒻߩ৻⇟ฝ஥߇ౣ↢᷷ᐲ㧘Ꮐ஥߇಄ළ᳓᷷ᐲ㧘⋥✢ߩᏀ஥ߩ┵ὐ߇⫳⊒᷷ᐲ㧘ฝ஥ߩ┵ὐ߇ಝ❗᷷ᐲߦኻᔕߔࠆ㧚྾ⷺᒻߩᮮ᏷߇ๆ⌕᧚ߦๆ⌕ߐࠇࠆ಄ᇦỚᐲߩᏅࠍ␜ߒߡ߅ࠅ㧘಄ಓ಴ജߦ⋥ធߟߥ߇ࠆᜰᮡߢ޽ࠆ㧚 නᲑဳๆ⌕಄ಓࠨࠗࠢ࡞ ೨ㅀߩᣇᴺߢߪ৻ࠨࠗࠢ࡞ߩ㑆ߦඨಽߩᤨ㑆ߒ߆಄ᾲ߇⊒↢ߢ߈ߥ޿ߚ߼㧘ࡃ࠶࠴ㆇォࠍⴕߞߡᏱᤨ
಄ළ⢻ജࠍ⛽ᜬߔࠆࠃ߁㧘ๆ⣕⌕෻ᔕེࠍ 2 ၮ᦭ߒ㧘ඨ๟ᦼ૏⋧ࠍߕࠄߖߡ੤੕ߦๆ⌕෻ᔕߣ⣕⌕෻ᔕࠍⴕ߁ࠃ߁ߦㆇォߐࠇࠆ㧚ๆ⌕಄ಓᯏߩၮᧄ᭴ᚑࠍ࿑
㧟ߦ␜ߔ㧚ߎߩࠨࠗࠢ࡞േ૞ߪᰴߩㅢࠅߢ޽ࠆ㧚 Ԙ ⫳⊒ེߣ৻ᣇߩࠪ࡝ࠞࠥ࡞ᮏ߇ធ⛯ߐࠇ㧘⫳᳇߇ๆ⌕ߐࠇࠆ㧔ๆ⌕ེ㧕㧚ઁᣇߩࠪ࡝ࠞࠥ࡞ᮏߪಝ
❗ེߣធ⛯ߐࠇ㧘ࠪ࡝ࠞࠥ࡞߇ടᾲߐࠇࠆߎߣߦࠃ
ߞߡ⫳᳇ࠍ᡼಴ߒ㧘ಝ❗ེ߳⒖േߔࠆ㧔⣕⌕ེ㧕㧚 ԙ ⫳⊒ེ㧘ಝ❗ེߣߩ㑆ߦ޽ࠆࡃ࡞ࡉ߇㐽ߓࠄࠇ㧘㜞᷷ߩ⣕⌕ེߪ಄ළߐࠇࠆ৻ᣇ㧘ૐ᷷ߩๆ⌕ེߪടᾲߐࠇࠆ㧚ߎߩᎿ⒟ߪᰴߩๆ⌕࡮⣕⌕ࠍⴕ߁ߚ߼ߩḰ஻Ꮏ⒟ߢ޽ࠆ㧚 Ԛ ⣕⌕ེߛߞߚ෻ᔕེߪ⫳⊒ེߣㅪ⚿ߐࠇ㧘ๆ⌕ེߦᦧࠊࠆ㧚৻ᣇ㧘ๆ⌕ེߛߞߚ෻ᔕེߪಝ❗ེߣㅪ⚿ߐࠇ㧘⣕⌕ེߦᦧࠊߞߡㆇォߐࠇࠆ㧚 ԛ ౣ߮ࡃ࡞ࡉ߇㐽ߓࠄࠇߡḰ஻Ꮏ⒟ߦ౉ࠅ㧘⣕⌕ེߪ಄ළ㧘ๆ⌕ེߪടᾲߐࠇࠆ㧚ߘߩᓟԘߦᚯߞ
ߡࠨࠗࠢ࡞ࠍ➅ࠅ㄰ߔ㧚 ߎߩၮᧄ⊛ߥࠨࠗࠢ࡞ࠍ㧘ᓟߦㅀߴࠆᄙᲑဳࠨࠗ
ࠢ࡞ߦኻᲧߒߡනᲑဳࠨࠗࠢ࡞ߣ๭߱㧚ടᾲ᷷ᐲ 70
ޯ80͠ߢ COP㧔಄ᾲ಴ജ㧛᷷ᾲ౉ജ㧕ߪ 0.6 ⒟ᐲߣ㧘

࿑ 3 නᲑဳๆ⌕಄ಓᯏߩ᭴ᚑ

વᾲ 2006 ᐕ 1 ᦬- 46 -

නല↪ๆ෼಄ಓᯏߣ߶߷ห⒟ᐲߩᄌ឵ല₸ࠍᜬߟ㧚⺖㗴ߪๆ⣕⌕෻ᔕེࠍ 2 ၮᜬߟߚ߼ࠨࠗ࠭߇ᄢ߈޿
ߎߣ㧘ࡃ࠶࠴ㆇォߢ෻ᔕེߩടᾲ࡮಄ළࠍߊࠅ㄰ߔ
ߚ߼㧘㗼ᾲ⊛ߥࠛࡀ࡞ࠡ࡯៊ᄬ߇⊒↢ߔࠆߎߣ߇޽
ߍࠄࠇࠆ㧚ߎߩ៊ᄬߪ COP ࠍᒁ߈ਅߍࠆⷐ࿃ߣߒߡ௛ߊ㧚 ߥ߅㧘ߎߩනᲑဳๆ⌕಄ಓᯏߪᣣᧄߢ໡↪ൻߐࠇߡ߅ࠅ㧘࠺ࠖ࡯࠯࡞ࠛࡦࠫࡦߩࠫࡖࠤ࠶࠻಄ළ᳓ឃ
ᾲ㧔75͠㧕ࠍ೑↪ߒߚ಄ᚱ↪಄᳓ߩ⵾ㅧߥߤߦᔕ↪
ߐࠇߡ޿ࠆ[1]㧚
㧚ๆ⌕಄ಓࠨࠗࠢ࡞ߩૐ᷷ᾲ㚟േൻ ᄙᲑๆ⌕಄ಓᯏ ᾲ㚟േ಄ಓᯏߩᄢ߈ߥᛛⴚ㐿⊒⺖㗴ߩ৻ߟߪ㚟േᾲḮߩૐ᷷ൻߢ޽ࠆ㧚৻⥸⊛ߦૐ᷷ߦߥࠆ߶ߤឃᾲ
߇ᄙ޿ߣ⠨߃ࠄࠇࠆߩߢ㧘ࠃࠅᔕ↪▸࿐߇ᐢ߇ࠆߣ
੍ᗐߐࠇࠆ㧚ࠪ࡝ࠞࠥ࡞ߪᲧセ⊛ૐ᷷ߦะ޿ߡ޿ࠆ
ߚ߼㧘ࠃࠅⅣႺ᷷ᐲߦㄭ޿᷷ᐲၞߢേ૞ߔࠆๆ⌕಄ಓࠨࠗࠢ࡞߇⎇ⓥߐࠇߡ޿ࠆ㧚ౕ૕⊛ߦߪ㧘ๆ⣕⌕෻ᔕེࡍࠕࠍᄙᲑߦⓍߺ㊀ߨࠆߎߣߦࠃߞߡ㧘ᾲḮߩૐ᷷ൻࠍ࿑ࠆߎߣ߇ߢ߈ࠆ㧚࿑㧞ࠃࠅ㧘ടᾲ᷷ᐲ߇ૐਅߔࠆߦߟࠇߡๆ⌕ߩỚᐲ᏷ߪዊߐߊߥࠅ㧘߿߇ߡ಴ജ߇ߣࠇߥߊߥࠆߎߣ߇ࠊ߆ࠆ㧚ߎߩᤨ㧘නᲑဳߩ࠺ࡘ࡯࡝ࡦࠣ✢࿑ߩ྾ⷺᒻࠍਛ㑆࿶ജߢੑߟ
ߦಽഀߒ㧘਄ㇱࠍᏀ஥ߦነߖࠆߎߣߦࠃߞߡ㚟േ᷷ᐲ㧔྾ⷺᒻฝ஥ߩ┵㧕ࠍૐ᷷஥ߦ⒖േߐߖࠆߎߣߦ
ࠃࠅ㧘ૐ᷷ߢ߽಄ᾲ಴ജߩขࠅ಴ߖࠆࠃ߁ߦߢ߈ࠆ㧚ߎࠇ߇࿑㧠(a)ߦ␜ߔ㧞Ბဳࠨࠗࠢ࡞ߢ޽ࠆ㧚ߐࠄߦਃߟߦಽഀߒߚ႐ว߇࿑㧠(b)ߢ޽ࠅ㧘㧟Ბဳࠨࠗࠢ
࡞ߦ⋧ᒰߔࠆ㧚㧟Ბဳߢߪ㧞Ბဳࠃࠅ߽ߐࠄߦ㚟േᾲḮ߇ૐ᷷஥ߦነߞߡ޿ࠆߎߣ߇⷗ߡขࠇࠆ㧚㧞Ბൻߔࠆߎߣߦࠃߞߡ㧘ᾲḮ᷷ᐲࠍ 60ޯ70͠ߦૐਅߐ
ߖࠆߎߣ߇ߢ߈㧘ߐࠄߦ 3 Ბߦߔࠇ߫ 60͠ࠍਅ࿁ࠆ
ឃᾲࠍ૶ߞߡ಄᳓ࠍ⵾ㅧߔࠆߎߣ߇น⢻ߣߥࠆ㧚࿑㧡ߦ㧞Ბဳๆ⌕ࠨࠗࠢ࡞ߩⵝ⟎᭴ᚑࠍ␜ߔ㧚ਅᲑߩ෻ᔕེ߇⫳⊒ེ߆ࠄๆ⌕ߒߚ⫳᳇ߪ㧘ౣ↢Ꮏ⒟ߢ਄
Ბߩ෻ᔕེߦๆ⌕ߐࠇࠆ㧚ߐࠄߦ㧘਄Ბ߆ࠄౣ↢ߐࠇߚ⫳᳇߇ಝ❗ེߢᶧൻߐࠇ㧘⫳⊒ེߦᚯߞߡࠨࠗ
ࠢ࡞ࠍ➅ࠅ㄰ߔ㧚 ᄙᲑߦߔࠆ߶ߤ෻ᔕེߩᢙ߇ᄙߊߥࠅ㧘㗼ᾲࡠࠬ߇Ⴧടߔࠆߚ߼ല₸߇ૐਅߔࠆߣหᤨߦኈⓍ߇ᄢ߈ߊߥࠆ㔍ὐ߇޽ࠆ㧚ᄙᲑൻߦߒߚ߇ߞߡ෻ᔕེߩᢙ
߇Ⴧ߃ࠆߚ߼㧘ࠦࡦࡄࠢ࠻ൻ߇ᄢ߈ߥ⺖㗴ߢ޽ࠆ㧚 ࿑㧢ߦߪታ㛎ߦࠃߞߡᓧࠄࠇߚනᲑဳ㧘㧞Ბဳ㧘

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(a) 㧞Ბဳࠨࠗࠢ࡞

࿑ 5 㧞Ბဳๆ⌕಄ಓᯏߩ᭴ᚑ(b) 㧟Ბဳࠨࠗࠢ࡞
࿑ 4 ᄙᲑဳๆ⌕಄ಓࠨࠗࠢ࡞✢࿑㧟Ბဳߦ߅ߌࠆᾲḮ᷷ᐲߦኻߔࠆ಄ಓ಴ജ SCP㧔ๆ⌕᧚㊀㊂޽ߚࠅߩ಄ಓ಴ജ㧕ߩᲧセࠍ␜ߔ[2]㧚Ბᢙߦࠃߞߡๆ⌕᧚૶↪㊂߇⇣ߥࠆߚ߼㧘ߘߩ㊀㊂ߢⷙᩰൻߒߡ޿ࠆ㧚ߥ߅㧘಄᳓౉ญ᷷ᐲࠍ 14͠㧘಴ญ᷷
ᐲࠍ 9͠৻ቯߩ᧦ઙߣߒߡ޿ࠆ㧚ᾲḮ᷷ᐲ߇ૐ᷷ߦ
ߥࠆߦߒߚ߇ߞߡ޿ߕࠇߩࠨࠗࠢ࡞߽಄ಓ⢻ജ߇⋥✢⊛ߦૐਅߔࠆ㧚ߎߩ⚿ᨐࠃࠅ㧘නᲑဳߪ 70͠એ਄ߢ㧘㧞Ბဳߪ 55͠ޯ70͠ߢ㧘㧟Ბဳߪ 55͠એਅߢఝ
૏ߣߥࠆߎߣ߇ࠊ߆ࠆ㧚COP ߦߟ޿ߡ߽ฦࠨࠗࠢ࡞
ߩఝ૏ߥ᧦ઙߪ߶߷ห᭽ߩ᷷ᐲ▸࿐ߣߥࠆ㧚ߚߛߒ㧘
COP ߩᡷༀߪᾲ᷷ᐲ߇਄߇ࠆߦߟࠇߡ㘻๺ߔࠆ௑ะࠍ␜ߔ㧚 ࡂࠗࡉ࡝࠶࠼ๆ⌕಄ಓᯏ නᲑဳߩ߹߹ߢ㚟േᾲḮ᷷ᐲࠍਅߍࠆ⹜ߺߣߒߡ㧘વᾲ 2006 ᐕ 1 ᦬- 47 -

࿑ 6 නᲑ߅ࠃ߮ᄙᲑࠨࠗࠢ࡞ߩๆ⌕೷లႯ㊂    ޽ߚࠅ಄ಓ಴ജߩᲧセ㧔಄᳓಴ญ 9͠㧕࿶❗ᯏߣ⚵ߺวߖߚࡂࠗࡉ࡝࠶࠼ᣇᑼ߇ࡈࠖ࡯࡞࠼
⹜㛎ߐࠇߡ޿ࠆ[3]㧚㜞⾰ߥࠛࡀ࡞ࠡ࡯ߢ޽ࠆ㔚ജࠍ⧯ᐓട߃ߡ߿ࠆߎߣߦࠃࠅ㧘40͠ߩឃᾲߦࠃߞߡ㚟േߒ㧘಄ᾲࠍขࠅ಴ߔߎߣ߇น⢻ߣߥࠆ㧚ᧄࠨࠗࠢ࡞ߩ࠺ࡘ࡯࡝ࡦࠣ✢࿑ࠍ࿑㧣ߦ␜ߔ㧚40͠࡟ࡌ࡞ߩ
ടᾲߩ႐ว㧘⣕⌕ེ߆ࠄ⊒↢ߒߚ಄ᇦ⫳᳇ࠍಝ❗ߐߖࠆߦߪૐ᷷ߩ಄ළ᳓߇ᔅⷐߦߥࠆ߇㧘ߎߩ⫳᳇ࠍ࿶❗ߒߡ㜞࿶ߦߔࠆߎߣߦࠃߞߡㅢᏱߩⅣႺ᷷ᐲߢಝ❗ࠍน⢻ߣߔࠆ㧚ߔߥࠊߜ㧘ๆ⣕⌕෻ᔕེߣಝ❗
ེߩ㑆ߦ࿶❗ᯏࠍᜬߟߎߣ߇ߎߩࡂࠗࡉ࡝࠶࠼ࠪࠬ

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࿑ 7 ࡂࠗࡉ࡝࠶࠼ဳๆ⌕಄ಓࠨࠗࠢ࡞✢࿑
࠹ࡓߩ․ᓽߢ޽ࠆ㧚ᕈ⢻ߣߒߡߪ㧘࿶❗ᯏ↪㔚ജߩߺࠍ౉ജߣ⠨߃ߚ㧔ౣ↢Ꮏ⒟ߢߩឃᾲ౉ജߪ㒰ᄖߔࠆ㧕ߣ߈ߩ COP ߪ 10 ࠍ㆐ᚑߔࠆߎߣ߇ႎ๔ߐࠇߡ
޿ࠆ㧚㧚ࠕ࠼ࡃࡦࠬ࠻ๆ⌕಄ಓࠨࠗࠢ࡞
 ࡝ࡅ࡯࠻ࠨࠗࠢ࡞ නᲑဳๆ⌕಄ಓࠨࠗࠢ࡞ߢߪๆ⌕㧛⣕⌕Ꮏ⒟⚳ੌᓟߦടᾲ㧛಄ළ߇ߥߐࠇ㧘ᰴߩ⣕⌕㧛ๆ⌕Ꮏ⒟ߦะ
ߌߡ෻ᔕེߩ᷷ᐲࠍ⺞ᢛߔࠆ㧚ๆ⌕㧛⣕⌕Ꮏ⒟߇⚳ੌߒߚߣ߈㧘ๆ⌕ེߪૐ࿶⁁ᘒߦ޽ࠅ㧘⣕⌕ེߪ㜞࿶⁁ᘒߦ޽ࠆ㧚⫳⊒ེ࡮ಝ❗ེߣߩ㑆ߩࡃ࡞ࡉࠍ㐽ߓ㧞ߟߩ෻ᔕེࠍធ⛯ߔࠆߣ㧘෻ᔕེౝߩ࿶ജ߇ห
ߓߦߥࠆߩߢ㧘ๆ⌕ེ஥ߪ࿶ജ߇਄᣹ߒ㧘⣕⌕ེ஥ߪ࿶ജ߇ૐਅߔࠆ㧚ߔࠆߣ㧘࠺ࡘ࡯࡝ࡦࠣ✢࿑߆ࠄࠊ߆ࠆࠃ߁ߦ㧘᷷ᐲ৻ቯߢ࿶ജ߇਄߇ࠇ߫ๆ⌕㊂߇
Ⴧടߒ㧘࿶ജ߇ਅ߇ࠇ߫ๆ⌕㊂ߪᷫዋߔࠆ㧚ߔߥࠊߜ㧘⣕⌕ེౝߩๆ⌕᧚ߪࠃࠅ⣕⌕߇ଦㅴߐࠇ㧘ߘߩ಄ᇦ⫳᳇ߪๆ⌕ེ஥ߦ⒖േߒߡๆ⌕ߐࠇࠆߎߣߦߥ
ࠆ㧚ߒߚ߇ߞߡ㧘ๆ⣕⌕ߩỚᐲ᏷߇᜛ᄢߔࠆ⚿ᨐ㧘಄ಓ಴ജ߇Ⴧᒝߐࠇࠆ㧚 ߎߩࡊࡠ࠮ࠬࠍ࿑␜ߒߚ߽ߩ߇࿑ 8 ߢ޽ࠆ㧔ߚߛߒ㧘ᮨᑼ⊛ߦ෻ᔕེ㑆ࠍធ⛯ߔࠆ೨ᓟߢ಄ළ㧛ടᾲߩḰ஻Ꮏ⒟ࠍ฽߻ࠃ߁ߦ⴫ߒߡ޿ࠆ㧕㧚ߎߩ✢࿑ࠃࠅ
ᧄࠨࠗࠢ࡞ߪනᲑဳߩࠪࠬ࠹ࡓ᭴ᚑߢ޽ࠅߥ߇ࠄ㧘ᡆૃ⊛ߦ㧞Ბဳࠨࠗࠢ࡞ߣหߓࠃ߁ߥ⚻〝ࠍឬ޿ߡ޿ࠆߎߣ߇ࠊ߆ࠆ㧚㧞Ბဳࠨࠗࠢ࡞ߪ਄ਅੑߟߩࠨ
ࠗࠢ࡞߇ಽ㔌ߒߡ޿ࠆ߇㧘ᧄࠨࠗࠢ࡞ߢߪ⋥೉ߦߟߥ߇ߞߚᒻᘒࠍߒߡ޿ࠆὐߦ㆑޿߇޽ࠆ㧚ࠨࠗࠢ࡞ߩ㚟േᾲḮ᷷ᐲߪ✢࿑ߩᦨ߽ฝ஥ߩ┵ὐ߇ⷙቯߒߡ

વᾲ 2006 ᐕ 1 ᦬- 48 -

࿑ 8 ࡝ࡅ࡯࠻ࠨࠗࠢ࡞ߩ࠺ࡘ࡯࡝ࡦࠣ✢࿑

࿑ 9 ࡝ࡅ࡯࠻ࠨࠗࠢ࡞ߣᣢሽࠨࠗࠢ࡞ߣߩᲧセ޿ࠆߩߢ㧘ᧄࠨࠗࠢ࡞ߢ߽㧞Ბဳߣหߓࠃ߁ߥૐ޿
ᾲḮ᷷ᐲߦ߅޿ߡ಄ಓ಴ജࠍขࠅ಴ߔߎߣ߇ߢ߈ࠆ㧚ߎߩࠨࠗࠢ࡞ࠍ࡝ࡅ࡯࠻ࠨࠗࠢ࡞ߣ๭ࠎߢ޿ࠆ㧚 ߎߩࠨࠗࠢ࡞ߪࠨࠗࠢ࡞ᤨ㑆ࠍ㐳ߊߣࠇ߫㧞Ბဳߣหߓࠃ߁ߦ௛ߊ৻ᣇ㧘ࠨࠗࠢ࡞ᤨ㑆ࠍ⍴ߊߣࠇ߫නᲑဳࠨࠗࠢ࡞ߦㄭߠ޿ߡ޿ߊߩߢ㧘නᲑဳߩࠃ߁
ߦㆇ↪ߢ߈ࠆ․ᓽࠍᜬߟ㧚ࠨࠗࠢ࡞ࠪࡒࡘ࡟࡯࡚ࠪ
ࡦߦࠃߞߡᓧࠄࠇߚ㚟േᾲḮ᷷ᐲߦኻߔࠆᕈ⢻ߩᲧセࠍ࿑㧥ߦ␜ߒߚ[4]㧚ߚߛߒ㧘ࠨࠗࠢ࡞ᤨ㑆ࠍ㐳ߊߔࠆߣ಄ಓ಴ജ߇ߣࠇߥ޿ᤨ㑆Ꮺ߇㐳ߊߥࠆߚ߼㧘ㅪ⛯⊛ߦ಄ಓ಴ജࠍ⛽ᜬߔࠆߚ߼ߦߪ߽߁৻⚵ߩๆ

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․㓸㧦ๆ⌕ߩ਎⇇̆ࡒࠢࡠ߆ࠄࡑࠢࡠ㧘ߘߒߡࠪࠬ࠹ࡓ̆

⣕⌕ེࠍᜬߜ㧘ࡃ࠶࠴ㆇォߔࠆߎߣ߇ᔅⷐߣߥࠆ㧚 ࡝ࡅ࡯࠻ࠨࠗࠢ࡞ߢߪ㧘ࠨࠗࠢ࡞ᤨ㑆ࠍ⺞▵ߔࠆߎߣߦࠃߞߡ৻บߢᾲḮ᷷ᐲߦᔕߓߚㆇォ߇น⢻ߣߥࠅ㧘᭽‫ߥޘ‬᷷ᐲၞߩឃᾲḮ߿ᤨ㑆⊛ߦᄌേߔࠆឃ
ᾲḮࠍ᦭ല೑↪ߔࠆߩߦㆡߒߡ޿ࠆߣ⠨߃ࠄࠇࠆ㧚 ࡑ࡞࠴ࡌ࠶࠼ๆ⌕಄ಓᯏ ࡑ࡞࠴ࡌ࠶࠼ဳߣߪๆ⣕⌕෻ᔕེࠍ㧠ၮߥ޿ߒ㧢ၮ᦭ߔࠆනᲑဳๆ⌕಄ಓᯏߢ޽ࠆ㧚ㅢᏱߩනᲑဳߢ
ߪ෻ᔕེߩ૏⋧߇ 180 ᐲߕࠇߡㆇォߐࠇߡ޿ࠆߩߦ
ኻߒ㧘ࡑ࡞࠴ࡌ࠶࠼㧔㧠ၮ㧕ဳߢߪ 90 ᐲߕࠇߡㆇォߐࠇࠆ㧚ߐࠄߦ㧘వⴕߔࠆ෻ᔕེߩᾲḮ᳓޽ࠆ޿ߪ
಄ළ᳓ࠍㅊ㓐ߔࠆ෻ᔕེ߇ࠞࠬࠤ࡯࠼⊛ߦ೑↪ߔࠆ
ὐߦ․ᓽ߇޽ࠆ㧚ߔߥࠊߜ㧘⣕⌕Ꮏ⒟߆ࠄឃ಴ߐࠇ
ࠆ⧯ᐓ᷷ᐲ߇ૐਅߒߚ᷷᳓ࠍḰ஻Ꮏ⒟ߩടᾲ߅ࠃ߮
⣕⌕Ꮏ⒟ೋᦼߦ೑↪ߔࠆ㧚߹ߚ㧘ๆ⌕Ꮏ⒟߆ࠄឃ಴
ߐࠇࠆ⧯ᐓ᷷ᐲ߇਄᣹ߒߚ಄ළ᳓ࠍḰ஻Ꮏ⒟ߩ಄ළ
߅ࠃ߮ๆ⌕Ꮏ⒟ೋᦼߦ೑↪ߔࠆ㧚 ߎߩ૏⋧Ꮕㆇォߦࠃࠅ㧘ࡑ࡞࠴ࡌ࠶࠼ဳߢߪᏱߦ
޿ߕࠇ߆ߩ෻ᔕེ߇⫳⊒ེߣߟߥ߇ߞߡ޿ࠆߚ߼಄
ᾲ಴ജ߇ㅜಾࠇࠆߎߣߥߊ㧘ࡃ࠶࠴ㆇォߢ޽ࠅߥ߇
ࠄ಄ᾲ಴ജߩᄌേ߇ᛥ೙ߐࠇࠆ․ᓽࠍᜬߟ㧔ㅢᏱߩනᲑဳࠨࠗࠢ࡞ߢߪḰ஻Ꮏ⒟ߢ಴ജ߇಴ߥ޿㧕㧚 ࡑ࡞࠴ࡌ࠶࠼㧔㧠ၮ㧕ဳߩታ㛎⚿ᨐࠍ࿑ 10 ߦ␜ߔ[5]㧚ࠨࠗࠢ࡞ᤨ㑆ࠍᄌൻߐߖߚ႐วߩ⚿ᨐࠍ⷗ࠆߣ㧘
COP ߦߟ޿ߡߪᓥ᧪ߩනᲑဳߣࡑ࡞࠴ࡌ࠶࠼ဳߪ
᭎ߨห⒟ᐲߣߥߞߡ޿ࠆ߇㧘಄ಓ⢻ജߢߪࡑ࡞࠴ࡌ
࠶࠼ဳߩᣇ߇਄࿁ߞߡ޿ࠆ㧚․ߦࠨࠗࠢ࡞ᤨ㑆߇⍴޿▸࿐ߦ߅޿ߡᄢ᏷ߥᡷༀ߇⹺߼ࠄࠇࠆ㧚ߘߩℂ↱ߪࠨࠗࠢ࡞ᤨ㑆߇⍴ߊߥࠆߦߟࠇߡߘࠇߦභ߼ࠆḰ
஻Ꮏ⒟ᤨ㑆߇ᄢ߈ߊߥࠅ㧘ᓥ᧪ဳߢߪ಴ജ߇ߣࠇߥ
޿ߎߣߦ⿠࿃ߔࠆ㧚ࡑ࡞࠴ࡌ࠶࠼ൻߔࠆߎߣߦࠃߞ
ߡᏱᤨ಴ജ߇ขࠇࠆߎߣߩലᨐ߇⴫ࠇߡ޿ࠆ㧚㧚߅ࠊࠅߦ
 ᧄⓂߢߪ࿕૕ๆ⌕᧚ࠍ೑↪ߒߚ಄ಓᯏ㧔ࡅ࡯࠻ࡐࡦࡊ㧕ߣߒߡๆ⌕಄ಓᯏߦߟ޿ߡ⚫੺ߒߚ㧚ๆ⌕಄ಓࠨࠗࠢ࡞ߪૐ᷷ߩᾲߢ㚟േߢ߈ࠆߎߣ߇ᄢ߈ߥ․ᓽߢ޽ࠆ㧚ᾲࠍ೑↪ߔࠆߚ߼ᄐቄᤤ㑆ߩⓨ⺞⽶⩄ߦࠃࠆ㔚ജࠪࠬ࠹ࡓߩࡇ࡯ࠢ⽶⩄ࠍ೥ᷫߔࠆߎߣߦነ
ਈߔࠆߩߺߥࠄߕ㧘ࡅ࡯࠻ࠞࠬࠤ࡯࠺ࠖࡦࠣߩᦨ⚳Ბߣߒߡઁߢߪ૶߃ߥ޿ឃᾲ߆ࠄߐࠄߦ᦭↪ߥࠛࡀ࡞ࠡ࡯ࠍขࠅ಴ߖࠆᛛⴚߢ޽ࠆߎߣࠍᒝ⺞ߒߚ޿㧚

વᾲ 2006 ᐕ 1 ᦬

- 49 -

࿑ 10 ࡑ࡞࠴ࡌ࠶࠼ဳๆ⌕ࠨࠗࠢ࡞ߩ಴ജ․ᕈ
߹ߚ㧘ᄥ㓁ᾲ߿ࡃࠗࠝࡑࠬΆ὾ᾲߥߤߩౣ↢น⢻ࠛࡀ࡞ࠡ࡯߇೑↪ߢ߈ࠆߎߣ߽․ᓽߢ޽ࠆ㧚ᣣᧄ߿ࠕࠫࠕ࿾ၞߦ߅޿ߡⓨ⺞ࠍ⋭ࠛࡀ࡞ࠡ࡯⊛ߦታ⃻ߔࠆߎߣߪ㧘࿾⃿᷷ᥦൻᛥ೙ࠍ⢛᥊ߣߒߡ዁᧪⊛ߥ⺖㗴ߦߥࠆߣ੍ᗐߐࠇࠆ㧚੹ᓟ㧘ๆ⌕಄ಓࠨࠗࠢ࡞ߩᓎ
ഀ߇ᦼᓙߐࠇࠆ㧚ෳ⠨ᢥ₂
[1] ೨ Ꮉ ⵾ ૞ ᚲ ࡎ ࡯ ࡓ ࡍ ࡯ ࠫ ,http://www.mycomj.co.jp/adref/nadoref1.html[2] ⑺Ỉ ᷕ㧘ựᧄ⧐ᓼ㧘⿒ᐔ ੫㧘ᨰᧁቁᄦ㧘಄᳓಴ญ᷷ᐲ৻ቯ᧦ઙߦ߅ߌࠆᄙᲑๆ⌕಄ಓࠨࠗࠢ
࡞ߩ಴ജ․ᕈ㧘ᐔᚑ 17 ᐕᐲᣣᧄ಄ಓⓨ⺞ቇળቇⴚ⻠Ṷળ⻠Ṷ⺰ᢥ㓸 (2005) C110-1~C110-4.
[3] ਛ ㇱ 㔚 ജ ࡎ ࡯ ࡓ ࡍ ࡯ ࠫ 㧘
http://www.chuden.co.jp/press/data/pre2001/pre0220_02.html[4] Uyun Aep Saepul, K.C. Amanul Alam, ⿒ᐔ ੫㧘ựᧄ⧐ᓼ㧘⑺Ỉ ᷕ㧘ᨰᧁቁᄦ㧘࡝ࡅ࡯࠻ੑᲑဳ
ๆ⌕ࠨࠗࠢ࡞ߩᕈ⢻ࠪࡒࡘ࡟࡯࡚ࠪࡦ㧘ᣣᧄᯏ᪾ቇળ╙ 14 ࿁ⅣႺᎿቇ✚วࠪࡦࡐࠫ࠙ࡓ 2004 ⻠Ṷ⺰ᢥ㓸 (2004), 356-359.
[5] Ng, K.C., Chua, H.T., Wang, J.B., Wang, X.L.,
Kashiwagi, T., Akisawa, A., Saha, B.B.,
Experimental Investigation on a Novel Four-bed
Adsorption Chiller, Proceedings of the Asian
Conference on Refrigeration and Air Conditioning
2002, Dec. 4, Kobe, Japan (2002) 371-374.

