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Diaqua(1,4,7,10,13-pentaoxacyclopentadecane)iron(II)bis(µ-cis -1,2-dicyano-1,2-ethylenedithiolato)bis[(cis -1,2dicyano-1,2-ethylenedithiolato)ferrate(III)]
1,4,7,10,13-pentaoxacyclopentadecane disolvate
Toshiki Yamaguchi, Shigeyuki Masaoka and Ken Sakai

Acta Cryst. (2008). E64, m1557–m1558

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Acta Cryst. (2008). E64, m1557–m1558

Yamaguchi et al. · [Fe(C10 H20 O5 )(H2 O)2 ][Fe2 (C4 N2 S2 )4 ]·2C10 H20 O5

metal-organic compounds
Acta Crystallographica Section E

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Diaqua(1,4,7,10,13-pentaoxacyclopentadecane)iron(II) bis(l-cis-1,2-dicyano-1,2ethylenedithiolato)bis[(cis-1,2-dicyano1,2-ethylenedithiolato)ferrate(III)]
1,4,7,10,13-pentaoxacyclopentadecane
disolvate[Fe(C10H20O5)(H2O)2][Fe2(C4N2S2)4]2C10H20O5
Mr = 1425.08
Monoclinic, P21 =c
a = 13.376 (4) Å
b = 15.739 (4) Å
c = 30.069 (8) Å = 91.600 (4)V = 6328 (3) Å3
Z=4
Mo K radiation
 = 1.01 mm 1
T = 100 (2) K
0.20  0.05  0.04 mm

Data collection
Bruker SMART APEX CCD areadetector diffractometer
Absorption correction: multi-scan(SADABS; Sheldrick, 1996)
Tmin = 0.742, Tmax = 0.960

Toshiki Yamaguchi, Shigeyuki Masaoka and Ken Sakai*Reﬁnement

Department of Chemistry, Faculty of Science, Kyushu University, Hakozaki 6-10-1,
Higashi-ku, Fukuoka 812-8581, Japan
Correspondence e-mail: ksakai@chem.kyushu-univ.jp

R[F 2 > 2(F 2)] = 0.036
wR(F 2) = 0.073
S = 1.04
13837 reﬂections
755 parameters

68765 measured reﬂections
13837 independent reﬂections
10591 reﬂections with I > 2(I)Rint = 0.056

H atoms treated by a mixture ofindependent and constrained
reﬁnementmax = 0.55 e Å 3
min = 0.34 e Å 3

Received 30 October 2008; accepted 8 November 2008
Key indicators: single-crystal X-ray study; T = 100 K; mean (C–C) = 0.003 Å;
R factor = 0.036; wR factor = 0.073; data-to-parameter ratio = 18.3.

The title compound, [Fe(C10H20O5)(H2O)2][Fe2(C4N2S2)4]2C10H20O5, consists of an [FeII(15-crown-5)(H2O)2]2+ cation,
sandwiched between and O—H  O hydrogen bonded by two
additional 15-crown-5 ether molecules and two independent[FeIII(mnt)2] anions, where 15-crown-5 ether denotes
1,4,7,10,13-pentaoxacyclopentadecane and mnt denotes cis1,2-dicyano-1,2-ethylenedithiolate.
Each
independent[FeIII(mnt)2] unit forms a centrosymmetric dimer supported
by two intermonomer FeIII—S bonds [Fe—S = 2.4715 (9) and2.4452 (9) Å]. In the crystal structure, the dimers form onedimensional – stacks along the a axis, with an interplanar
separation of 3.38 (6) Å.

Related literature
For general background, see: Adams (1990); Frey (2002);
Georgakaki et al. (2003); Gloaguen et al. (2001); Liu et al.
(2005); McCleverty et al. (1967); Na et al. (2006); Nicolet et al.
(1999); Peters et al. (1998); Sakata (2000); Sellmann et al.
(1991); Sun et al. (2005); Trasatti (1972); Yamaguchi et al.
(2008). For related structures, see: Hamilton & Bernal (1967);
Hao et al. (2005).

