SAFETY DATA SHEET
According to OSHA Hazard Communication Standard 29CFR 1910.1200(HCS 2012)
GSLA_LMC-6044P Black Aerosol Can

LA LMC-6044P Spray
Product specification
VersionMaterial number

11800
2.5
1379493

Revision Date
Print Date
Page

08/17/2017
02/08/2018
Page 1 of 13

SECTION 1. IDENTIFICATION
Product name:

LA LMC-6044P Spray
GSLA_LMC-6044P Black Aerosol Can

Manufacturer or supplier's details
Company name of supplier: RINSYUNDOU Co.,Ltd.
Address:

RSD Building 2F
2-32 Nagarahigashi, Gifu
Gifu, Japan 502-0082

Telephone:

0081+58295-5755

Fax Number:

0081+58294-0020

Recommended use of the chemical and restrictions on use
Recommended use: Consult the technical guidelines for the use of thissubstance/mixture.

SECTION 2. HAZARDS IDENTIFICATIONGHS Classification
Flammable aerosols: Category 1

GHS Label element
Hazard pictograms:

Signal word:

DangerHazard statements

:

H222

Precautionary statements:

Prevention:
P210
P211
P251
Storage:

Extremely flammable aerosol.
Keep away from heat/sparks/open
flames/hot surfaces. - No smoking.
Do not spray on an open flame orother ignition source.
Pressurized container: Do not pierce
or burn, even after use.

SAFETY DATA SHEET
According to OSHA Hazard Communication Standard 29CFR 1910.1200(HCS 2012)
GSLA_LMC-6044P Black Aerosol Can

LA LMC-6044P Spray
Product specification
VersionMaterial number

11800
2.5
1379493

Revision Date
Print Date
Page

P410 + P412

08/17/2017
02/08/2018
Page 2 of 13

Protect from sunlight. Do not expose
to temperatures exceeding 50 °C/
122 °F.

Other hazards
None known.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance / Mixture: Mixture

Chemical nature: organic solvent, glass/frit, inorganic pigment, extremely
flammable liquefied gas, glycol ether/-acetate, hydrocarbon,
aliphatic

Hazardous components
Chemical Nameethanolbutaneisobutane
2-methoxy-1-methylethyl acetate
propane

CAS-No.
64-17-5
106-97-8
75-28-5
108-65-6
74-98-6

Concentration (%)>= 20 - < 30>= 10 - < 20>= 5 - < 10>= 5 - < 10>= 5 - < 10

SECTION 4. FIRST AID MEASURES
General advice: Consult a physician.

If inhaled: Remove to fresh air.
If unconscious place in recovery position and seek medical
advice.
Never give anything by mouth to an unconscious person.

In case of skin contact: Wash off immediately with soap and plenty of water.
If a person feels unwell or symptoms of skin irritation appear,
consult a physician.

In case of eye contact: Rinse immediately with plenty of water and seek medical
advice.

If swallowed: Do NOT induce vomiting.
Rinse immediately with plenty of water and seek medical
advice.

Most important symptoms
and effects, both acute anddelayed: None known.

SAFETY DATA SHEET
According to OSHA Hazard Communication Standard 29CFR 1910.1200(HCS 2012)
GSLA_LMC-6044P Black Aerosol Can

LA LMC-6044P Spray
Product specification
VersionMaterial number

11800
2.5
1379493

Revision Date
Print Date
Page

08/17/2017
02/08/2018
Page 3 of 13

SECTION 5. FIREFIGHTING MEASURES
Specific hazards during
firefighting: Exposure to decomposition products may be a hazard to
health.
Do not allow run-off from fire fighting to enter drains or water
courses.

Further information: Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations.

Special protective equipment
for firefighters: In the event of fire, wear self-contained breathing apparatus.

SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions,protective equipment andemergency procedures: Ensure adequate ventilation.
Follow safe handling advice and personal protective
equipment recommendations.

Environmental precautions: Do not flush into surface water or sanitary sewer system.
Prevent product from entering drains.

Methods and materials forcontainment and cleaning up: Sweep up and shovel into suitable containers for disposal.
Clean contaminated floors and objects thoroughly whileobserving environmental regulations.

SECTION 7. HANDLING AND STORAGE
Advice on protection against
fire and explosion: Keep away from heat and sources of ignition.

Advice on safe handling: Do not get in eyes or mouth or on skin.
For personal protection see section 8.
Smoking, eating and drinking should be prohibited in theapplication area.
Do not use in areas without adequate ventilation.
Keep away from heat and sources of ignition.

Conditions for safe storage: Keep in a dry, cool and well-ventilated place.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters

SAFETY DATA SHEET
According to OSHA Hazard Communication Standard 29CFR 1910.1200(HCS 2012)
GSLA_LMC-6044P Black Aerosol Can

LA LMC-6044P Spray
Product specification
VersionMaterial number

11800
2.5
1379493

Revision Date
Print Date
Page

Components

CAS-No.