J. HTSJ, Vol. 45, No. 190

․೎ነⓂ
↲⮮ᅢ㇢వ↢ߏㆮⓂ

‫ޟ‬ᴣ㛛ߩ⑼ቇ㧔㧡㧕‫ޠ‬
Science of Boiling (5)





↲⮮ ᅢ㇢㧔᧲੩ᄢቇฬ⹷ᢎ᝼㧕
Yoshiro KATTO (Professor Emeritus of The University of Tokyo)
᷷ᐲ 100͠ߩ㘻๺᳓߇㧘᷷ᐲ 120͠ߩടᾲ㕙ߦ⸅ࠇ㧡 ᩭᴣ㛛ߩ㒢⇇ߡᴣ㛛ߔࠆᤨ㧘ടᾲ㕙ߣ㘻๺᳓ߣߩ᷷ᐲᏅ߇௖߆
㒢⇇ߣ޿߁߽ߩ
20͠ߒ߆ߥ޿ߩߦ㧘ടᾲ㕙ߩ㕙Ⓧ㧝ᐔᣇࡔ࡯࠻࡞ ߎߩ਎ߩਛߢశߩㅦᐲࠃࠅㅦ޿ㅦᐲߪߥ޿ߣ⸒
޽ߚࠅ⚂ 1100 ࠠࡠࡢ࠶࠻߽ߩᾲ߇᳓஥ߦવࠊࠅ
ࠊࠇ߹ߔ㧚ᓥߞߡశㅦߪㅦᐲߩ㒢⇇ߣ޿߁ߎߣߦ
߹ߔ㧚߹ߚ࿶ജ߇଀߃߫ᄢ᳇࿶ߩ⚂ 73 ୚ߩ㘻๺᳓ߥࠅ߹ߔ߇㧘ߎࠇߪ⥄ὼ⇇߇ߘ߁޿߁㘑ߦ಴᧪ߡ㧔㘻๺᷷ᐲ⚂ 290͠㧕ߩᤨߦߪ㧘೨ߣห⒟ᐲߦㆊ
޿ࠆ߆ࠄߢ޽ߞߡ㧘ߘࠇࠍ⹺߼ࠆઁߥߊ㧘ߥߗశᾲߐࠇߚടᾲ㕙߆ࠄ⚂ 4800 ࠠࡠࡢ࠶࠻ߩᾲ߇વ
ㅦ߇޽ࠄࠁࠆㅦᐲߩߥ߆ߢᦨ㜞ㅦᐲߦߥࠆߩ߆ߣ
ࠊࠅ߹ߔ㧚޿ߞߚ⼏⺰ࠍߒߡߺߡ߽ᗧ๧߇޽ࠅ߹ߖࠎ㧚 ᓥߞߡߎߩࠃ߁ߥᩭᴣ㛛ߩ⁁ᘒߘߩ߹߹ࠍ଻ߜ ৻ᣇߎࠇߣߪ㆑޿㧘⢛᥊ߦ޿ࠈ޿ࠈߩ‛ℂ⊛ේߥ߇ࠄടᾲ㕙ߩ᷷ᐲࠍ޽ߍ㧘ടᾲ㕙߆ࠄવࠊࠆᾲ
࿃߇޽ߞߡ㧘ߘߩߚ߼޽ࠆႺ⇇ߩ೨ᓟߢ⁁ᴫ߇⾰ߩᒝߐࠍߐࠄߦჇߒߡⴕߊߎߣ߇಴᧪ࠇ߫㧘Ყセ⊛ߦᄌߞߡߒ߹߁ߣ޿ߞߚ႐ว߇޿ࠈ޿ࠈ޽ࠅ߹
⊛ૐ޿ടᾲ㕙᷷ᐲߢታߦᄙ㊂ߩᾲࠍવ߃ࠆ੐߇น
ߔ㧚৻଀ߣߒߡ⥶ⓨᯏߦ᥉ㅢ૶ࠊࠇߡ޿ࠆࠫࠚ࠶
⢻ߦߥࠆ╫ߢߔ㧚ߘߎߢߎߣߩᚑุࠍ⏕߆߼ࠆߚ࠻ࠛࡦࠫࡦࠍ⠨߃ߡߺ߹ߒࠂ߁㧚ߎߩࠛࡦࠫࡦߢ
߼㧘ߣࠅ޽߃ߕ◲නߥታ㛎ࠍ߿ߞߡߺ߹ߒࠂ߁㧚ߪ㧘೨ᣇ߆ࠄๆㄟ߻ⓨ᳇ࠍ࿶❗ߔࠆߚ߼ᴛጊߩ⠀ߔߥࠊߜ㧘ኈེౝߩ㘻๺᳓ߩਛߦ㧘㧞ᧄߩ㔚ᭂࠍᩮߩߟ޿ߚゲᵹ࿶❗ᯏ߇ਛߢ߹ࠊߞߡ޿߹ߔ㧚ߘ౉ࠇ࠾ࠢࡠࡓ✢ࠍᒛߞߡ㧘ߘࠇߦᵹߔ㔚ᵹࠍᓢ‫ޘ‬
ߒߡߎߩ⒳ߩ࿶❗ᯏߪ৻⥸ߦ㧘ⓨ᳇ߩᵹ㊂߇චಽߦჇߒߡߺ߹ߔ㧚ߘ߁ߔࠆߣ࠾ࠢࡠࡓ✢ߩ਄ߦᴣ޽ߞߡᱜᏱߦേߊ㗔ၞߣ㧘ᵹ㊂߇ዋߥߊߡỗߒ޿㛛߇ᆎ߹ࠅ㧘ߐࠄߦ㔚ᵹࠍჇߒߡⴕߊߣᴣ㛛߇⋓ᝄേࠍᒁ߈⿠ߎߔ㗔ၞߣࠍᜬߞߡ޿߹ߔ㧚ߘߎߢࠎߦߥߞߡⴕ߈߹ߔ㧚ߒ߆ߒߘࠇߪ૗ᤨ߹ߢ߽⛯ࠛࡦࠫࡦߩࠬ࠲࡯࠻ߩ㓙ߥߤⓨ᳇ᵹ㊂߇ዋߥ޿ᤨ㧘ߊ߽ߩߢߪߥߊ㧘㔚ᵹߩჇടߣ౒ߦ߿߇ߡ޽ࠆߣ
ߎߩᝄേ㗔ၞߦ౉ࠄߥ޿ࠃ߁ߥᎿᄦ߇ߐࠇ㧘ߘࠇߎࠈߢ࠾ࠢࡠࡓ✢߇⓭ὼࡄ࠶ߣ⿒ᾲߒߡ὾ߌಾࠇ
ߦࠃߞߡࠛࡦࠫࡦߪ቟ోߦ૞േߔࠆࠊߌߢߔ߇㧘ߡߒ߹޿߹ߔ㧚ߟ߹ࠅ㧘ߎߩ⿒ᾲ὾៊߇⿠ߎࠆ⋥ߎߩࠃ߁ߦ޽ࠆႺ⇇✢ߩ೨ᓟߢ⁁ᴫ߇߹ࠆߢ㆑ߞ
೨߹ߢߪ㧘㘻๺᷷ᐲߦㄭ޿Ყセ⊛ૐ޿᷷ᐲߢఝࠇ
ߡߒ߹߁ࠃ߁ߥ႐ว㧘⑳ߚߜߪࠃߊ㧘ߘߩႺ⇇ߩߚᴣ㛛ᾲવ㆐ࠍ⛯ߌߡ޿ߚ࠾ࠢࡠࡓ✢߇㧘߶ࠎߩߎߣࠍ৻ᣇߩ㗔ၞߩ㒢⇇ߣ๭߱ߎߣ߇޽ࠅ߹ߔ㧚௖߆㔚ᵹࠍჇߔߣ⓭ὼ㧘ᾲવ㆐ߩഠൻߩߚ߼㕖Ᏹߘߒߡߎࠇ߆ࠄᧄ┨ߢ߅⹤ߒࠃ߁ߣߒߡ޿ࠆᩭᴣ
ߥ㜞᷷ߦߥࠅ⍍ᤨߦ὾ߌಾࠇࠆߣ޿߁഍⊛ߥᄌൻ㛛ߩ㒢⇇߽㧘ߎߩࠃ߁ߥᗧ๧ว޿ߩ߽ߩߥߩߢߔ㧚߇⿠ߎࠆࠊߌߢߔ㧚 ߥ߅࠾ࠢࡠࡓ✢ߩઍࠅߦ㧘⊕㊄✢ࠍ૶߁ߣ㧘ห◲නߥታ㛎
ߓߊ㜞᷷ߦߥࠅ߹ߔ߽ߩߩ⠴ᾲᕈ߇޽ࠆߩߢ὾៊ ߐߡ‛૕ߩ⴫㕙ߣ㧘ߘࠇߦធߒߡᵹࠇࠆᵹ૕ߣ
ߛߌߪㆱߌࠄࠇ߹ߔ㧚ߒ߆ߒߎߩ႐ว㧘߶ߣࠎߤߩ㑆ߦ㧘ߥࠆߴߊዋߥ޿᷷ᐲᏅߢ㧘ߥࠆߴߊᄙ㊂⊕ᾲ⁁ᘒߦ߹ߢ㜞᷷ߦߥߞߚ⊕㊄✢ߩ߹ࠊࠅో㕙ߩᾲࠍ੤឵಴᧪ࠆ⁁ᘒ߶ߤ㧘ᾲવ㆐ߩᕈ⢻߇⦟޿ࠍ⭯޿⫳᳇⤑߇൮߻ߣ޿߁㧘ᩭᴣ㛛ߣߪ߹ࠆߢ⇣ߣ⸒߁ߎߣߦߥࠅ߹ߔ㧚ߘߒߡ㧘ߎࠇߦߟ޿ߡᩭ
⾰ߥᴣ㛛⁁ᘒ㧔ᰴߩ㧢┨ߢᛒ޿߹ߔ㧕ߦߥߞߡߒ
ᴣ㛛㧘․ߦ‫ޟ‬ᒝ޿ᩭᴣ㛛‫ߪޠ‬㧘㛳ߊ߶ߤఝࠇߚᾲ
߹޿߹ߔ㧚
વ㆐ᕈ⢻ࠍᜬߟ߽ߩߥߩߢߔ㧚଀߃߫㧘ᄢ᳇࿶㧘

વᾲ 2006 ᐕ 1 ᦬

- 50 -J. HTSJ, Vol. 45, No. 190

․೎ነⓂ

㒢⇇ᾲᵹ᧤ߩ⃻⽎ ߣ߽޽ࠇ⑳ߚߜߪ޿߹㧘◲නߥታ㛎ߦࠃߞߡᩭ
ᴣ㛛ߩ㗔ၞߦ㒢⇇߇޽ࠆߎߣࠍ⍮ࠅ߹ߒߚ߇㧘ታߪ߽ߞߣᄢ߈ߥടᾲ㕙ࠍ૶ߞߚ㧘޽ࠆ޿ߪ߽ߞߣ
ⶄ㔀ߥታ㛎ߢ߽੐ᖱߪ߹ߞߚߊห᭽ߥߩߢߔ㧚‫ޟ‬ᒝ޿ᩭᴣ㛛‫ߡ߼ࠊ߈ߦ⥸৻ߪޠ‬ᾲવ㆐ᕈ⢻߇ఝࠇߡ޿ࠆߛߌߦ㧘ߎࠇߪ㕖Ᏹߦᱷᔨߥߎߣߢߔ㧚߹ߚ㧘ߘ߁޿߁ఝࠇߚᾲવ㆐⁁ᘒ߇ᄖ⷗⊛ߦߪ૗ߩ೨⸅ࠇ߽ߥߊ⓭ὼᶖṌߒߡߒ߹߁ߎߣ⥄૕㧘࿾㔡߿ྃἫ߇⓭ὼ⿠ߎࠆߩߦૃߡ㧘⑳ߚߜߦߪ૗ߣ
߽ㅅᖺߥߎߣߢ޽ࠅ߹ߔ ߒ߆ߒ㧘ߘࠎߥੱ㑆⊛ᗵᖱߪߐߡ߅߈㧘ߎߩᩭᴣ㛛ߩ਄㒢ߩᾲᵹ᧤㧔න૏㕙Ⓧ㧘න૏ᤨ㑆޽ߚࠅ
಴ࠆᾲ㊂㧕ߩߎߣࠍ৻⥸ߦ‫ޟ‬㒢⇇ᾲᵹ᧤‫ߣޠ‬๭߮㧘߹ߚߎߩ਄㒢߇⃻ࠇࠆ⃻⽎ࠍᜰߒߡ‫ޟ‬㒢⇇ᾲᵹ᧤⃻⽎‫ߔ߹޿⸒ߣޠ‬㧚߹ߚടᾲ㕙ߩᾲᵹ᧤߇㒢⇇ࠍ⿥߃ࠆᤨ㧘೨㗄ߩ࠾ࠢࡠࡓ✢ߩ଀ߢ߽⷗ߚࠃ߁ߦ
⿒ᾲ὾៊ࠍ⿠ߎߔߎߣ߇ᄙ޿ߩߢ㧘‫࠙ࠕࡦ࡯ࡃޟ‬࠻ᾲᵹ᧤‫ޠ‬㧘‫૶߽⪲⸒ߩߤߥޠ⽎⃻࠻࠙ࠕࡦ࡯ࡃޟ‬ࠊࠇ߹ߔ㧚ߎߎߦࡃ࡯ࡦࠕ࠙࠻ߣߪ㧘὾߈ߟߊߔ
ߣ߆㧘Ά߃ߟ߈ࠆߣ޿߁ᗧ๧ߢߔ㧚߹ߚ㧘ߎࠇߦᄙዋૃߚᗵߓߩ⸒⪲ߢߔ߇㧘ᣥ࠰ㅪߢߪ‫ޟ‬ᴣ㛛ෂᯏ‫ߔ߹ࠅ޽߽ߣߎ߁޿ߣޠ‬㧚ߚߛ㧘‫ޠ࠻࠙ࠕࡦ࡯ࡃޟ‬ߪ⃻⽎ߩේ࿃ߢߥߊ⚿ᨐߢ޽ࠅ㧘߹ߚ⊕㊄✢ߩ႐วߩࠃ߁ߦ὾៊ߩ⿠ߎࠄߥ޿႐ว߽޽ࠆߩߢߔ߆
ࠄ㧘ਇㆡᒰߥ↪⺆ߛߣ޿߁ੱ߽޽ࠅ㧘ᦨㄭߪ㒢⇇ᾲᵹ᧤㧔critical heat flux㧕ߩ↪⺆ߩᣇ߇਎⇇⊛ߦᐢߊ⹺߼ࠄࠇߡ᧪ߡ޿߹ߔ㧚 ߐߡ㧘ߎߩ㒢⇇ᾲᵹ᧤ߪ㧘ߔߢߦ  ┨ߢ߽⸅ࠇߚࠃ߁ߦ㧘ᦨㄭߪේሶἹ߿⒳‫࡯ࠡ࡞ࡀࠛߩޘ‬ᯏེߘߩઁ㧘వ┵ᛛⴚⵝ⟎ߩ቟ోᕈߦ߽㑐ଥߔࠆ㕖Ᏹ
ߦ㊀ⷐߥ⃻⽎ߦߥߞߡ޿߹ߔ߇㧘ታߪ 1934 ᐕ㧘᧲ർᄢቇߩᛮጊ྾㇢ᢎ᝼㧔1896㧙1983㧕߇㧘⦁⥾ߩࡏࠗ࡜࡯ߩዊဳൻࠍ⋡⊛ߣߒߡ㧘࠾ࠢࡠࡓ✢߿⊕㊄✢ߩᴣ㛛ታ㛎߆ࠄ਎⇇ߦߐ߈߇ߌߡ⊒⷗ߒߚ⃻⽎ߢߔ㧚߹ߚ㧘ㅢᏱߩ⁁ᴫਅߩ㘻๺ࡊ࡯࡞ᴣ㛛ߩ㒢⇇ᾲᵹ᧤ qc ߩ୯ߪ㧘ࡠࠪࠕߩࠢ࠲࠹࡜࡯࠯ᢎ᝼
㧔1914㧙1986㧕߇ 1950 ᐕ㧘ᓐ߇߹ߛࡐ࡞࠭ࡁࡈ⎇ⓥᚲߦ޿ߚᤨߦឭ಴ߒߚᰴߩᑼߢᄢ૕੍᷹಴᧪ࠆ
ߎߣ߇⍮ࠄࠇߡ޿߹ߔ㧚
qc
UV h fgª U  UV Vg º
0.13  0.19 « L
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UV 2
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વᾲ 2006 ᐕ 1 ᦬ߎߩᑼߪ㧘㒢⇇ᾲᵹ᧤ߩ⃻⽎߇㧘ᕟࠄߊ᳇૕ߣᶧ
૕ߩ౒ሽߔࠆᵹࠇߩജቇ⊛ߥ᧦ઙ߆ࠄ⿠ߎࠆߣ޿
߁ផቯߦၮߠ޿ߡ㧘ߎߩ᧦ઙߦ㑐ଥߒߘ߁ߥ޿ࠈ
޿ࠈߩ‛ℂ⊛࿃ሶࠍ⠨߃㧘ታ㛎࠺࡯࠲ߩᢛℂ߆ࠄ⚻㛎⊛ߦ᳞߼ࠄࠇߚ߽ߩߢߔ㧚ߒ߆ߒ㧘ߐࠄߦㅴࠎߢ㧘ߎߩ㒢⇇⃻⽎߇ౕ૕⊛ߦߤࠎߥ‛ℂ⊛઀⚵ߺߢ⊒↢ߔࠆߩ߆㧘ߘߩ⻘⸃߈ߣߥࠆߣ㓐ಽ߿ߞ߆޿ߥ໧㗴ߦߥࠅ߹ߔ߇㧘ᧄ┨ߢߪ৻ᔕ㧘ᾲኈ㊂߇චಽߦ޽ࠆ᥉ㅢߩടᾲო㧔ෘߐ߇ 0.5 ࡒ࡝ࡔ࡯࠻࡞⒟ᐲએ਄޽ࠆ㊄ዻო㧕ߩ႐วߦ㒢ߞߡ㧘ᩭᴣ㛛ߩ㒢⇇໧㗴ࠍ⠨߃ߡߺࠆߎߣߦߒ߹ߒࠂ߁㧔߽ߒടᾲოߩෘߐࠍߎࠇࠃࠅ⭯ߊߔࠆߣ㧘㒢⇇ᾲᵹ᧤ߩ୯߇᥉ㅢࠃࠅዊߐߊߥࠆߣ޿߁㧘߆ߥࠅ㕙ୟߥ໧㗴߇↢ߓ߹ߔ㧕㧚‫ޟ‬᳇ᶧ⋧ኻㅦᐲߩ㒢⇇‫࡞࠺ࡕޠ‬ ೨㗄ߢ㧘ᩭᴣ㛛ߩ㒢⇇ࠍᜰߔ↪⺆ߦ޿ࠈ޿ࠈ޽
ࠆߎߣࠍ߅⹤ߒ߹ߒߚ߇㧘⑼ቇ਄ߩ↪⺆ߦߟ޿ߡߎࠎߥ੐ᘒࠍ↢ߓࠆߩߪ㧘ߎߩ⃻⽎ߦኻߒߡੱ‫ޘ‬ߩᜬߟࠗࡔ࡯ࠫߩ㑆ߦ㧘߆ߥࠅߩಽᢔ߇޽ࠆߚ߼
ߢߒࠂ߁㧚߹ߚ੐ታ㧘ߎߩ㒢⇇⃻⽎߇ߤࠎߥࡔࠞ
࠾࠭ࡓߢ಴⃻ߔࠆߩ߆㧘ߘߩ⊒↢ᯏ᭴ߦߟ޿ߡ߽㧘ᓥ᧪޿ࠈ޿ࠈߩ⠨߃߇ឭ಴ߐࠇߡ᧪߹ߒߚ㧚ߌࠇߤ߽㧘ߘࠇࠄࠍዋߒᄢ⢙ߦಽ㘃ߒߡߺࠆߣੑߟߩ
࠲ࠗࡊߦᄢ೎಴᧪ߡ㧘߹ߕߘߩ৻ߟࠍߎߎߢ⚫੺ߔࠆߎߣߦ޿ߚߒ߹ߔ㧚 ߐߡ㧘߆ߥࠅએ೨㧘㒢⇇ᾲᵹ᧤ߩࡔࠞ࠾࠭ࡓߩ
⎇ⓥ߇ᆎ߹ߞߚ㗃ߪ㧘߹ߛᴣ㛛ߩ⁁ᴫ߿᭽⋧⥄૕㧘․ߦ‫ޟ‬ᒝ޿ᩭᴣ㛛‫ߩޠ‬᭽⋧߇චಽߦᛠីߐࠇߡ޿
ߚࠊߌߢߪߥߊ㧘⑳ߚߜߦりㄭߥ‫ޟ‬ᒙ޿ᩭᴣ㛛‫ޠ‬ߩⷰኤࠍਥ૕ߦᗐቯߐࠇߚࡔࠞ࠾࠭ࡓ߇⠨߃ࠄࠇߡ޿߹ߒߚ㧚଀߃߫ᾲᵹ᧤߇Ⴧߔߦߟࠇߡടᾲ㕙ㄭߊߩᶧਛߦዊߐߥ᳇ᵃ߇৻᧰ߦలḩߒߡ᧪ߡ㧘ߘࠇએ਄߽ߪ߿᳇ᵃ߇౉ࠇߥߊߥߞߚᤨߦ㒢⇇ᾲᵹ᧤ߦߥࠆߩߛߣ⸒ߞߚ㧘⚛ᧉߥ⠨߃ᣇߥߤ߇ߘ
ࠇߦ౉ࠅ߹ߒࠂ߁㧚ߒ߆ߒᴣ㛛ߩ⎇ⓥ߇ㅴ߻ߦߟ
ࠇߡ㧘߿߇ߡടᾲ㕙਄ߦ⊒↢ߔࠆ⫳᳇߇ᶧ૕ࠍㅢ
ߒߡ㔌⣕ߒߡⴕߊࡔࠞ࠾࠭ࡓߦߟ޿ߡ㧘߽߁ዋߒ⃻ታ⊛ߥࡕ࠺࡞߇⠨߃ࠄࠇࠆࠃ߁ߦߥࠅ߹ߔ㧚 ޿߹㧘᧦ઙࠍߪߞ߈ࠅߐߖࠆߚ߼㧘ᐢ޿᳓ᐔട
ᾲ㕙ߩ਄ߦ↢ߓߡ޿ࠆᒝ޿ᩭᴣ㛛ࠍ⠨߃ߡߺ߹ߒ
ࠂ߁㧚ᒝ޿ᩭᴣ㛛ߢߔ߆ࠄ㧘ടᾲ㕙߆ࠄߩᾲ߇ߔ
ߴߡ㧘ߘߎߢ⫳᳇ߩ⊒↢ߦ૶ࠊࠇߡߒ߹߁ߣ⠨߃ߡࠃ޿ࠊߌߢߔ߇㧘ߎߩ⊒↢⫳᳇ߪᶧ૕ࠍ᛼ߒಽ

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- 51 -J. HTSJ, Vol. 45, No. 190

․೎ነⓂ

ߌߡ਄ᣇߦㅏߍࠆ৻ᣇ㧘ᴣ㛛߇⛮⛯ߔࠆߚ߼ߦߪ㧘ߘߩ⫳᳇ߣหߓߛߌߩ⾰㊂ߩᶧ૕߇ടᾲ㕙ߩᣇ߳ᔅߕଏ⛎ߐࠇߡ޿ࠆ╫ߢߔ㧚ߟ߹ࠅ㧘⫳᳇ߣᶧ૕ߪߎ߁ߒߡ੕ߦߔࠇߜ߇߁ቯᏱᵹࠇࠍ૞ࠆߎߣߦ
ߥࠅ߹ߔ߇㧘ᾲᵹ᧤߇ߐࠄߦჇߔߣ㧘ߎߩߔࠇߜ
߇޿ߩേ߈߇߹ߔ߹ߔỗߒߊߥࠅ㧘ߘࠇߢ޿ߟ߆
⫳᳇ߪᶧ૕ࠍㅢߒߡㅏߍࠆߎߣ߇಴᧪ߥߊߥࠆߣ
⠨߃ࠆߩߢߔ㧚 ߘߒߡߎߩ‫ޟ‬᳇ᶧ⋧ኻㅦᐲߩ㒢⇇‫ߪ࡞࠺ࡕޠ‬㧘ࠕࡔ࡝ࠞߩ࠭࡯ࡃ࡯ඳ჻߇ 1959 ᐕߦឭ಴ߒߚቇ
૏⺰ᢥ‫ޟ‬ᴣ㛛ᾲવ㆐ߩᵹ૕ജቇ⊛᭽⋧‫ߩޠ‬ਛߩ㧝┨ߦ⸥ߐࠇߚ߽ߩߢ㧘ߎࠇ߆ࠄએਅߦ߅⹤ߒߔࠆ
ࠃ߁ߥℂ⺰ߩᒻࠍߣࠅ㧘ߒ߆߽೨㗄ߢㅀߴߚ㒢⇇ᾲᵹ᧤ߦ㑐ߔࠆࠢ࠲࠹࡜࡯࠯ߩ⚻㛎ᑼࠍ߁߹ߊ⺑᣿߽ߒ߹ߒߚߩߢ㧘ࡊ࡯࡞ᩭᴣ㛛ߩ㒢⇇ᾲᵹ᧤ߦߟ޿ߡߩ㧘޿ࠊ߫ᡰ㈩⊛ߥ‛ℂࡕ࠺࡞ߣߒߡ਎⇇⊛ߦ㐳ߊㅢ↪ߒߡ᧪߹ߒߚ㧚 ޿߹㧘ߘߩℂ⺰ߩ╭ࠍ⚫੺޿ߚߒ߹ߒࠂ߁㧚߹ߕᐢ޿᳓ᐔ਄ะ߈ടᾲ㕙ߩ਄ߢ㧘㧠┨ߢ߅⹤ߒߚ
࠹ࠗ࡜࡯ਇ቟ቯࠍ⠨ᘦߔࠆߣ㧘ߘߩ⥃⇇ᵄ㐳 Ȝ㧔ᄢc᳇࿶ߩ㘻๺᳓ߢߪ 15.7 ࡒ࡝ࡔ࡯࠻࡞㧕ߩࡇ࠶࠴ߢ
ടᾲ㕙߇ၮ⋚⋡⁁ߦಽߌࠄࠇ߹ߔ㧚ߘߒߡߎߩฦ
න૏඙↹ߏߣߦ㧘ടᾲ㕙ߦု⋥ߦ㧘⋥ᓘ߇೨⸥ࡇ
࠶࠴ߩඨಽ Ȝc /2㧔ᄢ᳇࿶ߩ㘻๺᳓ߢߪ 7.85 ࡒ࡝ࡔ࡯࠻࡞㧕ࠍ⋥ᓘߣߔࠆ౞ᩇ⁁ߩ⫳᳇ྃᵹ߇޽ߞߡ
ቯᏱ⊛ߦ⫳᳇ࠍ਄ߦㅏߔ৻ᣇ㧘ߘߩ๟࿐ߢߪᶧ૕
߇ടᾲ㕙ߦะ߆ߞߡㅒߦᵹࠇߡ޿ࠆߣ޿߁ቯᏱᵹ
ࡕ࠺࡞ࠍ઒ቯߒ߹ߔ㧚ߎࠇߢ⫳᳇ߣᶧ૕ߩᵹࠇࠆ
ᢿ㕙ߩ㕙Ⓧ߇᳿ࠅ㧘ߘߒߡߘߎࠍᵹࠇࠆ⫳᳇ߣᶧ
૕ߩ⾰㊂ߪ੕޿ߦ╬ߒ޿╫ߢߔ߆ࠄ㧘ടᾲ㕙߆ࠄ಴ࠆᾲߦࠃߞߡ⊒↢ߔࠆ⫳᳇ߩᵹㅦ uV ߩ୯㧘߅ࠃ߮ᶧ૕ߩᵹㅦ uL ߩ୯߇ߔߋߦ᳞߼ࠄࠇ㧘⚿ዪ㧘ᾲᵹ᧤ q ߩᤨߩ᳇ᶧߩߔࠇߜ߇޿ㅦᐲ uV - uL ߩ୯߇᳿ࠅ߹ߔ㧚 ৻ᣇ㧘ߎߩ⫳᳇ྃᵹߩ᳇ᶧ⇇㕙ߦߟ޿ߡ㧘㧠┨ߩ⚳ࠊࠅߩᣇߢ߅⹤ߒߚࡋ࡞ࡓࡎ࡞࠷ਇ቟ቯࠍ⠨߃㧘⇇㕙਄ߦ↢ߓࠆᵄߩㅦᐲ c ࠍਈ߃ࠆᑼߩฝㄝ
ߩᐔᣇᩮߩਛࠍ㔖ߣ߅߈߹ߔ㧚ߚߛ੹࿁ߪ㧘ߘߩ㔖ߣ߅޿ߚᑼ߆ࠄ㧘᳇ᶧ⇇㕙߇უࠇߡⴕߊ⥃⇇ᵄ㐳 Ȝc ߢߪߥߒߦ㧘᳇ᶧߩߔࠇߜ߇޿ㅦᐲ uV - uL ߩᣇࠍ᳞߼ߡ
uV  u L

વᾲ 2006 ᐕ 1 ᦬

2SV U L  UVUV U L Oߟ߹ࠅ㧘ߎߩᑼߩਈ߃ࠆ⋧ኻㅦᐲߦߥࠆߣ᳇ᶧ⇇㕙ߪਇ቟ቯߣߥࠅ㧘⫳᳇ߪᶧ૕ࠍㅢߒߡㅏߍࠄࠇ
ߥߊߥࠆߣ⠨߃ࠆߩߢߔ㧚ߘߒߡ᳇ᶧߩߔࠇߜ߇
޿ㅦᐲ uV - uL ߣᾲᵹ᧤ q ߩ㑐ଥߪ೨ߦ᳞߼ߡ޽ࠅ
߹ߔ߆ࠄ㧘ߎࠇߢ㒢⇇ᾲᵹ᧤ߩ୯߇᳞߼ࠄࠇࠆߎ
ߣߦߥࠅ߹ߔ㧚 ߒ߆ߒ࿎ߞߚߎߣߦ㧘޿߹ฝߦ᳞߼ߚߔࠇ㆑޿
ㅦᐲ uV - uL ߩᑼߩฝㄝᩮภౝߦ฽߹ࠇߡ޿ࠆᵄ㐳Ȝ ߩ୯߇ಽ߆ࠄߥ޿ߩߢߔ㧚ߘߎߢ㧘ߎߩ໧㗴ࠍ
ಣℂߔࠆߚ߼㧘ᶧ૕ߩਛࠍᵹࠇࠆ⫳᳇ྃᵹ㧔⃻࿷ߘߩ⋥ᓘߪ೨ㅀߩࠃ߁ߦ Ȝc / 2㧕ߪ㧘ߘߩ᳇ᶧ⇇㕙ߩᵄߩᵄ㐳 Ȝ ߇ྃᵹߩ౞๟ߩ㐳ߐ㧔⃻࿷ ʌȜc / 2 ߦߥࠅ߹ߔ㧕ࠃࠅᄢ߈޿ᤨ㧘⫳᳇ㅦᐲߦ㑐ଥߥߊᏱߦਇ቟ቯߦߥࠆߣ޿߁㧘೎ߩਇ቟ቯ᧦ઙࠍ⠨߃วߖ㧘ߟ߹ࠅ Ȝ = ʌȜc /2 ߣ߅޿ߡ Ȝ ߩ୯ࠍ᳿߼߹ߔ㧚ߘߒߡߎߩ Ȝ ߩ୯ࠍ૶߁ߣ㧘㛳޿ߚߎߣߦ೨ߩࠢ
࠲࠹࡜࡯࠯ߩ⚻㛎ᑼߣ߶߷ห᭽ߥ⚿ᨐ߇಴ߡ᧪ࠆ
ߩߢߔ㧚㊀ᄢߥ໧㗴ὐ ‫ޟ‬᳇ᶧ⋧ኻㅦᐲߩ㒢⇇‫ߦ࡞࠺ࡕޠ‬ၮߠߊ㒢⇇ᾲᵹ᧤ߩ⊒↢ᯏ᭴ߩ⺑᣿ߪ㧘ߎ߁ߒߡߔ߫ࠄߒ޿ᚑ
ᨐࠍ෼߼߹ߒߚ㧚߹ߚ᳇ᶧ⇇㕙ߦ⿠ߎࠆ᳇ᶧਇ቟
ቯߩ⠨߃ࠍ㧘ೋ߼ߡᴣ㛛ߩ⎇ⓥߦዉ౉ߒߚഞ❣ߪ㧘↹ᦼ⊛ߥ߽ߩߣ⸒߃߹ߔ㧚ߌࠇߤ߽㧘ࠃߊᬌ⸛ߒ
ߡߺࠆߣߎߩࡕ࠺࡞ߦߪ㊀ᄢߥ໧㗴߇฽߹ࠇߡ޿
ࠆߩߢ޽ߞߡ㧘޿߹㧟ߟߩ໧㗴ࠍ᜼ߍߡߺࠃ߁ߣ
ᕁ޿߹ߔ㧚 ╙㧝ߩ໧㗴ߪ㧘ℂ⺰⊛໧㗴ߢߔ㧚㧠┨ߢㅀߴߚࠃ߁ߦ㧘࠹ࠗ࡜࡯ਇ቟ቯߪ㧘ਈ߃ࠄࠇߚᄢ߈ߐߩ
㊀ജ g ߩਅߦ޽ࠆ᳇ᶧ⇇㕙ߦኻߒߡ⇇㕙߇უࠇࠆᤨߩᵄ㐳ߩ୯ࠍ␜ߒ㧘৻ᣇ㧘ࡋ࡞ࡓࡎ࡞࠷ਇ቟ቯ
ߪਈ߃ࠄࠇߚ⋧ኻㅦᐲ uV - uL ߢᵹࠇߡ޿ࠆ᳇ᶧߩ
⇇㕙ߦኻߒߡ⇇㕙߇უࠇࠆᤨߩᵄ㐳ߩ୯ࠍ␜ߔ߽
ߩߢߔ㧚ߣߎࠈ߇⃻࿷ߩࡕ࠺࡞ߢߪ㧘೨⠪߆ࠄߪ⏕߆ߦ‫ޟ‬ᵄ㐳‫ࠍޠ‬᳞߼߹ߔ߇㧘ᓟ⠪߆ࠄߪ‫⋧ޟ‬ኻㅦᐲ‫ࠍޠ‬᳞߼ࠆߣ޿߁㧘߹ߞߚߊ⇣⾰ߥขࠅᛒ޿
ࠍߒߡ޿߹ߔ㧚ߘߒߡߘߩߚ߼㧘ᓟ⠪ߩਇ቟ቯᵄ
㐳ǳߩ୯߇ਇቯߩ߹߹ߣߥࠅ㧘ߘߩ୯ߩ᳿ቯߩߚ
߼ᱛ߻ࠍᓧߕ㧘ࡋ࡞ࡓࡎ࡞࠷ߩਇ቟ቯ᧦ઙߩ਄ߦ㧘ߐࠄߦ߽߁৻ߟ೎ߩਇ቟ቯ᧦ઙࠍ㊀ⶄߒߡㆡ↪ߔࠆߣ޿߁ήℂࠍ‽ߐߨ߫ߥࠄߥߊߥߞߡ޿ࠆߩߢߔ㧚 ᾲᵹ᧤߇Ⴧߔߦߟࠇߡ㧘⫳᳇ߩ⊒↢㊂߇߰߃㧘- 52 -J. HTSJ, Vol. 45, No. 190

