MATERIAL SAFETY DATA SHEETPRODUCT: SprayREVISION NUMBER: 3

REVISION DATE: 04/27/2006
Date Printed: 04/27/2006

1. PRODUCT AND COMPANY IDENTIFICATIONMANUFACTURED BY:RINSYUNDOU Co.,Ltd.
RSD Building 2F
2-32 Nagarahigashi, Gifu
Gifu, Japan 502-0082

Use the CHEMTREC telephone number only inthe event of chemical emergencies.

PREPARED BY:

Mike Pellegrini
Environmental Engineer

PRODUCT CODE:

LMM-6000AERPRODUCT TRADE NAME:

LMM-6000 METAL MARKI NG AEROSOL SPRAYCAS NO:CHEMICAL FAMILY:PRODUCT TYPE:

MixtureDecorative Coating
Laser Marking Coating

2. COMPOSITION/INFORMATION ON INGREDIENTSThis product does not have exposure limit values. Exposure lim
guideline for safe use of this product.

INGREDIENTS/CAS #Mica Group Minerals
12001-26-2
Molybdenum Trioxide
1313-27-5
Crystalline Silica
14808-60-7Ethyl Alcohol
64-17-5
Methyl Alcohol
67-56-1

it values for some of the components are listed below as a

HAZARDOUS COMPONENTS
OSHA PEL:
TWA: 20 mppcf

ACGIH TLV:TWA: (respirable fraction): 3 mg/m3

TWA Insoluble Mo compounds: 10.0 mg/m3
Soluble Mo compounds: 3.0 mg/m3
TWA respirable dust: 0.1 mg/m3

TWA 5.0 mg/m3

TWA: 1000 ppm;TWA: 1900 mg/m3

TWA: 1000 ppm;TWA: 1880 mg/m3

TWA: 200 ppm; 260 mg/m3

TWA: 200 ppm; 262 mg/m3

TWA respirable dust: 0.05 mg/m3

3. HAZARDS IDENTIFICATION
PRINCIPLE ROUTES OF EXPOSURE: Inhalation, ingestion and dermal.

RINSYUNDOU Co.,Ltd.

Page 1 of 7

PRODUCT TRADE NAME: LMM-6000 METAL MARKING AEROSOL SPRAY

The key immediate hazards are:Skin, eye, and respiratory irritant
Extremely Flammable Aerosol.
Harmful if swallowed or inhaled.

Effects from Acute Exposure:
EYE CONTACT :Causes eye irritation.

SKIN CONTACT:

Causes skin irritation.

INHALATION:

Causes lung irritation.

INGESTION:

May be harmful if swallowed.

AGGRAVATED MEDICAL CONDITIONS:
Respiratory

Effects from Chronic Exposure:
CARCINOGENIC INGREDIENTS:

This product contains greater than 0.1% crystalline silica. The International Agency for Research on Cancer(IARC) has determined that "there is sufficient evidence for the carcinogenicity of crystalline silica toexperimental animals and limited evidence of carcinogenicity in humans. "The National Toxiocology Program(NTP) Sixth Annual Report confirms this determination. It has listed crystalline silica as a substancereasonably anticipated to be a carcinogen.

RINSYUNDOU Co.,Ltd.

Page 2 of 7

PRODUCT TRADE NAME: LMM-6000 METAL MARKING AEROSOL SPRAYOVEREXPOSURE EFFECTS:CONTAINS MOLYBDENUM COMPOUND(S) :Molybdenum compounds can cause eye and respiratory irritation. They can be toxic if swallowed or inhaled
based on animal studies where symptoms included anemia, loss of appetite, diarrhea, tiredness, joint pain andchanges, liver and kidney damage, and lung effects.
CONTAINS CRYSTALLINE SILICA:
Crystalline silica can cause silicosis, a lung disease characterized by coughing, wheezing, impaired lungfunction and increased sputum production. This damage can be progressive and may cause death. May
cause cancer following repeated and prolonged inhalation of the fine dust. Smoking aggravates these effects.
Skin and eye contact may cause irritation due to mechanical abrasion.
CONTAINS DENATURED ALCOHOL:
Overexposure to denatured alcohol can cause serious health effects such as liver toxicity and central nervous
system depression ("drunk"). Use during pregnancy may cause fetal alcohol syndrome. Inhalation may cause
headache and respiratory irritation. Skin and eye irritant. Denaturants are added to discourage ingestion andwill cause nausea and vomiting.
CONTAINS SURFACTANT:This surfactant can cause skin and eye irritation. Symptoms can include redness of skin and eyes, as well astearing.
CONTAINS PROPANE AND ISOBUTANE:
When inhaled, this product is an asphyxiant and may exhibit anesthetic properties at very high concentrations.
Initial symptoms of exposure at these concentrations are disorientation, lack of coordination, rapid respiration,
headache, and nausea. Continued exposure may result in unconsciousness, coma, and possible death.

