MATERIAL SAFETY DATA SHEETRINSYUNDOU Co.,Ltd.
RSD Building 2F
2-32 Nagarahigashi, Gifu
Gifu, Japan 502-0082
Phone Number: 0081+58295-5755
Fax Number: 0081+58294-0020

Prepared by : Sadako Hayashi
Chief Executive Officer

Use the CHEMTREC telephone number only in the event of chemical emergencies.

1.

IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING

Product Name:
CAS-No.:Recommended use:
Product Code:
Product trade Name:

Metal Marker LMM-6000 Aerosol Spray Can
MixtureIndustrial Use OnlyMetal Marker
RSD Metal Marker

Date of Preparation: 04/26/2017

2. HAZARDS IDENTIFICATION
Emergency Overview
Warning
Highly flammable liquid and vapor. Vapors may travel to a source and flash back. Vapors may cause flash fire or explosion. Avoid
contact with the skin and the eyes. Irritating to eyes. May be harmful if swallowed. May be harmful by inhalation.

Color: Gray
Physical Liquidstate:
Characteristic
Odor:

Health:Flammability:
Physical Hazard:
PPE:

HMIS
3*41
B

NFPA 704
341

Potential Health Effects
Principle routes of exposure:

Inhalation, ingestion, skin and eye contact.

Eye contact:

May cause severe eye irritation.

Skin contact:

Extremely irritating to the skin. Prolonged skin contact may defat the skin and produce
dermatitis.

Inhalation:

May be harmful by inhalation. Vapors extremely irritating to eyes and respiratory tract.

Ingestion:

May be harmful if swallowed.

Chronic toxicity:

Excessive inhalation of fumes or dust may cause chemical pneumonitis, cyanosis, andpulmonary edema. Chronic exposure to ethanol can cause developmental damage. Long-term
exposure can also cause loss of appetite, weight loss, nervousness, memory loss, mental
retardation and liver damage. Combined exposure to ethanol and certain other chemicals may
result in increased toxic effects.

3. COMPOSITION/INFORMATION ON INGREDIENTS
Components
Ethanol

CAS Number
64-17-5

Weight %30 - 40%____________________________________________________________________________________________
Product name: Metal Marker LMM-6000 Aerosol Spray Can

Page 1 of 73. COMPOSITION/INFORMATION ON INGREDIENTSPetroleum gases, liquefied, sweetened
Molybdenum Compounds
Vandadium Compounds
Silicate mineral
Methanol
Proprietary Additive
Methyl isobutyl ketone

68476-86-8

67-56-1
1 0 8 - 1 0 -1

20 - 30%
20 - 30%
10 - 20%
5 - 10%
1 - 5%
1 - 5%
0. 1 - 0 . 5 %The specific chemical identities are being withheld as a trade secret (29CFR1910.1200).

4. FIRST AID MEASURES
Eye contact:

Rinse immediately with plenty of water, also under the eyelids. Get medical attention if irritation
develops.

Skin contact:

Wash off immediately with soap and plenty of water. Remove and wash contaminated clothing
before re-use. If symptoms persist, call a physician.

Inhalation:

Move to fresh air. If breathing is difficult, give oxygen. If symptoms persist, call a physician.

Ingestion:

Drink plenty of water. Do not induce vomiting. Consult a physician if necessary.

Notes to physician:Treat symptomatically.

5. FIRE-FIGHTING MEASURES
Flash point (°C): 13( 55°F) Method: PMCC
Suitable extinguishing media:

Use dry chemical, CO2, water spray or foam.

Hazardous decomposition products Carbon oxides. Molybdenum compounds.
under fire conditions:
Special protective equipment forfirefighters:

As in any fire, wear self-contained breathing apparatus (pressure-demand, NIOSH approved orequivalent) and full protective gear

Unusual hazards:

Flammable solid. Vapors may form explosive mixture with air. Vapors are heavier than air andmay spread along floors. Vapor may travel considerable distance to source of ignition and flashback.

6. ACCIDENTAL RELEASE MEASURES
Personal precautions:

Flammable liquid. Remove all sources of ignition. Remove all non-essential people from theaffected area. Ensure adequate ventilation. In case of insufficient ventilation, wear suitable
respiratory equipment. Avoid contact with skin, eyes and clothing. Wear personal protectiveequipment.

Environmental precautions:

Prevent further leakage or spillage if safe to do so. Prevent product from entering drains. Do
not flush into surface water or sanitary sewer system. Do not allow material to contaminate
ground water system.

Methods for cleaning up:

Wear personal protective equipment. Absorb spill with inert material (e.g. dry sand or earth),then place in a chemical waste container. Clean contaminated surface thoroughly. Dispose ofpromptly.