․೎ነⓂ

⇇ߎߘ߇㧘ᩭᴣ㛛ߩ਄㒢ࠍ߈߼ࠆ㊀ⷐߥࡐࠗࡦ࠻
ߛߣߩ⠨߃߽ᓥ᧪߆ࠄή߆ߞߚࠊߌߢߪ޽ࠅ߹ߖ
ࠎ㧚ߒ߆ߒℂ⺰ൻ߇਄ᚻߊ಴᧪ߥ޿ߚ߼㧘ߘߩਥᒛߦജࠍᰳ޿ߡ޿߹ߒߚ㧚ߌࠇߤ߽Ყセ⊛ᦨㄭ㧘᧲੩ᄢቇߢ╩⠪ࠍਛᔃߦ㧘ߔߢߦ㧠┨ߦㅀߴߚࠃ
߁ߥ⫳᳇ߩ߆ߚ߹ࠅ㧘ᩭᴣ㛛ᶧጀߥߤߩ⁁ᴫߦߟ
޿ߡߩቯ㊂⊛ߥࡕ࠺࡞ൻߩ⎇ⓥ߇ㅴ߻ߦߟࠇߡ㧘ߎࠇࠄࠍၮ␆ߦ㒢⇇ᾲᵹ᧤ߩಽᨆ߇಴᧪ࠆࠃ߁ߦ
ߥߞߡ᧪߹ߒߚ㧚ߒ߆߽ߎࠇߪࡊ࡯࡞ᴣ㛛ߛߌߢߥߊ㧘ടᾲ㕙ߦᴪߞߡᶧ૕߇ᒝ೙⊛ߦᵹߐࠇߡ޿
ࠆᤨߩᴣ㛛߹ߢ㧘ᐢߊ޿ࠈ޿ࠈߩ⁁ᴫਅߩᩭᴣ㛛ߩ㒢⇇ᾲᵹ᧤ߦኻߒߡ㧘ߘߩ⺑᣿ࠍน⢻ߦߔࠆജࠍᜬߞߡ޿߹ߔ㧚ᧄ㗄ߣᰴ㗄ߢ㧘ߘߩߎߣࠍዋߒ
⷗ߡߺ߹ߒࠂ߁㧚 Ԙ‫ޟ‬ᐢ޿਄ะ߈ടᾲ㕙਄ߩ㒢⇇ᾲᵹ᧤‫ޠ‬ ߹ߕᐢߊᐔࠄߥ਄ะ߈ടᾲ㕙਄ߩᩭᴣ㛛ࠍ⷗ߡߺ߹ߒࠂ߁㧚ߎߩᤨ㧘೨ߣห᭽ߦ࠹ࠗ࡜࡯ਇ቟ቯ
ߩ⥃⇇ᵄ㐳 Ȝc ߩ㑆㓒ߢಽߌࠄࠇߚන૏඙↹߇⠨߃ࠄࠇ߹ߔ߇㧘ߚߛ੹࿁ߪฦ඙↹ߏߣߦ⫳᳇ߩ߆ߚ߹ࠅ߇ᚑ㐳㧘㔌⣕ࠍ➅ࠅ㄰ߔߣ⠨߃߹ߔ㧚ߘߒߡ㧘ߘߩ৻ߟߩන૏඙↹㧔㕙Ⓧ Ȝc2㧕ߦᵈ⋡ߔࠆߣ㧘ߘߎߢ৻୘ߩ⫳᳇ߩ߆ߚ߹ࠅ߇಴᧪ᆎ߼ߡ߆ࠄ㔌⣕ߔࠆ߹ߢ㧘ടᾲ㕙਄ߦṛ⇐ߔࠆᤨ㑆 tD ߇㧠┨ߢ߅⹤ߒߚࡔࠞ࠾࠭ࡓߦࠃߞߡ᳿ࠅ߹ߔ㧚ߥ߅㧘޿߹ᵈ⋡ߒߡ޿ࠆ඙↹ߩ๟࿐ߦ޽ࠆฦ඙↹ߢ߽ߘࠇߙ
ࠇ㧘⫳᳇ߩ߆ߚ߹ࠅߩᐩㇱ߇޿ߟ߽ടᾲ㕙ࠍⷒ߁ᒻߦߥߞߡ޿߹ߔߩߢ㧘޿߹ᵈ⋡ߒߡ޿ࠆ඙↹ߩടᾲ㕙਄߳ߩᶧ૕ߩ⵬⛎ߪ㧘ߎߩ඙↹ߩ⫳᳇ߩ߆ߚ߹ࠅ߇਄ᣇߦ㔌⣕ߒ㧘ߘߩᓟߦᶧ૕߇౉ߞߡ᧪
ࠆᤨߛߌߦⴕࠊࠇࠆߣㄭૃ⊛ߦ⠨߃ߡᄢ߈ߥ⺋ࠅߪߥ޿ߢߒࠂ߁㧚ߘߒߡߘߩᤨ㧘ടᾲ㕙਄ߩᩭᴣ㛛ᶧጀ߇㒢⇇ෘߐ㧔㧠┨ߢㅀߴߚ㒢⇇ෘߐ įc㧕߹ߢ࿁ᓳߒ㧘ߘࠇએᓟ㧘ᣂߒ޿⫳᳇ߩ߆ߚ߹ࠅߩ
ṛ⇐ᤨ㑆 tD ߩ㑆㧘ᶧ૕ߩ⵬⛎ߥߒߦ⫳⊒ᶖ⠻ߒߡⴕߊߎߣߦߥࠅ߹ߔ㧚ߘߒߡߎߩࠃ߁ߥ⁁ᴫਅߦടᾲ㕙ߩᾲᵹ᧤ q ࠍჇߒߡⴕߞߚߣߔࠆߣ㧘ᩭᴣ㛛ᶧጀߩೋᦼෘߐ įc ߪ q2 ߦ෻Ყ଀ߒߡ⭯ߊߥࠆ㧔㧠┨ෳᾖ㧕৻ᣇ㧘ᶧጀߩ⫳⊒ㅦᐲߩᣇߪ q ߦᲧ଀ߒߡㅦߊߥࠅ߹ߔ㧚߹ߚᶧጀ߇⫳᳇ߦⷒࠊࠇࠆ
ᤨ㑆 tD ߩᣇߪ㧘㧠┨ߢߺߚࠃ߁ߦᾲᵹ᧤ q ߦࠃߞߡ޽߹ࠅᄌࠅ߹ߖࠎ߆ࠄ㧘⚿ዪએ਄ࠍ✚วߒߡ㧘ᾲᵹ᧤ q ߩჇടߣ౒ߦ޿ߟ߆ᔅߕᤨ㑆 tD ߩ⚳ࠅߦ㧘ടᾲ㕙਄ߩᶧጀ߇ߜࠂ߁ߤੇ߈ಾࠆ㒢⇇⁁ᘒ߇⃻ࠇࠆߎߣߦߥࠅ߹ߔ㧚ߟ߹ࠅ㧘ߎࠇ߇㒢⇇ᾲᵹ᧤ᓥߞߡߘߩ⫳᳇߇ᶧਛࠍㅏߍ෰ࠆᤨߩ᳇ᶧߩ⋧ኻㅦᐲ uV - uL ߇Ⴧߒ㧘ߘߩ㒢⇇߇㒢⇇ᾲᵹ᧤ߣ⚿߮ߟߊߣ޿߁⠨߃ߪ㧘ᄢᄌ⥄ὼߥᗵߓߩ߽ߩߢ޽ߞ
ߡ㧘⺕ߒ߽ߘ߁⠨߃ߚߊߥࠆ㝯ജࠍᜬߞߡ޿߹ߔ㧚ߒ߆ߒห৻ߩ⇇㕙ߦኻߒߡ㧞ߟߩਇ቟ቯ᧦ઙࠍ㊀ⶄߒߡ⠨߃ࠆߣ޿߁ߩߪ㧘⺰ℂ⊛ߦ߿ߪࠅ໧㗴߇޽ࠅ߹ߔ㧚 ╙㧞ߪ㧘⃻࿷ߩࡕ࠺࡞߇ਥᒛߔࠆᦨ߽ᄢಾߥ੐
ᨩߦኻߒ㧘᣿⊕ߦ㔌෻ߔࠆታ㛎⊛੐ታ߇޽ࠆߣ޿
߁ߎߣߢߔ㧚ߔߥࠊߜ㧘ߎߩࡕ࠺࡞ߦࠃࠇ߫㧘㒢⇇ᾲᵹ᧤ࠃࠅߐࠄߦ㜞޿ᾲᵹ᧤ߩᴣ㛛ߣ޿߁߽ߩ
ߪ㧘ߘߩ⊒↢⫳᳇㊂߇㔌⣕น⢻ߥ㒢⇇㊂ࠍ⿥߃ࠆߎߣߦߥࠅ߹ߔ߆ࠄ㧘ߤࠎߥᣇᴺߦࠃߞߡ߽ታ⃻߇ਇน⢻ߩ╫ߢߔ㧚ߣߎࠈ߇ታ㓙ߦߪ㧘㒢⇇ᾲᵹ᧤ߦㄭ޿⁁ᘒߩടᾲ㕙ߩ਄ߦ㧘ߚߣ߃߫ᵈ኿㊎ߩࠃ߁ߦ⚦㐳޿▤㧔⊒↢⫳᳇ߩ᜼േߦᓇ㗀ࠍਈ߃ߥ޿૏ߩ㧕ࠍ૶ߞߡᶧ૕ࠍੱᎿ⊛ߦ⵬⛎ߒߡ߿ߞߚ
ࠅߔࠆߣ㧘ᩭᴣ㛛ࠍ߽ߞߣ㜞޿ᾲᵹ᧤߹ߢኈᤃߦ
਄ߍߡⴕߊߎߣ߇಴᧪ࠆߩߢߔ㧚ߟ߹ࠅടᾲ㕙਄ߢ⊒↢ߔࠆ⫳᳇ߩ㊂߇㧘ߎߩࡕ࠺࡞ߩ޿߁㒢⇇㊂
ࠍ⿥߃ߡᄢ߈ߊߥߞߡ߽㧘⫳᳇ߪ૗ߩ㓚ኂ߽ߥߊᶧਛࠍㅢߞߡ㔌⣕಴᧪ࠆߩߢߔ㧚 ╙㧟ߦ㧘ߎߩࡕ࠺࡞ߢߪ㧘೨ߦ߅⹤ߒߚࠃ߁ߦ㧘ടᾲ㕙਄ߦᲧセ⊛ᄢ߈ߥ⋥ᓘߩ‫ޟ‬ቯᏱ⊛‫⫳ߥޠ‬᳇ྃᵹߩሽ࿷ࠍ઒ቯߒߡ޿߹ߔ㧚ߒ߆ߒ⃻ታߦߪ㧟┨‫ޟ‬ᒝ޿ᩭᴣ㛛ߩ಴⃻‫ߩޠ‬㗄㧘߹ߚ㧠┨‫ޟ‬ⓨ᳇ߩᵹࠇ߇ಽᢿߐࠇࠆ⹤ߒ‫ߩޠ‬㗄ߢㅀߴߚࠃ߁ߦ㧘ᒝ޿ᩭᴣ㛛ߩ႐ว㧘ടᾲ㕙਄ߦߪ⫳᳇ߩ߆ߚ߹ࠅ߇
‫ޟ‬๟ᦼ⊛‫↢ߦޠ‬ᚑ㔌⣕ࠍ➅ࠅ㄰ߒߡ߅ࠅ㧘ᓥߞߡታ㓙ߩᵹࠇߩ⁁ᘒ߇ᧄࡕ࠺࡞ߩ઒ቯߣ߹ࠆߢ㆑߁ߩߢߔ㧚‫ޟ‬ᩭᴣ㛛ᶧጀෘߐߩ㒢⇇‫࡞࠺ࡕޠ‬ ߐߡએ਄ߦ⷗ߡ᧪ߚ‫ޟ‬᳇ᶧ⋧ኻㅦᐲߩ㒢⇇‫ࡕޠ‬࠺࡞ߢߪ㧘ടᾲ㕙ࠃࠅዋߒ㔌ࠇߚߣߎࠈߦ઒ᗐߒ
ߚ᳇૕ߣᶧ૕ߩߔࠇ㆑޿ᵹࠇ߇ਥᓎߢ޽ߞߡ㧘ടᾲ㕙⥄りߪߚߛ⫳᳇ࠍ⊒↢ߔࠆߛߌߩᓎഀߦߥߞ
ߡ޿߹ߔ㧚ߟ߹ࠅടᾲ㕙ߪ⫳᳇ࠍ⊒↢ߒߐ߃ߔࠇ
߫ࠃߊ㧘ടᾲ㕙਄ߢ᳇ᶧ߇ߤࠎߥ‛ℂ⊛⁁ᴫߦߥߞߡ޿ࠆ߆ߪ໧㗴ߢߪ޽ࠅ߹ߖࠎ㧚ᭂ┵ߥߎߣࠍ⸒߁ߣ㧘ᰴߩ㧢┨ߢㅀߴࠆ⤑ᴣ㛛ߩࠃ߁ߦ㧘ടᾲ㕙߇ᶧ૕ߢỨࠇߡ޿ߥߊߡ߽޿޿ߩߢߔ㧚 ৻ᣇߎࠇߦኻߒߡ㧘߽ߞߣടᾲ㕙ㄭߊߩ⁁ᴫ㧘․ߦടᾲ㕙ࠍᏱߦᶧ૕ߢỨࠇߚ⁁ᘒߦ⟎߈ᓧࠆ㒢

વᾲ 2006 ᐕ 1 ᦬- 53 -J. HTSJ, Vol. 45, No. 190

․೎ነⓂ

ࠆߎߣߦߥࠅ߹ߔ㧚ԙ‫ޟ‬ᒙ޿ᒝ೙ᵹࠇࠍട߃ߚ႐ว‫ޠ‬ ᰴߦ㧘౞ᩇടᾲ㕙ߩ߹ࠊࠅߩ㘻๺ᶧ૕ࠍ਄ะ߈
ߦ㧘ࠁߞߊࠅߒߚㅦᐲߢᒝ೙⊛ߦᵹߔࠃ߁ߦߒߚ
႐วߪߤ߁ߥࠆߢߒࠂ߁߆㧚ߎߩᤨߪ㧘߹ߛᶧ૕ߩᵹㅦ߇߅ߘߊ㧘ᓥߞߡ㊀ജߩ૞↪㧘ߟ߹ࠅᶋജ
ߩ૞↪߇ᡰ㈩⊛ߥߩߢ㧘೨ߩࡊ࡯࡞ᴣ㛛ߩᤨߣห᭽ߥᕈᩰߩ⫳᳇ߩ߆ߚ߹ࠅߩᚑ㐳㧘㔌⣕ߩ᜼േ߇⷗ࠄࠇ߹ߔ㧚ߒ߆ߒ㧘ᶧ૕ߩᒝ೙ᵹࠇߩਛߦ߅߆
ࠇࠆ⫳᳇ߩ߆ߚ߹ࠅߪ㧘ߘߩᓇ㗀ࠍฃߌߡ㧘ടᾲ㕙߹ࠊࠅߦṛ⇐ߔࠆᤨ㑆߇ࡊ࡯࡞ᴣ㛛ߩᤨࠃࠅዋ
ߒ⍴ߊߥࠅ߹ߔ㧚ߛ߆ࠄ㧘㒢⇇ᾲᵹ᧤ߩ୯ߪ㧘ߎߩᒝ೙ᵹࠇߩᵹㅦߩჇടߣ౒ߦࡊ࡯࡞ᴣ㛛ߩᤨࠃࠅᓢ‫ߦޘ‬㜞ߊߥߞߡⴕ߈߹ߔ㧚Ԛ‫ޟ‬ᒝ೙ᵹേᴣ㛛ߩ႐ว‫ޠ‬ ᦨᓟߦ㧘೨⸥ߩᒝ೙⊛ߦᵹߔᶧ૕ߩᵹㅦࠍචಽ
ߦ㜞ߊߒߡߺ߹ߔߣ㧘ᶋജߩ૞↪߇ᶖ߃ߡ㧘੹߹ߢߣߪ߹ߞߚߊ㆑߁⫳᳇ߩ㔌⣕⁁ᘒ߇⃻ࠊࠇ߹ߔ㧚ߔߥࠊߜടᾲ㕙਄ߩᩭᴣ㛛ߢቯᏱ⊛ߦ૞ࠅ಴ߐࠇ
ࠆ⫳᳇ߪ㧘౞ᩇടᾲ㕙߆ࠄᓟᵹߩᣇߦ⛯ߊ৻ᨎߩࠪ࡯࠻⁁ߩ⫳᳇ᵹࠇࠍ૞ࠅ㧘ߘߩࠪ࡯࠻⁁ᵹࠇߩᓟ✼߆ࠄ⫳᳇߇ਇⷙೣߦජಾࠇߥ߇ࠄᓟᣇ߳ᵹࠇ
෰ࠆߣ޿߁⁁ᴫߦߥࠆߩߢߔ㧚ߘߒߡߎߩᤨ㧘ᒝ೙⊛ߦᵹߐࠇߡ޿ࠆᶧ૕߇㧘਄ᵹ஥߆ࠄ౞ᩇടᾲ
㕙ߦ߹ߞߔߋᒰߚࠆ㒝ㄭߪ㧘⫳᳇ߩ⫾Ⓧ߇߹ߛ↢ߓߥ޿ㇱಽߥߩߢ㧘ߎߎ߆ࠄᶧ૕߇⛘߃ߕടᾲ㕙਄ߩᩭᴣ㛛ᶧጀߦଏ⛎ߐࠇߡ޿ࠆߣ⠨߃ࠆߎߣ߇
಴᧪߹ߔ㧚ߘߒߡᾲᵹ᧤߇Ⴧߔߣ㧘㧠┨ߩ⚳ࠊࠅߦㅀߴߚࠃ߁ߦᩭᴣ㛛ᶧጀߩ㒢⇇ෘߐ įc ߇⭯ߊߥࠅ߹ߔߩߢ㧘ߘࠇߦᵹ౉ߔࠆᶧ૕ߩ㊂ߪᷫዋߒ㧘৻ᣇ㧘ടᾲ㕙਄ߢߩᶧ૕ߩ⫳⊒㊂ߪᄙߊߥࠅ߹ߔ㧚ߘߒߡᩭᴣ㛛ᶧጀߦቯᏱ⊛ߦᵹࠇㄟ߻ᶧ૕߇㧘ߜࠂ߁ߤടᾲ㕙਄ߢ⫳⊒ߒ߈ࠆߛߌߩᾲᵹ᧤ߦ㆐ߒ
ߚᤨ㧘㒢⇇ᾲᵹ᧤ߦߥࠆࠊߌߢߔ㧚ߎߩ႐ว㧘ᶧ૕ߩᵹㅦ߇Ⴧߔߣߣ߽ߦᶧጀߦᵹ౉ߔࠆᶧ㊂߇߰߃ࠆߩߢ㧘৻⥸ߦᶧ૕ߩᵹㅦࠍჇߖ߫㒢⇇ᾲᵹ᧤ߩ୯߇਄᣹ߒ߹ߔ㧚ߚߛߒߎߩ႐ว㧘౞ᩇടᾲ㕙ߩ⋥ᓘ߇߆ߥࠅᄢ߈ߊߥࠆߣ㧘೨ㅀߩࠃ߁ߦߒߡ
ᶧጀߦᵹ౉ߒߚ⭯޿ᶧ૕ߩᵹࠇ߇☼ᕈߩᓇ㗀ਅߦടᾲ㕙਄ࠍߤߩࠃ߁ߦᵹࠇߡⴕߊ߆ߩ໧㗴߇ᄢ߈ߊߥࠅ߹ߔ㧚ᓥߞߡߎߎߢߩ⺑᣿ߪ㧘޽ࠆ⒟ᐲએ
਄㧘⚦޿౞ᩇടᾲ㕙ߩ႐วߢ޽ࠆߣ⠨߃ߡਅߐ޿㧚 ߥ߅ᰴߩᑼߪ㧘⋥ᓘ d ߩ౞ᩇടᾲ㕙ࠍᵹㅦ uLߩ㘻๺ᶧ૕ߩᵹࠇߦ⋥੤ߔࠆࠃ߁ߦ⟎޿ߚᤨߩ㒢ߦߥࠆࠊߌߢ㧘߹ߚ੐ታ㧘એ਄ߩ⸃ᨆࠍⴕ߁ߣ㧘೨ߩࠢ࠲࠹࡜࡯࠯ߩ⚻㛎ᑼߣ߶߷หߓࠃ߁ߥ⚿ᨐ߇಴ߡ᧪ࠆߩߢߔ㧚ԙ‫ޟ‬ਅะ߈ߩടᾲ㕙ߩ㒢⇇ᾲᵹ᧤‫ޠ‬ ᰴߦ㧘ዋߒ⓭㘧ߥ଀ߢߔ߇㧘ᐔࠄߥടᾲ㕙ࠍᶧ૕ߩਛߦ᳓ᐔਅะ߈ߦ౉ࠇߚ․ᱶߥ႐วߩᩭᴣ㛛ߦߟ޿ߡ㧘㒢⇇ᾲᵹ᧤ߩ⊒↢ࡔࠞ࠾࠭ࡓࠍ⷗ࠆߎ
ߣߦߒ߹ߒࠂ߁㧚߽ߜࠈࠎߎߩࠃ߁ߥ♽ߢߪ㧘⫳᳇߇਄ߦㅏߍࠄࠇߥ޿ߢߪߥ޿߆ߣᔃ㈩ߥੱ߇޿
ࠆ߆߽⍮ࠇ߹ߖࠎ㧚⏕߆ߦടᾲ㕙߇㕖Ᏹߦᐢ޿ߣ
ߘߩㅢࠅߢߔ㧚ߒ߆ߒ㧘଀߃߫⋥ᓘ 20 ࡒ࡝ࡔ࡯࠻
࡞૏ߩടᾲ㌃᫔㧔ߘߩਅ┵ߩ┵㕙ࠍ౞ᒻടᾲ㕙ߦߔࠆ㧕ߩ߹ࠊࠅࠍ࡝ࡦࠣ⁁ߩᢿᾲㇱߢࠞࡃ࡯ߒߚ
߽ߩࠍ㧘ᶧ૕ࡊ࡯࡞ߩਛߦ਄߆ࠄု⋥ߦ౉ࠇߡ⷗
߹ߒࠂ߁㧚ߎߩᤨߪ㧘ടᾲ㕙ߣ๟࿐ᢿᾲㇱߩਅ㕙ߦ⫳᳇߇ߚ߹ࠆߎߣߦߥࠅ㧘ߎߩ⫳᳇ߩ߆ߚ߹ࠅ
߇චಽᄢ߈ߊᐢ߇ࠆߚ߮ߦ㧘┵ߩᣇ߆ࠄ਄ᣇߦᵹ
ࠇ෰ࠆߣ޿ߞߚേ߈߇๟ᦼ⊛ߦ⿠ߎࠅ߹ߔ㧚ߘߒߡ㧘৻ߟߩ⫳᳇ߩ߆ߚ߹ࠅ߇ടᾲ㕙ࠍⷒ߁ᦼ㑆 tDߣ㧘ߘߩ㑆ߩᩭᴣ㛛ᶧጀߩ⫳᳇ᶖ⠻ߣ߆ࠄ㧘೨ߩԘߩ଀ߣห᭽ߥේℂߢ㒢⇇ᾲᵹ᧤ߩቯ߹ࠆߎߣ߇
ℂ⸃಴᧪߹ߔ㧚ߎߩ႐ว㧘ߚߣ޿ടᾲ㕙ߩᄢ߈ߐ߇৻ቯߢ޽ߞߡ߽㧘ߘߩ๟࿐ߦઃߌߚᢿᾲㇱߩᄖᓘࠍჇߔߣ㧘⫳᳇ߩṛ⇐ᤨ㑆 tD ߇Ⴧߒ߹ߔ߆ࠄ㒢⇇ᾲᵹ᧤ߩ୯߇ᷫߞߡⴕߊߎߣߦߥࠅ߹ߔ㧚᳓ᐔ౞ᩇടᾲ㕙਄ߩ㒢⇇ᾲᵹ᧤ ೨㗄ߢㅀߴߚ‫ޟ‬ᩭᴣ㛛ᶧጀෘߐߩ㒢⇇‫࡞࠺ࡕޠ‬ߩઁߩㆡ↪଀ߣߒߡ㧘ߎߎߦߐࠄߦ㧘㐳޿౞ᩇടᾲ㕙ࠍ㘻๺ᶧ૕ߩਛߦ᳓ᐔߦ଻ᜬߒߚᤨߩᩭᴣ㛛ߩ㒢⇇ᾲᵹ᧤ߦߟ޿ߡዋߒ⸅ࠇߡ߅߈߹ߒࠂ߁㧚Ԙ ‫࡞࡯ࡊޟ‬ᴣ㛛ߩ႐ว‫ޠ‬ ߹ߕࡊ࡯࡞ᴣ㛛ߩ႐ว㧘ᒝ޿ᩭᴣ㛛⁁ᘒߦߥࠆߣ㧘଀ߩ࠹ࠗ࡜࡯ਇ቟ቯߩߖ޿ߢ᳓ᐔ౞ᩇടᾲ㕙ߩゲᣇะߦ㧘⛔⸘⊛ߦ㧘޽ࠆࡇ࠶࠴ߏߣߦ⫳᳇ߩ߆ߚ߹ࠅߩᚑ㐳㧘㔌⣕߇߅ߎࠆߎߣߦߥࠅ߹ߔ㧚ߚߛ㧘ߘߩࡇ࠶࠴㑆㓒ߪ㧘೨ߦ⺑᣿ߒߚᐢ޿ᐔ㕙਄ߩ࠹ࠗ࡜࡯ਇ቟ቯߩ⥃⇇ᵄ㐳ࠃࠅߪ⍴ߊ㧘߆ߟ౞ᩇ߇⚦޿߶ߤ⍴ߊߥࠅ߹ߔ㧚ߥߗߥࠄ೨ߩᐔ㕙ടᾲ㕙ߩᤨߦᲧߴ㧘⃻࿷ߪ⊒↢⫳᳇߇౞ᩇߩ߹ࠊ
ࠅࠍ൮߻ᒻߦߥࠅ߹ߔ߆ࠄ㧘᳇ᶧ⇇㕙߇౞ᩇ߹ࠊ
ࠅߦᦛ߇ࠆߎߣߦߥࠅ㧘ߘߩᦛ߇ࠅߩᓇ㗀߇ടࠊࠆ߆ࠄߢߔ㧚ߒ߆ߒߘࠇએᄖߪ㧘ᐢ޿ᐔ㕙ߩᤨߣ߶߷ห᭽ߥᯏ᭴ߦࠃߞߡ㒢⇇ᾲᵹ᧤ߩ⃻⽎߇⿠ߎ

વᾲ 2006 ᐕ 1 ᦬

- 54 -J. HTSJ, Vol. 45, No. 190

․೎ነⓂ
⇇ᾲᵹ᧤ qc ߦߟ޿ߡ㧘ℂ⺰ᑼࠍࡌ࡯ࠬߦߒߥ߇ࠄ㧘⫳᳇ߣᶧ૕ߩኒᐲߩᲧ߇ ȡV/ȡL = 0.0005㨪0.4 ߣ޿߁㕖Ᏹߦᐢ޿▸࿐ߦࠊߚࠆታ㛎࠺࡯࠲ࠍᢛℂߒߡ᳞߼ߚ⚿ᨐߢqc
U L h fg u Lߎߎߦ  Kmª U LV ºK«
2 »¬« U L u L d ¼»

0.00588  UV / U L
0.42 UV / U Lᶧ૕ߦỨࠇߦߊ޿ടᾲ㕙ߩ႐ว ೨ߦ㧞┨ߦ߅޿ߡ㧘࿶ജ߇㕖Ᏹߦૐ޿ᤨߩᴣ㛛߇ㅢᏱߩᴣ㛛ߣ߆ߥࠅ㆑ߞߚ᭽⋧ߩ߽ߩߦߥࠆߎ
ߣࠍ߅⹤ߒߒ߹ߒߚ߇㧘ߘࠇએᄖߦ߽㧘ടᾲ㕙߇ᶧ૕ߦỨࠇߦߊ޿႐วߥߤ᥉ㅢߣዋߒ᭽ሶߩ㆑߁
ᴣ㛛⁁ᘒ߇޿ߊߟ߆޽ࠅ߹ߔ㧚଀߃߫ᦨㄭ㧘⴫㕙ߦ࠹ࡈࡠࡦടᎿߒߚࡈ࡜ࠗࡄࡦߣ߆㍿㧔᳓ߦỨࠇߦߊ޿㧕߇ኅᐸߦ಴࿁ߞߡ޿߹ߔ߇㧘ߎࠇߦ᳓ࠍ
౉ࠇߡࠟࠬ࡟ࡦࠫߦ߆ߌߡᴣ㛛ߐߖࠆߣ㧘᥉ㅢߩᴣ㛛ߣߪ߹ࠆߢ㆑߁㧘ߜࠂߞߣ᳇๧ߩᖡ޿ࠃ߁ߥ
ᄢ߈ߥ᳇ᵃ߇ടᾲ㕙਄ߦᷙߺวߞߡ⃻ࠇࠆߎߣߦ㧘ߔߢߦ᳇ઃ޿ߡ޿ࠆੱ߇޽ࠆ߆߽⍮ࠇ߹ߖࠎ㧚ߘߒߡ㧘ߎ߁ߒߚ႐ว㧘ߘߩടᾲ㕙਄ߦ↢ߓࠆ‫ޟ‬ᒝ޿ᩭᴣ㛛‫߽ޠ‬㧘߅߅߹߆ߦ⸒ߞߡ㧘㧟┨ߢㅀߴߚ᥉ㅢߩ⁁ᴫߣߪ߿߿᭽ሶ߇ᄌࠆߩߢ޽ߞߡ㧘ߥߗߥࠄടᾲ㕙߳ߩᶧ૕ߩଏ⛎߿㧘ടᾲ㕙ߣᶧ૕ߩធ
⸅଻ᜬߥߤ߇ߣ߆ߊ㔍ߒߊߥࠆ߆ࠄߢߔ㧚ߘߒߡߘߩߚ߼㧘ૐ޿ᾲᵹ᧤ߢᣧߊᩭᴣ㛛ߩ㒢⇇߇᧪ߚࠅ㧘߹ߚ㒢⇇ᾲᵹ᧤ߩ୯߇߫ࠄߟ߈ߩᄙ޿߽ߩߦ
ߥߞߚࠅߒ߇ߜߢߔ㧚㧔ᰴภߦ⛯ߊ㧕



m

1.11

0.0428೨ߦ㧘ࡊ࡯࡞ᴣ㛛ߩ㒢⇇ᾲᵹ᧤ߦߟ޿ߡࠢ࠲࠹࡜
࡯࠯ߩ⚻㛎ᑼ㧔㧡┨‫ޟ‬㒢⇇ᾲᵹ᧤ߩ⃻⽎‫ߩޠ‬㗄ෳᾖ㧕ࠍ⸥ߒ߹ߒߚ߇㧘ߎߎߦ⸥ߒߚᒝ೙ᵹേᴣ㛛ߩᑼߣᲧセߒ㧘ࡊ࡯࡞ᴣ㛛㧔㊀ജ g ߦᡰ㈩ߐࠇࠆ㧕ߣᒝ೙ᵹേᴣ㛛㧔ᶧ૕ߩᵹㅦ uL ߦᡰ㈩ߐࠇࠆ㧕ߣߢ㧘ᢛℂᑼߩᒻ߇ߤߩࠃ߁ߦᄌࠆ߆ࠍ⷗ߡߺࠆߩ
߽㕙⊕޿ߢߒࠂ߁㧚㧔౮⌀෸߮࿑ߪర᧲੩ᄢቇવᾲᎿቇ⎇ⓥቶ ᮮ⼱ቯ㓶᳁ ឭଏ㧕
q=7.7x105 kcal/m2h

0.82X105

Bubble Volume, cm3

㰱Tsat = 39.7 K

Heat Flux (kcal/m2 h), d=10mm
1.6X105
2.0X105 6.7X105 8.6X105

Time ms
5

d=10mm, q=1.78X10 kcal/m

22d=35mm, q=8.9X105 kcal/m hᾲᵹ᧤ߦࠃࠆ⊒↢᳇ᵃߩᄌൻ㧚d ߪടᾲ㕙ߩ⋥ᓘ㧚

વᾲ 2006 ᐕ 1 ᦬- 55 -

ว૕᳇ᵃ㧔⫳᳇႙㧕૕Ⓧߩᤨ㑆⊛ᄌൻ㧚㔌⣕⋥೨ߪ᳇ᵃߩ๟࿐߆ࠄടᾲ㕙ߦᶧ૕ߩᶐ౉߇޽ࠅ㧘૕ⓍߪᕆჇߔࠆ㧚

J. HTSJ, Vol. 45, No. 190

․೎ነⓂ

ࠬࠤ࡯࠻ߪߤ߁ߒߡṖࠆߩߢߔ߆㧫Why skate so slippery ?

ኻ㚍 ൎᐕ㧔ንጊᄢቇ㧕
Katsutosi TUSIMA (University of Toyama)e-mail: tusima@sci.toyama-u.ac.jpᧄ⸥੐ߪ㧘Torino 2006 ౻ቄࠝ࡝ࡦࡇ࠶ࠢߦ
ߜߥࠎߢ㧘HP‫ޡ‬ൻቇߩ⾰໧޽ࠅ߹߳ࠎ߆‫ޕ‬‫ޢ‬
http://www.chemistryquestion.jp/situmon/shitum
on_kurashi_kagaku62_ice_skate.html
߆ࠄ㧘ኻ㚍ൎᐕ ንጊᄢቇᢎ᝼ߩߏੌ⸃ࠍᓧ
ߡォタߐߖߡ޿ߚߛ߈߹ߒߚ㧚㧔✬㓸಴ ㇱળ㧕 ⾰໧ ࠬࠤ࡯࠻ߪߤ߁ߒߡṖࠆߩߢߔ߆㧫 ᢎ߃ߡߊߛߐ޿㧍߃ࠅ᭽㧔2005 ᐕ 4 ᦬㧕࿁╵ ߏ⾰໧ߪᐔࠄߥ᳖ߩ࡝ࡦࠢߩ਄ߢ‫ߪ࠻࡯ࠤࠬޟ‬ߤ߁ߒߡ೨ㅴ㧔Ṗߞߡ೨ㅴ㧕ߢ߈ࠆߩ߆㧫‫ࠍޠ‬዆ߨߡ޿ࠆߩ߆㧘ߘࠇߣ߽૕⢒㙚߿ࠕࠬࡈࠔ࡞࠻㆏
〝ߩ਄ߢߪࠬࠤ࡯࠻ࠍᭉߒ߼ߥ޿ߩߦ‫ޟ‬᳖ߩ਄ߢߪߥߗシᔟߦṖࠆߎߣ߇ߢ߈ࠆߩ߆㧫‫ࠍޠ‬዆ߨߡ޿ࠆߩ߆ߪߞ߈ࠅߒ߹ߖࠎ㧚ᓟ⠪ߩ႐วߪ‫ࠤࠬޟ‬࡯࠻ߪߣ߽߆ߊࠃߊṖࠆ㧚ߥߗߘࠎߥߦࠃߊṖࠆߩߢߔ߆㧫‫⾰߁޿ߣޠ‬໧ߦ߅߈߆߃ࠆߎߣߦߒ߹
ߔ㧚ߤߜࠄ߽⥝๧޽ࠆ໧㗴ߢߔ߇㧘⑳ߩኾ㐷ߩᓟ⠪ߦߟ޿ߡ߅╵߃ߒ߹ߔ㧚 ࠬࠤ࡯࠻߇ࠃߊṖࠆේ࿃ߣߒߡߪᱧผ⊛ߦߪ޿ߊߟ߆ߩ᦭ജߥቇ⺑߇಴ߐࠇߡ߈߹ߒߚ㧚ߒ߆ߒ㧘⃻Ბ㓏ߢ⑳ߦ߅╵߃ߢ߈ࠆߎߣߪ㧘߹ߛߤߩ⺑߇߽ߞߣ߽ࠃߊᒰߡߪ߹ࠆߩ߆᳿⌕߇ߟ޿ߡ޿ߥ޿㧚ᷙᴋߩ⁁ᘒߦ޽ࠆߣ޿߁ߎߣߢߔ㧚ߎࠇߢߪ⾰໧⠪ߪ⚊ᓧߒߥ޿ߢߒࠂ߁߆ࠄ㧘ዋߒ㐳ߊߥࠅ߹ߔ
߇એਅߦฦቇ⺑ࠍ⺑᣿ߒ߹ߔ㧚 ޿ߊߟ߆ߩ᦭ജߥቇ⺑ߣߪએਅߩ㧟ߟߢߔ㧚Ԙ࿶ജⲢ⸃⺑

વᾲ 2006 ᐕ 1 ᦬- 56 -

 ߎࠇߪ᳖߇᳓ߦᶋߊߣ޿߁․⇣ᕈߦᵈ⋡ߒߚ߽ߩߢߔ㧚‛⾰ߪಓࠆߣኒᐲ߇ᄢ߈ߊߥߞߡᶧ૕ߩ
ᐩߦᴉࠎߢ޿ߊߩ߇᥉ㅢߢߔ㧚᳖ߩࠃ߁ߦಓࠆߣ
ኒᐲ߇ዊߐߊߥࠅ㧘ᶧ૕ߦᶋߊ‛⾰ߪ᳖㧘ࠥ࡞ࡑ࠾࠙ࡓ㧘ࠪ࡝ࠦࡦ㧘ࠕࡦ࠴ࡕࡦ㨮ࡆࠬࡑࠬ㨮ࠟ࡝࠙ࡓߥߤߏߊዊᢙߦ㒢ࠄࠇ㧘ᄢᄌ⃟ߒ޿ߎߣߢߔ㧚ߎߩࠃ߁ߥ‛⾰ߪ࿶ജࠍട߃ࠆߣᶧ૕ߩሽ࿷㗔ၞ߇᳖ὐਅߩ᷷ᐲ㗔ၞߦᐢ߇ࠅ߹ߔ㧚᳖ߦ㧝᳇࿶ߩ࿶ജࠍട߃ࠆߏߣߦⲢὐ߇ 0.0075͠ߕߟਅ߇ࠅ߹ߔ㧚 ࠬࠤ࡯࠻ߪ᏷ 1mm㧘㐳ߐ 400mm ߶ߤ޽ࠅ߹ߔ
߇㧘ో૕ߣߒߡ೨ᓟᣇะߦࠁࠆߊḧᦛߒߡ޿߹ߔ㧚ߢߔ߆ࠄ㧘ࠬࠤ࡯࠻ߣ᳖ߩធ⸅㕙ߪ㐳ߐ 100mm⒟ᐲߦߥࠆߩ߇᥉ㅢߢߔ㧚ߘߎߦ૕㊀ 60kg㧔600N㧕
ߩੱ߇ߩߞߚߣߔࠆߣ㧘࿶ജߪ 60 ᳇࿶ߦߥࠅ߹ߔ㧚ߒߚ߇ߞߡ㧘-0.45͠߹ߢߪ᳓߇ሽ࿷ߢ߈ࠆߎߣߦ
ߥࠅ߹ߔ㧚ࠬࠤ࡯࠻ߩ಺߇᳖ߩ㕙ߦု⋥ߢߪߥߊ㧘௑޿ߡṖࠆߎߣ㧘಺ߩᐩ߽ 10 ਁಽߩ 1mm ⒟ᐲߩ
ಳಲࠍ߽ߞߡ޿ࠆߎߣ㧘ߐࠄߦ᳖ߩ⴫㕙ߦ߽ಳಲ߇޽ࠆߎߣࠍ⠨ᘦߔࠆߣ㧘ࠬࠤ࡯࠻ߩᐩߣ࡝ࡦࠢ
ߩ᳖߇ኒ⌕ߒߡ޿ࠆ㕙Ⓧߪ 100mm2 ࠃࠅߕߞߣዊ
ߐߊߥࠆߣ੍ᗐߐࠇ߹ߔ㧚઒ߦ 10 ಽߩ 1 ߟ߹ࠅ㧘
10mm2 ߢ޽ߞߚߣߔࠆߣ㧘-4.5͠߹ߢ᳓߇ሽ࿷ߢ
߈ࠆߎߣߦߥࠅ߹ߔ㧚ߎߩ⌀ߦኒ⌕ߒߡ޿ࠆ㕙Ⓧ
ߪṖ⿛ਛߩࠬࠤ࡯࠻ߢ߽㧘᳖ߩ਄ߦ㕒ᱛߒߡ޿ࠆ
ࠬࠤ࡯࠻ߢ߽᷹ቯߔࠆߎߣ߇㔍ߒߊ㧘ᧂߛ⌀ߩធ
⸅㕙Ⓧ߇ਇ᣿ߥߩߢߔ㧚 ߒߚ߇ߞߡ㧘᳖ߣ޿߁‛⾰ߪ㜞޿࿶ജߩ߽ߣߢ
ߪ㧘0͠એਅߢ߽᳖ߣ᳓߇౒ሽߢ߈ࠆ‛⾰ߢ޽ࠆ㧚ࠬࠤ࡯࠻ߢߪ᳖ߩ⴫㕙ߦ㜞޿࿶ജࠍ⊒↢ߢ߈ࠆ߆ࠄ㧘ታ㓙ߦ᳓߇ሽ࿷ߒ㧘ߘߩ᳓߇Ṗࠅࠍ⦟ߊߒߡ
޿ࠆߪߕߛߣ޿߁ߩ߇࿶ജⲢ⸃⺑ߩਥᒛߢߔ㧚
1886 ᐕߦࠗࠡ࡝ࠬߩ‛ℂቇ⠪࡚ࠫ࡝࡯[1] ߦࠃߞߡឭ᩺ߐࠇߚ߽ߩߢߔ㧚 ᄙߊߩ⪺ᦠߦߎߩ࿶ജⲢ⸃⺑߇ࠬࠤ࡯࠻ߩṖࠅᯏ᭴ߣߒߡ⚫੺ߐࠇߡ߈߹ߒߚ㧚

