Magna Spray FY-8100

Denshijiki Industry Co., Ltd.

SDS15110-02e

SAFETY DATA SHEET
1.

Product and Company Identification
Product Name:

Magna Spray FY-8100 (Spray-type fluorescent magnetic powder formagnetic-particle testing)Company Name:

Denshijiki Industry Co., Ltd.

Address:

5-6-20 Ukima, Kita-Ku, Tokyo

Section in Charge:

Development department

Telephone:+81-3-5970-8681

FAX:+81-3-5970-8680

Emergency Telephone: Same as the section in charge
Date of Creation:

December 3, 2019

Reference Number:

SDS15110-02e

Product Code:

15110

Date of Revision:

January 21, 2021

Recommended Uses and Restrictions on Use: Magnetic particle testing (Spray)

2.

Hazards Identification
GHS Classification
Physical Hazards

Aerosols

Category 1

Health Hazards

Acute toxicity (oral)

Classification not possible

Acute toxicity (dermal)

Classification not possible

Acute toxicity (inhalation: vapors/dust/mist)

Classification not possible

Skin corrosion/irritation

Classification not possible

Serious eye damage/eye irritation

Classification not possible

Respiratory Sensitization

Classification not possible

Skin sensitization

Classification not possible

Germ cell mutagenicity

Classification not possible

Carcinogenicity

Classification not possible

Reproductive toxicity

Classification not possible

Reproductive toxicity/effects on or via
lactation

Classification not possible

Specific target organ toxicity (singleexposure)

Category 3 (Anesthetic effect)

Specific target organ toxicity (repeatedexposure)Classification not possible

Aspiration hazard

Classification not possible

Hazardous to the aquatic environment(acute)Classification not possible

Hazardous to the aquatic environment(chronic)

Classification not possible

Hazardous to the ozone layer

Classification not possible

Environmental Hazards

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Denshijiki Industry Co., Ltd.

SDS15110-02e

GHS Label Elements

Pictograms:
Signal Word:

DangerHazard Statement:

Extremely flammable aerosol
Pressurized container: may burst if heated
May cause drowsiness or dizziness

Precautionary Statement:
Prevention

Keep away from ignition sources such as heat, sparks, open flames and hot objects. Nosmoking.
Do not spray on an open flame or other ignition source.
Do not pierce or burn, even after use.
Avoid breathing gas, mist, vapors, spray.
Use only outdoors or in a well-ventilated area.
Wear protective gloves/eye protection/face protection/protective clothing.

Response

IF SWALLOWED: Do not induce vomiting.
IF ON SKIN: Wash with plenty of water and soap.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
Call a POISON CENTER/doctor, if you feel unwell.

Storage

Store in a well-ventilated place Keep container tightly closed.
Store locked up.
Protect from sunlight. Do not expose to temperatures exceeding 40ºC/104ºF.

Disposal

Dispose of contents/container at an approved waste disposal plant in accordance withlocal/regional/national regulations.

Other hazards not categorized by GHS classification
Contact with liquefied gas may cause frostbite

3.

Composition/Information on Ingredients
Substance/Mixture: Mixture
Chemical Name or Common Name

Content (%)

CAS No.

Isoparaffin(Aliphatic hydrocarbon)

65–75

68551-20-2

Iron oxide
Iron
Organic fluorescent pigment
Melamine resin< 0.51317-61-9
7439-89-6
Registered9003-08-1

Sorbitan Monooleate< 0.51338-43-8

Propane10–30

74-98-6n-butane, i-butane

5–15

106-97-8,75-28-5

LPG (Liquefied Petroleum Gas)

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Magna Spray FY-8100

4.

5.

6.

Denshijiki Industry Co., Ltd.

SDS15110-02e

First Aid Measures
IF INHALED::

Remove person to fresh air and keep comfortable for breathing.
Call a POISON CENTER/doctor, if you feel unwell.

IF ON SKIN::

Take off contaminated clothing immediately and wash skin with plenty of waterand soap. Take off contaminated clothing and wash it before reuse. If skinirritation occurs, get medical advice/attention.

IF IN EYES::

Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Rinse for at least 15 minutes, and thenget medical attention.

IF SWALLOWED::

Call a POISON CENTER/doctor, if you feel unwell.
If the product remains in the mouth, rinse thoroughly.
Do NOT induce vomiting.

Extinguishing Media:

Small fire: Carbon dioxide, powder extinguisher, water sprinkling and foam
extinguisher.
Large fire: Water sprinkling, sprayed water and foam extinguisher

Inappropriate ExtinguishingMedia:

Straight stream of waterSpecific Hazards:

May explode if aerosol container is at the scene of a fire.
Extremely flammable and easily ignited by heat, spark and flame.
May cause vapor-explosion indoors, outdoors or in a sewage trench.
May generate irritant, poisonous, or corrosive gas in a fire.