7. HANDLING AND STORAGE____________________________________________________________________________________________
Product name: Metal Marker LMM-6000 Aerosol Spray Can

Page 2 of 7

7. HANDLING AND STORAGE
Handling:
Keep away from open flames, hot surfaces and sources of ignition. Handle in accordance with good industrial hygiene and safety
practice. Use only in area provided with appropriate exhaust ventilation. In case of insufficient ventilation, wear suitable respiratory
equipment. Avoid contact with skin, eyes and clothing. Wear personal protective equipment. Do not eat, drink, or smoke in areas of useor storage. Do not take internally. Wash thoroughly after handling.
Storage:
Keep containers dry and tightly closed to avoid moisture absorption and contamination. Keep product and empty container away fromheat and sources of ignition.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure limits
Minimize exposure in accordance with good hygiene practice.
Components
Ethanol
Silicate mineral
Methanol

OSHA PEL
1000 ppm TWA
1900 mg/m3 TWA
20 mppcf TWA
200 ppm TWA
260 mg/m3 TWA

Methyl isobutyl ketone

ACGIH1000 ppm STEL
3 mg/m3 TWA respirable fraction
Skin
250 ppm STEL
200 ppm TWA
75 ppm STEL
20 ppm TWA

100 ppm TWA
410 mg/m3 TWA

Engineering measures:

Provide appropriate exhaust ventilation wherever dust, mist, vapors, or fumes can begenerated. Ensure that eyewash stations and safety showers are proximal to the work-station
location.

Eye protection:

Safety glasses with side-shields.

Skin and body protection:

Lightweight protective clothing. Keep working clothes separately. Remove and wash
contaminated clothing before re-use.

Hand protection:

Impervious gloves. Follow the recommendations given by the manufacturer of protective
gloves.

Respiratory protection:

In case of insufficient ventilation, wear suitable respiratory equipment. NIOSH-approved
respirators should be worn where engineering controls and work practices do not reduce
exposure to or below the PEL. Seek professional advice prior to respirator selection and use.

Hygiene measures:

Wash hands before breaks and at the end of workday

9. PHYSICAL AND CHEMICAL PROPERTIES
Color:Odor:
Boiling point/range (°C):
Melting point/range (°C):
Vapor pressure :VOC content

Gray
Characteristic
77.8
No data available
No data available
51.1%

Physical state:
Molecular weight:
pH:
Specific gravity (Water =1):
Water solubility:

LiquidNo data available
3.0
1.4
Partly soluble

10. STABILITY AND REACTIVITY
Stability:

Stable at normal conditions.

Polymerization

None under normal processing.

Hazardous decomposition products: Thermal decomposition can lead to release of irritating gases and vapors. Carbon oxides.
Molybdenum compounds.
Materials to avoid:

Strong oxidizing agents. Strong reducing agents.

____________________________________________________________________________________________
Product name: Metal Marker LMM-6000 Aerosol Spray Can

Page 3 of 7

Conditions to avoid

Heat, flames and sparks. Avoid elevated temperatures.

11. TOXICOLOGICAL INFORMATION
Acute toxicity:

Information given is based on data on the components and the toxicology of similar products

Carcinogenic Effects:

The International Agency for Research on Cancer (IARC) has determined alcoholic beverages
are carcinogenic to humans (Group 1) and the occurrence of malignant tumors of the oralcavity, pharynx, larynx, esophagus and liver is causally related to the consumption of alcoholic
beverages in humans. Animal studies on ethanol do not provide sufficient indication ofcarcinogenicity.

C o m p o n en t s
Ethanol
Silicate mineral
Methanol
Methyl isobutyl ketone

NIOSH - Pocket Guide - Target Organs
eyes respiratory system CNS liver skin blood reproductive system
respiratory systemeyes CNS skin GI tract respiratory systemeyes CNS respiratory system liver skin kidneys

Component information, if any, is listed below
Ethanol
LD50s and LC50s:
OSHA - Select Carcinogens:
NTP:
IARC - Group 1:
Molybdenum Compounds
LD50s and LC50s:
Vandadium Compounds
LD50s and LC50s:
MethanolLD50s and LC50s:

Proprietary Additive
LD50s and LC50s:
Methyl isobutyl ketone
LD50s and LC50s:
OSHA - Select Carcinogens:
IARC - Group 2B:

Inhalation LC50 (Rat) = 124.7 mg/L
Oral LD50 (Rat) = 7060 mg/kg
PresentKnown Human Carcinogen
ListedOral LD50 (Rat) = 2689 mg/kg
Dermal LD50 (Rat) = 2 g/kg
Inhalation LC50 (Rat) = 5840 mg/m3
Oral LD50 (Rat) = 98 mg/kg
Dermal LD50 (Rabbit) = 15800 mg/kg
Oral LD50 (Rat) = 5628 mg/kg
Inhalation LC50 (Rat) = 64000 ppm
Inhalation LC50 (Rat) = 83.2 mg/L
Oral LD50 (Rat) = 10200 mg/kg
Oral LD50 (Rat) = 2080 mg/kg
Inhalation LC50 (Rat) = 8.2 mg/L
Dermal LD50 (Rabbit) = 16000 mg/kg
PresentListed____________________________________________________________________________________________
Product name: Metal Marker LMM-6000 Aerosol Spray Can

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12. ECOLOGICAL INFORMATION
Aquatic toxicity:

No data is available on the product itself. Information given is based on data on thecomponents and the ecotoxicology of similar products.