J. HTSJ, Vol. 45, No. 190

․೎ነⓂ

 ߐߡ㧘ࠬࠤ࡯࠻ߪ૗ᐲ߹ߢࠃߊṖࠆߩߢߒࠂ߁
߆㧘-30͠㧘-25͠ߢ߽Ṗࠆߩߢߒࠂ߁߆㧫 ࠞ࠽࠳߿ਛ࿖᧲ർㇱߢߪ -25 ͠⒟ᐲߩૐ᷷ߢ߽ࠬࠤ࡯
࠻߇Ṗࠅ߹ߔ㧚ૐ᷷ታ㛎ቶߢߪ-30͠ߢ߽ࠬࠤ࡯࠻
ߪࠃߊṖࠅ߹ߔ㧚ߎߩߎߣ߇࿶ജⲢ⸃⺑߇ุቯߐࠇࠆᩮᧄ⊛ߥℂ↱ߦߥࠆߩߢߔ㧚࿶ജࠍട߃ࠆߛ
ߌߢߪ᳖ߪṁߌ߹ߖࠎ߆ࠄ㧘᳖ࠍṁ߆ߔߚ߼ߩᾲ
ߩଏ⛎߇ᔅⷐߦߥࠅ߹ߔ㧚⑽ㅦ 10m ߢṖࠆ႐ว㧘᳖߇ࠬࠤ࡯࠻ߦធ⸅ߒߡ޿ࠆᤨ㑆ߪ 1000 ಽߩ 1⑽⒟ᐲߢߔ㧚ߘߩ㑆ߦ᳖ࠍṁ߆ߔᾲ߇ଏ⛎ߐࠇࠆᔅⷐ߇޽ࠅ߹ߔ߇㧘ઁߩ෻ኻ⺰ߣߒߡߪᤨ㑆߇⍴ߔ߉ߡⲢ⸃ߪήℂߛࠈ߁ߣ޿߁⠨߃߇޽ࠅ߹ߔ㧚 ߐࠄߦ᳿ቯ⊛ߥᰳ㒱߇Ꮒᄢන⚿᥏᳖࡝ࡦࠢታ⃻ߦࠃߞߡ್᣿ߒ߹ߒߚ㧚ߟ߹ࠅ㧘᳖ߩ⚿᥏㕙ߦࠃߞߡࠬࠤ࡯࠻ߩṖࠅ߿ߔߐߦ㆑޿ߩ޽ࠆߎߣ߇್
᣿ߒߚߩߢߔ㧚ߎࠇߎߘ㧘࿶ജⲢ⸃⺑ߢߪ⺑᣿ߢ߈ߥ޿ᣂ੐ታߢߔ㧚ԙ៺ᡂⲢ⸃⺑ ߣߌ᳓߇ࠬࠤ࡯࠻ߩṖࠅࠍ⦟ߊߒߡ޿ࠆߎߣߪ
㑆㆑޿ߥ޿ߣߒߡ߽㧘ߘߩ᳓ߪ៺ᡂᾲߦࠃߞߡ૞
ࠄࠇࠆߣߔࠆቇ⺑ߢߔ㧚1939 ᐕ⧷࿖ߩࠤࡦࡉ࡝࠶
ࠫᄢቇࠠࡖࡌࡦ࠺ࠖࠪࡘ⎇ⓥᚲߩࡃ࠙࠺ࡦ[2] ߦࠃߞߡឭ໒ߐࠇ߹ߒߚ㧚੹ᣣ߹ߢ߽ߞߣ߽ᒝߊᡰ
ᜬߐࠇߡ߈ߚቇ⺑ߢߔ㧚៺ᡂࠍߔࠆߣᾲ߇⊒↢ߒ߹ߔ㧚ߘߩᾲߢ᳖߇ṁߌࠆߣਥᒛߔࠆ߽ߩߢ㧘ࠬࠤ࡯࠻ߩṖࠅߩ޿ࠈ޿ࠈ߇ᕈ⾰㧘ߚߣ߃߫㧘ㅦᐲ߇ㅦ޿߶ߤ៺ᡂ߇ዊߐ޿㧔ࠃߊṖࠆ㧕㧘᷷ᐲ߇㜞޿
߶ߤࠃߊṖࠆ㧘ᾲવዉߩዊߐ޿ࠬࠤ࡯࠻߶ߤࠃߊ
Ṗࠆ㧘ߘߩ߶߆᳓ࠍߪߓߊ⢻ജߩ㜞޿ࠬࠤ࡯࠻߶
ߤࠃߊṖࠆߥߤߩታ㛎⊛ⵣઃߌߩ߽ߣߦਥᒛߐࠇ
߹ߒߚ㧚߶ߣࠎߤ㕖ߩᛂߜᚲ߇ߥ޿߶ߤ⺑ᓧജߩ޽ࠆቇ⺑ߢ޽ࠅ㧘࿶ୟ⊛ᄙߊߩቇ⠪ߦฃߌ౉ࠇࠄ
ࠇ߹ߒߚ㧚ߘߩᓟ߽ታ㛎߿ℂ⺰㕙ߢߎߩቇ⺑߇⵬ᒝߐࠇߡ޿߈߹ߒߚ㧚 ߒ߆ߒ㧘ࠞ࠽࠳ߢ᳖ߩ៺ᡂࠍ♖ജ⊛ߦ⎇ⓥߒߚ
࠾࡯ࡉࡦᢎ᝼[3] ߪ៺ᡂⲢ⸃⺑ߦ⇼໧ࠍᛩߍ߆ߌ㧘᳓ಽሶ࿁ォ⺑ߣ޿߁⁛⥄ߩቇ⺑ࠍឭ໒ߒߡ޿߹ߔ㧚 ⑳ߪᰴߩԚߩቇ⺑ࠍਥᒛߒߡ޿߹ߔ߇㧘ᓟ਎ߩੱ߇ᣂቇ⺑ࠍਥᒛߔࠆߦߪ㧘ߘࠇ߹ߢߩቇ⺑ߩਇㇺว߽᣿ࠄ߆ߦߔࠆᔅⷐ߇޽ࠅ߹ߔ㧚⑳ߪ᳓ߩ⊒↢ߒߥ޿ࠃ߁ߥ᧦ઙਅߩṖࠅߢ߽ࠬࠤ࡯࠻ߪࠃߊ
Ṗࠆߣ޿߁ታ㛎⚿ᨐࠍ␜ߔߎߣߢ㧘ࡃ࠙࠺ࡦࠄߩ

વᾲ 2006 ᐕ 1 ᦬- 57 -

៺ᡂⲢ⸃⺑߇໑৻ߩ⺑᣿ߣߪ㒢ࠄߥ޿ߎߣࠍਥᒛ
ߒߡ߈߹ߒߚ㧚ߒ߆ߒ㧘ߘࠇߢߪੑߟߩቇ⺑߇ਗ߱ߛߌߢ⺑ᓧജߦᰳߌߡ޿߹ߒߚ㧚㐳޿⧰㑵ߩᧃ㧘ㆀߦ៺ᡂⲢ⸃⺑ߩ⍦⋫ࠍ⷗ᛮߊߎߣ߇ߢ߈ߚߩߢ
ߔ㧚ߘࠇߎߘ߇៺ᡂⲢ⸃⺑߇ุቯߐࠇࠆℂ⺰⊛ᩮ᜚ߣߥࠅ߹ߔ㧚 ៺ᡂⲢ⸃⺑ߩ⍦⋫ࠍ⚫੺ߒ߹ߒࠂ߁㧚៺ᡂⲢ⸃⺑ߢߪߣߌ᳓߇ẢṖ೷ߩᓎഀࠍᨐߚߒߡṖࠅࠍ⦟ߊߔࠆߣਥᒛߒ߹ߔ㧚ߢߪ᳖߇ߤߩࠃ߁ߦߒߡṁߌߡ᳓ߣߥࠆߩߢߒࠂ߁߆㧫 ᳖ߦⲢ⸃ᾲࠍଏ⛎
ߒߥߌࠇ߫ߣߌ᳓ߪ⃻ࠇ߹ߖࠎ㧚៺ᡂⲢ⸃⺑ߢߪߘߩ᳓ߪ៺ᡂᾲ߇ଏ⛎ߔࠆߩߢߔ㧚៺ᡂ߇ᄢ߈޿
ߣ߈ߦ᳖ߪṁߌ㧘ẢṖ೷ߣߥࠆ᳓߇⃻ࠇߡṖࠅ߇⦟ߊߥࠅ߹ߔ㧚ߢߪ៺ᡂ߇ᭂ┵ߦዊߐߊߥࠅ㧘߽ߪ߿៺ᡂᾲߢ᳖ࠍṁ߆ߖߥߊߥߞߚࠄߤ߁ߥࠆߩ
ߢߒࠂ߁߆㧫 ៺ᡂⲢ⸃⺑ߢߪ‫ޟ‬᳓߇ߥ޿߆ࠄṖࠄߥ޿‫ߔ߹ࠅߥߦ⺰⚿߁޿ߣޠ‬㧚ታ㓙㧘ࡃ࠙࠺ࡦߪૐㅦᐲߩ៺ᡂߢߪ⊒↢ߔࠆ៺ᡂᾲߪᄢ߈ߊߡ߽㧘ࠁߞߊࠅṖߞߡ޿ࠆߚ߼⊒↢ߔࠆᾲ߇વዉߢ៺ᡂ
㕙߆ࠄㅏߍߡߒ߹޿㧘᳖ߪṁߌߥ޿㧚ߛ߆ࠄૐㅦ
ᐲߩṖࠅߢߪ៺ᡂ߇ᄢ߈޿ߣਥᒛߒߡ޿߹ߔ㧚 㜞ㅦᐲߩ៺ᡂߢ߽㧘⊒↢ߔࠆ៺ᡂᾲࠍᭂ┵ߦዊߐߊߒߡ޿ߌ߫㧘Ⲣ⸃ߪ⊒↢ߖߕ㧘៺ᡂ߇ᄢ߈ߊ
ߥࠆ႐ว߇⃻ࠇࠆߪߕߢߔ㧚޿޿߆߃ࠆߣ㧘‫៺ޟ‬ᡂࠍዊߐߊߒߡ޿ߊߣ㧘៺ᡂ߇ᄢ߈ߊߥࠆ‫߁޿ߣޠ‬ߩ߇៺ᡂⲢ⸃⺑ߩਥᒛߢߔ㧚ߎࠇߪ᣿ࠄ߆ߥౝㇱ⍦⋫ߢߔ㧚 ߎߩࠃ߁ߥන⚐ߥ⺰ℂ⊛⍦⋫ࠍੱ㘃ߪඨ਎♿એ਄߽ߩ㑆㧔66 ᐕ㑆㧕⷗ㅏߒߡ߈ߚߎߣߦߥࠅ߹ߔ㧚ߎߩ⍦⋫ߪ㐳㊁ࠝ࡝ࡦࡇ࠶ࠢߩ㗃⹤㗴ߦߥߞߚ᳖
╯࡝ࡦࠢߢ┙⸽ߐࠇ߹ߒߚ㧚ࠬࠤ࡯࠻ߣ᳖ߩ㑆ߩേ៺ᡂଥᢙߪ 0.005 ⒟ᐲߣዊߐ޿(1972 ᐕߩᧅᏻ౻
ቄࠝ࡝ࡦࡇ࠶ࠢߦ㑐ㅪߒߚ⑼ቇ⎇ⓥߢ߽ࠬࠤ࡯࠻
ߩ៺ᡂଥᢙߣߒߡ 0.003-0.006 ߩ୯߇⸘᷹ߐࠇ߹
ߒߚ㧕ߩߢߔ㧚᥉ㅢߩ៺ᡂଥᢙ߇ 0.4 ⒟ᐲߢߔ߆
ࠄ㧘ࠬࠤ࡯࠻ߩ៺ᡂߪᭂ┵ߦዊߐ޿ߣ޿߃߹ߔ㧚ታ㓙㧘࿾⃿਄ߦሽ࿷ߔࠆ࿕૕‛⾰ߩਛߢ߽ߞߣ߽
៺ᡂߩዊߐ޿‛⾰߇᳖ߢߔ㧚᳖╯࡝ࡦࠢߢߪ࡝ࡦ
ࠢߩ᳖ߩ⚿᥏㕙߇᳖ߩ(0001)㕙ߦឥ߃ࠄࠇ㧘ᓥ᧪ߩᄙ⚿᥏᳖ߩ࡝ࡦࠢࠃࠅ 22%߆ࠄ 16㧑߽ࠃߊṖࠆ࡝ࡦࠢ߇ታ⃻ߒ߹ߒߚ㧚᳖ߩ⚿᥏㕙ߦࠃࠆṖࠅߩ㆑޿ߪ៺ᡂⲢ⸃⺑ߢߪ⺑᣿ߢ߈ߥ޿ߩ߽੐ታߢߔ㧚

J. HTSJ, Vol. 45, No. 190

․೎ነⓂ

࿑ 1 ᳖ߩ⚿᥏㕙ߦࠃࠆ៺ᡂߩ㆑޿ࠍ␜ߔ៺ᡂᦛ✢ߢߔ㧚Ṗߞߡ޿ߊ᳖ߩ⚿᥏☸߇ᄌࠆᲤߦࠬ࠴࡯࡞ߩ₹ߩࠬࠤ࡯࠻㧔⿥ዊဳࠬࠤ࡯࠻㧕ߩ៺ᡂ߇ᄌൻߔࠆߎߣ߇␜ߐࠇߡ޿߹ߔ㧚(᳖ߩ⚿᥏㕙ߦࠃࠆ៺ᡂߩ⇣ᣇᕈ㧕

࿑ 2 ห৻⚿᥏㕙਄ߢṖࠆᣇะࠍᄌ߃ߚߣ߈ߩ៺ᡂᦛ✢ߢߔ㧚᳖ߩ 1, 0, 1, 0 ߣ޿߁ห৻㕙਄ߢ߽Ṗࠆᣇะߦࠃߞߡ៺ᡂ߇⇣ߥࠆߎߣ߇␜ߐࠇߡ޿߹ߔ㧚(ห৻᳖⚿᥏㕙਄ߩṖࠆᣇ૏ߦࠃࠆ៺ᡂߩ⇣ᣇᕈ㧕Ԛಝ⌕⺑ ಝ⌕⺑ߘߩ߽ߩߪ৻⥸ߩ‛⾰㑆ߩ៺ᡂᯏ᭴ߣߒ
ߡ 1930 ᐕઍߦ⏕┙ߐࠇߚቇ⺑ߢߔ㧚ߘࠇ߹ߢߪ៺
ᡂߩේ࿃ߪ⴫㕙ߩಳಲߩ߆ߺว޿ߦࠃࠆߣ⠨߃ࠄࠇߡ޿߹ߒߚ㧚ߒ߆ߒ㧘⴫㕙ࠍ⏴޿ߡߥ߼ࠄ߆ߦ
ߔࠆ߶ߤ៺ᡂ߇ᄢ߈ߊߥࠆߎߣ㧘޽ࠆ޿ߪ㔕Უߩഎ㐿㕙ߩࠃ߁ߦಽሶࠝ࡯࠳࡯ߩᐔṖߥ㕙ߩ៺ᡂ߇࠯ࡠߦߪߥࠄߥ޿ߣ޿߁⚿ᨐ߇᣿ࠄ߆ߦߥߞߡ㧘ಳಲ⺑ߪ៺ᡂߩᧄ⾰ࠍ⺑᣿ߢ߈ߥ޿ߎߣ߇್᣿ߒ㧘߆ࠊߞߡಝ⌕⺑߇⊓႐ߒ߹ߒߚ㧚ߎࠇߪ⴫㕙ߩ⓭

વᾲ 2006 ᐕ 1 ᦬- 58 -

⿠ㇱ߇ធ⸅ߒ㧘ធ⸅㕙ߩᄢㇱಽߪ㓗㑆ߢ޽ࠆߣ޿
߁ߎߣ߇᣿ࠄ߆ߦߥߞߚߎߣߦ㑐ଥߒ߹ߔ㧚៺ᡂ
ߩಽ㊁ߢߪ‫ߩߌ߆⷗ޟ‬ធ⸅㕙‫ߩ⌀ޟߣޠ‬ធ⸅㕙‫ޠ‬ࠍ඙೎ߒ߹ߔ㧚⌀ߩធ⸅㕙ߦో⩄㊀߇㓸ਛߒ߹ߔ߆ࠄ㧘⌀ߩធ⸅㕙ߪᭂ߼ߡ㜞޿࿶ജߦߥࠅ߹ߔ㧚ߘߒߡ㧘㊄ዻห჻ߩ៺ᡂߩ႐วߦߪṁធߐࠇߚࠃ
߁ߥ㊄ዻ⚿ว߇⍍ᤨߦᒻᚑߐࠇ߹ߔ㧚ߘߎࠍუߒ
ߡṖߞߡ޿ߊߩ߇៺ᡂߢߔ㧚უࠇࠆߣ㧘ᣂߒ޿⚿ว߇⷗߆ߌߩធ⸅㕙ߩ޽ߜߎߜߢหᤨߦ⊒↢ߔࠆߚ߼㧘ߔߴࠅߦߪ߶߷৻ቯߩജ߇ᔅⷐߦߥࠅ߹ߔ㧚

J. HTSJ, Vol. 45, No. 190

․೎ነⓂ

ෳ⠨ᢥ₂
[1] Joly, J., The phenomena of skating and Professor
J. Thomson's thermodynamic relation, Proc. Roy.
Dublin Soc. (N.S.), Vol. 5, 453-454 (1886).
[2] Bowden, F.P. and Hughes, T.P., The mechanism of
sliding on ice and snow, Proc. Roy. Soc. London
Vol. 172, No. 947, 280-298 (1939).
[3] Niven, C.D., A proposed mechanism for ice
friction, Can. J. Physics. Vol. 37, No. 3, 247-255,(1959).

 ࠬࠤ࡯࠻ߩṖࠅߩಝ⌕⺑ߢߪ᳖ߩ․ᕈ߇ᵈ⋡ߐࠇ߹ߒߚ㧚᳖ߪᲧセ⊛⎬޿‛⾰ߢߔ㧚 -10͠ߢߪ
1mm2 ߢᦨᄢ 100N ߩ⩄㊀ߦ⠴߃߹ߔ㧚ߎࠇ߇⌀ߩធ⸅㕙ߩ࿶ജࠍਈ߃߹ߔ㧚৻ᣇ㧘᳖ߩ೻ᢿᒝߐ
㧔ᮮߦṖࠄߖࠆജߢ᳖ࠍუߔ㧕ߪ 1mm2 ߢ 1N ⒟ᐲߣዊߐ޿ߩߢߔ㧚᳖ߪᄢ߈ߥ⩄㊀ࠍᡰ߃ࠆ⢻ജ߇޽ࠅ㧘೻ᢿߩജߦߪ◲නߦუࠇߡṖࠆߣ޿߁ᕈ
⾰߇޽ࠅ߹ߔ㧚ߎߩ᳖ߩ․ᕈߎߘࠬࠤ࡯࠻߇ࠃߊ
Ṗࠆේ࿃ߢ޽ࠆߣߔࠆߩ߇ಝ⌕⺑ߢߔ㧚ኻ㚍߇
1976 ᐕߦឭ໒ߒ߹ߒߚ㧚[4, 5] න⚿᥏᳖ࠍ↪޿ߚṖࠅߢߪ᳖߇᳿ߒߡṁߌߥ޿ߣᕁࠊࠇࠆૐ᷷㧘ૐㅦߩ᧦ઙਅߢ߽ࠬࠤ࡯࠻ߪࠃ
ߊṖࠅ߹ߔߒ㧘᳖ߩ⚿᥏㕙ߦࠃߞߡ៺ᡂ߇⇣ߥࠅ㧘ߐࠄߦห৻⚿᥏㕙਄ߢ߽Ṗࠆᣇะࠍᄌ߃ࠆߣ៺ᡂ
߇ᄌൻߔࠆ⚿ᨐ߇ታ㛎⊛ߦᓧࠄࠇ߹ߒߚ㧚ߎߩࠃ߁ߥන⚿᥏᳖߆ࠄᓧࠄࠇߚ⚿ᨐߪԘߩ࿶ജⲢ⸃⺑ߢ߽㧘ԙߩ៺ᡂⲢ⸃⺑ߢ߽㧘ߘߩઁߩቇ⺑ߢ߽⺑᣿ߢ߈ߥ޿ߩߢߔ㧚ಝ⌕⺑ߛߌ߇᳖ߩ៺ᡂ㧘ࠬࠤ࡯࠻ߩṖࠅߦ⺑᣿ࠍਈ߃ࠆߎߣ߇ߢ߈߹ߔ㧚 ߒ߆ߒ㧘⃻Ბ㓏ߢߪࠬࠤ࡯࠻ߩṖࠅᯏ᭴ߣߒߡ
ߩಝ⌕⺑ߪ࿖㓙⊛ߥቇ⇇ߢᐢߊ⹺⍮ߐࠇߡ޿ࠆࠊ
ߌߢߪ޽ࠅ߹ߖࠎ㧚ߘ߁޿߁ࠊߌߢ㧘ߪߓ߼ߩߣ
ߎࠈߢ㧘ࠬࠤ࡯࠻ߩṖࠆේ࿃ߪ⃻Ბ㓏ߢߪᷙᴋߩ
⁁ᘒߦ޽ࠆߣ޿߁࿁╵ߦߥߞߚࠊߌߢߔ㧚ᧄᢥࠍ⺒߹ࠇߚ⺒⠪ߪᷙᴋ߆ࠄᛮߌ಴ߔߩߪᤨ㑆ߩ໧㗴ߢ޽ࠆߣᗵߓขࠄࠇߚߣᕁ޿߹ߔ㧚⑳߽⺒⠪ߩᦼᓙߦᔕ߃ࠆࠃ߁ദജߒࠃ߁ߣᕁ޿߹ߔ㧚વᾲ 2006 ᐕ 1 ᦬[4] ኻ㚍ൎᐕ, ᳖ߩ៺ᡂᯏ᭴ߦߟ޿ߡ, ẢṖ, 21 Ꮞ,
5 ภ, 287-294 (1976).
[5] ኻ㚍ൎᐕ, න⚿᥏᳖ߩ៺ᡂ(1), ẢṖ, 22 Ꮞ, 8
ภ, 514-521 (1977).

ኻ㚍ൎᐕ ንጊᄢቇᢎ᝼㧔ℂቇㇱ࿾⃿⑼ቇ⑼㧕
ኾ㐷㧦㔐᳖ቇ㧘㔐᳖ߩ࠻࡜ࠗࡏࡠࠫ࡯㧘ᾲࠨࠗࡎࡦᑼ⊒㔚ࠍ⎇ⓥ㧘1943 ᐕ↢߹ࠇ㧚

- 59 -J. HTSJ, Vol. 45, No. 190

ࡀࠗ࠴ࡖ࡯Q
ࡀࠗ࠴ࡖ࡯㧽

ቝቮ‛ℂቇߣᾲജቇ
Astrophysics and Thermodynamics㒋਄ 㓷ᤘ㧔੩ㇺᄢቇᄢቇ㒮ੱ㑆࡮ⅣႺቇ⎇ⓥ⑼㧕
Masa-aki SAKAGAMI (Graduate School of Human and Environmental Studies, Kyoto University)e-mail: sakagami@phys.h.kyoto-u.ac.jp

0.7%ߢ޽ࠆߎߣ㧘ਛᔃㇱߩ⚂ 10%ߩ᳓⚛ࠍᶖ⾌ߔࠆߣᤊߪߘߩ↢ᶦࠍ⚳߃ࠆߎߣࠍ⠨ᘦߔࠆߣ⚂㧝㧜㧜ంᐕߣ޿߁ᱜߒ޿୯߇ዉ಴ߢ߈ࠆ㧚㧝㧚ߪߓ߼ߦ
࡜ࡃ࡯࡞ࡁ࠭࡞ࠍ↪޿ߚᵹ૕ߢߩࡉ࡜࠶ࠢࡎ࡯
࡞ߩࠪࡒࡘ࡟࡯࡚ࠪࡦታ㛎 [1] ࠍ౒หߢⴕߞߡ޿
ࠆ✼ߢ㧘✬㓸಴ ㇱળ㐳ߩศ↰⧷↢ᢎ᝼㧔੩ㇺᄢቇ㧕߆ࠄቝቮߣᾲജቇߩ㑐ࠊࠅߦߟ޿ߡߩ⸥੐ߩ
ଐ㗬ࠍ㗂޿ߚ㧚
ቝቮߢߪ⒳‫ߡߞߎ⿠߇⽎⃻ߥࠢ࠶࠴ࡑ࡜࠼ߩޘ‬޿ࠆ㧚଀߃߫㧘㊀޿ᤊߩ↢ᶦߩᦨᓟߦ⿠ߎࠆ⿥ᣂ
ᤊ῜⊒ߢߪࡑ࠶ࡂᢙ߇ 10,000 ࠍ⿥߃ࠆⴣ᠄ᵄ߇ቝቮⓨ㑆ࠍવ៝ߒ㧘ਛᔃߦߪኒᐲ߇ 1015 g/cm 3 ߦ߽ߥࠆਛᕈሶᤊ߇ᒻᚑߐࠇࠆ㧚ߎࠇࠄߩ⃻⽎߇⑳ߚߜߣή✼߆ߣ޿߁ߣ᳿ߒߡߘ߁ߢߪߥ޿㧚㌁ᴡ♽ߢߪ߅ࠃߘ㧝㧜㧜ᐕߦ৻ᐲ⿥ᣂᤊ῜⊒߇⿠ߎࠅ㧘ᄥ㓁♽߽฽߼ߡ㌁ᴡ♽ߩోߡߩ႐ᚲ߇ⴣ᠄ᵄߩㅢ
ㆊࠍ⚻㛎ߒߡ޿ࠆߣ⸒ࠊࠇߡ޿ࠆ㧚㧞㧚ᤊߩ‛ℂߣᾲജቇ
ቝቮ‛ℂቇߪᕡᤊߩ⎇ⓥ߆ࠄᆎ߹ߞߚߣ޿ߞߡ
ㆊ⸒ߢߪߥ޿㧚ᣣᧄߢߎߩಽ㊁ߩ⎇ⓥ߇⊒ዷߒߚ⚻✲ߦߟ޿ߡߪᣣᧄ‛ℂቇળ⹹ߩ㧡㧜๟ᐕ⸥ᔨภ
ߦ⹦ߒߊㅀߴࠄࠇߡ޿ࠆ[2]㧚߹ߕ㧘ᕡᤊߩઍ⴫ߢ
޽ࠆᄥ㓁ߩユ኿㊂ߣ޿߁◲නߥ⹤߆ࠄߪߓ߼ࠃ߁㧚ᄥ㓁߆ࠄ࿾⃿ߦ㒠ࠅᵈߋࠛࡀ࡞ࠡ࡯ࡈ࡜࠶ࠢࠬߪ
޿ࠊࠁࠆᄥ㓁ቯᢙ㧘⚂ 2 cal/(cm2min) (1.4 kW/m2)ߢਈ߃ࠄࠇࠆ㧚ߎࠇߣᄥ㓁ߣ࿾⃿ߩᐔဋ〒㔌1.5 u 1011 m 㧔శߢ 500 s㧕߆ࠄᄥ㓁߇න૏ᤨ㑆ߦ᡼኿ߔࠆࠛࡀ࡞ࠡ࡯(ユ኿㊂) ߪL | 4 u 10 26 W              (1)ߣ᳞߼ࠄࠇࠆ㧚ߏሽ⍮ߩࠃ߁ߦᕡᤊߩࠛࡀ࡞ࠡ࡯
ߪਛᔃㇱߢߩᩭⲢว෻ᔕߢଏ⛎ߐࠇߡ޿ࠆ㧚ᓥߞ
ߡ⾰㊂ߣࠛࡀ࡞ࠡ࡯ߩห╬ᕈ E mc 2 ࠍ↪޿ࠆߣ㧘వߦ⸘▚ߒߚࠃ߁ߦᄥ㓁ߩユ኿㊂ (1) ߪ⤘ᄢߢ޽ࠅ㧘ࠛࡀ࡞ࠡ࡯ḮߣߒߡߩᩭⲢวߩน⢻ᕈࠍ⴫ߒߡ޿ࠆࠃ߁ߦ⷗߃ࠆ㧚ᧄᒰߦߘ߁ߛࠈ߁߆㧚ߘߎߢ㧘ߎߩ୯ࠍᄥ㓁ߩ⾰㊂ߢഀߞߡߺࠆߎߣߦߒ
ࠃ߁㧚ߔࠆߣ 1 kg ޽ߚࠅߩユ኿㊂ߪ 2 u 10 4 W/kgߣߐ߶ߤᄢ߈ߊߥ޿㧚Ყセߩߚ߼ߦੱ㑆ࠍ⠨߃ߡߺࠃ߁㧚㧝ᣣߩၮ␆ઍ⻢㊂ߪ⚂ 2000 kcal ߥߩߢੱ㑆ߪ⚂ 100 W ߩᾲḮߢ޽ࠆ㧚૕㊀ࠍ 50 kg ߣߔࠆߣ 1 kg ޽ߚࠅߩユ኿㊂ߪ 2 W/kg ߣߥࠅ㧘૗ߣੱ㑆ߩᣇ߇㧠ᩴᄢ߈޿ߩߢ޽ࠆ㧚න૏⾰㊂޽ߚࠅߩユ኿㊂ߢߩᲧセߣ޿߁ᣇᴺߦߪ⇣⺰߇޽ࠆ߆߽
ߒࠇߥ޿߇㧘ࠛࡀ࡞ࠡ࡯ḮߣߒߡߩᩭⲢวߩน⢻ᕈߦ⇼໧ࠍᛩߍ߆ߌࠆ୯ߛߣᗵߓߐߖࠄࠇࠆ㧚ߐࠄߦ⹦ߒߊᕡᤊߩ᭴ㅧ߿ㅴൻࠍ⼏⺰ߔࠆߚ߼ߦߪ㧘ౝㇱߢߩユ኿߿ኻᵹߦࠃࠆᾲャㅍ㧘ߔߥࠊߜવᾲߩ໧㗴ࠍᛒࠊߥߌࠇ߫ߥࠄߥ޿㧚ౕ૕⊛ߦߪ㧘㊀ജߣ࿶ജ൨㈩ߩࡃ࡜ࡦࠬࠍ⴫ߔ㕒᳓࿶ᐔⴧ㧘ਛᔃߢߩᩭⲢว෻ᔕߦࠃࠆࠛࡀ࡞ࠡ࡯↢ᚑ㧘ߘߒߡユ኿ߣኻᵹߦࠃࠆᾲャㅍࠍหᤨߦᢙ୯⊛ߦ⸃޿ߡ޿ࠆ㧘ߒ߆ߒ㧘ߎߎߢߪ߽ߞߣቯᕈ⊛ߥ⼏⺰ࠍ⚫੺ߔࠆߎߣߦߒࠃ߁㧚ᄥ㓁ߪ㧘⊕⦡⍵ᤊߣߒߡߘߩ↢ᶦࠍ⚳߃ࠆߎߣ߇⍮ࠄࠇߡ޿ࠆ㧚⊕⦡⍵ᤊߩਛᔃߢߪ߽ߪ߿ᩭⲢ
ว෻ᔕߪ⿠ߎߞߡ߅ࠄߕ㧘㔚ሶߩ❗ㅌ࿶ߢ⥄ಽ⥄りߩ㊀ജࠍᡰ߃ߡ޿ࠆ㧚❗ㅌ࿶ߦߟ޿ߡᱜߒߊℂ
⸃ߔࠆߚ߼ߦߪࡈࠚ࡞ࡒ⛔⸘ߦߟ޿ߡߩ⍮⼂߇ᔅⷐߢ޽ࠆ߇㧘ߎߎߢߪ⚿ᨐߣߒߡ࿶ജ p ߣኒᐲUߩ㑆ߦ޿ࠊࠁࠆᢿᾲᄌൻߩ㑐ଥJ

p v U                (2)ᄥ㓁ߢߪ㧝⑽㑆ߦ 4 u 10 9 kg ߩ⾰㊂߇ᶖ⾌ߐࠇߡ߇ᓧࠄࠇࠆߎߣߛߌࠍ↪޿ߡ⼏⺰ࠍㅴ߼ࠆ[3-5]㧚
੹ᓟߎߩ⁁ᘒᣇ⒟ᑼࠍࡐ࡝࠻ࡠ࡯ࡊ㑐ଥߣࠃ߱ߎ
ߣߦߔࠆ㧚 J ߪᢿᾲᜰᢙ㧔ᲧᾲᲧ㧕ߢ㔚ሶࠟࠬߩ޿ࠆߎߣ߇ࠊ߆ࠆ㧚ᄥ㓁ߩ⾰㊂ߪ 2 u 10 30 kg ߢ޽ࠆ߆ࠄ㧘ߎࠇࠍ㧝⑽޽ߚࠅߩᶖ⾌㊂ߢഀࠆߣᄥ㓁ߩኼ๮߇⸘▚ߢ߈ߘ߁ߢ޽ࠆ㧚ߒ߆ߒ㧘ߘߩ୯ߪታ
㓙ߩኼ๮ࠃࠅ㧟ᩴ߶ߤᄢ߈ߊߥߞߡߒ߹߁㧚㧠୘ߩ᳓⚛߆ࠄࡋ࡝࠙ࡓࠍߟߊࠆ㓙ߩ⾰㊂ᰳ៊߇

વᾲ 2006 ᐕ 1 ᦬

႐วߪ 5/3 ߢ޽ࠆ㧚ߒ߆ߒᤊߩ⾰㊂߇ᄢ߈ߊߥࠆ
ߣ㧘ਛᔃઃㄭߢߩ㔚ሶߩᐔဋࠛࡀ࡞ࠡ࡯߇㔚ሶߩ- 60 -J. HTSJ, Vol. 45, No. 190

ࡀࠗ࠴ࡖ࡯Qmass)ߣ๭߫ࠇߡ޿ࠆ[6]㧚⥃⇇⾰㊂ߩዉ಴ߪ੹ߣߥ
ߞߡߪߐ߶ߤ㔍ߒ޿߽ߩߢߪߥ޿㧚ߣߪ޿߃ࡈࠚ
࡞ࡒ⛔⸘ߣ㔚ሶߩ❗ㅌ࿶ߦߟ޿ߡᄙዋߩ⍮⼂߇ᔅⷐߥߩߢ㧘ߎߎߢߪ
2
3/ 2
§
·
¨ 1 ¸ §¨ h c ·¸
M ch | ¨| ᄥ㓁⾰㊂ߩ1.4୚
¨ m p ¸¸ ¨© 2S G ¸¹©
¹ߣ޿߁⚿ᨐߛߌࠍ⚫੺ߔࠆߦߣߤ߼ߡ߅ߊ[3,5]㧚
ߎߎߢ m p ߪ㓁ሶߩ⾰㊂㧘c ߪశㅦᐲߘߒߡ h ߪࡊ㕒ᱛࠛࡀ࡞ࠡ࡯ me c 2 ࠍ⿥߃ࠆ㧚ߎࠇࠍቝቮ‛ℂ
ߩಽ㊁ߢߪ㔚ሶࠟࠬ߇⋧ኻ⺰⊛⁁ᘒߦߥߞߚߣ޿
߁㧚ߎߩᤨ㧘㔚ሶࠟࠬߩᕈ⾰ߪశሶࠟࠬߦㄭߠ߈
J 4 / 3 ߦߥࠆߎߣ߇⍮ࠄࠇߡ޿ࠆ[3,4]㧚ߎߩᢿᾲᜰᢙߩᄌൻ߇⊕⦡⍵ᤊߩ቟ቯᕈߦ߅޿ߡ㕖Ᏹߦ㊀ⷐߥᓎഀࠍᨐߚߔ㧚M࡜ࡦࠢቯᢙ[7]ߢ޽ࠆ㧚㊂ሶ⺰( h )㧘⋧ኻᕈℂ⺰( c )ߘߒߡ㊀ജ (G) ࠍ․ᓽߠߌࠆၮᧄ⊛ߥ‛ℂቯᢙߩߺߢࡑࠢࡠߥሽ࿷ߢ޽ࠆᤊߩ⾰㊂߇ዉ߆ࠇߡ޿ࠆ㧚
ቝቮ‛ℂቇߩᢙ‫ߩޘ‬ᚑᨐߩਛߢ߽ᦨ߽⟤ߒ޿ᑼߢ޽ࠆ㧚Chandrasekhar ߩߎߩ⎇ⓥߪ 1930 ᐕઍߣߒߡߪ↹ᦼ⊛ߢ޽ࠅߔ߉ߚߚ߼㧘ߥ߆ߥ߆‛ℂቇ
⠪࡮ᄤᢥቇ⠪ߦฃߌ౉ࠇࠄࠇߥ߆ߞߚ㧚⋧ኻᕈℂ⺰߿ᄤᢥቇߩ╙৻ੱ⠪ߢ޽ߞߚ Eddington ෌߇ࡠࡦ࠼ࡦߩ₺┙ᄤᢥቇදળߢ Chandrasekhar ߩ⎇ⓥࠍᛕ್ߔࠆ⻠Ṷࠍߒߚߎߣߪ᦭ฬߢ޽ࠆ[6]㧚