Special FirefightingProcedures:

Extremely low flash point: Use water if other extinguishing media are noteffective
Remove containers from the fire area, if it can be done safely.
If not, spray containers and the surrounding area with water to keep them cool.
Conduct firefighting activities from the most distant place that allows it to bedone effectively using an unmanned hose holder or a nozzle with a monitor.
Keep cooling containers with plenty of water even after the fire is extinguished.

Protection of Firefighters:

Wear appropriate protective equipment to avoid inhalation of toxic gases.
Fight a fire from upwind.

Personal Precautions,Protective Equipment andEmergency Procedures:

Operators must wear proper protective gear (refer to 8. Exposure
Controls/Personal Protection) and avoid contact with the eyes and skin, and gas
inhalation.
When leaking (spraying), handle from upwind. Keep the leaking spot facing up.
Let the gas spray out completely and then perform the subsequent procedures.
Quickly remove nearby ignition sources, high-temperature objects andflammables. Evacuate anyone who is downwind and keep everyone out except
authorized persons
Ventilate before entering the restricted area.

Environmental Precautions:

Avoid draining to drainage trench, sewage trench, basement or a closed space.
Be careful not to discharge into rivers or anywhere else that would affect theenvironment.

Firefighting Measures

Accidental Release Measures

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Magna Spray FY-8100
Method and Materials forContainment and Cleaning
UpSDS15110-02e:

Use tools whose materials do not generate sparks upon impact or due to staticelectricity.
For small leaks, collect the material by absorbing the released material with soil,sand, or non-combustible material.
For large leaks, put sand around the leakage to keep it from flowing out.
Process contaminated items and waste according to relevant regulations.

:

Inform relevant organizations immediately to prevent further accidents andexpansion.
Remove nearby potential ignition sources immediately and prepare fire
extinguishing media.
Do not walk on the released material unnecessarily.

Technical Measures:Amounts larger than the designated amount must be handled in a factory, astorage facility, or a laboratory in compliance with the standards required by therelevant regulations.
Connect the equipment to ground and use explosion-proof electric appliances as
an anti-static measure.
Do not use high-temperature objects, sparks and fire nearby. - No smoking.
Take engineering measures and use protective equipment as described inSection 8. Exposure Controls/Personal Protection.
Provide local and general ventilation as described in Section 8. Exposure
Controls/Personal Protection.

Precautions for Safe
Handling:

Do not use things that generate fire, sparks and arcs or high-temperature objects.
Do not spray at an open flame or high-temperature incandescent objects.
Use this substance with one's back facing upwind to prevent it from being
blown back on the user.
The container may rupture if stored in a high-temperature place.
Avoid contact, inhalation, or ingestion. Do not get in eyes. Wash hands
thoroughly after handling.
Avoid contact with combustibles and oxidizing agents.

Proper Storage Conditions:

Store in a cool, well-ventilated place, away from direct sunlight. Keep
containers sealed.
May leak or spray out if containers get rusty. Avoid storing it in a humid spot.
Store away from fire and heat sources.
Do not store where the temperature exceeds 40°C.
Use explosion-proof grounded electric appliances if using them in the storage
area.
Store away from combustibles and oxidizing agents.
Store locked up.

Safe Packaging Materials:

Use containers regulated by the High Pressure Gas Safety Act and otherregulations.

Measures to Prevent
Secondary Accidents

7.

Denshijiki Industry Co., Ltd.

Handling and StorageHandling

Storage

8.

Exposure Controls/Personal Protection
Control Levels:

Total dust 3.0 mg/m3

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Magna Spray FY-8100

Denshijiki Industry Co., Ltd.

SDS15110-02e

Permissible Exposure Levels
Japan Society for
Occupational Health(2018version):

Iron oxide...inhalant dust 1 mg/m3, Total dust 4 mg/m3
Butane...500 ppm, 1,200 mg/m3

ACGIH(2008 Version):

TLV-TWA
Iron oxide...5 mg, Fe/m3, propane...1,000 ppm, butane...1,000 ppm

Engineering Measures:

In an indoor, inadequately ventilated workplace, provide local or general
ventilation equipment. Install a face-washer and safety shower.
Do not put high-temperature and ignition sources near where this material ishandled.

Protective Equipment

9.

Wear the following protective equipment as needed:

Respiratory System
Protection:

Organic gas masks, air-supplied respirators, breathing equipment, etc.