Table 1

Hydrogen-bond geometry (Å,  ).
D—H  A

D—H

H  AD  A

D—H  A

O6—H1  O8
O6—H2  O10
O7—H3  O13
O7—H4  O16

0.78 (3)0.76 (3)0.76 (3)0.81 (3)1.96 (3)2.13 (3)2.04 (3)1.94 (3)2.726 (3)2.882 (2)2.779 (2)2.740 (2)171 (3)173 (3)164 (3)170 (3)

Data collection: APEX2 (Bruker, 2007); cell reﬁnement: SAINT(Bruker, 2007); data reduction: SAINT; program(s) used to solve
structure: SHELXS97 (Sheldrick, 2008); program(s) used to reﬁne
structure: SHELXL97 (Sheldrick, 2008); molecular graphics: KENX
(Sakai, 2004); software used to prepare material for publication:
SHELXL97, TEXSAN (Molecular Structure Corporation, 2001),
KENX and ORTEPII (Johnson, 1976).

This work was supported in part by a Grant-in-Aid for
Scientiﬁc Research (A) (No. 17205008), a Grant-in-Aid forSpecially Promoted Research (No. 18002016), and a Grant-inAid for the Global COE Program (’Science for Future
Molecular Systems’) from the Ministry of Education, Culture,
Sports, Science and Technology of Japan.
Supplementary data and ﬁgures for this paper are available from the
IUCr electronic archives (Reference: LH2727).

References
Adams, M. W. W. (1990). Biochim. Biophys. Acta, 1020, 115–145.
Bruker (2007). APEX2 and SAINT. Bruker AXS Inc., Madison, Wisconsin,
USA.
Frey, M. (2002). ChemBioChem, 3, 153–160.
Georgakaki, I. P., Thomson, L. M., Lyon, E. J., Hall, M. B. & Darensbourg, M.
Y. (2003). Coord. Chem. Rev. 238–239, 255–266.
Gloaguen, F., Lawrence, J. D. & Rauchfuss, T. B. (2001). J. Am. Chem. Soc. 123,
9476–9477.
Hamilton, W. C. & Bernal, I. (1967). Inorg. Chem. 6, 2003–2008.
Hao, X., Siegler, M. A., Parkin, S. & Brock, C. P. (2005). Cryst. Growth Des. 5,2225–2232.
Acta Cryst. (2008). E64, m1557–m1558

doi:10.1107/S1600536808036805

electronic reprint

Yamaguchi et al.

m1557

metal-organic compounds
Johnson, C. K. (1976). ORTEPII. Report ORNL-5138. Oak Ridge National
Laboratory, Tennessee, USA.
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(1967). J. Am. Chem. Soc. 89, 6082–6092.
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Texas, USA.
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691, 5045–5051.
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(1999). Structure, 7, 13–23.

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282, 1853–1858.
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5264.
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1663.
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Yamaguchi, T., Masaoka, S. & Sakai, K. (2008). Unpublished results.

Yamaguchi et al.  [Fe(C10H20O5)(H2O)2][Fe2(C4N2S2)4]2C10H20O5

electronic reprint

Acta Cryst. (2008). E64, m1557–m1558

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E-""!#G   -    1!  % % %!  9  '%&% !1! #  CC% $ 9 CCF 47 I CCF, = I-""

!#G   -   % %$% )%!17 =I!()#1!.
,, '%!1% % % %!  ! $% ! 9 8 !% # %)%$C#%   4E-. ,, ! 0%%(! % ! ! C#%  9  = D == E( !%   ! ! C#%  9  ==, D =, E %" %! % #% ! 0%%"1!  #)#%! #  ! %%&%! $%2$=%&!1%!  "%1! )% #J%% %!  '%!1% ! %(:#'%%)"! $KK%& $ %! 1! #(' '!%#B%   ! '! "!  #0 # %& $$! "
% (1! # "% +!'  $ %!1%! ;C;=H/C/% #%!1;, ; / 7%)%$ 1% ! (! !KK%!%! %$! "  0% %0%%! %%#%4 47 E(%#! %)%$1!1%! ;, ; /% #71! (0% #1 #("%! ;C;=H/C/ % # 0!% !! %%$! "%;=C;F4 44 % #/C;F4 4=4 E" 