R࿑ 1ߎߎߢ࿑㧝ߩࠃ߁ߥඨᓘ R 㧘⾰㊂ M ߩᤊࠍ⠨߃ࠃ߁㧚ᤊߩ᭴ㅧߪ㊀ജߣ࿶ജ൨㈩ߩߟࠅ޽޿㧔㕒᳓࿶ᐔⴧ㧕ߢ᳿߹ࠆ㧚ߟ߹ࠅ⥄Ꮖ㊀ജࠍ࿶ജߢᡰ
߃ࠆࠊߌߢ޽ࠆ㧚ᧄᒰߪ࿶ജ൨㈩ߢᡰ߃ࠆߩߢ޽
ࠆ߇㧘⹤ࠍ◲නߦߔࠆߚ߼ኒᐲߣ࿶ജߪ৻ቯߣߔ
ࠆ㧚ߎߩ႐ว㧘㕒᳓࿶ᐔⴧߩ᧦ઙߪ㧘⊕⦡⍵ᤊߩ࿶ജࠍߦߥ߁㔚ሶࠟࠬߩౝㇱࠛࡀ࡞ࠡ࡯ߣ㊀ജࠛࡀ࡞ࠡ࡯ߩᄢ߈ߐ߇ห⒟ᐲߢ޽ࠆߎߣࠍ␜ߔ
GM 2
p R3 |
R
ߣ޿߁ᑼߢ⴫ߔߎߣ߇ߢ߈ࠆ㧚ߎߎߢ G ߪ㊀ജቯᢙߢ޽ࠆ㧚߹ߚඨᓘ߇ᄌൻߒߡ߽ᤊߩ⾰㊂ߪ
M | U R 3 | ৻ቯ ߣ଻ߚࠇࠆ㧚ߎࠇࠄ㧞ߟߩ㑐ଥᑼ߆

㧟㧚㊀ജᄙ૕♽ߩᲧᾲߎߎ߹ߢ㧘ᾲജቇ㧘⛔⸘ജቇߘߒߡᵹ૕ജቇߣ
ቝቮ‛ℂߣߩ㑐ࠊࠅߦߟ޿ߡ⺑᣿ߒߡ߈ߚ㧚ቝቮߢߪᣣᏱߣߪ߆ߌ㔌ࠇߚࠬࠤ࡯࡞ߢߩ⃻⽎߇⃻ࠇࠆ㧚ߘߩ߅߆ߍߢ‛ℂᴺೣߩᧄ⾰߇ᶋ߆߮਄߇ߞ
ߡ᧪ࠆߎߣ߇ᄢ߈ߥ㝯ജߢ޽ࠆ㧚ߣ޿ߞߡ㧘ߘߎߢ⊓႐ߔࠆᾲജቇࠍᆎ߼ߣߔࠆ‛ℂᴺೣ߇㧘ᣣᏱߩ‛ℂ⃻⽎ࠍℂ⸃ߔࠆߚ߼ߩ߽ߩߣᄢ߈ߊ⇣ߥࠆߩ߆ߣ޿߁ߣᔅߕߒ߽ߘ߁ߢߪߥ޿㧚‛ℂ㊂߇ᭂ
㒢⊛ߥ୯ࠍขࠆߩߢ޽ߞߡ㧘ᴺೣ⥄૕߇ᄢ߈ߊᄌ
ᦝߐࠇߡ޿ࠆ⸶ߢߪߥ޿㧚ࠄ p v U 4 / 3 ߇ዉ߆ࠇࠆ㧚ߎࠇߪᤊߩ⥄Ꮖ㊀ജߪኒᐲᄌൻߦኻߒߡ J

4 / 3 ߩࠟࠬߣหߓ߰ࠆ߹޿ࠍ

ߔࠆߎߣࠍ␜ໂߒߡ߅ࠅ㧘ቝቮ‛ℂߩಽ㊁ߢߪ“㊀ജߩ Ȗ ߪ 4/3”ߣ⴫⃻ߐࠇࠆ㧚ߚߛߒ㧘 J 4 / 3 ߩࠟࠬ߇⥄Ꮖ㊀ജߣߟࠅ޽߁ߎߣࠍᗧ๧ߔࠆࠊߌߢߪ
ߥ޿㧚߻ߒࠈㅒߢ޽ࠆ㧚 J 4 / 3 ߩࠟࠬߩ႐ว㧘૗ࠄ߆ߩේ࿃ߢ෼❗߇ᆎ߹ࠆߣኒᐲߩ਄᣹ߦࠃࠆ࿶
ജߩჇടߣ㊀ജߩჇട߇หߓߥߩߢ෼❗ࠍ㘩޿ᱛ߼ࠆߎߣ߇ߢ߈ߥ޿㧚৻ᣇ㧘J 5 / 3 ߩࠟࠬߩ႐ว㧘࿶ജߩჇടߩᣇ߇㊀ജࠃࠅᄢ߈޿ߩߢ㧘෼❗ࠍ㘩޿ᱛ߼ࠆߎߣ߇ߢ߈ࠆ㧚ᓥߞߡᤊ߇቟ቯߦሽ࿷ߔ
ࠆߚ߼ߦߪ㧘࿶ജߩේ࿃ߣߥߞߡ޿ࠆࠟࠬߩᢿᾲ
ᜰᢙ߇ J ! 4 / 3 ߢߥߌࠇ߫ߥࠄߥ޿㧚ߎߎߢ㧘⊕⦡⍵ᤊࠍᡰ߃ߡ޿ࠆ㔚ሶࠟࠬߩ႐ว㧘ᤊߩ⾰㊂߇ᄢ߈ߊߥࠆߣ㔚ሶࠟࠬߩᐔဋࠛࡀ࡞ࠡ
࡯߇㔚ሶߩ㕒ᱛࠛࡀ࡞ࠡ࡯ࠍ⿥߃㧔⋧ኻ⺰⊛ߦߥࠆ㧕J 4 / 3 ߦߥߞߚߎߣࠍᕁ޿ߛߘ߁㧚ߔࠆߣ㔚ሶߩ❗ㅌ࿶ߢᡰ߃ࠆߎߣ߇ߢ߈ࠆ⾰㊂ߦ਄㒢߇޽ࠆߎߣߦ᳇ߠߊߛࠈ߁㧚ߎߩ⥃⇇⾰㊂ߪ⊒⷗⠪ߦߜ ߥ ߺ ࠴ ࡖ ࡦ ࠼ ࡜ ࠮ ࠞ ࡯ ࡞ ⾰ ㊂ (Chandrasekharવᾲ 2006 ᐕ 1 ᦬

࿑ 2- 61 -J. HTSJ, Vol. 45, No. 190

ࡀࠗ࠴ࡖ࡯Q
ߣߎࠈ߇㊀ജ߇ᧄ⾰⊛ߥᓎഀࠍᨐߚߔ႐วߦߪ
੐ᖱ߇⇣ߥߞߡߊࠆ㧚ߎߎߢߪ⃿⁁ᤊ࿅ߣ޿߁
100 ਁ୘޽߹ࠅߩᤊߩ㓸࿅ࠍ⠨߃ࠃ߁㧚࿑㧞ߪࡋ࡜ࠢ࡟ࠬᐳߦ޽ࠆ㧹㧝㧟ߣ޿߁ઍ⴫⊛ߥ⃿⁁ᤊ࿅ߢ޽ࠆ㧚ߎߩ♽ߪ㊀ജߩߺߢ⋧੕૞↪ߔࠆ⾰ὐ♽ߣ⷗ߥߖࠆߩߢ㊀ജᄙ૕♽ߣࠃ߫ࠇߡ޿ࠆ㧚㊀ജ߇㐳〒㔌ജߢ޽ࠅ㧘ߒ߆߽ࠢ࡯ࡠࡦജߣ⇣ߥࠅߟߨߦᒁജߢ޽ࠆߎߣ߆ࠄ㊀ജᄙ૕♽ߩᾲജቇ⊛ᕈ⾰ߪㅢᏱߩࠟࠬߣᄢ߈ߊ⇣ߥࠆߎߣߪኈᤃߦᗐ௝
ߢ߈ࠆߛࠈ߁㧚ታߪ㊀ജᄙ૕♽ߩᲧᾲߪ⽶ߥߩߢ޽ࠆ㧚ߘߩߚ߼ߎߩ♽ߦߪ޿ࠊࠁࠆᾲᐔⴧ⁁ᘒ߇ሽ࿷ߒߥ޿㧚

ߒߡ᰼ߒ޿㧚ᰴߦ㧘ੱᎿⴡᤊ߇ᄢ᳇ߦࠃࠆᛶ᛫ࠍ
ฃߌߡ޿ࠆߣߒࠃ߁㧚ߎߩ႐ว㧘ోࠛࡀ࡞ࠡ࡯ߪ
଻ሽߒߥߊߥࠆ߇㧘ࡆ࡝ࠕ࡞㑐ଥ(4)ߪㄭૃ⊛ߦᚑࠅ┙ߟߎߣ߇⍮ࠄࠇߡ޿ࠆ㧚ⓨ᳇ᛶ᛫ߦࠃࠆᓸዋ
ߥోࠛࡀ࡞ࠡ࡯ߩ៊ᄬࠍ 'E ߢ⴫ߔߣ߹ߕ㧘⽶ߩᲧᾲࠍℂ⸃ߔࠆߚ߼ߩ◲නߥ଀ߣߒߡ
࿑㧟ߩࠃ߁ߥ࿾⃿ߩ๟࿐ࠍ࿁ࠆੱᎿⴡᤊߩ╬ㅦ౞ㆇേࠍ⠨߃ߡ㗂߈ߚ޿㧚 ߽ߜࠈࠎ㧝ߟߩ‛૕ߩㆇേߥߩߢ㧘਄ߩ଀ߦߪ
᷷ᐲߣ޿߁᭎ᔨߪߥ޿㧚៺ᡂߦࠃࠅోࠛࡀ࡞ࠡ࡯
߇ᷫዋߔࠆߦ߽߆߆ࠊࠄߕ㧘ㆇേࠛࡀ࡞ࠡ࡯ߪჇ
ടߔࠆ⃻⽎ࠍ̌⽶ߩᲧᾲ̍ߣᲧ༙ߒߚߛߌߢ޽ࠆ㧚ᧄᒰߩᗧ๧ߢߩ⽶ߩᲧᾲߪ㧘ᤊߩ㓸࿅ߢ޽ࠆ⃿⁁ᤊ࿅㧔㊀ജᄙ૕♽㧕ߦ߅޿ߡ⃻ࠇࠆ㧚ߎߩ႐ว㧘K
ߪ♽ߩోㆇേࠛࡀ࡞ࠡ࡯ߢ޽ࠆ㧚ߘߒߡ K ߪ⃿⁁ᤊ࿅ߩ᷷ᐲߦᲧ଀ߔࠆߣ⠨߃ߡࠃ޿㧚ੱᎿⴡᤊߩ
⼏⺰ߢߪࡆ࡝ࠕ࡞㑐ଥ߇㊀ⷐߥᓎഀࠍᨐߚߒߡ޿
ߚߎߣࠍᕁ޿಴ߒߡ᰼ߒ޿㧚㊀ജᄙ૕♽ߦኻߒߡ߽ࡆ࡝ࠕ࡞㑐ଥ (4) ߪ৻⥸⊛⁁ᴫߢᚑ┙ߔࠆߎߣ߇⍮ࠄࠇߡ޿ࠆ[8]㧚ᓥߞߡ㧘⃿⁁ᤊ࿅ߦߟ޿ߡ
߽(6)ᑼ߇ᚑ┙ߒ㧘Ყᾲ߇⽶ߢ޽ࠆߎߣ߇␜ߐࠇࠆ㧚

'K

 'E

(6)

ߣᓸዋᄌൻ㊂ߦߟ޿ߡ߽ (5) ߣห᭽ߩᑼ߇ዉ߆ࠇ
ࠆ㧚ߎߩᑼߪᄢ᳇࿤ߦ⓭౉ߒߚੱᎿⴡᤊ߇ⓨ᳇ᛶ᛫ࠍฃߌࠆߎߣߢᷫㅦߢߪߥߊㅒߦടㅦߐࠇࠆߎ
ߣࠍ␜ߒߡ޿ࠆ㧚㊀ജ♽ߦ߅޿ߡ̌⽶ߩᲧᾲ̍߇
⃻ࠇࠆᦨ߽◲නߥ଀ߢ޽ࠆ㧚

v
m
M
R
࿑ 3
ੱᎿⴡᤊߩㆇേᣇ⒟ᑼߪ
v 2 GMm             (3)mR
R2ߢਈ߃ࠄࠇࠆ㧚ߎߎߢੱᎿⴡᤊߩㆇേࠛࡀ࡞ࠡ࡯
ߣ㊀ജࠛࡀ࡞ࠡ࡯ࠍ
K

m 2
v , V
2



GMm
R

ߣߔࠆߣ(3)ࠃࠅࡆ࡝ࠕ࡞㑐ଥ
2K  V

(4)

0

࿑ 4

߇ᓧࠄࠇࠆ㧚ߎߎߢੱᎿⴡᤊߩోࠛࡀ࡞ࠡ࡯
E K  V ߦ਄ߩࡆ࡝ࠕ࡞㑐ଥ (4) ࠍઍ౉ߒ V ࠍ
ᶖ෰ߔࠆߣ
K

E

( E  0)㧠㧚㊀ജᾲജቇ⊛ਇ቟ቯᕈ
ߢߪ⃿⁁ᤊ࿅ߪߤߩࠃ߁ߦㅴൻߔࠆߛࠈ߁߆㧚ታߪ⃿⁁ᤊ࿅ߢߪ⥄Ꮖ㊀ജ߇ലߊਛᔃઃㄭ㧔ࠦࠕ㧕ߪ⽶ߩᲧᾲࠍ߽ߟߩߦኻߒ㧘ߘߩ๟ㄝㇱ㧔ࡂࡠ࡯㧕ߪᲧᾲ߇ᱜߩᾲജቇ⊛ߦᱜᏱߥ♽ߢ޽ࠆߎߣ߇⍮ࠄࠇߡ޿ࠆ㧔࿑㧠㧕

(5)߇ᓧࠄࠇࠆ㧚ੱᎿⴡᤊߪ࿾⃿ߩ㊀ജߦ᧤❈ߐࠇߡ޿ࠆߩߢోࠛࡀ࡞ࠡ࡯ E ߪ⽶ߢ޽ࠆߎߣߦᵈᗧવᾲ 2006 ᐕ 1 ᦬- 62 -J. HTSJ, Vol. 45, No. 190

ࡀࠗ࠴ࡖ࡯Q ߘߩߚ߼᷷ᐲߩ㜞޿ਛᔃㇱ㧔ࠦࠕ㧕߆ࠄ᷷ᐲߩ
ૐ޿๟ㄝㇱ㧔ࡂࡠ࡯㧕ߦᾲ߇ᵹࠇࠆߣ㧘ਛᔃㇱߩ᷷ᐲߪ߹ߔ߹ߔ਄᣹ߒ㧘ߐࠄߦᄙߊߩᾲ߇ᵹࠇࠆ
ߎߣߦߥࠆ㧚ߎࠇ߇㊀ജᾲജቇ⊛ਇ቟ቯᕈߢ޽ࠆ㧚ਛᔃㇱߪ᷷ᐲ਄᣹ߣߣ߽ߦኒᐲ߽਄᣹ߔࠆ㧘ࠦࠕ෼❗ߣ޿߁ㅴൻࠍ␜ߔ㧚⹤ࠍరߦᚯߘ߁㧚㊀ജᾲജቇ⊛ਇ቟ቯᕈߦࠃࠆ
ࠦࠕ෼❗ߪ޿ߟ߹ߢ߽⛯߈⃿⁁ᤊ࿅ߩਛᔃㇱߩኒᐲߪ߿߇ߡ⊒ᢔߔࠆߩߛࠈ߁߆㧚࿑㧡ߢߪࠦࠕ෼
❗ߒߚ⃿⁁ᤊ࿅ߩኒᐲಽᏓࠍ⚫੺ߒߚ߇㧘ታߪࠦࠕ෼❗ࠍ␜ߐߥ޿⃿⁁ᤊ࿅߽ᢙᄙߊ᷹ⷰߐࠇߡ޿
ࠆ㧚ਛᔃㇱ߇㜞ኒᐲߦߥࠆߣㅪᤊ߇ᒻᚑߐࠇࠆߎ
ߣ߇㊀ⷐߢ޽ࠆ㧚ㅪᤊߩறࠍ╙㧟ߩᤊ߇ㅢㆊߔࠆ
ߣߒࠃ߁㧚ߘߩߣ߈ㅪᤊߪࠃࠅᒝߊ⚿วߒ㊀ജࡐ࠹ࡦࠪࡖ࡞ߩᷓ޿⁁ᘒߦ⒖ⴕߒ㧘૛ߞߚࠛࡀ࡞ࠡ
࡯ࠍ╙㧟ߩᤊߦਈ߃ࠆ㧚ߎߩࡔࠞ࠾࠭ࡓߦࠃࠅㅪ
ᤊߪᾲḮߣߒߡ߰ࠆ߹߁ߩߢ޽ࠆ㧚⃿⁁ᤊ࿅ߩਛᔃㇱߪᲧᾲ߇⽶ߢ޽ߞߚߎߣࠍᕁ޿಴ߘ߁㧚ߘߩߚ߼ㅪᤊ߆ࠄᵈ౉ߐࠇߚᾲߦࠃߞߡਛᔃㇱߩ᷷ᐲߪਅ߇ࠅ㧘ࠦࠕߩ෼❗ߪᱛ߼ࠄࠇࠆ㧚ߎߩߣ߈ࠦ
ࠕㄭறߢߪ✭߿߆ߢߪ޽ࠆ߇ਛᔃ߶ߤ᷷ᐲ߇ૐ޿
ߣ޿߁ㅒߩ᷷ᐲ൨㈩߇ᒻᚑߐࠇߡ޿ࠆ㧚ߘߩߚ߼๟ㄝㇱ߆ࠄਛᔃߦะ߆ߞߡᾲ߇ᵹࠇࠦࠕ߇⤘ᒛߔࠆߣ޿߁ㅒะ߈ߩ㊀ജᾲജቇ⊛ਇ቟ቯᕈ߇ㅴⴕߔ
ࠆ㧔㊀ജᾲജቇ⊛⤘ᒛ㧕㧚࿑ 5࿑㧡ߪࠦࠕ෼❗ߒߚ⃿⁁ᤊ࿅ߩ᷹ⷰ଀ߢ޽ࠆ㧚❑ゲߪኒᐲ㧘ᮮゲߪਛᔃ߆ࠄߩ〒㔌ࠍኻᢙ⋡⋓ߢࡊࡠ࠶࠻ߒߚ߽ߩߢ޽ࠆ㧚ਛᔃߦㄭߠߊ߶ߤࡌࠠ⊛ߦኒᐲࠍᄢ߈ߊߥߞߡ޿ࠆ㧚ㅢᏱߩ♽ߢ޽ࠇ᷷߫
ᐲᏅ߇↢ߓࠇ߫ᾲ߇ᵹࠇ᷷ᐲᏅࠍߥࠄߒ᷷ᐲ߇৻
᭽ߥ㧘޿ࠊࠁࠆᾲᐔⴧߦᦨ⚳⊛ߦ⪭ߜ⌕ߊ㧚৻ᣇ㧘⃿⁁ᤊ࿅ߢߪᲧᾲ߇⽶ߩਛᔃㇱߢ᷷ᐲ਄᣹ߣ෼❗
߇⛯߈㧘♽ߪᾲᐔⴧߣߪోߊ⇣ߥࠆࠦࠕ࡮ࡂࡠ࡯
᭴ㅧߣ޿߁⁁ᘒ߳ㅴൻߔࠆߩߢ޽ࠆ㧚ߎߩࠃ߁ߦ
㊀ജ߇ᧄ⾰⊛ߥᓎഀࠍᨐߚߔ♽ߢߪ㧘ᾲᐔⴧߣ޿
߁ᾲജቇߢߩᦨ߽ၮᧄ⊛ߥ᭎ᔨߔࠄᄌࠊߞߡߒ߹
߁ߩߢ޽ࠆ㧚

਄ߩㅒะ߈ߩ᷷ᐲ൨㈩ߪਛᔃઃㄭߦ㒢ቯߐࠇߡ޿ߚ㧚߹ߚਛᔃߦ޽ߞߚㅪᤊ߽㧘╙㧟ߩᤊߦࠛࡀ
࡞ࠡ࡯ࠍਈ߃ߚߣ߈ߩ෻૞↪ߢ߿߇ߡࠦࠕ߆ࠄ㘧߮಴ߒߡ޿ߊ㧚ߎ߁ߒߡ㊀ജᾲജቇ⊛⤘ᒛߪ⚳ࠊࠅࠍ๔ߍࠆ㧚ߘߒߡࠦࠕ߆ࠄࡂࡠ࡯߳ᾲ߇ᵹࠇ㧘ࠦࠕ߇෼❗ߔࠆ㊀ജᾲജቇ⊛ਇ቟ቯᕈ߇ౣ߮ᆎ߹
ࠆߩߢ޽ࠆ㧚ߎߩࠃ߁ߦߒߡ⃿⁁ᤊ࿅ߪࠦࠕߩ෼
❗ߣ⤘ᒛࠍ➅ࠅ㄰ߒߡ޿ࠆߣ⠨߃ࠄࠇߡ޿ࠆ㧚࿑㧢ߪ⃿⁁ᤊ࿅ߩㅴൻࠍ㧺૕ᢙ୯ࠪࡒࡘ࡟࡯࡚ࠪࡦ
ߢ⺞ߴߚ⚿ᨐߢ޽ࠆ㧚❑ゲߪਛᔃኒᐲ㧔ኻᢙ⋡⋓㧕ߢ޽ࠆ㧚☸ሶᢙ㧺ߪ 2000 ߆ࠄ 32000 ߣ⃻ታߩ⃿⁁ᤊ࿅ߦᲧߴࠆߣ߆ߥࠅዋߥ޿߇㧘ᾲജቇ⊛ਇ቟ቯᕈߦࠃࠅࠦࠕ߇ᝄേߔࠆߎߣࠍ⷗੐ߦ␜ߒߡ޿
ࠆ㧚ߚߛߒᝄേߩᤨ㑆ࠬࠤ࡯࡞ߪᢙ㧝㧜ంᐕߦ⋧ᒰߔࠆߚ߼㧘⃿⁁ᤊ࿅ߢታ㓙ߦߎߩᝄേࠍ᷹ⷰߔ
ࠆߎߣߪߢ߈ߥ޿㧚ߒ߆ߒ㧘వߦㅀߴߚࠃ߁ߦ࿑
㧡ߩࠃ߁ߥࠦࠕ෼❗ߒߚ⃿⁁ᤊ࿅ߣࠦࠕ෼❗ߒߡ޿ߥ޿⃿⁁ᤊ࿅߇ਔᣇ᷹ⷰߐࠇࠆߎߣߪࠦࠕߩᝄ
േߩ㑆ធ⊛ߥ⸽᜚ߛߣ⠨߃ࠄࠇߡ޿ࠆ㧚ᾲജቇ╙㧞ᴺೣ߇᳇ߦߥࠆᣇ߽ᄙ޿ߛࠈ߁㧚⥄Ꮖ㊀ജ♽ߛ߆ࠄߣ޿ߞߡ╙㧞ᴺೣ߇⎕ࠇߡ޿ࠆࠊߌ
ߢߪߥ޿㧚ࠦࠕ࡮ࡂࡠ࡯᭴ㅧ߇ᚑ㐳ߔࠆㆊ⒟ߢࠛ
ࡦ࠻ࡠࡇ࡯ߪߟߨߦჇടߒߡ޿ࠆ㧚Ყᾲ߇ᱜߩㅢ
Ᏹߩ♽ߢ޽ࠇ᷷߫ᐲ߇৻᭽ߥᾲᐔⴧ⁁ᘒ߇ࠛࡦ࠻
ࡠࡇ࡯ߩᭂᄢߢ޽ߞߚ㧚ߣߎࠈ߇㊀ജᄙ૕♽ߩࠃ߁ߥᲧᾲ߇⽶ߩ♽ߢߪࠛࡦ࠻ࡠࡇ࡯ᭂᄢ⁁ᘒ߇ሽ࿷ߒߥ޿ߩߢ޽ࠆ㧚ࠦࠕ߆ࠄࡂࡠ࡯߳ᾲࠍᵹߔߎ
ߣߢࠦࠕ෼❗߇ㅴߺ㧘♽ߪࠃࠅࠛࡦ࠻ࡠࡇ࡯ߩᄢ
߈ߥ⁁ᘒߦㅴൻߒߡࠁߊ㧚૛⺣ߢ޽ࠆ߇㧘ᾲജቇ
╙㧞ᴺೣߦ㑐ㅪߒߡ̌ቝቮߩᾲᱫ̍߇⼏⺰ߐࠇࠆવᾲ 2006 ᐕ 1 ᦬ߎߣ߇ࠃߊ޽ࠆ㧚᷷ᐲᏅ߇޽ࠆߣᾲ߇ᵹࠇ㧘ቝቮߪ߿߇ߡ޿ߚࠆߣߎࠈ᷷ᐲ߇৻ቯߩᾲᐔⴧ⁁ᘒߦ㒱ߞߡߒ߹߁㧚ߘࠇߪ߽ߪ߿᭴ㅧ߽ㅴൻ߽ߥ޿̌ᾲ
ᱫ̍ߩ⁁ᘒߢ޽ࠆ㧘ߣ޿߁⠨߃ᣇߢ޽ࠆ㧚ߒ߆ߒ㧘ߘߩࠃ߁ߥᔃ㈩ࠍߔࠆᔅⷐߪߥ޿㧚ቝቮߢߩ⻉⃻⽎ߢߪ⃿⁁ᤊ࿅ߣห᭽ߦ㊀ജ߇ᧄ⾰⊛ߥᓎഀࠍᨐ
ߚߒߡ޿ࠆ㧚ᓥߞߡ㧘᭴ㅧࠍㅧࠅߥ߇ࠄቝቮߩࠛ
ࡦ࠻ࡠࡇ࡯ߪ㓙㒢ߥߊჇടߒߡ޿ߊߩߢ޽ࠆ㧚- 63 -J. HTSJ, Vol. 45, No. 190

ࡀࠗ࠴ࡖ࡯Qෳ⠨ᢥ₂

[1] M. Sakagami, H. Yoshida, K. Takano, W. Kitazato,
K. Kanamaru, M. Saito, H. Iwai and K. Takeishi,
Black Hole and Hawking Radiation in Laval
Nozzle, Extended Abstract, pp. 218-219,
CD-ROM, 3-b-11, ExHFT-6 (2005).
[2] ᄤ૕‛ℂℂ⺰ -- ੩ᄢᄤ૕ᩭ⎇ⓥቶߩ⿷〔߆ࠄ--http://wwwsoc.nii.ac.jp/jps/jps/butsuri/50th/nofr
ame/50(3)/50th-p172.html[3] ૒⮮ᢥ㓉㧘ጤᵄ⻠ᐳ⃻ઍߩ‛ℂቇ㧝㧝‫ޟ‬ቝቮ
‛ℂ‫ޠ‬ጤᵄᦠᐫ(1995)㧘㧝㧙㧟▵[4] ࡜ࡦ࠳࠙㧘࡝ࡈࠪ࠶࠷㧘⛔⸘‛ℂቇ㧔਄㧕ጤᵄᦠᐫ(1980)㧘§58,§61[5] ࡜ࡦ࠳࠙㧘࡝ࡈࠪ࠶࠷㧘⛔⸘‛ℂቇ㧔ਅ㧕ጤᵄᦠᐫ(1980)㧘§106-§107[6] K࡮࠰࡯ࡦ㧘ࡉ࡜࠶ࠢࡎ࡯࡞ߣᤨⓨߩᱡߺ㧘⊕
឴␠(1997) ╙㧠┨[7] ౞ጊ㊀⋥㧘વᾲ㧘Vol.44 No.186 (2005) p44[8] J. Binney and S. Tremaine, Galactic Dynamics,
Princeton Univ. Press (1985)[9] M. Sakagami and A. Taruya, Continuum
Mechanics and Thermodynamics 16 (2004) p.279

࿑ 6㧡㧚߹ߣ߼ߣᦨㄭߩ⹤㗴ߎߎ߹ߢㅀߴߡ߈ߚࠃ߁ߦ㧘ቝቮߪᣣᏱߣߪ߆
ߌ㔌ࠇߚ⃻⽎ࠍ⑳ߚߜߦ၂㑆⷗ߖߡߊࠇࠆ㧚ታ㛎ቶߢߪታ⃻ߢ߈ߥ޿ᭂ㒢⊛ߥ⁁ᴫࠍḰ஻ߒ㧘ߐ߹ߑ߹ߥ‛ℂᴺೣߩᧄ⾰ࠍ⷗ߖߡߊࠇࠆ㧚ߒ߆ߒ㧘⃿⁁ᤊ࿅ߩࠃ߁ߥ㊀ജ߇ᧄ⾰⊛ߥᓎഀࠍᨐߚߔ♽ߢߪ㧘ࠬࠤ࡯࡞߇߆ߌ㔌ࠇߡ޿ࠆߛߌߢߥߊ㧘ᾲജቇߩࠃ߁ߥ‛ℂߩၮᧄ⊛ᨒ⚵ߺߦኻߒߡߘߩ⷗
⋥ߒࠍߖ߹ࠆߩߢ޽ࠆ㧚ㅢᏱߩ♽ߢ޽ࠇ᷷߫ᐲᏅ
߇޽ࠆߣᾲࠍᵹߒ᷷ᐲ߇৻᭽ߥᾲᐔⴧ⁁ᘒߦ♽ߪㅴൻߔࠆ㧚ᓥߞߡ૗ࠄ߆ߩ᭴ㅧߪႺ⇇᧦ઙ╬ߩᄖ⊛ⷐ࿃ߦࠃࠅㅧࠄߥߊߡߪߥࠄߥ޿㧚৻ᣇ㧘⽶ߩᲧᾲࠍ߽ߟ㊀ജ♽ߢߪ㧘ᄖ⊛ⷐ࿃ߦ㗬ࠄߕߦౝㇱߦࠦࠕ࡮ࡂࡠ࡯᭴ㅧࠍᒻᚑߔࠆߎߣ߇ߢ߈ࠆ㧚ߎߩ⃻⽎ߪ㧘ࡂࡠ࡯ߣ޿߁ࠛࡀ࡞ࠡ࡯߿ࠛࡦ࠻ࡠࡇ
࡯ߩᝥߡ႐ࠍ♽ߩౝㇱߦߺߕ߆ࠄ↪ᗧߔࠆߎߣߢ
ਛᔃㇱߩࠦࠕ߇ㅴൻߒߡ޿ߊߣ⸃㉼ߢ߈ࠆ㧚ߐࠄߦ㧘ㅪᤊ♽ߩࠃ߁ߥᾲḮࠍ⥄⊒⊛ߦㅧࠆߎߣ߽ㅢ
Ᏹߩ♽ߢߪ଀ߩߥ޿⥝๧ᷓ޿ᕈ⾰ߢ޽ࠆ㧚 ߎߩࠃ߁ߦ⃿⁁ᤊ࿅ߦઍ⴫ߐࠇࠆ㊀ജᄙ૕♽ߪ㧘Ყᾲ߇⽶ߢ޽ࠆߚ߼㧘ߘߩㅴൻߪᧄ⾰⊛ߦ㕖ቯᏱ㕖ᐔⴧߢ޽ࠆ㧚ߘߩߚ߼ቯᕈ⊛ߥℂ⸃ߪߎߎ߹ߢ
⺑᣿ߒߡ߈ߚ㊀ജᾲജቇ⊛ਇ቟ቯᕈߢℂ⸃ߢ߈ࠆ߇㧘ቯ㊂⊛ߥ⼏⺰ߦߟ޿ߡߪᢙ୯ࠪࡒࡘ࡟࡯࡚ࠪ
ࡦߒ߆᦭ലߥᣇᴺ߇ή޿ߣ⠨߃ࠄࠇߡ߈ߚ㧚ߒ߆ߒᦨㄭ㧘╩⠪ߪ౒ห⎇ⓥ⠪ߣ Tsallis ⛔⸘ߣࠃ߫ࠇ
ࠆ㕖ടᴺ⊛ࠛࡦ࠻ࡠࡇ࡯ࠍ↪޿ߚᨒ⚵ߺ߇㊀ജᄙ૕♽ߩḰቯᏱ⁁ᘒߩㅴൻࠍ⸥ㅀߔࠆߩߦ᦭ലߢ޽
ࠆน⢻ᕈࠍ␜ߒߡ޿ࠆ㧚ߎߩ⹤㗴ߦߟ޿ߡߪ⑳ߚߜߩ࡟ࡆࡘ࡯=?ࠍߏⷩ޿ߚߛ߈ߚ޿㧚

વᾲ 2006 ᐕ 1 ᦬- 64 -

㒋਄ 㓷ᤘ
㧝㧥㧡㧣ᐕᄢ㒋Ꮢ↢߹ࠇ㧚ᄢ㒋ᄢቇℂቇㇱතᬺ㧘ᄢ㒋ᄢቇᄢቇ㒮ℂቇ⎇ⓥ⑼ୃੌ㧔ℂቇඳ჻㧕㧚⑔੗ᄢቇᢎ⢒ቇㇱഥᢎ᝼ࠍ⚻ߡ㧘⃻࿷㧘੩ㇺᄢቇᄢቇ㒮ੱ㑆࡮ⅣႺቇ⎇ⓥ⑼ᢎ᝼㧚ኾ㐷ߪ‛ℂቇ㧚ߥ߆ߢ߽㊀ജ㧘⋧ኻᕈℂ⺰㧘ቝቮ‛ℂ㧘㕖✢ᒻ‛ℂߥ
ߤߩಽ㊁ߢ⎇ⓥࠍ߅ߎߥߞߡ޿ࠆ㧚