4. FIRST AID MEASURESINGESTION: If swallowed, give at least 3-4 glasses of water, but do not induce vomiting. Do not give anythingby mouth to an unconscious or convulsing person. Get immediate medical attention.
SKIN: For skin contact, wash affected areas with plenty of water, and soap if available, for several minutes.
Get medical attention if irritation occurs.
INHALATION: If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation develops orif breathing becomes difficult.
EYES: For eye contact, immediately flush eyes for at least 15 minutes with running water. Hold eyelids apart toensure rinsing of the entire eye surface and lids with water. Get immediate medical attention if irritation
develops.
NOTES TO PHYSICIAN: None specified.

RINSYUNDOU Co.,Ltd.

Page 3 of 7

PRODUCT TRADE NAME: LMM-6000 METAL MARKING AEROSOL SPRAY

5. FIRE FIGHTING MEASURESOSHA FLAMMABILITY CLASS: FLAMMABLE
FLASH POINT (°F): -156 F
Flashpoint Method: Pensky-Martin Closed Cup or Grabner Mini-flash
Lower Explosive Limit:

Not Available

Upper Explosive Limit:

Not Available

EXTINGUISHING MEDIA: Carbon Dioxide, Dry Chemical, Foam or Water Mist
FIRE FIGHTING PROCEDURES: Fire-Fighters should wear self-contained breathing apparatus and full protective

clothing when fighting chemical fires.

Use water spray to cool nearby containers and structures exposed to fire.
UNUSUAL HAZARDS: Keep away from heat, sparks and flame.

Decomposition and combustion products may be toxic.
This product presents an extreme fire hazard. Liquid very quickly evaporates, even at low temperatures, andforms vapor (fumes) which can catch fire and burn with explosive violence. Invisible vapor spreads easily andcan be set on fire by many sources such as pilot lights, welding equipment, and electrical motors and switches.
For fires involving this material, do not enter any enclosed or confined fire space without proper protectiveequipment. This may include self-contained breathing apparatus against the hazardous effects of normal
products of combustion or oxygen deficiency. Petroleum gases are heavier than air and travel along theground or into drains to possible distant ignition sources, causing an explosive flashback.

6. ACCIDENTAL RELEASE MEASURESSPILL PROCEDURES: Wear appropriate protective equipment. Avoid the generation of dust. Collect material
and place in closable container(s) for disposal.

7. HANDLING AND STORAGE
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Caution, contents under pressure. Do not
puncture, incinerate, crush, or store above 120 degrees fahrenheit. Heat from sunlight, radiators, stoves, orother sources may cause container to burst.

Store in a cool, dry location away from incompatible materials.
NOTES ON HANDLING INFORMATION: Minimize dust generation during handling. Use adequate ventilation.

8. EXPOSURE CONTROLS/PERSONAL PROTECTIONRINSYUNDOU Co.,Ltd.

Page 4 of 7

PRODUCT TRADE NAME: LMM-6000 METAL MARKING AEROSOL SPRAYVENTILATION: Adequate ventilation should be provided to keep concentrations below acceptable Exposure

Limits. Discharge from the ventilation system should comply with the applicable air pollution controlregulations.

EYE PROTECTION: Wear safety glasses or goggles to protect against exposure.
PROTECTIVE GLOVES: Use gloves as a standard industrial handling procedure.
RESPIRATORY PROTECTION: Appropriate respiratory protection is required when exposure to airborne
contaminant is likely to exceed acceptable limits. Respirators should be selected and used in accordance with
OSHA Subpart I (29 CFR 1910.134) and manufacturer's recommendations.
OTHER PERSONAL PROTECTIVE EQUIPMENT: None specified.

9. PHYSICAL AND CHEMICAL PROPERTIESAPPEARANCE: Off-white Liquid
BOILING POINT: Not Available
VAPOR DENSITY (AIR=1): Heavier than air
EVAP. RATE(BUTYL ACETATE=1): Slower than n-Butyl Acetate
VOC, Wt.% (EPA METH.24): 70 wt.%
BULK DENSITY: 1150 g/L
SOLUBILITY (in water): Insoluble

10. STABILITY AND REACTIVITY
STABILITY DATA: STABLE
POLYMERIZATION: WILL NOT OCCURHAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide and depending on conditions,some hydrocarbon fragments may also be formed.

INCOMPATIBILITY(MATERIALS TO AVOID): Strong oxidizing agents
CONDITIONS/HAZARDS TO AVOID: Keep away from heat,sparks and flame.

