'LYLVLRQRI6\QWKHWLF&KHPLVWU\±6WUXFWXUDO2UJDQLF&KHPLVWU\±KWWSVZZZVFON\RWRXDFMSaNRX]RXHQLQGH[KWPO

Prof
085$7$<DVXMLUR'(QJ

Assoc Prof
Assist Prof+,526(7DNDVKL +$6+,.$:$<RVKLIXPL
'(QJ
'(QJ

6WXGHQWV+8$1**XDQJOLQ '
=+$1*=KHQJ '+8:HL]KH '*8-LDMLDQ '/,8=KLER '
6+,085$5HR 8*

Guest Res Assoc&+$2/80(1 3K' ,QQHU0RQJROLD8QLYHUVLW\35&KLQD$XJXVW±$XJXVW

 6FRSHRI5HVHDUFK)XQGDPHQWDO VWXGLHV DUH EHLQJ FRQGXFWHG IRU WKH FUHDWLRQ RI QHZ IXQFWLRQDO ʌV\VWHPV ZLWK QRYHO VWUXFWXUHV DQGS URSHUWLHVDQGIRUHYDOXDWLRQRIWKHLUDSSOLFDWLRQDVRUJDQLFVHPLFRQGXFWLQJPDWHULDOVIRUSKRWRYROWDLFDQGHOHFWUROXPLQHVFHQWGHYLFHV7KHPDMRUVXEMHFWVDUH RUJDQRFKHPLFDOWUDQVIRUPDWLRQRIIXOOHUHQHV& and CVSHFL¿FDOO\RUJDQLF
V\QWKHVLVRIHQGRKHGUDOIXOOHUHQHVE\WKHWHFKQLTXHRIPROHFXODUVXUJHU\ JHQHUDWLRQRILRQLFIXOOHUHQHVSHFLHVDQGWKHLUDSSOLFDWLRQIRU
.(<:25'6WKHV\QWKHVLVRIIXQFWLRQDOPDWHULDO V\QWKHVLVRIQHZFDUERQULFKʌ&RQMXJDWHG6\VWHPV(QGRKHGUDO)XOOHUHQHVPDWHULDOVE\WKHXVHRIWUDQVLWLRQPHWDOFRPSOH[DQG FUHDWLRQRI)XQFWLRQDO0DWHULDOV+HOLFDO6WUXFWXUHVQHZIXQFWLRQDOʌPDWHULDOVZLWKXQLTXHSKRWRHOHFWULFSURSHUWLHV
5DGLFDO6SHFLHV

5HFHQW6HOHFWHG3XEOLFDWLRQV=KDQJ=0XUDWD<+LURVH7&LUFXODUO\3RODUL]HG/XPLQHVFHQFHRI+HWHUR>n@KHOLFHQHVZLWK7KLDGLD]ROH5LQJVDW%RWK(QGV'HVLJQRI0DJQHWLFDOO\$OORZHG(OHFWURQLF7UDQVLWLRQVYLD+HWHURDWRP(PEHGGLQJTetrahedron142,  +XDQJ*,GH<+DVKLNDZD<+LURVH70XUDWD<&+3CN@open-C$Q(൵HFWLYH,QQHU6SDFH0RGL¿FDWLRQDQG,VRWRSH(൵HFWLQVLGH
D1DQR6L]HG)ODVNChem.-Eur. J.29H  +DVKLNDZD<6DGDL60XUDWD<%LODWHUDOʌ([WHQVLRQRIDQ2SHQ>@)XOOHUHQHLQD+HOLFDO0DQQHUChem. Commun.59,
 6DGDL6+DVKLNDZD<0XUDWD<ʌ([WHQGHG2SHQ>@)XOOHUHQHVZLWKD)XVHG$]DDFHQHOrg. Lett.25  +DVKLNDZD<6DGDL62NDPRWR60XUDWD<1HDU,QIUDUHG$EVRUELQJ&KLUDO2SHQ>@)XOOHUHQHVAngew. ChemInt. Ed.62H
 