J. HTSJ, Vol. 45, No. 190

ࡊࡠࠫࠚࠢ࠻ Qࡊࡠࠫࠚࠢ࠻ QᄙᲑ⫳᳇ࠗࡦࠫࠚࠢ࠲ߩ㐿⊒ߣવᾲDevelopment of Multi-Stage Steam Injectors with Innovative Heat-Transferᄹ⦟ᨋ㩷 ⋥䋨ർᄢ䋩䋬᫪㩷 ᴦ༹䋨᧲㔚䋩
Tadashi NARABAYASHI (Hokkaido University), Michitsugu MORI (TEPCO)㧝㧚ߪߓ߼ߦ ⫳᳇ࠗࡦࠫࠚࠢ࠲(SI)ߪ⫳᳇ߣ᳓ߢ૞േߔࠆྃ
ᵹࠫࠚ࠶࠻ࡐࡦࡊߢ޽ࠆ㧚⫳᳇ߩ⿥㖸ㅦྃᵹ߇᳇
⋧ਛߦྃ኿ߐࠇߚ᳓ྃᵹߩ⴫㕙ߦಝ❗ߔࠆ㓙ߦ᳓ྃᵹࠍടㅦߔࠆ㧚ฎߊߪ⫳᳇ᯏ㑐ゞߩࡏࠗ࡜࡯߳
ߩ⛎᳓ࡐࡦࡊߣߒߡ↪޿ࠄࠇߡ޿ߚ㧚⫳᳇ࠗࡦࠫࠚࠢ࠲ߪྃᵹࡐࡦࡊߣߒߡߩ૞↪ߩ߶߆㧘ఝࠇߚ⋥ធធ⸅ᑼᾲ੤឵ེߣߒߡߩ↪ㅜ߽޽ࠆ㧚⪺⠪ࠄߪ㧘ߎߩ࠲ࠗࡊߩ⫳᳇ࠗࡦࠫࠚࠢ࠲ߩࡐࡦࡊ૞↪
߿વᾲᕈ⢻ะ਄ߩߚ߼㧘᳢↪ᵹേ⸃ᨆࠦ࡯࠼ߦಽ
㔌ੑ⋧ᵹࡕ࠺࡞ࠍ⚵ߺㄟߺ㧘࡟࡯ࠩ࡯࠼࠶ࡊ࡜࡯ᵹㅦ⸘(LDV)߿ᭂ⚦✢ᒏᒻᾲ㔚ኻࠍ↪޿ߚนⷞൻ
ၮ␆ታ㛎࠺࡯࠲ࠍ↪޿ߡᬌ⸽ߣ⸃ᨆࡕ࠺࡞ߩᡷ⦟
ࠍታᣉߒߚ⚿ᨐ㧘⫳᳇ࠗࡦࠫࠚࠢ࠲ౝߩ⿥㖸ㅦྃᵹ߿᳓ྃᵹ⴫㕙߳ߩ⫳᳇ಝ❗ࠍ⸃ᨆน⢻ߣߒߚ
[1]-[4]㧚ߎߩᵹേ⸃ᨆࠦ࡯࠼ࠍ↪޿ߡ⫳᳇ࠗࡦࠫࠚࠢ࠲ߩࡁ࠭࡞ᡷ⦟ࠍㅴ߼㧘❗ዤࡕ࠺࡞⹜㛎ߦࠃࠆᬌ⸽ࠍ➅ࠅ㄰ߒߚ⚿ᨐ㧘ᴣ㛛᳓ᒻේሶἹ(BWR)ߩ⛎᳓ടᾲེߣห╬ߩૐ࿶⫳᳇ߢ⫳᳇ࠗࡦࠫࠚࠢ
࠲ࠍ⋥ធಝ❗ᾲ੤឵ེߣߒߡ૞േߐߖ㧘ᓥ᧪ߩૐ࿶⛎᳓ടᾲེో 12 ၮࠍ೥㒰ߒ㧘⛎᳓♽ߩ‛㊂ࠍᄢ᏷ߦ೥ᷫߔࠆߣหᤨߦ⃻ⴕߩ ABWR ࠍಒߋᾲല
₸ࠍᓧࠆ⷗ㅢߒࠍᓧߚ㧚ߎߩᛛⴚ㐿⊒ߪ㧘ᣣᧄේሶജቇળߣᣣᧄᯏ᪾ቇળߩᛛⴚ⾨ࠍฃ⾨ߒߚ߶߆㧘⚻ᷣ↥ᬺ⋭ߩ‫ޟ‬㕟ᣂ⊛ታ↪ේሶജᛛⴚ㐿⊒౏൐੐ᬺ‫৻ߩޠ‬Ⅳߣߒߡታ↪ൻࠍ⋡ᜰߒߚᡷ⦟⎇ⓥࠍታ
ᣉߒߡ޿ࠆ[7][8]㧚৻ㅪߩ㐿⊒⎇ⓥߪᐔᚑరᐕߎࠈ
߆ࠄ㐿ᆎߒߚ߇㧘ߒ߆ߒߥ߇ࠄ☨࿖ේሶജડᬺߢ
ߩ㐿⊒⹜㛎ߩᄬᢌ߿න⚐ൻ BWR 㐿⊒ߩਛᢿ╬ߩ૛ᵄࠍฃߌ㧘ㅒ㘑ߦ⠴߃ߥ߇ࠄ㐿⊒⎇ⓥࠍㅴ߼ߚᤨᦼ߽޽ߞߚ㧚㐳ᦼߦਗ਼ߞߚ㐿⊒ᦼ㑆߿࠼࡜ࠬ࠹
ࠖ࠶ࠢߥࠪࠬ࠹ࡓ߳ߩࠗࡦࡄࠢ࠻߆ࠄ㐿⊒ਛᱛߩⷐ⺧߇޽ߞߚ৻ᣇ㧘ᄞߩ޽ࠆᛛⴚߣߒߡ㐿⊒⛮⛯ࠍᡰᜬߐࠇߚߎߣ߽޽ߞߚ㧚৻ᣇߢ㧘ౝㇱߩવᾲᵹേ⃻⽎ߣߒߡߪ㧘⿥㖸ㅦྃᵹ߿ታ࿷ߔࠆಝ❗ᾲવ㆐ߣߒߡᾲജቇ⊛ಽሶㆇേ⺰ߩ਄㒢ߢ޽ࠆℂᗐવᾲ 2006 ᐕ 1 ᦬ಝ❗ᾲવ㆐ߦㄼࠆᾲᵹ᧤߇ᓧࠄࠇߡ߅ࠅ㧘㕖Ᏹߦ⥝๧ᷓ޿ߎߩ⃻⽎ⓥ᣿߳ߩ⥝๧ߣታ↪ൻ߳ߩၫᔨ
ߦኻߔࠆ౒ห⎇ⓥ⠪หᔒߩᖱᾲ߇㧘㐳ᐕߦࠊߚࠆ
⎇ⓥߩේേജߣߥߞߡ޿ࠆ㧚ੱᜰߒᜰ㧝ᧄߦ㧞
MW ߽ߩᾲࠛࡀ࡞ࠡ࡯ࠍ᦭ߔࠆ⫳᳇߇㧘⿥㖸ㅦߢಝ❗ߔࠆ⃻⽎ߪታߦ⥝๧ᷓ޿߽ߩ߇޽ࠆ㧚
㧞.⿥㜞ᕈ⢻⋥ធធ⸅ᾲ੤឵ེ㧙⫳᳇ࠗࡦࠫࠚࠢ
࠲ߩવᾲ⃻⽎ߣߘߩᔕ↪
㪉㪅㪈 ⫳᳇ࠗࡦࠫࠚࠢ࠲ߩ૞േේℂ ⫳᳇ࠗࡦࠫࠚࠢ࠲ 5+ ߩ૞േේℂࠍ Fig.1 ߦ␜ߔ㧚Ᏹ᷷᳓ࠍゲਛᔃߦ㈩ߒߚ᳓ࡁ࠭࡞߆ࠄྃ኿ߒ㧘⫳᳇ࠍ᳓ࡁ࠭࡞ᄖ஥ߣᷙวࡁ࠭࡞౉ญߣߢᒻᚑߐ
ࠇࠆⅣ⁁ߩ⫳᳇ࡁ࠭࡞ߦଏ⛎ߔࠆߣ㧘Fig.2 ߦ␜ߔㅢࠅ㧘นⷞൻ⓹߆ࠄེౝߩ⫳᳇ߩᵹㅦࠍ LDV ߢ᷹ቯߒߚ⚿ᨐ㧘ᷙวࡁ࠭࡞ౝߢ⫳᳇ߪ⿥㖸ㅦᵹߣߥࠅ㧘᳓ྃᵹࠍടㅦߒߡࠬࡠ࡯࠻ߦ㜞ㅦ᳓ᵹࠍ૞
ࠆߎߣࠍ⏕⹺ߒߚ㧚ࠬࡠ࡯࠻એ㒠ߢߪ⫳᳇ߩಝ❗
ߪ⚳ࠊࠅ㧘ᵹࠇߪ᳓ߩන⋧ᵹߣߥࠅ࠺ࠖࡈࡘ࡯ࠩ
ߢᷫㅦߐࠇ㧘ࡌ࡞࠿࡯ࠗߩቯℂߦࠃࠅ㜞޿࿶ജߦ᣹࿶ߐࠇࠆ㧚৻ᣇ㧘⫳᳇ࠗࡦࠫࠚࠢ࠲ࠍ⋥ធಝ❗
ᾲ੤឵ེߣߒߡ↪޿ࠆ႐ว㧘⫳᳇ࠗࡦࠫࠚࠢ࠲ౝ
ߩེౝ࿶ࠍਅߍߡ⫳᳇ߩ⿥㖸ㅦྃᵹࠍᒻᚑߔࠆߣ
⫳᳇ߩ᷷ᐲ߇ૐਅߒ㧘ᾲ੤឵ེߣߒߡߩᕈ⢻߇ૐਅߔࠆ㧚ᓥߞߡ㧘⫳᳇ࠗࡦࠫࠚࠢ࠲ߩ⫳᳇ࡁ࠭࡞౉ญ㕙Ⓧࠍචಽߦᄢ߈ߊߒߡ㧘⫳᳇ྃᵹࠍ੝㖸ㅦᵹߣߒ㧘⫳᳇࿶ജࠍ਄ߍߡ㧘ᢿᾲ⤘ᒛߦ઻߁⫳᳇᷷ᐲߩૐਅࠍ㒐ᱛߔࠆᔅⷐ߇޽ࠆ㧚

Steam

Water Jet Nozzle- 65 -

Water jetDiffuser

Mixing Nozzle Throat

Fig.1: Principle of 㨍steam injector

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ࡊࡠࠫࠚࠢ࠻ Q

Super-sonic Steam FlowFirst Stage Second Stage Third Stage Final Stage with Jet deaerator

Central Water Jet

Water Jet

Fig.2: A water jet in a visualized steam injector

Fig.3:
steam Injector
injectorSystemsystem
Fig.2Four-stage
Four-Stage Steam

MSH

RFPT

ABWR

1356MWRPV

LP Turbine

HP Turbine
7646t/hCond.

0.4MPa209t/h

7624t/h 2.4MPa
415t/h
216'C

186'C

1.3MPaTD-RFP 19MW
566t/h
139'C
156'C
8.7MPa

0.21MPa
198t/h117'C

GEN.

0.1MPa216t/h97'C

AESJ

0.05MPa
313t/h

LPCP
3MW

HPCP
5.7MW

75'C

2.2MPa49'C

HP HTR
࠼࡟ࡦ

HPDT
࠲ࡦࠢ

RIP 10units
13MW

CF/CD

MD-RFP

HPDP
4.8MW

LP HTR
A,B,C 3X4=12units

42'C

LPDT 2.8MPa 0.29MPa

LPDP
0.9MW

Fig.4: Balance of Plant (BOP) sytem of a current ABWR

Fig.5: Low-pressure fedd water heaters ਎⇇ೋߩ⹜ߺ㧙◲⚛ൻ⛎᳓ടᾲ♽߳ߩᄙᲑ SIߩㆡ↪
 ◲⚛ൻ⛎᳓♽ߦ↪޿ࠆ⫳᳇ࠗࡦࠫࠚࠢ࠲(SI)ߪ㧘
Fig.3 ߦ␜ߔࠃ߁ߦ⫳᳇ࠗࡦࠫࠚࠢ࠲ࠍ㧟Ბ⋥೉ߦធ⛯ߒ㧘㧠Ბ⋡ߦࠫࠚ࠶࠻⣕᳇ེࠍធ⛯ߒߡ
Fig.4 ߦ␜ߔ⃻ⴕߩ ABWR ߩ⛎᳓ടᾲེ㧔ో 12ၮ㧕ߣห╬ߩ⛎᳓ടᾲᯏ⢻ࠍታ⃻ߐߖࠆ߽ߩߢ޽

વᾲ 2006 ᐕ 1 ᦬- 66 -

ࠆ[5]㧚Fig.4 ߆ࠄૐ࿶⛎᳓ടᾲེߩㇱಽࠍ᛽಴ߒߚ ߽ ߩ ߇ Fig.5 ߢ 㧘 㧠 Ბ ߘ ࠇ ߙ ࠇ ߦ 0.05MPa,
0.1MPa, 0.21MPa, 0.4MPa ߩ࠲࡯ࡆࡦ᛽᳇⫳᳇ࠍଏ⛎ߔࠆ㧚ᄙᲑ⫳᳇ࠗࡦࠫࠚࠢ࠲ߢߪ㧘Fig.6 ߦ␜ߔㅢࠅ㧘ฦᓳ᳓ེߦ㧞ၮߕߟਗ೉ߣߒ㧘3 ♽೉ߩᓳ᳓ེߢߪ⸘㧢ၮߩ SI ࠍ⸳⟎ߔࠆ㧚Fig.7 ߪ⃻ⴕ
ABWR ߩᓳ᳓ེ਄ㇱߦࡀ࠶ࠢࡅ࡯࠲ߣߒߡ⸳⟎ߐࠇߚૐ࿶⛎᳓ടᾲེߢ޽ࠆ㧚Fig.8 ߪߎࠇࠍᄙᲑ
⫳᳇ࠗࡦࠫࠚࠢ࠲ߦ⟎߈឵߃ߚ႐วߩ㧟ᰴర
CAD ࿑ߢ޽ࠆ㧚ᄢဳߩ⛎᳓ടᾲེ߇೥㒰ߐࠇ㧘ዊญᓘߩ⫳᳇ࠗࡦࠫࠚࠢ࠲ߦ⟎߈឵߃ࠆߎߣߦࠃࠅ㧘ᓳ᳓ེߩ㜞ߐ㧘ߟ߹ࠅ࠲࡯ࡆࡦਥᯏߩᝪઃ㜞ߐ㧔හߜ㧘࠲࡯ࡆࡦᑪደߩ㜞ߐ㧕߇ 3.5m ૐᷫߢ߈ࠆߣ
౒ߦ㧘Fig.9 ߦ␜ߔㅢࠅ㧘⃻࿷ߩૐ࿶⛎᳓ടᾲ♽ߩ‛㊂㧔૕Ⓧ߅ࠃ߮⾰㊂㧕߇⚂ 1/3 ߦ೥ᷫߢ߈ࠆ
[8][9]䋮

J. HTSJ, Vol. 45, No. 190

ࡊࡠࠫࠚࠢ࠻ Q

㪌㪇 㪇

ABWR

ABWR

㪋㪇 㪇

Simplified
by SI

Simplified
by SI

㪊㪇 㪇
㪉㪇 㪇
㪈㪇 㪇
㪇

3

Weight㪉 (ton)Volume㪈 (m )

Fig.9


Fig.6:
Simplified feedwater heater
multi-stage SI and a jet deaeratersystem ushing

Necked heaters

Simplification of BOP systen using the muliti-stage SI.

㧟㧚ᵹേ⸃ᨆߦࠃࠆᄙᲑ 5+ ⛎᳓ടᾲེߩᕈ⢻ะ਄
3.1 ಽ㔌ੑ⋧ᵹࡕ࠺࡞ ⫳᳇ࠗࡦࠫࠚࠢ࠲ 5+ ౝߩ㜞ㅦੑ⋧ᵹ⃻⽎ࠍ⸃ᨆߔࠆߚ߼㧘⫳᳇㧘᳓ߩߘࠇߙࠇߦኻߒߡ⾰㊂࡮
ㆇേ㊂࡮ࠛࡀ࡞ࠡ࡯ߩၮ␆ᣇ⒟ᑼࠍ↪ᗧߔࠆಽ㔌ੑ⋧ᵹࡕ࠺࡞ߣߒ㧘᳇ᶧ⇇㕙ߦኻߒߡ  ᑼߩℂᗐಝ❗ᾲવ㆐₸ߣ  ᑼߩ⾰㊂ャㅍߣ  ᑼߩࠛࡀ࡞
ࠡ࡯ャㅍࠍ⠨ᘦߒߚ㧚-ǭߩੂᵹࡕ࠺࡞ߪ㧘ᵹേ⸃ᨆࠦ࡯࠼ߩ೙⚂߆ࠄᶧ⋧ߦߩߺㆡ↪ߒߚ㧚
3/ 2

Hci =Cc 2 h lg /[{vg(vg-vl)}{Tsat(Tsat-Tli)}]1/2  (1) gl = Hci(Ts - Tli)Ai/hlgm&Condensationwater

 glhgdiv( U l Ul hl - * hl grad hl) = m

 (2)  (3)᳇ᶧ⇇㕙ߩ⇇㕙ㅦᐲߪᰴᑼߩࠃ߁ߦ⇇㕙ࠍߪߐ߻᳇⋧ߣᶧ⋧ߩㅦᐲߦ᳇ᶧߩ೻ᢿᔕജߩ㊀ߺࠍઃߌߡ▚಴ߒߚ㧚

Wli = ( W gWg+ W gWl)/( W g+ W l)     (4)Fig. 5 Low-pressure
Fig.7: Turbine
condenser withnecked
necked feedwater
low-pressure heaters
RecircSteam

BufferTank

W g = (vg+vgT)/ ' rg and W l = (vl+vlT)/ ' rl  (5)Discharge#3rd SI

0.05MPa
Steam

0.1MP
a
S

0.21MPa#4th Jet Deaerator

Fig.8

ߎߎߢ㧘

0.4MPaSteam#2nd SI#1st SI

Feed
Water



Multi-stage SI in a uppper part of a turbine condenserવᾲ 2006 ᐕ 1 ᦬- 67 -

ߘߎߢ᳇ᶧ⇇㕙ߪ㧞ᰴరゲኻ⒓ߩ౞ᩇ⁁ߩࡔ࠶ࠪࡘߩඨᓘࠍ moving mesh ߩᯏ⢻ࠍ↪޿ߡ᳇ᶧ⇇㕙ߩ࿶ജ߇ㅪ⛯ߣߥࠆࠃ߁ߦ෼᧤ߐߖߚ㧚ߎߩࠃ߁ߦ᣿⏕ߥ᳇ᶧ⇇㕙߇ሽ࿷ߔࠆߚ߼㧘᳇⋧߅ࠃ߮ᶧ⋧ߪන⋧ᵹߣߒߡขࠅᛒ߁ߎߣ߇ߢ߈㧘᳇ᶧ⇇㕙ߪ⫳᳇ߦኻߒߡߪಝ❗ߦ઻߁ᵹ಴Ⴚ⇇㧘ᶧ⋧ߦߣߞߡߪᵹ౉Ⴚ⇇ߣߒߡ(1)㨪(5)ᑼࠍㆡ↪ߒ㧘⸃ᨆࠍ㜞ㅦൻߒߚ㧚

J. HTSJ, Vol. 45, No. 190

ࡊࡠࠫࠚࠢ࠻ Q

Fig.10

3D CAD model for 4-stage steam injector analysis[18]Fig.11: Improvement of temperature distribution by changing the shape of mix-nozzle diameter at the 1ststage steam injector[18]3.2 ◲⚛ൻ⛎᳓♽↪ᄙᲑ SI ߩᵹേ⸃ᨆ
◲⚛ൻ⛎᳓♽䈪䈲⫳᳇䉟䊮䉳䉢䉪䉺(SI)䉕⋥೉䋳Ბ䈮ធ⛯䈚䋬䋴Ბ⋡䈮䉳䉢䉾䊃⣕᳇ེ䉕ធ⛯䈜䉎䋮䉳䉢䉾䊃⣕᳇ེ䈮䈲╙䋳Ბ SI 䈱ฯ಴᷷᳓䈏䊉䉵䊦䈎䉌ྃ኿䈘䉏䋬ᶧṢൻ䈚䈩㘻๺᷷ᐲ䉁䈪ടᾲ䈘䉏䉎䈫౒䈮䋬⫳᳇䈫䈱⋧ኻㅦᐲ䈮䉋䉎ᶧṢ⴫㕙䈫ౝㇱ䈫䈱ኻᵹ䈮䉋䉍㜞ᕈ⢻⣕᳇䈘䉏䉎䋮ᓥ䈦䈩╙䋴Ბ䈱ടᾲᕈ⢻䈲⃻ⴕ
ABWR 䈱⛎᳓ടᾲེ䉋䉍䉅⦟䈒䈭䉎䋮ᓥ䈦䈩䋬◲⚛ൻ⛎᳓♽䈱ᕈ⢻䈲䋬╙䋱Ბ䈎䉌╙䋳Ბ䉁䈪䈱ᄙᲑ SI 䈱ടᾲᕈ⢻䈫╙䋳Ბ SI ฯ಴䊉䉵䊦䈪䈱࿶ജ䈏䉳䉢䉾䊃⣕᳇ེ䈮චಽ䈭ྃ኿䉕䈪䈐䉎ฯ಴䉕᦭䈚䈩䈇䉎䈎䈏್ቯၮḰ䈫䈭䉎䋮䈠䈖䈪ᵹേ⸃ᨆ䈲 Fig.10 䈱 CAD 䊝䊂䊦䈮␜䈜䉋䈉䈮╙䋱Ბ䈎䉌╙䋳Ბ䉁䈪䈱ᄙᲑ⫳᳇䉟䊮䉳䉢䉪䉺䉕䊝䊂䊦ൻ䈚䈢䋮Fig.䋱䋱䈮⸃ᨆ⚿ᨐ䈱᷷ᐲಽᏓ䈱䉦䊤䊷䉮䊮䉺䊷䉕␜䈜䋮ห࿑ (a) 䈲ᡷ⦟೨䋬ห
࿑(b)䈲❗ዤ䊝䊂䊦⹜㛎䈪䈱ᬌ⸽䈭䈬[6]-[8]䈱䉴䊁䉾䊒䉕〯䉖䈪䋬╙䋱Ბ䈱䊉䉵䊦ᒻ⁁䉕ᡷ⦟䈚䈢⚿ᨐ䈪䈅䉎䋮䊉䉵䊦ᒻ⁁䈱ᡷ⦟䉕╙䋱Ბ䈮㊀ὐ䉕᛼䈚䈢䈱䈲╙䋱Ბ䈱᛽᳇⫳᳇࿶ജ䈏 0.05MPa 䈫ᦨ䉅ૐ䈒䋬╙䋱Ბ䈪䈖䈱࿶ജ䈱⫳᳇䉕䈭䉎䈼䈒ᄙ䈒૶䈦䈩ടᾲ䈜䉎䈖䈫䈏䊒䊤䊮䊃䈱ᾲല₸਄䋬᦭೑䈪䈅䉎䈢䉄䈪䈅䉎䋮䊉䉵䊦ᒻ⁁䈱ᡷ⦟䈲䋬䊔䊦䊙䉡䉴ㇱ䉕ゲᣇะ䈮ᑧ㐳䈚䈩᳓ྃᵹ䈱ടᾲ㐳䈘䉕㐳䈒䈜䉎䈫౒䈮䋬╙䋱Ბᷙว䊉䉵䊦䈱ਅᵹ஥䈱ౝᓘ䉕ᄥ䈒䈚䈩⫳᳇ᵹㅦ䉕ਅ䈕䈢䋬䋲ὐ
䈪䈅䉎䋮Fig.䋱2 䈮␜䈜ㅢ䉍䋬╙䋱Ბ䈱ᷙว䊉䉵䊦ᒻ⁁䉕ᡷ⦟䈜䉎䈖䈫䈮䉋䉍䋬╙䋱Ბ䈱ടᾲᕈ⢻䈏ะ਄䈚䋬╙䋱Ბ䈱ടᾲᕈ⢻䈲⃻ⴕ ABWR 䈱ૐ࿶⛎᳓ടᾲེવᾲ 2006 ᐕ 1 ᦬಴ญ᷷ᐲ䈫䈾䈿੕ⷺ䈮䈭䈦䈢䋮╙䋴Ბߩടᾲᕈ⢻ߪࠫࠚ࠶࠻⣕᳇ེߩᣇ߇㜞޿ߩߢ㧘╙㧝Ბ߇੕ⷺߦ
ߥࠆߎߣߦࠃࠅ㧘⛎᳓ടᾲᕈ⢻߇⃻ⴕ ABWR ࠍߒߩߋߎߣߦߥࠆ㧚㧠㧚⚿ ⸒
ታኸᄢߩᄢဳታ⸽⹜㛎ߦઍ߃ߡ㧘ࡕ࠺࡞⹜㛎ߣᵹേ⸃ᨆࠍ૬↪ߒߚ㐿⊒ࠍㅴ߼ߡ޿ࠆ㧚ㅒ㘑ߦ⠴߃ߥ߇ࠄ㐳ᐕߩ☼ࠅᒝ޿㐿⊒ߩᚑᨐߪ㧘ᄢဳߩ⛎
᳓ടᾲེ߇೥㒰ߐࠇዊญᓘߩ⫳᳇ࠗࡦࠫࠚࠢ࠲ߦ
⟎߈឵߃ࠆߎߣߦࠃࠅ㧘ᓳ᳓ེߩ㜞ߐ㧘ߟ߹ࠅ࠲࡯ࡆࡦਥᯏߩᝪઃ㜞ߐ㧔හߜ㧘࠲࡯ࡆࡦᑪደߩ㜞ߐ㧕߇ 3.5m ૐᷫߢ߈㧘⃻࿷ߩૐ࿶⛎᳓ടᾲ♽ߩ‛㊂㧔૕Ⓧ߅ࠃ߮⾰㊂㧕߇⚂ 1/3 ߦ೥ᷫߢ߈ࠆߎ
ߣࠍ␜ߒߚ㧚዁᧪ᄢ᏷ߥࠦࠬ࠻ૐᷫߦነਈߔࠆߎ
ߣ߇ᦼᓙߐࠇࠆ㧚ߐࠄߦ⫳᳇ࠗࡦࠫࠚࠢ࠲ᧄ૕ߦ
ߟ޿ߡߪ㧘╙䋱Ბ䈱ᷙว䊉䉵䊦ᒻ⁁䉕ᡷ⦟䈜䉎䈖䈫䈮䉋䉍╙䋱Ბ䈱ടᾲᕈ⢻䈏ะ਄䈚䋬╙䋱Ბ䈱ടᾲᕈ⢻䈲⃻ⴕ ABWR 䈱ૐ࿶⛎᳓ടᾲེ಴ญ᷷ᐲ䈫䈾䈿੕ⷺ䈮䈭䉎䈖䈫䉕␜䈚䈢䋮╙䋴Ბ䈱ടᾲᕈ⢻䈲䉳䉢䉾䊃⣕᳇ེ䈱ᣇ䈏㜞䈇䈱䈪䋬╙䋱Ბ䈏੕ⷺ䈮䈭䉎䈖䈫䈮䉋䉍䋬⛎᳓ടᾲᕈ⢻䈏⃻ⴕ ABWR 䉕ಒ䈓䈖䈫䈏⸃ᨆ⊛䈮␜䈘䉏䋬䊒䊤䊮䊃ല₸䈱ᡷༀ䈏⷗ㄟ䉁䉏䉎䋮੹ᓟ䈲䋬⍫ㇱ䉌䈮䉋䈦䈩㐿⊒䈘䉏䈢᳇ᶧ䈱⥄↱⇇㕙䈱ข䉍ᛒ䈇䈏ኈᤃ䈪䈎䈧ኒᐲ䈱⇣䈭䉎⫳᳇䈫᳓䉕หᤨ䈮⸃ᨆ䈜䉎䈖䈫䈏䈪䈐䉎 CIP ᴺ[10]䉅䋬䊉䉵䊦ᒻ⁁䈱ᡷ⦟䈮↪䈇䉎੍ቯ䈪䈅䉎䋮- 68 -J. HTSJ, Vol. 45, No. 190

ࡊࡠࠫࠚࠢ࠻ Q

Temperature ('C䋩ൻ⛎᳓♽ߩ㐿⊒ (5)ᵹേ⸃ᨆߦࠃࠆᾲ᳓ജᕈ⢻ߩะ਄‫ޠ‬ේሶജቇળ ⑺ߩᄢળ㧔2001㧕
㧚[6] Mori, M., Ohmori, S., and Narabayashi, T.,"Development of Simplified Steam Injector
Feedwater Heater System- Large Scale Model Tests
andDesignImprovementby
CFD-",ICONE11-36488 (2003).
[7] Mori, et al., Research and Development Programof Innovative Simplified and Severe- Accident-Free
BWR by High-Performance Steam Injector System,
ICAPP'03, Cordoba, Spain (2003).

Distance from the 1st-stage water jet nozzle (mm)[8] ᄢ᫪ୃ৻, ᄹ⦟ᨋ ⋥, ᫪ ᴦ༹‫ޟ‬㜞ᕈ⢻⫳᳇ࠗ,ࡦࠫࠚࠢ࠲ߦࠃࠆ㕟ᣂ⊛◲⚛ൻේሶജ⊒㔚ࡊ࡜ࡦ࠻ߩᛛⴚ㐿⊒‫ޠ‬㧘ᣣᧄᯏ᪾ቇળᐕᰴᄢળ㧘2101(2003)㧚
[9] Narabayashi, T., et.al., ”Development ofTechnologies on Innovative Simplified Nuicler
Power Plant Using High-Efficiency SteamInjectors(3) Development of Multi-Stage SteamInjector for Feedwater Heaters Using Two-Phase
Flow Analysis, ICONE13-50780, (2005, Beijin,
China).

(a) An original shape of multi-stage SI
㪈㪊㪇
㪈㪉㪇
㪈㪈㪇

㪫㩷㪲㷄 㪴

㪈㪇㪇
㪐㪇
㪏㪇

75͠

㪎㪇
㪍㪇
㪌㪇
㪋㪇
㪄㪌㪇㪇

㪇
㪌㪇㪇
㪈㪇㪇㪇
㪈㪌㪇㪇
㪉㪇㪇㪇
㪛㫀㫊㫋㪸㫅㪺㪼㩷㪽㫉㫆㫄㩷㫋㪿㪼㩷㪈㫊㫋㪄㪪㫋㪸㪾㪼㩷㪮㪸㫋㪼㫉㩷㪡㪼㫋㩷㪥㫆㫑㫑㫃㪼㩷㪲㫄㫄㪴㪉㪌㪇㪇[10] ⍫ㇱ ቁ㧘ౝᶏ㓉ⴕ㧘የᒻ㓁৻⪺㧘‫ޟ‬CIP ᴺ ේሶ߆ࠄቝቮ߹ߢࠍ⸃ߊࡑ࡞࠴ࠬࠤ࡯࡞⸃ᴺ‫ޠ‬㧘᫪ർ಴ 㧔2003㧕

(b) An improved shape of multi-stage SI
Fig.12: Improved result of water heat-up along the axisෳ⠨ᢥ₂[1] Narabayashi, T., et.al., "Study on two-phase flow
dynamics in steam injectors",.Nuclear Engineering
Design, 175, (1997), 147-156.
[2] Narabayashi, T., et.al., "Study on two-phase flow
dynamics in steam injectors II.High-pressure tests
using scale-models", Nuclear Engineering Design,
200, (2000), pp.261-271.
[3] Iwaki, C. et al., "Study of Heat and Momentum
Transfer Mechanisms in Steam Injectors for
Next-Generation Reactors, Proc. Winter Ann. Mtg.
ASME
(ME-94),ChicagoUSA,
HTDVol.294,(1994), pp.19-30.

NomenclatureC

shear coefficient of interface between
gas liquid phases
H
Heat-transfer CoefficienthSpecific enthalpy (kJ/(kg s))m
Mass flow rate (kg/s)
U, V, W  Velocity (m/s)(Greek letters)[4] ᄹ⦟ᨋ ⋥㧘᫪ ᴦ༹㧘ጤၔᥓ㚅ሶ㧘ᄢ᫪ୃ৻,‫⫳ޟ‬᳇ࠗࡦࠫࠚࠢ࠲ߩ᳇ᶧ⇇㕙ᾲャㅍߦ㑐ߔࠆ⎇ⓥ㧔ࠦࡦࡄࠢ࠻⛎᳓ടᾲེߩ㐿⊒㧕‫ޠ‬, ᷙ⋧ᵹቇળ OMF01-Fukushima㧘(2001)㧚
[5] ᄹ⦟ᨋ ⋥߶߆㧘‫⫳ޟ‬᳇ࠗࡦࠫࠚࠢ࠲ടᾲ◲⚛

વᾲ 2006 ᐕ 1 ᦬Urdensity (kg/m3)
radial ccordinate in cylindrical geometry (m)WShear stress (MPa)(Subscripts)ggass
iInterface between phaseslliquidsatsaturated- 69 -J. HTSJ, Vol. 45, No. 190

࿖㓙ᵴേ࡮ળ⼏ႎ๔૒⾐ᄢቇߩ㐷಴᡽ೣᢎ᝼ߣశᱞ㓶৻ഥᢎ᝼߇ ASME 2005 Best Paper Award ࠍฃ⾨
Prof. Masanori Monde and Prof. Yuichi Mitsutake of Saga University Received ASME 2005 Best Paper Award 2005 ᐕ 11 ᦬ 5 ᣣ㨪 11 ᣣߦࠊߚࠅ Orland 㧔ࠕࡔ࡝ࠞ࡮ࡈࡠ࡝࠳Ꮊ㧕ߩ Walt Disney World Swan &Dolphin Hotel ߢ 2005 ASME International
Mechanical Engineering Congress and Exposition㧔ࠕࡔ࡝ࠞᯏ᪾ቇળߩᐕᰴᄢળ㧕㐿௅ߐࠇ߹ߒߚ㧚ߘ
ߩBanquet Program㧔11᦬10ᣣ㧕ߦ߅޿ߡ㧘2005ᐕ
ߩHeat Transfer DivisionߩBest Paper Award㧔વᾲㇱ㐷ߩᦨఝ⑲⺰ᢥ⾨㧕߇㧘૒⾐ᄢቇߩ㐷಴᡽ೣవ↢ߣశᱞ㓶৻వ↢ߦ⿅ࠄࠇ߹ߒߚ㧚ߎߩ⾨ߪASME
ߩJournal of Heat Transferߩឝタ⺰ᢥ߆ࠄㆬ߫ࠇࠆ
⾨ߢߔ߇㧘ᣣᧄ߆ࠄߩฃ⾨ߪ10ᐕ߱ࠅ㧔೨࿁ฃ⾨⠪ߪ㧘᡿࿯ᣇ㇌ᄦవ↢ߩࠣ࡞࡯ࡊ㧕ߢ㧘ᣣᧄߩવᾲ⇇ߦߣߞߡ߽ᄢᄌฬ⹷ߥฃ⾨ߢߔ㧚ਔవ↢ߦᔃࠃࠅ߅␸޿↳ߒ਄ߍࠆߣߣ߽ߦ㧘વᾲ✬㓸಴ ㇱળߩ৻ᆔຬߣߒߡ◲නߥႎ๔⸥੐ࠍၫ╩ߐߖߡ㗂߈߹ߔ㧚 Best Paper Award ฃ⾨ߩኻ⽎ߣߥߞߚ⺰ᢥߪ㧘
ASME Journal of Heat Transfer, Vol.125, 2003,㐷಴᡽ೣ૒⾐ᄢቇᢎ᝼ శᱞ㓶৻૒⾐ᄢቇഥᢎ᝼


pp.1038-1045 ߦ ឝ タ ߐ ࠇ ߡ ޿ ࠆ “ Ultra High
Critical Heat Flux During Forced Flow Boiling Heat
Transfer with an Impinging Jet ” ߢߔ㧚੹ߐࠄ⑳߇↳ߒ਄ߍࠆ߹ߢ߽ߥߊ⊝᭽ࠃߊߏሽߓߩߎߣߢߔ
߇㧘㐷಴࡮శᱞਔవ↢ߩ૒⾐ᄢቇᾲᎿቇ⎇ⓥቶߢ
ߪᢙචᐕߦࠊߚࠅߕߞߣ‫ޟ‬㒢⇇ᾲᵹ᧤‫߁޿ߣޠ‬ᄢ߈ߥ⎇ⓥ࠹࡯ࡑߦขࠅ⚵ࠎߢߎࠄࠇ߹ߒߚ߇㧘਄⸥⺰ᢥߪߘߩౝߩ㧝ᚑᨐߢ޽ࠅ㧘਎⇇ᦨ㜞ߩ಄ළ㒢⇇ߦ᜸ᚢߔࠆߣ޿߁ჽᄢߥ࠹࡯ࡑߢߔ㧚㐷಴వ↢ߩࠦࡔࡦ࠻ߢߪ㧘‫ޟ‬ᱷᔨߥ߇ࠄ਎⇇ᦨ㜞ߩ⸥㍳
㧔276MW/m2㧕ߦߪ෸߫ߥ߆ߞߚ‫߇ߔߢ߁ߘޠ‬㧘ⴣ⓭ྃᵹᴣ㛛♽ߢಽሶㆇേ⺰߆ࠄ᳿ቯߐࠇࠆᦨ㜞㒢⇇ᾲᵹ᧤ߩ⚂ 50%ㄭߊ߹ߢẋㄭߢ߈ߚߣหᤨߦ
ߘߩ㒢⇇ᾲᵹ᧤ࠍ 214MW/m2 ߹ߢᡷༀߐࠇ߹ߒߚ㧚߹ߚ㧘ߎߩ㒢⇇ᾲᵹ᧤ߩ▸࿐߹ߢ㧘㐷಴వ↢ࠄ߇ឭ᩺ߒߡ޿ࠆ੍᷹ᑼ߇ㆡ↪ߢ߈ࠆߎߣࠍታ㛎⊛ߦᬌ⸽ߒߚὐ߇㜞ߊ⹏ଔߐࠇߚߩߢߪߥ޿ߢߒࠂ߁
߆㧚⑳߽ਔవ↢ࠍ⋡ᮡߣߒߡ㧘੹ᓟߩᦝߥࠆ♖ㅴ߇ᔅⷐߛߣ∩ᗵ⥌ߒ߹ߒߚ㧚ਔవ↢ߩ੹ᓟߩ⋉‫ޘ‬ߩߏᵴべࠍ߅␨ࠅ⥌ߒ߹ߔ㧚

ASME Best Paper Award ߩ⴫ᓆ⁁᳗੗ ੑ㇢㧔⑔੗ᄢቇ㧕
Niro NAGAI (University of Fukui)e-mail: nagai@mech.fukui-u.ac.jp