Value type
(Form ofexposure)

ethanol

64-17-5

TWA
TWA
TWA
TWA

butane106-97-8

STEL
TWA
TWA

isobutane75-28-5STEL
TWA

2-methoxy-1-methylethyl
acetatepropane108-65-6

STEL
TWA

74-98-6

TWA
TWA
TWA

Engineering measures

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Page 4 of 13

Controlparameters /Permissible
concentration
1,000 ppm
1,000 ppm
1,900 mg/m3
1,000 ppm
1,900 mg/m3
1,000 ppm
1,900 mg/m3
1,000 ppm
800 ppm
1,900 mg/m3
800 ppm
1,900 mg/m3
1,000 ppm
800 ppm
1,900 mg/m3
1,000 ppm
50 ppmBasis

1,000 ppm
1,800 mg/m3
1,000 ppm
1,800 mg/m3
1,000 ppm
1,800 mg/m3

NIOSH RELACGIHNIOSH REL
OSHA Z-1
OSHA P0ACGIHNIOSH REL
OSHA P0ACGIHNIOSH REL
ACGIH
US WEEL

OSHA Z-1
OSHA P0: Apply technical measures to comply with the occupational
exposure limits.
Provide adequate ventilation.

Personal protective equipment
Respiratory protection: When workers are facing concentrations above the exposure
limit they must use appropriate certified respirators.
Hand protection
Material: Protective gloves

Eye protection: Safety glasses with side-shields
Ensure that eyewash stations and safety showers are close
to the workstation location.

Protective measures: Wear suitable protective equipment.
Avoid contact with skin.
When using do not eat, drink or smoke.

Hygiene measures: Remove contaminated clothing and protective equipment
before entering eating areas.
Wash hands before breaks and immediately after handlingSAFETY DATA SHEET
According to OSHA Hazard Communication Standard 29CFR 1910.1200(HCS 2012)
GSLA_LMC-6044P Black Aerosol Can

LA LMC-6044P Spray
Product specification
VersionMaterial number

11800
2.5
1379493

Revision Date
Print DatePage

the product.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: aerosol

Colour: black

Odour: characteristic

Odour Threshold: No data available

pH: No data available

Melting point/range: No data available

Boiling point/boiling range: No data available

Flash point: 14 °C

Evaporation rate

: No data available

Flammability (solid, gas)

: No data available

Burning rate

: No data available

Upper explosion limit: 19 %(V)

Lower explosion limit: 1.3 %(V)

Vapour pressure: No data available

Relative vapour density: No data available

Relative density: No data available

Density: No data available

Bulk density: No data available

Solubility(ies)
Water solubility: soluble

Solubility in other solvents: No data available

Partition coefficient: noctanol/water: No data available

Auto-ignition temperature: Not determined

Decomposition temperature: No data available

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Page 5 of 13

SAFETY DATA SHEET
According to OSHA Hazard Communication Standard 29CFR 1910.1200(HCS 2012)
GSLA_LMC-6044P Black Aerosol Can

LA LMC-6044P Spray
Product specification
VersionMaterial number

11800
2.5
1379493

Revision Date
Print Date
Page

Viscosity
Viscosity, dynamic: No data available

Viscosity, kinematic: No data available

08/17/2017
02/08/2018
Page 6 of 13

Explosive properties: No data available

Oxidizing properties: No data available

Refractive index: No data available

Volatile organic compounds(VOC) content: The following chemical(s) are listed under the U.S. Clean Air
Act Section 111 SOCMI Intermediate or Final VOC's (40 CFR
60.489):This product does not contain any VOC exemptions listed
under the U.S. Clean Air Act Section 450.

SECTION 10. STABILITY AND REACTIVITY
Reactivity: Stable under recommended storage conditions.

Chemical stability: No decomposition if stored and applied as directed.

Conditions to avoid: Extremes of temperature and direct sunlight.

Hazardous decomposition
products: Stable under normal conditions.