TOPICS AND INTRODUCTORY COLUMNS OF LABORATORIESTopics
1HDU,QIUDUHG$EVRUELQJ&KLUDO2SHQ>@Fullerenes>@)XOOHUHQHLVDQDFKLUDOPROHFXODUQDQRFDUERQZLWKIhV\PPHWU\ ZKLOH LW FRXOG DWWDLQ DQ LQKHUHQW FKLUDOLW\ GHSHQGLQJXSRQDIXQFWLRQDOL]DWLRQSDWWHUQ7KHFRQYHQWLRQDOchiral induction of CUHOLHVPDLQO\XSRQDPXOWLSOHDGGLWLRQWKXVD൵RUGLQJDPL[WXUHRIDFKLUDODQGFKLUDOLVRPHUV,Q PRVW FDVHV KRZHYHU WKHLU FKLUDO IXQFWLRQ ZRXOG EH
ODUJHO\R൵VHWE\SVHXGRPLUURUSODQH V 7KHVHDUHPDMRUREVWDFOHV WR SURFHHG IXUWKHU VWXG\ RQ IXOOHUHQH FKLUDOLW\DQG\HWOHDYHLWVXQGHUVWDQGLQJHOXVLYH,QWKLVVWXG\ZH
GHYHORSHGDFDUEHQHPHGLDWHGV\QWKHVLVRICV\PPHWULF
FKLUDO RSHQ>@IXOOHUHQHV VKRZLQJ DQ LQWHQVH IDUUHG WR
QHDULQIUDUHG DEVRUSWLRQ7KH ODUJH GLVV\PPHWU\ IDFWRU
of |gabs_   ZDV FRQ¿UPHGDWȜ  QPIRU FLUFXODUGLFKURLVPLQEHQ]RQLWULOH7KLVLVLQJHQHUDOXQDFKLHYDEOH
E\RWKHUVPDOOFKLUDORUJDQLFPROHFXOHVGHPRQVWUDWLQJWKH
SRWHQWLDO XVDJH RI RSHQ>@IXOOHUHQHV DV QRYHO W\SHV RI
chiral chromophores.

DWLYHRIDVWUHQJWKHQHGHOHFWURQDFFHSWLQJDELOLW\ZKLFKLV
PDLQO\ DWWULEXWHG WR D FDJH GHIRUPDWLRQ DV VXSSRUWHG E\FRPSXWDWLRQDOVWXGLHV7KHVHUHVXOWVDUHGHPRQVWUDWLYHRI
trapped species working as a modulator for external propHUWLHVRI>@IXOOHUHQHVIURPWKHLQWHULRU)LJXUH$FHWRQLWULOHWUDSSHGZLWKLQD>@IXOOHUHQHFDJH'HVLJQRI0DJQHWLFDOO\$OORZHG(OHFWURQLF
Transitions by Heteroatom Embedding for an(൶FLHQW&LUFXODUO\3RODUL]HG/XPLQHVFHQFH
&3/)LJXUH$QLQKHUHQWO\FKLUDORSHQ>@IXOOHUHQH

CH3&1#RSHQ&60$Q(൵HFWLYH,QQHU6SDFH0RGL¿FDWLRQDQG,VRWRSH(൵HFWLQVLGHD1DQR6L]HG)ODVN
7KHODUJHRUL¿FHZLWKDULQJDWRPFRXQWRIRQD>@IXOOHUHQHFDJHZDVIRXQGWRDOORZIRUDPROHFXOHRI&+3CNWR EH WUDSSHG LQVLGH WKH FDUERQ QDQRFDYLW\ XQGHU KLJKSUHVVXUH FRQGLWLRQV7KH WKXV IRUPHG PROHFXODU FRPSOH[H[KLELWHG D KLJKHU SRODULW\ WKDQ WKH HPSW\ FDJH RQ VLOLFDJHO UHÀHFWLQJ DQ LQFUHDVHG PROHFXODU GLSROH PRPHQW)XUWKHUPRUH WKH HQFDSVXODWLRQ RI &+3CN caused less
QHJDWLYHUHGXFWLRQVZLWKUHVSHFWWRHPSW\RQHEHLQJLQGLF-'HVLJQ RI H[FHOOHQW FLUFXODUO\ SRODUL]HG OXPLQHVFHQFH
&3/ HPLWWHUVUHTXLUHVFKLUDOPROHFXOHVZLWKODUJHWUDQsition magnetic dipole moments 70'0 _m|). In this
ZRUN >@ >@ DQG >@KHOLFHQH GHULYDWLYHV ZLWK WKLDGLD]ROHULQJVDWERWKHQGVZHUHGHVLJQHGDQGV\QWKHVL]HG:HUHYHDOHGWKDWWKH>@KHOLFHQHGHULYDWLYH 7'>@H VKRZHGDQH[FHOOHQW&3/ZLWKDODUJHglumRIDW
QPLQWROXHQHZKLFKZDVVLJQL¿FDQWO\ODUJHUWKDQWKDWRIXQVXEVWLWXWHGFDUER>@KHOLFHQH glum  'HQVLW\IXQFWLRQDO WKHRU\ ')7  FDOFXODWLRQV VXJJHVWHG WKDW WKH
remarkable glum of 7'>@+ was attributed to the magnetiFDOO\DOORZHGWUDQVLWLRQZLWKDODUJH70'0 _m_ îíHUJ*í IRUWKH6ĺ60 transition.

)LJXUH(QKDQFHPHQWRIWKHGLVV\PPHWU\IDFWRURI&3/ glum E\KHWeroatom embedding.

ICR ANNUAL REPORT, 2023