Hand Protection:

Protective gloves (solvent resistant, impermeable)

Eye Protection:

Eye protection, face protection.

Skin and Body
Protection:

Oil-resistant (impermeable, anti-static) apron(anti-static) protective wear, electrically conductive boots, etc.

Physical and Chemical Properties
Contained liquidSpraying agent (LPG)

LiquidUnder atmospheric pressure: gas, inpressurized container: liquid

Color

Colorless and transparent

Colorless and transparent

Odor

Almost none

odorless-60°C or less (pour point)-187.7–-138.4°C

Boiling point or
initial boiling point
and boiling range

210–250°C-42.1–-0.5°C

Flammability

Flammable

Flammable

Lower and upper
explosion limit /flammability limit

0.6–6.5%

1.8–9.5vol%

Flash point

90°C or higher (open cup)-104.4–-73.8°C

Auto-ignition
temperatureapprox. 350°C

405–550°C

Decomposition
temperatureNo data available

No data available

pHNo data available

No data available

Kinematic viscosity

No data available

No data available

Water insoluble, poorly soluble in alcohol
Readily soluble in toluene and hexane

Slightly soluble in water

Partition coefficientn-octanol/water (logvalue)

No data available

No data available

Vapor pressure

No data available

0.278–1.275 MPa (40°C)

Density and/or

0.79 (15/4°C)

0.539 (20°C)

Physical state

Melting point/
freezing pointSolubility

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Denshijiki Industry Co., Ltd.

SDS15110-02e

relative density
Relative vapordensity

No data available

1.895–2.538 kg/m3 (1 MPa 15.6°C)

Particlecharacteristics

10µm（5-16µm）

No data available

10. Stability and Reactivity
Chemical Reactivity andStability:

May rupture at 40°C or higher
Internal pressure at ambient temperature: approx. 0.35 MPa
May catch fire and explode by electrostatic discharge

Possibility of Hazardous
Reactions:

May rupture by heat and impact.
A flammable liquefied gas and readily forms an explosive gas when mixed withair.

Conditions to Avoid:Storage in hot, humid spots and usage near fire.

Incompatible Materials:

No data available

Hazardous Decomposition
Products:

No data available

Acute Toxicity (oral):

LD50 ≥ 20 g/kg (mouse): isoparaffin

Acute toxicity (dermal):

No data available

Acute Toxicity (inhalation):gas...
LC50 > 55,000 ppm/2 h (guinea pig): propane
LC50 > 38,890 ppm/4 h (guinea pig): propane
LC50 > 277,374 ppm/4 h (rat): n-butane

Skin Corrosion and Skin
Irritation:

No data available

Serious Eye Damage or Eye
Irritation:

No data available

Respiratory Sensitization orSkin Sensitization:

Respiratory sensitization: No data available
Skin sensitization: No data available

Germ Cell Mutagenicity:

No data available

Carcinogenicity:

No data available

Reproductive Toxicity:

No data available

Specific Target Organ
Toxicity, Single Exposure:

Description in ACGIH: propane "Anesthetic to humans"
Description in ACGIH and Japan Society for Occupational Healthrecommendation: n-butane "Anesthetic or central nervous system depressant inhumans by high-concentration inhalation"

Specific Target Organ
Toxicity, Repeated Exposure:

No data available

Aspiration Hazard:

No data available:

No data available

11. Toxicological Information

12. Ecological Information
Ecotoxicity

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Denshijiki Industry Co., Ltd.

Persistency/Degradability:

No data available

Bioaccumulative Potential:

No data available

Mobility in Soil:

No data available

Hazardous to the OzoneLayer:

No data available

SDS15110-02e

13. Disposal Considerations
Dispose of after complete degassing.
Have contents/container disposed of by an industrial waste disposal contractor licensed by the prefectural governor.
Dispose of or have waste generated from effluent treatment or incineration disposed of by a waste disposal contractor
in accordance with the Waste Management and Public Cleansing Act and other related laws.

14. Transport information
UN Hazard Class:2.1UN No.

:

1950

Follow other related laws and regulations.

15. Regulatory Information
Comply with the applicable laws and regulations regarding this product in each country/region.

16. Other Information
This Safety Data Sheet was prepared in accordance with JIS Z 7253:2019 to provide users of this product withreference information to ensure safe handling. Users are responsible for taking appropriate measures for individual
handling conditions with reference to this SDS.
This SDS does not represent any guarantee of safety.
Major references
Safety Data Sheets (SDS) provided by raw material manufacturers
Japanese Industrial Standards JIS Z 7253:2019 “Hazard communication of chemicals based on GHS”
NITE Chemical Risk Information Platform (CHRIP)

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