SECTION 11. TOXICOLOGICAL INFORMATION
Acute toxicity
Not classified based on available information.
Product:
Acute dermal toxicity: Acute toxicity estimate: > 5,000 mg/kg
Method: Calculation method

Components:
ethanol:
Acute oral toxicity: LD50 Oral (Rat): 10,470 mg/kg

Acute dermal toxicity: LD50 (Rabbit): 15,800 mg/kg

butane:Acute inhalation toxicity: LC50 (Rat, male and female): 658 g/m3
Exposure time: 4 h
Test atmosphere: gas

2-methoxy-1-methylethyl acetate:

SAFETY DATA SHEET
According to OSHA Hazard Communication Standard 29CFR 1910.1200(HCS 2012)
GSLA_LMC-6044P Black Aerosol Can

LA LMC-6044P Spray
Product specification
VersionMaterial number

11800
2.5
1379493

Acute oral toxicity

Revision Date
Print Date
Page

08/17/2017
02/08/2018
Page 7 of 13: LD50 Oral (Rat, female): 8,532 mg/kg
LD50 (Rat, male): >= 10,000 mg/kg

Acute inhalation toxicity:

Acute dermal toxicity: LD50 Dermal (Rat, male and female): >= 2,000 mg/kg
Method: OECD Test Guideline 402
GLP: yes
Remarks: No adverse effect has been observed in acutetoxicity tests.

propane:Acute inhalation toxicity(Rat, females): 16.48 mg/l
Exposure time: 8 h
Test atmosphere: vapour
Assessment: The substance or mixture has no acuteinhalation toxicity: LC50 (Rat): 658 mg/l
Exposure time: 4 h
Test atmosphere: gas

Skin corrosion/irritation
Not classified based on available information.
Components:
ethanol: Species:
Rabbit Exposure
time: 24 h
Method: OECD Test Guideline 404
Result: No skin irritation
Serious eye damage/eye irritation
Not classified based on available information.
Components:
ethanol:
Species: Rabbit
Result: Moderate eye irritation
Method: OECD Test Guideline 405
Respiratory or skin sensitisation
Skin sensitisation: Not classified based on available information.
Respiratory sensitisation: Not classified based on available information.
Germ cell mutagenicity
Not classified based on available information.
Carcinogenicity
Not classified based on available information.
IARC
No component of this product present at levels greater than orequal to 0.1% is identified as probable, possible or confirmed

SAFETY DATA SHEET
According to OSHA Hazard Communication Standard 29CFR 1910.1200(HCS 2012)
GSLA_LMC-6044P Black Aerosol Can

LA LMC-6044P Spray
Product specification
VersionMaterial number

11800
2.5
1379493

Revision Date
Print Date
Page

08/17/2017
02/08/2018
Page 8 of 13

human carcinogen by IARC.
OSHA

No component of this product present at levels greater than orequal to 0.1% is identified as a carcinogen or potential
carcinogen by OSHA.

NTP

No component of this product present at levels greater than orequal to 0.1% is identified as a known or anticipated carcinogen
by NTP.

Reproductive toxicity
Not classified based on available information.
STOT Specific Target Organ Toxicity - single exposure
Not classified based on available information.
STOT Specific Target Organ Toxicity - repeated exposure
Not classified based on available information.
Aspiration toxicity
Not classified based on available information.
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
Product:
Ecotoxicology Assessment
Acute aquatic toxicity: No data available

Chronic aquatic toxicity: No data available

Components:
ethanol:
Toxicity to daphnia and otheraquatic invertebrates: LC50 (Daphnia (water flea)): 9,268 mg/l
Exposure time: 48 h

2-methoxy-1-methylethyl acetate:
Toxicity to fish
: LC50 (Oryzias latipes (Orange-red killifish)): >= 100 mg/l
Exposure time: 96 h
Test Type: semi-static test
Method: OECD Test Guideline 203
GLP: yes

Toxicity to daphnia and otheraquatic invertebrates: EC50 (Daphnia magna (Water flea)): 408 mg/l
Exposure time: 48 h
Test Type: static test
Method: OECD Test Guideline 202
GLP: yes

SAFETY DATA SHEET
According to OSHA Hazard Communication Standard 29CFR 1910.1200(HCS 2012)
GSLA_LMC-6044P Black Aerosol Can

LA LMC-6044P Spray
Product specification
VersionMaterial number

11800
2.5
1379493

Revision Date
Print Date
Page

Persistence and degradability
Product:
Biodegradability: Remarks: No data available

Components:
ethanol:
Biodegradability: Remarks: No data available

butane:Biodegradability: Remarks: No data available

2-methoxy-1-methylethyl acetate:
Biodegradability: Remarks: No data available

propane:
Biodegradability: Remarks: No data available

Bioaccumulative potential
Product:
Bioaccumulation: Remarks: No data available

Components:
ethanol:
Bioaccumulation: Remarks: No data available

Partition coefficient: noctanol/waterbutane:Bioaccumulation
Partition coefficient: noctanol/water: log Pow: -0.349 (24 °C): Remarks: No data available: log Pow: 2.745

2-methoxy-1-methylethyl acetate:
Bioaccumulation: Remarks: No data available

Partition coefficient: noctanol/water: log Pow: 0.43 (20 °C)
pH: 7

propane:Bioaccumulation: Remarks: No data available

Partition coefficient: noctanol/water: Remarks: No data available

08/17/2017
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Page 9 of 13

SAFETY DATA SHEET
According to OSHA Hazard Communication Standard 29CFR 1910.1200(HCS 2012)
GSLA_LMC-6044P Black Aerosol Can