11. TOXICOLOGICAL INFORMATIONNo Toxicological data known.

12. ECOLOGICAL INFORMATIONECOTOXICOLOGICAL INFORMATION: No data at this time

RINSYUNDOU Co.,Ltd.

Page 5 of 7

PRODUCT TRADE NAME: LMM-6000 METAL MARKING AEROSOL SPRAYCHEMICAL FATE INFORMATION: No data at this time.
PERSISTENCE/DEGRADABILITY: No data at this time.
APPRAISAL: No data at this time.
MOBILITY: No data at this time.

13. DISPOSAL CONSIDERATIONSDISPOSAL OF WASTE METHOD: Dispose in accordance with Federal, State and Local regulations.

14. TRANSPORT INFORMATIONDOT Shipping Name: CONSUMER COMMODITY
DOT HAZARD CLASS: ORM-D
DOT LABEL(S): NONE
UN/NA NUMBER: UN8000
PACKING GROUP: NONE

15. REGULATORY INFORMATIONSARA SECTION 302: None Found
SARA (311, 312) HAZARD CLASS: ACUTE HEALTH HAZARDCHRONIC HEALTH HAZARD
FIRE HAZARD

SARA 313 Title III Toxic Chemical List:
The following chemicals are subject to the reporting requirements of Section 313 of Title III of the SuperfundAmendments and Reauthorization Act of 1986 and 40 CFR part 372.
221% Vanadium% Molybdenum Trioxide% Methanol% Methyl Isobutyl Ketone<1%21%<1%<1%This product (and/or all of its components) is in compliance with the U.S. EPA Toxic
Substance Control Act, TSCA, (15 U.S.C. 2604).
This product and all of its components is listed on the DSL inventory.

TSCA Inventory Status:

16. OTHER INFORMATION
Revisions: The Format has been changed to meet the requirements of the new ANSI Standard Z400.1.

RINSYUNDOU Co.,Ltd.

Page 6 of 7

PRODUCT TRADE NAME: LMM-6000 METAL MARKING AEROSOL SPRAYLABEL INFORMATION:DANGER!
Extremely flammable.
Keep away from heat, sparks and flame.
Vapors will accumulate and may ignite explosively. Turn off all sources of flame and sparks before use. Do
not smoke. Keep area well ventilated until all vapors (odors) are gone.
Contains crystalline silica which can cause lung damage, including cancer.
Skin, eye, and respiratory irritant.
Avoid contact with eyes, skin and clothing.
Harmful if swallowed or inhaled.
Keep away from food products.
Avoid breathing dust, mist or vapor.
Wash thoroughly after handling and before eating, drinking or using cosmetic or tobacco products or toilet
facilities.
Use with adequate ventilation.
Keep container closed when not in use.
FIRST AID: If inhaled, remove to fresh air. If breathing is difficult, give oxygen. In case of contact, immediately
flush eyes or skin with plenty of water. Remove contaminated clothing. Get medical attention.
IN CASE OF FIRE: Use water, dry chemical or carbon dioxide.
IN CASE OF SPILL: Soak up with inert absorbent and dispose in accordance with federal, state and localregulations.
FOR INDUSTRIAL USE ONLY.
Do not breathe dust.
WARNING!
IN CASE OF SPILL: Collect and dispose in accordance with federal, state and local regulations.
DEFINITIONS AND ABBREVIATIONS :ACGIHC (CEIL)
CAS #EPA
IARC
NIOSH
NTP
OSHA
PEL
SARA
STEL
TLV
TSCA
TWA
VOC

= American Conference of Governmental Industrial Hygienists= The concentration that shall not be exceeded during any part of the working exposure.
= Chemical Abstracts Service Registry Number= Environmental Protection Agency= International Agency for Research on Cancer= National Institute for Occupational Safety and Health= National Toxicology Program= Occupational Safety and Health Administration= Permissible Exposure Limit= Superfund Amendments and Reauthorization Act= Short Term Exposure Limit. Usually a 15 minute time weighted average exposure.
= Threshold Limit Values= Toxic Substance Control Act= Time Weighted Average. Exposure concentration for a normal 8 hour day or 40 hour week.
= Volatile Organic Content
DISCLAIMER: The information contained in this Material Safety Data Sheet (MSDS) has been compiled fromsources believed to be reliable and to represent the most reasonable current opinion on the subject when theMSDS was prepared. No guarantee is made as to the correctness or sufficiency of the information. The userof this product must decide what safety measures are necessary to safely use this product, either alone or in
combination with other products, and determine the regulatory compliance obligations under any applicable
federal or state laws.
*** END OF MSDS ***RINSYUNDOU Co.,Ltd.

Page 7 of 7