Ethanol
Ecotoxicity - Fish Species Data:
96 h LC50 (Oncorhynchus mykiss) = 12.0 - 16.0 mL/L static
96 h LC50 (Pimephales promelas) = 13400 - 15100 mg/L flow-through96 h LC50 (Pimephales promelas) = 100 mg/L static
Ecotoxicity - Water Flea Data:
48 h LC50 (Daphnia magna) = 9268 - 14221 mg/L
24 h EC50 (Daphnia magna) = 10800 mg/L
48 h EC50 (Daphnia magna) = 2 mg/L Static
Methanol
Ecotoxicity - Fish Species Data:
96 h LC50 (Lepomis macrochirus) = 13500 - 17600 mg/L flow-through96 h LC50 (Oncorhynchus mykiss) = 18 - 20 mL/L static
96 h LC50 (Oncorhynchus mykiss) = 19500 - 20700 mg/L flow-through96 h LC50 (Pimephales promelas) = 28200 mg/L flow-through96 h LC50 (Pimephales promelas) = 100 mg/L static
Methyl isobutyl ketone
Ecotoxicity - Fish Species Data:
96 h LC50 (Pimephales promelas) = 496 - 514 mg/L flow-throughEcotoxicity - Water Flea Data:
48 h EC50 (Daphnia magna) = 170 mg/L
Ecotoxicity - Freshwater Algae Data:
96 h EC50 (Pseudokirchneriella subcapitata) = 400 mg/L
Not determined
Persistence and degradability:

13. DISPOSAL CONSIDERATIONS
Waste from residues / unusedproducts:

Waste must be disposed of in accordance with federal, state and local environmental control
regulations. Where possible recycling is preferred to disposal or incineration.

14. TRANSPORT INFORMATION
DOT (U.S.)
UN/ID No:
Proper shipping name:
Hazard Class:
ERG No:

UN1950Aerosols
2.1
126

TDG (Canada)
UN-No
Proper Shipping Name
Hazard Class

UN2150Aerosols
2.1

IMDG
UN-No
Proper Shipping Name
Hazard Class
Ems:

UN2150Aerosols, flammable
2.1
F-D, S-U____________________________________________________________________________________________
Product name: Metal Marker LMM-6000 Aerosol Spray Can

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Description

UN1950, Aerosols, flammable,2.1

IATA
UN-No
Proper shipping name
Hazard ClassERG CodeShipping Description

UN1950Aerosols, flammable
2.1
10P
UN1950,Aerosols, flammable,2.1

15. REGULATORY INFORMATION
U.S. Regulations:
Not subject to TSCA 12(b) Export Notification

TSCA:

SARA 313:
Components
Methanol (1 - 5%)
Molybdenum Compounds (20 - 30%)

U.S. - CERCLA/SARA - Section 313 - Emission Reporting
1.0 % de minimis concentration
1.0 % de minimis concentration

State Regulations
This product or its ingredients have been evaluated for New Jersey, Pennsylvania, and California Prop 65 supplier notification
requirements. Substances that are subject to notification requirements, if any, are listed below.
Components
Metha n ol
Molybdenum Compounds

PARTK:
L is ted (PAR TK )Listed (PARTK)

Components
Methyl isobutyl ketone
Ethyl Acetate
E th a n o l
Me t h a n o l

NJRTK:
12 6 80841
08 441222

Components
Methyl isobutyl ketone
EthanolState Regulation - CA Prop65
Ca r c i n o g en
Carcin ogen
Developmental Toxicity
D e ve l o p m en t a l T o x ic it y

Me th a n ol

Canadian WHMIS
WHMIS hazard class:

B2 Flammable liquid D1B Toxic materials D2A Very toxic materials

Canadian Ingredient Disclosure List (IDL):
Components
Silicate mineral
Et hanol
Me t h a n o l
Va ndadi um C om pounds
Molybdenum Compounds

Canada - WHMIS Ingredient Disclosure:
10.1
11
1

International Inventories
U.S. EPA TSCA 8(b):Canada DSL/NDSL list
Europe (EINECS):
Philippines (PICCS):
Japan (ENCS):

Listed or exempt.
All ingredient(s) are listed on the DSL or NDSLListed or exempt.
Listed.
One or more ingredient(s) are not on the ENCS list.

____________________________________________________________________________________________
Product name: Metal Marker LMM-6000 Aerosol Spray Can

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Korea (KECL):
China (IECS):
Australia (AICS):New Zealand (NZloC):

Listed.
Listed.
Listed.
Listed.

16. OTHER INFORMATIONFor Industrial Use Only
Prepared by: Ferro Technical Center
Disclaimer: The information and recommendations contained in this Material Safety Data Sheet have been compiled from sources
believed to be reliable and to represent the most reasonable current opinion on the subject when the MSDS was prepared. Nowarranty, guaranty or representation is made as to the correctness or sufficiency of the information. The user of this product must
decide what safety measures are necessary to safely use this product, either alone or in combination with other products, anddetermine its environmental regulatory compliance obligations under any applicable federal or state laws.

End of Safety Data Sheet____________________________________________________________________________________________
Product name: Metal Marker LMM-6000 Aerosol Spray Can

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