LA LMC-6044P Spray
Product specification
VersionMaterial number

11800
2.5
1379493

Revision Date
Print Date
Page

08/17/2017
02/08/2018
Page 10 of 13

Mobility in soil
Product:
Distribution among
environmental compartments: Remarks: No data available

Components:
ethanol: Distribution among
environmental compartments: Remarks: No data available

butane: Distribution among
environmental compartments: Remarks: No data available

2-methoxy-1-methylethyl acetate:
Distribution among: Remarks: No data available
environmental compartments

propane: Distribution among
environmental compartments: Remarks: No data available

Other adverse effects
Product:
Ozone-Depletion Potential: Regulation: 40 CFR Protection of Environment; Part 82
Protection of Stratospheric Ozone - CAA Section 602 Class I
Substances
Remarks: This product neither contains, nor was
manufactured with a Class I or Class II ODS as defined by the
U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A +B).

SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods
Waste from residues: Dispose of wastes in an approved waste disposal facility.

SECTION 14. TRANSPORT INFORMATION
IATA-DGR
UN number
Proper shipping nameClass
Packing group

:
:
:
:

UN 1950
Aerosols, flammable2.1
Not assigned by regulation

SAFETY DATA SHEET
According to OSHA Hazard Communication Standard 29CFR 1910.1200(HCS 2012)
GSLA_LMC-6044P Black Aerosol Can

LA LMC-6044P Spray
Product specification
VersionMaterial number

11800
2.5
1379493

LabelsPacking instruction (cargo
aircraft)Packing instruction(passenger aircraft)

Revision Date
Print Date
Page

08/17/2017
02/08/2018
Page 11 of 13

: 2.1
: 203
: 203

IMDG-CodeUN number
Proper shipping name: UN 1950: AEROSOLSClass
Packing group
LabelsEmS Code
Marine pollutant: 2.1: Not assigned by regulation: 2.1: F-D, S-U: noTransport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Pollution category: N/AShip type: N/A
National Regulations
49 CFR
UN/ID/NA number
Proper shipping name: UN 1950: AEROSOLSClass
Packing group
LabelsERG Code
Marine pollutant: 2.1: Not assigned by regulation
: 2.1
: 126
: no

SECTION 15. REGULATORY INFORMATIONTSCA list: TSCA 5a - Not relevant

TSCA list: TSCA_12b - Not relevant

EPCRA - Emergency Planning and Community Right-to-Know Act
CERCLA Reportable Quantity
This material does not contain any components with a CERCLA RQ.
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.
SARA 311/312 Hazards: Fire Hazard
Acute Health Hazard

SARA 302: No chemicals in this material are subject to the reporting
requirements of SARA Title III, Section 302.

SAFETY DATA SHEET
According to OSHA Hazard Communication Standard 29CFR 1910.1200(HCS 2012)
GSLA_LMC-6044P Black Aerosol Can

LA LMC-6044P Spray
Product specification
VersionMaterial number

11800
2.5
1379493

SARA 313

Revision Date
Print Date
Page

08/17/2017
02/08/2018
Page 12 of 13: This product contains components that are reportable under
the regulation.
Chromium III CompoundsCobalt,
inorganic compounds

Clean Air Act
This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by
the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B).
This product contains components that are reportable under the regulation.
This product contains components that are reportable under the regulation.
This product contains components that are reportable under the regulation.
Clean Water Act
This product does not contain any Hazardous Substances listed under the U.S. CleanWater Act,
Section 311, Table 116.4A.
This product does not contain any Hazardous Chemicals listed under the U.S. CleanWater Act,
Section 311, Table 117.3.
This product contains components that are reportable under the regulation.
Massachusetts Right To Know
This product contains components that are reportable under
the regulation.
Pennsylvania Right To Know
This product contains components that are reportable under
the regulation.
New Jersey Right To Know
This product contains components that are reportable under
the regulation.
California Prop 65

This product does not contain any chemicals known to Stateof California to cause cancer, birth defects, or any otherreproductive harm.

SAFETY DATA SHEET
According to OSHA Hazard Communication Standard 29CFR 1910.1200(HCS 2012)
GSLA_LMC-6044P Black Aerosol Can

LA LMC-6044P Spray
Product specification
VersionMaterial number

11800
2.5
1379493

Revision Date
Print Date
Page

08/17/2017
02/08/2018
Page 13 of 13

SECTION 16. OTHER INFORMATION
Revision Date

: 08/17/2017

The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release andis not to be considered a warranty or quality specification. The information relates only to thespecific material designated and may not be valid for such material used in combination withany other materials or in any process, unless specified in the text.
US / EN