વᾲ 2006 ᐕ 1 ᦬- 70 -J. HTSJ, Vol. 45, No. 190

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r t Transfer
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ᑝ↰ ⌀ผ㧔ฬฎደᄢቇ㧕
Masafumi HIROTA (Nagoya University)e-mail: hirota@mech.nagoya-u.ac.jp ታ㛎ቶߩ౉ߞߡ޿ࠆᑪ‛ߩߔߋⵣᚻߦᣂߒ޿ᣉ
⸳߇ᑪ⸳ߐࠇࠆߎߣߦߥࠅ㧘ᤓᐕߩ㧝㧜᦬㗃߆ࠄᎿ੐߇ᆎ߹ߞߡ޿߹ߔ㧚ฎ޿ᑪ‛ࠍขࠅუߒߡ߆
ࠄၮ␆Ꮏ੐߇ᆎ߹ߞߚߩߢߔ߇㧘᧮ᛂߜᎿ੐ߦ౉
ࠆ㗃߆ࠄ৻ㇱߩ᷹ቯེߩାภߦࡁࠗ࠭߇ਸ਼ࠆࠃ߁
ߦߥࠅ߹ߒߚ㧚ߎࠇ߹ߢߦ⚻㛎ߒߚߎߣߩߥ޿ၫ
ᜓߥࡁࠗ࠭ߢ㧘ᄢቇ㒮ߩ᝼ᬺਛߦߎߩߎߣࠍ߰ߣ
ṳࠄߔߣ㧘ᗧᄖߥߎߣߦᎿ੐⃻႐߆ࠄ߆ߥࠅ㔌ࠇߚ⎇ⓥቶߢ߽ᤨᦼࠍ╬ߒߊߒߡࡁࠗ࠭߇Ⴧ߃ߡߒ
߹޿࿎ߞߡ޿ࠆߣߩߎߣ㧚ේ࿃ߩផ᷹ߢ৻ㅢࠅ⋓ࠅ਄߇ߞߚߩߢߔ߇㧘಴ߡ߈ߚᗧ⷗ࠍ೉᜼ߒߡߺ
ࠆߣ㧘࡮Ꮏ੐ߦ૶߁ᯏ᪾ߩࡕ࡯࠲࡯߇ේ࿃㧚࡮ࡕ࡯࠲࡯ࠃࠅ߽ṁធᯏߩᣇ߇ᖡ޿㧚࡮㔚᳇ߩ૶޿ߔ߉ߢ㔚࿶߇ਇ቟ቯߦߥߞߚ㧚࡮᧮ᛂߜߩᓇ㗀ߢࠕ࡯ࠬ߇߅߆ߒߊߥߞߚ㧚࡮ᒁߞߎᛮ߆ࠇߚᧁߩ␺ࠅ߆߽⍮ࠇߥ޿㧚࡮ߘ߁⸒߃߫ᷡ߼ߩႮ߇⟎߆ࠇߡ޿ߚ㧚㧚㧚ߣ㧘߹޽ᦨᓟߪ߅᳿߹ࠅߩᚲ㧔㧫㧕߳⪭ߜ⌕߈߹ߒߚ߇㧘ᚲ⹢ߪ⚛ੱ㓸࿅ߩᖤߒߐ㧘⚿ዪේ࿃ߪਇ
᣿ߩ߹߹ߢߔ߇㧘ߘࠇߢ߽⎇ⓥቶᲤߦ᭽‫ࠗࡁߥޘ‬࠭ኻ╷ߩࡁ࠙ࡂ࠙߇વࠊߞߡ޿ࠆࠄߒߊ㧘⡞޿ߡ޿ߡߥ߆ߥ߆⥝๧ᷓ޿߽ߩ߇޽ࠅ߹ߒߚ㧚‫⎇ޟ‬ⓥ
ቶߩ⸥ᙘ‫ߨߔߢߟ߿߁޿ߣޠ‬㧚 ቇ↢ߩ㗃㧘ੂᵹવᾲߩታ㛎ࠍᆎ߼ߚߣ߈ߦ߽㧘߿ߪࠅ᷹ቯེ߆ࠄߩାภߦࡁࠗ࠭߇ਸ਼ࠅ⧰ߒࠎߛ
ߎߣ߇޽ࠅ߹ߔ㧚ߎߩᤨߪ⹜ⴕ㍲⺋ࠍ➅ࠅ㄰ߒߡߤ߁ߦ߆⸃᳿㧔ᄙಽ㧕ߒ߹ߒߚ߇㧘਄ᚻߊⴕ߆ߥ
޿ᤨߦߪ‫ੂޟ‬ᵹߥࠎߡᧄᒰߪሽ࿷ߒߥߊߡࡁࠗ࠭
ࠍ⷗ߡ޿ࠆߛߌߥࠎߓ߾ߥ޿ߩ㧫‫ޠ‬㧘‫࡞࠻ࠢࡍࠬޟ‬ߪනߦ㔚ሶ࿁〝ߩ․ᕈࠍ⴫ߒߡ޿ࠆߩߢߪ㧫‫ޠ‬㧘‫ᧄޟ‬ᒰߪߺࠎߥᕋߒ޿ߣᕁߞߡ޿ࠆߌߤ⸒޿಴ߖ
ߥ޿ߩ߆ߥ㧫‫ߟ౎ߣߤߥޠ‬ᒰߚࠅ᳇๧ߦ⠨߃ߡ޿߹ߒߚ㧚ࠝ࡯࠺ࠖࠝࠕࡦࡊߩ⸳⸘⠪߇㧘ࡁࠗ࠭ࠍਅߍࠆߚ߼ߦㇱຠߩ㈩⟎ߦ޿߆ߦ᳇ࠍ૶߁߆ࠍ⺆ߞߡ޿ߚ⸥੐ࠍᕁ޿಴ߒ㧘ࠦࡦࡄࠢ࠻ߦ߹ߣ߹ߞ

વᾲ 2006 ᐕ 1 ᦬ߚ᷹ቯེߦ૗ߣߥߊਇାߩ⋡ࠍะߌߚߎߣࠍⷡ߃
ߡ޿߹ߔ㧚⠨߃ߡߺࠇ߫㧘ੂᵹߪߘ߽ߘ߽นⷞൻ
ߢ⊒⷗ߐࠇߚࠊߌߢߔߒ㧘-5/3 ਸ਼ೣߪℂ⺰⊛ߦዉ߆ࠇߚᴺೣߥߩߢ㧘ߎࠇߪోߊߩᅦᗐߛߞߚࠊߌ
ߢߔ߇㧘੹࿁ߩࡁࠗ࠭㛍േߢ޽ߩᤨᗵߓߚ৻⒳ߩ
ෂ߁ߐࠍᕁ޿಴ߒ߹ߒߚ㧚 ᾲᵹേߩ⸘᷹ߢߪ㧘࠺ࠫ࠲࡞ᛛⴚߩㅴᱠߦ઻޿
ࠗࡔ࡯ࠫࡦࠣࠍ೑↪ߒߚᚻᴺ߇ਥᵹߦߥࠅߟߟ޽
ࠅ߹ߔ߇㧘ੂᵹߩࠃ߁ߦᤨ㑆࡮ⓨ㑆ಽ⸃⢻ߩ㜞޿ㅪ⛯ᵄᒻࠍขࠅߚ޿႐วߦߪ㧘ᣥ᧪ߩࠕ࠽ࡠࠣᯏ
ེ߇ᕈ⢻⊛ߦఝࠇߡ޿ࠆࠃ߁ߦᕁ޿߹ߔ㧚ઙ㧔ߊߛࠎ㧕ߩ᷹ቯེ㧔Ꮢ⽼ߩࠕ࠽ࡠ᷷ࠣᐲ⸘㧕ߪߘߩᓟ߽૶޿⛯ߌߡ޿߹ߔ߇㧘⻉੐ᖱ߆ࠄ৻ᤨᦼ⥄૞ࠍ⹜ߺߚߎߣ߇޽ࠅ߹ߒߚ㧚ర‫ޘ‬ᚻ૞ࠅߦㄭ޿⵾
ຠߢ㧘ේℂ⊛ߦߪߐ߶ߤ㔍ߒߊߥߊ㧘ㇱຠߥߤ߽㐿⊒ᒰᤨߦᲧߴࠇ߫ㅴࠎߢ޿ࠆߣᕁߞߚߚ߼㧘ߔߋߦାภ߇ขࠇࠆ߽ߩߣᦼᓙߒ߹ߒߚ߇㧘ߎࠇ߇ోߊ਄ᚻߊⴕ߆ߥ޿㧚⦡‫ޘ‬ේ࿃ࠍ⺞ߴߡߺࠆߣ㧘ߤ߁߿ࠄ૶ࠊࠇߡ޿ࠆ㔚ሶㇱຠ৻ߟ৻ߟߩ⾰ߩ㆑޿߇ᕈ⢻ߩᏅߦߥߞߡ⃻ࠇߡ޿ࠆࠄߒ޿㧚੐ᖱㅢߦࠃࠆߣ㧘ߎߩ᷹ቯེߦ૶ࠊࠇߚㇱຠߪߤࠇ߽ㆬ
ࠅߔߋࠅߩ㜞ຠ⾰ຠߢ㧘ߎ߁ߒߚㇱຠߪ⃻࿷ߢߪ߽߁↢↥ߐࠇߡ߅ࠄߕ㧘౉ᚻߪ࿎㔍ߣߩߎߣߢߒ
ߚ㧚૗ߩᄌື߽ߥ޿▫ߩࠃ߁ߥⵝ⟎ߢߔ߇㧘⸳⸘⠪ߩ㝬ࠍߘߎߦ⷗ࠆࠃ߁ߢ㧘ᤄ⇼ߞߚߎߣ߽ᔓࠇ
ߡฎ޿෹ੱߩࠃ߁ߦᗵߓߚᰴ╙ߢߔ㧚ߘࠇߦߒߡ
߽㧘৻ᣤㅜಾࠇߡߒ߹ߞߚࠕ࠽ࡠࠣᛛⴚߪᄙಽੑ
ᐲߣᓳᵴߔࠆߎߣߪήߊ㧘੹ߪᒰߚࠅ೨ߦⷰኤߒ
ߡ޿ࠆᵄᒻ߽ߘߩ߁ߜ⷗ࠄࠇߥߊߥࠆ߆߽⍮ࠇߥ޿ߣᕁ߁ߣ㧘૗߆༄߇߭ࠅߟߊࠃ߁ߥὶࠅࠍᗵߓ߹ߔ㧚 ౨㗡ߩࡁࠗ࠭ߢߔ߇㧘ߥ߆ߥ߆ᶖߔߎߣ߇಴᧪
߹ߖࠎ㧚ᧄᒰߦᎿ੐߇⚳ࠊࠆߣᶖ߃ࠆߩ߆㧘޽ࠆ޿ߪᖠߺߩ⒳߇߹ߚ৻ߟჇ߃ߡߒ߹߁ߩ߆㧘ᦼᓙߣਇ቟߇ඨ‫ߔߢޘ‬㧚Ꮏ੐ߪዋߒㆃࠇ᳇๧ߥ߇ࠄ߽㧘⌕‫ߣޘ‬ㅴࠎߢ޿߹ߔ㧚- 71 -J. HTSJ, Vol. 45, No. 190

વᾲ 2006 ᐕ 1 ᦬- 72 -J. HTSJ, Vol. 45, No. 190

ⴕ੐ࠞ࡟ࡦ࠳࡯

ⴕ੐ࠞ࡟ࡦ࠳࡯

ᧄળਥ௅ⴕ੐
㐿௅ᣣ
2006 ᐕ
5᦬
31 ᣣ(᳓)㨪6 ᦬ 2 ᣣ(㊄)ⴕ੐ฬ(㐿௅࿾㧘㐿௅࿖)╙ 43 ࿁ᣣᧄવᾲࠪࡦࡐࠫ࠙ࡓ
ฬฎደ࿖㓙ળ⼏႐

↳ㄟ✦ಾ

ේⓂ✦ಾ

໧วవ

ឝタภ

'06.1.20'06.3.13╙ 43 ࿁ᣣᧄવᾲࠪࡦࡐࠫ࠙ࡓታⴕᆔຬળ
ฬฎደᎿᬺᄢቇ ߒߊߺ㗔ၞౝ
FAX: 052-735-5343,
E-mail: nhts43@thermo.mech.nitech.ac.jp
HP: http://thermo.mech.nitech.ac.jp/~nhts43/

11 ᦬ภ
1 ᦬ภ

↳ㄟ✦ಾ

ේⓂ✦ಾ

໧วవ

ឝタภ

ᧄળ౒௅㧘ද⾥㧘ᓟេⴕ੐㐿௅ᣣⴕ੐ฬ(㐿௅࿾㧘㐿௅࿖)
2006 ᐕ
26 ᣣ㧔ᧁ㧕 2005 ᐕᐲࠟࠬ࠲࡯ࡆࡦ࠮ࡒ࠽࡯
1᦬~‫ᦨߩࡦࡆ࡯࠲ࠬࠟޟ‬ᣂᛛⴚേะߣ዁᧪ዷᦸ‫ޠ‬
27 ᣣ㧔㊄㧕2᦬

2 ᣣ(ᧁ)㨪
3 ᣣ(㊄)

12th Symposium on “Microjoining and AssemblyTechnology in Electronics” (Mate 2006)3᦬

7 ᣣ㧔Ἣ㧕
~8 ᣣ㧔᳓㧕

╙ 6 ࿁ GSC ࠪࡦࡐࠫ࠙ࡓ(ቇⴚ✚ว࠮ࡦ࠲࡯࡮৻ᯅ⸥ᔨ⻠ၴ)㧔᧲੩㧕3᦬

13 ᣣ㧔᦬㧕 ᣣᧄታ㛎ജቇળ 2006 ᐕᐲᐕᰴ⻠Ṷળ(ਛㇱᄢቇ࡮ᗲ~⍮⋵ᤐᣣ੗Ꮢ)15 ᣣ㧔᳓㧕4᦬

20 ᣣ㧔ᧁ㧕 ߎߎߪਠᧄ㧘߻߆޿ߪᄢፉ࠮ࡒ࠽࡯㧔No.06-12 ᣣᧄ~ᯏ᪾ቇળᾲᎿቇㇱ㐷ડ↹࠮ࡒ࠽࡯㧕㧔࿖᳃ኋ⥢‫޽ޟ‬
21 ᣣ(㊄)ࠄ߰ߨ‫ޠ‬๺᱌ጊ⋵㧕5᦬

25 ᣣ㧔ᧁ㧕 Second International Sympojium on Standard Materials
and Metrology for Nanotechnology (SMAM-2)~
26 ᣣ㧔㊄㧕6᦬

11 ᣣ(ᣣ)㨪
15(ᧁ)

Second International Conference on
Transport Phenomena in Micro and Nanodevices
Il Ciocco Hotel and Conference Center
Barga, Italy8᦬

13 ᣣ(ᣣ)㨪18 ᣣ(㊄)The International Heat Transfer Conference IHTC-138᦬

27 ᣣ(ᣣ)㨪
9 ᦬ 1 ᣣ(㊄)10th International Conference on Liquid Atomizationand Spray Systems (ICLASS-2006)9᦬

4 ᣣ(᦬)㨪
8 ᣣ(㊄)The Seventeenth International Symposium on Transport
Phenomena (ISTP-17)

વᾲ 2006 ᐕ 1 ᦬’05.9.1’05.11.18’05.12.1’06.1.13’06.3.31'05.11.30'05.7.31’06.2.28’05.12.15’06.03.18- 73 -‫ޥ‬160-0023 ᧲੩ㇺᣂኋ඙⷏ᣂኋ 7-5-13╙ 3 Ꮏᣂࡆ࡞ 4 㓏㧔␠㧕ࠟࠬ࠲࡯ࡆࡦቇળ
TEL:03-3365-0095 FAX:03-3365-0387
E-mail:gtsj@pluto.dti.ne.jp‫ޥ‬101-0025 ᧲੩ㇺජઍ↰඙␹↰૒ਭ㑆↸1-11(␠)ṁធቇળ Mate 2006 ੐ോዪ
TEL:06-6879-4166 FAX:06-6879-4166
E-mail:mate@casi.osaka-u.ac.jp‫ޥ‬101-0051 ᧲੩ㇺජઍ↰඙␹↰␹଻↸1-3-5(⽷)ൻቇᛛⴚᚢ⇛ផㅴᯏ᭴ౝ GSC ࡀ࠶࠻ࡢ࡯ࠢ੐ോዪᜂᒰ ᧻ጊ৻ᄦTEL:03-5282-7270
E-mail:matsuyama@jcii.or.jp‫ޥ‬487-8501 ᗲ⍮⋵ᤐᣣ੗Ꮢ᧻ᧄ↸ 1200
ਛㇱᄢቇᎿቇㇱᯏ᪾Ꮏቇ⑼ ട⮮ ┨TEL:0568-51-9385 FAX:0568-51-1194
E-mail:katoa@isc.chubu.ac.jp␹ᚭᄢቇ Ꮏቇㇱ ᵻ㊁╬㧔ᾲᎿቇㇱ㐷⻠⠌ળᆔຬળ࡮ᐙ੐㧕
TEL/FAX 078-803-6122
E-mail:asano@mech.kobe-u.ac.jp‫ޥ‬305-8568 ߟߊ߫Ꮢ᪢࿦ 1-1-1 ↥✚⎇ਛᄩ╙ 5
SMAM2-EC@m.aist.go.jp
T.Fujimoto@aist.go.jp
Co-Chair:
Professor Nobuhide Kasagi
Department of Mechanical Engineering
The University of Tokyo
Hongo, Tokyo 113-8656
E-Mail: kasagi@thtlab.t.u-tokyo.ac.jp
IHTC-13 Conference Managers
GPO Box 128
SYDNEY NSW 2001 AUSTRALIA
Phone: + 61 2 9265 0700
Fax: +61 2 9267 5443
Email: ihtc-13@tourhosts.com.au
http://ihtc-13.mech.unsw.edu.au/‫ޥ‬554-0022 ᄢ㒋Ꮢᱝ⧎඙ᤐᣣ಴ਛ 2-14-9
ᣣᧄᶧ૕ᓸ☸ൻቇળ ੐ോዪࢃቇⴚ಴ ශ೚᳇ઃ ੐ോዪ㐳 ㄭ⮮ ஜ
Tel:06-6466-1588 Fax:06-6463-2522
E-mail:info@ilass-japan.gr.jp‫ޥ‬939-0398
ንጊ⋵኿᳓㇭ዊ᧖㤥ᴡ 5180
ንጊ⋵┙ᄢቇᎿቇㇱ ᯏ᪾ࠪࠬ࠹ࡓᎿቇ⑼ᢎ᝼ ⍹Ⴆ ൎTel:0766-56-7500 Fax:0766-56-6131
e-mail: ishizuka@pu-toyama.ac.jp

J. HTSJ, Vol. 45, No. 190

ⴕ੐ࠞ࡟ࡦ࠳࡯
9᦬

25 ᣣ㧔᦬㧕 5th International Symposium on Turbulence, Heat andMass Transfer (Dubrovnik, Croatia)㨪29 ᣣ㧔㊄㧕10 ᦬

15 ᣣ㧔ᣣ㧕 International Workshop on Process Intensification(IWPI2006)㧔␹ᚭᄢቇ⊖ᐕ⸥ᔨળ㙚‫␹ޔ‬ᚭᏒ㧕㨪
18 ᣣ(᳓)'06.1.31'06.5.31’06.04.15

Professor Yasutaka Nagano, Co-Chairman
Department of Mechanical Engineering
Nagoya Institute of Technology
Gokiso-cho, Showa-ku, Nagoya 466-8555
E-mail: thmt-06@heat.mech.nitech.ac.jp
URL: http://www.ichmt.org/Thmt-06‫ޥ‬657-8501
␹ᚭᏒἥ඙౐↲บ↸ 1-1␹ᚭᄢቇᄢቇ㒮⥄ὼ⑼ቇ⎇ⓥ⑼㋈ᧁ ᵗTel / Fax:078-803-6490
e-mail: hero@kobe-u.ac.jp

11 ᦬ภ





વᾲ 2006 ᐕ 1 ᦬- 74 -J. HTSJ, Vol. 45, No. 190

߅⍮ࠄߖ╙ 43 ࿁ᣣᧄવᾲࠪࡦࡐࠫ࠙ࡓෳട↳ㄟᣇᴺ࡮㐿㐿 ௅ ᣣᐔᚑ 18 ᐕ 5 ᦬ 31 ᣣ (᳓) ޯ 6 ᦬ 2 ᣣ (㊄)࡮ળળ   ႐ฬฎደ࿖㓙ળ⼏႐㧔‫ޥ‬456-0036 ฬฎደᏒᾲ↰඙ᾲ↰⷏↸ 1 ⇟ 1 ภ㧘
Tel: 052-683-7711㧘http://www.u-net.city.nagoya.jp/ncc/㧕࡮ࠪࠪࡦࡐࠫ࠙ࡓෳ ട ⾌৻⥸㧔੐೨↳ㄟ㧦8,000 ౞㧘ળ႐↳ㄟ㧦10,000 ౞㧕ቇ↢㧔੐೨↳ㄟ㧦4,000 ౞㧘ળ႐↳ㄟ㧦5,000 ౞㧕

࡮⻠
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વᾲቇળળຬ㧦ήᢱ㧔CD-ROMࠍ੐೨ߦㅍઃߒ߹ߔ㧚ශ೚ ߪࠪࡦࡐࠫ࠙ࡓෳട⠪ߦᒰᣣᚻᷰߒ߹ߔ㧚㧕㕖ળຬ㧦8,000 ౞㧔ߚߛߒ㧘ળ႐ฃઃߢᣣᧄવᾲቇળߦ౉ળߐࠇࠆ႐วߪήᢱߢߔ㧚⺰ᢥ㓸ߩ⸤ㅍࠍᏗᦸߐࠇࠆ႐วߪ㧘೎ㅜㅍᢱ 1,000 ౞ࠍ↳ߒฃߌ߹ߔ㧚㧕࡮ᙣᙣ ⷫ ળᣣ ᤨ㧦 ᐔᚑ 18 ᐕ 6 ᦬ 1 ᣣ (ᧁ)ળ ႐㧦 ోᣣⓨࡎ࠹࡞࠭ ࡎ࠹࡞ࠣ࡜ࡦࠦ࡯࠻ฬฎደ
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㊄ߊߛߐ޿㧚ㅍ㊄ߦ޽ߚߞߡߪ㧘ᧄภߦ✄ㄟߺߩᛄㄟขᛒ␿ߩㅢାᰣߦ㧘ෳෳട↳ㄟ 1 ઙߏߣߦ‫ޟ‬ෳടฃઃ⇟ภ㧘ෳട⠪ߩ᳁ฬ㧘㊄㗵‫ࠍޠ‬ᔅߕ⸥౉ߊߛߐ޿㧚4 ઙࠍ⿥߃ࠆಽߩ
ㅍ㊄ߦߟ޿ߡߪ㧘ㇷଢዪ஻ઃߩᛄㄟขᛒ␿ߦࠃࠅ਄⸥ߣหߓᦠᑼߢㅍ㊄ߊߛߐ޿㧚৻ᐲෳട⊓㍳ߐࠇߚౝኈߪᄌᦝߢ߈߹ߖࠎ㧚ࡎ࡯ࡓࡍ࡯ࠫ߆ࠄෳട↳ㄟߢ߈ߥ޿႐วߦߪ㧘ਅ⸥੐ോዪ߹ߢ߅໧޿วࠊߖߊߛߐ޿㧚࡮ෳෳട⾌ᛄㄟవ

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ญᐳฬ⒓㧦╙ 43 ࿁ᣣᧄવᾲࠪࡦࡐࠫ࠙ࡓታⴕᆔຬળ

࡮੐੐೨↳ㄟ✦ಾ

ᐔᚑ 18 ᐕ 4 ᦬ 14 ᣣ (㊄)࡮ኋኋᴱ࡮⥶ⓨ೛

ታⴕᆔຬળߢߪ㧘ኋᴱ㧘⥶ⓨ೛╬ߩᢷᣓ࡮ખ੺ߪ޿ߚߒ߹ߖࠎߩߢ㧘ᰴ㗁ߩળ႐߳ߩ੤
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࡯ࠫߦߪኋᴱ࡮ᣏⴕ↪ߩ Web ࠨࠗ࠻ࠍឝタߒߡ޿߹ߔ㧚࡮߅߅໧޿วߖవ

‫ޥ‬466-8555 ฬฎደᏒᤘ๺඙ᓮེᚲ↸ฬฎደᎿᬺᄢቇ ߒߊߺ㗔ၞౝ╙ 43 ࿁ᣣᧄવᾲࠪࡦࡐࠫ࠙ࡓታⴕᆔຬળ
FAX: 052-735-5343
E-mail: nhts43@thermo.mech.nitech.ac.jp
URL: http://thermo.mech.nitech.ac.jp/~nhts43/

વᾲ 2006 ᐕ 1 ᦬- 75 -J. HTSJ, Vol. 45, No. 190

߅⍮ࠄߖળ႐߳ߩ੤ㅢ᩺ౝ

ᙣⷫળ႐ోᣣⓨࡎ࠹࡞࠭
ࠣ࡜ࡦࠦ࡯࠻ฬฎደ

⻠Ṷળ႐ฬฎደ࿖㓙ળ⼏႐̪ฬฎደ࿖㓙ળ⼏႐ࡎ࡯ࡓࡍ࡯ࠫ (http://www.ncvb.or.jp/ncc/koutu/kouiki/index.html) ࠃࠅォタ㧔৻ㇱᡷᄌ㧕੤ㅢࠕࠢ࠮ࠬ
ฬฎደ㚞࠲ࠢࠪ࡯࡮᧲ᶏ㆏ᣂᐙ✢
࡮㧶㧾✢
࡮ฬ㋕✢

ฬฎደ㚞
࿾ਅ㋕

࡮ㄭ㋕✢

ਛㇱ࿖㓙ⓨ᷼
(࠮ࡦ࠻࡟ࠕ)ฬ㋕✢㧗࿾ਅ㋕

વᾲ 2006 ᐕ 1 ᦬ฬฎደ࿖㓙ળ⼏႐ ⚂ 20 ಽ ⚂ 2,000 ౞ฬฎደ㚞᧲ጊ✢‫ޟ‬ᩕ‫ޠ‬̖̖ ਸ਼឵ ̖̖᪉ㅢ✢‫ޟ‬ਭደᄢㅢ‫ޠ‬ฬ᷼✢‫ޟ‬ᣣᲧ㊁‫ޠ‬ਅゞฬၔ✢‫⷏ޟ‬㜞⬿‫ޠ‬ਛㇱ࿖㓙ⓨ᷼

ᓤᱠ⚂ 5 ಽⓨ᷼✢ᔟㅦ․ᕆ 25 ಽฬ᷼✢‫ޟ‬ᣣᲧ㊁‫ޠ‬ਅゞฬၔ✢‫⷏ޟ‬㜞⬿‫ޠ‬ᓤᱠ⚂ 5 ಽ- 76 -⚂ 30 ಽ

࿾ਅ㋕
230 ౞⚂ 40 ಽ

ⓨ᷼✢
1,140 ౞࿾ਅ㋕200 ౞ฬฎደ࿖㓙ળ⼏႐㊄ጊ

࿾ਅ㋕ 2 ಽฬฎደ࿖㓙ળ⼏႐

J. HTSJ, Vol. 45, No. 190

߅⍮ࠄߖળ႐๟ㄝߩࡎ࠹࡞ߥߤ
⥋ฬฎደ㚞ోᣣⓨࡎ࠹࡞࠭ ࡎ࠹࡞ࠣ࡜ࡦࠦ࡯࠻Ԝ ԡԘ ฬฎደ ‫ޣ‬ᙣⷫળ႐‫ޤ‬ԣԙ ࠞࡊ࠮࡞ࠗࡦฬฎደ

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Ԛ ฬฎደ㊄ጊࡢࠪࡦ࠻ࡦࡎ࠹࡞ࡊ࡜ࠩ

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㊄ጊ✚ว㚞ԛ ࠨࠗࡊ࡟ࠬࠟ࡯࠺ࡦࡎ࠹࡞ԛԞԜ ࡎ࠹࡞࡛ࠠࠪฬฎደ╙ੑԠ

ԝ ㊄ጊࡊ࡜ࠩࡎ࠹࡞⷏㜞⬿㚞Ԟ ࡊ࠴ࡎ࠹࡞ ࠾ࡘ࡯߭߰ߺ

ᣣᲧ㊁㚞ԟ ᾲ↰ߩ᧡ࡎ࠹࡞ᷓ⠑⧞ԟฬฎደ࿖㓙ળ⼏႐Ԡ ࡎ࠹࡞޿ࠈߪԡ ࡎ࠹࡞࡛ࠠࠪฬฎደԢ ࠛࠢ࠮࡞ࠗࡦฬฎደ࡮ᾲ↰ԣ ࡆࠫࡀࠬࡎ࠹࡞ߥ߆߿߹
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500m

Ԥ ฬ㋕ࠗࡦ ฬฎደ ㊄ጊ

1km̪ฬฎደ࿖㓙ળ⼏႐ࡎ࡯ࡓࡍ࡯ࠫ (http://www.ncvb.or.jp/ncc/guide/shukuhaku/index.html) ࠃࠅォタ㧔৻ㇱᡷᄌ㧕

વᾲ 2006 ᐕ 1 ᦬

- 77 -J. HTSJ, Vol. 45, No. 190

߅⍮ࠄߖ╙ 43 ࿁ᣣᧄવᾲࠪࡦࡐࠫ࠙ࡓ⻠Ṷ⺰ᢥේⓂߩឭ಴ᣇᴺ
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࡮⻠Ṷ⺰ᢥ㓸ߣߒߡ㧘ࠝࡈ࠮࠶࠻ශ೚ 㧔ౠሶ૕㧘⊕㤥㧕ߣ CD-ROM ࠍ૞⵾ߒ߹ߔ㧚ශ೚ ߩ⻠Ṷ⺰ᢥߩ㐳ߐߪ 1 㗴⋡޽ߚࠅ A4 ࠨࠗ࠭ߢ 2 ࡍ࡯ࠫߣߒ߹ߔ㧚⺰ᢥߩ૞ᚑࡈࠜ࡯ࡑ࠶࠻ߪ೨࿁ߣห᭽ߢߔ㧔2 Ბ⚵஥ 26 ሼ60 ⴕ㧕㧚ߚߛߒ㧘CD-ROM ߦߪ㧘ࠝࡈ࠮࠶࠻ශ೚ ߣหߓ߽ߩ߆㧘߹ߚߪ 8 ࡍ࡯ࠫએౝߩࡈ
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ߚ⺰ᢥߪ⻠Ṷ⺰ᢥ㓸ߦឝタߐࠇߥ޿ߎߣ߇޽ࠅ߹ߔ㧚ේⓂឭ಴✦ಾᣣߦߪචಽߏᵈᗧߊߛߐ޿㧚
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PDF ᄌ឵࠰ࡈ࠻࠙ࠚࠕࠍ⸳ቯߊߛߐ޿㧚⻠Ṷ⺰ᢥ㓸ឝタᤨߩ⻉໧㗴ߦߟ޿ߡߪේೣߣߒߡ⪺⠪ߩ⽿છߣߒ߹ߔ㧚࡮⺰ᢥߩ૞ᚑ߅ࠃ߮㔚ሶࡈࠔࠗ࡞ൻ㧔PDF ߳ߩᄌ឵㧕ߦ޽ߚߞߡߪᰴߩ⸃⺑߇ෳ⠨ߦߥࠅ߹ߔ㧚ዊᨋஜ৻㧘‫ޟ‬Microsoft Word ࠍ૶ߞߚ⺰ᢥ૞ᚑᣇᴺ‫ޠ‬㧘ᣣᧄᯏ᪾ቇળ⹹㧘103-979 (2000.6)㧘pp. 396-403.
Ꮉ㊁ᶈ৻㇢࡮ጟᧄቁม㧘‫⺰ޟ‬ᢥߩ㔚ሶൻߦߟ޿ߡ㧔ࠃࠅ⦟޿ PDF ࠍ૞ࠆߚ߼ߦ㧕‫ޠ‬㧘นⷞൻᖱႎ㧘20-77 (2000.4),
pp. 133-138.