"!#1!   ;! 0! #9 '%00%#%1!!' /%999
,7 !%!! !1/%999  48'%00%#%0)!"#(#?;)"  48 $  7!  % !  '%%###!'  ,$ ,!  $#%&(!' !! '%#1!  % #)%0!%# ###0 "%:%! %# % # $!1!! %!!  0%1!=#%"%11!##(%& #!19 ''!#("1%! '%#'!#% ! % ### @#G $4,L  % $ %%! % %(!(electronic reprint 

4L!1990)%#("?M(%0!!0" @% %$  0(# 99! %%%#("!'  ! %!  + %"%%#1!;=77=4/8G; 4 - = 4-/  7 ! #G; 4 7=- = -/  ,7 9*N   G447' 47' ' 7' = 7' = ='=7' 44 4' ,' 7' =, =  4 4, ,7 ,4  4 7' =7'  =4' =' =' 
%! 201!!!1'% !'0%# #%:#0!!  " ;CF ,,E % # ## 1    %# $ !#%00!2 %! '! F O6 " ; %! !1'% !
'1 #!!0%" "#!$ (! # $$! !1%! '00!)%#"!10!! #  #("%6%%%!  9 1 %#11 ! %0 $0%&'%!%# ,E1!
%!  #0!'%!%# E1! %!  $  !199!'  4A%! !' $%! %( $ 
"#!$ %! 201!!!1'% !%! #1!%"  %0!#%#0%"#%L0!(%(" P%#  #%"#!$ (! #$  "%!1!  #0 # # !1999   !' $%! %( $ ""!#G     %0!#%#0%"#%L0!(%("$ 4 !1! # #0 # # !1999   !' $%! %( $ ""!#G     %0!#%#0%"#%L0!(%("$ = +)'%! $%2 !' $ %  '%! % #% ! 0%
%"%&%! $%2!$)! #  ! %!  "#!$ %! %! #1!
%"  %0!#%#0%"#%L0!(%("$  +)'00 #%!0% #1 #("%! ;C;=H/C/'%%K
%&!0% #1 #("%! ;, ; /% #7""!#1!    %0!#%#0%"#%L0!(%("%( %0%% 1!"#!$ (! #1! #(' %2%%6%$% #% #!'  ! 99!'  4A!

electronic reprint

   !(#" ( ) 

 ""# "$ %%$&'(#" ( )
# ) $&*# ) $  %%%$+ ! ""# "#,
;8 8 ;=/ =Q;8F, F= 

2F =,7?$?! !  H
%" (!G."(F4 47= E!F 4,= E
F4 7, E
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R
WF "F X/# (%& Z Z =
<&?+*+. [;;P%%#!#11%!
44 #0 # 1! *%#%! !G!% $% !#'% !1!,1! '%\]% $ & F 7?! !! %!G$%0"F X

U %2F V^% #_% 

U  F V+(!0! !! G %+P+<-#& ,,7"  F = " %2F ,7
77 %#1! 'FR`(FR`
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*1   ! ! #%"%! !%! G#11 ! %0&\] F 47

"#!$ !%! G 1#1!  $(! $%! %#("% 2!1
 #0 # % #! % #1   *& F 4

*FH]! A 7 A4 

5%6% %2G1

electronic reprint 'F!A H4%2F 

F =aH]

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0%% 

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2 ! !11 Gc+
4# /! 11% '% #% #!1#%%!! !)%%% "0!(#%"0 !  !  
'%B#$#!( $$(  !#%"!! '%%00#!#%%
5/# +  # d20  #  ##%% $(' '!  0%  % %# $1!)%%  %
2   # d%%&  !%!  #)#%"  %! !1  # d #%  % $% #!! % $-!%! ('   # d 0%% %! "#' "%#1 #(""%"" + %00!2 %!!0 %  !1  # d#1! % $  # d )!) $  0% 
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