JST ࠺࡯࠲ࡌ࡯ࠬ↪๺ᢥᛞ㍳ߩឭ಴ߩ߅㗿޿ᧄࠪࡦࡐࠫ࠙ࡓߢ⊒⴫ߐࠇࠆ⺰ᢥߩᛞ㍳ߪ⑼ቇᛛⴚᝄ⥝ᯏ᭴㧔JST㧕ߩ࠺࡯࠲ࡌ࡯ࠬߦ෼㍳ߐࠇ߹ߔߩߢ㧘ࡎ࡯ࡓࡍ࡯ࠫߩ౉Ⓜ᩺ౝߦߒߚ߇ߞߡ JST ࠺࡯࠲ࡌ࡯ࠬ↪ᛞ㍳㧔๺ᢥ㧕ࠍឭ಴ߊߛߐ޿㧚⻠Ṷ↳ㄟᤨߩࠕࡉ
ࠬ࠻࡜ࠢ࠻ࠍᄌᦝߒߥ޿႐วߦߪ㧘ᡷ߼ߡឭ಴ߔࠆᔅⷐߪ޽ࠅ߹ߖࠎ㧚ᄌᦝߔࠆ႐วߦߪ㧘౉Ⓜ↪ Web ࡍ࡯ࠫߩ⹥ᒰᰣߦᄌᦝᓟߩᛞ㍳ࠍ౉ജߊߛߐ޿㧚ᧄࠪࡦࡐࠫ࠙ࡓߢ⊒⴫ߐࠇߚ⺰ᢥ߇ㅦ߿߆ߦ߆ߟᐢߊᒁ↪ߐࠇࠆߎߣ߇⋡⊛ߢߔߩߢ㧘ߏදജߊߛߐࠆࠃ߁߅㗿޿ߒ߹ߔ㧚વᾲቇળ⺰ᢥ⹹ "Thermal Science and Engineering" (TSE) ߳ߩᛩⓂߦߟ޿ߡᧄࠪࡦࡐࠫ࠙ࡓߩ⻠Ṷ⺰ᢥߩ߁ߜ CD-ROM ߦឝタߐࠇߚࡈ࡞ࡍ࡯ࡄ࡯ߪ㧘ᣣᧄવᾲቇળ⹹‫ޟ‬વᾲ‫ߣޠ‬ߩวᧄߢ޽ࠆ"Thermal Science and Engineering"㧔એਅ TSE㧕߳ߘߩ߹߹ᛩⓂߢ߈߹ߔ㧚TSE ߳ᛩⓂࠍᏗᦸߐࠇࠆ႐วߪ㧘ේⓂឭ಴ߩ㓙ߦ Web ౉Ⓜࠪࠬ࠹ࡓߢߘߩᣦ߅⍮ࠄߖߊߛߐ޿㧚ᛩⓂࠍᏗᦸߐࠇࠆ೨ߦ㧘TSE ߩ
ᛩⓂⷙቯࠍߏ৻⺒㗿޿߹ߔ㧔ᣥ TSE ߩᛩⓂⷙቯߣၮᧄ⊛ߦห৻ߢߔ㧕㧚ᩏ⺒ߪࠪࡦࡐࠫ࠙ࡓ⚳ੌᓟ㧘CD-ROMߦឝタߐࠇߚ⻠Ṷ⺰ᢥࠍ߽ߣߦ㧘TSE ࠴࡯ࡈࠛ࠺ࠖ࠲࡯ߩਅߢⴕࠊࠇ߹ߔߩߢ㧘ߘߩᜰ␜ߦᓥߞߡߊߛߐ
޿㧚ឝタนߣߥߞߚߣ߈㧘TSE ߩ࠹ࡦࡊ࡟࡯࠻ࠍ↪޿ߚᦨ⚳ේⓂߩᦠ߈⋥ߒߩᜰ␜߇޽ࠅ߹ߔ㧚ߘߩᲑ㓏ߢ㧘ࡢ࡯ࡊࡠ౉ജࡒࠬ╬ਇㆡಾߥ߽ߩ߇޽ࠆ႐วߦߪ㧘✬㓸⠪߇⪺⠪ߦౣᐲୃᱜ╬ߩᜰ␜ࠍⴕ޿߹ߔߩߢ㧘ߘࠇ

વᾲ 2006 ᐕ 1 ᦬

- 78 -J. HTSJ, Vol. 45, No. 190

߅⍮ࠄߖߦᓥߞߡߊߛߐ޿㧚ߘߩઁߦߟ޿ߡߪ㧘ᣣᧄવᾲቇળ TSE ߩࡎ࡯ࡓࡍ࡯ࠫߦឝタߒߡ޽ࠆౝኈߦḰ᜚ߔࠆ߽ߩߣߒ߹ߔ㧚ߥ߅㧘ᧄࠪࠬ࠹ࡓߢ TSE ߳ᛩⓂߐࠇߚ႐ว㧘⺰ᢥฃℂᣣߪવᾲࠪࡦࡐࠫ࠙ࡓታⴕᆔຬળ߇⺰
ᢥේⓂࠍฃߌઃߌߚᣣߦߥࠅ߹ߔ㧚߹ߚ㧘ࠞ࡜࡯ේⓂߩ႐วߢ߽ TSE ឝタᤨߪࡕࡁࠢࡠߢශ೚ߐࠇ߹ߔ߇㧘Ꮧᦸߦࠃࠅࠞ࡜࡯ශ೚߽น⢻ߢߔ㧔᦭ᢱ㧕㧚‫߅ޣ‬໧޿วߖవ‫ޤ‬‫ޥ‬466-8555 ฬฎደᏒᤘ๺඙ᓮེᚲ↸ฬฎደᎿᬺᄢቇ ߒߊߺ㗔ၞౝ╙ 43 ࿁ᣣᧄવᾲࠪࡦࡐࠫ࠙ࡓታⴕᆔຬળ
FAX: 052-735-5343
E-mail: nhts43@thermo.mech.nitech.ac.jp
URL: http://thermo.mech.nitech.ac.jp/~nhts43/‫⺰ޣ‬ᢥේⓂឭ಴ߩ✦ಾ‫ޤ‬

ᐔᚑ 18 ᐕ 3 ᦬ 13 ᣣ (᦬)વᾲ 2006 ᐕ 1 ᦬- 79 -J. HTSJ, Vol. 45, No. 190

߅⍮ࠄߖવᾲࠪࡦࡐࠫ࠙ࡓ⻠Ṷ⺰ᢥߩᦠ߈ᣇ
ߎߎߢߪ㧘⺰ᢥේⓂߩᦠᑼߣ PDF ࡈࠔࠗ࡞ൻࠍਛᔃߦߒߡ㧘⻠Ṷ⺰ᢥߩᦠ߈ᣇࠍ⺑᣿ߒ߹ߔ㧚‫⺰ޟ‬ᢥේⓂߩ㐳ߐ㧔ᓥ᧪ߣߪ⇣ߥࠆὐ㧕‫ޠ‬⺰ᢥේⓂߩ㐳ߐ㧔ࡍ࡯ࠫᢙ㧕ߪ㧘ශ೚ ߢߪ 2 ࡍ࡯ࠫએౝ㧔ࡕࡁࠢࡠ㧕ߣᓥ᧪ߤ߅ࠅߢߔ߇㧘CD-ROM
ߢߪ 8 ࡍ࡯ࠫએౝ㧔ࠞ࡜࡯น㧕߹ߢᦠߌࠆࠃ߁ߦߥࠅ߹ߒߚ㧚ߚߛߒ㧘޿ߕࠇߩ႐วߢ߽ේⓂߩࡈࠔ
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߹ߊㆬᛯߒߡශ೚ 㧔ࡕࡁࠢࡠ㧕ߢ್߽⺒ߢ߈ࠆࠃ߁ߦ࿑ࠍ૞ᚑߊߛߐ޿㧚‫ޟ‬ᢥ┨㧘࿑࡮⴫࡮౮⌀㧘ᢙᑼߥߤߩ㔚ሶൻ‫ޠ‬
ේⓂߩ PDF ࡈࠔࠗ࡞ࠍ૞ᚑߔࠆߚ߼ߦ㧘ᢥ┨㧘࿑࡮⴫࡮౮⌀㧘ᢙᑼߥߤ⺰ᢥߢ૶↪ߔࠆోߡߩ⚛᧚ࠍ㔚ሶࡈࠔࠗ࡞ൻߒߡ㧘ߘࠇࠄࠍࡢ࡯ࡊࡠ࠰ࡈ࠻╬ߢ࡟ࠗࠕ࠙࠻ߒߡߊߛߐ޿㧚‫ޟ‬PDF ࡈࠔࠗ࡞ߩࠨࠗ࠭‫ޠ‬㧝ߟߩ⺰ᢥ޽ߚࠅ 2 MB㧔ࡔࠟࡃࠗ࠻㧕ߦ෼߹ࠆࠃ߁ߦ⺞ᢛߊߛߐ޿㧚ࡈࠔࠗ࡞ࠨࠗ࠭߇ 2 MB ࠍ⿥߃ࠆ
ේⓂߪฃℂߐࠇߥ޿น⢻ᕈ߇޽ࠅ߹ߔ㧚ߤ߁ߒߡ߽෼߹ࠄߥ޿႐วߦߪ੐ോዪߦߏㅪ⛊ߊߛߐ޿㧚‫↪૶ޟ‬น⢻ߥࡈࠜࡦ࠻‫ޠ‬⺰ᢥ㧔ᧄᢥ㧘࿑࡮⴫ߥߤ㧕ߢߪਅ⴫ߦ␜ߔࡈࠜࡦ࠻ࠍ૶↪ߊߛߐ޿㧚ߎࠇએᄖߩࡈࠜࡦ࠻ࠍ↪޿ࠆߣ㧘
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࡮Acrobat Distiller Ver. 7.0 ߢ޽ࠇ߫㧘ࡊ࡟ࠬຠ⾰ߩ࡚ࠫࡉࠝࡊ࡚ࠪࡦࠍ⸳ቯߔࠆ㧔ᣥࡃ࡯࡚ࠫࡦߩ

વᾲ 2006 ᐕ 1 ᦬- 80 -J. HTSJ, Vol. 45, No. 190

߅⍮ࠄߖ⺰ᢥේⓂߩ⷗ᧄ㧔వ㗡ࡍ࡯ࠫߩᦠᑼ㧕႐วߪ㧘ㆊ෰ߩળ๔╬ࠍෳᾖߊߛߐ޿㧕㧚
4㧚ශ೚ࠍታⴕߒ㧘಴ജߐࠇߚ PDF ࡈࠔࠗ࡞ࠍᬌᩏߒߡ໧㗴߇ߥ޿ߎߣࠍ⏕⹺ߔࠆ㧚ᵈ) ⻠Ṷ⇟ภ㧘ࠪࡦࡐࠫ࠙ࡓฬ㧘ࡍ࡯ࠫ⇟ภ╬ߪታⴕᆔຬળ஥ߢ⸥౉ߒ߹ߔ㧚਄૛⊕㧦20 mm

Ბ㑆㓒㧦10 mm

ฝ૛⊕㧦15 mm

150 mmᏀ૛⊕㧦15 mm‫ޟ‬ේⓂᦠᑼߩ⹦⚦‫ޠ‬⻠Ṷ⺰ᢥߩේⓂߪએਅߩⷐ㗔ߢ૞ᚑߊߛߐ޿㧚٠ ⴫㗴ㇱಽ
ฝ࿑ߩࠃ߁ߦᲑ⚵ߺߖߕߦ᏷ 150 mm ߦ෼߼ߡߊߛߐ޿㧚⺰ᢥ㗴⋡㧘ળຬ⾗ᩰ࡮⪺⠪ฬ࡮ᚲዻ㧔⇛⸥㧕ߪ⻠Ṷ↳ㄟᤨߩౝኈߣ৻⥌ߐߖߡߊߛ
ߐ޿㧚↳ㄟᤨߣ⇣ߥࠆߣ⋡ᰴ╬ߦߪ෻ᤋߐࠇ߹
ߖࠎ㧚ㅪฬߩ႐วߦߪ⻠Ṷ⠪᳁ฬߩ೨ߦ㧖ශࠍઃߌߡߊߛߐ޿㧚⧷ᢥᚲዻ߇ⶄᢙ޽ࠆ႐วߪ㧘ਅߩ⷗ᧄߩࠃ߁ߦ਄ઃ߈ᢙሼߢ඙೎ߊߛߐ޿㧚٠ ᧄᢥ
1 ࡍ࡯ࠫ⋡ߪ㧘ฝ࿑ߩࠃ߁ߦ 2 Ბ⚵㧔 ஥ 1 ⴕ
26 ᢥሼ⒟ᐲ㧕ߦߒߡ 9 ࡐࠗࡦ࠻ߢ૞ᚑߊߛߐ޿㧚
2 ࡍ࡯ࠫ⋡એ㒠ߪ㧘ࡍ࡯ࠫߩవ㗡߆ࠄ 2 Ბ⚵㧔஥ 60 ⴕ⒟ᐲ㧕ߦ⸳ቯߒߡߊߛߐ޿㧚٠ ࿑߅ࠃ߮⴫
࿑⴫ਛߩ⸥ภ߅ࠃ߮࿑⴫ߩᮡ㗴㧔ࠠࡖࡊ࡚ࠪࡦ㧕ߪ⧷⺆ߢᦠ޿ߡߊߛߐ޿㧚٠ ෳ⠨ᢥ₂ᒁ↪ߒߚ޿▎ᚲߦዊ᜝ᒐઃ߈ߩᢥ₂⇟ภ(1)ࠍᝌ
౉ߒ߹ߔ㧚ᢥ₂࡝ࠬ࠻ߪ㧘ᰴߩ᭽ᑼߦࠃࠆ৻ⷩ
ᒻᑼߢᧄᢥߩᧃየߦ㈩⟎ߒߡߊߛߐ޿㧚(1) વᾲ࡮ઁ 2 ฬ㧘ᯏ⺰(B)㧘99-999 (2005), 123.
[⪺⠪ฬ㧘㔀⹹⇛⒓㧘Ꮞ-ภ (⊒ⴕᐕ)㧘వ㗡ࡍ࡯ࠫ].

⺰ᢥ㗴⋡㧔๺ᢥ࡮⧷ᢥ㧕ળຬ⾗ᩰ࡮⪺⠪ฬ࡮ᚲዻ㧔๺ᢥ࡮⧷ᢥ㧕⧷ᢥࠕࡉࠬ࠻࡜ࠢ࠻
⧷⺆ࠠ࡯ࡢ࡯࠼

ᧄᢥ 

ᧄᢥ 

࡮ශ೚ 㧔2 ࡍ࡯ࠫએౝ㧘ࡕࡁࠢࡠ㧕࡮CD-ROM 㧔8 ࡍ࡯ࠫએౝ㧘ࠞ࡜࡯น㧕ශ೚ 㧦 2 ࡍ࡯ࠫએౝ㧔ࡕࡁࠢࡠ㧕
CD-ROM 㧦 8 ࡍ࡯ࠫએౝ㧔ࠞ࡜࡯น㧕ਅ૛⊕㧦20 mm↪⚕㧦A4 (210 mm297 mm) ߩ❑⴫㗴ㇱಽߩ⷗ᧄ

વᾲࠪࡦࡐࠫ࠙ࡓ⻠Ṷ⺰ᢥߩᦠ߈ᣇ㧔๺ᢥ㗴⋡࡮14 ࡐࠗࡦ࠻㧕㧔๺ᢥ೽㗴࡮12 ࡐࠗࡦ࠻㧘ή޿႐วߪ 1 ⴕ޽ߌࠆ㧕
Instruction for Preparing a Paper 㧔⧷ᢥ㗴⋡࡮12 ࡐࠗࡦ࠻㧕㧔⧷ᢥ೽㗴࡮12 ࡐࠗࡦ࠻㧘ή޿႐วߪߟ߼ࠆ㧕㧔1 ⴕ޽ߌࠆ㧕વᱜ 㧖વᾲ ᄥ㇢㧔ᾲ㊀Ꮏ㧕ᯏᱜ  ᯏ᪾ ᰴ㇢㧔વᎿᄢ㧕વቇ  ᾲജ ⧎ሶ㧔વᎿᄢ㧕㧔12 ࡐࠗࡦ࠻㧘⻠Ṷ⠪ߦߪ㧖ࠍઃߌࠆ㧕㧔1 ⴕ޽ߌࠆ㧕
Taro DENNETSU1, Jiro KIKAI2, Hanako NETURIKI2㧔10 ࡐࠗࡦ࠻㧕1
Netsu Heavy Industries Ltd., 1-2-3 Sakura, Ohmiya, Saitama 123-4567
2
Dept. of Mech. Eng., Dennetsu Inst. Tech., 4-5 Fuji, Yokohama, Kanagawa 890-1234
㧔1 ⴕ޽ߌࠆ㧕㧔5 ᢥሼ޽ߌࠆ㧕English abstract. 㧔⧷ᢥࠕࡉࠬ࠻࡜ࠢ࠻࡮10 ࡐࠗࡦ࠻㧘100 ⺆⒟ᐲ㧕‫غغغغ‬‫غغغغغغغغغغغغغغغغغغغغغغغغغغغغغغغغغغغغغغغغغ‬‫غغغغغغغغغغغ‬.
㧔1 ⴕ޽ߌࠆ㧕
Key Words : Heat Transfer, Forced Convection...㧔10 ࡐࠗࡦ࠻࡮3㨪5 ୘⒟ᐲ㧕વᾲ 2006 ᐕ 1 ᦬- 81 -J. HTSJ, Vol. 45, No. 190

߅⍮ࠄߖInternational Heat Transfer Conference 2006㐿௅ᦼ㑆 2006 ᐕ 8 ᦬ 13 ᣣ(ᣣ)㨪18 ᣣ(㊄)㐿௅ળ႐ ࠝ࡯ࠬ࠻࡜࡝ࠕ ࠪ࠼࠾࡯ Sydney Convention & Exhibition Centre಴Ꮸ࠷ࠕ࡯ߩߏ᩺ౝ㧔੍๔ 㧕
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Conference 2006 (IHTC2006) ߇㐿௅ߐࠇ߹ߔ㧚ᑷ␠ߪ㧘ߎࠇ߹ߢ೨࿁ߩࠣ࡞ࡁ࡯ࡉ࡞ߢߩળ⼏ࠍߪߓ߼㧘AJTEC 2003 ߩࠝࡈࠖࠪࡖ࡞ࠛ࡯ࠫࠚࡦࠪ࡯ߣߒߡળ⼏ߩㆇ༡߆ࠄෳട⠪ߩᣏⴕᚻ㈩߹ߢ᏷ᐢߊ߅ᚻવ޿ߐ
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વᾲ 2006 ᐕ 1 ᦬- 82 -J. HTSJ, Vol. 45, No. 190

੐ോዪ߆ࠄߩㅪ⛊੐ോዪ߆ࠄߩㅪ⛊㧝㧚ቇળ᩺ౝߣ౉ળᚻ⛯߈ߦߟ޿ߡ

ߢߩળ⾌ࠍ⚊౉ߒߚળຬߦ㒢ࠆ㧕‫ޤ⊛⋡ޣ‬
ᧄળߪ㧘વᾲߦ㑐ߔࠆቇℂᛛⴚߩㅴዷߣ⍮⼂ߩ᥉෸㧘ળຬ⋧੕߅ࠃ߮࿖㓙⊛ߥ੤ᵹࠍ࿑ࠆߎߣࠍ⋡⊛ߣߒߡ޿߹ߔ㧚‫ޣ‬ળ⸘ᐕᐲ‫ޤ‬ળ⸘ᐕᐲߪ㧘Ფᐕ 4᦬ 1ᣣߦᆎ߹ࠅ⠉ᐕ 3᦬ 31ᣣ߹ߢߢߔ㧚‫ޣ‬ળຬߩ⒳೎ߣળ⾌‫ޤ‬ળຬ⒳೎

⾗  ᩰ

વᾲߦ㑐ߔࠆቇ⼂⚻㛎ࠍ᦭ߔࠆᱜ⠪ߢ㧘ᧄળߩ⋡⊛ߦ⾥หߒߡ౉ળ
ળຬ
ߒߚ୘ੱ

ળ⾌
㧔ᐕ㗵㧕
8,000౞

ᧄળߩ⋡⊛ߦ⾥หߒ㧘ᧄળߩ੐ᬺ
1ญ
⾥ഥࠍេഥߔࠆᴺੱ߹ߚߪߘߩ੐ᬺ
30,000౞ળຬᚲ㧘޽ࠆ޿ߪ୘ੱ
㜞ኾ㧘⍴ᄢ㧘ᄢቇߩቇㇱ߅ࠃ߮ᄢቇ↢ቇ㒮ߦ࿷ቇਛߩቇ↢ߢ㧘ᧄળߩ⋡ળຬ⊛ߦ⾥หߒߡ౉ળߒߚ୘ੱ

‫౉ޣ‬ળᚻ⛯߈‫ޤ‬ᱜળຬ߹ߚߪቇ↢ળຬ߳ߩ౉ળߩ㓙ߪ㧘౉ળ↳ㄟ↪
⚕ߦߏ⸥౉ߩ਄㧘੐ോዪተߦࡈࠔ࠶ࠢࠬ߹ߚߪㇷㅍߢㅍࠅ㧘ㇷଢᝄᦧߦߡᒰ⹥ᐕᐲળ⾌ࠍ߅ᡰᛄ޿ਅߐ
޿㧚⾥ഥળຬ߳ߩ౉ળߩ㓙ߪ㧘౉ળ↳ㄟ↪⚕ߦߏ⸥౉ߩ਄㧘੐ോዪተߦࡈࠔ࠶ࠢࠬ߹ߚߪㇷㅍߢ߅ㅍࠅ
ਅߐ޿㧚ᔅⷐ߇޽ࠇ߫ᧄળߩౝኈ㧘ળೣ㧘౉ળᚻ⛯߈╬ߦߟ޿ߡߏ⺑᣿ߒ߹ߔ㧚⾥ഥળຬ߳ߩ↳ㄟߺߪ૗ญߢ߽น⢻ߢߔ㧚㧔ᵈᗧ㧕࡮↳ㄟ↪⚕ߦߪ᳁ฬࠍ᣿⍎ߦ⸥౉ߒ㧘㔍⺒ᢥሼߦߪ JIS ࠦ࡯࠼ߩߏᜰ␜ࠍ߅㗿޿ߒ߹ߔ㧚࡮ળ⾌⚊౉ᤨߩㇷଢᝄᦧ↪⚕ߦߪ㧘ળຬฬ㧔ᔅⷐߦᔕߓߡࡈ࡝ࠟ࠽ࠍઃߔ㧕ࠍᔅߕ⸥౉ߒߡਅߐ޿㧚ળ␠ฬߩߺ⸥タߩ႐ว㧘౉㊄ߩขᛒ޿߇ߢ߈ߕ㧘ળ⾌ᧂ⚊ߩ߹߹ߣߥࠅ߹ߔ㧚࡮ቇ↢ળຬ߳ߩ౉ળ↳ㄟߦ߅޿ߡߪ㧘ᜰዉᢎቭߦࠃ
ࠆ࿷ቇ⸽᣿㧔⟑ฬ࡮ᝲශ㧕߇ᔅⷐߢߔ㧚㧞㧚ળຬߩᣇ‫߳ޘ‬4,000౞

‫ޣ‬ળຬჇടߣ⾥ഥળຬญᢙჇടߩ߅㗿޿‫ޤ‬8,000౞ฬ⹷ ᧄળߦ․ߦഞഭߩ޽ߞߚ⠪ߢ㧘✚
ૉߒ70ᚽ
ળຬ ળߦ߅޿ߡផ⮈ߐࠇߚ⠪એ਄ߪ0౞ᧄળߩ⊒ዷߦነਈߔࠆߎߣ߇ᦼ
ផ⮈ᓙߢ߈ࠆ⠪ߢ㧘ᒰ⹥ᐕᐲߩ✚ળߦળຬ߅޿ߡផ⮈ߐࠇߚ⠪୘ੱળຬߣ⾥ഥળຬߩჇട߇ᬌ⸛ߐࠇߡ޿߹ߔ㧚ળຬߩ⊝᭽ߦ߅߆ࠇ߹ߒߡ߽㧘ߢ߈ࠆ㒢ࠅ๟࿐ߩ㑐ㅪߩᣇ‫߿ޘ‬࿅૕ߦ౉ળࠍ߅⺃޿ਅߐࠆࠃ߁߅
㗿޿ߒ߹ߔ㧚߹ߚ㧘⾥ഥળຬ߳ߩ౉ળ↳ㄟߺฃઃߦ߅߈߹ߒߡ㧘 A㧔 3ญ㧕㧘 B㧔 2ญ㧕㧘 C㧔 1ญ㧕ߣಽߌߡ߅ࠅ߹ߔ㧚⃻⾥ഥળຬߦ߅߆ࠇ߹ߒߡ߽㧘ߢ߈ࠆ㒢ࠅญᢙߩჇടࠍ߅㗿޿ߒ߹ߔ㧚0౞‫ޣ‬ળຬߩ․ౖ‫ޤ‬ળຬߪᧄળߩᵴേߦෳടߢ߈㧘ᰴߩ․ౖ߇޽ࠅ߹ߔ㧚

1. ‫ޟ‬વᾲ‫ ޠ‬, ‫ ޟ‬Thermal Science and Engineering ‫ޠ‬ࠍㇷㅍߒ߹ߔ㧚 㧔ᧄᐕᐲ⊒ⴕ੍ቯ㧦 4㧘 7㧘 10㧘 1᦬ภ㧕  ࡮ᱜળຬ㧘ቇ↢ળຬ㧘ฬ⹷ળຬ㧘ផ⮈ળຬߦ 1ౠㅍઃ  ࡮⾥ഥળຬߦญᢙಽߩౠᢙㅍઃ

2. ‫ޟ‬ᣣᧄવᾲࠪࡦࡐࠫ࠙ࡓ⻠Ṷ⺰ᢥ㓸‫ࠍޠ‬ήᢱߢߐߒ޽ߍ߹ߔ㧚  ࡮ᱜ࡮ቇ↢࡮ฬ⹷࡮ផ⮈ߩฦળຬߦ 1 ㇱ㧘⾥ഥળຬߦญᢙಽߩㇱᢙ㧔ૉߒ㧘વᾲࠪࡦࡐࠫ࠙
ࡓ㐿௅ߩ೨ᐕᐲߩ 3 ᦬ 25 ᣣ߹ߢߦ೨ᐕᐲಽ߹

વᾲ 2006 ᐕ 1 ᦬- 83 -‫ޣ‬ળ⾌⚊౉ߦߟ޿ߡ‫ޤ‬ળ⾌ߪᒰ⹥ᐕᐲౝߦ⚊౉ߒߡߊߛߐ޿㧚⺧᳞ᦠߪ߅↳ߒ಴ߩߥ޿㒢ࠅ․ߦ⊒ⴕߒ߹ߖࠎ㧚ળ⾌⚊౉⁁ᴫߪ੐ോዪߦ߅໧޿วߖਅߐ޿㧚ળ⾌⚊౉ߦߪ᛬ㄟߺߩㇷଢᝄᦧ↪⚕ࠍߏ೑↪ਅߐ޿㧚ߘߩઁߩ
ㅍ㊄ᣇᴺߢᚻᢙᢱ߇ᔅⷐߥ႐วߦߪ㧘ㅍ㊄⠪஥ߩ
⽶ᜂߦߡ߅㗿޿⥌ߒ߹ߔ㧚ࡈ࡝ࠟ࠽ฬߩᬌ⚝ߦࠃ
ߞߡ౉㊄ߩ੐ോಣℂࠍⴕߞߡ߅ࠅ߹ߔߩߢળ␠
ฬߩߺߢળຬฬߩ⸥タ߇ߥ޿႐วߦߪᧂ⚊ᛒ޿ߦߥࠅ߹ߔ㧚
‫ޣ‬ᄌᦝዯߦߟ޿ߡ‫ޤ‬㧔ൕോవ㧘૑ᚲ㧘ㅢାవ╬ߩᄌᦝ㧕ൕോవ㧘૑ᚲ㧘ㅢାవ╬ߦᄌᦝ߇↢ߓߚ႐วߦߪ㧘

J. HTSJ, Vol. 45, No. 190

੐ോዪ߆ࠄߩㅪ⛊Ꮞᧃߩ‫ޟ‬ᄌᦝዯ↪⚕‫ߡߦޠ‬ㅦ߿߆ߦ੐ോዪ߳߅⍮ࠄߖਅߐ޿㧚ㅢାవߩᄌᦝዯ߇ߥ޿႐วߦߪ㧘ㇷㅍ‛߇ળຬߦ⏕ታߦዯ߆ߕ㧘޽ࠆ޿ߪተฬਇ᣿ߦ
ࠃࠅએ㒠ߩㇷㅍ߇⛮⛯ߢ߈ߥߊߥࠅ߹ߔ㧚߹ߚ㧘ౣ⊒ㅍ߇น⢻ߥ႐วߦ߽ߘߩ⾌↪ࠍߏ⽶ᜂ㗂ߊߎߣߦߥࠅ߹ߔ㧚㧔⾥ഥળຬߩઍ⴫⠪ᄌᦝ㧕
⾥ഥળຬߩ႐วߦߪ㧘ᔅⷐߦᔕߓߡઍ⴫⠪ࠍᄌᦝߢ߈߹ߔ㧚㧔ቇ↢ળຬ߆ࠄᱜળຬ߳ߩᄌᦝ㧕ቇ↢ળຬ߇␠ળੱߦߥࠄࠇߚ႐วߦߪ㧘ળ⾌߇ᄌࠊࠅ߹ߔߩߢᱜળຬ߳ߩᄌᦝዯࠍㅦ߿߆ߦߏឭ
಴ਅߐ޿㧚ߎߩߎߣߦߟ߈߹ߒߡߪ㧘ᜰዉᢎቭߩ
ᣇ‫ߏ߽ࠄ߆ޘ‬ᜰዉࠍ߅㗿޿ߒ߹ߔ㧚㧔ᄌᦝዯឭ಴਄ߩᵈᗧ㧕ળຬ࠺࡯࠲ࠍᄌᦝߔࠆ㓙ߩ⺋ࠅࠍ㒐ߋߚ߼㧘ᄌᦝዯߪᔅߕᦠ㕙ߦߡળຬ⥄り߽ߒߊߪઍℂߣ⹺߼ࠄࠇࠆᣇ߇ߏឭ಴ਅߐࠆࠃ߁߅㗿޿ߒ߹ߔ㧚‫ޣ‬ㅌળዯߦߟ޿ߡ‫ޤ‬ㅌળࠍᏗᦸߐࠇࠆᣇߪ㧘ㅌળᣣઃߌࠍ⸥ߒߚᦠ㕙ߦߡㅌળዯ㧔ㇷଢᝄᦧ↪⚕ߦ⸥タน㧕ࠍឭ಴ߒ㧘ᧂ⚊ળ⾌ࠍ⚊౉ߒߡਅߐ޿㧚ળຬ⊓㍳ࠍ᛹ᶖߒ߹ߔ㧚‫ޣ‬ળ⾌ࠍ㐳ᦼṛ⚊ߐࠇߡ޿ࠆᣇ߳‫ޤ‬㐳ᦼ㑆㧘ળ⾌ࠍṛ⚊ߐࠇߡ޿ࠆળຬߩᣇ‫ߪޘ‬㧘⥋ᕆ⚊౉ࠍ߅㗿޿ߒ߹ߔ㧚․ߦ㧘ᐔᚑ 15 ᐕᐲએ㒠ߩળ⾌ᧂ⚊ߩᣇߦߪ‫ޟ‬વᾲ‫ ޟޠ‬Thermal Scienceand Engineering ‫ߩޠ‬ㅍઃࠍ஗ᱛߒߡ߅ࠅ㧘ㄭߊ㒰ฬಣಽ߇ℂ੐ળߢ᳿ቯߐࠇ߹ߔ㧚㧟㧚੐ോዪߦߟ޿ߡ
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ㇱળࡁ࡯࠻㧦ๆ⌕ߦ㑐ߔࠆ․㓸߳ߩ߅߽޿

Note from the Editorial Board: A Thought for Special Forum on Adsorption Phenomena
੹ภߩ․㓸ߪ㧘ๆ⌕ߩ਎⇇ʊࡒࠢࡠ߆ࠄࡑࠢࡠ
߹ߢ㧘ߘߒߡࠪࠬ࠹ࡓ߳㧙‫ޠ‬㧔Field of Adsorption From Micro to Macro, and Associated Systems㧕ߣ޿߁ߎߣߢ㧘ࡒࠢࡠߥⷞὐߢߩ᧚ᢱ㐿⊒ߣๆ⌕⃻⽎ߩࡕ࠺࡝ࡦࠣ㧘ࡑࠢࡠߥⷞὐߢߩᾲ‛⾰⒖േ⃻⽎ߩ⸃ᨆߣๆ⌕ེߩᦨㆡൻ㧘ߘߒߡ㧘ๆ⌕ࠪࠬ࠹ࡓߩ㜞ᐲൻ߹ߢ㧘ૐ᷷ឃᾲߢ㚟േน⢻ߥๆ⌕಄ಓࠪࠬ࠹ࡓ㧘࠺ࠪࠞࡦ࠻ⓨ⺞ࠪࠬ࠹ࡓߥߤࠍታ↪ൻߔ
ࠆ਄ߢ㊀ⷐߥ⎇ⓥ㐿⊒⺖㗴ࠍขࠅ਄ߍߡ㧘╙৻✢ߢߏᵴべਛߩవ↢ᣇߦએਅߩౝኈߢߏၫ╩㗂߈߹ߒߚ㧚(1)ਅጟ᳁ࠄߦࠃࠆๆ⌕ࡅ࡯࠻ࡐࡦࡊߩේℂߣๆ⌕೷ߦ᳞߼ࠄࠇࠆᕈ⾰㧘ߐࠄߦᣂⷙߦ㐿⊒ߐࠇߚๆ⌕೷ߩ‛ᕈߦ㑐ߔࠆ⸃⺑㧘(2)ᄢችมవ↢ߦࠃࠆࡒࠢࡠߥⷞὐߦࠃࠆๆ⌕‛ℂࡕ࠺࡞ߩ⸃⺑ߣಽሶࠪࡒࡘ࡟࡯࡚ࠪࡦߩᦨㄭߩേะߩ⸃⺑㧘(3)ഏ
వ↢ߦࠃࠆൻቇ⫾ᾲ᧚ߣߒߡߩ㊄ዻႮ♽᧚ᢱߩ㐿⊒⁁ᴫߩ⚫੺㧘(4)ᷰㄝవ↢ࠄߦࠃࠆๆ⌕ེౝߩᾲ‛⾰⒖േߩࡕ࠺࡝ࡦࠣߣๆ⌕ེߩᦨㆡ⸳⸘ᴺ߅ࠃ
߮ࠪࠬ࠹ࡓߩᕈ⢻⹏ଔ⚿ᨐߩ⚫੺㧘(5)ựᧄవ↢వࠄߦࠃࠆẜᾲ࡮㗼ᾲ⁛┙೙ᓮᣇᑼߦࠃࠆⓨ⺞ࠪࠬ࠹ࡓߩ⸃⺑㧘(6)ఽ₹వ↢ߦࠃࠆ㜞ᐲߥๆ⌕࠺ࠪࠞࡦ࠻ᑼⓨ⺞ࠪࠬ࠹ࡓߩ⸃⺑㧘(7)⑺Ỉవ↢ߦࠃࠆኒ㐽ᑼߩๆ⌕಄ಓࠪࠬ࠹ࡓߩ㜞ᕈ⢻ൻߦ㑐ߔࠆ⸃⺑㧚 ᧄ․㓸ࠍߏၫ╩㗂޿ߚవ↢ᣇ߽ㅀߴߡ߅ࠄࠇࠆ
ࠃ߁ߦߎࠇ߹ߢᑄ᫈ߐࠇߡ޿ߚᾲࠍߣߎߣࠎ૶޿
ಾࠆᛛⴚߪ੹ᓟ߹ߔ߹ߔ㊀ⷐߦߥࠆ߽ߩߣ⏕ାߒߡ޿߹ߔ㧚ᧄ․㓸߇㧘ᄙߊߩ⎇ⓥ⠪߅ࠃ߮ᛛⴚ⠪߇‫ޟ‬ๆ⌕ߩ਎⇇‫ࠍ⋡ߦޠ‬ะߌߡ㗂ߊ߈ߞ߆ߌߦߥ
ࠇ߫ᐘ޿ߢߔ㧚ൻቇ࡮᧚ᢱ♽⎇ⓥಽ㊁ࠍਛᔃߣߒߚ⎇ⓥᚲߩᯏ᪾♽ᢎຬߣߒߡ⎇ⓥᢎ⢒ᵴേࠍⴕߞߡ޿ࠆߖ޿߆㧘ߪߚ߹ߚߘߩࠃ߁ߥ⎇ⓥᚲߦ߅ߌࠆ⥄ࠄߩሽ࿷ᗧ
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߆㧘ᣣ㗃߆ࠄ‫᧚ޟ‬ᢱߣࠛࡀ࡞ࠡ࡯ࠪࠬ࠹ࡓ‫ߩߣޠ‬㑐ࠊࠅࠍᒝߊᗧ⼂ߒߡ߅ࠅ㧘ᤓ੹ߩⅣႺ࡮ࠛࡀ࡞
ࠡ࡯໧㗴ߩਛߢ㧘಄ಓⓨ⺞ಽ㊁ߦ㑐ߔࠆ⎇ⓥߦ៤
ࠊߞߡ޿ࠆ৻⎇ⓥ⠪ߣߒߡ㧘⫳᳇࿶❗ᑼ಄ಓⓨ⺞ࠪࠬ࠹ࡓߩᦝߥࠆน⢻ᕈࠍାߓߟߟ㧘৻ᣇߢࡉ࡟
࡯ࠢࠬ࡞࡯ࠍ↢߻น⢻ᕈߩ޽ࠆࠪࠬ࠹ࡓߣߒߡๆ
⌕⃻⽎ࠍᔕ↪ߒߚᾲ㚟േᑼ޽ࠆ޿ߪ࿶❗࡮ᾲ㚟േࡂࠗࡉ࡝࠶࠼ᑼ಄ಓⓨ⺞ࠪࠬ࠹ࡓߦᒝ޿⥝๧ߣ⎇ⓥߩᔅⷐᕈࠍ୘ੱ⊛ߦᒝߊᗵߓߡ޿߹ߒߚ㧚ߘߩࠃ߁ߥߎߣ߽޽ߞߡ㧘੹࿁㧘ൎᚻߥ߇ࠄ㧘಴ ㇱળߢ਄⸥ߩࠃ߁ߥ․㓸ߩડ↹ࠍ┙ߡߐߖߡ㗂߈߹ߒߚ㧚ᧄ․㓸ߦ߅޿ߡ㧘ߏᄙᔔߦ߽߆߆ࠊࠄߕ㧘ၫ╩⠪ߦߪ⾆㊀ߥ⸃⺑⺰ᢥࠍߏᛩⓂ㗂߈߹ߒߚ㧚ߎߎߦ㧘ෘߊᓮ␞↳ߒ਄ߍ߹ߔ㧚ߥ߅㧘ᧄ․㓸ߦᒰߚࠅ㧘ᒰㇱળᆔຬߩ᧲੩Ꮏᬺ
ᄢቇߩട⮮ਯ⾆వ↢ߩ⛘ᄢߥࠆᡰេࠍ㗂߈߹ߒߚ㧔ታ㓙ߦߪቢోߦ㗬ࠅಾߞߡ޿߹ߒߚ㧕ߎߣࠍ↳ߒᷝ߃߹ߔ㧚
ዊጊ❥㧔਻Ꮊᄢቇ㧕
Shigeru KOYAMA (Kyushu University)e-mail: koyama@cm.kyushu-u.ac.jp೽ળ㐳  ൎ↰ᱜᢥ㧔ᣧⒷ↰ᄢቇ㧕    ㇱળ㐳 ศ↰⧷↢㧔੩ㇺᄢቇ㧕ᆔ ຬ㧔ℂ ੐㧕᫪ ᴦ༹㧔᧲੩㔚ജ㧕     ㅩဈᤘᴦ㧔ᓼፉᄢቇ㧕     ዊጊ ❥㧔਻Ꮊᄢቇ㧕㧔⹏⼏ຬ㧕ਣ↰ ⮍㧔᧲ർᄢቇ㧕     ᧖ጊᥓਯ㧔ᣣᧄේሶജ⎇ⓥ㐿⊒ᯏ᭴㧕     ਛㄟ⑲᮸㧔ජ⪲ᄢቇ㧕     ട⮮ਯ⾆㧔᧲੩Ꮏᬺᄢቇ㧕   ᳗੗ੑ㇢㧔⑔੗ᄢቇ㧕     ↰ဈ⺈ဋ㧔૑෹㊄ዻᎿᬺ㧕   ᐔỈ⨃᮸㧔␹ᚭᄢቇ㧕
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વ ᾲ
ISSN 1344-8692
Journal of the Heat Transfer Society of Japan
Vol. 45, No. 190
2006 ᐕ 1 ᦬⊒ⴕ
THERMAL SCIENCE AND ENGINEERING(ᣣᧄવᾲቇળ⺰ᢥ㓸)Vol. 14, No. 1

ISSN 0918-9963
January, 2006⊒ⴕᚲ ␠࿅ᴺੱ ᣣ ᧄ વ ᾲ ቇ ળ‫ޥ‬113-0034 ᧲੩ㇺᢥ੩඙ḡፉ 2-16-16

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